####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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#######################################################################

data_(Sb13S16Cl2)[AlCl4]5
_database_code_depnum_ccdc_archive 'CCDC 2125501'
loop_
_audit_author_name
_audit_author_address
'Matthias Grasser'
;Technische Universitaet Dresden
Germany
;
_audit_update_record             
;
2021-12-01 deposited with the CCDC.	2022-02-03 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         (Sb13S16Cl2)[AlCl4]5
_chemical_formula_sum            'Al5 Cl22 S16 Sb13'
_chemical_formula_weight         3010.51

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Al Al 0.0645 0.0514 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.8886(10)
_cell_length_b                   19.043(2)
_cell_length_c                   21.125(2)
_cell_angle_alpha                63.884(2)
_cell_angle_beta                 80.322(2)
_cell_angle_gamma                88.699(2)
_cell_volume                     3159.7(6)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    9899
_cell_measurement_theta_min      2.33
_cell_measurement_theta_max      32.33

_exptl_crystal_description       plank
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    3.164
_exptl_crystal_F_000             2716
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.056
_exptl_crystal_size_mid          0.042
_exptl_crystal_size_min          0.032
_exptl_absorpt_coefficient_mu    7.003
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5687
_exptl_absorpt_correction_T_max  0.7464
_exptl_absorpt_process_details   'SADABS (Bruker 2014)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            127692
_diffrn_reflns_av_unetI/netI     0.0269
_diffrn_reflns_av_R_equivalents  0.0319
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_theta_min         1.940
_diffrn_reflns_theta_max         32.623
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             23016
_reflns_number_gt                17999
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     'w=1/[σ²(Fo²)] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     'dual space'
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         23016
_refine_ls_number_parameters     505
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0442
_refine_ls_R_factor_gt           0.0272
_refine_ls_wR_factor_ref         0.0273
_refine_ls_wR_factor_gt          0.0265
_refine_ls_goodness_of_fit_ref   1.308
_refine_ls_restrained_S_all      1.308
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 0.65721(2) 0.05138(2) 0.39474(2) 0.02928(4) Uani 1 1 d . . . . .
Sb2 Sb 0.44715(2) 0.19221(2) 0.24793(2) 0.03215(4) Uani 1 1 d . . . . .
Sb3 Sb 0.85620(2) 0.20627(2) 0.21487(2) 0.03163(4) Uani 1 1 d . . . . .
Sb4 Sb 0.63728(2) 0.26670(2) 0.35803(2) 0.02534(3) Uani 1 1 d . . . . .
Sb5 Sb 0.39673(2) 0.37672(2) 0.44307(2) 0.02786(4) Uani 1 1 d . . . . .
Sb6 Sb 0.80252(2) 0.40628(2) 0.41710(2) 0.02881(4) Uani 1 1 d . . . . .
Sb7 Sb 0.61953(2) 0.50057(2) 0.25417(2) 0.02748(4) Uani 1 1 d . . . . .
Sb8 Sb 0.54211(2) 0.63579(2) 0.06741(2) 0.02666(4) Uani 1 1 d . . . . .
Sb9 Sb 0.92389(2) 0.59428(2) 0.09232(2) 0.02952(4) Uani 1 1 d . . . . .
Sb10 Sb 0.71910(2) 0.73534(2) 0.15788(2) 0.02762(4) Uani 1 1 d . . . . .
Sb11 Sb 0.43632(2) 0.80096(2) 0.27108(2) 0.02962(4) Uani 1 1 d . . . . .
Sb12 Sb 0.83116(2) 0.83260(2) 0.27442(2) 0.03012(4) Uani 1 1 d . . . . .
Sb13 Sb 0.67075(2) 0.96508(2) 0.10975(2) 0.03531(4) Uani 1 1 d . . . . .
S1 S 0.44199(6) 0.14278(3) 0.37697(3) 0.03021(13) Uani 1 1 d . . . . .
S2 S 0.65151(7) 0.11234(3) 0.22977(3) 0.03292(14) Uani 1 1 d . . . . .
S3 S 0.87539(6) 0.14870(3) 0.34097(3) 0.02952(13) Uani 1 1 d . . . . .
S4 S 0.64978(7) 0.29952(3) 0.22556(3) 0.02829(13) Uani 1 1 d . . . . .
S5 S 0.40954(6) 0.34686(3) 0.34119(3) 0.02731(13) Uani 1 1 d . . . . .
S6 S 0.61100(6) 0.29704(3) 0.48814(3) 0.02769(13) Uani 1 1 d . . . . .
S7 S 0.81863(6) 0.39775(3) 0.29970(3) 0.02624(13) Uani 1 1 d . . . . .
S8 S 0.58751(7) 0.49630(3) 0.38511(4) 0.03604(15) Uani 1 1 d . . . . .
S9 S 0.68649(7) 0.51302(3) 0.11542(4) 0.03491(15) Uani 1 1 d . . . . .
S10 S 0.85127(6) 0.59335(3) 0.21416(3) 0.02875(13) Uani 1 1 d . . . . .
S11 S 0.78965(6) 0.71059(3) 0.02394(3) 0.03152(14) Uani 1 1 d . . . . .
S12 S 0.48553(6) 0.65460(3) 0.17878(3) 0.02907(13) Uani 1 1 d . . . . .
S13 S 0.66356(6) 0.71352(3) 0.28888(3) 0.02917(13) Uani 1 1 d . . . . .
S14 S 0.50541(6) 0.84524(3) 0.13977(3) 0.03011(13) Uani 1 1 d . . . . .
S15 S 0.89766(7) 0.89185(4) 0.14488(3) 0.03532(15) Uani 1 1 d . . . . .
S16 S 0.59178(6) 0.89835(3) 0.28049(3) 0.03240(14) Uani 1 1 d . . . . .
Cl1 Cl 0.64885(7) 0.06646(4) 0.50282(3) 0.04335(16) Uani 1 1 d . . . . .
Cl2 Cl 0.74125(10) 0.97974(5) -0.00823(4) 0.0738(2) Uani 1 1 d . . . . .
Al1 Al 0.04822(7) 0.17929(4) 0.52701(4) 0.02626(15) Uani 1 1 d . . . . .
Cl11 Cl 0.01530(7) 0.27088(4) 0.42558(3) 0.04504(17) Uani 1 1 d . . . . .
Cl12 Cl 0.26711(7) 0.20389(4) 0.54677(4) 0.04990(19) Uani 1 1 d . . . . .
Cl13 Cl 0.06037(8) 0.07101(4) 0.52317(4) 0.05177(18) Uani 1 1 d . . . . .
Cl14 Cl -0.12506(7) 0.18586(4) 0.60580(3) 0.05004(18) Uani 1 1 d . . . . .
Al2 Al 0.22776(7) 0.78846(4) -0.01401(4) 0.02634(15) Uani 1 1 d . . . . .
Cl21 Cl 0.12852(7) 0.72661(4) 0.09671(3) 0.04160(16) Uani 1 1 d . . . . .
Cl22 Cl 0.22482(7) 0.70259(4) -0.05380(3) 0.04167(15) Uani 1 1 d . . . . .
Cl23 Cl 0.45858(7) 0.82389(4) -0.02330(4) 0.04651(17) Uani 1 1 d . . . . .
Cl24 Cl 0.09646(7) 0.88424(4) -0.06589(4) 0.05052(18) Uani 1 1 d . . . . .
Al3 Al 0.21473(7) 0.40175(4) 0.14249(4) 0.02949(16) Uani 1 1 d . . . . .
Cl31 Cl 0.14504(7) 0.30370(4) 0.24360(3) 0.04573(17) Uani 1 1 d . . . . .
Cl32 Cl 0.26057(7) 0.50046(4) 0.16112(4) 0.04651(17) Uani 1 1 d . . . . .
Cl33 Cl 0.03186(8) 0.42281(4) 0.08432(4) 0.0565(2) Uani 1 1 d . . . . .
Cl34 Cl 0.41493(7) 0.37739(5) 0.08705(4) 0.0562(2) Uani 1 1 d . . . . .
Al4 Al 0.11277(7) 0.60166(4) 0.36097(4) 0.02660(15) Uani 1 1 d . . . . .
Cl41 Cl 0.10645(7) 0.70771(3) 0.26597(3) 0.03888(15) Uani 1 1 d . . . . .
Cl42 Cl 0.29295(7) 0.61269(4) 0.41172(3) 0.04144(15) Uani 1 1 d . . . . .
Cl43 Cl 0.16569(7) 0.50645(4) 0.33429(3) 0.04223(16) Uani 1 1 d . . . . .
Cl44 Cl -0.10305(7) 0.57997(4) 0.42897(4) 0.05043(18) Uani 1 1 d . . . . .
Al5 Al 0.16690(7) 0.02429(4) 0.23864(4) 0.02960(16) Uani 1 1 d . . . . .
Cl51 Cl -0.07090(6) -0.01069(4) 0.27932(4) 0.04048(16) Uani 1 1 d . . . . .
Cl52 Cl 0.28602(7) 0.02036(4) 0.31893(3) 0.04607(17) Uani 1 1 d . . . . .
Cl53 Cl 0.25506(7) -0.05255(4) 0.19418(3) 0.04628(17) Uani 1 1 d . . . . .
Cl54 Cl 0.19006(8) 0.14203(4) 0.15876(4) 0.05372(19) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb1 Cl1 2.4123(7) . ?
Sb1 S3 2.4607(6) . ?
Sb1 S1 2.5188(6) . ?
Sb1 S2 3.1609(7) . ?
Sb1 Cl1 3.3380(7) 2_656 ?
Sb1 Sb3 3.7917(3) . ?
Sb2 S2 2.4320(6) . ?
Sb2 S1 2.4537(7) . ?
Sb2 S4 2.5834(6) . ?
Sb2 Cl52 3.1906(7) . ?
Sb2 Cl31 3.3734(7) . ?
Sb2 Sb3 3.5785(5) . ?
Sb3 S3 2.4289(6) . ?
Sb3 S2 2.4636(7) . ?
Sb3 S4 2.5761(6) . ?
Sb3 Cl22 3.2677(7) 2_665 ?
Sb3 Cl54 3.4114(8) 1_655 ?
Sb3 Cl31 3.4833(7) 1_655 ?
Sb4 S5 2.4856(6) . ?
Sb4 S4 2.5677(6) . ?
Sb4 S7 2.6744(6) . ?
Sb4 S1 2.8042(6) . ?
Sb4 S6 3.0198(7) . ?
Sb4 S3 3.1463(7) . ?
Sb5 S5 2.4415(6) . ?
Sb5 S6 2.4582(6) . ?
Sb5 S8 2.5656(6) . ?
Sb5 Cl12 3.1520(7) . ?
Sb5 Cl43 3.4583(7) . ?
Sb5 Sb6 3.5753(5) . ?
Sb6 S6 2.4559(6) . ?
Sb6 S8 2.5126(6) . ?
Sb6 S7 2.5361(6) . ?
Sb6 Cl11 3.1214(7) 1_655 ?
Sb6 Cl42 3.4293(7) 2_666 ?
Sb7 S10 2.5187(6) . ?
Sb7 S7 2.5783(6) . ?
Sb7 S8 2.6978(7) . ?
Sb7 S9 2.7946(7) . ?
Sb7 S12 2.9875(6) . ?
Sb7 S5 3.1286(6) . ?
Sb8 S11 2.4546(6) . ?
Sb8 S12 2.5004(6) . ?
Sb8 S9 2.5211(6) . ?
Sb8 Cl32 3.3104(7) . ?
Sb8 Cl34 3.3398(8) 2_665 ?
Sb8 Cl23 3.3716(8) . ?
Sb9 S11 2.4615(6) . ?
Sb9 S9 2.4946(6) . ?
Sb9 S10 2.5382(7) . ?
Sb9 Cl21 3.1839(7) 1_655 ?
Sb9 Cl33 3.4498(8) 1_655 ?
Sb10 S12 2.4714(6) . ?
Sb10 S13 2.5714(7) . ?
Sb10 S14 2.7373(6) . ?
Sb10 S10 2.7568(6) . ?
Sb10 S11 3.0308(7) . ?
Sb10 S15 3.2901(7) . ?
Sb11 S16 2.4335(6) . ?
Sb11 S14 2.4848(7) . ?
Sb11 S13 2.5584(6) . ?
Sb11 Cl53 3.1149(7) 1_565 ?
Sb11 Sb12 3.5920(4) . ?
Sb12 S15 2.4246(7) . ?
Sb12 S16 2.4578(6) . ?
Sb12 S13 2.6164(6) . ?
Sb12 Cl51 3.1773(7) 1_665 ?
Sb12 Cl41 3.4114(7) 1_655 ?
Sb12 Cl12 3.4818(8) 2_666 ?
Sb13 Cl2 2.3563(8) . ?
Sb13 S15 2.4552(7) . ?
Sb13 S14 2.5169(6) . ?
Sb13 S16 3.2049(7) . ?
Sb13 Cl24 3.2646(7) 2_675 ?
Cl1 Sb1 3.3380(7) 2_656 ?
Al1 Cl13 2.0986(10) . ?
Al1 Cl14 2.1145(9) . ?
Al1 Cl11 2.1486(9) . ?
Al1 Cl12 2.1599(9) . ?
Cl11 Sb6 3.1214(7) 1_455 ?
Cl12 Sb12 3.4819(8) 2_666 ?
Al2 Cl24 2.1127(9) . ?
Al2 Cl23 2.1246(9) . ?
Al2 Cl21 2.1364(9) . ?
Al2 Cl22 2.1449(9) . ?
Cl21 Sb9 3.1839(7) 1_455 ?
Cl22 Sb3 3.2677(7) 2_665 ?
Cl24 Sb13 3.2647(7) 2_675 ?
Al3 Cl34 2.1199(9) . ?
Al3 Cl33 2.1263(9) . ?
Al3 Cl31 2.1281(9) . ?
Al3 Cl32 2.1434(10) . ?
Cl31 Sb3 3.4832(7) 1_455 ?
Cl33 Sb9 3.4498(8) 1_455 ?
Cl34 Sb8 3.3398(8) 2_665 ?
Al4 Cl44 2.1215(9) . ?
Al4 Cl42 2.1330(9) . ?
Al4 Cl41 2.1386(9) . ?
Al4 Cl43 2.1443(9) . ?
Cl41 Sb12 3.4114(7) 1_455 ?
Cl42 Sb6 3.4291(7) 2_666 ?
Al5 Cl54 2.1191(10) . ?
Al5 Cl52 2.1194(9) . ?
Al5 Cl53 2.1324(9) . ?
Al5 Cl51 2.1446(9) . ?
Cl51 Sb12 3.1773(7) 1_445 ?
Cl53 Sb11 3.1149(7) 1_545 ?
Cl54 Sb3 3.4114(8) 1_455 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl1 Sb1 S3 87.28(2) . . ?
Cl1 Sb1 S1 82.99(2) . . ?
S3 Sb1 S1 99.24(2) . . ?
Cl1 Sb1 S2 154.32(2) . . ?
S3 Sb1 S2 78.799(18) . . ?
S1 Sb1 S2 78.148(18) . . ?
Cl1 Sb1 Cl1 79.76(2) . 2_656 ?
S3 Sb1 Cl1 166.706(19) . 2_656 ?
S1 Sb1 Cl1 76.375(19) . 2_656 ?
S2 Sb1 Cl1 112.009(16) . 2_656 ?
Cl1 Sb1 Sb3 121.233(17) . . ?
S3 Sb1 Sb3 38.852(14) . . ?
S1 Sb1 Sb3 85.015(15) . . ?
S2 Sb1 Sb3 40.235(12) . . ?
Cl1 Sb1 Sb3 150.187(12) 2_656 . ?
S2 Sb2 S1 95.43(2) . . ?
S2 Sb2 S4 89.29(2) . . ?
S1 Sb2 S4 88.716(19) . . ?
S2 Sb2 Cl52 76.48(2) . . ?
S1 Sb2 Cl52 74.799(18) . . ?
S4 Sb2 Cl52 156.837(18) . . ?
S2 Sb2 Cl31 168.67(2) . . ?
S1 Sb2 Cl31 94.949(18) . . ?
S4 Sb2 Cl31 95.47(2) . . ?
Cl52 Sb2 Cl31 101.960(19) . . ?
S2 Sb2 Sb3 43.380(15) . . ?
S1 Sb2 Sb3 90.769(14) . . ?
S4 Sb2 Sb3 46.003(14) . . ?
Cl52 Sb2 Sb3 116.768(14) . . ?
Cl31 Sb2 Sb3 140.963(13) . . ?
S3 Sb3 S2 95.06(2) . . ?
S3 Sb3 S4 94.10(2) . . ?
S2 Sb3 S4 88.77(2) . . ?
S3 Sb3 Cl22 169.652(19) . 2_665 ?
S2 Sb3 Cl22 82.756(19) . 2_665 ?
S4 Sb3 Cl22 75.772(18) . 2_665 ?
S3 Sb3 Cl54 96.628(19) . 1_655 ?
S2 Sb3 Cl54 106.38(2) . 1_655 ?
S4 Sb3 Cl54 160.504(17) . 1_655 ?
Cl22 Sb3 Cl54 93.689(17) 2_665 1_655 ?
S3 Sb3 Cl31 69.136(17) . 1_655 ?
S2 Sb3 Cl31 164.046(19) . 1_655 ?
S4 Sb3 Cl31 94.372(19) . 1_655 ?
Cl22 Sb3 Cl31 113.181(16) 2_665 1_655 ?
Cl54 Sb3 Cl31 74.480(18) 1_655 1_655 ?
S5 Sb4 S4 83.998(19) . . ?
S5 Sb4 S7 89.74(2) . . ?
S4 Sb4 S7 81.443(18) . . ?
S5 Sb4 S1 86.52(2) . . ?
S4 Sb4 S1 81.831(18) . . ?
S7 Sb4 S1 163.152(18) . . ?
S5 Sb4 S6 80.976(18) . . ?
S4 Sb4 S6 157.290(18) . . ?
S7 Sb4 S6 81.558(17) . . ?
S1 Sb4 S6 113.967(17) . . ?
S5 Sb4 S3 159.056(18) . . ?
S4 Sb4 S3 79.080(17) . . ?
S7 Sb4 S3 99.766(18) . . ?
S1 Sb4 S3 78.983(18) . . ?
S6 Sb4 S3 118.696(16) . . ?
S5 Sb5 S6 94.49(2) . . ?
S5 Sb5 S8 98.92(2) . . ?
S6 Sb5 S8 87.27(2) . . ?
S5 Sb5 Cl12 89.55(2) . . ?
S6 Sb5 Cl12 71.510(19) . . ?
S8 Sb5 Cl12 157.764(19) . . ?
S5 Sb5 Cl43 74.376(18) . . ?
S6 Sb5 Cl43 163.818(18) . . ?
S8 Sb5 Cl43 83.020(19) . . ?
Cl12 Sb5 Cl43 119.150(17) . . ?
S5 Sb5 Sb6 93.187(14) . . ?
S6 Sb5 Sb6 43.292(14) . . ?
S8 Sb5 Sb6 44.648(14) . . ?
Cl12 Sb5 Sb6 114.775(13) . . ?
Cl43 Sb5 Sb6 124.200(13) . . ?
S6 Sb6 S8 88.51(2) . . ?
S6 Sb6 S7 96.625(19) . . ?
S8 Sb6 S7 89.16(2) . . ?
S6 Sb6 Cl11 82.64(2) . 1_655 ?
S8 Sb6 Cl11 159.38(2) . 1_655 ?
S7 Sb6 Cl11 73.505(18) . 1_655 ?
S6 Sb6 Cl42 70.015(18) . 2_666 ?
S8 Sb6 Cl42 87.921(19) . 2_666 ?
S7 Sb6 Cl42 166.387(16) . 2_666 ?
Cl11 Sb6 Cl42 106.276(17) 1_655 2_666 ?
S6 Sb6 Sb5 43.343(14) . . ?
S8 Sb6 Sb5 45.854(15) . . ?
S7 Sb6 Sb5 87.989(13) . . ?
Cl11 Sb6 Sb5 120.633(14) 1_655 . ?
Cl42 Sb6 Sb5 80.448(11) 2_666 . ?
S10 Sb7 S7 81.94(2) . . ?
S10 Sb7 S8 89.185(19) . . ?
S7 Sb7 S8 84.357(19) . . ?
S10 Sb7 S9 84.375(19) . . ?
S7 Sb7 S9 93.154(18) . . ?
S8 Sb7 S9 173.369(18) . . ?
S10 Sb7 S12 78.870(19) . . ?
S7 Sb7 S12 160.566(17) . . ?
S8 Sb7 S12 98.349(18) . . ?
S9 Sb7 S12 81.984(17) . . ?
S10 Sb7 S5 159.093(17) . . ?
S7 Sb7 S5 78.685(18) . . ?
S8 Sb7 S5 81.203(17) . . ?
S9 Sb7 S5 104.375(17) . . ?
S12 Sb7 S5 120.743(17) . . ?
S11 Sb8 S12 94.46(2) . . ?
S11 Sb8 S9 87.73(2) . . ?
S12 Sb8 S9 98.20(2) . . ?
S11 Sb8 Cl32 163.805(19) . . ?
S12 Sb8 Cl32 79.644(18) . . ?
S9 Sb8 Cl32 78.306(19) . . ?
S11 Sb8 Cl34 88.12(2) . 2_665 ?
S12 Sb8 Cl34 173.697(18) . 2_665 ?
S9 Sb8 Cl34 87.63(2) . 2_665 ?
Cl32 Sb8 Cl34 99.337(19) . 2_665 ?
S11 Sb8 Cl23 75.018(18) . . ?
S12 Sb8 Cl23 87.438(19) . . ?
S9 Sb8 Cl23 162.256(17) . . ?
Cl32 Sb8 Cl23 119.358(17) . . ?
Cl34 Sb8 Cl23 87.677(19) 2_665 . ?
S11 Sb9 S9 88.18(2) . . ?
S11 Sb9 S10 97.90(2) . . ?
S9 Sb9 S10 90.49(2) . . ?
S11 Sb9 Cl21 80.25(2) . 1_655 ?
S9 Sb9 Cl21 156.484(19) . 1_655 ?
S10 Sb9 Cl21 71.136(17) . 1_655 ?
S11 Sb9 Cl33 137.73(2) . 1_655 ?
S9 Sb9 Cl33 72.269(19) . 1_655 ?
S10 Sb9 Cl33 118.763(19) . 1_655 ?
Cl21 Sb9 Cl33 129.156(18) 1_655 1_655 ?
S11 Sb9 Sb8 43.865(14) . . ?
S9 Sb9 Sb8 45.415(15) . . ?
S10 Sb9 Sb8 88.085(14) . . ?
Cl21 Sb9 Sb8 117.226(15) 1_655 . ?
Cl33 Sb9 Sb8 112.999(12) 1_655 . ?
S12 Sb10 S13 90.304(19) . . ?
S12 Sb10 S14 79.93(2) . . ?
S13 Sb10 S14 83.712(18) . . ?
S12 Sb10 S10 84.34(2) . . ?
S13 Sb10 S10 83.608(18) . . ?
S14 Sb10 S10 159.694(18) . . ?
S12 Sb10 S11 82.087(18) . . ?
S13 Sb10 S11 163.557(17) . . ?
S14 Sb10 S11 109.055(18) . . ?
S10 Sb10 S11 81.160(18) . . ?
S12 Sb10 S15 152.548(18) . . ?
S13 Sb10 S15 79.019(17) . . ?
S14 Sb10 S15 73.848(18) . . ?
S10 Sb10 S15 118.942(18) . . ?
S11 Sb10 S15 113.937(16) . . ?
S16 Sb11 S14 98.58(2) . . ?
S16 Sb11 S13 88.83(2) . . ?
S14 Sb11 S13 89.292(19) . . ?
S16 Sb11 Cl53 81.42(2) . 1_565 ?
S14 Sb11 Cl53 71.539(18) . 1_565 ?
S13 Sb11 Cl53 156.758(19) . 1_565 ?
S16 Sb11 Sb12 43.010(14) . . ?
S14 Sb11 Sb12 88.687(15) . . ?
S13 Sb11 Sb12 46.711(15) . . ?
Cl53 Sb11 Sb12 117.753(15) 1_565 . ?
S16 Sb11 Sb10 101.287(16) . . ?
S14 Sb11 Sb10 46.850(14) . . ?
S13 Sb11 Sb10 43.158(14) . . ?
Cl53 Sb11 Sb10 118.243(14) 1_565 . ?
Sb12 Sb11 Sb10 64.587(7) . . ?
S15 Sb12 S16 96.62(2) . . ?
S15 Sb12 S13 96.74(2) . . ?
S16 Sb12 S13 87.01(2) . . ?
S15 Sb12 Cl51 92.03(2) . 1_665 ?
S16 Sb12 Cl51 75.269(19) . 1_665 ?
S13 Sb12 Cl51 161.033(17) . 1_665 ?
S15 Sb12 Cl41 83.651(19) . 1_655 ?
S16 Sb12 Cl41 166.101(18) . 1_655 ?
S13 Sb12 Cl41 79.176(19) . 1_655 ?
Cl51 Sb12 Cl41 118.629(16) 1_665 1_655 ?
S15 Sb12 Cl12 165.65(2) . 2_666 ?
S16 Sb12 Cl12 75.415(19) . 2_666 ?
S13 Sb12 Cl12 94.758(17) . 2_666 ?
Cl51 Sb12 Cl12 74.519(17) 1_665 2_666 ?
Cl41 Sb12 Cl12 106.989(16) 1_655 2_666 ?
Cl2 Sb13 S15 91.27(3) . . ?
Cl2 Sb13 S14 89.19(3) . . ?
S15 Sb13 S14 94.38(2) . . ?
Cl2 Sb13 S16 165.02(3) . . ?
S15 Sb13 S16 78.986(19) . . ?
S14 Sb13 S16 80.343(18) . . ?
Cl2 Sb13 Cl24 88.25(3) . 2_675 ?
S15 Sb13 Cl24 82.83(2) . 2_675 ?
S14 Sb13 Cl24 176.170(19) . 2_675 ?
S16 Sb13 Cl24 101.624(18) . 2_675 ?
Cl2 Sb13 Sb11 129.43(2) . . ?
S15 Sb13 Sb11 87.589(16) . . ?
S14 Sb13 Sb11 40.670(14) . . ?
S16 Sb13 Sb11 39.758(11) . . ?
Cl24 Sb13 Sb11 141.382(15) 2_675 . ?
Sb2 S1 Sb1 100.86(2) . . ?
Sb2 S1 Sb4 93.039(19) . . ?
Sb1 S1 Sb4 91.83(2) . . ?
Sb2 S2 Sb3 93.93(2) . . ?
Sb2 S2 Sb1 85.482(18) . . ?
Sb3 S2 Sb1 83.794(18) . . ?
Sb3 S3 Sb1 101.69(2) . . ?
Sb3 S3 Sb4 87.905(18) . . ?
Sb1 S3 Sb4 85.201(19) . . ?
Sb4 S4 Sb3 98.74(2) . . ?
Sb4 S4 Sb2 95.824(19) . . ?
Sb3 S4 Sb2 87.83(2) . . ?
Sb5 S5 Sb4 98.85(2) . . ?
Sb5 S5 Sb7 85.980(18) . . ?
Sb4 S5 Sb7 90.694(19) . . ?
Sb6 S6 Sb5 93.37(2) . . ?
Sb6 S6 Sb4 87.461(18) . . ?
Sb5 S6 Sb4 85.540(17) . . ?
Sb6 S7 Sb7 94.148(19) . . ?
Sb6 S7 Sb4 93.843(18) . . ?
Sb7 S7 Sb4 99.83(2) . . ?
Sb6 S8 Sb5 89.50(2) . . ?
Sb6 S8 Sb7 91.83(2) . . ?
Sb5 S8 Sb7 93.38(2) . . ?
Sb9 S9 Sb8 89.78(2) . . ?
Sb9 S9 Sb7 89.58(2) . . ?
Sb8 S9 Sb7 91.59(2) . . ?
Sb7 S10 Sb9 95.13(2) . . ?
Sb7 S10 Sb10 100.51(2) . . ?
Sb9 S10 Sb10 92.497(18) . . ?
Sb8 S11 Sb9 92.11(2) . . ?
Sb8 S11 Sb10 85.551(18) . . ?
Sb9 S11 Sb10 87.724(19) . . ?
Sb10 S12 Sb8 97.89(2) . . ?
Sb10 S12 Sb7 95.61(2) . . ?
Sb8 S12 Sb7 87.622(18) . . ?
Sb11 S13 Sb10 93.95(2) . . ?
Sb11 S13 Sb12 87.91(2) . . ?
Sb10 S13 Sb12 98.323(19) . . ?
Sb11 S14 Sb13 98.02(2) . . ?
Sb11 S14 Sb10 91.676(19) . . ?
Sb13 S14 Sb10 101.20(2) . . ?
Sb12 S15 Sb13 101.48(2) . . ?
Sb12 S15 Sb10 85.332(18) . . ?
Sb13 S15 Sb10 88.761(19) . . ?
Sb11 S16 Sb12 94.51(2) . . ?
Sb11 S16 Sb13 82.861(18) . . ?
Sb12 S16 Sb13 82.577(18) . . ?
Sb1 Cl1 Sb1 100.24(2) . 2_656 ?
Cl13 Al1 Cl14 116.08(4) . . ?
Cl13 Al1 Cl11 110.63(4) . . ?
Cl14 Al1 Cl11 106.97(4) . . ?
Cl13 Al1 Cl12 106.59(4) . . ?
Cl14 Al1 Cl12 108.53(4) . . ?
Cl11 Al1 Cl12 107.76(4) . . ?
Al1 Cl11 Sb6 121.09(3) . 1_455 ?
Al1 Cl12 Sb5 111.94(3) . . ?
Al1 Cl12 Sb12 100.24(3) . 2_666 ?
Sb5 Cl12 Sb12 113.95(2) . 2_666 ?
Cl24 Al2 Cl23 112.31(4) . . ?
Cl24 Al2 Cl21 109.92(4) . . ?
Cl23 Al2 Cl21 109.29(4) . . ?
Cl24 Al2 Cl22 112.10(4) . . ?
Cl23 Al2 Cl22 108.77(4) . . ?
Cl21 Al2 Cl22 104.11(4) . . ?
Al2 Cl21 Sb9 100.22(3) . 1_455 ?
Al2 Cl22 Sb3 106.50(3) . 2_665 ?
Al2 Cl23 Sb8 90.72(3) . . ?
Al2 Cl24 Sb13 102.70(3) . 2_675 ?
Cl34 Al3 Cl33 110.92(4) . . ?
Cl34 Al3 Cl31 109.68(4) . . ?
Cl33 Al3 Cl31 107.65(4) . . ?
Cl34 Al3 Cl32 109.93(4) . . ?
Cl33 Al3 Cl32 110.51(4) . . ?
Cl31 Al3 Cl32 108.09(4) . . ?
Al3 Cl31 Sb2 100.40(3) . . ?
Al3 Cl31 Sb3 103.97(3) . 1_455 ?
Sb2 Cl31 Sb3 103.89(2) . 1_455 ?
Al3 Cl32 Sb8 124.84(3) . . ?
Al3 Cl33 Sb9 97.43(3) . 1_455 ?
Al3 Cl34 Sb8 127.89(3) . 2_665 ?
Cl44 Al4 Cl42 111.58(4) . . ?
Cl44 Al4 Cl41 108.26(4) . . ?
Cl42 Al4 Cl41 109.56(4) . . ?
Cl44 Al4 Cl43 111.09(4) . . ?
Cl42 Al4 Cl43 106.12(4) . . ?
Cl41 Al4 Cl43 110.23(4) . . ?
Al4 Cl41 Sb12 117.32(3) . 1_455 ?
Al4 Cl42 Sb6 117.78(3) . 2_666 ?
Al4 Cl43 Sb5 112.23(3) . . ?
Cl54 Al5 Cl52 106.43(4) . . ?
Cl54 Al5 Cl53 110.69(4) . . ?
Cl52 Al5 Cl53 112.03(4) . . ?
Cl54 Al5 Cl51 109.50(4) . . ?
Cl52 Al5 Cl51 112.21(4) . . ?
Cl53 Al5 Cl51 106.01(4) . . ?
Al5 Cl51 Sb12 113.41(3) . 1_445 ?
Al5 Cl52 Sb2 102.27(3) . . ?
Al5 Cl53 Sb11 124.71(3) . 1_545 ?
Al5 Cl54 Sb3 99.00(3) . 1_455 ?

_refine_diff_density_max         1.291
_refine_diff_density_min         -1.063
_refine_diff_density_rms         0.130


_exptl_crystal_recrystallization_method ionothermal
_chemical_properties_physical    
Air-sensitive,Moisture-sensitive,Oxygen-sensitive
