# Electronic Supplementary Material (ESI) for Chemical Science.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_Homo-4
_database_code_depnum_ccdc_archive 'CCDC 1946051'
loop_
_audit_author_name
_audit_author_address
Lu
;Fudan university
China
;
_audit_update_record             
;
2019-08-08 deposited with the CCDC.	2020-10-05 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C93 H110 F12 N4 O28 Rh4 S8'
_chemical_formula_weight         2627.96

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0137 0.0067 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0583 0.0400 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0241 0.0134 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0389 0.0241 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -0.0161 2.8414 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.2925 0.4295 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 2/c'
_space_group_name_Hall           '-C 2yc'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   71.953(14)
_cell_length_b                   17.886(5)
_cell_length_c                   37.342(8)
_cell_angle_alpha                90
_cell_angle_beta                 96.315(8)
_cell_angle_gamma                90
_cell_volume                     47767(19)
_cell_formula_units_Z            16
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    9750
_cell_measurement_theta_min      2.83
_cell_measurement_theta_max      45.33

_exptl_crystal_description       prism
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.462
_exptl_crystal_F_000             21376
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.390
_exptl_crystal_size_mid          0.080
_exptl_crystal_size_min          0.040
_exptl_absorpt_coefficient_mu    4.328
_shelx_estimated_absorpt_T_min   0.283
_shelx_estimated_absorpt_T_max   0.846
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.419
_exptl_absorpt_correction_T_max  0.703
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     1.34138
_diffrn_radiation_type           GaK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            228175
_diffrn_reflns_av_unetI/netI     0.1209
_diffrn_reflns_av_R_equivalents  0.0985
_diffrn_reflns_limit_h_min       -92
_diffrn_reflns_limit_h_max       90
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -47
_diffrn_reflns_limit_l_max       47
_diffrn_reflns_theta_min         1.075
_diffrn_reflns_theta_max         59.205
_diffrn_reflns_theta_full        53.594
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             51861
_reflns_number_gt                24148
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 Structure factors included contributions from the .fab file. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          
; 
 32 ISOR, 2 DELU and 28 DFIX instructions were used to 
 restrain anions, ligands and Cp* fragments so that there 
 were 222 restraints in the data. Hydrogen of methanol 
 molecule could not be found and others were put in 
 calculated positions. 
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1541P)²+15.0752P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         51861
_refine_ls_number_parameters     2144
_refine_ls_number_restraints     222
_refine_ls_R_factor_all          0.1527
_refine_ls_R_factor_gt           0.0854
_refine_ls_wR_factor_ref         0.3086
_refine_ls_wR_factor_gt          0.2573
_refine_ls_goodness_of_fit_ref   1.061
_refine_ls_restrained_S_all      1.068
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.65766(2) -0.12618(3) 0.18282(2) 0.08519(18) Uani 1 1 d . . . . .
Rh2 Rh 0.57201(2) -0.06964(4) 0.30081(2) 0.1130(3) Uani 1 1 d . . . . .
Rh3 Rh 0.73981(2) 0.68684(3) 0.28310(2) 0.08792(19) Uani 1 1 d . . . . .
Rh4 Rh 0.65474(2) 0.74454(3) 0.40045(2) 0.0922(2) Uani 1 1 d . . . . .
Rh5 Rh 0.58454(2) 0.13030(4) 0.07946(2) 0.1153(3) Uani 1 1 d . . . . .
Rh6 Rh 0.51364(2) 0.45790(5) 0.11894(2) 0.1231(3) Uani 1 1 d . . . . .
Rh7 Rh 0.69593(2) 0.23256(4) 0.46998(2) 0.0960(2) Uani 1 1 d . . . . .
Rh8 Rh 0.60605(2) 0.45032(5) 0.52403(3) 0.1391(4) Uani 1 1 d . . . . .
N1 N 0.66497(9) -0.0178(3) 0.20377(18) 0.0860(16) Uani 1 1 d . . . . .
N2 N 0.72361(10) 0.5902(4) 0.2667(3) 0.100(2) Uani 1 1 d . . . . .
N3 N 0.58567(13) 0.0312(4) 0.3175(3) 0.118(3) Uani 1 1 d . . . . .
N4 N 0.64527(10) 0.6390(3) 0.3805(2) 0.0913(18) Uani 1 1 d . . . . .
N5 N 0.59917(13) 0.1610(5) 0.13046(18) 0.109(2) Uani 1 1 d . . . . .
N6 N 0.67972(9) 0.2132(4) 0.42083(18) 0.0891(16) Uani 1 1 d . . . . .
N7 N 0.52850(13) 0.4574(5) 0.1697(3) 0.131(3) Uani 1 1 d . . . . .
N8 N 0.59659(12) 0.4235(5) 0.4705(3) 0.125(3) Uani 1 1 d . . . . .
O1 O 0.64968(8) -0.1467(3) 0.23474(13) 0.0894(14) Uani 1 1 d . . . . .
O2 O 0.62967(8) -0.0863(3) 0.17858(14) 0.0921(14) Uani 1 1 d . . . . .
O3 O 0.58002(10) -0.0486(3) 0.24841(17) 0.1086(17) Uani 1 1 d . . . . .
O4 O 0.59919(9) -0.1149(3) 0.30343(17) 0.1084(17) Uani 1 1 d . . . . .
O5 O 0.73175(7) 0.6704(3) 0.33482(15) 0.0927(14) Uani 1 1 d . . . . .
O6 O 0.71364(7) 0.7415(2) 0.28122(13) 0.0821(12) Uani 1 1 d . . . . .
O7 O 0.66229(7) 0.7665(3) 0.34810(13) 0.0845(12) Uani 1 1 d . . . . .
O8 O 0.68181(8) 0.6969(3) 0.40290(14) 0.1011(16) Uani 1 1 d . . . . .
O9 O 0.58038(9) 0.2476(3) 0.07292(15) 0.1012(15) Uani 1 1 d . . . . .
O10 O 0.55904(9) 0.1490(4) 0.10222(16) 0.1127(17) Uani 1 1 d . . . . .
O11 O 0.51649(8) 0.3397(4) 0.12092(18) 0.1175(19) Uani 1 1 d . . . . .
O12 O 0.53970(8) 0.4399(3) 0.09899(18) 0.1125(19) Uani 1 1 d . . . . .
O13 O 0.68412(7) 0.3420(3) 0.46917(14) 0.0945(14) Uani 1 1 d . . . . .
O14 O 0.67087(8) 0.2140(3) 0.49261(15) 0.1015(15) Uani 1 1 d . . . . .
O15 O 0.61849(10) 0.3416(4) 0.5271(2) 0.140(2) Uani 1 1 d . . . . .
O16 O 0.63210(10) 0.4715(4) 0.50488(19) 0.127(2) Uani 1 1 d . . . . .
O17 O 0.70493(15) 1.0657(4) 0.3365(2) 0.158(3) Uani 1 1 d . . . . .
O18 O 0.68204(14) 0.9600(5) 0.3328(3) 0.178(3) Uani 1 1 d . . . . .
O19 O 0.7017(3) 0.9982(7) 0.3875(3) 0.258(7) Uani 1 1 d . U . . .
O20 O 0.75890(19) 0.4366(8) 0.3299(2) 0.232(6) Uani 1 1 d . . . . .
O21 O 0.76485(14) 0.3490(5) 0.3799(2) 0.160(3) Uani 1 1 d . . . . .
O22 O 0.73289(16) 0.3895(8) 0.3591(3) 0.216(5) Uani 1 1 d . . . . .
O23 O 0.43199(16) 0.6846(6) 0.0714(4) 0.227(6) Uani 1 1 d . . . . .
O24 O 0.44927(19) 0.5667(6) 0.0740(4) 0.222(5) Uani 1 1 d . . . . .
O25 O 0.4587(2) 0.6555(9) 0.1194(4) 0.227(5) Uani 1 1 d . . . . .
S1 S 0.70353(3) 0.28949(10) 0.29032(6) 0.0944(6) Uani 1 1 d . . . . .
S2 S 0.67949(3) 0.29056(11) 0.18358(6) 0.1020(6) Uani 1 1 d . . . . .
S3 S 0.62964(3) 0.33050(11) 0.40125(6) 0.0977(6) Uani 1 1 d . . . . .
S4 S 0.60370(3) 0.33434(11) 0.29595(6) 0.0937(6) Uani 1 1 d . . . . .
S5 S 0.65000(3) 0.29800(9) 0.27942(5) 0.0851(5) Uani 1 1 d . . . . .
S6 S 0.63172(3) 0.07628(10) 0.26767(5) 0.0900(5) Uani 1 1 d . . . . .
S7 S 0.57429(4) 0.54067(14) 0.33239(9) 0.1258(9) Uani 1 1 d . . . . .
S8 S 0.55297(4) 0.32815(15) 0.30542(10) 0.1292(9) Uani 1 1 d . . . . .
S9 S 0.69909(6) 0.99884(15) 0.35050(8) 0.1391(11) Uani 1 1 d . . . . .
S10 S 0.75306(7) 0.4048(3) 0.36253(10) 0.1732(15) Uani 1 1 d . . . . .
S11 S 0.44756(8) 0.6475(3) 0.08332(18) 0.205(2) Uani 1 1 d . . . . .
F1 F 0.71696(15) 0.8705(4) 0.3525(3) 0.215(4) Uani 1 1 d D U . . .
F2 F 0.7131(2) 0.9265(5) 0.3022(4) 0.259(6) Uani 1 1 d D U . . .
F3 F 0.7330(2) 0.9670(8) 0.3462(6) 0.339(9) Uani 1 1 d D U . . .
F4 F 0.75121(12) 0.4689(5) 0.42573(19) 0.169(3) Uani 1 1 d . . . . .
F5 F 0.77268(16) 0.5076(4) 0.3981(2) 0.176(3) Uani 1 1 d . . . . .
F6 F 0.74489(17) 0.5411(6) 0.3818(2) 0.228(5) Uani 1 1 d . U . . .
F7 F 0.4770(2) 0.6712(10) 0.0548(5) 0.333(9) Uani 1 1 d D U . . .
F8 F 0.4500(2) 0.6867(7) 0.0165(4) 0.265(5) Uani 1 1 d D U . . .
F9 F 0.4607(3) 0.7673(7) 0.0594(5) 0.330(9) Uani 1 1 d D U . . .
C1 C 0.63316(13) -0.1236(4) 0.2400(2) 0.086(2) Uani 1 1 d . . . . .
C2 C 0.62153(12) -0.0894(4) 0.2080(2) 0.086(2) Uani 1 1 d . . . . .
C3 C 0.60395(13) -0.0638(4) 0.2102(2) 0.094(2) Uani 1 1 d . . . . .
H3 H 0.5969 -0.0415 0.1901 0.113 Uiso 1 1 calc R U . . .
C4 C 0.59648(14) -0.0712(4) 0.2435(2) 0.095(2) Uani 1 1 d . . . . .
C5 C 0.60778(13) -0.1077(4) 0.2755(2) 0.095(2) Uani 1 1 d . . . . .
C6 C 0.62589(13) -0.1295(4) 0.2731(2) 0.092(2) Uani 1 1 d . . . . .
H6 H 0.6334 -0.1483 0.2936 0.111 Uiso 1 1 calc R U . . .
C7 C 0.71551(11) 0.6917(4) 0.3395(2) 0.0794(18) Uani 1 1 d . . . . .
C8 C 0.70457(10) 0.7311(3) 0.30859(19) 0.0737(17) Uani 1 1 d . . . . .
C9 C 0.68706(10) 0.7549(4) 0.31133(19) 0.0766(17) Uani 1 1 d . . . . .
H9 H 0.6802 0.7788 0.2913 0.092 Uiso 1 1 calc R U . . .
C10 C 0.67880(10) 0.7452(4) 0.34298(19) 0.0746(17) Uani 1 1 d . . . . .
C11 C 0.68978(11) 0.7044(4) 0.3738(2) 0.085(2) Uani 1 1 d . . . . .
C12 C 0.70764(10) 0.6797(4) 0.3716(2) 0.086(2) Uani 1 1 d . . . . .
H12 H 0.7145 0.6551 0.3913 0.103 Uiso 1 1 calc R U . . .
C13 C 0.67432(12) -0.0109(4) 0.2369(2) 0.091(2) Uani 1 1 d . . . . .
H13 H 0.6765 -0.0549 0.2509 0.109 Uiso 1 1 calc R U . . .
C14 C 0.68086(11) 0.0559(4) 0.2516(2) 0.094(2) Uani 1 1 d . . . . .
H14 H 0.6866 0.0576 0.2757 0.112 Uiso 1 1 calc R U . . .
C15 C 0.67911(11) 0.1192(4) 0.2317(3) 0.089(2) Uani 1 1 d . . . . .
C16 C 0.66926(13) 0.1149(4) 0.1970(3) 0.100(3) Uani 1 1 d . . . . .
H16 H 0.6673 0.1582 0.1824 0.120 Uiso 1 1 calc R U . . .
C17 C 0.66222(13) 0.0427(4) 0.1842(2) 0.094(2) Uani 1 1 d . . . . .
H17 H 0.6554 0.0392 0.1610 0.112 Uiso 1 1 calc R U . . .
C18 C 0.69655(9) 0.2056(3) 0.28341(18) 0.0687(16) Uani 1 1 d . . . . .
H18 H 0.6984 0.1677 0.3013 0.082 Uiso 1 1 calc R U . . .
C19 C 0.68682(12) 0.1913(4) 0.2466(3) 0.097(2) Uani 1 1 d . . . . .
C20 C 0.68733(11) 0.2605(4) 0.2279(2) 0.092(2) Uani 1 1 d . . . . .
C21 C 0.69568(10) 0.3196(3) 0.2465(2) 0.0764(17) Uani 1 1 d . . . . .
C22 C 0.69647(12) 0.3885(4) 0.2266(3) 0.100(3) Uani 1 1 d . . . . .
C23 C 0.68686(10) 0.3713(4) 0.1954(2) 0.0804(18) Uani 1 1 d . . . . .
H23 H 0.6841 0.4108 0.1787 0.097 Uiso 1 1 calc R U . . .
C24 C 0.71344(14) 0.5876(5) 0.2340(3) 0.105(3) Uani 1 1 d . . . . .
H24 H 0.7123 0.6312 0.2194 0.126 Uiso 1 1 calc R U . . .
C25 C 0.70475(13) 0.5225(5) 0.2218(3) 0.108(3) Uani 1 1 d . . . . .
H25 H 0.6980 0.5214 0.1984 0.129 Uiso 1 1 calc R U . . .
C26 C 0.70561(12) 0.4610(4) 0.2421(3) 0.092(2) Uani 1 1 d . . . . .
C27 C 0.71517(12) 0.4613(4) 0.2759(3) 0.096(2) Uani 1 1 d . . . . .
H27 H 0.7158 0.4182 0.2908 0.115 Uiso 1 1 calc R U . . .
C28 C 0.72444(12) 0.5321(4) 0.2880(3) 0.103(3) Uani 1 1 d . . . . .
H28 H 0.7310 0.5354 0.3114 0.124 Uiso 1 1 calc R U . . .
C29 C 0.58219(15) 0.0942(5) 0.2986(3) 0.117(3) Uani 1 1 d . . . . .
H29 H 0.5741 0.0935 0.2767 0.141 Uiso 1 1 calc R U . . .
C30 C 0.59088(15) 0.1630(5) 0.3116(3) 0.113(3) Uani 1 1 d . . . . .
H30 H 0.5887 0.2079 0.2982 0.136 Uiso 1 1 calc R U . . .
C31 C 0.60231(13) 0.1630(5) 0.3436(3) 0.098(2) Uani 1 1 d . . . . .
C32 C 0.60560(14) 0.0965(4) 0.3631(3) 0.106(3) Uani 1 1 d . . . . .
H32 H 0.6137 0.0950 0.3850 0.127 Uiso 1 1 calc R U . . .
C33 C 0.59672(17) 0.0343(5) 0.3492(3) 0.115(3) Uani 1 1 d . . . . .
H33 H 0.5984 -0.0106 0.3628 0.138 Uiso 1 1 calc R U . . .
C34 C 0.62105(10) 0.2500(4) 0.39295(19) 0.0812(19) Uani 1 1 d . . . . .
H34 H 0.6223 0.2121 0.4109 0.097 Uiso 1 1 calc R U . . .
C35 C 0.61154(12) 0.2355(4) 0.3589(3) 0.097(3) Uani 1 1 d . . . . .
C36 C 0.61221(11) 0.3036(4) 0.3396(2) 0.090(2) Uani 1 1 d . . . . .
C37 C 0.62141(10) 0.3623(4) 0.3573(2) 0.086(2) Uani 1 1 d . . . . .
C38 C 0.62157(11) 0.4309(4) 0.3383(3) 0.093(2) Uani 1 1 d . . . . .
C39 C 0.61269(8) 0.4173(3) 0.30486(16) 0.0609(14) Uani 1 1 d . . . . .
H39 H 0.6117 0.4553 0.2870 0.073 Uiso 1 1 calc R U . . .
C40 C 0.63337(13) 0.6346(4) 0.3495(3) 0.093(2) Uani 1 1 d . . . . .
H40 H 0.6301 0.6796 0.3369 0.112 Uiso 1 1 calc R U . . .
C41 C 0.62590(13) 0.5690(5) 0.3356(3) 0.100(2) Uani 1 1 d . . . . .
H41 H 0.6178 0.5695 0.3137 0.120 Uiso 1 1 calc R U . . .
C42 C 0.63000(11) 0.5029(4) 0.3530(2) 0.089(2) Uani 1 1 d D . . . .
C43 C 0.64140(12) 0.5047(4) 0.3842(3) 0.098(2) Uani 1 1 d D . . . .
H43 H 0.6439 0.4598 0.3975 0.117 Uiso 1 1 calc R U . . .
C44 C 0.64999(13) 0.5754(5) 0.3980(3) 0.102(2) Uani 1 1 d . . . . .
H44 H 0.6588 0.5757 0.4189 0.123 Uiso 1 1 calc R U . . .
C45 C 0.65539(17) -0.2203(6) 0.1467(4) 0.132(4) Uani 1 1 d . . . . .
C46 C 0.66228(17) -0.1535(5) 0.1293(3) 0.112(3) Uani 1 1 d . . . . .
C47 C 0.67923(15) -0.1329(5) 0.1463(3) 0.104(3) Uani 1 1 d . . . . .
C48 C 0.68321(17) -0.1792(5) 0.1767(2) 0.108(3) Uani 1 1 d . . . . .
C49 C 0.6694(2) -0.2355(6) 0.1780(3) 0.129(4) Uani 1 1 d . . . . .
C50 C 0.6380(3) -0.2613(11) 0.1362(6) 0.244(10) Uani 1 1 d . U . . .
H50A H 0.6278 -0.2257 0.1297 0.366 Uiso 1 1 calc R U . . .
H50B H 0.6349 -0.2923 0.1564 0.366 Uiso 1 1 calc R U . . .
H50C H 0.6396 -0.2934 0.1155 0.366 Uiso 1 1 calc R U . . .
C51 C 0.6527(2) -0.1163(8) 0.0944(3) 0.161(5) Uani 1 1 d . . . . .
H51A H 0.6568 -0.0641 0.0934 0.242 Uiso 1 1 calc R U . . .
H51B H 0.6391 -0.1181 0.0944 0.242 Uiso 1 1 calc R U . . .
H51C H 0.6563 -0.1432 0.0733 0.242 Uiso 1 1 calc R U . . .
C52 C 0.69093(18) -0.0660(6) 0.1358(3) 0.144(4) Uani 1 1 d . . . . .
H52A H 0.7001 -0.0831 0.1201 0.216 Uiso 1 1 calc R U . . .
H52B H 0.6975 -0.0435 0.1576 0.216 Uiso 1 1 calc R U . . .
H52C H 0.6827 -0.0287 0.1231 0.216 Uiso 1 1 calc R U . . .
C53 C 0.70090(17) -0.1731(8) 0.2011(4) 0.149(4) Uani 1 1 d . . . . .
H53A H 0.6984 -0.1841 0.2259 0.224 Uiso 1 1 calc R U . . .
H53B H 0.7059 -0.1223 0.2000 0.224 Uiso 1 1 calc R U . . .
H53C H 0.7100 -0.2090 0.1937 0.224 Uiso 1 1 calc R U . . .
C54 C 0.6694(3) -0.2942(6) 0.2051(5) 0.197(7) Uani 1 1 d . . . . .
H54A H 0.6793 -0.3304 0.2018 0.296 Uiso 1 1 calc R U . . .
H54B H 0.6573 -0.3195 0.2025 0.296 Uiso 1 1 calc R U . . .
H54C H 0.6717 -0.2720 0.2292 0.296 Uiso 1 1 calc R U . . .
C55 C 0.55794(19) -0.1689(6) 0.3165(5) 0.152(5) Uani 1 1 d D . . . .
C56 C 0.55710(16) -0.1095(7) 0.3438(4) 0.134(4) Uani 1 1 d D . . . .
C57 C 0.54748(19) -0.0483(8) 0.3248(5) 0.155(5) Uani 1 1 d D U . . .
C58 C 0.5425(2) -0.0690(10) 0.2892(6) 0.166(5) Uani 1 1 d D . . . .
C59 C 0.5490(2) -0.1415(11) 0.2846(4) 0.166(6) Uani 1 1 d D . . . .
C60 C 0.5675(3) -0.2421(7) 0.3258(5) 0.205(7) Uani 1 1 d . U . . .
H60A H 0.5583 -0.2827 0.3228 0.307 Uiso 1 1 calc R U . . .
H60B H 0.5733 -0.2408 0.3508 0.307 Uiso 1 1 calc R U . . .
H60C H 0.5772 -0.2507 0.3097 0.307 Uiso 1 1 calc R U . . .
C61 C 0.5640(2) -0.1078(10) 0.3841(5) 0.190(6) Uani 1 1 d . U . . .
H61A H 0.5684 -0.0574 0.3909 0.286 Uiso 1 1 calc R U . . .
H61B H 0.5743 -0.1434 0.3891 0.286 Uiso 1 1 calc R U . . .
H61C H 0.5537 -0.1215 0.3980 0.286 Uiso 1 1 calc R U . . .
C62 C 0.5417(2) 0.0240(9) 0.3385(5) 0.204(7) Uani 1 1 d . U . . .
H62A H 0.5360 0.0545 0.3184 0.307 Uiso 1 1 calc R U . . .
H62B H 0.5527 0.0500 0.3505 0.307 Uiso 1 1 calc R U . . .
H62C H 0.5326 0.0159 0.3558 0.307 Uiso 1 1 calc R U . . .
C63 C 0.5331(3) -0.0286(13) 0.2579(7) 0.251(11) Uani 1 1 d . . . . .
H63A H 0.5195 -0.0314 0.2584 0.376 Uiso 1 1 calc R U . . .
H63B H 0.5364 -0.0514 0.2357 0.376 Uiso 1 1 calc R U . . .
H63C H 0.5370 0.0239 0.2589 0.376 Uiso 1 1 calc R U . . .
C64 C 0.5472(3) -0.1840(16) 0.2512(6) 0.329(18) Uani 1 1 d D . . . .
H64A H 0.5480 -0.2375 0.2568 0.493 Uiso 1 1 calc R U . . .
H64B H 0.5573 -0.1701 0.2369 0.493 Uiso 1 1 calc R U . . .
H64C H 0.5351 -0.1730 0.2375 0.493 Uiso 1 1 calc R U . . .
C65 C 0.75599(11) 0.7759(4) 0.2635(3) 0.090(2) Uani 1 1 d . . . . .
C66 C 0.76378(11) 0.7555(5) 0.2971(3) 0.092(2) Uani 1 1 d . . . . .
C67 C 0.76898(11) 0.6757(5) 0.2950(3) 0.095(2) Uani 1 1 d . . . . .
C68 C 0.76390(11) 0.6510(5) 0.2582(3) 0.104(3) Uani 1 1 d . . . . .
C69 C 0.75509(13) 0.7134(5) 0.2379(3) 0.105(3) Uani 1 1 d . . . . .
C70 C 0.74791(14) 0.8517(5) 0.2527(3) 0.116(3) Uani 1 1 d . . . . .
H70A H 0.7345 0.8519 0.2551 0.174 Uiso 1 1 calc R U . . .
H70B H 0.7499 0.8621 0.2277 0.174 Uiso 1 1 calc R U . . .
H70C H 0.7541 0.8901 0.2684 0.174 Uiso 1 1 calc R U . . .
C71 C 0.76727(14) 0.7987(6) 0.3291(3) 0.118(3) Uani 1 1 d . . . . .
H71A H 0.7807 0.8098 0.3337 0.177 Uiso 1 1 calc R U . . .
H71B H 0.7633 0.7705 0.3495 0.177 Uiso 1 1 calc R U . . .
H71C H 0.7602 0.8456 0.3263 0.177 Uiso 1 1 calc R U . . .
C72 C 0.77831(15) 0.6270(7) 0.3243(4) 0.146(4) Uani 1 1 d . . . . .
H72A H 0.7745 0.5749 0.3198 0.219 Uiso 1 1 calc R U . . .
H72B H 0.7746 0.6431 0.3476 0.219 Uiso 1 1 calc R U . . .
H72C H 0.7919 0.6312 0.3247 0.219 Uiso 1 1 calc R U . . .
C73 C 0.76610(16) 0.5734(6) 0.2440(4) 0.144(4) Uani 1 1 d . . . . .
H73A H 0.7615 0.5370 0.2606 0.216 Uiso 1 1 calc R U . . .
H73B H 0.7793 0.5637 0.2419 0.216 Uiso 1 1 calc R U . . .
H73C H 0.7589 0.5687 0.2202 0.216 Uiso 1 1 calc R U . . .
C74 C 0.74838(15) 0.7103(6) 0.1995(3) 0.126(3) Uani 1 1 d . . . . .
H74A H 0.7582 0.6898 0.1862 0.190 Uiso 1 1 calc R U . . .
H74B H 0.7451 0.7608 0.1908 0.190 Uiso 1 1 calc R U . . .
H74C H 0.7373 0.6783 0.1959 0.190 Uiso 1 1 calc R U . . .
C75 C 0.6430(3) 0.8569(7) 0.4052(4) 0.163(5) Uani 1 1 d D U . . .
C76 C 0.63123(19) 0.8046(7) 0.4125(3) 0.129(4) Uani 1 1 d D U . . .
C77 C 0.6353(2) 0.7537(7) 0.4387(4) 0.148(5) Uani 1 1 d D U . . .
C78 C 0.6536(3) 0.7757(11) 0.4532(3) 0.198(9) Uani 1 1 d D . . . .
C79 C 0.6582(3) 0.8460(8) 0.4306(4) 0.178(7) Uani 1 1 d D . . . .
C80 C 0.6417(2) 0.9142(7) 0.3753(4) 0.198(8) Uani 1 1 d D . . . .
H80A H 0.6542 0.9336 0.3726 0.297 Uiso 1 1 calc R U . . .
H80B H 0.6336 0.9554 0.3813 0.297 Uiso 1 1 calc R U . . .
H80C H 0.6365 0.8908 0.3527 0.297 Uiso 1 1 calc R U . . .
C81 C 0.6124(3) 0.8072(8) 0.3924(6) 0.214(8) Uani 1 1 d . U . . .
H81A H 0.6079 0.7562 0.3877 0.321 Uiso 1 1 calc R U . . .
H81B H 0.6131 0.8333 0.3695 0.321 Uiso 1 1 calc R U . . .
H81C H 0.6039 0.8339 0.4066 0.321 Uiso 1 1 calc R U . . .
C82 C 0.6268(3) 0.6913(10) 0.4558(5) 0.248(10) Uani 1 1 d . U . . .
H82A H 0.6357 0.6702 0.4748 0.373 Uiso 1 1 calc R U . . .
H82B H 0.6157 0.7089 0.4664 0.373 Uiso 1 1 calc R U . . .
H82C H 0.6231 0.6528 0.4377 0.373 Uiso 1 1 calc R U . . .
C83 C 0.6699(3) 0.7629(17) 0.4812(6) 0.314(14) Uani 1 1 d D U . . .
H83A H 0.6813 0.7826 0.4726 0.471 Uiso 1 1 calc R U . . .
H83B H 0.6714 0.7092 0.4859 0.471 Uiso 1 1 calc R U . . .
H83C H 0.6677 0.7886 0.5035 0.471 Uiso 1 1 calc R U . . .
C84 C 0.6741(4) 0.8998(13) 0.4303(6) 0.296(13) Uani 1 1 d D U . . .
H84A H 0.6773 0.9056 0.4056 0.444 Uiso 1 1 calc R U . . .
H84B H 0.6850 0.8807 0.4457 0.444 Uiso 1 1 calc R U . . .
H84C H 0.6704 0.9484 0.4394 0.444 Uiso 1 1 calc R U . . .
C85 C 0.56604(12) 0.2742(5) 0.0859(2) 0.090(2) Uani 1 1 d . . . . .
C86 C 0.55322(13) 0.2187(5) 0.1010(2) 0.101(2) Uani 1 1 d . . . . .
C87 C 0.53662(13) 0.2402(5) 0.1135(3) 0.109(3) Uani 1 1 d . . . . .
H87 H 0.5288 0.2043 0.1232 0.131 Uiso 1 1 calc R U . . .
C88 C 0.53175(13) 0.3136(6) 0.1117(2) 0.104(2) Uani 1 1 d . . . . .
C89 C 0.54486(12) 0.3721(5) 0.0983(2) 0.099(2) Uani 1 1 d . . . . .
C90 C 0.56154(11) 0.3477(4) 0.0863(2) 0.094(2) Uani 1 1 d . . . . .
H90 H 0.5699 0.3834 0.0782 0.112 Uiso 1 1 calc R U . . .
C91 C 0.66844(11) 0.3448(5) 0.4821(2) 0.088(2) Uani 1 1 d . . . . .
C92 C 0.66082(11) 0.2748(5) 0.4952(2) 0.093(2) Uani 1 1 d . . . . .
C93 C 0.64374(13) 0.2709(6) 0.5094(3) 0.112(3) Uani 1 1 d . . . . .
H93 H 0.6387 0.2248 0.5164 0.135 Uiso 1 1 calc R U . . .
C94 C 0.63448(13) 0.3392(6) 0.5127(2) 0.110(3) Uani 1 1 d . . . . .
C95 C 0.64171(13) 0.4113(5) 0.5002(3) 0.109(3) Uani 1 1 d . . . . .
C96 C 0.65894(12) 0.4110(5) 0.4853(2) 0.100(2) Uani 1 1 d . . . . .
H96 H 0.6640 0.4565 0.4776 0.120 Uiso 1 1 calc R U . . .
C97 C 0.59539(15) 0.1263(5) 0.1606(2) 0.107(3) Uani 1 1 d . . . . .
H97 H 0.5857 0.0902 0.1598 0.129 Uiso 1 1 calc R U . . .
C98 C 0.60602(14) 0.1439(4) 0.1938(2) 0.098(2) Uani 1 1 d . . . . .
H98 H 0.6037 0.1183 0.2151 0.117 Uiso 1 1 calc R U . . .
C99 C 0.61973(13) 0.1981(5) 0.1950(2) 0.096(2) Uani 1 1 d . . . . .
C100 C 0.62301(15) 0.2323(6) 0.1632(3) 0.112(3) Uani 1 1 d . . . . .
H100 H 0.6326 0.2686 0.1630 0.135 Uiso 1 1 calc R U . . .
C101 C 0.61245(16) 0.2139(6) 0.1322(3) 0.113(3) Uani 1 1 d . . . . .
H101 H 0.6145 0.2395 0.1107 0.135 Uiso 1 1 calc R U . . .
C102 C 0.63899(9) 0.2922(3) 0.23903(17) 0.0674(16) Uani 1 1 d . . . . .
H102 H 0.6378 0.3332 0.2228 0.081 Uiso 1 1 calc R U . . .
C103 C 0.63114(11) 0.2194(4) 0.2301(2) 0.087(2) Uani 1 1 d . . . . .
C104 C 0.63499(11) 0.1723(4) 0.2597(2) 0.0821(19) Uani 1 1 d . . . . .
C105 C 0.64545(10) 0.2033(4) 0.28893(19) 0.0778(18) Uani 1 1 d . . . . .
C106 C 0.65082(11) 0.1543(4) 0.3192(2) 0.087(2) Uani 1 1 d . . . . .
C107 C 0.64272(10) 0.0883(3) 0.3065(2) 0.0788(19) Uani 1 1 d . . . . .
H107 H 0.6438 0.0464 0.3222 0.095 Uiso 1 1 calc R U . . .
C108 C 0.67987(12) 0.2595(5) 0.3927(3) 0.094(2) Uani 1 1 d . . . . .
H108 H 0.6865 0.3054 0.3957 0.112 Uiso 1 1 calc R U . . .
C109 C 0.67051(12) 0.2417(4) 0.3596(2) 0.087(2) Uani 1 1 d . . . . .
H109 H 0.6709 0.2755 0.3401 0.104 Uiso 1 1 calc R U . . .
C110 C 0.66073(10) 0.1770(4) 0.3541(2) 0.0792(18) Uani 1 1 d . . . . .
C111 C 0.66015(13) 0.1286(5) 0.3848(2) 0.098(2) Uani 1 1 d . . . . .
H111 H 0.6533 0.0832 0.3828 0.118 Uiso 1 1 calc R U . . .
C112 C 0.66938(13) 0.1487(5) 0.4158(3) 0.099(2) Uani 1 1 d . . . . .
H112 H 0.6688 0.1165 0.4360 0.119 Uiso 1 1 calc R U . . .
C113 C 0.52376(15) 0.4109(6) 0.1961(4) 0.124(3) Uani 1 1 d . . . . .
H113 H 0.5143 0.3744 0.1905 0.149 Uiso 1 1 calc R U . . .
C114 C 0.53249(18) 0.4159(6) 0.2309(4) 0.134(4) Uani 1 1 d . . . . .
H114 H 0.5289 0.3836 0.2490 0.161 Uiso 1 1 calc R U . . .
C115 C 0.54727(16) 0.4708(7) 0.2398(4) 0.128(3) Uani 1 1 d . . . . .
C116 C 0.55152(19) 0.5130(7) 0.2109(5) 0.150(4) Uani 1 1 d . . . . .
H116 H 0.5614 0.5482 0.2149 0.180 Uiso 1 1 calc R U . . .
C117 C 0.54242(19) 0.5073(7) 0.1770(4) 0.147(4) Uani 1 1 d . . . . .
H117 H 0.5459 0.5387 0.1584 0.176 Uiso 1 1 calc R U . . .
C118 C 0.56497(16) 0.5435(6) 0.2913(3) 0.127(3) Uani 1 1 d . . . . .
H118 H 0.5654 0.5884 0.2778 0.153 Uiso 1 1 calc R U . . .
C119 C 0.55606(16) 0.4782(6) 0.2749(4) 0.124(3) Uani 1 1 d . . . . .
C120 C 0.55905(14) 0.4225(6) 0.3035(4) 0.117(3) Uani 1 1 d . . . . .
C121 C 0.56836(13) 0.4452(5) 0.3347(3) 0.108(3) Uani 1 1 d . . . . .
C122 C 0.57138(13) 0.3891(6) 0.3616(4) 0.117(3) Uani 1 1 d . . . . .
C123 C 0.56312(12) 0.3220(5) 0.3478(3) 0.110(3) Uani 1 1 d . . . . .
H123 H 0.5633 0.2771 0.3615 0.132 Uiso 1 1 calc R U . . .
C124 C 0.58706(17) 0.3602(7) 0.4585(4) 0.134(4) Uani 1 1 d . . . . .
H124 H 0.5862 0.3214 0.4756 0.161 Uiso 1 1 calc R U . . .
C125 C 0.57882(16) 0.3477(7) 0.4248(4) 0.136(4) Uani 1 1 d . . . . .
H125 H 0.5721 0.3025 0.4196 0.163 Uiso 1 1 calc R U . . .
C126 C 0.58003(14) 0.3993(6) 0.3978(4) 0.120(3) Uani 1 1 d . . . . .
C127 C 0.59098(15) 0.4658(6) 0.4102(3) 0.118(3) Uani 1 1 d . . . . .
H127 H 0.5927 0.5043 0.3934 0.141 Uiso 1 1 calc R U . . .
C128 C 0.59846(16) 0.4739(7) 0.4440(3) 0.125(3) Uani 1 1 d . . . . .
H128 H 0.6056 0.5177 0.4501 0.149 Uiso 1 1 calc R U . . .
C129 C 0.6060(2) 0.0618(8) 0.0620(4) 0.141(4) Uani 1 1 d . U . . .
C130 C 0.5921(3) 0.0152(7) 0.0733(3) 0.136(4) Uani 1 1 d . . . . .
C131 C 0.5760(3) 0.0279(9) 0.0507(5) 0.175(6) Uani 1 1 d . . . . .
C132 C 0.5781(3) 0.0859(10) 0.0266(3) 0.158(5) Uani 1 1 d D U . . .
C133 C 0.5973(3) 0.1061(7) 0.0325(4) 0.164(6) Uani 1 1 d D U . . .
C134 C 0.6258(3) 0.0592(11) 0.0784(5) 0.206(7) Uani 1 1 d . . . . .
H13D H 0.6263 0.0629 0.1046 0.309 Uiso 1 1 calc R U . . .
H13E H 0.6328 0.1009 0.0692 0.309 Uiso 1 1 calc R U . . .
H13F H 0.6315 0.0118 0.0720 0.309 Uiso 1 1 calc R U . . .
C135 C 0.5935(3) -0.0438(7) 0.1032(4) 0.196(7) Uani 1 1 d . . . . .
H13A H 0.5991 -0.0895 0.0946 0.294 Uiso 1 1 calc R U . . .
H13B H 0.5810 -0.0547 0.1099 0.294 Uiso 1 1 calc R U . . .
H13C H 0.6014 -0.0247 0.1243 0.294 Uiso 1 1 calc R U . . .
C136 C 0.5563(3) -0.0060(11) 0.0524(6) 0.225(9) Uani 1 1 d . . . . .
H13G H 0.5547 -0.0493 0.0363 0.338 Uiso 1 1 calc R U . . .
H13H H 0.5468 0.0317 0.0449 0.338 Uiso 1 1 calc R U . . .
H13I H 0.5550 -0.0218 0.0771 0.338 Uiso 1 1 calc R U . . .
C137 C 0.5664(3) 0.1211(10) -0.0050(4) 0.237(9) Uani 1 1 d D U . . .
H13J H 0.5627 0.1716 0.0015 0.356 Uiso 1 1 calc R U . . .
H13K H 0.5552 0.0907 -0.0115 0.356 Uiso 1 1 calc R U . . .
H13L H 0.5738 0.1238 -0.0256 0.356 Uiso 1 1 calc R U . . .
C138 C 0.6084(4) 0.1622(10) 0.0151(5) 0.245(9) Uani 1 1 d . U . . .
H13M H 0.6214 0.1607 0.0261 0.368 Uiso 1 1 calc R U . . .
H13N H 0.6079 0.1511 -0.0107 0.368 Uiso 1 1 calc R U . . .
H13O H 0.6032 0.2120 0.0183 0.368 Uiso 1 1 calc R U . . .
C139 C 0.5045(2) 0.5486(9) 0.0868(5) 0.163(5) Uani 1 1 d D . . . .
C140 C 0.4941(2) 0.4826(10) 0.0745(4) 0.162(5) Uani 1 1 d D . . . .
C141 C 0.48427(17) 0.4647(11) 0.1032(5) 0.167(6) Uani 1 1 d D . . . .
C142 C 0.4891(2) 0.5124(10) 0.1324(5) 0.178(7) Uani 1 1 d D . . . .
C143 C 0.5011(2) 0.5659(10) 0.1207(6) 0.188(7) Uani 1 1 d D . . . .
C144 C 0.5184(2) 0.5947(10) 0.0630(6) 0.210(8) Uani 1 1 d . . . . .
H14D H 0.5120 0.6042 0.0389 0.314 Uiso 1 1 calc R U . . .
H14E H 0.5297 0.5652 0.0610 0.314 Uiso 1 1 calc R U . . .
H14F H 0.5218 0.6424 0.0749 0.314 Uiso 1 1 calc R U . . .
C145 C 0.4931(3) 0.4470(14) 0.0373(6) 0.252(10) Uani 1 1 d D . . . .
H14M H 0.4992 0.3979 0.0392 0.377 Uiso 1 1 calc R U . . .
H14N H 0.4995 0.4791 0.0213 0.377 Uiso 1 1 calc R U . . .
H14O H 0.4800 0.4410 0.0275 0.377 Uiso 1 1 calc R U . . .
C146 C 0.47274(19) 0.3936(12) 0.1046(6) 0.222(8) Uani 1 1 d . . . . .
H14A H 0.4612 0.4047 0.1153 0.333 Uiso 1 1 calc R U . . .
H14B H 0.4800 0.3560 0.1193 0.333 Uiso 1 1 calc R U . . .
H14C H 0.4696 0.3742 0.0801 0.333 Uiso 1 1 calc R U . . .
C147 C 0.4816(3) 0.5116(15) 0.1692(5) 0.261(11) Uani 1 1 d D . . . .
H14J H 0.4680 0.5058 0.1659 0.392 Uiso 1 1 calc R U . . .
H14K H 0.4849 0.5587 0.1817 0.392 Uiso 1 1 calc R U . . .
H14L H 0.4872 0.4697 0.1835 0.392 Uiso 1 1 calc R U . . .
C148 C 0.5081(3) 0.6339(11) 0.1425(7) 0.254(11) Uani 1 1 d . . . . .
H14G H 0.5193 0.6536 0.1332 0.381 Uiso 1 1 calc R U . . .
H14H H 0.5110 0.6196 0.1678 0.381 Uiso 1 1 calc R U . . .
H14I H 0.4983 0.6724 0.1406 0.381 Uiso 1 1 calc R U . . .
C149 C 0.71998(14) 0.2511(8) 0.5072(4) 0.132(4) Uani 1 1 d . . . . .
C150 C 0.71317(15) 0.1764(9) 0.5100(3) 0.131(4) Uani 1 1 d . . . . .
C151 C 0.71380(15) 0.1389(7) 0.4786(4) 0.123(3) Uani 1 1 d . . . . .
C152 C 0.72138(13) 0.1856(6) 0.4535(3) 0.113(3) Uani 1 1 d . . . . .
C153 C 0.72477(13) 0.2554(6) 0.4699(3) 0.111(3) Uani 1 1 d . . . . .
C154 C 0.7218(2) 0.3100(9) 0.5357(5) 0.196(7) Uani 1 1 d . U . . .
H15J H 0.7175 0.2901 0.5579 0.295 Uiso 1 1 calc R U . . .
H15K H 0.7141 0.3533 0.5275 0.295 Uiso 1 1 calc R U . . .
H15L H 0.7349 0.3254 0.5405 0.295 Uiso 1 1 calc R U . . .
C155 C 0.7046(2) 0.1402(9) 0.5438(3) 0.178(6) Uani 1 1 d . . . . .
H15M H 0.7055 0.1763 0.5637 0.267 Uiso 1 1 calc R U . . .
H15N H 0.6915 0.1272 0.5370 0.267 Uiso 1 1 calc R U . . .
H15O H 0.7117 0.0950 0.5515 0.267 Uiso 1 1 calc R U . . .
C156 C 0.7078(2) 0.0540(8) 0.4715(4) 0.164(5) Uani 1 1 d . . . . .
H15D H 0.7032 0.0474 0.4460 0.246 Uiso 1 1 calc R U . . .
H15E H 0.6979 0.0409 0.4864 0.246 Uiso 1 1 calc R U . . .
H15F H 0.7186 0.0213 0.4777 0.246 Uiso 1 1 calc R U . . .
C157 C 0.72502(16) 0.1712(7) 0.4161(3) 0.144(4) Uani 1 1 d . . . . .
H15A H 0.7378 0.1521 0.4159 0.216 Uiso 1 1 calc R U . . .
H15B H 0.7236 0.2179 0.4023 0.216 Uiso 1 1 calc R U . . .
H15C H 0.7161 0.1342 0.4052 0.216 Uiso 1 1 calc R U . . .
C158 C 0.73187(16) 0.3241(7) 0.4538(5) 0.164(5) Uani 1 1 d . . . . .
H15G H 0.7325 0.3162 0.4279 0.246 Uiso 1 1 calc R U . . .
H15H H 0.7444 0.3356 0.4655 0.246 Uiso 1 1 calc R U . . .
H15I H 0.7235 0.3659 0.4572 0.246 Uiso 1 1 calc R U . . .
C159 C 0.6036(3) 0.4689(12) 0.5799(4) 0.170(7) Uani 1 1 d . . . . .
C160 C 0.6069(3) 0.5445(11) 0.5615(5) 0.195(7) Uani 1 1 d D U . . .
C161 C 0.5931(2) 0.5543(7) 0.5335(4) 0.146(4) Uani 1 1 d D . . . .
C162 C 0.57936(18) 0.4962(6) 0.5350(3) 0.132(4) Uani 1 1 d D . . . .
C163 C 0.5862(3) 0.4449(9) 0.5612(6) 0.212(10) Uani 1 1 d . . . . .
C164 C 0.6126(4) 0.4247(14) 0.6081(5) 0.272(11) Uani 1 1 d . U . . .
H16M H 0.6033 0.4069 0.6235 0.408 Uiso 1 1 calc R U . . .
H16N H 0.6220 0.4549 0.6225 0.408 Uiso 1 1 calc R U . . .
H16O H 0.6186 0.3818 0.5979 0.408 Uiso 1 1 calc R U . . .
C165 C 0.6252(3) 0.5905(15) 0.5716(6) 0.265(11) Uani 1 1 d . U . . .
H16J H 0.6287 0.6158 0.5500 0.398 Uiso 1 1 calc R U . . .
H16K H 0.6353 0.5567 0.5811 0.398 Uiso 1 1 calc R U . . .
H16L H 0.6231 0.6278 0.5899 0.398 Uiso 1 1 calc R U . . .
C166 C 0.5927(3) 0.6239(7) 0.5118(5) 0.199(7) Uani 1 1 d . U . . .
H16D H 0.6052 0.6464 0.5142 0.299 Uiso 1 1 calc R U . . .
H16E H 0.5838 0.6591 0.5205 0.299 Uiso 1 1 calc R U . . .
H16F H 0.5889 0.6121 0.4864 0.299 Uiso 1 1 calc R U . . .
C167 C 0.5617(2) 0.4942(8) 0.5102(4) 0.171(5) Uani 1 1 d . U . . .
H16A H 0.5607 0.4464 0.4973 0.256 Uiso 1 1 calc R U . . .
H16B H 0.5617 0.5353 0.4928 0.256 Uiso 1 1 calc R U . . .
H16C H 0.5510 0.4997 0.5241 0.256 Uiso 1 1 calc R U . . .
C168 C 0.5743(3) 0.3700(9) 0.5674(5) 0.223(8) Uani 1 1 d . U . . .
H16G H 0.5667 0.3565 0.5448 0.334 Uiso 1 1 calc R U . . .
H16H H 0.5660 0.3792 0.5861 0.334 Uiso 1 1 calc R U . . .
H16I H 0.5828 0.3290 0.5749 0.334 Uiso 1 1 calc R U . . .
C169 C 0.7159(2) 0.9386(7) 0.3395(5) 0.184(7) Uani 1 1 d D . . . .
C170 C 0.7550(2) 0.4811(8) 0.3933(3) 0.134(4) Uani 1 1 d . . . . .
C171 C 0.4597(3) 0.6960(10) 0.0502(6) 0.216(7) Uani 1 1 d D U . . .
C177 C 0.5945(3) 0.4064(14) 0.1674(9) 0.288(12) Uani 1 1 d D U . . .
O41 O 0.57632(16) 0.3621(6) 0.1735(3) 0.194(4) Uani 1 1 d D . . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C48 2.103(10) . ?
Rh1 O1 2.114(5) . ?
Rh1 C46 2.118(9) . ?
Rh1 O2 2.126(6) . ?
Rh1 N1 2.135(6) . ?
Rh1 C49 2.146(9) . ?
Rh1 C45 2.152(9) . ?
Rh1 C47 2.178(9) . ?
Rh2 C57 2.100(12) . ?
Rh2 O4 2.109(6) . ?
Rh2 N3 2.114(9) . ?
Rh2 C58 2.120(15) . ?
Rh2 C59 2.130(13) . ?
Rh2 O3 2.133(6) . ?
Rh2 C56 2.149(10) . ?
Rh2 C55 2.157(10) . ?
Rh3 O5 2.098(5) . ?
Rh3 C67 2.107(8) . ?
Rh3 O6 2.116(5) . ?
Rh3 C66 2.135(8) . ?
Rh3 N2 2.136(7) . ?
Rh3 C65 2.148(7) . ?
Rh3 C68 2.153(8) . ?
Rh3 C69 2.166(8) . ?
Rh4 C78 2.056(10) . ?
Rh4 C76 2.094(11) . ?
Rh4 C77 2.112(9) . ?
Rh4 N4 2.113(7) . ?
Rh4 O8 2.119(6) . ?
Rh4 O7 2.122(5) . ?
Rh4 C79 2.136(12) . ?
Rh4 C75 2.193(12) . ?
Rh5 C133 2.115(11) . ?
Rh5 O9 2.129(6) . ?
Rh5 C132 2.130(12) . ?
Rh5 C129 2.131(12) . ?
Rh5 O10 2.132(7) . ?
Rh5 N5 2.144(8) . ?
Rh5 C130 2.149(11) . ?
Rh5 C131 2.178(14) . ?
Rh6 N7 2.072(11) . ?
Rh6 C139 2.081(14) . ?
Rh6 C140 2.101(15) . ?
Rh6 O12 2.117(5) . ?
Rh6 O11 2.125(7) . ?
Rh6 C142 2.126(11) . ?
Rh6 C141 2.134(13) . ?
Rh6 C143 2.135(16) . ?
Rh7 C150 2.091(10) . ?
Rh7 N6 2.092(7) . ?
Rh7 O14 2.101(6) . ?
Rh7 C151 2.115(10) . ?
Rh7 C153 2.115(10) . ?
Rh7 C149 2.124(10) . ?
Rh7 O13 2.133(5) . ?
Rh7 C152 2.164(9) . ?
Rh8 N8 2.094(11) . ?
Rh8 C163 2.102(11) . ?
Rh8 O16 2.112(6) . ?
Rh8 C161 2.127(12) . ?
Rh8 O15 2.139(7) . ?
Rh8 C159 2.140(13) . ?
Rh8 C162 2.168(10) . ?
Rh8 C160 2.187(19) . ?
N1 C17 1.308(9) . ?
N1 C13 1.346(10) . ?
N2 C28 1.305(11) . ?
N2 C24 1.354(12) . ?
N3 C29 1.338(13) . ?
N3 C33 1.354(13) . ?
N4 C44 1.337(11) . ?
N4 C40 1.365(11) . ?
N5 C97 1.340(11) . ?
N5 C101 1.341(13) . ?
N6 C108 1.337(11) . ?
N6 C112 1.375(11) . ?
N7 C117 1.346(14) . ?
N7 C113 1.360(13) . ?
N8 C128 1.356(13) . ?
N8 C124 1.373(16) . ?
O1 C1 1.293(9) . ?
O2 C2 1.300(9) . ?
O3 C4 1.283(10) . ?
O4 C5 1.277(9) . ?
O5 C7 1.259(8) . ?
O6 C8 1.285(8) . ?
O7 C10 1.282(8) . ?
O8 C11 1.289(8) . ?
O9 C85 1.279(9) . ?
O10 C86 1.314(10) . ?
O11 C88 1.274(10) . ?
O12 C89 1.269(10) . ?
O13 C91 1.276(9) . ?
O14 C92 1.316(9) . ?
O15 C94 1.323(10) . ?
O16 C95 1.302(10) . ?
O17 S9 1.388(7) . ?
O18 S9 1.499(10) . ?
O19 S9 1.374(11) . ?
O20 S10 1.449(12) . ?
O21 S10 1.420(9) . ?
O22 S10 1.468(12) . ?
O23 S11 1.335(9) . ?
O24 S11 1.494(12) . ?
O25 S11 1.498(13) . ?
S1 C18 1.595(7) . ?
S1 C21 1.757(8) . ?
S2 C23 1.584(8) . ?
S2 C20 1.772(10) . ?
S3 C34 1.583(8) . ?
S3 C37 1.776(9) . ?
S4 C39 1.639(6) . ?
S4 C36 1.767(9) . ?
S5 C102 1.628(7) . ?
S5 C105 1.769(7) . ?
S6 C107 1.588(8) . ?
S6 C104 1.763(7) . ?
S7 C118 1.606(13) . ?
S7 C121 1.764(10) . ?
S8 C123 1.673(12) . ?
S8 C120 1.747(11) . ?
S9 C169 1.705(17) . ?
S10 C170 1.778(14) . ?
S11 C171 1.81(2) . ?
F1 C169 1.311(13) . ?
F2 C169 1.401(15) . ?
F3 C169 1.327(14) . ?
F4 C170 1.291(13) . ?
F5 C170 1.350(15) . ?
F6 C170 1.342(14) . ?
F7 C171 1.309(15) . ?
F8 C171 1.382(16) . ?
F9 C171 1.319(15) . ?
C1 C6 1.397(11) . ?
C1 C2 1.512(12) . ?
C2 C3 1.357(11) . ?
C3 C4 1.414(12) . ?
C3 H3 0.9500 . ?
C4 C5 1.515(13) . ?
C5 C6 1.372(12) . ?
C6 H6 0.9500 . ?
C7 C12 1.398(10) . ?
C7 C8 1.498(11) . ?
C8 C9 1.345(9) . ?
C9 C10 1.391(9) . ?
C9 H9 0.9500 . ?
C10 C11 1.511(11) . ?
C11 C12 1.370(10) . ?
C12 H12 0.9500 . ?
C13 C14 1.377(10) . ?
C13 H13 0.9500 . ?
C14 C15 1.354(11) . ?
C14 H14 0.9500 . ?
C15 C16 1.408(12) . ?
C15 C19 1.487(11) . ?
C16 C17 1.448(11) . ?
C16 H16 0.9500 . ?
C17 H17 0.9500 . ?
C18 C19 1.494(12) . ?
C18 H18 0.9500 . ?
C19 C20 1.424(11) . ?
C20 C21 1.366(10) . ?
C21 C22 1.443(10) . ?
C22 C23 1.324(12) . ?
C22 C26 1.537(13) . ?
C23 H23 0.9500 . ?
C24 C25 1.376(12) . ?
C24 H24 0.9500 . ?
C25 C26 1.335(12) . ?
C25 H25 0.9500 . ?
C26 C27 1.369(12) . ?
C27 C28 1.479(12) . ?
C27 H27 0.9500 . ?
C28 H28 0.9500 . ?
C29 C30 1.441(14) . ?
C29 H29 0.9500 . ?
C30 C31 1.376(13) . ?
C30 H30 0.9500 . ?
C31 C32 1.401(12) . ?
C31 C35 1.538(12) . ?
C32 C33 1.358(14) . ?
C32 H32 0.9500 . ?
C33 H33 0.9500 . ?
C34 C35 1.399(12) . ?
C34 H34 0.9500 . ?
C35 C36 1.418(10) . ?
C36 C37 1.371(11) . ?
C37 C38 1.419(10) . ?
C38 C39 1.360(11) . ?
C38 C42 1.501(12) . ?
C39 H39 0.9500 . ?
C40 C41 1.369(12) . ?
C40 H40 0.9500 . ?
C41 C42 1.366(11) . ?
C41 H41 0.9500 . ?
C42 C43 1.350(10) . ?
C43 C44 1.475(12) . ?
C43 H43 0.9500 . ?
C44 H44 0.9500 . ?
C45 C50 1.47(2) . ?
C45 C46 1.472(15) . ?
C45 C49 1.483(17) . ?
C46 C47 1.362(14) . ?
C46 C51 1.556(16) . ?
C47 C48 1.407(13) . ?
C47 C52 1.538(14) . ?
C48 C49 1.418(16) . ?
C48 C53 1.487(16) . ?
C49 C54 1.458(17) . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C55 C59 1.382(15) . ?
C55 C56 1.479(19) . ?
C55 C60 1.50(2) . ?
C56 C57 1.440(14) . ?
C56 C61 1.53(2) . ?
C57 C58 1.388(15) . ?
C57 C62 1.467(19) . ?
C58 C59 1.396(15) . ?
C58 C63 1.47(2) . ?
C59 C64 1.452(16) . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C63 H63A 0.9800 . ?
C63 H63B 0.9800 . ?
C63 H63C 0.9800 . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C65 C66 1.366(12) . ?
C65 C69 1.468(12) . ?
C65 C70 1.512(13) . ?
C66 C71 1.423(12) . ?
C66 C67 1.479(12) . ?
C67 C68 1.453(13) . ?
C67 C72 1.498(15) . ?
C68 C69 1.455(13) . ?
C68 C73 1.501(12) . ?
C69 C74 1.462(14) . ?
C70 H70A 0.9800 . ?
C70 H70B 0.9800 . ?
C70 H70C 0.9800 . ?
C71 H71A 0.9800 . ?
C71 H71B 0.9800 . ?
C71 H71C 0.9800 . ?
C72 H72A 0.9800 . ?
C72 H72B 0.9800 . ?
C72 H72C 0.9800 . ?
C73 H73A 0.9800 . ?
C73 H73B 0.9800 . ?
C73 H73C 0.9800 . ?
C74 H74A 0.9800 . ?
C74 H74B 0.9800 . ?
C74 H74C 0.9800 . ?
C75 C76 1.312(17) . ?
C75 C79 1.378(16) . ?
C75 C80 1.510(15) . ?
C76 C77 1.346(14) . ?
C76 C81 1.47(2) . ?
C77 C78 1.423(15) . ?
C77 C82 1.455(18) . ?
C78 C83 1.499(17) . ?
C78 C79 1.57(2) . ?
C79 C84 1.50(2) . ?
C80 H80A 0.9800 . ?
C80 H80B 0.9800 . ?
C80 H80C 0.9800 . ?
C81 H81A 0.9800 . ?
C81 H81B 0.9800 . ?
C81 H81C 0.9800 . ?
C82 H82A 0.9800 . ?
C82 H82B 0.9800 . ?
C82 H82C 0.9800 . ?
C83 H83A 0.9800 . ?
C83 H83B 0.9800 . ?
C83 H83C 0.9800 . ?
C84 H84A 0.9800 . ?
C84 H84B 0.9800 . ?
C84 H84C 0.9800 . ?
C85 C90 1.354(11) . ?
C85 C86 1.506(12) . ?
C86 C87 1.384(13) . ?
C87 C88 1.359(13) . ?
C87 H87 0.9500 . ?
C88 C89 1.529(11) . ?
C89 C90 1.397(11) . ?
C90 H90 0.9500 . ?
C91 C96 1.380(11) . ?
C91 C92 1.471(12) . ?
C92 C93 1.391(12) . ?
C93 C94 1.403(13) . ?
C93 H93 0.9500 . ?
C94 C95 1.485(14) . ?
C95 C96 1.413(12) . ?
C96 H96 0.9500 . ?
C97 C98 1.416(13) . ?
C97 H97 0.9500 . ?
C98 C99 1.381(12) . ?
C98 H98 0.9500 . ?
C99 C100 1.379(12) . ?
C99 C103 1.517(12) . ?
C100 C101 1.353(14) . ?
C100 H100 0.9500 . ?
C101 H101 0.9500 . ?
C102 C103 1.444(10) . ?
C102 H102 0.9500 . ?
C103 C104 1.394(10) . ?
C104 C105 1.372(11) . ?
C105 C106 1.450(11) . ?
C106 C107 1.378(10) . ?
C106 C110 1.472(11) . ?
C107 H107 0.9500 . ?
C108 C109 1.381(11) . ?
C108 H108 0.9500 . ?
C109 C110 1.358(10) . ?
C109 H109 0.9500 . ?
C110 C111 1.440(11) . ?
C111 C112 1.321(12) . ?
C111 H111 0.9500 . ?
C112 H112 0.9500 . ?
C113 C114 1.383(16) . ?
C113 H113 0.9500 . ?
C114 C115 1.459(16) . ?
C114 H114 0.9500 . ?
C115 C116 1.376(17) . ?
C115 C119 1.397(16) . ?
C116 C117 1.365(18) . ?
C116 H116 0.9500 . ?
C117 H117 0.9500 . ?
C118 C119 1.437(15) . ?
C118 H118 0.9500 . ?
C119 C120 1.459(16) . ?
C120 C121 1.343(15) . ?
C121 C122 1.419(15) . ?
C122 C123 1.411(14) . ?
C122 C126 1.434(16) . ?
C123 H123 0.9500 . ?
C124 C125 1.350(17) . ?
C124 H124 0.9500 . ?
C125 C126 1.379(15) . ?
C125 H125 0.9500 . ?
C126 C127 1.474(16) . ?
C127 C128 1.324(15) . ?
C127 H127 0.9500 . ?
C128 H128 0.9500 . ?
C129 C130 1.405(19) . ?
C129 C133 1.444(19) . ?
C129 C134 1.49(2) . ?
C130 C131 1.37(2) . ?
C130 C135 1.532(17) . ?
C131 C132 1.39(2) . ?
C131 C136 1.55(3) . ?
C132 C133 1.422(15) . ?
C132 C137 1.510(15) . ?
C133 C138 1.47(2) . ?
C134 H13D 0.9800 . ?
C134 H13E 0.9800 . ?
C134 H13F 0.9800 . ?
C135 H13A 0.9800 . ?
C135 H13B 0.9800 . ?
C135 H13C 0.9800 . ?
C136 H13G 0.9800 . ?
C136 H13H 0.9800 . ?
C136 H13I 0.9800 . ?
C137 H13J 0.9800 . ?
C137 H13K 0.9800 . ?
C137 H13L 0.9800 . ?
C138 H13M 0.9800 . ?
C138 H13N 0.9800 . ?
C138 H13O 0.9800 . ?
C139 C143 1.35(2) . ?
C139 C140 1.446(15) . ?
C139 C144 1.630(19) . ?
C140 C141 1.384(19) . ?
C140 C145 1.523(16) . ?
C141 C142 1.397(15) . ?
C141 C146 1.52(2) . ?
C142 C143 1.394(15) . ?
C142 C147 1.528(15) . ?
C143 C148 1.52(3) . ?
C144 H14D 0.9800 . ?
C144 H14E 0.9800 . ?
C144 H14F 0.9800 . ?
C145 H14M 0.9800 . ?
C145 H14N 0.9800 . ?
C145 H14O 0.9800 . ?
C146 H14A 0.9800 . ?
C146 H14B 0.9800 . ?
C146 H14C 0.9800 . ?
C147 H14J 0.9800 . ?
C147 H14K 0.9800 . ?
C147 H14L 0.9800 . ?
C148 H14G 0.9800 . ?
C148 H14H 0.9800 . ?
C148 H14I 0.9800 . ?
C149 C150 1.430(17) . ?
C149 C153 1.475(17) . ?
C149 C154 1.493(16) . ?
C150 C151 1.356(15) . ?
C150 C155 1.600(19) . ?
C151 C152 1.408(15) . ?
C151 C156 1.594(18) . ?
C152 C153 1.400(14) . ?
C152 C157 1.473(15) . ?
C153 C158 1.484(17) . ?
C154 H15J 0.9800 . ?
C154 H15K 0.9800 . ?
C154 H15L 0.9800 . ?
C155 H15M 0.9800 . ?
C155 H15N 0.9800 . ?
C155 H15O 0.9800 . ?
C156 H15D 0.9800 . ?
C156 H15E 0.9800 . ?
C156 H15F 0.9800 . ?
C157 H15A 0.9800 . ?
C157 H15B 0.9800 . ?
C157 H15C 0.9800 . ?
C158 H15G 0.9800 . ?
C158 H15H 0.9800 . ?
C158 H15I 0.9800 . ?
C159 C164 1.41(2) . ?
C159 C163 1.43(3) . ?
C159 C160 1.55(2) . ?
C160 C161 1.370(16) . ?
C160 C165 1.56(3) . ?
C161 C162 1.440(13) . ?
C161 C166 1.483(18) . ?
C162 C163 1.390(19) . ?
C162 C167 1.491(19) . ?
C163 C168 1.62(3) . ?
C164 H16M 0.9800 . ?
C164 H16N 0.9800 . ?
C164 H16O 0.9800 . ?
C165 H16J 0.9800 . ?
C165 H16K 0.9800 . ?
C165 H16L 0.9800 . ?
C166 H16D 0.9800 . ?
C166 H16E 0.9800 . ?
C166 H16F 0.9800 . ?
C167 H16A 0.9800 . ?
C167 H16B 0.9800 . ?
C167 H16C 0.9800 . ?
C168 H16G 0.9800 . ?
C168 H16H 0.9800 . ?
C168 H16I 0.9800 . ?
C177 O41 1.57(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C48 Rh1 O1 110.5(3) . . ?
C48 Rh1 C46 64.1(4) . . ?
O1 Rh1 C46 155.8(3) . . ?
C48 Rh1 O2 167.2(3) . . ?
O1 Rh1 O2 77.0(2) . . ?
C46 Rh1 O2 104.7(4) . . ?
C48 Rh1 N1 105.4(4) . . ?
O1 Rh1 N1 84.4(2) . . ?
C46 Rh1 N1 119.8(3) . . ?
O2 Rh1 N1 85.2(2) . . ?
C48 Rh1 C49 39.0(4) . . ?
O1 Rh1 C49 93.9(3) . . ?
C46 Rh1 C49 66.8(4) . . ?
O2 Rh1 C49 132.8(4) . . ?
N1 Rh1 C49 140.8(5) . . ?
C48 Rh1 C45 65.5(4) . . ?
O1 Rh1 C45 115.4(4) . . ?
C46 Rh1 C45 40.3(4) . . ?
O2 Rh1 C45 102.1(4) . . ?
N1 Rh1 C45 159.9(4) . . ?
C49 Rh1 C45 40.4(5) . . ?
C48 Rh1 C47 38.3(3) . . ?
O1 Rh1 C47 148.0(3) . . ?
C46 Rh1 C47 36.9(4) . . ?
O2 Rh1 C47 134.9(3) . . ?
N1 Rh1 C47 96.6(3) . . ?
C49 Rh1 C47 65.3(4) . . ?
C45 Rh1 C47 64.9(4) . . ?
C57 Rh2 O4 150.3(5) . . ?
C57 Rh2 N3 96.0(5) . . ?
O4 Rh2 N3 85.1(3) . . ?
C57 Rh2 C58 38.4(4) . . ?
O4 Rh2 C58 156.1(6) . . ?
N3 Rh2 C58 118.6(6) . . ?
C57 Rh2 C59 64.4(6) . . ?
O4 Rh2 C59 118.0(6) . . ?
N3 Rh2 C59 156.9(6) . . ?
C58 Rh2 C59 38.3(4) . . ?
C57 Rh2 O3 133.1(5) . . ?
O4 Rh2 O3 76.5(2) . . ?
N3 Rh2 O3 87.4(3) . . ?
C58 Rh2 O3 100.2(6) . . ?
C59 Rh2 O3 97.2(5) . . ?
C57 Rh2 C56 39.6(4) . . ?
O4 Rh2 C56 112.0(4) . . ?
N3 Rh2 C56 108.5(4) . . ?
C58 Rh2 C56 65.4(6) . . ?
C59 Rh2 C56 65.0(5) . . ?
O3 Rh2 C56 162.1(4) . . ?
C57 Rh2 C55 65.9(5) . . ?
O4 Rh2 C55 97.6(4) . . ?
N3 Rh2 C55 147.0(6) . . ?
C58 Rh2 C55 64.6(6) . . ?
C59 Rh2 C55 37.6(4) . . ?
O3 Rh2 C55 125.3(5) . . ?
C56 Rh2 C55 40.2(5) . . ?
O5 Rh3 C67 99.3(3) . . ?
O5 Rh3 O6 76.10(19) . . ?
C67 Rh3 O6 155.9(3) . . ?
O5 Rh3 C66 98.8(3) . . ?
C67 Rh3 C66 40.8(3) . . ?
O6 Rh3 C66 115.8(3) . . ?
O5 Rh3 N2 87.3(3) . . ?
C67 Rh3 N2 119.0(3) . . ?
O6 Rh3 N2 84.8(2) . . ?
C66 Rh3 N2 159.4(3) . . ?
O5 Rh3 C65 129.2(3) . . ?
C67 Rh3 C65 65.0(3) . . ?
O6 Rh3 C65 99.2(2) . . ?
C66 Rh3 C65 37.2(3) . . ?
N2 Rh3 C65 143.3(3) . . ?
O5 Rh3 C68 132.3(3) . . ?
C67 Rh3 C68 39.9(3) . . ?
O6 Rh3 C68 151.6(3) . . ?
C66 Rh3 C68 67.0(3) . . ?
N2 Rh3 C68 94.3(3) . . ?
C65 Rh3 C68 65.2(3) . . ?
O5 Rh3 C69 164.5(3) . . ?
C67 Rh3 C69 66.8(4) . . ?
O6 Rh3 C69 113.5(3) . . ?
C66 Rh3 C69 66.4(3) . . ?
N2 Rh3 C69 105.2(3) . . ?
C65 Rh3 C69 39.8(3) . . ?
C68 Rh3 C69 39.4(4) . . ?
C78 Rh4 C76 62.5(5) . . ?
C78 Rh4 C77 39.9(4) . . ?
C76 Rh4 C77 37.3(4) . . ?
C78 Rh4 N4 122.3(7) . . ?
C76 Rh4 N4 107.3(4) . . ?
C77 Rh4 N4 95.5(4) . . ?
C78 Rh4 O8 101.5(5) . . ?
C76 Rh4 O8 163.3(4) . . ?
C77 Rh4 O8 132.4(5) . . ?
N4 Rh4 O8 85.1(2) . . ?
C78 Rh4 O7 150.8(7) . . ?
C76 Rh4 O7 113.4(4) . . ?
C77 Rh4 O7 149.9(5) . . ?
N4 Rh4 O7 86.9(2) . . ?
O8 Rh4 O7 77.70(19) . . ?
C78 Rh4 C79 43.9(6) . . ?
C76 Rh4 C79 60.0(6) . . ?
C77 Rh4 C79 67.9(5) . . ?
N4 Rh4 C79 163.4(4) . . ?
O8 Rh4 C79 105.5(6) . . ?
O7 Rh4 C79 107.6(4) . . ?
C78 Rh4 C75 67.6(6) . . ?
C76 Rh4 C75 35.6(5) . . ?
C77 Rh4 C75 65.6(5) . . ?
N4 Rh4 C75 137.3(6) . . ?
O8 Rh4 C75 136.4(5) . . ?
O7 Rh4 C75 92.5(4) . . ?
C79 Rh4 C75 37.1(4) . . ?
C133 Rh5 O9 100.1(4) . . ?
C133 Rh5 C132 39.2(4) . . ?
O9 Rh5 C132 104.3(5) . . ?
C133 Rh5 C129 39.8(5) . . ?
O9 Rh5 C129 129.0(5) . . ?
C132 Rh5 C129 66.0(6) . . ?
C133 Rh5 O10 146.7(6) . . ?
O9 Rh5 O10 77.0(2) . . ?
C132 Rh5 O10 108.6(6) . . ?
C129 Rh5 O10 153.8(5) . . ?
C133 Rh5 N5 125.0(7) . . ?
O9 Rh5 N5 84.2(3) . . ?
C132 Rh5 N5 162.5(5) . . ?
C129 Rh5 N5 96.7(4) . . ?
O10 Rh5 N5 88.0(3) . . ?
C133 Rh5 C130 64.9(5) . . ?
O9 Rh5 C130 165.0(4) . . ?
C132 Rh5 C130 64.8(5) . . ?
C129 Rh5 C130 38.3(5) . . ?
O10 Rh5 C130 115.6(5) . . ?
N5 Rh5 C130 103.6(4) . . ?
C133 Rh5 C131 62.8(7) . . ?
O9 Rh5 C131 138.1(6) . . ?
C132 Rh5 C131 37.7(6) . . ?
C129 Rh5 C131 62.6(7) . . ?
O10 Rh5 C131 96.9(6) . . ?
N5 Rh5 C131 137.6(6) . . ?
C130 Rh5 C131 37.0(5) . . ?
N7 Rh6 C139 129.0(6) . . ?
N7 Rh6 C140 163.1(5) . . ?
C139 Rh6 C140 40.4(4) . . ?
N7 Rh6 O12 86.2(3) . . ?
C139 Rh6 O12 98.7(4) . . ?
C140 Rh6 O12 107.2(5) . . ?
N7 Rh6 O11 85.8(3) . . ?
C139 Rh6 O11 145.0(6) . . ?
C140 Rh6 O11 106.9(5) . . ?
O12 Rh6 O11 77.0(2) . . ?
N7 Rh6 C142 98.3(5) . . ?
C139 Rh6 C142 64.0(5) . . ?
C140 Rh6 C142 65.7(6) . . ?
O12 Rh6 C142 160.8(5) . . ?
O11 Rh6 C142 121.8(5) . . ?
N7 Rh6 C141 130.4(5) . . ?
C139 Rh6 C141 63.7(6) . . ?
C140 Rh6 C141 38.1(5) . . ?
O12 Rh6 C141 143.2(5) . . ?
O11 Rh6 C141 98.9(5) . . ?
C142 Rh6 C141 38.3(4) . . ?
N7 Rh6 C143 98.8(7) . . ?
C139 Rh6 C143 37.3(6) . . ?
C140 Rh6 C143 65.5(7) . . ?
O12 Rh6 C143 122.8(5) . . ?
O11 Rh6 C143 159.8(5) . . ?
C142 Rh6 C143 38.2(4) . . ?
C141 Rh6 C143 63.2(7) . . ?
C150 Rh7 N6 141.0(5) . . ?
C150 Rh7 O14 96.0(4) . . ?
N6 Rh7 O14 84.6(2) . . ?
C150 Rh7 C151 37.6(4) . . ?
N6 Rh7 C151 105.9(4) . . ?
O14 Rh7 C151 110.4(4) . . ?
C150 Rh7 C153 65.7(5) . . ?
N6 Rh7 C153 118.9(4) . . ?
O14 Rh7 C153 156.5(4) . . ?
C151 Rh7 C153 64.7(4) . . ?
C150 Rh7 C149 39.7(5) . . ?
N6 Rh7 C149 159.4(4) . . ?
O14 Rh7 C149 115.8(4) . . ?
C151 Rh7 C149 65.5(4) . . ?
C153 Rh7 C149 40.7(5) . . ?
C150 Rh7 O13 130.9(4) . . ?
N6 Rh7 O13 87.5(2) . . ?
O14 Rh7 O13 78.0(2) . . ?
C151 Rh7 O13 164.6(4) . . ?
C153 Rh7 O13 102.3(3) . . ?
C149 Rh7 O13 99.3(4) . . ?
C150 Rh7 C152 64.0(4) . . ?
N6 Rh7 C152 95.4(3) . . ?
O14 Rh7 C152 147.5(4) . . ?
C151 Rh7 C152 38.4(4) . . ?
C153 Rh7 C152 38.2(4) . . ?
C149 Rh7 C152 65.9(4) . . ?
O13 Rh7 C152 134.5(4) . . ?
N8 Rh8 C163 116.5(9) . . ?
N8 Rh8 O16 85.7(3) . . ?
C163 Rh8 O16 157.7(9) . . ?
N8 Rh8 C161 104.8(5) . . ?
C163 Rh8 C161 65.7(5) . . ?
O16 Rh8 C161 108.7(4) . . ?
N8 Rh8 O15 86.1(3) . . ?
C163 Rh8 O15 103.5(4) . . ?
O16 Rh8 O15 78.4(2) . . ?
C161 Rh8 O15 167.1(4) . . ?
N8 Rh8 C159 156.0(6) . . ?
C163 Rh8 C159 39.5(7) . . ?
O16 Rh8 C159 118.2(6) . . ?
C161 Rh8 C159 67.6(6) . . ?
O15 Rh8 C159 99.7(5) . . ?
N8 Rh8 C162 93.7(4) . . ?
C163 Rh8 C162 37.9(5) . . ?
O16 Rh8 C162 146.5(3) . . ?
C161 Rh8 C162 39.2(4) . . ?
O15 Rh8 C162 135.1(3) . . ?
C159 Rh8 C162 65.7(6) . . ?
N8 Rh8 C160 140.3(6) . . ?
C163 Rh8 C160 65.5(8) . . ?
O16 Rh8 C160 96.7(5) . . ?
C161 Rh8 C160 37.0(4) . . ?
O15 Rh8 C160 133.2(6) . . ?
C159 Rh8 C160 41.9(7) . . ?
C162 Rh8 C160 63.2(6) . . ?
C17 N1 C13 117.9(6) . . ?
C17 N1 Rh1 122.0(6) . . ?
C13 N1 Rh1 119.8(5) . . ?
C28 N2 C24 120.5(8) . . ?
C28 N2 Rh3 118.8(7) . . ?
C24 N2 Rh3 120.6(6) . . ?
C29 N3 C33 119.0(9) . . ?
C29 N3 Rh2 120.6(9) . . ?
C33 N3 Rh2 120.1(7) . . ?
C44 N4 C40 117.7(7) . . ?
C44 N4 Rh4 122.3(7) . . ?
C40 N4 Rh4 119.9(5) . . ?
C97 N5 C101 119.7(9) . . ?
C97 N5 Rh5 120.2(8) . . ?
C101 N5 Rh5 120.1(6) . . ?
C108 N6 C112 117.7(7) . . ?
C108 N6 Rh7 122.3(6) . . ?
C112 N6 Rh7 119.9(6) . . ?
C117 N7 C113 120.0(12) . . ?
C117 N7 Rh6 118.7(9) . . ?
C113 N7 Rh6 121.3(8) . . ?
C128 N8 C124 113.3(11) . . ?
C128 N8 Rh8 119.8(9) . . ?
C124 N8 Rh8 126.8(8) . . ?
C1 O1 Rh1 115.5(5) . . ?
C2 O2 Rh1 115.7(5) . . ?
C4 O3 Rh2 114.9(6) . . ?
C5 O4 Rh2 117.0(6) . . ?
C7 O5 Rh3 116.0(5) . . ?
C8 O6 Rh3 115.8(4) . . ?
C10 O7 Rh4 114.7(4) . . ?
C11 O8 Rh4 114.4(5) . . ?
C85 O9 Rh5 115.6(5) . . ?
C86 O10 Rh5 114.8(5) . . ?
C88 O11 Rh6 115.9(5) . . ?
C89 O12 Rh6 115.2(5) . . ?
C91 O13 Rh7 113.4(5) . . ?
C92 O14 Rh7 113.7(5) . . ?
C94 O15 Rh8 112.6(6) . . ?
C95 O16 Rh8 113.7(6) . . ?
C18 S1 C21 94.3(3) . . ?
C23 S2 C20 87.3(4) . . ?
C34 S3 C37 91.5(4) . . ?
C39 S4 C36 90.3(4) . . ?
C102 S5 C105 92.5(3) . . ?
C107 S6 C104 87.7(4) . . ?
C118 S7 C121 90.0(6) . . ?
C123 S8 C120 91.0(6) . . ?
O19 S9 O17 111.9(6) . . ?
O19 S9 O18 116.9(8) . . ?
O17 S9 O18 120.1(6) . . ?
O19 S9 C169 102.5(10) . . ?
O17 S9 C169 101.7(7) . . ?
O18 S9 C169 99.8(6) . . ?
O21 S10 O20 116.6(7) . . ?
O21 S10 O22 116.3(8) . . ?
O20 S10 O22 112.1(8) . . ?
O21 S10 C170 104.1(6) . . ?
O20 S10 C170 103.4(8) . . ?
O22 S10 C170 101.9(7) . . ?
O23 S11 O24 119.4(8) . . ?
O23 S11 O25 126.8(8) . . ?
O24 S11 O25 104.6(9) . . ?
O23 S11 C171 89.2(10) . . ?
O24 S11 C171 104.2(8) . . ?
O25 S11 C171 108.4(9) . . ?
O1 C1 C6 123.3(8) . . ?
O1 C1 C2 116.5(7) . . ?
C6 C1 C2 120.1(8) . . ?
O2 C2 C3 123.2(8) . . ?
O2 C2 C1 115.1(7) . . ?
C3 C2 C1 121.7(8) . . ?
C2 C3 C4 118.1(8) . . ?
C2 C3 H3 121.0 . . ?
C4 C3 H3 121.0 . . ?
O3 C4 C3 122.8(9) . . ?
O3 C4 C5 116.6(8) . . ?
C3 C4 C5 120.6(8) . . ?
O4 C5 C6 125.0(9) . . ?
O4 C5 C4 114.9(8) . . ?
C6 C5 C4 120.2(8) . . ?
C5 C6 C1 119.1(8) . . ?
C5 C6 H6 120.4 . . ?
C1 C6 H6 120.4 . . ?
O5 C7 C12 122.8(7) . . ?
O5 C7 C8 117.0(6) . . ?
C12 C7 C8 120.2(7) . . ?
O6 C8 C9 125.2(7) . . ?
O6 C8 C7 114.2(6) . . ?
C9 C8 C7 120.6(6) . . ?
C8 C9 C10 121.1(7) . . ?
C8 C9 H9 119.5 . . ?
C10 C9 H9 119.5 . . ?
O7 C10 C9 125.4(7) . . ?
O7 C10 C11 116.4(6) . . ?
C9 C10 C11 118.2(6) . . ?
O8 C11 C12 121.7(7) . . ?
O8 C11 C10 116.7(7) . . ?
C12 C11 C10 121.5(6) . . ?
C11 C12 C7 118.4(7) . . ?
C11 C12 H12 120.8 . . ?
C7 C12 H12 120.8 . . ?
N1 C13 C14 124.0(8) . . ?
N1 C13 H13 118.0 . . ?
C14 C13 H13 118.0 . . ?
C15 C14 C13 120.0(8) . . ?
C15 C14 H14 120.0 . . ?
C13 C14 H14 120.0 . . ?
C14 C15 C16 117.8(7) . . ?
C14 C15 C19 120.7(9) . . ?
C16 C15 C19 121.5(7) . . ?
C15 C16 C17 118.4(7) . . ?
C15 C16 H16 120.8 . . ?
C17 C16 H16 120.8 . . ?
N1 C17 C16 121.8(8) . . ?
N1 C17 H17 119.1 . . ?
C16 C17 H17 119.1 . . ?
C19 C18 S1 114.6(5) . . ?
C19 C18 H18 122.7 . . ?
S1 C18 H18 122.7 . . ?
C20 C19 C15 126.7(9) . . ?
C20 C19 C18 105.6(7) . . ?
C15 C19 C18 127.6(7) . . ?
C21 C20 C19 117.2(8) . . ?
C21 C20 S2 108.4(5) . . ?
C19 C20 S2 134.4(7) . . ?
C20 C21 C22 116.1(8) . . ?
C20 C21 S1 108.3(5) . . ?
C22 C21 S1 135.6(6) . . ?
C23 C22 C21 101.9(7) . . ?
C23 C22 C26 133.5(8) . . ?
C21 C22 C26 124.5(9) . . ?
C22 C23 S2 125.7(7) . . ?
C22 C23 H23 117.1 . . ?
S2 C23 H23 117.1 . . ?
N2 C24 C25 120.6(9) . . ?
N2 C24 H24 119.7 . . ?
C25 C24 H24 119.7 . . ?
C26 C25 C24 121.2(10) . . ?
C26 C25 H25 119.4 . . ?
C24 C25 H25 119.4 . . ?
C25 C26 C27 120.5(9) . . ?
C25 C26 C22 119.3(9) . . ?
C27 C26 C22 120.1(7) . . ?
C26 C27 C28 116.7(8) . . ?
C26 C27 H27 121.6 . . ?
C28 C27 H27 121.6 . . ?
N2 C28 C27 120.4(9) . . ?
N2 C28 H28 119.8 . . ?
C27 C28 H28 119.8 . . ?
N3 C29 C30 119.5(11) . . ?
N3 C29 H29 120.2 . . ?
C30 C29 H29 120.2 . . ?
C31 C30 C29 119.3(9) . . ?
C31 C30 H30 120.4 . . ?
C29 C30 H30 120.4 . . ?
C30 C31 C32 120.1(8) . . ?
C30 C31 C35 121.1(8) . . ?
C32 C31 C35 118.8(10) . . ?
C33 C32 C31 116.9(10) . . ?
C33 C32 H32 121.6 . . ?
C31 C32 H32 121.6 . . ?
N3 C33 C32 125.1(9) . . ?
N3 C33 H33 117.5 . . ?
C32 C33 H33 117.5 . . ?
C35 C34 S3 119.2(6) . . ?
C35 C34 H34 120.4 . . ?
S3 C34 H34 120.4 . . ?
C34 C35 C36 105.1(7) . . ?
C34 C35 C31 129.9(8) . . ?
C36 C35 C31 124.9(9) . . ?
C37 C36 C35 117.1(8) . . ?
C37 C36 S4 107.8(5) . . ?
C35 C36 S4 135.2(7) . . ?
C36 C37 C38 116.9(8) . . ?
C36 C37 S3 107.0(5) . . ?
C38 C37 S3 136.0(7) . . ?
C39 C38 C37 106.0(7) . . ?
C39 C38 C42 128.2(7) . . ?
C37 C38 C42 125.8(9) . . ?
C38 C39 S4 118.9(5) . . ?
C38 C39 H39 120.6 . . ?
S4 C39 H39 120.6 . . ?
N4 C40 C41 123.8(8) . . ?
N4 C40 H40 118.1 . . ?
C41 C40 H40 118.1 . . ?
C42 C41 C40 120.3(9) . . ?
C42 C41 H41 119.8 . . ?
C40 C41 H41 119.8 . . ?
C43 C42 C41 118.0(8) . . ?
C43 C42 C38 121.2(8) . . ?
C41 C42 C38 120.8(9) . . ?
C42 C43 C44 120.8(7) . . ?
C42 C43 H43 119.6 . . ?
C44 C43 H43 119.6 . . ?
N4 C44 C43 119.1(9) . . ?
N4 C44 H44 120.4 . . ?
C43 C44 H44 120.4 . . ?
C50 C45 C46 127.4(16) . . ?
C50 C45 C49 127.4(15) . . ?
C46 C45 C49 105.2(9) . . ?
C50 C45 Rh1 124.3(9) . . ?
C46 C45 Rh1 68.6(5) . . ?
C49 C45 Rh1 69.6(5) . . ?
C47 C46 C45 110.0(10) . . ?
C47 C46 C51 124.4(11) . . ?
C45 C46 C51 125.3(12) . . ?
C47 C46 Rh1 74.0(5) . . ?
C45 C46 Rh1 71.1(5) . . ?
C51 C46 Rh1 126.3(7) . . ?
C46 C47 C48 107.9(10) . . ?
C46 C47 C52 125.4(10) . . ?
C48 C47 C52 126.5(11) . . ?
C46 C47 Rh1 69.1(5) . . ?
C48 C47 Rh1 67.9(5) . . ?
C52 C47 Rh1 124.3(6) . . ?
C47 C48 C49 111.4(11) . . ?
C47 C48 C53 122.4(11) . . ?
C49 C48 C53 125.8(10) . . ?
C47 C48 Rh1 73.7(6) . . ?
C49 C48 Rh1 72.2(6) . . ?
C53 C48 Rh1 126.8(7) . . ?
C48 C49 C54 126.1(14) . . ?
C48 C49 C45 105.1(9) . . ?
C54 C49 C45 128.7(14) . . ?
C48 C49 Rh1 68.9(5) . . ?
C54 C49 Rh1 124.5(8) . . ?
C45 C49 Rh1 70.0(5) . . ?
C45 C50 H50A 109.5 . . ?
C45 C50 H50B 109.5 . . ?
H50A C50 H50B 109.5 . . ?
C45 C50 H50C 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
C46 C51 H51A 109.5 . . ?
C46 C51 H51B 109.5 . . ?
H51A C51 H51B 109.5 . . ?
C46 C51 H51C 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
C47 C52 H52A 109.5 . . ?
C47 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C47 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C48 C53 H53A 109.5 . . ?
C48 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C48 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C49 C54 H54A 109.5 . . ?
C49 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
C49 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C59 C55 C56 106.8(11) . . ?
C59 C55 C60 131.7(18) . . ?
C56 C55 C60 121.4(17) . . ?
C59 C55 Rh2 70.1(7) . . ?
C56 C55 Rh2 69.6(5) . . ?
C60 C55 Rh2 124.3(9) . . ?
C57 C56 C55 105.1(13) . . ?
C57 C56 C61 123.8(14) . . ?
C55 C56 C61 131.1(13) . . ?
C57 C56 Rh2 68.4(6) . . ?
C55 C56 Rh2 70.2(6) . . ?
C61 C56 Rh2 126.4(9) . . ?
C58 C57 C56 109.2(14) . . ?
C58 C57 C62 121.1(17) . . ?
C56 C57 C62 129.5(17) . . ?
C58 C57 Rh2 71.6(8) . . ?
C56 C57 Rh2 72.0(7) . . ?
C62 C57 Rh2 126.3(10) . . ?
C57 C58 C59 108.2(15) . . ?
C57 C58 C63 132.5(19) . . ?
C59 C58 C63 119(2) . . ?
C57 C58 Rh2 70.0(8) . . ?
C59 C58 Rh2 71.2(9) . . ?
C63 C58 Rh2 121.8(11) . . ?
C55 C59 C58 110.7(13) . . ?
C55 C59 C64 123(2) . . ?
C58 C59 C64 126(2) . . ?
C55 C59 Rh2 72.3(7) . . ?
C58 C59 Rh2 70.5(8) . . ?
C64 C59 Rh2 123.6(10) . . ?
C55 C60 H60A 109.5 . . ?
C55 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C55 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
C56 C61 H61A 109.5 . . ?
C56 C61 H61B 109.5 . . ?
H61A C61 H61B 109.5 . . ?
C56 C61 H61C 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C57 C62 H62A 109.5 . . ?
C57 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
C57 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
C58 C63 H63A 109.5 . . ?
C58 C63 H63B 109.5 . . ?
H63A C63 H63B 109.5 . . ?
C58 C63 H63C 109.5 . . ?
H63A C63 H63C 109.5 . . ?
H63B C63 H63C 109.5 . . ?
C59 C64 H64A 109.5 . . ?
C59 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C59 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
C66 C65 C69 112.3(8) . . ?
C66 C65 C70 126.2(8) . . ?
C69 C65 C70 121.4(9) . . ?
C66 C65 Rh3 70.9(4) . . ?
C69 C65 Rh3 70.8(4) . . ?
C70 C65 Rh3 123.2(6) . . ?
C65 C66 C71 130.1(9) . . ?
C65 C66 C67 106.9(7) . . ?
C71 C66 C67 123.0(9) . . ?
C65 C66 Rh3 71.9(5) . . ?
C71 C66 Rh3 125.5(6) . . ?
C67 C66 Rh3 68.6(4) . . ?
C68 C67 C66 107.7(8) . . ?
C68 C67 C72 124.0(9) . . ?
C66 C67 C72 128.2(10) . . ?
C68 C67 Rh3 71.8(5) . . ?
C66 C67 Rh3 70.6(5) . . ?
C72 C67 Rh3 124.4(6) . . ?
C67 C68 C69 108.0(8) . . ?
C67 C68 C73 126.3(10) . . ?
C69 C68 C73 125.6(10) . . ?
C67 C68 Rh3 68.3(4) . . ?
C69 C68 Rh3 70.8(4) . . ?
C73 C68 Rh3 123.3(6) . . ?
C68 C69 C74 124.1(9) . . ?
C68 C69 C65 105.0(9) . . ?
C74 C69 C65 130.8(9) . . ?
C68 C69 Rh3 69.8(5) . . ?
C74 C69 Rh3 127.9(7) . . ?
C65 C69 Rh3 69.5(4) . . ?
C65 C70 H70A 109.5 . . ?
C65 C70 H70B 109.5 . . ?
H70A C70 H70B 109.5 . . ?
C65 C70 H70C 109.5 . . ?
H70A C70 H70C 109.5 . . ?
H70B C70 H70C 109.5 . . ?
C66 C71 H71A 109.5 . . ?
C66 C71 H71B 109.5 . . ?
H71A C71 H71B 109.5 . . ?
C66 C71 H71C 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
C67 C72 H72A 109.5 . . ?
C67 C72 H72B 109.5 . . ?
H72A C72 H72B 109.5 . . ?
C67 C72 H72C 109.5 . . ?
H72A C72 H72C 109.5 . . ?
H72B C72 H72C 109.5 . . ?
C68 C73 H73A 109.5 . . ?
C68 C73 H73B 109.5 . . ?
H73A C73 H73B 109.5 . . ?
C68 C73 H73C 109.5 . . ?
H73A C73 H73C 109.5 . . ?
H73B C73 H73C 109.5 . . ?
C69 C74 H74A 109.5 . . ?
C69 C74 H74B 109.5 . . ?
H74A C74 H74B 109.5 . . ?
C69 C74 H74C 109.5 . . ?
H74A C74 H74C 109.5 . . ?
H74B C74 H74C 109.5 . . ?
C76 C75 C79 103.7(14) . . ?
C76 C75 C80 130.4(18) . . ?
C79 C75 C80 125.8(16) . . ?
C76 C75 Rh4 68.1(7) . . ?
C79 C75 Rh4 69.2(8) . . ?
C80 C75 Rh4 123.8(8) . . ?
C75 C76 C77 122.5(14) . . ?
C75 C76 C81 116.7(15) . . ?
C77 C76 C81 120.6(14) . . ?
C75 C76 Rh4 76.4(8) . . ?
C77 C76 Rh4 72.1(6) . . ?
C81 C76 Rh4 128.7(9) . . ?
C76 C77 C78 102.1(12) . . ?
C76 C77 C82 140.0(18) . . ?
C78 C77 C82 117.8(19) . . ?
C76 C77 Rh4 70.6(6) . . ?
C78 C77 Rh4 68.0(6) . . ?
C82 C77 Rh4 125.5(9) . . ?
C77 C78 C83 147(2) . . ?
C77 C78 C79 104.9(12) . . ?
C83 C78 C79 108(2) . . ?
C77 C78 Rh4 72.1(6) . . ?
C83 C78 Rh4 121.2(12) . . ?
C79 C78 Rh4 70.8(6) . . ?
C75 C79 C84 116.9(18) . . ?
C75 C79 C78 106.7(13) . . ?
C84 C79 C78 136(2) . . ?
C75 C79 Rh4 73.7(7) . . ?
C84 C79 Rh4 125.9(12) . . ?
C78 C79 Rh4 65.4(6) . . ?
C75 C80 H80A 109.5 . . ?
C75 C80 H80B 109.5 . . ?
H80A C80 H80B 109.5 . . ?
C75 C80 H80C 109.5 . . ?
H80A C80 H80C 109.5 . . ?
H80B C80 H80C 109.5 . . ?
C76 C81 H81A 109.5 . . ?
C76 C81 H81B 109.5 . . ?
H81A C81 H81B 109.5 . . ?
C76 C81 H81C 109.5 . . ?
H81A C81 H81C 109.5 . . ?
H81B C81 H81C 109.5 . . ?
C77 C82 H82A 109.5 . . ?
C77 C82 H82B 109.5 . . ?
H82A C82 H82B 109.5 . . ?
C77 C82 H82C 109.5 . . ?
H82A C82 H82C 109.5 . . ?
H82B C82 H82C 109.5 . . ?
C78 C83 H83A 109.5 . . ?
C78 C83 H83B 109.5 . . ?
H83A C83 H83B 109.5 . . ?
C78 C83 H83C 109.5 . . ?
H83A C83 H83C 109.5 . . ?
H83B C83 H83C 109.5 . . ?
C79 C84 H84A 109.5 . . ?
C79 C84 H84B 109.5 . . ?
H84A C84 H84B 109.5 . . ?
C79 C84 H84C 109.5 . . ?
H84A C84 H84C 109.5 . . ?
H84B C84 H84C 109.5 . . ?
O9 C85 C90 124.7(7) . . ?
O9 C85 C86 116.7(7) . . ?
C90 C85 C86 118.6(7) . . ?
O10 C86 C87 122.4(8) . . ?
O10 C86 C85 115.6(8) . . ?
C87 C86 C85 122.0(9) . . ?
C88 C87 C86 118.6(8) . . ?
C88 C87 H87 120.7 . . ?
C86 C87 H87 120.7 . . ?
O11 C88 C87 124.4(8) . . ?
O11 C88 C89 114.8(8) . . ?
C87 C88 C89 120.8(8) . . ?
O12 C89 C90 124.6(7) . . ?
O12 C89 C88 117.0(7) . . ?
C90 C89 C88 118.3(8) . . ?
C85 C90 C89 121.4(8) . . ?
C85 C90 H90 119.3 . . ?
C89 C90 H90 119.3 . . ?
O13 C91 C96 122.2(8) . . ?
O13 C91 C92 118.1(7) . . ?
C96 C91 C92 119.7(7) . . ?
O14 C92 C93 120.1(8) . . ?
O14 C92 C91 116.8(7) . . ?
C93 C92 C91 123.1(7) . . ?
C92 C93 C94 116.0(9) . . ?
C92 C93 H93 122.0 . . ?
C94 C93 H93 122.0 . . ?
O15 C94 C93 120.4(9) . . ?
O15 C94 C95 116.8(8) . . ?
C93 C94 C95 122.8(8) . . ?
O16 C95 C96 124.0(9) . . ?
O16 C95 C94 117.7(7) . . ?
C96 C95 C94 118.2(7) . . ?
C91 C96 C95 120.1(8) . . ?
C91 C96 H96 119.9 . . ?
C95 C96 H96 119.9 . . ?
N5 C97 C98 119.5(9) . . ?
N5 C97 H97 120.3 . . ?
C98 C97 H97 120.3 . . ?
C99 C98 C97 120.0(8) . . ?
C99 C98 H98 120.0 . . ?
C97 C98 H98 120.0 . . ?
C100 C99 C98 118.2(9) . . ?
C100 C99 C103 120.4(9) . . ?
C98 C99 C103 121.4(7) . . ?
C101 C100 C99 119.7(10) . . ?
C101 C100 H100 120.2 . . ?
C99 C100 H100 120.2 . . ?
N5 C101 C100 122.9(9) . . ?
N5 C101 H101 118.5 . . ?
C100 C101 H101 118.5 . . ?
C103 C102 S5 114.2(5) . . ?
C103 C102 H102 122.9 . . ?
S5 C102 H102 122.9 . . ?
C104 C103 C102 108.8(7) . . ?
C104 C103 C99 125.2(7) . . ?
C102 C103 C99 125.9(7) . . ?
C105 C104 C103 115.5(7) . . ?
C105 C104 S6 109.3(6) . . ?
C103 C104 S6 134.7(7) . . ?
C104 C105 C106 116.9(7) . . ?
C104 C105 S5 108.9(5) . . ?
C106 C105 S5 134.1(6) . . ?
C107 C106 C105 100.5(7) . . ?
C107 C106 C110 133.4(7) . . ?
C105 C106 C110 125.9(7) . . ?
C106 C107 S6 125.5(6) . . ?
C106 C107 H107 117.3 . . ?
S6 C107 H107 117.3 . . ?
N6 C108 C109 121.0(7) . . ?
N6 C108 H108 119.5 . . ?
C109 C108 H108 119.5 . . ?
C110 C109 C108 121.6(7) . . ?
C110 C109 H109 119.2 . . ?
C108 C109 H109 119.2 . . ?
C109 C110 C111 117.0(8) . . ?
C109 C110 C106 124.0(7) . . ?
C111 C110 C106 119.0(7) . . ?
C112 C111 C110 118.6(8) . . ?
C112 C111 H111 120.7 . . ?
C110 C111 H111 120.7 . . ?
C111 C112 N6 124.0(9) . . ?
C111 C112 H112 118.0 . . ?
N6 C112 H112 118.0 . . ?
N7 C113 C114 121.1(11) . . ?
N7 C113 H113 119.5 . . ?
C114 C113 H113 119.5 . . ?
C113 C114 C115 120.2(11) . . ?
C113 C114 H114 119.9 . . ?
C115 C114 H114 119.9 . . ?
C116 C115 C119 124.5(13) . . ?
C116 C115 C114 114.2(13) . . ?
C119 C115 C114 121.3(11) . . ?
C117 C116 C115 124.1(13) . . ?
C117 C116 H116 117.9 . . ?
C115 C116 H116 117.9 . . ?
N7 C117 C116 120.5(12) . . ?
N7 C117 H117 119.8 . . ?
C116 C117 H117 119.8 . . ?
C119 C118 S7 120.1(9) . . ?
C119 C118 H118 119.9 . . ?
S7 C118 H118 119.9 . . ?
C115 C119 C118 127.7(11) . . ?
C115 C119 C120 129.6(11) . . ?
C118 C119 C120 102.7(12) . . ?
C121 C120 C119 116.7(11) . . ?
C121 C120 S8 111.1(9) . . ?
C119 C120 S8 132.3(11) . . ?
C120 C121 C122 115.0(10) . . ?
C120 C121 S7 110.5(8) . . ?
C122 C121 S7 134.5(10) . . ?
C123 C122 C121 108.6(11) . . ?
C123 C122 C126 125.0(11) . . ?
C121 C122 C126 126.2(10) . . ?
C122 C123 S8 114.3(8) . . ?
C122 C123 H123 122.8 . . ?
S8 C123 H123 122.8 . . ?
C125 C124 N8 126.5(11) . . ?
C125 C124 H124 116.8 . . ?
N8 C124 H124 116.8 . . ?
C124 C125 C126 121.0(13) . . ?
C124 C125 H125 119.5 . . ?
C126 C125 H125 119.5 . . ?
C125 C126 C122 123.2(12) . . ?
C125 C126 C127 112.6(13) . . ?
C122 C126 C127 124.3(10) . . ?
C128 C127 C126 122.5(11) . . ?
C128 C127 H127 118.8 . . ?
C126 C127 H127 118.8 . . ?
C127 C128 N8 124.1(12) . . ?
C127 C128 H128 117.9 . . ?
N8 C128 H128 117.9 . . ?
C130 C129 C133 106.9(14) . . ?
C130 C129 C134 122.8(15) . . ?
C133 C129 C134 130.2(18) . . ?
C130 C129 Rh5 71.5(7) . . ?
C133 C129 Rh5 69.5(7) . . ?
C134 C129 Rh5 126.0(9) . . ?
C131 C130 C129 107.4(13) . . ?
C131 C130 C135 123.2(18) . . ?
C129 C130 C135 129.3(16) . . ?
C131 C130 Rh5 72.7(7) . . ?
C129 C130 Rh5 70.1(7) . . ?
C135 C130 Rh5 125.4(8) . . ?
C130 C131 C132 112.0(18) . . ?
C130 C131 C136 128.5(19) . . ?
C132 C131 C136 119(2) . . ?
C130 C131 Rh5 70.3(8) . . ?
C132 C131 Rh5 69.3(8) . . ?
C136 C131 Rh5 121.2(11) . . ?
C131 C132 C133 105.3(14) . . ?
C131 C132 C137 136(2) . . ?
C133 C132 C137 118(2) . . ?
C131 C132 Rh5 73.0(8) . . ?
C133 C132 Rh5 69.8(7) . . ?
C137 C132 Rh5 128.0(9) . . ?
C132 C133 C129 108.1(13) . . ?
C132 C133 C138 131.8(19) . . ?
C129 C133 C138 120(2) . . ?
C132 C133 Rh5 71.0(7) . . ?
C129 C133 Rh5 70.7(6) . . ?
C138 C133 Rh5 122.0(9) . . ?
C129 C134 H13D 109.5 . . ?
C129 C134 H13E 109.5 . . ?
H13D C134 H13E 109.5 . . ?
C129 C134 H13F 109.5 . . ?
H13D C134 H13F 109.5 . . ?
H13E C134 H13F 109.5 . . ?
C130 C135 H13A 109.5 . . ?
C130 C135 H13B 109.5 . . ?
H13A C135 H13B 109.5 . . ?
C130 C135 H13C 109.5 . . ?
H13A C135 H13C 109.5 . . ?
H13B C135 H13C 109.5 . . ?
C131 C136 H13G 109.5 . . ?
C131 C136 H13H 109.5 . . ?
H13G C136 H13H 109.5 . . ?
C131 C136 H13I 109.5 . . ?
H13G C136 H13I 109.5 . . ?
H13H C136 H13I 109.5 . . ?
C132 C137 H13J 109.5 . . ?
C132 C137 H13K 109.5 . . ?
H13J C137 H13K 109.5 . . ?
C132 C137 H13L 109.5 . . ?
H13J C137 H13L 109.5 . . ?
H13K C137 H13L 109.5 . . ?
C133 C138 H13M 109.5 . . ?
C133 C138 H13N 109.5 . . ?
H13M C138 H13N 109.5 . . ?
C133 C138 H13O 109.5 . . ?
H13M C138 H13O 109.5 . . ?
H13N C138 H13O 109.5 . . ?
C143 C139 C140 110.1(14) . . ?
C143 C139 C144 125.3(17) . . ?
C140 C139 C144 124.6(17) . . ?
C143 C139 Rh6 73.5(10) . . ?
C140 C139 Rh6 70.5(8) . . ?
C144 C139 Rh6 122.3(9) . . ?
C141 C140 C139 103.6(15) . . ?
C141 C140 C145 129.2(18) . . ?
C139 C140 C145 127.0(17) . . ?
C141 C140 Rh6 72.2(9) . . ?
C139 C140 Rh6 69.0(8) . . ?
C145 C140 Rh6 126.3(12) . . ?
C140 C141 C142 111.0(14) . . ?
C140 C141 C146 123.1(18) . . ?
C142 C141 C146 124.9(15) . . ?
C140 C141 Rh6 69.7(7) . . ?
C142 C141 Rh6 70.5(8) . . ?
C146 C141 Rh6 118.0(11) . . ?
C143 C142 C141 106.5(15) . . ?
C143 C142 C147 125(2) . . ?
C141 C142 C147 127.9(17) . . ?
C143 C142 Rh6 71.3(8) . . ?
C141 C142 Rh6 71.2(7) . . ?
C147 C142 Rh6 126.2(11) . . ?
C139 C143 C142 108.6(17) . . ?
C139 C143 C148 127.2(18) . . ?
C142 C143 C148 124(2) . . ?
C139 C143 Rh6 69.2(9) . . ?
C142 C143 Rh6 70.5(8) . . ?
C148 C143 Rh6 128.8(14) . . ?
C139 C144 H14D 109.5 . . ?
C139 C144 H14E 109.5 . . ?
H14D C144 H14E 109.5 . . ?
C139 C144 H14F 109.5 . . ?
H14D C144 H14F 109.5 . . ?
H14E C144 H14F 109.5 . . ?
C140 C145 H14M 109.5 . . ?
C140 C145 H14N 109.5 . . ?
H14M C145 H14N 109.5 . . ?
C140 C145 H14O 109.5 . . ?
H14M C145 H14O 109.5 . . ?
H14N C145 H14O 109.5 . . ?
C141 C146 H14A 109.5 . . ?
C141 C146 H14B 109.5 . . ?
H14A C146 H14B 109.5 . . ?
C141 C146 H14C 109.5 . . ?
H14A C146 H14C 109.5 . . ?
H14B C146 H14C 109.5 . . ?
C142 C147 H14J 109.5 . . ?
C142 C147 H14K 109.5 . . ?
H14J C147 H14K 109.5 . . ?
C142 C147 H14L 109.5 . . ?
H14J C147 H14L 109.5 . . ?
H14K C147 H14L 109.5 . . ?
C143 C148 H14G 109.5 . . ?
C143 C148 H14H 109.5 . . ?
H14G C148 H14H 109.5 . . ?
C143 C148 H14I 109.5 . . ?
H14G C148 H14I 109.5 . . ?
H14H C148 H14I 109.5 . . ?
C150 C149 C153 103.6(9) . . ?
C150 C149 C154 127.7(15) . . ?
C153 C149 C154 128.7(15) . . ?
C150 C149 Rh7 69.0(6) . . ?
C153 C149 Rh7 69.3(5) . . ?
C154 C149 Rh7 125.2(8) . . ?
C151 C150 C149 110.8(12) . . ?
C151 C150 C155 122.3(14) . . ?
C149 C150 C155 126.8(12) . . ?
C151 C150 Rh7 72.1(6) . . ?
C149 C150 Rh7 71.4(6) . . ?
C155 C150 Rh7 120.6(8) . . ?
C150 C151 C152 109.4(11) . . ?
C150 C151 C156 125.6(13) . . ?
C152 C151 C156 124.9(11) . . ?
C150 C151 Rh7 70.3(6) . . ?
C152 C151 Rh7 72.7(6) . . ?
C156 C151 Rh7 125.4(8) . . ?
C153 C152 C151 107.5(10) . . ?
C153 C152 C157 121.9(12) . . ?
C151 C152 C157 130.5(11) . . ?
C153 C152 Rh7 69.0(5) . . ?
C151 C152 Rh7 68.9(6) . . ?
C157 C152 Rh7 125.5(7) . . ?
C152 C153 C149 108.5(11) . . ?
C152 C153 C158 127.8(12) . . ?
C149 C153 C158 123.7(11) . . ?
C152 C153 Rh7 72.8(6) . . ?
C149 C153 Rh7 70.0(6) . . ?
C158 C153 Rh7 122.8(7) . . ?
C149 C154 H15J 109.5 . . ?
C149 C154 H15K 109.5 . . ?
H15J C154 H15K 109.5 . . ?
C149 C154 H15L 109.5 . . ?
H15J C154 H15L 109.5 . . ?
H15K C154 H15L 109.5 . . ?
C150 C155 H15M 109.5 . . ?
C150 C155 H15N 109.5 . . ?
H15M C155 H15N 109.5 . . ?
C150 C155 H15O 109.5 . . ?
H15M C155 H15O 109.5 . . ?
H15N C155 H15O 109.5 . . ?
C151 C156 H15D 109.5 . . ?
C151 C156 H15E 109.5 . . ?
H15D C156 H15E 109.5 . . ?
C151 C156 H15F 109.5 . . ?
H15D C156 H15F 109.5 . . ?
H15E C156 H15F 109.5 . . ?
C152 C157 H15A 109.5 . . ?
C152 C157 H15B 109.5 . . ?
H15A C157 H15B 109.5 . . ?
C152 C157 H15C 109.5 . . ?
H15A C157 H15C 109.5 . . ?
H15B C157 H15C 109.5 . . ?
C153 C158 H15G 109.5 . . ?
C153 C158 H15H 109.5 . . ?
H15G C158 H15H 109.5 . . ?
C153 C158 H15I 109.5 . . ?
H15G C158 H15I 109.5 . . ?
H15H C158 H15I 109.5 . . ?
C164 C159 C163 120(2) . . ?
C164 C159 C160 138(2) . . ?
C163 C159 C160 102.2(14) . . ?
C164 C159 Rh8 124.1(11) . . ?
C163 C159 Rh8 68.8(8) . . ?
C160 C159 Rh8 70.7(8) . . ?
C161 C160 C159 108.6(18) . . ?
C161 C160 C165 129.5(19) . . ?
C159 C160 C165 121(2) . . ?
C161 C160 Rh8 69.1(10) . . ?
C159 C160 Rh8 67.4(9) . . ?
C165 C160 Rh8 121.4(10) . . ?
C160 C161 C162 108.6(14) . . ?
C160 C161 C166 119.4(16) . . ?
C162 C161 C166 131.0(16) . . ?
C160 C161 Rh8 73.9(10) . . ?
C162 C161 Rh8 72.0(6) . . ?
C166 C161 Rh8 128.7(8) . . ?
C163 C162 C161 108.3(16) . . ?
C163 C162 C167 129.3(16) . . ?
C161 C162 C167 122.3(12) . . ?
C163 C162 Rh8 68.4(7) . . ?
C161 C162 Rh8 68.9(6) . . ?
C167 C162 Rh8 125.9(8) . . ?
C162 C163 C159 111.6(17) . . ?
C162 C163 C168 120(2) . . ?
C159 C163 C168 128.8(18) . . ?
C162 C163 Rh8 73.6(6) . . ?
C159 C163 Rh8 71.7(8) . . ?
C168 C163 Rh8 122.7(11) . . ?
C159 C164 H16M 109.5 . . ?
C159 C164 H16N 109.5 . . ?
H16M C164 H16N 109.5 . . ?
C159 C164 H16O 109.5 . . ?
H16M C164 H16O 109.5 . . ?
H16N C164 H16O 109.5 . . ?
C160 C165 H16J 109.5 . . ?
C160 C165 H16K 109.5 . . ?
H16J C165 H16K 109.5 . . ?
C160 C165 H16L 109.5 . . ?
H16J C165 H16L 109.5 . . ?
H16K C165 H16L 109.5 . . ?
C161 C166 H16D 109.5 . . ?
C161 C166 H16E 109.5 . . ?
H16D C166 H16E 109.5 . . ?
C161 C166 H16F 109.5 . . ?
H16D C166 H16F 109.5 . . ?
H16E C166 H16F 109.5 . . ?
C162 C167 H16A 109.5 . . ?
C162 C167 H16B 109.5 . . ?
H16A C167 H16B 109.5 . . ?
C162 C167 H16C 109.5 . . ?
H16A C167 H16C 109.5 . . ?
H16B C167 H16C 109.5 . . ?
C163 C168 H16G 109.5 . . ?
C163 C168 H16H 109.5 . . ?
H16G C168 H16H 109.5 . . ?
C163 C168 H16I 109.5 . . ?
H16G C168 H16I 109.5 . . ?
H16H C168 H16I 109.5 . . ?
F1 C169 F3 105.8(14) . . ?
F1 C169 F2 102.8(12) . . ?
F3 C169 F2 106.1(18) . . ?
F1 C169 S9 120.7(13) . . ?
F3 C169 S9 112.3(12) . . ?
F2 C169 S9 107.9(10) . . ?
F4 C170 F6 105.7(10) . . ?
F4 C170 F5 103.2(12) . . ?
F6 C170 F5 103.3(13) . . ?
F4 C170 S10 117.9(10) . . ?
F6 C170 S10 114.0(10) . . ?
F5 C170 S10 111.2(9) . . ?
F7 C171 F9 105.8(19) . . ?
F7 C171 F8 117(2) . . ?
F9 C171 F8 111.1(17) . . ?
F7 C171 S11 105.6(15) . . ?
F9 C171 S11 107.5(17) . . ?
F8 C171 S11 109.2(14) . . ?

_refine_diff_density_max         1.438
_refine_diff_density_min         -1.432
_refine_diff_density_rms         0.092



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Homo-5
_database_code_depnum_ccdc_archive 'CCDC 1946991'
loop_
_audit_author_name
_audit_author_address
Lu
;Fudan university
China
;
_audit_update_record             
;
2019-08-14 deposited with the CCDC.	2020-10-05 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C104.50 H125 F12 N13 O30.50 Rh4 S4'
_chemical_formula_weight         2819.05

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0150 0.0070 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0600 0.0410 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0250 0.0140 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0410 0.0250 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -0.0160 2.8650 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.2920 0.4250 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   17.0321(14)
_cell_length_b                   18.8424(16)
_cell_length_c                   39.863(3)
_cell_angle_alpha                77.452(4)
_cell_angle_beta                 81.200(3)
_cell_angle_gamma                72.008(4)
_cell_volume                     11826.0(17)
_cell_formula_units_Z            4
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    9150
_cell_measurement_theta_min      3.20
_cell_measurement_theta_max      56.64

_exptl_crystal_description       block
_exptl_crystal_colour            brown
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.583
_exptl_crystal_F_000             5756
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.440
_exptl_crystal_size_mid          0.240
_exptl_crystal_size_min          0.160
_exptl_absorpt_coefficient_mu    3.944
_shelx_estimated_absorpt_T_min   0.276
_shelx_estimated_absorpt_T_max   0.571
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.333
_exptl_absorpt_correction_T_max  0.580
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     1.34138
_diffrn_radiation_type           GaK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            135878
_diffrn_reflns_av_unetI/netI     0.1104
_diffrn_reflns_av_R_equivalents  0.1185
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_l_min       -48
_diffrn_reflns_limit_l_max       48
_diffrn_reflns_theta_min         2.689
_diffrn_reflns_theta_max         55.000
_diffrn_reflns_theta_full        53.594
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measured_fraction_theta_full 0.985
_diffrn_reflns_Laue_measured_fraction_max 0.985
_diffrn_reflns_Laue_measured_fraction_full 0.985
_diffrn_reflns_point_group_measured_fraction_max 0.985
_diffrn_reflns_point_group_measured_fraction_full 0.985
_reflns_number_total             44422
_reflns_number_gt                26994
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 Structure factors included contributions from the .fab file. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          
; 
 One pentamethylcyclopentadienyl ligand (Cp* for short) was 
 disordered and it was divided into two parts (47:53). 40 
 ISOR, 1 SIMU, 4 DELU and 16 DFIX instructions were used to 
 restrain anions and Cp* fragments so that there were 357 
 restraints in the data. 
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.2000P)²+84.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         44422
_refine_ls_number_parameters     2202
_refine_ls_number_restraints     357
_refine_ls_R_factor_all          0.1977
_refine_ls_R_factor_gt           0.1512
_refine_ls_wR_factor_ref         0.4335
_refine_ls_wR_factor_gt          0.3966
_refine_ls_goodness_of_fit_ref   1.151
_refine_ls_restrained_S_all      1.150
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.58814(8) -0.08549(6) 0.68278(3) 0.0709(3) Uani 1 1 d . . . . .
Rh2 Rh 1.05062(7) -0.08476(6) 0.69153(3) 0.0696(3) Uani 1 1 d . . . . .
Rh3 Rh 0.12460(7) 0.64475(6) 0.84408(3) 0.0661(3) Uani 1 1 d . . . . .
Rh4 Rh 0.58569(6) 0.66180(6) 0.83875(3) 0.0630(3) Uani 1 1 d . . . . .
Rh5 Rh 0.29992(8) 0.22480(6) 0.52964(3) 0.0671(3) Uani 1 1 d . . . . .
Rh6 Rh 0.77282(9) 0.18642(9) 0.53948(3) 0.0932(5) Uani 1 1 d . . . . .
Rh7 Rh 0.05516(8) 0.27408(8) 0.92403(3) 0.0769(3) Uani 1 1 d D . . . .
Rh8 Rh 0.51788(8) 0.27720(10) 0.93076(3) 0.0936(5) Uani 1 1 d . . . . .
N1 N 0.5433(8) 0.0047(7) 0.7101(3) 0.069(3) Uani 1 1 d . . . . .
N2 N 0.4153(8) 0.1777(7) 0.7993(3) 0.069(3) Uani 1 1 d . . . . .
H2 H 0.4300 0.1336 0.8132 0.083 Uiso 1 1 calc R U . . .
N3 N 0.3391(8) 0.3846(7) 0.7291(3) 0.068(3) Uani 1 1 d . . . . .
H3 H 0.3207 0.4279 0.7150 0.082 Uiso 1 1 calc R U . . .
N4 N 0.1893(7) 0.5556(6) 0.8162(3) 0.063(3) Uani 1 1 d . . . . .
N5 N 0.9731(8) 0.0055(6) 0.7160(3) 0.067(3) Uani 1 1 d . . . . .
N6 N 0.8093(7) 0.1862(6) 0.7987(3) 0.059(3) Uani 1 1 d . . . . .
H6 H 0.8206 0.1431 0.8135 0.071 Uiso 1 1 calc R U . . .
N7 N 0.7509(7) 0.3892(6) 0.7246(3) 0.061(3) Uani 1 1 d . . . . .
H7 H 0.7386 0.4321 0.7098 0.073 Uiso 1 1 calc R U . . .
N8 N 0.6315(8) 0.5714(6) 0.8109(3) 0.071(3) Uani 1 1 d . . . . .
N9 N 0.2765(7) 0.2447(6) 0.5805(3) 0.059(3) Uani 1 1 d . . . . .
N10 N 0.1844(7) 0.3525(6) 0.6926(3) 0.063(3) Uani 1 1 d . . . . .
H10 H 0.1724 0.3946 0.6772 0.075 Uiso 1 1 calc R U . . .
N11 N 0.2489(7) 0.1484(6) 0.7643(3) 0.060(3) Uani 1 1 d . . . . .
H11 H 0.2601 0.1062 0.7797 0.072 Uiso 1 1 calc R U . . .
N12 N 0.1112(8) 0.2535(7) 0.8739(3) 0.070(3) Uani 1 1 d . . . . .
N13 N 0.7256(8) 0.2112(9) 0.5885(3) 0.077(3) Uani 1 1 d . . . . .
N14 N 0.6041(8) 0.3279(7) 0.6968(3) 0.076(3) Uani 1 1 d . . . . .
H14 H 0.5965 0.3691 0.6808 0.091 Uiso 1 1 calc R U . . .
N15 N 0.6552(8) 0.1289(7) 0.7722(3) 0.068(3) Uani 1 1 d . . . . .
H15 H 0.6674 0.0888 0.7887 0.081 Uiso 1 1 calc R U . . .
N16 N 0.5472(9) 0.2521(10) 0.8799(3) 0.089(4) Uani 1 1 d . . . . .
O1 O 0.6780(7) -0.0353(7) 0.6576(3) 0.083(3) Uani 1 1 d . . . . .
O2 O 0.6865(6) -0.1318(5) 0.7160(2) 0.066(2) Uani 1 1 d . . . . .
O3 O 0.9641(6) -0.1430(5) 0.7173(3) 0.071(2) Uani 1 1 d . . . . .
O4 O 0.9545(7) -0.0479(6) 0.6583(2) 0.076(3) Uani 1 1 d . . . . .
O5 O 0.2103(5) 0.6990(5) 0.8141(2) 0.062(2) Uani 1 1 d . . . . .
O6 O 0.2276(6) 0.6032(6) 0.8733(2) 0.068(2) Uani 1 1 d . . . . .
O7 O 0.5014(6) 0.6024(6) 0.8677(2) 0.067(2) Uani 1 1 d . . . . .
O8 O 0.4851(5) 0.6998(5) 0.8080(2) 0.061(2) Uani 1 1 d . . . . .
O9 O 0.3533(7) 0.2535(5) 0.8398(2) 0.072(3) Uani 1 1 d . . . . .
O10 O 0.4043(6) 0.3116(6) 0.6878(2) 0.071(2) Uani 1 1 d . . . . .
O11 O 0.7509(7) 0.2649(6) 0.8378(2) 0.078(3) Uani 1 1 d . . . . .
O12 O 0.8079(6) 0.3073(5) 0.6861(2) 0.066(2) Uani 1 1 d . . . . .
O13 O 0.3809(6) 0.2937(5) 0.5223(2) 0.067(2) Uani 1 1 d . . . . .
O14 O 0.4081(8) 0.1449(5) 0.5435(3) 0.079(3) Uani 1 1 d . . . . .
O15 O 0.6877(6) 0.1213(6) 0.5465(2) 0.076(3) Uani 1 1 d . . . . .
O16 O 0.6595(7) 0.2696(6) 0.5238(2) 0.077(3) Uani 1 1 d . . . . .
O17 O 0.1276(6) 0.3501(6) 0.9176(2) 0.068(2) Uani 1 1 d . . . . .
O18 O 0.1738(7) 0.1999(6) 0.9391(2) 0.077(3) Uani 1 1 d . . . . .
O19 O 0.4513(10) 0.2055(10) 0.9381(3) 0.129(5) Uani 1 1 d . U . . .
O20 O 0.4019(7) 0.3480(8) 0.9156(3) 0.091(3) Uani 1 1 d . . . . .
O21 O 0.1339(7) 0.4069(5) 0.7414(3) 0.072(2) Uani 1 1 d . . . . .
O22 O 0.3027(6) 0.0933(5) 0.7157(2) 0.067(2) Uani 1 1 d . . . . .
O23 O 0.5475(7) 0.3864(6) 0.7439(3) 0.086(3) Uani 1 1 d . . . . .
O24 O 0.7073(7) 0.0683(7) 0.7255(3) 0.080(3) Uani 1 1 d . . . . .
O25 O 0.8515(14) 0.6239(14) 0.9152(5) 0.172(8) Uani 1 1 d . . . . .
O26 O 0.7314(13) 0.7257(12) 0.9364(6) 0.167(7) Uani 1 1 d . . . . .
O27 O 0.8691(13) 0.7246(15) 0.9412(7) 0.191(10) Uani 1 1 d . . . . .
O28 O 0.338(2) 0.9540(10) 0.5897(7) 0.215(12) Uani 1 1 d D . . . .
O29 O 0.3015(17) 0.8332(19) 0.6046(8) 0.256(16) Uani 1 1 d . . . . .
O30 O 0.425(4) 0.836(3) 0.6173(10) 0.43(4) Uani 1 1 d . . . . .
S1 S 0.8192(5) 0.6796(4) 0.93766(18) 0.126(2) Uani 1 1 d . . . . .
S2 S 0.3659(5) 0.8700(6) 0.5956(2) 0.147(3) Uani 1 1 d D . . . .
F1 F 0.8901(11) 0.5707(15) 0.9860(5) 0.228(11) Uani 1 1 d D . . . .
F2 F 0.797(2) 0.652(3) 1.0045(7) 0.38(3) Uani 1 1 d . . . . .
F3 F 0.7635(14) 0.5761(18) 0.9813(6) 0.250(13) Uani 1 1 d . . . . .
F4 F 0.4320(13) 0.7945(11) 0.5500(6) 0.205(8) Uani 1 1 d D U . . .
F5 F 0.3343(15) 0.8907(15) 0.5347(6) 0.241(10) Uani 1 1 d D U . . .
F6 F 0.4562(18) 0.9050(19) 0.5430(9) 0.299(14) Uani 1 1 d D U . . .
C1 C 0.7471(10) -0.0574(7) 0.6703(4) 0.064(3) Uani 1 1 d . . . . .
C2 C 0.7504(10) -0.1146(8) 0.7040(3) 0.064(3) Uani 1 1 d . . . . .
C3 C 0.8247(10) -0.1412(8) 0.7203(4) 0.073(4) Uani 1 1 d . . . . .
H3A H 0.8265 -0.1737 0.7422 0.088 Uiso 1 1 calc R U . . .
C4 C 0.8954(11) -0.1204(7) 0.7049(4) 0.069(4) Uani 1 1 d . . . . .
C5 C 0.8916(8) -0.0659(7) 0.6707(3) 0.057(3) Uani 1 1 d . . . . .
C6 C 0.8191(11) -0.0378(8) 0.6549(4) 0.075(4) Uani 1 1 d . . . . .
H6A H 0.8178 -0.0046 0.6331 0.090 Uiso 1 1 calc R U . . .
C7 C 0.2808(7) 0.6794(7) 0.8243(3) 0.052(3) Uani 1 1 d . . . . .
C8 C 0.2926(9) 0.6220(8) 0.8588(4) 0.063(3) Uani 1 1 d . . . . .
C9 C 0.3679(9) 0.5986(8) 0.8727(3) 0.067(3) Uani 1 1 d . . . . .
H9 H 0.3744 0.5648 0.8942 0.080 Uiso 1 1 calc R U . . .
C10 C 0.4301(8) 0.6226(8) 0.8565(4) 0.062(3) Uani 1 1 d . . . . .
C11 C 0.4224(8) 0.6782(6) 0.8219(3) 0.053(3) Uani 1 1 d . . . . .
C12 C 0.3456(8) 0.7037(7) 0.8069(4) 0.060(3) Uani 1 1 d . . . . .
H12 H 0.3398 0.7369 0.7852 0.071 Uiso 1 1 calc R U . . .
C13 C 0.5213(8) 0.0765(7) 0.6933(3) 0.059(3) Uani 1 1 d . . . . .
H13 H 0.5304 0.0860 0.6688 0.071 Uiso 1 1 calc R U . . .
C14 C 0.4867(9) 0.1360(7) 0.7097(3) 0.061(3) Uani 1 1 d . . . . .
H14P H 0.4723 0.1863 0.6969 0.073 Uiso 1 1 calc R U . . .
C15 C 0.4723(8) 0.1230(7) 0.7458(4) 0.062(3) Uani 1 1 d . . . . .
C16 C 0.4966(12) 0.0500(9) 0.7631(4) 0.082(5) Uani 1 1 d . . . . .
H16 H 0.4872 0.0393 0.7876 0.098 Uiso 1 1 calc R U . . .
C17 C 0.5351(14) -0.0086(10) 0.7449(4) 0.101(6) Uani 1 1 d . . . . .
H17 H 0.5560 -0.0587 0.7571 0.121 Uiso 1 1 calc R U . . .
C18 C 0.4300(9) 0.1881(8) 0.7636(3) 0.063(3) Uani 1 1 d . . . . .
C19 C 0.3985(9) 0.2629(7) 0.7505(3) 0.060(3) Uani 1 1 d . . . . .
C20 C 0.3624(9) 0.3027(8) 0.7784(3) 0.061(3) Uani 1 1 d . . . . .
C21 C 0.3258(8) 0.3768(7) 0.7641(3) 0.060(3) Uani 1 1 d . . . . .
C22 C 0.3739(9) 0.2466(8) 0.8101(3) 0.065(3) Uani 1 1 d . . . . .
C23 C 0.3846(9) 0.3176(8) 0.7175(4) 0.066(3) Uani 1 1 d . . . . .
C24 C 0.2240(12) 0.4858(9) 0.8337(4) 0.079(4) Uani 1 1 d . . . . .
H24 H 0.2187 0.4776 0.8582 0.095 Uiso 1 1 calc R U . . .
C25 C 0.2650(11) 0.4281(9) 0.8180(4) 0.078(4) Uani 1 1 d . . . . .
H25 H 0.2876 0.3795 0.8313 0.093 Uiso 1 1 calc R U . . .
C26 C 0.2752(10) 0.4384(7) 0.7823(3) 0.063(3) Uani 1 1 d . . . . .
C27 C 0.2377(10) 0.5088(8) 0.7642(4) 0.068(4) Uani 1 1 d . . . . .
H27 H 0.2392 0.5179 0.7398 0.082 Uiso 1 1 calc R U . . .
C28 C 0.1975(10) 0.5658(7) 0.7829(4) 0.067(4) Uani 1 1 d . . . . .
H28 H 0.1747 0.6154 0.7705 0.080 Uiso 1 1 calc R U . . .
C29 C 0.9480(9) 0.0778(7) 0.6973(4) 0.065(3) Uani 1 1 d . . . . .
H29 H 0.9644 0.0867 0.6732 0.077 Uiso 1 1 calc R U . . .
C30 C 0.9001(9) 0.1369(8) 0.7126(4) 0.068(4) Uani 1 1 d . . . . .
H30 H 0.8840 0.1862 0.6990 0.082 Uiso 1 1 calc R U . . .
C31 C 0.8746(7) 0.1267(7) 0.7474(3) 0.056(3) Uani 1 1 d . . . . .
C32 C 0.8948(10) 0.0548(8) 0.7659(3) 0.067(4) Uani 1 1 d . . . . .
H32 H 0.8739 0.0453 0.7895 0.081 Uiso 1 1 calc R U . . .
C33 C 0.9472(10) -0.0058(8) 0.7501(3) 0.069(4) Uani 1 1 d . . . . .
H33 H 0.9645 -0.0551 0.7636 0.082 Uiso 1 1 calc R U . . .
C34 C 0.8290(8) 0.1912(7) 0.7631(3) 0.057(3) Uani 1 1 d . . . . .
C35 C 0.7975(8) 0.2660(7) 0.7486(3) 0.060(3) Uani 1 1 d . . . . .
C36 C 0.7608(8) 0.3086(7) 0.7758(3) 0.057(3) Uani 1 1 d . . . . .
C37 C 0.7344(8) 0.3833(8) 0.7613(4) 0.062(3) Uani 1 1 d . . . . .
C38 C 0.7707(8) 0.2552(7) 0.8085(3) 0.057(3) Uani 1 1 d . . . . .
C39 C 0.7888(8) 0.3183(7) 0.7155(3) 0.056(3) Uani 1 1 d . . . . .
C40 C 0.6457(13) 0.4997(9) 0.8278(4) 0.091(5) Uani 1 1 d . . . . .
H40 H 0.6339 0.4912 0.8522 0.109 Uiso 1 1 calc R U . . .
C41 C 0.6754(13) 0.4396(10) 0.8123(4) 0.094(6) Uani 1 1 d . . . . .
H41 H 0.6834 0.3900 0.8256 0.113 Uiso 1 1 calc R U . . .
C42 C 0.6945(9) 0.4490(7) 0.7772(3) 0.061(3) Uani 1 1 d . . . . .
C43 C 0.6816(11) 0.5240(8) 0.7594(4) 0.078(4) Uani 1 1 d . . . . .
H43 H 0.6941 0.5351 0.7351 0.094 Uiso 1 1 calc R U . . .
C44 C 0.6510(10) 0.5787(8) 0.7780(4) 0.073(4) Uani 1 1 d . . . . .
H44 H 0.6425 0.6292 0.7656 0.088 Uiso 1 1 calc R U . . .
C45 C 0.5418(10) -0.1816(8) 0.6893(4) 0.072(4) Uani 1 1 d D U . . .
C46 C 0.4730(14) -0.1147(11) 0.6874(6) 0.102(7) Uani 1 1 d . . . . .
C47 C 0.4835(14) -0.0667(10) 0.6561(6) 0.101(7) Uani 1 1 d . . . . .
C48 C 0.5507(16) -0.1043(11) 0.6375(5) 0.106(6) Uani 1 1 d . . . . .
C49 C 0.5954(12) -0.1778(10) 0.6582(4) 0.096(5) Uani 1 1 d D U . . .
C50 C 0.5618(14) -0.2480(11) 0.7162(6) 0.105(6) Uani 1 1 d . . . . .
H50A H 0.5503 -0.2904 0.7092 0.158 Uiso 1 1 calc R U . . .
H50B H 0.5280 -0.2372 0.7377 0.158 Uiso 1 1 calc R U . . .
H50C H 0.6206 -0.2616 0.7198 0.158 Uiso 1 1 calc R U . . .
C51 C 0.4111(14) -0.1024(14) 0.7161(7) 0.130(9) Uani 1 1 d . . . . .
H51A H 0.4138 -0.1507 0.7319 0.196 Uiso 1 1 calc R U . . .
H51B H 0.3560 -0.0813 0.7076 0.196 Uiso 1 1 calc R U . . .
H51C H 0.4212 -0.0667 0.7284 0.196 Uiso 1 1 calc R U . . .
C52 C 0.4252(17) 0.0104(11) 0.6410(7) 0.135(10) Uani 1 1 d . . . . .
H52A H 0.4111 0.0442 0.6579 0.203 Uiso 1 1 calc R U . . .
H52B H 0.3744 0.0029 0.6356 0.203 Uiso 1 1 calc R U . . .
H52C H 0.4529 0.0332 0.6199 0.203 Uiso 1 1 calc R U . . .
C53 C 0.590(3) -0.0715(15) 0.6023(6) 0.189(17) Uani 1 1 d . . . . .
H53A H 0.5647 -0.0805 0.5837 0.284 Uiso 1 1 calc R U . . .
H53B H 0.6496 -0.0964 0.6003 0.284 Uiso 1 1 calc R U . . .
H53C H 0.5799 -0.0168 0.6006 0.284 Uiso 1 1 calc R U . . .
C54 C 0.6790(15) -0.2360(12) 0.6488(5) 0.110(7) Uani 1 1 d . . . . .
H54A H 0.7188 -0.2088 0.6368 0.166 Uiso 1 1 calc R U . . .
H54B H 0.6699 -0.2670 0.6338 0.166 Uiso 1 1 calc R U . . .
H54C H 0.7010 -0.2689 0.6699 0.166 Uiso 1 1 calc R U . . .
C55 C 1.1507(10) -0.0760(10) 0.6538(5) 0.094(6) Uani 1 1 d D . . . .
C56 C 1.1637(13) -0.0574(10) 0.6855(6) 0.109(7) Uani 1 1 d D . . . .
C57 C 1.1674(12) -0.1209(12) 0.7121(7) 0.106(6) Uani 1 1 d . . . . .
C58 C 1.1542(13) -0.1762(9) 0.6957(6) 0.097(6) Uani 1 1 d . . . . .
C59 C 1.1487(12) -0.1536(10) 0.6609(5) 0.097(6) Uani 1 1 d . . . . .
C60 C 1.1407(16) -0.0217(15) 0.6204(7) 0.153(12) Uani 1 1 d . . . . .
H60A H 1.1954 -0.0226 0.6082 0.230 Uiso 1 1 calc R U . . .
H60B H 1.1119 0.0296 0.6248 0.230 Uiso 1 1 calc R U . . .
H60C H 1.1082 -0.0363 0.6062 0.230 Uiso 1 1 calc R U . . .
C61 C 1.1705(17) 0.0196(15) 0.6932(10) 0.163(12) Uani 1 1 d . . . . .
H61A H 1.1191 0.0444 0.7060 0.245 Uiso 1 1 calc R U . . .
H61B H 1.1795 0.0532 0.6714 0.245 Uiso 1 1 calc R U . . .
H61C H 1.2172 0.0087 0.7070 0.245 Uiso 1 1 calc R U . . .
C62 C 1.1843(14) -0.1307(18) 0.7481(6) 0.144(10) Uani 1 1 d . . . . .
H62A H 1.2408 -0.1287 0.7487 0.216 Uiso 1 1 calc R U . . .
H62B H 1.1787 -0.1800 0.7607 0.216 Uiso 1 1 calc R U . . .
H62C H 1.1447 -0.0901 0.7588 0.216 Uiso 1 1 calc R U . . .
C63 C 1.1627(19) -0.2596(10) 0.7171(7) 0.153(12) Uani 1 1 d . . . . .
H63A H 1.1260 -0.2819 0.7089 0.229 Uiso 1 1 calc R U . . .
H63B H 1.1473 -0.2574 0.7416 0.229 Uiso 1 1 calc R U . . .
H63C H 1.2202 -0.2909 0.7139 0.229 Uiso 1 1 calc R U . . .
C64 C 1.1346(15) -0.1927(17) 0.6353(7) 0.151(11) Uani 1 1 d . . . . .
H64A H 1.1317 -0.2437 0.6466 0.227 Uiso 1 1 calc R U . . .
H64B H 1.1804 -0.1967 0.6170 0.227 Uiso 1 1 calc R U . . .
H64C H 1.0824 -0.1640 0.6254 0.227 Uiso 1 1 calc R U . . .
C65 C 0.7009(8) 0.6657(11) 0.8506(5) 0.086(6) Uani 1 1 d . . . . .
C66 C 0.6670(10) 0.7303(12) 0.8258(4) 0.086(5) Uani 1 1 d . . . . .
C67 C 0.5948(12) 0.7686(10) 0.8405(6) 0.087(5) Uani 1 1 d . . . . .
C68 C 0.5768(13) 0.7373(11) 0.8726(5) 0.093(5) Uani 1 1 d . . . . .
C69 C 0.6463(13) 0.6665(11) 0.8802(5) 0.094(6) Uani 1 1 d . . . . .
C70 C 0.7809(14) 0.591(2) 0.8486(10) 0.187(13) Uani 1 1 d . U . . .
H70A H 0.8138 0.5986 0.8264 0.281 Uiso 1 1 calc R U . . .
H70B H 0.8150 0.5844 0.8674 0.281 Uiso 1 1 calc R U . . .
H70C H 0.7618 0.5464 0.8508 0.281 Uiso 1 1 calc R U . . .
C71 C 0.7016(18) 0.7570(16) 0.7909(6) 0.140(9) Uani 1 1 d . U . . .
H71A H 0.6570 0.7784 0.7755 0.210 Uiso 1 1 calc R U . . .
H71B H 0.7430 0.7143 0.7822 0.210 Uiso 1 1 calc R U . . .
H71C H 0.7278 0.7960 0.7917 0.210 Uiso 1 1 calc R U . . .
C72 C 0.547(2) 0.8434(15) 0.8206(10) 0.195(14) Uani 1 1 d . U . . .
H72A H 0.5460 0.8846 0.8322 0.292 Uiso 1 1 calc R U . . .
H72B H 0.4903 0.8427 0.8196 0.292 Uiso 1 1 calc R U . . .
H72C H 0.5742 0.8515 0.7972 0.292 Uiso 1 1 calc R U . . .
C73 C 0.4999(18) 0.772(2) 0.8945(9) 0.177(13) Uani 1 1 d . U . . .
H73A H 0.5110 0.7584 0.9188 0.266 Uiso 1 1 calc R U . . .
H73B H 0.4545 0.7530 0.8914 0.266 Uiso 1 1 calc R U . . .
H73C H 0.4841 0.8274 0.8875 0.266 Uiso 1 1 calc R U . . .
C74 C 0.645(2) 0.6076(17) 0.9127(7) 0.157(11) Uani 1 1 d . . . . .
H74A H 0.6055 0.5799 0.9115 0.235 Uiso 1 1 calc R U . . .
H74B H 0.6279 0.6327 0.9328 0.235 Uiso 1 1 calc R U . . .
H74C H 0.7004 0.5719 0.9149 0.235 Uiso 1 1 calc R U . . .
C75 C -0.0014(9) 0.6767(12) 0.8299(5) 0.089(5) Uani 1 1 d . U . . .
C76 C 0.0103(12) 0.6174(11) 0.8586(7) 0.110(7) Uani 1 1 d . . . . .
C77 C 0.0356(12) 0.6336(11) 0.8868(5) 0.089(5) Uani 1 1 d . . . . .
C78 C 0.0384(12) 0.7100(12) 0.8783(5) 0.102(6) Uani 1 1 d D . . . .
C79 C 0.0179(14) 0.7360(13) 0.8438(6) 0.127(9) Uani 1 1 d D . . . .
C80 C -0.0201(17) 0.6825(19) 0.7955(8) 0.160(12) Uani 1 1 d . . . . .
H80A H -0.0721 0.7225 0.7911 0.240 Uiso 1 1 calc R U . . .
H80B H -0.0258 0.6340 0.7926 0.240 Uiso 1 1 calc R U . . .
H80C H 0.0248 0.6952 0.7791 0.240 Uiso 1 1 calc R U . . .
C81 C 0.0072(17) 0.5357(15) 0.8558(10) 0.161(11) Uani 1 1 d . U . . .
H81A H 0.0481 0.4970 0.8699 0.242 Uiso 1 1 calc R U . . .
H81B H 0.0200 0.5291 0.8316 0.242 Uiso 1 1 calc R U . . .
H81C H -0.0483 0.5305 0.8641 0.242 Uiso 1 1 calc R U . . .
C82 C 0.0553(18) 0.576(2) 0.9196(8) 0.169(12) Uani 1 1 d . U . . .
H82A H 0.0160 0.5457 0.9247 0.253 Uiso 1 1 calc R U . . .
H82B H 0.0507 0.6024 0.9387 0.253 Uiso 1 1 calc R U . . .
H82C H 0.1118 0.5427 0.9165 0.253 Uiso 1 1 calc R U . . .
C83 C 0.066(2) 0.747(2) 0.9028(9) 0.192(16) Uani 1 1 d . . . . .
H83A H 0.0232 0.7572 0.9219 0.287 Uiso 1 1 calc R U . . .
H83B H 0.0761 0.7950 0.8903 0.287 Uiso 1 1 calc R U . . .
H83C H 0.1177 0.7131 0.9120 0.287 Uiso 1 1 calc R U . . .
C84 C 0.018(2) 0.8150(15) 0.8271(10) 0.184(15) Uani 1 1 d . . . . .
H84A H -0.0377 0.8434 0.8198 0.276 Uiso 1 1 calc R U . . .
H84B H 0.0585 0.8136 0.8069 0.276 Uiso 1 1 calc R U . . .
H84C H 0.0315 0.8400 0.8436 0.276 Uiso 1 1 calc R U . . .
C85 C 0.4582(10) 0.2543(8) 0.5268(3) 0.065(3) Uani 1 1 d . . . . .
C86 C 0.4747(10) 0.1702(7) 0.5403(3) 0.062(3) Uani 1 1 d . . . . .
C87 C 0.5507(9) 0.1241(7) 0.5461(3) 0.062(3) Uani 1 1 d . . . . .
H87 H 0.5604 0.0708 0.5529 0.074 Uiso 1 1 calc R U . . .
C88 C 0.6152(9) 0.1577(8) 0.5416(3) 0.064(4) Uani 1 1 d . . . . .
C89 C 0.5955(10) 0.2436(8) 0.5283(3) 0.065(3) Uani 1 1 d . . . . .
C90 C 0.5191(8) 0.2885(7) 0.5228(3) 0.056(3) Uani 1 1 d . . . . .
H90 H 0.5080 0.3420 0.5164 0.067 Uiso 1 1 calc R U . . .
C91 C 0.2037(9) 0.3204(8) 0.9212(3) 0.063(3) Uani 1 1 d . . . . .
C92 C 0.2278(10) 0.2349(10) 0.9342(3) 0.077(5) Uani 1 1 d . . . . .
C93 C 0.3075(12) 0.1959(11) 0.9386(4) 0.090(5) Uani 1 1 d . . . . .
H93 H 0.3232 0.1423 0.9452 0.108 Uiso 1 1 calc R U . . .
C94 C 0.3670(10) 0.2355(10) 0.9331(4) 0.080(4) Uani 1 1 d . U . . .
C95 C 0.3468(10) 0.3164(10) 0.9200(3) 0.074(4) Uani 1 1 d . . . . .
C96 C 0.2605(9) 0.3590(8) 0.9153(3) 0.064(3) Uani 1 1 d . . . . .
H96 H 0.2448 0.4125 0.9083 0.077 Uiso 1 1 calc R U . . .
C97 C 0.2919(9) 0.1863(7) 0.6076(3) 0.062(3) Uani 1 1 d . . . . .
H97 H 0.3139 0.1361 0.6030 0.075 Uiso 1 1 calc R U . . .
C98 C 0.2769(9) 0.1966(7) 0.6414(3) 0.064(3) Uani 1 1 d . . . . .
H98 H 0.2887 0.1539 0.6596 0.077 Uiso 1 1 calc R U . . .
C99 C 0.2449(8) 0.2687(7) 0.6490(3) 0.058(3) Uani 1 1 d . . . . .
C100 C 0.2279(10) 0.3292(8) 0.6201(3) 0.067(3) Uani 1 1 d . . . . .
H100 H 0.2036 0.3800 0.6235 0.080 Uiso 1 1 calc R U . . .
C101 C 0.2465(10) 0.3138(8) 0.5881(4) 0.069(4) Uani 1 1 d . . . . .
H101 H 0.2375 0.3555 0.5694 0.083 Uiso 1 1 calc R U . . .
C102 C 0.2217(9) 0.2829(8) 0.6844(4) 0.063(3) Uani 1 1 d . . . . .
C103 C 0.2360(8) 0.2290(7) 0.7152(3) 0.058(3) Uani 1 1 d . . . . .
C104 C 0.2005(8) 0.2715(8) 0.7421(3) 0.056(3) Uani 1 1 d . . . . .
C105 C 0.2115(7) 0.2187(8) 0.7722(3) 0.059(3) Uani 1 1 d . . . . .
C106 C 0.1674(9) 0.3502(8) 0.7277(4) 0.065(3) Uani 1 1 d . . . . .
C107 C 0.2670(8) 0.1514(8) 0.7292(3) 0.061(3) Uani 1 1 d . . . . .
C108 C 0.1013(9) 0.3129(9) 0.8467(3) 0.067(3) Uani 1 1 d . . . . .
H108 H 0.0714 0.3627 0.8504 0.080 Uiso 1 1 calc R U . . .
C109 C 0.1349(9) 0.3004(9) 0.8138(4) 0.067(3) Uani 1 1 d . . . . .
H109 H 0.1285 0.3418 0.7950 0.081 Uiso 1 1 calc R U . . .
C110 C 0.1749(8) 0.2329(7) 0.8087(3) 0.056(3) Uani 1 1 d . . . . .
C111 C 0.1882(11) 0.1733(10) 0.8357(4) 0.086(5) Uani 1 1 d . . . . .
H111 H 0.2201 0.1238 0.8324 0.103 Uiso 1 1 calc R U . . .
C112 C 0.1530(11) 0.1878(11) 0.8688(4) 0.081(4) Uani 1 1 d . . . . .
H112 H 0.1609 0.1470 0.8879 0.097 Uiso 1 1 calc R U . . .
C113 C 0.7174(9) 0.1518(9) 0.6157(4) 0.073(4) Uani 1 1 d . . . . .
H113 H 0.7286 0.1018 0.6114 0.087 Uiso 1 1 calc R U . . .
C114 C 0.6920(10) 0.1670(9) 0.6501(4) 0.074(4) Uani 1 1 d . . . . .
H114 H 0.6904 0.1262 0.6687 0.088 Uiso 1 1 calc R U . . .
C115 C 0.6704(10) 0.2384(9) 0.6564(4) 0.070(4) Uani 1 1 d . . . . .
C116 C 0.6741(13) 0.3022(11) 0.6272(4) 0.091(5) Uani 1 1 d . . . . .
H116 H 0.6574 0.3536 0.6301 0.110 Uiso 1 1 calc R U . . .
C117 C 0.7037(12) 0.2802(12) 0.5954(4) 0.090(5) Uani 1 1 d . . . . .
H117 H 0.7088 0.3197 0.5765 0.108 Uiso 1 1 calc R U . . .
C118 C 0.6409(9) 0.2562(9) 0.6905(4) 0.069(4) Uani 1 1 d . . . . .
C119 C 0.6444(8) 0.2043(8) 0.7219(3) 0.063(3) Uani 1 1 d . . . . .
C120 C 0.6101(9) 0.2495(9) 0.7474(3) 0.067(4) Uani 1 1 d . . . . .
C121 C 0.6165(9) 0.1991(9) 0.7786(4) 0.068(4) Uani 1 1 d . . . . .
C122 C 0.5283(10) 0.3059(10) 0.8515(4) 0.079(4) Uani 1 1 d . . . . .
H122 H 0.4999 0.3567 0.8541 0.095 Uiso 1 1 calc R U . . .
C123 C 0.5487(10) 0.2895(11) 0.8194(4) 0.079(4) Uani 1 1 d . . . . .
H123 H 0.5350 0.3286 0.7999 0.095 Uiso 1 1 calc R U . . .
C124 C 0.5891(9) 0.2167(9) 0.8149(3) 0.064(3) Uani 1 1 d . . . . .
C125 C 0.6119(11) 0.1610(11) 0.8439(4) 0.083(4) Uani 1 1 d . . . . .
H125 H 0.6412 0.1100 0.8418 0.100 Uiso 1 1 calc R U . . .
C126 C 0.5908(12) 0.1823(11) 0.8748(4) 0.090(5) Uani 1 1 d . . . . .
H126 H 0.6081 0.1450 0.8946 0.107 Uiso 1 1 calc R U . . .
C127 C 0.5803(10) 0.3278(10) 0.7314(4) 0.073(4) Uani 1 1 d . . . . .
C128 C 0.6739(10) 0.1248(9) 0.7379(4) 0.070(4) Uani 1 1 d . . . . .
C129 C 0.2845(12) 0.2279(11) 0.4780(4) 0.085(5) Uani 1 1 d . . . . .
C130 C 0.2765(13) 0.1578(9) 0.4968(4) 0.089(5) Uani 1 1 d . . . . .
C131 C 0.2105(10) 0.1741(10) 0.5242(4) 0.074(4) Uani 1 1 d . . . . .
C132 C 0.1717(11) 0.2519(11) 0.5204(4) 0.085(5) Uani 1 1 d . . . . .
C133 C 0.2191(12) 0.2870(12) 0.4909(4) 0.090(5) Uani 1 1 d . . . . .
C134 C 0.3447(16) 0.2429(14) 0.4468(5) 0.118(7) Uani 1 1 d . . . . .
H13A H 0.3654 0.2846 0.4489 0.177 Uiso 1 1 calc R U . . .
H13B H 0.3161 0.2565 0.4258 0.177 Uiso 1 1 calc R U . . .
H13C H 0.3913 0.1971 0.4456 0.177 Uiso 1 1 calc R U . . .
C135 C 0.3290(13) 0.0797(10) 0.4935(5) 0.093(5) Uani 1 1 d . . . . .
H13D H 0.3165 0.0658 0.4730 0.140 Uiso 1 1 calc R U . . .
H13E H 0.3175 0.0438 0.5140 0.140 Uiso 1 1 calc R U . . .
H13F H 0.3877 0.0780 0.4912 0.140 Uiso 1 1 calc R U . . .
C136 C 0.1794(12) 0.1136(11) 0.5502(5) 0.098(6) Uani 1 1 d . . . . .
H13G H 0.1605 0.1311 0.5723 0.147 Uiso 1 1 calc R U . . .
H13H H 0.2245 0.0663 0.5536 0.147 Uiso 1 1 calc R U . . .
H13I H 0.1332 0.1048 0.5414 0.147 Uiso 1 1 calc R U . . .
C137 C 0.1014(11) 0.2946(11) 0.5405(5) 0.094(5) Uani 1 1 d . . . . .
H13J H 0.1088 0.2771 0.5652 0.140 Uiso 1 1 calc R U . . .
H13K H 0.0503 0.2868 0.5357 0.140 Uiso 1 1 calc R U . . .
H13L H 0.0978 0.3487 0.5343 0.140 Uiso 1 1 calc R U . . .
C138 C 0.2022(14) 0.3718(12) 0.4770(5) 0.111(7) Uani 1 1 d . . . . .
H13M H 0.2545 0.3852 0.4728 0.166 Uiso 1 1 calc R U . . .
H13N H 0.1649 0.4003 0.4939 0.166 Uiso 1 1 calc R U . . .
H13O H 0.1762 0.3846 0.4553 0.166 Uiso 1 1 calc R U . . .
C139 C 0.9001(13) 0.1793(12) 0.5429(6) 0.111(6) Uani 1 1 d D U . . .
C140 C 0.8955(13) 0.1081(12) 0.5383(6) 0.110(7) Uani 1 1 d D . . . .
C141 C 0.8691(16) 0.1162(16) 0.5061(5) 0.120(8) Uani 1 1 d . . . . .
C142 C 0.8529(15) 0.1938(16) 0.4911(6) 0.114(7) Uani 1 1 d . . . . .
C143 C 0.8691(17) 0.2275(15) 0.5122(6) 0.130(8) Uani 1 1 d D . . . .
C144 C 0.9287(16) 0.1933(19) 0.5750(8) 0.154(11) Uani 1 1 d . . . . .
H14A H 0.8811 0.2056 0.5921 0.230 Uiso 1 1 calc R U . . .
H14B H 0.9531 0.2357 0.5684 0.230 Uiso 1 1 calc R U . . .
H14C H 0.9702 0.1476 0.5849 0.230 Uiso 1 1 calc R U . . .
C145 C 0.9247(15) 0.0344(17) 0.5628(7) 0.152(11) Uani 1 1 d . . . . .
H14D H 0.9012 -0.0032 0.5579 0.228 Uiso 1 1 calc R U . . .
H14E H 0.9066 0.0423 0.5866 0.228 Uiso 1 1 calc R U . . .
H14F H 0.9854 0.0160 0.5599 0.228 Uiso 1 1 calc R U . . .
C146 C 0.8579(15) 0.0562(14) 0.4918(7) 0.137(9) Uani 1 1 d . U . . .
H14G H 0.9077 0.0359 0.4769 0.206 Uiso 1 1 calc R U . . .
H14H H 0.8100 0.0764 0.4781 0.206 Uiso 1 1 calc R U . . .
H14I H 0.8484 0.0157 0.5105 0.206 Uiso 1 1 calc R U . . .
C147 C 0.814(2) 0.234(2) 0.4580(7) 0.171(13) Uani 1 1 d . U . . .
H14J H 0.8084 0.2884 0.4547 0.257 Uiso 1 1 calc R U . . .
H14K H 0.7589 0.2267 0.4592 0.257 Uiso 1 1 calc R U . . .
H14L H 0.8489 0.2132 0.4385 0.257 Uiso 1 1 calc R U . . .
C148 C 0.865(2) 0.312(2) 0.5076(11) 0.217(17) Uani 1 1 d . U . . .
H14M H 0.9206 0.3178 0.5024 0.326 Uiso 1 1 calc R U . . .
H14N H 0.8390 0.3309 0.5289 0.326 Uiso 1 1 calc R U . . .
H14O H 0.8311 0.3411 0.4885 0.326 Uiso 1 1 calc R U . . .
C149 C -0.0157(15) 0.2384(14) 0.9702(5) 0.111(7) Uani 1 1 d D . . . .
C150 C -0.0418(16) 0.315(2) 0.9624(6) 0.146(12) Uani 1 1 d . . . . .
C151 C -0.0703(12) 0.3375(13) 0.9273(6) 0.126(9) Uani 1 1 d D . . . .
C152 C -0.0648(14) 0.2670(14) 0.9198(6) 0.115(7) Uani 1 1 d D U . . .
C153 C -0.0190(19) 0.2025(13) 0.9427(7) 0.173(12) Uani 1 1 d D U . . .
C154 C 0.024(2) 0.191(2) 1.0023(7) 0.195(14) Uani 1 1 d . U . . .
H15A H 0.0831 0.1675 0.9964 0.293 Uiso 1 1 calc R U . . .
H15B H -0.0031 0.1507 1.0120 0.293 Uiso 1 1 calc R U . . .
H15C H 0.0175 0.2228 1.0194 0.293 Uiso 1 1 calc R U . . .
C155 C -0.033(2) 0.367(2) 0.9848(9) 0.197(14) Uani 1 1 d . U . . .
H15D H -0.0597 0.3548 1.0081 0.295 Uiso 1 1 calc R U . . .
H15E H -0.0598 0.4198 0.9747 0.295 Uiso 1 1 calc R U . . .
H15F H 0.0258 0.3603 0.9861 0.295 Uiso 1 1 calc R U . . .
C156 C -0.1051(16) 0.4137(17) 0.9092(9) 0.172(14) Uani 1 1 d . . . . .
H15G H -0.0628 0.4293 0.8922 0.258 Uiso 1 1 calc R U . . .
H15H H -0.1241 0.4484 0.9258 0.258 Uiso 1 1 calc R U . . .
H15I H -0.1521 0.4151 0.8974 0.258 Uiso 1 1 calc R U . . .
C157 C -0.090(2) 0.258(3) 0.8839(8) 0.21(2) Uani 1 1 d . . . . .
H15J H -0.1078 0.2124 0.8875 0.316 Uiso 1 1 calc R U . . .
H15K H -0.0413 0.2540 0.8668 0.316 Uiso 1 1 calc R U . . .
H15L H -0.1346 0.3027 0.8757 0.316 Uiso 1 1 calc R U . . .
C158 C -0.011(2) 0.1196(15) 0.9466(12) 0.205(17) Uani 1 1 d D . . . .
H15M H 0.0297 0.0981 0.9287 0.307 Uiso 1 1 calc R U . . .
H15N H -0.0652 0.1134 0.9442 0.307 Uiso 1 1 calc R U . . .
H15O H 0.0064 0.0933 0.9694 0.307 Uiso 1 1 calc R U . . .
C159 C 0.6483(5) 0.2378(5) 0.94507(19) 0.098(7) Uani 0.47(2) 1 d G U P A 1
C160 C 0.6106(5) 0.3171(5) 0.93970(19) 0.087(6) Uani 0.47(2) 1 d G U P A 1
C161 C 0.5386(5) 0.3318(5) 0.96309(19) 0.128(19) Uani 0.47(2) 1 d G U P A 1
C162 C 0.5318(6) 0.2616(6) 0.9829(2) 0.105(14) Uani 0.47(2) 1 d G U P A 1
C163 C 0.5996(6) 0.2035(5) 0.9718(2) 0.089(11) Uani 0.47(2) 1 d G U P A 1
C164 C 0.7264(5) 0.1971(5) 0.9258(2) 0.114(12) Uani 0.47(2) 1 d G U P A 1
H16A H 0.7714 0.1783 0.9409 0.171 Uiso 0.47(2) 1 calc R U P A 1
H16B H 0.7413 0.2322 0.9056 0.171 Uiso 0.47(2) 1 calc R U P A 1
H16C H 0.7174 0.1543 0.9182 0.171 Uiso 0.47(2) 1 calc R U P A 1
C165 C 0.6416(4) 0.3756(5) 0.91369(19) 0.125(13) Uani 0.47(2) 1 d G U P A 1
H16D H 0.7011 0.3550 0.9076 0.187 Uiso 0.47(2) 1 calc R U P A 1
H16E H 0.6319 0.4211 0.9236 0.187 Uiso 0.47(2) 1 calc R U P A 1
H16F H 0.6120 0.3886 0.8930 0.187 Uiso 0.47(2) 1 calc R U P A 1
C166 C 0.4797(5) 0.4086(6) 0.9663(2) 0.131(18) Uani 0.47(2) 1 d G U P A 1
H16G H 0.5112 0.4437 0.9672 0.197 Uiso 0.47(2) 1 calc R U P A 1
H16H H 0.4424 0.4043 0.9875 0.197 Uiso 0.47(2) 1 calc R U P A 1
H16I H 0.4470 0.4279 0.9463 0.197 Uiso 0.47(2) 1 calc R U P A 1
C167 C 0.4644(6) 0.2506(6) 1.0109(2) 0.16(2) Uani 0.47(2) 1 d G U P A 1
H16J H 0.4364 0.2172 1.0051 0.240 Uiso 0.47(2) 1 calc R U P A 1
H16K H 0.4242 0.2999 1.0130 0.240 Uiso 0.47(2) 1 calc R U P A 1
H16L H 0.4887 0.2276 1.0329 0.240 Uiso 0.47(2) 1 calc R U P A 1
C168 C 0.6169(7) 0.1199(6) 0.9859(2) 0.132(18) Uani 0.47(2) 1 d G U P A 1
H16M H 0.6268 0.1101 1.0103 0.198 Uiso 0.47(2) 1 calc R U P A 1
H16N H 0.6660 0.0919 0.9729 0.198 Uiso 0.47(2) 1 calc R U P A 1
H16O H 0.5691 0.1032 0.9837 0.198 Uiso 0.47(2) 1 calc R U P A 1
C259 C 0.6344(5) 0.2496(5) 0.94945(19) 0.091(6) Uani 0.53(2) 1 d G U P A 2
C260 C 0.6166(5) 0.3272(5) 0.93391(19) 0.087(6) Uani 0.53(2) 1 d G U P A 2
C261 C 0.5441(5) 0.3675(5) 0.95198(19) 0.070(8) Uani 0.53(2) 1 d G U P A 2
C262 C 0.5171(5) 0.3148(6) 0.9787(2) 0.063(7) Uani 0.53(2) 1 d G U P A 2
C263 C 0.5729(6) 0.2418(5) 0.9771(2) 0.094(11) Uani 0.53(2) 1 d G U P A 2
C264 C 0.7061(5) 0.1863(5) 0.9385(2) 0.137(13) Uani 0.53(2) 1 d G U P A 2
H26A H 0.7097 0.1399 0.9557 0.206 Uiso 0.53(2) 1 calc R U P A 2
H26B H 0.7577 0.2003 0.9364 0.206 Uiso 0.53(2) 1 calc R U P A 2
H26C H 0.6977 0.1775 0.9161 0.206 Uiso 0.53(2) 1 calc R U P A 2
C265 C 0.6661(4) 0.3610(5) 0.90351(18) 0.097(10) Uani 0.53(2) 1 d G U P A 2
H26D H 0.7174 0.3224 0.8980 0.145 Uiso 0.53(2) 1 calc R U P A 2
H26E H 0.6798 0.4036 0.9092 0.145 Uiso 0.53(2) 1 calc R U P A 2
H26F H 0.6334 0.3792 0.8835 0.145 Uiso 0.53(2) 1 calc R U P A 2
C266 C 0.5030(5) 0.4517(5) 0.9442(2) 0.113(13) Uani 0.53(2) 1 d G U P A 2
H26G H 0.4438 0.4609 0.9425 0.169 Uiso 0.53(2) 1 calc R U P A 2
H26H H 0.5284 0.4737 0.9223 0.169 Uiso 0.53(2) 1 calc R U P A 2
H26I H 0.5101 0.4752 0.9627 0.169 Uiso 0.53(2) 1 calc R U P A 2
C267 C 0.4422(6) 0.3330(6) 1.0043(2) 0.113(13) Uani 0.53(2) 1 d G U P A 2
H26J H 0.4134 0.2939 1.0077 0.170 Uiso 0.53(2) 1 calc R U P A 2
H26K H 0.4047 0.3825 0.9955 0.170 Uiso 0.53(2) 1 calc R U P A 2
H26L H 0.4598 0.3344 1.0263 0.170 Uiso 0.53(2) 1 calc R U P A 2
C268 C 0.5678(7) 0.1689(6) 1.0007(2) 0.140(17) Uani 0.53(2) 1 d G U P A 2
H26M H 0.6139 0.1269 0.9941 0.210 Uiso 0.53(2) 1 calc R U P A 2
H26N H 0.5709 0.1728 1.0246 0.210 Uiso 0.53(2) 1 calc R U P A 2
H26O H 0.5151 0.1597 0.9989 0.210 Uiso 0.53(2) 1 calc R U P A 2
C169 C 0.8161(8) 0.6197(7) 0.9777(3) 0.22(2) Uani 1 1 d DG . . . .
C170 C 0.4021(11) 0.8656(6) 0.5530(3) 0.158(10) Uani 1 1 d DG U . . .
C177 C 0.4753(6) 0.2690(5) 0.61455(19) 0.075(4) Uani 1 1 d G . . . .
C178 C 0.4504(5) 0.3502(5) 0.60589(19) 0.103(6) Uani 1 1 d G . . . .
H17A H 0.4766 0.3662 0.5830 0.154 Uiso 1 1 calc R U . . .
H17B H 0.4677 0.3711 0.6230 0.154 Uiso 1 1 calc R U . . .
H17C H 0.3900 0.3688 0.6057 0.154 Uiso 1 1 calc R U . . .
N17 N 0.4942(6) 0.2065(5) 0.6194(2) 0.092(4) Uani 1 1 d G . . . .
C179 C 0.4504(4) 0.5229(4) 0.78481(16) 0.126(8) Uani 1 1 d G . . . .
C180 C 0.4507(5) 0.5540(4) 0.74846(17) 0.123(8) Uani 1 1 d G . . . .
H18A H 0.4976 0.5752 0.7411 0.184 Uiso 1 1 calc R U . . .
H18B H 0.3988 0.5942 0.7440 0.184 Uiso 1 1 calc R U . . .
H18C H 0.4558 0.5139 0.7355 0.184 Uiso 1 1 calc R U . . .
N18 N 0.4570(4) 0.4868(4) 0.81343(16) 0.157(10) Uani 1 1 d G . . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 O1 2.063(13) . ?
Rh1 N1 2.098(12) . ?
Rh1 C47 2.111(19) . ?
Rh1 C48 2.135(19) . ?
Rh1 C49 2.139(17) . ?
Rh1 C45 2.140(14) . ?
Rh1 O2 2.143(10) . ?
Rh1 C46 2.17(2) . ?
Rh2 C58 2.048(18) . ?
Rh2 C56 2.11(2) . ?
Rh2 C55 2.114(16) . ?
Rh2 O3 2.116(10) . ?
Rh2 O4 2.117(11) . ?
Rh2 C57 2.12(2) . ?
Rh2 N5 2.126(11) . ?
Rh2 C59 2.166(17) . ?
Rh3 C79 2.08(2) . ?
Rh3 O6 2.105(10) . ?
Rh3 O5 2.112(9) . ?
Rh3 C77 2.120(16) . ?
Rh3 C78 2.128(18) . ?
Rh3 C76 2.13(2) . ?
Rh3 N4 2.137(11) . ?
Rh3 C75 2.171(13) . ?
Rh4 C67 2.083(16) . ?
Rh4 C66 2.108(15) . ?
Rh4 C69 2.108(15) . ?
Rh4 O8 2.110(8) . ?
Rh4 C65 2.114(11) . ?
Rh4 N8 2.115(12) . ?
Rh4 C68 2.122(16) . ?
Rh4 O7 2.138(9) . ?
Rh5 O14 2.050(12) . ?
Rh5 C131 2.089(15) . ?
Rh5 N9 2.098(10) . ?
Rh5 C129 2.099(14) . ?
Rh5 O13 2.119(10) . ?
Rh5 C133 2.127(17) . ?
Rh5 C132 2.154(18) . ?
Rh5 C130 2.158(16) . ?
Rh6 C143 2.08(3) . ?
Rh6 N13 2.088(13) . ?
Rh6 O15 2.124(12) . ?
Rh6 C139 2.15(2) . ?
Rh6 C140 2.15(2) . ?
Rh6 O16 2.157(11) . ?
Rh6 C142 2.190(19) . ?
Rh6 C141 2.23(2) . ?
Rh7 C153 2.07(2) . ?
Rh7 C151 2.10(2) . ?
Rh7 O17 2.115(10) . ?
Rh7 C152 2.12(2) . ?
Rh7 C149 2.14(2) . ?
Rh7 N12 2.141(12) . ?
Rh7 C150 2.15(2) . ?
Rh7 O18 2.158(12) . ?
Rh8 C161 1.945(7) . ?
Rh8 O19 1.97(2) . ?
Rh8 C160 2.052(7) . ?
Rh8 C162 2.076(7) . ?
Rh8 C263 2.085(7) . ?
Rh8 C259 2.100(8) . ?
Rh8 O20 2.106(11) . ?
Rh8 N16 2.130(13) . ?
Rh8 C262 2.174(7) . ?
Rh8 C260 2.198(8) . ?
Rh8 C159 2.235(8) . ?
Rh8 C261 2.241(8) . ?
N1 C13 1.337(17) . ?
N1 C17 1.35(2) . ?
N2 C18 1.388(17) . ?
N2 C22 1.397(18) . ?
N2 H2 0.8800 . ?
N3 C21 1.365(17) . ?
N3 C23 1.395(18) . ?
N3 H3 0.8800 . ?
N4 C28 1.291(17) . ?
N4 C24 1.347(18) . ?
N5 C33 1.356(17) . ?
N5 C29 1.374(17) . ?
N6 C38 1.373(16) . ?
N6 C34 1.399(16) . ?
N6 H6 0.8800 . ?
N7 C39 1.392(16) . ?
N7 C37 1.431(18) . ?
N7 H7 0.8800 . ?
N8 C44 1.291(19) . ?
N8 C40 1.34(2) . ?
N9 C101 1.327(18) . ?
N9 C97 1.354(16) . ?
N10 C102 1.357(17) . ?
N10 C106 1.379(18) . ?
N10 H10 0.8800 . ?
N11 C105 1.364(17) . ?
N11 C107 1.377(17) . ?
N11 H11 0.8800 . ?
N12 C112 1.26(2) . ?
N12 C108 1.365(19) . ?
N13 C117 1.32(2) . ?
N13 C113 1.41(2) . ?
N14 C118 1.36(2) . ?
N14 C127 1.378(19) . ?
N14 H14 0.8800 . ?
N15 C121 1.344(19) . ?
N15 C128 1.368(19) . ?
N15 H15 0.8800 . ?
N16 C126 1.34(2) . ?
N16 C122 1.35(2) . ?
O1 C1 1.267(18) . ?
O2 C2 1.227(17) . ?
O3 C4 1.254(18) . ?
O4 C5 1.225(16) . ?
O5 C7 1.246(15) . ?
O6 C8 1.282(16) . ?
O7 C10 1.273(16) . ?
O8 C11 1.265(15) . ?
O9 C22 1.207(16) . ?
O10 C23 1.199(16) . ?
O11 C38 1.206(16) . ?
O12 C39 1.214(15) . ?
O13 C85 1.314(17) . ?
O14 C86 1.341(19) . ?
O15 C88 1.235(16) . ?
O16 C89 1.300(18) . ?
O17 C91 1.259(17) . ?
O18 C92 1.26(2) . ?
O19 C94 1.40(2) . ?
O20 C95 1.231(19) . ?
O21 C106 1.243(16) . ?
O22 C107 1.267(16) . ?
O23 C127 1.244(19) . ?
O24 C128 1.214(19) . ?
O25 S1 1.452(19) . ?
O26 S1 1.48(2) . ?
O27 S1 1.41(2) . ?
O28 S2 1.481(16) . ?
O29 S2 1.43(3) . ?
O30 S2 1.34(4) . ?
S1 C169 1.749(14) . ?
S2 C170 1.728(13) . ?
F1 C169 1.350(16) . ?
F2 C169 1.29(3) . ?
F3 C169 1.37(3) . ?
F4 C170 1.302(16) . ?
F5 C170 1.363(16) . ?
F6 C170 1.320(17) . ?
C1 C6 1.40(2) . ?
C1 C2 1.525(19) . ?
C2 C3 1.41(2) . ?
C3 C4 1.39(2) . ?
C3 H3A 0.9500 . ?
C4 C5 1.512(19) . ?
C5 C6 1.38(2) . ?
C6 H6A 0.9500 . ?
C7 C12 1.361(18) . ?
C7 C8 1.549(18) . ?
C8 C9 1.38(2) . ?
C9 C10 1.31(2) . ?
C9 H9 0.9500 . ?
C10 C11 1.536(18) . ?
C11 C12 1.423(18) . ?
C12 H12 0.9500 . ?
C13 C14 1.352(19) . ?
C13 H13 0.9500 . ?
C14 C15 1.402(19) . ?
C14 H14P 0.9500 . ?
C15 C16 1.36(2) . ?
C15 C18 1.485(19) . ?
C16 C17 1.39(2) . ?
C16 H16 0.9500 . ?
C17 H17 0.9500 . ?
C18 C19 1.358(18) . ?
C19 C20 1.430(19) . ?
C19 C23 1.486(19) . ?
C20 C21 1.373(19) . ?
C20 C22 1.457(19) . ?
C21 C26 1.475(19) . ?
C24 C25 1.32(2) . ?
C24 H24 0.9500 . ?
C25 C26 1.384(19) . ?
C25 H25 0.9500 . ?
C26 C27 1.375(19) . ?
C27 C28 1.384(19) . ?
C27 H27 0.9500 . ?
C28 H28 0.9500 . ?
C29 C30 1.364(19) . ?
C29 H29 0.9500 . ?
C30 C31 1.378(19) . ?
C30 H30 0.9500 . ?
C31 C32 1.362(18) . ?
C31 C34 1.439(18) . ?
C32 C33 1.42(2) . ?
C32 H32 0.9500 . ?
C33 H33 0.9500 . ?
C34 C35 1.372(18) . ?
C35 C36 1.441(18) . ?
C35 C39 1.461(18) . ?
C36 C37 1.361(19) . ?
C36 C38 1.458(18) . ?
C37 C42 1.445(19) . ?
C40 C41 1.33(2) . ?
C40 H40 0.9500 . ?
C41 C42 1.37(2) . ?
C41 H41 0.9500 . ?
C42 C43 1.40(2) . ?
C43 C44 1.33(2) . ?
C43 H43 0.9500 . ?
C44 H44 0.9500 . ?
C45 C49 1.426(16) . ?
C45 C46 1.43(2) . ?
C45 C50 1.45(2) . ?
C46 C47 1.40(3) . ?
C46 C51 1.44(3) . ?
C47 C48 1.35(3) . ?
C47 C52 1.54(2) . ?
C48 C49 1.49(3) . ?
C48 C53 1.55(4) . ?
C49 C54 1.56(3) . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C55 C59 1.44(3) . ?
C55 C56 1.445(17) . ?
C55 C60 1.49(3) . ?
C56 C57 1.41(3) . ?
C56 C61 1.59(3) . ?
C57 C58 1.43(3) . ?
C57 C62 1.47(3) . ?
C58 C59 1.37(3) . ?
C58 C63 1.59(2) . ?
C59 C64 1.47(3) . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C63 H63A 0.9800 . ?
C63 H63B 0.9800 . ?
C63 H63C 0.9800 . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C65 C69 1.39(3) . ?
C65 C66 1.42(3) . ?
C65 C70 1.63(3) . ?
C66 C67 1.34(3) . ?
C66 C71 1.47(3) . ?
C67 C68 1.32(3) . ?
C67 C72 1.51(3) . ?
C68 C69 1.49(3) . ?
C68 C73 1.51(3) . ?
C69 C74 1.52(3) . ?
C70 H70A 0.9800 . ?
C70 H70B 0.9800 . ?
C70 H70C 0.9800 . ?
C71 H71A 0.9800 . ?
C71 H71B 0.9800 . ?
C71 H71C 0.9800 . ?
C72 H72A 0.9800 . ?
C72 H72B 0.9800 . ?
C72 H72C 0.9800 . ?
C73 H73A 0.9800 . ?
C73 H73B 0.9800 . ?
C73 H73C 0.9800 . ?
C74 H74A 0.9800 . ?
C74 H74B 0.9800 . ?
C74 H74C 0.9800 . ?
C75 C76 1.41(3) . ?
C75 C80 1.43(3) . ?
C75 C79 1.49(3) . ?
C76 C77 1.39(3) . ?
C76 C81 1.58(3) . ?
C77 C78 1.42(3) . ?
C77 C82 1.51(3) . ?
C78 C79 1.414(17) . ?
C78 C83 1.52(4) . ?
C79 C84 1.49(4) . ?
C80 H80A 0.9800 . ?
C80 H80B 0.9800 . ?
C80 H80C 0.9800 . ?
C81 H81A 0.9800 . ?
C81 H81B 0.9800 . ?
C81 H81C 0.9800 . ?
C82 H82A 0.9800 . ?
C82 H82B 0.9800 . ?
C82 H82C 0.9800 . ?
C83 H83A 0.9800 . ?
C83 H83B 0.9800 . ?
C83 H83C 0.9800 . ?
C84 H84A 0.9800 . ?
C84 H84B 0.9800 . ?
C84 H84C 0.9800 . ?
C85 C90 1.35(2) . ?
C85 C86 1.510(18) . ?
C86 C87 1.34(2) . ?
C87 C88 1.40(2) . ?
C87 H87 0.9500 . ?
C88 C89 1.54(2) . ?
C89 C90 1.34(2) . ?
C90 H90 0.9500 . ?
C91 C96 1.34(2) . ?
C91 C92 1.53(2) . ?
C92 C93 1.35(2) . ?
C93 C94 1.40(3) . ?
C93 H93 0.9500 . ?
C94 C95 1.45(2) . ?
C95 C96 1.46(2) . ?
C96 H96 0.9500 . ?
C97 C98 1.378(18) . ?
C97 H97 0.9500 . ?
C98 C99 1.381(18) . ?
C98 H98 0.9500 . ?
C99 C100 1.429(19) . ?
C99 C102 1.463(19) . ?
C100 C101 1.34(2) . ?
C100 H100 0.9500 . ?
C101 H101 0.9500 . ?
C102 C103 1.414(19) . ?
C103 C107 1.409(19) . ?
C103 C104 1.424(18) . ?
C104 C105 1.379(19) . ?
C104 C106 1.434(19) . ?
C105 C110 1.537(19) . ?
C108 C109 1.389(19) . ?
C108 H108 0.9500 . ?
C109 C110 1.288(19) . ?
C109 H109 0.9500 . ?
C110 C111 1.37(2) . ?
C111 C112 1.41(2) . ?
C111 H111 0.9500 . ?
C112 H112 0.9500 . ?
C113 C114 1.44(2) . ?
C113 H113 0.9500 . ?
C114 C115 1.35(2) . ?
C114 H114 0.9500 . ?
C115 C118 1.45(2) . ?
C115 C116 1.49(2) . ?
C116 C117 1.39(3) . ?
C116 H116 0.9500 . ?
C117 H117 0.9500 . ?
C118 C119 1.405(19) . ?
C119 C120 1.41(2) . ?
C119 C128 1.46(2) . ?
C120 C121 1.386(19) . ?
C120 C127 1.44(2) . ?
C121 C124 1.53(2) . ?
C122 C123 1.35(2) . ?
C122 H122 0.9500 . ?
C123 C124 1.37(2) . ?
C123 H123 0.9500 . ?
C124 C125 1.40(2) . ?
C125 C126 1.34(2) . ?
C125 H125 0.9500 . ?
C126 H126 0.9500 . ?
C129 C130 1.40(2) . ?
C129 C133 1.43(3) . ?
C129 C134 1.52(3) . ?
C130 C131 1.45(2) . ?
C130 C135 1.49(2) . ?
C131 C132 1.39(2) . ?
C131 C136 1.53(2) . ?
C132 C137 1.46(2) . ?
C132 C133 1.47(3) . ?
C133 C138 1.52(3) . ?
C134 H13A 0.9800 . ?
C134 H13B 0.9800 . ?
C134 H13C 0.9800 . ?
C135 H13D 0.9800 . ?
C135 H13E 0.9800 . ?
C135 H13F 0.9800 . ?
C136 H13G 0.9800 . ?
C136 H13H 0.9800 . ?
C136 H13I 0.9800 . ?
C137 H13J 0.9800 . ?
C137 H13K 0.9800 . ?
C137 H13L 0.9800 . ?
C138 H13M 0.9800 . ?
C138 H13N 0.9800 . ?
C138 H13O 0.9800 . ?
C139 C140 1.419(18) . ?
C139 C143 1.423(18) . ?
C139 C144 1.54(3) . ?
C140 C141 1.39(3) . ?
C140 C145 1.51(3) . ?
C141 C142 1.41(3) . ?
C141 C146 1.45(4) . ?
C142 C143 1.26(3) . ?
C142 C147 1.51(4) . ?
C143 C148 1.54(4) . ?
C144 H14A 0.9800 . ?
C144 H14B 0.9800 . ?
C144 H14C 0.9800 . ?
C145 H14D 0.9800 . ?
C145 H14E 0.9800 . ?
C145 H14F 0.9800 . ?
C146 H14G 0.9800 . ?
C146 H14H 0.9800 . ?
C146 H14I 0.9800 . ?
C147 H14J 0.9800 . ?
C147 H14K 0.9800 . ?
C147 H14L 0.9800 . ?
C148 H14M 0.9800 . ?
C148 H14N 0.9800 . ?
C148 H14O 0.9800 . ?
C149 C150 1.34(4) . ?
C149 C153 1.425(18) . ?
C149 C154 1.51(3) . ?
C150 C151 1.48(3) . ?
C150 C155 1.52(4) . ?
C151 C152 1.396(18) . ?
C151 C156 1.44(3) . ?
C152 C153 1.439(18) . ?
C152 C157 1.60(4) . ?
C153 C158 1.501(18) . ?
C154 H15A 0.9800 . ?
C154 H15B 0.9800 . ?
C154 H15C 0.9800 . ?
C155 H15D 0.9800 . ?
C155 H15E 0.9800 . ?
C155 H15F 0.9800 . ?
C156 H15G 0.9800 . ?
C156 H15H 0.9800 . ?
C156 H15I 0.9800 . ?
C157 H15J 0.9800 . ?
C157 H15K 0.9800 . ?
C157 H15L 0.9800 . ?
C158 H15M 0.9800 . ?
C158 H15N 0.9800 . ?
C158 H15O 0.9800 . ?
C159 C160 1.4146 . ?
C159 C163 1.4148 . ?
C159 C164 1.5043(10) . ?
C160 C161 1.4149 . ?
C160 C165 1.5038(10) . ?
C161 C162 1.4147 . ?
C161 C166 1.5041(10) . ?
C162 C163 1.4148 . ?
C162 C167 1.5038(10) . ?
C163 C168 1.5038(10) . ?
C164 H16A 0.9800 . ?
C164 H16B 0.9800 . ?
C164 H16C 0.9800 . ?
C165 H16D 0.9800 . ?
C165 H16E 0.9800 . ?
C165 H16F 0.9800 . ?
C166 H16G 0.9800 . ?
C166 H16H 0.9800 . ?
C166 H16I 0.9800 . ?
C167 H16J 0.9800 . ?
C167 H16K 0.9800 . ?
C167 H16L 0.9800 . ?
C168 H16M 0.9800 . ?
C168 H16N 0.9800 . ?
C168 H16O 0.9800 . ?
C259 C260 1.4167 . ?
C259 C263 1.4169 . ?
C259 C264 1.5060(10) . ?
C260 C261 1.4166 . ?
C260 C265 1.5063(10) . ?
C261 C262 1.4165 . ?
C261 C266 1.5060(10) . ?
C262 C263 1.4169 . ?
C262 C267 1.5062(10) . ?
C263 C268 1.5059(10) . ?
C264 H26A 0.9800 . ?
C264 H26B 0.9800 . ?
C264 H26C 0.9800 . ?
C265 H26D 0.9800 . ?
C265 H26E 0.9800 . ?
C265 H26F 0.9800 . ?
C266 H26G 0.9800 . ?
C266 H26H 0.9800 . ?
C266 H26I 0.9800 . ?
C267 H26J 0.9800 . ?
C267 H26K 0.9800 . ?
C267 H26L 0.9800 . ?
C268 H26M 0.9800 . ?
C268 H26N 0.9800 . ?
C268 H26O 0.9800 . ?
C177 N17 1.1015 . ?
C177 C178 1.4338 . ?
C178 H17A 0.9800 . ?
C178 H17B 0.9800 . ?
C178 H17C 0.9800 . ?
C179 N18 1.1969 . ?
C179 C180 1.4398 . ?
C180 H18A 0.9800 . ?
C180 H18B 0.9800 . ?
C180 H18C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Rh1 N1 88.0(5) . . ?
O1 Rh1 C47 116.6(7) . . ?
N1 Rh1 C47 99.0(6) . . ?
O1 Rh1 C48 96.2(7) . . ?
N1 Rh1 C48 131.6(7) . . ?
C47 Rh1 C48 37.1(8) . . ?
O1 Rh1 C49 107.5(6) . . ?
N1 Rh1 C49 162.5(7) . . ?
C47 Rh1 C49 67.2(7) . . ?
C48 Rh1 C49 40.8(7) . . ?
O1 Rh1 C45 145.5(5) . . ?
N1 Rh1 C45 126.5(5) . . ?
C47 Rh1 C45 65.2(7) . . ?
C48 Rh1 C45 64.1(7) . . ?
C49 Rh1 C45 38.9(5) . . ?
O1 Rh1 O2 76.9(4) . . ?
N1 Rh1 O2 87.8(4) . . ?
C47 Rh1 O2 164.9(7) . . ?
C48 Rh1 O2 140.1(7) . . ?
C49 Rh1 O2 103.2(6) . . ?
C45 Rh1 O2 99.9(5) . . ?
O1 Rh1 C46 154.6(6) . . ?
N1 Rh1 C46 96.9(7) . . ?
C47 Rh1 C46 38.1(8) . . ?
C48 Rh1 C46 62.2(9) . . ?
C49 Rh1 C46 65.6(8) . . ?
C45 Rh1 C46 38.7(6) . . ?
O2 Rh1 C46 128.0(6) . . ?
C58 Rh2 C56 65.2(7) . . ?
C58 Rh2 C55 64.6(7) . . ?
C56 Rh2 C55 40.0(5) . . ?
C58 Rh2 O3 97.1(6) . . ?
C56 Rh2 O3 153.9(7) . . ?
C55 Rh2 O3 150.3(6) . . ?
C58 Rh2 O4 132.5(7) . . ?
C56 Rh2 O4 129.4(7) . . ?
C55 Rh2 O4 98.3(6) . . ?
O3 Rh2 O4 76.6(4) . . ?
C58 Rh2 C57 40.1(8) . . ?
C56 Rh2 C57 38.9(8) . . ?
C55 Rh2 C57 66.4(8) . . ?
O3 Rh2 C57 115.4(7) . . ?
O4 Rh2 C57 164.5(7) . . ?
C58 Rh2 N5 144.4(7) . . ?
C56 Rh2 N5 99.5(6) . . ?
C55 Rh2 N5 124.8(6) . . ?
O3 Rh2 N5 83.9(4) . . ?
O4 Rh2 N5 82.5(4) . . ?
C57 Rh2 N5 107.7(7) . . ?
C58 Rh2 C59 37.8(8) . . ?
C56 Rh2 C59 66.1(8) . . ?
C55 Rh2 C59 39.2(7) . . ?
O3 Rh2 C59 112.2(6) . . ?
O4 Rh2 C59 100.6(7) . . ?
C57 Rh2 C59 66.3(8) . . ?
N5 Rh2 C59 163.9(6) . . ?
C79 Rh3 O6 134.4(8) . . ?
C79 Rh3 O5 100.5(7) . . ?
O6 Rh3 O5 77.4(4) . . ?
C79 Rh3 C77 65.1(7) . . ?
O6 Rh3 C77 95.3(6) . . ?
O5 Rh3 C77 151.7(7) . . ?
C79 Rh3 C78 39.2(5) . . ?
O6 Rh3 C78 99.6(6) . . ?
O5 Rh3 C78 114.5(7) . . ?
C77 Rh3 C78 39.0(8) . . ?
C79 Rh3 C76 63.7(9) . . ?
O6 Rh3 C76 124.9(8) . . ?
O5 Rh3 C76 157.7(7) . . ?
C77 Rh3 C76 38.1(9) . . ?
C78 Rh3 C76 64.2(9) . . ?
C79 Rh3 N4 141.0(8) . . ?
O6 Rh3 N4 84.4(4) . . ?
O5 Rh3 N4 83.0(4) . . ?
C77 Rh3 N4 123.9(6) . . ?
C78 Rh3 N4 162.5(7) . . ?
C76 Rh3 N4 99.5(7) . . ?
C79 Rh3 C75 40.9(9) . . ?
O6 Rh3 C75 161.6(6) . . ?
O5 Rh3 C75 119.6(6) . . ?
C77 Rh3 C75 66.4(8) . . ?
C78 Rh3 C75 67.9(8) . . ?
C76 Rh3 C75 38.1(8) . . ?
N4 Rh3 C75 103.7(7) . . ?
C67 Rh4 C66 37.2(7) . . ?
C67 Rh4 C69 64.7(7) . . ?
C66 Rh4 C69 65.2(7) . . ?
C67 Rh4 O8 96.7(6) . . ?
C66 Rh4 O8 113.1(5) . . ?
C69 Rh4 O8 152.3(7) . . ?
C67 Rh4 C65 63.7(7) . . ?
C66 Rh4 C65 39.2(7) . . ?
C69 Rh4 C65 38.3(7) . . ?
O8 Rh4 C65 151.8(7) . . ?
C67 Rh4 N8 142.8(7) . . ?
C66 Rh4 N8 108.0(7) . . ?
C69 Rh4 N8 121.2(7) . . ?
O8 Rh4 N8 86.1(4) . . ?
C65 Rh4 N8 97.7(6) . . ?
C67 Rh4 C68 36.5(7) . . ?
C66 Rh4 C68 63.5(8) . . ?
C69 Rh4 C68 41.3(8) . . ?
O8 Rh4 C68 111.7(6) . . ?
C65 Rh4 C68 65.4(7) . . ?
N8 Rh4 C68 162.0(7) . . ?
C67 Rh4 O7 129.6(7) . . ?
C66 Rh4 O7 161.4(6) . . ?
C69 Rh4 O7 98.1(6) . . ?
O8 Rh4 O7 77.6(4) . . ?
C65 Rh4 O7 130.3(7) . . ?
N8 Rh4 O7 87.3(4) . . ?
C68 Rh4 O7 98.8(7) . . ?
O14 Rh5 C131 111.3(6) . . ?
O14 Rh5 N9 88.2(4) . . ?
C131 Rh5 N9 105.1(5) . . ?
O14 Rh5 C129 110.0(6) . . ?
C131 Rh5 C129 66.5(6) . . ?
N9 Rh5 C129 161.6(6) . . ?
O14 Rh5 O13 79.3(4) . . ?
C131 Rh5 O13 164.7(5) . . ?
N9 Rh5 O13 85.7(4) . . ?
C129 Rh5 O13 100.0(5) . . ?
O14 Rh5 C133 149.4(6) . . ?
C131 Rh5 C133 65.6(7) . . ?
N9 Rh5 C133 122.4(6) . . ?
C129 Rh5 C133 39.6(7) . . ?
O13 Rh5 C133 99.6(6) . . ?
O14 Rh5 C132 149.2(6) . . ?
C131 Rh5 C132 38.3(7) . . ?
N9 Rh5 C132 95.9(5) . . ?
C129 Rh5 C132 67.2(7) . . ?
O13 Rh5 C132 131.3(6) . . ?
C133 Rh5 C132 40.3(7) . . ?
O14 Rh5 C130 92.8(6) . . ?
C131 Rh5 C130 40.0(7) . . ?
N9 Rh5 C130 142.0(6) . . ?
C129 Rh5 C130 38.5(6) . . ?
O13 Rh5 C130 131.8(6) . . ?
C133 Rh5 C130 64.9(7) . . ?
C132 Rh5 C130 65.7(7) . . ?
C143 Rh6 N13 120.3(9) . . ?
C143 Rh6 O15 153.2(8) . . ?
N13 Rh6 O15 86.5(5) . . ?
C143 Rh6 C139 39.2(5) . . ?
N13 Rh6 C139 97.7(7) . . ?
O15 Rh6 C139 143.6(6) . . ?
C143 Rh6 C140 62.6(9) . . ?
N13 Rh6 C140 113.5(7) . . ?
O15 Rh6 C140 107.0(6) . . ?
C139 Rh6 C140 38.5(5) . . ?
C143 Rh6 O16 106.1(7) . . ?
N13 Rh6 O16 83.7(5) . . ?
O15 Rh6 O16 76.8(4) . . ?
C139 Rh6 O16 139.6(7) . . ?
C140 Rh6 O16 162.4(7) . . ?
C143 Rh6 C142 34.3(9) . . ?
N13 Rh6 C142 154.5(8) . . ?
O15 Rh6 C142 119.0(7) . . ?
C139 Rh6 C142 62.8(9) . . ?
C140 Rh6 C142 62.3(9) . . ?
O16 Rh6 C142 100.6(8) . . ?
C143 Rh6 C141 60.1(11) . . ?
N13 Rh6 C141 149.5(7) . . ?
O15 Rh6 C141 96.2(9) . . ?
C139 Rh6 C141 62.9(9) . . ?
C140 Rh6 C141 36.8(8) . . ?
O16 Rh6 C141 126.6(7) . . ?
C142 Rh6 C141 37.2(9) . . ?
C153 Rh7 C151 69.9(9) . . ?
C153 Rh7 O17 166.2(8) . . ?
C151 Rh7 O17 107.9(7) . . ?
C153 Rh7 C152 40.1(6) . . ?
C151 Rh7 C152 38.6(5) . . ?
O17 Rh7 C152 143.7(7) . . ?
C153 Rh7 C149 39.5(6) . . ?
C151 Rh7 C149 65.8(8) . . ?
O17 Rh7 C149 126.8(8) . . ?
C152 Rh7 C149 61.9(9) . . ?
C153 Rh7 N12 108.4(8) . . ?
C151 Rh7 N12 116.5(8) . . ?
O17 Rh7 N12 85.0(4) . . ?
C152 Rh7 N12 98.6(7) . . ?
C149 Rh7 N12 147.2(8) . . ?
C153 Rh7 C150 66.4(12) . . ?
C151 Rh7 C150 40.9(10) . . ?
O17 Rh7 C150 102.6(9) . . ?
C152 Rh7 C150 62.7(9) . . ?
C149 Rh7 C150 36.6(10) . . ?
N12 Rh7 C150 157.4(9) . . ?
C153 Rh7 O18 100.4(8) . . ?
C151 Rh7 O18 160.8(7) . . ?
O17 Rh7 O18 77.3(4) . . ?
C152 Rh7 O18 138.9(7) . . ?
C149 Rh7 O18 96.0(7) . . ?
N12 Rh7 O18 82.0(4) . . ?
C150 Rh7 O18 120.3(10) . . ?
C161 Rh8 O19 129.7(4) . . ?
C161 Rh8 C160 41.35(14) . . ?
O19 Rh8 C160 155.6(5) . . ?
C161 Rh8 C162 41.04(13) . . ?
O19 Rh8 C162 93.4(4) . . ?
C160 Rh8 C162 67.36(19) . . ?
O19 Rh8 C263 99.1(4) . . ?
O19 Rh8 C259 123.3(5) . . ?
C263 Rh8 C259 39.57(12) . . ?
C161 Rh8 O20 100.9(4) . . ?
O19 Rh8 O20 77.5(6) . . ?
C160 Rh8 O20 123.6(5) . . ?
C162 Rh8 O20 115.1(4) . . ?
C263 Rh8 O20 134.7(4) . . ?
C259 Rh8 O20 156.5(5) . . ?
C161 Rh8 N16 145.4(5) . . ?
O19 Rh8 N16 84.8(5) . . ?
C160 Rh8 N16 106.4(5) . . ?
C162 Rh8 N16 155.8(5) . . ?
C263 Rh8 N16 137.0(5) . . ?
C259 Rh8 N16 103.5(4) . . ?
O20 Rh8 N16 88.2(5) . . ?
O19 Rh8 C262 110.2(4) . . ?
C263 Rh8 C262 38.79(11) . . ?
C259 Rh8 C262 64.83(18) . . ?
O20 Rh8 C262 99.3(4) . . ?
N16 Rh8 C262 164.3(5) . . ?
O19 Rh8 C260 161.5(5) . . ?
C263 Rh8 C260 64.66(19) . . ?
C259 Rh8 C260 38.41(13) . . ?
O20 Rh8 C260 119.9(5) . . ?
N16 Rh8 C260 101.1(5) . . ?
C262 Rh8 C260 63.24(19) . . ?
C161 Rh8 C159 66.0(2) . . ?
O19 Rh8 C159 120.5(5) . . ?
C160 Rh8 C159 38.24(13) . . ?
C162 Rh8 C159 64.02(19) . . ?
O20 Rh8 C159 161.8(5) . . ?
N16 Rh8 C159 96.2(4) . . ?
O19 Rh8 C261 145.0(4) . . ?
C263 Rh8 C261 63.87(18) . . ?
C259 Rh8 C261 63.64(19) . . ?
O20 Rh8 C261 93.1(4) . . ?
N16 Rh8 C261 129.0(5) . . ?
C262 Rh8 C261 37.38(12) . . ?
C260 Rh8 C261 37.20(12) . . ?
C13 N1 C17 118.7(13) . . ?
C13 N1 Rh1 120.6(9) . . ?
C17 N1 Rh1 120.7(10) . . ?
C18 N2 C22 110.9(11) . . ?
C18 N2 H2 124.6 . . ?
C22 N2 H2 124.6 . . ?
C21 N3 C23 113.8(12) . . ?
C21 N3 H3 123.1 . . ?
C23 N3 H3 123.1 . . ?
C28 N4 C24 118.0(12) . . ?
C28 N4 Rh3 122.7(9) . . ?
C24 N4 Rh3 119.3(9) . . ?
C33 N5 C29 117.9(11) . . ?
C33 N5 Rh2 121.8(9) . . ?
C29 N5 Rh2 120.3(9) . . ?
C38 N6 C34 113.5(11) . . ?
C38 N6 H6 123.2 . . ?
C34 N6 H6 123.2 . . ?
C39 N7 C37 111.3(11) . . ?
C39 N7 H7 124.3 . . ?
C37 N7 H7 124.3 . . ?
C44 N8 C40 114.8(13) . . ?
C44 N8 Rh4 125.4(10) . . ?
C40 N8 Rh4 119.8(11) . . ?
C101 N9 C97 116.4(11) . . ?
C101 N9 Rh5 122.7(9) . . ?
C97 N9 Rh5 120.8(8) . . ?
C102 N10 C106 112.7(11) . . ?
C102 N10 H10 123.6 . . ?
C106 N10 H10 123.6 . . ?
C105 N11 C107 111.7(11) . . ?
C105 N11 H11 124.2 . . ?
C107 N11 H11 124.2 . . ?
C112 N12 C108 119.3(13) . . ?
C112 N12 Rh7 121.6(11) . . ?
C108 N12 Rh7 119.0(9) . . ?
C117 N13 C113 117.7(13) . . ?
C117 N13 Rh6 123.2(11) . . ?
C113 N13 Rh6 119.1(11) . . ?
C118 N14 C127 111.4(13) . . ?
C118 N14 H14 124.3 . . ?
C127 N14 H14 124.3 . . ?
C121 N15 C128 114.5(12) . . ?
C121 N15 H15 122.8 . . ?
C128 N15 H15 122.8 . . ?
C126 N16 C122 116.8(14) . . ?
C126 N16 Rh8 120.6(11) . . ?
C122 N16 Rh8 122.5(13) . . ?
C1 O1 Rh1 116.8(9) . . ?
C2 O2 Rh1 113.9(8) . . ?
C4 O3 Rh2 114.3(9) . . ?
C5 O4 Rh2 114.3(9) . . ?
C7 O5 Rh3 116.1(8) . . ?
C8 O6 Rh3 115.1(9) . . ?
C10 O7 Rh4 114.8(8) . . ?
C11 O8 Rh4 114.1(8) . . ?
C85 O13 Rh5 113.0(8) . . ?
C86 O14 Rh5 116.0(8) . . ?
C88 O15 Rh6 115.8(10) . . ?
C89 O16 Rh6 114.5(9) . . ?
C91 O17 Rh7 116.2(9) . . ?
C92 O18 Rh7 111.7(10) . . ?
C94 O19 Rh8 117.5(13) . . ?
C95 O20 Rh8 115.0(12) . . ?
O27 S1 O25 118.6(13) . . ?
O27 S1 O26 110.4(15) . . ?
O25 S1 O26 118.0(14) . . ?
O27 S1 C169 104.6(13) . . ?
O25 S1 C169 100.3(11) . . ?
O26 S1 C169 101.7(11) . . ?
O30 S2 O29 109(3) . . ?
O30 S2 O28 116(2) . . ?
O29 S2 O28 116.0(19) . . ?
O30 S2 C170 113(3) . . ?
O29 S2 C170 107.9(16) . . ?
O28 S2 C170 94.2(13) . . ?
O1 C1 C6 125.5(14) . . ?
O1 C1 C2 114.6(13) . . ?
C6 C1 C2 119.7(14) . . ?
O2 C2 C3 124.3(13) . . ?
O2 C2 C1 117.3(13) . . ?
C3 C2 C1 118.3(14) . . ?
C4 C3 C2 121.1(14) . . ?
C4 C3 H3A 119.4 . . ?
C2 C3 H3A 119.4 . . ?
O3 C4 C3 124.8(13) . . ?
O3 C4 C5 115.7(14) . . ?
C3 C4 C5 119.5(14) . . ?
O4 C5 C6 122.1(13) . . ?
O4 C5 C4 117.6(13) . . ?
C6 C5 C4 120.3(13) . . ?
C5 C6 C1 120.8(13) . . ?
C5 C6 H6A 119.6 . . ?
C1 C6 H6A 119.6 . . ?
O5 C7 C12 124.3(12) . . ?
O5 C7 C8 115.6(11) . . ?
C12 C7 C8 120.1(12) . . ?
O6 C8 C9 124.7(13) . . ?
O6 C8 C7 115.3(12) . . ?
C9 C8 C7 119.9(12) . . ?
C10 C9 C8 120.5(13) . . ?
C10 C9 H9 119.8 . . ?
C8 C9 H9 119.8 . . ?
O7 C10 C9 123.7(13) . . ?
O7 C10 C11 114.5(12) . . ?
C9 C10 C11 121.8(12) . . ?
O8 C11 C12 122.7(11) . . ?
O8 C11 C10 118.1(11) . . ?
C12 C11 C10 119.2(11) . . ?
C7 C12 C11 118.5(12) . . ?
C7 C12 H12 120.7 . . ?
C11 C12 H12 120.7 . . ?
N1 C13 C14 122.7(12) . . ?
N1 C13 H13 118.7 . . ?
C14 C13 H13 118.7 . . ?
C13 C14 C15 119.4(12) . . ?
C13 C14 H14P 120.3 . . ?
C15 C14 H14P 120.3 . . ?
C16 C15 C14 118.2(13) . . ?
C16 C15 C18 122.5(13) . . ?
C14 C15 C18 119.3(12) . . ?
C15 C16 C17 119.7(14) . . ?
C15 C16 H16 120.1 . . ?
C17 C16 H16 120.1 . . ?
N1 C17 C16 121.0(14) . . ?
N1 C17 H17 119.5 . . ?
C16 C17 H17 119.5 . . ?
C19 C18 N2 108.6(12) . . ?
C19 C18 C15 130.4(13) . . ?
N2 C18 C15 121.1(12) . . ?
C18 C19 C20 108.9(12) . . ?
C18 C19 C23 142.4(13) . . ?
C20 C19 C23 108.6(11) . . ?
C21 C20 C19 107.2(12) . . ?
C21 C20 C22 145.7(13) . . ?
C19 C20 C22 106.8(12) . . ?
N3 C21 C20 108.7(12) . . ?
N3 C21 C26 123.7(12) . . ?
C20 C21 C26 127.5(12) . . ?
O9 C22 N2 124.5(13) . . ?
O9 C22 C20 130.7(14) . . ?
N2 C22 C20 104.9(11) . . ?
O10 C23 N3 125.2(13) . . ?
O10 C23 C19 133.2(13) . . ?
N3 C23 C19 101.6(11) . . ?
C25 C24 N4 122.4(13) . . ?
C25 C24 H24 118.8 . . ?
N4 C24 H24 118.8 . . ?
C24 C25 C26 120.2(14) . . ?
C24 C25 H25 119.9 . . ?
C26 C25 H25 119.9 . . ?
C27 C26 C25 117.8(13) . . ?
C27 C26 C21 120.7(12) . . ?
C25 C26 C21 121.5(13) . . ?
C26 C27 C28 117.6(13) . . ?
C26 C27 H27 121.2 . . ?
C28 C27 H27 121.2 . . ?
N4 C28 C27 123.8(12) . . ?
N4 C28 H28 118.1 . . ?
C27 C28 H28 118.1 . . ?
C30 C29 N5 121.4(13) . . ?
C30 C29 H29 119.3 . . ?
N5 C29 H29 119.3 . . ?
C29 C30 C31 121.4(12) . . ?
C29 C30 H30 119.3 . . ?
C31 C30 H30 119.3 . . ?
C32 C31 C30 118.1(12) . . ?
C32 C31 C34 122.0(12) . . ?
C30 C31 C34 119.8(11) . . ?
C31 C32 C33 119.8(12) . . ?
C31 C32 H32 120.1 . . ?
C33 C32 H32 120.1 . . ?
N5 C33 C32 121.1(12) . . ?
N5 C33 H33 119.4 . . ?
C32 C33 H33 119.4 . . ?
C35 C34 N6 106.4(11) . . ?
C35 C34 C31 130.7(12) . . ?
N6 C34 C31 122.9(11) . . ?
C34 C35 C36 108.7(11) . . ?
C34 C35 C39 142.7(12) . . ?
C36 C35 C39 108.6(11) . . ?
C37 C36 C35 108.1(11) . . ?
C37 C36 C38 144.4(13) . . ?
C35 C36 C38 107.3(11) . . ?
C36 C37 N7 107.9(11) . . ?
C36 C37 C42 130.1(13) . . ?
N7 C37 C42 122.0(12) . . ?
O11 C38 N6 125.1(12) . . ?
O11 C38 C36 131.0(12) . . ?
N6 C38 C36 103.9(11) . . ?
O12 C39 N7 124.6(12) . . ?
O12 C39 C35 131.4(12) . . ?
N7 C39 C35 104.0(11) . . ?
C41 C40 N8 123.6(16) . . ?
C41 C40 H40 118.2 . . ?
N8 C40 H40 118.2 . . ?
C40 C41 C42 120.3(16) . . ?
C40 C41 H41 119.8 . . ?
C42 C41 H41 119.8 . . ?
C41 C42 C43 116.4(13) . . ?
C41 C42 C37 119.6(13) . . ?
C43 C42 C37 123.6(13) . . ?
C44 C43 C42 117.0(14) . . ?
C44 C43 H43 121.5 . . ?
C42 C43 H43 121.5 . . ?
N8 C44 C43 127.8(14) . . ?
N8 C44 H44 116.1 . . ?
C43 C44 H44 116.1 . . ?
C49 C45 C46 109.6(16) . . ?
C49 C45 C50 119.4(16) . . ?
C46 C45 C50 130.9(18) . . ?
C49 C45 Rh1 70.5(9) . . ?
C46 C45 Rh1 71.6(10) . . ?
C50 C45 Rh1 125.2(13) . . ?
C47 C46 C45 108(2) . . ?
C47 C46 C51 130(2) . . ?
C45 C46 C51 121(2) . . ?
C47 C46 Rh1 68.8(13) . . ?
C45 C46 Rh1 69.6(11) . . ?
C51 C46 Rh1 122.8(15) . . ?
C48 C47 C46 107.8(17) . . ?
C48 C47 C52 123(2) . . ?
C46 C47 C52 129(2) . . ?
C48 C47 Rh1 72.4(12) . . ?
C46 C47 Rh1 73.1(11) . . ?
C52 C47 Rh1 127.1(14) . . ?
C47 C48 C49 111.5(18) . . ?
C47 C48 C53 126(2) . . ?
C49 C48 C53 121(2) . . ?
C47 C48 Rh1 70.5(11) . . ?
C49 C48 Rh1 69.7(10) . . ?
C53 C48 Rh1 117.3(18) . . ?
C45 C49 C48 102.1(16) . . ?
C45 C49 C54 128.3(16) . . ?
C48 C49 C54 129.6(17) . . ?
C45 C49 Rh1 70.6(9) . . ?
C48 C49 Rh1 69.5(10) . . ?
C54 C49 Rh1 122.7(14) . . ?
C45 C50 H50A 109.5 . . ?
C45 C50 H50B 109.5 . . ?
H50A C50 H50B 109.5 . . ?
C45 C50 H50C 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
C46 C51 H51A 109.5 . . ?
C46 C51 H51B 109.5 . . ?
H51A C51 H51B 109.5 . . ?
C46 C51 H51C 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
C47 C52 H52A 109.5 . . ?
C47 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C47 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C48 C53 H53A 109.5 . . ?
C48 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C48 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C49 C54 H54A 109.5 . . ?
C49 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
C49 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C59 C55 C56 108.2(16) . . ?
C59 C55 C60 128(2) . . ?
C56 C55 C60 124(2) . . ?
C59 C55 Rh2 72.3(9) . . ?
C56 C55 Rh2 69.9(11) . . ?
C60 C55 Rh2 123.1(13) . . ?
C57 C56 C55 108.8(17) . . ?
C57 C56 C61 121(2) . . ?
C55 C56 C61 130(2) . . ?
C57 C56 Rh2 71.1(13) . . ?
C55 C56 Rh2 70.1(11) . . ?
C61 C56 Rh2 123.0(16) . . ?
C56 C57 C58 104(2) . . ?
C56 C57 C62 129(2) . . ?
C58 C57 C62 127(2) . . ?
C56 C57 Rh2 70.1(13) . . ?
C58 C57 Rh2 67.1(12) . . ?
C62 C57 Rh2 128.2(15) . . ?
C59 C58 C57 113.8(17) . . ?
C59 C58 C63 126(2) . . ?
C57 C58 C63 119(2) . . ?
C59 C58 Rh2 75.8(11) . . ?
C57 C58 Rh2 72.8(10) . . ?
C63 C58 Rh2 128.6(16) . . ?
C58 C59 C55 104.8(18) . . ?
C58 C59 C64 131(2) . . ?
C55 C59 C64 124(2) . . ?
C58 C59 Rh2 66.4(11) . . ?
C55 C59 Rh2 68.4(10) . . ?
C64 C59 Rh2 124.2(15) . . ?
C55 C60 H60A 109.5 . . ?
C55 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C55 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
C56 C61 H61A 109.5 . . ?
C56 C61 H61B 109.5 . . ?
H61A C61 H61B 109.5 . . ?
C56 C61 H61C 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C57 C62 H62A 109.5 . . ?
C57 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
C57 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
C58 C63 H63A 109.5 . . ?
C58 C63 H63B 109.5 . . ?
H63A C63 H63B 109.5 . . ?
C58 C63 H63C 109.5 . . ?
H63A C63 H63C 109.5 . . ?
H63B C63 H63C 109.5 . . ?
C59 C64 H64A 109.5 . . ?
C59 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C59 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
C69 C65 C66 108.3(15) . . ?
C69 C65 C70 118(2) . . ?
C66 C65 C70 133(2) . . ?
C69 C65 Rh4 70.6(8) . . ?
C66 C65 Rh4 70.1(8) . . ?
C70 C65 Rh4 118.4(13) . . ?
C67 C66 C65 106.9(16) . . ?
C67 C66 C71 123(2) . . ?
C65 C66 C71 130(2) . . ?
C67 C66 Rh4 70.4(9) . . ?
C65 C66 Rh4 70.6(8) . . ?
C71 C66 Rh4 126.5(14) . . ?
C68 C67 C66 113.8(18) . . ?
C68 C67 C72 127(2) . . ?
C66 C67 C72 119(2) . . ?
C68 C67 Rh4 73.3(11) . . ?
C66 C67 Rh4 72.4(10) . . ?
C72 C67 Rh4 126.4(16) . . ?
C67 C68 C69 105.7(17) . . ?
C67 C68 C73 123(2) . . ?
C69 C68 C73 131(2) . . ?
C67 C68 Rh4 70.1(10) . . ?
C69 C68 Rh4 68.8(9) . . ?
C73 C68 Rh4 125.8(16) . . ?
C65 C69 C68 105.3(16) . . ?
C65 C69 C74 131(2) . . ?
C68 C69 C74 123(2) . . ?
C65 C69 Rh4 71.1(9) . . ?
C68 C69 Rh4 69.8(9) . . ?
C74 C69 Rh4 117.8(15) . . ?
C65 C70 H70A 109.5 . . ?
C65 C70 H70B 109.5 . . ?
H70A C70 H70B 109.5 . . ?
C65 C70 H70C 109.5 . . ?
H70A C70 H70C 109.5 . . ?
H70B C70 H70C 109.5 . . ?
C66 C71 H71A 109.5 . . ?
C66 C71 H71B 109.5 . . ?
H71A C71 H71B 109.5 . . ?
C66 C71 H71C 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
C67 C72 H72A 109.5 . . ?
C67 C72 H72B 109.5 . . ?
H72A C72 H72B 109.5 . . ?
C67 C72 H72C 109.5 . . ?
H72A C72 H72C 109.5 . . ?
H72B C72 H72C 109.5 . . ?
C68 C73 H73A 109.5 . . ?
C68 C73 H73B 109.5 . . ?
H73A C73 H73B 109.5 . . ?
C68 C73 H73C 109.5 . . ?
H73A C73 H73C 109.5 . . ?
H73B C73 H73C 109.5 . . ?
C69 C74 H74A 109.5 . . ?
C69 C74 H74B 109.5 . . ?
H74A C74 H74B 109.5 . . ?
C69 C74 H74C 109.5 . . ?
H74A C74 H74C 109.5 . . ?
H74B C74 H74C 109.5 . . ?
C76 C75 C80 133(2) . . ?
C76 C75 C79 100.3(17) . . ?
C80 C75 C79 126(2) . . ?
C76 C75 Rh3 69.4(10) . . ?
C80 C75 Rh3 122.7(16) . . ?
C79 C75 Rh3 66.3(10) . . ?
C77 C76 C75 114.7(19) . . ?
C77 C76 C81 124(2) . . ?
C75 C76 C81 121(3) . . ?
C77 C76 Rh3 70.5(11) . . ?
C75 C76 Rh3 72.5(10) . . ?
C81 C76 Rh3 118.5(15) . . ?
C76 C77 C78 107.4(17) . . ?
C76 C77 C82 123(2) . . ?
C78 C77 C82 130(2) . . ?
C76 C77 Rh3 71.4(11) . . ?
C78 C77 Rh3 70.8(10) . . ?
C82 C77 Rh3 123.2(15) . . ?
C79 C78 C77 105.9(19) . . ?
C79 C78 C83 132(3) . . ?
C77 C78 C83 122(2) . . ?
C79 C78 Rh3 68.6(11) . . ?
C77 C78 Rh3 70.2(10) . . ?
C83 C78 Rh3 121.8(16) . . ?
C78 C79 C75 111.5(18) . . ?
C78 C79 C84 119(3) . . ?
C75 C79 C84 130(2) . . ?
C78 C79 Rh3 72.2(11) . . ?
C75 C79 Rh3 72.8(11) . . ?
C84 C79 Rh3 122.6(19) . . ?
C75 C80 H80A 109.5 . . ?
C75 C80 H80B 109.5 . . ?
H80A C80 H80B 109.5 . . ?
C75 C80 H80C 109.5 . . ?
H80A C80 H80C 109.5 . . ?
H80B C80 H80C 109.5 . . ?
C76 C81 H81A 109.5 . . ?
C76 C81 H81B 109.5 . . ?
H81A C81 H81B 109.5 . . ?
C76 C81 H81C 109.5 . . ?
H81A C81 H81C 109.5 . . ?
H81B C81 H81C 109.5 . . ?
C77 C82 H82A 109.5 . . ?
C77 C82 H82B 109.5 . . ?
H82A C82 H82B 109.5 . . ?
C77 C82 H82C 109.5 . . ?
H82A C82 H82C 109.5 . . ?
H82B C82 H82C 109.5 . . ?
C78 C83 H83A 109.5 . . ?
C78 C83 H83B 109.5 . . ?
H83A C83 H83B 109.5 . . ?
C78 C83 H83C 109.5 . . ?
H83A C83 H83C 109.5 . . ?
H83B C83 H83C 109.5 . . ?
C79 C84 H84A 109.5 . . ?
C79 C84 H84B 109.5 . . ?
H84A C84 H84B 109.5 . . ?
C79 C84 H84C 109.5 . . ?
H84A C84 H84C 109.5 . . ?
H84B C84 H84C 109.5 . . ?
O13 C85 C90 121.5(12) . . ?
O13 C85 C86 117.0(13) . . ?
C90 C85 C86 121.1(14) . . ?
C87 C86 O14 122.9(12) . . ?
C87 C86 C85 122.6(14) . . ?
O14 C86 C85 114.3(12) . . ?
C86 C87 C88 117.3(12) . . ?
C86 C87 H87 121.4 . . ?
C88 C87 H87 121.4 . . ?
O15 C88 C87 123.3(13) . . ?
O15 C88 C89 118.4(15) . . ?
C87 C88 C89 118.2(12) . . ?
O16 C89 C90 122.5(13) . . ?
O16 C89 C88 114.2(14) . . ?
C90 C89 C88 123.3(13) . . ?
C89 C90 C85 117.0(13) . . ?
C89 C90 H90 121.5 . . ?
C85 C90 H90 121.5 . . ?
O17 C91 C96 124.7(14) . . ?
O17 C91 C92 114.2(13) . . ?
C96 C91 C92 121.1(14) . . ?
O18 C92 C93 119.7(17) . . ?
O18 C92 C91 119.9(13) . . ?
C93 C92 C91 120.2(18) . . ?
C92 C93 C94 119.2(18) . . ?
C92 C93 H93 120.4 . . ?
C94 C93 H93 120.4 . . ?
C93 C94 O19 127.3(17) . . ?
C93 C94 C95 121.9(15) . . ?
O19 C94 C95 110.7(17) . . ?
O20 C95 C94 118.9(15) . . ?
O20 C95 C96 121.9(16) . . ?
C94 C95 C96 118.9(15) . . ?
C91 C96 C95 118.3(14) . . ?
C91 C96 H96 120.8 . . ?
C95 C96 H96 120.8 . . ?
N9 C97 C98 122.9(12) . . ?
N9 C97 H97 118.6 . . ?
C98 C97 H97 118.6 . . ?
C97 C98 C99 120.2(12) . . ?
C97 C98 H98 119.9 . . ?
C99 C98 H98 119.9 . . ?
C98 C99 C100 115.8(12) . . ?
C98 C99 C102 122.7(12) . . ?
C100 C99 C102 121.2(12) . . ?
C101 C100 C99 119.6(13) . . ?
C101 C100 H100 120.2 . . ?
C99 C100 H100 120.2 . . ?
N9 C101 C100 124.9(13) . . ?
N9 C101 H101 117.5 . . ?
C100 C101 H101 117.5 . . ?
N10 C102 C103 108.6(12) . . ?
N10 C102 C99 124.2(12) . . ?
C103 C102 C99 127.1(12) . . ?
C107 C103 C102 144.8(13) . . ?
C107 C103 C104 110.3(12) . . ?
C102 C103 C104 104.7(11) . . ?
C105 C104 C103 104.9(12) . . ?
C105 C104 C106 144.9(12) . . ?
C103 C104 C106 110.2(12) . . ?
N11 C105 C104 109.2(11) . . ?
N11 C105 C110 123.8(12) . . ?
C104 C105 C110 126.2(12) . . ?
O21 C106 N10 124.2(13) . . ?
O21 C106 C104 132.1(13) . . ?
N10 C106 C104 103.7(11) . . ?
O22 C107 N11 123.2(12) . . ?
O22 C107 C103 132.9(13) . . ?
N11 C107 C103 103.9(12) . . ?
N12 C108 C109 119.9(13) . . ?
N12 C108 H108 120.0 . . ?
C109 C108 H108 120.0 . . ?
C110 C109 C108 120.3(13) . . ?
C110 C109 H109 119.8 . . ?
C108 C109 H109 119.8 . . ?
C109 C110 C111 120.4(14) . . ?
C109 C110 C105 120.5(12) . . ?
C111 C110 C105 119.1(13) . . ?
C110 C111 C112 117.8(16) . . ?
C110 C111 H111 121.1 . . ?
C112 C111 H111 121.1 . . ?
N12 C112 C111 122.1(16) . . ?
N12 C112 H112 119.0 . . ?
C111 C112 H112 119.0 . . ?
N13 C113 C114 119.7(15) . . ?
N13 C113 H113 120.2 . . ?
C114 C113 H113 120.2 . . ?
C115 C114 C113 121.0(14) . . ?
C115 C114 H114 119.5 . . ?
C113 C114 H114 119.5 . . ?
C114 C115 C118 122.4(13) . . ?
C114 C115 C116 119.5(15) . . ?
C118 C115 C116 118.2(15) . . ?
C117 C116 C115 114.5(17) . . ?
C117 C116 H116 122.7 . . ?
C115 C116 H116 122.7 . . ?
N13 C117 C116 127.5(15) . . ?
N13 C117 H117 116.3 . . ?
C116 C117 H117 116.3 . . ?
N14 C118 C119 109.4(14) . . ?
N14 C118 C115 123.8(13) . . ?
C119 C118 C115 126.7(15) . . ?
C118 C119 C120 104.9(13) . . ?
C118 C119 C128 144.8(15) . . ?
C120 C119 C128 110.1(12) . . ?
C121 C120 C119 105.4(13) . . ?
C121 C120 C127 144.6(15) . . ?
C119 C120 C127 109.9(12) . . ?
N15 C121 C120 108.4(13) . . ?
N15 C121 C124 123.4(13) . . ?
C120 C121 C124 128.2(14) . . ?
C123 C122 N16 121.8(17) . . ?
C123 C122 H122 119.1 . . ?
N16 C122 H122 119.1 . . ?
C122 C123 C124 120.3(15) . . ?
C122 C123 H123 119.9 . . ?
C124 C123 H123 119.9 . . ?
C123 C124 C125 118.7(14) . . ?
C123 C124 C121 120.1(12) . . ?
C125 C124 C121 120.9(14) . . ?
C126 C125 C124 117.3(18) . . ?
C126 C125 H125 121.4 . . ?
C124 C125 H125 121.4 . . ?
N16 C126 C125 124.9(16) . . ?
N16 C126 H126 117.5 . . ?
C125 C126 H126 117.5 . . ?
O23 C127 N14 123.7(14) . . ?
O23 C127 C120 131.8(14) . . ?
N14 C127 C120 104.2(13) . . ?
O24 C128 N15 127.1(13) . . ?
O24 C128 C119 131.4(13) . . ?
N15 C128 C119 101.5(14) . . ?
C130 C129 C133 108.4(16) . . ?
C130 C129 C134 128.4(18) . . ?
C133 C129 C134 122.9(18) . . ?
C130 C129 Rh5 73.0(9) . . ?
C133 C129 Rh5 71.2(8) . . ?
C134 C129 Rh5 126.3(14) . . ?
C129 C130 C131 106.9(15) . . ?
C129 C130 C135 129.3(18) . . ?
C131 C130 C135 123.5(16) . . ?
C129 C130 Rh5 68.5(9) . . ?
C131 C130 Rh5 67.5(8) . . ?
C135 C130 Rh5 123.9(13) . . ?
C132 C131 C130 110.5(15) . . ?
C132 C131 C136 124.6(16) . . ?
C130 C131 C136 124.3(16) . . ?
C132 C131 Rh5 73.4(10) . . ?
C130 C131 Rh5 72.6(10) . . ?
C136 C131 Rh5 128.2(11) . . ?
C131 C132 C137 130.4(17) . . ?
C131 C132 C133 105.6(15) . . ?
C137 C132 C133 124.0(17) . . ?
C131 C132 Rh5 68.3(9) . . ?
C137 C132 Rh5 125.5(13) . . ?
C133 C132 Rh5 68.9(10) . . ?
C129 C133 C132 108.2(16) . . ?
C129 C133 C138 126.1(17) . . ?
C132 C133 C138 125.7(18) . . ?
C129 C133 Rh5 69.1(10) . . ?
C132 C133 Rh5 70.8(9) . . ?
C138 C133 Rh5 124.8(13) . . ?
C129 C134 H13A 109.5 . . ?
C129 C134 H13B 109.5 . . ?
H13A C134 H13B 109.5 . . ?
C129 C134 H13C 109.5 . . ?
H13A C134 H13C 109.5 . . ?
H13B C134 H13C 109.5 . . ?
C130 C135 H13D 109.5 . . ?
C130 C135 H13E 109.5 . . ?
H13D C135 H13E 109.5 . . ?
C130 C135 H13F 109.5 . . ?
H13D C135 H13F 109.5 . . ?
H13E C135 H13F 109.5 . . ?
C131 C136 H13G 109.5 . . ?
C131 C136 H13H 109.5 . . ?
H13G C136 H13H 109.5 . . ?
C131 C136 H13I 109.5 . . ?
H13G C136 H13I 109.5 . . ?
H13H C136 H13I 109.5 . . ?
C132 C137 H13J 109.5 . . ?
C132 C137 H13K 109.5 . . ?
H13J C137 H13K 109.5 . . ?
C132 C137 H13L 109.5 . . ?
H13J C137 H13L 109.5 . . ?
H13K C137 H13L 109.5 . . ?
C133 C138 H13M 109.5 . . ?
C133 C138 H13N 109.5 . . ?
H13M C138 H13N 109.5 . . ?
C133 C138 H13O 109.5 . . ?
H13M C138 H13O 109.5 . . ?
H13N C138 H13O 109.5 . . ?
C140 C139 C143 102(2) . . ?
C140 C139 C144 125(2) . . ?
C143 C139 C144 133(2) . . ?
C140 C139 Rh6 70.8(12) . . ?
C143 C139 Rh6 67.8(15) . . ?
C144 C139 Rh6 122.1(16) . . ?
C141 C140 C139 109(2) . . ?
C141 C140 C145 126(2) . . ?
C139 C140 C145 125(2) . . ?
C141 C140 Rh6 74.5(13) . . ?
C139 C140 Rh6 70.8(12) . . ?
C145 C140 Rh6 126.5(16) . . ?
C140 C141 C142 107(2) . . ?
C140 C141 C146 126(2) . . ?
C142 C141 C146 127(2) . . ?
C140 C141 Rh6 68.7(12) . . ?
C142 C141 Rh6 69.9(12) . . ?
C146 C141 Rh6 124.7(19) . . ?
C143 C142 C141 108(2) . . ?
C143 C142 C147 124(3) . . ?
C141 C142 C147 128(3) . . ?
C143 C142 Rh6 68.3(16) . . ?
C141 C142 Rh6 72.8(12) . . ?
C147 C142 Rh6 118.9(17) . . ?
C142 C143 C139 115(3) . . ?
C142 C143 C148 128(3) . . ?
C139 C143 C148 117(3) . . ?
C142 C143 Rh6 77.4(17) . . ?
C139 C143 Rh6 73.0(15) . . ?
C148 C143 Rh6 121(2) . . ?
C139 C144 H14A 109.5 . . ?
C139 C144 H14B 109.5 . . ?
H14A C144 H14B 109.5 . . ?
C139 C144 H14C 109.5 . . ?
H14A C144 H14C 109.5 . . ?
H14B C144 H14C 109.5 . . ?
C140 C145 H14D 109.5 . . ?
C140 C145 H14E 109.5 . . ?
H14D C145 H14E 109.5 . . ?
C140 C145 H14F 109.5 . . ?
H14D C145 H14F 109.5 . . ?
H14E C145 H14F 109.5 . . ?
C141 C146 H14G 109.5 . . ?
C141 C146 H14H 109.5 . . ?
H14G C146 H14H 109.5 . . ?
C141 C146 H14I 109.5 . . ?
H14G C146 H14I 109.5 . . ?
H14H C146 H14I 109.5 . . ?
C142 C147 H14J 109.5 . . ?
C142 C147 H14K 109.5 . . ?
H14J C147 H14K 109.5 . . ?
C142 C147 H14L 109.5 . . ?
H14J C147 H14L 109.5 . . ?
H14K C147 H14L 109.5 . . ?
C143 C148 H14M 109.5 . . ?
C143 C148 H14N 109.5 . . ?
H14M C148 H14N 109.5 . . ?
C143 C148 H14O 109.5 . . ?
H14M C148 H14O 109.5 . . ?
H14N C148 H14O 109.5 . . ?
C150 C149 C153 113(2) . . ?
C150 C149 C154 127(3) . . ?
C153 C149 C154 119(3) . . ?
C150 C149 Rh7 71.9(13) . . ?
C153 C149 Rh7 67.7(12) . . ?
C154 C149 Rh7 122.7(18) . . ?
C149 C150 C151 109(2) . . ?
C149 C150 C155 124(3) . . ?
C151 C150 C155 126(4) . . ?
C149 C150 Rh7 71.5(14) . . ?
C151 C150 Rh7 68.0(11) . . ?
C155 C150 Rh7 121.2(19) . . ?
C152 C151 C156 131(3) . . ?
C152 C151 C150 101(2) . . ?
C156 C151 C150 127(3) . . ?
C152 C151 Rh7 71.5(13) . . ?
C156 C151 Rh7 126.4(16) . . ?
C150 C151 Rh7 71.1(13) . . ?
C151 C152 C153 115.1(19) . . ?
C151 C152 C157 122(3) . . ?
C153 C152 C157 121(3) . . ?
C151 C152 Rh7 69.9(12) . . ?
C153 C152 Rh7 68.1(13) . . ?
C157 C152 Rh7 121.0(17) . . ?
C149 C153 C152 100(2) . . ?
C149 C153 C158 124(3) . . ?
C152 C153 C158 131(3) . . ?
C149 C153 Rh7 72.8(13) . . ?
C152 C153 Rh7 71.8(13) . . ?
C158 C153 Rh7 138(2) . . ?
C149 C154 H15A 109.5 . . ?
C149 C154 H15B 109.5 . . ?
H15A C154 H15B 109.5 . . ?
C149 C154 H15C 109.5 . . ?
H15A C154 H15C 109.5 . . ?
H15B C154 H15C 109.5 . . ?
C150 C155 H15D 109.5 . . ?
C150 C155 H15E 109.5 . . ?
H15D C155 H15E 109.5 . . ?
C150 C155 H15F 109.5 . . ?
H15D C155 H15F 109.5 . . ?
H15E C155 H15F 109.5 . . ?
C151 C156 H15G 109.5 . . ?
C151 C156 H15H 109.5 . . ?
H15G C156 H15H 109.5 . . ?
C151 C156 H15I 109.5 . . ?
H15G C156 H15I 109.5 . . ?
H15H C156 H15I 109.5 . . ?
C152 C157 H15J 109.5 . . ?
C152 C157 H15K 109.5 . . ?
H15J C157 H15K 109.5 . . ?
C152 C157 H15L 109.5 . . ?
H15J C157 H15L 109.5 . . ?
H15K C157 H15L 109.5 . . ?
C153 C158 H15M 109.5 . . ?
C153 C158 H15N 109.5 . . ?
H15M C158 H15N 109.5 . . ?
C153 C158 H15O 109.5 . . ?
H15M C158 H15O 109.5 . . ?
H15N C158 H15O 109.5 . . ?
C160 C159 C163 108.0 . . ?
C160 C159 C164 126.0 . . ?
C163 C159 C164 126.0 . . ?
C160 C159 Rh8 63.9(2) . . ?
C163 C159 Rh8 72.1(2) . . ?
C164 C159 Rh8 129.49(18) . . ?
C159 C160 C161 108.0 . . ?
C159 C160 C165 126.0 . . ?
C161 C160 C165 126.0 . . ?
C159 C160 Rh8 77.9(2) . . ?
C161 C160 Rh8 65.3(2) . . ?
C165 C160 Rh8 122.2(2) . . ?
C162 C161 C160 108.0 . . ?
C162 C161 C166 126.0 . . ?
C160 C161 C166 126.0 . . ?
C162 C161 Rh8 74.4(2) . . ?
C160 C161 Rh8 73.4(2) . . ?
C166 C161 Rh8 118.2(2) . . ?
C161 C162 C163 108.0 . . ?
C161 C162 C167 126.0 . . ?
C163 C162 C167 126.0 . . ?
C161 C162 Rh8 64.5(2) . . ?
C163 C162 Rh8 77.7(2) . . ?
C167 C162 Rh8 123.2(2) . . ?
C162 C163 C159 108.0 . . ?
C162 C163 C168 126.0 . . ?
C159 C163 C168 126.0 . . ?
C162 C163 Rh8 64.4(2) . . ?
C159 C163 Rh8 71.1(2) . . ?
C168 C163 Rh8 130.1(2) . . ?
C159 C164 H16A 109.5 . . ?
C159 C164 H16B 109.5 . . ?
H16A C164 H16B 109.5 . . ?
C159 C164 H16C 109.5 . . ?
H16A C164 H16C 109.5 . . ?
H16B C164 H16C 109.5 . . ?
C160 C165 H16D 109.5 . . ?
C160 C165 H16E 109.5 . . ?
H16D C165 H16E 109.5 . . ?
C160 C165 H16F 109.5 . . ?
H16D C165 H16F 109.5 . . ?
H16E C165 H16F 109.5 . . ?
C161 C166 H16G 109.5 . . ?
C161 C166 H16H 109.5 . . ?
H16G C166 H16H 109.5 . . ?
C161 C166 H16I 109.5 . . ?
H16G C166 H16I 109.5 . . ?
H16H C166 H16I 109.5 . . ?
C162 C167 H16J 109.5 . . ?
C162 C167 H16K 109.5 . . ?
H16J C167 H16K 109.5 . . ?
C162 C167 H16L 109.5 . . ?
H16J C167 H16L 109.5 . . ?
H16K C167 H16L 109.5 . . ?
C163 C168 H16M 109.5 . . ?
C163 C168 H16N 109.5 . . ?
H16M C168 H16N 109.5 . . ?
C163 C168 H16O 109.5 . . ?
H16M C168 H16O 109.5 . . ?
H16N C168 H16O 109.5 . . ?
C260 C259 C263 108.0 . . ?
C260 C259 C264 126.0 . . ?
C263 C259 C264 126.0 . . ?
C260 C259 Rh8 74.5(2) . . ?
C263 C259 Rh8 69.6(2) . . ?
C264 C259 Rh8 121.6(2) . . ?
C261 C260 C259 108.0 . . ?
C261 C260 C265 126.0 . . ?
C259 C260 C265 126.0 . . ?
C261 C260 Rh8 73.1(2) . . ?
C259 C260 Rh8 67.1(2) . . ?
C265 C260 Rh8 125.36(18) . . ?
C262 C261 C260 108.0 . . ?
C262 C261 C266 126.0 . . ?
C260 C261 C266 126.0 . . ?
C262 C261 Rh8 68.73(19) . . ?
C260 C261 Rh8 69.7(2) . . ?
C266 C261 Rh8 127.1(2) . . ?
C261 C262 C263 108.0 . . ?
C261 C262 C267 126.0 . . ?
C263 C262 C267 126.0 . . ?
C261 C262 Rh8 73.9(2) . . ?
C263 C262 Rh8 67.2(2) . . ?
C267 C262 Rh8 124.5(2) . . ?
C262 C263 C259 108.0 . . ?
C262 C263 C268 126.0 . . ?
C259 C263 C268 126.0 . . ?
C262 C263 Rh8 74.0(2) . . ?
C259 C263 Rh8 70.8(2) . . ?
C268 C263 Rh8 121.0(2) . . ?
C259 C264 H26A 109.5 . . ?
C259 C264 H26B 109.5 . . ?
H26A C264 H26B 109.5 . . ?
C259 C264 H26C 109.5 . . ?
H26A C264 H26C 109.5 . . ?
H26B C264 H26C 109.5 . . ?
C260 C265 H26D 109.5 . . ?
C260 C265 H26E 109.5 . . ?
H26D C265 H26E 109.5 . . ?
C260 C265 H26F 109.5 . . ?
H26D C265 H26F 109.5 . . ?
H26E C265 H26F 109.5 . . ?
C261 C266 H26G 109.5 . . ?
C261 C266 H26H 109.5 . . ?
H26G C266 H26H 109.5 . . ?
C261 C266 H26I 109.5 . . ?
H26G C266 H26I 109.5 . . ?
H26H C266 H26I 109.5 . . ?
C262 C267 H26J 109.5 . . ?
C262 C267 H26K 109.5 . . ?
H26J C267 H26K 109.5 . . ?
C262 C267 H26L 109.5 . . ?
H26J C267 H26L 109.5 . . ?
H26K C267 H26L 109.5 . . ?
C263 C268 H26M 109.5 . . ?
C263 C268 H26N 109.5 . . ?
H26M C268 H26N 109.5 . . ?
C263 C268 H26O 109.5 . . ?
H26M C268 H26O 109.5 . . ?
H26N C268 H26O 109.5 . . ?
F2 C169 F1 99(2) . . ?
F2 C169 F3 106(2) . . ?
F1 C169 F3 105.6(18) . . ?
F2 C169 S1 116(2) . . ?
F1 C169 S1 114.5(12) . . ?
F3 C169 S1 114.4(11) . . ?
F4 C170 F6 114(2) . . ?
F4 C170 F5 103.7(17) . . ?
F6 C170 F5 115(2) . . ?
F4 C170 S2 108.4(13) . . ?
F6 C170 S2 109.3(18) . . ?
F5 C170 S2 106.7(16) . . ?
N17 C177 C178 176.2 . . ?
C177 C178 H17A 109.5 . . ?
C177 C178 H17B 109.5 . . ?
H17A C178 H17B 109.5 . . ?
C177 C178 H17C 109.5 . . ?
H17A C178 H17C 109.5 . . ?
H17B C178 H17C 109.5 . . ?
N18 C179 C180 169.9 . . ?
C179 C180 H18A 109.5 . . ?
C179 C180 H18B 109.5 . . ?
H18A C180 H18B 109.5 . . ?
C179 C180 H18C 109.5 . . ?
H18A C180 H18C 109.5 . . ?
H18B C180 H18C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 O1 C1 C6 171.4(11) . . . . ?
Rh1 O1 C1 C2 -3.9(15) . . . . ?
Rh1 O2 C2 C3 -176.9(11) . . . . ?
Rh1 O2 C2 C1 6.7(15) . . . . ?
O1 C1 C2 O2 -2.2(18) . . . . ?
C6 C1 C2 O2 -177.8(13) . . . . ?
O1 C1 C2 C3 -178.8(12) . . . . ?
C6 C1 C2 C3 5.6(19) . . . . ?
O2 C2 C3 C4 178.7(13) . . . . ?
C1 C2 C3 C4 -5(2) . . . . ?
Rh2 O3 C4 C3 -169.4(11) . . . . ?
Rh2 O3 C4 C5 9.7(14) . . . . ?
C2 C3 C4 O3 -178.2(13) . . . . ?
C2 C3 C4 C5 3(2) . . . . ?
Rh2 O4 C5 C6 170.5(10) . . . . ?
Rh2 O4 C5 C4 -9.0(14) . . . . ?
O3 C4 C5 O4 -0.5(18) . . . . ?
C3 C4 C5 O4 178.7(12) . . . . ?
O3 C4 C5 C6 180.0(12) . . . . ?
C3 C4 C5 C6 -0.9(19) . . . . ?
O4 C5 C6 C1 -177.9(13) . . . . ?
C4 C5 C6 C1 2(2) . . . . ?
O1 C1 C6 C5 -179.1(13) . . . . ?
C2 C1 C6 C5 -4(2) . . . . ?
Rh3 O5 C7 C12 174.6(10) . . . . ?
Rh3 O5 C7 C8 -3.9(13) . . . . ?
Rh3 O6 C8 C9 -177.4(11) . . . . ?
Rh3 O6 C8 C7 6.8(14) . . . . ?
O5 C7 C8 O6 -2.0(17) . . . . ?
C12 C7 C8 O6 179.4(12) . . . . ?
O5 C7 C8 C9 -178.1(12) . . . . ?
C12 C7 C8 C9 3.4(19) . . . . ?
O6 C8 C9 C10 -177.8(14) . . . . ?
C7 C8 C9 C10 -2(2) . . . . ?
Rh4 O7 C10 C9 -172.7(12) . . . . ?
Rh4 O7 C10 C11 7.4(15) . . . . ?
C8 C9 C10 O7 -179.0(13) . . . . ?
C8 C9 C10 C11 1(2) . . . . ?
Rh4 O8 C11 C12 173.8(9) . . . . ?
Rh4 O8 C11 C10 -5.9(13) . . . . ?
O7 C10 C11 O8 -1.1(18) . . . . ?
C9 C10 C11 O8 179.0(13) . . . . ?
O7 C10 C11 C12 179.2(12) . . . . ?
C9 C10 C11 C12 -1(2) . . . . ?
O5 C7 C12 C11 178.5(11) . . . . ?
C8 C7 C12 C11 -3.1(18) . . . . ?
O8 C11 C12 C7 -177.8(11) . . . . ?
C10 C11 C12 C7 1.9(18) . . . . ?
C17 N1 C13 C14 -4(2) . . . . ?
Rh1 N1 C13 C14 175.2(10) . . . . ?
N1 C13 C14 C15 -1(2) . . . . ?
C13 C14 C15 C16 2(2) . . . . ?
C13 C14 C15 C18 -176.7(13) . . . . ?
C14 C15 C16 C17 1(3) . . . . ?
C18 C15 C16 C17 179.4(17) . . . . ?
C13 N1 C17 C16 7(3) . . . . ?
Rh1 N1 C17 C16 -172.4(15) . . . . ?
C15 C16 C17 N1 -5(3) . . . . ?
C22 N2 C18 C19 -0.4(17) . . . . ?
C22 N2 C18 C15 -179.1(13) . . . . ?
C16 C15 C18 C19 -176.6(17) . . . . ?
C14 C15 C18 C19 2(2) . . . . ?
C16 C15 C18 N2 2(2) . . . . ?
C14 C15 C18 N2 -179.4(13) . . . . ?
N2 C18 C19 C20 0.3(17) . . . . ?
C15 C18 C19 C20 178.8(14) . . . . ?
N2 C18 C19 C23 -175.6(18) . . . . ?
C15 C18 C19 C23 3(3) . . . . ?
C18 C19 C20 C21 -175.5(12) . . . . ?
C23 C19 C20 C21 1.9(16) . . . . ?
C18 C19 C20 C22 -0.1(16) . . . . ?
C23 C19 C20 C22 177.3(12) . . . . ?
C23 N3 C21 C20 0.1(17) . . . . ?
C23 N3 C21 C26 -176.2(13) . . . . ?
C19 C20 C21 N3 -1.2(16) . . . . ?
C22 C20 C21 N3 -173(2) . . . . ?
C19 C20 C21 C26 174.9(13) . . . . ?
C22 C20 C21 C26 3(3) . . . . ?
C18 N2 C22 O9 179.7(14) . . . . ?
C18 N2 C22 C20 0.3(16) . . . . ?
C21 C20 C22 O9 -7(3) . . . . ?
C19 C20 C22 O9 -179.5(16) . . . . ?
C21 C20 C22 N2 172(2) . . . . ?
C19 C20 C22 N2 -0.1(15) . . . . ?
C21 N3 C23 O10 -179.0(14) . . . . ?
C21 N3 C23 C19 1.0(16) . . . . ?
C18 C19 C23 O10 -6(3) . . . . ?
C20 C19 C23 O10 178.3(16) . . . . ?
C18 C19 C23 N3 174.2(19) . . . . ?
C20 C19 C23 N3 -1.7(15) . . . . ?
C28 N4 C24 C25 0(3) . . . . ?
Rh3 N4 C24 C25 -179.8(14) . . . . ?
N4 C24 C25 C26 1(3) . . . . ?
C24 C25 C26 C27 -3(2) . . . . ?
C24 C25 C26 C21 175.5(15) . . . . ?
N3 C21 C26 C27 0(2) . . . . ?
C20 C21 C26 C27 -175.4(14) . . . . ?
N3 C21 C26 C25 -178.6(14) . . . . ?
C20 C21 C26 C25 6(2) . . . . ?
C25 C26 C27 C28 5(2) . . . . ?
C21 C26 C27 C28 -174.2(13) . . . . ?
C24 N4 C28 C27 2(2) . . . . ?
Rh3 N4 C28 C27 -178.6(12) . . . . ?
C26 C27 C28 N4 -4(2) . . . . ?
C33 N5 C29 C30 1(2) . . . . ?
Rh2 N5 C29 C30 -178.2(11) . . . . ?
N5 C29 C30 C31 0(2) . . . . ?
C29 C30 C31 C32 -3(2) . . . . ?
C29 C30 C31 C34 175.7(13) . . . . ?
C30 C31 C32 C33 6(2) . . . . ?
C34 C31 C32 C33 -173.3(13) . . . . ?
C29 N5 C33 C32 1(2) . . . . ?
Rh2 N5 C33 C32 -179.3(11) . . . . ?
C31 C32 C33 N5 -5(2) . . . . ?
C38 N6 C34 C35 -3.7(15) . . . . ?
C38 N6 C34 C31 175.7(12) . . . . ?
C32 C31 C34 C35 -174.3(14) . . . . ?
C30 C31 C34 C35 7(2) . . . . ?
C32 C31 C34 N6 6(2) . . . . ?
C30 C31 C34 N6 -172.5(13) . . . . ?
N6 C34 C35 C36 2.4(15) . . . . ?
C31 C34 C35 C36 -176.9(13) . . . . ?
N6 C34 C35 C39 -178.8(18) . . . . ?
C31 C34 C35 C39 2(3) . . . . ?
C34 C35 C36 C37 176.3(12) . . . . ?
C39 C35 C36 C37 -2.9(15) . . . . ?
C34 C35 C36 C38 -0.4(15) . . . . ?
C39 C35 C36 C38 -179.7(11) . . . . ?
C35 C36 C37 N7 2.2(15) . . . . ?
C38 C36 C37 N7 176.9(18) . . . . ?
C35 C36 C37 C42 -179.3(14) . . . . ?
C38 C36 C37 C42 -5(3) . . . . ?
C39 N7 C37 C36 -0.7(15) . . . . ?
C39 N7 C37 C42 -179.3(12) . . . . ?
C34 N6 C38 O11 -177.2(13) . . . . ?
C34 N6 C38 C36 3.3(14) . . . . ?
C37 C36 C38 O11 4(3) . . . . ?
C35 C36 C38 O11 178.9(15) . . . . ?
C37 C36 C38 N6 -176.3(19) . . . . ?
C35 C36 C38 N6 -1.7(14) . . . . ?
C37 N7 C39 O12 178.6(13) . . . . ?
C37 N7 C39 C35 -1.1(14) . . . . ?
C34 C35 C39 O12 4(3) . . . . ?
C36 C35 C39 O12 -177.2(14) . . . . ?
C34 C35 C39 N7 -176.4(19) . . . . ?
C36 C35 C39 N7 2.4(14) . . . . ?
C44 N8 C40 C41 -2(3) . . . . ?
Rh4 N8 C40 C41 -179.2(17) . . . . ?
N8 C40 C41 C42 1(3) . . . . ?
C40 C41 C42 C43 0(3) . . . . ?
C40 C41 C42 C37 173.7(17) . . . . ?
C36 C37 C42 C41 -2(2) . . . . ?
N7 C37 C42 C41 175.9(15) . . . . ?
C36 C37 C42 C43 170.3(16) . . . . ?
N7 C37 C42 C43 -11(2) . . . . ?
C41 C42 C43 C44 -1(2) . . . . ?
C37 C42 C43 C44 -173.9(15) . . . . ?
C40 N8 C44 C43 1(3) . . . . ?
Rh4 N8 C44 C43 178.5(14) . . . . ?
C42 C43 C44 N8 0(3) . . . . ?
C49 C45 C46 C47 -3(2) . . . . ?
C50 C45 C46 C47 179.0(18) . . . . ?
Rh1 C45 C46 C47 58.0(13) . . . . ?
C49 C45 C46 C51 -177.3(19) . . . . ?
C50 C45 C46 C51 4(3) . . . . ?
Rh1 C45 C46 C51 -116.8(19) . . . . ?
C49 C45 C46 Rh1 -60.5(12) . . . . ?
C50 C45 C46 Rh1 121.1(19) . . . . ?
C45 C46 C47 C48 6(2) . . . . ?
C51 C46 C47 C48 -180(2) . . . . ?
Rh1 C46 C47 C48 64.5(15) . . . . ?
C45 C46 C47 C52 177.1(17) . . . . ?
C51 C46 C47 C52 -9(3) . . . . ?
Rh1 C46 C47 C52 -124(2) . . . . ?
C45 C46 C47 Rh1 -58.5(12) . . . . ?
C51 C46 C47 Rh1 116(2) . . . . ?
C46 C47 C48 C49 -7(2) . . . . ?
C52 C47 C48 C49 -179.1(18) . . . . ?
Rh1 C47 C48 C49 57.7(15) . . . . ?
C46 C47 C48 C53 -175(2) . . . . ?
C52 C47 C48 C53 13(4) . . . . ?
Rh1 C47 C48 C53 -110(2) . . . . ?
C46 C47 C48 Rh1 -65.0(13) . . . . ?
C52 C47 C48 Rh1 123(2) . . . . ?
C46 C45 C49 C48 -1.7(19) . . . . ?
C50 C45 C49 C48 177.0(16) . . . . ?
Rh1 C45 C49 C48 -62.9(12) . . . . ?
C46 C45 C49 C54 178.0(19) . . . . ?
C50 C45 C49 C54 -3(3) . . . . ?
Rh1 C45 C49 C54 117(2) . . . . ?
C46 C45 C49 Rh1 61.2(12) . . . . ?
C50 C45 C49 Rh1 -120.1(16) . . . . ?
C47 C48 C49 C45 6(2) . . . . ?
C53 C48 C49 C45 174(2) . . . . ?
Rh1 C48 C49 C45 63.7(11) . . . . ?
C47 C48 C49 C54 -174(2) . . . . ?
C53 C48 C49 C54 -6(3) . . . . ?
Rh1 C48 C49 C54 -116(2) . . . . ?
C47 C48 C49 Rh1 -58.1(16) . . . . ?
C53 C48 C49 Rh1 110(2) . . . . ?
C59 C55 C56 C57 -2(2) . . . . ?
C60 C55 C56 C57 177.8(18) . . . . ?
Rh2 C55 C56 C57 60.8(15) . . . . ?
C59 C55 C56 C61 -179(2) . . . . ?
C60 C55 C56 C61 0(4) . . . . ?
Rh2 C55 C56 C61 -117(2) . . . . ?
C59 C55 C56 Rh2 -62.6(12) . . . . ?
C60 C55 C56 Rh2 117.0(18) . . . . ?
C55 C56 C57 C58 -1(2) . . . . ?
C61 C56 C57 C58 177(2) . . . . ?
Rh2 C56 C57 C58 58.8(13) . . . . ?
C55 C56 C57 C62 176.2(19) . . . . ?
C61 C56 C57 C62 -6(3) . . . . ?
Rh2 C56 C57 C62 -124(2) . . . . ?
C55 C56 C57 Rh2 -60.3(14) . . . . ?
C61 C56 C57 Rh2 118(2) . . . . ?
C56 C57 C58 C59 4(2) . . . . ?
C62 C57 C58 C59 -173(2) . . . . ?
Rh2 C57 C58 C59 65.3(16) . . . . ?
C56 C57 C58 C63 174.1(19) . . . . ?
C62 C57 C58 C63 -4(3) . . . . ?
Rh2 C57 C58 C63 -125(2) . . . . ?
C56 C57 C58 Rh2 -60.8(13) . . . . ?
C62 C57 C58 Rh2 121(2) . . . . ?
C57 C58 C59 C55 -5(2) . . . . ?
C63 C58 C59 C55 -174(2) . . . . ?
Rh2 C58 C59 C55 58.0(12) . . . . ?
C57 C58 C59 C64 -179(2) . . . . ?
C63 C58 C59 C64 12(4) . . . . ?
Rh2 C58 C59 C64 -116(2) . . . . ?
C57 C58 C59 Rh2 -63.5(15) . . . . ?
C63 C58 C59 Rh2 128(2) . . . . ?
C56 C55 C59 C58 4(2) . . . . ?
C60 C55 C59 C58 -175.3(19) . . . . ?
Rh2 C55 C59 C58 -56.7(13) . . . . ?
C56 C55 C59 C64 178.5(19) . . . . ?
C60 C55 C59 C64 -1(3) . . . . ?
Rh2 C55 C59 C64 117(2) . . . . ?
C56 C55 C59 Rh2 61.0(13) . . . . ?
C60 C55 C59 Rh2 -119(2) . . . . ?
C69 C65 C66 C67 0.8(18) . . . . ?
C70 C65 C66 C67 172.2(18) . . . . ?
Rh4 C65 C66 C67 61.4(11) . . . . ?
C69 C65 C66 C71 177.6(18) . . . . ?
C70 C65 C66 C71 -11(3) . . . . ?
Rh4 C65 C66 C71 -122(2) . . . . ?
C69 C65 C66 Rh4 -60.6(10) . . . . ?
C70 C65 C66 Rh4 110.8(18) . . . . ?
C65 C66 C67 C68 0(2) . . . . ?
C71 C66 C67 C68 -176.5(18) . . . . ?
Rh4 C66 C67 C68 62.0(14) . . . . ?
C65 C66 C67 C72 176.1(18) . . . . ?
C71 C66 C67 C72 -1(3) . . . . ?
Rh4 C66 C67 C72 -122.4(19) . . . . ?
C65 C66 C67 Rh4 -61.5(11) . . . . ?
C71 C66 C67 Rh4 121.5(17) . . . . ?
C66 C67 C68 C69 -1(2) . . . . ?
C72 C67 C68 C69 -177(2) . . . . ?
Rh4 C67 C68 C69 60.0(12) . . . . ?
C66 C67 C68 C73 178.0(19) . . . . ?
C72 C67 C68 C73 3(3) . . . . ?
Rh4 C67 C68 C73 -120(2) . . . . ?
C66 C67 C68 Rh4 -61.5(14) . . . . ?
C72 C67 C68 Rh4 123(2) . . . . ?
C66 C65 C69 C68 -1.6(17) . . . . ?
C70 C65 C69 C68 -174.4(15) . . . . ?
Rh4 C65 C69 C68 -61.9(11) . . . . ?
C66 C65 C69 C74 171(2) . . . . ?
C70 C65 C69 C74 -2(3) . . . . ?
Rh4 C65 C69 C74 111(2) . . . . ?
C66 C65 C69 Rh4 60.3(10) . . . . ?
C70 C65 C69 Rh4 -112.6(15) . . . . ?
C67 C68 C69 C65 1.9(19) . . . . ?
C73 C68 C69 C65 -178(2) . . . . ?
Rh4 C68 C69 C65 62.7(11) . . . . ?
C67 C68 C69 C74 -171.6(19) . . . . ?
C73 C68 C69 C74 9(3) . . . . ?
Rh4 C68 C69 C74 -110.7(19) . . . . ?
C67 C68 C69 Rh4 -60.8(13) . . . . ?
C73 C68 C69 Rh4 120(2) . . . . ?
C80 C75 C76 C77 174(2) . . . . ?
C79 C75 C76 C77 -2(2) . . . . ?
Rh3 C75 C76 C77 58.0(15) . . . . ?
C80 C75 C76 C81 3(3) . . . . ?
C79 C75 C76 C81 -172.9(19) . . . . ?
Rh3 C75 C76 C81 -113.2(19) . . . . ?
C80 C75 C76 Rh3 116(2) . . . . ?
C79 C75 C76 Rh3 -59.6(12) . . . . ?
C75 C76 C77 C78 3(2) . . . . ?
C81 C76 C77 C78 174(2) . . . . ?
Rh3 C76 C77 C78 62.0(13) . . . . ?
C75 C76 C77 C82 -177.1(19) . . . . ?
C81 C76 C77 C82 -6(3) . . . . ?
Rh3 C76 C77 C82 -118.0(19) . . . . ?
C75 C76 C77 Rh3 -59.1(15) . . . . ?
C81 C76 C77 Rh3 112(2) . . . . ?
C76 C77 C78 C79 -3(2) . . . . ?
C82 C77 C78 C79 177(2) . . . . ?
Rh3 C77 C78 C79 59.6(14) . . . . ?
C76 C77 C78 C83 -178.1(19) . . . . ?
C82 C77 C78 C83 2(3) . . . . ?
Rh3 C77 C78 C83 -116(2) . . . . ?
C76 C77 C78 Rh3 -62.4(13) . . . . ?
C82 C77 C78 Rh3 118(2) . . . . ?
C77 C78 C79 C75 2(2) . . . . ?
C83 C78 C79 C75 177(2) . . . . ?
Rh3 C78 C79 C75 62.5(15) . . . . ?
C77 C78 C79 C84 -179(2) . . . . ?
C83 C78 C79 C84 -4(4) . . . . ?
Rh3 C78 C79 C84 -118(2) . . . . ?
C77 C78 C79 Rh3 -60.6(13) . . . . ?
C83 C78 C79 Rh3 114(2) . . . . ?
C76 C75 C79 C78 0(2) . . . . ?
C80 C75 C79 C78 -176(2) . . . . ?
Rh3 C75 C79 C78 -62.2(15) . . . . ?
C76 C75 C79 C84 -180(2) . . . . ?
C80 C75 C79 C84 4(4) . . . . ?
Rh3 C75 C79 C84 118(3) . . . . ?
C76 C75 C79 Rh3 61.9(12) . . . . ?
C80 C75 C79 Rh3 -114(2) . . . . ?
Rh5 O13 C85 C90 179.3(10) . . . . ?
Rh5 O13 C85 C86 -7.3(14) . . . . ?
Rh5 O14 C86 C87 -175.2(10) . . . . ?
Rh5 O14 C86 C85 -0.4(13) . . . . ?
O13 C85 C86 C87 -179.8(12) . . . . ?
C90 C85 C86 C87 -6.3(19) . . . . ?
O13 C85 C86 O14 5.3(16) . . . . ?
C90 C85 C86 O14 178.8(12) . . . . ?
O14 C86 C87 C88 179.4(11) . . . . ?
C85 C86 C87 C88 5.0(18) . . . . ?
Rh6 O15 C88 C87 -178.0(9) . . . . ?
Rh6 O15 C88 C89 4.9(14) . . . . ?
C86 C87 C88 O15 179.2(12) . . . . ?
C86 C87 C88 C89 -3.8(17) . . . . ?
Rh6 O16 C89 C90 174.2(10) . . . . ?
Rh6 O16 C89 C88 -4.1(13) . . . . ?
O15 C88 C89 O16 -0.5(17) . . . . ?
C87 C88 C89 O16 -177.7(11) . . . . ?
O15 C88 C89 C90 -178.8(12) . . . . ?
C87 C88 C89 C90 4.0(18) . . . . ?
O16 C89 C90 C85 176.8(12) . . . . ?
C88 C89 C90 C85 -5.1(19) . . . . ?
O13 C85 C90 C89 179.2(12) . . . . ?
C86 C85 C90 C89 6.0(18) . . . . ?
Rh7 O17 C91 C96 174.2(10) . . . . ?
Rh7 O17 C91 C92 -7.5(14) . . . . ?
Rh7 O18 C92 C93 -172.7(11) . . . . ?
Rh7 O18 C92 C91 3.5(15) . . . . ?
O17 C91 C92 O18 2.6(18) . . . . ?
C96 C91 C92 O18 -179.1(12) . . . . ?
O17 C91 C92 C93 178.8(13) . . . . ?
C96 C91 C92 C93 -3(2) . . . . ?
O18 C92 C93 C94 -179.8(13) . . . . ?
C91 C92 C93 C94 4(2) . . . . ?
C92 C93 C94 O19 176.5(14) . . . . ?
C92 C93 C94 C95 -6(2) . . . . ?
Rh8 O19 C94 C93 -176.4(13) . . . . ?
Rh8 O19 C94 C95 5.5(16) . . . . ?
Rh8 O20 C95 C94 -3.0(17) . . . . ?
Rh8 O20 C95 C96 171.5(10) . . . . ?
C93 C94 C95 O20 -179.6(14) . . . . ?
O19 C94 C95 O20 -1(2) . . . . ?
C93 C94 C95 C96 6(2) . . . . ?
O19 C94 C95 C96 -176.0(12) . . . . ?
O17 C91 C96 C95 -178.8(12) . . . . ?
C92 C91 C96 C95 3.0(19) . . . . ?
O20 C95 C96 C91 -178.9(13) . . . . ?
C94 C95 C96 C91 -4(2) . . . . ?
C101 N9 C97 C98 1(2) . . . . ?
Rh5 N9 C97 C98 -179.5(11) . . . . ?
N9 C97 C98 C99 0(2) . . . . ?
C97 C98 C99 C100 1(2) . . . . ?
C97 C98 C99 C102 175.2(14) . . . . ?
C98 C99 C100 C101 -3(2) . . . . ?
C102 C99 C100 C101 -177.0(14) . . . . ?
C97 N9 C101 C100 -3(2) . . . . ?
Rh5 N9 C101 C100 177.6(12) . . . . ?
C99 C100 C101 N9 4(2) . . . . ?
C106 N10 C102 C103 -3.4(16) . . . . ?
C106 N10 C102 C99 178.5(13) . . . . ?
C98 C99 C102 N10 -174.9(14) . . . . ?
C100 C99 C102 N10 -1(2) . . . . ?
C98 C99 C102 C103 7(2) . . . . ?
C100 C99 C102 C103 -178.7(14) . . . . ?
N10 C102 C103 C107 178.3(18) . . . . ?
C99 C102 C103 C107 -4(3) . . . . ?
N10 C102 C103 C104 3.0(15) . . . . ?
C99 C102 C103 C104 -179.0(13) . . . . ?
C107 C103 C104 C105 0.7(14) . . . . ?
C102 C103 C104 C105 177.8(11) . . . . ?
C107 C103 C104 C106 -178.8(11) . . . . ?
C102 C103 C104 C106 -1.7(15) . . . . ?
C107 N11 C105 C104 2.3(15) . . . . ?
C107 N11 C105 C110 172.7(11) . . . . ?
C103 C104 C105 N11 -1.7(14) . . . . ?
C106 C104 C105 N11 177.4(18) . . . . ?
C103 C104 C105 C110 -171.9(12) . . . . ?
C106 C104 C105 C110 7(3) . . . . ?
C102 N10 C106 O21 179.6(13) . . . . ?
C102 N10 C106 C104 2.2(15) . . . . ?
C105 C104 C106 O21 4(3) . . . . ?
C103 C104 C106 O21 -177.3(15) . . . . ?
C105 C104 C106 N10 -179.3(18) . . . . ?
C103 C104 C106 N10 -0.2(15) . . . . ?
C105 N11 C107 O22 179.3(12) . . . . ?
C105 N11 C107 C103 -1.7(14) . . . . ?
C102 C103 C107 O22 4(3) . . . . ?
C104 C103 C107 O22 179.4(14) . . . . ?
C102 C103 C107 N11 -174.5(19) . . . . ?
C104 C103 C107 N11 0.6(14) . . . . ?
C112 N12 C108 C109 2(2) . . . . ?
Rh7 N12 C108 C109 -178.0(11) . . . . ?
N12 C108 C109 C110 1(2) . . . . ?
C108 C109 C110 C111 -3(2) . . . . ?
C108 C109 C110 C105 179.4(12) . . . . ?
N11 C105 C110 C109 -174.8(13) . . . . ?
C104 C105 C110 C109 -6(2) . . . . ?
N11 C105 C110 C111 8(2) . . . . ?
C104 C105 C110 C111 176.7(14) . . . . ?
C109 C110 C111 C112 3(2) . . . . ?
C105 C110 C111 C112 -179.2(14) . . . . ?
C108 N12 C112 C111 -2(2) . . . . ?
Rh7 N12 C112 C111 178.2(13) . . . . ?
C110 C111 C112 N12 -1(3) . . . . ?
C117 N13 C113 C114 -5(2) . . . . ?
Rh6 N13 C113 C114 174.5(11) . . . . ?
N13 C113 C114 C115 5(2) . . . . ?
C113 C114 C115 C118 177.1(14) . . . . ?
C113 C114 C115 C116 -1(2) . . . . ?
C114 C115 C116 C117 -3(2) . . . . ?
C118 C115 C116 C117 179.4(15) . . . . ?
C113 N13 C117 C116 1(3) . . . . ?
Rh6 N13 C117 C116 -178.0(15) . . . . ?
C115 C116 C117 N13 2(3) . . . . ?
C127 N14 C118 C119 -1.1(17) . . . . ?
C127 N14 C118 C115 178.4(13) . . . . ?
C114 C115 C118 N14 -167.1(15) . . . . ?
C116 C115 C118 N14 11(2) . . . . ?
C114 C115 C118 C119 12(2) . . . . ?
C116 C115 C118 C119 -169.8(15) . . . . ?
N14 C118 C119 C120 -1.9(15) . . . . ?
C115 C118 C119 C120 178.6(13) . . . . ?
N14 C118 C119 C128 -176.0(19) . . . . ?
C115 C118 C119 C128 5(3) . . . . ?
C118 C119 C120 C121 -177.5(12) . . . . ?
C128 C119 C120 C121 -1.1(16) . . . . ?
C118 C119 C120 C127 4.2(16) . . . . ?
C128 C119 C120 C127 -179.4(13) . . . . ?
C128 N15 C121 C120 -2.8(17) . . . . ?
C128 N15 C121 C124 179.3(13) . . . . ?
C119 C120 C121 N15 2.3(16) . . . . ?
C127 C120 C121 N15 180(2) . . . . ?
C119 C120 C121 C124 180.0(13) . . . . ?
C127 C120 C121 C124 -3(3) . . . . ?
C126 N16 C122 C123 3(3) . . . . ?
Rh8 N16 C122 C123 178.7(12) . . . . ?
N16 C122 C123 C124 1(3) . . . . ?
C122 C123 C124 C125 -3(2) . . . . ?
C122 C123 C124 C121 -176.5(14) . . . . ?
N15 C121 C124 C123 -178.9(14) . . . . ?
C120 C121 C124 C123 4(2) . . . . ?
N15 C121 C124 C125 8(2) . . . . ?
C120 C121 C124 C125 -169.6(15) . . . . ?
C123 C124 C125 C126 2(2) . . . . ?
C121 C124 C125 C126 175.0(15) . . . . ?
C122 N16 C126 C125 -5(3) . . . . ?
Rh8 N16 C126 C125 179.7(15) . . . . ?
C124 C125 C126 N16 2(3) . . . . ?
C118 N14 C127 O23 177.9(15) . . . . ?
C118 N14 C127 C120 3.6(17) . . . . ?
C121 C120 C127 O23 4(4) . . . . ?
C119 C120 C127 O23 -178.5(17) . . . . ?
C121 C120 C127 N14 178(2) . . . . ?
C119 C120 C127 N14 -4.8(17) . . . . ?
C121 N15 C128 O24 -178.8(15) . . . . ?
C121 N15 C128 C119 2.0(16) . . . . ?
C118 C119 C128 O24 -6(3) . . . . ?
C120 C119 C128 O24 -179.6(16) . . . . ?
C118 C119 C128 N15 173.4(19) . . . . ?
C120 C119 C128 N15 -0.5(16) . . . . ?
C133 C129 C130 C131 -6.3(19) . . . . ?
C134 C129 C130 C131 179.8(18) . . . . ?
Rh5 C129 C130 C131 56.6(12) . . . . ?
C133 C129 C130 C135 -179.7(18) . . . . ?
C134 C129 C130 C135 6(3) . . . . ?
Rh5 C129 C130 C135 -117(2) . . . . ?
C133 C129 C130 Rh5 -62.9(11) . . . . ?
C134 C129 C130 Rh5 123(2) . . . . ?
C129 C130 C131 C132 7(2) . . . . ?
C135 C130 C131 C132 -179.3(17) . . . . ?
Rh5 C130 C131 C132 64.1(12) . . . . ?
C129 C130 C131 C136 178.0(15) . . . . ?
C135 C130 C131 C136 -8(3) . . . . ?
Rh5 C130 C131 C136 -124.8(16) . . . . ?
C129 C130 C131 Rh5 -57.2(12) . . . . ?
C135 C130 C131 Rh5 116.7(18) . . . . ?
C130 C131 C132 C137 177.6(18) . . . . ?
C136 C131 C132 C137 6(3) . . . . ?
Rh5 C131 C132 C137 -119(2) . . . . ?
C130 C131 C132 C133 -4.5(19) . . . . ?
C136 C131 C132 C133 -175.6(15) . . . . ?
Rh5 C131 C132 C133 59.1(11) . . . . ?
C130 C131 C132 Rh5 -63.6(12) . . . . ?
C136 C131 C132 Rh5 125.3(16) . . . . ?
C130 C129 C133 C132 3.7(19) . . . . ?
C134 C129 C133 C132 178.0(17) . . . . ?
Rh5 C129 C133 C132 -60.3(11) . . . . ?
C130 C129 C133 C138 -177.3(17) . . . . ?
C134 C129 C133 C138 -3(3) . . . . ?
Rh5 C129 C133 C138 118.6(17) . . . . ?
C130 C129 C133 Rh5 64.0(12) . . . . ?
C134 C129 C133 Rh5 -121.6(18) . . . . ?
C131 C132 C133 C129 0.5(18) . . . . ?
C137 C132 C133 C129 178.6(16) . . . . ?
Rh5 C132 C133 C129 59.3(11) . . . . ?
C131 C132 C133 C138 -178.4(16) . . . . ?
C137 C132 C133 C138 0(3) . . . . ?
Rh5 C132 C133 C138 -119.7(17) . . . . ?
C131 C132 C133 Rh5 -58.8(11) . . . . ?
C137 C132 C133 Rh5 119.4(18) . . . . ?
C143 C139 C140 C141 4(3) . . . . ?
C144 C139 C140 C141 -179(2) . . . . ?
Rh6 C139 C140 C141 65.1(16) . . . . ?
C143 C139 C140 C145 177(2) . . . . ?
C144 C139 C140 C145 -5(4) . . . . ?
Rh6 C139 C140 C145 -122(2) . . . . ?
C143 C139 C140 Rh6 -61.3(16) . . . . ?
C144 C139 C140 Rh6 116(2) . . . . ?
C139 C140 C141 C142 -3(3) . . . . ?
C145 C140 C141 C142 -176(2) . . . . ?
Rh6 C140 C141 C142 59.8(16) . . . . ?
C139 C140 C141 C146 179(2) . . . . ?
C145 C140 C141 C146 6(4) . . . . ?
Rh6 C140 C141 C146 -118(3) . . . . ?
C139 C140 C141 Rh6 -62.7(16) . . . . ?
C145 C140 C141 Rh6 124(2) . . . . ?
C140 C141 C142 C143 1(3) . . . . ?
C146 C141 C142 C143 179(3) . . . . ?
Rh6 C141 C142 C143 60(2) . . . . ?
C140 C141 C142 C147 -173(2) . . . . ?
C146 C141 C142 C147 5(4) . . . . ?
Rh6 C141 C142 C147 -114(2) . . . . ?
C140 C141 C142 Rh6 -59.0(16) . . . . ?
C146 C141 C142 Rh6 119(3) . . . . ?
C141 C142 C143 C139 2(3) . . . . ?
C147 C142 C143 C139 176(2) . . . . ?
Rh6 C142 C143 C139 64(2) . . . . ?
C141 C142 C143 C148 178(3) . . . . ?
C147 C142 C143 C148 -9(5) . . . . ?
Rh6 C142 C143 C148 -120(3) . . . . ?
C141 C142 C143 Rh6 -62.6(17) . . . . ?
C147 C142 C143 Rh6 111(2) . . . . ?
C140 C139 C143 C142 -4(3) . . . . ?
C144 C139 C143 C142 179(3) . . . . ?
Rh6 C139 C143 C142 -67(2) . . . . ?
C140 C139 C143 C148 -180(2) . . . . ?
C144 C139 C143 C148 3(4) . . . . ?
Rh6 C139 C143 C148 117(3) . . . . ?
C140 C139 C143 Rh6 63.5(15) . . . . ?
C144 C139 C143 Rh6 -114(3) . . . . ?
C153 C149 C150 C151 3(3) . . . . ?
C154 C149 C150 C151 175(2) . . . . ?
Rh7 C149 C150 C151 57.7(15) . . . . ?
C153 C149 C150 C155 -171(2) . . . . ?
C154 C149 C150 C155 2(4) . . . . ?
Rh7 C149 C150 C155 -116(2) . . . . ?
C153 C149 C150 Rh7 -55(2) . . . . ?
C154 C149 C150 Rh7 118(3) . . . . ?
C149 C150 C151 C152 6(3) . . . . ?
C155 C150 C151 C152 179(2) . . . . ?
Rh7 C150 C151 C152 66.0(15) . . . . ?
C149 C150 C151 C156 178(2) . . . . ?
C155 C150 C151 C156 -9(4) . . . . ?
Rh7 C150 C151 C156 -122(2) . . . . ?
C149 C150 C151 Rh7 -59.9(18) . . . . ?
C155 C150 C151 Rh7 113(2) . . . . ?
C156 C151 C152 C153 175(2) . . . . ?
C150 C151 C152 C153 -13(3) . . . . ?
Rh7 C151 C152 C153 52(2) . . . . ?
C156 C151 C152 C157 8(4) . . . . ?
C150 C151 C152 C157 180(2) . . . . ?
Rh7 C151 C152 C157 -115(2) . . . . ?
C156 C151 C152 Rh7 123(3) . . . . ?
C150 C151 C152 Rh7 -65.8(13) . . . . ?
C150 C149 C153 C152 -10(3) . . . . ?
C154 C149 C153 C152 177(2) . . . . ?
Rh7 C149 C153 C152 -67.3(15) . . . . ?
C150 C149 C153 C158 -166(3) . . . . ?
C154 C149 C153 C158 20(4) . . . . ?
Rh7 C149 C153 C158 136(3) . . . . ?
C150 C149 C153 Rh7 57(2) . . . . ?
C154 C149 C153 Rh7 -116(2) . . . . ?
C151 C152 C153 C149 15(3) . . . . ?
C157 C152 C153 C149 -178(2) . . . . ?
Rh7 C152 C153 C149 68.1(16) . . . . ?
C151 C152 C153 C158 169(3) . . . . ?
C157 C152 C153 C158 -24(5) . . . . ?
Rh7 C152 C153 C158 -138(4) . . . . ?
C151 C152 C153 Rh7 -53.3(19) . . . . ?
C157 C152 C153 Rh7 114(2) . . . . ?
C163 C159 C160 C161 0.0 . . . . ?
C164 C159 C160 C161 180.0 . . . . ?
Rh8 C159 C160 C161 58.7(2) . . . . ?
C163 C159 C160 C165 -180.0 . . . . ?
C164 C159 C160 C165 0.0 . . . . ?
Rh8 C159 C160 C165 -121.2(2) . . . . ?
C163 C159 C160 Rh8 -58.7(2) . . . . ?
C164 C159 C160 Rh8 121.3(2) . . . . ?
C159 C160 C161 C162 0.0 . . . . ?
C165 C160 C161 C162 180.0 . . . . ?
Rh8 C160 C161 C162 66.9(3) . . . . ?
C159 C160 C161 C166 -180.0 . . . . ?
C165 C160 C161 C166 0.0 . . . . ?
Rh8 C160 C161 C166 -113.1(3) . . . . ?
C159 C160 C161 Rh8 -66.9(3) . . . . ?
C165 C160 C161 Rh8 113.0(3) . . . . ?
C160 C161 C162 C163 0.0 . . . . ?
C166 C161 C162 C163 180.0 . . . . ?
Rh8 C161 C162 C163 66.2(2) . . . . ?
C160 C161 C162 C167 -180.0 . . . . ?
C166 C161 C162 C167 0.0 . . . . ?
Rh8 C161 C162 C167 -113.8(2) . . . . ?
C160 C161 C162 Rh8 -66.2(2) . . . . ?
C166 C161 C162 Rh8 113.8(2) . . . . ?
C161 C162 C163 C159 0.0 . . . . ?
C167 C162 C163 C159 180.0 . . . . ?
Rh8 C162 C163 C159 57.7(2) . . . . ?
C161 C162 C163 C168 180.0 . . . . ?
C167 C162 C163 C168 0.0 . . . . ?
Rh8 C162 C163 C168 -122.3(2) . . . . ?
C161 C162 C163 Rh8 -57.7(2) . . . . ?
C167 C162 C163 Rh8 122.2(2) . . . . ?
C160 C159 C163 C162 0.0 . . . . ?
C164 C159 C163 C162 180.0 . . . . ?
Rh8 C159 C163 C162 -53.7(2) . . . . ?
C160 C159 C163 C168 -180.0 . . . . ?
C164 C159 C163 C168 0.0 . . . . ?
Rh8 C159 C163 C168 126.3(2) . . . . ?
C160 C159 C163 Rh8 53.7(2) . . . . ?
C164 C159 C163 Rh8 -126.3(2) . . . . ?
C263 C259 C260 C261 0.0 . . . . ?
C264 C259 C260 C261 -180.0 . . . . ?
Rh8 C259 C260 C261 62.0(2) . . . . ?
C263 C259 C260 C265 180.0 . . . . ?
C264 C259 C260 C265 0.0 . . . . ?
Rh8 C259 C260 C265 -118.0(2) . . . . ?
C263 C259 C260 Rh8 -62.0(2) . . . . ?
C264 C259 C260 Rh8 118.0(2) . . . . ?
C259 C260 C261 C262 0.0 . . . . ?
C265 C260 C261 C262 180.0 . . . . ?
Rh8 C260 C261 C262 58.2(2) . . . . ?
C259 C260 C261 C266 180.0 . . . . ?
C265 C260 C261 C266 0.0 . . . . ?
Rh8 C260 C261 C266 -121.8(2) . . . . ?
C259 C260 C261 Rh8 -58.2(2) . . . . ?
C265 C260 C261 Rh8 121.8(2) . . . . ?
C260 C261 C262 C263 0.0 . . . . ?
C266 C261 C262 C263 -180.0 . . . . ?
Rh8 C261 C262 C263 58.8(2) . . . . ?
C260 C261 C262 C267 180.0 . . . . ?
C266 C261 C262 C267 0.0 . . . . ?
Rh8 C261 C262 C267 -121.2(2) . . . . ?
C260 C261 C262 Rh8 -58.8(2) . . . . ?
C266 C261 C262 Rh8 121.2(2) . . . . ?
C261 C262 C263 C259 0.0 . . . . ?
C267 C262 C263 C259 -180.0 . . . . ?
Rh8 C262 C263 C259 63.1(2) . . . . ?
C261 C262 C263 C268 180.0 . . . . ?
C267 C262 C263 C268 0.0 . . . . ?
Rh8 C262 C263 C268 -116.9(2) . . . . ?
C261 C262 C263 Rh8 -63.1(2) . . . . ?
C267 C262 C263 Rh8 117.0(2) . . . . ?
C260 C259 C263 C262 0.0 . . . . ?
C264 C259 C263 C262 180.0 . . . . ?
Rh8 C259 C263 C262 -65.2(3) . . . . ?
C260 C259 C263 C268 -180.0 . . . . ?
C264 C259 C263 C268 0.0 . . . . ?
Rh8 C259 C263 C268 114.8(2) . . . . ?
C260 C259 C263 Rh8 65.2(2) . . . . ?
C264 C259 C263 Rh8 -114.9(3) . . . . ?
O27 S1 C169 F2 50(2) . . . . ?
O25 S1 C169 F2 173(2) . . . . ?
O26 S1 C169 F2 -65(2) . . . . ?
O27 S1 C169 F1 -64.4(19) . . . . ?
O25 S1 C169 F1 59.0(18) . . . . ?
O26 S1 C169 F1 -179.3(18) . . . . ?
O27 S1 C169 F3 173.5(19) . . . . ?
O25 S1 C169 F3 -63.1(19) . . . . ?
O26 S1 C169 F3 59(2) . . . . ?
O30 S2 C170 F4 59(3) . . . . ?
O29 S2 C170 F4 -61(2) . . . . ?
O28 S2 C170 F4 179.9(18) . . . . ?
O30 S2 C170 F6 -65(3) . . . . ?
O29 S2 C170 F6 174(2) . . . . ?
O28 S2 C170 F6 55(2) . . . . ?
O30 S2 C170 F5 170(3) . . . . ?
O29 S2 C170 F5 50(2) . . . . ?
O28 S2 C170 F5 -69.0(19) . . . . ?

_refine_diff_density_max         3.565
_refine_diff_density_min         -2.382
_refine_diff_density_rms         0.190



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Hetero-6
_database_code_depnum_ccdc_archive 'CCDC 1946053'
loop_
_audit_author_name
_audit_author_address
Lu
;Fudan university
China
;
_audit_update_record             
;
2019-08-08 deposited with the CCDC.	2020-10-05 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C103 H107.50 F12 N12.50 O21.50 Rh4 S7'
_chemical_formula_weight         2728.57

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0137 0.0067 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0583 0.0400 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0241 0.0134 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0389 0.0241 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -0.0161 2.8414 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.2925 0.4295 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 2/c'
_space_group_name_Hall           '-C 2yc'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   67.429(5)
_cell_length_b                   23.8798(16)
_cell_length_c                   29.2782(19)
_cell_angle_alpha                90
_cell_angle_beta                 103.301(3)
_cell_angle_gamma                90
_cell_volume                     45879(5)
_cell_formula_units_Z            16
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    9679
_cell_measurement_theta_min      3.28
_cell_measurement_theta_max      54.86

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.580
_exptl_crystal_F_000             22160
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.400
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_exptl_absorpt_coefficient_mu    4.400
_shelx_estimated_absorpt_T_min   0.272
_shelx_estimated_absorpt_T_max   0.473
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.367
_exptl_absorpt_correction_T_max  0.657
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     1.34138
_diffrn_radiation_type           GaK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            200019
_diffrn_reflns_av_unetI/netI     0.0440
_diffrn_reflns_av_R_equivalents  0.0540
_diffrn_reflns_limit_h_min       -82
_diffrn_reflns_limit_h_max       82
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_theta_min         3.141
_diffrn_reflns_theta_max         54.995
_diffrn_reflns_theta_full        53.594
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             43546
_reflns_number_gt                35704
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 Structure factors included contributions from the .fab file. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          
; 
 In the metallarectangles, some coordination sites were 
 occupied by two kinds of bipyridine ligand and they were 
 divided into two parts (50:50). One Cp* fragment and one 
 triflate anion were disordered and they were divided into 
 two parts (49:51 for Cp* and 66:34 for anion). 70 ISOR, 7 
 SIMU, 12 DELU and 76 DFIX instructions were used to restrain 
 anions, ligands and Cp* fragments so that there were 866 
 restraints in the data. 
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1736P)²+184.5583P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         43546
_refine_ls_number_parameters     2419
_refine_ls_number_restraints     866
_refine_ls_R_factor_all          0.1009
_refine_ls_R_factor_gt           0.0907
_refine_ls_wR_factor_ref         0.2944
_refine_ls_wR_factor_gt          0.2814
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_restrained_S_all      1.029
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.58583(2) -0.04642(2) 0.67989(2) 0.07660(16) Uani 1 1 d . . . . .
Rh2 Rh 0.53109(2) -0.08207(3) 0.40966(2) 0.08371(17) Uani 1 1 d . . . . .
Rh3 Rh 0.67671(2) 0.50399(3) 0.49638(2) 0.0949(2) Uani 1 1 d . . . . .
Rh4 Rh 0.69929(2) 0.31861(3) 0.28763(2) 0.09032(19) Uani 1 1 d . . . . .
Rh5 Rh 0.58627(2) 0.56005(3) 0.33216(2) 0.1069(2) Uani 1 1 d . . . . .
Rh6 Rh 0.53943(2) 0.59210(4) 0.55577(3) 0.1209(3) Uani 1 1 d . . . . .
Rh7 Rh 0.67025(2) -0.01576(2) 0.58495(2) 0.07713(15) Uani 1 1 d . . . . .
Rh8 Rh 0.70808(2) 0.16815(3) 0.81550(2) 0.1007(2) Uani 1 1 d . . . . .
N1 N 0.59544(8) 0.0327(2) 0.65899(17) 0.0699(12) Uani 1 1 d . . . . .
N4 N 0.66786(12) 0.4273(3) 0.5228(2) 0.0898(18) Uani 1 1 d . . . . .
N5 N 0.55172(10) -0.0174(3) 0.4021(2) 0.0847(16) Uani 1 1 d . . . . .
N8 N 0.68127(11) 0.2647(3) 0.3179(2) 0.0865(16) Uani 1 1 d . . . . .
N9 N 0.59488(12) 0.4776(3) 0.3577(2) 0.0906(17) Uani 1 1 d . . . . .
N12 N 0.66130(11) 0.0614(3) 0.5496(2) 0.0831(15) Uani 1 1 d . . . . .
N13 N 0.55874(17) 0.5245(4) 0.5850(3) 0.123(3) Uani 1 1 d . . . . .
N16 N 0.68733(15) 0.2181(3) 0.7683(3) 0.107(2) Uani 1 1 d . . . . .
O1 O 0.55862(7) -0.0259(2) 0.63084(16) 0.0788(11) Uani 1 1 d . . . . .
O2 O 0.59067(8) -0.0814(2) 0.61709(17) 0.0807(12) Uani 1 1 d . . . . .
O3 O 0.55610(8) -0.1134(2) 0.46177(17) 0.0864(13) Uani 1 1 d . . . . .
O4 O 0.52783(8) -0.0398(2) 0.47136(16) 0.0858(13) Uani 1 1 d . . . . .
O7 O 0.66309(9) 0.4778(2) 0.42713(19) 0.0901(14) Uani 1 1 d . . . . .
O8 O 0.69981(9) 0.4560(2) 0.47759(19) 0.0954(15) Uani 1 1 d . . . . .
O9 O 0.71297(9) 0.3439(2) 0.3566(2) 0.0942(15) Uani 1 1 d . . . . .
O10 O 0.67933(9) 0.3807(2) 0.30161(18) 0.0899(14) Uani 1 1 d . . . . .
O11 O 0.56046(11) 0.5429(3) 0.3565(2) 0.1111(19) Uani 1 1 d . . . . .
O12 O 0.59419(11) 0.5879(3) 0.4024(2) 0.1070(18) Uani 1 1 d . . . . .
O13 O 0.56504(12) 0.6172(3) 0.5296(2) 0.1113(18) Uani 1 1 d . . . . .
O14 O 0.53466(12) 0.5497(4) 0.4905(3) 0.124(2) Uani 1 1 d . . . . .
O15 O 0.66101(7) 0.0132(2) 0.64512(18) 0.0777(11) Uani 1 1 d . . . . .
O16 O 0.69590(8) 0.0290(2) 0.62228(17) 0.0791(11) Uani 1 1 d . . . . .
O17 O 0.71814(8) 0.1394(2) 0.75716(19) 0.0920(14) Uani 1 1 d . . . . .
O18 O 0.68679(8) 0.1037(3) 0.78827(17) 0.0904(14) Uani 1 1 d . . . . .
O21 O 0.80119(16) 0.4338(6) 0.5700(4) 0.188(5) Uani 1 1 d D . . . .
O22 O 0.7851(3) 0.3599(8) 0.5271(9) 0.315(11) Uani 1 1 d D U . . .
O23 O 0.7757(4) 0.4607(11) 0.5048(8) 0.381(14) Uani 1 1 d D U . . .
O24 O 0.6198(5) 0.4088(14) 0.1913(11) 0.392(16) Uani 1 1 d . U . . .
O25 O 0.6334(3) 0.3252(7) 0.2072(4) 0.240(7) Uani 1 1 d . U . . .
O26 O 0.5977(3) 0.3510(8) 0.1669(5) 0.282(9) Uani 1 1 d D U . . .
S3 S 0.60252(3) 0.19500(8) 0.33105(7) 0.0869(5) Uani 1 1 d . . . . .
S4 S 0.63107(3) 0.05572(9) 0.40049(7) 0.0874(5) Uani 1 1 d . . . . .
S7 S 0.60683(6) 0.30069(13) 0.69733(10) 0.1291(10) Uani 1 1 d . . . . .
S8 S 0.63508(7) 0.43244(16) 0.64602(11) 0.1458(12) Uani 1 1 d . U . . .
S9 S 0.78417(6) 0.4174(3) 0.53907(13) 0.1630(16) Uani 1 1 d D U . . .
S10 S 0.61630(16) 0.3636(4) 0.2042(3) 0.262(4) Uani 1 1 d D . . . .
F1 F 0.74637(16) 0.3977(9) 0.5322(6) 0.297(9) Uani 1 1 d D . . . .
F2 F 0.7689(2) 0.3712(9) 0.5993(7) 0.307(10) Uani 1 1 d D . . . .
F3 F 0.7589(2) 0.4552(7) 0.5822(6) 0.251(7) Uani 1 1 d D . . . .
F4 F 0.6224(2) 0.3599(9) 0.2919(4) 0.311(11) Uani 1 1 d . . . . .
F5 F 0.5919(2) 0.3826(7) 0.2572(5) 0.249(6) Uani 1 1 d . U . . .
F6 F 0.6044(3) 0.2965(6) 0.2535(7) 0.284(8) Uani 1 1 d . . . . .
S1 S 0.60926(13) 0.2824(6) 0.5696(7) 0.076(2) Uani 0.446(8) 1 d D U P A 1
S2 S 0.65796(11) 0.1794(3) 0.6300(2) 0.0739(17) Uani 0.446(8) 1 d D U P A 1
C18 C 0.5988(8) 0.2241(15) 0.5922(18) 0.064(4) Uani 0.446(8) 1 d . U P A 1
H18 H 0.5847 0.2190 0.5909 0.077 Uiso 0.446(8) 1 calc R U P A 1
C23 C 0.6648(3) 0.2355(14) 0.602(2) 0.086(6) Uani 0.446(8) 1 d D U P A 1
H23 H 0.6784 0.2377 0.5980 0.103 Uiso 0.446(8) 1 calc R U P A 1
N2 N 0.5998(5) 0.2342(10) 0.5894(12) 0.074(5) Uani 0.554(8) 1 d D U P A 2
H2 H 0.5865 0.2341 0.5857 0.089 Uiso 0.554(8) 1 calc R U P A 2
N3 N 0.6648(3) 0.2412(9) 0.6064(13) 0.088(5) Uani 0.554(8) 1 d D U P A 2
H3 H 0.6781 0.2439 0.6118 0.105 Uiso 0.554(8) 1 calc R U P A 2
O5 O 0.59850(17) 0.3171(4) 0.5539(4) 0.093(3) Uani 0.554(8) 1 d D U P A 2
O6 O 0.66259(19) 0.1571(5) 0.6367(5) 0.074(3) Uani 0.554(8) 1 d D U P A 2
C18' C 0.6108(3) 0.2779(17) 0.575(2) 0.068(6) Uani 0.554(8) 1 d D U P A 2
C23' C 0.6542(2) 0.1985(7) 0.6194(8) 0.084(5) Uani 0.554(8) 1 d D U P A 2
S5 S 0.60346(9) 0.2222(4) 0.4563(5) 0.0765(14) Uani 0.554(8) 1 d . U P A 1
S6 S 0.65354(9) 0.3106(2) 0.43320(17) 0.0787(14) Uani 0.554(8) 1 d . U P A 1
C102 C 0.5938(4) 0.2863(10) 0.4318(10) 0.085(5) Uani 0.554(8) 1 d . U P A 1
H102 H 0.5802 0.2993 0.4287 0.102 Uiso 0.554(8) 1 calc R U P A 1
C107 C 0.6636(4) 0.2507(14) 0.4637(13) 0.078(5) Uani 0.554(8) 1 d . U P A 1
H107 H 0.6777 0.2416 0.4725 0.093 Uiso 0.554(8) 1 calc R U P A 1
O19 O 0.5941(2) 0.1900(7) 0.4623(5) 0.108(4) Uani 0.446(8) 1 d D U P A 2
O20 O 0.6605(2) 0.3325(7) 0.4319(6) 0.086(4) Uani 0.446(8) 1 d D U P A 2
N10 N 0.5949(3) 0.2737(7) 0.4257(8) 0.072(4) Uani 0.446(8) 1 d D U P A 2
H10 H 0.5816 0.2758 0.4152 0.086 Uiso 0.446(8) 1 calc R U P A 2
N11 N 0.6584(4) 0.2479(13) 0.4636(14) 0.078(5) Uani 0.446(8) 1 d D U P A 2
H11 H 0.6717 0.2422 0.4709 0.094 Uiso 0.446(8) 1 calc R U P A 2
C202 C 0.6051(3) 0.2300(18) 0.453(3) 0.071(6) Uani 0.446(8) 1 d D U P A 2
C207 C 0.6497(3) 0.2943(10) 0.4394(10) 0.076(5) Uani 0.446(8) 1 d D U P A 2
C1 C 0.55793(11) -0.0415(3) 0.5890(2) 0.0742(16) Uani 1 1 d . . . . .
C2 C 0.57555(11) -0.0765(3) 0.5820(2) 0.0730(15) Uani 1 1 d . . . . .
C3 C 0.57487(12) -0.1010(3) 0.5383(3) 0.0798(17) Uani 1 1 d . . . . .
H3A H 0.5858 -0.1241 0.5340 0.096 Uiso 1 1 calc R U . . .
C4 C 0.55849(11) -0.0917(3) 0.5019(2) 0.0780(17) Uani 1 1 d . . . . .
C5 C 0.54216(11) -0.0511(3) 0.5075(2) 0.0804(18) Uani 1 1 d . . . . .
C6 C 0.54228(11) -0.0273(3) 0.5517(2) 0.0798(17) Uani 1 1 d . . . . .
H6 H 0.5319 -0.0022 0.5555 0.096 Uiso 1 1 calc R U . . .
C7 C 0.67461(13) 0.4480(3) 0.4075(3) 0.0835(19) Uani 1 1 d . . . . .
C8 C 0.69611(14) 0.4327(4) 0.4381(3) 0.089(2) Uani 1 1 d . . . . .
C9 C 0.70826(14) 0.3969(4) 0.4220(3) 0.100(2) Uani 1 1 d . . . . .
H9 H 0.7207 0.3848 0.4421 0.119 Uiso 1 1 calc R U . . .
C10 C 0.70255(13) 0.3773(3) 0.3750(3) 0.087(2) Uani 1 1 d . . . . .
C11 C 0.68278(13) 0.3969(3) 0.3437(3) 0.0819(18) Uani 1 1 d . . . . .
C12 C 0.66933(13) 0.4305(3) 0.3607(3) 0.0837(19) Uani 1 1 d . . . . .
H12 H 0.6567 0.4414 0.3408 0.100 Uiso 1 1 calc R U . . .
C13 C 0.61441(11) 0.0404(3) 0.6522(2) 0.0720(15) Uani 1 1 d . . . . .
H13 H 0.6236 0.0098 0.6576 0.086 Uiso 1 1 calc R U . . .
C14 C 0.62091(11) 0.0902(3) 0.6378(2) 0.0740(16) Uani 1 1 d . . . . .
H14 H 0.6344 0.0936 0.6335 0.089 Uiso 1 1 calc R U . . .
C15 C 0.60767(11) 0.1362(3) 0.6294(2) 0.0703(15) Uani 1 1 d . . . . .
C16 C 0.58807(11) 0.1270(3) 0.6384(3) 0.0792(17) Uani 1 1 d . . . . .
H16 H 0.5785 0.1568 0.6345 0.095 Uiso 1 1 calc R U . . .
C17 C 0.58297(12) 0.0764(3) 0.6526(2) 0.0822(18) Uani 1 1 d . . . . .
H17 H 0.5698 0.0718 0.6583 0.099 Uiso 1 1 calc R U . . .
C19 C 0.61328(11) 0.1882(3) 0.6114(2) 0.0701(15) Uani 1 1 d . . . . .
C20 C 0.63308(11) 0.2076(3) 0.6086(2) 0.0734(16) Uani 1 1 d D . . . .
C21 C 0.63197(12) 0.2589(3) 0.5864(2) 0.086(2) Uani 1 1 d D . . . .
C22 C 0.65138(14) 0.2785(3) 0.5838(2) 0.090(2) Uani 1 1 d D . . . .
C24 C 0.64828(17) 0.4137(3) 0.5191(3) 0.096(2) Uani 1 1 d . . . . .
H24 H 0.6381 0.4383 0.5021 0.115 Uiso 1 1 calc R U . . .
C25 C 0.64209(15) 0.3666(3) 0.5382(3) 0.091(2) Uani 1 1 d . . . . .
H25 H 0.6280 0.3590 0.5350 0.109 Uiso 1 1 calc R U . . .
C26 C 0.65727(15) 0.3288(3) 0.5633(3) 0.091(2) Uani 1 1 d . . . . .
C27 C 0.67733(17) 0.3436(4) 0.5664(3) 0.102(2) Uani 1 1 d . . . . .
H27 H 0.6880 0.3201 0.5827 0.123 Uiso 1 1 calc R U . . .
C28 C 0.68187(17) 0.3924(4) 0.5460(3) 0.105(3) Uani 1 1 d . . . . .
H28 H 0.6958 0.4016 0.5487 0.125 Uiso 1 1 calc R U . . .
C29 C 0.57096(13) -0.0306(3) 0.4022(3) 0.0865(19) Uani 1 1 d . . . . .
H29 H 0.5756 -0.0678 0.4097 0.104 Uiso 1 1 calc R U . . .
C30 C 0.58432(13) 0.0090(3) 0.3918(3) 0.0852(19) Uani 1 1 d . . . . .
H30 H 0.5980 -0.0010 0.3922 0.102 Uiso 1 1 calc R U . . .
C31 C 0.57760(12) 0.0631(3) 0.3806(2) 0.0756(16) Uani 1 1 d . . . . .
C32 C 0.55744(15) 0.0745(4) 0.3814(3) 0.097(2) Uani 1 1 d . . . . .
H32 H 0.5522 0.1112 0.3742 0.116 Uiso 1 1 calc R U . . .
C33 C 0.54532(14) 0.0351(4) 0.3922(3) 0.095(2) Uani 1 1 d . . . . .
H33 H 0.5317 0.0446 0.3929 0.113 Uiso 1 1 calc R U . . .
C34 C 0.58407(13) 0.1545(3) 0.3437(3) 0.0834(18) Uani 1 1 d . . . . .
H34 H 0.5701 0.1646 0.3357 0.100 Uiso 1 1 calc R U . . .
C35 C 0.59095(11) 0.1054(3) 0.3666(2) 0.0740(16) Uani 1 1 d . . . . .
C36 C 0.61259(12) 0.1023(3) 0.3735(2) 0.0745(16) Uani 1 1 d . . . . .
C37 C 0.62117(11) 0.1484(3) 0.3559(2) 0.0743(16) Uani 1 1 d . . . . .
C38 C 0.64303(11) 0.1460(3) 0.3653(2) 0.0752(16) Uani 1 1 d . . . . .
C39 C 0.64978(13) 0.0987(3) 0.3892(2) 0.0845(19) Uani 1 1 d . . . . .
H39 H 0.6639 0.0899 0.3990 0.101 Uiso 1 1 calc R U . . .
C40 C 0.66137(14) 0.2656(4) 0.3028(3) 0.093(2) Uani 1 1 d . . . . .
H40 H 0.6556 0.2932 0.2803 0.112 Uiso 1 1 calc R U . . .
C41 C 0.64841(12) 0.2295(3) 0.3171(3) 0.0862(19) Uani 1 1 d . . . . .
H41 H 0.6341 0.2325 0.3046 0.103 Uiso 1 1 calc R U . . .
C42 C 0.65605(12) 0.1882(3) 0.3503(2) 0.0787(17) Uani 1 1 d . . . . .
C43 C 0.67727(12) 0.1880(3) 0.3670(2) 0.0814(18) Uani 1 1 d . . . . .
H43 H 0.6835 0.1614 0.3900 0.098 Uiso 1 1 calc R U . . .
C44 C 0.68911(12) 0.2256(3) 0.3505(3) 0.0849(19) Uani 1 1 d . . . . .
H44 H 0.7035 0.2243 0.3623 0.102 Uiso 1 1 calc R U . . .
C45 C 0.60607(15) -0.0542(5) 0.7474(3) 0.103(3) Uani 1 1 d . . . . .
C46 C 0.58775(18) -0.0294(5) 0.7522(3) 0.107(3) Uani 1 1 d D . . . .
C47 C 0.57215(16) -0.0705(5) 0.7358(3) 0.109(3) Uani 1 1 d . . . . .
C48 C 0.58066(18) -0.1179(5) 0.7185(4) 0.122(4) Uani 1 1 d . . . . .
C49 C 0.60251(15) -0.1070(6) 0.7274(3) 0.115(3) Uani 1 1 d . . . . .
C50 C 0.62660(18) -0.0262(7) 0.7625(4) 0.148(5) Uani 1 1 d . . . . .
H50A H 0.6317 -0.0310 0.7964 0.222 Uiso 1 1 calc R U . . .
H50B H 0.6252 0.0138 0.7551 0.222 Uiso 1 1 calc R U . . .
H50C H 0.6362 -0.0432 0.7460 0.222 Uiso 1 1 calc R U . . .
C51 C 0.5847(3) 0.0273(6) 0.7728(4) 0.174(7) Uani 1 1 d D . . . .
H51A H 0.5927 0.0292 0.8053 0.261 Uiso 1 1 calc R U . . .
H51B H 0.5702 0.0326 0.7722 0.261 Uiso 1 1 calc R U . . .
H51C H 0.5892 0.0568 0.7543 0.261 Uiso 1 1 calc R U . . .
C52 C 0.55039(16) -0.0629(8) 0.7347(4) 0.159(6) Uani 1 1 d . . . . .
H52A H 0.5422 -0.0812 0.7067 0.239 Uiso 1 1 calc R U . . .
H52B H 0.5472 -0.0228 0.7338 0.239 Uiso 1 1 calc R U . . .
H52C H 0.5473 -0.0796 0.7628 0.239 Uiso 1 1 calc R U . . .
C53 C 0.5704(3) -0.1724(6) 0.6975(6) 0.183(7) Uani 1 1 d . . . . .
H53A H 0.5616 -0.1865 0.7172 0.275 Uiso 1 1 calc R U . . .
H53B H 0.5809 -0.2003 0.6959 0.275 Uiso 1 1 calc R U . . .
H53C H 0.5622 -0.1651 0.6658 0.275 Uiso 1 1 calc R U . . .
C54 C 0.6173(2) -0.1470(6) 0.7145(5) 0.139(4) Uani 1 1 d . . . . .
H54A H 0.6312 -0.1350 0.7289 0.208 Uiso 1 1 calc R U . . .
H54B H 0.6154 -0.1479 0.6803 0.208 Uiso 1 1 calc R U . . .
H54C H 0.6150 -0.1845 0.7258 0.208 Uiso 1 1 calc R U . . .
C55 C 0.51920(15) -0.0936(4) 0.3359(3) 0.100(2) Uani 1 1 d . . . . .
C56 C 0.52662(18) -0.1455(4) 0.3584(3) 0.111(3) Uani 1 1 d . . . . .
C57 C 0.51417(18) -0.1572(4) 0.3923(3) 0.108(3) Uani 1 1 d . . . . .
C58 C 0.50052(16) -0.1143(4) 0.3920(3) 0.104(3) Uani 1 1 d . . . . .
C59 C 0.50263(15) -0.0730(4) 0.3577(3) 0.097(2) Uani 1 1 d . . . . .
C60 C 0.5268(2) -0.0670(5) 0.2994(3) 0.128(4) Uani 1 1 d . . . . .
H60A H 0.5172 -0.0730 0.2691 0.192 Uiso 1 1 calc R U . . .
H60B H 0.5401 -0.0832 0.2983 0.192 Uiso 1 1 calc R U . . .
H60C H 0.5284 -0.0268 0.3057 0.192 Uiso 1 1 calc R U . . .
C61 C 0.5423(2) -0.1815(7) 0.3480(5) 0.153(5) Uani 1 1 d . . . . .
H61A H 0.5359 -0.2112 0.3264 0.229 Uiso 1 1 calc R U . . .
H61B H 0.5501 -0.1984 0.3771 0.229 Uiso 1 1 calc R U . . .
H61C H 0.5514 -0.1595 0.3334 0.229 Uiso 1 1 calc R U . . .
C62 C 0.5163(3) -0.2081(6) 0.4264(5) 0.165(6) Uani 1 1 d . . . . .
H62A H 0.5156 -0.1950 0.4577 0.247 Uiso 1 1 calc R U . . .
H62B H 0.5294 -0.2266 0.4281 0.247 Uiso 1 1 calc R U . . .
H62C H 0.5052 -0.2347 0.4148 0.247 Uiso 1 1 calc R U . . .
C63 C 0.48539(19) -0.1113(5) 0.4215(4) 0.128(4) Uani 1 1 d . . . . .
H63A H 0.4826 -0.0720 0.4274 0.191 Uiso 1 1 calc R U . . .
H63B H 0.4908 -0.1305 0.4514 0.191 Uiso 1 1 calc R U . . .
H63C H 0.4727 -0.1296 0.4051 0.191 Uiso 1 1 calc R U . . .
C64 C 0.49062(17) -0.0240(6) 0.3452(4) 0.128(4) Uani 1 1 d . . . . .
H64A H 0.4767 -0.0348 0.3298 0.192 Uiso 1 1 calc R U . . .
H64B H 0.4964 -0.0013 0.3237 0.192 Uiso 1 1 calc R U . . .
H64C H 0.4905 -0.0023 0.3736 0.192 Uiso 1 1 calc R U . . .
C65 C 0.6680(2) 0.5559(4) 0.5470(4) 0.111(3) Uani 1 1 d D . . . .
C66 C 0.68874(18) 0.5542(4) 0.5561(3) 0.111(3) Uani 1 1 d D . . . .
C67 C 0.6959(2) 0.5748(5) 0.5208(5) 0.141(5) Uani 1 1 d D U . . .
C68 C 0.6792(2) 0.5912(4) 0.4853(4) 0.137(5) Uani 1 1 d D U . . .
C69 C 0.6614(2) 0.5797(4) 0.5015(5) 0.141(4) Uani 1 1 d D . . . .
C70 C 0.6564(3) 0.5362(6) 0.5813(6) 0.184(8) Uani 1 1 d . . . . .
H70A H 0.6657 0.5187 0.6082 0.276 Uiso 1 1 calc R U . . .
H70B H 0.6461 0.5088 0.5662 0.276 Uiso 1 1 calc R U . . .
H70C H 0.6496 0.5682 0.5922 0.276 Uiso 1 1 calc R U . . .
C71 C 0.7019(3) 0.5327(6) 0.6013(5) 0.170(6) Uani 1 1 d D . . . .
H71A H 0.7124 0.5077 0.5945 0.255 Uiso 1 1 calc R U . . .
H71B H 0.6934 0.5121 0.6187 0.255 Uiso 1 1 calc R U . . .
H71C H 0.7084 0.5644 0.6202 0.255 Uiso 1 1 calc R U . . .
C72 C 0.7189(3) 0.5793(8) 0.5149(8) 0.207(8) Uani 1 1 d . U . . .
H72A H 0.7244 0.6165 0.5249 0.311 Uiso 1 1 calc R U . . .
H72B H 0.7192 0.5734 0.4820 0.311 Uiso 1 1 calc R U . . .
H72C H 0.7273 0.5507 0.5344 0.311 Uiso 1 1 calc R U . . .
C73 C 0.6815(4) 0.6153(6) 0.4396(6) 0.221(9) Uani 1 1 d . U . . .
H73A H 0.6920 0.6442 0.4455 0.331 Uiso 1 1 calc R U . . .
H73B H 0.6685 0.6318 0.4230 0.331 Uiso 1 1 calc R U . . .
H73C H 0.6853 0.5855 0.4203 0.331 Uiso 1 1 calc R U . . .
C74 C 0.6415(4) 0.5932(9) 0.4718(10) 0.31(2) Uani 1 1 d . . . . .
H74A H 0.6324 0.5609 0.4703 0.469 Uiso 1 1 calc R U . . .
H74B H 0.6430 0.6024 0.4401 0.469 Uiso 1 1 calc R U . . .
H74C H 0.6357 0.6254 0.4849 0.469 Uiso 1 1 calc R U . . .
C75 C 0.69361(17) 0.2830(4) 0.2182(3) 0.107(3) Uani 1 1 d D . . . .
C76 C 0.6965(3) 0.3403(5) 0.2154(4) 0.135(4) Uani 1 1 d . . . . .
C77 C 0.7167(2) 0.3546(5) 0.2437(4) 0.133(4) Uani 1 1 d . . . . .
C78 C 0.72668(19) 0.3009(5) 0.2646(4) 0.123(4) Uani 1 1 d D . . . .
C79 C 0.71198(16) 0.2587(4) 0.2477(3) 0.104(3) Uani 1 1 d D . . . .
C80 C 0.67485(19) 0.2517(5) 0.1961(4) 0.126(4) Uani 1 1 d . . . . .
H80A H 0.6629 0.2743 0.1974 0.189 Uiso 1 1 calc R U . . .
H80B H 0.6744 0.2164 0.2130 0.189 Uiso 1 1 calc R U . . .
H80C H 0.6749 0.2436 0.1633 0.189 Uiso 1 1 calc R U . . .
C81 C 0.6827(3) 0.3813(6) 0.1915(4) 0.190(8) Uani 1 1 d . . . . .
H81A H 0.6808 0.3761 0.1575 0.285 Uiso 1 1 calc R U . . .
H81B H 0.6883 0.4187 0.2001 0.285 Uiso 1 1 calc R U . . .
H81C H 0.6696 0.3774 0.2002 0.285 Uiso 1 1 calc R U . . .
C82 C 0.7277(3) 0.4109(5) 0.2531(7) 0.190(8) Uani 1 1 d . . . . .
H82A H 0.7183 0.4410 0.2396 0.284 Uiso 1 1 calc R U . . .
H82B H 0.7394 0.4112 0.2386 0.284 Uiso 1 1 calc R U . . .
H82C H 0.7324 0.4165 0.2870 0.284 Uiso 1 1 calc R U . . .
C83 C 0.74723(18) 0.2957(7) 0.2977(5) 0.157(6) Uani 1 1 d D . . . .
H83A H 0.7516 0.2565 0.2994 0.235 Uiso 1 1 calc R U . . .
H83B H 0.7464 0.3086 0.3289 0.235 Uiso 1 1 calc R U . . .
H83C H 0.7571 0.3188 0.2863 0.235 Uiso 1 1 calc R U . . .
C84 C 0.71612(18) 0.1991(4) 0.2587(4) 0.117(3) Uani 1 1 d . . . . .
H84A H 0.7238 0.1833 0.2371 0.176 Uiso 1 1 calc R U . . .
H84B H 0.7032 0.1790 0.2553 0.176 Uiso 1 1 calc R U . . .
H84C H 0.7241 0.1954 0.2910 0.176 Uiso 1 1 calc R U . . .
C85 C 0.56100(15) 0.5547(4) 0.3984(3) 0.098(2) Uani 1 1 d . . . . .
C86 C 0.57999(18) 0.5832(4) 0.4245(3) 0.104(3) Uani 1 1 d . . . . .
C87 C 0.58166(18) 0.6051(4) 0.4702(4) 0.110(3) Uani 1 1 d . . . . .
H87 H 0.5935 0.6246 0.4860 0.132 Uiso 1 1 calc R U . . .
C88 C 0.56558(17) 0.5973(4) 0.4907(3) 0.104(3) Uani 1 1 d . . . . .
C89 C 0.54764(19) 0.5611(5) 0.4676(3) 0.114(3) Uani 1 1 d . . . . .
C90 C 0.54598(17) 0.5403(4) 0.4207(3) 0.107(3) Uani 1 1 d . . . . .
H90 H 0.5348 0.5174 0.4058 0.129 Uiso 1 1 calc R U . . .
C91 C 0.69389(11) 0.0514(3) 0.6604(3) 0.0765(16) Uani 1 1 d . . . . .
C92 C 0.67434(10) 0.0392(3) 0.6743(2) 0.0722(15) Uani 1 1 d . . . . .
C93 C 0.67226(12) 0.0570(3) 0.7193(3) 0.0801(18) Uani 1 1 d . . . . .
H93 H 0.6601 0.0485 0.7292 0.096 Uiso 1 1 calc R U . . .
C94 C 0.68723(11) 0.0859(3) 0.7483(2) 0.0768(17) Uani 1 1 d . . . . .
C95 C 0.70577(11) 0.1061(3) 0.7300(3) 0.0824(18) Uani 1 1 d . . . . .
C96 C 0.70872(12) 0.0854(3) 0.6881(3) 0.0823(18) Uani 1 1 d . . . . .
H96 H 0.7208 0.0944 0.6782 0.099 Uiso 1 1 calc R U . . .
C97 C 0.61333(16) 0.4647(4) 0.3795(3) 0.094(2) Uani 1 1 d . . . . .
H97 H 0.6235 0.4929 0.3829 0.113 Uiso 1 1 calc R U . . .
C98 C 0.61922(13) 0.4112(3) 0.3986(2) 0.0844(19) Uani 1 1 d . . . . .
H98 H 0.6330 0.4039 0.4137 0.101 Uiso 1 1 calc R U . . .
C99 C 0.60437(13) 0.3689(3) 0.3950(2) 0.0817(18) Uani 1 1 d . . . . .
C100 C 0.58435(14) 0.3826(4) 0.3706(3) 0.097(2) Uani 1 1 d . . . . .
H100 H 0.5737 0.3557 0.3661 0.116 Uiso 1 1 calc R U . . .
C101 C 0.58067(16) 0.4369(4) 0.3532(3) 0.104(3) Uani 1 1 d . . . . .
H101 H 0.5672 0.4459 0.3370 0.124 Uiso 1 1 calc R U . . .
C103 C 0.60903(13) 0.3146(3) 0.4177(2) 0.0822(19) Uani 1 1 d D . . . .
C104 C 0.62814(12) 0.2902(3) 0.4348(2) 0.0741(16) Uani 1 1 d D . . . .
C105 C 0.62706(12) 0.2387(3) 0.4567(2) 0.0788(17) Uani 1 1 d D . . . .
C106 C 0.64604(14) 0.2142(3) 0.4744(2) 0.086(2) Uani 1 1 d . . . . .
C108 C 0.64173(12) 0.0798(3) 0.5375(2) 0.0787(17) Uani 1 1 d . . . . .
H108 H 0.6313 0.0582 0.5461 0.094 Uiso 1 1 calc R U . . .
C109 C 0.63661(13) 0.1289(3) 0.5131(2) 0.0837(18) Uani 1 1 d . . . . .
H109 H 0.6227 0.1402 0.5050 0.100 Uiso 1 1 calc R U . . .
C110 C 0.65124(13) 0.1623(3) 0.5000(2) 0.0787(17) Uani 1 1 d . . . . .
C111 C 0.67113(14) 0.1425(3) 0.5120(3) 0.090(2) Uani 1 1 d . . . . .
H111 H 0.6817 0.1632 0.5030 0.108 Uiso 1 1 calc R U . . .
C112 C 0.67581(14) 0.0928(3) 0.5369(3) 0.090(2) Uani 1 1 d . . . . .
H112 H 0.6896 0.0807 0.5452 0.108 Uiso 1 1 calc R U . . .
C113 C 0.5778(2) 0.5328(5) 0.6037(4) 0.120(3) Uani 1 1 d . . . . .
H113 H 0.5831 0.5696 0.6029 0.144 Uiso 1 1 calc R U . . .
C114 C 0.59104(18) 0.4904(5) 0.6251(3) 0.113(3) Uani 1 1 d . . . . .
H114 H 0.6051 0.4977 0.6377 0.136 Uiso 1 1 calc R U . . .
C115 C 0.5829(2) 0.4376(5) 0.6272(3) 0.114(3) Uani 1 1 d . . . . .
C116 C 0.5619(2) 0.4282(5) 0.6063(4) 0.131(4) Uani 1 1 d . . . . .
H116 H 0.5559 0.3925 0.6070 0.157 Uiso 1 1 calc R U . . .
C117 C 0.5512(3) 0.4723(6) 0.5856(4) 0.148(5) Uani 1 1 d . . . . .
H117 H 0.5373 0.4663 0.5704 0.178 Uiso 1 1 calc R U . . .
C118 C 0.58833(17) 0.3430(4) 0.6698(3) 0.101(2) Uani 1 1 d . . . . .
H118 H 0.5743 0.3351 0.6668 0.121 Uiso 1 1 calc R U . . .
C119 C 0.59513(19) 0.3904(5) 0.6517(3) 0.117(3) Uani 1 1 d D . . . .
C120 C 0.61688(19) 0.3913(4) 0.6608(3) 0.109(3) Uani 1 1 d D U . . .
C121 C 0.62547(19) 0.3425(4) 0.6854(3) 0.108(3) Uani 1 1 d . . . . .
C122 C 0.6470(2) 0.3400(4) 0.6918(3) 0.114(3) Uani 1 1 d . . . . .
C123 C 0.6539(2) 0.3850(5) 0.6729(4) 0.120(3) Uani 1 1 d . . . . .
H123 H 0.6680 0.3907 0.6740 0.145 Uiso 1 1 calc R U . . .
C124 C 0.6675(2) 0.2183(4) 0.7682(4) 0.118(3) Uani 1 1 d . . . . .
H124 H 0.6628 0.1909 0.7867 0.142 Uiso 1 1 calc R U . . .
C125 C 0.65337(19) 0.2553(5) 0.7431(4) 0.119(3) Uani 1 1 d . . . . .
H125 H 0.6394 0.2526 0.7441 0.143 Uiso 1 1 calc R U . . .
C126 C 0.65983(19) 0.2961(4) 0.7166(3) 0.109(3) Uani 1 1 d . . . . .
C127 C 0.6809(2) 0.2946(5) 0.7158(4) 0.122(3) Uani 1 1 d . . . . .
H127 H 0.6861 0.3209 0.6971 0.146 Uiso 1 1 calc R U . . .
C128 C 0.6942(2) 0.2553(5) 0.7418(4) 0.121(3) Uani 1 1 d . . . . .
H128 H 0.7081 0.2551 0.7406 0.145 Uiso 1 1 calc R U . . .
C129 C 0.6032(2) 0.5658(5) 0.2782(4) 0.125(4) Uani 1 1 d D U . . .
C130 C 0.5814(3) 0.5549(7) 0.2588(4) 0.143(5) Uani 1 1 d . . . . .
C131 C 0.5703(3) 0.6015(8) 0.2687(5) 0.148(5) Uani 1 1 d . U . . .
C132 C 0.5834(3) 0.6367(9) 0.2941(6) 0.159(6) Uani 1 1 d . . . . .
C133 C 0.6036(2) 0.6179(5) 0.3018(4) 0.133(4) Uani 1 1 d D . . . .
C134 C 0.6196(3) 0.5268(7) 0.2736(5) 0.161(5) Uani 1 1 d . U . . .
H13A H 0.6145 0.5013 0.2473 0.242 Uiso 1 1 calc R U . . .
H13B H 0.6239 0.5051 0.3026 0.242 Uiso 1 1 calc R U . . .
H13C H 0.6312 0.5481 0.2678 0.242 Uiso 1 1 calc R U . . .
C135 C 0.5740(4) 0.5088(8) 0.2327(5) 0.210(10) Uani 1 1 d . . . . .
H13D H 0.5610 0.4976 0.2393 0.315 Uiso 1 1 calc R U . . .
H13E H 0.5838 0.4780 0.2407 0.315 Uiso 1 1 calc R U . . .
H13F H 0.5720 0.5177 0.1993 0.315 Uiso 1 1 calc R U . . .
C136 C 0.5479(3) 0.6063(12) 0.2550(8) 0.255(13) Uani 1 1 d . U . . .
H13G H 0.5422 0.5737 0.2360 0.383 Uiso 1 1 calc R U . . .
H13H H 0.5425 0.6077 0.2833 0.383 Uiso 1 1 calc R U . . .
H13I H 0.5441 0.6405 0.2366 0.383 Uiso 1 1 calc R U . . .
C137 C 0.5777(3) 0.6912(6) 0.3111(7) 0.203(8) Uani 1 1 d . . . . .
H13J H 0.5634 0.6904 0.3125 0.304 Uiso 1 1 calc R U . . .
H13K H 0.5799 0.7209 0.2896 0.304 Uiso 1 1 calc R U . . .
H13L H 0.5862 0.6986 0.3425 0.304 Uiso 1 1 calc R U . . .
C138 C 0.6220(3) 0.6473(7) 0.3277(6) 0.186(7) Uani 1 1 d D . . . .
H13M H 0.6210 0.6537 0.3602 0.279 Uiso 1 1 calc R U . . .
H13N H 0.6232 0.6834 0.3126 0.279 Uiso 1 1 calc R U . . .
H13O H 0.6341 0.6244 0.3276 0.279 Uiso 1 1 calc R U . . .
C139 C 0.51896(18) 0.6610(5) 0.5472(4) 0.119(3) Uani 1 1 d D . . . .
C140 C 0.5087(2) 0.6113(7) 0.5510(6) 0.153(5) Uani 1 1 d D . . . .
C141 C 0.5144(3) 0.5839(7) 0.5922(6) 0.183(7) Uani 1 1 d D U . . .
C142 C 0.5323(3) 0.6205(9) 0.6177(5) 0.166(5) Uani 1 1 d . U . . .
C143 C 0.5342(2) 0.6654(7) 0.5897(5) 0.144(4) Uani 1 1 d D U . . .
C144 C 0.5146(3) 0.6956(8) 0.5053(6) 0.194(8) Uani 1 1 d D . . . .
H14A H 0.5065 0.6741 0.4790 0.292 Uiso 1 1 calc R U . . .
H14B H 0.5274 0.7074 0.4978 0.292 Uiso 1 1 calc R U . . .
H14C H 0.5069 0.7287 0.5108 0.292 Uiso 1 1 calc R U . . .
C145 C 0.4905(3) 0.5891(10) 0.5113(7) 0.213(9) Uani 1 1 d . . . . .
H14D H 0.4776 0.5951 0.5206 0.319 Uiso 1 1 calc R U . . .
H14E H 0.4923 0.5490 0.5065 0.319 Uiso 1 1 calc R U . . .
H14F H 0.4903 0.6093 0.4820 0.319 Uiso 1 1 calc R U . . .
C146 C 0.5081(4) 0.5264(9) 0.6067(8) 0.237(10) Uani 1 1 d D U . . .
H14G H 0.4932 0.5242 0.5998 0.355 Uiso 1 1 calc R U . . .
H14H H 0.5136 0.5210 0.6404 0.355 Uiso 1 1 calc R U . . .
H14I H 0.5134 0.4973 0.5892 0.355 Uiso 1 1 calc R U . . .
C147 C 0.5444(3) 0.6090(11) 0.6669(6) 0.230(10) Uani 1 1 d . U . . .
H14J H 0.5398 0.5740 0.6783 0.346 Uiso 1 1 calc R U . . .
H14K H 0.5589 0.6058 0.6667 0.346 Uiso 1 1 calc R U . . .
H14L H 0.5426 0.6399 0.6876 0.346 Uiso 1 1 calc R U . . .
C148 C 0.5484(3) 0.7067(10) 0.6050(7) 0.207(7) Uani 1 1 d . U . . .
H14M H 0.5475 0.7349 0.5803 0.311 Uiso 1 1 calc R U . . .
H14N H 0.5457 0.7243 0.6332 0.311 Uiso 1 1 calc R U . . .
H14O H 0.5620 0.6902 0.6123 0.311 Uiso 1 1 calc R U . . .
C149 C 0.66770(16) -0.0655(4) 0.5219(3) 0.098(2) Uani 1 1 d . . . . .
C150 C 0.68592(15) -0.0793(3) 0.5564(3) 0.095(2) Uani 1 1 d D . . . .
C151 C 0.68012(17) -0.0991(3) 0.5972(3) 0.100(2) Uani 1 1 d D . . . .
C152 C 0.65909(17) -0.0992(4) 0.5892(4) 0.106(3) Uani 1 1 d D . . . .
C153 C 0.65104(16) -0.0764(4) 0.5439(4) 0.108(3) Uani 1 1 d D . . . .
C154 C 0.6674(2) -0.0435(5) 0.4749(4) 0.134(4) Uani 1 1 d . . . . .
H15A H 0.6808 -0.0282 0.4744 0.201 Uiso 1 1 calc R U . . .
H15B H 0.6571 -0.0138 0.4672 0.201 Uiso 1 1 calc R U . . .
H15C H 0.6640 -0.0738 0.4518 0.201 Uiso 1 1 calc R U . . .
C155 C 0.70699(18) -0.0720(5) 0.5488(5) 0.125(3) Uani 1 1 d . . . . .
H15D H 0.7132 -0.1088 0.5468 0.187 Uiso 1 1 calc R U . . .
H15E H 0.7153 -0.0509 0.5752 0.187 Uiso 1 1 calc R U . . .
H15F H 0.7063 -0.0513 0.5196 0.187 Uiso 1 1 calc R U . . .
C156 C 0.6954(2) -0.1197(5) 0.6435(4) 0.135(4) Uani 1 1 d . . . . .
H15G H 0.6907 -0.1067 0.6710 0.202 Uiso 1 1 calc R U . . .
H15H H 0.7090 -0.1043 0.6446 0.202 Uiso 1 1 calc R U . . .
H15I H 0.6961 -0.1607 0.6437 0.202 Uiso 1 1 calc R U . . .
C157 C 0.6462(2) -0.1162(5) 0.6216(5) 0.131(4) Uani 1 1 d . . . . .
H15J H 0.6447 -0.1570 0.6212 0.197 Uiso 1 1 calc R U . . .
H15K H 0.6327 -0.0989 0.6116 0.197 Uiso 1 1 calc R U . . .
H15L H 0.6526 -0.1038 0.6535 0.197 Uiso 1 1 calc R U . . .
C158 C 0.62902(17) -0.0684(5) 0.5190(5) 0.139(4) Uani 1 1 d . . . . .
H15M H 0.6244 -0.1005 0.4985 0.208 Uiso 1 1 calc R U . . .
H15N H 0.6277 -0.0341 0.5001 0.208 Uiso 1 1 calc R U . . .
H15O H 0.6207 -0.0653 0.5422 0.208 Uiso 1 1 calc R U . . .
C159 C 0.73335(16) 0.1641(4) 0.8666(2) 0.126(5) Uani 0.51(3) 1 d G U P B 1
C160 C 0.73236(11) 0.2208(3) 0.8540(2) 0.126(4) Uani 0.51(3) 1 d G U P B 1
C161 C 0.71453(13) 0.2433(6) 0.8634(4) 0.135(6) Uani 0.51(3) 1 d G U P B 1
C162 C 0.70450(13) 0.2005(9) 0.8819(3) 0.117(7) Uani 0.51(3) 1 d G U P B 1
C163 C 0.7161(2) 0.1515(7) 0.8839(2) 0.129(9) Uani 0.51(3) 1 d G U P B 1
C164 C 0.7498(2) 0.1242(4) 0.8625(4) 0.213(13) Uani 0.51(3) 1 d G U P B 1
H16A H 0.7468 0.0872 0.8738 0.320 Uiso 0.51(3) 1 calc R U P B 1
H16B H 0.7506 0.1214 0.8295 0.320 Uiso 0.51(3) 1 calc R U P B 1
H16C H 0.7629 0.1376 0.8814 0.320 Uiso 0.51(3) 1 calc R U P B 1
C165 C 0.7476(2) 0.2517(5) 0.8340(4) 0.174(11) Uani 0.51(3) 1 d G U P B 1
H16D H 0.7474 0.2915 0.8422 0.261 Uiso 0.51(3) 1 calc R U P B 1
H16E H 0.7442 0.2476 0.7997 0.261 Uiso 0.51(3) 1 calc R U P B 1
H16F H 0.7612 0.2364 0.8468 0.261 Uiso 0.51(3) 1 calc R U P B 1
C166 C 0.7075(3) 0.3023(8) 0.8552(6) 0.26(2) Uani 0.51(3) 1 d G U P B 1
H16G H 0.6946 0.3070 0.8648 0.395 Uiso 0.51(3) 1 calc R U P B 1
H16H H 0.7177 0.3275 0.8736 0.395 Uiso 0.51(3) 1 calc R U P B 1
H16I H 0.7055 0.3113 0.8218 0.395 Uiso 0.51(3) 1 calc R U P B 1
C167 C 0.68491(18) 0.2061(14) 0.8968(5) 0.156(12) Uani 0.51(3) 1 d G U P B 1
H16J H 0.6800 0.2447 0.8917 0.234 Uiso 0.51(3) 1 calc R U P B 1
H16K H 0.6748 0.1805 0.8784 0.234 Uiso 0.51(3) 1 calc R U P B 1
H16L H 0.6871 0.1967 0.9302 0.234 Uiso 0.51(3) 1 calc R U P B 1
C168 C 0.7111(4) 0.0960(9) 0.9013(3) 0.219(18) Uani 0.51(3) 1 d G U P B 1
H16M H 0.7037 0.0734 0.8749 0.328 Uiso 0.51(3) 1 calc R U P B 1
H16N H 0.7025 0.1012 0.9239 0.328 Uiso 0.51(3) 1 calc R U P B 1
H16O H 0.7237 0.0767 0.9167 0.328 Uiso 0.51(3) 1 calc R U P B 1
C259 C 0.73773(17) 0.1593(3) 0.8645(3) 0.120(5) Uani 0.49(3) 1 d G U P B 2
C260 C 0.73182(11) 0.2157(3) 0.8564(2) 0.124(5) Uani 0.49(3) 1 d G U P B 2
C261 C 0.71360(11) 0.2236(7) 0.8714(3) 0.130(5) Uani 0.49(3) 1 d G U P B 2
C262 C 0.70825(18) 0.1721(9) 0.8887(2) 0.125(9) Uani 0.49(3) 1 d G U P B 2
C263 C 0.7232(2) 0.1323(6) 0.8844(2) 0.114(7) Uani 0.49(3) 1 d G U P B 2
C264 C 0.7562(2) 0.1327(6) 0.8537(5) 0.148(9) Uani 0.49(3) 1 d G U P B 2
H26A H 0.7645 0.1156 0.8823 0.223 Uiso 0.49(3) 1 calc R U P B 2
H26B H 0.7643 0.1613 0.8422 0.223 Uiso 0.49(3) 1 calc R U P B 2
H26C H 0.7521 0.1038 0.8297 0.223 Uiso 0.49(3) 1 calc R U P B 2
C265 C 0.7430(2) 0.2596(5) 0.8356(4) 0.172(11) Uani 0.49(3) 1 d G U P B 2
H26D H 0.7339 0.2753 0.8075 0.257 Uiso 0.49(3) 1 calc R U P B 2
H26E H 0.7549 0.2428 0.8271 0.257 Uiso 0.49(3) 1 calc R U P B 2
H26F H 0.7474 0.2895 0.8587 0.257 Uiso 0.49(3) 1 calc R U P B 2
C266 C 0.7020(2) 0.2773(9) 0.8693(6) 0.187(14) Uani 0.49(3) 1 d G U P B 2
H26G H 0.6898 0.2755 0.8436 0.281 Uiso 0.49(3) 1 calc R U P B 2
H26H H 0.7106 0.3085 0.8639 0.281 Uiso 0.49(3) 1 calc R U P B 2
H26I H 0.6979 0.2830 0.8991 0.281 Uiso 0.49(3) 1 calc R U P B 2
C267 C 0.6899(3) 0.1614(14) 0.9082(4) 0.172(14) Uani 0.49(3) 1 d G U P B 2
H26J H 0.6898 0.1221 0.9177 0.258 Uiso 0.49(3) 1 calc R U P B 2
H26K H 0.6904 0.1856 0.9355 0.258 Uiso 0.49(3) 1 calc R U P B 2
H26L H 0.6775 0.1695 0.8841 0.258 Uiso 0.49(3) 1 calc R U P B 2
C268 C 0.7235(4) 0.0720(7) 0.8986(4) 0.185(15) Uani 0.49(3) 1 d G U P B 2
H26M H 0.7355 0.0537 0.8918 0.277 Uiso 0.49(3) 1 calc R U P B 2
H26N H 0.7240 0.0695 0.9322 0.277 Uiso 0.49(3) 1 calc R U P B 2
H26O H 0.7111 0.0534 0.8809 0.277 Uiso 0.49(3) 1 calc R U P B 2
C169 C 0.7632(3) 0.4091(9) 0.5644(7) 0.197(7) Uani 1 1 d D U . . .
C170 C 0.6076(4) 0.3494(8) 0.2531(6) 0.176(7) Uani 1 1 d . U . . .
S11 S 0.69484(16) 0.7181(4) 0.5765(4) 0.187(4) Uani 0.658(12) 1 d D U P C 1
O27 O 0.7087(4) 0.6995(11) 0.5462(10) 0.260(12) Uani 0.658(12) 1 d D U P C 1
O28 O 0.7041(3) 0.7568(8) 0.6131(7) 0.210(9) Uani 0.658(12) 1 d D U P C 1
O29 O 0.6850(4) 0.6737(7) 0.5914(7) 0.220(10) Uani 0.658(12) 1 d D U P C 1
C171 C 0.6767(4) 0.7541(8) 0.5319(8) 0.133(6) Uani 0.658(12) 1 d D U P C 1
F7 F 0.6695(4) 0.7233(9) 0.4953(7) 0.231(9) Uani 0.658(12) 1 d D U P C 1
F8 F 0.6613(5) 0.7709(14) 0.5462(13) 0.332(15) Uani 0.658(12) 1 d D U P C 1
F9 F 0.6841(4) 0.7970(6) 0.5128(7) 0.277(11) Uani 0.658(12) 1 d D U P C 1
S11' S 0.7004(3) 0.7412(10) 0.5489(10) 0.227(10) Uani 0.342(12) 1 d D U P C 2
O27' O 0.7010(10) 0.741(2) 0.4998(11) 0.28(2) Uani 0.342(12) 1 d D U P C 2
O28' O 0.7106(7) 0.6911(17) 0.572(2) 0.35(3) Uani 0.342(12) 1 d D U P C 2
O29' O 0.7098(7) 0.7902(16) 0.5714(17) 0.26(2) Uani 0.342(12) 1 d D U P C 2
C271 C 0.6749(5) 0.7309(11) 0.5544(11) 0.134(12) Uani 0.342(12) 1 d D U P C 2
F7' F 0.6624(5) 0.7128(18) 0.5152(13) 0.243(16) Uani 0.342(12) 1 d D U P C 2
F8' F 0.6665(4) 0.7780(9) 0.5638(13) 0.192(12) Uani 0.342(12) 1 d D U P C 2
F9' F 0.6729(6) 0.6953(15) 0.5868(15) 0.29(3) Uani 0.342(12) 1 d D U P C 2
C172 C 0.4739(3) 0.7790(10) 0.2838(8) 0.187(7) Uani 1 1 d . . . . .
F10 F 0.4866(4) 0.7544(10) 0.3241(8) 0.411(14) Uani 1 1 d . U . . .
F11 F 0.4711(3) 0.7415(8) 0.2492(7) 0.308(9) Uani 1 1 d . U . . .
F12 F 0.4869(3) 0.8193(12) 0.2744(9) 0.392(13) Uani 1 1 d . U . . .
O30 O 0.4389(3) 0.7640(9) 0.3058(9) 0.369(14) Uani 1 1 d D U . . .
O31 O 0.4574(3) 0.8576(9) 0.3179(9) 0.373(14) Uani 1 1 d D U . . .
O32 O 0.4390(4) 0.8279(13) 0.2466(7) 0.411(16) Uani 1 1 d D U . . .
S12 S 0.45087(12) 0.8102(5) 0.2953(3) 0.281(5) Uani 1 1 d D U . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 O1 2.111(5) . ?
Rh1 O2 2.113(5) . ?
Rh1 C48 2.121(9) . ?
Rh1 C46 2.130(9) . ?
Rh1 N1 2.133(5) . ?
Rh1 C47 2.134(8) . ?
Rh1 C45 2.135(8) . ?
Rh1 C49 2.138(9) . ?
Rh2 C56 2.105(9) . ?
Rh2 N5 2.124(6) . ?
Rh2 O4 2.124(5) . ?
Rh2 C57 2.124(9) . ?
Rh2 O3 2.133(5) . ?
Rh2 C55 2.142(8) . ?
Rh2 C58 2.150(10) . ?
Rh2 C59 2.168(9) . ?
Rh3 C69 2.102(12) . ?
Rh3 O8 2.107(7) . ?
Rh3 C65 2.114(9) . ?
Rh3 O7 2.119(5) . ?
Rh3 C68 2.120(10) . ?
Rh3 C66 2.121(8) . ?
Rh3 N4 2.125(6) . ?
Rh3 C67 2.150(10) . ?
Rh4 N8 2.100(6) . ?
Rh4 O10 2.106(6) . ?
Rh4 O9 2.108(5) . ?
Rh4 C77 2.115(10) . ?
Rh4 C76 2.144(10) . ?
Rh4 C79 2.146(9) . ?
Rh4 C78 2.149(11) . ?
Rh4 C75 2.156(8) . ?
Rh5 O11 2.068(7) . ?
Rh5 C130 2.100(11) . ?
Rh5 O12 2.109(7) . ?
Rh5 C132 2.128(16) . ?
Rh5 C133 2.129(11) . ?
Rh5 N9 2.139(7) . ?
Rh5 C129 2.153(10) . ?
Rh5 C131 2.161(13) . ?
Rh6 C143 2.083(15) . ?
Rh6 C142 2.096(14) . ?
Rh6 C140 2.096(15) . ?
Rh6 O14 2.120(8) . ?
Rh6 C139 2.124(11) . ?
Rh6 N13 2.126(9) . ?
Rh6 O13 2.130(7) . ?
Rh6 C141 2.201(16) . ?
Rh7 C151 2.103(8) . ?
Rh7 O16 2.111(5) . ?
Rh7 O15 2.115(5) . ?
Rh7 C153 2.122(9) . ?
Rh7 C150 2.128(8) . ?
Rh7 N12 2.130(6) . ?
Rh7 C152 2.144(9) . ?
Rh7 C149 2.168(8) . ?
Rh8 C163 1.991(7) . ?
Rh8 C159 1.995(8) . ?
Rh8 C261 2.071(7) . ?
Rh8 O17 2.094(5) . ?
Rh8 N16 2.098(8) . ?
Rh8 C260 2.099(7) . ?
Rh8 O18 2.130(6) . ?
Rh8 C262 2.143(6) . ?
Rh8 C162 2.157(7) . ?
Rh8 C160 2.163(7) . ?
Rh8 C259 2.186(9) . ?
Rh8 C263 2.212(10) . ?
N1 C17 1.326(10) . ?
N1 C13 1.352(9) . ?
N4 C28 1.324(13) . ?
N4 C24 1.340(12) . ?
N5 C29 1.334(11) . ?
N5 C33 1.336(11) . ?
N8 C40 1.313(11) . ?
N8 C44 1.353(10) . ?
N9 C97 1.298(12) . ?
N9 C101 1.350(12) . ?
N12 C112 1.352(10) . ?
N12 C108 1.359(10) . ?
N13 C113 1.290(15) . ?
N13 C117 1.350(17) . ?
N16 C128 1.330(14) . ?
N16 C124 1.335(14) . ?
O1 C1 1.272(8) . ?
O2 C2 1.274(8) . ?
O3 C4 1.261(9) . ?
O4 C5 1.286(9) . ?
O7 C7 1.284(10) . ?
O8 C8 1.256(9) . ?
O9 C10 1.260(10) . ?
O10 C11 1.262(9) . ?
O11 C85 1.250(11) . ?
O12 C86 1.280(12) . ?
O13 C88 1.243(12) . ?
O14 C89 1.251(13) . ?
O15 C92 1.252(9) . ?
O16 C91 1.272(8) . ?
O17 C95 1.287(9) . ?
O18 C94 1.251(8) . ?
O21 S9 1.346(10) . ?
O22 S9 1.421(15) . ?
O23 S9 1.462(14) . ?
O24 S10 1.19(3) . ?
O25 S10 1.459(13) . ?
O26 S10 1.493(14) . ?
S3 C34 1.683(8) . ?
S3 C37 1.711(8) . ?
S4 C39 1.717(8) . ?
S4 C36 1.721(8) . ?
S7 C118 1.663(10) . ?
S7 C121 1.703(13) . ?
S8 C120 1.704(12) . ?
S8 C123 1.748(12) . ?
S9 C169 1.75(2) . ?
S10 C170 1.70(2) . ?
F1 C169 1.328(15) . ?
F2 C169 1.353(16) . ?
F3 C169 1.281(16) . ?
F4 C170 1.35(2) . ?
F5 C170 1.353(19) . ?
F6 C170 1.28(2) . ?
S1 C21 1.599(11) . ?
S1 C18 1.76(3) . ?
S2 C23 1.694(17) . ?
S2 C20 1.782(9) . ?
C18 C19 1.32(5) . ?
C18 H18 0.9500 . ?
C23 C22 1.391(18) . ?
C23 H23 0.9500 . ?
N2 C18' 1.399(19) . ?
N2 C19 1.47(3) . ?
N2 H2 0.8800 . ?
N3 C22 1.331(15) . ?
N3 C23' 1.350(16) . ?
N3 H3 0.8800 . ?
O5 C18' 1.307(17) . ?
O6 C23' 1.193(15) . ?
C18' C21 1.464(17) . ?
C23' C20 1.401(16) . ?
S5 C105 1.637(11) . ?
S5 C102 1.75(3) . ?
S6 C107 1.74(3) . ?
S6 C104 1.792(9) . ?
C102 C103 1.37(3) . ?
C102 H102 0.9500 . ?
C107 C106 1.56(3) . ?
C107 H107 0.9500 . ?
O19 C202 1.283(17) . ?
O20 C207 1.218(16) . ?
N10 C202 1.390(19) . ?
N10 C103 1.419(18) . ?
N10 H10 0.8800 . ?
N11 C106 1.25(3) . ?
N11 C207 1.372(19) . ?
N11 H11 0.8800 . ?
C202 C105 1.469(18) . ?
C207 C104 1.433(17) . ?
C1 C6 1.375(10) . ?
C1 C2 1.504(10) . ?
C2 C3 1.398(10) . ?
C3 C4 1.366(11) . ?
C3 H3A 0.9500 . ?
C4 C5 1.502(11) . ?
C5 C6 1.413(10) . ?
C6 H6 0.9500 . ?
C7 C12 1.398(10) . ?
C7 C8 1.562(13) . ?
C8 C9 1.341(13) . ?
C9 C10 1.422(11) . ?
C9 H9 0.9500 . ?
C10 C11 1.507(12) . ?
C11 C12 1.385(12) . ?
C12 H12 0.9500 . ?
C13 C14 1.365(9) . ?
C13 H13 0.9500 . ?
C14 C15 1.401(10) . ?
C14 H14 0.9500 . ?
C15 C16 1.424(10) . ?
C15 C19 1.434(9) . ?
C16 C17 1.348(11) . ?
C16 H16 0.9500 . ?
C17 H17 0.9500 . ?
C19 C20 1.433(10) . ?
C20 C21 1.381(10) . ?
C21 C22 1.408(11) . ?
C22 C26 1.439(10) . ?
C24 C25 1.365(11) . ?
C24 H24 0.9500 . ?
C25 C26 1.434(13) . ?
C25 H25 0.9500 . ?
C26 C27 1.380(13) . ?
C27 C28 1.377(12) . ?
C27 H27 0.9500 . ?
C28 H28 0.9500 . ?
C29 C30 1.389(11) . ?
C29 H29 0.9500 . ?
C30 C31 1.384(11) . ?
C30 H30 0.9500 . ?
C31 C32 1.392(12) . ?
C31 C35 1.471(10) . ?
C32 C33 1.330(12) . ?
C32 H32 0.9500 . ?
C33 H33 0.9500 . ?
C34 C35 1.378(11) . ?
C34 H34 0.9500 . ?
C35 C36 1.428(11) . ?
C36 C37 1.396(9) . ?
C37 C38 1.437(10) . ?
C38 C39 1.352(11) . ?
C38 C42 1.467(10) . ?
C39 H39 0.9500 . ?
C40 C41 1.360(11) . ?
C40 H40 0.9500 . ?
C41 C42 1.397(11) . ?
C41 H41 0.9500 . ?
C42 C43 1.402(11) . ?
C43 C44 1.362(11) . ?
C43 H43 0.9500 . ?
C44 H44 0.9500 . ?
C45 C49 1.388(16) . ?
C45 C46 1.406(15) . ?
C45 C50 1.509(14) . ?
C46 C47 1.438(16) . ?
C46 C51 1.516(14) . ?
C47 C48 1.414(17) . ?
C47 C52 1.471(14) . ?
C48 C49 1.460(15) . ?
C48 C53 1.534(19) . ?
C49 C54 1.491(17) . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C55 C60 1.436(14) . ?
C55 C56 1.438(14) . ?
C55 C59 1.494(14) . ?
C56 C61 1.447(17) . ?
C56 C57 1.467(15) . ?
C57 C58 1.375(15) . ?
C57 C62 1.558(16) . ?
C58 C59 1.438(13) . ?
C58 C63 1.481(15) . ?
C59 C64 1.421(16) . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C63 H63A 0.9800 . ?
C63 H63B 0.9800 . ?
C63 H63C 0.9800 . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C65 C66 1.360(15) . ?
C65 C69 1.421(14) . ?
C65 C70 1.490(16) . ?
C66 C67 1.332(12) . ?
C66 C71 1.504(14) . ?
C67 C68 1.403(15) . ?
C67 C72 1.60(2) . ?
C68 C69 1.412(14) . ?
C68 C73 1.498(18) . ?
C69 C74 1.46(2) . ?
C70 H70A 0.9800 . ?
C70 H70B 0.9800 . ?
C70 H70C 0.9800 . ?
C71 H71A 0.9800 . ?
C71 H71B 0.9800 . ?
C71 H71C 0.9800 . ?
C72 H72A 0.9800 . ?
C72 H72B 0.9800 . ?
C72 H72C 0.9800 . ?
C73 H73A 0.9800 . ?
C73 H73B 0.9800 . ?
C73 H73C 0.9800 . ?
C74 H74A 0.9800 . ?
C74 H74B 0.9800 . ?
C74 H74C 0.9800 . ?
C75 C76 1.388(15) . ?
C75 C79 1.459(12) . ?
C75 C80 1.483(14) . ?
C76 C81 1.418(19) . ?
C76 C77 1.46(2) . ?
C77 C78 1.511(18) . ?
C77 C82 1.527(16) . ?
C78 C79 1.420(14) . ?
C78 C83 1.502(14) . ?
C79 C84 1.471(14) . ?
C80 H80A 0.9800 . ?
C80 H80B 0.9800 . ?
C80 H80C 0.9800 . ?
C81 H81A 0.9800 . ?
C81 H81B 0.9800 . ?
C81 H81C 0.9800 . ?
C82 H82A 0.9800 . ?
C82 H82B 0.9800 . ?
C82 H82C 0.9800 . ?
C83 H83A 0.9800 . ?
C83 H83B 0.9800 . ?
C83 H83C 0.9800 . ?
C84 H84A 0.9800 . ?
C84 H84B 0.9800 . ?
C84 H84C 0.9800 . ?
C85 C90 1.369(14) . ?
C85 C86 1.495(15) . ?
C86 C87 1.416(14) . ?
C87 C88 1.367(15) . ?
C87 H87 0.9500 . ?
C88 C89 1.515(16) . ?
C89 C90 1.439(14) . ?
C90 H90 0.9500 . ?
C91 C96 1.395(10) . ?
C91 C92 1.496(10) . ?
C92 C93 1.423(10) . ?
C93 C94 1.349(11) . ?
C93 H93 0.9500 . ?
C94 C95 1.547(11) . ?
C95 C96 1.377(10) . ?
C96 H96 0.9500 . ?
C97 C98 1.414(12) . ?
C97 H97 0.9500 . ?
C98 C99 1.410(11) . ?
C98 H98 0.9500 . ?
C99 C100 1.413(12) . ?
C99 C103 1.458(10) . ?
C100 C101 1.393(13) . ?
C100 H100 0.9500 . ?
C101 H101 0.9500 . ?
C103 C104 1.398(11) . ?
C104 C105 1.395(10) . ?
C105 C106 1.394(12) . ?
C106 C110 1.449(11) . ?
C108 C109 1.374(10) . ?
C108 H108 0.9500 . ?
C109 C110 1.390(11) . ?
C109 H109 0.9500 . ?
C110 C111 1.389(12) . ?
C111 C112 1.390(11) . ?
C111 H111 0.9500 . ?
C112 H112 0.9500 . ?
C113 C114 1.399(15) . ?
C113 H113 0.9500 . ?
C114 C115 1.381(15) . ?
C114 H114 0.9500 . ?
C115 C116 1.425(17) . ?
C115 C119 1.481(15) . ?
C116 C117 1.341(17) . ?
C116 H116 0.9500 . ?
C117 H117 0.9500 . ?
C118 C119 1.370(15) . ?
C118 H118 0.9500 . ?
C119 C120 1.429(13) . ?
C120 C121 1.422(13) . ?
C121 C122 1.421(16) . ?
C122 C123 1.341(16) . ?
C122 C126 1.443(14) . ?
C123 H123 0.9500 . ?
C124 C125 1.381(15) . ?
C124 H124 0.9500 . ?
C125 C126 1.378(15) . ?
C125 H125 0.9500 . ?
C126 C127 1.429(16) . ?
C127 C128 1.394(16) . ?
C127 H127 0.9500 . ?
C128 H128 0.9500 . ?
C129 C133 1.421(13) . ?
C129 C130 1.473(19) . ?
C129 C134 1.475(19) . ?
C130 C135 1.37(2) . ?
C130 C131 1.41(2) . ?
C131 C132 1.32(2) . ?
C131 C136 1.48(2) . ?
C132 C133 1.398(19) . ?
C132 C137 1.48(2) . ?
C133 C138 1.477(15) . ?
C134 H13A 0.9800 . ?
C134 H13B 0.9800 . ?
C134 H13C 0.9800 . ?
C135 H13D 0.9800 . ?
C135 H13E 0.9800 . ?
C135 H13F 0.9800 . ?
C136 H13G 0.9800 . ?
C136 H13H 0.9800 . ?
C136 H13I 0.9800 . ?
C137 H13J 0.9800 . ?
C137 H13K 0.9800 . ?
C137 H13L 0.9800 . ?
C138 H13M 0.9800 . ?
C138 H13N 0.9800 . ?
C138 H13O 0.9800 . ?
C139 C140 1.391(19) . ?
C139 C143 1.424(14) . ?
C139 C144 1.452(13) . ?
C140 C141 1.350(16) . ?
C140 C145 1.57(2) . ?
C141 C146 1.527(16) . ?
C141 C142 1.53(3) . ?
C142 C143 1.37(2) . ?
C142 C147 1.51(2) . ?
C143 C148 1.37(2) . ?
C144 H14A 0.9800 . ?
C144 H14B 0.9800 . ?
C144 H14C 0.9800 . ?
C145 H14D 0.9800 . ?
C145 H14E 0.9800 . ?
C145 H14F 0.9800 . ?
C146 H14G 0.9800 . ?
C146 H14H 0.9800 . ?
C146 H14I 0.9800 . ?
C147 H14J 0.9800 . ?
C147 H14K 0.9800 . ?
C147 H14L 0.9800 . ?
C148 H14M 0.9800 . ?
C148 H14N 0.9800 . ?
C148 H14O 0.9800 . ?
C149 C150 1.437(13) . ?
C149 C153 1.442(14) . ?
C149 C154 1.468(14) . ?
C150 C151 1.421(11) . ?
C150 C155 1.497(14) . ?
C151 C152 1.383(14) . ?
C151 C156 1.582(14) . ?
C152 C153 1.420(12) . ?
C152 C157 1.485(15) . ?
C153 C158 1.508(15) . ?
C154 H15A 0.9800 . ?
C154 H15B 0.9800 . ?
C154 H15C 0.9800 . ?
C155 H15D 0.9800 . ?
C155 H15E 0.9800 . ?
C155 H15F 0.9800 . ?
C156 H15G 0.9800 . ?
C156 H15H 0.9800 . ?
C156 H15I 0.9800 . ?
C157 H15J 0.9800 . ?
C157 H15K 0.9800 . ?
C157 H15L 0.9800 . ?
C158 H15M 0.9800 . ?
C158 H15N 0.9800 . ?
C158 H15O 0.9800 . ?
C159 C160 1.402(4) . ?
C159 C163 1.402(4) . ?
C159 C164 1.490(4) . ?
C160 C161 1.401(4) . ?
C160 C165 1.490(4) . ?
C161 C162 1.402(4) . ?
C161 C166 1.490(4) . ?
C162 C163 1.401(4) . ?
C162 C167 1.489(4) . ?
C163 C168 1.490(4) . ?
C164 H16A 0.9800 . ?
C164 H16B 0.9800 . ?
C164 H16C 0.9800 . ?
C165 H16D 0.9800 . ?
C165 H16E 0.9800 . ?
C165 H16F 0.9800 . ?
C166 H16G 0.9800 . ?
C166 H16H 0.9800 . ?
C166 H16I 0.9800 . ?
C167 H16J 0.9800 . ?
C167 H16K 0.9800 . ?
C167 H16L 0.9800 . ?
C168 H16M 0.9800 . ?
C168 H16N 0.9800 . ?
C168 H16O 0.9800 . ?
C259 C260 1.409(4) . ?
C259 C263 1.409(4) . ?
C259 C264 1.497(4) . ?
C260 C261 1.409(4) . ?
C260 C265 1.498(4) . ?
C261 C262 1.409(4) . ?
C261 C266 1.498(4) . ?
C262 C263 1.409(4) . ?
C262 C267 1.498(4) . ?
C263 C268 1.497(4) . ?
C264 H26A 0.9800 . ?
C264 H26B 0.9800 . ?
C264 H26C 0.9800 . ?
C265 H26D 0.9800 . ?
C265 H26E 0.9800 . ?
C265 H26F 0.9800 . ?
C266 H26G 0.9800 . ?
C266 H26H 0.9800 . ?
C266 H26I 0.9800 . ?
C267 H26J 0.9800 . ?
C267 H26K 0.9800 . ?
C267 H26L 0.9800 . ?
C268 H26M 0.9800 . ?
C268 H26N 0.9800 . ?
C268 H26O 0.9800 . ?
S11 O29 1.373(14) . ?
S11 O28 1.445(14) . ?
S11 O27 1.493(15) . ?
S11 C171 1.79(3) . ?
C171 F8 1.27(3) . ?
C171 F7 1.30(3) . ?
C171 F9 1.320(16) . ?
S11' O29' 1.420(18) . ?
S11' O27' 1.446(19) . ?
S11' O28' 1.463(18) . ?
S11' C271 1.78(3) . ?
C271 F9' 1.302(19) . ?
C271 F8' 1.314(19) . ?
C271 F7' 1.331(19) . ?
C172 F11 1.33(2) . ?
C172 F12 1.37(3) . ?
C172 F10 1.42(2) . ?
C172 S12 1.82(2) . ?
O30 S12 1.442(13) . ?
O31 S12 1.334(14) . ?
O32 S12 1.527(15) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Rh1 O2 77.50(19) . . ?
O1 Rh1 C48 109.0(3) . . ?
O2 Rh1 C48 102.9(4) . . ?
O1 Rh1 C46 118.5(3) . . ?
O2 Rh1 C46 162.6(3) . . ?
C48 Rh1 C46 66.6(4) . . ?
O1 Rh1 N1 82.7(2) . . ?
O2 Rh1 N1 89.03(19) . . ?
C48 Rh1 N1 164.7(3) . . ?
C46 Rh1 N1 99.4(3) . . ?
O1 Rh1 C47 97.1(3) . . ?
O2 Rh1 C47 137.8(4) . . ?
C48 Rh1 C47 38.8(5) . . ?
C46 Rh1 C47 39.4(4) . . ?
N1 Rh1 C47 132.2(4) . . ?
O1 Rh1 C45 157.0(3) . . ?
O2 Rh1 C45 125.2(4) . . ?
C48 Rh1 C45 65.5(4) . . ?
C46 Rh1 C45 38.5(4) . . ?
N1 Rh1 C45 99.8(3) . . ?
C47 Rh1 C45 64.2(4) . . ?
O1 Rh1 C49 147.6(4) . . ?
O2 Rh1 C49 97.7(4) . . ?
C48 Rh1 C49 40.1(4) . . ?
C46 Rh1 C49 65.2(4) . . ?
N1 Rh1 C49 129.6(4) . . ?
C47 Rh1 C49 64.8(4) . . ?
C45 Rh1 C49 37.9(4) . . ?
C56 Rh2 N5 116.0(4) . . ?
C56 Rh2 O4 157.3(4) . . ?
N5 Rh2 O4 86.7(2) . . ?
C56 Rh2 C57 40.6(4) . . ?
N5 Rh2 C57 156.6(3) . . ?
O4 Rh2 C57 116.7(3) . . ?
C56 Rh2 O3 102.6(3) . . ?
N5 Rh2 O3 84.3(2) . . ?
O4 Rh2 O3 77.2(2) . . ?
C57 Rh2 O3 99.6(3) . . ?
C56 Rh2 C55 39.6(4) . . ?
N5 Rh2 C55 95.2(3) . . ?
O4 Rh2 C55 146.2(3) . . ?
C57 Rh2 C55 66.0(4) . . ?
O3 Rh2 C55 136.6(3) . . ?
C56 Rh2 C58 66.3(4) . . ?
N5 Rh2 C58 148.3(3) . . ?
O4 Rh2 C58 95.3(3) . . ?
C57 Rh2 C58 37.5(4) . . ?
O3 Rh2 C58 127.1(3) . . ?
C55 Rh2 C58 66.2(4) . . ?
C56 Rh2 C59 67.3(4) . . ?
N5 Rh2 C59 110.4(3) . . ?
O4 Rh2 C59 107.5(3) . . ?
C57 Rh2 C59 65.0(4) . . ?
O3 Rh2 C59 164.5(3) . . ?
C55 Rh2 C59 40.5(4) . . ?
C58 Rh2 C59 38.9(3) . . ?
C69 Rh3 O8 152.9(4) . . ?
C69 Rh3 C65 39.4(4) . . ?
O8 Rh3 C65 147.4(4) . . ?
C69 Rh3 O7 102.1(4) . . ?
O8 Rh3 O7 76.9(2) . . ?
C65 Rh3 O7 135.6(4) . . ?
C69 Rh3 C68 39.1(4) . . ?
O8 Rh3 C68 113.9(4) . . ?
C65 Rh3 C68 64.9(4) . . ?
O7 Rh3 C68 100.1(4) . . ?
C69 Rh3 C66 63.6(5) . . ?
O8 Rh3 C66 110.9(4) . . ?
C65 Rh3 C66 37.5(4) . . ?
O7 Rh3 C66 162.7(3) . . ?
C68 Rh3 C66 62.7(4) . . ?
C69 Rh3 N4 122.1(5) . . ?
O8 Rh3 N4 85.0(3) . . ?
C65 Rh3 N4 96.0(3) . . ?
O7 Rh3 N4 89.9(2) . . ?
C68 Rh3 N4 160.1(4) . . ?
C66 Rh3 N4 105.8(3) . . ?
C69 Rh3 C67 64.4(5) . . ?
O8 Rh3 C67 95.1(4) . . ?
C65 Rh3 C67 63.2(4) . . ?
O7 Rh3 C67 130.2(4) . . ?
C68 Rh3 C67 38.3(4) . . ?
C66 Rh3 C67 36.3(3) . . ?
N4 Rh3 C67 139.0(4) . . ?
N8 Rh4 O10 83.8(3) . . ?
N8 Rh4 O9 86.5(2) . . ?
O10 Rh4 O9 76.7(2) . . ?
N8 Rh4 C77 164.1(3) . . ?
O10 Rh4 C77 107.6(4) . . ?
O9 Rh4 C77 106.6(4) . . ?
N8 Rh4 C76 129.5(5) . . ?
O10 Rh4 C76 96.2(4) . . ?
O9 Rh4 C76 142.8(4) . . ?
C77 Rh4 C76 40.2(5) . . ?
N8 Rh4 C79 99.3(3) . . ?
O10 Rh4 C79 158.2(3) . . ?
O9 Rh4 C79 124.9(3) . . ?
C77 Rh4 C79 66.0(4) . . ?
C76 Rh4 C79 65.1(4) . . ?
N8 Rh4 C78 129.3(4) . . ?
O10 Rh4 C78 146.5(3) . . ?
O9 Rh4 C78 98.0(4) . . ?
C77 Rh4 C78 41.5(5) . . ?
C76 Rh4 C78 67.9(5) . . ?
C79 Rh4 C78 38.6(4) . . ?
N8 Rh4 C75 99.3(3) . . ?
O10 Rh4 C75 118.6(3) . . ?
O9 Rh4 C75 164.0(4) . . ?
C77 Rh4 C75 65.8(4) . . ?
C76 Rh4 C75 37.7(4) . . ?
C79 Rh4 C75 39.7(3) . . ?
C78 Rh4 C75 66.7(4) . . ?
O11 Rh5 C130 113.2(5) . . ?
O11 Rh5 O12 76.7(3) . . ?
C130 Rh5 O12 163.8(5) . . ?
O11 Rh5 C132 111.6(5) . . ?
C130 Rh5 C132 62.7(7) . . ?
O12 Rh5 C132 102.2(6) . . ?
O11 Rh5 C133 149.0(4) . . ?
C130 Rh5 C133 65.4(5) . . ?
O12 Rh5 C133 99.3(4) . . ?
C132 Rh5 C133 38.3(5) . . ?
O11 Rh5 N9 83.1(3) . . ?
C130 Rh5 N9 105.6(5) . . ?
O12 Rh5 N9 87.8(2) . . ?
C132 Rh5 N9 163.6(5) . . ?
C133 Rh5 N9 127.8(5) . . ?
O11 Rh5 C129 153.5(4) . . ?
C130 Rh5 C129 40.5(5) . . ?
O12 Rh5 C129 129.5(4) . . ?
C132 Rh5 C129 64.0(5) . . ?
C133 Rh5 C129 38.8(4) . . ?
N9 Rh5 C129 99.7(4) . . ?
O11 Rh5 C131 95.5(5) . . ?
C130 Rh5 C131 38.5(6) . . ?
O12 Rh5 C131 131.2(5) . . ?
C132 Rh5 C131 35.8(6) . . ?
C133 Rh5 C131 63.6(6) . . ?
N9 Rh5 C131 139.8(6) . . ?
C129 Rh5 C131 65.4(6) . . ?
C143 Rh6 C142 38.4(7) . . ?
C143 Rh6 C140 64.8(6) . . ?
C142 Rh6 C140 64.2(6) . . ?
C143 Rh6 O14 145.5(5) . . ?
C142 Rh6 O14 156.6(6) . . ?
C140 Rh6 O14 95.9(5) . . ?
C143 Rh6 C139 39.6(4) . . ?
C142 Rh6 C139 65.1(5) . . ?
C140 Rh6 C139 38.5(5) . . ?
O14 Rh6 C139 107.7(4) . . ?
C143 Rh6 N13 127.0(5) . . ?
C142 Rh6 N13 98.1(5) . . ?
C140 Rh6 N13 134.3(6) . . ?
O14 Rh6 N13 87.2(3) . . ?
C139 Rh6 N13 163.1(4) . . ?
C143 Rh6 O13 100.1(5) . . ?
C142 Rh6 O13 126.0(7) . . ?
C140 Rh6 O13 141.8(5) . . ?
O14 Rh6 O13 77.2(3) . . ?
C139 Rh6 O13 107.3(4) . . ?
N13 Rh6 O13 83.5(4) . . ?
C143 Rh6 C141 67.1(6) . . ?
C142 Rh6 C141 41.7(7) . . ?
C140 Rh6 C141 36.5(5) . . ?
O14 Rh6 C141 114.8(6) . . ?
C139 Rh6 C141 65.0(5) . . ?
N13 Rh6 C141 101.8(6) . . ?
O13 Rh6 C141 166.9(5) . . ?
C151 Rh7 O16 101.6(3) . . ?
C151 Rh7 O15 108.0(3) . . ?
O16 Rh7 O15 76.49(18) . . ?
C151 Rh7 C153 65.1(4) . . ?
O16 Rh7 C153 163.5(3) . . ?
O15 Rh7 C153 115.9(3) . . ?
C151 Rh7 C150 39.3(3) . . ?
O16 Rh7 C150 98.2(3) . . ?
O15 Rh7 C150 146.0(3) . . ?
C153 Rh7 C150 65.4(4) . . ?
C151 Rh7 N12 160.8(3) . . ?
O16 Rh7 N12 85.4(2) . . ?
O15 Rh7 N12 91.0(2) . . ?
C153 Rh7 N12 104.3(3) . . ?
C150 Rh7 N12 122.5(3) . . ?
C151 Rh7 C152 38.0(4) . . ?
O16 Rh7 C152 134.2(3) . . ?
O15 Rh7 C152 94.7(3) . . ?
C153 Rh7 C152 38.9(3) . . ?
C150 Rh7 C152 64.7(4) . . ?
N12 Rh7 C152 140.2(3) . . ?
C151 Rh7 C149 65.6(4) . . ?
O16 Rh7 C149 127.8(3) . . ?
O15 Rh7 C149 155.1(3) . . ?
C153 Rh7 C149 39.3(4) . . ?
C150 Rh7 C149 39.1(4) . . ?
N12 Rh7 C149 95.9(3) . . ?
C152 Rh7 C149 65.2(4) . . ?
C163 Rh8 C159 41.18(17) . . ?
C163 Rh8 O17 133.7(6) . . ?
C159 Rh8 O17 102.4(4) . . ?
C261 Rh8 O17 145.2(4) . . ?
C163 Rh8 N16 139.7(6) . . ?
C159 Rh8 N16 147.9(3) . . ?
C261 Rh8 N16 97.4(4) . . ?
O17 Rh8 N16 86.6(3) . . ?
C261 Rh8 C260 39.49(15) . . ?
O17 Rh8 C260 107.2(3) . . ?
N16 Rh8 C260 112.0(3) . . ?
C163 Rh8 O18 103.7(3) . . ?
C159 Rh8 O18 129.2(3) . . ?
C261 Rh8 O18 137.8(4) . . ?
O17 Rh8 O18 77.0(2) . . ?
N16 Rh8 O18 82.8(3) . . ?
C260 Rh8 O18 164.6(3) . . ?
C261 Rh8 C262 39.01(14) . . ?
O17 Rh8 C262 154.5(6) . . ?
N16 Rh8 C262 118.9(6) . . ?
C260 Rh8 C262 65.0(2) . . ?
O18 Rh8 C262 104.7(3) . . ?
C163 Rh8 C162 39.24(14) . . ?
C159 Rh8 C162 66.1(2) . . ?
O17 Rh8 C162 167.8(3) . . ?
N16 Rh8 C162 101.2(6) . . ?
O18 Rh8 C162 113.0(4) . . ?
C163 Rh8 C160 66.0(2) . . ?
C159 Rh8 C160 39.13(13) . . ?
O17 Rh8 C160 105.5(3) . . ?
N16 Rh8 C160 108.8(3) . . ?
O18 Rh8 C160 168.2(3) . . ?
C162 Rh8 C160 63.3(2) . . ?
C261 Rh8 C259 64.7(2) . . ?
O17 Rh8 C259 94.8(3) . . ?
N16 Rh8 C259 149.1(3) . . ?
C260 Rh8 C259 38.32(13) . . ?
O18 Rh8 C259 127.7(3) . . ?
C262 Rh8 C259 63.5(2) . . ?
C261 Rh8 C263 64.2(2) . . ?
O17 Rh8 C263 116.8(5) . . ?
N16 Rh8 C263 156.6(6) . . ?
C260 Rh8 C263 63.8(2) . . ?
O18 Rh8 C263 101.0(2) . . ?
C262 Rh8 C263 37.71(15) . . ?
C259 Rh8 C263 37.38(16) . . ?
C17 N1 C13 117.6(6) . . ?
C17 N1 Rh1 120.9(5) . . ?
C13 N1 Rh1 121.6(5) . . ?
C28 N4 C24 117.6(7) . . ?
C28 N4 Rh3 120.1(6) . . ?
C24 N4 Rh3 122.2(6) . . ?
C29 N5 C33 119.3(7) . . ?
C29 N5 Rh2 119.1(5) . . ?
C33 N5 Rh2 121.2(6) . . ?
C40 N8 C44 116.8(7) . . ?
C40 N8 Rh4 119.6(5) . . ?
C44 N8 Rh4 123.4(5) . . ?
C97 N9 C101 117.1(8) . . ?
C97 N9 Rh5 122.8(6) . . ?
C101 N9 Rh5 120.0(6) . . ?
C112 N12 C108 117.9(7) . . ?
C112 N12 Rh7 118.2(6) . . ?
C108 N12 Rh7 123.8(5) . . ?
C113 N13 C117 118.7(11) . . ?
C113 N13 Rh6 120.8(9) . . ?
C117 N13 Rh6 120.6(9) . . ?
C128 N16 C124 118.6(9) . . ?
C128 N16 Rh8 119.7(8) . . ?
C124 N16 Rh8 121.3(7) . . ?
C1 O1 Rh1 114.9(5) . . ?
C2 O2 Rh1 114.2(5) . . ?
C4 O3 Rh2 115.6(5) . . ?
C5 O4 Rh2 113.2(5) . . ?
C7 O7 Rh3 114.8(5) . . ?
C8 O8 Rh3 118.6(6) . . ?
C10 O9 Rh4 115.2(5) . . ?
C11 O10 Rh4 115.0(5) . . ?
C85 O11 Rh5 117.2(7) . . ?
C86 O12 Rh5 114.6(6) . . ?
C88 O13 Rh6 114.8(7) . . ?
C89 O14 Rh6 113.6(8) . . ?
C92 O15 Rh7 115.3(4) . . ?
C91 O16 Rh7 115.3(4) . . ?
C95 O17 Rh8 114.9(5) . . ?
C94 O18 Rh8 115.9(5) . . ?
C34 S3 C37 92.3(4) . . ?
C39 S4 C36 90.7(4) . . ?
C118 S7 C121 92.9(5) . . ?
C120 S8 C123 90.2(6) . . ?
O21 S9 O22 111.7(11) . . ?
O21 S9 O23 113.1(13) . . ?
O22 S9 O23 123.0(16) . . ?
O21 S9 C169 113.2(8) . . ?
O22 S9 C169 94.5(12) . . ?
O23 S9 C169 98.4(13) . . ?
O24 S10 O25 112(2) . . ?
O24 S10 O26 98.4(17) . . ?
O25 S10 O26 115.8(11) . . ?
O24 S10 C170 126(2) . . ?
O25 S10 C170 104.1(9) . . ?
O26 S10 C170 100.5(13) . . ?
C21 S1 C18 93(2) . . ?
C23 S2 C20 82.6(8) . . ?
C19 C18 S1 110(3) . . ?
C19 C18 H18 124.8 . . ?
S1 C18 H18 124.8 . . ?
C22 C23 S2 122.7(14) . . ?
C22 C23 H23 118.6 . . ?
S2 C23 H23 118.6 . . ?
C18' N2 C19 112(2) . . ?
C18' N2 H2 124.1 . . ?
C19 N2 H2 124.1 . . ?
C22 N3 C23' 107.7(14) . . ?
C22 N3 H3 126.2 . . ?
C23' N3 H3 126.2 . . ?
O5 C18' N2 111(2) . . ?
O5 C18' C21 144(2) . . ?
N2 C18' C21 105(2) . . ?
O6 C23' N3 121.0(17) . . ?
O6 C23' C20 125.7(16) . . ?
N3 C23' C20 113.3(13) . . ?
C105 S5 C102 93.5(10) . . ?
C107 S6 C104 91.4(10) . . ?
C103 C102 S5 108.6(17) . . ?
C103 C102 H102 125.7 . . ?
S5 C102 H102 125.7 . . ?
C106 C107 S6 109.8(16) . . ?
C106 C107 H107 125.1 . . ?
S6 C107 H107 125.1 . . ?
C202 N10 C103 110.3(16) . . ?
C202 N10 H10 124.8 . . ?
C103 N10 H10 124.8 . . ?
C106 N11 C207 114.7(19) . . ?
C106 N11 H11 122.7 . . ?
C207 N11 H11 122.7 . . ?
O19 C202 N10 116.6(19) . . ?
O19 C202 C105 135(2) . . ?
N10 C202 C105 107.3(17) . . ?
O20 C207 N11 120(2) . . ?
O20 C207 C104 132(2) . . ?
N11 C207 C104 107.4(15) . . ?
O1 C1 C6 123.0(7) . . ?
O1 C1 C2 115.9(6) . . ?
C6 C1 C2 121.1(6) . . ?
O2 C2 C3 123.4(7) . . ?
O2 C2 C1 116.9(6) . . ?
C3 C2 C1 119.7(6) . . ?
C4 C3 C2 119.8(7) . . ?
C4 C3 H3A 120.1 . . ?
C2 C3 H3A 120.1 . . ?
O3 C4 C3 124.6(7) . . ?
O3 C4 C5 115.3(6) . . ?
C3 C4 C5 120.1(7) . . ?
O4 C5 C6 120.9(7) . . ?
O4 C5 C4 118.5(6) . . ?
C6 C5 C4 120.6(6) . . ?
C1 C6 C5 118.0(7) . . ?
C1 C6 H6 121.0 . . ?
C5 C6 H6 121.0 . . ?
O7 C7 C12 124.2(8) . . ?
O7 C7 C8 116.7(7) . . ?
C12 C7 C8 119.1(8) . . ?
O8 C8 C9 126.6(9) . . ?
O8 C8 C7 112.8(8) . . ?
C9 C8 C7 120.6(7) . . ?
C8 C9 C10 119.9(9) . . ?
C8 C9 H9 120.1 . . ?
C10 C9 H9 120.1 . . ?
O9 C10 C9 124.6(9) . . ?
O9 C10 C11 116.1(7) . . ?
C9 C10 C11 119.3(8) . . ?
O10 C11 C12 122.6(8) . . ?
O10 C11 C10 115.9(7) . . ?
C12 C11 C10 121.5(7) . . ?
C11 C12 C7 118.9(8) . . ?
C11 C12 H12 120.5 . . ?
C7 C12 H12 120.5 . . ?
N1 C13 C14 123.1(7) . . ?
N1 C13 H13 118.5 . . ?
C14 C13 H13 118.5 . . ?
C13 C14 C15 120.0(6) . . ?
C13 C14 H14 120.0 . . ?
C15 C14 H14 120.0 . . ?
C14 C15 C16 115.4(6) . . ?
C14 C15 C19 122.2(6) . . ?
C16 C15 C19 122.4(6) . . ?
C17 C16 C15 120.5(7) . . ?
C17 C16 H16 119.7 . . ?
C15 C16 H16 119.7 . . ?
N1 C17 C16 123.4(7) . . ?
N1 C17 H17 118.3 . . ?
C16 C17 H17 118.3 . . ?
C18 C19 C20 112.0(18) . . ?
C18 C19 C15 119.0(18) . . ?
C20 C19 C15 129.0(6) . . ?
C20 C19 N2 102.9(12) . . ?
C15 C19 N2 128.1(12) . . ?
C21 C20 C23' 100.7(8) . . ?
C21 C20 C19 111.3(6) . . ?
C23' C20 C19 148.0(9) . . ?
C21 C20 S2 116.4(6) . . ?
C19 C20 S2 132.2(6) . . ?
C20 C21 C22 111.7(7) . . ?
C20 C21 C18' 109.1(12) . . ?
C22 C21 C18' 139.1(12) . . ?
C20 C21 S1 113.7(7) . . ?
C22 C21 S1 134.6(7) . . ?
N3 C22 C21 106.5(9) . . ?
C23 C22 C21 105.5(10) . . ?
N3 C22 C26 123.0(10) . . ?
C23 C22 C26 123.8(11) . . ?
C21 C22 C26 130.5(9) . . ?
N4 C24 C25 123.7(10) . . ?
N4 C24 H24 118.2 . . ?
C25 C24 H24 118.2 . . ?
C24 C25 C26 118.7(9) . . ?
C24 C25 H25 120.7 . . ?
C26 C25 H25 120.7 . . ?
C27 C26 C25 116.5(7) . . ?
C27 C26 C22 123.1(9) . . ?
C25 C26 C22 120.4(8) . . ?
C28 C27 C26 120.0(10) . . ?
C28 C27 H27 120.0 . . ?
C26 C27 H27 120.0 . . ?
N4 C28 C27 123.5(10) . . ?
N4 C28 H28 118.2 . . ?
C27 C28 H28 118.2 . . ?
N5 C29 C30 121.2(8) . . ?
N5 C29 H29 119.4 . . ?
C30 C29 H29 119.4 . . ?
C31 C30 C29 119.6(8) . . ?
C31 C30 H30 120.2 . . ?
C29 C30 H30 120.2 . . ?
C30 C31 C32 116.5(7) . . ?
C30 C31 C35 121.2(7) . . ?
C32 C31 C35 122.3(7) . . ?
C33 C32 C31 121.5(9) . . ?
C33 C32 H32 119.3 . . ?
C31 C32 H32 119.3 . . ?
C32 C33 N5 121.9(9) . . ?
C32 C33 H33 119.0 . . ?
N5 C33 H33 119.0 . . ?
C35 C34 S3 114.4(6) . . ?
C35 C34 H34 122.8 . . ?
S3 C34 H34 122.8 . . ?
C34 C35 C36 109.3(6) . . ?
C34 C35 C31 124.1(7) . . ?
C36 C35 C31 126.6(7) . . ?
C37 C36 C35 113.8(7) . . ?
C37 C36 S4 111.2(6) . . ?
C35 C36 S4 134.9(5) . . ?
C36 C37 C38 113.1(6) . . ?
C36 C37 S3 110.1(6) . . ?
C38 C37 S3 136.7(5) . . ?
C39 C38 C37 109.9(6) . . ?
C39 C38 C42 125.1(7) . . ?
C37 C38 C42 125.0(7) . . ?
C38 C39 S4 115.2(6) . . ?
C38 C39 H39 122.4 . . ?
S4 C39 H39 122.4 . . ?
N8 C40 C41 124.5(8) . . ?
N8 C40 H40 117.8 . . ?
C41 C40 H40 117.8 . . ?
C40 C41 C42 120.1(8) . . ?
C40 C41 H41 120.0 . . ?
C42 C41 H41 120.0 . . ?
C41 C42 C43 115.4(7) . . ?
C41 C42 C38 122.8(7) . . ?
C43 C42 C38 121.8(7) . . ?
C44 C43 C42 120.6(7) . . ?
C44 C43 H43 119.7 . . ?
C42 C43 H43 119.7 . . ?
N8 C44 C43 122.7(7) . . ?
N8 C44 H44 118.6 . . ?
C43 C44 H44 118.6 . . ?
C49 C45 C46 110.7(9) . . ?
C49 C45 C50 125.8(12) . . ?
C46 C45 C50 123.5(12) . . ?
C49 C45 Rh1 71.2(5) . . ?
C46 C45 Rh1 70.6(5) . . ?
C50 C45 Rh1 125.6(6) . . ?
C45 C46 C47 105.8(10) . . ?
C45 C46 C51 128.2(12) . . ?
C47 C46 C51 125.9(12) . . ?
C45 C46 Rh1 71.0(5) . . ?
C47 C46 Rh1 70.4(5) . . ?
C51 C46 Rh1 125.7(7) . . ?
C48 C47 C46 109.9(9) . . ?
C48 C47 C52 125.1(13) . . ?
C46 C47 C52 124.9(13) . . ?
C48 C47 Rh1 70.1(5) . . ?
C46 C47 Rh1 70.2(5) . . ?
C52 C47 Rh1 123.7(6) . . ?
C47 C48 C49 105.6(10) . . ?
C47 C48 C53 129.8(13) . . ?
C49 C48 C53 124.4(15) . . ?
C47 C48 Rh1 71.1(5) . . ?
C49 C48 Rh1 70.6(5) . . ?
C53 C48 Rh1 125.6(8) . . ?
C45 C49 C48 107.9(11) . . ?
C45 C49 C54 128.9(11) . . ?
C48 C49 C54 123.2(13) . . ?
C45 C49 Rh1 70.9(6) . . ?
C48 C49 Rh1 69.3(5) . . ?
C54 C49 Rh1 123.5(7) . . ?
C45 C50 H50A 109.5 . . ?
C45 C50 H50B 109.5 . . ?
H50A C50 H50B 109.5 . . ?
C45 C50 H50C 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
C46 C51 H51A 109.5 . . ?
C46 C51 H51B 109.5 . . ?
H51A C51 H51B 109.5 . . ?
C46 C51 H51C 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
C47 C52 H52A 109.5 . . ?
C47 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C47 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C48 C53 H53A 109.5 . . ?
C48 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C48 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C49 C54 H54A 109.5 . . ?
C49 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
C49 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C60 C55 C56 125.2(10) . . ?
C60 C55 C59 127.2(10) . . ?
C56 C55 C59 107.7(8) . . ?
C60 C55 Rh2 125.4(8) . . ?
C56 C55 Rh2 68.8(5) . . ?
C59 C55 Rh2 70.6(4) . . ?
C55 C56 C61 127.5(11) . . ?
C55 C56 C57 106.4(9) . . ?
C61 C56 C57 126.0(11) . . ?
C55 C56 Rh2 71.6(5) . . ?
C61 C56 Rh2 125.9(9) . . ?
C57 C56 Rh2 70.4(5) . . ?
C58 C57 C56 109.9(9) . . ?
C58 C57 C62 123.1(11) . . ?
C56 C57 C62 126.9(12) . . ?
C58 C57 Rh2 72.2(5) . . ?
C56 C57 Rh2 69.0(5) . . ?
C62 C57 Rh2 122.7(8) . . ?
C57 C58 C59 110.0(9) . . ?
C57 C58 C63 125.6(10) . . ?
C59 C58 C63 124.4(11) . . ?
C57 C58 Rh2 70.2(6) . . ?
C59 C58 Rh2 71.2(5) . . ?
C63 C58 Rh2 126.4(7) . . ?
C64 C59 C58 127.0(10) . . ?
C64 C59 C55 126.8(9) . . ?
C58 C59 C55 106.0(9) . . ?
C64 C59 Rh2 128.6(7) . . ?
C58 C59 Rh2 69.9(5) . . ?
C55 C59 Rh2 68.8(5) . . ?
C55 C60 H60A 109.5 . . ?
C55 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C55 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
C56 C61 H61A 109.5 . . ?
C56 C61 H61B 109.5 . . ?
H61A C61 H61B 109.5 . . ?
C56 C61 H61C 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C57 C62 H62A 109.5 . . ?
C57 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
C57 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
C58 C63 H63A 109.5 . . ?
C58 C63 H63B 109.5 . . ?
H63A C63 H63B 109.5 . . ?
C58 C63 H63C 109.5 . . ?
H63A C63 H63C 109.5 . . ?
H63B C63 H63C 109.5 . . ?
C59 C64 H64A 109.5 . . ?
C59 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C59 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
C66 C65 C69 106.4(10) . . ?
C66 C65 C70 122.4(13) . . ?
C69 C65 C70 131.2(14) . . ?
C66 C65 Rh3 71.5(6) . . ?
C69 C65 Rh3 69.9(6) . . ?
C70 C65 Rh3 124.3(7) . . ?
C67 C66 C65 112.2(12) . . ?
C67 C66 C71 124.2(14) . . ?
C65 C66 C71 123.6(12) . . ?
C67 C66 Rh3 73.0(6) . . ?
C65 C66 Rh3 71.0(5) . . ?
C71 C66 Rh3 124.7(8) . . ?
C66 C67 C68 107.6(12) . . ?
C66 C67 C72 130.0(16) . . ?
C68 C67 C72 122.4(13) . . ?
C66 C67 Rh3 70.6(5) . . ?
C68 C67 Rh3 69.6(6) . . ?
C72 C67 Rh3 122.8(9) . . ?
C67 C68 C69 107.3(11) . . ?
C67 C68 C73 122.6(15) . . ?
C69 C68 C73 130.1(17) . . ?
C67 C68 Rh3 72.0(6) . . ?
C69 C68 Rh3 69.8(6) . . ?
C73 C68 Rh3 122.8(9) . . ?
C68 C69 C65 106.5(12) . . ?
C68 C69 C74 119(2) . . ?
C65 C69 C74 134(2) . . ?
C68 C69 Rh3 71.1(7) . . ?
C65 C69 Rh3 70.7(6) . . ?
C74 C69 Rh3 123.1(9) . . ?
C65 C70 H70A 109.5 . . ?
C65 C70 H70B 109.5 . . ?
H70A C70 H70B 109.5 . . ?
C65 C70 H70C 109.5 . . ?
H70A C70 H70C 109.5 . . ?
H70B C70 H70C 109.5 . . ?
C66 C71 H71A 109.5 . . ?
C66 C71 H71B 109.5 . . ?
H71A C71 H71B 109.5 . . ?
C66 C71 H71C 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
C67 C72 H72A 109.5 . . ?
C67 C72 H72B 109.5 . . ?
H72A C72 H72B 109.5 . . ?
C67 C72 H72C 109.5 . . ?
H72A C72 H72C 109.5 . . ?
H72B C72 H72C 109.5 . . ?
C68 C73 H73A 109.5 . . ?
C68 C73 H73B 109.5 . . ?
H73A C73 H73B 109.5 . . ?
C68 C73 H73C 109.5 . . ?
H73A C73 H73C 109.5 . . ?
H73B C73 H73C 109.5 . . ?
C69 C74 H74A 109.5 . . ?
C69 C74 H74B 109.5 . . ?
H74A C74 H74B 109.5 . . ?
C69 C74 H74C 109.5 . . ?
H74A C74 H74C 109.5 . . ?
H74B C74 H74C 109.5 . . ?
C76 C75 C79 108.3(10) . . ?
C76 C75 C80 126.2(12) . . ?
C79 C75 C80 125.5(9) . . ?
C76 C75 Rh4 70.7(5) . . ?
C79 C75 Rh4 69.8(5) . . ?
C80 C75 Rh4 124.0(7) . . ?
C75 C76 C81 128.6(16) . . ?
C75 C76 C77 108.9(12) . . ?
C81 C76 C77 122.5(14) . . ?
C75 C76 Rh4 71.6(6) . . ?
C81 C76 Rh4 123.5(9) . . ?
C77 C76 Rh4 68.9(6) . . ?
C76 C77 C78 107.5(9) . . ?
C76 C77 C82 131.0(15) . . ?
C78 C77 C82 121.5(15) . . ?
C76 C77 Rh4 71.0(6) . . ?
C78 C77 Rh4 70.5(5) . . ?
C82 C77 Rh4 124.1(8) . . ?
C79 C78 C83 129.3(11) . . ?
C79 C78 C77 104.6(11) . . ?
C83 C78 C77 126.0(11) . . ?
C79 C78 Rh4 70.6(6) . . ?
C83 C78 Rh4 123.1(8) . . ?
C77 C78 Rh4 68.0(6) . . ?
C78 C79 C75 110.7(9) . . ?
C78 C79 C84 121.9(10) . . ?
C75 C79 C84 127.4(9) . . ?
C78 C79 Rh4 70.8(6) . . ?
C75 C79 Rh4 70.6(5) . . ?
C84 C79 Rh4 127.3(7) . . ?
C75 C80 H80A 109.5 . . ?
C75 C80 H80B 109.5 . . ?
H80A C80 H80B 109.5 . . ?
C75 C80 H80C 109.5 . . ?
H80A C80 H80C 109.5 . . ?
H80B C80 H80C 109.5 . . ?
C76 C81 H81A 109.5 . . ?
C76 C81 H81B 109.5 . . ?
H81A C81 H81B 109.5 . . ?
C76 C81 H81C 109.5 . . ?
H81A C81 H81C 109.5 . . ?
H81B C81 H81C 109.5 . . ?
C77 C82 H82A 109.5 . . ?
C77 C82 H82B 109.5 . . ?
H82A C82 H82B 109.5 . . ?
C77 C82 H82C 109.5 . . ?
H82A C82 H82C 109.5 . . ?
H82B C82 H82C 109.5 . . ?
C78 C83 H83A 109.5 . . ?
C78 C83 H83B 109.5 . . ?
H83A C83 H83B 109.5 . . ?
C78 C83 H83C 109.5 . . ?
H83A C83 H83C 109.5 . . ?
H83B C83 H83C 109.5 . . ?
C79 C84 H84A 109.5 . . ?
C79 C84 H84B 109.5 . . ?
H84A C84 H84B 109.5 . . ?
C79 C84 H84C 109.5 . . ?
H84A C84 H84C 109.5 . . ?
H84B C84 H84C 109.5 . . ?
O11 C85 C90 123.6(10) . . ?
O11 C85 C86 115.6(9) . . ?
C90 C85 C86 120.7(9) . . ?
O12 C86 C87 122.7(10) . . ?
O12 C86 C85 115.6(9) . . ?
C87 C86 C85 121.6(10) . . ?
C88 C87 C86 117.7(11) . . ?
C88 C87 H87 121.2 . . ?
C86 C87 H87 121.2 . . ?
O13 C88 C87 123.0(10) . . ?
O13 C88 C89 116.0(9) . . ?
C87 C88 C89 120.9(10) . . ?
O14 C89 C90 121.8(11) . . ?
O14 C89 C88 118.0(10) . . ?
C90 C89 C88 120.2(10) . . ?
C85 C90 C89 117.7(10) . . ?
C85 C90 H90 121.2 . . ?
C89 C90 H90 121.2 . . ?
O16 C91 C96 123.3(6) . . ?
O16 C91 C92 115.8(6) . . ?
C96 C91 C92 120.9(6) . . ?
O15 C92 C93 124.9(6) . . ?
O15 C92 C91 116.7(6) . . ?
C93 C92 C91 118.4(7) . . ?
C94 C93 C92 121.2(7) . . ?
C94 C93 H93 119.4 . . ?
C92 C93 H93 119.4 . . ?
O18 C94 C93 125.9(7) . . ?
O18 C94 C95 114.4(7) . . ?
C93 C94 C95 119.2(6) . . ?
O17 C95 C96 124.4(7) . . ?
O17 C95 C94 116.0(6) . . ?
C96 C95 C94 119.5(7) . . ?
C95 C96 C91 119.7(7) . . ?
C95 C96 H96 120.1 . . ?
C91 C96 H96 120.1 . . ?
N9 C97 C98 124.0(9) . . ?
N9 C97 H97 118.0 . . ?
C98 C97 H97 118.0 . . ?
C99 C98 C97 119.2(8) . . ?
C99 C98 H98 120.4 . . ?
C97 C98 H98 120.4 . . ?
C98 C99 C100 116.8(7) . . ?
C98 C99 C103 121.9(7) . . ?
C100 C99 C103 121.2(7) . . ?
C101 C100 C99 118.0(9) . . ?
C101 C100 H100 121.0 . . ?
C99 C100 H100 121.0 . . ?
N9 C101 C100 124.9(9) . . ?
N9 C101 H101 117.6 . . ?
C100 C101 H101 117.6 . . ?
C102 C103 C104 112.4(12) . . ?
C104 C103 N10 104.5(10) . . ?
C102 C103 C99 118.5(13) . . ?
C104 C103 C99 128.2(7) . . ?
N10 C103 C99 127.2(11) . . ?
C105 C104 C103 113.0(7) . . ?
C105 C104 C207 100.1(10) . . ?
C103 C104 C207 146.9(11) . . ?
C105 C104 S6 113.8(6) . . ?
C103 C104 S6 133.2(6) . . ?
C106 C105 C104 113.6(7) . . ?
C106 C105 C202 142.3(12) . . ?
C104 C105 C202 104.2(11) . . ?
C106 C105 S5 135.1(6) . . ?
C104 C105 S5 111.3(6) . . ?
N11 C106 C105 104.2(14) . . ?
N11 C106 C110 125.7(14) . . ?
C105 C106 C110 130.0(8) . . ?
C105 C106 C107 111.4(12) . . ?
C110 C106 C107 118.5(12) . . ?
N12 C108 C109 121.7(7) . . ?
N12 C108 H108 119.2 . . ?
C109 C108 H108 119.2 . . ?
C108 C109 C110 121.6(8) . . ?
C108 C109 H109 119.2 . . ?
C110 C109 H109 119.2 . . ?
C111 C110 C109 116.1(7) . . ?
C111 C110 C106 121.8(7) . . ?
C109 C110 C106 122.1(8) . . ?
C110 C111 C112 120.8(8) . . ?
C110 C111 H111 119.6 . . ?
C112 C111 H111 119.6 . . ?
N12 C112 C111 121.8(8) . . ?
N12 C112 H112 119.1 . . ?
C111 C112 H112 119.1 . . ?
N13 C113 C114 123.3(12) . . ?
N13 C113 H113 118.3 . . ?
C114 C113 H113 118.3 . . ?
C115 C114 C113 117.5(11) . . ?
C115 C114 H114 121.2 . . ?
C113 C114 H114 121.2 . . ?
C114 C115 C116 119.3(11) . . ?
C114 C115 C119 122.4(11) . . ?
C116 C115 C119 118.3(11) . . ?
C117 C116 C115 116.9(13) . . ?
C117 C116 H116 121.6 . . ?
C115 C116 H116 121.6 . . ?
C116 C117 N13 124.3(14) . . ?
C116 C117 H117 117.9 . . ?
N13 C117 H117 117.9 . . ?
C119 C118 S7 114.1(9) . . ?
C119 C118 H118 122.9 . . ?
S7 C118 H118 122.9 . . ?
C118 C119 C120 111.2(10) . . ?
C118 C119 C115 128.2(11) . . ?
C120 C119 C115 120.6(11) . . ?
C121 C120 C119 111.3(10) . . ?
C121 C120 S8 111.6(9) . . ?
C119 C120 S8 136.9(9) . . ?
C122 C121 C120 112.7(11) . . ?
C122 C121 S7 136.7(8) . . ?
C120 C121 S7 110.5(9) . . ?
C123 C122 C121 110.7(10) . . ?
C123 C122 C126 124.4(13) . . ?
C121 C122 C126 124.9(11) . . ?
C122 C123 S8 114.9(11) . . ?
C122 C123 H123 122.6 . . ?
S8 C123 H123 122.6 . . ?
N16 C124 C125 124.9(11) . . ?
N16 C124 H124 117.6 . . ?
C125 C124 H124 117.6 . . ?
C126 C125 C124 118.9(11) . . ?
C126 C125 H125 120.6 . . ?
C124 C125 H125 120.6 . . ?
C125 C126 C127 115.8(10) . . ?
C125 C126 C122 124.5(11) . . ?
C127 C126 C122 119.6(11) . . ?
C128 C127 C126 121.6(11) . . ?
C128 C127 H127 119.2 . . ?
C126 C127 H127 119.2 . . ?
N16 C128 C127 120.1(12) . . ?
N16 C128 H128 119.9 . . ?
C127 C128 H128 119.9 . . ?
C133 C129 C130 104.3(12) . . ?
C133 C129 C134 131.8(15) . . ?
C130 C129 C134 123.8(14) . . ?
C133 C129 Rh5 69.7(6) . . ?
C130 C129 Rh5 67.8(6) . . ?
C134 C129 Rh5 124.2(7) . . ?
C135 C130 C131 128(2) . . ?
C135 C130 C129 124.0(19) . . ?
C131 C130 C129 108.0(14) . . ?
C135 C130 Rh5 124.8(10) . . ?
C131 C130 Rh5 73.1(8) . . ?
C129 C130 Rh5 71.7(6) . . ?
C132 C131 C130 107.7(17) . . ?
C132 C131 C136 128(2) . . ?
C130 C131 C136 124(2) . . ?
C132 C131 Rh5 70.7(9) . . ?
C130 C131 Rh5 68.4(7) . . ?
C136 C131 Rh5 123.0(12) . . ?
C131 C132 C133 112.7(17) . . ?
C131 C132 C137 124.1(18) . . ?
C133 C132 C137 123(2) . . ?
C131 C132 Rh5 73.5(10) . . ?
C133 C132 Rh5 70.9(7) . . ?
C137 C132 Rh5 125.6(11) . . ?
C132 C133 C129 107.1(15) . . ?
C132 C133 C138 127.0(17) . . ?
C129 C133 C138 125.8(15) . . ?
C132 C133 Rh5 70.8(9) . . ?
C129 C133 Rh5 71.5(6) . . ?
C138 C133 Rh5 124.9(8) . . ?
C129 C134 H13A 109.5 . . ?
C129 C134 H13B 109.5 . . ?
H13A C134 H13B 109.5 . . ?
C129 C134 H13C 109.5 . . ?
H13A C134 H13C 109.5 . . ?
H13B C134 H13C 109.5 . . ?
C130 C135 H13D 109.5 . . ?
C130 C135 H13E 109.5 . . ?
H13D C135 H13E 109.5 . . ?
C130 C135 H13F 109.5 . . ?
H13D C135 H13F 109.5 . . ?
H13E C135 H13F 109.5 . . ?
C131 C136 H13G 109.5 . . ?
C131 C136 H13H 109.5 . . ?
H13G C136 H13H 109.5 . . ?
C131 C136 H13I 109.5 . . ?
H13G C136 H13I 109.5 . . ?
H13H C136 H13I 109.5 . . ?
C132 C137 H13J 109.5 . . ?
C132 C137 H13K 109.5 . . ?
H13J C137 H13K 109.5 . . ?
C132 C137 H13L 109.5 . . ?
H13J C137 H13L 109.5 . . ?
H13K C137 H13L 109.5 . . ?
C133 C138 H13M 109.5 . . ?
C133 C138 H13N 109.5 . . ?
H13M C138 H13N 109.5 . . ?
C133 C138 H13O 109.5 . . ?
H13M C138 H13O 109.5 . . ?
H13N C138 H13O 109.5 . . ?
C140 C139 C143 105.4(12) . . ?
C140 C139 C144 123.1(14) . . ?
C143 C139 C144 131.4(15) . . ?
C140 C139 Rh6 69.7(8) . . ?
C143 C139 Rh6 68.7(7) . . ?
C144 C139 Rh6 122.8(10) . . ?
C141 C140 C139 116.1(15) . . ?
C141 C140 C145 120.8(18) . . ?
C139 C140 C145 123.0(16) . . ?
C141 C140 Rh6 76.0(10) . . ?
C139 C140 Rh6 71.8(8) . . ?
C145 C140 Rh6 124.4(12) . . ?
C140 C141 C146 130(2) . . ?
C140 C141 C142 101.0(14) . . ?
C146 C141 C142 128.1(19) . . ?
C140 C141 Rh6 67.5(9) . . ?
C146 C141 Rh6 120.7(14) . . ?
C142 C141 Rh6 65.5(8) . . ?
C143 C142 C147 127(2) . . ?
C143 C142 C141 109.0(13) . . ?
C147 C142 C141 124(2) . . ?
C143 C142 Rh6 70.3(8) . . ?
C147 C142 Rh6 125.6(12) . . ?
C141 C142 Rh6 72.8(9) . . ?
C142 C143 C148 121.3(17) . . ?
C142 C143 C139 108.4(14) . . ?
C148 C143 C139 130.2(18) . . ?
C142 C143 Rh6 71.3(10) . . ?
C148 C143 Rh6 125.1(11) . . ?
C139 C143 Rh6 71.8(7) . . ?
C139 C144 H14A 109.5 . . ?
C139 C144 H14B 109.5 . . ?
H14A C144 H14B 109.5 . . ?
C139 C144 H14C 109.5 . . ?
H14A C144 H14C 109.5 . . ?
H14B C144 H14C 109.5 . . ?
C140 C145 H14D 109.5 . . ?
C140 C145 H14E 109.5 . . ?
H14D C145 H14E 109.5 . . ?
C140 C145 H14F 109.5 . . ?
H14D C145 H14F 109.5 . . ?
H14E C145 H14F 109.5 . . ?
C141 C146 H14G 109.5 . . ?
C141 C146 H14H 109.5 . . ?
H14G C146 H14H 109.5 . . ?
C141 C146 H14I 109.5 . . ?
H14G C146 H14I 109.5 . . ?
H14H C146 H14I 109.5 . . ?
C142 C147 H14J 109.5 . . ?
C142 C147 H14K 109.5 . . ?
H14J C147 H14K 109.5 . . ?
C142 C147 H14L 109.5 . . ?
H14J C147 H14L 109.5 . . ?
H14K C147 H14L 109.5 . . ?
C143 C148 H14M 109.5 . . ?
C143 C148 H14N 109.5 . . ?
H14M C148 H14N 109.5 . . ?
C143 C148 H14O 109.5 . . ?
H14M C148 H14O 109.5 . . ?
H14N C148 H14O 109.5 . . ?
C150 C149 C153 105.8(8) . . ?
C150 C149 C154 124.5(10) . . ?
C153 C149 C154 129.7(10) . . ?
C150 C149 Rh7 69.0(5) . . ?
C153 C149 Rh7 68.6(5) . . ?
C154 C149 Rh7 125.6(7) . . ?
C151 C150 C149 108.1(9) . . ?
C151 C150 C155 128.1(10) . . ?
C149 C150 C155 123.8(9) . . ?
C151 C150 Rh7 69.4(5) . . ?
C149 C150 Rh7 72.0(5) . . ?
C155 C150 Rh7 123.2(7) . . ?
C152 C151 C150 109.1(9) . . ?
C152 C151 C156 125.9(10) . . ?
C150 C151 C156 124.9(10) . . ?
C152 C151 Rh7 72.6(5) . . ?
C150 C151 Rh7 71.3(5) . . ?
C156 C151 Rh7 124.0(7) . . ?
C151 C152 C153 108.3(9) . . ?
C151 C152 C157 128.5(10) . . ?
C153 C152 C157 123.1(11) . . ?
C151 C152 Rh7 69.4(5) . . ?
C153 C152 Rh7 69.7(5) . . ?
C157 C152 Rh7 123.8(7) . . ?
C152 C153 C149 108.5(9) . . ?
C152 C153 C158 128.5(11) . . ?
C149 C153 C158 122.8(11) . . ?
C152 C153 Rh7 71.4(5) . . ?
C149 C153 Rh7 72.1(5) . . ?
C158 C153 Rh7 126.2(7) . . ?
C149 C154 H15A 109.5 . . ?
C149 C154 H15B 109.5 . . ?
H15A C154 H15B 109.5 . . ?
C149 C154 H15C 109.5 . . ?
H15A C154 H15C 109.5 . . ?
H15B C154 H15C 109.5 . . ?
C150 C155 H15D 109.5 . . ?
C150 C155 H15E 109.5 . . ?
H15D C155 H15E 109.5 . . ?
C150 C155 H15F 109.5 . . ?
H15D C155 H15F 109.5 . . ?
H15E C155 H15F 109.5 . . ?
C151 C156 H15G 109.5 . . ?
C151 C156 H15H 109.5 . . ?
H15G C156 H15H 109.5 . . ?
C151 C156 H15I 109.5 . . ?
H15G C156 H15I 109.5 . . ?
H15H C156 H15I 109.5 . . ?
C152 C157 H15J 109.5 . . ?
C152 C157 H15K 109.5 . . ?
H15J C157 H15K 109.5 . . ?
C152 C157 H15L 109.5 . . ?
H15J C157 H15L 109.5 . . ?
H15K C157 H15L 109.5 . . ?
C153 C158 H15M 109.5 . . ?
C153 C158 H15N 109.5 . . ?
H15M C158 H15N 109.5 . . ?
C153 C158 H15O 109.5 . . ?
H15M C158 H15O 109.5 . . ?
H15N C158 H15O 109.5 . . ?
C160 C159 C163 108.0 . . ?
C160 C159 C164 126.0 . . ?
C163 C159 C164 126.0 . . ?
C160 C159 Rh8 76.9(4) . . ?
C163 C159 Rh8 69.2(3) . . ?
C164 C159 Rh8 119.6(3) . . ?
C161 C160 C159 108.0 . . ?
C161 C160 C165 126.0 . . ?
C159 C160 C165 126.0 . . ?
C161 C160 Rh8 75.2(3) . . ?
C159 C160 Rh8 63.9(4) . . ?
C165 C160 Rh8 126.2(2) . . ?
C160 C161 C162 108.0 . . ?
C160 C161 C166 126.0 . . ?
C162 C161 C166 126.0 . . ?
C160 C161 Rh8 67.9(2) . . ?
C162 C161 Rh8 67.6(2) . . ?
C166 C161 Rh8 130.0(3) . . ?
C163 C162 C161 108.0 . . ?
C163 C162 C167 126.0 . . ?
C161 C162 C167 126.0 . . ?
C163 C162 Rh8 64.0(4) . . ?
C161 C162 Rh8 75.4(3) . . ?
C167 C162 Rh8 126.0(2) . . ?
C162 C163 C159 108.0 . . ?
C162 C163 C168 126.0 . . ?
C159 C163 C168 126.0 . . ?
C162 C163 Rh8 76.8(4) . . ?
C159 C163 Rh8 69.6(2) . . ?
C168 C163 Rh8 119.4(3) . . ?
C159 C164 H16A 109.5 . . ?
C159 C164 H16B 109.5 . . ?
H16A C164 H16B 109.5 . . ?
C159 C164 H16C 109.5 . . ?
H16A C164 H16C 109.5 . . ?
H16B C164 H16C 109.5 . . ?
C160 C165 H16D 109.5 . . ?
C160 C165 H16E 109.5 . . ?
H16D C165 H16E 109.5 . . ?
C160 C165 H16F 109.5 . . ?
H16D C165 H16F 109.5 . . ?
H16E C165 H16F 109.5 . . ?
C161 C166 H16G 109.5 . . ?
C161 C166 H16H 109.5 . . ?
H16G C166 H16H 109.5 . . ?
C161 C166 H16I 109.5 . . ?
H16G C166 H16I 109.5 . . ?
H16H C166 H16I 109.5 . . ?
C162 C167 H16J 109.5 . . ?
C162 C167 H16K 109.5 . . ?
H16J C167 H16K 109.5 . . ?
C162 C167 H16L 109.5 . . ?
H16J C167 H16L 109.5 . . ?
H16K C167 H16L 109.5 . . ?
C163 C168 H16M 109.5 . . ?
C163 C168 H16N 109.5 . . ?
H16M C168 H16N 109.5 . . ?
C163 C168 H16O 109.5 . . ?
H16M C168 H16O 109.5 . . ?
H16N C168 H16O 109.5 . . ?
C260 C259 C263 108.0 . . ?
C260 C259 C264 126.0 . . ?
C263 C259 C264 126.0 . . ?
C260 C259 Rh8 67.5(3) . . ?
C263 C259 Rh8 72.3(3) . . ?
C264 C259 Rh8 125.7(2) . . ?
C259 C260 C261 108.0 . . ?
C259 C260 C265 126.0 . . ?
C261 C260 C265 126.0 . . ?
C259 C260 Rh8 74.2(4) . . ?
C261 C260 Rh8 69.2(3) . . ?
C265 C260 Rh8 122.3(3) . . ?
C262 C261 C260 108.0 . . ?
C262 C261 C266 126.0 . . ?
C260 C261 C266 126.0 . . ?
C262 C261 Rh8 73.2(3) . . ?
C260 C261 Rh8 71.3(2) . . ?
C266 C261 Rh8 121.2(3) . . ?
C261 C262 C263 108.0 . . ?
C261 C262 C267 126.0 . . ?
C263 C262 C267 126.0 . . ?
C261 C262 Rh8 67.8(3) . . ?
C263 C262 Rh8 73.8(3) . . ?
C267 C262 Rh8 124.0(2) . . ?
C262 C263 C259 108.0 . . ?
C262 C263 C268 126.0 . . ?
C259 C263 C268 126.0 . . ?
C262 C263 Rh8 68.5(3) . . ?
C259 C263 Rh8 70.3(2) . . ?
C268 C263 Rh8 126.8(3) . . ?
C259 C264 H26A 109.5 . . ?
C259 C264 H26B 109.5 . . ?
H26A C264 H26B 109.5 . . ?
C259 C264 H26C 109.5 . . ?
H26A C264 H26C 109.5 . . ?
H26B C264 H26C 109.5 . . ?
C260 C265 H26D 109.5 . . ?
C260 C265 H26E 109.5 . . ?
H26D C265 H26E 109.5 . . ?
C260 C265 H26F 109.5 . . ?
H26D C265 H26F 109.5 . . ?
H26E C265 H26F 109.5 . . ?
C261 C266 H26G 109.5 . . ?
C261 C266 H26H 109.5 . . ?
H26G C266 H26H 109.5 . . ?
C261 C266 H26I 109.5 . . ?
H26G C266 H26I 109.5 . . ?
H26H C266 H26I 109.5 . . ?
C262 C267 H26J 109.5 . . ?
C262 C267 H26K 109.5 . . ?
H26J C267 H26K 109.5 . . ?
C262 C267 H26L 109.5 . . ?
H26J C267 H26L 109.5 . . ?
H26K C267 H26L 109.5 . . ?
C263 C268 H26M 109.5 . . ?
C263 C268 H26N 109.5 . . ?
H26M C268 H26N 109.5 . . ?
C263 C268 H26O 109.5 . . ?
H26M C268 H26O 109.5 . . ?
H26N C268 H26O 109.5 . . ?
F3 C169 F1 103.0(19) . . ?
F3 C169 F2 109(2) . . ?
F1 C169 F2 116.6(19) . . ?
F3 C169 S9 110.9(15) . . ?
F1 C169 S9 111.3(14) . . ?
F2 C169 S9 106.3(14) . . ?
F6 C170 F4 105.6(16) . . ?
F6 C170 F5 116(2) . . ?
F4 C170 F5 105.0(16) . . ?
F6 C170 S10 107.3(15) . . ?
F4 C170 S10 110.0(18) . . ?
F5 C170 S10 112.9(11) . . ?
O29 S11 O28 114.5(14) . . ?
O29 S11 O27 111.8(12) . . ?
O28 S11 O27 114.0(14) . . ?
O29 S11 C171 107.8(13) . . ?
O28 S11 C171 110.0(12) . . ?
O27 S11 C171 97.1(16) . . ?
F8 C171 F7 106(2) . . ?
F8 C171 F9 108(2) . . ?
F7 C171 F9 101.4(18) . . ?
F8 C171 S11 113(2) . . ?
F7 C171 S11 113.2(18) . . ?
F9 C171 S11 115(2) . . ?
O29' S11' O27' 110(2) . . ?
O29' S11' O28' 110(2) . . ?
O27' S11' O28' 109(2) . . ?
O29' S11' C271 114(2) . . ?
O27' S11' C271 110(3) . . ?
O28' S11' C271 102(2) . . ?
F9' C271 F8' 107(2) . . ?
F9' C271 F7' 105(2) . . ?
F8' C271 F7' 104(2) . . ?
F9' C271 S11' 115(2) . . ?
F8' C271 S11' 112(2) . . ?
F7' C271 S11' 114(2) . . ?
F11 C172 F12 108(2) . . ?
F11 C172 F10 108(2) . . ?
F12 C172 F10 99.4(19) . . ?
F11 C172 S12 116.0(15) . . ?
F12 C172 S12 111(2) . . ?
F10 C172 S12 113.2(19) . . ?
O31 S12 O30 133.1(15) . . ?
O31 S12 O32 105.7(16) . . ?
O30 S12 O32 102.1(12) . . ?
O31 S12 C172 103.8(12) . . ?
O30 S12 C172 105.7(15) . . ?
O32 S12 C172 103.1(14) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C21 S1 C18 C19 -1(4) . . . . ?
C20 S2 C23 C22 10(4) . . . . ?
C19 N2 C18' O5 177(3) . . . . ?
C19 N2 C18' C21 2(6) . . . . ?
C22 N3 C23' O6 173(3) . . . . ?
C22 N3 C23' C20 -4(4) . . . . ?
C105 S5 C102 C103 9.8(18) . . . . ?
C104 S6 C107 C106 1(2) . . . . ?
C103 N10 C202 O19 -180(5) . . . . ?
C103 N10 C202 C105 -8(6) . . . . ?
C106 N11 C207 O20 172(3) . . . . ?
C106 N11 C207 C104 1(4) . . . . ?
Rh1 O1 C1 C6 -173.7(6) . . . . ?
Rh1 O1 C1 C2 5.6(7) . . . . ?
Rh1 O2 C2 C3 -174.1(5) . . . . ?
Rh1 O2 C2 C1 6.8(7) . . . . ?
O1 C1 C2 O2 -8.5(9) . . . . ?
C6 C1 C2 O2 170.8(6) . . . . ?
O1 C1 C2 C3 172.4(6) . . . . ?
C6 C1 C2 C3 -8.3(10) . . . . ?
O2 C2 C3 C4 -177.1(6) . . . . ?
C1 C2 C3 C4 1.9(10) . . . . ?
Rh2 O3 C4 C3 -171.8(6) . . . . ?
Rh2 O3 C4 C5 5.5(8) . . . . ?
C2 C3 C4 O3 -177.3(7) . . . . ?
C2 C3 C4 C5 5.5(10) . . . . ?
Rh2 O4 C5 C6 -179.2(6) . . . . ?
Rh2 O4 C5 C4 -1.0(8) . . . . ?
O3 C4 C5 O4 -3.1(10) . . . . ?
C3 C4 C5 O4 174.3(7) . . . . ?
O3 C4 C5 C6 175.1(7) . . . . ?
C3 C4 C5 C6 -7.4(11) . . . . ?
O1 C1 C6 C5 -174.4(7) . . . . ?
C2 C1 C6 C5 6.4(11) . . . . ?
O4 C5 C6 C1 179.3(7) . . . . ?
C4 C5 C6 C1 1.2(11) . . . . ?
Rh3 O7 C7 C12 -174.2(5) . . . . ?
Rh3 O7 C7 C8 3.4(7) . . . . ?
Rh3 O8 C8 C9 -173.7(7) . . . . ?
Rh3 O8 C8 C7 4.3(8) . . . . ?
O7 C7 C8 O8 -5.2(9) . . . . ?
C12 C7 C8 O8 172.6(6) . . . . ?
O7 C7 C8 C9 172.9(7) . . . . ?
C12 C7 C8 C9 -9.3(11) . . . . ?
O8 C8 C9 C10 -175.3(7) . . . . ?
C7 C8 C9 C10 6.8(12) . . . . ?
Rh4 O9 C10 C9 176.0(6) . . . . ?
Rh4 O9 C10 C11 -4.2(8) . . . . ?
C8 C9 C10 O9 179.6(8) . . . . ?
C8 C9 C10 C11 -0.2(12) . . . . ?
Rh4 O10 C11 C12 -169.3(5) . . . . ?
Rh4 O10 C11 C10 10.5(8) . . . . ?
O9 C10 C11 O10 -4.3(10) . . . . ?
C9 C10 C11 O10 175.5(7) . . . . ?
O9 C10 C11 C12 175.5(7) . . . . ?
C9 C10 C11 C12 -4.7(11) . . . . ?
O10 C11 C12 C7 -178.0(7) . . . . ?
C10 C11 C12 C7 2.2(10) . . . . ?
O7 C7 C12 C11 -178.1(7) . . . . ?
C8 C7 C12 C11 4.3(10) . . . . ?
C17 N1 C13 C14 -2.0(9) . . . . ?
Rh1 N1 C13 C14 178.5(5) . . . . ?
N1 C13 C14 C15 -0.1(10) . . . . ?
C13 C14 C15 C16 2.1(9) . . . . ?
C13 C14 C15 C19 -175.9(6) . . . . ?
C14 C15 C16 C17 -2.1(10) . . . . ?
C19 C15 C16 C17 175.9(7) . . . . ?
C13 N1 C17 C16 2.0(10) . . . . ?
Rh1 N1 C17 C16 -178.5(6) . . . . ?
C15 C16 C17 N1 0.1(12) . . . . ?
S1 C18 C19 C20 1(4) . . . . ?
S1 C18 C19 C15 -176.3(18) . . . . ?
C14 C15 C19 C18 162(3) . . . . ?
C16 C15 C19 C18 -16(3) . . . . ?
C14 C15 C19 C20 -14.9(10) . . . . ?
C16 C15 C19 C20 167.2(6) . . . . ?
C14 C15 C19 N2 162.4(19) . . . . ?
C16 C15 C19 N2 -15(2) . . . . ?
C18' N2 C19 C20 -1(4) . . . . ?
C18' N2 C19 C15 -178(4) . . . . ?
O6 C23' C20 C21 -175(3) . . . . ?
N3 C23' C20 C21 2(3) . . . . ?
O6 C23' C20 C19 7(4) . . . . ?
N3 C23' C20 C19 -176(2) . . . . ?
C18 C19 C20 C21 0(3) . . . . ?
C15 C19 C20 C21 176.4(6) . . . . ?
N2 C19 C20 C21 -1.4(16) . . . . ?
C15 C19 C20 C23' -6(2) . . . . ?
N2 C19 C20 C23' 177(2) . . . . ?
C18 C19 C20 S2 177(3) . . . . ?
C15 C19 C20 S2 -6.3(10) . . . . ?
C23 S2 C20 C21 -6(2) . . . . ?
C23 S2 C20 C19 177(2) . . . . ?
C23' C20 C21 C22 0.6(12) . . . . ?
C19 C20 C21 C22 179.6(5) . . . . ?
S2 C20 C21 C22 1.8(8) . . . . ?
C23' C20 C21 C18' -176(3) . . . . ?
C19 C20 C21 C18' 3(3) . . . . ?
C19 C20 C21 S1 -0.4(11) . . . . ?
S2 C20 C21 S1 -178.2(10) . . . . ?
O5 C18' C21 C20 -175(8) . . . . ?
N2 C18' C21 C20 -3(5) . . . . ?
O5 C18' C21 C22 9(13) . . . . ?
N2 C18' C21 C22 -178.4(19) . . . . ?
C18 S1 C21 C20 1(2) . . . . ?
C18 S1 C21 C22 -179.3(19) . . . . ?
C23' N3 C22 C21 4(3) . . . . ?
C23' N3 C22 C26 -177.7(17) . . . . ?
S2 C23 C22 C21 -11(5) . . . . ?
S2 C23 C22 C26 174(3) . . . . ?
C20 C21 C22 N3 -3.1(19) . . . . ?
C18' C21 C22 N3 172(5) . . . . ?
C20 C21 C22 C23 5(3) . . . . ?
S1 C21 C22 C23 -175(3) . . . . ?
C20 C21 C22 C26 179.0(7) . . . . ?
C18' C21 C22 C26 -6(5) . . . . ?
S1 C21 C22 C26 -1.1(17) . . . . ?
C28 N4 C24 C25 0.8(12) . . . . ?
Rh3 N4 C24 C25 -175.7(6) . . . . ?
N4 C24 C25 C26 -0.9(11) . . . . ?
C24 C25 C26 C27 0.5(11) . . . . ?
C24 C25 C26 C22 -179.6(7) . . . . ?
N3 C22 C26 C27 -2(2) . . . . ?
C23 C22 C26 C27 -11(3) . . . . ?
C21 C22 C26 C27 175.7(8) . . . . ?
N3 C22 C26 C25 178(2) . . . . ?
C23 C22 C26 C25 169(3) . . . . ?
C21 C22 C26 C25 -4.2(11) . . . . ?
C25 C26 C27 C28 -0.1(12) . . . . ?
C22 C26 C27 C28 180.0(8) . . . . ?
C24 N4 C28 C27 -0.4(13) . . . . ?
Rh3 N4 C28 C27 176.1(7) . . . . ?
C26 C27 C28 N4 0.1(14) . . . . ?
C33 N5 C29 C30 -0.9(11) . . . . ?
Rh2 N5 C29 C30 172.1(6) . . . . ?
N5 C29 C30 C31 -0.4(11) . . . . ?
C29 C30 C31 C32 1.0(11) . . . . ?
C29 C30 C31 C35 -176.4(6) . . . . ?
C30 C31 C32 C33 -0.4(12) . . . . ?
C35 C31 C32 C33 177.1(8) . . . . ?
C31 C32 C33 N5 -1.0(14) . . . . ?
C29 N5 C33 C32 1.6(13) . . . . ?
Rh2 N5 C33 C32 -171.3(7) . . . . ?
C37 S3 C34 C35 0.0(6) . . . . ?
S3 C34 C35 C36 0.0(7) . . . . ?
S3 C34 C35 C31 -179.1(5) . . . . ?
C30 C31 C35 C34 162.4(7) . . . . ?
C32 C31 C35 C34 -14.9(10) . . . . ?
C30 C31 C35 C36 -16.5(10) . . . . ?
C32 C31 C35 C36 166.2(7) . . . . ?
C34 C35 C36 C37 0.0(8) . . . . ?
C31 C35 C36 C37 179.0(6) . . . . ?
C34 C35 C36 S4 177.5(6) . . . . ?
C31 C35 C36 S4 -3.5(10) . . . . ?
C39 S4 C36 C37 1.3(5) . . . . ?
C39 S4 C36 C35 -176.2(7) . . . . ?
C35 C36 C37 C38 177.0(5) . . . . ?
S4 C36 C37 C38 -1.1(7) . . . . ?
C35 C36 C37 S3 0.0(7) . . . . ?
S4 C36 C37 S3 -178.0(3) . . . . ?
C34 S3 C37 C36 0.0(5) . . . . ?
C34 S3 C37 C38 -176.0(7) . . . . ?
C36 C37 C38 C39 0.1(8) . . . . ?
S3 C37 C38 C39 175.9(6) . . . . ?
C36 C37 C38 C42 179.0(6) . . . . ?
S3 C37 C38 C42 -5.1(11) . . . . ?
C37 C38 C39 S4 1.0(8) . . . . ?
C42 C38 C39 S4 -178.0(5) . . . . ?
C36 S4 C39 C38 -1.4(6) . . . . ?
C44 N8 C40 C41 -1.1(13) . . . . ?
Rh4 N8 C40 C41 174.5(7) . . . . ?
N8 C40 C41 C42 0.3(14) . . . . ?
C40 C41 C42 C43 0.9(11) . . . . ?
C40 C41 C42 C38 -176.4(8) . . . . ?
C39 C38 C42 C41 165.4(8) . . . . ?
C37 C38 C42 C41 -13.4(11) . . . . ?
C39 C38 C42 C43 -11.8(11) . . . . ?
C37 C38 C42 C43 169.5(7) . . . . ?
C41 C42 C43 C44 -1.2(11) . . . . ?
C38 C42 C43 C44 176.2(7) . . . . ?
C40 N8 C44 C43 0.8(12) . . . . ?
Rh4 N8 C44 C43 -174.6(6) . . . . ?
C42 C43 C44 N8 0.4(12) . . . . ?
C49 C45 C46 C47 2.2(9) . . . . ?
C50 C45 C46 C47 -177.3(7) . . . . ?
Rh1 C45 C46 C47 62.3(5) . . . . ?
C49 C45 C46 C51 179.1(9) . . . . ?
C50 C45 C46 C51 -0.5(14) . . . . ?
Rh1 C45 C46 C51 -120.9(9) . . . . ?
C49 C45 C46 Rh1 -60.0(6) . . . . ?
C50 C45 C46 Rh1 120.4(8) . . . . ?
C45 C46 C47 C48 -3.6(9) . . . . ?
C51 C46 C47 C48 179.4(9) . . . . ?
Rh1 C46 C47 C48 59.0(6) . . . . ?
C45 C46 C47 C52 179.5(8) . . . . ?
C51 C46 C47 C52 2.6(14) . . . . ?
Rh1 C46 C47 C52 -117.8(8) . . . . ?
C45 C46 C47 Rh1 -62.6(5) . . . . ?
C51 C46 C47 Rh1 120.4(9) . . . . ?
C46 C47 C48 C49 3.6(9) . . . . ?
C52 C47 C48 C49 -179.6(8) . . . . ?
Rh1 C47 C48 C49 62.6(6) . . . . ?
C46 C47 C48 C53 179.9(10) . . . . ?
C52 C47 C48 C53 -3.3(16) . . . . ?
Rh1 C47 C48 C53 -121.1(11) . . . . ?
C46 C47 C48 Rh1 -59.0(6) . . . . ?
C52 C47 C48 Rh1 117.8(9) . . . . ?
C46 C45 C49 C48 -0.1(9) . . . . ?
C50 C45 C49 C48 179.5(8) . . . . ?
Rh1 C45 C49 C48 -59.7(6) . . . . ?
C46 C45 C49 C54 177.7(9) . . . . ?
C50 C45 C49 C54 -2.7(14) . . . . ?
Rh1 C45 C49 C54 118.1(10) . . . . ?
C46 C45 C49 Rh1 59.7(6) . . . . ?
C50 C45 C49 Rh1 -120.8(8) . . . . ?
C47 C48 C49 C45 -2.2(9) . . . . ?
C53 C48 C49 C45 -178.8(10) . . . . ?
Rh1 C48 C49 C45 60.7(6) . . . . ?
C47 C48 C49 C54 179.9(8) . . . . ?
C53 C48 C49 C54 3.3(14) . . . . ?
Rh1 C48 C49 C54 -117.2(9) . . . . ?
C47 C48 C49 Rh1 -62.9(6) . . . . ?
C53 C48 C49 Rh1 120.5(11) . . . . ?
C60 C55 C56 C61 -2.5(17) . . . . ?
C59 C55 C56 C61 178.1(11) . . . . ?
Rh2 C55 C56 C61 -121.6(12) . . . . ?
C60 C55 C56 C57 -178.6(10) . . . . ?
C59 C55 C56 C57 2.1(10) . . . . ?
Rh2 C55 C56 C57 62.3(6) . . . . ?
C60 C55 C56 Rh2 119.1(10) . . . . ?
C59 C55 C56 Rh2 -60.2(6) . . . . ?
C55 C56 C57 C58 -2.2(11) . . . . ?
C61 C56 C57 C58 -178.4(11) . . . . ?
Rh2 C56 C57 C58 60.9(7) . . . . ?
C55 C56 C57 C62 -178.9(10) . . . . ?
C61 C56 C57 C62 4.9(18) . . . . ?
Rh2 C56 C57 C62 -115.8(11) . . . . ?
C55 C56 C57 Rh2 -63.1(6) . . . . ?
C61 C56 C57 Rh2 120.8(11) . . . . ?
C56 C57 C58 C59 1.5(11) . . . . ?
C62 C57 C58 C59 178.3(10) . . . . ?
Rh2 C57 C58 C59 60.4(6) . . . . ?
C56 C57 C58 C63 179.9(9) . . . . ?
C62 C57 C58 C63 -3.3(16) . . . . ?
Rh2 C57 C58 C63 -121.3(10) . . . . ?
C56 C57 C58 Rh2 -58.9(7) . . . . ?
C62 C57 C58 Rh2 118.0(11) . . . . ?
C57 C58 C59 C64 176.5(10) . . . . ?
C63 C58 C59 C64 -1.9(15) . . . . ?
Rh2 C58 C59 C64 -123.7(10) . . . . ?
C57 C58 C59 C55 -0.1(10) . . . . ?
C63 C58 C59 C55 -178.6(9) . . . . ?
Rh2 C58 C59 C55 59.6(6) . . . . ?
C57 C58 C59 Rh2 -59.8(7) . . . . ?
C63 C58 C59 Rh2 121.8(10) . . . . ?
C60 C55 C59 C64 2.8(16) . . . . ?
C56 C55 C59 C64 -177.9(9) . . . . ?
Rh2 C55 C59 C64 123.0(10) . . . . ?
C60 C55 C59 C58 179.5(10) . . . . ?
C56 C55 C59 C58 -1.2(9) . . . . ?
Rh2 C55 C59 C58 -60.3(6) . . . . ?
C60 C55 C59 Rh2 -120.2(10) . . . . ?
C56 C55 C59 Rh2 59.1(6) . . . . ?
C69 C65 C66 C67 0.2(11) . . . . ?
C70 C65 C66 C67 -178.8(9) . . . . ?
Rh3 C65 C66 C67 61.7(7) . . . . ?
C69 C65 C66 C71 178.8(9) . . . . ?
C70 C65 C66 C71 -0.2(15) . . . . ?
Rh3 C65 C66 C71 -119.6(10) . . . . ?
C69 C65 C66 Rh3 -61.6(6) . . . . ?
C70 C65 C66 Rh3 119.4(9) . . . . ?
C65 C66 C67 C68 -0.4(12) . . . . ?
C71 C66 C67 C68 -179.0(10) . . . . ?
Rh3 C66 C67 C68 60.1(8) . . . . ?
C65 C66 C67 C72 -177.5(11) . . . . ?
C71 C66 C67 C72 3.8(18) . . . . ?
Rh3 C66 C67 C72 -117.0(13) . . . . ?
C65 C66 C67 Rh3 -60.5(7) . . . . ?
C71 C66 C67 Rh3 120.9(10) . . . . ?
C66 C67 C68 C69 0.5(13) . . . . ?
C72 C67 C68 C69 177.8(11) . . . . ?
Rh3 C67 C68 C69 61.2(7) . . . . ?
C66 C67 C68 C73 -178.6(11) . . . . ?
C72 C67 C68 C73 -1.2(18) . . . . ?
Rh3 C67 C68 C73 -117.9(12) . . . . ?
C66 C67 C68 Rh3 -60.7(7) . . . . ?
C72 C67 C68 Rh3 116.7(11) . . . . ?
C67 C68 C69 C65 -0.3(12) . . . . ?
C73 C68 C69 C65 178.6(12) . . . . ?
Rh3 C68 C69 C65 62.3(7) . . . . ?
C67 C68 C69 C74 179.3(11) . . . . ?
C73 C68 C69 C74 -1.7(19) . . . . ?
Rh3 C68 C69 C74 -118.1(11) . . . . ?
C67 C68 C69 Rh3 -62.6(8) . . . . ?
C73 C68 C69 Rh3 116.3(13) . . . . ?
C66 C65 C69 C68 0.1(11) . . . . ?
C70 C65 C69 C68 179.0(10) . . . . ?
Rh3 C65 C69 C68 -62.6(7) . . . . ?
C66 C65 C69 C74 -179.5(13) . . . . ?
C70 C65 C69 C74 -1(2) . . . . ?
Rh3 C65 C69 C74 117.9(14) . . . . ?
C66 C65 C69 Rh3 62.7(6) . . . . ?
C70 C65 C69 Rh3 -118.4(11) . . . . ?
C79 C75 C76 C81 -178.5(11) . . . . ?
C80 C75 C76 C81 -0.1(18) . . . . ?
Rh4 C75 C76 C81 -118.6(13) . . . . ?
C79 C75 C76 C77 -0.8(11) . . . . ?
C80 C75 C76 C77 177.5(9) . . . . ?
Rh4 C75 C76 C77 59.0(7) . . . . ?
C79 C75 C76 Rh4 -59.9(7) . . . . ?
C80 C75 C76 Rh4 118.5(10) . . . . ?
C75 C76 C77 C78 0.6(11) . . . . ?
C81 C76 C77 C78 178.4(10) . . . . ?
Rh4 C76 C77 C78 61.3(7) . . . . ?
C75 C76 C77 C82 -179.9(11) . . . . ?
C81 C76 C77 C82 -2.0(19) . . . . ?
Rh4 C76 C77 C82 -119.1(12) . . . . ?
C75 C76 C77 Rh4 -60.7(7) . . . . ?
C81 C76 C77 Rh4 117.1(11) . . . . ?
C76 C77 C78 C79 -0.1(10) . . . . ?
C82 C77 C78 C79 -179.7(10) . . . . ?
Rh4 C77 C78 C79 61.6(6) . . . . ?
C76 C77 C78 C83 -177.4(10) . . . . ?
C82 C77 C78 C83 3.0(16) . . . . ?
Rh4 C77 C78 C83 -115.7(11) . . . . ?
C76 C77 C78 Rh4 -61.7(7) . . . . ?
C82 C77 C78 Rh4 118.7(10) . . . . ?
C83 C78 C79 C75 176.8(10) . . . . ?
C77 C78 C79 C75 -0.4(10) . . . . ?
Rh4 C78 C79 C75 59.5(7) . . . . ?
C83 C78 C79 C84 -5.3(16) . . . . ?
C77 C78 C79 C84 177.5(9) . . . . ?
Rh4 C78 C79 C84 -122.6(9) . . . . ?
C83 C78 C79 Rh4 117.3(11) . . . . ?
C77 C78 C79 Rh4 -59.9(6) . . . . ?
C76 C75 C79 C78 0.8(11) . . . . ?
C80 C75 C79 C78 -177.6(9) . . . . ?
Rh4 C75 C79 C78 -59.6(7) . . . . ?
C76 C75 C79 C84 -177.0(10) . . . . ?
C80 C75 C79 C84 4.6(16) . . . . ?
Rh4 C75 C79 C84 122.6(10) . . . . ?
C76 C75 C79 Rh4 60.4(7) . . . . ?
C80 C75 C79 Rh4 -118.0(10) . . . . ?
Rh5 O11 C85 C90 -172.8(7) . . . . ?
Rh5 O11 C85 C86 3.8(10) . . . . ?
Rh5 O12 C86 C87 -172.9(7) . . . . ?
Rh5 O12 C86 C85 4.8(10) . . . . ?
O11 C85 C86 O12 -5.8(12) . . . . ?
C90 C85 C86 O12 170.8(9) . . . . ?
O11 C85 C86 C87 171.9(9) . . . . ?
C90 C85 C86 C87 -11.4(14) . . . . ?
O12 C86 C87 C88 -179.6(9) . . . . ?
C85 C86 C87 C88 2.8(14) . . . . ?
Rh6 O13 C88 C87 -174.6(8) . . . . ?
Rh6 O13 C88 C89 2.7(10) . . . . ?
C86 C87 C88 O13 -176.4(9) . . . . ?
C86 C87 C88 C89 6.5(14) . . . . ?
Rh6 O14 C89 C90 -174.5(8) . . . . ?
Rh6 O14 C89 C88 6.3(12) . . . . ?
O13 C88 C89 O14 -6.3(14) . . . . ?
C87 C88 C89 O14 171.1(10) . . . . ?
O13 C88 C89 C90 174.4(9) . . . . ?
C87 C88 C89 C90 -8.2(14) . . . . ?
O11 C85 C90 C89 -174.2(9) . . . . ?
C86 C85 C90 C89 9.4(14) . . . . ?
O14 C89 C90 C85 -179.5(10) . . . . ?
C88 C89 C90 C85 -0.2(14) . . . . ?
Rh7 O16 C91 C96 -175.8(6) . . . . ?
Rh7 O16 C91 C92 4.2(8) . . . . ?
Rh7 O15 C92 C93 -172.9(5) . . . . ?
Rh7 O15 C92 C91 6.5(7) . . . . ?
O16 C91 C92 O15 -7.3(9) . . . . ?
C96 C91 C92 O15 172.7(7) . . . . ?
O16 C91 C92 C93 172.1(6) . . . . ?
C96 C91 C92 C93 -7.9(10) . . . . ?
O15 C92 C93 C94 -178.6(7) . . . . ?
C91 C92 C93 C94 2.1(10) . . . . ?
Rh8 O18 C94 C93 -161.4(6) . . . . ?
Rh8 O18 C94 C95 10.8(8) . . . . ?
C92 C93 C94 O18 179.4(7) . . . . ?
C92 C93 C94 C95 7.5(11) . . . . ?
Rh8 O17 C95 C96 175.3(7) . . . . ?
Rh8 O17 C95 C94 -8.7(9) . . . . ?
O18 C94 C95 O17 -1.5(10) . . . . ?
C93 C94 C95 O17 171.3(7) . . . . ?
O18 C94 C95 C96 174.7(7) . . . . ?
C93 C94 C95 C96 -12.5(11) . . . . ?
O17 C95 C96 C91 -177.3(8) . . . . ?
C94 C95 C96 C91 6.8(12) . . . . ?
O16 C91 C96 C95 -177.0(7) . . . . ?
C92 C91 C96 C95 2.9(12) . . . . ?
C101 N9 C97 C98 -0.1(12) . . . . ?
Rh5 N9 C97 C98 177.0(6) . . . . ?
N9 C97 C98 C99 -1.3(12) . . . . ?
C97 C98 C99 C100 2.2(10) . . . . ?
C97 C98 C99 C103 -174.0(7) . . . . ?
C98 C99 C100 C101 -1.7(12) . . . . ?
C103 C99 C100 C101 174.5(8) . . . . ?
C97 N9 C101 C100 0.6(14) . . . . ?
Rh5 N9 C101 C100 -176.6(7) . . . . ?
C99 C100 C101 N9 0.4(14) . . . . ?
S5 C102 C103 C104 -11.6(19) . . . . ?
S5 C102 C103 C99 178.4(10) . . . . ?
C202 N10 C103 C104 8(4) . . . . ?
C202 N10 C103 C99 -174(4) . . . . ?
C98 C99 C103 C102 150.3(14) . . . . ?
C100 C99 C103 C102 -25.8(16) . . . . ?
C98 C99 C103 C104 -17.9(11) . . . . ?
C100 C99 C103 C104 166.0(7) . . . . ?
C98 C99 C103 N10 164.8(13) . . . . ?
C100 C99 C103 N10 -11.3(16) . . . . ?
C102 C103 C104 C105 8.2(14) . . . . ?
N10 C103 C104 C105 -5.2(12) . . . . ?
C99 C103 C104 C105 177.0(6) . . . . ?
N10 C103 C104 C207 173(3) . . . . ?
C99 C103 C104 C207 -5(3) . . . . ?
C102 C103 C104 S6 -173.5(13) . . . . ?
C99 C103 C104 S6 -4.7(11) . . . . ?
O20 C207 C104 C105 -170(4) . . . . ?
N11 C207 C104 C105 -2(3) . . . . ?
O20 C207 C104 C103 11(6) . . . . ?
N11 C207 C104 C103 -180(2) . . . . ?
C107 S6 C104 C105 -1.6(14) . . . . ?
C107 S6 C104 C103 -179.8(15) . . . . ?
C103 C104 C105 C106 -179.4(6) . . . . ?
C207 C104 C105 C106 1.8(14) . . . . ?
S6 C104 C105 C106 2.0(7) . . . . ?
C103 C104 C105 C202 0(3) . . . . ?
C207 C104 C105 C202 -178(4) . . . . ?
C103 C104 C105 S5 -0.5(9) . . . . ?
S6 C104 C105 S5 -179.1(7) . . . . ?
O19 C202 C105 C106 -6(13) . . . . ?
N10 C202 C105 C106 -175.6(13) . . . . ?
O19 C202 C105 C104 174(8) . . . . ?
N10 C202 C105 C104 5(5) . . . . ?
C102 S5 C105 C106 173.2(11) . . . . ?
C102 S5 C105 C104 -5.3(13) . . . . ?
C207 N11 C106 C105 0(3) . . . . ?
C207 N11 C106 C110 -179.8(19) . . . . ?
C104 C105 C106 N11 -1(2) . . . . ?
C202 C105 C106 N11 179(6) . . . . ?
C104 C105 C106 C110 178.5(6) . . . . ?
C202 C105 C106 C110 -1(5) . . . . ?
S5 C105 C106 C110 0.0(15) . . . . ?
C104 C105 C106 C107 -1.4(18) . . . . ?
S5 C105 C106 C107 -179.9(19) . . . . ?
S6 C107 C106 C105 0(3) . . . . ?
S6 C107 C106 C110 -179.7(13) . . . . ?
C112 N12 C108 C109 -0.1(10) . . . . ?
Rh7 N12 C108 C109 -177.4(5) . . . . ?
N12 C108 C109 C110 -0.6(11) . . . . ?
C108 C109 C110 C111 1.5(10) . . . . ?
C108 C109 C110 C106 -179.7(6) . . . . ?
N11 C106 C110 C111 -5(3) . . . . ?
C105 C106 C110 C111 175.3(7) . . . . ?
C107 C106 C110 C111 -5(2) . . . . ?
N11 C106 C110 C109 176(2) . . . . ?
C105 C106 C110 C109 -3.4(11) . . . . ?
C107 C106 C110 C109 176.5(19) . . . . ?
C109 C110 C111 C112 -1.8(11) . . . . ?
C106 C110 C111 C112 179.4(7) . . . . ?
C108 N12 C112 C111 -0.3(12) . . . . ?
Rh7 N12 C112 C111 177.2(6) . . . . ?
C110 C111 C112 N12 1.3(13) . . . . ?
C117 N13 C113 C114 -0.6(18) . . . . ?
Rh6 N13 C113 C114 177.4(8) . . . . ?
N13 C113 C114 C115 -2.0(17) . . . . ?
C113 C114 C115 C116 2.3(15) . . . . ?
C113 C114 C115 C119 -175.9(9) . . . . ?
C114 C115 C116 C117 -0.2(17) . . . . ?
C119 C115 C116 C117 178.1(11) . . . . ?
C115 C116 C117 N13 -3(2) . . . . ?
C113 N13 C117 C116 3(2) . . . . ?
Rh6 N13 C117 C116 -175.0(11) . . . . ?
C121 S7 C118 C119 -1.6(7) . . . . ?
S7 C118 C119 C120 0.6(9) . . . . ?
S7 C118 C119 C115 -177.0(7) . . . . ?
C114 C115 C119 C118 156.7(10) . . . . ?
C116 C115 C119 C118 -21.5(14) . . . . ?
C114 C115 C119 C120 -20.7(13) . . . . ?
C116 C115 C119 C120 161.1(9) . . . . ?
C118 C119 C120 C121 1.0(10) . . . . ?
C115 C119 C120 C121 178.8(7) . . . . ?
C118 C119 C120 S8 174.3(7) . . . . ?
C115 C119 C120 S8 -7.9(14) . . . . ?
C123 S8 C120 C121 -0.5(7) . . . . ?
C123 S8 C120 C119 -173.7(10) . . . . ?
C119 C120 C121 C122 175.3(7) . . . . ?
S8 C120 C121 C122 0.3(9) . . . . ?
C119 C120 C121 S7 -2.1(9) . . . . ?
S8 C120 C121 S7 -177.2(4) . . . . ?
C118 S7 C121 C122 -174.5(9) . . . . ?
C118 S7 C121 C120 2.1(6) . . . . ?
C120 C121 C122 C123 0.2(10) . . . . ?
S7 C121 C122 C123 176.7(8) . . . . ?
C120 C121 C122 C126 178.1(8) . . . . ?
S7 C121 C122 C126 -5.3(14) . . . . ?
C121 C122 C123 S8 -0.6(10) . . . . ?
C126 C122 C123 S8 -178.5(7) . . . . ?
C120 S8 C123 C122 0.6(8) . . . . ?
C128 N16 C124 C125 -1.4(16) . . . . ?
Rh8 N16 C124 C125 170.5(9) . . . . ?
N16 C124 C125 C126 -1.3(17) . . . . ?
C124 C125 C126 C127 3.0(15) . . . . ?
C124 C125 C126 C122 -174.9(10) . . . . ?
C123 C122 C126 C125 167.9(10) . . . . ?
C121 C122 C126 C125 -9.8(15) . . . . ?
C123 C122 C126 C127 -10.0(14) . . . . ?
C121 C122 C126 C127 172.3(9) . . . . ?
C125 C126 C127 C128 -2.4(15) . . . . ?
C122 C126 C127 C128 175.6(9) . . . . ?
C124 N16 C128 C127 2.1(15) . . . . ?
Rh8 N16 C128 C127 -170.0(8) . . . . ?
C126 C127 C128 N16 -0.1(16) . . . . ?
C133 C129 C130 C135 179.2(11) . . . . ?
C134 C129 C130 C135 -3.0(16) . . . . ?
Rh5 C129 C130 C135 -120.2(12) . . . . ?
C133 C129 C130 C131 4.0(11) . . . . ?
C134 C129 C130 C131 -178.2(10) . . . . ?
Rh5 C129 C130 C131 64.6(8) . . . . ?
C133 C129 C130 Rh5 -60.6(6) . . . . ?
C134 C129 C130 Rh5 117.2(9) . . . . ?
C135 C130 C131 C132 -178.5(13) . . . . ?
C129 C130 C131 C132 -3.6(15) . . . . ?
Rh5 C130 C131 C132 60.1(11) . . . . ?
C135 C130 C131 C136 5(2) . . . . ?
C129 C130 C131 C136 -179.7(13) . . . . ?
Rh5 C130 C131 C136 -116.0(15) . . . . ?
C135 C130 C131 Rh5 121.4(14) . . . . ?
C129 C130 C131 Rh5 -63.7(7) . . . . ?
C130 C131 C132 C133 1.7(17) . . . . ?
C136 C131 C132 C133 177.6(14) . . . . ?
Rh5 C131 C132 C133 60.3(10) . . . . ?
C130 C131 C132 C137 179.2(13) . . . . ?
C136 C131 C132 C137 -5(3) . . . . ?
Rh5 C131 C132 C137 -122.1(15) . . . . ?
C130 C131 C132 Rh5 -58.6(9) . . . . ?
C136 C131 C132 Rh5 117.3(17) . . . . ?
C131 C132 C133 C129 0.9(15) . . . . ?
C137 C132 C133 C129 -176.7(13) . . . . ?
Rh5 C132 C133 C129 62.7(7) . . . . ?
C131 C132 C133 C138 178.5(12) . . . . ?
C137 C132 C133 C138 1(2) . . . . ?
Rh5 C132 C133 C138 -119.7(12) . . . . ?
C131 C132 C133 Rh5 -61.9(12) . . . . ?
C137 C132 C133 Rh5 120.6(15) . . . . ?
C130 C129 C133 C132 -2.9(11) . . . . ?
C134 C129 C133 C132 179.5(11) . . . . ?
Rh5 C129 C133 C132 -62.3(8) . . . . ?
C130 C129 C133 C138 179.5(10) . . . . ?
C134 C129 C133 C138 1.9(18) . . . . ?
Rh5 C129 C133 C138 120.1(11) . . . . ?
C130 C129 C133 Rh5 59.3(6) . . . . ?
C134 C129 C133 Rh5 -118.2(11) . . . . ?
C143 C139 C140 C141 3.8(18) . . . . ?
C144 C139 C140 C141 -179.8(15) . . . . ?
Rh6 C139 C140 C141 63.6(13) . . . . ?
C143 C139 C140 C145 -179.5(14) . . . . ?
C144 C139 C140 C145 -3(2) . . . . ?
Rh6 C139 C140 C145 -119.7(15) . . . . ?
C143 C139 C140 Rh6 -59.7(9) . . . . ?
C144 C139 C140 Rh6 116.6(14) . . . . ?
C139 C140 C141 C146 -173.3(18) . . . . ?
C145 C140 C141 C146 10(3) . . . . ?
Rh6 C140 C141 C146 -112(2) . . . . ?
C139 C140 C141 C142 -3.9(19) . . . . ?
C145 C140 C141 C142 179.3(14) . . . . ?
Rh6 C140 C141 C142 57.4(11) . . . . ?
C139 C140 C141 Rh6 -61.3(12) . . . . ?
C145 C140 C141 Rh6 121.9(16) . . . . ?
C140 C141 C142 C143 2.5(18) . . . . ?
C146 C141 C142 C143 172.2(17) . . . . ?
Rh6 C141 C142 C143 61.4(11) . . . . ?
C140 C141 C142 C147 179.3(16) . . . . ?
C146 C141 C142 C147 -11(3) . . . . ?
Rh6 C141 C142 C147 -121.8(17) . . . . ?
C140 C141 C142 Rh6 -58.9(11) . . . . ?
C146 C141 C142 Rh6 110.9(19) . . . . ?
C147 C142 C143 C148 0(3) . . . . ?
C141 C142 C143 C148 176.7(15) . . . . ?
Rh6 C142 C143 C148 -120.3(15) . . . . ?
C147 C142 C143 C139 -177.1(15) . . . . ?
C141 C142 C143 C139 -0.4(17) . . . . ?
Rh6 C142 C143 C139 62.5(10) . . . . ?
C147 C142 C143 Rh6 120.4(17) . . . . ?
C141 C142 C143 Rh6 -62.9(11) . . . . ?
C140 C139 C143 C142 -1.8(16) . . . . ?
C144 C139 C143 C142 -177.7(15) . . . . ?
Rh6 C139 C143 C142 -62.2(11) . . . . ?
C140 C139 C143 C148 -178.6(16) . . . . ?
C144 C139 C143 C148 5(3) . . . . ?
Rh6 C139 C143 C148 121.0(17) . . . . ?
C140 C139 C143 Rh6 60.4(9) . . . . ?
C144 C139 C143 Rh6 -115.5(16) . . . . ?
C153 C149 C150 C151 1.3(9) . . . . ?
C154 C149 C150 C151 179.8(9) . . . . ?
Rh7 C149 C150 C151 60.3(6) . . . . ?
C153 C149 C150 C155 -177.4(8) . . . . ?
C154 C149 C150 C155 1.2(14) . . . . ?
Rh7 C149 C150 C155 -118.4(9) . . . . ?
C153 C149 C150 Rh7 -59.0(6) . . . . ?
C154 C149 C150 Rh7 119.5(9) . . . . ?
C149 C150 C151 C152 1.3(10) . . . . ?
C155 C150 C151 C152 179.9(9) . . . . ?
Rh7 C150 C151 C152 63.2(6) . . . . ?
C149 C150 C151 C156 179.2(8) . . . . ?
C155 C150 C151 C156 -2.2(15) . . . . ?
Rh7 C150 C151 C156 -118.9(9) . . . . ?
C149 C150 C151 Rh7 -61.9(6) . . . . ?
C155 C150 C151 Rh7 116.7(9) . . . . ?
C150 C151 C152 C153 -3.4(10) . . . . ?
C156 C151 C152 C153 178.8(9) . . . . ?
Rh7 C151 C152 C153 59.0(6) . . . . ?
C150 C151 C152 C157 -179.7(9) . . . . ?
C156 C151 C152 C157 2.4(16) . . . . ?
Rh7 C151 C152 C157 -117.3(10) . . . . ?
C150 C151 C152 Rh7 -62.4(6) . . . . ?
C156 C151 C152 Rh7 119.7(9) . . . . ?
C151 C152 C153 C149 4.2(10) . . . . ?
C157 C152 C153 C149 -179.2(9) . . . . ?
Rh7 C152 C153 C149 63.0(6) . . . . ?
C151 C152 C153 C158 179.2(9) . . . . ?
C157 C152 C153 C158 -4.2(16) . . . . ?
Rh7 C152 C153 C158 -122.0(10) . . . . ?
C151 C152 C153 Rh7 -58.8(6) . . . . ?
C157 C152 C153 Rh7 117.8(9) . . . . ?
C150 C149 C153 C152 -3.3(9) . . . . ?
C154 C149 C153 C152 178.2(9) . . . . ?
Rh7 C149 C153 C152 -62.5(6) . . . . ?
C150 C149 C153 C158 -178.7(8) . . . . ?
C154 C149 C153 C158 2.8(15) . . . . ?
Rh7 C149 C153 C158 122.1(9) . . . . ?
C150 C149 C153 Rh7 59.2(6) . . . . ?
C154 C149 C153 Rh7 -119.2(10) . . . . ?
C163 C159 C160 C161 0.0 . . . . ?
C164 C159 C160 C161 -180.0 . . . . ?
Rh8 C159 C160 C161 62.7(3) . . . . ?
C163 C159 C160 C165 180.0 . . . . ?
C164 C159 C160 C165 0.0 . . . . ?
Rh8 C159 C160 C165 -117.3(3) . . . . ?
C163 C159 C160 Rh8 -62.7(3) . . . . ?
C164 C159 C160 Rh8 117.3(3) . . . . ?
C159 C160 C161 C162 0.0 . . . . ?
C165 C160 C161 C162 180.0 . . . . ?
Rh8 C160 C161 C162 55.7(3) . . . . ?
C159 C160 C161 C166 -180.0 . . . . ?
C165 C160 C161 C166 0.0 . . . . ?
Rh8 C160 C161 C166 -124.3(3) . . . . ?
C159 C160 C161 Rh8 -55.7(3) . . . . ?
C165 C160 C161 Rh8 124.3(3) . . . . ?
C160 C161 C162 C163 0.0 . . . . ?
C166 C161 C162 C163 180.0 . . . . ?
Rh8 C161 C162 C163 55.9(3) . . . . ?
C160 C161 C162 C167 -180.0 . . . . ?
C166 C161 C162 C167 0.0 . . . . ?
Rh8 C161 C162 C167 -124.1(3) . . . . ?
C160 C161 C162 Rh8 -55.9(3) . . . . ?
C166 C161 C162 Rh8 124.1(3) . . . . ?
C161 C162 C163 C159 0.0 . . . . ?
C167 C162 C163 C159 180.0 . . . . ?
Rh8 C162 C163 C159 63.1(3) . . . . ?
C161 C162 C163 C168 180.0 . . . . ?
C167 C162 C163 C168 0.0 . . . . ?
Rh8 C162 C163 C168 -117.0(2) . . . . ?
C161 C162 C163 Rh8 -63.1(2) . . . . ?
C167 C162 C163 Rh8 116.9(2) . . . . ?
C160 C159 C163 C162 0.0 . . . . ?
C164 C159 C163 C162 180.0 . . . . ?
Rh8 C159 C163 C162 -67.8(4) . . . . ?
C160 C159 C163 C168 -180.0 . . . . ?
C164 C159 C163 C168 0.0 . . . . ?
Rh8 C159 C163 C168 112.2(4) . . . . ?
C160 C159 C163 Rh8 67.8(4) . . . . ?
C164 C159 C163 Rh8 -112.2(4) . . . . ?
C263 C259 C260 C261 0.0 . . . . ?
C264 C259 C260 C261 -180.0 . . . . ?
Rh8 C259 C260 C261 61.3(2) . . . . ?
C263 C259 C260 C265 180.0 . . . . ?
C264 C259 C260 C265 0.0 . . . . ?
Rh8 C259 C260 C265 -118.7(2) . . . . ?
C263 C259 C260 Rh8 -61.3(2) . . . . ?
C264 C259 C260 Rh8 118.7(2) . . . . ?
C259 C260 C261 C262 0.0 . . . . ?
C265 C260 C261 C262 -180.0 . . . . ?
Rh8 C260 C261 C262 64.5(4) . . . . ?
C259 C260 C261 C266 180.0 . . . . ?
C265 C260 C261 C266 0.0 . . . . ?
Rh8 C260 C261 C266 -115.5(4) . . . . ?
C259 C260 C261 Rh8 -64.5(4) . . . . ?
C265 C260 C261 Rh8 115.5(4) . . . . ?
C260 C261 C262 C263 0.0 . . . . ?
C266 C261 C262 C263 180.0 . . . . ?
Rh8 C261 C262 C263 63.3(3) . . . . ?
C260 C261 C262 C267 180.0 . . . . ?
C266 C261 C262 C267 0.0 . . . . ?
Rh8 C261 C262 C267 -116.7(3) . . . . ?
C260 C261 C262 Rh8 -63.3(3) . . . . ?
C266 C261 C262 Rh8 116.7(3) . . . . ?
C261 C262 C263 C259 0.0 . . . . ?
C267 C262 C263 C259 180.0 . . . . ?
Rh8 C262 C263 C259 59.4(3) . . . . ?
C261 C262 C263 C268 180.0 . . . . ?
C267 C262 C263 C268 0.0 . . . . ?
Rh8 C262 C263 C268 -120.6(3) . . . . ?
C261 C262 C263 Rh8 -59.4(3) . . . . ?
C267 C262 C263 Rh8 120.6(3) . . . . ?
C260 C259 C263 C262 0.0 . . . . ?
C264 C259 C263 C262 180.0 . . . . ?
Rh8 C259 C263 C262 -58.3(3) . . . . ?
C260 C259 C263 C268 -180.0 . . . . ?
C264 C259 C263 C268 0.0 . . . . ?
Rh8 C259 C263 C268 121.7(3) . . . . ?
C260 C259 C263 Rh8 58.3(3) . . . . ?
C264 C259 C263 Rh8 -121.7(3) . . . . ?
O21 S9 C169 F3 60.4(18) . . . . ?
O22 S9 C169 F3 176.3(17) . . . . ?
O23 S9 C169 F3 -59.3(19) . . . . ?
O21 S9 C169 F1 174.5(16) . . . . ?
O22 S9 C169 F1 -69.6(19) . . . . ?
O23 S9 C169 F1 55(2) . . . . ?
O21 S9 C169 F2 -57.5(18) . . . . ?
O22 S9 C169 F2 58.4(18) . . . . ?
O23 S9 C169 F2 -177.2(19) . . . . ?
O24 S10 C170 F6 176(2) . . . . ?
O25 S10 C170 F6 -53(2) . . . . ?
O26 S10 C170 F6 67.3(18) . . . . ?
O24 S10 C170 F4 -70(3) . . . . ?
O25 S10 C170 F4 61.4(17) . . . . ?
O26 S10 C170 F4 -178.4(15) . . . . ?
O24 S10 C170 F5 47(3) . . . . ?
O25 S10 C170 F5 178.3(17) . . . . ?
O26 S10 C170 F5 -61(2) . . . . ?
O29 S11 C171 F8 58(2) . . . . ?
O28 S11 C171 F8 -68(2) . . . . ?
O27 S11 C171 F8 173(2) . . . . ?
O29 S11 C171 F7 -62(2) . . . . ?
O28 S11 C171 F7 172.6(19) . . . . ?
O27 S11 C171 F7 54(2) . . . . ?
O29 S11 C171 F9 -177.8(17) . . . . ?
O28 S11 C171 F9 57(2) . . . . ?
O27 S11 C171 F9 -62(2) . . . . ?
O29' S11' C271 F9' -99(3) . . . . ?
O27' S11' C271 F9' 136(3) . . . . ?
O28' S11' C271 F9' 20(3) . . . . ?
O29' S11' C271 F8' 22(3) . . . . ?
O27' S11' C271 F8' -103(3) . . . . ?
O28' S11' C271 F8' 141(3) . . . . ?
O29' S11' C271 F7' 139(3) . . . . ?
O27' S11' C271 F7' 14(3) . . . . ?
O28' S11' C271 F7' -102(3) . . . . ?
F11 C172 S12 O31 -159(2) . . . . ?
F12 C172 S12 O31 -35(2) . . . . ?
F10 C172 S12 O31 76(2) . . . . ?
F11 C172 S12 O30 58(2) . . . . ?
F12 C172 S12 O30 -178.5(19) . . . . ?
F10 C172 S12 O30 -68(2) . . . . ?
F11 C172 S12 O32 -49(2) . . . . ?
F12 C172 S12 O32 75(2) . . . . ?
F10 C172 S12 O32 -174(2) . . . . ?

_refine_diff_density_max         2.775
_refine_diff_density_min         -1.220
_refine_diff_density_rms         0.120



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Hetero-7
_database_code_depnum_ccdc_archive 'CCDC 1946054'
loop_
_audit_author_name
_audit_author_address
Lu
;Fudan university
China
;
_audit_update_record             
;
2019-08-08 deposited with the CCDC.	2020-10-05 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C208 H264 F24 N26 O68 Rh8 S10'
_chemical_formula_weight         5816.32

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0137 0.0067 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0583 0.0400 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0241 0.0134 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0389 0.0241 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -0.0161 2.8414 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.2925 0.4295 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   22.383(4)
_cell_length_b                   24.161(4)
_cell_length_c                   24.592(4)
_cell_angle_alpha                92.104(7)
_cell_angle_beta                 98.905(7)
_cell_angle_gamma                102.575(7)
_cell_volume                     12790(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    9745
_cell_measurement_theta_min      3.27
_cell_measurement_theta_max      55.72

_exptl_crystal_description       block
_exptl_crystal_colour            brown
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.510
_exptl_crystal_F_000             5948
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.450
_exptl_crystal_size_mid          0.280
_exptl_crystal_size_min          0.240
_exptl_absorpt_coefficient_mu    3.819
_shelx_estimated_absorpt_T_min   0.278
_shelx_estimated_absorpt_T_max   0.461
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.348
_exptl_absorpt_correction_T_max  0.579
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     1.34138
_diffrn_radiation_type           GaK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            232175
_diffrn_reflns_av_unetI/netI     0.0812
_diffrn_reflns_av_R_equivalents  0.0784
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_theta_min         2.760
_diffrn_reflns_theta_max         56.000
_diffrn_reflns_theta_full        53.594
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             50484
_reflns_number_gt                37106
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 Structure factors included contributions from the .fab file. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          
; 
 Two linkers were occupied by two kinds of bipyridine ligand 
 which have similar shape and they were divided into two 
 parts (50:50). One Cp* fragment was disordered and it was 
 divided into two parts (61:39). 55 ISOR, 1 SIMU and 25 DFIX 
 instructions were used to restrain anions, solvents and Cp* 
 fragments so that there were 541 restraints in the data. 
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1973P)²+14.0955P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_extinction_coef       0.00088(7)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         50484
_refine_ls_number_parameters     2687
_refine_ls_number_restraints     541
_refine_ls_R_factor_all          0.1172
_refine_ls_R_factor_gt           0.1005
_refine_ls_wR_factor_ref         0.3201
_refine_ls_wR_factor_gt          0.2969
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_restrained_S_all      1.050
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.80887(2) -0.01480(2) 0.89633(2) 0.07513(15) Uani 1 1 d . . . . .
Rh2 Rh 0.79632(4) 0.28377(3) 1.04046(4) 0.1257(3) Uani 1 1 d . . . . .
Rh3 Rh 0.21945(3) 0.04859(3) 0.47513(2) 0.08857(18) Uani 1 1 d . . . . .
Rh4 Rh 0.19005(2) 0.33140(2) 0.63551(3) 0.08440(17) Uani 1 1 d . . . . .
Rh5 Rh 0.24652(3) 0.33511(2) 0.94743(3) 0.0972(2) Uani 1 1 d . . . . .
Rh6 Rh 0.18956(2) 0.04187(2) 0.76709(2) 0.06701(14) Uani 1 1 d . . . . .
Rh7 Rh 0.83332(3) 0.63737(3) 0.69419(3) 0.1057(2) Uani 1 1 d . . . . .
Rh8 Rh 0.77786(3) 0.34072(3) 0.52062(3) 0.0953(2) Uani 1 1 d . . . . .
N2 N 0.5339(3) 0.0894(3) 0.6220(2) 0.0794(15) Uani 0.552(9) 1 d . . P A 1
H2 H 0.5375 0.1112 0.5943 0.095 Uiso 0.552(9) 1 calc R U P A 1
N3 N 0.5018(3) -0.0131(3) 0.7583(3) 0.0901(18) Uani 0.552(9) 1 d . . P A 1
H3 H 0.4971 -0.0349 0.7859 0.108 Uiso 0.552(9) 1 calc R U P A 1
O9 O 0.6388(4) 0.0959(4) 0.6582(3) 0.077(2) Uani 0.552(9) 1 d . . P A 1
O10 O 0.3982(3) -0.0191(4) 0.7222(3) 0.079(2) Uani 0.552(9) 1 d . . P A 1
C18 C 0.4766(3) 0.0632(3) 0.6335(3) 0.0797(17) Uani 0.552(9) 1 d . . P A 1
C19 C 0.4862(3) 0.0353(3) 0.6814(3) 0.0811(17) Uani 0.552(9) 1 d . . P A 1
C20 C 0.5500(3) 0.0413(3) 0.7000(3) 0.0824(17) Uani 0.552(9) 1 d . . P A 1
C21 C 0.5596(3) 0.0129(3) 0.7469(3) 0.0825(17) Uani 0.552(9) 1 d . . P A 1
C22 C 0.5946(4) 0.0785(2) 0.6615(2) 0.129(2) Uani 0.552(9) 1 d . . P A 1
C23 C 0.4466(3) -0.0009(3) 0.7192(2) 0.1280(19) Uani 0.552(9) 1 d . . P A 1
S1' S 0.5946(4) 0.0785(2) 0.6615(2) 0.129(2) Uani 0.448(9) 1 d . . P A 2
S2' S 0.4466(3) -0.0009(3) 0.7192(2) 0.1280(19) Uani 0.448(9) 1 d . . P A 2
C18' C 0.4766(3) 0.0632(3) 0.6335(3) 0.0797(17) Uani 0.448(9) 1 d . . P A 2
C19' C 0.4862(3) 0.0353(3) 0.6814(3) 0.0811(17) Uani 0.448(9) 1 d . . P A 2
C20' C 0.5500(3) 0.0413(3) 0.7000(3) 0.0824(17) Uani 0.448(9) 1 d . . P A 2
C21' C 0.5596(3) 0.0129(3) 0.7469(3) 0.0825(17) Uani 0.448(9) 1 d . . P A 2
C22' C 0.5339(3) 0.0894(3) 0.6220(2) 0.0794(15) Uani 0.448(9) 1 d . . P A 2
H22' H 0.5377 0.1129 0.5921 0.095 Uiso 0.448(9) 1 calc R U P A 2
C23' C 0.5018(3) -0.0131(3) 0.7583(3) 0.0901(18) Uani 0.448(9) 1 d . . P A 2
H23' H 0.4968 -0.0367 0.7881 0.108 Uiso 0.448(9) 1 calc R U P A 2
N10 N 0.5541(3) 0.4315(3) 0.8894(3) 0.0916(18) Uani 0.448(9) 1 d . . P A 1
H10 H 0.5570 0.4125 0.9192 0.110 Uiso 0.448(9) 1 calc R U P A 1
N11 N 0.5208(4) 0.5205(4) 0.7396(3) 0.103(2) Uani 0.448(9) 1 d . . P A 1
H11 H 0.5165 0.5414 0.7113 0.124 Uiso 0.448(9) 1 calc R U P A 1
O21 O 0.6595(5) 0.4691(5) 0.8821(5) 0.082(3) Uani 0.448(9) 1 d . . P A 1
O22 O 0.4165(4) 0.4886(5) 0.7474(5) 0.083(3) Uani 0.448(9) 1 d . . P A 1
C102 C 0.4944(4) 0.4328(3) 0.8588(4) 0.094(2) Uani 0.448(9) 1 d . . P A 1
C103 C 0.5056(4) 0.4666(3) 0.8147(3) 0.0899(19) Uani 0.448(9) 1 d . . P A 1
C104 C 0.5691(4) 0.4857(3) 0.8140(3) 0.0866(18) Uani 0.448(9) 1 d . . P A 1
C105 C 0.5789(4) 0.5180(4) 0.7702(3) 0.098(2) Uani 0.448(9) 1 d . . P A 1
C106 C 0.6173(4) 0.46622(18) 0.8680(2) 0.134(2) Uani 0.448(9) 1 d . . P A 1
C107 C 0.4639(3) 0.4815(2) 0.7617(2) 0.1384(18) Uani 0.448(9) 1 d . . P A 1
S3' S 0.6173(4) 0.46622(18) 0.8680(2) 0.134(2) Uani 0.552(9) 1 d . . P A 2
S4' S 0.4639(3) 0.4815(2) 0.7617(2) 0.1384(18) Uani 0.552(9) 1 d . . P A 2
C202 C 0.4944(4) 0.4328(3) 0.8588(4) 0.094(2) Uani 0.552(9) 1 d . . P A 2
C203 C 0.5056(4) 0.4666(3) 0.8147(3) 0.0899(19) Uani 0.552(9) 1 d . . P A 2
C204 C 0.5691(4) 0.4857(3) 0.8140(3) 0.0866(18) Uani 0.552(9) 1 d . . P A 2
C205 C 0.5789(4) 0.5180(4) 0.7702(3) 0.098(2) Uani 0.552(9) 1 d . . P A 2
C206 C 0.5541(3) 0.4315(3) 0.8894(3) 0.0916(18) Uani 0.552(9) 1 d . . P A 2
H206 H 0.5572 0.4109 0.9216 0.110 Uiso 0.552(9) 1 calc R U P A 2
C207 C 0.5208(4) 0.5205(4) 0.7396(3) 0.103(2) Uani 0.552(9) 1 d . . P A 2
H207 H 0.5162 0.5430 0.7090 0.124 Uiso 0.552(9) 1 calc R U P A 2
C75 C 0.1079(9) 0.3465(8) 0.6520(10) 0.113(4) Uani 0.609(19) 1 d D U P B 1
C76 C 0.1545(8) 0.3781(8) 0.6932(7) 0.097(3) Uani 0.609(19) 1 d . U P B 1
C77 C 0.1958(8) 0.4178(7) 0.6649(8) 0.098(3) Uani 0.609(19) 1 d . U P B 1
C78 C 0.1698(9) 0.4091(8) 0.6093(8) 0.100(3) Uani 0.609(19) 1 d . U P B 1
C79 C 0.1180(8) 0.3672(9) 0.5979(8) 0.110(4) Uani 0.609(19) 1 d D U P B 1
C80 C 0.0527(10) 0.2999(11) 0.6589(15) 0.168(10) Uani 0.609(19) 1 d D U P B 1
H80A H 0.0142 0.3125 0.6471 0.251 Uiso 0.609(19) 1 calc R U P B 1
H80B H 0.0556 0.2914 0.6977 0.251 Uiso 0.609(19) 1 calc R U P B 1
H80C H 0.0525 0.2656 0.6362 0.251 Uiso 0.609(19) 1 calc R U P B 1
C81 C 0.1559(14) 0.3731(12) 0.7497(10) 0.156(9) Uani 0.609(19) 1 d . U P B 1
H81A H 0.1929 0.3994 0.7702 0.234 Uiso 0.609(19) 1 calc R U P B 1
H81B H 0.1186 0.3822 0.7604 0.234 Uiso 0.609(19) 1 calc R U P B 1
H81C H 0.1574 0.3340 0.7582 0.234 Uiso 0.609(19) 1 calc R U P B 1
C82 C 0.2522(11) 0.4599(9) 0.6922(11) 0.143(8) Uani 0.609(19) 1 d . U P B 1
H82A H 0.2739 0.4427 0.7225 0.215 Uiso 0.609(19) 1 calc R U P B 1
H82B H 0.2402 0.4934 0.7068 0.215 Uiso 0.609(19) 1 calc R U P B 1
H82C H 0.2798 0.4712 0.6653 0.215 Uiso 0.609(19) 1 calc R U P B 1
C83 C 0.1979(13) 0.4417(10) 0.5632(11) 0.152(9) Uani 0.609(19) 1 d . U P B 1
H83A H 0.1963 0.4818 0.5678 0.228 Uiso 0.609(19) 1 calc R U P B 1
H83B H 0.1741 0.4252 0.5272 0.228 Uiso 0.609(19) 1 calc R U P B 1
H83C H 0.2412 0.4388 0.5652 0.228 Uiso 0.609(19) 1 calc R U P B 1
C84 C 0.0785(12) 0.3459(12) 0.5414(10) 0.155(8) Uani 0.609(19) 1 d D U P B 1
H84A H 0.0424 0.3163 0.5462 0.232 Uiso 0.609(19) 1 calc R U P B 1
H84B H 0.1034 0.3302 0.5181 0.232 Uiso 0.609(19) 1 calc R U P B 1
H84C H 0.0643 0.3776 0.5239 0.232 Uiso 0.609(19) 1 calc R U P B 1
C75' C 0.0978(6) 0.3455(6) 0.6315(6) 0.097(5) Uani 0.391(19) 1 d G U P B 2
C76' C 0.1303(8) 0.3616(7) 0.6848(6) 0.100(5) Uani 0.391(19) 1 d G U P B 2
C77' C 0.1813(8) 0.4054(7) 0.6815(7) 0.104(5) Uani 0.391(19) 1 d G U P B 2
C78' C 0.1804(7) 0.4164(6) 0.6261(8) 0.103(5) Uani 0.391(19) 1 d G U P B 2
C79' C 0.1287(7) 0.3794(6) 0.5952(6) 0.108(5) Uani 0.391(19) 1 d G U P B 2
C80' C 0.0403(8) 0.3003(8) 0.6160(12) 0.122(9) Uani 0.391(19) 1 d G U P B 2
H80D H 0.0042 0.3160 0.6196 0.183 Uiso 0.391(19) 1 calc R U P B 2
H80E H 0.0416 0.2693 0.6405 0.183 Uiso 0.391(19) 1 calc R U P B 2
H80F H 0.0372 0.2856 0.5778 0.183 Uiso 0.391(19) 1 calc R U P B 2
C81' C 0.1135(13) 0.3365(11) 0.7360(9) 0.136(11) Uani 0.391(19) 1 d G U P B 2
H81D H 0.1509 0.3414 0.7639 0.203 Uiso 0.391(19) 1 calc R U P B 2
H81E H 0.0944 0.2959 0.7280 0.203 Uiso 0.391(19) 1 calc R U P B 2
H81F H 0.0839 0.3557 0.7499 0.203 Uiso 0.391(19) 1 calc R U P B 2
C82' C 0.2284(12) 0.4352(11) 0.7285(11) 0.175(16) Uani 0.391(19) 1 d G U P B 2
H82D H 0.2086 0.4561 0.7527 0.262 Uiso 0.391(19) 1 calc R U P B 2
H82E H 0.2612 0.4618 0.7146 0.262 Uiso 0.391(19) 1 calc R U P B 2
H82F H 0.2464 0.4072 0.7494 0.262 Uiso 0.391(19) 1 calc R U P B 2
C83' C 0.2263(11) 0.4599(10) 0.6040(13) 0.180(17) Uani 0.391(19) 1 d G U P B 2
H83D H 0.2044 0.4808 0.5773 0.270 Uiso 0.391(19) 1 calc R U P B 2
H83E H 0.2534 0.4412 0.5858 0.270 Uiso 0.391(19) 1 calc R U P B 2
H83F H 0.2514 0.4864 0.6344 0.270 Uiso 0.391(19) 1 calc R U P B 2
C84' C 0.1101(12) 0.3765(11) 0.5345(8) 0.120(8) Uani 0.391(19) 1 d G U P B 2
H84D H 0.1055 0.3375 0.5191 0.179 Uiso 0.391(19) 1 calc R U P B 2
H84E H 0.1419 0.4022 0.5185 0.179 Uiso 0.391(19) 1 calc R U P B 2
H84F H 0.0704 0.3878 0.5256 0.179 Uiso 0.391(19) 1 calc R U P B 2
N1 N 0.3051(3) 0.0618(3) 0.5296(2) 0.0824(14) Uani 1 1 d . . . . .
N4 N 0.7264(2) -0.0097(3) 0.8437(2) 0.0802(14) Uani 1 1 d . . . . .
N5 N 0.2767(3) 0.3238(3) 0.6783(3) 0.0851(15) Uani 1 1 d . . . . .
N6 N 0.5075(2) 0.3363(3) 0.7520(3) 0.0859(15) Uani 1 1 d D . . . .
H6 H 0.5114 0.3559 0.7228 0.103 Uiso 1 1 calc R U . . .
N7 N 0.4858(3) 0.2374(3) 0.8897(3) 0.1018(19) Uani 1 1 d . . . . .
H7 H 0.4827 0.2173 0.9186 0.122 Uiso 1 1 calc R U . . .
N8 N 0.7124(4) 0.2746(3) 0.9838(4) 0.118(3) Uani 1 1 d . . . . .
N9 N 0.3270(3) 0.3593(3) 0.9115(3) 0.0965(18) Uani 1 1 d . . . . .
N12 N 0.7485(4) 0.6008(3) 0.7194(3) 0.1016(19) Uani 1 1 d . . . . .
N13 N 0.2749(2) 0.0837(2) 0.7443(2) 0.0732(12) Uani 1 1 d . . . . .
N14 N 0.5021(3) 0.1736(3) 0.7338(3) 0.0889(16) Uani 1 1 d . . . . .
H14 H 0.5068 0.1547 0.7635 0.107 Uiso 1 1 calc R U . . .
N15 N 0.4724(3) 0.2608(3) 0.5876(3) 0.1001(19) Uani 1 1 d D . . . .
H15 H 0.4675 0.2790 0.5575 0.120 Uiso 1 1 calc R U . . .
N16 N 0.6970(3) 0.3200(3) 0.5562(4) 0.102(2) Uani 1 1 d . . . . .
O1 O 0.7714(2) 0.02048(19) 0.95948(19) 0.0749(10) Uani 1 1 d . . . . .
O2 O 0.8353(2) 0.0737(3) 0.8890(2) 0.0923(14) Uani 1 1 d . . . . .
O3 O 0.8305(3) 0.2491(2) 0.9731(3) 0.120(2) Uani 1 1 d . . . . .
O4 O 0.7682(3) 0.1958(2) 1.0451(3) 0.1029(16) Uani 1 1 d . . . . .
O5 O 0.1849(2) 0.0769(2) 0.5436(2) 0.0832(12) Uani 1 1 d . . . . .
O6 O 0.2402(2) 0.1373(2) 0.4717(2) 0.0902(13) Uani 1 1 d . . . . .
O7 O 0.2205(2) 0.3041(2) 0.5653(2) 0.0892(13) Uani 1 1 d . . . . .
O8 O 0.1650(2) 0.2417(2) 0.6356(2) 0.0830(12) Uani 1 1 d . . . . .
O11 O 0.6120(3) 0.3490(3) 0.7859(3) 0.1066(16) Uani 1 1 d . . . . .
O12 O 0.3822(3) 0.2231(3) 0.8536(3) 0.1109(18) Uani 1 1 d . . . . .
O13 O 0.2661(3) 0.2536(2) 0.9499(2) 0.0902(13) Uani 1 1 d . . . . .
O14 O 0.2015(3) 0.2955(2) 0.8684(3) 0.0957(14) Uani 1 1 d . . . . .
O15 O 0.1673(2) 0.12270(19) 0.76357(18) 0.0743(10) Uani 1 1 d . . . . .
O16 O 0.2303(2) 0.08123(18) 0.84582(17) 0.0727(10) Uani 1 1 d . . . . .
O17 O 0.8534(3) 0.5566(3) 0.7006(2) 0.1043(16) Uani 1 1 d . . . . .
O18 O 0.7923(3) 0.5955(2) 0.6167(2) 0.0955(14) Uani 1 1 d . . . . .
O19 O 0.7607(2) 0.4226(2) 0.5147(2) 0.0975(15) Uani 1 1 d . . . . .
O20 O 0.8225(2) 0.3824(2) 0.5983(3) 0.0997(15) Uani 1 1 d . . . . .
O23 O 0.6057(2) 0.2084(3) 0.7293(3) 0.1034(16) Uani 1 1 d . . . . .
O24 O 0.3692(3) 0.2274(3) 0.5959(3) 0.1113(18) Uani 1 1 d . . . . .
O25 O 0.4312(6) 0.8116(5) 0.5667(6) 0.213(5) Uani 1 1 d . . . . .
O26 O 0.4453(4) 0.8476(4) 0.4762(3) 0.161(3) Uani 1 1 d . . . . .
O27 O 0.5285(5) 0.8392(6) 0.5422(5) 0.209(5) Uani 1 1 d . . . . .
O28 O 0.5769(6) 0.3818(6) -0.0070(5) 0.190(4) Uani 1 1 d . . . . .
O29 O 0.5901(7) 0.3445(6) 0.0856(6) 0.213(5) Uani 1 1 d . . . . .
O30 O 0.4942(6) 0.3263(4) 0.0286(7) 0.254(8) Uani 1 1 d D . . . .
O31 O 0.9907(5) 0.8933(4) 0.8704(5) 0.174(4) Uani 1 1 d . . . . .
O32 O 0.9979(6) 0.7970(5) 0.8617(5) 0.192(5) Uani 1 1 d . . . . .
O33 O 0.9082(4) 0.8231(4) 0.9001(7) 0.227(6) Uani 1 1 d . U . . .
O34 O 0.4738(4) 0.9254(6) 0.8519(4) 0.176(4) Uani 1 1 d . . . . .
O35 O 0.3901(5) 0.9793(6) 0.8452(5) 0.194(5) Uani 1 1 d . . . . .
O36 O 0.4379(11) 0.9529(10) 0.9338(7) 0.346(12) Uani 1 1 d . U . . .
O37 O 0.1700(8) 0.9153(9) 0.3027(8) 0.315(10) Uani 1 1 d . U . . .
O38 O 0.1177(8) 0.8448(8) 0.2283(8) 0.293(9) Uani 1 1 d . U . . .
O39 O 0.0684(10) 0.9241(8) 0.2407(10) 0.317(10) Uani 1 1 d . U . . .
O40 O 0.0105(7) 0.1899(8) 0.3907(5) 0.255(7) Uani 1 1 d . U . . .
O41 O -0.0457(6) 0.1035(5) 0.4230(5) 0.214(5) Uani 1 1 d . U . . .
O42 O -0.0588(12) 0.1985(11) 0.4665(11) 0.362(12) Uani 1 1 d . U . . .
S1 S 0.46523(15) 0.84653(13) 0.53360(15) 0.1305(9) Uani 1 1 d . . . . .
S2 S 0.5569(2) 0.36368(14) 0.0425(2) 0.1573(13) Uani 1 1 d D . . . .
S3 S 0.97103(17) 0.83897(18) 0.88652(19) 0.1543(12) Uani 1 1 d D . . . .
S4 S 0.42347(17) 0.9439(2) 0.87597(17) 0.1604(14) Uani 1 1 d . . . . .
S5 S 0.1115(2) 0.8940(3) 0.2680(3) 0.210(2) Uani 1 1 d . . . . .
S6 S -0.0232(3) 0.1639(3) 0.4282(2) 0.222(3) Uani 1 1 d . . . . .
F1 F 0.5093(9) 0.9526(4) 0.5388(7) 0.291(8) Uani 1 1 d . U . . .
F2 F 0.4195(10) 0.9301(9) 0.5553(10) 0.358(12) Uani 1 1 d . U . . .
F3 F 0.4921(9) 0.9236(7) 0.6153(6) 0.292(8) Uani 1 1 d D U . . .
F4 F 0.5827(7) 0.4643(4) 0.0870(7) 0.267(7) Uani 1 1 d . . . . .
F5 F 0.5000(7) 0.4463(5) 0.0349(7) 0.266(7) Uani 1 1 d D . . . .
F6 F 0.5151(10) 0.4172(8) 0.1185(7) 0.302(9) Uani 1 1 d . . . . .
F7 F 1.0020(7) 0.7905(6) 0.9777(6) 0.261(7) Uani 1 1 d D . . . .
F8 F 1.0739(4) 0.8527(7) 0.9470(6) 0.282(8) Uani 1 1 d D U . . .
F9 F 0.9978(10) 0.8805(6) 0.9868(5) 0.300(9) Uani 1 1 d D . . . .
F10 F 0.3538(6) 0.8584(6) 0.8226(7) 0.260(7) Uani 1 1 d . . . . .
F11 F 0.3921(9) 0.8431(7) 0.9067(8) 0.327(10) Uani 1 1 d . . . . .
F12 F 0.3204(5) 0.8900(7) 0.8920(6) 0.274(7) Uani 1 1 d D . . . .
F13 F 0.0530(7) 0.9036(10) 0.3441(8) 0.351(12) Uani 1 1 d . . . . .
F14 F 0.0064(7) 0.8376(7) 0.2881(7) 0.294(9) Uani 1 1 d . . . . .
F15 F 0.0876(12) 0.8268(12) 0.3374(10) 0.457(19) Uani 1 1 d D . . . .
F16 F 0.0667(5) 0.2181(4) 0.5063(4) 0.201(4) Uani 1 1 d D U . . .
F17 F 0.0096(6) 0.1427(7) 0.5285(5) 0.293(9) Uani 1 1 d D U . . .
F18 F 0.0712(8) 0.1380(8) 0.4687(8) 0.318(9) Uani 1 1 d D U . . .
C1 C 0.7847(3) 0.0742(3) 0.9662(3) 0.0735(15) Uani 1 1 d . . . . .
C2 C 0.8208(3) 0.1051(3) 0.9246(3) 0.0816(17) Uani 1 1 d . . . . .
C3 C 0.8347(4) 0.1651(4) 0.9268(4) 0.102(3) Uani 1 1 d . . . . .
H3A H 0.8560 0.1845 0.9000 0.123 Uiso 1 1 calc R U . . .
C4 C 0.8177(3) 0.1950(3) 0.9672(4) 0.097(2) Uani 1 1 d . . . . .
C5 C 0.7834(3) 0.1647(3) 1.0091(3) 0.0845(19) Uani 1 1 d . . . . .
C6 C 0.7675(3) 0.1052(3) 1.0071(3) 0.0771(16) Uani 1 1 d . . . . .
H6A H 0.7452 0.0863 1.0335 0.093 Uiso 1 1 calc R U . . .
C7 C 0.1909(3) 0.1299(3) 0.5508(3) 0.0736(15) Uani 1 1 d . . . . .
C8 C 0.2240(3) 0.1663(3) 0.5097(3) 0.0782(16) Uani 1 1 d . . . . .
C9 C 0.2345(3) 0.2251(3) 0.5153(3) 0.0845(18) Uani 1 1 d . . . . .
H9 H 0.2552 0.2476 0.4900 0.101 Uiso 1 1 calc R U . . .
C10 C 0.2146(3) 0.2502(3) 0.5577(3) 0.0780(16) Uani 1 1 d . . . . .
C11 C 0.1821(3) 0.2149(3) 0.5983(3) 0.0803(17) Uani 1 1 d . . . . .
C12 C 0.1717(3) 0.1567(3) 0.5939(3) 0.0777(16) Uani 1 1 d . . . . .
H12 H 0.1517 0.1349 0.6199 0.093 Uiso 1 1 calc R U . . .
C13 C 0.3085(4) 0.0271(4) 0.5721(3) 0.090(2) Uani 1 1 d . . . . .
H13 H 0.2719 0.0011 0.5775 0.108 Uiso 1 1 calc R U . . .
C14 C 0.3627(3) 0.0285(4) 0.6070(3) 0.0890(19) Uani 1 1 d . . . . .
H14A H 0.3630 0.0048 0.6371 0.107 Uiso 1 1 calc R U . . .
C15 C 0.4181(3) 0.0650(3) 0.5983(3) 0.0800(17) Uani 1 1 d . . . . .
C16 C 0.4145(4) 0.0990(4) 0.5544(3) 0.0910(19) Uani 1 1 d . . . . .
H16 H 0.4508 0.1235 0.5461 0.109 Uiso 1 1 calc R U . . .
C17 C 0.3576(4) 0.0968(4) 0.5232(3) 0.097(2) Uani 1 1 d . . . . .
H17 H 0.3557 0.1223 0.4948 0.116 Uiso 1 1 calc R U . . .
C24 C 0.6712(3) -0.0329(4) 0.8564(3) 0.0892(19) Uani 1 1 d . . . . .
H24 H 0.6699 -0.0549 0.8876 0.107 Uiso 1 1 calc R U . . .
C25 C 0.6157(3) -0.0268(4) 0.8267(3) 0.0875(18) Uani 1 1 d . . . . .
H25 H 0.5773 -0.0437 0.8376 0.105 Uiso 1 1 calc R U . . .
C26 C 0.6171(3) 0.0053(3) 0.7794(3) 0.0822(17) Uani 1 1 d . . . . .
C27 C 0.6743(3) 0.0289(4) 0.7656(3) 0.091(2) Uani 1 1 d . . . . .
H27 H 0.6771 0.0500 0.7339 0.109 Uiso 1 1 calc R U . . .
C28 C 0.7280(3) 0.0212(4) 0.7991(3) 0.0866(19) Uani 1 1 d . . . . .
H28 H 0.7673 0.0384 0.7901 0.104 Uiso 1 1 calc R U . . .
C29 C 0.2816(3) 0.2914(3) 0.7214(3) 0.0838(17) Uani 1 1 d . . . . .
H29 H 0.2445 0.2719 0.7327 0.101 Uiso 1 1 calc R U . . .
C30 C 0.3368(3) 0.2848(3) 0.7497(3) 0.0834(17) Uani 1 1 d . . . . .
H30 H 0.3377 0.2607 0.7793 0.100 Uiso 1 1 calc R U . . .
C31 C 0.3912(3) 0.3139(3) 0.7344(3) 0.0811(17) Uani 1 1 d . . . . .
C32 C 0.3877(3) 0.3480(4) 0.6911(4) 0.093(2) Uani 1 1 d . . . . .
H32 H 0.4245 0.3682 0.6797 0.111 Uiso 1 1 calc R U . . .
C33 C 0.3310(4) 0.3525(4) 0.6646(4) 0.098(2) Uani 1 1 d . . . . .
H33 H 0.3293 0.3768 0.6352 0.118 Uiso 1 1 calc R U . . .
C34 C 0.4509(3) 0.3097(3) 0.7654(3) 0.0815(17) Uani 1 1 d . . . . .
C35 C 0.4645(3) 0.2804(3) 0.8117(3) 0.0847(18) Uani 1 1 d . . . . .
C36 C 0.5293(4) 0.2921(3) 0.8284(4) 0.095(2) Uani 1 1 d . . . . .
C37 C 0.5417(3) 0.2663(3) 0.8772(4) 0.098(2) Uani 1 1 d . . . . .
C38 C 0.5596(3) 0.3284(3) 0.7913(3) 0.088(2) Uani 1 1 d D . . . .
C39 C 0.4338(4) 0.2436(3) 0.8508(4) 0.093(2) Uani 1 1 d . . . . .
C40 C 0.6596(5) 0.2489(4) 0.9986(5) 0.114(3) Uani 1 1 d . . . . .
H40 H 0.6600 0.2332 1.0335 0.137 Uiso 1 1 calc R U . . .
C41 C 0.6033(4) 0.2445(4) 0.9634(4) 0.107(3) Uani 1 1 d . . . . .
H41 H 0.5660 0.2242 0.9740 0.128 Uiso 1 1 calc R U . . .
C42 C 0.6006(4) 0.2686(3) 0.9141(5) 0.108(3) Uani 1 1 d . . . . .
C43 C 0.6554(4) 0.2964(4) 0.9016(5) 0.120(3) Uani 1 1 d . . . . .
H43 H 0.6562 0.3152 0.8683 0.145 Uiso 1 1 calc R U . . .
C44 C 0.7096(5) 0.2979(5) 0.9363(5) 0.125(3) Uani 1 1 d . . . . .
H44 H 0.7473 0.3168 0.9255 0.150 Uiso 1 1 calc R U . . .
C45 C 0.8997(3) -0.0285(4) 0.8961(3) 0.0866(19) Uani 1 1 d . . . . .
C46 C 0.8802(3) -0.0445(4) 0.9472(3) 0.090(2) Uani 1 1 d . . . . .
C47 C 0.8252(4) -0.0889(4) 0.9353(3) 0.091(2) Uani 1 1 d . . . . .
C48 C 0.8102(4) -0.1018(4) 0.8763(4) 0.093(2) Uani 1 1 d . . . . .
C49 C 0.8570(4) -0.0639(4) 0.8523(3) 0.092(2) Uani 1 1 d . . . . .
C50 C 0.9531(3) 0.0162(5) 0.8896(4) 0.109(3) Uani 1 1 d . . . . .
H50A H 0.9660 0.0418 0.9232 0.163 Uiso 1 1 calc R U . . .
H50B H 0.9417 0.0378 0.8582 0.163 Uiso 1 1 calc R U . . .
H50C H 0.9875 -0.0009 0.8830 0.163 Uiso 1 1 calc R U . . .
C51 C 0.9103(4) -0.0180(5) 1.0030(3) 0.113(3) Uani 1 1 d . . . . .
H51A H 0.9320 -0.0442 1.0230 0.170 Uiso 1 1 calc R U . . .
H51B H 0.8786 -0.0097 1.0235 0.170 Uiso 1 1 calc R U . . .
H51C H 0.9401 0.0175 0.9995 0.170 Uiso 1 1 calc R U . . .
C52 C 0.7918(4) -0.1173(4) 0.9775(4) 0.106(3) Uani 1 1 d . . . . .
H52A H 0.8180 -0.1389 0.9994 0.159 Uiso 1 1 calc R U . . .
H52B H 0.7533 -0.1432 0.9594 0.159 Uiso 1 1 calc R U . . .
H52C H 0.7820 -0.0886 1.0018 0.159 Uiso 1 1 calc R U . . .
C53 C 0.7598(5) -0.1468(5) 0.8476(6) 0.130(4) Uani 1 1 d . . . . .
H53A H 0.7730 -0.1829 0.8478 0.196 Uiso 1 1 calc R U . . .
H53B H 0.7486 -0.1376 0.8094 0.196 Uiso 1 1 calc R U . . .
H53C H 0.7236 -0.1502 0.8663 0.196 Uiso 1 1 calc R U . . .
C54 C 0.8613(5) -0.0639(5) 0.7925(3) 0.110(3) Uani 1 1 d . . . . .
H54A H 0.8713 -0.0246 0.7820 0.165 Uiso 1 1 calc R U . . .
H54B H 0.8215 -0.0841 0.7708 0.165 Uiso 1 1 calc R U . . .
H54C H 0.8940 -0.0830 0.7853 0.165 Uiso 1 1 calc R U . . .
C55 C 0.8835(6) 0.3267(5) 1.0863(7) 0.144(5) Uani 1 1 d D . . . .
C56 C 0.8531(9) 0.3676(4) 1.0583(8) 0.183(8) Uani 1 1 d D . . . .
C57 C 0.7982(9) 0.3644(6) 1.0770(9) 0.188(8) Uani 1 1 d . . . . .
C58 C 0.7881(7) 0.3211(6) 1.1174(6) 0.152(5) Uani 1 1 d D U . . .
C59 C 0.8448(6) 0.3000(5) 1.1234(6) 0.144(5) Uani 1 1 d D . . . .
C60 C 0.9451(6) 0.3190(6) 1.0808(7) 0.173(6) Uani 1 1 d . . . . .
H60A H 0.9763 0.3534 1.0961 0.260 Uiso 1 1 calc R U . . .
H60B H 0.9472 0.3121 1.0416 0.260 Uiso 1 1 calc R U . . .
H60C H 0.9534 0.2864 1.1008 0.260 Uiso 1 1 calc R U . . .
C61 C 0.8793(8) 0.4063(7) 1.0219(8) 0.220(10) Uani 1 1 d . . . . .
H61A H 0.8515 0.4010 0.9862 0.331 Uiso 1 1 calc R U . . .
H61B H 0.9197 0.3995 1.0166 0.331 Uiso 1 1 calc R U . . .
H61C H 0.8848 0.4453 1.0375 0.331 Uiso 1 1 calc R U . . .
C62 C 0.7525(10) 0.4009(6) 1.0589(9) 0.252(13) Uani 1 1 d . . . . .
H62A H 0.7167 0.3908 1.0780 0.378 Uiso 1 1 calc R U . . .
H62B H 0.7728 0.4411 1.0681 0.378 Uiso 1 1 calc R U . . .
H62C H 0.7385 0.3943 1.0190 0.378 Uiso 1 1 calc R U . . .
C63 C 0.7358(8) 0.3039(7) 1.1491(8) 0.193(8) Uani 1 1 d D . . . .
H63A H 0.7441 0.3281 1.1835 0.289 Uiso 1 1 calc R U . . .
H63B H 0.7321 0.2641 1.1577 0.289 Uiso 1 1 calc R U . . .
H63C H 0.6970 0.3081 1.1268 0.289 Uiso 1 1 calc R U . . .
C64 C 0.8597(7) 0.2538(5) 1.1588(5) 0.153(5) Uani 1 1 d . . . . .
H64A H 0.8973 0.2434 1.1501 0.230 Uiso 1 1 calc R U . . .
H64B H 0.8250 0.2204 1.1517 0.230 Uiso 1 1 calc R U . . .
H64C H 0.8666 0.2675 1.1978 0.230 Uiso 1 1 calc R U . . .
C65 C 0.1766(4) -0.0400(4) 0.4578(4) 0.104(2) Uani 1 1 d D . . . .
C66 C 0.1332(5) -0.0062(5) 0.4354(4) 0.114(3) Uani 1 1 d D . . . .
C67 C 0.1587(6) 0.0284(6) 0.3969(4) 0.131(4) Uani 1 1 d . . . . .
C68 C 0.2187(7) 0.0182(6) 0.3941(4) 0.141(5) Uani 1 1 d . . . . .
C69 C 0.2276(6) -0.0264(5) 0.4308(4) 0.123(3) Uani 1 1 d . . . . .
C70 C 0.1652(5) -0.0824(4) 0.4972(4) 0.117(3) Uani 1 1 d . . . . .
H70A H 0.1397 -0.1180 0.4780 0.176 Uiso 1 1 calc R U . . .
H70B H 0.1434 -0.0690 0.5248 0.176 Uiso 1 1 calc R U . . .
H70C H 0.2049 -0.0891 0.5156 0.176 Uiso 1 1 calc R U . . .
C71 C 0.0717(5) -0.0075(6) 0.4520(6) 0.146(4) Uani 1 1 d . . . . .
H71A H 0.0410 -0.0401 0.4323 0.218 Uiso 1 1 calc R U . . .
H71B H 0.0589 0.0277 0.4426 0.218 Uiso 1 1 calc R U . . .
H71C H 0.0749 -0.0110 0.4918 0.218 Uiso 1 1 calc R U . . .
C72 C 0.1287(8) 0.0685(8) 0.3657(6) 0.188(7) Uani 1 1 d . U . . .
H72A H 0.1594 0.0941 0.3484 0.282 Uiso 1 1 calc R U . . .
H72B H 0.1115 0.0908 0.3908 0.282 Uiso 1 1 calc R U . . .
H72C H 0.0952 0.0474 0.3371 0.282 Uiso 1 1 calc R U . . .
C73 C 0.2578(9) 0.0427(9) 0.3571(6) 0.212(8) Uani 1 1 d . U . . .
H73A H 0.2964 0.0292 0.3632 0.318 Uiso 1 1 calc R U . . .
H73B H 0.2366 0.0316 0.3191 0.318 Uiso 1 1 calc R U . . .
H73C H 0.2674 0.0842 0.3634 0.318 Uiso 1 1 calc R U . . .
C74 C 0.2874(7) -0.0523(6) 0.4448(7) 0.168(6) Uani 1 1 d . U . . .
H74A H 0.2928 -0.0611 0.4836 0.252 Uiso 1 1 calc R U . . .
H74B H 0.3241 -0.0246 0.4382 0.252 Uiso 1 1 calc R U . . .
H74C H 0.2820 -0.0872 0.4212 0.252 Uiso 1 1 calc R U . . .
C85 C 0.2445(3) 0.2209(3) 0.9060(3) 0.0769(15) Uani 1 1 d . . . . .
C86 C 0.2071(3) 0.2444(3) 0.8600(3) 0.0784(16) Uani 1 1 d . . . . .
C87 C 0.1822(3) 0.2118(3) 0.8111(3) 0.0763(15) Uani 1 1 d . . . . .
H87 H 0.1601 0.2271 0.7813 0.092 Uiso 1 1 calc R U . . .
C88 C 0.1898(3) 0.1566(3) 0.8061(2) 0.0673(13) Uani 1 1 d . . . . .
C89 C 0.2267(3) 0.1329(3) 0.8538(3) 0.0697(14) Uani 1 1 d . . . . .
C90 C 0.2537(3) 0.1658(3) 0.9013(3) 0.0713(14) Uani 1 1 d . . . . .
H90 H 0.2780 0.1516 0.9302 0.086 Uiso 1 1 calc R U . . .
C91 C 0.8328(3) 0.5215(3) 0.6576(3) 0.0893(19) Uani 1 1 d . . . . .
C92 C 0.7983(3) 0.5441(3) 0.6100(3) 0.0823(17) Uani 1 1 d . . . . .
C93 C 0.7726(3) 0.5105(3) 0.5619(3) 0.0865(18) Uani 1 1 d . . . . .
H93 H 0.7495 0.5247 0.5320 0.104 Uiso 1 1 calc R U . . .
C94 C 0.7810(3) 0.4566(3) 0.5586(3) 0.0858(19) Uani 1 1 d . . . . .
C95 C 0.8174(3) 0.4332(3) 0.6062(4) 0.0874(19) Uani 1 1 d . . . . .
C96 C 0.8400(3) 0.4663(4) 0.6546(4) 0.095(2) Uani 1 1 d . . . . .
H96 H 0.8604 0.4514 0.6856 0.114 Uiso 1 1 calc R U . . .
C97 C 0.3802(4) 0.3464(3) 0.9335(4) 0.099(2) Uani 1 1 d . . . . .
H97 H 0.3799 0.3212 0.9622 0.119 Uiso 1 1 calc R U . . .
C98 C 0.4355(4) 0.3682(3) 0.9160(4) 0.101(2) Uani 1 1 d . . . . .
H98 H 0.4722 0.3573 0.9320 0.121 Uiso 1 1 calc R U . . .
C99 C 0.4376(4) 0.4051(3) 0.8762(4) 0.093(2) Uani 1 1 d . . . . .
C100 C 0.3815(4) 0.4157(4) 0.8506(4) 0.098(2) Uani 1 1 d . . . . .
H100 H 0.3812 0.4392 0.8205 0.117 Uiso 1 1 calc R U . . .
C101 C 0.3273(4) 0.3928(4) 0.8681(4) 0.102(2) Uani 1 1 d . . . . .
H101 H 0.2895 0.4001 0.8499 0.122 Uiso 1 1 calc R U . . .
C108 C 0.6936(5) 0.6023(4) 0.6913(4) 0.106(2) Uani 1 1 d . . . . .
H108 H 0.6929 0.6220 0.6586 0.127 Uiso 1 1 calc R U . . .
C109 C 0.6382(4) 0.5779(4) 0.7055(4) 0.104(2) Uani 1 1 d . . . . .
H109 H 0.6007 0.5817 0.6835 0.125 Uiso 1 1 calc R U . . .
C110 C 0.6362(4) 0.5467(3) 0.7531(3) 0.095(2) Uani 1 1 d . . . . .
C111 C 0.6921(4) 0.5455(4) 0.7831(4) 0.107(2) Uani 1 1 d . . . . .
H111 H 0.6938 0.5263 0.8161 0.129 Uiso 1 1 calc R U . . .
C112 C 0.7487(4) 0.5728(5) 0.7655(4) 0.115(3) Uani 1 1 d . . . . .
H112 H 0.7872 0.5710 0.7870 0.138 Uiso 1 1 calc R U . . .
C113 C 0.3298(3) 0.0794(4) 0.7737(3) 0.0860(18) Uani 1 1 d . . . . .
H113 H 0.3300 0.0556 0.8036 0.103 Uiso 1 1 calc R U . . .
C114 C 0.3857(3) 0.1091(3) 0.7612(3) 0.0872(19) Uani 1 1 d . . . . .
H114 H 0.4237 0.1049 0.7822 0.105 Uiso 1 1 calc R U . . .
C115 C 0.3868(3) 0.1447(3) 0.7183(3) 0.0777(16) Uani 1 1 d . . . . .
C116 C 0.3304(3) 0.1489(3) 0.6884(3) 0.0825(17) Uani 1 1 d . . . . .
H116 H 0.3290 0.1726 0.6584 0.099 Uiso 1 1 calc R U . . .
C117 C 0.2755(3) 0.1176(3) 0.7031(3) 0.0805(16) Uani 1 1 d . . . . .
H117 H 0.2369 0.1209 0.6826 0.097 Uiso 1 1 calc R U . . .
C118 C 0.4454(3) 0.1765(3) 0.7044(3) 0.086(2) Uani 1 1 d . . . . .
C119 C 0.4550(3) 0.2097(3) 0.6601(3) 0.0829(18) Uani 1 1 d . . . . .
C120 C 0.5193(3) 0.2281(3) 0.6610(4) 0.089(2) Uani 1 1 d . . . . .
C121 C 0.5298(3) 0.2568(3) 0.6167(4) 0.093(2) Uani 1 1 d . . . . .
C122 C 0.5529(3) 0.2055(3) 0.7098(3) 0.0792(17) Uani 1 1 d . . . . .
C123 C 0.4223(3) 0.2314(3) 0.6131(4) 0.0877(19) Uani 1 1 d D . . . .
C124 C 0.6438(4) 0.3292(4) 0.5296(4) 0.099(2) Uani 1 1 d . . . . .
H124 H 0.6447 0.3494 0.4972 0.119 Uiso 1 1 calc R U . . .
C125 C 0.5864(4) 0.3104(4) 0.5474(4) 0.101(2) Uani 1 1 d . . . . .
H125 H 0.5490 0.3168 0.5274 0.121 Uiso 1 1 calc R U . . .
C126 C 0.5872(4) 0.2815(4) 0.5963(4) 0.102(2) Uani 1 1 d . . . . .
C127 C 0.6428(4) 0.2746(4) 0.6233(5) 0.108(3) Uani 1 1 d . . . . .
H127 H 0.6435 0.2552 0.6562 0.130 Uiso 1 1 calc R U . . .
C128 C 0.6975(4) 0.2944(4) 0.6050(5) 0.111(3) Uani 1 1 d . . . . .
H128 H 0.7356 0.2904 0.6259 0.133 Uiso 1 1 calc R U . . .
C129 C 0.2683(6) 0.3764(4) 1.0301(4) 0.123(3) Uani 1 1 d . . . . .
C130 C 0.2557(5) 0.4175(3) 0.9900(5) 0.111(3) Uani 1 1 d . . . . .
C131 C 0.1961(5) 0.3978(4) 0.9611(5) 0.121(3) Uani 1 1 d . . . . .
C132 C 0.1702(7) 0.3447(5) 0.9828(8) 0.145(5) Uani 1 1 d . . . . .
C133 C 0.2140(9) 0.3330(5) 1.0247(7) 0.156(6) Uani 1 1 d . . . . .
C134 C 0.3256(9) 0.3789(6) 1.0681(5) 0.165(6) Uani 1 1 d . . . . .
H13A H 0.3213 0.3927 1.1050 0.248 Uiso 1 1 calc R U . . .
H13B H 0.3599 0.4048 1.0554 0.248 Uiso 1 1 calc R U . . .
H13C H 0.3341 0.3408 1.0697 0.248 Uiso 1 1 calc R U . . .
C135 C 0.3030(6) 0.4696(4) 0.9818(5) 0.124(3) Uani 1 1 d . . . . .
H13D H 0.2904 0.4839 0.9460 0.186 Uiso 1 1 calc R U . . .
H13E H 0.3434 0.4600 0.9827 0.186 Uiso 1 1 calc R U . . .
H13F H 0.3060 0.4989 1.0113 0.186 Uiso 1 1 calc R U . . .
C136 C 0.1665(7) 0.4284(6) 0.9122(6) 0.157(5) Uani 1 1 d . . . . .
H13G H 0.1462 0.4563 0.9269 0.236 Uiso 1 1 calc R U . . .
H13H H 0.1357 0.4002 0.8868 0.236 Uiso 1 1 calc R U . . .
H13I H 0.1990 0.4477 0.8926 0.236 Uiso 1 1 calc R U . . .
C137 C 0.1025(8) 0.3119(7) 0.9634(10) 0.206(8) Uani 1 1 d . U . . .
H13J H 0.0952 0.3041 0.9232 0.309 Uiso 1 1 calc R U . . .
H13K H 0.0742 0.3347 0.9735 0.309 Uiso 1 1 calc R U . . .
H13L H 0.0952 0.2759 0.9811 0.309 Uiso 1 1 calc R U . . .
C138 C 0.2045(10) 0.2816(6) 1.0586(7) 0.189(7) Uani 1 1 d . U . . .
H13M H 0.1689 0.2526 1.0397 0.284 Uiso 1 1 calc R U . . .
H13N H 0.1966 0.2929 1.0950 0.284 Uiso 1 1 calc R U . . .
H13O H 0.2418 0.2662 1.0629 0.284 Uiso 1 1 calc R U . . .
C139 C 0.1015(4) -0.0114(3) 0.7678(4) 0.096(2) Uani 1 1 d . . . . .
C140 C 0.1112(3) -0.0077(3) 0.7114(3) 0.0860(18) Uani 1 1 d . . . . .
C141 C 0.1623(4) -0.0270(3) 0.7060(3) 0.0874(19) Uani 1 1 d . . . . .
C142 C 0.1870(4) -0.0462(3) 0.7562(4) 0.095(2) Uani 1 1 d . . . . .
C143 C 0.1478(5) -0.0379(3) 0.7948(3) 0.108(3) Uani 1 1 d . . . . .
C144 C 0.0498(6) 0.0057(6) 0.7903(8) 0.195(8) Uani 1 1 d . . . . .
H144 H 0.0287 0.0269 0.7633 0.293 Uiso 1 1 calc R U . . .
H14B H 0.0665 0.0298 0.8246 0.293 Uiso 1 1 calc R U . . .
H14C H 0.0203 -0.0283 0.7979 0.293 Uiso 1 1 calc R U . . .
C145 C 0.0742(6) 0.0182(5) 0.6676(6) 0.149(5) Uani 1 1 d . . . . .
H14D H 0.0510 -0.0114 0.6392 0.224 Uiso 1 1 calc R U . . .
H14E H 0.1022 0.0472 0.6510 0.224 Uiso 1 1 calc R U . . .
H14F H 0.0450 0.0358 0.6841 0.224 Uiso 1 1 calc R U . . .
C146 C 0.1881(7) -0.0286(5) 0.6520(5) 0.140(4) Uani 1 1 d . . . . .
H14G H 0.1652 -0.0627 0.6287 0.210 Uiso 1 1 calc R U . . .
H14H H 0.2322 -0.0295 0.6602 0.210 Uiso 1 1 calc R U . . .
H14I H 0.1836 0.0053 0.6326 0.210 Uiso 1 1 calc R U . . .
C147 C 0.2428(6) -0.0728(5) 0.7661(7) 0.150(5) Uani 1 1 d . . . . .
H14J H 0.2312 -0.1120 0.7495 0.225 Uiso 1 1 calc R U . . .
H14K H 0.2566 -0.0730 0.8059 0.225 Uiso 1 1 calc R U . . .
H14L H 0.2765 -0.0508 0.7494 0.225 Uiso 1 1 calc R U . . .
C148 C 0.1529(8) -0.0509(6) 0.8543(4) 0.172(6) Uani 1 1 d . . . . .
H14M H 0.1414 -0.0210 0.8756 0.258 Uiso 1 1 calc R U . . .
H14N H 0.1957 -0.0528 0.8687 0.258 Uiso 1 1 calc R U . . .
H14O H 0.1249 -0.0876 0.8575 0.258 Uiso 1 1 calc R U . . .
C149 C 0.9174(7) 0.6878(6) 0.7383(6) 0.169(7) Uani 1 1 d D . . . .
C150 C 0.9168(5) 0.6928(5) 0.6810(5) 0.127(3) Uani 1 1 d D U . . .
C151 C 0.8673(5) 0.7192(4) 0.6635(6) 0.129(4) Uani 1 1 d D . . . .
C152 C 0.8359(8) 0.7260(6) 0.7034(8) 0.154(5) Uani 1 1 d . . . . .
C153 C 0.8664(9) 0.7067(7) 0.7522(6) 0.169(7) Uani 1 1 d . . . . .
C154 C 0.9667(10) 0.6577(9) 0.7715(9) 0.281(15) Uani 1 1 d . . . . .
H15A H 1.0053 0.6860 0.7849 0.421 Uiso 1 1 calc R U . . .
H15B H 0.9752 0.6284 0.7471 0.421 Uiso 1 1 calc R U . . .
H15C H 0.9500 0.6401 0.8029 0.421 Uiso 1 1 calc R U . . .
C155 C 0.9574(7) 0.6769(7) 0.6433(8) 0.188(7) Uani 1 1 d D . . . .
H15D H 0.9317 0.6548 0.6104 0.281 Uiso 1 1 calc R U . . .
H15E H 0.9841 0.6539 0.6624 0.281 Uiso 1 1 calc R U . . .
H15F H 0.9834 0.7114 0.6323 0.281 Uiso 1 1 calc R U . . .
C156 C 0.8459(8) 0.7315(6) 0.6061(6) 0.170(6) Uani 1 1 d . U . . .
H15G H 0.8454 0.6990 0.5809 0.256 Uiso 1 1 calc R U . . .
H15H H 0.8741 0.7654 0.5965 0.256 Uiso 1 1 calc R U . . .
H15I H 0.8039 0.7382 0.6029 0.256 Uiso 1 1 calc R U . . .
C157 C 0.7770(10) 0.7529(7) 0.7062(11) 0.232(9) Uani 1 1 d . U . . .
H15J H 0.7417 0.7231 0.7122 0.349 Uiso 1 1 calc R U . . .
H15K H 0.7663 0.7698 0.6715 0.349 Uiso 1 1 calc R U . . .
H15L H 0.7871 0.7824 0.7368 0.349 Uiso 1 1 calc R U . . .
C158 C 0.8484(12) 0.7089(10) 0.8150(9) 0.252(11) Uani 1 1 d . U . . .
H15M H 0.8644 0.7474 0.8326 0.377 Uiso 1 1 calc R U . . .
H15N H 0.8671 0.6821 0.8370 0.377 Uiso 1 1 calc R U . . .
H15O H 0.8032 0.6985 0.8125 0.377 Uiso 1 1 calc R U . . .
C159 C 0.8539(5) 0.3266(7) 0.4844(7) 0.145(4) Uani 1 1 d . U . . .
C160 C 0.8327(5) 0.2796(6) 0.5104(6) 0.130(4) Uani 1 1 d . . . . .
C161 C 0.7706(5) 0.2562(4) 0.4871(5) 0.111(3) Uani 1 1 d . . . . .
C162 C 0.7515(5) 0.2905(5) 0.4428(5) 0.115(3) Uani 1 1 d . . . . .
C163 C 0.8081(8) 0.3370(5) 0.4422(6) 0.146(5) Uani 1 1 d . . . . .
C164 C 0.9186(7) 0.3673(12) 0.4996(11) 0.277(13) Uani 1 1 d . . . . .
H16A H 0.9217 0.3878 0.5354 0.415 Uiso 1 1 calc R U . . .
H16B H 0.9243 0.3946 0.4713 0.415 Uiso 1 1 calc R U . . .
H16C H 0.9507 0.3453 0.5016 0.415 Uiso 1 1 calc R U . . .
C165 C 0.8673(7) 0.2563(8) 0.5576(8) 0.202(8) Uani 1 1 d . . . . .
H16D H 0.8647 0.2158 0.5489 0.303 Uiso 1 1 calc R U . . .
H16E H 0.8491 0.2609 0.5908 0.303 Uiso 1 1 calc R U . . .
H16F H 0.9109 0.2768 0.5642 0.303 Uiso 1 1 calc R U . . .
C166 C 0.7301(6) 0.2028(4) 0.5026(6) 0.131(4) Uani 1 1 d . . . . .
H16G H 0.7305 0.1708 0.4771 0.197 Uiso 1 1 calc R U . . .
H16H H 0.6876 0.2077 0.5006 0.197 Uiso 1 1 calc R U . . .
H16I H 0.7460 0.1951 0.5404 0.197 Uiso 1 1 calc R U . . .
C167 C 0.6960(7) 0.2823(6) 0.4072(5) 0.145(4) Uani 1 1 d . . . . .
H16J H 0.6970 0.2575 0.3751 0.218 Uiso 1 1 calc R U . . .
H16K H 0.6894 0.3190 0.3951 0.218 Uiso 1 1 calc R U . . .
H16L H 0.6621 0.2644 0.4261 0.218 Uiso 1 1 calc R U . . .
C168 C 0.8084(8) 0.3838(7) 0.4054(7) 0.178(6) Uani 1 1 d . . . . .
H16M H 0.8488 0.4108 0.4134 0.267 Uiso 1 1 calc R U . . .
H16N H 0.7756 0.4033 0.4112 0.267 Uiso 1 1 calc R U . . .
H16O H 0.8011 0.3684 0.3669 0.267 Uiso 1 1 calc R U . . .
C169 C 0.4709(11) 0.9153(9) 0.5626(8) 0.196(8) Uani 1 1 d D . . . .
C170 C 0.5353(7) 0.4222(7) 0.0715(8) 0.164(5) Uani 1 1 d D . . . .
C171 C 1.0135(8) 0.8404(7) 0.9546(6) 0.193(7) Uani 1 1 d D U . . .
C172 C 0.3742(8) 0.8839(10) 0.8759(9) 0.188(7) Uani 1 1 d D . . . .
C173 C 0.0575(10) 0.8621(8) 0.3124(7) 0.177(6) Uani 1 1 d D . . . .
C174 C 0.0279(7) 0.1672(6) 0.4851(6) 0.168(5) Uani 1 1 d D U . . .
C177 C 0.5411(6) 0.4294(8) 0.6240(7) 0.175(6) Uani 1 1 d . . . . .
H177 H 0.5095 0.4393 0.5982 0.210 Uiso 1 1 calc R U . . .
C178 C 0.6474(6) 0.4334(7) 0.6543(6) 0.157(5) Uani 1 1 d . . . . .
H17A H 0.6333 0.4211 0.6886 0.236 Uiso 1 1 calc R U . . .
H17B H 0.6816 0.4671 0.6625 0.236 Uiso 1 1 calc R U . . .
H17C H 0.6616 0.4028 0.6366 0.236 Uiso 1 1 calc R U . . .
C179 C 0.6086(9) 0.4897(10) 0.5713(7) 0.229(10) Uani 1 1 d . . . . .
H17D H 0.6272 0.5280 0.5887 0.343 Uiso 1 1 calc R U . . .
H17E H 0.5694 0.4899 0.5472 0.343 Uiso 1 1 calc R U . . .
H17F H 0.6371 0.4776 0.5494 0.343 Uiso 1 1 calc R U . . .
N17 N 0.5958(4) 0.4474(5) 0.6169(4) 0.132(3) Uani 1 1 d . . . . .
O49 O 0.5239(4) 0.3996(5) 0.6617(4) 0.173(4) Uani 1 1 d . . . . .
C180 C 0.5367(5) 0.0960(6) 0.8714(6) 0.136(4) Uani 1 1 d D U . . .
H180 H 0.5036 0.0743 0.8870 0.163 Uiso 1 1 calc R U . . .
C181 C 0.6470(5) 0.1328(5) 0.8767(5) 0.129(3) Uani 1 1 d . . . . .
H18A H 0.6332 0.1513 0.8437 0.193 Uiso 1 1 calc R U . . .
H18B H 0.6714 0.1059 0.8670 0.193 Uiso 1 1 calc R U . . .
H18C H 0.6727 0.1617 0.9048 0.193 Uiso 1 1 calc R U . . .
C182 C 0.6106(8) 0.0851(8) 0.9525(6) 0.173(6) Uani 1 1 d . . . . .
H18D H 0.5755 0.0822 0.9724 0.260 Uiso 1 1 calc R U . . .
H18E H 0.6465 0.1130 0.9726 0.260 Uiso 1 1 calc R U . . .
H18F H 0.6212 0.0479 0.9496 0.260 Uiso 1 1 calc R U . . .
N18 N 0.5940(3) 0.1029(4) 0.8981(3) 0.109(2) Uani 1 1 d D U . . .
O50 O 0.5241(3) 0.1171(5) 0.8261(3) 0.154(3) Uani 1 1 d . . . . .
C183 C 0.5859(6) 0.8751(5) 0.0536(5) 0.123(3) Uani 1 1 d . . . . .
H183 H 0.6115 0.8664 0.0851 0.148 Uiso 1 1 calc R U . . .
C184 C 0.6660(5) 0.9582(5) 0.0499(5) 0.122(3) Uani 1 1 d . . . . .
H18G H 0.6844 0.9448 0.0843 0.183 Uiso 1 1 calc R U . . .
H18H H 0.6607 0.9969 0.0569 0.183 Uiso 1 1 calc R U . . .
H18I H 0.6934 0.9582 0.0224 0.183 Uiso 1 1 calc R U . . .
C185 C 0.5677(7) 0.9387(7) -0.0166(6) 0.180(7) Uani 1 1 d . . . . .
H18J H 0.5245 0.9302 -0.0104 0.271 Uiso 1 1 calc R U . . .
H18K H 0.5706 0.9180 -0.0508 0.271 Uiso 1 1 calc R U . . .
H18L H 0.5817 0.9796 -0.0195 0.271 Uiso 1 1 calc R U . . .
N19 N 0.6065(4) 0.9211(4) 0.0294(4) 0.119(2) Uani 1 1 d . . . . .
O51 O 0.5338(4) 0.8416(4) 0.0373(4) 0.143(3) Uani 1 1 d . . . . .
C186 C 0.3196(9) 0.8719(8) 0.6452(9) 0.169(6) Uani 1 1 d . U . . .
C187 C 0.3612(13) 0.8496(8) 0.6853(9) 0.230(9) Uani 1 1 d . U . . .
H18M H 0.3505 0.8079 0.6808 0.346 Uiso 1 1 calc R U . . .
H18N H 0.3570 0.8620 0.7227 0.346 Uiso 1 1 calc R U . . .
H18O H 0.4041 0.8637 0.6796 0.346 Uiso 1 1 calc R U . . .
N20 N 0.2811(8) 0.8868(8) 0.6132(8) 0.220(8) Uani 1 1 d . U . . .
C188 C 0.9568(8) 0.1660(6) 0.2575(6) 0.141(4) Uani 1 1 d D U . . .
C189 C 1.0137(8) 0.1507(5) 0.2685(6) 0.155(5) Uani 1 1 d . . . . .
H18P H 1.0125 0.1238 0.2975 0.233 Uiso 1 1 calc R U . . .
H18Q H 1.0467 0.1847 0.2809 0.233 Uiso 1 1 calc R U . . .
H18R H 1.0219 0.1327 0.2349 0.233 Uiso 1 1 calc R U . . .
N21 N 0.9032(10) 0.1718(8) 0.2526(8) 0.233(7) Uani 1 1 d D U . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 O1 2.112(4) . ?
Rh1 O2 2.113(6) . ?
Rh1 N4 2.114(5) . ?
Rh1 C45 2.131(7) . ?
Rh1 C47 2.135(8) . ?
Rh1 C49 2.136(7) . ?
Rh1 C46 2.139(7) . ?
Rh1 C48 2.149(8) . ?
Rh2 O4 2.093(6) . ?
Rh2 C57 2.105(14) . ?
Rh2 C58 2.118(15) . ?
Rh2 C55 2.122(11) . ?
Rh2 N8 2.123(7) . ?
Rh2 C56 2.133(11) . ?
Rh2 C59 2.135(11) . ?
Rh2 O3 2.144(9) . ?
Rh3 C68 2.093(10) . ?
Rh3 O6 2.100(6) . ?
Rh3 O5 2.110(5) . ?
Rh3 N1 2.115(6) . ?
Rh3 C69 2.137(10) . ?
Rh3 C65 2.143(10) . ?
Rh3 C67 2.151(9) . ?
Rh3 C66 2.155(10) . ?
Rh4 C75 2.047(18) . ?
Rh4 O7 2.088(6) . ?
Rh4 C79 2.100(17) . ?
Rh4 N5 2.106(6) . ?
Rh4 O8 2.116(5) . ?
Rh4 C78 2.125(16) . ?
Rh4 C78' 2.129(15) . ?
Rh4 C76 2.131(16) . ?
Rh4 C79' 2.136(13) . ?
Rh4 C77' 2.142(15) . ?
Rh4 C75' 2.153(12) . ?
Rh4 C77 2.155(16) . ?
Rh5 C132 2.086(12) . ?
Rh5 N9 2.107(7) . ?
Rh5 O13 2.110(5) . ?
Rh5 C131 2.123(10) . ?
Rh5 O14 2.133(6) . ?
Rh5 C133 2.137(13) . ?
Rh5 C129 2.167(10) . ?
Rh5 C130 2.169(7) . ?
Rh6 O16 2.104(4) . ?
Rh6 C139 2.109(7) . ?
Rh6 C141 2.118(7) . ?
Rh6 O15 2.120(4) . ?
Rh6 C142 2.122(7) . ?
Rh6 N13 2.126(5) . ?
Rh6 C143 2.136(8) . ?
Rh6 C140 2.147(7) . ?
Rh7 C153 2.085(11) . ?
Rh7 O18 2.100(5) . ?
Rh7 O17 2.101(7) . ?
Rh7 N12 2.109(8) . ?
Rh7 C149 2.115(10) . ?
Rh7 C150 2.126(10) . ?
Rh7 C152 2.133(14) . ?
Rh7 C151 2.166(11) . ?
Rh8 O19 2.102(6) . ?
Rh8 N16 2.104(6) . ?
Rh8 O20 2.120(6) . ?
Rh8 C159 2.123(12) . ?
Rh8 C161 2.136(10) . ?
Rh8 C163 2.144(11) . ?
Rh8 C160 2.147(10) . ?
Rh8 C162 2.156(11) . ?
N2 C18 1.377(10) . ?
N2 C22 1.619(9) . ?
N2 H2 0.8800 . ?
N3 C21 1.386(10) . ?
N3 C23 1.533(8) . ?
N3 H3 0.8800 . ?
O9 C22 1.005(8) . ?
O10 C23 1.092(9) . ?
C18 C19 1.391(10) . ?
C18 C15 1.462(9) . ?
C19 C20 1.405(10) . ?
C19 C23 1.548(10) . ?
C20 C21 1.375(11) . ?
C20 C22 1.633(10) . ?
C21 C26 1.458(9) . ?
S1' C22' 1.619(9) . ?
S1' C20' 1.633(10) . ?
S2' C23' 1.533(8) . ?
S2' C19' 1.548(10) . ?
C18' C22' 1.377(10) . ?
C18' C19' 1.391(10) . ?
C18' C15 1.462(9) . ?
C19' C20' 1.405(10) . ?
C20' C21' 1.375(11) . ?
C21' C23' 1.386(10) . ?
C21' C26 1.458(9) . ?
C22' H22' 0.9500 . ?
C23' H23' 0.9500 . ?
N10 C102 1.435(11) . ?
N10 C106 1.653(10) . ?
N10 H10 0.8800 . ?
N11 C105 1.412(12) . ?
N11 C107 1.592(10) . ?
N11 H11 0.8800 . ?
O21 C106 0.942(10) . ?
O22 C107 1.117(10) . ?
C102 C103 1.403(12) . ?
C102 C99 1.437(12) . ?
C103 C104 1.397(11) . ?
C103 C107 1.583(10) . ?
C104 C105 1.370(12) . ?
C104 C106 1.725(11) . ?
C105 C110 1.451(13) . ?
S3' C206 1.653(10) . ?
S3' C204 1.725(11) . ?
S4' C203 1.583(10) . ?
S4' C207 1.592(10) . ?
C202 C203 1.403(12) . ?
C202 C206 1.435(12) . ?
C202 C99 1.437(12) . ?
C203 C204 1.397(11) . ?
C204 C205 1.370(12) . ?
C205 C207 1.412(11) . ?
C205 C110 1.451(13) . ?
C206 H206 0.9500 . ?
C207 H207 0.9500 . ?
C75 C76 1.40(3) . ?
C75 C79 1.47(3) . ?
C75 C80 1.517(17) . ?
C76 C81 1.40(3) . ?
C76 C77 1.46(2) . ?
C77 C78 1.39(3) . ?
C77 C82 1.49(3) . ?
C78 C79 1.35(2) . ?
C78 C83 1.54(2) . ?
C79 C84 1.531(17) . ?
C80 H80A 0.9800 . ?
C80 H80B 0.9800 . ?
C80 H80C 0.9800 . ?
C81 H81A 0.9800 . ?
C81 H81B 0.9800 . ?
C81 H81C 0.9800 . ?
C82 H82A 0.9800 . ?
C82 H82B 0.9800 . ?
C82 H82C 0.9800 . ?
C83 H83A 0.9800 . ?
C83 H83B 0.9800 . ?
C83 H83C 0.9800 . ?
C84 H84A 0.9800 . ?
C84 H84B 0.9800 . ?
C84 H84C 0.9800 . ?
C75' C79' 1.394(8) . ?
C75' C76' 1.394(8) . ?
C75' C80' 1.482(8) . ?
C76' C77' 1.394(8) . ?
C76' C81' 1.482(8) . ?
C77' C78' 1.394(8) . ?
C77' C82' 1.482(8) . ?
C78' C79' 1.394(8) . ?
C78' C83' 1.482(8) . ?
C79' C84' 1.482(8) . ?
C80' H80D 0.9800 . ?
C80' H80E 0.9800 . ?
C80' H80F 0.9800 . ?
C81' H81D 0.9800 . ?
C81' H81E 0.9800 . ?
C81' H81F 0.9800 . ?
C82' H82D 0.9800 . ?
C82' H82E 0.9800 . ?
C82' H82F 0.9800 . ?
C83' H83D 0.9800 . ?
C83' H83E 0.9800 . ?
C83' H83F 0.9800 . ?
C84' H84D 0.9800 . ?
C84' H84E 0.9800 . ?
C84' H84F 0.9800 . ?
N1 C17 1.325(11) . ?
N1 C13 1.367(10) . ?
N4 C24 1.330(9) . ?
N4 C28 1.350(10) . ?
N5 C29 1.347(9) . ?
N5 C33 1.359(10) . ?
N6 C34 1.385(9) . ?
N6 C38 1.447(9) . ?
N6 H6 0.8800 . ?
N7 C37 1.378(11) . ?
N7 C39 1.426(10) . ?
N7 H7 0.8800 . ?
N8 C44 1.314(14) . ?
N8 C40 1.323(14) . ?
N9 C97 1.334(11) . ?
N9 C101 1.363(11) . ?
N12 C108 1.321(12) . ?
N12 C112 1.341(12) . ?
N13 C117 1.325(9) . ?
N13 C113 1.354(8) . ?
N14 C118 1.376(9) . ?
N14 C122 1.450(9) . ?
N14 H14 0.8800 . ?
N15 C121 1.395(11) . ?
N15 C123 1.433(9) . ?
N15 H15 0.8800 . ?
N16 C124 1.333(12) . ?
N16 C128 1.371(13) . ?
O1 C1 1.266(8) . ?
O2 C2 1.263(10) . ?
O3 C4 1.273(10) . ?
O4 C5 1.274(10) . ?
O5 C7 1.261(8) . ?
O6 C8 1.289(9) . ?
O7 C10 1.283(9) . ?
O8 C11 1.259(9) . ?
O11 C38 1.200(9) . ?
O12 C39 1.166(10) . ?
O13 C85 1.277(8) . ?
O14 C86 1.281(8) . ?
O15 C88 1.270(8) . ?
O16 C89 1.279(7) . ?
O17 C91 1.288(10) . ?
O18 C92 1.285(9) . ?
O19 C94 1.291(9) . ?
O20 C95 1.269(10) . ?
O23 C122 1.191(8) . ?
O24 C123 1.180(9) . ?
O25 S1 1.383(10) . ?
O26 S1 1.417(9) . ?
O27 S1 1.449(10) . ?
O28 S2 1.411(13) . ?
O29 S2 1.355(12) . ?
O30 S2 1.476(11) . ?
O31 S3 1.384(10) . ?
O32 S3 1.447(10) . ?
O33 S3 1.468(11) . ?
O34 S4 1.492(9) . ?
O35 S4 1.420(10) . ?
O36 S4 1.408(17) . ?
O37 S5 1.427(16) . ?
O38 S5 1.554(14) . ?
O39 S5 1.433(17) . ?
O40 S6 1.366(12) . ?
O41 S6 1.431(13) . ?
O42 S6 1.638(19) . ?
S1 C169 1.75(2) . ?
S2 C170 1.754(17) . ?
S3 C171 1.788(14) . ?
S4 C172 1.62(2) . ?
S5 C173 1.82(2) . ?
S6 C174 1.653(15) . ?
F1 C169 1.32(2) . ?
F2 C169 1.27(2) . ?
F3 C169 1.302(16) . ?
F4 C170 1.298(17) . ?
F5 C170 1.340(14) . ?
F6 C170 1.30(2) . ?
F7 C171 1.342(14) . ?
F8 C171 1.365(15) . ?
F9 C171 1.365(14) . ?
F10 C172 1.39(2) . ?
F11 C172 1.36(2) . ?
F12 C172 1.359(15) . ?
F13 C173 1.28(2) . ?
F14 C173 1.22(2) . ?
F15 C173 1.312(15) . ?
F16 C174 1.373(13) . ?
F17 C174 1.317(14) . ?
F18 C174 1.415(15) . ?
C1 C6 1.380(10) . ?
C1 C2 1.520(10) . ?
C2 C3 1.411(12) . ?
C3 C4 1.357(14) . ?
C3 H3A 0.9500 . ?
C4 C5 1.497(13) . ?
C5 C6 1.402(10) . ?
C6 H6A 0.9500 . ?
C7 C12 1.391(10) . ?
C7 C8 1.534(10) . ?
C8 C9 1.387(11) . ?
C9 C10 1.368(11) . ?
C9 H9 0.9500 . ?
C10 C11 1.507(10) . ?
C11 C12 1.371(10) . ?
C12 H12 0.9500 . ?
C13 C14 1.367(10) . ?
C13 H13 0.9500 . ?
C14 C15 1.408(11) . ?
C14 H14A 0.9500 . ?
C15 C16 1.384(11) . ?
C16 C17 1.372(11) . ?
C16 H16 0.9500 . ?
C17 H17 0.9500 . ?
C24 C25 1.381(10) . ?
C24 H24 0.9500 . ?
C25 C26 1.422(11) . ?
C25 H25 0.9500 . ?
C26 C27 1.381(10) . ?
C27 C28 1.402(10) . ?
C27 H27 0.9500 . ?
C28 H28 0.9500 . ?
C29 C30 1.364(10) . ?
C29 H29 0.9500 . ?
C30 C31 1.382(10) . ?
C30 H30 0.9500 . ?
C31 C32 1.373(11) . ?
C31 C34 1.458(9) . ?
C32 C33 1.363(11) . ?
C32 H32 0.9500 . ?
C33 H33 0.9500 . ?
C34 C35 1.390(11) . ?
C35 C36 1.407(10) . ?
C35 C39 1.481(12) . ?
C36 C37 1.390(13) . ?
C36 C38 1.431(13) . ?
C37 C42 1.470(11) . ?
C40 C41 1.394(13) . ?
C40 H40 0.9500 . ?
C41 C42 1.362(14) . ?
C41 H41 0.9500 . ?
C42 C43 1.352(14) . ?
C43 C44 1.363(13) . ?
C43 H43 0.9500 . ?
C44 H44 0.9500 . ?
C45 C46 1.432(11) . ?
C45 C49 1.437(11) . ?
C45 C50 1.460(12) . ?
C46 C47 1.429(12) . ?
C46 C51 1.487(12) . ?
C47 C48 1.444(12) . ?
C47 C52 1.476(12) . ?
C48 C49 1.449(13) . ?
C48 C53 1.455(14) . ?
C49 C54 1.488(11) . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C55 C59 1.43(2) . ?
C55 C56 1.452(13) . ?
C55 C60 1.46(2) . ?
C56 C57 1.36(3) . ?
C56 C61 1.42(2) . ?
C57 C58 1.48(2) . ?
C57 C62 1.52(2) . ?
C58 C59 1.458(14) . ?
C58 C63 1.497(16) . ?
C59 C64 1.504(17) . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C63 H63A 0.9800 . ?
C63 H63B 0.9800 . ?
C63 H63C 0.9800 . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C65 C69 1.394(15) . ?
C65 C70 1.446(14) . ?
C65 C66 1.457(12) . ?
C66 C67 1.393(16) . ?
C66 C71 1.489(17) . ?
C67 C68 1.430(19) . ?
C67 C72 1.468(19) . ?
C68 C73 1.416(18) . ?
C68 C69 1.457(18) . ?
C69 C74 1.593(19) . ?
C70 H70A 0.9800 . ?
C70 H70B 0.9800 . ?
C70 H70C 0.9800 . ?
C71 H71A 0.9800 . ?
C71 H71B 0.9800 . ?
C71 H71C 0.9800 . ?
C72 H72A 0.9800 . ?
C72 H72B 0.9800 . ?
C72 H72C 0.9800 . ?
C73 H73A 0.9800 . ?
C73 H73B 0.9800 . ?
C73 H73C 0.9800 . ?
C74 H74A 0.9800 . ?
C74 H74B 0.9800 . ?
C74 H74C 0.9800 . ?
C85 C90 1.393(9) . ?
C85 C86 1.505(10) . ?
C86 C87 1.381(10) . ?
C87 C88 1.384(9) . ?
C87 H87 0.9500 . ?
C88 C89 1.531(9) . ?
C89 C90 1.365(9) . ?
C90 H90 0.9500 . ?
C91 C96 1.377(12) . ?
C91 C92 1.489(11) . ?
C92 C93 1.380(11) . ?
C93 C94 1.359(11) . ?
C93 H93 0.9500 . ?
C94 C95 1.520(11) . ?
C95 C96 1.370(12) . ?
C96 H96 0.9500 . ?
C97 C98 1.374(13) . ?
C97 H97 0.9500 . ?
C98 C99 1.347(12) . ?
C98 H98 0.9500 . ?
C99 C100 1.395(12) . ?
C100 C101 1.361(12) . ?
C100 H100 0.9500 . ?
C101 H101 0.9500 . ?
C108 C109 1.356(13) . ?
C108 H108 0.9500 . ?
C109 C110 1.418(12) . ?
C109 H109 0.9500 . ?
C110 C111 1.356(12) . ?
C111 C112 1.432(13) . ?
C111 H111 0.9500 . ?
C112 H112 0.9500 . ?
C113 C114 1.385(10) . ?
C113 H113 0.9500 . ?
C114 C115 1.385(11) . ?
C114 H114 0.9500 . ?
C115 C116 1.385(10) . ?
C115 C118 1.465(10) . ?
C116 C117 1.403(10) . ?
C116 H116 0.9500 . ?
C117 H117 0.9500 . ?
C118 C119 1.394(12) . ?
C119 C120 1.407(9) . ?
C119 C123 1.448(12) . ?
C120 C121 1.338(12) . ?
C120 C122 1.498(12) . ?
C121 C126 1.465(10) . ?
C124 C125 1.407(11) . ?
C124 H124 0.9500 . ?
C125 C126 1.413(14) . ?
C125 H125 0.9500 . ?
C126 C127 1.364(13) . ?
C127 C128 1.364(12) . ?
C127 H127 0.9500 . ?
C128 H128 0.9500 . ?
C129 C133 1.406(19) . ?
C129 C134 1.455(19) . ?
C129 C130 1.466(15) . ?
C130 C131 1.385(15) . ?
C130 C135 1.499(13) . ?
C131 C132 1.445(18) . ?
C131 C136 1.567(18) . ?
C132 C133 1.39(2) . ?
C132 C137 1.54(2) . ?
C133 C138 1.515(19) . ?
C134 H13A 0.9800 . ?
C134 H13B 0.9800 . ?
C134 H13C 0.9800 . ?
C135 H13D 0.9800 . ?
C135 H13E 0.9800 . ?
C135 H13F 0.9800 . ?
C136 H13G 0.9800 . ?
C136 H13H 0.9800 . ?
C136 H13I 0.9800 . ?
C137 H13J 0.9800 . ?
C137 H13K 0.9800 . ?
C137 H13L 0.9800 . ?
C138 H13M 0.9800 . ?
C138 H13N 0.9800 . ?
C138 H13O 0.9800 . ?
C139 C143 1.426(14) . ?
C139 C140 1.438(12) . ?
C139 C144 1.487(12) . ?
C140 C141 1.348(11) . ?
C140 C145 1.496(13) . ?
C141 C142 1.410(12) . ?
C141 C146 1.531(12) . ?
C142 C143 1.425(13) . ?
C142 C147 1.515(12) . ?
C143 C148 1.500(13) . ?
C144 H144 0.9800 . ?
C144 H14B 0.9800 . ?
C144 H14C 0.9800 . ?
C145 H14D 0.9800 . ?
C145 H14E 0.9800 . ?
C145 H14F 0.9800 . ?
C146 H14G 0.9800 . ?
C146 H14H 0.9800 . ?
C146 H14I 0.9800 . ?
C147 H14J 0.9800 . ?
C147 H14K 0.9800 . ?
C147 H14L 0.9800 . ?
C148 H14M 0.9800 . ?
C148 H14N 0.9800 . ?
C148 H14O 0.9800 . ?
C149 C153 1.40(2) . ?
C149 C150 1.417(14) . ?
C149 C154 1.59(2) . ?
C150 C151 1.414(13) . ?
C150 C155 1.491(14) . ?
C151 C152 1.32(2) . ?
C151 C156 1.482(18) . ?
C152 C153 1.43(2) . ?
C152 C157 1.60(2) . ?
C153 C158 1.66(2) . ?
C154 H15A 0.9800 . ?
C154 H15B 0.9800 . ?
C154 H15C 0.9800 . ?
C155 H15D 0.9800 . ?
C155 H15E 0.9800 . ?
C155 H15F 0.9800 . ?
C156 H15G 0.9800 . ?
C156 H15H 0.9800 . ?
C156 H15I 0.9800 . ?
C157 H15J 0.9800 . ?
C157 H15K 0.9800 . ?
C157 H15L 0.9800 . ?
C158 H15M 0.9800 . ?
C158 H15N 0.9800 . ?
C158 H15O 0.9800 . ?
C159 C160 1.356(19) . ?
C159 C163 1.41(2) . ?
C159 C164 1.54(2) . ?
C160 C161 1.401(15) . ?
C160 C165 1.49(2) . ?
C161 C162 1.461(15) . ?
C161 C166 1.505(14) . ?
C162 C167 1.375(16) . ?
C162 C163 1.500(17) . ?
C163 C168 1.48(2) . ?
C164 H16A 0.9800 . ?
C164 H16B 0.9800 . ?
C164 H16C 0.9800 . ?
C165 H16D 0.9800 . ?
C165 H16E 0.9800 . ?
C165 H16F 0.9800 . ?
C166 H16G 0.9800 . ?
C166 H16H 0.9800 . ?
C166 H16I 0.9800 . ?
C167 H16J 0.9800 . ?
C167 H16K 0.9800 . ?
C167 H16L 0.9800 . ?
C168 H16M 0.9800 . ?
C168 H16N 0.9800 . ?
C168 H16O 0.9800 . ?
C177 N17 1.247(14) . ?
C177 O49 1.253(16) . ?
C177 H177 0.9500 . ?
C178 N17 1.468(16) . ?
C178 H17A 0.9800 . ?
C178 H17B 0.9800 . ?
C178 H17C 0.9800 . ?
C179 N17 1.562(19) . ?
C179 H17D 0.9800 . ?
C179 H17E 0.9800 . ?
C179 H17F 0.9800 . ?
C180 O50 1.261(15) . ?
C180 N18 1.319(12) . ?
C180 H180 0.9500 . ?
C181 N18 1.434(13) . ?
C181 H18A 0.9800 . ?
C181 H18B 0.9800 . ?
C181 H18C 0.9800 . ?
C182 N18 1.441(15) . ?
C182 H18D 0.9800 . ?
C182 H18E 0.9800 . ?
C182 H18F 0.9800 . ?
C183 O51 1.261(14) . ?
C183 N19 1.309(13) . ?
C183 H183 0.9500 . ?
C184 N19 1.440(13) . ?
C184 H18G 0.9800 . ?
C184 H18H 0.9800 . ?
C184 H18I 0.9800 . ?
C185 N19 1.449(15) . ?
C185 H18J 0.9800 . ?
C185 H18K 0.9800 . ?
C185 H18L 0.9800 . ?
C186 N20 1.20(2) . ?
C186 C187 1.45(3) . ?
C187 H18M 0.9800 . ?
C187 H18N 0.9800 . ?
C187 H18O 0.9800 . ?
C188 N21 1.226(18) . ?
C188 C189 1.39(2) . ?
C189 H18P 0.9800 . ?
C189 H18Q 0.9800 . ?
C189 H18R 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Rh1 O2 76.4(2) . . ?
O1 Rh1 N4 85.87(19) . . ?
O2 Rh1 N4 84.6(2) . . ?
O1 Rh1 C45 130.2(2) . . ?
O2 Rh1 C45 94.5(3) . . ?
N4 Rh1 C45 142.8(2) . . ?
O1 Rh1 C47 98.1(2) . . ?
O2 Rh1 C47 149.5(3) . . ?
N4 Rh1 C47 125.3(3) . . ?
C45 Rh1 C47 65.8(3) . . ?
O1 Rh1 C49 162.9(2) . . ?
O2 Rh1 C49 114.1(3) . . ?
N4 Rh1 C49 107.9(3) . . ?
C45 Rh1 C49 39.3(3) . . ?
C47 Rh1 C49 65.9(3) . . ?
O1 Rh1 C46 98.3(2) . . ?
O2 Rh1 C46 111.2(3) . . ?
N4 Rh1 C46 164.1(3) . . ?
C45 Rh1 C46 39.2(3) . . ?
C47 Rh1 C46 39.1(3) . . ?
C49 Rh1 C46 65.7(3) . . ?
O1 Rh1 C48 129.9(3) . . ?
O2 Rh1 C48 153.4(3) . . ?
N4 Rh1 C48 99.6(3) . . ?
C45 Rh1 C48 66.3(3) . . ?
C47 Rh1 C48 39.4(3) . . ?
C49 Rh1 C48 39.5(3) . . ?
C46 Rh1 C48 65.9(3) . . ?
O4 Rh2 C57 145.4(8) . . ?
O4 Rh2 C58 105.9(5) . . ?
C57 Rh2 C58 40.9(7) . . ?
O4 Rh2 C55 118.2(3) . . ?
C57 Rh2 C55 65.0(6) . . ?
C58 Rh2 C55 67.6(6) . . ?
O4 Rh2 N8 85.1(3) . . ?
C57 Rh2 N8 97.6(5) . . ?
C58 Rh2 N8 110.3(5) . . ?
C55 Rh2 N8 156.6(4) . . ?
O4 Rh2 C56 158.0(4) . . ?
C57 Rh2 C56 37.6(7) . . ?
C58 Rh2 C56 67.3(8) . . ?
C55 Rh2 C56 39.9(4) . . ?
N8 Rh2 C56 116.9(4) . . ?
O4 Rh2 C59 95.0(4) . . ?
C57 Rh2 C59 65.6(5) . . ?
C58 Rh2 C59 40.1(4) . . ?
C55 Rh2 C59 39.2(5) . . ?
N8 Rh2 C59 149.2(5) . . ?
C56 Rh2 C59 66.0(6) . . ?
O4 Rh2 O3 76.5(2) . . ?
C57 Rh2 O3 138.0(8) . . ?
C58 Rh2 O3 164.3(4) . . ?
C55 Rh2 O3 97.5(5) . . ?
N8 Rh2 O3 85.2(3) . . ?
C56 Rh2 O3 104.5(7) . . ?
C59 Rh2 O3 124.9(4) . . ?
C68 Rh3 O6 103.6(4) . . ?
C68 Rh3 O5 158.3(5) . . ?
O6 Rh3 O5 77.0(2) . . ?
C68 Rh3 N1 116.4(5) . . ?
O6 Rh3 N1 85.4(2) . . ?
O5 Rh3 N1 85.3(2) . . ?
C68 Rh3 C69 40.3(5) . . ?
O6 Rh3 C69 140.2(4) . . ?
O5 Rh3 C69 142.8(4) . . ?
N1 Rh3 C69 97.1(4) . . ?
C68 Rh3 C65 66.2(4) . . ?
O6 Rh3 C65 162.3(3) . . ?
O5 Rh3 C65 106.9(3) . . ?
N1 Rh3 C65 112.0(3) . . ?
C69 Rh3 C65 38.0(4) . . ?
C68 Rh3 C67 39.3(5) . . ?
O6 Rh3 C67 97.1(4) . . ?
O5 Rh3 C67 119.0(4) . . ?
N1 Rh3 C67 155.6(4) . . ?
C69 Rh3 C67 65.7(5) . . ?
C65 Rh3 C67 65.7(4) . . ?
C68 Rh3 C66 64.9(5) . . ?
O6 Rh3 C66 123.5(3) . . ?
O5 Rh3 C66 96.3(3) . . ?
N1 Rh3 C66 150.8(3) . . ?
C69 Rh3 C66 64.4(4) . . ?
C65 Rh3 C66 39.6(3) . . ?
C67 Rh3 C66 37.8(4) . . ?
C75 Rh4 O7 134.8(7) . . ?
C75 Rh4 C79 41.5(8) . . ?
O7 Rh4 C79 99.6(5) . . ?
C75 Rh4 N5 139.3(7) . . ?
O7 Rh4 N5 85.4(2) . . ?
C79 Rh4 N5 161.2(6) . . ?
C75 Rh4 O8 96.8(5) . . ?
O7 Rh4 O8 77.0(2) . . ?
C79 Rh4 O8 113.6(6) . . ?
N5 Rh4 O8 85.1(2) . . ?
C75 Rh4 C78 64.5(7) . . ?
O7 Rh4 C78 99.4(5) . . ?
C79 Rh4 C78 37.2(7) . . ?
N5 Rh4 C78 124.2(6) . . ?
O8 Rh4 C78 150.3(6) . . ?
O7 Rh4 C78' 107.6(5) . . ?
N5 Rh4 C78' 114.9(5) . . ?
O8 Rh4 C78' 159.5(4) . . ?
C75 Rh4 C76 39.2(7) . . ?
O7 Rh4 C76 163.9(5) . . ?
C79 Rh4 C76 67.3(7) . . ?
N5 Rh4 C76 104.1(5) . . ?
O8 Rh4 C76 116.3(5) . . ?
C78 Rh4 C76 64.5(7) . . ?
O7 Rh4 C79' 97.4(4) . . ?
N5 Rh4 C79' 152.4(5) . . ?
O8 Rh4 C79' 122.3(4) . . ?
C78' Rh4 C79' 38.2(3) . . ?
O7 Rh4 C77' 143.4(6) . . ?
N5 Rh4 C77' 98.3(4) . . ?
O8 Rh4 C77' 139.5(6) . . ?
C78' Rh4 C77' 38.1(3) . . ?
C79' Rh4 C77' 63.7(4) . . ?
O7 Rh4 C75' 121.2(4) . . ?
N5 Rh4 C75' 153.1(4) . . ?
O8 Rh4 C75' 96.6(4) . . ?
C78' Rh4 C75' 63.6(4) . . ?
C79' Rh4 C75' 37.9(3) . . ?
C77' Rh4 C75' 63.4(4) . . ?
C75 Rh4 C77 65.9(7) . . ?
O7 Rh4 C77 127.2(5) . . ?
C79 Rh4 C77 65.3(7) . . ?
N5 Rh4 C77 97.2(5) . . ?
O8 Rh4 C77 155.8(5) . . ?
C78 Rh4 C77 37.8(7) . . ?
C76 Rh4 C77 39.7(6) . . ?
C132 Rh5 N9 157.9(4) . . ?
C132 Rh5 O13 115.5(4) . . ?
N9 Rh5 O13 86.4(2) . . ?
C132 Rh5 C131 40.2(5) . . ?
N9 Rh5 C131 118.0(4) . . ?
O13 Rh5 C131 155.6(3) . . ?
C132 Rh5 O14 100.7(5) . . ?
N9 Rh5 O14 86.7(3) . . ?
O13 Rh5 O14 77.29(19) . . ?
C131 Rh5 O14 103.2(4) . . ?
C132 Rh5 C133 38.4(6) . . ?
N9 Rh5 C133 142.6(6) . . ?
O13 Rh5 C133 95.1(4) . . ?
C131 Rh5 C133 65.6(6) . . ?
O14 Rh5 C133 130.1(6) . . ?
C132 Rh5 C129 64.6(6) . . ?
N9 Rh5 C129 106.5(4) . . ?
O13 Rh5 C129 109.3(3) . . ?
C131 Rh5 C129 65.2(5) . . ?
O14 Rh5 C129 165.3(4) . . ?
C133 Rh5 C129 38.1(5) . . ?
C132 Rh5 C130 64.7(4) . . ?
N9 Rh5 C130 95.2(3) . . ?
O13 Rh5 C130 147.8(3) . . ?
C131 Rh5 C130 37.6(4) . . ?
O14 Rh5 C130 134.9(3) . . ?
C133 Rh5 C130 64.7(4) . . ?
C129 Rh5 C130 39.5(4) . . ?
O16 Rh6 C139 111.8(3) . . ?
O16 Rh6 C141 154.6(3) . . ?
C139 Rh6 C141 64.7(3) . . ?
O16 Rh6 O15 77.35(16) . . ?
C139 Rh6 O15 101.2(3) . . ?
C141 Rh6 O15 127.9(3) . . ?
O16 Rh6 C142 115.8(3) . . ?
C139 Rh6 C142 65.9(3) . . ?
C141 Rh6 C142 38.8(3) . . ?
O15 Rh6 C142 163.8(2) . . ?
O16 Rh6 N13 83.92(19) . . ?
C139 Rh6 N13 164.0(3) . . ?
C141 Rh6 N13 99.8(3) . . ?
O15 Rh6 N13 85.00(19) . . ?
C142 Rh6 N13 105.1(3) . . ?
O16 Rh6 C143 96.3(2) . . ?
C139 Rh6 C143 39.2(4) . . ?
C141 Rh6 C143 64.6(3) . . ?
O15 Rh6 C143 134.7(4) . . ?
C142 Rh6 C143 39.1(4) . . ?
N13 Rh6 C143 139.6(4) . . ?
O16 Rh6 C140 150.6(3) . . ?
C139 Rh6 C140 39.5(3) . . ?
C141 Rh6 C140 36.8(3) . . ?
O15 Rh6 C140 99.7(2) . . ?
C142 Rh6 C140 64.2(3) . . ?
N13 Rh6 C140 125.2(3) . . ?
C143 Rh6 C140 64.7(3) . . ?
C153 Rh7 O18 156.1(7) . . ?
C153 Rh7 O17 126.2(7) . . ?
O18 Rh7 O17 76.9(2) . . ?
C153 Rh7 N12 100.6(5) . . ?
O18 Rh7 N12 85.5(2) . . ?
O17 Rh7 N12 86.1(3) . . ?
C153 Rh7 C149 39.0(7) . . ?
O18 Rh7 C149 142.7(6) . . ?
O17 Rh7 C149 99.5(5) . . ?
N12 Rh7 C149 131.7(5) . . ?
C153 Rh7 C150 65.4(5) . . ?
O18 Rh7 C150 105.4(4) . . ?
O17 Rh7 C150 105.8(4) . . ?
N12 Rh7 C150 165.3(4) . . ?
C149 Rh7 C150 39.0(4) . . ?
C153 Rh7 C152 39.6(7) . . ?
O18 Rh7 C152 116.6(5) . . ?
O17 Rh7 C152 164.4(5) . . ?
N12 Rh7 C152 102.1(5) . . ?
C149 Rh7 C152 65.1(6) . . ?
C150 Rh7 C152 64.3(6) . . ?
C153 Rh7 C151 62.7(6) . . ?
O18 Rh7 C151 96.0(4) . . ?
O17 Rh7 C151 141.0(4) . . ?
N12 Rh7 C151 132.1(4) . . ?
C149 Rh7 C151 63.3(5) . . ?
C150 Rh7 C151 38.5(4) . . ?
C152 Rh7 C151 35.7(5) . . ?
O19 Rh8 N16 86.6(3) . . ?
O19 Rh8 O20 77.2(2) . . ?
N16 Rh8 O20 86.6(3) . . ?
O19 Rh8 C159 115.4(5) . . ?
N16 Rh8 C159 157.5(5) . . ?
O20 Rh8 C159 102.2(4) . . ?
O19 Rh8 C161 151.9(3) . . ?
N16 Rh8 C161 95.0(3) . . ?
O20 Rh8 C161 130.9(3) . . ?
C159 Rh8 C161 63.6(5) . . ?
O19 Rh8 C163 95.3(4) . . ?
N16 Rh8 C163 140.8(5) . . ?
O20 Rh8 C163 132.1(5) . . ?
C159 Rh8 C163 38.6(6) . . ?
C161 Rh8 C163 66.2(4) . . ?
O19 Rh8 C160 152.1(4) . . ?
N16 Rh8 C160 121.3(4) . . ?
O20 Rh8 C160 101.4(4) . . ?
C159 Rh8 C160 37.0(5) . . ?
C161 Rh8 C160 38.2(4) . . ?
C163 Rh8 C160 64.6(6) . . ?
O19 Rh8 C162 112.5(4) . . ?
N16 Rh8 C162 102.7(4) . . ?
O20 Rh8 C162 166.7(3) . . ?
C159 Rh8 C162 65.8(5) . . ?
C161 Rh8 C162 39.8(4) . . ?
C163 Rh8 C162 40.8(5) . . ?
C160 Rh8 C162 65.6(5) . . ?
C18 N2 C22 117.5(6) . . ?
C18 N2 H2 121.2 . . ?
C22 N2 H2 121.2 . . ?
C21 N3 C23 114.9(6) . . ?
C21 N3 H3 122.5 . . ?
C23 N3 H3 122.5 . . ?
N2 C18 C19 107.7(6) . . ?
N2 C18 C15 123.3(7) . . ?
C19 C18 C15 128.9(7) . . ?
C18 C19 C20 110.4(7) . . ?
C18 C19 C23 138.0(6) . . ?
C20 C19 C23 111.6(6) . . ?
C21 C20 C19 110.5(7) . . ?
C21 C20 C22 135.4(6) . . ?
C19 C20 C22 114.1(6) . . ?
C20 C21 N3 107.3(6) . . ?
C20 C21 C26 130.3(7) . . ?
N3 C21 C26 122.2(7) . . ?
O9 C22 N2 125.3(8) . . ?
O9 C22 C20 144.3(8) . . ?
N2 C22 C20 90.1(5) . . ?
O10 C23 N3 123.6(7) . . ?
O10 C23 C19 140.6(6) . . ?
N3 C23 C19 95.5(5) . . ?
C22' S1' C20' 90.1(5) . . ?
C23' S2' C19' 95.5(5) . . ?
C22' C18' C19' 107.7(6) . . ?
C22' C18' C15 123.3(7) . . ?
C19' C18' C15 128.9(7) . . ?
C18' C19' C20' 110.4(7) . . ?
C18' C19' S2' 138.0(6) . . ?
C20' C19' S2' 111.6(6) . . ?
C21' C20' C19' 110.5(7) . . ?
C21' C20' S1' 135.4(6) . . ?
C19' C20' S1' 114.1(6) . . ?
C20' C21' C23' 107.3(6) . . ?
C20' C21' C26 130.3(7) . . ?
C23' C21' C26 122.2(7) . . ?
C18' C22' S1' 117.5(6) . . ?
C18' C22' H22' 121.2 . . ?
S1' C22' H22' 121.2 . . ?
C21' C23' S2' 114.9(6) . . ?
C21' C23' H23' 122.5 . . ?
S2' C23' H23' 122.5 . . ?
C102 N10 C106 119.0(7) . . ?
C102 N10 H10 120.5 . . ?
C106 N10 H10 120.5 . . ?
C105 N11 C107 112.8(7) . . ?
C105 N11 H11 123.6 . . ?
C107 N11 H11 123.6 . . ?
C103 C102 N10 106.5(7) . . ?
C103 C102 C99 131.5(8) . . ?
N10 C102 C99 121.9(8) . . ?
C104 C103 C102 112.0(7) . . ?
C104 C103 C107 112.6(7) . . ?
C102 C103 C107 134.9(7) . . ?
C105 C104 C103 110.9(7) . . ?
C105 C104 C106 134.1(7) . . ?
C103 C104 C106 115.0(7) . . ?
C104 C105 N11 108.8(8) . . ?
C104 C105 C110 130.5(8) . . ?
N11 C105 C110 120.7(8) . . ?
O21 C106 N10 130.5(10) . . ?
O21 C106 C104 142.0(10) . . ?
N10 C106 C104 87.4(5) . . ?
O22 C107 C103 141.3(8) . . ?
O22 C107 N11 117.9(8) . . ?
C103 C107 N11 94.1(5) . . ?
C206 S3' C204 87.4(5) . . ?
C203 S4' C207 94.1(5) . . ?
C203 C202 C206 106.5(7) . . ?
C203 C202 C99 131.5(8) . . ?
C206 C202 C99 121.9(8) . . ?
C204 C203 C202 112.0(7) . . ?
C204 C203 S4' 112.6(7) . . ?
C202 C203 S4' 134.9(7) . . ?
C205 C204 C203 110.9(7) . . ?
C205 C204 S3' 134.1(7) . . ?
C203 C204 S3' 115.0(7) . . ?
C204 C205 C207 108.8(8) . . ?
C204 C205 C110 130.5(8) . . ?
C207 C205 C110 120.7(8) . . ?
C202 C206 S3' 119.0(7) . . ?
C202 C206 H206 120.5 . . ?
S3' C206 H206 120.5 . . ?
C205 C207 S4' 112.8(7) . . ?
C205 C207 H207 123.6 . . ?
S4' C207 H207 123.6 . . ?
C76 C75 C79 109.4(15) . . ?
C76 C75 C80 128(2) . . ?
C79 C75 C80 122(2) . . ?
C76 C75 Rh4 73.6(10) . . ?
C79 C75 Rh4 71.2(9) . . ?
C80 C75 Rh4 123.6(14) . . ?
C81 C76 C75 124.5(18) . . ?
C81 C76 C77 129.2(19) . . ?
C75 C76 C77 106.2(16) . . ?
C81 C76 Rh4 129.5(13) . . ?
C75 C76 Rh4 67.2(10) . . ?
C77 C76 Rh4 71.0(9) . . ?
C78 C77 C76 105.9(15) . . ?
C78 C77 C82 128.9(18) . . ?
C76 C77 C82 125.2(19) . . ?
C78 C77 Rh4 69.9(10) . . ?
C76 C77 Rh4 69.3(9) . . ?
C82 C77 Rh4 127.1(12) . . ?
C79 C78 C77 114.1(16) . . ?
C79 C78 C83 121.3(19) . . ?
C77 C78 C83 124.5(19) . . ?
C79 C78 Rh4 70.4(10) . . ?
C77 C78 Rh4 72.2(9) . . ?
C83 C78 Rh4 123.9(13) . . ?
C78 C79 C75 104.4(15) . . ?
C78 C79 C84 128(2) . . ?
C75 C79 C84 128(2) . . ?
C78 C79 Rh4 72.4(9) . . ?
C75 C79 Rh4 67.3(10) . . ?
C84 C79 Rh4 124.2(13) . . ?
C75 C80 H80A 109.5 . . ?
C75 C80 H80B 109.5 . . ?
H80A C80 H80B 109.5 . . ?
C75 C80 H80C 109.5 . . ?
H80A C80 H80C 109.5 . . ?
H80B C80 H80C 109.5 . . ?
C76 C81 H81A 109.5 . . ?
C76 C81 H81B 109.5 . . ?
H81A C81 H81B 109.5 . . ?
C76 C81 H81C 109.5 . . ?
H81A C81 H81C 109.5 . . ?
H81B C81 H81C 109.5 . . ?
C77 C82 H82A 109.5 . . ?
C77 C82 H82B 109.5 . . ?
H82A C82 H82B 109.5 . . ?
C77 C82 H82C 109.5 . . ?
H82A C82 H82C 109.5 . . ?
H82B C82 H82C 109.5 . . ?
C78 C83 H83A 109.5 . . ?
C78 C83 H83B 109.5 . . ?
H83A C83 H83B 109.5 . . ?
C78 C83 H83C 109.5 . . ?
H83A C83 H83C 109.5 . . ?
H83B C83 H83C 109.5 . . ?
C79 C84 H84A 109.5 . . ?
C79 C84 H84B 109.5 . . ?
H84A C84 H84B 109.5 . . ?
C79 C84 H84C 109.5 . . ?
H84A C84 H84C 109.5 . . ?
H84B C84 H84C 109.5 . . ?
C79' C75' C76' 108.0 . . ?
C79' C75' C80' 126.0 . . ?
C76' C75' C80' 126.0 . . ?
C79' C75' Rh4 70.4(5) . . ?
C76' C75' Rh4 71.3(4) . . ?
C80' C75' Rh4 124.0(5) . . ?
C75' C76' C77' 108.0 . . ?
C75' C76' C81' 126.0 . . ?
C77' C76' C81' 126.0 . . ?
C75' C76' Rh4 71.0(4) . . ?
C77' C76' Rh4 70.5(5) . . ?
C81' C76' Rh4 124.1(5) . . ?
C78' C77' C76' 108.0 . . ?
C78' C77' C82' 126.0 . . ?
C76' C77' C82' 126.0 . . ?
C78' C77' Rh4 70.4(5) . . ?
C76' C77' Rh4 71.7(5) . . ?
C82' C77' Rh4 123.5(4) . . ?
C77' C78' C79' 108.0 . . ?
C77' C78' C83' 126.0 . . ?
C79' C78' C83' 126.0 . . ?
C77' C78' Rh4 71.5(5) . . ?
C79' C78' Rh4 71.2(5) . . ?
C83' C78' Rh4 123.0(4) . . ?
C75' C79' C78' 108.0 . . ?
C75' C79' C84' 126.0 . . ?
C78' C79' C84' 126.0 . . ?
C75' C79' Rh4 71.7(5) . . ?
C78' C79' Rh4 70.6(5) . . ?
C84' C79' Rh4 123.3(4) . . ?
C75' C80' H80D 109.5 . . ?
C75' C80' H80E 109.5 . . ?
H80D C80' H80E 109.5 . . ?
C75' C80' H80F 109.5 . . ?
H80D C80' H80F 109.5 . . ?
H80E C80' H80F 109.5 . . ?
C76' C81' H81D 109.5 . . ?
C76' C81' H81E 109.5 . . ?
H81D C81' H81E 109.5 . . ?
C76' C81' H81F 109.5 . . ?
H81D C81' H81F 109.5 . . ?
H81E C81' H81F 109.5 . . ?
C77' C82' H82D 109.5 . . ?
C77' C82' H82E 109.5 . . ?
H82D C82' H82E 109.5 . . ?
C77' C82' H82F 109.5 . . ?
H82D C82' H82F 109.5 . . ?
H82E C82' H82F 109.5 . . ?
C78' C83' H83D 109.5 . . ?
C78' C83' H83E 109.5 . . ?
H83D C83' H83E 109.5 . . ?
C78' C83' H83F 109.5 . . ?
H83D C83' H83F 109.5 . . ?
H83E C83' H83F 109.5 . . ?
C79' C84' H84D 109.5 . . ?
C79' C84' H84E 109.5 . . ?
H84D C84' H84E 109.5 . . ?
C79' C84' H84F 109.5 . . ?
H84D C84' H84F 109.5 . . ?
H84E C84' H84F 109.5 . . ?
C17 N1 C13 116.4(6) . . ?
C17 N1 Rh3 125.8(5) . . ?
C13 N1 Rh3 117.3(5) . . ?
C24 N4 C28 118.1(6) . . ?
C24 N4 Rh1 120.6(5) . . ?
C28 N4 Rh1 121.1(4) . . ?
C29 N5 C33 116.1(6) . . ?
C29 N5 Rh4 122.1(5) . . ?
C33 N5 Rh4 121.8(5) . . ?
C34 N6 C38 112.6(7) . . ?
C34 N6 H6 123.7 . . ?
C38 N6 H6 123.7 . . ?
C37 N7 C39 113.0(8) . . ?
C37 N7 H7 123.5 . . ?
C39 N7 H7 123.5 . . ?
C44 N8 C40 117.8(8) . . ?
C44 N8 Rh2 123.0(7) . . ?
C40 N8 Rh2 119.0(8) . . ?
C97 N9 C101 118.3(8) . . ?
C97 N9 Rh5 121.0(6) . . ?
C101 N9 Rh5 120.5(6) . . ?
C108 N12 C112 116.8(8) . . ?
C108 N12 Rh7 123.6(6) . . ?
C112 N12 Rh7 119.6(6) . . ?
C117 N13 C113 118.5(6) . . ?
C117 N13 Rh6 120.5(4) . . ?
C113 N13 Rh6 120.8(5) . . ?
C118 N14 C122 111.6(7) . . ?
C118 N14 H14 124.2 . . ?
C122 N14 H14 124.2 . . ?
C121 N15 C123 111.4(7) . . ?
C121 N15 H15 124.3 . . ?
C123 N15 H15 124.3 . . ?
C124 N16 C128 119.6(7) . . ?
C124 N16 Rh8 119.7(7) . . ?
C128 N16 Rh8 120.7(6) . . ?
C1 O1 Rh1 115.9(4) . . ?
C2 O2 Rh1 116.1(5) . . ?
C4 O3 Rh2 114.7(7) . . ?
C5 O4 Rh2 116.2(6) . . ?
C7 O5 Rh3 116.0(4) . . ?
C8 O6 Rh3 116.5(5) . . ?
C10 O7 Rh4 115.7(4) . . ?
C11 O8 Rh4 115.2(4) . . ?
C85 O13 Rh5 115.2(5) . . ?
C86 O14 Rh5 114.3(5) . . ?
C88 O15 Rh6 115.3(4) . . ?
C89 O16 Rh6 115.7(4) . . ?
C91 O17 Rh7 116.0(5) . . ?
C92 O18 Rh7 115.2(5) . . ?
C94 O19 Rh8 115.5(5) . . ?
C95 O20 Rh8 115.6(5) . . ?
O25 S1 O26 122.9(8) . . ?
O25 S1 O27 109.5(8) . . ?
O26 S1 O27 108.3(7) . . ?
O25 S1 C169 103.8(8) . . ?
O26 S1 C169 106.2(8) . . ?
O27 S1 C169 104.5(10) . . ?
O29 S2 O28 127.3(9) . . ?
O29 S2 O30 110.0(9) . . ?
O28 S2 O30 108.5(9) . . ?
O29 S2 C170 104.1(8) . . ?
O28 S2 C170 105.2(9) . . ?
O30 S2 C170 97.4(9) . . ?
O31 S3 O32 113.7(8) . . ?
O31 S3 O33 117.8(7) . . ?
O32 S3 O33 120.6(8) . . ?
O31 S3 C171 104.4(8) . . ?
O32 S3 C171 96.3(7) . . ?
O33 S3 C171 97.9(9) . . ?
O36 S4 O35 119.8(13) . . ?
O36 S4 O34 112.0(12) . . ?
O35 S4 O34 117.9(6) . . ?
O36 S4 C172 95.1(12) . . ?
O35 S4 C172 105.5(9) . . ?
O34 S4 C172 101.4(9) . . ?
O37 S5 O39 129.8(14) . . ?
O37 S5 O38 108.5(10) . . ?
O39 S5 O38 109.7(13) . . ?
O37 S5 C173 106.9(13) . . ?
O39 S5 C173 92.4(11) . . ?
O38 S5 C173 106.3(11) . . ?
O40 S6 O41 119.9(11) . . ?
O40 S6 O42 122.1(14) . . ?
O41 S6 O42 114.9(11) . . ?
O40 S6 C174 104.8(9) . . ?
O41 S6 C174 97.0(9) . . ?
O42 S6 C174 84.9(12) . . ?
O1 C1 C6 124.7(6) . . ?
O1 C1 C2 115.7(6) . . ?
C6 C1 C2 119.6(6) . . ?
O2 C2 C3 124.5(7) . . ?
O2 C2 C1 115.5(6) . . ?
C3 C2 C1 119.9(8) . . ?
C4 C3 C2 119.9(8) . . ?
C4 C3 H3A 120.1 . . ?
C2 C3 H3A 120.1 . . ?
O3 C4 C3 123.6(9) . . ?
O3 C4 C5 116.1(9) . . ?
C3 C4 C5 120.3(7) . . ?
O4 C5 C6 122.5(8) . . ?
O4 C5 C4 116.4(7) . . ?
C6 C5 C4 121.1(8) . . ?
C1 C6 C5 119.3(7) . . ?
C1 C6 H6A 120.4 . . ?
C5 C6 H6A 120.4 . . ?
O5 C7 C12 124.5(6) . . ?
O5 C7 C8 116.3(6) . . ?
C12 C7 C8 119.2(6) . . ?
O6 C8 C9 125.3(7) . . ?
O6 C8 C7 114.2(6) . . ?
C9 C8 C7 120.5(7) . . ?
C10 C9 C8 119.1(7) . . ?
C10 C9 H9 120.5 . . ?
C8 C9 H9 120.5 . . ?
O7 C10 C9 123.6(7) . . ?
O7 C10 C11 115.5(7) . . ?
C9 C10 C11 120.8(7) . . ?
O8 C11 C12 122.6(7) . . ?
O8 C11 C10 116.3(6) . . ?
C12 C11 C10 121.1(7) . . ?
C11 C12 C7 119.4(7) . . ?
C11 C12 H12 120.3 . . ?
C7 C12 H12 120.3 . . ?
N1 C13 C14 122.6(8) . . ?
N1 C13 H13 118.7 . . ?
C14 C13 H13 118.7 . . ?
C13 C14 C15 119.7(7) . . ?
C13 C14 H14A 120.1 . . ?
C15 C14 H14A 120.1 . . ?
C16 C15 C14 117.4(6) . . ?
C16 C15 C18 123.1(7) . . ?
C14 C15 C18 119.4(7) . . ?
C16 C15 C18' 123.1(7) . . ?
C14 C15 C18' 119.4(7) . . ?
C17 C16 C15 118.8(8) . . ?
C17 C16 H16 120.6 . . ?
C15 C16 H16 120.6 . . ?
N1 C17 C16 125.0(8) . . ?
N1 C17 H17 117.5 . . ?
C16 C17 H17 117.5 . . ?
N4 C24 C25 123.6(7) . . ?
N4 C24 H24 118.2 . . ?
C25 C24 H24 118.2 . . ?
C24 C25 C26 118.6(7) . . ?
C24 C25 H25 120.7 . . ?
C26 C25 H25 120.7 . . ?
C27 C26 C25 118.1(6) . . ?
C27 C26 C21 121.5(7) . . ?
C25 C26 C21 120.4(6) . . ?
C27 C26 C21' 121.5(7) . . ?
C25 C26 C21' 120.4(6) . . ?
C26 C27 C28 118.9(7) . . ?
C26 C27 H27 120.5 . . ?
C28 C27 H27 120.5 . . ?
N4 C28 C27 122.7(7) . . ?
N4 C28 H28 118.6 . . ?
C27 C28 H28 118.6 . . ?
N5 C29 C30 123.9(7) . . ?
N5 C29 H29 118.0 . . ?
C30 C29 H29 118.0 . . ?
C29 C30 C31 118.7(7) . . ?
C29 C30 H30 120.7 . . ?
C31 C30 H30 120.7 . . ?
C32 C31 C30 118.7(6) . . ?
C32 C31 C34 121.3(7) . . ?
C30 C31 C34 120.0(7) . . ?
C33 C32 C31 119.4(7) . . ?
C33 C32 H32 120.3 . . ?
C31 C32 H32 120.3 . . ?
N5 C33 C32 123.1(8) . . ?
N5 C33 H33 118.4 . . ?
C32 C33 H33 118.4 . . ?
N6 C34 C35 106.2(6) . . ?
N6 C34 C31 123.6(7) . . ?
C35 C34 C31 130.3(7) . . ?
C34 C35 C36 109.0(7) . . ?
C34 C35 C39 141.3(7) . . ?
C36 C35 C39 109.6(7) . . ?
C37 C36 C35 108.1(8) . . ?
C37 C36 C38 141.6(7) . . ?
C35 C36 C38 110.2(7) . . ?
N7 C37 C36 107.9(7) . . ?
N7 C37 C42 121.4(9) . . ?
C36 C37 C42 130.7(8) . . ?
O11 C38 C36 136.9(8) . . ?
O11 C38 N6 121.1(8) . . ?
C36 C38 N6 101.9(6) . . ?
O12 C39 N7 124.5(9) . . ?
O12 C39 C35 134.1(7) . . ?
N7 C39 C35 101.4(7) . . ?
N8 C40 C41 120.5(11) . . ?
N8 C40 H40 119.7 . . ?
C41 C40 H40 119.7 . . ?
C42 C41 C40 121.5(10) . . ?
C42 C41 H41 119.3 . . ?
C40 C41 H41 119.3 . . ?
C43 C42 C41 116.0(8) . . ?
C43 C42 C37 121.4(10) . . ?
C41 C42 C37 122.5(10) . . ?
C42 C43 C44 120.6(11) . . ?
C42 C43 H43 119.7 . . ?
C44 C43 H43 119.7 . . ?
N8 C44 C43 123.6(10) . . ?
N8 C44 H44 118.2 . . ?
C43 C44 H44 118.2 . . ?
C46 C45 C49 107.9(7) . . ?
C46 C45 C50 126.1(7) . . ?
C49 C45 C50 126.0(7) . . ?
C46 C45 Rh1 70.7(4) . . ?
C49 C45 Rh1 70.5(4) . . ?
C50 C45 Rh1 123.7(6) . . ?
C47 C46 C45 108.3(7) . . ?
C47 C46 C51 125.6(8) . . ?
C45 C46 C51 126.1(8) . . ?
C47 C46 Rh1 70.3(4) . . ?
C45 C46 Rh1 70.1(4) . . ?
C51 C46 Rh1 123.5(6) . . ?
C46 C47 C48 108.6(7) . . ?
C46 C47 C52 124.4(8) . . ?
C48 C47 C52 126.9(9) . . ?
C46 C47 Rh1 70.6(5) . . ?
C48 C47 Rh1 70.8(5) . . ?
C52 C47 Rh1 126.1(5) . . ?
C47 C48 C49 106.8(7) . . ?
C47 C48 C53 125.8(9) . . ?
C49 C48 C53 127.3(9) . . ?
C47 C48 Rh1 69.8(5) . . ?
C49 C48 Rh1 69.8(5) . . ?
C53 C48 Rh1 128.1(6) . . ?
C45 C49 C48 108.4(7) . . ?
C45 C49 C54 126.2(8) . . ?
C48 C49 C54 125.3(8) . . ?
C45 C49 Rh1 70.1(4) . . ?
C48 C49 Rh1 70.7(4) . . ?
C54 C49 Rh1 127.2(6) . . ?
C45 C50 H50A 109.5 . . ?
C45 C50 H50B 109.5 . . ?
H50A C50 H50B 109.5 . . ?
C45 C50 H50C 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
C46 C51 H51A 109.5 . . ?
C46 C51 H51B 109.5 . . ?
H51A C51 H51B 109.5 . . ?
C46 C51 H51C 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
C47 C52 H52A 109.5 . . ?
C47 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C47 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C48 C53 H53A 109.5 . . ?
C48 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C48 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C49 C54 H54A 109.5 . . ?
C49 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
C49 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C59 C55 C56 107.6(15) . . ?
C59 C55 C60 126.9(11) . . ?
C56 C55 C60 125.2(17) . . ?
C59 C55 Rh2 70.9(7) . . ?
C56 C55 Rh2 70.4(6) . . ?
C60 C55 Rh2 128.6(11) . . ?
C57 C56 C61 127.4(16) . . ?
C57 C56 C55 107.5(17) . . ?
C61 C56 C55 125(2) . . ?
C57 C56 Rh2 70.1(8) . . ?
C61 C56 Rh2 129.4(14) . . ?
C55 C56 Rh2 69.7(6) . . ?
C56 C57 C58 112.1(14) . . ?
C56 C57 C62 125(2) . . ?
C58 C57 C62 123(2) . . ?
C56 C57 Rh2 72.3(9) . . ?
C58 C57 Rh2 70.1(8) . . ?
C62 C57 Rh2 125.4(10) . . ?
C59 C58 C57 103.1(15) . . ?
C59 C58 C63 126.1(15) . . ?
C57 C58 C63 130.7(15) . . ?
C59 C58 Rh2 70.6(7) . . ?
C57 C58 Rh2 69.0(9) . . ?
C63 C58 Rh2 126.7(11) . . ?
C55 C59 C58 109.5(13) . . ?
C55 C59 C64 123.6(12) . . ?
C58 C59 C64 126.7(16) . . ?
C55 C59 Rh2 69.9(7) . . ?
C58 C59 Rh2 69.3(7) . . ?
C64 C59 Rh2 123.2(7) . . ?
C55 C60 H60A 109.5 . . ?
C55 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C55 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
C56 C61 H61A 109.5 . . ?
C56 C61 H61B 109.5 . . ?
H61A C61 H61B 109.5 . . ?
C56 C61 H61C 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C57 C62 H62A 109.5 . . ?
C57 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
C57 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
C58 C63 H63A 109.5 . . ?
C58 C63 H63B 109.5 . . ?
H63A C63 H63B 109.5 . . ?
C58 C63 H63C 109.5 . . ?
H63A C63 H63C 109.5 . . ?
H63B C63 H63C 109.5 . . ?
C59 C64 H64A 109.5 . . ?
C59 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C59 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
C69 C65 C70 127.7(10) . . ?
C69 C65 C66 106.7(10) . . ?
C70 C65 C66 125.4(9) . . ?
C69 C65 Rh3 70.8(6) . . ?
C70 C65 Rh3 127.3(7) . . ?
C66 C65 Rh3 70.6(6) . . ?
C67 C66 C65 109.5(11) . . ?
C67 C66 C71 125.1(11) . . ?
C65 C66 C71 125.4(10) . . ?
C67 C66 Rh3 71.0(6) . . ?
C65 C66 Rh3 69.8(5) . . ?
C71 C66 Rh3 124.6(8) . . ?
C66 C67 C68 107.7(11) . . ?
C66 C67 C72 125.4(14) . . ?
C68 C67 C72 126.9(13) . . ?
C66 C67 Rh3 71.3(5) . . ?
C68 C67 Rh3 68.2(6) . . ?
C72 C67 Rh3 125.3(10) . . ?
C73 C68 C67 124.8(16) . . ?
C73 C68 C69 127.4(17) . . ?
C67 C68 C69 107.3(10) . . ?
C73 C68 Rh3 127.2(10) . . ?
C67 C68 Rh3 72.5(6) . . ?
C69 C68 Rh3 71.5(5) . . ?
C65 C69 C68 108.6(11) . . ?
C65 C69 C74 123.1(11) . . ?
C68 C69 C74 128.0(12) . . ?
C65 C69 Rh3 71.2(6) . . ?
C68 C69 Rh3 68.2(6) . . ?
C74 C69 Rh3 121.4(8) . . ?
C65 C70 H70A 109.5 . . ?
C65 C70 H70B 109.5 . . ?
H70A C70 H70B 109.5 . . ?
C65 C70 H70C 109.5 . . ?
H70A C70 H70C 109.5 . . ?
H70B C70 H70C 109.5 . . ?
C66 C71 H71A 109.5 . . ?
C66 C71 H71B 109.5 . . ?
H71A C71 H71B 109.5 . . ?
C66 C71 H71C 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
C67 C72 H72A 109.5 . . ?
C67 C72 H72B 109.5 . . ?
H72A C72 H72B 109.5 . . ?
C67 C72 H72C 109.5 . . ?
H72A C72 H72C 109.5 . . ?
H72B C72 H72C 109.5 . . ?
C68 C73 H73A 109.5 . . ?
C68 C73 H73B 109.5 . . ?
H73A C73 H73B 109.5 . . ?
C68 C73 H73C 109.5 . . ?
H73A C73 H73C 109.5 . . ?
H73B C73 H73C 109.5 . . ?
C69 C74 H74A 109.5 . . ?
C69 C74 H74B 109.5 . . ?
H74A C74 H74B 109.5 . . ?
C69 C74 H74C 109.5 . . ?
H74A C74 H74C 109.5 . . ?
H74B C74 H74C 109.5 . . ?
O13 C85 C90 122.0(7) . . ?
O13 C85 C86 116.5(6) . . ?
C90 C85 C86 121.4(6) . . ?
O14 C86 C87 123.1(7) . . ?
O14 C86 C85 116.6(6) . . ?
C87 C86 C85 120.3(6) . . ?
C86 C87 C88 119.0(6) . . ?
C86 C87 H87 120.5 . . ?
C88 C87 H87 120.5 . . ?
O15 C88 C87 124.0(6) . . ?
O15 C88 C89 115.9(5) . . ?
C87 C88 C89 120.1(6) . . ?
O16 C89 C90 123.4(6) . . ?
O16 C89 C88 115.6(5) . . ?
C90 C89 C88 121.0(6) . . ?
C89 C90 C85 118.1(6) . . ?
C89 C90 H90 120.9 . . ?
C85 C90 H90 120.9 . . ?
O17 C91 C96 124.3(8) . . ?
O17 C91 C92 115.1(7) . . ?
C96 C91 C92 120.6(7) . . ?
O18 C92 C93 122.1(7) . . ?
O18 C92 C91 116.7(7) . . ?
C93 C92 C91 121.1(7) . . ?
C94 C93 C92 118.2(7) . . ?
C94 C93 H93 120.9 . . ?
C92 C93 H93 120.9 . . ?
O19 C94 C93 122.8(7) . . ?
O19 C94 C95 115.7(7) . . ?
C93 C94 C95 121.4(7) . . ?
O20 C95 C96 124.6(8) . . ?
O20 C95 C94 115.9(7) . . ?
C96 C95 C94 119.4(7) . . ?
C95 C96 C91 119.2(8) . . ?
C95 C96 H96 120.4 . . ?
C91 C96 H96 120.4 . . ?
N9 C97 C98 122.5(9) . . ?
N9 C97 H97 118.8 . . ?
C98 C97 H97 118.8 . . ?
C99 C98 C97 120.0(9) . . ?
C99 C98 H98 120.0 . . ?
C97 C98 H98 120.0 . . ?
C98 C99 C100 117.5(8) . . ?
C98 C99 C202 123.0(8) . . ?
C100 C99 C202 119.4(8) . . ?
C98 C99 C102 123.0(8) . . ?
C100 C99 C102 119.4(8) . . ?
C101 C100 C99 121.0(9) . . ?
C101 C100 H100 119.5 . . ?
C99 C100 H100 119.5 . . ?
C100 C101 N9 120.3(8) . . ?
C100 C101 H101 119.8 . . ?
N9 C101 H101 119.8 . . ?
N12 C108 C109 125.1(9) . . ?
N12 C108 H108 117.5 . . ?
C109 C108 H108 117.5 . . ?
C108 C109 C110 120.0(9) . . ?
C108 C109 H109 120.0 . . ?
C110 C109 H109 120.0 . . ?
C111 C110 C109 115.7(8) . . ?
C111 C110 C105 121.0(8) . . ?
C109 C110 C105 123.3(8) . . ?
C111 C110 C205 121.0(8) . . ?
C109 C110 C205 123.3(8) . . ?
C110 C111 C112 120.9(9) . . ?
C110 C111 H111 119.6 . . ?
C112 C111 H111 119.6 . . ?
N12 C112 C111 121.5(9) . . ?
N12 C112 H112 119.3 . . ?
C111 C112 H112 119.3 . . ?
N13 C113 C114 121.3(7) . . ?
N13 C113 H113 119.3 . . ?
C114 C113 H113 119.3 . . ?
C113 C114 C115 120.6(6) . . ?
C113 C114 H114 119.7 . . ?
C115 C114 H114 119.7 . . ?
C114 C115 C116 117.8(6) . . ?
C114 C115 C118 121.5(6) . . ?
C116 C115 C118 120.8(7) . . ?
C115 C116 C117 118.8(7) . . ?
C115 C116 H116 120.6 . . ?
C117 C116 H116 120.6 . . ?
N13 C117 C116 123.0(6) . . ?
N13 C117 H117 118.5 . . ?
C116 C117 H117 118.5 . . ?
N14 C118 C119 108.9(6) . . ?
N14 C118 C115 122.1(8) . . ?
C119 C118 C115 128.9(7) . . ?
C118 C119 C120 108.7(7) . . ?
C118 C119 C123 142.3(6) . . ?
C120 C119 C123 109.0(7) . . ?
C121 C120 C119 109.8(7) . . ?
C121 C120 C122 141.2(7) . . ?
C119 C120 C122 108.8(7) . . ?
C120 C121 N15 107.6(6) . . ?
C120 C121 C126 131.9(8) . . ?
N15 C121 C126 120.5(8) . . ?
O23 C122 N14 121.8(7) . . ?
O23 C122 C120 136.2(7) . . ?
N14 C122 C120 102.0(5) . . ?
O24 C123 N15 124.7(8) . . ?
O24 C123 C119 133.3(7) . . ?
N15 C123 C119 102.0(6) . . ?
N16 C124 C125 123.0(9) . . ?
N16 C124 H124 118.5 . . ?
C125 C124 H124 118.5 . . ?
C124 C125 C126 116.8(8) . . ?
C124 C125 H125 121.6 . . ?
C126 C125 H125 121.6 . . ?
C127 C126 C125 118.4(7) . . ?
C127 C126 C121 120.0(9) . . ?
C125 C126 C121 121.5(8) . . ?
C128 C127 C126 122.8(10) . . ?
C128 C127 H127 118.6 . . ?
C126 C127 H127 118.6 . . ?
C127 C128 N16 119.2(9) . . ?
C127 C128 H128 120.4 . . ?
N16 C128 H128 120.4 . . ?
C133 C129 C134 125.9(13) . . ?
C133 C129 C130 106.8(13) . . ?
C134 C129 C130 127.3(11) . . ?
C133 C129 Rh5 69.8(7) . . ?
C134 C129 Rh5 124.6(9) . . ?
C130 C129 Rh5 70.3(5) . . ?
C131 C130 C129 108.3(9) . . ?
C131 C130 C135 128.4(11) . . ?
C129 C130 C135 123.2(10) . . ?
C131 C130 Rh5 69.3(5) . . ?
C129 C130 Rh5 70.1(5) . . ?
C135 C130 Rh5 123.5(7) . . ?
C130 C131 C132 107.3(12) . . ?
C130 C131 C136 123.8(11) . . ?
C132 C131 C136 128.8(12) . . ?
C130 C131 Rh5 73.0(5) . . ?
C132 C131 Rh5 68.6(6) . . ?
C136 C131 Rh5 121.7(8) . . ?
C133 C132 C131 108.8(12) . . ?
C133 C132 C137 128.6(16) . . ?
C131 C132 C137 122.4(17) . . ?
C133 C132 Rh5 72.8(8) . . ?
C131 C132 Rh5 71.3(6) . . ?
C137 C132 Rh5 125.7(10) . . ?
C132 C133 C129 108.8(13) . . ?
C132 C133 C138 125.2(17) . . ?
C129 C133 C138 125.9(19) . . ?
C132 C133 Rh5 68.8(8) . . ?
C129 C133 Rh5 72.1(7) . . ?
C138 C133 Rh5 124.7(9) . . ?
C129 C134 H13A 109.5 . . ?
C129 C134 H13B 109.5 . . ?
H13A C134 H13B 109.5 . . ?
C129 C134 H13C 109.5 . . ?
H13A C134 H13C 109.5 . . ?
H13B C134 H13C 109.5 . . ?
C130 C135 H13D 109.5 . . ?
C130 C135 H13E 109.5 . . ?
H13D C135 H13E 109.5 . . ?
C130 C135 H13F 109.5 . . ?
H13D C135 H13F 109.5 . . ?
H13E C135 H13F 109.5 . . ?
C131 C136 H13G 109.5 . . ?
C131 C136 H13H 109.5 . . ?
H13G C136 H13H 109.5 . . ?
C131 C136 H13I 109.5 . . ?
H13G C136 H13I 109.5 . . ?
H13H C136 H13I 109.5 . . ?
C132 C137 H13J 109.5 . . ?
C132 C137 H13K 109.5 . . ?
H13J C137 H13K 109.5 . . ?
C132 C137 H13L 109.5 . . ?
H13J C137 H13L 109.5 . . ?
H13K C137 H13L 109.5 . . ?
C133 C138 H13M 109.5 . . ?
C133 C138 H13N 109.5 . . ?
H13M C138 H13N 109.5 . . ?
C133 C138 H13O 109.5 . . ?
H13M C138 H13O 109.5 . . ?
H13N C138 H13O 109.5 . . ?
C143 C139 C140 106.4(7) . . ?
C143 C139 C144 128.5(12) . . ?
C140 C139 C144 125.0(12) . . ?
C143 C139 Rh6 71.4(4) . . ?
C140 C139 Rh6 71.7(4) . . ?
C144 C139 Rh6 125.2(7) . . ?
C141 C140 C139 108.5(7) . . ?
C141 C140 C145 125.7(9) . . ?
C139 C140 C145 125.5(9) . . ?
C141 C140 Rh6 70.4(4) . . ?
C139 C140 Rh6 68.9(4) . . ?
C145 C140 Rh6 122.3(6) . . ?
C140 C141 C142 110.6(7) . . ?
C140 C141 C146 123.9(9) . . ?
C142 C141 C146 125.5(9) . . ?
C140 C141 Rh6 72.7(4) . . ?
C142 C141 Rh6 70.7(4) . . ?
C146 C141 Rh6 124.5(6) . . ?
C141 C142 C143 106.6(7) . . ?
C141 C142 C147 126.4(10) . . ?
C143 C142 C147 126.9(11) . . ?
C141 C142 Rh6 70.4(4) . . ?
C143 C142 Rh6 71.0(4) . . ?
C147 C142 Rh6 125.5(7) . . ?
C142 C143 C139 107.7(7) . . ?
C142 C143 C148 129.0(12) . . ?
C139 C143 C148 123.3(12) . . ?
C142 C143 Rh6 69.9(4) . . ?
C139 C143 Rh6 69.4(4) . . ?
C148 C143 Rh6 124.0(7) . . ?
C139 C144 H144 109.5 . . ?
C139 C144 H14B 109.5 . . ?
H144 C144 H14B 109.5 . . ?
C139 C144 H14C 109.5 . . ?
H144 C144 H14C 109.5 . . ?
H14B C144 H14C 109.5 . . ?
C140 C145 H14D 109.5 . . ?
C140 C145 H14E 109.5 . . ?
H14D C145 H14E 109.5 . . ?
C140 C145 H14F 109.5 . . ?
H14D C145 H14F 109.5 . . ?
H14E C145 H14F 109.5 . . ?
C141 C146 H14G 109.5 . . ?
C141 C146 H14H 109.5 . . ?
H14G C146 H14H 109.5 . . ?
C141 C146 H14I 109.5 . . ?
H14G C146 H14I 109.5 . . ?
H14H C146 H14I 109.5 . . ?
C142 C147 H14J 109.5 . . ?
C142 C147 H14K 109.5 . . ?
H14J C147 H14K 109.5 . . ?
C142 C147 H14L 109.5 . . ?
H14J C147 H14L 109.5 . . ?
H14K C147 H14L 109.5 . . ?
C143 C148 H14M 109.5 . . ?
C143 C148 H14N 109.5 . . ?
H14M C148 H14N 109.5 . . ?
C143 C148 H14O 109.5 . . ?
H14M C148 H14O 109.5 . . ?
H14N C148 H14O 109.5 . . ?
C153 C149 C150 107.7(13) . . ?
C153 C149 C154 133.1(19) . . ?
C150 C149 C154 118.8(19) . . ?
C153 C149 Rh7 69.3(6) . . ?
C150 C149 Rh7 70.9(6) . . ?
C154 C149 Rh7 119.4(10) . . ?
C151 C150 C149 105.0(12) . . ?
C151 C150 C155 123.4(13) . . ?
C149 C150 C155 131.6(15) . . ?
C151 C150 Rh7 72.3(6) . . ?
C149 C150 Rh7 70.1(6) . . ?
C155 C150 Rh7 123.1(9) . . ?
C152 C151 C150 112.1(14) . . ?
C152 C151 C156 121.5(15) . . ?
C150 C151 C156 125.8(14) . . ?
C152 C151 Rh7 70.8(8) . . ?
C150 C151 Rh7 69.2(6) . . ?
C156 C151 Rh7 121.2(8) . . ?
C151 C152 C153 107.2(16) . . ?
C151 C152 C157 132.7(18) . . ?
C153 C152 C157 119.9(19) . . ?
C151 C152 Rh7 73.5(8) . . ?
C153 C152 Rh7 68.4(8) . . ?
C157 C152 Rh7 125.4(10) . . ?
C149 C153 C152 107.6(12) . . ?
C149 C153 C158 125(2) . . ?
C152 C153 C158 127(2) . . ?
C149 C153 Rh7 71.7(7) . . ?
C152 C153 Rh7 72.0(7) . . ?
C158 C153 Rh7 124.3(10) . . ?
C149 C154 H15A 109.5 . . ?
C149 C154 H15B 109.5 . . ?
H15A C154 H15B 109.5 . . ?
C149 C154 H15C 109.5 . . ?
H15A C154 H15C 109.5 . . ?
H15B C154 H15C 109.5 . . ?
C150 C155 H15D 109.5 . . ?
C150 C155 H15E 109.5 . . ?
H15D C155 H15E 109.5 . . ?
C150 C155 H15F 109.5 . . ?
H15D C155 H15F 109.5 . . ?
H15E C155 H15F 109.5 . . ?
C151 C156 H15G 109.5 . . ?
C151 C156 H15H 109.5 . . ?
H15G C156 H15H 109.5 . . ?
C151 C156 H15I 109.5 . . ?
H15G C156 H15I 109.5 . . ?
H15H C156 H15I 109.5 . . ?
C152 C157 H15J 109.5 . . ?
C152 C157 H15K 109.5 . . ?
H15J C157 H15K 109.5 . . ?
C152 C157 H15L 109.5 . . ?
H15J C157 H15L 109.5 . . ?
H15K C157 H15L 109.5 . . ?
C153 C158 H15M 109.5 . . ?
C153 C158 H15N 109.5 . . ?
H15M C158 H15N 109.5 . . ?
C153 C158 H15O 109.5 . . ?
H15M C158 H15O 109.5 . . ?
H15N C158 H15O 109.5 . . ?
C160 C159 C163 111.8(12) . . ?
C160 C159 C164 126.0(17) . . ?
C163 C159 C164 122.1(17) . . ?
C160 C159 Rh8 72.4(6) . . ?
C163 C159 Rh8 71.5(7) . . ?
C164 C159 Rh8 120.8(12) . . ?
C159 C160 C161 109.0(12) . . ?
C159 C160 C165 126.9(13) . . ?
C161 C160 C165 124.0(14) . . ?
C159 C160 Rh8 70.5(7) . . ?
C161 C160 Rh8 70.5(6) . . ?
C165 C160 Rh8 123.3(10) . . ?
C160 C161 C162 109.1(10) . . ?
C160 C161 C166 126.3(11) . . ?
C162 C161 C166 124.5(10) . . ?
C160 C161 Rh8 71.3(6) . . ?
C162 C161 Rh8 70.8(6) . . ?
C166 C161 Rh8 126.3(7) . . ?
C167 C162 C161 129.4(11) . . ?
C167 C162 C163 126.3(13) . . ?
C161 C162 C163 104.2(11) . . ?
C167 C162 Rh8 127.3(8) . . ?
C161 C162 Rh8 69.4(6) . . ?
C163 C162 Rh8 69.2(6) . . ?
C159 C163 C168 131.4(15) . . ?
C159 C163 C162 105.9(12) . . ?
C168 C163 C162 122.6(16) . . ?
C159 C163 Rh8 69.9(7) . . ?
C168 C163 Rh8 121.6(9) . . ?
C162 C163 Rh8 70.0(6) . . ?
C159 C164 H16A 109.5 . . ?
C159 C164 H16B 109.5 . . ?
H16A C164 H16B 109.5 . . ?
C159 C164 H16C 109.5 . . ?
H16A C164 H16C 109.5 . . ?
H16B C164 H16C 109.5 . . ?
C160 C165 H16D 109.5 . . ?
C160 C165 H16E 109.5 . . ?
H16D C165 H16E 109.5 . . ?
C160 C165 H16F 109.5 . . ?
H16D C165 H16F 109.5 . . ?
H16E C165 H16F 109.5 . . ?
C161 C166 H16G 109.5 . . ?
C161 C166 H16H 109.5 . . ?
H16G C166 H16H 109.5 . . ?
C161 C166 H16I 109.5 . . ?
H16G C166 H16I 109.5 . . ?
H16H C166 H16I 109.5 . . ?
C162 C167 H16J 109.5 . . ?
C162 C167 H16K 109.5 . . ?
H16J C167 H16K 109.5 . . ?
C162 C167 H16L 109.5 . . ?
H16J C167 H16L 109.5 . . ?
H16K C167 H16L 109.5 . . ?
C163 C168 H16M 109.5 . . ?
C163 C168 H16N 109.5 . . ?
H16M C168 H16N 109.5 . . ?
C163 C168 H16O 109.5 . . ?
H16M C168 H16O 109.5 . . ?
H16N C168 H16O 109.5 . . ?
F2 C169 F3 106.4(18) . . ?
F2 C169 F1 106(2) . . ?
F3 C169 F1 106(2) . . ?
F2 C169 S1 112.7(19) . . ?
F3 C169 S1 115.3(16) . . ?
F1 C169 S1 109.7(12) . . ?
F4 C170 F6 98.1(16) . . ?
F4 C170 F5 100.9(16) . . ?
F6 C170 F5 112.4(17) . . ?
F4 C170 S2 111.7(13) . . ?
F6 C170 S2 118.2(15) . . ?
F5 C170 S2 113.0(13) . . ?
F7 C171 F8 108.5(13) . . ?
F7 C171 F9 108.7(14) . . ?
F8 C171 F9 114.6(17) . . ?
F7 C171 S3 113.9(12) . . ?
F8 C171 S3 103.5(11) . . ?
F9 C171 S3 107.7(11) . . ?
F11 C172 F12 104.8(15) . . ?
F11 C172 F10 106(2) . . ?
F12 C172 F10 102.4(18) . . ?
F11 C172 S4 118.4(17) . . ?
F12 C172 S4 112.9(17) . . ?
F10 C172 S4 111.2(13) . . ?
F14 C173 F13 110.2(19) . . ?
F14 C173 F15 112(2) . . ?
F13 C173 F15 114(2) . . ?
F14 C173 S5 114.7(14) . . ?
F13 C173 S5 104.7(17) . . ?
F15 C173 S5 101.1(16) . . ?
F17 C174 F16 104.5(13) . . ?
F17 C174 F18 106.1(16) . . ?
F16 C174 F18 100.4(13) . . ?
F17 C174 S6 119.2(11) . . ?
F16 C174 S6 120.6(10) . . ?
F18 C174 S6 103.5(13) . . ?
N17 C177 O49 126.2(15) . . ?
N17 C177 H177 116.9 . . ?
O49 C177 H177 116.9 . . ?
N17 C178 H17A 109.5 . . ?
N17 C178 H17B 109.5 . . ?
H17A C178 H17B 109.5 . . ?
N17 C178 H17C 109.5 . . ?
H17A C178 H17C 109.5 . . ?
H17B C178 H17C 109.5 . . ?
N17 C179 H17D 109.5 . . ?
N17 C179 H17E 109.5 . . ?
H17D C179 H17E 109.5 . . ?
N17 C179 H17F 109.5 . . ?
H17D C179 H17F 109.5 . . ?
H17E C179 H17F 109.5 . . ?
C177 N17 C178 120.4(13) . . ?
C177 N17 C179 118.7(13) . . ?
C178 N17 C179 120.6(12) . . ?
O50 C180 N18 122.5(12) . . ?
O50 C180 H180 118.8 . . ?
N18 C180 H180 118.8 . . ?
N18 C181 H18A 109.5 . . ?
N18 C181 H18B 109.5 . . ?
H18A C181 H18B 109.5 . . ?
N18 C181 H18C 109.5 . . ?
H18A C181 H18C 109.5 . . ?
H18B C181 H18C 109.5 . . ?
N18 C182 H18D 109.5 . . ?
N18 C182 H18E 109.5 . . ?
H18D C182 H18E 109.5 . . ?
N18 C182 H18F 109.5 . . ?
H18D C182 H18F 109.5 . . ?
H18E C182 H18F 109.5 . . ?
C180 N18 C181 122.8(11) . . ?
C180 N18 C182 124.9(11) . . ?
C181 N18 C182 112.2(10) . . ?
O51 C183 N19 123.7(11) . . ?
O51 C183 H183 118.2 . . ?
N19 C183 H183 118.2 . . ?
N19 C184 H18G 109.5 . . ?
N19 C184 H18H 109.5 . . ?
H18G C184 H18H 109.5 . . ?
N19 C184 H18I 109.5 . . ?
H18G C184 H18I 109.5 . . ?
H18H C184 H18I 109.5 . . ?
N19 C185 H18J 109.5 . . ?
N19 C185 H18K 109.5 . . ?
H18J C185 H18K 109.5 . . ?
N19 C185 H18L 109.5 . . ?
H18J C185 H18L 109.5 . . ?
H18K C185 H18L 109.5 . . ?
C183 N19 C184 121.5(10) . . ?
C183 N19 C185 120.6(11) . . ?
C184 N19 C185 117.7(9) . . ?
N20 C186 C187 174(2) . . ?
C186 C187 H18M 109.5 . . ?
C186 C187 H18N 109.5 . . ?
H18M C187 H18N 109.5 . . ?
C186 C187 H18O 109.5 . . ?
H18M C187 H18O 109.5 . . ?
H18N C187 H18O 109.5 . . ?
N21 C188 C189 169.2(19) . . ?
C188 C189 H18P 109.5 . . ?
C188 C189 H18Q 109.5 . . ?
H18P C189 H18Q 109.5 . . ?
C188 C189 H18R 109.5 . . ?
H18P C189 H18R 109.5 . . ?
H18Q C189 H18R 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C22 N2 C18 C19 4.2(8) . . . . ?
C22 N2 C18 C15 -174.1(5) . . . . ?
N2 C18 C19 C20 -2.5(8) . . . . ?
C15 C18 C19 C20 175.6(7) . . . . ?
N2 C18 C19 C23 178.7(7) . . . . ?
C15 C18 C19 C23 -3.2(13) . . . . ?
C18 C19 C20 C21 -178.9(6) . . . . ?
C23 C19 C20 C21 0.2(8) . . . . ?
C18 C19 C20 C22 0.1(8) . . . . ?
C23 C19 C20 C22 179.3(5) . . . . ?
C19 C20 C21 N3 1.6(8) . . . . ?
C22 C20 C21 N3 -177.2(7) . . . . ?
C19 C20 C21 C26 177.4(7) . . . . ?
C22 C20 C21 C26 -1.4(14) . . . . ?
C23 N3 C21 C20 -2.9(9) . . . . ?
C23 N3 C21 C26 -179.1(6) . . . . ?
C18 N2 C22 O9 -178.1(9) . . . . ?
C18 N2 C22 C20 -3.6(6) . . . . ?
C21 C20 C22 O9 -7.1(17) . . . . ?
C19 C20 C22 O9 174.1(12) . . . . ?
C21 C20 C22 N2 -179.4(8) . . . . ?
C19 C20 C22 N2 1.9(6) . . . . ?
C21 N3 C23 O10 178.4(9) . . . . ?
C21 N3 C23 C19 2.7(7) . . . . ?
C18 C19 C23 O10 2.8(17) . . . . ?
C20 C19 C23 O10 -175.9(11) . . . . ?
C18 C19 C23 N3 177.1(8) . . . . ?
C20 C19 C23 N3 -1.6(7) . . . . ?
C22' C18' C19' C20' -2.5(8) . . . . ?
C15 C18' C19' C20' 175.6(7) . . . . ?
C22' C18' C19' S2' 178.7(7) . . . . ?
C15 C18' C19' S2' -3.2(13) . . . . ?
C23' S2' C19' C18' 177.1(8) . . . . ?
C23' S2' C19' C20' -1.6(7) . . . . ?
C18' C19' C20' C21' -178.9(6) . . . . ?
S2' C19' C20' C21' 0.2(8) . . . . ?
C18' C19' C20' S1' 0.1(8) . . . . ?
S2' C19' C20' S1' 179.3(5) . . . . ?
C22' S1' C20' C21' -179.4(8) . . . . ?
C22' S1' C20' C19' 1.9(6) . . . . ?
C19' C20' C21' C23' 1.6(8) . . . . ?
S1' C20' C21' C23' -177.2(7) . . . . ?
C19' C20' C21' C26 177.4(7) . . . . ?
S1' C20' C21' C26 -1.4(14) . . . . ?
C19' C18' C22' S1' 4.2(8) . . . . ?
C15 C18' C22' S1' -174.1(5) . . . . ?
C20' S1' C22' C18' -3.6(6) . . . . ?
C20' C21' C23' S2' -2.9(9) . . . . ?
C26 C21' C23' S2' -179.1(6) . . . . ?
C19' S2' C23' C21' 2.7(7) . . . . ?
C106 N10 C102 C103 -0.6(9) . . . . ?
C106 N10 C102 C99 -177.8(6) . . . . ?
N10 C102 C103 C104 1.9(9) . . . . ?
C99 C102 C103 C104 178.8(8) . . . . ?
N10 C102 C103 C107 172.4(7) . . . . ?
C99 C102 C103 C107 -10.7(15) . . . . ?
C102 C103 C104 C105 179.1(7) . . . . ?
C107 C103 C104 C105 6.4(9) . . . . ?
C102 C103 C104 C106 -2.6(9) . . . . ?
C107 C103 C104 C106 -175.3(5) . . . . ?
C103 C104 C105 N11 -0.8(10) . . . . ?
C106 C104 C105 N11 -178.5(7) . . . . ?
C103 C104 C105 C110 179.7(8) . . . . ?
C106 C104 C105 C110 1.9(15) . . . . ?
C107 N11 C105 C104 -5.1(10) . . . . ?
C107 N11 C105 C110 174.5(7) . . . . ?
C102 N10 C106 O21 -178.0(12) . . . . ?
C102 N10 C106 C104 -0.7(7) . . . . ?
C105 C104 C106 O21 -3.7(19) . . . . ?
C103 C104 C106 O21 178.6(15) . . . . ?
C105 C104 C106 N10 179.6(8) . . . . ?
C103 C104 C106 N10 1.9(6) . . . . ?
C104 C103 C107 O22 -155.4(12) . . . . ?
C102 C103 C107 O22 34.2(17) . . . . ?
C104 C103 C107 N11 -8.2(7) . . . . ?
C102 C103 C107 N11 -178.7(9) . . . . ?
C105 N11 C107 O22 165.2(9) . . . . ?
C105 N11 C107 C103 7.8(8) . . . . ?
C206 C202 C203 C204 1.9(9) . . . . ?
C99 C202 C203 C204 178.8(8) . . . . ?
C206 C202 C203 S4' 172.4(7) . . . . ?
C99 C202 C203 S4' -10.7(15) . . . . ?
C207 S4' C203 C204 -8.2(7) . . . . ?
C207 S4' C203 C202 -178.7(9) . . . . ?
C202 C203 C204 C205 179.1(7) . . . . ?
S4' C203 C204 C205 6.4(9) . . . . ?
C202 C203 C204 S3' -2.6(9) . . . . ?
S4' C203 C204 S3' -175.3(5) . . . . ?
C206 S3' C204 C205 179.6(8) . . . . ?
C206 S3' C204 C203 1.9(6) . . . . ?
C203 C204 C205 C207 -0.8(10) . . . . ?
S3' C204 C205 C207 -178.5(7) . . . . ?
C203 C204 C205 C110 179.7(8) . . . . ?
S3' C204 C205 C110 1.9(15) . . . . ?
C203 C202 C206 S3' -0.6(9) . . . . ?
C99 C202 C206 S3' -177.8(6) . . . . ?
C204 S3' C206 C202 -0.7(7) . . . . ?
C204 C205 C207 S4' -5.1(10) . . . . ?
C110 C205 C207 S4' 174.5(7) . . . . ?
C203 S4' C207 C205 7.8(8) . . . . ?
C79 C75 C76 C81 174.1(17) . . . . ?
C80 C75 C76 C81 -3(3) . . . . ?
Rh4 C75 C76 C81 -123.3(18) . . . . ?
C79 C75 C76 C77 -2.0(18) . . . . ?
C80 C75 C76 C77 -179.1(18) . . . . ?
Rh4 C75 C76 C77 60.7(11) . . . . ?
C79 C75 C76 Rh4 -62.7(12) . . . . ?
C80 C75 C76 Rh4 120(2) . . . . ?
C81 C76 C77 C78 -173.3(18) . . . . ?
C75 C76 C77 C78 2.5(17) . . . . ?
Rh4 C76 C77 C78 60.7(11) . . . . ?
C81 C76 C77 C82 5(3) . . . . ?
C75 C76 C77 C82 -179.7(16) . . . . ?
Rh4 C76 C77 C82 -121.5(16) . . . . ?
C81 C76 C77 Rh4 126.0(19) . . . . ?
C75 C76 C77 Rh4 -58.2(11) . . . . ?
C76 C77 C78 C79 -2.3(19) . . . . ?
C82 C77 C78 C79 -180.0(17) . . . . ?
Rh4 C77 C78 C79 58.0(13) . . . . ?
C76 C77 C78 C83 -179.6(16) . . . . ?
C82 C77 C78 C83 3(3) . . . . ?
Rh4 C77 C78 C83 -119.3(17) . . . . ?
C76 C77 C78 Rh4 -60.3(10) . . . . ?
C82 C77 C78 Rh4 122.0(18) . . . . ?
C77 C78 C79 C75 1.0(19) . . . . ?
C83 C78 C79 C75 178.4(16) . . . . ?
Rh4 C78 C79 C75 60.1(11) . . . . ?
C77 C78 C79 C84 -179.0(17) . . . . ?
C83 C78 C79 C84 -2(3) . . . . ?
Rh4 C78 C79 C84 -120.0(19) . . . . ?
C77 C78 C79 Rh4 -59.0(12) . . . . ?
C83 C78 C79 Rh4 118.4(16) . . . . ?
C76 C75 C79 C78 0.7(19) . . . . ?
C80 C75 C79 C78 178.0(18) . . . . ?
Rh4 C75 C79 C78 -63.6(11) . . . . ?
C76 C75 C79 C84 -179.3(17) . . . . ?
C80 C75 C79 C84 -2(3) . . . . ?
Rh4 C75 C79 C84 116.5(18) . . . . ?
C76 C75 C79 Rh4 64.2(12) . . . . ?
C80 C75 C79 Rh4 -118.4(19) . . . . ?
C79' C75' C76' C77' 0.0 . . . . ?
C80' C75' C76' C77' 180.0 . . . . ?
Rh4 C75' C76' C77' 61.1(5) . . . . ?
C79' C75' C76' C81' 180.0 . . . . ?
C80' C75' C76' C81' 0.0 . . . . ?
Rh4 C75' C76' C81' -118.9(5) . . . . ?
C79' C75' C76' Rh4 -61.1(5) . . . . ?
C80' C75' C76' Rh4 118.9(5) . . . . ?
C75' C76' C77' C78' 0.0 . . . . ?
C81' C76' C77' C78' 180.0 . . . . ?
Rh4 C76' C77' C78' 61.4(5) . . . . ?
C75' C76' C77' C82' 180.0 . . . . ?
C81' C76' C77' C82' 0.0 . . . . ?
Rh4 C76' C77' C82' -118.6(5) . . . . ?
C75' C76' C77' Rh4 -61.4(5) . . . . ?
C81' C76' C77' Rh4 118.6(5) . . . . ?
C76' C77' C78' C79' 0.0 . . . . ?
C82' C77' C78' C79' 180.0 . . . . ?
Rh4 C77' C78' C79' 62.2(5) . . . . ?
C76' C77' C78' C83' 180.0 . . . . ?
C82' C77' C78' C83' 0.0 . . . . ?
Rh4 C77' C78' C83' -117.8(5) . . . . ?
C76' C77' C78' Rh4 -62.2(5) . . . . ?
C82' C77' C78' Rh4 117.8(5) . . . . ?
C76' C75' C79' C78' 0.0 . . . . ?
C80' C75' C79' C78' 180.0 . . . . ?
Rh4 C75' C79' C78' -61.7(5) . . . . ?
C76' C75' C79' C84' 180.0 . . . . ?
C80' C75' C79' C84' 0.0 . . . . ?
Rh4 C75' C79' C84' 118.3(5) . . . . ?
C76' C75' C79' Rh4 61.7(5) . . . . ?
C80' C75' C79' Rh4 -118.3(5) . . . . ?
C77' C78' C79' C75' 0.0 . . . . ?
C83' C78' C79' C75' 180.0 . . . . ?
Rh4 C78' C79' C75' 62.4(5) . . . . ?
C77' C78' C79' C84' 180.0 . . . . ?
C83' C78' C79' C84' 0.0 . . . . ?
Rh4 C78' C79' C84' -117.6(5) . . . . ?
C77' C78' C79' Rh4 -62.4(5) . . . . ?
C83' C78' C79' Rh4 117.6(5) . . . . ?
Rh1 O1 C1 C6 -176.4(5) . . . . ?
Rh1 O1 C1 C2 5.3(7) . . . . ?
Rh1 O2 C2 C3 179.5(5) . . . . ?
Rh1 O2 C2 C1 -1.8(7) . . . . ?
O1 C1 C2 O2 -2.4(8) . . . . ?
C6 C1 C2 O2 179.2(6) . . . . ?
O1 C1 C2 C3 176.4(6) . . . . ?
C6 C1 C2 C3 -2.0(9) . . . . ?
O2 C2 C3 C4 -179.2(7) . . . . ?
C1 C2 C3 C4 2.2(11) . . . . ?
Rh2 O3 C4 C3 179.4(6) . . . . ?
Rh2 O3 C4 C5 -2.2(8) . . . . ?
C2 C3 C4 O3 177.5(7) . . . . ?
C2 C3 C4 C5 -0.9(11) . . . . ?
Rh2 O4 C5 C6 -179.8(5) . . . . ?
Rh2 O4 C5 C4 -1.6(8) . . . . ?
O3 C4 C5 O4 2.6(9) . . . . ?
C3 C4 C5 O4 -178.9(7) . . . . ?
O3 C4 C5 C6 -179.2(6) . . . . ?
C3 C4 C5 C6 -0.8(10) . . . . ?
O1 C1 C6 C5 -177.8(6) . . . . ?
C2 C1 C6 C5 0.5(9) . . . . ?
O4 C5 C6 C1 179.0(6) . . . . ?
C4 C5 C6 C1 0.9(9) . . . . ?
Rh3 O5 C7 C12 -179.2(5) . . . . ?
Rh3 O5 C7 C8 -1.5(7) . . . . ?
Rh3 O6 C8 C9 178.8(5) . . . . ?
Rh3 O6 C8 C7 -1.1(7) . . . . ?
O5 C7 C8 O6 1.7(8) . . . . ?
C12 C7 C8 O6 179.6(5) . . . . ?
O5 C7 C8 C9 -178.1(6) . . . . ?
C12 C7 C8 C9 -0.3(9) . . . . ?
O6 C8 C9 C10 179.8(6) . . . . ?
C7 C8 C9 C10 -0.4(9) . . . . ?
Rh4 O7 C10 C9 -177.1(5) . . . . ?
Rh4 O7 C10 C11 4.5(7) . . . . ?
C8 C9 C10 O7 -178.0(6) . . . . ?
C8 C9 C10 C11 0.4(9) . . . . ?
Rh4 O8 C11 C12 177.4(5) . . . . ?
Rh4 O8 C11 C10 -3.1(7) . . . . ?
O7 C10 C11 O8 -0.9(8) . . . . ?
C9 C10 C11 O8 -179.4(6) . . . . ?
O7 C10 C11 C12 178.6(6) . . . . ?
C9 C10 C11 C12 0.2(9) . . . . ?
O8 C11 C12 C7 178.7(6) . . . . ?
C10 C11 C12 C7 -0.8(9) . . . . ?
O5 C7 C12 C11 178.5(6) . . . . ?
C8 C7 C12 C11 0.8(9) . . . . ?
C17 N1 C13 C14 0.9(11) . . . . ?
Rh3 N1 C13 C14 174.3(6) . . . . ?
N1 C13 C14 C15 -2.7(12) . . . . ?
C13 C14 C15 C16 1.1(11) . . . . ?
C13 C14 C15 C18 -175.7(7) . . . . ?
C13 C14 C15 C18' -175.7(7) . . . . ?
N2 C18 C15 C16 -8.7(11) . . . . ?
C19 C18 C15 C16 173.4(7) . . . . ?
N2 C18 C15 C14 167.8(7) . . . . ?
C19 C18 C15 C14 -10.0(11) . . . . ?
C22' C18' C15 C16 -8.7(11) . . . . ?
C19' C18' C15 C16 173.4(7) . . . . ?
C22' C18' C15 C14 167.8(7) . . . . ?
C19' C18' C15 C14 -10.0(11) . . . . ?
C14 C15 C16 C17 2.1(11) . . . . ?
C18 C15 C16 C17 178.7(7) . . . . ?
C18' C15 C16 C17 178.7(7) . . . . ?
C13 N1 C17 C16 2.6(12) . . . . ?
Rh3 N1 C17 C16 -170.2(6) . . . . ?
C15 C16 C17 N1 -4.1(13) . . . . ?
C28 N4 C24 C25 -0.5(12) . . . . ?
Rh1 N4 C24 C25 173.9(6) . . . . ?
N4 C24 C25 C26 1.0(13) . . . . ?
C24 C25 C26 C27 -0.2(12) . . . . ?
C24 C25 C26 C21 -179.8(7) . . . . ?
C24 C25 C26 C21' -179.8(7) . . . . ?
C20 C21 C26 C27 1.1(13) . . . . ?
N3 C21 C26 C27 176.3(7) . . . . ?
C20 C21 C26 C25 -179.3(8) . . . . ?
N3 C21 C26 C25 -4.0(11) . . . . ?
C20' C21' C26 C27 1.1(13) . . . . ?
C23' C21' C26 C27 176.3(7) . . . . ?
C20' C21' C26 C25 -179.3(8) . . . . ?
C23' C21' C26 C25 -4.0(11) . . . . ?
C25 C26 C27 C28 -1.1(12) . . . . ?
C21 C26 C27 C28 178.5(7) . . . . ?
C21' C26 C27 C28 178.5(7) . . . . ?
C24 N4 C28 C27 -0.9(12) . . . . ?
Rh1 N4 C28 C27 -175.3(6) . . . . ?
C26 C27 C28 N4 1.7(13) . . . . ?
C33 N5 C29 C30 -2.2(12) . . . . ?
Rh4 N5 C29 C30 179.2(6) . . . . ?
N5 C29 C30 C31 1.5(12) . . . . ?
C29 C30 C31 C32 -0.5(11) . . . . ?
C29 C30 C31 C34 177.4(7) . . . . ?
C30 C31 C32 C33 0.4(12) . . . . ?
C34 C31 C32 C33 -177.4(8) . . . . ?
C29 N5 C33 C32 2.1(13) . . . . ?
Rh4 N5 C33 C32 -179.3(7) . . . . ?
C31 C32 C33 N5 -1.3(14) . . . . ?
C38 N6 C34 C35 -3.9(8) . . . . ?
C38 N6 C34 C31 176.2(6) . . . . ?
C32 C31 C34 N6 -3.8(11) . . . . ?
C30 C31 C34 N6 178.3(7) . . . . ?
C32 C31 C34 C35 176.3(8) . . . . ?
C30 C31 C34 C35 -1.5(12) . . . . ?
N6 C34 C35 C36 3.6(8) . . . . ?
C31 C34 C35 C36 -176.5(7) . . . . ?
N6 C34 C35 C39 179.3(9) . . . . ?
C31 C34 C35 C39 -0.9(15) . . . . ?
C34 C35 C36 C37 175.2(6) . . . . ?
C39 C35 C36 C37 -1.9(9) . . . . ?
C34 C35 C36 C38 -2.1(9) . . . . ?
C39 C35 C36 C38 -179.2(6) . . . . ?
C39 N7 C37 C36 -1.4(10) . . . . ?
C39 N7 C37 C42 175.7(7) . . . . ?
C35 C36 C37 N7 2.0(9) . . . . ?
C38 C36 C37 N7 177.9(9) . . . . ?
C35 C36 C37 C42 -174.8(8) . . . . ?
C38 C36 C37 C42 1.1(17) . . . . ?
C37 C36 C38 O11 6.6(18) . . . . ?
C35 C36 C38 O11 -177.5(9) . . . . ?
C37 C36 C38 N6 -176.1(10) . . . . ?
C35 C36 C38 N6 -0.3(8) . . . . ?
C34 N6 C38 O11 -179.6(7) . . . . ?
C34 N6 C38 C36 2.6(7) . . . . ?
C37 N7 C39 O12 -179.6(9) . . . . ?
C37 N7 C39 C35 0.2(9) . . . . ?
C34 C35 C39 O12 5.2(18) . . . . ?
C36 C35 C39 O12 -179.2(10) . . . . ?
C34 C35 C39 N7 -174.6(9) . . . . ?
C36 C35 C39 N7 1.0(8) . . . . ?
C44 N8 C40 C41 3.0(14) . . . . ?
Rh2 N8 C40 C41 177.0(7) . . . . ?
N8 C40 C41 C42 -3.0(14) . . . . ?
C40 C41 C42 C43 0.4(14) . . . . ?
C40 C41 C42 C37 -177.8(8) . . . . ?
N7 C37 C42 C43 179.3(9) . . . . ?
C36 C37 C42 C43 -4.3(15) . . . . ?
N7 C37 C42 C41 -2.7(13) . . . . ?
C36 C37 C42 C41 173.8(9) . . . . ?
C41 C42 C43 C44 2.1(16) . . . . ?
C37 C42 C43 C44 -179.8(10) . . . . ?
C40 N8 C44 C43 -0.5(17) . . . . ?
Rh2 N8 C44 C43 -174.3(9) . . . . ?
C42 C43 C44 N8 -2.1(19) . . . . ?
C49 C45 C46 C47 -0.8(8) . . . . ?
C50 C45 C46 C47 178.4(8) . . . . ?
Rh1 C45 C46 C47 60.2(5) . . . . ?
C49 C45 C46 C51 -178.5(8) . . . . ?
C50 C45 C46 C51 0.7(13) . . . . ?
Rh1 C45 C46 C51 -117.5(8) . . . . ?
C49 C45 C46 Rh1 -61.0(5) . . . . ?
C50 C45 C46 Rh1 118.2(8) . . . . ?
C45 C46 C47 C48 0.8(8) . . . . ?
C51 C46 C47 C48 178.6(8) . . . . ?
Rh1 C46 C47 C48 60.9(5) . . . . ?
C45 C46 C47 C52 178.8(7) . . . . ?
C51 C46 C47 C52 -3.5(12) . . . . ?
Rh1 C46 C47 C52 -121.1(7) . . . . ?
C45 C46 C47 Rh1 -60.1(5) . . . . ?
C51 C46 C47 Rh1 117.6(8) . . . . ?
C46 C47 C48 C49 -0.6(8) . . . . ?
C52 C47 C48 C49 -178.5(7) . . . . ?
Rh1 C47 C48 C49 60.2(5) . . . . ?
C46 C47 C48 C53 176.2(8) . . . . ?
C52 C47 C48 C53 -1.7(13) . . . . ?
Rh1 C47 C48 C53 -123.0(8) . . . . ?
C46 C47 C48 Rh1 -60.8(5) . . . . ?
C52 C47 C48 Rh1 121.3(8) . . . . ?
C46 C45 C49 C48 0.5(8) . . . . ?
C50 C45 C49 C48 -178.8(8) . . . . ?
Rh1 C45 C49 C48 -60.7(5) . . . . ?
C46 C45 C49 C54 -176.8(8) . . . . ?
C50 C45 C49 C54 4.0(13) . . . . ?
Rh1 C45 C49 C54 122.1(8) . . . . ?
C46 C45 C49 Rh1 61.1(5) . . . . ?
C50 C45 C49 Rh1 -118.1(8) . . . . ?
C47 C48 C49 C45 0.1(8) . . . . ?
C53 C48 C49 C45 -176.6(8) . . . . ?
Rh1 C48 C49 C45 60.3(5) . . . . ?
C47 C48 C49 C54 177.3(7) . . . . ?
C53 C48 C49 C54 0.6(13) . . . . ?
Rh1 C48 C49 C54 -122.5(8) . . . . ?
C47 C48 C49 Rh1 -60.2(5) . . . . ?
C53 C48 C49 Rh1 123.1(9) . . . . ?
C59 C55 C56 C57 -1.3(15) . . . . ?
C60 C55 C56 C57 -175.9(13) . . . . ?
Rh2 C55 C56 C57 60.1(10) . . . . ?
C59 C55 C56 C61 174.1(15) . . . . ?
C60 C55 C56 C61 0(2) . . . . ?
Rh2 C55 C56 C61 -124.5(17) . . . . ?
C59 C55 C56 Rh2 -61.5(9) . . . . ?
C60 C55 C56 Rh2 124.0(14) . . . . ?
C61 C56 C57 C58 -176.1(15) . . . . ?
C55 C56 C57 C58 -0.9(17) . . . . ?
Rh2 C56 C57 C58 59.0(10) . . . . ?
C61 C56 C57 C62 4(3) . . . . ?
C55 C56 C57 C62 178.9(12) . . . . ?
Rh2 C56 C57 C62 -121.2(15) . . . . ?
C61 C56 C57 Rh2 124.9(17) . . . . ?
C55 C56 C57 Rh2 -59.9(9) . . . . ?
C56 C57 C58 C59 2.7(15) . . . . ?
C62 C57 C58 C59 -177.2(12) . . . . ?
Rh2 C57 C58 C59 63.0(8) . . . . ?
C56 C57 C58 C63 178.8(15) . . . . ?
C62 C57 C58 C63 -1(2) . . . . ?
Rh2 C57 C58 C63 -120.9(17) . . . . ?
C56 C57 C58 Rh2 -60.3(12) . . . . ?
C62 C57 C58 Rh2 119.9(13) . . . . ?
C56 C55 C59 C58 3.1(14) . . . . ?
C60 C55 C59 C58 177.5(13) . . . . ?
Rh2 C55 C59 C58 -58.1(8) . . . . ?
C56 C55 C59 C64 178.3(10) . . . . ?
C60 C55 C59 C64 -7(2) . . . . ?
Rh2 C55 C59 C64 117.2(10) . . . . ?
C56 C55 C59 Rh2 61.2(8) . . . . ?
C60 C55 C59 Rh2 -124.4(14) . . . . ?
C57 C58 C59 C55 -3.4(13) . . . . ?
C63 C58 C59 C55 -179.8(14) . . . . ?
Rh2 C58 C59 C55 58.4(8) . . . . ?
C57 C58 C59 C64 -178.5(11) . . . . ?
C63 C58 C59 C64 5(2) . . . . ?
Rh2 C58 C59 C64 -116.6(11) . . . . ?
C57 C58 C59 Rh2 -61.9(9) . . . . ?
C63 C58 C59 Rh2 121.8(15) . . . . ?
C69 C65 C66 C67 -1.9(11) . . . . ?
C70 C65 C66 C67 -177.4(9) . . . . ?
Rh3 C65 C66 C67 60.0(7) . . . . ?
C69 C65 C66 C71 179.4(10) . . . . ?
C70 C65 C66 C71 3.9(16) . . . . ?
Rh3 C65 C66 C71 -118.7(10) . . . . ?
C69 C65 C66 Rh3 -61.9(6) . . . . ?
C70 C65 C66 Rh3 122.6(9) . . . . ?
C65 C66 C67 C68 -0.6(12) . . . . ?
C71 C66 C67 C68 178.1(10) . . . . ?
Rh3 C66 C67 C68 58.6(7) . . . . ?
C65 C66 C67 C72 -179.8(11) . . . . ?
C71 C66 C67 C72 -1.0(18) . . . . ?
Rh3 C66 C67 C72 -120.5(13) . . . . ?
C65 C66 C67 Rh3 -59.3(7) . . . . ?
C71 C66 C67 Rh3 119.5(11) . . . . ?
C66 C67 C68 C73 175.8(12) . . . . ?
C72 C67 C68 C73 -5(2) . . . . ?
Rh3 C67 C68 C73 -123.6(14) . . . . ?
C66 C67 C68 C69 2.8(12) . . . . ?
C72 C67 C68 C69 -178.0(12) . . . . ?
Rh3 C67 C68 C69 63.4(7) . . . . ?
C66 C67 C68 Rh3 -60.6(7) . . . . ?
C72 C67 C68 Rh3 118.5(13) . . . . ?
C70 C65 C69 C68 179.0(9) . . . . ?
C66 C65 C69 C68 3.6(11) . . . . ?
Rh3 C65 C69 C68 -58.2(7) . . . . ?
C70 C65 C69 C74 -7.0(16) . . . . ?
C66 C65 C69 C74 177.6(9) . . . . ?
Rh3 C65 C69 C74 115.8(10) . . . . ?
C70 C65 C69 Rh3 -122.8(10) . . . . ?
C66 C65 C69 Rh3 61.8(6) . . . . ?
C73 C68 C69 C65 -176.8(12) . . . . ?
C67 C68 C69 C65 -4.1(12) . . . . ?
Rh3 C68 C69 C65 60.0(7) . . . . ?
C73 C68 C69 C74 9.6(19) . . . . ?
C67 C68 C69 C74 -177.6(10) . . . . ?
Rh3 C68 C69 C74 -113.5(11) . . . . ?
C73 C68 C69 Rh3 123.2(14) . . . . ?
C67 C68 C69 Rh3 -64.1(8) . . . . ?
Rh5 O13 C85 C90 179.9(5) . . . . ?
Rh5 O13 C85 C86 -1.6(8) . . . . ?
Rh5 O14 C86 C87 -178.9(5) . . . . ?
Rh5 O14 C86 C85 -0.6(8) . . . . ?
O13 C85 C86 O14 1.5(9) . . . . ?
C90 C85 C86 O14 -180.0(6) . . . . ?
O13 C85 C86 C87 179.9(6) . . . . ?
C90 C85 C86 C87 -1.6(10) . . . . ?
O14 C86 C87 C88 -178.9(6) . . . . ?
C85 C86 C87 C88 2.8(10) . . . . ?
Rh6 O15 C88 C87 177.9(5) . . . . ?
Rh6 O15 C88 C89 -2.8(6) . . . . ?
C86 C87 C88 O15 177.9(6) . . . . ?
C86 C87 C88 C89 -1.3(9) . . . . ?
Rh6 O16 C89 C90 -176.0(5) . . . . ?
Rh6 O16 C89 C88 3.6(7) . . . . ?
O15 C88 C89 O16 -0.5(8) . . . . ?
C87 C88 C89 O16 178.8(6) . . . . ?
O15 C88 C89 C90 179.1(6) . . . . ?
C87 C88 C89 C90 -1.6(9) . . . . ?
O16 C89 C90 C85 -177.6(6) . . . . ?
C88 C89 C90 C85 2.8(9) . . . . ?
O13 C85 C90 C89 177.2(6) . . . . ?
C86 C85 C90 C89 -1.3(9) . . . . ?
Rh7 O17 C91 C96 -178.3(6) . . . . ?
Rh7 O17 C91 C92 0.4(8) . . . . ?
Rh7 O18 C92 C93 178.3(5) . . . . ?
Rh7 O18 C92 C91 0.4(8) . . . . ?
O17 C91 C92 O18 -0.5(10) . . . . ?
C96 C91 C92 O18 178.2(7) . . . . ?
O17 C91 C92 C93 -178.4(7) . . . . ?
C96 C91 C92 C93 0.3(11) . . . . ?
O18 C92 C93 C94 -179.7(7) . . . . ?
C91 C92 C93 C94 -1.8(10) . . . . ?
Rh8 O19 C94 C93 -178.6(5) . . . . ?
Rh8 O19 C94 C95 3.5(7) . . . . ?
C92 C93 C94 O19 -177.5(6) . . . . ?
C92 C93 C94 C95 0.4(10) . . . . ?
Rh8 O20 C95 C96 176.4(6) . . . . ?
Rh8 O20 C95 C94 -0.9(8) . . . . ?
O19 C94 C95 O20 -1.7(9) . . . . ?
C93 C94 C95 O20 -179.7(7) . . . . ?
O19 C94 C95 C96 -179.2(7) . . . . ?
C93 C94 C95 C96 2.8(10) . . . . ?
O20 C95 C96 C91 178.4(7) . . . . ?
C94 C95 C96 C91 -4.3(11) . . . . ?
O17 C91 C96 C95 -178.5(7) . . . . ?
C92 C91 C96 C95 2.9(11) . . . . ?
C101 N9 C97 C98 3.9(12) . . . . ?
Rh5 N9 C97 C98 -170.6(6) . . . . ?
N9 C97 C98 C99 1.6(13) . . . . ?
C97 C98 C99 C100 -5.8(12) . . . . ?
C97 C98 C99 C202 175.3(8) . . . . ?
C97 C98 C99 C102 175.3(8) . . . . ?
C203 C202 C99 C98 171.5(8) . . . . ?
C206 C202 C99 C98 -12.1(12) . . . . ?
C203 C202 C99 C100 -7.4(13) . . . . ?
C206 C202 C99 C100 169.1(7) . . . . ?
C103 C102 C99 C98 171.5(8) . . . . ?
N10 C102 C99 C98 -12.1(12) . . . . ?
C103 C102 C99 C100 -7.4(13) . . . . ?
N10 C102 C99 C100 169.1(7) . . . . ?
C98 C99 C100 C101 4.8(12) . . . . ?
C202 C99 C100 C101 -176.3(8) . . . . ?
C102 C99 C100 C101 -176.3(8) . . . . ?
C99 C100 C101 N9 0.6(13) . . . . ?
C97 N9 C101 C100 -4.9(12) . . . . ?
Rh5 N9 C101 C100 169.6(7) . . . . ?
C112 N12 C108 C109 0.0(15) . . . . ?
Rh7 N12 C108 C109 178.1(8) . . . . ?
N12 C108 C109 C110 -1.6(16) . . . . ?
C108 C109 C110 C111 2.6(14) . . . . ?
C108 C109 C110 C105 -178.2(9) . . . . ?
C108 C109 C110 C205 -178.2(9) . . . . ?
C104 C105 C110 C111 -2.0(14) . . . . ?
N11 C105 C110 C111 178.5(9) . . . . ?
C104 C105 C110 C109 178.9(9) . . . . ?
N11 C105 C110 C109 -0.7(13) . . . . ?
C204 C205 C110 C111 -2.0(14) . . . . ?
C207 C205 C110 C111 178.5(9) . . . . ?
C204 C205 C110 C109 178.9(9) . . . . ?
C207 C205 C110 C109 -0.7(13) . . . . ?
C109 C110 C111 C112 -2.2(14) . . . . ?
C105 C110 C111 C112 178.6(9) . . . . ?
C205 C110 C111 C112 178.6(9) . . . . ?
C108 N12 C112 C111 0.5(15) . . . . ?
Rh7 N12 C112 C111 -177.7(8) . . . . ?
C110 C111 C112 N12 0.7(16) . . . . ?
C117 N13 C113 C114 -0.7(11) . . . . ?
Rh6 N13 C113 C114 -176.3(6) . . . . ?
N13 C113 C114 C115 0.9(12) . . . . ?
C113 C114 C115 C116 -0.8(11) . . . . ?
C113 C114 C115 C118 179.9(7) . . . . ?
C114 C115 C116 C117 0.6(10) . . . . ?
C118 C115 C116 C117 179.9(7) . . . . ?
C113 N13 C117 C116 0.5(11) . . . . ?
Rh6 N13 C117 C116 176.1(6) . . . . ?
C115 C116 C117 N13 -0.5(11) . . . . ?
C122 N14 C118 C119 0.0(8) . . . . ?
C122 N14 C118 C115 175.9(6) . . . . ?
C114 C115 C118 N14 -1.5(10) . . . . ?
C116 C115 C118 N14 179.3(7) . . . . ?
C114 C115 C118 C119 173.6(7) . . . . ?
C116 C115 C118 C119 -5.7(11) . . . . ?
N14 C118 C119 C120 0.4(8) . . . . ?
C115 C118 C119 C120 -175.2(7) . . . . ?
N14 C118 C119 C123 179.4(9) . . . . ?
C115 C118 C119 C123 3.9(15) . . . . ?
C118 C119 C120 C121 175.7(6) . . . . ?
C123 C119 C120 C121 -3.7(9) . . . . ?
C118 C119 C120 C122 -0.6(8) . . . . ?
C123 C119 C120 C122 180.0(6) . . . . ?
C119 C120 C121 N15 3.7(9) . . . . ?
C122 C120 C121 N15 178.2(9) . . . . ?
C119 C120 C121 C126 -175.6(8) . . . . ?
C122 C120 C121 C126 -1.1(17) . . . . ?
C123 N15 C121 C120 -2.4(10) . . . . ?
C123 N15 C121 C126 176.9(7) . . . . ?
C118 N14 C122 O23 179.8(6) . . . . ?
C118 N14 C122 C120 -0.4(7) . . . . ?
C121 C120 C122 O23 5.8(16) . . . . ?
C119 C120 C122 O23 -179.6(8) . . . . ?
C121 C120 C122 N14 -173.9(10) . . . . ?
C119 C120 C122 N14 0.6(7) . . . . ?
C121 N15 C123 O24 -178.4(9) . . . . ?
C121 N15 C123 C119 0.2(9) . . . . ?
C118 C119 C123 O24 1.3(18) . . . . ?
C120 C119 C123 O24 -179.6(10) . . . . ?
C118 C119 C123 N15 -177.0(9) . . . . ?
C120 C119 C123 N15 2.0(8) . . . . ?
C128 N16 C124 C125 -4.3(13) . . . . ?
Rh8 N16 C124 C125 172.2(7) . . . . ?
N16 C124 C125 C126 1.1(13) . . . . ?
C124 C125 C126 C127 1.1(13) . . . . ?
C124 C125 C126 C121 -176.1(8) . . . . ?
C120 C121 C126 C127 2.9(15) . . . . ?
N15 C121 C126 C127 -176.3(9) . . . . ?
C120 C121 C126 C125 180.0(9) . . . . ?
N15 C121 C126 C125 0.8(13) . . . . ?
C125 C126 C127 C128 -0.1(15) . . . . ?
C121 C126 C127 C128 177.1(9) . . . . ?
C126 C127 C128 N16 -3.1(16) . . . . ?
C124 N16 C128 C127 5.2(14) . . . . ?
Rh8 N16 C128 C127 -171.3(8) . . . . ?
C133 C129 C130 C131 -1.5(11) . . . . ?
C134 C129 C130 C131 178.1(11) . . . . ?
Rh5 C129 C130 C131 59.1(7) . . . . ?
C133 C129 C130 C135 -178.4(9) . . . . ?
C134 C129 C130 C135 1.3(17) . . . . ?
Rh5 C129 C130 C135 -117.8(9) . . . . ?
C133 C129 C130 Rh5 -60.6(7) . . . . ?
C134 C129 C130 Rh5 119.1(12) . . . . ?
C129 C130 C131 C132 0.8(11) . . . . ?
C135 C130 C131 C132 177.4(10) . . . . ?
Rh5 C130 C131 C132 60.3(7) . . . . ?
C129 C130 C131 C136 -176.7(10) . . . . ?
C135 C130 C131 C136 -0.1(16) . . . . ?
Rh5 C130 C131 C136 -117.1(11) . . . . ?
C129 C130 C131 Rh5 -59.6(7) . . . . ?
C135 C130 C131 Rh5 117.0(10) . . . . ?
C130 C131 C132 C133 0.3(13) . . . . ?
C136 C131 C132 C133 177.6(11) . . . . ?
Rh5 C131 C132 C133 63.5(9) . . . . ?
C130 C131 C132 C137 175.8(12) . . . . ?
C136 C131 C132 C137 -6.9(19) . . . . ?
Rh5 C131 C132 C137 -120.9(13) . . . . ?
C130 C131 C132 Rh5 -63.2(7) . . . . ?
C136 C131 C132 Rh5 114.1(12) . . . . ?
C131 C132 C133 C129 -1.3(14) . . . . ?
C137 C132 C133 C129 -176.5(13) . . . . ?
Rh5 C132 C133 C129 61.3(8) . . . . ?
C131 C132 C133 C138 179.1(11) . . . . ?
C137 C132 C133 C138 4(2) . . . . ?
Rh5 C132 C133 C138 -118.3(12) . . . . ?
C131 C132 C133 Rh5 -62.6(8) . . . . ?
C137 C132 C133 Rh5 122.3(14) . . . . ?
C134 C129 C133 C132 -178.0(12) . . . . ?
C130 C129 C133 C132 1.7(13) . . . . ?
Rh5 C129 C133 C132 -59.2(9) . . . . ?
C134 C129 C133 C138 1.6(19) . . . . ?
C130 C129 C133 C138 -178.7(11) . . . . ?
Rh5 C129 C133 C138 120.4(12) . . . . ?
C134 C129 C133 Rh5 -118.7(12) . . . . ?
C130 C129 C133 Rh5 61.0(7) . . . . ?
C143 C139 C140 C141 -3.9(8) . . . . ?
C144 C139 C140 C141 -180.0(8) . . . . ?
Rh6 C139 C140 C141 59.4(5) . . . . ?
C143 C139 C140 C145 -178.7(8) . . . . ?
C144 C139 C140 C145 5.3(13) . . . . ?
Rh6 C139 C140 C145 -115.3(8) . . . . ?
C143 C139 C140 Rh6 -63.4(5) . . . . ?
C144 C139 C140 Rh6 120.6(9) . . . . ?
C139 C140 C141 C142 2.4(9) . . . . ?
C145 C140 C141 C142 177.2(8) . . . . ?
Rh6 C140 C141 C142 60.9(5) . . . . ?
C139 C140 C141 C146 -178.8(8) . . . . ?
C145 C140 C141 C146 -4.1(13) . . . . ?
Rh6 C140 C141 C146 -120.4(8) . . . . ?
C139 C140 C141 Rh6 -58.5(5) . . . . ?
C145 C140 C141 Rh6 116.3(8) . . . . ?
C140 C141 C142 C143 0.1(9) . . . . ?
C146 C141 C142 C143 -178.6(8) . . . . ?
Rh6 C141 C142 C143 62.2(5) . . . . ?
C140 C141 C142 C147 177.6(9) . . . . ?
C146 C141 C142 C147 -1.1(14) . . . . ?
Rh6 C141 C142 C147 -120.3(9) . . . . ?
C140 C141 C142 Rh6 -62.1(6) . . . . ?
C146 C141 C142 Rh6 119.2(8) . . . . ?
C141 C142 C143 C139 -2.5(8) . . . . ?
C147 C142 C143 C139 179.9(9) . . . . ?
Rh6 C142 C143 C139 59.3(5) . . . . ?
C141 C142 C143 C148 -179.8(9) . . . . ?
C147 C142 C143 C148 2.6(15) . . . . ?
Rh6 C142 C143 C148 -118.0(10) . . . . ?
C141 C142 C143 Rh6 -61.8(5) . . . . ?
C147 C142 C143 Rh6 120.7(9) . . . . ?
C140 C139 C143 C142 3.9(8) . . . . ?
C144 C139 C143 C142 179.8(9) . . . . ?
Rh6 C139 C143 C142 -59.6(5) . . . . ?
C140 C139 C143 C148 -178.6(8) . . . . ?
C144 C139 C143 C148 -2.7(14) . . . . ?
Rh6 C139 C143 C148 117.9(9) . . . . ?
C140 C139 C143 Rh6 63.6(5) . . . . ?
C144 C139 C143 Rh6 -120.6(9) . . . . ?
C153 C149 C150 C151 4.6(13) . . . . ?
C154 C149 C150 C151 178.1(11) . . . . ?
Rh7 C149 C150 C151 64.4(7) . . . . ?
C153 C149 C150 C155 -176.9(13) . . . . ?
C154 C149 C150 C155 -3.3(19) . . . . ?
Rh7 C149 C150 C155 -117.1(13) . . . . ?
C153 C149 C150 Rh7 -59.8(8) . . . . ?
C154 C149 C150 Rh7 113.7(12) . . . . ?
C149 C150 C151 C152 -5.1(13) . . . . ?
C155 C150 C151 C152 176.2(11) . . . . ?
Rh7 C150 C151 C152 57.7(9) . . . . ?
C149 C150 C151 C156 -177.1(10) . . . . ?
C155 C150 C151 C156 4.2(17) . . . . ?
Rh7 C150 C151 C156 -114.2(11) . . . . ?
C149 C150 C151 Rh7 -62.8(7) . . . . ?
C155 C150 C151 Rh7 118.4(11) . . . . ?
C150 C151 C152 C153 3.5(14) . . . . ?
C156 C151 C152 C153 175.9(10) . . . . ?
Rh7 C151 C152 C153 60.4(9) . . . . ?
C150 C151 C152 C157 179.9(13) . . . . ?
C156 C151 C152 C157 -8(2) . . . . ?
Rh7 C151 C152 C157 -123.3(16) . . . . ?
C150 C151 C152 Rh7 -56.9(8) . . . . ?
C156 C151 C152 Rh7 115.5(11) . . . . ?
C150 C149 C153 C152 -2.7(14) . . . . ?
C154 C149 C153 C152 -174.9(14) . . . . ?
Rh7 C149 C153 C152 -63.5(8) . . . . ?
C150 C149 C153 C158 -179.7(13) . . . . ?
C154 C149 C153 C158 8(2) . . . . ?
Rh7 C149 C153 C158 119.5(14) . . . . ?
C150 C149 C153 Rh7 60.8(8) . . . . ?
C154 C149 C153 Rh7 -111.5(15) . . . . ?
C151 C152 C153 C149 -0.5(14) . . . . ?
C157 C152 C153 C149 -177.4(12) . . . . ?
Rh7 C152 C153 C149 63.3(9) . . . . ?
C151 C152 C153 C158 176.5(13) . . . . ?
C157 C152 C153 C158 0(2) . . . . ?
Rh7 C152 C153 C158 -119.8(14) . . . . ?
C151 C152 C153 Rh7 -63.7(9) . . . . ?
C157 C152 C153 Rh7 119.4(12) . . . . ?
C163 C159 C160 C161 -0.8(15) . . . . ?
C164 C159 C160 C161 176.0(14) . . . . ?
Rh8 C159 C160 C161 60.2(8) . . . . ?
C163 C159 C160 C165 -178.5(12) . . . . ?
C164 C159 C160 C165 -2(2) . . . . ?
Rh8 C159 C160 C165 -117.5(13) . . . . ?
C163 C159 C160 Rh8 -61.0(10) . . . . ?
C164 C159 C160 Rh8 115.7(16) . . . . ?
C159 C160 C161 C162 0.8(13) . . . . ?
C165 C160 C161 C162 178.6(11) . . . . ?
Rh8 C160 C161 C162 61.0(7) . . . . ?
C159 C160 C161 C166 178.0(11) . . . . ?
C165 C160 C161 C166 -4.2(18) . . . . ?
Rh8 C160 C161 C166 -121.7(11) . . . . ?
C159 C160 C161 Rh8 -60.3(9) . . . . ?
C165 C160 C161 Rh8 117.6(12) . . . . ?
C160 C161 C162 C167 176.8(11) . . . . ?
C166 C161 C162 C167 -0.5(18) . . . . ?
Rh8 C161 C162 C167 -121.9(12) . . . . ?
C160 C161 C162 C163 -0.5(11) . . . . ?
C166 C161 C162 C163 -177.8(10) . . . . ?
Rh8 C161 C162 C163 60.8(7) . . . . ?
C160 C161 C162 Rh8 -61.3(7) . . . . ?
C166 C161 C162 Rh8 121.4(10) . . . . ?
C160 C159 C163 C168 176.5(13) . . . . ?
C164 C159 C163 C168 0(2) . . . . ?
Rh8 C159 C163 C168 114.9(14) . . . . ?
C160 C159 C163 C162 0.4(15) . . . . ?
C164 C159 C163 C162 -176.4(14) . . . . ?
Rh8 C159 C163 C162 -61.1(8) . . . . ?
C160 C159 C163 Rh8 61.6(10) . . . . ?
C164 C159 C163 Rh8 -115.3(15) . . . . ?
C167 C162 C163 C159 -177.3(12) . . . . ?
C161 C162 C163 C159 0.1(12) . . . . ?
Rh8 C162 C163 C159 61.0(9) . . . . ?
C167 C162 C163 C168 6.2(18) . . . . ?
C161 C162 C163 C168 -176.4(11) . . . . ?
Rh8 C162 C163 C168 -115.5(12) . . . . ?
C167 C162 C163 Rh8 121.6(11) . . . . ?
C161 C162 C163 Rh8 -61.0(7) . . . . ?
O25 S1 C169 F2 -69.6(19) . . . . ?
O26 S1 C169 F2 61.2(18) . . . . ?
O27 S1 C169 F2 175.6(16) . . . . ?
O25 S1 C169 F3 52.8(19) . . . . ?
O26 S1 C169 F3 -176.4(16) . . . . ?
O27 S1 C169 F3 -61.9(18) . . . . ?
O25 S1 C169 F1 172.0(17) . . . . ?
O26 S1 C169 F1 -57.1(19) . . . . ?
O27 S1 C169 F1 57.3(18) . . . . ?
O29 S2 C170 F4 68.8(18) . . . . ?
O28 S2 C170 F4 -66.8(17) . . . . ?
O30 S2 C170 F4 -178.4(16) . . . . ?
O29 S2 C170 F6 -43.9(18) . . . . ?
O28 S2 C170 F6 -179.6(15) . . . . ?
O30 S2 C170 F6 68.9(17) . . . . ?
O29 S2 C170 F5 -178.2(15) . . . . ?
O28 S2 C170 F5 46.2(16) . . . . ?
O30 S2 C170 F5 -65.4(16) . . . . ?
O31 S3 C171 F7 -178.6(12) . . . . ?
O32 S3 C171 F7 -62.2(14) . . . . ?
O33 S3 C171 F7 60.0(13) . . . . ?
O31 S3 C171 F8 -61.0(13) . . . . ?
O32 S3 C171 F8 55.5(13) . . . . ?
O33 S3 C171 F8 177.6(12) . . . . ?
O31 S3 C171 F9 60.7(14) . . . . ?
O32 S3 C171 F9 177.2(14) . . . . ?
O33 S3 C171 F9 -60.7(14) . . . . ?
O36 S4 C172 F11 -51(2) . . . . ?
O35 S4 C172 F11 -174.2(16) . . . . ?
O34 S4 C172 F11 62.3(19) . . . . ?
O36 S4 C172 F12 71.6(19) . . . . ?
O35 S4 C172 F12 -51.3(18) . . . . ?
O34 S4 C172 F12 -174.7(15) . . . . ?
O36 S4 C172 F10 -173.9(16) . . . . ?
O35 S4 C172 F10 63.2(14) . . . . ?
O34 S4 C172 F10 -60.3(13) . . . . ?
O37 S5 C173 F14 -174.1(17) . . . . ?
O39 S5 C173 F14 52.9(19) . . . . ?
O38 S5 C173 F14 -58.4(18) . . . . ?
O37 S5 C173 F13 64.9(17) . . . . ?
O39 S5 C173 F13 -68.1(17) . . . . ?
O38 S5 C173 F13 -179.4(14) . . . . ?
O37 S5 C173 F15 -54(2) . . . . ?
O39 S5 C173 F15 173(2) . . . . ?
O38 S5 C173 F15 62(2) . . . . ?
O40 S6 C174 F17 -176.6(17) . . . . ?
O41 S6 C174 F17 -53.0(17) . . . . ?
O42 S6 C174 F17 61.5(18) . . . . ?
O40 S6 C174 F16 51.9(18) . . . . ?
O41 S6 C174 F16 175.4(14) . . . . ?
O42 S6 C174 F16 -70.1(16) . . . . ?
O40 S6 C174 F18 -59.2(16) . . . . ?
O41 S6 C174 F18 64.4(13) . . . . ?
O42 S6 C174 F18 178.9(16) . . . . ?
O49 C177 N17 C178 1(3) . . . . ?
O49 C177 N17 C179 -173.2(18) . . . . ?
O50 C180 N18 C181 -2.8(19) . . . . ?
O50 C180 N18 C182 173.1(13) . . . . ?
O51 C183 N19 C184 179.4(11) . . . . ?
O51 C183 N19 C185 4(2) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C127 H127 O23 0.95 2.33 3.232(12) 158.3 .
C116 H116 O24 0.95 2.23 3.120(10) 155.0 .
C114 H114 O50 0.95 2.29 3.219(10) 165.7 .
C111 H111 O21 0.95 2.29 3.189(16) 158.6 .
C100 H100 O22 0.95 2.34 3.241(15) 158.4 .
C43 H43 O11 0.95 2.37 3.255(13) 155.2 .
C41 H41 O51 0.95 2.42 3.310(13) 156.8 2_666
C32 H32 O49 0.95 2.30 3.234(11) 165.8 .
C30 H30 O12 0.95 2.26 3.150(10) 155.7 .
C27 H27 O9 0.95 2.35 3.234(12) 155.3 .
C25 H25 O34 0.95 2.36 3.297(11) 168.8 1_545
C16 H16 O26 0.95 2.43 3.334(13) 158.6 2_666
C14 H14A O10 0.95 2.26 3.149(11) 155.0 .
N14 H14 O50 0.88 1.85 2.725(12) 175.1 .
N7 H7 O51 0.88 1.83 2.683(11) 162.9 2_666
N6 H6 O49 0.88 1.89 2.767(11) 177.1 .
C206 H206 O28 0.95 1.94 2.877(16) 168.6 1_556
N10 H10 O28 0.88 2.01 2.877(16) 169.0 1_556
C23' H23' O34 0.95 1.93 2.863(12) 167.3 1_545
C22' H22' O26 0.95 2.01 2.946(11) 169.1 2_666
N3 H3 O34 0.88 2.00 2.863(12) 167.8 1_545
N2 H2 O26 0.88 2.08 2.946(11) 169.5 2_666

_refine_diff_density_max         3.421
_refine_diff_density_min         -1.227
_refine_diff_density_rms         0.151



