# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_09072017_49_0m
_database_code_depnum_ccdc_archive 'CCDC 2080226'
loop_
_audit_author_name
_audit_author_address
'S. Masoud Nabavizadeh'
;Shiraz University
Iran
;
_audit_update_record             
;
2021-04-26 deposited with the CCDC.	2021-09-13 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C42 H46 I2 N2 P2 Pt2'
_chemical_formula_weight         1284.73

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.721(3)
_cell_length_b                   13.229(4)
_cell_length_c                   14.256(4)
_cell_angle_alpha                71.461(11)
_cell_angle_beta                 84.633(8)
_cell_angle_gamma                76.338(6)
_cell_volume                     2036.1(10)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    330
_cell_measurement_theta_min      2.7
_cell_measurement_theta_max      28.6

_exptl_crystal_description       rod
_exptl_crystal_colour            pale_yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.096
_exptl_crystal_F_000             1208
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.050
_exptl_absorpt_coefficient_mu    8.490
_shelx_estimated_absorpt_T_min   0.282
_shelx_estimated_absorpt_T_max   0.676
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4740
_exptl_absorpt_correction_T_max  0.7455
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker Kappa Apex II'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            12953
_diffrn_reflns_av_unetI/netI     0.0865
_diffrn_reflns_av_R_equivalents  0.0476
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_theta_min         1.507
_diffrn_reflns_theta_max         27.219
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.952
_diffrn_measured_fraction_theta_full 0.960
_diffrn_reflns_Laue_measured_fraction_max 0.952
_diffrn_reflns_Laue_measured_fraction_full 0.960
_diffrn_reflns_point_group_measured_fraction_max 0.952
_diffrn_reflns_point_group_measured_fraction_full 0.960
_reflns_number_total             8645
_reflns_number_gt                6177
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0562P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         8645
_refine_ls_number_parameters     455
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0801
_refine_ls_R_factor_gt           0.0475
_refine_ls_wR_factor_ref         0.1188
_refine_ls_wR_factor_gt          0.1048
_refine_ls_goodness_of_fit_ref   0.992
_refine_ls_restrained_S_all      0.992
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.6370(10) 0.3861(9) 0.9394(8) 0.028(3) Uani 1 1 d . . . . .
H1A H 0.6933 0.4036 0.9752 0.042 Uiso 1 1 calc R U . . .
H1B H 0.6510 0.3067 0.9537 0.042 Uiso 1 1 calc R U . . .
H1C H 0.5569 0.4138 0.9605 0.042 Uiso 1 1 calc R U . . .
C2 C 0.8123(9) 0.3969(8) 0.7856(8) 0.018(2) Uani 1 1 d . . . . .
C3 C 0.8455(9) 0.2881(9) 0.7894(8) 0.022(2) Uani 1 1 d . . . . .
H3 H 0.7878 0.2453 0.8035 0.027 Uiso 1 1 calc R U . . .
C4 C 0.9608(9) 0.2404(9) 0.7730(8) 0.024(2) Uani 1 1 d . . . . .
H4 H 0.9820 0.1655 0.7761 0.029 Uiso 1 1 calc R U . . .
C5 C 1.0462(9) 0.3036(9) 0.7519(8) 0.024(2) Uani 1 1 d . . . . .
H5 H 1.1259 0.2711 0.7416 0.029 Uiso 1 1 calc R U . . .
C6 C 1.0146(9) 0.4130(8) 0.7460(8) 0.024(2) Uani 1 1 d . . . . .
H6 H 1.0725 0.4557 0.7299 0.029 Uiso 1 1 calc R U . . .
C7 C 0.8976(9) 0.4617(9) 0.7635(8) 0.022(2) Uani 1 1 d . . . . .
H7 H 0.8763 0.5365 0.7607 0.027 Uiso 1 1 calc R U . . .
C8 C 0.6342(9) 0.5930(8) 0.8029(8) 0.019(2) Uani 1 1 d . . . . .
C9 C 0.6933(9) 0.6225(9) 0.8669(8) 0.025(3) Uani 1 1 d . . . . .
H9 H 0.7511 0.5687 0.9091 0.030 Uiso 1 1 calc R U . . .
C10 C 0.6695(10) 0.7280(9) 0.8702(9) 0.027(3) Uani 1 1 d . . . . .
H10 H 0.7108 0.7463 0.9145 0.032 Uiso 1 1 calc R U . . .
C11 C 0.5848(9) 0.8091(9) 0.8088(9) 0.024(2) Uani 1 1 d . . . . .
H11 H 0.5672 0.8821 0.8114 0.029 Uiso 1 1 calc R U . . .
C12 C 0.5273(10) 0.7794(10) 0.7440(9) 0.030(3) Uani 1 1 d . . . . .
H12 H 0.4698 0.8335 0.7018 0.036 Uiso 1 1 calc R U . . .
C13 C 0.5510(9) 0.6746(9) 0.7390(8) 0.021(2) Uani 1 1 d . . . . .
H13 H 0.5116 0.6571 0.6929 0.026 Uiso 1 1 calc R U . . .
C14 C 0.6040(9) 0.5210(8) 0.5803(8) 0.017(2) Uani 1 1 d . . . . .
C15 C 0.5444(8) 0.5312(7) 0.4950(7) 0.013(2) Uani 1 1 d . . . . .
C16 C 0.6493(9) 0.6506(8) 0.3880(8) 0.021(2) Uani 1 1 d . . . . .
H16 H 0.6638 0.6966 0.3238 0.025 Uiso 1 1 calc R U . . .
C17 C 0.7162(9) 0.6423(8) 0.4670(8) 0.021(2) Uani 1 1 d . . . . .
H17 H 0.7781 0.6801 0.4559 0.026 Uiso 1 1 calc R U . . .
C18 C 0.6926(8) 0.5785(8) 0.5625(8) 0.017(2) Uani 1 1 d . . . . .
H18 H 0.7379 0.5744 0.6159 0.021 Uiso 1 1 calc R U . . .
C19 C 0.1226(9) 0.7262(8) 0.8491(8) 0.019(2) Uani 1 1 d . . . . .
C20 C 0.2339(9) 0.6915(9) 0.8123(9) 0.026(3) Uani 1 1 d . . . . .
H20 H 0.2813 0.7430 0.7824 0.031 Uiso 1 1 calc R U . . .
C21 C 0.2770(9) 0.5813(9) 0.8189(8) 0.024(2) Uani 1 1 d . . . . .
H21 H 0.3530 0.5582 0.7934 0.029 Uiso 1 1 calc R U . . .
C22 C 0.2083(10) 0.5066(9) 0.8626(8) 0.025(2) Uani 1 1 d . . . . .
H22 H 0.2378 0.4316 0.8685 0.030 Uiso 1 1 calc R U . . .
C23 C 0.0968(10) 0.5408(9) 0.8977(8) 0.025(2) Uani 1 1 d . . . . .
H23 H 0.0493 0.4892 0.9260 0.030 Uiso 1 1 calc R U . . .
C24 C 0.0529(9) 0.6497(9) 0.8923(8) 0.020(2) Uani 1 1 d . . . . .
H24 H -0.0235 0.6722 0.9175 0.024 Uiso 1 1 calc R U . . .
C25 C -0.0705(9) 0.9014(7) 0.8865(7) 0.015(2) Uani 1 1 d . . . . .
C26 C -0.0993(9) 0.8451(9) 0.9848(8) 0.019(2) Uani 1 1 d . . . . .
H26 H -0.0406 0.7894 1.0243 0.023 Uiso 1 1 calc R U . . .
C27 C -0.2120(9) 0.8693(9) 1.0256(8) 0.022(2) Uani 1 1 d . . . . .
H27 H -0.2303 0.8301 1.0915 0.026 Uiso 1 1 calc R U . . .
C28 C -0.2971(10) 0.9528(9) 0.9666(9) 0.025(2) Uani 1 1 d . . . . .
H28 H -0.3738 0.9703 0.9935 0.030 Uiso 1 1 calc R U . . .
C29 C -0.2718(9) 1.0108(9) 0.8694(9) 0.026(3) Uani 1 1 d . . . . .
H29 H -0.3309 1.0664 0.8303 0.031 Uiso 1 1 calc R U . . .
C30 C -0.1560(9) 0.9854(8) 0.8294(8) 0.018(2) Uani 1 1 d . . . . .
H30 H -0.1371 1.0256 0.7640 0.022 Uiso 1 1 calc R U . . .
C31 C 0.1644(10) 0.8820(9) 0.9316(8) 0.024(2) Uani 1 1 d . . . . .
H31A H 0.1405 0.9557 0.9380 0.037 Uiso 1 1 calc R U . . .
H31B H 0.2480 0.8672 0.9133 0.037 Uiso 1 1 calc R U . . .
H31C H 0.1508 0.8285 0.9949 0.037 Uiso 1 1 calc R U . . .
C32 C 0.0363(9) 1.0358(7) 0.4729(7) 0.014(2) Uani 1 1 d . . . . .
C33 C 0.0218(9) 1.0859(8) 0.3688(7) 0.016(2) Uani 1 1 d . . . . .
C34 C 0.0933(9) 1.1567(7) 0.3225(8) 0.018(2) Uani 1 1 d . . . . .
H34 H 0.0878 1.1930 0.2534 0.022 Uiso 1 1 calc R U . . .
C35 C 0.1748(9) 1.1747(8) 0.3786(8) 0.019(2) Uani 1 1 d . . . . .
H35 H 0.2234 1.2244 0.3464 0.023 Uiso 1 1 calc R U . . .
C36 C 0.1862(9) 1.1227(9) 0.4783(8) 0.022(2) Uani 1 1 d . . . . .
H36 H 0.2442 1.1345 0.5135 0.026 Uiso 1 1 calc R U . . .
C37 C 0.0485(11) 0.6287(10) 0.5007(10) 0.035(3) Uani 1 1 d . . . . .
H37A H -0.0085 0.6948 0.4667 0.052 Uiso 1 1 calc R U . . .
H37B H 0.0085 0.5812 0.5539 0.052 Uiso 1 1 calc R U . . .
H37C H 0.0842 0.5898 0.4534 0.052 Uiso 1 1 calc R U . . .
C38 C 0.1428(10) 0.6600(9) 0.5439(8) 0.024(2) Uani 1 1 d . . . . .
H38A H 0.1072 0.6930 0.5960 0.028 Uiso 1 1 calc R U . . .
H38B H 0.2019 0.5931 0.5754 0.028 Uiso 1 1 calc R U . . .
C39 C 0.2034(10) 0.7390(9) 0.4682(9) 0.029(3) Uani 1 1 d . . . . .
H39A H 0.1430 0.8034 0.4341 0.034 Uiso 1 1 calc R U . . .
H39B H 0.2416 0.7039 0.4181 0.034 Uiso 1 1 calc R U . . .
C40 C 0.2952(10) 0.7790(9) 0.5068(8) 0.025(3) Uani 1 1 d . . . . .
H40A H 0.2582 0.8130 0.5581 0.030 Uiso 1 1 calc R U . . .
H40B H 0.3578 0.7154 0.5388 0.030 Uiso 1 1 calc R U . . .
C41 C 0.3506(10) 0.8612(10) 0.4271(9) 0.030(3) Uani 1 1 d . . . . .
H41A H 0.2877 0.9241 0.3945 0.036 Uiso 1 1 calc R U . . .
H41B H 0.3884 0.8268 0.3764 0.036 Uiso 1 1 calc R U . . .
C42 C 0.4425(12) 0.9039(11) 0.4652(10) 0.039(3) Uani 1 1 d . . . . .
H42A H 0.4037 0.9481 0.5075 0.059 Uiso 1 1 calc R U . . .
H42B H 0.4814 0.9488 0.4089 0.059 Uiso 1 1 calc R U . . .
H42C H 0.5011 0.8419 0.5035 0.059 Uiso 1 1 calc R U . . .
I1 I 0.46620(6) 0.26235(6) 0.84786(5) 0.02273(16) Uani 1 1 d . . . . .
I2 I 0.27580(6) 1.04775(5) 0.72357(5) 0.01913(15) Uani 1 1 d . . . . .
N1 N 0.5645(7) 0.5942(7) 0.4018(6) 0.0165(18) Uani 1 1 d . . . . .
N2 N 0.1148(7) 1.0544(6) 0.5268(5) 0.0129(17) Uani 1 1 d . . . . .
P1 P 0.6554(2) 0.4502(2) 0.8060(2) 0.0164(5) Uani 1 1 d . . . . .
P2 P 0.0790(2) 0.8720(2) 0.83671(18) 0.0137(5) Uani 1 1 d . . . . .
Pt1 Pt 0.54345(3) 0.41875(3) 0.70401(3) 0.01429(10) Uani 1 1 d . . . . .
Pt2 Pt 0.10381(3) 0.96935(3) 0.67986(3) 0.01408(10) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 P1 1.834(11) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C2 C3 1.384(14) . ?
C2 C7 1.417(15) . ?
C2 P1 1.839(10) . ?
C3 C4 1.382(14) . ?
C3 H3 0.9500 . ?
C4 C5 1.404(16) . ?
C4 H4 0.9500 . ?
C5 C6 1.384(14) . ?
C5 H5 0.9500 . ?
C6 C7 1.406(15) . ?
C6 H6 0.9500 . ?
C7 H7 0.9500 . ?
C8 C9 1.393(14) . ?
C8 C13 1.410(13) . ?
C8 P1 1.832(10) . ?
C9 C10 1.373(15) . ?
C9 H9 0.9500 . ?
C10 C11 1.401(15) . ?
C10 H10 0.9500 . ?
C11 C12 1.391(16) . ?
C11 H11 0.9500 . ?
C12 C13 1.372(15) . ?
C12 H12 0.9500 . ?
C13 H13 0.9500 . ?
C14 C18 1.386(14) . ?
C14 C15 1.412(13) . ?
C14 Pt1 2.036(11) . ?
C15 N1 1.359(13) . ?
C15 C15 1.446(19) 2_666 ?
C16 N1 1.343(13) . ?
C16 C17 1.393(15) . ?
C16 H16 0.9500 . ?
C17 C18 1.397(15) . ?
C17 H17 0.9500 . ?
C18 H18 0.9500 . ?
C19 C20 1.390(15) . ?
C19 C24 1.403(15) . ?
C19 P2 1.829(10) . ?
C20 C21 1.401(15) . ?
C20 H20 0.9500 . ?
C21 C22 1.379(16) . ?
C21 H21 0.9500 . ?
C22 C23 1.381(16) . ?
C22 H22 0.9500 . ?
C23 C24 1.390(14) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C25 C30 1.397(13) . ?
C25 C26 1.414(14) . ?
C25 P2 1.829(10) . ?
C26 C27 1.400(14) . ?
C26 H26 0.9500 . ?
C27 C28 1.403(15) . ?
C27 H27 0.9500 . ?
C28 C29 1.397(16) . ?
C28 H28 0.9500 . ?
C29 C30 1.429(14) . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?
C31 P2 1.811(11) . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 N2 1.363(13) . ?
C32 C32 1.42(2) 2_576 ?
C32 C33 1.428(14) . ?
C33 C34 1.375(14) . ?
C33 Pt2 2.051(10) 2_576 ?
C34 C35 1.407(14) . ?
C34 H34 0.9500 . ?
C35 C36 1.372(15) . ?
C35 H35 0.9500 . ?
C36 N2 1.359(14) . ?
C36 H36 0.9500 . ?
C37 C38 1.509(16) . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C38 C39 1.501(16) . ?
C38 H38A 0.9900 . ?
C38 H38B 0.9900 . ?
C39 C40 1.519(16) . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C40 C41 1.518(16) . ?
C40 H40A 0.9900 . ?
C40 H40B 0.9900 . ?
C41 C42 1.538(17) . ?
C41 H41A 0.9900 . ?
C41 H41B 0.9900 . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
I1 Pt1 2.6732(10) . ?
I2 Pt2 2.6760(9) . ?
N1 Pt1 2.128(8) 2_666 ?
N2 Pt2 2.121(7) . ?
P1 Pt1 2.238(3) . ?
P2 Pt2 2.229(3) . ?
Pt1 N1 2.128(8) 2_666 ?
Pt2 C33 2.051(10) 2_576 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 C1 H1A 109.5 . . ?
P1 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
P1 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C3 C2 C7 119.6(9) . . ?
C3 C2 P1 116.8(8) . . ?
C7 C2 P1 123.6(8) . . ?
C4 C3 C2 121.5(11) . . ?
C4 C3 H3 119.2 . . ?
C2 C3 H3 119.2 . . ?
C3 C4 C5 119.3(11) . . ?
C3 C4 H4 120.3 . . ?
C5 C4 H4 120.3 . . ?
C6 C5 C4 120.1(10) . . ?
C6 C5 H5 119.9 . . ?
C4 C5 H5 119.9 . . ?
C5 C6 C7 120.7(11) . . ?
C5 C6 H6 119.6 . . ?
C7 C6 H6 119.6 . . ?
C6 C7 C2 118.6(10) . . ?
C6 C7 H7 120.7 . . ?
C2 C7 H7 120.7 . . ?
C9 C8 C13 118.6(9) . . ?
C9 C8 P1 121.4(8) . . ?
C13 C8 P1 119.9(8) . . ?
C10 C9 C8 121.1(9) . . ?
C10 C9 H9 119.5 . . ?
C8 C9 H9 119.5 . . ?
C9 C10 C11 120.7(10) . . ?
C9 C10 H10 119.6 . . ?
C11 C10 H10 119.6 . . ?
C12 C11 C10 117.9(10) . . ?
C12 C11 H11 121.0 . . ?
C10 C11 H11 121.0 . . ?
C13 C12 C11 122.1(10) . . ?
C13 C12 H12 118.9 . . ?
C11 C12 H12 118.9 . . ?
C12 C13 C8 119.5(10) . . ?
C12 C13 H13 120.2 . . ?
C8 C13 H13 120.2 . . ?
C18 C14 C15 114.5(9) . . ?
C18 C14 Pt1 133.7(8) . . ?
C15 C14 Pt1 111.8(7) . . ?
N1 C15 C14 125.6(9) . . ?
N1 C15 C15 115.7(10) . 2_666 ?
C14 C15 C15 118.7(11) . 2_666 ?
N1 C16 C17 120.6(10) . . ?
N1 C16 H16 119.7 . . ?
C17 C16 H16 119.7 . . ?
C16 C17 C18 120.3(10) . . ?
C16 C17 H17 119.8 . . ?
C18 C17 H17 119.8 . . ?
C14 C18 C17 120.9(9) . . ?
C14 C18 H18 119.5 . . ?
C17 C18 H18 119.5 . . ?
C20 C19 C24 119.3(9) . . ?
C20 C19 P2 115.7(9) . . ?
C24 C19 P2 125.0(8) . . ?
C19 C20 C21 120.5(11) . . ?
C19 C20 H20 119.7 . . ?
C21 C20 H20 119.7 . . ?
C22 C21 C20 119.7(10) . . ?
C22 C21 H21 120.2 . . ?
C20 C21 H21 120.2 . . ?
C21 C22 C23 120.1(10) . . ?
C21 C22 H22 120.0 . . ?
C23 C22 H22 120.0 . . ?
C22 C23 C24 121.0(11) . . ?
C22 C23 H23 119.5 . . ?
C24 C23 H23 119.5 . . ?
C23 C24 C19 119.4(10) . . ?
C23 C24 H24 120.3 . . ?
C19 C24 H24 120.3 . . ?
C30 C25 C26 119.1(9) . . ?
C30 C25 P2 119.9(8) . . ?
C26 C25 P2 120.9(7) . . ?
C27 C26 C25 121.8(10) . . ?
C27 C26 H26 119.1 . . ?
C25 C26 H26 119.1 . . ?
C26 C27 C28 118.3(10) . . ?
C26 C27 H27 120.9 . . ?
C28 C27 H27 120.9 . . ?
C29 C28 C27 121.6(10) . . ?
C29 C28 H28 119.2 . . ?
C27 C28 H28 119.2 . . ?
C28 C29 C30 119.2(10) . . ?
C28 C29 H29 120.4 . . ?
C30 C29 H29 120.4 . . ?
C25 C30 C29 120.0(10) . . ?
C25 C30 H30 120.0 . . ?
C29 C30 H30 120.0 . . ?
P2 C31 H31A 109.5 . . ?
P2 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
P2 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
N2 C32 C32 115.9(11) . 2_576 ?
N2 C32 C33 124.2(9) . . ?
C32 C32 C33 119.9(12) 2_576 . ?
C34 C33 C32 116.1(9) . . ?
C34 C33 Pt2 133.7(8) . 2_576 ?
C32 C33 Pt2 110.1(7) . 2_576 ?
C33 C34 C35 119.3(10) . . ?
C33 C34 H34 120.3 . . ?
C35 C34 H34 120.3 . . ?
C36 C35 C34 122.0(10) . . ?
C36 C35 H35 119.0 . . ?
C34 C35 H35 119.0 . . ?
N2 C36 C35 120.2(10) . . ?
N2 C36 H36 119.9 . . ?
C35 C36 H36 119.9 . . ?
C38 C37 H37A 109.5 . . ?
C38 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C38 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C39 C38 C37 113.1(10) . . ?
C39 C38 H38A 109.0 . . ?
C37 C38 H38A 109.0 . . ?
C39 C38 H38B 109.0 . . ?
C37 C38 H38B 109.0 . . ?
H38A C38 H38B 107.8 . . ?
C38 C39 C40 116.2(10) . . ?
C38 C39 H39A 108.2 . . ?
C40 C39 H39A 108.2 . . ?
C38 C39 H39B 108.2 . . ?
C40 C39 H39B 108.2 . . ?
H39A C39 H39B 107.4 . . ?
C41 C40 C39 113.6(9) . . ?
C41 C40 H40A 108.8 . . ?
C39 C40 H40A 108.8 . . ?
C41 C40 H40B 108.8 . . ?
C39 C40 H40B 108.8 . . ?
H40A C40 H40B 107.7 . . ?
C40 C41 C42 114.3(10) . . ?
C40 C41 H41A 108.7 . . ?
C42 C41 H41A 108.7 . . ?
C40 C41 H41B 108.7 . . ?
C42 C41 H41B 108.7 . . ?
H41A C41 H41B 107.6 . . ?
C41 C42 H42A 109.5 . . ?
C41 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C41 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C16 N1 C15 118.1(9) . . ?
C16 N1 Pt1 129.4(7) . 2_666 ?
C15 N1 Pt1 112.4(7) . 2_666 ?
C36 N2 C32 118.1(8) . . ?
C36 N2 Pt2 129.4(7) . . ?
C32 N2 Pt2 112.4(6) . . ?
C8 P1 C1 99.7(5) . . ?
C8 P1 C2 108.7(5) . . ?
C1 P1 C2 101.9(5) . . ?
C8 P1 Pt1 115.8(3) . . ?
C1 P1 Pt1 117.7(4) . . ?
C2 P1 Pt1 111.5(3) . . ?
C31 P2 C19 101.9(5) . . ?
C31 P2 C25 101.5(5) . . ?
C19 P2 C25 108.9(5) . . ?
C31 P2 Pt2 119.1(4) . . ?
C19 P2 Pt2 109.6(3) . . ?
C25 P2 Pt2 114.7(3) . . ?
C14 Pt1 N1 81.3(4) . 2_666 ?
C14 Pt1 P1 93.9(3) . . ?
N1 Pt1 P1 174.2(2) 2_666 . ?
C14 Pt1 I1 170.4(3) . . ?
N1 Pt1 I1 91.7(2) 2_666 . ?
P1 Pt1 I1 93.39(8) . . ?
C33 Pt2 N2 81.5(4) 2_576 . ?
C33 Pt2 P2 92.6(3) 2_576 . ?
N2 Pt2 P2 174.1(2) . . ?
C33 Pt2 I2 174.0(3) 2_576 . ?
N2 Pt2 I2 92.7(2) . . ?
P2 Pt2 I2 93.14(7) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C7 C2 C3 C4 0.6(16) . . . . ?
P1 C2 C3 C4 178.6(8) . . . . ?
C2 C3 C4 C5 -0.1(16) . . . . ?
C3 C4 C5 C6 -1.0(16) . . . . ?
C4 C5 C6 C7 1.7(16) . . . . ?
C5 C6 C7 C2 -1.2(16) . . . . ?
C3 C2 C7 C6 0.0(15) . . . . ?
P1 C2 C7 C6 -177.8(8) . . . . ?
C13 C8 C9 C10 1.7(17) . . . . ?
P1 C8 C9 C10 -174.2(9) . . . . ?
C8 C9 C10 C11 -0.1(18) . . . . ?
C9 C10 C11 C12 -0.9(18) . . . . ?
C10 C11 C12 C13 0.1(18) . . . . ?
C11 C12 C13 C8 1.5(18) . . . . ?
C9 C8 C13 C12 -2.4(16) . . . . ?
P1 C8 C13 C12 173.6(9) . . . . ?
C18 C14 C15 N1 -2.7(14) . . . . ?
Pt1 C14 C15 N1 179.4(7) . . . . ?
C18 C14 C15 C15 176.1(10) . . . 2_666 ?
Pt1 C14 C15 C15 -1.8(13) . . . 2_666 ?
N1 C16 C17 C18 -2.6(15) . . . . ?
C15 C14 C18 C17 1.4(14) . . . . ?
Pt1 C14 C18 C17 178.7(8) . . . . ?
C16 C17 C18 C14 1.1(15) . . . . ?
C24 C19 C20 C21 -0.6(16) . . . . ?
P2 C19 C20 C21 179.3(8) . . . . ?
C19 C20 C21 C22 -0.2(17) . . . . ?
C20 C21 C22 C23 1.4(16) . . . . ?
C21 C22 C23 C24 -1.7(17) . . . . ?
C22 C23 C24 C19 0.9(16) . . . . ?
C20 C19 C24 C23 0.3(15) . . . . ?
P2 C19 C24 C23 -179.6(8) . . . . ?
C30 C25 C26 C27 1.7(15) . . . . ?
P2 C25 C26 C27 177.6(7) . . . . ?
C25 C26 C27 C28 -0.8(15) . . . . ?
C26 C27 C28 C29 0.4(16) . . . . ?
C27 C28 C29 C30 -0.8(16) . . . . ?
C26 C25 C30 C29 -2.1(15) . . . . ?
P2 C25 C30 C29 -178.0(8) . . . . ?
C28 C29 C30 C25 1.7(16) . . . . ?
N2 C32 C33 C34 0.1(14) . . . . ?
C32 C32 C33 C34 178.1(10) 2_576 . . . ?
N2 C32 C33 Pt2 178.8(7) . . . 2_576 ?
C32 C32 C33 Pt2 -3.2(13) 2_576 . . 2_576 ?
C32 C33 C34 C35 0.4(14) . . . . ?
Pt2 C33 C34 C35 -177.9(7) 2_576 . . . ?
C33 C34 C35 C36 0.8(15) . . . . ?
C34 C35 C36 N2 -2.5(16) . . . . ?
C37 C38 C39 C40 176.9(9) . . . . ?
C38 C39 C40 C41 -178.3(9) . . . . ?
C39 C40 C41 C42 179.1(10) . . . . ?
C17 C16 N1 C15 1.5(14) . . . . ?
C17 C16 N1 Pt1 -175.4(7) . . . 2_666 ?
C14 C15 N1 C16 1.2(14) . . . . ?
C15 C15 N1 C16 -177.5(10) 2_666 . . . ?
C14 C15 N1 Pt1 178.7(7) . . . 2_666 ?
C15 C15 N1 Pt1 -0.1(12) 2_666 . . 2_666 ?
C35 C36 N2 C32 2.9(14) . . . . ?
C35 C36 N2 Pt2 -176.4(7) . . . . ?
C32 C32 N2 C36 -179.9(10) 2_576 . . . ?
C33 C32 N2 C36 -1.8(14) . . . . ?
C32 C32 N2 Pt2 -0.5(13) 2_576 . . . ?
C33 C32 N2 Pt2 177.6(7) . . . . ?
C9 C8 P1 C1 48.7(10) . . . . ?
C13 C8 P1 C1 -127.1(9) . . . . ?
C9 C8 P1 C2 -57.5(11) . . . . ?
C13 C8 P1 C2 126.6(9) . . . . ?
C9 C8 P1 Pt1 176.1(8) . . . . ?
C13 C8 P1 Pt1 0.2(10) . . . . ?
C3 C2 P1 C8 177.6(8) . . . . ?
C7 C2 P1 C8 -4.5(10) . . . . ?
C3 C2 P1 C1 72.8(9) . . . . ?
C7 C2 P1 C1 -109.3(9) . . . . ?
C3 C2 P1 Pt1 -53.6(9) . . . . ?
C7 C2 P1 Pt1 124.3(8) . . . . ?
C20 C19 P2 C31 -74.6(9) . . . . ?
C24 C19 P2 C31 105.3(10) . . . . ?
C20 C19 P2 C25 178.7(8) . . . . ?
C24 C19 P2 C25 -1.4(10) . . . . ?
C20 C19 P2 Pt2 52.5(9) . . . . ?
C24 C19 P2 Pt2 -127.6(8) . . . . ?
C30 C25 P2 C31 125.0(9) . . . . ?
C26 C25 P2 C31 -50.8(9) . . . . ?
C30 C25 P2 C19 -127.9(8) . . . . ?
C26 C25 P2 C19 56.3(9) . . . . ?
C30 C25 P2 Pt2 -4.7(9) . . . . ?
C26 C25 P2 Pt2 179.5(7) . . . . ?

_refine_diff_density_max         2.407
_refine_diff_density_min         -3.180
_refine_diff_density_rms         0.277

