# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 2101581'
loop_
_audit_author_name
_audit_author_address
'Kazuhiro Uemura'
;Gifu University
Japan
;
_audit_update_record             
;
2021-11-29 deposited with the CCDC.	2021-12-06 downloaded from the CCDC.
;

_vrf_PLAT234_ALERT_4_B           
;
PROBLEM: Large Hirshfeld Difference C35 --C36 . 0.28 Ang.
RESPONSE: Atom C36 was found to be disordered.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C76 H172 F36 Mn3 N24 O16 P6 Pt6'
_chemical_formula_weight         3883.55

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.7933(3)
_cell_length_b                   17.2288(4)
_cell_length_c                   18.8687(5)
_cell_angle_alpha                63.799(2)
_cell_angle_beta                 81.414(2)
_cell_angle_gamma                83.195(2)
_cell_volume                     3395.37(16)
_cell_formula_units_Z            1
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    15825
_cell_measurement_theta_min      2.0410
_cell_measurement_theta_max      30.8250

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.899
_exptl_crystal_F_000             1881
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.350
_exptl_crystal_size_min          0.300
_exptl_absorpt_coefficient_mu    6.602
_shelx_estimated_absorpt_T_min   0.137
_shelx_estimated_absorpt_T_max   0.242
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.51897
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.40.53 (Rigaku Oxford Diffraction, 2019)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_oxdiff_exptl_absorpt_empirical_full_min 0.744
_oxdiff_exptl_absorpt_empirical_full_max 1.802
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
- Detector area scaling
;
_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_measurement_device_type  
'dtrek-CrysAlisPro-abstract goniometer imported rigaku-d*trek images'
_diffrn_measurement_method       'profile data from φ-scans'
_diffrn_detector_area_resol_mean 14.7059
_diffrn_reflns_number            26671
_diffrn_reflns_av_unetI/netI     0.0385
_diffrn_reflns_av_R_equivalents  0.0248
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         2.016
_diffrn_reflns_theta_max         27.499
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measured_fraction_theta_full 0.986
_diffrn_reflns_Laue_measured_fraction_max 0.981
_diffrn_reflns_Laue_measured_fraction_full 0.986
_diffrn_reflns_point_group_measured_fraction_max 0.981
_diffrn_reflns_point_group_measured_fraction_full 0.986
_reflns_number_total             15327
_reflns_number_gt                13083
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_cell_refinement       'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_data_reduction        'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_publication_material  
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'

_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1000P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         15327
_refine_ls_number_parameters     806
_refine_ls_number_restraints     102
_refine_ls_R_factor_all          0.0452
_refine_ls_R_factor_gt           0.0348
_refine_ls_wR_factor_ref         0.1116
_refine_ls_wR_factor_gt          0.0996
_refine_ls_goodness_of_fit_ref   0.835
_refine_ls_restrained_S_all      0.837
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt2 Pt 0.36377(2) 0.10065(2) 0.28717(2) 0.01879(6) Uani 1 1 d . . . . .
Pt3 Pt -0.01572(2) 0.38101(2) 0.45111(2) 0.01780(6) Uani 1 1 d . . . . .
Pt1 Pt 0.77314(2) 0.18309(2) 0.21334(2) 0.01893(6) Uani 1 1 d . . . . .
Mn1 Mn 0.55199(7) 0.19693(5) 0.16197(5) 0.02029(16) Uani 1 1 d . . . . .
Mn2 Mn 0.000000 0.500000 0.500000 0.0183(2) Uani 1 2 d S . P . .
P1 P 0.02226(12) 0.34228(9) 0.23593(9) 0.0233(3) Uani 1 1 d . . . . .
P2 P 0.35147(12) 0.18452(9) 0.52629(9) 0.0255(3) Uani 1 1 d . . . . .
P3 P 1.07670(14) -0.06141(10) 0.29719(11) 0.0331(3) Uani 1 1 d . . . . .
F1 F 0.1457(3) 0.3296(2) 0.1929(2) 0.0374(8) Uani 1 1 d . . . . .
F2 F 0.0717(3) 0.2942(2) 0.3209(2) 0.0335(8) Uani 1 1 d . . . . .
F4 F -0.0278(3) 0.3903(3) 0.1531(2) 0.0420(9) Uani 1 1 d . . . . .
F6 F 0.0583(3) 0.4331(2) 0.2287(2) 0.0330(8) Uani 1 1 d . . . . .
F10 F 0.4331(3) 0.1947(3) 0.4466(2) 0.0430(9) Uani 1 1 d . . . . .
F18 F 1.1051(4) -0.1599(2) 0.3132(3) 0.0541(12) Uani 1 1 d . . . . .
O7 O 0.2822(4) -0.0649(3) 0.5210(2) 0.0318(9) Uani 1 1 d . . . . .
O6 O -0.1525(3) 0.4479(2) 0.5751(2) 0.0251(8) Uani 1 1 d . . . . .
O5 O -0.1003(3) 0.5780(2) 0.4063(2) 0.0267(8) Uani 1 1 d . . . . .
F7 F 0.4607(3) 0.1732(3) 0.5700(3) 0.0570(12) Uani 1 1 d . . . . .
F9 F 0.2418(3) 0.1969(3) 0.4799(2) 0.0457(10) Uani 1 1 d . . . . .
F3 F -0.1002(3) 0.3567(2) 0.2802(2) 0.0360(8) Uani 1 1 d . . . . .
N4 N 0.7971(4) 0.2893(3) 0.1109(3) 0.0252(9) Uani 1 1 d . . . . .
H4 H 0.853768 0.321445 0.104894 0.030 Uiso 1 1 calc R U . . .
N2 N 0.7562(4) 0.0704(3) 0.3171(3) 0.0285(10) Uani 1 1 d . . . . .
H2 H 0.734377 0.083834 0.358920 0.043 Uiso 1 1 calc R U . . .
H2A H 0.824645 0.038953 0.324078 0.043 Uiso 1 1 calc R U . . .
H2B H 0.702055 0.038805 0.314095 0.043 Uiso 1 1 calc R U . . .
O2 O 0.6501(4) 0.2717(3) 0.0576(2) 0.0348(10) Uani 1 1 d . . . . .
O3 O 0.5945(3) 0.0648(2) 0.1913(3) 0.0291(9) Uani 1 1 d . . . . .
N6 N 0.4482(4) 0.0470(3) 0.3889(3) 0.0296(10) Uani 1 1 d . . . . .
H6 H 0.480172 0.089556 0.393953 0.044 Uiso 1 1 calc R U . . .
H6A H 0.504347 0.007473 0.385089 0.044 Uiso 1 1 calc R U . . .
H6B H 0.397143 0.020315 0.432164 0.044 Uiso 1 1 calc R U . . .
F13 F 1.1828(4) -0.0617(3) 0.3382(3) 0.0614(12) Uani 1 1 d . . . . .
N7 N 0.4285(4) 0.0044(3) 0.2584(3) 0.0239(9) Uani 1 1 d . . . . .
H7 H 0.389197 -0.042238 0.277466 0.029 Uiso 1 1 calc R U . . .
F8 F 0.2688(4) 0.1746(4) 0.6021(2) 0.0692(16) Uani 1 1 d . . . . .
F14 F 0.9971(4) -0.0910(3) 0.3808(3) 0.0617(13) Uani 1 1 d . . . . .
N5 N 0.3008(4) 0.2036(3) 0.3112(3) 0.0252(10) Uani 1 1 d . . . . .
H5 H 0.347875 0.248227 0.284369 0.038 Uiso 1 1 calc R U . . .
H5A H 0.297556 0.187498 0.364308 0.038 Uiso 1 1 calc R U . . .
H5B H 0.229111 0.220889 0.295573 0.038 Uiso 1 1 calc R U . . .
F5 F -0.0125(4) 0.2522(2) 0.2457(3) 0.0458(10) Uani 1 1 d . . . . .
O1 O 0.5256(3) 0.2735(2) 0.2243(3) 0.0277(8) Uani 1 1 d . . . . .
N12 N -0.1723(4) 0.3675(3) 0.5114(3) 0.0233(9) Uani 1 1 d . . . . .
H12 H -0.218225 0.335348 0.504375 0.028 Uiso 1 1 calc R U . . .
N8 N 0.2741(4) 0.1491(3) 0.1932(3) 0.0213(9) Uani 1 1 d . . . . .
H8 H 0.201700 0.136364 0.202337 0.026 Uiso 1 1 calc R U . . .
N10 N 0.1460(3) 0.4008(3) 0.3889(3) 0.0217(9) Uani 1 1 d . . . . .
H10 H 0.195791 0.356448 0.415954 0.033 Uiso 1 1 calc R U . . .
H10A H 0.170114 0.451681 0.383133 0.033 Uiso 1 1 calc R U . . .
H10B H 0.143308 0.402901 0.340088 0.033 Uiso 1 1 calc R U . . .
F12 F 0.3559(4) 0.0840(3) 0.5505(3) 0.0621(13) Uani 1 1 d . . . . .
O4 O 0.4147(4) 0.2207(3) 0.1003(2) 0.0395(11) Uani 1 1 d . . . . .
N1 N 0.8407(4) 0.1077(3) 0.1565(3) 0.0270(10) Uani 1 1 d . . . . .
H1 H 0.785553 0.074361 0.157473 0.040 Uiso 1 1 calc R U . . .
H1A H 0.900366 0.072859 0.181666 0.040 Uiso 1 1 calc R U . . .
H1B H 0.866144 0.142244 0.105250 0.040 Uiso 1 1 calc R U . . .
F11 F 0.3461(5) 0.2856(3) 0.4968(3) 0.0700(15) Uani 1 1 d . . . . .
N3 N 0.7008(4) 0.2608(3) 0.2646(3) 0.0224(9) Uani 1 1 d . . . . .
H3 H 0.739912 0.269475 0.296478 0.027 Uiso 1 1 calc R U . . .
N9 N 0.0471(4) 0.2841(3) 0.5501(3) 0.0237(9) Uani 1 1 d . . . . .
H9 H 0.094997 0.246658 0.535880 0.036 Uiso 1 1 calc R U . . .
H9A H -0.012199 0.255250 0.585072 0.036 Uiso 1 1 calc R U . . .
H9B H 0.086583 0.307433 0.573213 0.036 Uiso 1 1 calc R U . . .
N11 N -0.0768(4) 0.4795(3) 0.3567(3) 0.0241(9) Uani 1 1 d . . . . .
H11 H -0.081653 0.470275 0.314911 0.029 Uiso 1 1 calc R U . . .
F16 F 1.1551(5) -0.0311(3) 0.2153(3) 0.0660(13) Uani 1 1 d . . . . .
F15 F 0.9678(4) -0.0598(3) 0.2569(4) 0.0809(17) Uani 1 1 d . . . . .
C11 C 0.5234(4) 0.0055(3) 0.2141(3) 0.0210(10) Uani 1 1 d . . . . .
C6 C 0.7341(5) 0.3141(4) 0.0525(3) 0.0278(12) Uani 1 1 d . . . . .
F17 F 1.0444(4) 0.0376(3) 0.2804(4) 0.0767(17) Uani 1 1 d . . . . .
C26 C -0.2137(4) 0.4021(3) 0.5609(3) 0.0223(11) Uani 1 1 d . . . . .
C16 C 0.3115(4) 0.1970(3) 0.1210(3) 0.0218(10) Uani 1 1 d . . . . .
C31 C 0.2884(5) -0.1459(4) 0.5145(4) 0.0367(14) Uani 1 1 d . . . . .
H31 H 0.341550 -0.188729 0.550933 0.044 Uiso 1 1 calc R U . . .
H31A H 0.317132 -0.136925 0.459543 0.044 Uiso 1 1 calc R U . . .
C17 C 0.2356(5) 0.2285(4) 0.0526(3) 0.0281(12) Uani 1 1 d . . . . .
C1 C 0.5984(5) 0.2986(3) 0.2523(3) 0.0225(11) Uani 1 1 d . . . . .
C18 C 0.2369(6) 0.3284(4) 0.0099(4) 0.0410(16) Uani 1 1 d . . . . .
H18 H 0.199640 0.352944 0.046110 0.062 Uiso 1 1 calc R U . . .
H18A H 0.195422 0.350196 -0.037129 0.062 Uiso 1 1 calc R U . . .
H18B H 0.316529 0.345300 -0.006318 0.062 Uiso 1 1 calc R U . . .
C5 C 0.4346(5) 0.3955(4) 0.2747(4) 0.0305(13) Uani 1 1 d . . . . .
H5C H 0.402657 0.397771 0.228745 0.046 Uiso 1 1 calc R U . . .
H5D H 0.414515 0.450351 0.278875 0.046 Uiso 1 1 calc R U . . .
H5E H 0.402744 0.347758 0.323162 0.046 Uiso 1 1 calc R U . . .
C7 C 0.7599(6) 0.3952(4) -0.0235(4) 0.0387(14) Uani 1 1 d . . . . .
C34 C 0.1668(5) -0.0284(4) 0.5049(4) 0.0399(16) Uani 1 1 d . . . . .
H34 H 0.160380 -0.000804 0.447082 0.048 Uiso 1 1 calc R U . . .
H34A H 0.144549 0.015306 0.525926 0.048 Uiso 1 1 calc R U . . .
C27 C -0.3355(5) 0.3892(4) 0.6011(4) 0.0278(12) Uani 1 1 d . . . . .
C2 C 0.5666(5) 0.3810(3) 0.2643(4) 0.0270(12) Uani 1 1 d . . . . .
C32 C 0.1702(6) -0.1781(4) 0.5361(5) 0.0444(16) Uani 1 1 d . . . . .
H32 H 0.166386 -0.232321 0.585894 0.053 Uiso 1 1 calc R U . . .
H32A H 0.146886 -0.189135 0.493253 0.053 Uiso 1 1 calc R U . . .
C12 C 0.5537(5) -0.0642(3) 0.1833(3) 0.0271(12) Uani 1 1 d . . . . .
C4 C 0.6150(5) 0.3776(4) 0.3372(4) 0.0302(12) Uani 1 1 d . . . . .
H4A H 0.583302 0.329396 0.385282 0.045 Uiso 1 1 calc R U . . .
H4B H 0.593483 0.432167 0.341543 0.045 Uiso 1 1 calc R U . . .
H4C H 0.698870 0.369139 0.330972 0.045 Uiso 1 1 calc R U . . .
C3 C 0.6162(6) 0.4546(4) 0.1888(4) 0.0400(15) Uani 1 1 d . . . . .
H3A H 0.699972 0.445508 0.182559 0.060 Uiso 1 1 calc R U . . .
H3B H 0.595603 0.509743 0.192204 0.060 Uiso 1 1 calc R U . . .
H3C H 0.584819 0.455974 0.142958 0.060 Uiso 1 1 calc R U . . .
C19 C 0.1129(5) 0.2009(4) 0.0810(4) 0.0348(14) Uani 1 1 d . . . . .
H19 H 0.112918 0.137546 0.105006 0.052 Uiso 1 1 calc R U . . .
H19A H 0.067310 0.225533 0.035797 0.052 Uiso 1 1 calc R U . . .
H19B H 0.079299 0.221877 0.120605 0.052 Uiso 1 1 calc R U . . .
C14 C 0.4874(7) -0.1451(4) 0.2324(5) 0.0470(18) Uani 1 1 d . . . . .
H14 H 0.405321 -0.130778 0.226769 0.071 Uiso 1 1 calc R U . . .
H14A H 0.499602 -0.166995 0.288456 0.071 Uiso 1 1 calc R U . . .
H14B H 0.514598 -0.189509 0.213746 0.071 Uiso 1 1 calc R U . . .
C21 C -0.1101(4) 0.5566(3) 0.3522(3) 0.0210(10) Uani 1 1 d . . . . .
C22 C -0.1622(5) 0.6260(4) 0.2780(4) 0.0335(14) Uani 1 1 d . . . . .
C29 C -0.4013(5) 0.3346(4) 0.5773(5) 0.0394(16) Uani 1 1 d . . . . .
H29 H -0.387370 0.353917 0.519713 0.059 Uiso 1 1 calc R U . . .
H29A H -0.483676 0.341466 0.592668 0.059 Uiso 1 1 calc R U . . .
H29B H -0.375046 0.273517 0.604419 0.059 Uiso 1 1 calc R U . . .
C20 C 0.2916(6) 0.1908(4) -0.0045(4) 0.0380(15) Uani 1 1 d . . . . .
H20 H 0.367322 0.214057 -0.027192 0.057 Uiso 1 1 calc R U . . .
H20A H 0.243139 0.206559 -0.047363 0.057 Uiso 1 1 calc R U . . .
H20B H 0.300266 0.127551 0.024191 0.057 Uiso 1 1 calc R U . . .
C15 C 0.6813(6) -0.0893(5) 0.1836(5) 0.0464(18) Uani 1 1 d . . . . .
H15 H 0.698564 -0.137445 0.168553 0.070 Uiso 1 1 calc R U . . .
H15A H 0.703360 -0.107155 0.236889 0.070 Uiso 1 1 calc R U . . .
H15B H 0.724377 -0.039534 0.145454 0.070 Uiso 1 1 calc R U . . .
C33 C 0.0922(6) -0.1047(6) 0.5471(6) 0.056(2) Uani 1 1 d . . . . .
H33 H 0.020336 -0.094195 0.522114 0.068 Uiso 1 1 calc R U . . .
H33A H 0.072899 -0.118027 0.604001 0.068 Uiso 1 1 calc R U . . .
C28 C -0.3301(6) 0.3477(5) 0.6894(4) 0.0469(18) Uani 1 1 d . . . . .
H28 H -0.298615 0.287693 0.706386 0.070 Uiso 1 1 calc R U . . .
H28A H -0.407547 0.348199 0.716644 0.070 Uiso 1 1 calc R U . . .
H28B H -0.280619 0.380055 0.702743 0.070 Uiso 1 1 calc R U . . .
C30 C -0.3965(5) 0.4806(4) 0.5742(5) 0.0443(18) Uani 1 1 d . . . . .
H30 H -0.355204 0.516309 0.589162 0.066 Uiso 1 1 calc R U . . .
H30A H -0.475566 0.475975 0.600011 0.066 Uiso 1 1 calc R U . . .
H30B H -0.397421 0.507528 0.516400 0.066 Uiso 1 1 calc R U . . .
O8 O 0.8902(8) 0.1496(5) -0.0127(4) 0.098(2) Uani 1 1 d D U . . .
C23 C -0.0974(9) 0.7077(5) 0.2502(5) 0.069(3) Uani 1 1 d . . . . .
H23 H -0.014959 0.694105 0.241489 0.103 Uiso 1 1 calc R U . . .
H23A H -0.111565 0.729539 0.290914 0.103 Uiso 1 1 calc R U . . .
H23B H -0.124138 0.751925 0.200518 0.103 Uiso 1 1 calc R U . . .
C24 C -0.2878(6) 0.6420(5) 0.3059(5) 0.061(2) Uani 1 1 d . . . . .
H24 H -0.327494 0.682004 0.260040 0.091 Uiso 1 1 calc R U . . .
H24A H -0.291031 0.667197 0.343668 0.091 Uiso 1 1 calc R U . . .
H24B H -0.325383 0.586891 0.331829 0.091 Uiso 1 1 calc R U . . .
C13 C 0.5195(7) -0.0236(5) 0.0991(4) 0.0469(18) Uani 1 1 d . . . . .
H13 H 0.560452 0.029348 0.066968 0.070 Uiso 1 1 calc R U . . .
H13A H 0.436510 -0.009216 0.100495 0.070 Uiso 1 1 calc R U . . .
H13B H 0.539548 -0.064673 0.075592 0.070 Uiso 1 1 calc R U . . .
C9 C 0.8609(8) 0.4425(5) -0.0211(5) 0.067(3) Uani 1 1 d . . . . .
H9C H 0.930662 0.403986 -0.013401 0.101 Uiso 1 1 calc R U . . .
H9D H 0.843689 0.459187 0.022930 0.101 Uiso 1 1 calc R U . . .
H9E H 0.872594 0.494518 -0.071310 0.101 Uiso 1 1 calc R U . . .
C10 C 0.6506(8) 0.4579(6) -0.0341(5) 0.071(3) Uani 1 1 d . . . . .
H10C H 0.663688 0.511163 -0.083030 0.107 Uiso 1 1 calc R U . . .
H10D H 0.633979 0.472071 0.011403 0.107 Uiso 1 1 calc R U . . .
H10E H 0.585206 0.429930 -0.037552 0.107 Uiso 1 1 calc R U . . .
C25 C -0.1551(9) 0.5988(5) 0.2113(5) 0.069(3) Uani 1 1 d . . . . .
H25 H -0.187964 0.645893 0.165491 0.103 Uiso 1 1 calc R U . . .
H25A H -0.198221 0.546968 0.229218 0.103 Uiso 1 1 calc R U . . .
H25B H -0.074544 0.586034 0.195848 0.103 Uiso 1 1 calc R U . . .
C8 C 0.7843(10) 0.3713(6) -0.0916(4) 0.072(3) Uani 1 1 d . . . . .
H8A H 0.718847 0.342456 -0.093690 0.108 Uiso 1 1 calc R U . . .
H8B H 0.853261 0.331984 -0.084585 0.108 Uiso 1 1 calc R U . . .
H8C H 0.796710 0.423788 -0.141353 0.108 Uiso 1 1 calc R U . . .
C35 C 0.7808(11) 0.1325(8) -0.0295(8) 0.124(5) Uani 1 1 d D U . . .
C38 C 0.9993(14) 0.1059(13) -0.0347(12) 0.104(7) Uani 0.616(14) 1 d D U P A 1
C36 C 0.8333(18) 0.0720(14) -0.0657(12) 0.129(9) Uani 0.616(14) 1 d D U P A 1
C37 C 0.9616(17) 0.0602(14) -0.0779(13) 0.119(8) Uani 0.616(14) 1 d D U P A 1
C41 C 0.943(2) 0.1764(15) -0.0898(11) 0.070(7) Uani 0.384(14) 1 d D U P A 2
C39 C 0.769(2) 0.1549(17) -0.1127(13) 0.121(12) Uani 0.384(14) 1 d D U P A 2
C40 C 0.876(2) 0.195(2) -0.1582(12) 0.128(14) Uani 0.384(14) 1 d D U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt2 N7 1.999(4) . ?
Pt2 N8 2.000(4) . ?
Pt2 N5 2.050(4) . ?
Pt2 N6 2.077(5) . ?
Pt2 Mn1 3.0176(8) . ?
Pt3 N11 1.999(4) . ?
Pt3 N12 2.000(5) . ?
Pt3 N9 2.047(4) . ?
Pt3 N10 2.065(4) . ?
Pt3 Mn2 2.62666(18) . ?
Pt1 N4 2.000(5) . ?
Pt1 N3 2.021(4) . ?
Pt1 N1 2.050(4) . ?
Pt1 N2 2.064(5) . ?
Pt1 Mn1 2.8639(8) . ?
Mn1 O4 2.032(4) . ?
Mn1 O2 2.076(4) . ?
Mn1 O1 2.093(4) . ?
Mn1 O3 2.108(4) . ?
Mn2 O5 2.117(4) . ?
Mn2 O5 2.117(4) 2_566 ?
Mn2 O6 2.132(4) 2_566 ?
Mn2 O6 2.132(4) . ?
P1 F5 1.577(4) . ?
P1 F4 1.580(4) . ?
P1 F1 1.598(4) . ?
P1 F3 1.608(3) . ?
P1 F2 1.608(4) . ?
P1 F6 1.613(3) . ?
P2 F8 1.559(4) . ?
P2 F11 1.574(4) . ?
P2 F7 1.579(4) . ?
P2 F12 1.581(4) . ?
P2 F10 1.610(4) . ?
P2 F9 1.610(4) . ?
P3 F13 1.564(5) . ?
P3 F16 1.578(5) . ?
P3 F15 1.579(5) . ?
P3 F18 1.589(4) . ?
P3 F17 1.600(4) . ?
P3 F14 1.610(5) . ?
O7 C34 1.446(7) . ?
O7 C31 1.446(7) . ?
O6 C26 1.264(6) . ?
O5 C21 1.253(6) . ?
N4 C6 1.306(7) . ?
N4 H4 0.8800 . ?
N2 H2 0.9100 . ?
N2 H2A 0.9100 . ?
N2 H2B 0.9100 . ?
O2 C6 1.268(7) . ?
O3 C11 1.280(6) . ?
N6 H6 0.9100 . ?
N6 H6A 0.9100 . ?
N6 H6B 0.9100 . ?
N7 C11 1.290(7) . ?
N7 H7 0.8800 . ?
N5 H5 0.9100 . ?
N5 H5A 0.9100 . ?
N5 H5B 0.9100 . ?
O1 C1 1.277(6) . ?
N12 C26 1.323(7) . ?
N12 H12 0.8800 . ?
N8 C16 1.283(7) . ?
N8 H8 0.8800 . ?
N10 H10 0.9100 . ?
N10 H10A 0.9100 . ?
N10 H10B 0.9100 . ?
O4 C16 1.278(7) . ?
N1 H1 0.9100 . ?
N1 H1A 0.9100 . ?
N1 H1B 0.9100 . ?
N3 C1 1.304(7) . ?
N3 H3 0.8800 . ?
N9 H9 0.9100 . ?
N9 H9A 0.9100 . ?
N9 H9B 0.9100 . ?
N11 C21 1.310(6) . ?
N11 H11 0.8800 . ?
C11 C12 1.535(7) . ?
C6 C7 1.516(8) . ?
C26 C27 1.513(7) . ?
C16 C17 1.540(7) . ?
C31 C32 1.494(9) . ?
C31 H31 0.9900 . ?
C31 H31A 0.9900 . ?
C17 C19 1.522(8) . ?
C17 C20 1.526(8) . ?
C17 C18 1.545(8) . ?
C1 C2 1.531(7) . ?
C18 H18 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C5 C2 1.545(8) . ?
C5 H5C 0.9800 . ?
C5 H5D 0.9800 . ?
C5 H5E 0.9800 . ?
C7 C8 1.496(10) . ?
C7 C9 1.537(11) . ?
C7 C10 1.557(10) . ?
C34 C33 1.508(11) . ?
C34 H34 0.9900 . ?
C34 H34A 0.9900 . ?
C27 C28 1.504(9) . ?
C27 C29 1.528(8) . ?
C27 C30 1.547(8) . ?
C2 C3 1.520(8) . ?
C2 C4 1.541(8) . ?
C32 C33 1.544(9) . ?
C32 H32 0.9900 . ?
C32 H32A 0.9900 . ?
C12 C15 1.516(9) . ?
C12 C14 1.521(9) . ?
C12 C13 1.523(9) . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C19 H19 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C14 H14 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C21 C22 1.540(7) . ?
C22 C25 1.513(9) . ?
C22 C23 1.525(10) . ?
C22 C24 1.532(10) . ?
C29 H29 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C20 H20 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C15 H15 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C33 H33 0.9900 . ?
C33 H33A 0.9900 . ?
C28 H28 0.9800 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C30 H30 0.9800 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
O8 C41 1.384(16) . ?
O8 C35 1.465(12) . ?
O8 C38 1.510(15) . ?
C23 H23 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C24 H24 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C13 H13 0.9800 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C9 H9C 0.9800 . ?
C9 H9D 0.9800 . ?
C9 H9E 0.9800 . ?
C10 H10C 0.9800 . ?
C10 H10D 0.9800 . ?
C10 H10E 0.9800 . ?
C25 H25 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C35 C39 1.468(17) . ?
C35 C36 1.513(15) . ?
C38 C37 1.496(15) . ?
C36 C37 1.500(17) . ?
C41 C40 1.506(18) . ?
C39 C40 1.472(19) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N7 Pt2 N8 89.51(18) . . ?
N7 Pt2 N5 177.14(19) . . ?
N8 Pt2 N5 89.01(17) . . ?
N7 Pt2 N6 90.98(18) . . ?
N8 Pt2 N6 176.63(19) . . ?
N5 Pt2 N6 90.63(18) . . ?
N7 Pt2 Mn1 82.15(13) . . ?
N8 Pt2 Mn1 81.86(13) . . ?
N5 Pt2 Mn1 95.21(14) . . ?
N6 Pt2 Mn1 101.50(14) . . ?
N11 Pt3 N12 90.57(18) . . ?
N11 Pt3 N9 177.34(17) . . ?
N12 Pt3 N9 89.03(18) . . ?
N11 Pt3 N10 88.30(18) . . ?
N12 Pt3 N10 177.22(16) . . ?
N9 Pt3 N10 91.99(18) . . ?
N11 Pt3 Mn2 84.63(12) . . ?
N12 Pt3 Mn2 84.67(12) . . ?
N9 Pt3 Mn2 92.71(12) . . ?
N10 Pt3 Mn2 92.70(12) . . ?
N4 Pt1 N3 88.20(18) . . ?
N4 Pt1 N1 89.81(19) . . ?
N3 Pt1 N1 176.88(18) . . ?
N4 Pt1 N2 176.97(18) . . ?
N3 Pt1 N2 94.39(18) . . ?
N1 Pt1 N2 87.67(19) . . ?
N4 Pt1 Mn1 82.59(14) . . ?
N3 Pt1 Mn1 85.61(12) . . ?
N1 Pt1 Mn1 91.75(14) . . ?
N2 Pt1 Mn1 99.17(14) . . ?
O4 Mn1 O2 89.83(17) . . ?
O4 Mn1 O1 107.61(17) . . ?
O2 Mn1 O1 103.69(17) . . ?
O4 Mn1 O3 101.82(18) . . ?
O2 Mn1 O3 109.14(17) . . ?
O1 Mn1 O3 135.47(17) . . ?
O4 Mn1 Pt1 166.84(13) . . ?
O2 Mn1 Pt1 77.12(12) . . ?
O1 Mn1 Pt1 77.66(10) . . ?
O3 Mn1 Pt1 81.20(11) . . ?
O4 Mn1 Pt2 76.12(12) . . ?
O2 Mn1 Pt2 165.95(12) . . ?
O1 Mn1 Pt2 80.79(11) . . ?
O3 Mn1 Pt2 74.64(11) . . ?
Pt1 Mn1 Pt2 116.93(3) . . ?
O5 Mn2 O5 180.0 . 2_566 ?
O5 Mn2 O6 90.27(16) . 2_566 ?
O5 Mn2 O6 89.73(16) 2_566 2_566 ?
O5 Mn2 O6 89.73(16) . . ?
O5 Mn2 O6 90.27(16) 2_566 . ?
O6 Mn2 O6 180.0 2_566 . ?
O5 Mn2 Pt3 83.64(10) . . ?
O5 Mn2 Pt3 96.36(10) 2_566 . ?
O6 Mn2 Pt3 96.28(9) 2_566 . ?
O6 Mn2 Pt3 83.72(9) . . ?
O5 Mn2 Pt3 96.36(10) . 2_566 ?
O5 Mn2 Pt3 83.64(10) 2_566 2_566 ?
O6 Mn2 Pt3 83.72(9) 2_566 2_566 ?
O6 Mn2 Pt3 96.28(9) . 2_566 ?
Pt3 Mn2 Pt3 180.0 . 2_566 ?
F5 P1 F4 91.0(2) . . ?
F5 P1 F1 90.8(2) . . ?
F4 P1 F1 90.6(2) . . ?
F5 P1 F3 90.7(2) . . ?
F4 P1 F3 90.2(2) . . ?
F1 P1 F3 178.3(2) . . ?
F5 P1 F2 89.4(2) . . ?
F4 P1 F2 179.1(2) . . ?
F1 P1 F2 90.24(19) . . ?
F3 P1 F2 88.9(2) . . ?
F5 P1 F6 178.3(2) . . ?
F4 P1 F6 90.7(2) . . ?
F1 P1 F6 89.7(2) . . ?
F3 P1 F6 88.88(19) . . ?
F2 P1 F6 88.96(19) . . ?
F8 P2 F11 90.6(3) . . ?
F8 P2 F7 91.8(2) . . ?
F11 P2 F7 91.1(3) . . ?
F8 P2 F12 92.0(3) . . ?
F11 P2 F12 176.4(3) . . ?
F7 P2 F12 91.4(3) . . ?
F8 P2 F10 178.1(2) . . ?
F11 P2 F10 89.6(3) . . ?
F7 P2 F10 90.1(2) . . ?
F12 P2 F10 87.7(2) . . ?
F8 P2 F9 89.4(2) . . ?
F11 P2 F9 88.6(3) . . ?
F7 P2 F9 178.8(3) . . ?
F12 P2 F9 88.9(2) . . ?
F10 P2 F9 88.7(2) . . ?
F13 P3 F16 89.2(3) . . ?
F13 P3 F15 178.6(3) . . ?
F16 P3 F15 91.8(3) . . ?
F13 P3 F18 91.7(3) . . ?
F16 P3 F18 90.4(2) . . ?
F15 P3 F18 89.3(3) . . ?
F13 P3 F17 89.9(3) . . ?
F16 P3 F17 90.0(3) . . ?
F15 P3 F17 89.0(3) . . ?
F18 P3 F17 178.3(3) . . ?
F13 P3 F14 90.4(3) . . ?
F16 P3 F14 179.1(3) . . ?
F15 P3 F14 88.6(3) . . ?
F18 P3 F14 90.4(2) . . ?
F17 P3 F14 89.2(3) . . ?
C34 O7 C31 104.8(5) . . ?
C26 O6 Mn2 121.4(3) . . ?
C21 O5 Mn2 121.2(3) . . ?
C6 N4 Pt1 124.2(4) . . ?
C6 N4 H4 117.9 . . ?
Pt1 N4 H4 117.9 . . ?
Pt1 N2 H2 109.5 . . ?
Pt1 N2 H2A 109.5 . . ?
H2 N2 H2A 109.5 . . ?
Pt1 N2 H2B 109.5 . . ?
H2 N2 H2B 109.5 . . ?
H2A N2 H2B 109.5 . . ?
C6 O2 Mn1 125.5(4) . . ?
C11 O3 Mn1 126.1(3) . . ?
Pt2 N6 H6 109.5 . . ?
Pt2 N6 H6A 109.5 . . ?
H6 N6 H6A 109.5 . . ?
Pt2 N6 H6B 109.5 . . ?
H6 N6 H6B 109.5 . . ?
H6A N6 H6B 109.5 . . ?
C11 N7 Pt2 125.1(4) . . ?
C11 N7 H7 117.5 . . ?
Pt2 N7 H7 117.5 . . ?
Pt2 N5 H5 109.5 . . ?
Pt2 N5 H5A 109.5 . . ?
H5 N5 H5A 109.5 . . ?
Pt2 N5 H5B 109.5 . . ?
H5 N5 H5B 109.5 . . ?
H5A N5 H5B 109.5 . . ?
C1 O1 Mn1 129.5(3) . . ?
C26 N12 Pt3 126.4(4) . . ?
C26 N12 H12 116.8 . . ?
Pt3 N12 H12 116.8 . . ?
C16 N8 Pt2 126.6(4) . . ?
C16 N8 H8 116.7 . . ?
Pt2 N8 H8 116.7 . . ?
Pt3 N10 H10 109.5 . . ?
Pt3 N10 H10A 109.5 . . ?
H10 N10 H10A 109.5 . . ?
Pt3 N10 H10B 109.5 . . ?
H10 N10 H10B 109.5 . . ?
H10A N10 H10B 109.5 . . ?
C16 O4 Mn1 132.8(4) . . ?
Pt1 N1 H1 109.5 . . ?
Pt1 N1 H1A 109.5 . . ?
H1 N1 H1A 109.5 . . ?
Pt1 N1 H1B 109.5 . . ?
H1 N1 H1B 109.5 . . ?
H1A N1 H1B 109.5 . . ?
C1 N3 Pt1 122.4(4) . . ?
C1 N3 H3 118.8 . . ?
Pt1 N3 H3 118.8 . . ?
Pt3 N9 H9 109.5 . . ?
Pt3 N9 H9A 109.5 . . ?
H9 N9 H9A 109.5 . . ?
Pt3 N9 H9B 109.5 . . ?
H9 N9 H9B 109.5 . . ?
H9A N9 H9B 109.5 . . ?
C21 N11 Pt3 124.9(4) . . ?
C21 N11 H11 117.5 . . ?
Pt3 N11 H11 117.5 . . ?
O3 C11 N7 122.9(5) . . ?
O3 C11 C12 116.6(5) . . ?
N7 C11 C12 120.4(5) . . ?
O2 C6 N4 121.3(5) . . ?
O2 C6 C7 118.3(5) . . ?
N4 C6 C7 120.4(5) . . ?
O6 C26 N12 120.6(5) . . ?
O6 C26 C27 118.1(5) . . ?
N12 C26 C27 121.3(5) . . ?
O4 C16 N8 122.7(5) . . ?
O4 C16 C17 115.1(5) . . ?
N8 C16 C17 122.2(5) . . ?
O7 C31 C32 107.7(5) . . ?
O7 C31 H31 110.2 . . ?
C32 C31 H31 110.2 . . ?
O7 C31 H31A 110.2 . . ?
C32 C31 H31A 110.2 . . ?
H31 C31 H31A 108.5 . . ?
C19 C17 C20 109.9(5) . . ?
C19 C17 C16 112.8(5) . . ?
C20 C17 C16 107.0(4) . . ?
C19 C17 C18 110.3(5) . . ?
C20 C17 C18 109.2(5) . . ?
C16 C17 C18 107.4(5) . . ?
O1 C1 N3 122.5(4) . . ?
O1 C1 C2 117.8(5) . . ?
N3 C1 C2 119.5(5) . . ?
C17 C18 H18 109.5 . . ?
C17 C18 H18A 109.5 . . ?
H18 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C2 C5 H5C 109.5 . . ?
C2 C5 H5D 109.5 . . ?
H5C C5 H5D 109.5 . . ?
C2 C5 H5E 109.5 . . ?
H5C C5 H5E 109.5 . . ?
H5D C5 H5E 109.5 . . ?
C8 C7 C6 109.0(6) . . ?
C8 C7 C9 109.8(7) . . ?
C6 C7 C9 113.3(6) . . ?
C8 C7 C10 109.9(7) . . ?
C6 C7 C10 107.0(6) . . ?
C9 C7 C10 107.8(7) . . ?
O7 C34 C33 104.6(5) . . ?
O7 C34 H34 110.8 . . ?
C33 C34 H34 110.8 . . ?
O7 C34 H34A 110.8 . . ?
C33 C34 H34A 110.8 . . ?
H34 C34 H34A 108.9 . . ?
C28 C27 C26 107.9(5) . . ?
C28 C27 C29 110.7(6) . . ?
C26 C27 C29 113.0(5) . . ?
C28 C27 C30 110.4(6) . . ?
C26 C27 C30 106.2(5) . . ?
C29 C27 C30 108.6(5) . . ?
C3 C2 C1 105.8(5) . . ?
C3 C2 C4 110.3(5) . . ?
C1 C2 C4 112.8(5) . . ?
C3 C2 C5 109.6(5) . . ?
C1 C2 C5 109.7(4) . . ?
C4 C2 C5 108.6(5) . . ?
C31 C32 C33 105.0(6) . . ?
C31 C32 H32 110.8 . . ?
C33 C32 H32 110.8 . . ?
C31 C32 H32A 110.8 . . ?
C33 C32 H32A 110.8 . . ?
H32 C32 H32A 108.8 . . ?
C15 C12 C14 109.0(5) . . ?
C15 C12 C13 110.9(6) . . ?
C14 C12 C13 108.6(6) . . ?
C15 C12 C11 110.1(5) . . ?
C14 C12 C11 112.4(5) . . ?
C13 C12 C11 105.9(4) . . ?
C2 C4 H4A 109.5 . . ?
C2 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
C2 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C2 C3 H3A 109.5 . . ?
C2 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
C2 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C17 C19 H19 109.5 . . ?
C17 C19 H19A 109.5 . . ?
H19 C19 H19A 109.5 . . ?
C17 C19 H19B 109.5 . . ?
H19 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C12 C14 H14 109.5 . . ?
C12 C14 H14A 109.5 . . ?
H14 C14 H14A 109.5 . . ?
C12 C14 H14B 109.5 . . ?
H14 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
O5 C21 N11 122.6(5) . . ?
O5 C21 C22 117.1(4) . . ?
N11 C21 C22 120.3(5) . . ?
C25 C22 C23 110.0(7) . . ?
C25 C22 C24 110.4(7) . . ?
C23 C22 C24 110.1(6) . . ?
C25 C22 C21 113.3(5) . . ?
C23 C22 C21 107.2(5) . . ?
C24 C22 C21 105.8(6) . . ?
C27 C29 H29 109.5 . . ?
C27 C29 H29A 109.5 . . ?
H29 C29 H29A 109.5 . . ?
C27 C29 H29B 109.5 . . ?
H29 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C17 C20 H20 109.5 . . ?
C17 C20 H20A 109.5 . . ?
H20 C20 H20A 109.5 . . ?
C17 C20 H20B 109.5 . . ?
H20 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C12 C15 H15 109.5 . . ?
C12 C15 H15A 109.5 . . ?
H15 C15 H15A 109.5 . . ?
C12 C15 H15B 109.5 . . ?
H15 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C34 C33 C32 102.1(5) . . ?
C34 C33 H33 111.3 . . ?
C32 C33 H33 111.3 . . ?
C34 C33 H33A 111.3 . . ?
C32 C33 H33A 111.3 . . ?
H33 C33 H33A 109.2 . . ?
C27 C28 H28 109.5 . . ?
C27 C28 H28A 109.5 . . ?
H28 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C30 H30 109.5 . . ?
C27 C30 H30A 109.5 . . ?
H30 C30 H30A 109.5 . . ?
C27 C30 H30B 109.5 . . ?
H30 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C41 O8 C35 95.4(13) . . ?
C35 O8 C38 118.6(9) . . ?
C22 C23 H23 109.5 . . ?
C22 C23 H23A 109.5 . . ?
H23 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
H23 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C22 C24 H24 109.5 . . ?
C22 C24 H24A 109.5 . . ?
H24 C24 H24A 109.5 . . ?
C22 C24 H24B 109.5 . . ?
H24 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C12 C13 H13 109.5 . . ?
C12 C13 H13A 109.5 . . ?
H13 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
H13 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C7 C9 H9C 109.5 . . ?
C7 C9 H9D 109.5 . . ?
H9C C9 H9D 109.5 . . ?
C7 C9 H9E 109.5 . . ?
H9C C9 H9E 109.5 . . ?
H9D C9 H9E 109.5 . . ?
C7 C10 H10C 109.5 . . ?
C7 C10 H10D 109.5 . . ?
H10C C10 H10D 109.5 . . ?
C7 C10 H10E 109.5 . . ?
H10C C10 H10E 109.5 . . ?
H10D C10 H10E 109.5 . . ?
C22 C25 H25 109.5 . . ?
C22 C25 H25A 109.5 . . ?
H25 C25 H25A 109.5 . . ?
C22 C25 H25B 109.5 . . ?
H25 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
O8 C35 C39 116.9(13) . . ?
O8 C35 C36 95.1(12) . . ?
C37 C38 O8 104.5(12) . . ?
C37 C36 C35 118.9(15) . . ?
C38 C37 C36 102.1(13) . . ?
O8 C41 C40 121.9(18) . . ?
C35 C39 C40 105.5(16) . . ?
C39 C40 C41 98.8(17) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Mn1 O3 C11 N7 -35.4(7) . . . . ?
Mn1 O3 C11 C12 142.1(4) . . . . ?
Pt2 N7 C11 O3 8.9(8) . . . . ?
Pt2 N7 C11 C12 -168.6(4) . . . . ?
Mn1 O2 C6 N4 28.6(8) . . . . ?
Mn1 O2 C6 C7 -151.2(4) . . . . ?
Pt1 N4 C6 O2 1.0(8) . . . . ?
Pt1 N4 C6 C7 -179.2(4) . . . . ?
Mn2 O6 C26 N12 16.5(7) . . . . ?
Mn2 O6 C26 C27 -162.7(4) . . . . ?
Pt3 N12 C26 O6 -1.1(8) . . . . ?
Pt3 N12 C26 C27 178.1(4) . . . . ?
Mn1 O4 C16 N8 0.8(8) . . . . ?
Mn1 O4 C16 C17 -178.1(4) . . . . ?
Pt2 N8 C16 O4 -0.7(7) . . . . ?
Pt2 N8 C16 C17 178.1(3) . . . . ?
C34 O7 C31 C32 -28.6(7) . . . . ?
O4 C16 C17 C19 -178.1(5) . . . . ?
N8 C16 C17 C19 3.0(7) . . . . ?
O4 C16 C17 C20 60.9(6) . . . . ?
N8 C16 C17 C20 -118.0(6) . . . . ?
O4 C16 C17 C18 -56.3(6) . . . . ?
N8 C16 C17 C18 124.8(6) . . . . ?
Mn1 O1 C1 N3 -19.0(8) . . . . ?
Mn1 O1 C1 C2 155.5(4) . . . . ?
Pt1 N3 C1 O1 18.1(8) . . . . ?
Pt1 N3 C1 C2 -156.2(4) . . . . ?
O2 C6 C7 C8 -59.5(8) . . . . ?
N4 C6 C7 C8 120.7(7) . . . . ?
O2 C6 C7 C9 178.0(6) . . . . ?
N4 C6 C7 C9 -1.9(9) . . . . ?
O2 C6 C7 C10 59.3(8) . . . . ?
N4 C6 C7 C10 -120.5(7) . . . . ?
C31 O7 C34 C33 40.5(6) . . . . ?
O6 C26 C27 C28 -58.8(7) . . . . ?
N12 C26 C27 C28 122.0(6) . . . . ?
O6 C26 C27 C29 178.5(5) . . . . ?
N12 C26 C27 C29 -0.7(8) . . . . ?
O6 C26 C27 C30 59.6(7) . . . . ?
N12 C26 C27 C30 -119.7(6) . . . . ?
O1 C1 C2 C3 -93.4(6) . . . . ?
N3 C1 C2 C3 81.2(6) . . . . ?
O1 C1 C2 C4 146.0(5) . . . . ?
N3 C1 C2 C4 -39.4(7) . . . . ?
O1 C1 C2 C5 24.8(7) . . . . ?
N3 C1 C2 C5 -160.7(5) . . . . ?
O7 C31 C32 C33 5.8(8) . . . . ?
O3 C11 C12 C15 40.2(7) . . . . ?
N7 C11 C12 C15 -142.2(6) . . . . ?
O3 C11 C12 C14 161.9(5) . . . . ?
N7 C11 C12 C14 -20.5(7) . . . . ?
O3 C11 C12 C13 -79.7(6) . . . . ?
N7 C11 C12 C13 97.9(6) . . . . ?
Mn2 O5 C21 N11 12.0(7) . . . . ?
Mn2 O5 C21 C22 -167.1(4) . . . . ?
Pt3 N11 C21 O5 4.4(8) . . . . ?
Pt3 N11 C21 C22 -176.5(4) . . . . ?
O5 C21 C22 C25 171.7(7) . . . . ?
N11 C21 C22 C25 -7.4(9) . . . . ?
O5 C21 C22 C23 50.2(8) . . . . ?
N11 C21 C22 C23 -128.9(7) . . . . ?
O5 C21 C22 C24 -67.2(7) . . . . ?
N11 C21 C22 C24 113.7(6) . . . . ?
O7 C34 C33 C32 -35.7(7) . . . . ?
C31 C32 C33 C34 17.9(8) . . . . ?
C41 O8 C35 C39 -4.4(14) . . . . ?
C38 O8 C35 C36 -0.3(12) . . . . ?
C35 O8 C38 C37 5.6(19) . . . . ?
O8 C35 C36 C37 -5.7(15) . . . . ?
O8 C38 C37 C36 -8(2) . . . . ?
C35 C36 C37 C38 9(2) . . . . ?
C35 O8 C41 C40 12(2) . . . . ?
O8 C35 C39 C40 -3.4(18) . . . . ?
C35 C39 C40 C41 9(2) . . . . ?
O8 C41 C40 C39 -14(3) . . . . ?

_refine_diff_density_max         2.501
_refine_diff_density_min         -1.748
_refine_diff_density_rms         0.165




####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 2101582'
loop_
_audit_author_name
_audit_author_address
'Kazuhiro Uemura'
;Gifu University
Japan
;
_audit_update_record             
;
2021-11-30 deposited with the CCDC.	2021-12-06 downloaded from the CCDC.
;

_vrf_PLAT973_ALERT_2_A           
;
PROBLEM: Check Calcd Positive Resid. Density on Pt2 4.40 eA-3, Pt1 4.44 eA-3, and Rh1 2.64 eA-3.
RESPONSE: This compound contains several heavier metals with metal-metal bonds. Atoms Pt2, Pt1, and Rh1 were bound to other metals.
;

_vrf_PLAT430_ALERT_2_B           
;
PROBLEM: Short Inter D...A Contact O14 ..O14 . 2.64 Ang.
RESPONSE: Atom O15 was found to be disordered.
;

_vrf_PLAT972_ALERT_2_B           
;
PROBLEM: Check Calcd Resid. Dens. 0.78A From Pt1 -2.90 eA-3, and 0.83A From Pt2 -2.53 eA-3.
RESPONSE: This compound contains several heavier metals with metal-metal bonds. Atoms Pt1 and Pt2 were bound to other metals.
;

_vrf_PLAT975_ALERT_2_B           
;
PROBLEM: Check Calcd Resid. Dens. 1.01A From N2
RESPONSE: Atom N2 was bound to heavier metal of Pt1.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C62 H140 F24 Mn2 N16 O27 P4 Pt4 Rh4'
_chemical_formula_weight         3423.65

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.3429(6)
_cell_length_b                   14.0834(6)
_cell_length_c                   17.3084(8)
_cell_angle_alpha                105.038(4)
_cell_angle_beta                 102.407(4)
_cell_angle_gamma                94.234(4)
_cell_volume                     3038.7(2)
_cell_formula_units_Z            1
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    11797
_cell_measurement_theta_min      2.2200
_cell_measurement_theta_max      30.7810

_exptl_crystal_description       plate
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.871
_exptl_crystal_F_000             1658
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.450
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.030
_exptl_absorpt_coefficient_mu    5.465
_shelx_estimated_absorpt_T_min   0.192
_shelx_estimated_absorpt_T_max   0.853
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.64666
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.40.53 (Rigaku Oxford Diffraction, 2019)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_oxdiff_exptl_absorpt_empirical_full_min 0.765
_oxdiff_exptl_absorpt_empirical_full_max 1.434
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
- Detector area scaling
;
_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_measurement_device_type  
'dtrek-CrysAlisPro-abstract goniometer imported rigaku-d*trek images'
_diffrn_measurement_method       'profile data from φ-scans'
_diffrn_detector_area_resol_mean 14.7059
_diffrn_reflns_number            24291
_diffrn_reflns_av_unetI/netI     0.0658
_diffrn_reflns_av_R_equivalents  0.0388
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         2.030
_diffrn_reflns_theta_max         27.500
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measured_fraction_theta_full 0.988
_diffrn_reflns_Laue_measured_fraction_max 0.985
_diffrn_reflns_Laue_measured_fraction_full 0.988
_diffrn_reflns_point_group_measured_fraction_max 0.985
_diffrn_reflns_point_group_measured_fraction_full 0.988
_reflns_number_total             13750
_reflns_number_gt                10862
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_cell_refinement       'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_data_reduction        'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_publication_material  
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1000P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         13750
_refine_ls_number_parameters     680
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0758
_refine_ls_R_factor_gt           0.0572
_refine_ls_wR_factor_ref         0.1714
_refine_ls_wR_factor_gt          0.1466
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_restrained_S_all      1.062
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.16692(2) 0.41619(2) 0.83346(2) 0.02457(10) Uani 1 1 d . . . . .
Pt2 Pt 0.32729(2) 0.17739(2) 0.61519(2) 0.02494(10) Uani 1 1 d . . . . .
Rh1 Rh 0.04603(5) 0.47464(5) 0.94755(4) 0.02358(15) Uani 1 1 d . . . . .
Rh2 Rh 0.45068(5) 0.05537(5) 0.53613(4) 0.02403(15) Uani 1 1 d . . . . .
Mn1 Mn 0.25553(9) 0.39581(10) 0.68496(7) 0.0274(3) Uani 1 1 d . . . . .
P1 P 0.4682(2) 0.2704(2) 0.99251(18) 0.0464(6) Uani 1 1 d . . . . .
P2 P 0.0526(2) 0.0098(2) 0.70737(17) 0.0428(6) Uani 1 1 d . . . . .
O9 O 0.5259(4) 0.1670(4) 0.5056(4) 0.0286(13) Uani 1 1 d . . . . .
O10 O 0.6192(4) 0.0614(4) 0.4353(4) 0.0272(13) Uani 1 1 d . . . . .
O7 O 0.1493(4) 0.6002(5) 1.0026(4) 0.0336(14) Uani 1 1 d . . . . .
O6 O 0.0430(4) 0.4464(4) 1.1179(3) 0.0273(12) Uani 1 1 d . . . . .
O8 O 0.0633(4) 0.6493(4) 1.1044(4) 0.0291(13) Uani 1 1 d . . . . .
O5 O 0.1296(4) 0.3977(5) 1.0185(3) 0.0278(12) Uani 1 1 d . . . . .
O11 O 0.5656(4) 0.0745(4) 0.6414(4) 0.0276(12) Uani 1 1 d . . . . .
O12 O 0.6582(4) -0.0315(4) 0.5729(4) 0.0306(13) Uani 1 1 d . . . . .
O3 O 0.3881(4) 0.3774(5) 0.7637(3) 0.0306(13) Uani 1 1 d . . . . .
O1 O 0.1116(5) 0.3150(6) 0.6409(4) 0.0439(18) Uani 1 1 d . . . . .
O2 O 0.2544(5) 0.5465(5) 0.7260(4) 0.0458(18) Uani 1 1 d . . . . .
F8 F 0.1150(6) 0.1110(5) 0.7049(4) 0.065(2) Uani 1 1 d . . . . .
O4 O 0.2943(5) 0.3927(4) 0.5770(4) 0.0337(14) Uani 1 1 d . . . . .
N4 N 0.1449(6) 0.5461(6) 0.8088(5) 0.0349(18) Uani 1 1 d . . . . .
H4 H 0.098872 0.578200 0.830559 0.042 Uiso 1 1 calc R U . . .
N5 N 0.1944(5) 0.0760(6) 0.5535(4) 0.0308(16) Uani 1 1 d . . . . .
H5 H 0.137381 0.105045 0.561799 0.046 Uiso 1 1 calc R U . . .
H5A H 0.196180 0.022066 0.573166 0.046 Uiso 1 1 calc R U . . .
H5B H 0.191524 0.056785 0.498557 0.046 Uiso 1 1 calc R U . . .
N8 N 0.3034(5) 0.2296(6) 0.5163(4) 0.0314(16) Uani 1 1 d . . . . .
H8 H 0.298545 0.185616 0.468659 0.038 Uiso 1 1 calc R U . . .
N2 N 0.1825(7) 0.2835(6) 0.8636(5) 0.043(2) Uani 1 1 d . . . . .
H2 H 0.247806 0.268618 0.863830 0.065 Uiso 1 1 calc R U . . .
H2A H 0.135830 0.233953 0.825603 0.065 Uiso 1 1 calc R U . . .
H2B H 0.170760 0.289729 0.914405 0.065 Uiso 1 1 calc R U . . .
N7 N 0.4577(5) 0.2761(6) 0.6707(4) 0.0319(17) Uani 1 1 d . . . . .
H7 H 0.513073 0.263889 0.651916 0.038 Uiso 1 1 calc R U . . .
N3 N 0.0360(5) 0.3484(6) 0.7485(4) 0.0328(18) Uani 1 1 d . . . . .
H3 H -0.021269 0.340851 0.764960 0.039 Uiso 1 1 calc R U . . .
N6 N 0.3571(6) 0.1175(6) 0.7142(4) 0.0321(17) Uani 1 1 d . . . . .
H6 H 0.379231 0.167409 0.762042 0.048 Uiso 1 1 calc R U . . .
H6A H 0.407033 0.077322 0.708711 0.048 Uiso 1 1 calc R U . . .
H6B H 0.298162 0.081590 0.715364 0.048 Uiso 1 1 calc R U . . .
N1 N 0.3024(6) 0.4887(7) 0.9170(5) 0.045(2) Uani 1 1 d . . . . .
H1 H 0.354530 0.488148 0.890594 0.067 Uiso 1 1 calc R U . . .
H1A H 0.318274 0.457344 0.956963 0.067 Uiso 1 1 calc R U . . .
H1B H 0.294189 0.552499 0.940219 0.067 Uiso 1 1 calc R U . . .
F12 F 0.1317(6) -0.0531(5) 0.6619(4) 0.071(2) Uani 1 1 d . . . . .
F3 F 0.4743(7) 0.3824(6) 0.9896(5) 0.082(2) Uani 1 1 d . . . . .
F11 F -0.0227(6) 0.0752(6) 0.7519(6) 0.081(2) Uani 1 1 d . . . . .
C6 C 0.1917(6) 0.5897(7) 0.7633(5) 0.0294(18) Uani 1 1 d . . . . .
F7 F 0.1260(7) 0.0173(8) 0.7942(4) 0.101(3) Uani 1 1 d . . . . .
F6 F 0.4101(7) 0.2404(7) 0.8973(4) 0.094(3) Uani 1 1 d . . . . .
C1 C 0.0324(6) 0.3149(7) 0.6696(5) 0.0298(19) Uani 1 1 d . . . . .
C25 C 0.5888(6) 0.1462(7) 0.4596(5) 0.0301(18) Uani 1 1 d . . . . .
F4 F 0.3585(6) 0.2838(8) 1.0160(5) 0.092(3) Uani 1 1 d . . . . .
C23 C 0.1347(6) 0.6628(6) 1.0680(5) 0.0288(18) Uani 1 1 d . . . . .
C27 C 0.6418(6) 0.0277(7) 0.6390(5) 0.0292(18) Uani 1 1 d . . . . .
C11 C 0.4672(6) 0.3565(6) 0.7321(5) 0.0240(16) Uani 1 1 d . . . . .
C16 C 0.2940(6) 0.3211(6) 0.5133(5) 0.0247(16) Uani 1 1 d . . . . .
C12 C 0.5667(6) 0.4307(7) 0.7645(5) 0.033(2) Uani 1 1 d . . . . .
C15 C 0.5381(7) 0.5263(7) 0.7434(6) 0.037(2) Uani 1 1 d . . . . .
H15 H 0.511368 0.511995 0.683643 0.055 Uiso 1 1 calc R U . . .
H15A H 0.599774 0.576291 0.761759 0.055 Uiso 1 1 calc R U . . .
H15B H 0.484847 0.551534 0.771349 0.055 Uiso 1 1 calc R U . . .
C21 C 0.1081(7) 0.3972(7) 1.0872(5) 0.034(2) Uani 1 1 d . . . . .
F9 F -0.0148(7) 0.0040(7) 0.6174(5) 0.100(3) Uani 1 1 d . . . . .
C14 C 0.6003(7) 0.4486(7) 0.8583(5) 0.034(2) Uani 1 1 d . . . . .
H14 H 0.550083 0.483970 0.884220 0.051 Uiso 1 1 calc R U . . .
H14A H 0.668809 0.488519 0.879671 0.051 Uiso 1 1 calc R U . . .
H14B H 0.603309 0.384722 0.870768 0.051 Uiso 1 1 calc R U . . .
C13 C 0.6547(6) 0.3917(8) 0.7245(6) 0.038(2) Uani 1 1 d . . . . .
H13 H 0.668458 0.328400 0.735400 0.057 Uiso 1 1 calc R U . . .
H13A H 0.717602 0.440127 0.748042 0.057 Uiso 1 1 calc R U . . .
H13B H 0.633547 0.381914 0.664850 0.057 Uiso 1 1 calc R U . . .
C7 C 0.1711(7) 0.6918(8) 0.7548(5) 0.037(2) Uani 1 1 d . . . . .
F10 F -0.0098(7) -0.0898(7) 0.7080(7) 0.112(3) Uani 1 1 d . . . . .
C24 C 0.2087(7) 0.7576(7) 1.1033(6) 0.041(2) Uani 1 1 d . . . . .
H24 H 0.169861 0.813612 1.116522 0.062 Uiso 1 1 calc R U . . .
H24A H 0.247128 0.766493 1.062786 0.062 Uiso 1 1 calc R U . . .
H24B H 0.257346 0.754626 1.153532 0.062 Uiso 1 1 calc R U . . .
C26 C 0.6295(7) 0.2288(7) 0.4276(6) 0.037(2) Uani 1 1 d . . . . .
H26 H 0.697489 0.217335 0.416909 0.055 Uiso 1 1 calc R U . . .
H26A H 0.636164 0.292893 0.468948 0.055 Uiso 1 1 calc R U . . .
H26B H 0.581176 0.229285 0.376375 0.055 Uiso 1 1 calc R U . . .
C22 C 0.1665(7) 0.3339(8) 1.1358(6) 0.040(2) Uani 1 1 d . . . . .
H22 H 0.126023 0.268147 1.121528 0.059 Uiso 1 1 calc R U . . .
H22A H 0.177510 0.365930 1.194976 0.059 Uiso 1 1 calc R U . . .
H22B H 0.233701 0.326843 1.122149 0.059 Uiso 1 1 calc R U . . .
C3 C -0.0615(8) 0.2022(8) 0.5280(6) 0.044(2) Uani 1 1 d . . . . .
H3A H -0.126297 0.188621 0.485119 0.066 Uiso 1 1 calc R U . . .
H3B H -0.045975 0.140815 0.541775 0.066 Uiso 1 1 calc R U . . .
H3C H -0.005001 0.227837 0.507767 0.066 Uiso 1 1 calc R U . . .
C2 C -0.0732(6) 0.2808(7) 0.6064(5) 0.0304(18) Uani 1 1 d . . . . .
F2 F 0.5748(7) 0.2639(8) 0.9696(7) 0.111(3) Uani 1 1 d . . . . .
C17 C 0.2790(8) 0.3478(8) 0.4303(6) 0.040(2) Uani 1 1 d . . . . .
C8 C 0.1323(9) 0.6813(10) 0.6623(6) 0.056(3) Uani 1 1 d . . . . .
H8A H 0.183660 0.653759 0.633202 0.084 Uiso 1 1 calc R U . . .
H8B H 0.121986 0.746596 0.654413 0.084 Uiso 1 1 calc R U . . .
H8C H 0.066499 0.636708 0.640415 0.084 Uiso 1 1 calc R U . . .
F5 F 0.5211(8) 0.3087(9) 1.0874(5) 0.118(4) Uani 1 1 d . . . . .
C28 C 0.7178(7) 0.0350(8) 0.7183(6) 0.039(2) Uani 1 1 d . . . . .
H28 H 0.774234 0.088758 0.728617 0.058 Uiso 1 1 calc R U . . .
H28A H 0.746060 -0.027856 0.714684 0.058 Uiso 1 1 calc R U . . .
H28B H 0.682849 0.048844 0.763572 0.058 Uiso 1 1 calc R U . . .
C5 C -0.1571(8) 0.2336(9) 0.6413(7) 0.053(3) Uani 1 1 d . . . . .
H5C H -0.156937 0.276495 0.695895 0.079 Uiso 1 1 calc R U . . .
H5D H -0.141478 0.168060 0.645894 0.079 Uiso 1 1 calc R U . . .
H5E H -0.225541 0.226605 0.603997 0.079 Uiso 1 1 calc R U . . .
F1 F 0.4647(12) 0.1617(7) 0.9938(8) 0.149(5) Uani 1 1 d . . . . .
C4 C -0.1063(9) 0.3742(8) 0.5830(7) 0.052(3) Uani 1 1 d . . . . .
H4A H -0.104195 0.427105 0.633146 0.078 Uiso 1 1 calc R U . . .
H4B H -0.176911 0.358641 0.547772 0.078 Uiso 1 1 calc R U . . .
H4C H -0.058844 0.396356 0.553095 0.078 Uiso 1 1 calc R U . . .
C19 C 0.3489(12) 0.4395(10) 0.4413(7) 0.070(4) Uani 1 1 d . . . . .
H19 H 0.340108 0.491471 0.488478 0.105 Uiso 1 1 calc R U . . .
H19A H 0.331928 0.461577 0.391376 0.105 Uiso 1 1 calc R U . . .
H19B H 0.420882 0.426092 0.451276 0.105 Uiso 1 1 calc R U . . .
O13 O 0.5372(11) 0.0449(11) 0.8331(8) 0.114(5) Uani 1 1 d . . . . .
H13C H 0.522308 0.093100 0.866898 0.171 Uiso 1 1 calc R U . . .
C18 C 0.2967(10) 0.2621(9) 0.3603(6) 0.055(3) Uani 1 1 d . . . . .
H18 H 0.281931 0.280176 0.308438 0.082 Uiso 1 1 calc R U . . .
H18A H 0.250486 0.201901 0.354565 0.082 Uiso 1 1 calc R U . . .
H18B H 0.368855 0.249704 0.373516 0.082 Uiso 1 1 calc R U . . .
C10 C 0.0897(11) 0.7359(9) 0.8013(8) 0.069(4) Uani 1 1 d . . . . .
H10 H 0.024386 0.690490 0.780687 0.103 Uiso 1 1 calc R U . . .
H10A H 0.077913 0.800316 0.791951 0.103 Uiso 1 1 calc R U . . .
H10B H 0.115505 0.744544 0.860472 0.103 Uiso 1 1 calc R U . . .
C9 C 0.2764(10) 0.7604(9) 0.7886(9) 0.064(3) Uani 1 1 d . . . . .
H9 H 0.298651 0.771738 0.848448 0.096 Uiso 1 1 calc R U . . .
H9A H 0.268826 0.824037 0.776433 0.096 Uiso 1 1 calc R U . . .
H9B H 0.328402 0.728800 0.762451 0.096 Uiso 1 1 calc R U . . .
C20 C 0.1658(10) 0.3661(11) 0.4082(8) 0.068(4) Uani 1 1 d . . . . .
H20 H 0.152155 0.417187 0.453800 0.102 Uiso 1 1 calc R U . . .
H20A H 0.119810 0.304403 0.398286 0.102 Uiso 1 1 calc R U . . .
H20B H 0.153128 0.388514 0.358264 0.102 Uiso 1 1 calc R U . . .
C29 C 0.5342(19) -0.0386(14) 0.8625(13) 0.130(9) Uani 1 1 d . . . . .
H29 H 0.464612 -0.052950 0.871750 0.156 Uiso 1 1 calc R U . . .
H29A H 0.585340 -0.024030 0.916231 0.156 Uiso 1 1 calc R U . . .
C30 C 0.556(2) -0.1244(17) 0.8068(14) 0.168(12) Uani 1 1 d . . . . .
H30 H 0.529118 -0.122603 0.749898 0.252 Uiso 1 1 calc R U . . .
H30A H 0.522993 -0.184353 0.814806 0.252 Uiso 1 1 calc R U . . .
H30B H 0.631170 -0.124935 0.817333 0.252 Uiso 1 1 calc R U . . .
C31 C -0.094(3) -0.048(2) 1.0073(16) 0.089(14) Uani 0.5 1 d . . P . .
C32 C 0.003(2) -0.088(2) 1.0328(18) 0.069(7) Uani 0.5 1 d . . P . .
O14 O -0.094(3) -0.021(4) 0.951(2) 0.30(4) Uani 0.5 1 d . . P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N3 2.011(7) . ?
Pt1 N4 2.012(7) . ?
Pt1 N1 2.058(8) . ?
Pt1 N2 2.080(8) . ?
Pt1 Rh1 2.8108(6) . ?
Pt1 Mn1 3.0099(12) . ?
Pt2 N8 2.007(8) . ?
Pt2 N7 2.029(7) . ?
Pt2 N6 2.077(7) . ?
Pt2 N5 2.084(7) . ?
Pt2 Rh2 2.7752(6) . ?
Rh1 O7 2.033(6) . ?
Rh1 O6 2.049(6) 2_567 ?
Rh1 O5 2.051(6) . ?
Rh1 O8 2.057(6) 2_567 ?
Rh1 Rh1 2.3937(11) 2_567 ?
Rh2 O9 2.046(6) . ?
Rh2 O12 2.050(6) 2_656 ?
Rh2 O10 2.053(6) 2_656 ?
Rh2 O11 2.056(6) . ?
Rh2 Rh2 2.3931(11) 2_656 ?
Mn1 O4 2.035(6) . ?
Mn1 O1 2.040(7) . ?
Mn1 O2 2.058(7) . ?
Mn1 O3 2.066(6) . ?
P1 F1 1.535(10) . ?
P1 F2 1.558(8) . ?
P1 F5 1.573(9) . ?
P1 F3 1.588(9) . ?
P1 F6 1.593(8) . ?
P1 F4 1.612(8) . ?
P2 F7 1.581(8) . ?
P2 F10 1.582(8) . ?
P2 F11 1.598(7) . ?
P2 F9 1.600(8) . ?
P2 F8 1.611(7) . ?
P2 F12 1.628(7) . ?
O9 C25 1.274(9) . ?
O10 C25 1.285(10) . ?
O7 C23 1.303(9) . ?
O6 C21 1.271(10) . ?
O8 C23 1.278(9) . ?
O5 C21 1.283(9) . ?
O11 C27 1.255(10) . ?
O12 C27 1.301(9) . ?
O3 C11 1.308(9) . ?
O1 C1 1.262(9) . ?
O2 C6 1.261(9) . ?
O4 C16 1.286(9) . ?
N4 C6 1.340(11) . ?
N4 H4 0.8800 . ?
N5 H5 0.9100 . ?
N5 H5A 0.9100 . ?
N5 H5B 0.9100 . ?
N8 C16 1.316(11) . ?
N8 H8 0.8800 . ?
N2 H2 0.9100 . ?
N2 H2A 0.9100 . ?
N2 H2B 0.9100 . ?
N7 C11 1.312(10) . ?
N7 H7 0.8800 . ?
N3 C1 1.313(10) . ?
N3 H3 0.8800 . ?
N6 H6 0.9100 . ?
N6 H6A 0.9100 . ?
N6 H6B 0.9100 . ?
N1 H1 0.9100 . ?
N1 H1A 0.9100 . ?
N1 H1B 0.9100 . ?
C6 C7 1.521(13) . ?
C1 C2 1.542(11) . ?
C25 C26 1.526(12) . ?
C23 C24 1.501(12) . ?
C27 C28 1.495(12) . ?
C11 C12 1.530(11) . ?
C16 C17 1.553(12) . ?
C12 C14 1.535(12) . ?
C12 C15 1.537(14) . ?
C12 C13 1.551(11) . ?
C15 H15 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C21 C22 1.523(14) . ?
C14 H14 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C13 H13 0.9800 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C7 C8 1.536(13) . ?
C7 C9 1.551(15) . ?
C7 C10 1.559(13) . ?
C24 H24 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C26 H26 0.9800 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C22 H22 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C3 C2 1.557(11) . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C2 C4 1.542(13) . ?
C2 C5 1.566(13) . ?
C17 C19 1.481(15) . ?
C17 C20 1.535(15) . ?
C17 C18 1.545(13) . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C28 H28 0.9800 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C5 H5C 0.9800 . ?
C5 H5D 0.9800 . ?
C5 H5E 0.9800 . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C19 H19 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
O13 C29 1.40(2) . ?
O13 H13C 0.8400 . ?
C18 H18 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C10 H10 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C9 H9 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C20 H20 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C29 C30 1.43(2) . ?
C29 H29 0.9900 . ?
C29 H29A 0.9900 . ?
C30 H30 0.9800 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C31 O14 1.14(7) . ?
C31 C32 1.46(5) . ?
C32 O14 1.81(7) 2_557 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Pt1 N4 90.7(3) . . ?
N3 Pt1 N1 177.6(3) . . ?
N4 Pt1 N1 87.5(4) . . ?
N3 Pt1 N2 88.6(4) . . ?
N4 Pt1 N2 176.2(3) . . ?
N1 Pt1 N2 93.3(4) . . ?
N3 Pt1 Rh1 88.44(18) . . ?
N4 Pt1 Rh1 84.88(18) . . ?
N1 Pt1 Rh1 93.0(2) . . ?
N2 Pt1 Rh1 91.40(19) . . ?
N3 Pt1 Mn1 83.38(19) . . ?
N4 Pt1 Mn1 78.65(18) . . ?
N1 Pt1 Mn1 94.6(2) . . ?
N2 Pt1 Mn1 104.94(19) . . ?
Rh1 Pt1 Mn1 161.47(3) . . ?
N8 Pt2 N7 91.4(3) . . ?
N8 Pt2 N6 176.7(3) . . ?
N7 Pt2 N6 88.6(3) . . ?
N8 Pt2 N5 86.6(3) . . ?
N7 Pt2 N5 177.7(3) . . ?
N6 Pt2 N5 93.4(3) . . ?
N8 Pt2 Rh2 85.54(18) . . ?
N7 Pt2 Rh2 86.88(19) . . ?
N6 Pt2 Rh2 91.13(19) . . ?
N5 Pt2 Rh2 91.82(19) . . ?
O7 Rh1 O6 88.4(3) . 2_567 ?
O7 Rh1 O5 91.8(3) . . ?
O6 Rh1 O5 176.37(19) 2_567 . ?
O7 Rh1 O8 177.1(2) . 2_567 ?
O6 Rh1 O8 90.8(2) 2_567 2_567 ?
O5 Rh1 O8 88.8(3) . 2_567 ?
O7 Rh1 Rh1 88.90(15) . 2_567 ?
O6 Rh1 Rh1 87.55(14) 2_567 2_567 ?
O5 Rh1 Rh1 88.83(15) . 2_567 ?
O8 Rh1 Rh1 88.24(15) 2_567 2_567 ?
O7 Rh1 Pt1 88.79(15) . . ?
O6 Rh1 Pt1 95.80(14) 2_567 . ?
O5 Rh1 Pt1 87.83(14) . . ?
O8 Rh1 Pt1 94.11(14) 2_567 . ?
Rh1 Rh1 Pt1 175.88(4) 2_567 . ?
O9 Rh2 O12 87.7(2) . 2_656 ?
O9 Rh2 O10 176.9(2) . 2_656 ?
O12 Rh2 O10 92.9(2) 2_656 2_656 ?
O9 Rh2 O11 91.7(2) . . ?
O12 Rh2 O11 176.5(2) 2_656 . ?
O10 Rh2 O11 87.6(2) 2_656 . ?
O9 Rh2 Rh2 87.56(14) . 2_656 ?
O12 Rh2 Rh2 88.74(15) 2_656 2_656 ?
O10 Rh2 Rh2 89.46(14) 2_656 2_656 ?
O11 Rh2 Rh2 87.79(15) . 2_656 ?
O9 Rh2 Pt2 94.20(14) . . ?
O12 Rh2 Pt2 89.03(15) 2_656 . ?
O10 Rh2 Pt2 88.81(14) 2_656 . ?
O11 Rh2 Pt2 94.46(14) . . ?
Rh2 Rh2 Pt2 177.11(4) 2_656 . ?
O4 Mn1 O1 100.1(3) . . ?
O4 Mn1 O2 97.6(3) . . ?
O1 Mn1 O2 114.0(3) . . ?
O4 Mn1 O3 106.0(2) . . ?
O1 Mn1 O3 132.1(3) . . ?
O2 Mn1 O3 101.6(3) . . ?
O4 Mn1 Pt1 170.23(19) . . ?
O1 Mn1 Pt1 74.82(17) . . ?
O2 Mn1 Pt1 77.33(17) . . ?
O3 Mn1 Pt1 83.39(15) . . ?
F1 P1 F2 88.6(7) . . ?
F1 P1 F5 91.9(7) . . ?
F2 P1 F5 92.3(6) . . ?
F1 P1 F3 178.4(6) . . ?
F2 P1 F3 89.8(5) . . ?
F5 P1 F3 88.7(6) . . ?
F1 P1 F6 92.6(7) . . ?
F2 P1 F6 90.4(5) . . ?
F5 P1 F6 174.9(5) . . ?
F3 P1 F6 86.9(5) . . ?
F1 P1 F4 94.7(6) . . ?
F2 P1 F4 176.6(6) . . ?
F5 P1 F4 87.6(5) . . ?
F3 P1 F4 86.8(5) . . ?
F6 P1 F4 89.5(5) . . ?
F7 P2 F10 90.5(6) . . ?
F7 P2 F11 90.1(5) . . ?
F10 P2 F11 91.7(5) . . ?
F7 P2 F9 176.1(6) . . ?
F10 P2 F9 92.1(6) . . ?
F11 P2 F9 92.6(5) . . ?
F7 P2 F8 90.5(5) . . ?
F10 P2 F8 178.9(6) . . ?
F11 P2 F8 88.5(4) . . ?
F9 P2 F8 86.8(5) . . ?
F7 P2 F12 89.9(4) . . ?
F10 P2 F12 90.3(5) . . ?
F11 P2 F12 177.9(4) . . ?
F9 P2 F12 87.3(5) . . ?
F8 P2 F12 89.5(4) . . ?
C25 O9 Rh2 119.3(5) . . ?
C25 O10 Rh2 116.8(5) . 2_656 ?
C23 O7 Rh1 118.7(5) . . ?
C21 O6 Rh1 120.1(5) . 2_567 ?
C23 O8 Rh1 118.8(5) . 2_567 ?
C21 O5 Rh1 118.4(6) . . ?
C27 O11 Rh2 120.0(5) . . ?
C27 O12 Rh2 118.2(5) . 2_656 ?
C11 O3 Mn1 116.9(5) . . ?
C1 O1 Mn1 132.6(5) . . ?
C6 O2 Mn1 126.9(6) . . ?
C16 O4 Mn1 132.2(6) . . ?
C6 N4 Pt1 127.9(5) . . ?
C6 N4 H4 116.1 . . ?
Pt1 N4 H4 116.1 . . ?
Pt2 N5 H5 109.5 . . ?
Pt2 N5 H5A 109.5 . . ?
H5 N5 H5A 109.5 . . ?
Pt2 N5 H5B 109.5 . . ?
H5 N5 H5B 109.5 . . ?
H5A N5 H5B 109.5 . . ?
C16 N8 Pt2 128.5(6) . . ?
C16 N8 H8 115.7 . . ?
Pt2 N8 H8 115.7 . . ?
Pt1 N2 H2 109.5 . . ?
Pt1 N2 H2A 109.5 . . ?
H2 N2 H2A 109.5 . . ?
Pt1 N2 H2B 109.5 . . ?
H2 N2 H2B 109.5 . . ?
H2A N2 H2B 109.5 . . ?
C11 N7 Pt2 126.1(6) . . ?
C11 N7 H7 117.0 . . ?
Pt2 N7 H7 117.0 . . ?
C1 N3 Pt1 122.9(5) . . ?
C1 N3 H3 118.6 . . ?
Pt1 N3 H3 118.6 . . ?
Pt2 N6 H6 109.5 . . ?
Pt2 N6 H6A 109.5 . . ?
H6 N6 H6A 109.5 . . ?
Pt2 N6 H6B 109.5 . . ?
H6 N6 H6B 109.5 . . ?
H6A N6 H6B 109.5 . . ?
Pt1 N1 H1 109.5 . . ?
Pt1 N1 H1A 109.5 . . ?
H1 N1 H1A 109.5 . . ?
Pt1 N1 H1B 109.5 . . ?
H1 N1 H1B 109.5 . . ?
H1A N1 H1B 109.5 . . ?
O2 C6 N4 120.4(8) . . ?
O2 C6 C7 118.2(8) . . ?
N4 C6 C7 121.4(7) . . ?
O1 C1 N3 123.2(8) . . ?
O1 C1 C2 116.6(7) . . ?
N3 C1 C2 120.0(7) . . ?
O9 C25 O10 126.6(8) . . ?
O9 C25 C26 117.1(8) . . ?
O10 C25 C26 116.3(7) . . ?
O8 C23 O7 125.2(8) . . ?
O8 C23 C24 117.9(7) . . ?
O7 C23 C24 116.9(7) . . ?
O11 C27 O12 125.1(8) . . ?
O11 C27 C28 118.4(7) . . ?
O12 C27 C28 116.3(7) . . ?
O3 C11 N7 119.7(7) . . ?
O3 C11 C12 118.4(7) . . ?
N7 C11 C12 121.8(7) . . ?
O4 C16 N8 123.2(7) . . ?
O4 C16 C17 115.9(7) . . ?
N8 C16 C17 120.9(7) . . ?
C11 C12 C14 107.8(7) . . ?
C11 C12 C15 106.0(7) . . ?
C14 C12 C15 110.8(7) . . ?
C11 C12 C13 111.8(7) . . ?
C14 C12 C13 109.8(7) . . ?
C15 C12 C13 110.7(8) . . ?
C12 C15 H15 109.5 . . ?
C12 C15 H15A 109.5 . . ?
H15 C15 H15A 109.5 . . ?
C12 C15 H15B 109.5 . . ?
H15 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
O6 C21 O5 124.9(9) . . ?
O6 C21 C22 117.9(7) . . ?
O5 C21 C22 117.2(8) . . ?
C12 C14 H14 109.5 . . ?
C12 C14 H14A 109.5 . . ?
H14 C14 H14A 109.5 . . ?
C12 C14 H14B 109.5 . . ?
H14 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C12 C13 H13 109.5 . . ?
C12 C13 H13A 109.5 . . ?
H13 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
H13 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C6 C7 C8 107.3(8) . . ?
C6 C7 C9 106.8(8) . . ?
C8 C7 C9 109.2(9) . . ?
C6 C7 C10 113.3(8) . . ?
C8 C7 C10 109.6(9) . . ?
C9 C7 C10 110.4(9) . . ?
C23 C24 H24 109.5 . . ?
C23 C24 H24A 109.5 . . ?
H24 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
H24 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C25 C26 H26 109.5 . . ?
C25 C26 H26A 109.5 . . ?
H26 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C21 C22 H22 109.5 . . ?
C21 C22 H22A 109.5 . . ?
H22 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C2 C3 H3A 109.5 . . ?
C2 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
C2 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C1 C2 C4 105.9(8) . . ?
C1 C2 C3 110.3(7) . . ?
C4 C2 C3 109.3(8) . . ?
C1 C2 C5 112.7(7) . . ?
C4 C2 C5 110.7(8) . . ?
C3 C2 C5 107.9(8) . . ?
C19 C17 C20 109.7(11) . . ?
C19 C17 C18 110.7(9) . . ?
C20 C17 C18 108.6(10) . . ?
C19 C17 C16 109.8(9) . . ?
C20 C17 C16 105.7(7) . . ?
C18 C17 C16 112.1(8) . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C27 C28 H28 109.5 . . ?
C27 C28 H28A 109.5 . . ?
H28 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C2 C5 H5C 109.5 . . ?
C2 C5 H5D 109.5 . . ?
H5C C5 H5D 109.5 . . ?
C2 C5 H5E 109.5 . . ?
H5C C5 H5E 109.5 . . ?
H5D C5 H5E 109.5 . . ?
C2 C4 H4A 109.5 . . ?
C2 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
C2 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C17 C19 H19 109.5 . . ?
C17 C19 H19A 109.5 . . ?
H19 C19 H19A 109.5 . . ?
C17 C19 H19B 109.5 . . ?
H19 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C29 O13 H13C 109.5 . . ?
C17 C18 H18 109.5 . . ?
C17 C18 H18A 109.5 . . ?
H18 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C7 C10 H10 109.5 . . ?
C7 C10 H10A 109.5 . . ?
H10 C10 H10A 109.5 . . ?
C7 C10 H10B 109.5 . . ?
H10 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C7 C9 H9 109.5 . . ?
C7 C9 H9A 109.5 . . ?
H9 C9 H9A 109.5 . . ?
C7 C9 H9B 109.5 . . ?
H9 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C17 C20 H20 109.5 . . ?
C17 C20 H20A 109.5 . . ?
H20 C20 H20A 109.5 . . ?
C17 C20 H20B 109.5 . . ?
H20 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
O13 C29 C30 112.4(16) . . ?
O13 C29 H29 109.1 . . ?
C30 C29 H29 109.1 . . ?
O13 C29 H29A 109.1 . . ?
C30 C29 H29A 109.1 . . ?
H29 C29 H29A 107.8 . . ?
C29 C30 H30 109.5 . . ?
C29 C30 H30A 109.5 . . ?
H30 C30 H30A 109.5 . . ?
C29 C30 H30B 109.5 . . ?
H30 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
O14 C31 C32 111(4) . . ?
C31 C32 O14 99(2) . 2_557 ?
C31 O14 C32 115(3) . 2_557 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Mn1 O2 C6 N4 27.0(12) . . . . ?
Mn1 O2 C6 C7 -152.9(7) . . . . ?
Pt1 N4 C6 O2 3.9(13) . . . . ?
Pt1 N4 C6 C7 -176.2(7) . . . . ?
Mn1 O1 C1 N3 -22.1(15) . . . . ?
Mn1 O1 C1 C2 153.1(7) . . . . ?
Pt1 N3 C1 O1 5.9(14) . . . . ?
Pt1 N3 C1 C2 -169.1(6) . . . . ?
Rh2 O9 C25 O10 -7.3(11) . . . . ?
Rh2 O9 C25 C26 170.6(6) . . . . ?
Rh2 O10 C25 O9 6.3(11) 2_656 . . . ?
Rh2 O10 C25 C26 -171.5(6) 2_656 . . . ?
Rh1 O8 C23 O7 -5.4(12) 2_567 . . . ?
Rh1 O8 C23 C24 175.2(6) 2_567 . . . ?
Rh1 O7 C23 O8 4.6(12) . . . . ?
Rh1 O7 C23 C24 -176.0(6) . . . . ?
Rh2 O11 C27 O12 3.0(12) . . . . ?
Rh2 O11 C27 C28 -173.4(6) . . . . ?
Rh2 O12 C27 O11 -2.4(12) 2_656 . . . ?
Rh2 O12 C27 C28 174.1(6) 2_656 . . . ?
Mn1 O3 C11 N7 -59.3(9) . . . . ?
Mn1 O3 C11 C12 116.7(7) . . . . ?
Pt2 N7 C11 O3 1.3(12) . . . . ?
Pt2 N7 C11 C12 -174.6(6) . . . . ?
Mn1 O4 C16 N8 -26.0(12) . . . . ?
Mn1 O4 C16 C17 152.6(6) . . . . ?
Pt2 N8 C16 O4 -3.4(12) . . . . ?
Pt2 N8 C16 C17 178.1(6) . . . . ?
O3 C11 C12 C14 55.8(10) . . . . ?
N7 C11 C12 C14 -128.2(9) . . . . ?
O3 C11 C12 C15 -62.9(9) . . . . ?
N7 C11 C12 C15 113.1(9) . . . . ?
O3 C11 C12 C13 176.5(8) . . . . ?
N7 C11 C12 C13 -7.5(12) . . . . ?
Rh1 O6 C21 O5 5.4(12) 2_567 . . . ?
Rh1 O6 C21 C22 -175.6(6) 2_567 . . . ?
Rh1 O5 C21 O6 -4.9(12) . . . . ?
Rh1 O5 C21 C22 176.1(6) . . . . ?
O2 C6 C7 C8 57.1(11) . . . . ?
N4 C6 C7 C8 -122.8(9) . . . . ?
O2 C6 C7 C9 -60.0(11) . . . . ?
N4 C6 C7 C9 120.1(10) . . . . ?
O2 C6 C7 C10 178.2(9) . . . . ?
N4 C6 C7 C10 -1.7(13) . . . . ?
O1 C1 C2 C4 -87.0(10) . . . . ?
N3 C1 C2 C4 88.3(11) . . . . ?
O1 C1 C2 C3 31.1(12) . . . . ?
N3 C1 C2 C3 -153.6(9) . . . . ?
O1 C1 C2 C5 151.8(9) . . . . ?
N3 C1 C2 C5 -32.9(12) . . . . ?
O4 C16 C17 C19 47.5(11) . . . . ?
N8 C16 C17 C19 -133.9(10) . . . . ?
O4 C16 C17 C20 -70.8(11) . . . . ?
N8 C16 C17 C20 107.8(10) . . . . ?
O4 C16 C17 C18 171.1(8) . . . . ?
N8 C16 C17 C18 -10.3(12) . . . . ?
O14 C31 C32 O14 58(3) . . . 2_557 ?
C32 C31 O14 C32 -68(4) . . . 2_557 ?

_refine_diff_density_max         4.416
_refine_diff_density_min         -2.558
_refine_diff_density_rms         0.229



