data_csmopo
_audit_creation_date               2020-09-27
_audit_creation_method
;
Olex2 1.2-beta
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number       '2018/3'
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic
;
 ? 
;
_chemical_formula_moiety           '0.5(Cs12 Mo4 O38 P8)'
_chemical_formula_sum              'Cs6 Mo2 O19 P4'
_chemical_formula_weight           1417.22
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'Cs' 'Cs' -0.3680 2.1192
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Mo' 'Mo' -1.6832 0.6857
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'P' 'P' 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'monoclinic'
_space_group_IT_number             14
_space_group_name_H-M_alt          'P 1 21/c 1'
_space_group_name_Hall             '-P 2ybc'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, y+1/2, -z+1/2'
 '-x, -y, -z'
 'x, -y-1/2, z-1/2'

_cell_length_a                     10.6912(5)
_cell_length_b                     7.7144(3)
_cell_length_c                     14.5582(6)
_cell_angle_alpha                  90
_cell_angle_beta                   90.06(2)
_cell_angle_gamma                  90
_cell_volume                       1200.70(9)
_cell_formula_units_Z              2
_cell_measurement_reflns_used      4581
_cell_measurement_temperature      296(2)
_cell_measurement_theta_max        27.43
_cell_measurement_theta_min        2.80
_shelx_estimated_absorpt_T_max     0.7456
_shelx_estimated_absorpt_T_min     0.5480
_exptl_absorpt_coefficient_mu      10.350
_exptl_absorpt_correction_T_max    0.7456
_exptl_absorpt_correction_T_min    0.5480
_exptl_absorpt_correction_type     'none'
_exptl_absorpt_process_details
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.1119 before and 0.0462 after correction.
The Ratio of minimum to maximum transmission is 0.7350.
The λ/2 correction factor is 0.00150.
;
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              colourless
_exptl_crystal_density_diffrn      3.920
_exptl_crystal_density_meas        .
_exptl_crystal_density_method      'not measured'
_exptl_crystal_description         block
_exptl_crystal_F_000               1252
_exptl_crystal_size_max            0.114
_exptl_crystal_size_mid            0.086
_exptl_crystal_size_min            0.083
_exptl_special_details
;
 ? 
;
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0444
_diffrn_reflns_av_unetI/netI       0.0279
_diffrn_reflns_Laue_measured_fraction_full  1.000
_diffrn_reflns_Laue_measured_fraction_max  0.997
_diffrn_reflns_limit_h_max         13
_diffrn_reflns_limit_h_min         -13
_diffrn_reflns_limit_k_max         9
_diffrn_reflns_limit_k_min         -10
_diffrn_reflns_limit_l_max         18
_diffrn_reflns_limit_l_min         -18
_diffrn_reflns_number              19005
_diffrn_reflns_point_group_measured_fraction_full  1.000
_diffrn_reflns_point_group_measured_fraction_max  0.997
_diffrn_reflns_theta_full          25.242
_diffrn_reflns_theta_max           27.491
_diffrn_reflns_theta_min           1.905
_diffrn_ambient_temperature        296.15
_diffrn_detector_area_resol_mean   ?
_diffrn_measured_fraction_theta_full  1.000
_diffrn_measured_fraction_theta_max  0.997
_diffrn_measurement_device_type    'CCD area detector'
_diffrn_measurement_method         'phi and omega scans'
_diffrn_radiation_monochromator    'graphite'
_diffrn_radiation_type             MoK\a
_diffrn_radiation_wavelength       0.71073
_diffrn_source                     ?
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  2325
_reflns_number_total               2742
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'SAINT v8.34A (Bruker, 2013)'
_computing_data_collection         ?
_computing_data_reduction          'SAINT v8.34A (Bruker, 2013)'
_computing_molecular_graphics      'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement    'ShelXL (Sheldrick, 2015)'
_computing_structure_solution      'SHELXS-97 (Sheldrick, 1990)'
_refine_diff_density_max           0.884
_refine_diff_density_min           -0.789
_refine_diff_density_rms           0.156
_refine_ls_extinction_coef         0.00057(5)
_refine_ls_extinction_expression  
 'Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^'
_refine_ls_extinction_method       'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref     1.128
_refine_ls_hydrogen_treatment      undef
_refine_ls_matrix_type             full
_refine_ls_number_parameters       143
_refine_ls_number_reflns           2742
_refine_ls_number_restraints       0
_refine_ls_R_factor_all            0.0304
_refine_ls_R_factor_gt             0.0231
_refine_ls_restrained_S_all        1.128
_refine_ls_shift/su_max            0.001
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0162P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.0447
_refine_ls_wR_factor_ref           0.0465
_refine_special_details            ?
_olex2_refinement_description
;
;
_atom_sites_solution_hydrogens     .
_atom_sites_solution_primary       ?
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Cs1 Cs 0.48351(3) 0.16479(4) 0.86099(2) 0.02686(9) Uani 1 1 d . . . . .
 Cs2 Cs 0.76551(3) 0.15830(4) 0.55501(2) 0.02695(9) Uani 1 1 d . . . . .
 Mo1 Mo 0.13515(3) 0.15319(5) 0.99276(3) 0.01698(9) Uani 1 1 d . . . . .
 P1 P 0.79802(10) -0.06258(14) 0.82786(8) 0.0175(2) Uani 1 1 d . . . . .
 P2 P 0.38406(10) 0.19304(14) 0.60835(8) 0.0185(2) Uani 1 1 d . . . . .
 Cs3 Cs 0.89163(3) 0.07326(4) 0.29227(2) 0.02749(9) Uani 1 1 d . . . . .
 O1 O 0.8217(3) 0.0413(4) 0.7440(2) 0.0293(7) Uani 1 1 d . . . . .
 O2 O 0.2886(3) 0.2069(4) 0.5281(2) 0.0260(7) Uani 1 1 d . . . . .
 O3 O 0.7700(3) 0.0396(3) 0.91656(19) 0.0209(7) Uani 1 1 d . . . . .
 O4 O 0.2029(3) 0.0732(4) 0.8947(2) 0.0334(8) Uani 1 1 d . . . . .
 O5 O 0.6762(3) -0.1816(4) 0.8105(2) 0.0245(7) Uani 1 1 d . . . . .
 O6 O 0.0550(3) 0.3331(4) 0.9599(2) 0.0333(8) Uani 1 1 d . . . . .
 O7 O 0.000000 0.000000 1.000000 0.0355(12) Uani 1 2 d S T P . .
 O8 O 0.3833(3) 0.0158(4) 0.6468(2) 0.0361(9) Uani 1 1 d . . . . .
 O9 O 0.9019(3) -0.1892(4) 0.85769(19) 0.0219(7) Uani 1 1 d . . . . .
 O10 O 0.5055(3) 0.2720(4) 0.5823(2) 0.0356(8) Uani 1 1 d . . . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Cs1 P1 3.8234(11) . ?
 Cs1 P2 3.8338(12) . ?
 Cs1 P2 3.9127(12) 4_566 ?
 Cs1 O2 3.354(3) 4_566 ?
 Cs1 O3 3.311(3) . ?
 Cs1 O4 3.122(3) . ?
 Cs1 O5 3.454(3) . ?
 Cs1 O5 3.248(3) 2_656 ?
 Cs1 O8 3.061(3) 2_656 ?
 Cs1 O8 3.491(3) . ?
 Cs1 O10 3.142(3) 2_646 ?
 Cs1 O10 3.267(3) 4_566 ?
 Cs2 Mo1 4.0984(5) 2_646 ?
 Cs2 Mo1 4.0235(5) 2_656 ?
 Cs2 P2 3.9436(12) 3_656 ?
 Cs2 O1 2.957(3) . ?
 Cs2 O2 3.120(3) 3_656 ?
 Cs2 O3 3.081(3) 4_565 ?
 Cs2 O4 3.300(3) 2_656 ?
 Cs2 O6 3.393(3) 4_665 ?
 Cs2 O6 3.166(3) 2_646 ?
 Cs2 O7 3.7254(4) 2_656 ?
 Cs2 O8 3.600(3) 3_656 ?
 Cs2 O10 2.943(3) . ?
 Mo1 P1 2.7955(12) 3_657 ?
 Mo1 Cs3 4.4425(8) 4_466 ?
 Mo1 O2 2.029(3) 4_566 ?
 Mo1 O3 2.232(3) 3_657 ?
 Mo1 O4 1.716(3) . ?
 Mo1 O6 1.700(3) . ?
 Mo1 O7 1.8697(3) . ?
 Mo1 O9 2.231(3) 3_657 ?
 P1 Cs3 3.9396(11) 4_566 ?
 P1 Cs3 4.0978(11) 4_556 ?
 P1 Cs3 3.7533(12) 3_756 ?
 P1 O1 1.482(3) . ?
 P1 O3 1.543(3) . ?
 P1 O5 1.613(3) . ?
 P1 O9 1.541(3) . ?
 P2 Cs3 3.8743(12) 3_656 ?
 P2 O2 1.555(3) . ?
 P2 O5 1.657(3) 2_656 ?
 P2 O8 1.478(3) . ?
 P2 O10 1.484(3) . ?
 Cs3 O1 3.145(3) 4_565 ?
 Cs3 O1 3.234(3) 3_756 ?
 Cs3 O3 3.727(3) 4_565 ?
 Cs3 O4 3.114(3) 3_656 ?
 Cs3 O5 3.809(3) 4 ?
 Cs3 O6 3.085(3) 4_665 ?
 Cs3 O8 3.147(3) 3_656 ?
 Cs3 O9 3.233(3) 3_756 ?
 Cs3 O9 3.114(3) 4 ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 P1 Cs1 P2 118.98(3) . 4_566 ?
 P1 Cs1 P2 98.52(3) . . ?
 P2 Cs1 P2 142.34(3) . 4_566 ?
 O2 Cs1 P1 140.72(5) 4_566 . ?
 O2 Cs1 P2 120.47(5) 4_566 . ?
 O2 Cs1 P2 23.11(5) 4_566 4_566 ?
 O2 Cs1 O5 138.92(7) 4_566 . ?
 O2 Cs1 O8 123.69(7) 4_566 . ?
 O3 Cs1 P1 23.60(5) . . ?
 O3 Cs1 P2 96.26(5) . 4_566 ?
 O3 Cs1 P2 120.43(5) . . ?
 O3 Cs1 O2 118.96(7) . 4_566 ?
 O3 Cs1 O5 43.48(7) . . ?
 O3 Cs1 O8 113.90(7) . . ?
 O4 Cs1 P1 139.59(6) . . ?
 O4 Cs1 P2 69.92(6) . 4_566 ?
 O4 Cs1 P2 84.15(6) . . ?
 O4 Cs1 O2 49.82(7) . 4_566 ?
 O4 Cs1 O3 141.68(8) . . ?
 O4 Cs1 O5 115.59(8) . . ?
 O4 Cs1 O5 72.47(8) . 2_656 ?
 O4 Cs1 O8 76.81(8) . . ?
 O4 Cs1 O10 86.96(8) . 4_566 ?
 O4 Cs1 O10 77.07(8) . 2_646 ?
 O5 Cs1 P1 122.15(5) 2_656 . ?
 O5 Cs1 P1 24.95(5) . . ?
 O5 Cs1 P2 125.12(5) . 4_566 ?
 O5 Cs1 P2 117.53(5) 2_656 4_566 ?
 O5 Cs1 P2 90.28(5) . . ?
 O5 Cs1 P2 25.38(5) 2_656 . ?
 O5 Cs1 O2 97.08(7) 2_656 4_566 ?
 O5 Cs1 O3 141.24(7) 2_656 . ?
 O5 Cs1 O5 115.60(5) 2_656 . ?
 O5 Cs1 O8 43.34(7) 2_656 . ?
 O5 Cs1 O8 74.80(7) . . ?
 O5 Cs1 O10 137.83(7) 2_656 4_566 ?
 O8 Cs1 P1 90.30(5) . . ?
 O8 Cs1 P1 89.54(6) 2_656 . ?
 O8 Cs1 P2 146.21(5) . 4_566 ?
 O8 Cs1 P2 92.45(6) 2_656 . ?
 O8 Cs1 P2 85.01(6) 2_656 4_566 ?
 O8 Cs1 P2 22.66(5) . . ?
 O8 Cs1 O2 93.17(7) 2_656 4_566 ?
 O8 Cs1 O3 80.61(8) 2_656 . ?
 O8 Cs1 O4 130.78(8) 2_656 . ?
 O8 Cs1 O5 83.86(8) 2_656 2_656 ?
 O8 Cs1 O5 113.51(8) 2_656 . ?
 O8 Cs1 O8 113.61(7) 2_656 . ?
 O8 Cs1 O10 147.69(9) 2_656 2_646 ?
 O8 Cs1 O10 82.62(8) 2_656 4_566 ?
 O10 Cs1 P1 63.78(6) 2_646 . ?
 O10 Cs1 P1 97.50(6) 4_566 . ?
 O10 Cs1 P2 92.21(6) 2_646 4_566 ?
 O10 Cs1 P2 163.20(6) 4_566 . ?
 O10 Cs1 P2 21.53(5) 4_566 4_566 ?
 O10 Cs1 P2 108.49(7) 2_646 . ?
 O10 Cs1 O2 44.34(7) 4_566 4_566 ?
 O10 Cs1 O2 96.73(7) 2_646 4_566 ?
 O10 Cs1 O3 67.68(7) 2_646 . ?
 O10 Cs1 O3 74.75(7) 4_566 . ?
 O10 Cs1 O5 124.98(8) 2_646 2_656 ?
 O10 Cs1 O5 44.58(7) 2_646 . ?
 O10 Cs1 O5 106.43(7) 4_566 . ?
 O10 Cs1 O8 162.14(8) 4_566 . ?
 O10 Cs1 O8 85.90(8) 2_646 . ?
 O10 Cs1 O10 83.23(9) 2_646 4_566 ?
 Mo1 Cs2 Mo1 143.545(14) 2_656 2_646 ?
 P2 Cs2 Mo1 130.907(19) 3_656 2_656 ?
 P2 Cs2 Mo1 49.397(18) 3_656 2_646 ?
 O1 Cs2 Mo1 79.35(6) . 2_646 ?
 O1 Cs2 Mo1 113.40(6) . 2_656 ?
 O1 Cs2 P2 115.67(6) . 3_656 ?
 O1 Cs2 O2 97.03(8) . 3_656 ?
 O1 Cs2 O3 146.75(8) . 4_565 ?
 O1 Cs2 O4 93.95(8) . 2_656 ?
 O1 Cs2 O6 72.50(9) . 2_646 ?
 O1 Cs2 O6 101.62(8) . 4_665 ?
 O1 Cs2 O7 106.26(6) . 2_656 ?
 O1 Cs2 O8 137.29(7) . 3_656 ?
 O2 Cs2 Mo1 147.01(6) 3_656 2_656 ?
 O2 Cs2 Mo1 28.78(5) 3_656 2_646 ?
 O2 Cs2 P2 21.67(5) 3_656 3_656 ?
 O2 Cs2 O4 168.70(8) 3_656 2_656 ?
 O2 Cs2 O6 50.94(8) 3_656 2_646 ?
 O2 Cs2 O6 91.62(7) 3_656 4_665 ?
 O2 Cs2 O7 132.86(6) 3_656 2_656 ?
 O2 Cs2 O8 42.71(7) 3_656 3_656 ?
 O3 Cs2 Mo1 33.39(5) 4_565 2_656 ?
 O3 Cs2 Mo1 127.14(5) 4_565 2_646 ?
 O3 Cs2 P2 97.57(6) 4_565 3_656 ?
 O3 Cs2 O2 115.62(8) 4_565 3_656 ?
 O3 Cs2 O4 53.85(7) 4_565 2_656 ?
 O3 Cs2 O6 72.74(8) 4_565 4_665 ?
 O3 Cs2 O6 122.99(8) 4_565 2_646 ?
 O3 Cs2 O7 46.63(5) 4_565 2_656 ?
 O3 Cs2 O8 75.84(7) 4_565 3_656 ?
 O4 Cs2 Mo1 158.93(6) 2_656 2_646 ?
 O4 Cs2 Mo1 24.66(5) 2_656 2_656 ?
 O4 Cs2 P2 147.31(6) 2_656 3_656 ?
 O4 Cs2 O6 88.76(7) 2_656 4_665 ?
 O4 Cs2 O7 44.99(5) 2_656 2_656 ?
 O4 Cs2 O8 126.01(7) 2_656 3_656 ?
 O6 Cs2 Mo1 70.72(5) 4_665 2_656 ?
 O6 Cs2 Mo1 73.30(5) 4_665 2_646 ?
 O6 Cs2 Mo1 22.75(6) 2_646 2_646 ?
 O6 Cs2 Mo1 125.45(6) 2_646 2_656 ?
 O6 Cs2 P2 70.09(6) 2_646 3_656 ?
 O6 Cs2 P2 97.86(5) 4_665 3_656 ?
 O6 Cs2 O4 136.19(8) 2_646 2_656 ?
 O6 Cs2 O6 55.55(10) 2_646 4_665 ?
 O6 Cs2 O7 97.93(6) 2_646 2_656 ?
 O6 Cs2 O7 44.28(5) 4_665 2_656 ?
 O6 Cs2 O8 85.18(7) 2_646 3_656 ?
 O6 Cs2 O8 94.41(7) 4_665 3_656 ?
 O7 Cs2 Mo1 117.496(11) 2_656 2_646 ?
 O7 Cs2 Mo1 27.581(5) 2_656 2_656 ?
 O7 Cs2 P2 128.991(19) 2_656 3_656 ?
 O8 Cs2 Mo1 109.23(5) 3_656 2_656 ?
 O8 Cs2 Mo1 67.74(5) 3_656 2_646 ?
 O8 Cs2 P2 21.99(5) 3_656 3_656 ?
 O8 Cs2 O7 112.67(5) 3_656 2_656 ?
 O10 Cs2 Mo1 89.43(6) . 2_656 ?
 O10 Cs2 Mo1 123.47(6) . 2_646 ?
 O10 Cs2 P2 84.48(6) . 3_656 ?
 O10 Cs2 O1 98.99(9) . . ?
 O10 Cs2 O2 98.44(8) . 3_656 ?
 O10 Cs2 O3 83.01(8) . 4_565 ?
 O10 Cs2 O4 77.14(8) . 2_656 ?
 O10 Cs2 O6 144.91(9) . 2_646 ?
 O10 Cs2 O6 155.74(9) . 4_665 ?
 O10 Cs2 O7 117.01(6) . 2_656 ?
 O10 Cs2 O8 78.73(8) . 3_656 ?
 Cs1 Mo1 Cs2 154.773(11) . 4_466 ?
 Cs1 Mo1 Cs3 102.096(12) . 4_466 ?
 Cs2 Mo1 Cs1 70.825(8) 2_656 . ?
 Cs2 Mo1 Cs1 72.924(9) 2_646 . ?
 Cs2 Mo1 Cs2 143.545(14) 2_646 2_656 ?
 Cs2 Mo1 Cs2 87.288(10) 2_656 4_466 ?
 Cs2 Mo1 Cs2 126.798(9) 2_646 4_466 ?
 Cs2 Mo1 Cs3 119.456(11) 2_646 4_466 ?
 Cs2 Mo1 Cs3 65.709(9) 2_656 4_466 ?
 Cs2 Mo1 Cs3 56.000(11) 4_466 4_466 ?
 P1 Mo1 Cs1 101.92(3) 3_657 . ?
 P1 Mo1 Cs2 81.78(2) 3_657 2_646 ?
 P1 Mo1 Cs2 109.28(3) 3_657 2_656 ?
 P1 Mo1 Cs2 96.98(3) 3_657 4_466 ?
 P1 Mo1 Cs3 151.84(3) 3_657 4_466 ?
 O2 Mo1 Cs1 52.13(9) 4_566 . ?
 O2 Mo1 Cs2 47.76(8) 4_566 2_656 ?
 O2 Mo1 Cs2 109.57(9) 4_566 2_646 ?
 O2 Mo1 Cs2 120.58(9) 4_566 4_466 ?
 O2 Mo1 P1 71.98(8) 4_566 3_657 ?
 O2 Mo1 Cs3 112.76(8) 4_566 4_466 ?
 O2 Mo1 O3 80.68(11) 4_566 3_657 ?
 O2 Mo1 O9 80.26(11) 4_566 3_657 ?
 O3 Mo1 Cs1 83.20(7) 3_657 . ?
 O3 Mo1 Cs2 49.46(7) 3_657 2_646 ?
 O3 Mo1 Cs2 128.06(7) 3_657 2_656 ?
 O3 Mo1 Cs2 121.12(7) 3_657 4_466 ?
 O3 Mo1 P1 33.41(7) 3_657 3_657 ?
 O3 Mo1 Cs3 166.13(7) 3_657 4_466 ?
 O4 Mo1 Cs1 41.52(11) . . ?
 O4 Mo1 Cs2 95.23(11) . 2_656 ?
 O4 Mo1 Cs2 133.17(11) . 4_466 ?
 O4 Mo1 Cs2 53.36(11) . 2_646 ?
 O4 Mo1 P1 125.42(11) . 3_657 ?
 O4 Mo1 Cs3 82.63(11) . 4_466 ?
 O4 Mo1 O2 93.46(14) . 4_566 ?
 O4 Mo1 O3 93.47(13) . 3_657 ?
 O4 Mo1 O7 98.41(11) . . ?
 O4 Mo1 O9 158.78(13) . 3_657 ?
 O6 Mo1 Cs1 107.54(11) . . ?
 O6 Mo1 Cs2 46.08(11) . 2_656 ?
 O6 Mo1 Cs2 149.24(11) . 2_646 ?
 O6 Mo1 Cs2 47.27(11) . 4_466 ?
 O6 Mo1 P1 126.55(12) . 3_657 ?
 O6 Mo1 Cs3 29.79(11) . 4_466 ?
 O6 Mo1 O2 92.53(14) . 4_566 ?
 O6 Mo1 O3 159.96(13) . 3_657 ?
 O6 Mo1 O4 105.80(16) . . ?
 O6 Mo1 O7 98.21(11) . . ?
 O6 Mo1 O9 94.77(14) . 3_657 ?
 O7 Mo1 Cs1 136.577(16) . . ?
 O7 Mo1 Cs2 59.494(11) . 4_466 ?
 O7 Mo1 Cs2 67.304(12) . 2_646 ?
 O7 Mo1 Cs2 144.184(17) . 2_656 ?
 O7 Mo1 P1 89.20(3) . 3_657 ?
 O7 Mo1 Cs3 83.388(15) . 4_466 ?
 O7 Mo1 O2 161.16(8) . 4_566 ?
 O7 Mo1 O3 84.03(7) . 3_657 ?
 O7 Mo1 O9 83.44(7) . 3_657 ?
 O9 Mo1 Cs1 127.06(7) 3_657 . ?
 O9 Mo1 Cs2 109.52(7) 3_657 2_646 ?
 O9 Mo1 Cs2 95.36(7) 3_657 2_656 ?
 O9 Mo1 Cs2 65.72(7) 3_657 4_466 ?
 O9 Mo1 P1 33.38(7) 3_657 3_657 ?
 O9 Mo1 Cs3 118.52(7) 3_657 4_466 ?
 O9 Mo1 O3 65.59(10) 3_657 3_657 ?
 Cs1 P1 Cs3 132.22(3) . 4_556 ?
 Cs1 P1 Cs3 78.50(2) . 4_566 ?
 Mo1 P1 Cs1 102.76(3) 3_657 . ?
 Mo1 P1 Cs3 101.80(4) 3_657 3_756 ?
 Mo1 P1 Cs3 79.37(3) 3_657 4_556 ?
 Mo1 P1 Cs3 107.32(3) 3_657 4_566 ?
 Cs3 P1 Cs1 147.87(3) 3_756 . ?
 Cs3 P1 Cs3 147.40(3) 4_566 4_556 ?
 Cs3 P1 Cs3 72.77(2) 3_756 4_556 ?
 Cs3 P1 Cs3 74.63(2) 3_756 4_566 ?
 O1 P1 Cs1 90.39(13) . . ?
 O1 P1 Mo1 149.41(14) . 3_657 ?
 O1 P1 Cs3 47.94(12) . 4_566 ?
 O1 P1 Cs3 111.94(13) . 4_556 ?
 O1 P1 Cs3 58.43(13) . 3_756 ?
 O1 P1 O3 116.52(17) . . ?
 O1 P1 O5 108.51(17) . . ?
 O1 P1 O9 116.82(17) . . ?
 O3 P1 Cs1 59.23(11) . . ?
 O3 P1 Mo1 52.81(11) . 3_657 ?
 O3 P1 Cs3 70.72(11) . 4_566 ?
 O3 P1 Cs3 125.01(12) . 3_756 ?
 O3 P1 Cs3 130.16(11) . 4_556 ?
 O3 P1 O5 105.33(16) . . ?
 O5 P1 Cs1 64.59(11) . . ?
 O5 P1 Mo1 102.07(11) . 3_657 ?
 O5 P1 Cs3 136.89(11) . 4_566 ?
 O5 P1 Cs3 128.95(11) . 3_756 ?
 O5 P1 Cs3 68.30(11) . 4_556 ?
 O9 P1 Cs1 152.72(11) . . ?
 O9 P1 Mo1 52.77(11) . 3_657 ?
 O9 P1 Cs3 117.47(11) . 4_566 ?
 O9 P1 Cs3 58.68(11) . 3_756 ?
 O9 P1 Cs3 41.42(11) . 4_556 ?
 O9 P1 O3 103.22(16) . . ?
 O9 P1 O5 105.34(15) . . ?
 Cs1 P2 Cs1 145.44(3) . 4_565 ?
 Cs1 P2 Cs1 81.04(2) . 2_656 ?
 Cs1 P2 Cs1 75.33(2) 4_565 2_656 ?
 Cs1 P2 Cs2 74.21(2) 2_656 . ?
 Cs1 P2 Cs2 65.10(2) 4_565 . ?
 Cs1 P2 Cs2 84.52(3) . . ?
 Cs1 P2 Cs2 75.41(2) 4_565 3_656 ?
 Cs1 P2 Cs2 148.29(3) 2_656 3_656 ?
 Cs1 P2 Cs2 130.65(3) . 3_656 ?
 Cs1 P2 Cs3 79.74(3) . 3_656 ?
 Cs2 P2 Cs2 103.89(3) 3_656 . ?
 Cs3 P2 Cs1 134.42(3) 3_656 4_565 ?
 Cs3 P2 Cs1 136.28(3) 3_656 2_656 ?
 Cs3 P2 Cs2 63.42(2) 3_656 3_656 ?
 Cs3 P2 Cs2 141.42(3) 3_656 . ?
 O2 P2 Cs1 155.01(12) . . ?
 O2 P2 Cs1 104.93(12) . 2_656 ?
 O2 P2 Cs1 57.83(12) . 4_565 ?
 O2 P2 Cs2 47.82(11) . 3_656 ?
 O2 P2 Cs2 120.47(12) . . ?
 O2 P2 Cs3 79.52(12) . 3_656 ?
 O2 P2 O5 103.88(15) . 2_656 ?
 O5 P2 Cs1 126.76(11) 2_656 4_565 ?
 O5 P2 Cs1 61.25(11) 2_656 2_656 ?
 O5 P2 Cs1 57.13(10) 2_656 . ?
 O5 P2 Cs2 123.54(11) 2_656 . ?
 O5 P2 Cs2 132.30(11) 2_656 3_656 ?
 O5 P2 Cs3 75.33(11) 2_656 3_656 ?
 O8 P2 Cs1 127.56(13) . 4_565 ?
 O8 P2 Cs1 65.52(14) . . ?
 O8 P2 Cs1 144.69(15) . 2_656 ?
 O8 P2 Cs2 90.96(13) . . ?
 O8 P2 Cs2 65.80(14) . 3_656 ?
 O8 P2 Cs3 50.47(13) . 3_656 ?
 O8 P2 O2 110.17(19) . . ?
 O8 P2 O5 105.55(17) . 2_656 ?
 O8 P2 O10 118.82(19) . . ?
 O10 P2 Cs1 48.20(13) . 2_656 ?
 O10 P2 Cs1 53.91(14) . 4_565 ?
 O10 P2 Cs1 91.53(14) . . ?
 O10 P2 Cs2 28.46(13) . . ?
 O10 P2 Cs2 118.85(14) . 3_656 ?
 O10 P2 Cs3 168.36(15) . 3_656 ?
 O10 P2 O2 110.70(19) . . ?
 O10 P2 O5 106.46(18) . 2_656 ?
 P1 Cs3 P1 107.89(3) 3_756 4_565 ?
 P1 Cs3 P2 146.68(2) 3_756 3_656 ?
 P1 Cs3 O5 123.37(5) 3_756 4 ?
 P2 Cs3 P1 105.40(2) 3_656 4_565 ?
 O1 Cs3 P1 121.62(5) 3_756 4_565 ?
 O1 Cs3 P1 97.28(6) 4_565 3_756 ?
 O1 Cs3 P1 20.48(5) 4_565 4_565 ?
 O1 Cs3 P1 22.98(5) 3_756 3_756 ?
 O1 Cs3 P2 113.82(6) 4_565 3_656 ?
 O1 Cs3 P2 129.62(5) 3_756 3_656 ?
 O1 Cs3 O1 116.55(7) 4_565 3_756 ?
 O1 Cs3 O3 42.94(7) 4_565 4_565 ?
 O1 Cs3 O3 129.02(7) 3_756 4_565 ?
 O1 Cs3 O5 128.46(7) 4_565 4 ?
 O1 Cs3 O5 111.59(7) 3_756 4 ?
 O1 Cs3 O8 92.71(8) 4_565 3_656 ?
 O1 Cs3 O9 75.52(7) 4_565 3_756 ?
 O3 Cs3 P1 23.00(4) 4_565 4_565 ?
 O3 Cs3 P1 123.57(5) 4_565 3_756 ?
 O3 Cs3 P2 88.72(5) 4_565 3_656 ?
 O3 Cs3 O5 112.99(6) 4_565 4 ?
 O4 Cs3 P1 82.58(6) 3_656 3_756 ?
 O4 Cs3 P1 112.35(6) 3_656 4_565 ?
 O4 Cs3 P2 83.56(6) 3_656 3_656 ?
 O4 Cs3 O1 94.06(8) 3_656 4_565 ?
 O4 Cs3 O1 93.71(8) 3_656 3_756 ?
 O4 Cs3 O3 127.01(7) 3_656 4_565 ?
 O4 Cs3 O5 65.02(7) 3_656 4 ?
 O4 Cs3 O8 82.24(8) 3_656 3_656 ?
 O4 Cs3 O9 74.41(8) 3_656 3_756 ?
 O5 Cs3 P1 126.67(5) 4 4_565 ?
 O5 Cs3 P2 24.90(4) 4 3_656 ?
 O6 Cs3 P1 82.73(6) 4_665 3_756 ?
 O6 Cs3 P1 79.36(6) 4_665 4_565 ?
 O6 Cs3 P2 105.02(6) 4_665 3_656 ?
 O6 Cs3 O1 69.95(8) 4_665 3_756 ?
 O6 Cs3 O1 95.14(8) 4_665 4_565 ?
 O6 Cs3 O3 68.03(7) 4_665 4_565 ?
 O6 Cs3 O4 163.54(8) 4_665 3_656 ?
 O6 Cs3 O5 118.19(7) 4_665 4 ?
 O6 Cs3 O8 110.88(9) 4_665 3_656 ?
 O6 Cs3 O9 94.75(8) 4_665 3_756 ?
 O6 Cs3 O9 87.77(8) 4_665 4 ?
 O8 Cs3 P1 86.24(6) 3_656 4_565 ?
 O8 Cs3 P1 162.36(6) 3_656 3_756 ?
 O8 Cs3 P2 21.23(5) 3_656 3_656 ?
 O8 Cs3 O1 150.71(8) 3_656 3_756 ?
 O8 Cs3 O3 73.23(7) 3_656 4_565 ?
 O8 Cs3 O5 40.73(7) 3_656 4 ?
 O8 Cs3 O9 152.80(8) 3_656 3_756 ?
 O9 Cs3 P1 89.85(5) 3_756 4_565 ?
 O9 Cs3 P1 151.68(5) 4 4_565 ?
 O9 Cs3 P1 24.04(5) 3_756 3_756 ?
 O9 Cs3 P1 95.20(5) 4 3_756 ?
 O9 Cs3 P2 156.82(5) 3_756 3_656 ?
 O9 Cs3 P2 53.69(5) 4 3_656 ?
 O9 Cs3 O1 46.94(7) 3_756 3_756 ?
 O9 Cs3 O1 75.93(7) 4 3_756 ?
 O9 Cs3 O1 167.44(8) 4 4_565 ?
 O9 Cs3 O3 110.18(6) 3_756 4_565 ?
 O9 Cs3 O3 128.77(7) 4 4_565 ?
 O9 Cs3 O4 86.19(8) 4 3_656 ?
 O9 Cs3 O5 40.97(6) 4 4 ?
 O9 Cs3 O5 132.86(6) 3_756 4 ?
 O9 Cs3 O8 74.86(7) 4 3_656 ?
 O9 Cs3 O9 116.49(6) 4 3_756 ?
 Cs2 O1 Cs3 97.07(8) . 3_756 ?
 Cs2 O1 Cs3 88.12(7) . 4_566 ?
 P1 O1 Cs2 153.74(18) . . ?
 P1 O1 Cs3 111.59(15) . 4_566 ?
 P1 O1 Cs3 98.59(15) . 3_756 ?
 Cs3 O1 Cs3 93.99(8) 4_566 3_756 ?
 Cs2 O2 Cs1 95.76(7) 3_656 4_565 ?
 Mo1 O2 Cs1 99.34(11) 4_565 4_565 ?
 Mo1 O2 Cs2 103.45(11) 4_565 3_656 ?
 P2 O2 Cs1 99.06(13) . 4_565 ?
 P2 O2 Cs2 110.51(13) . 3_656 ?
 P2 O2 Mo1 139.20(17) . 4_565 ?
 Cs1 O3 Cs3 88.33(6) . 4_566 ?
 Cs2 O3 Cs1 85.66(7) 4_566 . ?
 Cs2 O3 Cs3 73.58(6) 4_566 4_566 ?
 Mo1 O3 Cs1 139.33(11) 3_657 . ?
 Mo1 O3 Cs2 97.15(9) 3_657 4_566 ?
 Mo1 O3 Cs3 131.51(11) 3_657 4_566 ?
 P1 O3 Cs1 97.17(13) . . ?
 P1 O3 Cs2 159.60(15) . 4_566 ?
 P1 O3 Mo1 93.78(13) . 3_657 ?
 P1 O3 Cs3 86.28(11) . 4_566 ?
 Cs1 O4 Cs2 98.98(9) . 2_646 ?
 Mo1 O4 Cs1 117.10(14) . . ?
 Mo1 O4 Cs2 101.97(13) . 2_646 ?
 Mo1 O4 Cs3 136.12(15) . 3_656 ?
 Cs3 O4 Cs1 104.82(9) 3_656 . ?
 Cs3 O4 Cs2 82.83(7) 3_656 2_646 ?
 Cs1 O5 Cs1 97.61(7) 2_646 . ?
 Cs1 O5 Cs3 171.72(9) . 4_556 ?
 Cs1 O5 Cs3 88.53(7) 2_646 4_556 ?
 P1 O5 Cs1 90.46(12) . . ?
 P1 O5 Cs1 138.73(15) . 2_646 ?
 P1 O5 P2 122.37(18) . 2_646 ?
 P1 O5 Cs3 88.53(12) . 4_556 ?
 P2 O5 Cs1 97.49(12) 2_646 2_646 ?
 P2 O5 Cs1 93.87(12) 2_646 . ?
 P2 O5 Cs3 79.77(11) 2_646 4_556 ?
 Cs2 O6 Cs2 124.45(10) 2_656 4_466 ?
 Mo1 O6 Cs2 111.14(13) . 4_466 ?
 Mo1 O6 Cs2 111.17(14) . 2_656 ?
 Mo1 O6 Cs3 134.32(16) . 4_466 ?
 Cs3 O6 Cs2 95.91(8) 4_466 2_656 ?
 Cs3 O6 Cs2 78.59(7) 4_466 4_466 ?
 Cs2 O7 Cs2 180.0 2_646 4_466 ?
 Mo1 O7 Cs2 85.115(13) 3_557 4_466 ?
 Mo1 O7 Cs2 94.886(13) . 4_466 ?
 Mo1 O7 Cs2 94.885(13) 3_557 2_646 ?
 Mo1 O7 Cs2 85.114(13) . 2_646 ?
 Mo1 O7 Mo1 180.0 3_557 . ?
 Cs1 O8 Cs1 100.49(9) 2_646 . ?
 Cs1 O8 Cs2 170.72(10) . 3_656 ?
 Cs1 O8 Cs2 81.09(7) 2_646 3_656 ?
 Cs1 O8 Cs3 104.60(9) 2_646 3_656 ?
 P2 O8 Cs1 143.31(18) . 2_646 ?
 P2 O8 Cs1 91.82(15) . . ?
 P2 O8 Cs2 92.21(15) . 3_656 ?
 P2 O8 Cs3 108.30(15) . 3_656 ?
 Cs3 O8 Cs1 96.08(8) 3_656 . ?
 Cs3 O8 Cs2 74.72(7) 3_656 3_656 ?
 Mo1 O9 Cs3 114.26(10) 3_657 4_556 ?
 Mo1 O9 Cs3 138.31(12) 3_657 3_756 ?
 P1 O9 Mo1 93.86(13) . 3_657 ?
 P1 O9 Cs3 97.28(12) . 3_756 ?
 P1 O9 Cs3 119.46(14) . 4_556 ?
 Cs3 O9 Cs3 94.63(7) 4_556 3_756 ?
 Cs1 O10 Cs1 96.77(9) 2_656 4_565 ?
 Cs2 O10 Cs1 106.73(9) . 2_656 ?
 Cs2 O10 Cs1 88.75(8) . 4_565 ?
 P2 O10 Cs1 104.56(16) . 4_565 ?
 P2 O10 Cs1 111.19(16) . 2_656 ?
 P2 O10 Cs2 137.64(19) . . ?

_olex2_submission_special_instructions  'No special instructions were received'
