# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 2024383'
loop_
_audit_author_name
_audit_author_address
'Naofumi Hara'
;Kyoto University
Japan
;
_audit_update_record             
;
2021-01-15 deposited with the CCDC.	2021-05-04 downloaded from the CCDC.
;
_audit_creation_date             2019-09-21
_audit_creation_method           
;
Olex2 1.3
(compiled 2019.09.11 svn.r3662 for OlexSys, GUI svn.r5938)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        
(N,N-bis(2-(diphenylphosphinomethylamido)phenyl)methylamine)-(dimethyl(phenyl)silyl)-(μ-pyridin-2-yl)-aluminium-rhodium
_chemical_formula_moiety         'C52 H50 Al N4 P2 Rh Si'
_chemical_formula_sum            'C52 H50 Al N4 P2 Rh Si'
_chemical_formula_weight         950.88
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Al Al 0.0645 0.0514 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   29.694(5)
_cell_length_b                   10.5922(16)
_cell_length_c                   32.967(5)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     10369(3)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    22763
_cell_measurement_temperature    143.15
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_shelx_estimated_absorpt_T_max   0.977
_shelx_estimated_absorpt_T_min   0.950
_exptl_absorpt_coefficient_mu    0.467
_exptl_absorpt_correction_T_max  1.00
_exptl_absorpt_correction_T_min  0.815
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear yellow'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   .
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.218
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             3936
_exptl_crystal_preparation       ?
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: dichloromethane/pentane'
_exptl_crystal_size_max          0.111
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.05
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0743
_diffrn_reflns_av_unetI/netI     0.0623
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.986
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -38
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       42
_diffrn_reflns_limit_l_min       -42
_diffrn_reflns_number            72398
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.986
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.485
_diffrn_reflns_theta_min         3.003
_diffrn_ambient_temperature      143.15
_diffrn_detector                 CCD
_diffrn_detector_area_resol_mean 28.5714
_diffrn_detector_type            'Rigaku Saturn724+'
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device       'AFC12 (Right): Kappa 3 circle'
_diffrn_measurement_device_type  'Rigaku Saturn724+ (4x4 bin mode)'
_diffrn_measurement_method       'profile data from ω-scans'
_diffrn_measurement_specimen_support 'Mitegen 50um'
_diffrn_radiation_collimation    0.3
_diffrn_radiation_monochromator  Confocal
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_source                   'Rotating Anode'
_diffrn_source_current           24.0
_diffrn_source_power             1.2
_diffrn_source_target            Mo
_diffrn_source_type              'Rotating Anode'
_diffrn_source_voltage           50.0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                9251
_reflns_number_total             11716
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrystalClear-SM Expert 2.0 r7 (Rigaku, 2011)
;
_computing_data_collection       
;
CrystalClear-SM Expert 2.0 r7 (Rigaku, 2011)
;
_computing_data_reduction        
;
CrystalClear-SM Expert 2.0 r7 (Rigaku, 2011)
;
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.640
_refine_diff_density_min         -0.776
_refine_diff_density_rms         0.085
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.094
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     553
_refine_ls_number_reflns         11716
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0797
_refine_ls_R_factor_gt           0.0611
_refine_ls_restrained_S_all      1.094
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0285P)²+19.6889P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1147
_refine_ls_wR_factor_ref         0.1239
_refine_special_details          'solvent mask'
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C00F(H00A,H00B), C00H(H00C,H00D)
2.b Aromatic/amide H refined with riding coordinates:
 C00I(H00I), C00L(H00L), C00N(H00N), C00O(H00O), C00R(H00R), C00T(H00T),
 C00U(H00U), C00V(H00V), C00W(H00W), C00X(H00X), C00Y(H00Y), C01A(H01A),
 C01B(H01B), C01C(H01C), C01D(H01D), C01E(H01E), C01F(H01F), C01G(H01G),
 C01H(H01H), C01I(H01I), C01J(H01J), C01K(H01K), C01L(H01L), C01M(H01M),
 C01N(H01N), C01O(H01O), C01P(H01P), C010(H010), C011(H011), C013(H013),
 C014(H014), C015(H015), C016(H016), C017(H017), C018(H018), C019(H019),
 C21(H21)
2.c Idealised Me refined as rotating group:
 C00Q(H00E,H00F,H00G), C00S(H00H,H00J,H00K), C012(H01Q,H01R,H01S)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.40835(2) 0.48744(2) 0.36203(2) 0.02307(8) Uani 1 1 d . . . . .
P2 P 0.42499(3) 0.48488(9) 0.42868(3) 0.02440(19) Uani 1 1 d . . . . .
P1 P 0.39037(3) 0.27869(9) 0.34996(3) 0.0256(2) Uani 1 1 d . . . . .
Si1 Si 0.42085(4) 0.71193(9) 0.35842(3) 0.0298(2) Uani 1 1 d . . . . .
Al1 Al 0.48652(4) 0.41387(10) 0.35175(3) 0.0246(2) Uani 1 1 d . . . . .
N1 N 0.47953(10) 0.2385(3) 0.35609(9) 0.0267(6) Uani 1 1 d . . . . .
N4 N 0.47134(10) 0.4762(3) 0.29697(8) 0.0284(7) Uani 1 1 d . . . . .
N2 N 0.55760(10) 0.3667(3) 0.34413(9) 0.0292(7) Uani 1 1 d . . . . .
N3 N 0.51035(10) 0.4906(3) 0.39819(8) 0.0269(6) Uani 1 1 d . . . . .
C19 C 0.55963(12) 0.2404(3) 0.36307(10) 0.0277(8) Uani 1 1 d . . . . .
C14 C 0.51832(13) 0.1765(3) 0.36796(10) 0.0285(8) Uani 1 1 d . . . . .
C34 C 0.39699(13) 0.5829(3) 0.46698(10) 0.0297(8) Uani 1 1 d . . . . .
C13 C 0.43726(12) 0.1719(3) 0.36287(11) 0.0284(8) Uani 1 1 d . . . . .
H00A H 0.434981 0.145706 0.391625 0.034 Uiso 1 1 calc R U . . .
H00B H 0.435983 0.095339 0.345702 0.034 Uiso 1 1 calc R U . . .
C28 C 0.42805(13) 0.3340(3) 0.45633(10) 0.0310(8) Uani 1 1 d . . . . .
C27 C 0.48344(12) 0.5418(3) 0.43143(10) 0.0281(8) Uani 1 1 d . . . . .
H00C H 0.483719 0.635168 0.430090 0.034 Uiso 1 1 calc R U . . .
H00D H 0.496868 0.516153 0.457653 0.034 Uiso 1 1 calc R U . . .
C29 C 0.46808(14) 0.2658(4) 0.45935(11) 0.0350(9) Uani 1 1 d . . . . .
H00I H 0.495219 0.300411 0.448910 0.042 Uiso 1 1 calc R U . . .
C7 C 0.37960(13) 0.2429(3) 0.29669(11) 0.0299(8) Uani 1 1 d . . . . .
C1 C 0.34211(12) 0.2073(3) 0.37539(11) 0.0286(8) Uani 1 1 d . . . . .
C50 C 0.41820(15) 0.5396(4) 0.23046(11) 0.0372(10) Uani 1 1 d . . . . .
H00L H 0.399869 0.558850 0.207662 0.045 Uiso 1 1 calc R U . . .
C26 C 0.55556(12) 0.5231(3) 0.39764(11) 0.0288(8) Uani 1 1 d . . . . .
C6 C 0.31242(13) 0.2828(4) 0.39640(12) 0.0362(9) Uani 1 1 d . . . . .
H00N H 0.316757 0.371681 0.396604 0.043 Uiso 1 1 calc R U . . .
C18 C 0.60021(14) 0.1839(4) 0.37361(11) 0.0360(9) Uani 1 1 d . . . . .
H00O H 0.627664 0.228509 0.369907 0.043 Uiso 1 1 calc R U . . .
C21 C 0.58195(13) 0.4623(4) 0.36820(11) 0.0304(8) Uani 1 1 d . . . . .
C20 C 0.57669(13) 0.3544(4) 0.30229(11) 0.0336(9) Uani 1 1 d . . . . .
H00E H 0.556541 0.302534 0.285657 0.050 Uiso 1 1 calc R U . . .
H00F H 0.606378 0.314252 0.303746 0.050 Uiso 1 1 calc R U . . .
H00G H 0.579640 0.438343 0.290079 0.050 Uiso 1 1 calc R U . . .
C33 C 0.38896(14) 0.2797(4) 0.47197(12) 0.0383(9) Uani 1 1 d . . . . .
H00R H 0.361398 0.325047 0.470572 0.046 Uiso 1 1 calc R U . . .
C40 C 0.47194(14) 0.7680(4) 0.32965(13) 0.0415(10) Uani 1 1 d . . . . .
H00H H 0.499260 0.740594 0.343810 0.062 Uiso 1 1 calc R U . . .
H00J H 0.471525 0.860350 0.327940 0.062 Uiso 1 1 calc R U . . .
H00K H 0.471588 0.732170 0.302242 0.062 Uiso 1 1 calc R U . . .
C8 C 0.41479(13) 0.2113(3) 0.27044(11) 0.0316(8) Uani 1 1 d . . . . .
H00T H 0.444014 0.195723 0.281060 0.038 Uiso 1 1 calc R U . . .
C25 C 0.57675(13) 0.6101(4) 0.42307(12) 0.0343(9) Uani 1 1 d . . . . .
H00U H 0.559960 0.651038 0.443784 0.041 Uiso 1 1 calc R U . . .
C30 C 0.46852(16) 0.1470(4) 0.47761(13) 0.0468(11) Uani 1 1 d . . . . .
H00V H 0.496041 0.101863 0.479921 0.056 Uiso 1 1 calc R U . . .
C12 C 0.33687(13) 0.2612(4) 0.28045(12) 0.0364(9) Uani 1 1 d . . . . .
H00W H 0.312389 0.280633 0.297919 0.044 Uiso 1 1 calc R U . . .
C35 C 0.41908(15) 0.6288(4) 0.50028(12) 0.0439(11) Uani 1 1 d . . . . .
H00X H 0.449686 0.606398 0.504601 0.053 Uiso 1 1 calc R U . . .
C15 C 0.52000(14) 0.0535(4) 0.38470(11) 0.0326(8) Uani 1 1 d . . . . .
H00Y H 0.492783 0.008271 0.388981 0.039 Uiso 1 1 calc R U . . .
C42 C 0.37010(14) 0.7677(4) 0.32845(11) 0.0346(9) Uani 1 1 d . . . . .
C32 C 0.38955(17) 0.1608(4) 0.48953(13) 0.0472(11) Uani 1 1 d . . . . .
H01A H 0.362487 0.124777 0.499650 0.057 Uiso 1 1 calc R U . . .
C11 C 0.32970(16) 0.2514(4) 0.23932(13) 0.0486(11) Uani 1 1 d . . . . .
H01B H 0.300364 0.264615 0.228626 0.058 Uiso 1 1 calc R U . . .
C47 C 0.32793(15) 0.7186(4) 0.33776(14) 0.0489(11) Uani 1 1 d . . . . .
H01C H 0.325465 0.657691 0.358804 0.059 Uiso 1 1 calc R U . . .
C43 C 0.37174(15) 0.8562(4) 0.29702(12) 0.0396(10) Uani 1 1 d . . . . .
H01D H 0.400042 0.890888 0.289556 0.048 Uiso 1 1 calc R U . . .
C49 C 0.46354(15) 0.5144(4) 0.22560(11) 0.0404(10) Uani 1 1 d . . . . .
H01E H 0.477085 0.519610 0.199547 0.048 Uiso 1 1 calc R U . . .
C10 C 0.36479(17) 0.2227(4) 0.21354(13) 0.0485(12) Uani 1 1 d . . . . .
H01F H 0.359625 0.216814 0.185165 0.058 Uiso 1 1 calc R U . . .
C36 C 0.39778(16) 0.7073(5) 0.52777(13) 0.0512(12) Uani 1 1 d . . . . .
H01G H 0.413975 0.740150 0.550259 0.061 Uiso 1 1 calc R U . . .
C23 C 0.64695(14) 0.5782(4) 0.38883(14) 0.0450(11) Uani 1 1 d . . . . .
H01H H 0.677956 0.597946 0.385672 0.054 Uiso 1 1 calc R U . . .
C4 C 0.26963(15) 0.1031(4) 0.41667(16) 0.0538(13) Uani 1 1 d . . . . .
H01I H 0.244842 0.067379 0.430824 0.065 Uiso 1 1 calc R U . . .
C39 C 0.35260(15) 0.6154(5) 0.46189(14) 0.0559(13) Uani 1 1 d . . . . .
H01J H 0.336776 0.585688 0.438731 0.067 Uiso 1 1 calc R U . . .
C44 C 0.33348(17) 0.8950(5) 0.27637(14) 0.0536(13) Uani 1 1 d . . . . .
H01K H 0.335784 0.955122 0.255081 0.064 Uiso 1 1 calc R U . . .
C3 C 0.29881(17) 0.0260(5) 0.39561(17) 0.0612(14) Uani 1 1 d . . . . .
H01L H 0.294394 -0.062787 0.395519 0.073 Uiso 1 1 calc R U . . .
C45 C 0.29258(18) 0.8465(6) 0.28676(17) 0.0691(16) Uani 1 1 d . . . . .
H01M H 0.266207 0.874610 0.273171 0.083 Uiso 1 1 calc R U . . .
C37 C 0.35354(17) 0.7373(5) 0.52260(14) 0.0611(14) Uani 1 1 d . . . . .
H01N H 0.338771 0.790592 0.541590 0.073 Uiso 1 1 calc R U . . .
C46 C 0.28926(17) 0.7559(6) 0.31724(17) 0.0661(15) Uani 1 1 d . . . . .
H01O H 0.260897 0.719989 0.323914 0.079 Uiso 1 1 calc R U . . .
C38 C 0.33040(16) 0.6905(6) 0.48988(16) 0.0747(19) Uani 1 1 d . . . . .
H01P H 0.299370 0.709534 0.486440 0.090 Uiso 1 1 calc R U . . .
C17 C 0.60079(15) 0.0620(4) 0.38960(12) 0.0388(10) Uani 1 1 d . . . . .
H010 H 0.628539 0.023355 0.396755 0.047 Uiso 1 1 calc R U . . .
C9 C 0.40736(15) 0.2024(4) 0.22890(12) 0.0404(10) Uani 1 1 d . . . . .
H011 H 0.431542 0.182425 0.211161 0.048 Uiso 1 1 calc R U . . .
C41 C 0.41901(15) 0.8219(4) 0.40415(12) 0.0422(10) Uani 1 1 d . . . . .
H01Q H 0.391350 0.806480 0.419593 0.063 Uiso 1 1 calc R U . . .
H01R H 0.419544 0.909757 0.394885 0.063 Uiso 1 1 calc R U . . .
H01S H 0.445203 0.805870 0.421497 0.063 Uiso 1 1 calc R U . . .
C24 C 0.62190(14) 0.6372(4) 0.41837(13) 0.0436(10) Uani 1 1 d . . . . .
H013 H 0.635829 0.697271 0.435704 0.052 Uiso 1 1 calc R U . . .
C48 C 0.48887(15) 0.4815(4) 0.25897(11) 0.0371(9) Uani 1 1 d . . . . .
H014 H 0.519802 0.461703 0.255257 0.045 Uiso 1 1 calc R U . . .
C22 C 0.62683(13) 0.4900(4) 0.36375(12) 0.0376(9) Uani 1 1 d . . . . .
H015 H 0.644071 0.448573 0.343447 0.045 Uiso 1 1 calc R U . . .
C5 C 0.27632(14) 0.2313(4) 0.41725(13) 0.0451(11) Uani 1 1 d . . . . .
H016 H 0.256300 0.284379 0.431878 0.054 Uiso 1 1 calc R U . . .
C2 C 0.33433(16) 0.0780(4) 0.37471(15) 0.0488(12) Uani 1 1 d . . . . .
H017 H 0.353832 0.024740 0.359592 0.059 Uiso 1 1 calc R U . . .
C16 C 0.56073(14) -0.0019(4) 0.39494(11) 0.0368(9) Uani 1 1 d . . . . .
H018 H 0.561073 -0.085048 0.405772 0.044 Uiso 1 1 calc R U . . .
C31 C 0.42936(18) 0.0949(4) 0.49230(13) 0.0515(12) Uani 1 1 d . . . . .
H019 H 0.429805 0.013490 0.504349 0.062 Uiso 1 1 calc R U . . .
C52 C 0.42612(12) 0.5049(3) 0.30272(11) 0.0286(8) Uani 1 1 d . . . . .
C51 C 0.39989(13) 0.5365(3) 0.26912(10) 0.0293(8) Uani 1 1 d . . . . .
H21 H 0.368941 0.556103 0.272791 0.035 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 P2 2.2523(9) . ?
Rh1 P1 2.3092(10) . ?
Rh1 Si1 2.4095(11) . ?
Rh1 Al1 2.4717(12) . ?
Rh1 C52 2.034(4) . ?
P2 C34 1.834(4) . ?
P2 C28 1.842(4) . ?
P2 C27 1.840(4) . ?
P1 C13 1.844(4) . ?
P1 C7 1.825(4) . ?
P1 C1 1.824(4) . ?
Si1 C40 1.885(4) . ?
Si1 C42 1.896(4) . ?
Si1 C41 1.906(4) . ?
Al1 N1 1.875(3) . ?
Al1 N4 1.975(3) . ?
Al1 N2 2.183(3) . ?
Al1 N3 1.872(3) . ?
N1 C14 1.382(4) . ?
N1 C13 1.457(4) . ?
N4 C48 1.358(4) . ?
N4 C52 1.390(5) . ?
N2 C19 1.478(4) . ?
N2 C21 1.476(5) . ?
N2 C20 1.497(4) . ?
N3 C27 1.461(4) . ?
N3 C26 1.386(5) . ?
C19 C14 1.410(5) . ?
C19 C18 1.390(5) . ?
C14 C15 1.415(5) . ?
C34 C35 1.369(5) . ?
C34 C39 1.372(6) . ?
C13 H00A 0.9900 . ?
C13 H00B 0.9900 . ?
C28 C29 1.395(5) . ?
C28 C33 1.394(5) . ?
C27 H00C 0.9900 . ?
C27 H00D 0.9900 . ?
C29 H00I 0.9500 . ?
C29 C30 1.394(5) . ?
C7 C8 1.398(5) . ?
C7 C12 1.391(5) . ?
C1 C6 1.377(5) . ?
C1 C2 1.389(5) . ?
C50 H00L 0.9500 . ?
C50 C49 1.382(6) . ?
C50 C51 1.386(5) . ?
C26 C21 1.404(5) . ?
C26 C25 1.396(5) . ?
C6 H00N 0.9500 . ?
C6 C5 1.385(5) . ?
C18 H00O 0.9500 . ?
C18 C17 1.395(6) . ?
C21 C22 1.372(5) . ?
C20 H00E 0.9800 . ?
C20 H00F 0.9800 . ?
C20 H00G 0.9800 . ?
C33 H00R 0.9500 . ?
C33 C32 1.387(6) . ?
C40 H00H 0.9800 . ?
C40 H00J 0.9800 . ?
C40 H00K 0.9800 . ?
C8 H00T 0.9500 . ?
C8 C9 1.390(5) . ?
C25 H00U 0.9500 . ?
C25 C24 1.380(6) . ?
C30 H00V 0.9500 . ?
C30 C31 1.375(6) . ?
C12 H00W 0.9500 . ?
C12 C11 1.376(5) . ?
C35 H00X 0.9500 . ?
C35 C36 1.383(5) . ?
C15 H00Y 0.9500 . ?
C15 C16 1.386(5) . ?
C42 C47 1.390(6) . ?
C42 C43 1.398(5) . ?
C32 H01A 0.9500 . ?
C32 C31 1.375(6) . ?
C11 H01B 0.9500 . ?
C11 C10 1.379(6) . ?
C47 H01C 0.9500 . ?
C47 C46 1.390(6) . ?
C43 H01D 0.9500 . ?
C43 C44 1.387(6) . ?
C49 H01E 0.9500 . ?
C49 C48 1.377(5) . ?
C10 H01F 0.9500 . ?
C10 C9 1.379(6) . ?
C36 H01G 0.9500 . ?
C36 C37 1.362(6) . ?
C23 H01H 0.9500 . ?
C23 C24 1.375(6) . ?
C23 C22 1.383(6) . ?
C4 H01I 0.9500 . ?
C4 C3 1.378(6) . ?
C4 C5 1.372(6) . ?
C39 H01J 0.9500 . ?
C39 C38 1.386(6) . ?
C44 H01K 0.9500 . ?
C44 C45 1.363(7) . ?
C3 H01L 0.9500 . ?
C3 C2 1.375(6) . ?
C45 H01M 0.9500 . ?
C45 C46 1.393(7) . ?
C37 H01N 0.9500 . ?
C37 C38 1.371(6) . ?
C46 H01O 0.9500 . ?
C38 H01P 0.9500 . ?
C17 H010 0.9500 . ?
C17 C16 1.380(6) . ?
C9 H011 0.9500 . ?
C41 H01Q 0.9800 . ?
C41 H01R 0.9800 . ?
C41 H01S 0.9800 . ?
C24 H013 0.9500 . ?
C48 H014 0.9500 . ?
C22 H015 0.9500 . ?
C5 H016 0.9500 . ?
C2 H017 0.9500 . ?
C16 H018 0.9500 . ?
C31 H019 0.9500 . ?
C52 C51 1.395(5) . ?
C51 H21 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2 Rh1 P1 101.97(3) . . ?
P2 Rh1 Si1 91.51(3) . . ?
P2 Rh1 Al1 85.65(3) . . ?
P1 Rh1 Si1 166.40(4) . . ?
P1 Rh1 Al1 83.78(4) . . ?
Si1 Rh1 Al1 99.19(4) . . ?
C52 Rh1 P2 151.91(11) . . ?
C52 Rh1 P1 88.94(10) . . ?
C52 Rh1 Si1 79.78(10) . . ?
C52 Rh1 Al1 69.72(11) . . ?
C34 P2 Rh1 124.42(12) . . ?
C34 P2 C28 99.97(16) . . ?
C34 P2 C27 102.03(16) . . ?
C28 P2 Rh1 120.26(12) . . ?
C27 P2 Rh1 104.53(11) . . ?
C27 P2 C28 102.32(17) . . ?
C13 P1 Rh1 111.89(12) . . ?
C7 P1 Rh1 113.92(12) . . ?
C7 P1 C13 103.13(17) . . ?
C1 P1 Rh1 119.95(12) . . ?
C1 P1 C13 103.46(16) . . ?
C1 P1 C7 102.62(17) . . ?
C40 Si1 Rh1 117.37(13) . . ?
C40 Si1 C42 106.22(19) . . ?
C40 Si1 C41 103.21(19) . . ?
C42 Si1 Rh1 102.16(13) . . ?
C42 Si1 C41 101.49(18) . . ?
C41 Si1 Rh1 124.01(13) . . ?
N1 Al1 Rh1 101.42(10) . . ?
N1 Al1 N4 112.07(13) . . ?
N1 Al1 N2 83.63(13) . . ?
N4 Al1 Rh1 78.79(9) . . ?
N4 Al1 N2 101.07(12) . . ?
N2 Al1 Rh1 174.64(10) . . ?
N3 Al1 Rh1 96.08(10) . . ?
N3 Al1 N1 114.18(14) . . ?
N3 Al1 N4 133.54(14) . . ?
N3 Al1 N2 80.09(12) . . ?
C14 N1 Al1 113.6(2) . . ?
C14 N1 C13 116.4(3) . . ?
C13 N1 Al1 125.9(2) . . ?
C48 N4 Al1 140.3(3) . . ?
C48 N4 C52 119.2(3) . . ?
C52 N4 Al1 99.7(2) . . ?
C19 N2 Al1 101.4(2) . . ?
C19 N2 C20 107.1(3) . . ?
C21 N2 Al1 104.8(2) . . ?
C21 N2 C19 112.0(3) . . ?
C21 N2 C20 111.7(3) . . ?
C20 N2 Al1 119.5(2) . . ?
C27 N3 Al1 124.6(2) . . ?
C26 N3 Al1 117.6(2) . . ?
C26 N3 C27 116.6(3) . . ?
C14 C19 N2 116.6(3) . . ?
C18 C19 N2 122.0(3) . . ?
C18 C19 C14 121.3(3) . . ?
N1 C14 C19 117.7(3) . . ?
N1 C14 C15 125.2(3) . . ?
C19 C14 C15 117.1(3) . . ?
C35 C34 P2 122.4(3) . . ?
C35 C34 C39 118.0(4) . . ?
C39 C34 P2 119.6(3) . . ?
P1 C13 H00A 110.0 . . ?
P1 C13 H00B 110.0 . . ?
N1 C13 P1 108.6(2) . . ?
N1 C13 H00A 110.0 . . ?
N1 C13 H00B 110.0 . . ?
H00A C13 H00B 108.4 . . ?
C29 C28 P2 121.8(3) . . ?
C33 C28 P2 120.0(3) . . ?
C33 C28 C29 118.0(4) . . ?
P2 C27 H00C 109.5 . . ?
P2 C27 H00D 109.5 . . ?
N3 C27 P2 110.9(2) . . ?
N3 C27 H00C 109.5 . . ?
N3 C27 H00D 109.5 . . ?
H00C C27 H00D 108.0 . . ?
C28 C29 H00I 119.8 . . ?
C30 C29 C28 120.4(4) . . ?
C30 C29 H00I 119.8 . . ?
C8 C7 P1 121.0(3) . . ?
C12 C7 P1 120.1(3) . . ?
C12 C7 C8 118.5(3) . . ?
C6 C1 P1 119.6(3) . . ?
C6 C1 C2 118.3(4) . . ?
C2 C1 P1 122.1(3) . . ?
C49 C50 H00L 120.5 . . ?
C49 C50 C51 118.9(4) . . ?
C51 C50 H00L 120.5 . . ?
N3 C26 C21 115.8(3) . . ?
N3 C26 C25 126.4(3) . . ?
C25 C26 C21 117.8(3) . . ?
C1 C6 H00N 119.5 . . ?
C1 C6 C5 121.0(4) . . ?
C5 C6 H00N 119.5 . . ?
C19 C18 H00O 119.9 . . ?
C19 C18 C17 120.2(4) . . ?
C17 C18 H00O 119.9 . . ?
C26 C21 N2 114.4(3) . . ?
C22 C21 N2 124.4(3) . . ?
C22 C21 C26 121.2(3) . . ?
N2 C20 H00E 109.5 . . ?
N2 C20 H00F 109.5 . . ?
N2 C20 H00G 109.5 . . ?
H00E C20 H00F 109.5 . . ?
H00E C20 H00G 109.5 . . ?
H00F C20 H00G 109.5 . . ?
C28 C33 H00R 119.4 . . ?
C32 C33 C28 121.2(4) . . ?
C32 C33 H00R 119.4 . . ?
Si1 C40 H00H 109.5 . . ?
Si1 C40 H00J 109.5 . . ?
Si1 C40 H00K 109.5 . . ?
H00H C40 H00J 109.5 . . ?
H00H C40 H00K 109.5 . . ?
H00J C40 H00K 109.5 . . ?
C7 C8 H00T 119.8 . . ?
C9 C8 C7 120.5(4) . . ?
C9 C8 H00T 119.8 . . ?
C26 C25 H00U 119.7 . . ?
C24 C25 C26 120.5(4) . . ?
C24 C25 H00U 119.7 . . ?
C29 C30 H00V 119.8 . . ?
C31 C30 C29 120.4(4) . . ?
C31 C30 H00V 119.8 . . ?
C7 C12 H00W 119.7 . . ?
C11 C12 C7 120.7(4) . . ?
C11 C12 H00W 119.7 . . ?
C34 C35 H00X 119.3 . . ?
C34 C35 C36 121.3(4) . . ?
C36 C35 H00X 119.3 . . ?
C14 C15 H00Y 119.5 . . ?
C16 C15 C14 121.0(4) . . ?
C16 C15 H00Y 119.5 . . ?
C47 C42 Si1 119.0(3) . . ?
C47 C42 C43 116.5(4) . . ?
C43 C42 Si1 124.6(3) . . ?
C33 C32 H01A 120.0 . . ?
C31 C32 C33 119.9(4) . . ?
C31 C32 H01A 120.0 . . ?
C12 C11 H01B 119.8 . . ?
C12 C11 C10 120.5(4) . . ?
C10 C11 H01B 119.8 . . ?
C42 C47 H01C 119.0 . . ?
C42 C47 C46 122.0(4) . . ?
C46 C47 H01C 119.0 . . ?
C42 C43 H01D 118.8 . . ?
C44 C43 C42 122.3(4) . . ?
C44 C43 H01D 118.8 . . ?
C50 C49 H01E 120.4 . . ?
C48 C49 C50 119.2(4) . . ?
C48 C49 H01E 120.4 . . ?
C11 C10 H01F 120.0 . . ?
C9 C10 C11 120.1(4) . . ?
C9 C10 H01F 120.0 . . ?
C35 C36 H01G 120.0 . . ?
C37 C36 C35 120.0(4) . . ?
C37 C36 H01G 120.0 . . ?
C24 C23 H01H 120.1 . . ?
C24 C23 C22 119.8(4) . . ?
C22 C23 H01H 120.1 . . ?
C3 C4 H01I 119.9 . . ?
C5 C4 H01I 119.9 . . ?
C5 C4 C3 120.1(4) . . ?
C34 C39 H01J 119.4 . . ?
C34 C39 C38 121.3(4) . . ?
C38 C39 H01J 119.4 . . ?
C43 C44 H01K 120.2 . . ?
C45 C44 C43 119.6(4) . . ?
C45 C44 H01K 120.2 . . ?
C4 C3 H01L 120.1 . . ?
C2 C3 C4 119.9(4) . . ?
C2 C3 H01L 120.1 . . ?
C44 C45 H01M 119.9 . . ?
C44 C45 C46 120.3(5) . . ?
C46 C45 H01M 119.9 . . ?
C36 C37 H01N 120.1 . . ?
C36 C37 C38 119.8(4) . . ?
C38 C37 H01N 120.1 . . ?
C47 C46 C45 119.2(5) . . ?
C47 C46 H01O 120.4 . . ?
C45 C46 H01O 120.4 . . ?
C39 C38 H01P 120.2 . . ?
C37 C38 C39 119.5(4) . . ?
C37 C38 H01P 120.2 . . ?
C18 C17 H010 120.3 . . ?
C16 C17 C18 119.5(4) . . ?
C16 C17 H010 120.3 . . ?
C8 C9 H011 120.1 . . ?
C10 C9 C8 119.8(4) . . ?
C10 C9 H011 120.1 . . ?
Si1 C41 H01Q 109.5 . . ?
Si1 C41 H01R 109.5 . . ?
Si1 C41 H01S 109.5 . . ?
H01Q C41 H01R 109.5 . . ?
H01Q C41 H01S 109.5 . . ?
H01R C41 H01S 109.5 . . ?
C25 C24 H013 119.6 . . ?
C23 C24 C25 120.7(4) . . ?
C23 C24 H013 119.6 . . ?
N4 C48 C49 122.5(4) . . ?
N4 C48 H014 118.7 . . ?
C49 C48 H014 118.7 . . ?
C21 C22 C23 120.0(4) . . ?
C21 C22 H015 120.0 . . ?
C23 C22 H015 120.0 . . ?
C6 C5 H016 120.2 . . ?
C4 C5 C6 119.7(4) . . ?
C4 C5 H016 120.2 . . ?
C1 C2 H017 119.5 . . ?
C3 C2 C1 121.0(4) . . ?
C3 C2 H017 119.5 . . ?
C15 C16 H018 119.6 . . ?
C17 C16 C15 120.8(4) . . ?
C17 C16 H018 119.6 . . ?
C30 C31 C32 120.0(4) . . ?
C30 C31 H019 120.0 . . ?
C32 C31 H019 120.0 . . ?
N4 C52 Rh1 111.2(2) . . ?
N4 C52 C51 118.9(3) . . ?
C51 C52 Rh1 129.8(3) . . ?
C50 C51 C52 121.1(4) . . ?
C50 C51 H21 119.4 . . ?
C52 C51 H21 119.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 P2 C34 C35 -146.5(3) . . . . ?
Rh1 P2 C34 C39 31.5(4) . . . . ?
Rh1 P2 C28 C29 89.8(3) . . . . ?
Rh1 P2 C28 C33 -84.7(3) . . . . ?
Rh1 P2 C27 N3 -39.5(3) . . . . ?
Rh1 P1 C13 N1 -30.9(3) . . . . ?
Rh1 P1 C7 C8 86.7(3) . . . . ?
Rh1 P1 C7 C12 -85.7(3) . . . . ?
Rh1 P1 C1 C6 10.5(4) . . . . ?
Rh1 P1 C1 C2 -168.8(3) . . . . ?
Rh1 Si1 C42 C47 43.5(3) . . . . ?
Rh1 Si1 C42 C43 -136.5(3) . . . . ?
Rh1 Al1 N1 C14 -155.0(2) . . . . ?
Rh1 Al1 N1 C13 1.2(3) . . . . ?
Rh1 Al1 N3 C27 14.1(3) . . . . ?
Rh1 Al1 N3 C26 -152.8(2) . . . . ?
Rh1 C52 C51 C50 -177.9(3) . . . . ?
P2 C34 C35 C36 177.0(4) . . . . ?
P2 C34 C39 C38 -179.2(5) . . . . ?
P2 C28 C29 C30 -174.7(3) . . . . ?
P2 C28 C33 C32 173.9(3) . . . . ?
P1 C7 C8 C9 -170.5(3) . . . . ?
P1 C7 C12 C11 171.0(3) . . . . ?
P1 C1 C6 C5 -177.7(3) . . . . ?
P1 C1 C2 C3 177.1(4) . . . . ?
Si1 C42 C47 C46 179.5(4) . . . . ?
Si1 C42 C43 C44 -179.1(3) . . . . ?
Al1 N1 C14 C19 -19.2(4) . . . . ?
Al1 N1 C14 C15 160.8(3) . . . . ?
Al1 N1 C13 P1 18.4(4) . . . . ?
Al1 N4 C48 C49 167.6(3) . . . . ?
Al1 N4 C52 Rh1 7.2(2) . . . . ?
Al1 N4 C52 C51 -171.0(3) . . . . ?
Al1 N2 C19 C14 18.2(3) . . . . ?
Al1 N2 C19 C18 -165.1(3) . . . . ?
Al1 N2 C21 C26 19.7(4) . . . . ?
Al1 N2 C21 C22 -161.8(3) . . . . ?
Al1 N3 C27 P2 15.1(4) . . . . ?
Al1 N3 C26 C21 -18.7(4) . . . . ?
Al1 N3 C26 C25 160.7(3) . . . . ?
N1 Al1 N3 C27 -91.3(3) . . . . ?
N1 Al1 N3 C26 101.7(3) . . . . ?
N1 C14 C15 C16 178.7(3) . . . . ?
N4 Al1 N1 C14 122.6(2) . . . . ?
N4 Al1 N1 C13 -81.2(3) . . . . ?
N4 Al1 N3 C27 94.4(3) . . . . ?
N4 Al1 N3 C26 -72.5(3) . . . . ?
N4 C52 C51 C50 -0.1(5) . . . . ?
N2 Al1 N1 C14 23.2(2) . . . . ?
N2 Al1 N1 C13 179.4(3) . . . . ?
N2 Al1 N3 C27 -169.7(3) . . . . ?
N2 Al1 N3 C26 23.4(3) . . . . ?
N2 C19 C14 N1 -2.2(4) . . . . ?
N2 C19 C14 C15 177.8(3) . . . . ?
N2 C19 C18 C17 -176.9(3) . . . . ?
N2 C21 C22 C23 -177.7(4) . . . . ?
N3 Al1 N1 C14 -52.9(3) . . . . ?
N3 Al1 N1 C13 103.3(3) . . . . ?
N3 C26 C21 N2 -3.8(5) . . . . ?
N3 C26 C21 C22 177.7(3) . . . . ?
N3 C26 C25 C24 -177.7(4) . . . . ?
C19 N2 C21 C26 -89.4(4) . . . . ?
C19 N2 C21 C22 89.1(4) . . . . ?
C19 C14 C15 C16 -1.3(5) . . . . ?
C19 C18 C17 C16 -0.1(6) . . . . ?
C14 N1 C13 P1 174.0(2) . . . . ?
C14 C19 C18 C17 -0.4(5) . . . . ?
C14 C15 C16 C17 0.9(6) . . . . ?
C34 P2 C28 C29 -130.1(3) . . . . ?
C34 P2 C28 C33 55.4(3) . . . . ?
C34 P2 C27 N3 -170.3(2) . . . . ?
C34 C35 C36 C37 1.9(8) . . . . ?
C34 C39 C38 C37 2.4(9) . . . . ?
C13 P1 C7 C8 -34.8(3) . . . . ?
C13 P1 C7 C12 152.8(3) . . . . ?
C13 P1 C1 C6 136.0(3) . . . . ?
C13 P1 C1 C2 -43.3(4) . . . . ?
C13 N1 C14 C19 -177.8(3) . . . . ?
C13 N1 C14 C15 2.2(5) . . . . ?
C28 P2 C34 C35 75.7(4) . . . . ?
C28 P2 C34 C39 -106.2(4) . . . . ?
C28 P2 C27 N3 86.6(3) . . . . ?
C28 C29 C30 C31 1.0(6) . . . . ?
C28 C33 C32 C31 1.0(6) . . . . ?
C27 P2 C34 C35 -29.3(4) . . . . ?
C27 P2 C34 C39 148.7(4) . . . . ?
C27 P2 C28 C29 -25.4(3) . . . . ?
C27 P2 C28 C33 160.1(3) . . . . ?
C27 N3 C26 C21 173.3(3) . . . . ?
C27 N3 C26 C25 -7.3(5) . . . . ?
C29 C28 C33 C32 -0.9(6) . . . . ?
C29 C30 C31 C32 -0.9(7) . . . . ?
C7 P1 C13 N1 91.9(3) . . . . ?
C7 P1 C1 C6 -116.9(3) . . . . ?
C7 P1 C1 C2 63.7(4) . . . . ?
C7 C8 C9 C10 -1.2(6) . . . . ?
C7 C12 C11 C10 0.3(7) . . . . ?
C1 P1 C13 N1 -161.4(2) . . . . ?
C1 P1 C7 C8 -142.1(3) . . . . ?
C1 P1 C7 C12 45.5(3) . . . . ?
C1 C6 C5 C4 -0.7(7) . . . . ?
C50 C49 C48 N4 -1.9(6) . . . . ?
C26 N3 C27 P2 -177.9(2) . . . . ?
C26 C21 C22 C23 0.7(6) . . . . ?
C26 C25 C24 C23 -0.6(7) . . . . ?
C6 C1 C2 C3 -2.2(7) . . . . ?
C18 C19 C14 N1 -178.9(3) . . . . ?
C18 C19 C14 C15 1.1(5) . . . . ?
C18 C17 C16 C15 -0.1(6) . . . . ?
C21 N2 C19 C14 129.4(3) . . . . ?
C21 N2 C19 C18 -53.9(4) . . . . ?
C21 C26 C25 C24 1.7(6) . . . . ?
C20 N2 C19 C14 -107.8(3) . . . . ?
C20 N2 C19 C18 68.9(4) . . . . ?
C20 N2 C21 C26 150.4(3) . . . . ?
C20 N2 C21 C22 -31.1(5) . . . . ?
C33 C28 C29 C30 -0.1(6) . . . . ?
C33 C32 C31 C30 -0.1(7) . . . . ?
C40 Si1 C42 C47 167.0(3) . . . . ?
C40 Si1 C42 C43 -13.0(4) . . . . ?
C8 C7 C12 C11 -1.6(6) . . . . ?
C25 C26 C21 N2 176.7(3) . . . . ?
C25 C26 C21 C22 -1.8(6) . . . . ?
C12 C7 C8 C9 2.0(6) . . . . ?
C12 C11 C10 C9 0.5(7) . . . . ?
C35 C34 C39 C38 -1.1(8) . . . . ?
C35 C36 C37 C38 -0.6(9) . . . . ?
C42 C47 C46 C45 -0.9(8) . . . . ?
C42 C43 C44 C45 0.2(7) . . . . ?
C11 C10 C9 C8 -0.1(6) . . . . ?
C47 C42 C43 C44 0.9(6) . . . . ?
C43 C42 C47 C46 -0.5(7) . . . . ?
C43 C44 C45 C46 -1.7(8) . . . . ?
C49 C50 C51 C52 -1.8(6) . . . . ?
C36 C37 C38 C39 -1.5(10) . . . . ?
C4 C3 C2 C1 1.8(8) . . . . ?
C39 C34 C35 C36 -1.0(7) . . . . ?
C44 C45 C46 C47 2.0(9) . . . . ?
C3 C4 C5 C6 0.3(8) . . . . ?
C41 Si1 C42 C47 -85.4(4) . . . . ?
C41 Si1 C42 C43 94.6(4) . . . . ?
C24 C23 C22 C21 0.5(7) . . . . ?
C48 N4 C52 Rh1 179.2(3) . . . . ?
C48 N4 C52 C51 1.0(5) . . . . ?
C22 C23 C24 C25 -0.5(7) . . . . ?
C5 C4 C3 C2 -0.8(8) . . . . ?
C2 C1 C6 C5 1.7(6) . . . . ?
C52 N4 C48 C49 0.0(6) . . . . ?
C51 C50 C49 C48 2.8(6) . . . . ?

_smtbx_masks_special_details     ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 0.250 -0.198 0.125 521.7 68.7 ?
2 0.250 -0.546 0.625 521.7 68.5 ?
3 0.750 -0.060 0.375 521.7 68.6 ?
4 0.750 -0.029 0.875 521.7 68.4 ?

_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
_olex2_submission_special_instructions 'No special instructions were received'
_chemical_properties_physical    
Air-sensitive,Moisture-sensitive,Oxygen-sensitive
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data__15_14_002b
_database_code_depnum_ccdc_archive 'CCDC 2056314'
loop_
_audit_author_name
_audit_author_address
'Naofumi Hara'
;Kyoto University
Japan
;
_audit_update_record             
;
2021-01-15 deposited with the CCDC.	2021-05-04 downloaded from the CCDC.
;
_audit_creation_date             2021-01-15
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.07.31 svn.rc2a77460 for OlexSys, GUI svn.r6145)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        
(η2,η2-bicyclo[2.2.1]hepta-2,5-diene)-(N,N-bis(2-(diphenylphosphinomethylamido)phenyl)methylamine)-(4-dimethylaminopyridine)-aluminium-rhodium
_chemical_formula_moiety         'C53 H53 Al N5 P2 Rh'
_chemical_formula_sum            'C53 H53 Al N5 P2 Rh'
_chemical_formula_weight         951.83
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Al Al 0.0645 0.0514 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.528(18)
_cell_length_b                   11.89(3)
_cell_length_c                   20.18(3)
_cell_angle_alpha                90.03(5)
_cell_angle_beta                 97.48(5)
_cell_angle_gamma                105.32(5)
_cell_volume                     2414(8)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    174
_cell_measurement_temperature    143.15
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_shelx_estimated_absorpt_T_max   0.958
_shelx_estimated_absorpt_T_min   0.945
_exptl_absorpt_coefficient_mu    0.479
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.812
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_lustre     .
_exptl_crystal_colour_modifier   .
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.309
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             988
_exptl_crystal_preparation       Loop
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.09
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0381
_diffrn_reflns_av_unetI/netI     0.0683
_diffrn_reflns_Laue_measured_fraction_full 0.974
_diffrn_reflns_Laue_measured_fraction_max 0.953
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            19679
_diffrn_reflns_point_group_measured_fraction_full 0.974
_diffrn_reflns_point_group_measured_fraction_max 0.953
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.492
_diffrn_reflns_theta_min         3.030
_diffrn_ambient_temperature      143.15
_diffrn_detector                 CCD
_diffrn_detector_area_resol_mean 28.5714
_diffrn_detector_type            'Rigaku Saturn724+'
_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.953
_diffrn_measurement_details      
;
scan:
	Number of images: 360
	           Slice: -110.0000 - 70.0000
	     Image width: 0.5000
	        Exp time: 8.0000
	   Rotation axis: Omega
	           Omega: 0.0000
	             Chi: 45.0000
	             Phi: 0.0000
	             XTD: 44.9714
	          2theta: -20.0248
scan:
	Number of images: 360
	           Slice: -110.0000 - 70.0000
	     Image width: 0.5000
	        Exp time: 8.0000
	   Rotation axis: Omega
	           Omega: 0.0000
	             Chi: 45.0000
	             Phi: 90.0000
	             XTD: 44.9714
	          2theta: -20.0248
;
_diffrn_measurement_device       'AFC12 (Right): Kappa 3 circle'
_diffrn_measurement_device_type  'Rigaku Saturn724+ (2x2 bin mode)'
_diffrn_measurement_method       'profile data from ω-scans'
_diffrn_measurement_specimen_support 'Mitegen 50um'
_diffrn_radiation_collimation    0.3
_diffrn_radiation_monochromator  Confocal
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_source                   'Rotating Anode'
_diffrn_source_current           24.0
_diffrn_source_power             1.2
_diffrn_source_target            Mo
_diffrn_source_type              'Rotating Anode'
_diffrn_source_voltage           50.0
_diffrn_special_details          
;
 ?
;
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                9094
_reflns_number_total             10587
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrystalClear-SM Expert 2.0 r7 (Rigaku, 2011)
;
_computing_data_collection       
;
CrystalClear-SM Expert 2.0 r7 (Rigaku, 2011)
;
_computing_data_reduction        
;
CrystalClear-SM Expert 2.0 r7 (Rigaku, 2011)
;
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.484
_refine_diff_density_min         -0.707
_refine_diff_density_rms         0.080
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.073
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     562
_refine_ls_number_reflns         10587
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0562
_refine_ls_R_factor_gt           0.0464
_refine_ls_restrained_S_all      1.073
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0327P)²+0.7459P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0915
_refine_ls_wR_factor_ref         0.0969
_refine_special_details          'solvent mask'
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C40(H40), C41(H41), C45(H45), C44(H44), C42(H42), C43(H43)
2.b Secondary CH2 refined with riding coordinates:
 C27(H27A,H27B), C13(H13A,H13B), C46(H46A,H46B)
2.c Aromatic/amide H refined with riding coordinates:
 C51(H51), C47(H47), C50(H50), C12(H12), C18(H18), C39(H39), C48(H48),
 C35(H35), C22(H22), C33(H33), C29(H29), C23(H23), C8(H8), C38(H38), C15(H15),
 C16(H16), C25(H25), C24(H24), C37(H37), C11(H11), C32(H32), C6(H6), C36(H36),
 C30(H30), C10(H10), C2(H2), C31(H31), C17(H17), C3(H3), C9(H9), C5(H5), C4(H4)
2.d Idealised Me refined as rotating group:
 C20(H20A,H20B,H20C), C52(H52A,H52B,H52C), C53(H53A,H53B,H53C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.58019(2) 0.67968(2) 0.18001(2) 0.01674(7) Uani 1 1 d . . . . .
P2 P 0.70148(7) 0.86323(6) 0.21013(3) 0.01654(15) Uani 1 1 d . . . . .
P1 P 0.35762(7) 0.64356(6) 0.16367(4) 0.01809(15) Uani 1 1 d . . . . .
Al1 Al 0.53471(8) 0.69043(7) 0.29740(4) 0.01677(17) Uani 1 1 d . . . . .
N4 N 0.5589(2) 0.5373(2) 0.32795(11) 0.0193(5) Uani 1 1 d . . . . .
N1 N 0.3623(2) 0.71347(19) 0.29037(11) 0.0174(5) Uani 1 1 d . . . . .
N2 N 0.4919(2) 0.70229(19) 0.41221(11) 0.0179(5) Uani 1 1 d . . . . .
N3 N 0.6762(2) 0.81188(19) 0.33959(11) 0.0194(5) Uani 1 1 d . . . . .
N009 N 0.6279(3) 0.2117(2) 0.36899(12) 0.0264(6) Uani 1 1 d . . . . .
C27 C 0.7737(3) 0.8780(2) 0.29988(14) 0.0218(6) Uani 1 1 d . . . . .
H27A H 0.853936 0.848649 0.305944 0.026 Uiso 1 1 calc R U . . .
H27B H 0.800065 0.961245 0.314797 0.026 Uiso 1 1 calc R U . . .
C51 C 0.6776(3) 0.5268(2) 0.35709(14) 0.0214(6) Uani 1 1 d . . . . .
H51 H 0.747231 0.596026 0.368065 0.026 Uiso 1 1 calc R U . . .
C40 C 0.6300(3) 0.5124(2) 0.17911(14) 0.0214(6) Uani 1 1 d . . . . .
H40 H 0.601267 0.452075 0.212553 0.026 Uiso 1 1 calc R U . . .
C34 C 0.6411(3) 0.9954(2) 0.20039(13) 0.0187(6) Uani 1 1 d . . . . .
C13 C 0.2926(3) 0.7219(2) 0.22422(13) 0.0200(6) Uani 1 1 d . . . . .
H13A H 0.306827 0.804745 0.212585 0.024 Uiso 1 1 calc R U . . .
H13B H 0.195998 0.686785 0.223444 0.024 Uiso 1 1 calc R U . . .
C7 C 0.2719(3) 0.6810(2) 0.08425(13) 0.0204(6) Uani 1 1 d . . . . .
C28 C 0.8542(3) 0.9167(2) 0.17091(14) 0.0204(6) Uani 1 1 d . . . . .
C47 C 0.4621(3) 0.4361(2) 0.31423(14) 0.0203(6) Uani 1 1 d . . . . .
H47 H 0.376724 0.440614 0.294445 0.024 Uiso 1 1 calc R U . . .
C49 C 0.6046(3) 0.3167(2) 0.35659(13) 0.0205(6) Uani 1 1 d . . . . .
C26 C 0.7167(3) 0.8159(2) 0.40796(13) 0.0184(6) Uani 1 1 d . . . . .
C21 C 0.6222(3) 0.7549(2) 0.44819(13) 0.0187(6) Uani 1 1 d . . . . .
C41 C 0.7494(3) 0.6041(3) 0.19288(15) 0.0241(6) Uani 1 1 d . . . . .
H41 H 0.809715 0.611543 0.236159 0.029 Uiso 1 1 calc R U . . .
C50 C 0.7040(3) 0.4214(2) 0.37189(14) 0.0239(6) Uani 1 1 d . . . . .
H50 H 0.789818 0.419631 0.392543 0.029 Uiso 1 1 calc R U . . .
C14 C 0.3355(3) 0.7801(2) 0.34054(13) 0.0189(6) Uani 1 1 d . . . . .
C12 C 0.3463(3) 0.7527(2) 0.04092(14) 0.0234(6) Uani 1 1 d . . . . .
H12 H 0.439877 0.780896 0.052440 0.028 Uiso 1 1 calc R U . . .
C19 C 0.4066(3) 0.7817(2) 0.40474(13) 0.0185(6) Uani 1 1 d . . . . .
C45 C 0.6169(3) 0.4801(2) 0.10407(14) 0.0256(6) Uani 1 1 d . . . . .
H45 H 0.555775 0.402553 0.088216 0.031 Uiso 1 1 calc R U . . .
C18 C 0.3899(3) 0.8488(3) 0.45678(14) 0.0237(6) Uani 1 1 d . . . . .
H18 H 0.440619 0.849206 0.499369 0.028 Uiso 1 1 calc R U . . .
C39 C 0.7206(3) 1.1078(2) 0.21974(14) 0.0224(6) Uani 1 1 d . . . . .
H39 H 0.809304 1.117664 0.240645 0.027 Uiso 1 1 calc R U . . .
C48 C 0.4800(3) 0.3276(2) 0.32719(13) 0.0216(6) Uani 1 1 d . . . . .
H48 H 0.408266 0.259901 0.316276 0.026 Uiso 1 1 calc R U . . .
C1 C 0.2551(3) 0.4927(2) 0.17093(14) 0.0226(6) Uani 1 1 d . . . . .
C35 C 0.5133(3) 0.9847(2) 0.16818(14) 0.0234(6) Uani 1 1 d . . . . .
H35 H 0.458628 0.909776 0.152938 0.028 Uiso 1 1 calc R U . . .
C22 C 0.6563(3) 0.7461(3) 0.51621(14) 0.0241(6) Uani 1 1 d . . . . .
H22 H 0.591936 0.702792 0.541993 0.029 Uiso 1 1 calc R U . . .
C33 C 0.8499(3) 0.9791(3) 0.11225(14) 0.0245(6) Uani 1 1 d . . . . .
H33 H 0.771017 1.000675 0.096208 0.029 Uiso 1 1 calc R U . . .
C29 C 0.9717(3) 0.8881(3) 0.19260(15) 0.0283(7) Uani 1 1 d . . . . .
H29 H 0.978459 0.846462 0.232489 0.034 Uiso 1 1 calc R U . . .
C44 C 0.5856(3) 0.5875(3) 0.07162(14) 0.0272(7) Uani 1 1 d . . . . .
H44 H 0.516896 0.583301 0.031850 0.033 Uiso 1 1 calc R U . . .
C23 C 0.7846(3) 0.8004(3) 0.54728(14) 0.0263(7) Uani 1 1 d . . . . .
H23 H 0.808199 0.794577 0.593974 0.032 Uiso 1 1 calc R U . . .
C8 C 0.1345(3) 0.6404(3) 0.06629(15) 0.0251(6) Uani 1 1 d . . . . .
H8 H 0.082114 0.591258 0.095311 0.030 Uiso 1 1 calc R U . . .
C38 C 0.6723(3) 1.2049(2) 0.20894(15) 0.0258(6) Uani 1 1 d . . . . .
H38 H 0.727693 1.280447 0.222272 0.031 Uiso 1 1 calc R U . . .
C15 C 0.2432(3) 0.8471(3) 0.33262(14) 0.0229(6) Uani 1 1 d . . . . .
H15 H 0.191728 0.847112 0.290291 0.028 Uiso 1 1 calc R U . . .
C20 C 0.4199(3) 0.5930(2) 0.44011(14) 0.0237(6) Uani 1 1 d . . . . .
H20A H 0.342648 0.553720 0.408050 0.036 Uiso 1 1 calc R U . . .
H20B H 0.390213 0.610628 0.482003 0.036 Uiso 1 1 calc R U . . .
H20C H 0.479133 0.541839 0.448817 0.036 Uiso 1 1 calc R U . . .
C16 C 0.2260(3) 0.9133(3) 0.38588(15) 0.0257(6) Uani 1 1 d . . . . .
H16 H 0.162365 0.957268 0.379439 0.031 Uiso 1 1 calc R U . . .
C25 C 0.8442(3) 0.8706(2) 0.44015(14) 0.0233(6) Uani 1 1 d . . . . .
H25 H 0.909621 0.913681 0.414866 0.028 Uiso 1 1 calc R U . . .
C42 C 0.8031(3) 0.6256(3) 0.12464(16) 0.0302(7) Uani 1 1 d . . . . .
H42 H 0.898079 0.670934 0.125854 0.036 Uiso 1 1 calc R U . . .
C43 C 0.6984(3) 0.6756(3) 0.08400(15) 0.0280(7) Uani 1 1 d . . . . .
H43 H 0.721427 0.742763 0.053989 0.034 Uiso 1 1 calc R U . . .
C24 C 0.8763(3) 0.8625(3) 0.50884(14) 0.0259(6) Uani 1 1 d . . . . .
H24 H 0.963320 0.900743 0.529646 0.031 Uiso 1 1 calc R U . . .
C37 C 0.5430(3) 1.1916(3) 0.17869(15) 0.0278(7) Uani 1 1 d . . . . .
H37 H 0.508868 1.257795 0.172287 0.033 Uiso 1 1 calc R U . . .
C11 C 0.2857(3) 0.7837(3) -0.01905(15) 0.0300(7) Uani 1 1 d . . . . .
H11 H 0.337450 0.833473 -0.048048 0.036 Uiso 1 1 calc R U . . .
C32 C 0.9570(3) 1.0101(3) 0.07717(15) 0.0285(7) Uani 1 1 d . . . . .
H32 H 0.951507 1.052535 0.037524 0.034 Uiso 1 1 calc R U . . .
C6 C 0.2719(3) 0.4054(3) 0.12973(17) 0.0321(7) Uani 1 1 d . . . . .
H6 H 0.330178 0.425396 0.096827 0.039 Uiso 1 1 calc R U . . .
C52 C 0.5237(3) 0.1035(3) 0.35247(16) 0.0331(7) Uani 1 1 d . . . . .
H52A H 0.448449 0.103228 0.376456 0.050 Uiso 1 1 calc R U . . .
H52B H 0.558519 0.036891 0.365654 0.050 Uiso 1 1 calc R U . . .
H52C H 0.494090 0.097646 0.304192 0.050 Uiso 1 1 calc R U . . .
C36 C 0.4639(3) 1.0818(3) 0.15788(16) 0.0282(7) Uani 1 1 d . . . . .
H36 H 0.375651 1.072625 0.136506 0.034 Uiso 1 1 calc R U . . .
C30 C 1.0798(3) 0.9190(3) 0.15734(16) 0.0321(7) Uani 1 1 d . . . . .
H30 H 1.159144 0.898232 0.173307 0.039 Uiso 1 1 calc R U . . .
C10 C 0.1493(3) 0.7417(3) -0.03637(15) 0.0303(7) Uani 1 1 d . . . . .
H10 H 0.107698 0.761424 -0.077733 0.036 Uiso 1 1 calc R U . . .
C2 C 0.1674(3) 0.4595(3) 0.21805(16) 0.0317(7) Uani 1 1 d . . . . .
H2 H 0.153089 0.517564 0.246350 0.038 Uiso 1 1 calc R U . . .
C46 C 0.7642(3) 0.5010(3) 0.09424(17) 0.0337(8) Uani 1 1 d . . . . .
H46A H 0.808740 0.448344 0.120304 0.040 Uiso 1 1 calc R U . . .
H46B H 0.777316 0.498049 0.046634 0.040 Uiso 1 1 calc R U . . .
C31 C 1.0729(3) 0.9792(3) 0.09969(16) 0.0294(7) Uani 1 1 d . . . . .
H31 H 1.146758 0.999647 0.075425 0.035 Uiso 1 1 calc R U . . .
C17 C 0.2994(3) 0.9162(3) 0.44769(15) 0.0267(7) Uani 1 1 d . . . . .
H17 H 0.288647 0.963318 0.483494 0.032 Uiso 1 1 calc R U . . .
C53 C 0.7618(3) 0.2038(3) 0.39324(16) 0.0347(8) Uani 1 1 d . . . . .
H53A H 0.822789 0.242350 0.362349 0.052 Uiso 1 1 calc R U . . .
H53B H 0.761979 0.121578 0.395986 0.052 Uiso 1 1 calc R U . . .
H53C H 0.790492 0.242217 0.437683 0.052 Uiso 1 1 calc R U . . .
C3 C 0.1004(3) 0.3431(3) 0.22445(17) 0.0380(8) Uani 1 1 d . . . . .
H3 H 0.040981 0.322514 0.256780 0.046 Uiso 1 1 calc R U . . .
C9 C 0.0739(3) 0.6713(3) 0.00640(15) 0.0293(7) Uani 1 1 d . . . . .
H9 H -0.019770 0.643876 -0.005179 0.035 Uiso 1 1 calc R U . . .
C5 C 0.2047(3) 0.2891(3) 0.13608(19) 0.0405(9) Uani 1 1 d . . . . .
H5 H 0.216719 0.230672 0.107282 0.049 Uiso 1 1 calc R U . . .
C4 C 0.1201(3) 0.2580(3) 0.18415(18) 0.0410(9) Uani 1 1 d . . . . .
H4 H 0.076136 0.178347 0.189154 0.049 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 P2 2.255(5) . ?
Rh1 P1 2.247(4) . ?
Rh1 Al1 2.487(4) . ?
Rh1 C40 2.188(6) . ?
Rh1 C41 2.185(4) . ?
Rh1 C44 2.460(4) . ?
Rh1 C43 2.442(4) . ?
P2 C27 1.860(4) . ?
P2 C34 1.846(5) . ?
P2 C28 1.846(4) . ?
P1 C13 1.839(3) . ?
P1 C7 1.849(4) . ?
P1 C1 1.850(5) . ?
Al1 N4 1.991(5) . ?
Al1 N1 1.893(4) . ?
Al1 N2 2.428(4) . ?
Al1 N3 1.887(4) . ?
N4 C51 1.347(4) . ?
N4 C47 1.357(4) . ?
N1 C13 1.454(4) . ?
N1 C14 1.387(4) . ?
N2 C21 1.444(4) . ?
N2 C19 1.460(4) . ?
N2 C20 1.474(4) . ?
N3 C27 1.449(4) . ?
N3 C26 1.387(4) . ?
N009 C49 1.352(5) . ?
N009 C52 1.459(5) . ?
N009 C53 1.457(5) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C51 H51 0.9500 . ?
C51 C50 1.378(5) . ?
C40 H40 1.0000 . ?
C40 C41 1.425(5) . ?
C40 C45 1.542(4) . ?
C34 C39 1.400(5) . ?
C34 C35 1.390(4) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C7 C12 1.389(4) . ?
C7 C8 1.397(5) . ?
C28 C33 1.399(4) . ?
C28 C29 1.385(4) . ?
C47 H47 0.9500 . ?
C47 C48 1.373(5) . ?
C49 C50 1.403(5) . ?
C49 C48 1.405(4) . ?
C26 C21 1.416(4) . ?
C26 C25 1.399(4) . ?
C21 C22 1.384(4) . ?
C41 H41 1.0000 . ?
C41 C42 1.552(5) . ?
C50 H50 0.9500 . ?
C14 C19 1.407(4) . ?
C14 C15 1.405(4) . ?
C12 H12 0.9500 . ?
C12 C11 1.390(4) . ?
C19 C18 1.376(4) . ?
C45 H45 1.0000 . ?
C45 C44 1.528(5) . ?
C45 C46 1.544(5) . ?
C18 H18 0.9500 . ?
C18 C17 1.394(4) . ?
C39 H39 0.9500 . ?
C39 C38 1.386(5) . ?
C48 H48 0.9500 . ?
C1 C6 1.391(5) . ?
C1 C2 1.396(5) . ?
C35 H35 0.9500 . ?
C35 C36 1.391(5) . ?
C22 H22 0.9500 . ?
C22 C23 1.398(5) . ?
C33 H33 0.9500 . ?
C33 C32 1.378(5) . ?
C29 H29 0.9500 . ?
C29 C30 1.388(5) . ?
C44 H44 1.0000 . ?
C44 C43 1.354(5) . ?
C23 H23 0.9500 . ?
C23 C24 1.377(5) . ?
C8 H8 0.9500 . ?
C8 C9 1.388(4) . ?
C38 H38 0.9500 . ?
C38 C37 1.386(5) . ?
C15 H15 0.9500 . ?
C15 C16 1.390(4) . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C16 H16 0.9500 . ?
C16 C17 1.374(4) . ?
C25 H25 0.9500 . ?
C25 C24 1.393(4) . ?
C42 H42 1.0000 . ?
C42 C43 1.533(5) . ?
C42 C46 1.533(5) . ?
C43 H43 1.0000 . ?
C24 H24 0.9500 . ?
C37 H37 0.9500 . ?
C37 C36 1.381(5) . ?
C11 H11 0.9500 . ?
C11 C10 1.387(5) . ?
C32 H32 0.9500 . ?
C32 C31 1.386(5) . ?
C6 H6 0.9500 . ?
C6 C5 1.391(5) . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C36 H36 0.9500 . ?
C30 H30 0.9500 . ?
C30 C31 1.370(5) . ?
C10 H10 0.9500 . ?
C10 C9 1.380(5) . ?
C2 H2 0.9500 . ?
C2 C3 1.392(5) . ?
C46 H46A 0.9900 . ?
C46 H46B 0.9900 . ?
C31 H31 0.9500 . ?
C17 H17 0.9500 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C3 H3 0.9500 . ?
C3 C4 1.371(5) . ?
C9 H9 0.9500 . ?
C5 H5 0.9500 . ?
C5 C4 1.386(5) . ?
C4 H4 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2 Rh1 Al1 79.92(7) . . ?
P2 Rh1 C44 122.11(10) . . ?
P2 Rh1 C43 91.77(11) . . ?
P1 Rh1 P2 118.17(8) . . ?
P1 Rh1 Al1 79.55(7) . . ?
P1 Rh1 C44 92.90(10) . . ?
P1 Rh1 C43 119.28(11) . . ?
C40 Rh1 P2 132.79(15) . . ?
C40 Rh1 P1 108.05(12) . . ?
C40 Rh1 Al1 100.35(9) . . ?
C40 Rh1 C44 61.37(13) . . ?
C40 Rh1 C43 72.81(12) . . ?
C41 Rh1 P2 95.10(17) . . ?
C41 Rh1 P1 146.02(12) . . ?
C41 Rh1 Al1 101.23(10) . . ?
C41 Rh1 C40 38.03(11) . . ?
C41 Rh1 C44 73.21(13) . . ?
C41 Rh1 C43 62.28(13) . . ?
C44 Rh1 Al1 157.25(9) . . ?
C43 Rh1 Al1 161.04(9) . . ?
C43 Rh1 C44 32.07(11) . . ?
C27 P2 Rh1 112.33(11) . . ?
C34 P2 Rh1 125.51(17) . . ?
C34 P2 C27 101.44(14) . . ?
C28 P2 Rh1 115.97(11) . . ?
C28 P2 C27 100.12(16) . . ?
C28 P2 C34 97.60(16) . . ?
C13 P1 Rh1 113.44(12) . . ?
C13 P1 C7 100.55(17) . . ?
C13 P1 C1 100.58(19) . . ?
C7 P1 Rh1 120.30(11) . . ?
C7 P1 C1 99.60(16) . . ?
C1 P1 Rh1 119.02(12) . . ?
N4 Al1 Rh1 99.63(10) . . ?
N4 Al1 N2 80.58(11) . . ?
N1 Al1 Rh1 104.94(9) . . ?
N1 Al1 N4 118.35(11) . . ?
N1 Al1 N2 75.30(10) . . ?
N2 Al1 Rh1 179.53(7) . . ?
N3 Al1 Rh1 104.97(11) . . ?
N3 Al1 N4 109.47(17) . . ?
N3 Al1 N1 116.89(16) . . ?
N3 Al1 N2 74.57(12) . . ?
C51 N4 Al1 121.4(2) . . ?
C51 N4 C47 115.9(3) . . ?
C47 N4 Al1 122.3(2) . . ?
C13 N1 Al1 118.68(18) . . ?
C14 N1 Al1 117.67(19) . . ?
C14 N1 C13 115.1(2) . . ?
C21 N2 Al1 103.25(18) . . ?
C21 N2 C19 113.3(3) . . ?
C21 N2 C20 114.3(2) . . ?
C19 N2 Al1 99.66(16) . . ?
C19 N2 C20 109.0(3) . . ?
C20 N2 Al1 116.54(19) . . ?
C27 N3 Al1 118.9(2) . . ?
C26 N3 Al1 121.9(2) . . ?
C26 N3 C27 115.7(2) . . ?
C49 N009 C52 121.2(3) . . ?
C49 N009 C53 120.3(3) . . ?
C53 N009 C52 118.2(3) . . ?
P2 C27 H27A 109.8 . . ?
P2 C27 H27B 109.8 . . ?
N3 C27 P2 109.6(2) . . ?
N3 C27 H27A 109.8 . . ?
N3 C27 H27B 109.8 . . ?
H27A C27 H27B 108.2 . . ?
N4 C51 H51 118.1 . . ?
N4 C51 C50 123.8(3) . . ?
C50 C51 H51 118.1 . . ?
Rh1 C40 H40 121.7 . . ?
C41 C40 Rh1 70.9(2) . . ?
C41 C40 H40 121.7 . . ?
C41 C40 C45 105.6(2) . . ?
C45 C40 Rh1 103.71(18) . . ?
C45 C40 H40 121.7 . . ?
C39 C34 P2 123.4(3) . . ?
C35 C34 P2 118.7(2) . . ?
C35 C34 C39 117.8(3) . . ?
P1 C13 H13A 110.0 . . ?
P1 C13 H13B 110.0 . . ?
N1 C13 P1 108.3(2) . . ?
N1 C13 H13A 110.0 . . ?
N1 C13 H13B 110.0 . . ?
H13A C13 H13B 108.4 . . ?
C12 C7 P1 119.1(2) . . ?
C12 C7 C8 118.6(3) . . ?
C8 C7 P1 122.3(2) . . ?
C33 C28 P2 119.5(2) . . ?
C29 C28 P2 123.2(2) . . ?
C29 C28 C33 117.0(3) . . ?
N4 C47 H47 118.0 . . ?
N4 C47 C48 124.0(3) . . ?
C48 C47 H47 118.0 . . ?
N009 C49 C50 121.8(3) . . ?
N009 C49 C48 122.2(3) . . ?
C50 C49 C48 116.0(3) . . ?
N3 C26 C21 116.9(3) . . ?
N3 C26 C25 125.7(3) . . ?
C25 C26 C21 117.3(3) . . ?
C26 C21 N2 114.6(3) . . ?
C22 C21 N2 124.2(3) . . ?
C22 C21 C26 121.2(3) . . ?
Rh1 C41 H41 122.2 . . ?
C40 C41 Rh1 71.1(2) . . ?
C40 C41 H41 122.2 . . ?
C40 C41 C42 104.8(3) . . ?
C42 C41 Rh1 102.5(2) . . ?
C42 C41 H41 122.2 . . ?
C51 C50 C49 120.3(3) . . ?
C51 C50 H50 119.9 . . ?
C49 C50 H50 119.9 . . ?
N1 C14 C19 117.8(3) . . ?
N1 C14 C15 125.4(3) . . ?
C15 C14 C19 116.9(3) . . ?
C7 C12 H12 119.6 . . ?
C7 C12 C11 120.9(3) . . ?
C11 C12 H12 119.6 . . ?
C14 C19 N2 114.9(2) . . ?
C18 C19 N2 123.4(3) . . ?
C18 C19 C14 121.6(3) . . ?
C40 C45 H45 116.8 . . ?
C40 C45 C46 101.1(2) . . ?
C44 C45 C40 101.9(2) . . ?
C44 C45 H45 116.8 . . ?
C44 C45 C46 100.8(3) . . ?
C46 C45 H45 116.8 . . ?
C19 C18 H18 119.7 . . ?
C19 C18 C17 120.7(3) . . ?
C17 C18 H18 119.7 . . ?
C34 C39 H39 119.4 . . ?
C38 C39 C34 121.2(3) . . ?
C38 C39 H39 119.4 . . ?
C47 C48 C49 120.0(3) . . ?
C47 C48 H48 120.0 . . ?
C49 C48 H48 120.0 . . ?
C6 C1 P1 118.2(3) . . ?
C6 C1 C2 117.6(3) . . ?
C2 C1 P1 124.1(2) . . ?
C34 C35 H35 119.4 . . ?
C34 C35 C36 121.2(3) . . ?
C36 C35 H35 119.4 . . ?
C21 C22 H22 119.7 . . ?
C21 C22 C23 120.6(3) . . ?
C23 C22 H22 119.7 . . ?
C28 C33 H33 119.1 . . ?
C32 C33 C28 121.7(3) . . ?
C32 C33 H33 119.2 . . ?
C28 C29 H29 119.3 . . ?
C28 C29 C30 121.4(3) . . ?
C30 C29 H29 119.3 . . ?
Rh1 C44 H44 123.5 . . ?
C45 C44 Rh1 92.9(2) . . ?
C45 C44 H44 123.5 . . ?
C43 C44 Rh1 73.25(19) . . ?
C43 C44 C45 106.4(3) . . ?
C43 C44 H44 123.5 . . ?
C22 C23 H23 120.7 . . ?
C24 C23 C22 118.7(3) . . ?
C24 C23 H23 120.7 . . ?
C7 C8 H8 119.7 . . ?
C9 C8 C7 120.5(3) . . ?
C9 C8 H8 119.7 . . ?
C39 C38 H38 120.0 . . ?
C37 C38 C39 120.0(3) . . ?
C37 C38 H38 120.0 . . ?
C14 C15 H15 119.6 . . ?
C16 C15 C14 120.9(3) . . ?
C16 C15 H15 119.6 . . ?
N2 C20 H20A 109.5 . . ?
N2 C20 H20B 109.5 . . ?
N2 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C15 C16 H16 119.4 . . ?
C17 C16 C15 121.3(3) . . ?
C17 C16 H16 119.4 . . ?
C26 C25 H25 119.6 . . ?
C24 C25 C26 120.7(3) . . ?
C24 C25 H25 119.6 . . ?
C41 C42 H42 116.8 . . ?
C43 C42 C41 102.3(2) . . ?
C43 C42 H42 116.8 . . ?
C43 C42 C46 100.4(3) . . ?
C46 C42 C41 101.0(3) . . ?
C46 C42 H42 116.8 . . ?
Rh1 C43 H43 123.2 . . ?
C44 C43 Rh1 74.7(2) . . ?
C44 C43 C42 107.1(3) . . ?
C44 C43 H43 123.2 . . ?
C42 C43 Rh1 92.5(2) . . ?
C42 C43 H43 123.2 . . ?
C23 C24 C25 121.5(3) . . ?
C23 C24 H24 119.2 . . ?
C25 C24 H24 119.2 . . ?
C38 C37 H37 120.1 . . ?
C36 C37 C38 119.8(3) . . ?
C36 C37 H37 120.1 . . ?
C12 C11 H11 120.1 . . ?
C10 C11 C12 119.7(3) . . ?
C10 C11 H11 120.1 . . ?
C33 C32 H32 120.0 . . ?
C33 C32 C31 120.0(3) . . ?
C31 C32 H32 120.0 . . ?
C1 C6 H6 119.6 . . ?
C5 C6 C1 120.9(3) . . ?
C5 C6 H6 119.6 . . ?
N009 C52 H52A 109.5 . . ?
N009 C52 H52B 109.5 . . ?
N009 C52 H52C 109.5 . . ?
H52A C52 H52B 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C35 C36 H36 120.0 . . ?
C37 C36 C35 120.1(3) . . ?
C37 C36 H36 120.0 . . ?
C29 C30 H30 119.7 . . ?
C31 C30 C29 120.6(3) . . ?
C31 C30 H30 119.7 . . ?
C11 C10 H10 120.0 . . ?
C9 C10 C11 120.1(3) . . ?
C9 C10 H10 120.0 . . ?
C1 C2 H2 119.3 . . ?
C3 C2 C1 121.4(3) . . ?
C3 C2 H2 119.3 . . ?
C45 C46 H46A 113.1 . . ?
C45 C46 H46B 113.1 . . ?
C42 C46 C45 93.2(2) . . ?
C42 C46 H46A 113.1 . . ?
C42 C46 H46B 113.1 . . ?
H46A C46 H46B 110.5 . . ?
C32 C31 H31 120.4 . . ?
C30 C31 C32 119.2(3) . . ?
C30 C31 H31 120.4 . . ?
C18 C17 H17 120.7 . . ?
C16 C17 C18 118.7(3) . . ?
C16 C17 H17 120.7 . . ?
N009 C53 H53A 109.5 . . ?
N009 C53 H53B 109.5 . . ?
N009 C53 H53C 109.5 . . ?
H53A C53 H53B 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C2 C3 H3 120.0 . . ?
C4 C3 C2 120.1(4) . . ?
C4 C3 H3 120.0 . . ?
C8 C9 H9 119.9 . . ?
C10 C9 C8 120.1(3) . . ?
C10 C9 H9 119.9 . . ?
C6 C5 H5 119.8 . . ?
C4 C5 C6 120.4(3) . . ?
C4 C5 H5 119.8 . . ?
C3 C4 C5 119.5(3) . . ?
C3 C4 H4 120.2 . . ?
C5 C4 H4 120.2 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 P2 C27 N3 -41.0(2) . . . . ?
Rh1 P2 C34 C39 -179.81(18) . . . . ?
Rh1 P2 C34 C35 -4.3(3) . . . . ?
Rh1 P2 C28 C33 93.2(3) . . . . ?
Rh1 P2 C28 C29 -79.9(3) . . . . ?
Rh1 P1 C13 N1 -43.5(2) . . . . ?
Rh1 P1 C7 C12 -13.2(3) . . . . ?
Rh1 P1 C7 C8 167.23(19) . . . . ?
Rh1 P1 C1 C6 -57.9(3) . . . . ?
Rh1 P1 C1 C2 118.0(3) . . . . ?
Rh1 Al1 N1 C13 -0.8(2) . . . . ?
Rh1 Al1 N1 C14 -147.20(19) . . . . ?
Rh1 Al1 N3 C27 3.9(2) . . . . ?
Rh1 Al1 N3 C26 -154.14(19) . . . . ?
Rh1 C40 C41 C42 -98.4(2) . . . . ?
Rh1 C40 C45 C44 3.8(2) . . . . ?
Rh1 C40 C45 C46 107.5(2) . . . . ?
Rh1 C41 C42 C43 -5.9(2) . . . . ?
Rh1 C41 C42 C46 -109.3(3) . . . . ?
Rh1 C44 C43 C42 87.9(2) . . . . ?
P2 C34 C39 C38 177.4(2) . . . . ?
P2 C34 C35 C36 -178.3(2) . . . . ?
P2 C28 C33 C32 -173.0(2) . . . . ?
P2 C28 C29 C30 172.6(3) . . . . ?
P1 C7 C12 C11 -179.5(2) . . . . ?
P1 C7 C8 C9 179.5(2) . . . . ?
P1 C1 C6 C5 175.5(3) . . . . ?
P1 C1 C2 C3 -175.0(2) . . . . ?
Al1 N4 C51 C50 -172.0(2) . . . . ?
Al1 N4 C47 C48 171.8(2) . . . . ?
Al1 N1 C13 P1 25.4(2) . . . . ?
Al1 N1 C14 C19 -28.2(3) . . . . ?
Al1 N1 C14 C15 151.4(2) . . . . ?
Al1 N2 C21 C26 20.2(3) . . . . ?
Al1 N2 C21 C22 -158.5(2) . . . . ?
Al1 N2 C19 C14 26.5(3) . . . . ?
Al1 N2 C19 C18 -157.0(2) . . . . ?
Al1 N3 C27 P2 21.2(3) . . . . ?
Al1 N3 C26 C21 -23.1(3) . . . . ?
Al1 N3 C26 C25 153.8(2) . . . . ?
N4 Al1 N1 C13 -110.7(2) . . . . ?
N4 Al1 N1 C14 102.9(2) . . . . ?
N4 Al1 N3 C27 110.0(2) . . . . ?
N4 Al1 N3 C26 -48.0(2) . . . . ?
N4 C51 C50 C49 0.1(4) . . . . ?
N4 C47 C48 C49 0.2(4) . . . . ?
N1 Al1 N3 C27 -111.9(2) . . . . ?
N1 Al1 N3 C26 90.1(2) . . . . ?
N1 C14 C19 N2 -5.9(4) . . . . ?
N1 C14 C19 C18 177.5(3) . . . . ?
N1 C14 C15 C16 -178.4(3) . . . . ?
N2 Al1 N1 C13 178.8(2) . . . . ?
N2 Al1 N1 C14 32.4(2) . . . . ?
N2 Al1 N3 C27 -176.1(2) . . . . ?
N2 Al1 N3 C26 25.9(2) . . . . ?
N2 C21 C22 C23 -179.6(2) . . . . ?
N2 C19 C18 C17 -175.0(3) . . . . ?
N3 Al1 N1 C13 115.0(2) . . . . ?
N3 Al1 N1 C14 -31.4(2) . . . . ?
N3 C26 C21 N2 -3.9(3) . . . . ?
N3 C26 C21 C22 174.9(2) . . . . ?
N3 C26 C25 C24 -175.7(3) . . . . ?
N009 C49 C50 C51 178.4(3) . . . . ?
N009 C49 C48 C47 -178.5(3) . . . . ?
C27 P2 C34 C39 51.8(3) . . . . ?
C27 P2 C34 C35 -132.7(2) . . . . ?
C27 P2 C28 C33 -145.7(2) . . . . ?
C27 P2 C28 C29 41.2(3) . . . . ?
C27 N3 C26 C21 178.2(2) . . . . ?
C27 N3 C26 C25 -4.8(4) . . . . ?
C51 N4 C47 C48 -1.2(4) . . . . ?
C40 C41 C42 C43 67.5(3) . . . . ?
C40 C41 C42 C46 -35.8(3) . . . . ?
C40 C45 C44 Rh1 -3.3(2) . . . . ?
C40 C45 C44 C43 70.1(3) . . . . ?
C40 C45 C46 C42 -53.1(3) . . . . ?
C34 P2 C27 N3 95.4(2) . . . . ?
C34 P2 C28 C33 -42.6(3) . . . . ?
C34 P2 C28 C29 144.4(3) . . . . ?
C34 C39 C38 C37 0.2(4) . . . . ?
C34 C35 C36 C37 1.2(5) . . . . ?
C13 P1 C7 C12 112.1(3) . . . . ?
C13 P1 C7 C8 -67.5(3) . . . . ?
C13 P1 C1 C6 177.6(2) . . . . ?
C13 P1 C1 C2 -6.5(3) . . . . ?
C13 N1 C14 C19 -175.9(2) . . . . ?
C13 N1 C14 C15 3.8(4) . . . . ?
C7 P1 C13 N1 -173.32(19) . . . . ?
C7 P1 C1 C6 74.9(3) . . . . ?
C7 P1 C1 C2 -109.2(3) . . . . ?
C7 C12 C11 C10 -0.7(4) . . . . ?
C7 C8 C9 C10 0.6(4) . . . . ?
C28 P2 C27 N3 -164.67(19) . . . . ?
C28 P2 C34 C39 -50.2(3) . . . . ?
C28 P2 C34 C35 125.3(2) . . . . ?
C28 C33 C32 C31 0.1(5) . . . . ?
C28 C29 C30 C31 0.1(5) . . . . ?
C47 N4 C51 C50 1.0(4) . . . . ?
C26 N3 C27 P2 -179.52(18) . . . . ?
C26 C21 C22 C23 1.8(4) . . . . ?
C26 C25 C24 C23 0.4(4) . . . . ?
C21 N2 C19 C14 135.5(2) . . . . ?
C21 N2 C19 C18 -48.0(4) . . . . ?
C21 C26 C25 C24 1.3(4) . . . . ?
C21 C22 C23 C24 -0.1(4) . . . . ?
C41 C40 C45 C44 -69.8(3) . . . . ?
C41 C40 C45 C46 33.8(3) . . . . ?
C41 C42 C43 Rh1 5.2(2) . . . . ?
C41 C42 C43 C44 -69.6(3) . . . . ?
C41 C42 C46 C45 53.7(3) . . . . ?
C50 C49 C48 C47 0.9(4) . . . . ?
C14 N1 C13 P1 172.66(19) . . . . ?
C14 C19 C18 C17 1.2(4) . . . . ?
C14 C15 C16 C17 0.6(5) . . . . ?
C12 C7 C8 C9 0.0(4) . . . . ?
C12 C11 C10 C9 1.3(4) . . . . ?
C19 N2 C21 C26 -86.5(3) . . . . ?
C19 N2 C21 C22 94.7(3) . . . . ?
C19 C14 C15 C16 1.3(4) . . . . ?
C19 C18 C17 C16 0.8(5) . . . . ?
C45 C40 C41 Rh1 99.42(19) . . . . ?
C45 C40 C41 C42 1.0(3) . . . . ?
C45 C44 C43 Rh1 -88.0(2) . . . . ?
C45 C44 C43 C42 -0.1(3) . . . . ?
C39 C34 C35 C36 -2.5(4) . . . . ?
C39 C38 C37 C36 -1.6(4) . . . . ?
C48 C49 C50 C51 -1.1(4) . . . . ?
C1 P1 C13 N1 84.7(2) . . . . ?
C1 P1 C7 C12 -145.2(2) . . . . ?
C1 P1 C7 C8 35.3(3) . . . . ?
C1 C6 C5 C4 -0.5(5) . . . . ?
C1 C2 C3 C4 0.2(5) . . . . ?
C35 C34 C39 C38 1.9(4) . . . . ?
C22 C23 C24 C25 -1.0(4) . . . . ?
C33 C28 C29 C30 -0.6(5) . . . . ?
C33 C32 C31 C30 -0.7(5) . . . . ?
C29 C28 C33 C32 0.5(4) . . . . ?
C29 C30 C31 C32 0.6(5) . . . . ?
C44 C45 C46 C42 51.5(3) . . . . ?
C8 C7 C12 C11 0.1(4) . . . . ?
C38 C37 C36 C35 1.0(5) . . . . ?
C15 C14 C19 N2 174.4(2) . . . . ?
C15 C14 C19 C18 -2.2(4) . . . . ?
C15 C16 C17 C18 -1.6(5) . . . . ?
C20 N2 C21 C26 147.8(2) . . . . ?
C20 N2 C21 C22 -30.9(4) . . . . ?
C20 N2 C19 C14 -96.0(3) . . . . ?
C20 N2 C19 C18 80.4(3) . . . . ?
C25 C26 C21 N2 178.9(2) . . . . ?
C25 C26 C21 C22 -2.4(4) . . . . ?
C43 C42 C46 C45 -51.2(3) . . . . ?
C11 C10 C9 C8 -1.2(4) . . . . ?
C6 C1 C2 C3 0.9(5) . . . . ?
C6 C5 C4 C3 1.7(5) . . . . ?
C52 N009 C49 C50 -179.7(3) . . . . ?
C52 N009 C49 C48 -0.2(4) . . . . ?
C2 C1 C6 C5 -0.7(5) . . . . ?
C2 C3 C4 C5 -1.5(5) . . . . ?
C46 C45 C44 Rh1 -107.2(2) . . . . ?
C46 C45 C44 C43 -33.9(3) . . . . ?
C46 C42 C43 Rh1 109.0(2) . . . . ?
C46 C42 C43 C44 34.3(3) . . . . ?
C53 N009 C49 C50 -5.7(4) . . . . ?
C53 N009 C49 C48 173.8(3) . . . . ?

_smtbx_masks_special_details     ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 0.000 0.500 0.500 297.4 48.7 ?
2 0.500 0.000 0.000 61.9 0.0 ?

_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: toluene/hexane'
_chemical_properties_physical    
Air-sensitive,Moisture-sensitive,Oxygen-sensitive
