# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_felix193
_database_code_depnum_ccdc_archive 'CCDC 2127859'
loop_
_audit_author_name
_audit_author_address
'Christian Nather'
;University of Kiel
Germany
;
_audit_update_record             
;
2021-12-10 deposited with the CCDC.	2022-03-09 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C39 H53 N2 P5 W'
_chemical_formula_weight         888.53

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   19.2033(8)
_cell_length_b                   9.4433(3)
_cell_length_c                   21.9208(10)
_cell_angle_alpha                90
_cell_angle_beta                 107.168(3)
_cell_angle_gamma                90
_cell_volume                     3798.1(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    200(2)
_cell_measurement_reflns_used    59003
_cell_measurement_theta_min      1.678
_cell_measurement_theta_max      28.003

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.554
_exptl_crystal_F_000             1800
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.07
_exptl_absorpt_coefficient_mu    3.283
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.3161
_exptl_absorpt_correction_T_max  0.6463
_exptl_absorpt_process_details   'X-Red and X-Shape (STOE, 2008)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      200(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'STOE IPDS-2'
_diffrn_measurement_method       'Omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            59003
_diffrn_reflns_av_unetI/netI     0.0235
_diffrn_reflns_av_R_equivalents  0.0542
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_theta_min         1.678
_diffrn_reflns_theta_max         28.003
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             9164
_reflns_number_gt                8455
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'X-AREA (STOE, 2008)'
_computing_cell_refinement       'X-AREA (STOE, 2008)'
_computing_data_reduction        'X-AREA (STOE, 2008)'
_computing_structure_solution    'SHELXT (Sheldrick, 2015)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0521P)²+4.8765P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_extinction_coef       0.00220(19)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         9164
_refine_ls_number_parameters     430
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0402
_refine_ls_R_factor_gt           0.0365
_refine_ls_wR_factor_ref         0.0921
_refine_ls_wR_factor_gt          0.0899
_refine_ls_goodness_of_fit_ref   1.076
_refine_ls_restrained_S_all      1.076
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
W1 W 0.48529(2) 0.39200(2) 0.25224(2) 0.02957(6) Uani 1 1 d . . . . .
N1 N 0.44836(18) 0.1905(3) 0.24101(15) 0.0383(7) Uani 1 1 d . . . . .
N2 N 0.4244(2) 0.0859(4) 0.23181(19) 0.0495(8) Uani 1 1 d . . . . .
C1 C 0.3824(2) 0.6769(5) 0.1421(2) 0.0478(10) Uani 1 1 d . . . . .
C2 C 0.3431(3) 0.7979(6) 0.0988(3) 0.0655(14) Uani 1 1 d . . . . .
H2A H 0.295706 0.764513 0.071777 0.098 Uiso 1 1 calc R U . . .
H2B H 0.372681 0.829453 0.071777 0.098 Uiso 1 1 calc R U . . .
H2C H 0.335815 0.877160 0.125135 0.098 Uiso 1 1 calc R U . . .
C3 C 0.3356(2) 0.6371(5) 0.1862(2) 0.0471(9) Uani 1 1 d . . . . .
H3A H 0.284027 0.631985 0.159789 0.056 Uiso 1 1 calc R U . . .
H3B H 0.339492 0.714681 0.217381 0.056 Uiso 1 1 calc R U . . .
P1 P 0.35906(5) 0.46777(10) 0.23126(5) 0.0366(2) Uani 1 1 d . . . . .
C4 C 0.3083(2) 0.5014(5) 0.2894(2) 0.0493(10) Uani 1 1 d . . . . .
H4A H 0.329666 0.582780 0.316084 0.074 Uiso 1 1 calc R U . . .
H4B H 0.311036 0.417655 0.316415 0.074 Uiso 1 1 calc R U . . .
H4C H 0.257168 0.521514 0.266498 0.074 Uiso 1 1 calc R U . . .
C5 C 0.2904(2) 0.3461(5) 0.1812(2) 0.0480(9) Uani 1 1 d . . . . .
H5A H 0.241545 0.384701 0.175436 0.072 Uiso 1 1 calc R U . . .
H5B H 0.294481 0.253430 0.202110 0.072 Uiso 1 1 calc R U . . .
H5C H 0.298830 0.335440 0.139450 0.072 Uiso 1 1 calc R U . . .
C6 C 0.3870(3) 0.5509(5) 0.09927(19) 0.0494(10) Uani 1 1 d . . . . .
H6A H 0.399060 0.587684 0.061341 0.059 Uiso 1 1 calc R U . . .
H6B H 0.338077 0.506922 0.084038 0.059 Uiso 1 1 calc R U . . .
P2 P 0.45432(6) 0.40949(11) 0.13641(5) 0.0402(2) Uani 1 1 d . . . . .
C7 C 0.5189(3) 0.4480(7) 0.0905(2) 0.0589(12) Uani 1 1 d . . . . .
H7A H 0.493575 0.440882 0.044752 0.088 Uiso 1 1 calc R U . . .
H7B H 0.559051 0.379549 0.102036 0.088 Uiso 1 1 calc R U . . .
H7C H 0.538383 0.543951 0.100518 0.088 Uiso 1 1 calc R U . . .
C8 C 0.4123(3) 0.2525(5) 0.0892(2) 0.0533(11) Uani 1 1 d . . . . .
H8A H 0.381773 0.202918 0.111153 0.080 Uiso 1 1 calc R U . . .
H8B H 0.450682 0.188582 0.084644 0.080 Uiso 1 1 calc R U . . .
H8C H 0.382237 0.282727 0.046872 0.080 Uiso 1 1 calc R U . . .
C9 C 0.4588(2) 0.7347(4) 0.1792(2) 0.0461(9) Uani 1 1 d . . . . .
H9A H 0.452902 0.834387 0.190761 0.055 Uiso 1 1 calc R U . . .
H9B H 0.489075 0.735314 0.149643 0.055 Uiso 1 1 calc R U . . .
P3 P 0.51033(5) 0.63925(10) 0.25317(4) 0.03544(19) Uani 1 1 d . . . . .
C10 C 0.4879(2) 0.7540(4) 0.31340(19) 0.0406(8) Uani 1 1 d . . . . .
H10A H 0.506622 0.850463 0.310014 0.049 Uiso 1 1 calc R U . . .
H10B H 0.434220 0.760598 0.303053 0.049 Uiso 1 1 calc R U . . .
C11 C 0.5185(2) 0.7037(4) 0.38208(19) 0.0406(8) Uani 1 1 d . . . . .
H11A H 0.514509 0.782002 0.410899 0.049 Uiso 1 1 calc R U . . .
H11B H 0.570987 0.682579 0.390296 0.049 Uiso 1 1 calc R U . . .
C12 C 0.4810(2) 0.5723(4) 0.39908(17) 0.0350(7) Uani 1 1 d . . . . .
H12A H 0.427643 0.587385 0.383563 0.042 Uiso 1 1 calc R U . . .
H12B H 0.494710 0.564652 0.446179 0.042 Uiso 1 1 calc R U . . .
P4 P 0.50197(5) 0.40058(9) 0.36674(4) 0.03084(18) Uani 1 1 d . . . . .
C13 C 0.44478(19) 0.2803(4) 0.39857(16) 0.0319(7) Uani 1 1 d . . . . .
C14 C 0.4021(2) 0.3220(4) 0.43700(18) 0.0376(7) Uani 1 1 d . . . . .
H14 H 0.399565 0.419312 0.447118 0.045 Uiso 1 1 calc R U . . .
C15 C 0.3632(2) 0.2232(4) 0.46067(19) 0.0421(8) Uani 1 1 d . . . . .
H15 H 0.334306 0.253565 0.486731 0.051 Uiso 1 1 calc R U . . .
C16 C 0.3660(2) 0.0811(4) 0.4467(2) 0.0446(9) Uani 1 1 d . . . . .
H16 H 0.339798 0.013482 0.463306 0.054 Uiso 1 1 calc R U . . .
C17 C 0.4075(2) 0.0387(4) 0.4081(2) 0.0461(9) Uani 1 1 d . . . . .
H17 H 0.409118 -0.058577 0.397634 0.055 Uiso 1 1 calc R U . . .
C18 C 0.4468(2) 0.1368(4) 0.38452(19) 0.0396(8) Uani 1 1 d . . . . .
H18 H 0.475472 0.105679 0.358435 0.048 Uiso 1 1 calc R U . . .
C19 C 0.5894(2) 0.3751(4) 0.43126(16) 0.0326(7) Uani 1 1 d . . . . .
C20 C 0.6491(2) 0.4594(4) 0.43032(17) 0.0360(7) Uani 1 1 d . . . . .
H20 H 0.646581 0.514386 0.393420 0.043 Uiso 1 1 calc R U . . .
C21 C 0.7117(2) 0.4649(4) 0.48170(19) 0.0412(8) Uani 1 1 d . . . . .
H21 H 0.751017 0.524310 0.480047 0.049 Uiso 1 1 calc R U . . .
C22 C 0.7170(2) 0.3840(4) 0.5353(2) 0.0417(8) Uani 1 1 d . . . . .
H22 H 0.759310 0.389394 0.571133 0.050 Uiso 1 1 calc R U . . .
C23 C 0.6604(2) 0.2956(4) 0.53636(18) 0.0412(8) Uani 1 1 d . . . . .
H23 H 0.664803 0.236622 0.572409 0.049 Uiso 1 1 calc R U . . .
C24 C 0.5968(2) 0.2914(4) 0.48519(17) 0.0364(7) Uani 1 1 d . . . . .
H24 H 0.558014 0.230875 0.487107 0.044 Uiso 1 1 calc R U . . .
C25 C 0.6038(2) 0.7053(4) 0.2623(2) 0.0430(9) Uani 1 1 d . . . . .
H25A H 0.600231 0.799784 0.242069 0.052 Uiso 1 1 calc R U . . .
H25B H 0.629162 0.717359 0.308375 0.052 Uiso 1 1 calc R U . . .
C26 C 0.6502(2) 0.6102(4) 0.2336(2) 0.0452(9) Uani 1 1 d . . . . .
H26A H 0.692556 0.665540 0.229842 0.054 Uiso 1 1 calc R U . . .
H26B H 0.620996 0.583194 0.189879 0.054 Uiso 1 1 calc R U . . .
C27 C 0.6785(2) 0.4744(4) 0.27144(19) 0.0405(8) Uani 1 1 d . . . . .
H27A H 0.696786 0.499077 0.317307 0.049 Uiso 1 1 calc R U . . .
H27B H 0.720474 0.438830 0.258355 0.049 Uiso 1 1 calc R U . . .
P5 P 0.61134(5) 0.32922(10) 0.26187(4) 0.03376(18) Uani 1 1 d . . . . .
C28 C 0.6282(2) 0.2237(4) 0.19583(18) 0.0384(8) Uani 1 1 d . . . . .
C29 C 0.6774(2) 0.2591(5) 0.1624(2) 0.0455(9) Uani 1 1 d . . . . .
H29 H 0.707772 0.339828 0.174929 0.055 Uiso 1 1 calc R U . . .
C30 C 0.6824(3) 0.1779(5) 0.1110(2) 0.0516(10) Uani 1 1 d . . . . .
H30 H 0.715233 0.204870 0.088107 0.062 Uiso 1 1 calc R U . . .
C31 C 0.6402(3) 0.0589(5) 0.0930(2) 0.0544(11) Uani 1 1 d . . . . .
H31 H 0.643942 0.003426 0.057964 0.065 Uiso 1 1 calc R U . . .
C32 C 0.5923(3) 0.0207(5) 0.1265(2) 0.0547(11) Uani 1 1 d . . . . .
H32 H 0.563457 -0.062319 0.114808 0.066 Uiso 1 1 calc R U . . .
C33 C 0.5861(3) 0.1024(4) 0.1767(2) 0.0465(9) Uani 1 1 d . . . . .
H33 H 0.552387 0.075458 0.198817 0.056 Uiso 1 1 calc R U . . .
C34 C 0.6627(2) 0.2085(4) 0.32673(17) 0.0350(7) Uani 1 1 d . . . . .
C35 C 0.7358(2) 0.2246(5) 0.36048(19) 0.0436(8) Uani 1 1 d . . . . .
H35 H 0.762955 0.300925 0.350723 0.052 Uiso 1 1 calc R U . . .
C36 C 0.7695(3) 0.1292(5) 0.4085(2) 0.0525(11) Uani 1 1 d . . . . .
H36 H 0.819612 0.140955 0.431283 0.063 Uiso 1 1 calc R U . . .
C37 C 0.7314(3) 0.0189(5) 0.4234(2) 0.0523(11) Uani 1 1 d . . . . .
H37 H 0.754820 -0.044958 0.456548 0.063 Uiso 1 1 calc R U . . .
C38 C 0.6589(3) 0.0005(5) 0.3901(2) 0.0501(10) Uani 1 1 d . . . . .
H38 H 0.632253 -0.076678 0.399805 0.060 Uiso 1 1 calc R U . . .
C39 C 0.6253(2) 0.0953(4) 0.3424(2) 0.0424(8) Uani 1 1 d . . . . .
H39 H 0.575225 0.082581 0.319829 0.051 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
W1 N1 2.020(3) . ?
W1 P3 2.3827(10) . ?
W1 P4 2.4361(9) . ?
W1 P2 2.4365(10) . ?
W1 P1 2.4374(10) . ?
W1 P5 2.4399(10) . ?
N1 N2 1.084(5) . ?
C1 C2 1.534(6) . ?
C1 C6 1.534(7) . ?
C1 C3 1.547(7) . ?
C1 C9 1.551(6) . ?
C3 P1 1.863(4) . ?
P1 C4 1.846(4) . ?
P1 C5 1.846(4) . ?
C6 P2 1.870(4) . ?
P2 C7 1.849(5) . ?
P2 C8 1.851(5) . ?
C9 P3 1.865(4) . ?
P3 C10 1.854(4) . ?
P3 C25 1.855(4) . ?
C10 C11 1.522(5) . ?
C11 C12 1.535(5) . ?
C12 P4 1.861(4) . ?
P4 C13 1.853(4) . ?
P4 C19 1.865(4) . ?
C13 C18 1.393(5) . ?
C13 C14 1.395(5) . ?
C14 C15 1.388(5) . ?
C15 C16 1.381(6) . ?
C16 C17 1.380(6) . ?
C17 C18 1.388(6) . ?
C19 C24 1.394(5) . ?
C19 C20 1.401(5) . ?
C20 C21 1.384(5) . ?
C21 C22 1.379(6) . ?
C22 C23 1.376(6) . ?
C23 C24 1.394(5) . ?
C25 C26 1.526(6) . ?
C26 C27 1.537(6) . ?
C27 P5 1.852(4) . ?
P5 C34 1.862(4) . ?
P5 C28 1.863(4) . ?
C28 C33 1.393(6) . ?
C28 C29 1.397(6) . ?
C29 C30 1.390(6) . ?
C30 C31 1.372(7) . ?
C31 C32 1.385(7) . ?
C32 C33 1.378(6) . ?
C34 C39 1.387(5) . ?
C34 C35 1.388(5) . ?
C35 C36 1.392(6) . ?
C36 C37 1.366(7) . ?
C37 C38 1.379(7) . ?
C38 C39 1.382(6) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 W1 P3 170.65(9) . . ?
N1 W1 P4 95.25(9) . . ?
P3 W1 P4 89.64(3) . . ?
N1 W1 P2 88.16(9) . . ?
P3 W1 P2 85.93(3) . . ?
P4 W1 P2 171.45(3) . . ?
N1 W1 P1 87.69(10) . . ?
P3 W1 P1 84.31(3) . . ?
P4 W1 P1 90.32(3) . . ?
P2 W1 P1 81.97(4) . . ?
N1 W1 P5 94.90(10) . . ?
P3 W1 P5 92.57(3) . . ?
P4 W1 P5 95.37(3) . . ?
P2 W1 P5 92.14(3) . . ?
P1 W1 P5 173.50(3) . . ?
N2 N1 W1 175.0(3) . . ?
C2 C1 C6 107.8(4) . . ?
C2 C1 C3 107.3(4) . . ?
C6 C1 C3 110.0(4) . . ?
C2 C1 C9 106.2(4) . . ?
C6 C1 C9 112.2(4) . . ?
C3 C1 C9 113.1(4) . . ?
C1 C3 P1 116.5(3) . . ?
C4 P1 C5 95.0(2) . . ?
C4 P1 C3 97.1(2) . . ?
C5 P1 C3 101.6(2) . . ?
C4 P1 W1 128.22(14) . . ?
C5 P1 W1 115.16(15) . . ?
C3 P1 W1 115.03(15) . . ?
C1 C6 P2 116.4(3) . . ?
C7 P2 C8 96.0(3) . . ?
C7 P2 C6 96.4(2) . . ?
C8 P2 C6 101.4(2) . . ?
C7 P2 W1 125.70(16) . . ?
C8 P2 W1 117.39(16) . . ?
C6 P2 W1 115.25(15) . . ?
C1 C9 P3 117.6(3) . . ?
C10 P3 C25 98.49(19) . . ?
C10 P3 C9 99.3(2) . . ?
C25 P3 C9 100.37(19) . . ?
C10 P3 W1 119.34(13) . . ?
C25 P3 W1 121.11(13) . . ?
C9 P3 W1 114.35(14) . . ?
C11 C10 P3 114.8(3) . . ?
C10 C11 C12 114.9(3) . . ?
C11 C12 P4 116.2(3) . . ?
C13 P4 C12 99.88(16) . . ?
C13 P4 C19 97.85(16) . . ?
C12 P4 C19 94.09(16) . . ?
C13 P4 W1 117.09(11) . . ?
C12 P4 W1 116.36(12) . . ?
C19 P4 W1 126.31(12) . . ?
C18 C13 C14 117.9(3) . . ?
C18 C13 P4 117.0(3) . . ?
C14 C13 P4 125.0(3) . . ?
C15 C14 C13 120.9(4) . . ?
C16 C15 C14 120.6(4) . . ?
C17 C16 C15 119.0(4) . . ?
C16 C17 C18 120.7(4) . . ?
C17 C18 C13 120.9(4) . . ?
C24 C19 C20 117.1(3) . . ?
C24 C19 P4 124.0(3) . . ?
C20 C19 P4 118.2(3) . . ?
C21 C20 C19 121.8(3) . . ?
C22 C21 C20 120.0(4) . . ?
C23 C22 C21 119.3(4) . . ?
C22 C23 C24 120.8(4) . . ?
C19 C24 C23 120.8(4) . . ?
C26 C25 P3 115.0(3) . . ?
C25 C26 C27 115.1(3) . . ?
C26 C27 P5 115.7(3) . . ?
C27 P5 C34 99.92(18) . . ?
C27 P5 C28 102.08(18) . . ?
C34 P5 C28 95.23(16) . . ?
C27 P5 W1 118.05(14) . . ?
C34 P5 W1 120.24(12) . . ?
C28 P5 W1 117.26(13) . . ?
C33 C28 C29 117.5(4) . . ?
C33 C28 P5 117.1(3) . . ?
C29 C28 P5 125.4(3) . . ?
C30 C29 C28 120.8(4) . . ?
C31 C30 C29 120.6(4) . . ?
C30 C31 C32 119.3(4) . . ?
C33 C32 C31 120.4(4) . . ?
C32 C33 C28 121.4(4) . . ?
C39 C34 C35 118.0(4) . . ?
C39 C34 P5 117.7(3) . . ?
C35 C34 P5 124.4(3) . . ?
C34 C35 C36 120.2(4) . . ?
C37 C36 C35 120.7(4) . . ?
C36 C37 C38 119.9(4) . . ?
C37 C38 C39 119.4(4) . . ?
C38 C39 C34 121.7(4) . . ?

_refine_diff_density_max         1.096
_refine_diff_density_min         -1.154
_refine_diff_density_rms         0.110



