# Electronic Supplementary Material (ESI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 2107116'
loop_
_audit_author_name
_audit_author_address
'Xiu-Mei Zhang'
;Huaibei Normal University
China
;
_audit_update_record             
;
2021-09-02 deposited with the CCDC.	2021-09-28 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C28 H30 Eu N2 O19.50'
_chemical_formula_weight         858.50

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           52
_space_group_name_H-M_alt        'P n n a'
_space_group_name_Hall           '-P 2a 2bc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z'
'-x+1/2, y+1/2, -z+1/2'
'x, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z'
'x-1/2, -y-1/2, z-1/2'
'-x, y-1/2, z-1/2'

_cell_length_a                   27.0123(16)
_cell_length_b                   21.1322(11)
_cell_length_c                   11.5913(6)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     6616.7(6)
_cell_formula_units_Z            8
_cell_measurement_temperature    298(2)
_cell_measurement_reflns_used    9924
_cell_measurement_theta_min      3.01
_cell_measurement_theta_max      27.43

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.724
_exptl_crystal_F_000             3448
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.100
_exptl_crystal_size_mid          0.080
_exptl_crystal_size_min          0.080
_exptl_absorpt_coefficient_mu    1.985
_shelx_estimated_absorpt_T_min   0.826
_shelx_estimated_absorpt_T_max   0.857
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      298(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            101208
_diffrn_reflns_av_unetI/netI     0.0225
_diffrn_reflns_av_R_equivalents  0.0700
_diffrn_reflns_limit_h_min       -32
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         2.865
_diffrn_reflns_theta_max         25.007
_diffrn_reflns_theta_full        25.007
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             5839
_reflns_number_gt                4728
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0223P)²+15.7609P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5839
_refine_ls_number_parameters     392
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0401
_refine_ls_R_factor_gt           0.0266
_refine_ls_wR_factor_ref         0.0628
_refine_ls_wR_factor_gt          0.0571
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_restrained_S_all      1.041
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.2500 0.0000 1.44698(2) 0.01741(7) Uani 1 2 d S T P . .
Eu2 Eu 0.44411(2) 0.2500 0.7500 0.02086(7) Uani 1 2 d S T P . .
O1 O 0.27627(11) 0.06600(13) 1.3004(2) 0.0409(7) Uani 1 1 d . . . . .
O2 O 0.32213(15) 0.15192(16) 1.2915(2) 0.0588(10) Uani 1 1 d D . . . .
H2 H 0.333(2) 0.157(3) 1.361(2) 0.088 Uiso 1 1 d D U . . .
O3 O 0.37865(10) 0.16283(13) 0.7604(2) 0.0375(7) Uani 1 1 d . . . . .
O4 O 0.38192(9) 0.22633(11) 0.9094(2) 0.0299(6) Uani 1 1 d . . . . .
O5 O 0.26066(18) -0.18246(14) 0.6061(3) 0.0842(15) Uani 1 1 d . . . . .
O6 O 0.25639(10) -0.08083(12) 0.5788(2) 0.0364(6) Uani 1 1 d . . . . .
O7 O 0.47413(11) 0.16839(13) 0.8716(2) 0.0425(7) Uani 1 1 d . . . . .
O8 O 0.53808(15) 0.15871(16) 0.9866(3) 0.0774(13) Uani 1 1 d . . . . .
O9 O 0.33414(9) 0.01856(12) 0.5305(2) 0.0345(6) Uani 1 1 d . . . . .
O10 O 0.33031(10) -0.05401(13) 0.3958(2) 0.0384(7) Uani 1 1 d . . . . .
O11 O 0.47663(10) -0.19839(13) 0.3376(3) 0.0458(8) Uani 1 1 d . . . . .
O12 O 0.54642(10) -0.17369(15) 0.4186(3) 0.0490(8) Uani 1 1 d . . . . .
N1 N 0.30497(14) -0.09545(14) 0.9906(3) 0.0412(9) Uani 1 1 d . . . . .
H1A H 0.3127 -0.0897 1.0618 0.049 Uiso 1 1 calc R U . . .
N2 N 0.53528(14) -0.04939(18) 0.7885(4) 0.0630(13) Uani 1 1 d . . . . .
H2A H 0.5413 -0.0869 0.7634 0.076 Uiso 1 1 calc R U . . .
C1 C 0.30391(14) 0.10361(17) 1.2474(3) 0.0319(8) Uani 1 1 d . . . . .
C2 C 0.31549(13) 0.09007(17) 1.1232(3) 0.0249(8) Uani 1 1 d . . . . .
C3 C 0.30770(13) 0.03006(17) 1.0784(3) 0.0268(8) Uani 1 1 d . . . . .
H3A H 0.2953 -0.0016 1.1260 0.032 Uiso 1 1 calc R U . . .
C4 C 0.31811(13) 0.01637(16) 0.9632(3) 0.0254(8) Uani 1 1 d . . . . .
C5 C 0.33729(13) 0.06418(16) 0.8938(3) 0.0253(8) Uani 1 1 d . . . . .
H5A H 0.3443 0.0559 0.8168 0.030 Uiso 1 1 calc R U . . .
C6 C 0.34601(13) 0.12407(16) 0.9382(3) 0.0237(8) Uani 1 1 d . . . . .
C7 C 0.33466(13) 0.13725(16) 1.0527(3) 0.0245(8) Uani 1 1 d . . . . .
H7A H 0.3399 0.1776 1.0821 0.029 Uiso 1 1 calc R U . . .
C8 C 0.36965(13) 0.17435(16) 0.8633(3) 0.0245(8) Uani 1 1 d . . . . .
C9 C 0.30688(14) -0.04735(17) 0.9159(3) 0.0277(8) Uani 1 1 d . . . . .
C10 C 0.2910(2) -0.15222(19) 0.9539(4) 0.0526(13) Uani 1 1 d . . . . .
H10A H 0.2899 -0.1852 1.0070 0.063 Uiso 1 1 calc R U . . .
C11 C 0.27817(18) -0.16482(18) 0.8419(3) 0.0447(11) Uani 1 1 d . . . . .
H11A H 0.2679 -0.2051 0.8199 0.054 Uiso 1 1 calc R U . . .
C12 C 0.28078(14) -0.11634(16) 0.7625(3) 0.0299(8) Uani 1 1 d . . . . .
C13 C 0.29512(13) -0.05671(16) 0.8003(3) 0.0263(8) Uani 1 1 d . . . . .
H13A H 0.2968 -0.0232 0.7485 0.032 Uiso 1 1 calc R U . . .
C14 C 0.26551(16) -0.12748(17) 0.6391(4) 0.0366(10) Uani 1 1 d . . . . .
C15 C 0.50967(15) 0.13801(19) 0.9128(3) 0.0359(10) Uani 1 1 d . . . . .
C16 C 0.51786(14) 0.07120(18) 0.8695(3) 0.0331(9) Uani 1 1 d . . . . .
C17 C 0.49027(14) 0.04649(19) 0.7793(3) 0.0348(9) Uani 1 1 d . . . . .
H17A H 0.4649 0.0702 0.7466 0.042 Uiso 1 1 calc R U . . .
C18 C 0.50063(14) -0.01350(19) 0.7383(4) 0.0419(11) Uani 1 1 d . . . . .
C19 C 0.56014(18) -0.0262(2) 0.8777(5) 0.0629(16) Uani 1 1 d . . . . .
H19A H 0.5833 -0.0521 0.9138 0.075 Uiso 1 1 calc R U . . .
C20 C 0.55339(17) 0.0341(2) 0.9196(4) 0.0492(12) Uani 1 1 d . . . . .
H20A H 0.5725 0.0493 0.9804 0.059 Uiso 1 1 calc R U . . .
C21 C 0.47513(14) -0.0409(2) 0.6354(4) 0.0425(11) Uani 1 1 d . . . . .
C22 C 0.42812(14) -0.02138(19) 0.6025(4) 0.0371(10) Uani 1 1 d . . . . .
H22A H 0.4122 0.0101 0.6447 0.044 Uiso 1 1 calc R U . . .
C23 C 0.40439(13) -0.04794(18) 0.5079(3) 0.0324(9) Uani 1 1 d . . . . .
C24 C 0.42798(14) -0.09553(18) 0.4457(4) 0.0353(10) Uani 1 1 d . . . . .
H24A H 0.4120 -0.1143 0.3833 0.042 Uiso 1 1 calc R U . . .
C25 C 0.47480(14) -0.1149(2) 0.4761(4) 0.0407(11) Uani 1 1 d . . . . .
C26 C 0.49836(14) -0.0873(2) 0.5693(4) 0.0507(13) Uani 1 1 d . . . . .
H26A H 0.5303 -0.0999 0.5881 0.061 Uiso 1 1 calc R U . . .
C27 C 0.50096(14) -0.1658(2) 0.4072(4) 0.0391(10) Uani 1 1 d . . . . .
C28 C 0.35392(13) -0.02630(17) 0.4749(3) 0.0278(8) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O6 2.298(2) 2_556 ?
Eu1 O6 2.298(2) 1_556 ?
Eu1 O1 2.310(3) 2 ?
Eu1 O1 2.310(3) . ?
Eu1 O9 2.501(2) 1_556 ?
Eu1 O9 2.501(2) 2_556 ?
Eu1 O10 2.522(3) 2_556 ?
Eu1 O10 2.522(3) 1_556 ?
Eu1 C28 2.880(4) 1_556 ?
Eu1 C28 2.880(4) 2_556 ?
Eu2 O7 2.370(3) 4_556 ?
Eu2 O7 2.370(3) . ?
Eu2 O4 2.547(2) . ?
Eu2 O4 2.547(2) 4_556 ?
Eu2 O12 2.547(3) 8_666 ?
Eu2 O12 2.547(3) 5_656 ?
Eu2 O3 2.556(2) 4_556 ?
Eu2 O3 2.556(2) . ?
Eu2 O11 2.608(3) 8_666 ?
Eu2 O11 2.608(3) 5_656 ?
Eu2 C8 2.886(3) 4_556 ?
Eu2 C8 2.886(3) . ?
O1 C1 1.252(4) . ?
O2 C1 1.243(5) . ?
O3 C8 1.242(4) . ?
O4 C8 1.265(4) . ?
O5 C14 1.230(5) . ?
O6 C14 1.233(4) . ?
O6 Eu1 2.298(2) 1_554 ?
O7 C15 1.250(5) . ?
O8 C15 1.230(5) . ?
O9 C28 1.264(4) . ?
O9 Eu1 2.501(2) 1_554 ?
O10 C28 1.261(4) . ?
O10 Eu1 2.522(3) 1_554 ?
O11 C27 1.248(5) . ?
O11 Eu2 2.609(3) 5_656 ?
O12 C27 1.246(5) . ?
O12 Eu2 2.547(3) 5_656 ?
N1 C10 1.328(5) . ?
N1 C9 1.336(5) . ?
N1 H1A 0.8600 . ?
N2 C19 1.326(6) . ?
N2 C18 1.338(5) . ?
N2 H2A 0.8600 . ?
C1 C2 1.501(5) . ?
C2 C3 1.386(5) . ?
C2 C7 1.390(5) . ?
C3 C4 1.395(5) . ?
C3 H3A 0.9300 . ?
C4 C5 1.391(5) . ?
C4 C9 1.485(5) . ?
C5 C6 1.386(5) . ?
C5 H5A 0.9300 . ?
C6 C7 1.390(5) . ?
C6 C8 1.513(5) . ?
C7 H7A 0.9300 . ?
C9 C13 1.392(5) . ?
C10 C11 1.370(6) . ?
C10 H10A 0.9300 . ?
C11 C12 1.379(5) . ?
C11 H11A 0.9300 . ?
C12 C13 1.389(5) . ?
C12 C14 1.507(5) . ?
C13 H13A 0.9300 . ?
C15 C16 1.515(5) . ?
C16 C20 1.368(5) . ?
C16 C17 1.386(5) . ?
C17 C18 1.383(5) . ?
C17 H17A 0.9300 . ?
C18 C21 1.494(5) . ?
C19 C20 1.378(6) . ?
C19 H19A 0.9300 . ?
C20 H20A 0.9300 . ?
C21 C22 1.389(5) . ?
C21 C26 1.393(5) . ?
C22 C23 1.389(5) . ?
C22 H22A 0.9300 . ?
C23 C24 1.392(5) . ?
C23 C28 1.488(5) . ?
C24 C25 1.375(5) . ?
C24 H24A 0.9300 . ?
C25 C26 1.383(6) . ?
C25 C27 1.514(5) . ?
C26 H26A 0.9300 . ?
C27 Eu2 2.948(4) 5_656 ?
C28 Eu1 2.880(4) 1_554 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O6 Eu1 O6 96.66(13) 2_556 1_556 ?
O6 Eu1 O1 156.16(10) 2_556 2 ?
O6 Eu1 O1 93.62(10) 1_556 2 ?
O6 Eu1 O1 93.62(10) 2_556 . ?
O6 Eu1 O1 156.16(10) 1_556 . ?
O1 Eu1 O1 85.31(14) 2 . ?
O6 Eu1 O9 72.22(9) 2_556 1_556 ?
O6 Eu1 O9 77.94(9) 1_556 1_556 ?
O1 Eu1 O9 131.18(9) 2 1_556 ?
O1 Eu1 O9 84.87(10) . 1_556 ?
O6 Eu1 O9 77.94(9) 2_556 2_556 ?
O6 Eu1 O9 72.22(9) 1_556 2_556 ?
O1 Eu1 O9 84.87(10) 2 2_556 ?
O1 Eu1 O9 131.18(9) . 2_556 ?
O9 Eu1 O9 134.48(13) 1_556 2_556 ?
O6 Eu1 O10 75.85(10) 2_556 2_556 ?
O6 Eu1 O10 123.88(9) 1_556 2_556 ?
O1 Eu1 O10 80.56(10) 2 2_556 ?
O1 Eu1 O10 79.51(9) . 2_556 ?
O9 Eu1 O10 143.29(9) 1_556 2_556 ?
O9 Eu1 O10 51.71(8) 2_556 2_556 ?
O6 Eu1 O10 123.88(9) 2_556 1_556 ?
O6 Eu1 O10 75.85(10) 1_556 1_556 ?
O1 Eu1 O10 79.51(9) 2 1_556 ?
O1 Eu1 O10 80.55(10) . 1_556 ?
O9 Eu1 O10 51.71(8) 1_556 1_556 ?
O9 Eu1 O10 143.29(9) 2_556 1_556 ?
O10 Eu1 O10 152.77(12) 2_556 1_556 ?
O6 Eu1 C28 98.16(10) 2_556 1_556 ?
O6 Eu1 C28 73.06(10) 1_556 1_556 ?
O1 Eu1 C28 105.41(10) 2 1_556 ?
O1 Eu1 C28 84.25(11) . 1_556 ?
O9 Eu1 C28 25.97(9) 1_556 1_556 ?
O9 Eu1 C28 144.29(10) 2_556 1_556 ?
O10 Eu1 C28 162.21(10) 2_556 1_556 ?
O10 Eu1 C28 25.94(9) 1_556 1_556 ?
O6 Eu1 C28 73.06(10) 2_556 2_556 ?
O6 Eu1 C28 98.16(10) 1_556 2_556 ?
O1 Eu1 C28 84.25(11) 2 2_556 ?
O1 Eu1 C28 105.41(10) . 2_556 ?
O9 Eu1 C28 144.29(10) 1_556 2_556 ?
O9 Eu1 C28 25.97(9) 2_556 2_556 ?
O10 Eu1 C28 25.94(9) 2_556 2_556 ?
O10 Eu1 C28 162.21(10) 1_556 2_556 ?
C28 Eu1 C28 167.09(15) 1_556 2_556 ?
O7 Eu2 O7 139.99(15) 4_556 . ?
O7 Eu2 O4 143.13(9) 4_556 . ?
O7 Eu2 O4 69.60(9) . . ?
O7 Eu2 O4 69.60(9) 4_556 4_556 ?
O7 Eu2 O4 143.13(9) . 4_556 ?
O4 Eu2 O4 97.45(12) . 4_556 ?
O7 Eu2 O12 87.79(10) 4_556 8_666 ?
O7 Eu2 O12 88.28(10) . 8_666 ?
O4 Eu2 O12 68.52(9) . 8_666 ?
O4 Eu2 O12 119.90(9) 4_556 8_666 ?
O7 Eu2 O12 88.28(10) 4_556 5_656 ?
O7 Eu2 O12 87.79(10) . 5_656 ?
O4 Eu2 O12 119.90(9) . 5_656 ?
O4 Eu2 O12 68.52(9) 4_556 5_656 ?
O12 Eu2 O12 168.48(12) 8_666 5_656 ?
O7 Eu2 O3 71.60(9) 4_556 4_556 ?
O7 Eu2 O3 142.08(9) . 4_556 ?
O4 Eu2 O3 73.70(8) . 4_556 ?
O4 Eu2 O3 50.81(8) 4_556 4_556 ?
O12 Eu2 O3 69.46(9) 8_666 4_556 ?
O12 Eu2 O3 119.32(9) 5_656 4_556 ?
O7 Eu2 O3 142.08(9) 4_556 . ?
O7 Eu2 O3 71.60(9) . . ?
O4 Eu2 O3 50.81(8) . . ?
O4 Eu2 O3 73.70(8) 4_556 . ?
O12 Eu2 O3 119.32(9) 8_666 . ?
O12 Eu2 O3 69.46(9) 5_656 . ?
O3 Eu2 O3 92.47(13) 4_556 . ?
O7 Eu2 O11 69.30(10) 4_556 8_666 ?
O7 Eu2 O11 77.99(10) . 8_666 ?
O4 Eu2 O11 109.94(9) . 8_666 ?
O4 Eu2 O11 137.88(9) 4_556 8_666 ?
O12 Eu2 O11 49.77(8) 8_666 8_666 ?
O12 Eu2 O11 118.76(8) 5_656 8_666 ?
O3 Eu2 O11 106.54(9) 4_556 8_666 ?
O3 Eu2 O11 148.29(9) . 8_666 ?
O7 Eu2 O11 77.99(10) 4_556 5_656 ?
O7 Eu2 O11 69.31(10) . 5_656 ?
O4 Eu2 O11 137.88(9) . 5_656 ?
O4 Eu2 O11 109.95(9) 4_556 5_656 ?
O12 Eu2 O11 118.76(8) 8_666 5_656 ?
O12 Eu2 O11 49.77(8) 5_656 5_656 ?
O3 Eu2 O11 148.29(9) 4_556 5_656 ?
O3 Eu2 O11 106.54(9) . 5_656 ?
O11 Eu2 O11 69.68(12) 8_666 5_656 ?
O7 Eu2 C8 64.20(10) 4_556 4_556 ?
O7 Eu2 C8 155.81(10) . 4_556 ?
O4 Eu2 C8 88.81(9) . 4_556 ?
O4 Eu2 C8 25.99(9) 4_556 4_556 ?
O12 Eu2 C8 93.93(10) 8_666 4_556 ?
O12 Eu2 C8 94.09(10) 5_656 4_556 ?
O3 Eu2 C8 25.48(9) 4_556 4_556 ?
O3 Eu2 C8 86.47(9) . 4_556 ?
O11 Eu2 C8 121.18(10) 8_666 4_556 ?
O11 Eu2 C8 128.79(10) 5_656 4_556 ?
O7 Eu2 C8 155.81(10) 4_556 . ?
O7 Eu2 C8 64.19(10) . . ?
O4 Eu2 C8 25.99(9) . . ?
O4 Eu2 C8 88.81(9) 4_556 . ?
O12 Eu2 C8 94.09(10) 8_666 . ?
O12 Eu2 C8 93.93(10) 5_656 . ?
O3 Eu2 C8 86.47(9) 4_556 . ?
O3 Eu2 C8 25.48(9) . . ?
O11 Eu2 C8 128.79(10) 8_666 . ?
O11 Eu2 C8 121.18(10) 5_656 . ?
C8 Eu2 C8 91.62(13) 4_556 . ?
C1 O1 Eu1 158.1(3) . . ?
C8 O3 Eu2 92.3(2) . . ?
C8 O4 Eu2 92.1(2) . . ?
C14 O6 Eu1 170.4(3) . 1_554 ?
C15 O7 Eu2 149.7(3) . . ?
C28 O9 Eu1 94.0(2) . 1_554 ?
C28 O10 Eu1 93.1(2) . 1_554 ?
C27 O11 Eu2 92.9(2) . 5_656 ?
C27 O12 Eu2 95.9(2) . 5_656 ?
C10 N1 C9 119.4(3) . . ?
C10 N1 H1A 120.3 . . ?
C9 N1 H1A 120.3 . . ?
C19 N2 C18 119.0(4) . . ?
C19 N2 H2A 120.5 . . ?
C18 N2 H2A 120.5 . . ?
O2 C1 O1 123.8(4) . . ?
O2 C1 C2 117.9(3) . . ?
O1 C1 C2 118.3(3) . . ?
C3 C2 C7 119.5(3) . . ?
C3 C2 C1 120.1(3) . . ?
C7 C2 C1 120.3(3) . . ?
C2 C3 C4 121.2(3) . . ?
C2 C3 H3A 119.4 . . ?
C4 C3 H3A 119.4 . . ?
C5 C4 C3 118.5(3) . . ?
C5 C4 C9 121.4(3) . . ?
C3 C4 C9 120.0(3) . . ?
C6 C5 C4 120.8(3) . . ?
C6 C5 H5A 119.6 . . ?
C4 C5 H5A 119.6 . . ?
C5 C6 C7 120.0(3) . . ?
C5 C6 C8 120.0(3) . . ?
C7 C6 C8 120.0(3) . . ?
C2 C7 C6 120.0(3) . . ?
C2 C7 H7A 120.0 . . ?
C6 C7 H7A 120.0 . . ?
O3 C8 O4 121.6(3) . . ?
O3 C8 C6 119.7(3) . . ?
O4 C8 C6 118.6(3) . . ?
O3 C8 Eu2 62.27(18) . . ?
O4 C8 Eu2 61.87(18) . . ?
C6 C8 Eu2 160.8(2) . . ?
N1 C9 C13 120.5(3) . . ?
N1 C9 C4 117.3(3) . . ?
C13 C9 C4 122.1(3) . . ?
N1 C10 C11 123.5(4) . . ?
N1 C10 H10A 118.3 . . ?
C11 C10 H10A 118.3 . . ?
C10 C11 C12 118.4(4) . . ?
C10 C11 H11A 120.8 . . ?
C12 C11 H11A 120.8 . . ?
C11 C12 C13 118.6(4) . . ?
C11 C12 C14 120.2(3) . . ?
C13 C12 C14 121.1(3) . . ?
C12 C13 C9 119.8(3) . . ?
C12 C13 H13A 120.1 . . ?
C9 C13 H13A 120.1 . . ?
O5 C14 O6 123.9(4) . . ?
O5 C14 C12 118.1(3) . . ?
O6 C14 C12 117.9(3) . . ?
O8 C15 O7 124.2(4) . . ?
O8 C15 C16 118.1(4) . . ?
O7 C15 C16 117.7(3) . . ?
C20 C16 C17 118.8(4) . . ?
C20 C16 C15 119.7(3) . . ?
C17 C16 C15 121.5(3) . . ?
C18 C17 C16 119.7(4) . . ?
C18 C17 H17A 120.1 . . ?
C16 C17 H17A 120.1 . . ?
N2 C18 C17 120.8(4) . . ?
N2 C18 C21 116.8(3) . . ?
C17 C18 C21 122.4(4) . . ?
N2 C19 C20 123.3(4) . . ?
N2 C19 H19A 118.3 . . ?
C20 C19 H19A 118.3 . . ?
C16 C20 C19 118.3(4) . . ?
C16 C20 H20A 120.9 . . ?
C19 C20 H20A 120.9 . . ?
C22 C21 C26 118.0(4) . . ?
C22 C21 C18 121.7(3) . . ?
C26 C21 C18 120.3(4) . . ?
C21 C22 C23 121.3(3) . . ?
C21 C22 H22A 119.4 . . ?
C23 C22 H22A 119.4 . . ?
C22 C23 C24 119.3(3) . . ?
C22 C23 C28 120.1(3) . . ?
C24 C23 C28 120.5(3) . . ?
C25 C24 C23 120.2(4) . . ?
C25 C24 H24A 119.9 . . ?
C23 C24 H24A 119.9 . . ?
C24 C25 C26 119.8(3) . . ?
C24 C25 C27 120.4(4) . . ?
C26 C25 C27 119.8(4) . . ?
C25 C26 C21 121.3(4) . . ?
C25 C26 H26A 119.3 . . ?
C21 C26 H26A 119.3 . . ?
O11 C27 O12 120.9(4) . . ?
O11 C27 C25 119.1(4) . . ?
O12 C27 C25 120.0(4) . . ?
O11 C27 Eu2 62.09(19) . 5_656 ?
O12 C27 Eu2 59.2(2) . 5_656 ?
C25 C27 Eu2 171.7(3) . 5_656 ?
O10 C28 O9 120.3(3) . . ?
O10 C28 C23 120.5(3) . . ?
O9 C28 C23 119.1(3) . . ?
O10 C28 Eu1 61.00(18) . 1_554 ?
O9 C28 Eu1 60.05(18) . 1_554 ?
C23 C28 Eu1 168.9(3) . 1_554 ?

_refine_diff_density_max         0.619
_refine_diff_density_min         -0.512
_refine_diff_density_rms         0.080




