# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_p
_audit_block_doi                 10.5517/ccdc.csd.cc23kqr5
_database_code_depnum_ccdc_archive 'CCDC 1953457'
loop_
_citation_id
_citation_doi
_citation_year
1 10.1021/acs.inorgchem.9b02956 2020
loop_
_audit_author_name
_audit_author_address
'Kuan-Guan Liu'
;Ningxia University
China
;
_audit_update_record             
;
2019-09-13 deposited with the CCDC.	2020-06-08 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C31 H30 Ag8 F12 N O9'
_chemical_formula_weight         1651.52

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   15.0304(14)
_cell_length_b                   22.8131(18)
_cell_length_c                   13.6252(13)
_cell_angle_alpha                90
_cell_angle_beta                 107.640(3)
_cell_angle_gamma                90
_cell_volume                     4452.3(7)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    10222
_cell_measurement_theta_min      2.844
_cell_measurement_theta_max      27.518

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      'not measured'
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    2.464
_exptl_crystal_F_000             3116
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.180
_exptl_crystal_size_mid          0.170
_exptl_crystal_size_min          0.060
_exptl_absorpt_coefficient_mu    3.538
_shelx_estimated_absorpt_T_min   0.568
_shelx_estimated_absorpt_T_max   0.816
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.534
_exptl_absorpt_correction_T_max  0.809
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.39.33c (Rigaku Oxford Diffraction, 2017)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            61813
_diffrn_reflns_av_unetI/netI     0.0313
_diffrn_reflns_av_R_equivalents  0.0421
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         2.844
_diffrn_reflns_theta_max         27.518
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             10222
_reflns_number_gt                8384
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX3'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL or Diamond'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0223P)²+42.1441P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         10222
_refine_ls_number_parameters     647
_refine_ls_number_restraints     355
_refine_ls_R_factor_all          0.0582
_refine_ls_R_factor_gt           0.0426
_refine_ls_wR_factor_ref         0.0923
_refine_ls_wR_factor_gt          0.0855
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_restrained_S_all      1.063
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.20693(3) 0.22674(2) 0.17598(3) 0.02233(9) Uani 1 1 d . . . . .
Ag2 Ag 0.21405(3) 0.25880(2) -0.05041(3) 0.02724(10) Uani 1 1 d . . . . .
Ag3 Ag 0.39262(3) 0.22748(2) 0.13653(4) 0.03823(13) Uani 1 1 d . . . . .
Ag4 Ag 0.36057(3) 0.20470(2) 0.35334(3) 0.02950(11) Uani 1 1 d . . . . .
Ag5 Ag 0.04046(4) 0.25448(2) 0.26009(4) 0.03879(13) Uani 1 1 d . . . . .
Ag6 Ag 0.20923(3) 0.13450(2) 0.02903(3) 0.03173(11) Uani 1 1 d . . . . .
Ag7 Ag 0.18976(4) 0.33862(2) 0.30758(4) 0.03701(13) Uani 1 1 d . . . . .
Ag8 Ag 0.25678(5) 0.34448(2) 0.11626(6) 0.05812(19) Uani 1 1 d . . . . .
C1 C 0.1231(4) 0.3030(3) 0.1398(4) 0.0259(12) Uani 1 1 d . U . . .
C2 C 0.0656(5) 0.3379(3) 0.0951(5) 0.0379(14) Uani 1 1 d . U . . .
C3 C -0.0071(6) 0.3799(4) 0.0393(6) 0.064(2) Uani 1 1 d . U . . .
C4 C -0.0658(6) 0.3538(4) -0.0589(7) 0.064(2) Uani 1 1 d . U . . .
H4A H -0.1117 0.3828 -0.0965 0.096 Uiso 1 1 calc R U . . .
H4B H -0.0983 0.3193 -0.0441 0.096 Uiso 1 1 calc R U . . .
H4C H -0.0261 0.3423 -0.1009 0.096 Uiso 1 1 calc R U . . .
C5 C -0.0578(11) 0.4032(7) 0.1101(11) 0.081(5) Uani 0.653(17) 1 d . U P A 1
C6 C 0.0213(16) 0.4387(10) 0.0375(18) 0.057(6) Uani 0.347(17) 1 d . U P A 2
C11 C 0.1011(4) 0.1968(2) -0.0836(4) 0.0221(11) Uani 1 1 d . . . . .
C12 C 0.0376(4) 0.1698(3) -0.0674(5) 0.0333(14) Uani 1 1 d . . . . .
C13 C -0.0401(5) 0.1380(3) -0.0439(7) 0.0484(19) Uani 1 1 d . . . . .
H13 H -0.0257 0.1386 0.0327 0.058 Uiso 1 1 calc R U . . .
C14 C -0.0424(6) 0.0758(3) -0.0736(8) 0.063(2) Uani 1 1 d . . . . .
H14A H -0.0583 0.0728 -0.1486 0.094 Uiso 1 1 calc R U . . .
H14B H -0.0893 0.0551 -0.0501 0.094 Uiso 1 1 calc R U . . .
H14C H 0.0191 0.0582 -0.0416 0.094 Uiso 1 1 calc R U . . .
C15 C -0.1306(5) 0.1712(4) -0.0867(8) 0.063(2) Uani 1 1 d . . . . .
H15A H -0.1471 0.1726 -0.1620 0.094 Uiso 1 1 calc R U . . .
H15B H -0.1230 0.2112 -0.0592 0.094 Uiso 1 1 calc R U . . .
H15C H -0.1803 0.1513 -0.0668 0.094 Uiso 1 1 calc R U . . .
C21 C 0.3063(4) 0.1565(2) 0.2011(4) 0.0222(11) Uani 1 1 d . . . . .
C22 C 0.3391(4) 0.1103(2) 0.1839(4) 0.0258(12) Uani 1 1 d . . . . .
C23 C 0.3861(5) 0.0542(3) 0.1728(5) 0.0337(14) Uani 1 1 d . . . . .
H23 H 0.3805 0.0494 0.0982 0.040 Uiso 1 1 calc R U . . .
C24 C 0.4897(5) 0.0568(3) 0.2322(6) 0.0424(16) Uani 1 1 d . . . . .
H24A H 0.5187 0.0896 0.2066 0.064 Uiso 1 1 calc R U . . .
H24B H 0.5197 0.0201 0.2225 0.064 Uiso 1 1 calc R U . . .
H24C H 0.4975 0.0625 0.3056 0.064 Uiso 1 1 calc R U . . .
C25 C 0.3377(5) 0.0020(3) 0.2045(6) 0.0458(18) Uani 1 1 d . . . . .
H25A H 0.3405 0.0060 0.2770 0.069 Uiso 1 1 calc R U . . .
H25B H 0.3692 -0.0343 0.1953 0.069 Uiso 1 1 calc R U . . .
H25C H 0.2723 0.0006 0.1616 0.069 Uiso 1 1 calc R U . . .
C31 C 0.3471(4) 0.3011(2) 0.0148(4) 0.0224(11) Uani 1 1 d . . . . .
C32 C 0.4085(4) 0.3338(3) 0.0653(4) 0.0275(12) Uani 1 1 d . . . . .
C33 C 0.4835(4) 0.3761(3) 0.1141(5) 0.0320(13) Uani 1 1 d . . . . .
H33 H 0.4696 0.3939 0.1748 0.038 Uiso 1 1 calc R U . . .
C34 C 0.4838(6) 0.4250(3) 0.0373(6) 0.056(2) Uani 1 1 d . . . . .
H34A H 0.4993 0.4084 -0.0219 0.084 Uiso 1 1 calc R U . . .
H34B H 0.5303 0.4546 0.0708 0.084 Uiso 1 1 calc R U . . .
H34C H 0.4218 0.4431 0.0138 0.084 Uiso 1 1 calc R U . . .
C35 C 0.5780(5) 0.3461(3) 0.1514(5) 0.0382(15) Uani 1 1 d . . . . .
H35A H 0.5757 0.3149 0.2000 0.057 Uiso 1 1 calc R U . . .
H35B H 0.6257 0.3749 0.1858 0.057 Uiso 1 1 calc R U . . .
H35C H 0.5935 0.3292 0.0925 0.057 Uiso 1 1 calc R U . . .
O1 O 0.5416(3) 0.2087(2) 0.2353(3) 0.0346(10) Uani 1 1 d . . . . .
O2 O 0.5224(3) 0.2003(2) 0.3920(3) 0.0433(12) Uani 1 1 d . . . . .
C103 C 0.5660(4) 0.1989(3) 0.3292(5) 0.0282(12) Uani 1 1 d . . . . .
C104 C 0.6701(5) 0.1821(3) 0.3725(5) 0.0407(15) Uani 1 1 d D U . . .
F5 F 0.7238(3) 0.2270(2) 0.3662(5) 0.0776(16) Uani 1 1 d D U . . .
F6 F 0.6979(5) 0.1714(4) 0.4727(4) 0.057(2) Uani 0.703(7) 1 d D U P B 1
F9 F 0.6853(15) 0.1459(7) 0.4541(13) 0.055(5) Uiso 0.297(7) 1 d D U P B 2
F7 F 0.6931(3) 0.1392(2) 0.3193(4) 0.0600(12) Uani 1 1 d D U . . .
O11 O 0.3692(6) 0.3227(3) 0.3117(5) 0.075(3) Uani 0.854(11) 1 d D U P C 1
O12 O 0.3559(6) 0.3566(4) 0.4577(9) 0.094(3) Uani 0.854(11) 1 d D U P C 1
O13 O 0.393(3) 0.365(2) 0.3028(18) 0.072(8) Uani 0.146(11) 1 d D U P C 2
O14 O 0.337(2) 0.3257(18) 0.419(4) 0.066(5) Uani 0.146(11) 1 d D U P C 2
C113 C 0.3982(6) 0.3489(3) 0.3927(6) 0.0515(19) Uani 1 1 d D U . . .
C114 C 0.4971(6) 0.3717(4) 0.4298(5) 0.0580(19) Uani 1 1 d D U . . .
F16 F 0.5338(4) 0.3610(3) 0.5287(4) 0.0930(18) Uani 1 1 d D U . . .
F15 F 0.5540(4) 0.3481(4) 0.3858(5) 0.070(2) Uani 0.703(7) 1 d D U P B 1
F17 F 0.4958(8) 0.4308(4) 0.4230(9) 0.100(4) Uani 0.703(7) 1 d D U P B 1
F18 F 0.4930(17) 0.4180(9) 0.3663(14) 0.077(4) Uani 0.297(7) 1 d D U P B 2
F20 F 0.5016(18) 0.4238(8) 0.4759(15) 0.085(4) Uani 0.297(7) 1 d D U P B 2
O21 O 0.2018(5) 0.4410(2) 0.3067(4) 0.0575(16) Uani 1 1 d . . . . .
C122 C 0.2067(5) 0.4723(3) 0.3826(5) 0.0341(14) Uani 1 1 d . . . . .
O22 O 0.1982(4) 0.04030(19) -0.0328(3) 0.0402(11) Uani 1 1 d . . . . .
C124 C 0.2271(6) 0.5374(3) 0.3693(6) 0.057(2) Uani 1 1 d D U . . .
F25 F 0.3161(7) 0.5458(5) 0.3908(12) 0.123(4) Uani 0.703(7) 1 d D U P B 1
F26 F 0.1942(8) 0.5547(3) 0.2725(6) 0.087(3) Uani 0.703(7) 1 d D U P B 1
F27 F 0.1868(10) 0.5729(3) 0.4155(9) 0.100(3) Uani 0.703(7) 1 d D U P B 1
F28 F 0.2910(15) 0.5458(8) 0.3237(16) 0.062(4) Uani 0.297(7) 1 d D U P B 2
F29 F 0.2675(12) 0.5643(5) 0.4606(9) 0.043(3) Uani 0.297(7) 1 d D U P B 2
F30 F 0.1529(14) 0.5696(9) 0.330(2) 0.098(5) Uani 0.297(7) 1 d D U P B 2
O31 O 0.1490(4) 0.1368(2) 0.3870(4) 0.0469(12) Uani 1 1 d . . . . .
C133 C 0.1127(4) 0.1256(3) 0.2957(5) 0.0334(14) Uani 1 1 d . . . . .
O32 O 0.0782(3) 0.1593(2) 0.2217(4) 0.0388(11) Uani 1 1 d . . . . .
C134 C 0.1049(5) 0.0608(3) 0.2653(6) 0.0526(19) Uani 1 1 d D U . . .
F35 F 0.1113(4) 0.0512(2) 0.1710(4) 0.0777(16) Uani 1 1 d D U . . .
F36 F 0.1704(5) 0.0275(2) 0.3248(4) 0.0856(18) Uani 1 1 d D U . . .
F37 F 0.0191(5) 0.0401(4) 0.2560(9) 0.077(3) Uani 0.703(7) 1 d D U P B 1
F38 F 0.0484(16) 0.0347(11) 0.3106(18) 0.080(5) Uani 0.297(7) 1 d D U P B 2
N1 N -0.1147(4) 0.2420(3) 0.1860(5) 0.0491(16) Uani 1 1 d . . . . .
C202 C -0.1890(5) 0.2267(3) 0.1521(6) 0.0400(16) Uani 1 1 d . . . . .
C203 C -0.2854(5) 0.2066(3) 0.1061(6) 0.0446(17) Uani 1 1 d . . . . .
H20A H -0.3284 0.2348 0.1219 0.067 Uiso 1 1 calc R U . . .
H20B H -0.2934 0.1681 0.1344 0.067 Uiso 1 1 calc R U . . .
H20C H -0.2990 0.2035 0.0313 0.067 Uiso 1 1 calc R U . . .
O301 O 0.2854(5) 0.4425(2) 0.1566(5) 0.0608(15) Uani 1 1 d . . . . .
C302 C 0.2589(8) 0.4890(4) 0.0861(7) 0.072(3) Uani 1 1 d . . . . .
H30A H 0.2593 0.4758 0.0178 0.108 Uiso 1 1 calc R U . . .
H30B H 0.3030 0.5216 0.1086 0.108 Uiso 1 1 calc R U . . .
H30C H 0.1960 0.5023 0.0827 0.108 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C1 2.117(6) . ?
Ag1 C21 2.146(5) . ?
Ag1 Ag4 2.8360(6) . ?
Ag1 Ag6 2.9119(6) . ?
Ag1 Ag8 2.9679(7) . ?
Ag1 Ag3 2.9980(7) . ?
Ag1 Ag5 3.1166(7) . ?
Ag1 Ag7 3.1744(7) . ?
Ag1 Ag2 3.2033(6) . ?
Ag2 C11 2.149(5) . ?
Ag2 C31 2.154(6) . ?
Ag2 Ag7 2.8962(7) 4_565 ?
Ag2 Ag8 2.9166(8) . ?
Ag2 Ag4 3.0022(6) 4_565 ?
Ag2 Ag6 3.0439(7) . ?
Ag2 Ag5 3.0794(7) 4_565 ?
Ag2 Ag3 3.1716(7) . ?
Ag3 O1 2.277(4) . ?
Ag3 C31 2.314(5) . ?
Ag3 C21 2.403(6) . ?
Ag3 C32 2.649(6) . ?
Ag3 Ag4 3.1767(7) . ?
Ag3 Ag8 3.3209(8) . ?
Ag4 C21 2.270(5) . ?
Ag4 C31 2.274(5) 4_566 ?
Ag4 O2 2.329(4) . ?
Ag4 Ag2 3.0022(6) 4_566 ?
Ag5 N1 2.261(6) . ?
Ag5 C11 2.329(5) 4_566 ?
Ag5 O32 2.343(5) . ?
Ag5 C1 2.587(6) . ?
Ag5 Ag7 2.8737(7) . ?
Ag5 Ag2 3.0794(7) 4_566 ?
Ag6 O22 2.296(4) . ?
Ag6 C11 2.346(5) . ?
Ag6 C21 2.409(5) . ?
Ag6 C22 2.464(6) . ?
Ag6 C12 2.642(6) . ?
Ag6 Ag7 3.0051(7) 4_565 ?
Ag7 O14 2.29(4) . ?
Ag7 O21 2.342(5) . ?
Ag7 C1 2.345(6) . ?
Ag7 C11 2.413(5) 4_566 ?
Ag7 Ag2 2.8962(7) 4_566 ?
Ag7 Ag6 3.0052(7) 4_566 ?
Ag7 Ag8 3.0691(8) . ?
Ag8 O301 2.312(5) . ?
Ag8 C1 2.329(6) . ?
Ag8 C31 2.423(6) . ?
Ag8 C32 2.589(6) . ?
C1 C2 1.197(8) . ?
C2 C3 1.479(10) . ?
C3 C6 1.41(3) . ?
C3 C4 1.485(12) . ?
C3 C5 1.495(16) . ?
C11 C12 1.212(8) . ?
C11 Ag5 2.329(5) 4_565 ?
C11 Ag7 2.413(5) 4_565 ?
C12 C13 1.490(9) . ?
C13 C14 1.471(10) . ?
C13 C15 1.511(11) . ?
C21 C22 1.215(8) . ?
C22 C23 1.492(8) . ?
C23 C24 1.523(9) . ?
C23 C25 1.525(9) . ?
C31 C32 1.223(8) . ?
C31 Ag4 2.274(5) 4_565 ?
C32 C33 1.481(8) . ?
C33 C35 1.519(9) . ?
C33 C34 1.529(9) . ?
O1 C103 1.241(7) . ?
O2 C103 1.226(7) . ?
C103 C104 1.543(9) . ?
C104 F6 1.323(8) . ?
C104 F7 1.324(7) . ?
C104 F5 1.324(7) . ?
C104 F9 1.348(13) . ?
O11 C113 1.215(9) . ?
O12 C113 1.249(10) . ?
O13 C113 1.261(17) . ?
O14 C113 1.209(17) . ?
C113 C114 1.509(12) . ?
C114 F15 1.301(9) . ?
C114 F16 1.315(8) . ?
C114 F20 1.336(14) . ?
C114 F17 1.350(11) . ?
C114 F18 1.355(14) . ?
F16 F20 1.61(2) . ?
F18 F20 1.47(3) . ?
O21 C122 1.240(8) . ?
C122 O22 1.231(8) 4_566 ?
C122 C124 1.538(9) . ?
O22 C122 1.231(8) 4_565 ?
C124 F27 1.285(9) . ?
C124 F25 1.293(10) . ?
C124 F28 1.307(12) . ?
C124 F30 1.308(14) . ?
C124 F26 1.321(9) . ?
C124 F29 1.355(11) . ?
O31 C133 1.224(8) . ?
C133 O32 1.249(8) . ?
C133 C134 1.530(10) . ?
C134 F36 1.312(8) . ?
C134 F38 1.333(14) . ?
C134 F35 1.335(8) . ?
C134 F37 1.343(9) . ?
N1 C202 1.126(9) . ?
C202 C203 1.468(10) . ?
O301 C302 1.405(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Ag1 C21 170.8(2) . . ?
C1 Ag1 Ag4 128.13(16) . . ?
C21 Ag1 Ag4 51.99(14) . . ?
C1 Ag1 Ag6 124.34(15) . . ?
C21 Ag1 Ag6 54.37(14) . . ?
Ag4 Ag1 Ag6 106.353(18) . . ?
C1 Ag1 Ag8 51.24(16) . . ?
C21 Ag1 Ag8 119.89(15) . . ?
Ag4 Ag1 Ag8 100.72(2) . . ?
Ag6 Ag1 Ag8 114.14(2) . . ?
C1 Ag1 Ag3 118.30(16) . . ?
C21 Ag1 Ag3 52.57(15) . . ?
Ag4 Ag1 Ag3 65.915(17) . . ?
Ag6 Ag1 Ag3 71.045(18) . . ?
Ag8 Ag1 Ag3 67.646(18) . . ?
C1 Ag1 Ag5 55.35(16) . . ?
C21 Ag1 Ag5 133.66(15) . . ?
Ag4 Ag1 Ag5 105.06(2) . . ?
Ag6 Ag1 Ag5 125.29(2) . . ?
Ag8 Ag1 Ag5 102.387(19) . . ?
Ag3 Ag1 Ag5 163.65(2) . . ?
C1 Ag1 Ag7 47.63(15) . . ?
C21 Ag1 Ag7 133.01(14) . . ?
Ag4 Ag1 Ag7 81.129(17) . . ?
Ag6 Ag1 Ag7 171.62(2) . . ?
Ag8 Ag1 Ag7 59.844(17) . . ?
Ag3 Ag1 Ag7 109.646(19) . . ?
Ag5 Ag1 Ag7 54.353(14) . . ?
C1 Ag1 Ag2 77.24(15) . . ?
C21 Ag1 Ag2 95.71(14) . . ?
Ag4 Ag1 Ag2 127.217(19) . . ?
Ag6 Ag1 Ag2 59.475(16) . . ?
Ag8 Ag1 Ag2 56.253(17) . . ?
Ag3 Ag1 Ag2 61.413(15) . . ?
Ag5 Ag1 Ag2 124.929(19) . . ?
Ag7 Ag1 Ag2 113.111(18) . . ?
C11 Ag2 C31 163.0(2) . . ?
C11 Ag2 Ag7 54.76(15) . 4_565 ?
C31 Ag2 Ag7 122.19(15) . 4_565 ?
C11 Ag2 Ag8 125.32(15) . . ?
C31 Ag2 Ag8 54.60(15) . . ?
Ag7 Ag2 Ag8 171.08(3) 4_565 . ?
C11 Ag2 Ag4 136.69(15) . 4_565 ?
C31 Ag2 Ag4 49.01(14) . 4_565 ?
Ag7 Ag2 Ag4 83.205(19) 4_565 4_565 ?
Ag8 Ag2 Ag4 97.854(19) . 4_565 ?
C11 Ag2 Ag6 50.18(14) . . ?
C31 Ag2 Ag6 112.94(14) . . ?
Ag7 Ag2 Ag6 60.722(16) 4_565 . ?
Ag8 Ag2 Ag6 111.77(2) . . ?
Ag4 Ag2 Ag6 120.89(2) 4_565 . ?
C11 Ag2 Ag5 49.03(14) . 4_565 ?
C31 Ag2 Ag5 146.56(14) . 4_565 ?
Ag7 Ag2 Ag5 57.392(16) 4_565 4_565 ?
Ag8 Ag2 Ag5 130.50(2) . 4_565 ?
Ag4 Ag2 Ag5 102.027(19) 4_565 4_565 ?
Ag6 Ag2 Ag5 95.800(18) . 4_565 ?
C11 Ag2 Ag3 116.30(14) . . ?
C31 Ag2 Ag3 46.84(14) . . ?
Ag7 Ag2 Ag3 105.57(2) 4_565 . ?
Ag8 Ag2 Ag3 65.96(2) . . ?
Ag4 Ag2 Ag3 81.895(18) 4_565 . ?
Ag6 Ag2 Ag3 67.051(16) . . ?
Ag5 Ag2 Ag3 161.26(2) 4_565 . ?
C11 Ag2 Ag1 78.33(14) . . ?
C31 Ag2 Ag1 90.16(14) . . ?
Ag7 Ag2 Ag1 115.713(19) 4_565 . ?
Ag8 Ag2 Ag1 57.791(17) . . ?
Ag4 Ag2 Ag1 136.628(19) 4_565 . ?
Ag6 Ag2 Ag1 55.494(13) . . ?
Ag5 Ag2 Ag1 121.187(19) 4_565 . ?
Ag3 Ag2 Ag1 56.102(15) . . ?
O1 Ag3 C31 125.78(17) . . ?
O1 Ag3 C21 101.57(16) . . ?
C31 Ag3 C21 132.57(19) . . ?
O1 Ag3 C32 101.95(18) . . ?
C31 Ag3 C32 27.48(19) . . ?
C21 Ag3 C32 150.42(19) . . ?
O1 Ag3 Ag1 134.07(11) . . ?
C31 Ag3 Ag1 92.48(14) . . ?
C21 Ag3 Ag1 45.17(13) . . ?
C32 Ag3 Ag1 105.25(13) . . ?
O1 Ag3 Ag2 163.44(11) . . ?
C31 Ag3 Ag2 42.79(14) . . ?
C21 Ag3 Ag2 91.51(12) . . ?
C32 Ag3 Ag2 69.38(13) . . ?
Ag1 Ag3 Ag2 62.485(16) . . ?
O1 Ag3 Ag4 79.57(11) . . ?
C31 Ag3 Ag4 133.64(14) . . ?
C21 Ag3 Ag4 45.43(12) . . ?
C32 Ag3 Ag4 123.12(13) . . ?
Ag1 Ag3 Ag4 54.591(14) . . ?
Ag2 Ag3 Ag4 116.99(2) . . ?
O1 Ag3 Ag8 132.09(12) . . ?
C31 Ag3 Ag8 46.84(14) . . ?
C21 Ag3 Ag8 100.69(13) . . ?
C32 Ag3 Ag8 49.86(13) . . ?
Ag1 Ag3 Ag8 55.745(15) . . ?
Ag2 Ag3 Ag8 53.329(17) . . ?
Ag4 Ag3 Ag8 86.91(2) . . ?
C21 Ag4 C31 138.0(2) . 4_566 ?
C21 Ag4 O2 104.32(19) . . ?
C31 Ag4 O2 99.91(18) 4_566 . ?
C21 Ag4 Ag1 48.14(14) . . ?
C31 Ag4 Ag1 123.13(14) 4_566 . ?
O2 Ag4 Ag1 136.46(11) . . ?
C21 Ag4 Ag2 115.17(14) . 4_566 ?
C31 Ag4 Ag2 45.66(14) 4_566 4_566 ?
O2 Ag4 Ag2 140.09(12) . 4_566 ?
Ag1 Ag4 Ag2 78.895(17) . 4_566 ?
C21 Ag4 Ag3 48.95(14) . . ?
C31 Ag4 Ag3 172.98(14) 4_566 . ?
O2 Ag4 Ag3 76.99(11) . . ?
Ag1 Ag4 Ag3 59.494(16) . . ?
Ag2 Ag4 Ag3 134.335(19) 4_566 . ?
N1 Ag5 C11 122.2(2) . 4_566 ?
N1 Ag5 O32 94.0(2) . . ?
C11 Ag5 O32 126.28(18) 4_566 . ?
N1 Ag5 C1 113.6(2) . . ?
C11 Ag5 C1 104.19(19) 4_566 . ?
O32 Ag5 C1 93.46(17) . . ?
N1 Ag5 Ag7 144.50(18) . . ?
C11 Ag5 Ag7 54.05(13) 4_566 . ?
O32 Ag5 Ag7 116.36(12) . . ?
C1 Ag5 Ag7 50.54(13) . . ?
N1 Ag5 Ag2 149.21(18) . 4_566 ?
C11 Ag5 Ag2 44.16(13) 4_566 4_566 ?
O32 Ag5 Ag2 83.98(11) . 4_566 ?
C1 Ag5 Ag2 97.22(13) . 4_566 ?
Ag7 Ag5 Ag2 58.098(17) . 4_566 ?
N1 Ag5 Ag1 130.15(17) . . ?
C11 Ag5 Ag1 107.31(14) 4_566 . ?
O32 Ag5 Ag1 56.92(12) . . ?
C1 Ag5 Ag1 42.32(13) . . ?
Ag7 Ag5 Ag1 63.849(17) . . ?
Ag2 Ag5 Ag1 73.600(18) 4_566 . ?
O22 Ag6 C11 111.62(18) . . ?
O22 Ag6 C21 120.49(17) . . ?
C11 Ag6 C21 127.24(18) . . ?
O22 Ag6 C22 93.18(18) . . ?
C11 Ag6 C22 155.17(19) . . ?
C21 Ag6 C22 28.86(18) . . ?
O22 Ag6 C12 98.75(18) . . ?
C11 Ag6 C12 27.32(19) . . ?
C21 Ag6 C12 129.23(19) . . ?
C22 Ag6 C12 153.5(2) . . ?
O22 Ag6 Ag1 156.09(11) . . ?
C11 Ag6 Ag1 82.04(13) . . ?
C21 Ag6 Ag1 46.38(13) . . ?
C22 Ag6 Ag1 75.18(13) . . ?
C12 Ag6 Ag1 84.72(14) . . ?
O22 Ag6 Ag7 81.26(11) . 4_565 ?
C11 Ag6 Ag7 51.84(13) . 4_565 ?
C21 Ag6 Ag7 141.32(13) . 4_565 ?
C22 Ag6 Ag7 135.77(14) . 4_565 ?
C12 Ag6 Ag7 69.83(14) . 4_565 ?
Ag1 Ag6 Ag7 121.67(2) . 4_565 ?
O22 Ag6 Ag2 138.43(11) . . ?
C11 Ag6 Ag2 44.70(13) . . ?
C21 Ag6 Ag2 94.55(13) . . ?
C22 Ag6 Ag2 114.52(14) . . ?
C12 Ag6 Ag2 70.35(14) . . ?
Ag1 Ag6 Ag2 65.031(16) . . ?
Ag7 Ag6 Ag2 57.209(15) 4_565 . ?
O14 Ag7 O21 94.0(10) . . ?
O14 Ag7 C1 130.1(11) . . ?
O21 Ag7 C1 110.55(19) . . ?
O14 Ag7 C11 98.7(7) . 4_566 ?
O21 Ag7 C11 113.28(19) . 4_566 ?
C1 Ag7 C11 109.31(19) . 4_566 ?
O14 Ag7 Ag5 126.5(8) . . ?
O21 Ag7 Ag5 136.15(17) . . ?
C1 Ag7 Ag5 58.38(14) . . ?
C11 Ag7 Ag5 51.37(13) 4_566 . ?
O14 Ag7 Ag2 63.7(7) . 4_566 ?
O21 Ag7 Ag2 140.71(12) . 4_566 ?
C1 Ag7 Ag2 108.41(14) . 4_566 ?
C11 Ag7 Ag2 46.65(13) 4_566 4_566 ?
Ag5 Ag7 Ag2 64.510(18) . 4_566 ?
O14 Ag7 Ag6 65.1(10) . 4_566 ?
O21 Ag7 Ag6 79.48(12) . 4_566 ?
C1 Ag7 Ag6 158.79(14) . 4_566 ?
C11 Ag7 Ag6 49.87(13) 4_566 4_566 ?
Ag5 Ag7 Ag6 101.20(2) . 4_566 ?
Ag2 Ag7 Ag6 62.069(16) 4_566 4_566 ?
O14 Ag7 Ag8 94.0(8) . . ?
O21 Ag7 Ag8 84.63(12) . . ?
C1 Ag7 Ag8 48.72(14) . . ?
C11 Ag7 Ag8 157.04(13) 4_566 . ?
Ag5 Ag7 Ag8 105.83(2) . . ?
Ag2 Ag7 Ag8 126.41(2) 4_566 . ?
Ag6 Ag7 Ag8 152.47(2) 4_566 . ?
O14 Ag7 Ag1 92.5(12) . . ?
O21 Ag7 Ag1 141.17(12) . . ?
C1 Ag7 Ag1 41.83(14) . . ?
C11 Ag7 Ag1 103.41(13) 4_566 . ?
Ag5 Ag7 Ag1 61.798(17) . . ?
Ag2 Ag7 Ag1 75.228(18) 4_566 . ?
Ag6 Ag7 Ag1 137.00(2) 4_566 . ?
Ag8 Ag7 Ag1 56.735(16) . . ?
O301 Ag8 C1 117.8(2) . . ?
O301 Ag8 C31 115.8(2) . . ?
C1 Ag8 C31 124.64(19) . . ?
O301 Ag8 C32 92.3(2) . . ?
C1 Ag8 C32 149.92(19) . . ?
C31 Ag8 C32 28.00(18) . . ?
O301 Ag8 Ag2 144.54(15) . . ?
C1 Ag8 Ag2 80.76(14) . . ?
C31 Ag8 Ag2 46.46(13) . . ?
C32 Ag8 Ag2 74.44(13) . . ?
O301 Ag8 Ag1 148.71(15) . . ?
C1 Ag8 Ag1 45.15(14) . . ?
C31 Ag8 Ag1 91.05(13) . . ?
C32 Ag8 Ag1 107.70(13) . . ?
Ag2 Ag8 Ag1 65.956(17) . . ?
O301 Ag8 Ag7 85.73(15) . . ?
C1 Ag8 Ag7 49.19(14) . . ?
C31 Ag8 Ag7 148.39(13) . . ?
C32 Ag8 Ag7 140.02(13) . . ?
Ag2 Ag8 Ag7 125.49(2) . . ?
Ag1 Ag8 Ag7 63.422(17) . . ?
O301 Ag8 Ag3 133.83(16) . . ?
C1 Ag8 Ag3 101.33(14) . . ?
C31 Ag8 Ag3 44.15(13) . . ?
C32 Ag8 Ag3 51.47(13) . . ?
Ag2 Ag8 Ag3 60.714(17) . . ?
Ag1 Ag8 Ag3 56.608(17) . . ?
Ag7 Ag8 Ag3 104.25(3) . . ?
C2 C1 Ag1 162.2(5) . . ?
C2 C1 Ag8 100.4(5) . . ?
Ag1 C1 Ag8 83.6(2) . . ?
C2 C1 Ag7 107.2(5) . . ?
Ag1 C1 Ag7 90.5(2) . . ?
Ag8 C1 Ag7 82.09(19) . . ?
C2 C1 Ag5 101.2(5) . . ?
Ag1 C1 Ag5 82.33(19) . . ?
Ag8 C1 Ag5 149.4(3) . . ?
Ag7 C1 Ag5 71.08(15) . . ?
C1 C2 C3 178.7(8) . . ?
C6 C3 C2 116.4(11) . . ?
C6 C3 C4 117.7(12) . . ?
C2 C3 C4 110.4(7) . . ?
C2 C3 C5 109.9(8) . . ?
C4 C3 C5 116.4(10) . . ?
C12 C11 Ag2 155.8(5) . . ?
C12 C11 Ag5 107.3(4) . 4_565 ?
Ag2 C11 Ag5 86.8(2) . 4_565 ?
C12 C11 Ag6 90.0(4) . . ?
Ag2 C11 Ag6 85.12(18) . . ?
Ag5 C11 Ag6 152.7(3) 4_565 . ?
C12 C11 Ag7 123.6(5) . 4_565 ?
Ag2 C11 Ag7 78.58(18) . 4_565 ?
Ag5 C11 Ag7 74.58(16) 4_565 4_565 ?
Ag6 C11 Ag7 78.29(16) . 4_565 ?
C11 C12 C13 177.9(7) . . ?
C11 C12 Ag6 62.6(4) . . ?
C13 C12 Ag6 117.1(5) . . ?
C14 C13 C12 111.5(6) . . ?
C14 C13 C15 115.7(7) . . ?
C12 C13 C15 110.1(6) . . ?
C22 C21 Ag1 156.9(5) . . ?
C22 C21 Ag4 122.8(4) . . ?
Ag1 C21 Ag4 79.87(18) . . ?
C22 C21 Ag3 102.6(4) . . ?
Ag1 C21 Ag3 82.26(18) . . ?
Ag4 C21 Ag3 85.62(18) . . ?
C22 C21 Ag6 78.1(4) . . ?
Ag1 C21 Ag6 79.25(17) . . ?
Ag4 C21 Ag6 159.1(3) . . ?
Ag3 C21 Ag6 91.09(18) . . ?
C21 C22 C23 174.5(6) . . ?
C21 C22 Ag6 73.1(4) . . ?
C23 C22 Ag6 112.4(4) . . ?
C22 C23 C24 110.6(5) . . ?
C22 C23 C25 111.1(6) . . ?
C24 C23 C25 112.3(6) . . ?
C32 C31 Ag2 162.4(5) . . ?
C32 C31 Ag4 107.8(4) . 4_565 ?
Ag2 C31 Ag4 85.33(19) . 4_565 ?
C32 C31 Ag3 91.7(4) . . ?
Ag2 C31 Ag3 90.37(19) . . ?
Ag4 C31 Ag3 123.9(2) 4_565 . ?
C32 C31 Ag8 83.6(4) . . ?
Ag2 C31 Ag8 78.93(18) . . ?
Ag4 C31 Ag8 143.7(3) 4_565 . ?
Ag3 C31 Ag8 89.01(18) . . ?
C31 C32 C33 172.9(6) . . ?
C31 C32 Ag8 68.4(4) . . ?
C33 C32 Ag8 115.5(4) . . ?
C31 C32 Ag3 60.8(3) . . ?
C33 C32 Ag3 125.0(4) . . ?
Ag8 C32 Ag3 78.67(16) . . ?
C32 C33 C35 111.3(5) . . ?
C32 C33 C34 109.1(5) . . ?
C35 C33 C34 111.2(6) . . ?
C103 O1 Ag3 125.0(4) . . ?
C103 O2 Ag4 125.9(4) . . ?
O2 C103 O1 131.4(6) . . ?
O2 C103 C104 115.8(5) . . ?
O1 C103 C104 112.8(5) . . ?
F6 C104 F7 112.1(7) . . ?
F6 C104 F5 101.6(7) . . ?
F7 C104 F5 105.7(6) . . ?
F7 C104 F9 89.6(10) . . ?
F5 C104 F9 125.0(11) . . ?
F6 C104 C103 114.0(6) . . ?
F7 C104 C103 112.1(5) . . ?
F5 C104 C103 110.5(5) . . ?
F9 C104 C103 111.5(11) . . ?
C113 O14 Ag7 115(3) . . ?
O11 C113 O12 126.4(10) . . ?
O14 C113 O13 126(3) . . ?
O14 C113 C114 144(2) . . ?
O11 C113 C114 121.3(8) . . ?
O12 C113 C114 112.1(7) . . ?
O13 C113 C114 89(2) . . ?
F15 C114 F16 105.3(7) . . ?
F16 C114 F20 74.8(11) . . ?
F15 C114 F17 112.3(9) . . ?
F16 C114 F17 104.4(8) . . ?
F16 C114 F18 136.3(12) . . ?
F20 C114 F18 66.0(14) . . ?
F15 C114 C113 114.9(7) . . ?
F16 C114 C113 110.1(7) . . ?
F20 C114 C113 111.6(13) . . ?
F17 C114 C113 109.2(7) . . ?
F18 C114 C113 101.9(11) . . ?
C114 F16 F20 53.2(6) . . ?
C114 F18 F20 56.4(9) . . ?
C114 F20 F18 57.6(9) . . ?
C114 F20 F16 52.0(8) . . ?
F18 F20 F16 107.2(13) . . ?
C122 O21 Ag7 123.7(4) . . ?
O22 C122 O21 130.5(6) 4_566 . ?
O22 C122 C124 114.6(6) 4_566 . ?
O21 C122 C124 114.9(6) . . ?
C122 O22 Ag6 123.0(4) 4_565 . ?
F27 C124 F25 113.8(10) . . ?
F28 C124 F30 112.5(17) . . ?
F27 C124 F26 102.2(9) . . ?
F25 C124 F26 103.3(9) . . ?
F28 C124 F29 100.4(12) . . ?
F30 C124 F29 102.0(14) . . ?
F27 C124 C122 114.3(7) . . ?
F25 C124 C122 110.3(8) . . ?
F28 C124 C122 113.6(10) . . ?
F30 C124 C122 114.6(12) . . ?
F26 C124 C122 112.2(7) . . ?
F29 C124 C122 112.3(7) . . ?
O31 C133 O32 129.9(6) . . ?
O31 C133 C134 116.7(6) . . ?
O32 C133 C134 113.4(6) . . ?
C133 O32 Ag5 117.3(4) . . ?
F36 C134 F38 85.3(13) . . ?
F36 C134 F35 103.9(6) . . ?
F38 C134 F35 127.9(13) . . ?
F36 C134 F37 111.9(8) . . ?
F35 C134 F37 101.4(8) . . ?
F36 C134 C133 114.3(6) . . ?
F38 C134 C133 108.3(13) . . ?
F35 C134 C133 113.4(6) . . ?
F37 C134 C133 111.0(7) . . ?
C202 N1 Ag5 169.1(6) . . ?
N1 C202 C203 179.0(8) . . ?
C302 O301 Ag8 125.1(5) . . ?

_refine_diff_density_max         3.076
_refine_diff_density_min         -3.639
_refine_diff_density_rms         0.166



