# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_132_sq
_database_code_depnum_ccdc_archive 'CCDC 2127906'
loop_
_audit_author_name
_audit_author_address
'Mei Ming'
;Tianjin Agricultural University
China
;
_audit_update_record             
;
2021-12-11 deposited with the CCDC.	2022-01-31 downloaded from the CCDC.
;
_audit_creation_date             2020-09-17
_audit_creation_method           
;
Olex2 1.2-beta
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C26 H16 Ag N4, B F4'
_chemical_formula_sum            'C26 H18 Ag B F4 N4'
_chemical_formula_weight         581.12
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C H O N Ag B F'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0090 0.0039 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   9.4608(3)
_cell_length_b                   22.8750(5)
_cell_length_c                   13.4599(3)
_cell_angle_alpha                90
_cell_angle_beta                 105.718(2)
_cell_angle_gamma                90
_cell_volume                     2804.01(13)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    5538
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      73.5880
_cell_measurement_theta_min      3.8150
_shelx_estimated_absorpt_T_max   0.372
_shelx_estimated_absorpt_T_min   0.372
_exptl_absorpt_coefficient_mu    6.173
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.29541
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.377
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1160
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0439
_diffrn_reflns_av_unetI/netI     0.0489
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.974
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            11371
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.974
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         73.821
_diffrn_reflns_theta_min         3.865
_diffrn_ambient_temperature      293(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 5.3031
_diffrn_detector_type            AtlasS2
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -16.00  26.00   1.00    3.77    --   40.80 -57.00 -60.00   42
  2  ω     44.00 118.00   1.00   15.09    --  107.14-125.00 -60.00   74
  3  ω     30.00  87.00   1.00   15.09    --  107.14 -95.00 -60.00   57
  4  ω     25.00 104.00   1.00   15.09    --  107.14 -95.00  90.00   79
  5  ω      5.00  54.00   1.00    3.77    --   40.80 -99.00 120.00   49
  6  ω     82.00 142.00   1.00   15.09    --  107.14  45.00  60.00   60
  7  ω     80.00 120.00   1.00   15.09    --  107.14  77.00 -60.00   40
  8  ω    123.00 154.00   1.00   15.09    --  107.14 125.00-120.00   31
  9  ω    139.00 177.00   1.00   15.09    --  107.14  61.00-120.00   38
 10  ω     78.00 178.00   1.00   15.09    --  107.14  61.00 150.00  100
 11  ω    -94.00 -49.00   1.00    3.77    --  -40.80 125.00-180.00   45
 12  ω   -114.00 -32.00   1.00    3.77    --  -40.80 -77.00  30.00   82
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, AtlasS2'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.1305305000
_diffrn_orient_matrix_UB_12      0.0428319000
_diffrn_orient_matrix_UB_13      0.0276034000
_diffrn_orient_matrix_UB_21      -0.1069930000
_diffrn_orient_matrix_UB_22      0.0518704000
_diffrn_orient_matrix_UB_23      -0.0296485000
_diffrn_orient_matrix_UB_31      -0.0118590000
_diffrn_orient_matrix_UB_32      0.0031802000
_diffrn_orient_matrix_UB_33      0.1117710000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4519
_reflns_number_total             5526
_reflns_odcompleteness_completeness 99.84
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'XS (Sheldrick, 2008)'
_refine_diff_density_max         1.031
_refine_diff_density_min         -1.086
_refine_diff_density_rms         0.100
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     325
_refine_ls_number_reflns         5526
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0640
_refine_ls_R_factor_gt           0.0578
_refine_ls_restrained_S_all      1.046
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1130P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1670
_refine_ls_wR_factor_ref         0.1754
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C10(H10), C7(H7), C18(H18), C3(H3), C16(H16), C13(H13), C5(H5), C24(H24),
 C25(H25), C14(H14), C19(H19), C15(H15), C2(H2), C21(H21), C20(H20), C1(H1)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.84537(4) 0.38184(2) 0.12844(2) 0.05897(17) Uani 1 1 d . . . . .
F4 F 0.5392(5) 0.33137(13) 0.9305(3) 0.0874(9) Uani 1 1 d . . . . .
N2 N 0.5104(4) 0.18294(13) 0.5788(3) 0.0497(7) Uani 1 1 d . . . . .
N4 N 0.9476(4) 0.58381(15) 0.7341(3) 0.0514(7) Uani 1 1 d . . . . .
N1 N 0.6865(4) 0.35736(15) 0.2225(2) 0.0486(7) Uani 1 1 d . . . . .
N3 N 0.7658(4) 0.43875(15) 0.9800(2) 0.0506(7) Uani 1 1 d . . . . .
C12 C 0.6251(4) 0.27437(15) 0.5573(2) 0.0388(7) Uani 1 1 d . . . . .
C23 C 0.7656(4) 0.51866(15) 0.6315(2) 0.0392(7) Uani 1 1 d . . . . .
C10 C 0.6496(4) 0.36297(16) 0.6698(2) 0.0417(7) Uani 1 1 d . . . . .
H10 H 0.637012 0.338768 0.722274 0.050 Uiso 1 1 calc R . . . .
C8 C 0.7069(4) 0.45798(15) 0.6124(2) 0.0394(7) Uani 1 1 d . . . . .
C9 C 0.6799(4) 0.42229(15) 0.6910(2) 0.0392(7) Uani 1 1 d . . . . .
C7 C 0.6853(4) 0.43492(15) 0.5141(2) 0.0404(7) Uani 1 1 d . . . . .
H7 H 0.695218 0.459326 0.461190 0.048 Uiso 1 1 calc R . . . .
C17 C 0.6833(4) 0.44644(15) 0.7947(2) 0.0411(7) Uani 1 1 d . . . . .
C11 C 0.6377(4) 0.33900(15) 0.5725(2) 0.0396(7) Uani 1 1 d . . . . .
C18 C 0.7574(4) 0.41832(16) 0.8852(3) 0.0440(7) Uani 1 1 d . . . . .
H18 H 0.804099 0.383159 0.879780 0.053 Uiso 1 1 calc R . . . .
C4 C 0.6204(4) 0.35598(15) 0.3828(2) 0.0399(7) Uani 1 1 d . . . . .
C3 C 0.5005(4) 0.31997(17) 0.3389(3) 0.0463(8) Uani 1 1 d . . . . .
H3 H 0.438394 0.307190 0.377460 0.056 Uiso 1 1 calc R . . . .
C22 C 0.8846(4) 0.53082(15) 0.7156(3) 0.0431(7) Uani 1 1 d . . . . .
C16 C 0.5224(4) 0.24153(16) 0.5900(3) 0.0447(7) Uani 1 1 d . . . . .
H16 H 0.458966 0.260843 0.620973 0.054 Uiso 1 1 calc R . . . .
C13 C 0.7193(4) 0.24526(17) 0.5112(3) 0.0445(7) Uani 1 1 d . . . . .
H13 H 0.789124 0.265873 0.488295 0.053 Uiso 1 1 calc R . . . .
C6 C 0.6491(4) 0.37642(15) 0.4921(3) 0.0404(7) Uani 1 1 d . . . . .
C5 C 0.7079(4) 0.37380(16) 0.3212(3) 0.0428(7) Uani 1 1 d . . . . .
H5 H 0.786179 0.398638 0.349871 0.051 Uiso 1 1 calc R . . . .
F1 F 0.5679(10) 0.2382(2) 0.9807(4) 0.174(3) Uani 1 1 d . . . . .
C24 C 0.7130(4) 0.56357(17) 0.5618(3) 0.0468(8) Uani 1 1 d . . . . .
H24 H 0.634322 0.557035 0.504175 0.056 Uiso 1 1 calc R . . . .
C26 C 0.8938(6) 0.62668(18) 0.6674(4) 0.0561(10) Uani 1 1 d . . . . .
C25 C 0.7784(5) 0.61800(16) 0.5787(4) 0.0530(10) Uani 1 1 d . . . . .
H25 H 0.746201 0.648277 0.531970 0.064 Uiso 1 1 calc R . . . .
F3 F 0.6841(6) 0.2701(2) 0.8672(4) 0.1289(19) Uani 1 1 d . . . . .
C14 C 0.7081(5) 0.18478(19) 0.4997(3) 0.0530(9) Uani 1 1 d . . . . .
H14 H 0.770228 0.164326 0.469130 0.064 Uiso 1 1 calc R . . . .
C19 C 0.6112(5) 0.49800(19) 0.8042(3) 0.0524(9) Uani 1 1 d . . . . .
H19 H 0.559196 0.518028 0.745565 0.063 Uiso 1 1 calc R . . . .
C15 C 0.6033(5) 0.15598(17) 0.5345(3) 0.0545(9) Uani 1 1 d . . . . .
H15 H 0.596513 0.115586 0.526902 0.065 Uiso 1 1 calc R . . . .
C2 C 0.4764(5) 0.3038(2) 0.2365(3) 0.0575(10) Uani 1 1 d . . . . .
H2 H 0.397075 0.280027 0.205239 0.069 Uiso 1 1 calc R . . . .
C21 C 0.6949(6) 0.4889(2) 0.9863(3) 0.0598(10) Uani 1 1 d . . . . .
H21 H 0.698829 0.503599 1.051352 0.072 Uiso 1 1 calc R . . . .
C20 C 0.6167(6) 0.51956(19) 0.9010(3) 0.0600(10) Uani 1 1 d . . . . .
H20 H 0.568549 0.554061 0.908481 0.072 Uiso 1 1 calc R . . . .
C1 C 0.5698(5) 0.3229(2) 0.1816(3) 0.0565(10) Uani 1 1 d . . . . .
H1 H 0.551829 0.311673 0.112924 0.068 Uiso 1 1 calc R . . . .
F2 F 0.4562(8) 0.2580(3) 0.8249(6) 0.180(3) Uani 1 1 d . . . . .
B1 B 0.5717(7) 0.2749(2) 0.9071(4) 0.0636(13) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N2 2.376(3) 4_665 ?
Ag1 N4 2.432(3) 3_766 ?
Ag1 N1 2.282(3) . ?
Ag1 N3 2.332(3) 1_554 ?
F4 B1 1.384(6) . ?
N2 C16 1.350(5) . ?
N2 C15 1.339(6) . ?
N4 C22 1.344(5) . ?
N4 C26 1.333(6) . ?
N1 C5 1.342(5) . ?
N1 C1 1.347(6) . ?
N3 C18 1.341(5) . ?
N3 C21 1.342(6) . ?
C12 C11 1.493(5) . ?
C12 C16 1.390(5) . ?
C12 C13 1.386(5) . ?
C23 C8 1.491(5) . ?
C23 C22 1.391(5) . ?
C23 C24 1.389(5) . ?
C10 H10 0.9300 . ?
C10 C9 1.400(5) . ?
C10 C11 1.396(5) . ?
C8 C9 1.413(5) . ?
C8 C7 1.386(5) . ?
C9 C17 1.493(4) . ?
C7 H7 0.9300 . ?
C7 C6 1.393(5) . ?
C17 C18 1.388(5) . ?
C17 C19 1.386(6) . ?
C11 C6 1.407(5) . ?
C18 H18 0.9300 . ?
C4 C3 1.397(5) . ?
C4 C6 1.496(4) . ?
C4 C5 1.382(5) . ?
C3 H3 0.9300 . ?
C3 C2 1.385(5) . ?
C16 H16 0.9300 . ?
C13 H13 0.9300 . ?
C13 C14 1.393(6) . ?
C5 H5 0.9300 . ?
F1 B1 1.307(6) . ?
C24 H24 0.9300 . ?
C24 C25 1.382(5) . ?
C26 C25 1.397(7) . ?
C25 H25 0.9300 . ?
F3 B1 1.319(7) . ?
C14 H14 0.9300 . ?
C14 C15 1.374(6) . ?
C19 H19 0.9300 . ?
C19 C20 1.381(6) . ?
C15 H15 0.9300 . ?
C2 H2 0.9300 . ?
C2 C1 1.369(7) . ?
C21 H21 0.9300 . ?
C21 C20 1.377(6) . ?
C20 H20 0.9300 . ?
C1 H1 0.9300 . ?
F2 B1 1.383(8) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Ag1 N4 87.72(12) 4_665 3_766 ?
N1 Ag1 N2 125.79(12) . 4_665 ?
N1 Ag1 N4 99.95(12) . 3_766 ?
N1 Ag1 N3 120.27(12) . 1_554 ?
N3 Ag1 N2 101.05(12) 1_554 4_665 ?
N3 Ag1 N4 118.56(12) 1_554 3_766 ?
C16 N2 Ag1 129.0(3) . 4_566 ?
C15 N2 Ag1 113.5(2) . 4_566 ?
C15 N2 C16 117.5(3) . . ?
C22 N4 Ag1 131.1(3) . 3_766 ?
C26 N4 Ag1 110.9(3) . 3_766 ?
C26 N4 C22 118.0(3) . . ?
C5 N1 Ag1 122.4(3) . . ?
C5 N1 C1 117.1(3) . . ?
C1 N1 Ag1 120.5(2) . . ?
C18 N3 Ag1 122.9(3) . 1_556 ?
C18 N3 C21 117.1(3) . . ?
C21 N3 Ag1 118.3(2) . 1_556 ?
C16 C12 C11 121.9(3) . . ?
C13 C12 C11 120.0(3) . . ?
C13 C12 C16 118.1(3) . . ?
C22 C23 C8 120.5(3) . . ?
C24 C23 C8 121.5(3) . . ?
C24 C23 C22 117.7(3) . . ?
C9 C10 H10 118.9 . . ?
C11 C10 H10 118.9 . . ?
C11 C10 C9 122.1(3) . . ?
C9 C8 C23 122.9(3) . . ?
C7 C8 C23 118.1(3) . . ?
C7 C8 C9 119.0(3) . . ?
C10 C9 C8 118.4(3) . . ?
C10 C9 C17 120.0(3) . . ?
C8 C9 C17 121.6(3) . . ?
C8 C7 H7 118.9 . . ?
C8 C7 C6 122.2(3) . . ?
C6 C7 H7 118.9 . . ?
C18 C17 C9 121.8(3) . . ?
C19 C17 C9 121.0(3) . . ?
C19 C17 C18 117.2(3) . . ?
C10 C11 C12 120.1(3) . . ?
C10 C11 C6 118.7(3) . . ?
C6 C11 C12 121.1(3) . . ?
N3 C18 C17 124.0(4) . . ?
N3 C18 H18 118.0 . . ?
C17 C18 H18 118.0 . . ?
C3 C4 C6 120.7(3) . . ?
C5 C4 C3 118.0(3) . . ?
C5 C4 C6 121.2(3) . . ?
C4 C3 H3 120.8 . . ?
C2 C3 C4 118.3(4) . . ?
C2 C3 H3 120.8 . . ?
N4 C22 C23 123.5(3) . . ?
N2 C16 C12 123.1(3) . . ?
N2 C16 H16 118.4 . . ?
C12 C16 H16 118.4 . . ?
C12 C13 H13 120.4 . . ?
C12 C13 C14 119.2(4) . . ?
C14 C13 H13 120.4 . . ?
C7 C6 C11 119.1(3) . . ?
C7 C6 C4 118.6(3) . . ?
C11 C6 C4 122.3(3) . . ?
N1 C5 C4 123.8(3) . . ?
N1 C5 H5 118.1 . . ?
C4 C5 H5 118.1 . . ?
C23 C24 H24 120.3 . . ?
C25 C24 C23 119.5(3) . . ?
C25 C24 H24 120.3 . . ?
N4 C26 C25 122.6(4) . . ?
C24 C25 C26 118.7(4) . . ?
C24 C25 H25 120.6 . . ?
C26 C25 H25 120.6 . . ?
C13 C14 H14 120.7 . . ?
C15 C14 C13 118.6(4) . . ?
C15 C14 H14 120.7 . . ?
C17 C19 H19 120.1 . . ?
C20 C19 C17 119.9(4) . . ?
C20 C19 H19 120.1 . . ?
N2 C15 C14 123.5(4) . . ?
N2 C15 H15 118.2 . . ?
C14 C15 H15 118.2 . . ?
C3 C2 H2 120.1 . . ?
C1 C2 C3 119.7(4) . . ?
C1 C2 H2 120.1 . . ?
N3 C21 H21 118.4 . . ?
N3 C21 C20 123.2(3) . . ?
C20 C21 H21 118.4 . . ?
C19 C20 H20 120.7 . . ?
C21 C20 C19 118.6(4) . . ?
C21 C20 H20 120.7 . . ?
N1 C1 C2 123.0(3) . . ?
N1 C1 H1 118.5 . . ?
C2 C1 H1 118.5 . . ?
F1 B1 F4 111.9(4) . . ?
F1 B1 F3 116.6(6) . . ?
F1 B1 F2 104.4(6) . . ?
F3 B1 F4 115.0(5) . . ?
F3 B1 F2 101.6(6) . . ?
F2 B1 F4 105.5(5) . . ?

_platon_squeeze_details          ?
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.000 0.500 0.500 298 -2 ' '
2 0.500 1.000 1.000 298 -2 ' '

_platon_squeeze_void_probe_radius 1.20
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 5.852
_oxdiff_exptl_absorpt_empirical_full_min 0.433
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_132Re
_database_code_depnum_ccdc_archive 'CCDC 2127907'
loop_
_audit_author_name
_audit_author_address
'Mei Ming'
;Tianjin Agricultural University
China
;
_audit_update_record             
;
2021-12-11 deposited with the CCDC.	2022-01-31 downloaded from the CCDC.
;
_audit_creation_date             2020-08-03
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.06.28 svn.raecde09e for OlexSys, GUI svn.r6132)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C26 H18 Ag2 N4 O4 Re, O4 Re'
_chemical_formula_sum            'C26 H18 Ag2 N4 O8 Re2'
_chemical_formula_weight         1102.58
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Re Re -1.0185 7.2310 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   21.6514(14)
_cell_length_b                   10.3653(6)
_cell_length_c                   24.7561(15)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     5555.8(6)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    4755
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      24.59
_cell_measurement_theta_min      2.33
_shelx_estimated_absorpt_T_max   0.263
_shelx_estimated_absorpt_T_min   0.214
_exptl_absorpt_coefficient_mu    10.133
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.4487
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2012/1 (Bruker,2012) was used for absorption correction.
wR2(int) was 0.1521 before and 0.0637 after correction.
The Ratio of minimum to maximum transmission is 0.6017.
The λ/2 correction factor is 0.0015.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.636
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             4080
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.18
_exptl_special_details           
;
 ? 
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0757
_diffrn_reflns_av_unetI/netI     0.0498
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            34603
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.500
_diffrn_reflns_theta_min         1.645
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4398
_reflns_number_total             5749
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'Bruker SHELXTL'
_refine_diff_density_max         1.430
_refine_diff_density_min         -1.803
_refine_diff_density_rms         0.184
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     379
_refine_ls_number_reflns         5749
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0573
_refine_ls_R_factor_gt           0.0378
_refine_ls_restrained_S_all      1.041
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0372P)²+20.3158P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0877
_refine_ls_wR_factor_ref         0.0942
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C1(H1), C3(H3), C4(H4), C5(H5), C6(H6), C7(H7), C8(H8), C10(H10), C11(H11),
 C13(H13), C14(H14), C15(H15), C16(H16), C18(H18), C19(H19), C20(H20), C22(H22),
  C25(H25)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.29237(3) 0.04078(8) 0.61324(2) 0.0459(2) Uani 1 1 d . . . . .
Ag2 Ag 0.53029(4) 0.36785(7) 0.51312(3) 0.0481(2) Uani 1 1 d . . . . .
Re1 Re 0.33759(2) 0.42049(4) 0.53720(2) 0.03886(11) Uani 1 1 d . . . . .
Re2 Re 0.44816(2) 0.11822(3) 0.66992(2) 0.03572(10) Uani 1 1 d . . . . .
O1 O 0.4161(3) 0.4028(7) 0.5397(3) 0.0609(19) Uani 1 1 d . . . . .
O2 O 0.3205(4) 0.5794(7) 0.5503(3) 0.073(2) Uani 1 1 d . . . . .
O3 O 0.3031(4) 0.3228(7) 0.5843(3) 0.072(2) Uani 1 1 d . . . . .
O4 O 0.3118(4) 0.3811(7) 0.4739(3) 0.0611(19) Uani 1 1 d . . . . .
O5 O 0.4179(3) 0.2573(7) 0.6965(3) 0.0601(19) Uani 1 1 d . . . . .
O6 O 0.3950(3) -0.0037(7) 0.6754(3) 0.0599(19) Uani 1 1 d . . . . .
O7 O 0.4657(3) 0.1412(7) 0.6032(3) 0.0593(19) Uani 1 1 d . . . . .
O8 O 0.5135(4) 0.0760(8) 0.7040(3) 0.077(2) Uani 1 1 d . . . . .
N1 N 0.5032(3) 0.3182(6) 0.4297(2) 0.0323(15) Uani 1 1 d . . . . .
N2 N 0.3432(3) 0.0083(6) 0.5392(2) 0.0299(15) Uani 1 1 d . . . . .
N3 N 0.2381(3) 0.4322(7) 0.1856(2) 0.0376(17) Uani 1 1 d . . . . .
N4 N 0.0713(3) 0.1237(6) 0.4066(2) 0.0298(14) Uani 1 1 d . . . . .
C1 C 0.4457(4) 0.2834(7) 0.4202(3) 0.0251(16) Uani 1 1 d . . . . .
H1 H 0.417916 0.286492 0.448859 0.030 Uiso 1 1 calc R U . . .
C2 C 0.4235(3) 0.2422(6) 0.3703(3) 0.0223(15) Uani 1 1 d . . . . .
C3 C 0.4652(4) 0.2430(7) 0.3278(3) 0.0285(17) Uani 1 1 d . . . . .
H3 H 0.452742 0.218896 0.293335 0.034 Uiso 1 1 calc R U . . .
C4 C 0.5255(4) 0.2803(8) 0.3375(3) 0.037(2) Uani 1 1 d . . . . .
H4 H 0.554175 0.279840 0.309507 0.045 Uiso 1 1 calc R U . . .
C5 C 0.5430(4) 0.3179(8) 0.3885(3) 0.038(2) Uani 1 1 d . . . . .
H5 H 0.583585 0.343688 0.394402 0.046 Uiso 1 1 calc R U . . .
C6 C 0.3960(4) -0.0575(7) 0.5367(3) 0.0332(19) Uani 1 1 d . . . . .
H6 H 0.411109 -0.096638 0.567847 0.040 Uiso 1 1 calc R U . . .
C7 C 0.4291(4) -0.0693(8) 0.4890(3) 0.0334(19) Uani 1 1 d . . . . .
H7 H 0.465910 -0.115708 0.488513 0.040 Uiso 1 1 calc R U . . .
C8 C 0.4079(4) -0.0133(7) 0.4433(3) 0.0267(17) Uani 1 1 d . . . . .
H8 H 0.429682 -0.021986 0.411076 0.032 Uiso 1 1 calc R U . . .
C9 C 0.3542(3) 0.0562(7) 0.4446(3) 0.0213(15) Uani 1 1 d . . . . .
C10 C 0.3226(4) 0.0645(7) 0.4936(3) 0.0265(16) Uani 1 1 d . . . . .
H10 H 0.285841 0.110686 0.494753 0.032 Uiso 1 1 calc R U . . .
C11 C 0.2594(4) 0.3540(7) 0.2243(3) 0.0324(19) Uani 1 1 d . . . . .
H11 H 0.295761 0.308909 0.217728 0.039 Uiso 1 1 calc R U . . .
C12 C 0.2302(3) 0.3362(7) 0.2741(2) 0.0220(15) Uani 1 1 d . . . . .
C13 C 0.1758(4) 0.4031(7) 0.2822(3) 0.0259(16) Uani 1 1 d . . . . .
H13 H 0.154487 0.393710 0.314599 0.031 Uiso 1 1 calc R U . . .
C14 C 0.1532(4) 0.4828(7) 0.2431(3) 0.0314(18) Uani 1 1 d . . . . .
H14 H 0.116404 0.527277 0.248447 0.038 Uiso 1 1 calc R U . . .
C15 C 0.1856(4) 0.4964(8) 0.1959(3) 0.038(2) Uani 1 1 d . . . . .
H15 H 0.170466 0.552698 0.169782 0.045 Uiso 1 1 calc R U . . .
C16 C 0.1309(4) 0.1480(7) 0.3999(3) 0.0284(17) Uani 1 1 d . . . . .
H16 H 0.154028 0.167449 0.430534 0.034 Uiso 1 1 calc R U . . .
C17 C 0.1616(3) 0.1466(7) 0.3503(3) 0.0241(16) Uani 1 1 d . . . . .
C18 C 0.1264(4) 0.1158(7) 0.3053(3) 0.0299(17) Uani 1 1 d . . . . .
H18 H 0.144569 0.111681 0.271273 0.036 Uiso 1 1 calc R U . . .
C19 C 0.0642(4) 0.0912(7) 0.3114(3) 0.0340(19) Uani 1 1 d . . . . .
H19 H 0.040103 0.071486 0.281438 0.041 Uiso 1 1 calc R U . . .
C20 C 0.0374(4) 0.0960(7) 0.3623(3) 0.0352(19) Uani 1 1 d . . . . .
H20 H -0.004626 0.079724 0.365998 0.042 Uiso 1 1 calc R U . . .
C21 C 0.2292(4) 0.1687(7) 0.3502(3) 0.0239(15) Uani 1 1 d . . . . .
C22 C 0.2630(4) 0.1048(6) 0.3892(3) 0.0231(16) Uani 1 1 d . . . . .
H22 H 0.242598 0.045331 0.410920 0.028 Uiso 1 1 calc R U . . .
C23 C 0.3254(4) 0.1238(7) 0.3978(2) 0.0236(16) Uani 1 1 d . . . . .
C24 C 0.3575(3) 0.2068(7) 0.3634(2) 0.0223(15) Uani 1 1 d . . . . .
C25 C 0.3238(3) 0.2693(7) 0.3227(3) 0.0256(16) Uani 1 1 d . . . . .
H25 H 0.344966 0.323975 0.299322 0.031 Uiso 1 1 calc R U . . .
C26 C 0.2613(3) 0.2542(7) 0.3155(2) 0.0211(15) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N2 2.164(6) . ?
Ag1 N3 2.162(6) 7_566 ?
Ag2 Ag2 3.1061(15) 5_666 ?
Ag2 O1 2.583(7) . ?
Ag2 N1 2.208(6) . ?
Ag2 N4 2.179(6) 4_556 ?
Re1 O1 1.712(7) . ?
Re1 O2 1.719(7) . ?
Re1 O3 1.715(7) . ?
Re1 O4 1.713(6) . ?
Re2 O5 1.716(6) . ?
Re2 O6 1.715(7) . ?
Re2 O7 1.710(6) . ?
Re2 O8 1.704(7) . ?
N1 C1 1.319(10) . ?
N1 C5 1.335(10) . ?
N2 C6 1.333(10) . ?
N2 C10 1.347(9) . ?
N3 C11 1.337(9) . ?
N3 C15 1.342(10) . ?
N4 C16 1.325(10) . ?
N4 C20 1.350(10) . ?
C1 H1 0.9300 . ?
C1 C2 1.393(9) . ?
C2 C3 1.384(10) . ?
C2 C24 1.485(10) . ?
C3 H3 0.9300 . ?
C3 C4 1.383(11) . ?
C4 H4 0.9300 . ?
C4 C5 1.374(12) . ?
C5 H5 0.9300 . ?
C6 H6 0.9300 . ?
C6 C7 1.386(11) . ?
C7 H7 0.9300 . ?
C7 C8 1.354(10) . ?
C8 H8 0.9300 . ?
C8 C9 1.368(10) . ?
C9 C10 1.393(9) . ?
C9 C23 1.492(9) . ?
C10 H10 0.9300 . ?
C11 H11 0.9300 . ?
C11 C12 1.397(9) . ?
C12 C13 1.381(10) . ?
C12 C26 1.491(9) . ?
C13 H13 0.9300 . ?
C13 C14 1.364(10) . ?
C14 H14 0.9300 . ?
C14 C15 1.371(11) . ?
C15 H15 0.9300 . ?
C16 H16 0.9300 . ?
C16 C17 1.397(10) . ?
C17 C18 1.388(10) . ?
C17 C21 1.480(10) . ?
C18 H18 0.9300 . ?
C18 C19 1.380(11) . ?
C19 H19 0.9300 . ?
C19 C20 1.387(12) . ?
C20 H20 0.9300 . ?
C21 C22 1.382(10) . ?
C21 C26 1.417(9) . ?
C22 H22 0.9300 . ?
C22 C23 1.380(10) . ?
C23 C24 1.397(10) . ?
C24 C25 1.403(9) . ?
C25 H25 0.9300 . ?
C25 C26 1.375(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Ag1 N2 177.3(3) 7_566 . ?
O1 Ag2 Ag2 61.66(17) . 5_666 ?
N1 Ag2 Ag2 84.13(17) . 5_666 ?
N1 Ag2 O1 91.0(2) . . ?
N4 Ag2 Ag2 109.13(17) 4_556 5_666 ?
N4 Ag2 O1 98.8(2) 4_556 . ?
N4 Ag2 N1 166.2(2) 4_556 . ?
O1 Re1 O2 108.1(4) . . ?
O1 Re1 O3 110.2(4) . . ?
O1 Re1 O4 109.4(3) . . ?
O3 Re1 O2 110.1(4) . . ?
O4 Re1 O2 109.3(4) . . ?
O4 Re1 O3 109.8(4) . . ?
O6 Re2 O5 109.4(4) . . ?
O7 Re2 O5 109.8(3) . . ?
O7 Re2 O6 109.2(3) . . ?
O8 Re2 O5 110.0(4) . . ?
O8 Re2 O6 109.2(4) . . ?
O8 Re2 O7 109.3(4) . . ?
Re1 O1 Ag2 163.1(4) . . ?
C1 N1 Ag2 118.7(5) . . ?
C1 N1 C5 118.2(7) . . ?
C5 N1 Ag2 123.0(6) . . ?
C6 N2 Ag1 123.7(5) . . ?
C6 N2 C10 117.8(6) . . ?
C10 N2 Ag1 118.4(5) . . ?
C11 N3 Ag1 119.0(5) . 7_565 ?
C11 N3 C15 117.3(6) . . ?
C15 N3 Ag1 123.6(5) . 7_565 ?
C16 N4 Ag2 120.2(5) . 4_456 ?
C16 N4 C20 118.0(7) . . ?
C20 N4 Ag2 121.8(5) . 4_456 ?
N1 C1 H1 117.7 . . ?
N1 C1 C2 124.5(7) . . ?
C2 C1 H1 117.7 . . ?
C1 C2 C24 120.5(6) . . ?
C3 C2 C1 116.6(7) . . ?
C3 C2 C24 122.8(6) . . ?
C2 C3 H3 120.5 . . ?
C4 C3 C2 119.1(7) . . ?
C4 C3 H3 120.5 . . ?
C3 C4 H4 120.1 . . ?
C5 C4 C3 119.9(7) . . ?
C5 C4 H4 120.1 . . ?
N1 C5 C4 121.7(8) . . ?
N1 C5 H5 119.2 . . ?
C4 C5 H5 119.2 . . ?
N2 C6 H6 119.0 . . ?
N2 C6 C7 121.9(7) . . ?
C7 C6 H6 119.0 . . ?
C6 C7 H7 120.0 . . ?
C8 C7 C6 119.9(8) . . ?
C8 C7 H7 120.0 . . ?
C7 C8 H8 120.2 . . ?
C7 C8 C9 119.5(7) . . ?
C9 C8 H8 120.2 . . ?
C8 C9 C10 118.1(6) . . ?
C8 C9 C23 125.7(6) . . ?
C10 C9 C23 116.2(6) . . ?
N2 C10 C9 122.7(7) . . ?
N2 C10 H10 118.6 . . ?
C9 C10 H10 118.6 . . ?
N3 C11 H11 118.1 . . ?
N3 C11 C12 123.8(7) . . ?
C12 C11 H11 118.1 . . ?
C11 C12 C26 118.5(6) . . ?
C13 C12 C11 116.6(6) . . ?
C13 C12 C26 124.8(6) . . ?
C12 C13 H13 119.8 . . ?
C14 C13 C12 120.5(7) . . ?
C14 C13 H13 119.8 . . ?
C13 C14 H14 120.5 . . ?
C13 C14 C15 119.0(8) . . ?
C15 C14 H14 120.5 . . ?
N3 C15 C14 122.9(7) . . ?
N3 C15 H15 118.5 . . ?
C14 C15 H15 118.5 . . ?
N4 C16 H16 117.6 . . ?
N4 C16 C17 124.8(7) . . ?
C17 C16 H16 117.6 . . ?
C16 C17 C21 118.0(6) . . ?
C18 C17 C16 116.6(7) . . ?
C18 C17 C21 125.3(7) . . ?
C17 C18 H18 120.3 . . ?
C19 C18 C17 119.4(7) . . ?
C19 C18 H18 120.3 . . ?
C18 C19 H19 119.9 . . ?
C18 C19 C20 120.1(8) . . ?
C20 C19 H19 119.9 . . ?
N4 C20 C19 121.1(8) . . ?
N4 C20 H20 119.4 . . ?
C19 C20 H20 119.4 . . ?
C22 C21 C17 116.7(6) . . ?
C22 C21 C26 117.6(7) . . ?
C26 C21 C17 125.7(6) . . ?
C21 C22 H22 118.0 . . ?
C23 C22 C21 123.9(6) . . ?
C23 C22 H22 118.0 . . ?
C22 C23 C9 117.6(6) . . ?
C22 C23 C24 118.8(6) . . ?
C24 C23 C9 123.6(7) . . ?
C23 C24 C2 124.3(6) . . ?
C23 C24 C25 117.6(7) . . ?
C25 C24 C2 117.9(6) . . ?
C24 C25 H25 118.2 . . ?
C26 C25 C24 123.6(7) . . ?
C26 C25 H25 118.2 . . ?
C21 C26 C12 123.4(7) . . ?
C25 C26 C12 118.0(6) . . ?
C25 C26 C21 118.4(6) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 N2 C6 C7 -175.9(6) . . . . ?
Ag1 N2 C10 C9 175.8(5) . . . . ?
Ag1 N3 C11 C12 175.6(6) 7_565 . . . ?
Ag1 N3 C15 C14 -176.8(6) 7_565 . . . ?
Ag2 N1 C1 C2 -175.9(5) . . . . ?
Ag2 N1 C5 C4 176.7(6) . . . . ?
Ag2 N4 C16 C17 -179.3(6) 4_456 . . . ?
Ag2 N4 C20 C19 179.9(5) 4_456 . . . ?
O2 Re1 O1 Ag2 -109.5(14) . . . . ?
O3 Re1 O1 Ag2 130.2(14) . . . . ?
O4 Re1 O1 Ag2 9.4(15) . . . . ?
N1 C1 C2 C3 -2.3(11) . . . . ?
N1 C1 C2 C24 -179.1(7) . . . . ?
N2 C6 C7 C8 -0.1(13) . . . . ?
N3 C11 C12 C13 1.0(12) . . . . ?
N3 C11 C12 C26 -175.3(8) . . . . ?
N4 C16 C17 C18 -0.8(11) . . . . ?
N4 C16 C17 C21 -176.6(7) . . . . ?
C1 N1 C5 C4 -1.1(12) . . . . ?
C1 C2 C3 C4 1.8(11) . . . . ?
C1 C2 C24 C23 -49.1(10) . . . . ?
C1 C2 C24 C25 125.1(7) . . . . ?
C2 C3 C4 C5 -1.1(12) . . . . ?
C2 C24 C25 C26 -173.8(6) . . . . ?
C3 C2 C24 C23 134.4(7) . . . . ?
C3 C2 C24 C25 -51.4(10) . . . . ?
C3 C4 C5 N1 0.8(13) . . . . ?
C5 N1 C1 C2 2.0(11) . . . . ?
C6 N2 C10 C9 0.0(11) . . . . ?
C6 C7 C8 C9 0.9(12) . . . . ?
C7 C8 C9 C10 -1.2(11) . . . . ?
C7 C8 C9 C23 179.6(7) . . . . ?
C8 C9 C10 N2 0.7(11) . . . . ?
C8 C9 C23 C22 132.0(8) . . . . ?
C8 C9 C23 C24 -49.6(11) . . . . ?
C9 C23 C24 C2 -2.4(11) . . . . ?
C9 C23 C24 C25 -176.6(6) . . . . ?
C10 N2 C6 C7 -0.3(12) . . . . ?
C10 C9 C23 C22 -47.2(9) . . . . ?
C10 C9 C23 C24 131.2(7) . . . . ?
C11 N3 C15 C14 -1.3(13) . . . . ?
C11 C12 C13 C14 -0.6(11) . . . . ?
C11 C12 C26 C21 -141.9(7) . . . . ?
C11 C12 C26 C25 42.9(9) . . . . ?
C12 C13 C14 C15 -0.6(12) . . . . ?
C13 C12 C26 C21 42.1(10) . . . . ?
C13 C12 C26 C25 -133.1(8) . . . . ?
C13 C14 C15 N3 1.7(13) . . . . ?
C15 N3 C11 C12 0.0(13) . . . . ?
C16 N4 C20 C19 0.8(11) . . . . ?
C16 C17 C18 C19 1.3(11) . . . . ?
C16 C17 C21 C22 44.0(9) . . . . ?
C16 C17 C21 C26 -132.7(7) . . . . ?
C17 C18 C19 C20 -0.8(11) . . . . ?
C17 C21 C22 C23 -173.8(6) . . . . ?
C17 C21 C26 C12 1.0(11) . . . . ?
C17 C21 C26 C25 176.2(7) . . . . ?
C18 C17 C21 C22 -131.4(7) . . . . ?
C18 C17 C21 C26 51.8(11) . . . . ?
C18 C19 C20 N4 -0.3(11) . . . . ?
C20 N4 C16 C17 -0.2(11) . . . . ?
C21 C17 C18 C19 176.7(7) . . . . ?
C21 C22 C23 C9 174.6(6) . . . . ?
C21 C22 C23 C24 -3.8(10) . . . . ?
C22 C21 C26 C12 -175.7(6) . . . . ?
C22 C21 C26 C25 -0.5(10) . . . . ?
C22 C23 C24 C2 175.9(6) . . . . ?
C22 C23 C24 C25 1.7(10) . . . . ?
C23 C9 C10 N2 -180.0(7) . . . . ?
C23 C24 C25 C26 0.8(10) . . . . ?
C24 C2 C3 C4 178.4(7) . . . . ?
C24 C25 C26 C12 174.1(6) . . . . ?
C24 C25 C26 C21 -1.4(11) . . . . ?
C26 C12 C13 C14 175.4(7) . . . . ?
C26 C21 C22 C23 3.1(10) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
