# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_mo_ZhuAgPt_0m
_audit_block_doi                 10.5517/ccdc.csd.cc25twgc
_database_code_depnum_ccdc_archive 'CCDC 2020873'
loop_
_audit_author_name
_audit_author_address
'Yan Zhu'
;Nanjing University
China
;
_audit_update_record             
;
2020-08-03 deposited with the CCDC.	2021-09-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C160 H176 Ag8 O12 Pt4 S16'
_chemical_formula_weight         4447.28

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 2/c'
_space_group_name_Hall           '-C 2yc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   12.125(3)
_cell_length_b                   26.995(5)
_cell_length_c                   21.902(5)
_cell_angle_alpha                90
_cell_angle_beta                 90.493(12)
_cell_angle_gamma                90
_cell_volume                     7168(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.060
_exptl_crystal_F_000             4352
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_absorpt_coefficient_mu    5.249
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            50749
_diffrn_reflns_av_unetI/netI     0.0381
_diffrn_reflns_av_R_equivalents  0.0696
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -33
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_theta_min         2.395
_diffrn_reflns_theta_max         26.480
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             7379
_reflns_number_gt                5691
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0180P)²+48.4583P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         7379
_refine_ls_number_parameters     387
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0517
_refine_ls_R_factor_gt           0.0293
_refine_ls_wR_factor_ref         0.0590
_refine_ls_wR_factor_gt          0.0520
_refine_ls_goodness_of_fit_ref   0.977
_refine_ls_restrained_S_all      0.977
_refine_ls_shift/su_max          0.178
_refine_ls_shift/su_mean         0.005

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 1.0000 0.07054(2) 0.7500 0.01422(6) Uani 1 2 d S T P . .
Pt2 Pt 1.0000 0.24836(2) 0.7500 0.01467(6) Uani 1 2 d S T P . .
Ag1 Ag 1.09490(3) 0.15809(2) 0.66347(2) 0.02500(9) Uani 1 1 d . . . . .
Ag2 Ag 0.84642(3) 0.15942(2) 0.69828(2) 0.02515(9) Uani 1 1 d . . . . .
S1 S 1.09763(10) 0.24635(4) 0.65876(5) 0.0208(3) Uani 1 1 d . . . . .
S2 S 0.83359(10) 0.24761(4) 0.69486(5) 0.0203(3) Uani 1 1 d . . . . .
S3 S 0.82514(10) 0.07144(4) 0.70296(5) 0.0187(2) Uani 1 1 d . . . . .
S4 S 1.08467(10) 0.06985(4) 0.65389(5) 0.0188(2) Uani 1 1 d . . . . .
C3 C 0.8573(4) 0.26736(17) 0.6184(2) 0.0186(10) Uani 1 1 d . . . . .
C4 C 0.8670(4) 0.23389(18) 0.5705(2) 0.0260(11) Uani 1 1 d . . . . .
H9 H 0.8617 0.2001 0.5782 0.031 Uiso 1 1 calc R U . . .
C5 C 0.8842(5) 0.2501(2) 0.5116(2) 0.0358(14) Uani 1 1 d . . . . .
H8 H 0.8920 0.2271 0.4804 0.043 Uiso 1 1 calc R U . . .
C6 C 0.8900(5) 0.2998(2) 0.4982(2) 0.0350(13) Uani 1 1 d . . . . .
C7 C 0.8808(4) 0.33271(19) 0.5464(2) 0.0280(12) Uani 1 1 d . . . . .
H1 H 0.8861 0.3664 0.5381 0.034 Uiso 1 1 calc R U . . .
C8 C 0.8641(4) 0.31813(17) 0.6065(2) 0.0201(10) Uani 1 1 d . . . . .
C9 C 0.8562(5) 0.35610(18) 0.6562(2) 0.0310(12) Uani 1 1 d . . . . .
H3 H 0.9184 0.3529 0.6834 0.046 Uiso 1 1 calc R U . . .
H2 H 0.7894 0.3511 0.6786 0.046 Uiso 1 1 calc R U . . .
H4 H 0.8559 0.3887 0.6386 0.046 Uiso 1 1 calc R U . . .
C10 C 0.9067(6) 0.3179(3) 0.4338(3) 0.0576(19) Uani 1 1 d . . . . .
H7 H 0.9840 0.3231 0.4269 0.086 Uiso 1 1 calc R U . . .
H5 H 0.8677 0.3485 0.4279 0.086 Uiso 1 1 calc R U . . .
H6 H 0.8792 0.2936 0.4056 0.086 Uiso 1 1 calc R U . . .
C15 C 0.7178(4) 0.06024(17) 0.7571(2) 0.0186(10) Uani 1 1 d . . . . .
C16 C 0.6548(4) 0.09929(18) 0.7798(2) 0.0246(11) Uani 1 1 d . . . . .
H18 H 0.6698 0.1316 0.7679 0.029 Uiso 1 1 calc R U . . .
C17 C 0.5694(4) 0.0899(2) 0.8203(2) 0.0310(12) Uani 1 1 d . . . . .
H17 H 0.5287 0.1162 0.8358 0.037 Uiso 1 1 calc R U . . .
C18 C 0.5445(4) 0.0424(2) 0.8375(2) 0.0337(13) Uani 1 1 d . . . . .
C19 C 0.6059(4) 0.00448(19) 0.8132(2) 0.0296(12) Uani 1 1 d . . . . .
H10 H 0.5879 -0.0279 0.8237 0.036 Uiso 1 1 calc R U . . .
C20 C 0.6938(4) 0.01193(17) 0.7735(2) 0.0215(10) Uani 1 1 d . . . . .
C21 C 0.7586(5) -0.03107(19) 0.7493(3) 0.0384(14) Uani 1 1 d . . . . .
H13 H 0.8332 -0.0292 0.7642 0.058 Uiso 1 1 calc R U . . .
H11 H 0.7583 -0.0301 0.7055 0.058 Uiso 1 1 calc R U . . .
H12 H 0.7257 -0.0615 0.7628 0.058 Uiso 1 1 calc R U . . .
C22 C 0.4510(5) 0.0323(3) 0.8817(3) 0.0505(17) Uani 1 1 d . . . . .
H15 H 0.3854 0.0488 0.8677 0.076 Uiso 1 1 calc R U . . .
H16 H 0.4710 0.0445 0.9215 0.076 Uiso 1 1 calc R U . . .
H14 H 0.4378 -0.0027 0.8838 0.076 Uiso 1 1 calc R U . . .
C23 C 0.9842(4) 0.05699(16) 0.5961(2) 0.0187(10) Uani 1 1 d . . . . .
C24 C 0.9439(4) 0.09398(18) 0.5580(2) 0.0252(11) Uani 1 1 d . . . . .
H19 H 0.9697 0.1262 0.5625 0.030 Uiso 1 1 calc R U . . .
C25 C 0.8654(4) 0.0834(2) 0.5133(2) 0.0319(13) Uani 1 1 d . . . . .
H27 H 0.8388 0.1086 0.4883 0.038 Uiso 1 1 calc R U . . .
C26 C 0.8265(4) 0.0355(2) 0.5056(2) 0.0321(13) Uani 1 1 d . . . . .
C27 C 0.7385(5) 0.0237(3) 0.4585(3) 0.0519(17) Uani 1 1 d . . . . .
H20 H 0.6682 0.0213 0.4781 0.078 Uiso 1 1 calc R U . . .
H22 H 0.7554 -0.0073 0.4392 0.078 Uiso 1 1 calc R U . . .
H21 H 0.7361 0.0495 0.4284 0.078 Uiso 1 1 calc R U . . .
C28 C 0.8704(4) -0.00062(19) 0.5426(2) 0.0304(12) Uani 1 1 d . . . . .
H23 H 0.8459 -0.0330 0.5372 0.036 Uiso 1 1 calc R U . . .
C29 C 0.9484(4) 0.00808(17) 0.5874(2) 0.0203(10) Uani 1 1 d . . . . .
C30 C 0.9918(5) -0.03381(18) 0.6261(2) 0.0335(13) Uani 1 1 d . . . . .
H26 H 0.9678 -0.0648 0.6091 0.050 Uiso 1 1 calc R U . . .
H25 H 0.9644 -0.0306 0.6669 0.050 Uiso 1 1 calc R U . . .
H24 H 1.0710 -0.0328 0.6269 0.050 Uiso 1 1 calc R U . . .
C31 C 1.2351(4) 0.26860(17) 0.66767(19) 0.0185(10) Uani 1 1 d . . . . .
C32 C 1.2526(4) 0.31989(17) 0.6639(2) 0.0213(10) Uani 1 1 d . . . . .
C33 C 1.3606(4) 0.33660(19) 0.6654(2) 0.0282(11) Uani 1 1 d . . . . .
H33 H 1.3729 0.3705 0.6627 0.034 Uiso 1 1 calc R U . . .
C34 C 1.4507(4) 0.3058(2) 0.6706(2) 0.0307(12) Uani 1 1 d . . . . .
C35 C 1.5671(5) 0.3261(2) 0.6700(3) 0.0454(16) Uani 1 1 d . . . . .
H30 H 1.5696 0.3568 0.6921 0.068 Uiso 1 1 calc R U . . .
H28 H 1.5892 0.3317 0.6286 0.068 Uiso 1 1 calc R U . . .
H29 H 1.6163 0.3027 0.6889 0.068 Uiso 1 1 calc R U . . .
C36 C 1.4313(4) 0.2554(2) 0.6756(2) 0.0294(12) Uani 1 1 d . . . . .
H32 H 1.4904 0.2337 0.6800 0.035 Uiso 1 1 calc R U . . .
C37 C 1.3245(4) 0.23693(18) 0.6739(2) 0.0235(11) Uani 1 1 d . . . . .
H31 H 1.3128 0.2030 0.6770 0.028 Uiso 1 1 calc R U . . .
C38 C 1.1586(4) 0.35591(18) 0.6575(3) 0.0321(13) Uani 1 1 d . . . . .
H38A H 1.0900 0.3381 0.6573 0.048 Uiso 1 1 calc R U . . .
H38B H 1.1600 0.3786 0.6912 0.048 Uiso 1 1 calc R U . . .
H38C H 1.1658 0.3739 0.6200 0.048 Uiso 1 1 calc R U . . .
C39 C 0.2239(7) 0.2751(3) 0.4944(3) 0.070(3) Uani 1 1 d . . . . .
H39A H 0.1840 0.2732 0.4559 0.084 Uiso 1 1 calc R U . . .
H39B H 0.1695 0.2802 0.5260 0.084 Uiso 1 1 calc R U . . .
C40 C 0.2912(8) 0.3187(3) 0.4925(3) 0.082(3) Uani 1 1 d . . . . .
H40A H 0.3466 0.3141 0.4613 0.098 Uiso 1 1 calc R U . . .
H40B H 0.3295 0.3218 0.5313 0.098 Uiso 1 1 calc R U . . .
C41 C 0.2303(8) 0.3670(3) 0.4795(4) 0.082(3) Uani 1 1 d . . . . .
H41A H 0.2822 0.3939 0.4792 0.122 Uiso 1 1 calc R U . . .
H41B H 0.1938 0.3649 0.4406 0.122 Uiso 1 1 calc R U . . .
H41C H 0.1767 0.3727 0.5108 0.122 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 S3 2.3494(13) . ?
Pt1 S3 2.3494(13) 2_756 ?
Pt1 S4 2.3500(12) . ?
Pt1 S4 2.3501(12) 2_756 ?
Pt1 Ag2 3.2359(6) . ?
Pt1 Ag2 3.2360(6) 2_756 ?
Pt1 Ag1 3.2465(6) 2_756 ?
Pt1 Ag1 3.2465(6) . ?
Pt2 S1 2.3319(12) 2_756 ?
Pt2 S1 2.3319(12) . ?
Pt2 S2 2.3426(13) . ?
Pt2 S2 2.3427(13) 2_756 ?
Pt2 Ag2 3.2370(6) 2_756 ?
Pt2 Ag2 3.2371(6) . ?
Pt2 Ag1 3.3001(6) . ?
Pt2 Ag1 3.3002(6) 2_756 ?
Ag1 S1 2.3851(13) . ?
Ag1 S4 2.3943(13) . ?
Ag1 Ag2 3.1046(8) 2_756 ?
Ag1 Ag2 3.1142(8) . ?
Ag2 S2 2.3870(13) . ?
Ag2 S3 2.3912(13) . ?
Ag2 Ag1 3.1045(8) 2_756 ?
S1 C31 1.781(5) . ?
S2 C3 1.783(5) . ?
S3 C15 1.794(5) . ?
S4 C23 1.784(5) . ?
C3 C4 1.391(6) . ?
C3 C8 1.398(6) . ?
C4 C5 1.380(7) . ?
C4 H9 0.9300 . ?
C5 C6 1.375(8) . ?
C5 H8 0.9300 . ?
C6 C7 1.383(7) . ?
C6 C10 1.507(7) . ?
C7 C8 1.390(7) . ?
C7 H1 0.9300 . ?
C8 C9 1.500(7) . ?
C9 H3 0.9600 . ?
C9 H2 0.9600 . ?
C9 H4 0.9600 . ?
C10 H7 0.9600 . ?
C10 H5 0.9600 . ?
C10 H6 0.9600 . ?
C15 C20 1.384(6) . ?
C15 C16 1.396(6) . ?
C16 C17 1.391(7) . ?
C16 H18 0.9300 . ?
C17 C18 1.369(8) . ?
C17 H17 0.9300 . ?
C18 C19 1.377(8) . ?
C18 C22 1.522(7) . ?
C19 C20 1.395(7) . ?
C19 H10 0.9300 . ?
C20 C21 1.500(7) . ?
C21 H13 0.9600 . ?
C21 H11 0.9600 . ?
C21 H12 0.9600 . ?
C22 H15 0.9600 . ?
C22 H16 0.9600 . ?
C22 H14 0.9600 . ?
C23 C24 1.386(6) . ?
C23 C29 1.402(6) . ?
C24 C25 1.390(7) . ?
C24 H19 0.9300 . ?
C25 C26 1.387(7) . ?
C25 H27 0.9300 . ?
C26 C28 1.373(7) . ?
C26 C27 1.511(7) . ?
C27 H20 0.9600 . ?
C27 H22 0.9600 . ?
C27 H21 0.9600 . ?
C28 C29 1.377(7) . ?
C28 H23 0.9300 . ?
C29 C30 1.505(7) . ?
C30 H26 0.9600 . ?
C30 H25 0.9600 . ?
C30 H24 0.9600 . ?
C31 C37 1.386(7) . ?
C31 C32 1.403(6) . ?
C32 C33 1.385(7) . ?
C32 C38 1.503(7) . ?
C33 C34 1.377(7) . ?
C33 H33 0.9300 . ?
C34 C36 1.387(7) . ?
C34 C35 1.514(7) . ?
C35 H30 0.9600 . ?
C35 H28 0.9600 . ?
C35 H29 0.9600 . ?
C36 C37 1.387(7) . ?
C36 H32 0.9300 . ?
C37 H31 0.9300 . ?
C38 H38A 0.9600 . ?
C38 H38B 0.9600 . ?
C38 H38C 0.9600 . ?
C39 C40 1.432(10) . ?
C39 C39 1.514(15) 7_556 ?
C39 H39A 0.9700 . ?
C39 H39B 0.9700 . ?
C40 C41 1.525(11) . ?
C40 H40A 0.9700 . ?
C40 H40B 0.9700 . ?
C41 H41A 0.9600 . ?
C41 H41B 0.9600 . ?
C41 H41C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S3 Pt1 S3 178.81(6) . 2_756 ?
S3 Pt1 S4 90.39(4) . . ?
S3 Pt1 S4 89.62(4) 2_756 . ?
S3 Pt1 S4 89.62(4) . 2_756 ?
S3 Pt1 S4 90.39(4) 2_756 2_756 ?
S4 Pt1 S4 179.11(6) . 2_756 ?
S3 Pt1 Ag2 47.50(3) . . ?
S3 Pt1 Ag2 131.32(3) 2_756 . ?
S4 Pt1 Ag2 86.95(3) . . ?
S4 Pt1 Ag2 93.72(3) 2_756 . ?
S3 Pt1 Ag2 131.31(3) . 2_756 ?
S3 Pt1 Ag2 47.50(3) 2_756 2_756 ?
S4 Pt1 Ag2 93.72(3) . 2_756 ?
S4 Pt1 Ag2 86.95(3) 2_756 2_756 ?
Ag2 Pt1 Ag2 84.28(2) . 2_756 ?
S3 Pt1 Ag1 85.72(3) . 2_756 ?
S3 Pt1 Ag1 93.41(3) 2_756 2_756 ?
S4 Pt1 Ag1 133.50(3) . 2_756 ?
S4 Pt1 Ag1 47.39(3) 2_756 2_756 ?
Ag2 Pt1 Ag1 57.229(16) . 2_756 ?
Ag2 Pt1 Ag1 57.424(16) 2_756 2_756 ?
S3 Pt1 Ag1 93.41(3) . . ?
S3 Pt1 Ag1 85.72(3) 2_756 . ?
S4 Pt1 Ag1 47.39(3) . . ?
S4 Pt1 Ag1 133.50(3) 2_756 . ?
Ag2 Pt1 Ag1 57.425(16) . . ?
Ag2 Pt1 Ag1 57.229(15) 2_756 . ?
Ag1 Pt1 Ag1 86.55(2) 2_756 . ?
S1 Pt2 S1 177.34(6) 2_756 . ?
S1 Pt2 S2 90.02(5) 2_756 . ?
S1 Pt2 S2 89.96(5) . . ?
S1 Pt2 S2 89.96(5) 2_756 2_756 ?
S1 Pt2 S2 90.02(5) . 2_756 ?
S2 Pt2 S2 179.02(6) . 2_756 ?
S1 Pt2 Ag2 88.72(3) 2_756 2_756 ?
S1 Pt2 Ag2 89.31(3) . 2_756 ?
S2 Pt2 Ag2 131.63(3) . 2_756 ?
S2 Pt2 Ag2 47.39(3) 2_756 2_756 ?
S1 Pt2 Ag2 89.31(3) 2_756 . ?
S1 Pt2 Ag2 88.72(3) . . ?
S2 Pt2 Ag2 47.39(3) . . ?
S2 Pt2 Ag2 131.63(3) 2_756 . ?
Ag2 Pt2 Ag2 84.25(2) 2_756 . ?
S1 Pt2 Ag1 131.07(3) 2_756 . ?
S1 Pt2 Ag1 46.27(3) . . ?
S2 Pt2 Ag1 90.03(3) . . ?
S2 Pt2 Ag1 89.24(3) 2_756 . ?
Ag2 Pt2 Ag1 56.697(16) 2_756 . ?
Ag2 Pt2 Ag1 56.889(16) . . ?
S1 Pt2 Ag1 46.27(3) 2_756 2_756 ?
S1 Pt2 Ag1 131.07(3) . 2_756 ?
S2 Pt2 Ag1 89.24(3) . 2_756 ?
S2 Pt2 Ag1 90.04(3) 2_756 2_756 ?
Ag2 Pt2 Ag1 56.890(16) 2_756 2_756 ?
Ag2 Pt2 Ag1 56.695(15) . 2_756 ?
Ag1 Pt2 Ag1 84.81(2) . 2_756 ?
S1 Ag1 S4 172.20(4) . . ?
S1 Ag1 Ag2 91.57(3) . 2_756 ?
S4 Ag1 Ag2 96.21(3) . 2_756 ?
S1 Ag1 Ag2 90.74(3) . . ?
S4 Ag1 Ag2 89.05(3) . . ?
Ag2 Ag1 Ag2 88.575(19) 2_756 . ?
S1 Ag1 Pt1 139.26(3) . . ?
S4 Ag1 Pt1 46.25(3) . . ?
Ag2 Ag1 Pt1 61.216(13) 2_756 . ?
Ag2 Ag1 Pt1 61.117(12) . . ?
S1 Ag1 Pt2 44.95(3) . . ?
S4 Ag1 Pt2 140.07(3) . . ?
Ag2 Ag1 Pt2 60.626(13) 2_756 . ?
Ag2 Ag1 Pt2 60.535(12) . . ?
Pt1 Ag1 Pt2 94.318(19) . . ?
S2 Ag2 S3 170.04(4) . . ?
S2 Ag2 Ag1 93.24(3) . 2_756 ?
S3 Ag2 Ag1 88.32(3) . 2_756 ?
S2 Ag2 Ag1 93.82(3) . . ?
S3 Ag2 Ag1 95.97(3) . . ?
Ag1 Ag2 Ag1 91.410(19) 2_756 . ?
S2 Ag2 Pt1 141.97(3) . . ?
S3 Ag2 Pt1 46.41(3) . . ?
Ag1 Ag2 Pt1 61.557(12) 2_756 . ?
Ag1 Ag2 Pt1 61.458(14) . . ?
S2 Ag2 Pt2 46.24(3) . . ?
S3 Ag2 Pt2 141.60(3) . . ?
Ag1 Ag2 Pt2 62.677(13) 2_756 . ?
Ag1 Ag2 Pt2 62.575(13) . . ?
Pt1 Ag2 Pt2 95.736(19) . . ?
C31 S1 Pt2 112.32(15) . . ?
C31 S1 Ag1 110.21(16) . . ?
Pt2 S1 Ag1 88.79(4) . . ?
C3 S2 Pt2 109.65(16) . . ?
C3 S2 Ag2 108.46(16) . . ?
Pt2 S2 Ag2 86.37(4) . . ?
C15 S3 Pt1 111.44(16) . . ?
C15 S3 Ag2 105.96(15) . . ?
Pt1 S3 Ag2 86.09(4) . . ?
C23 S4 Pt1 109.67(16) . . ?
C23 S4 Ag1 106.88(15) . . ?
Pt1 S4 Ag1 86.35(4) . . ?
C4 C3 C8 119.3(4) . . ?
C4 C3 S2 122.0(4) . . ?
C8 C3 S2 118.6(4) . . ?
C5 C4 C3 120.9(5) . . ?
C5 C4 H9 119.6 . . ?
C3 C4 H9 119.6 . . ?
C6 C5 C4 121.2(5) . . ?
C6 C5 H8 119.4 . . ?
C4 C5 H8 119.4 . . ?
C5 C6 C7 117.3(5) . . ?
C5 C6 C10 121.5(5) . . ?
C7 C6 C10 121.2(5) . . ?
C6 C7 C8 123.6(5) . . ?
C6 C7 H1 118.2 . . ?
C8 C7 H1 118.2 . . ?
C7 C8 C3 117.7(4) . . ?
C7 C8 C9 120.4(4) . . ?
C3 C8 C9 122.0(4) . . ?
C8 C9 H3 109.5 . . ?
C8 C9 H2 109.5 . . ?
H3 C9 H2 109.5 . . ?
C8 C9 H4 109.5 . . ?
H3 C9 H4 109.5 . . ?
H2 C9 H4 109.5 . . ?
C6 C10 H7 109.5 . . ?
C6 C10 H5 109.5 . . ?
H7 C10 H5 109.5 . . ?
C6 C10 H6 109.5 . . ?
H7 C10 H6 109.5 . . ?
H5 C10 H6 109.5 . . ?
C20 C15 C16 120.1(4) . . ?
C20 C15 S3 119.0(3) . . ?
C16 C15 S3 120.7(4) . . ?
C17 C16 C15 120.1(5) . . ?
C17 C16 H18 119.9 . . ?
C15 C16 H18 119.9 . . ?
C18 C17 C16 120.9(5) . . ?
C18 C17 H17 119.6 . . ?
C16 C17 H17 119.6 . . ?
C17 C18 C19 117.9(5) . . ?
C17 C18 C22 120.7(5) . . ?
C19 C18 C22 121.4(5) . . ?
C18 C19 C20 123.5(5) . . ?
C18 C19 H10 118.2 . . ?
C20 C19 H10 118.2 . . ?
C15 C20 C19 117.4(4) . . ?
C15 C20 C21 121.7(4) . . ?
C19 C20 C21 120.9(5) . . ?
C20 C21 H13 109.5 . . ?
C20 C21 H11 109.5 . . ?
H13 C21 H11 109.5 . . ?
C20 C21 H12 109.5 . . ?
H13 C21 H12 109.5 . . ?
H11 C21 H12 109.5 . . ?
C18 C22 H15 109.5 . . ?
C18 C22 H16 109.5 . . ?
H15 C22 H16 109.5 . . ?
C18 C22 H14 109.5 . . ?
H15 C22 H14 109.5 . . ?
H16 C22 H14 109.5 . . ?
C24 C23 C29 119.3(4) . . ?
C24 C23 S4 121.4(4) . . ?
C29 C23 S4 119.2(3) . . ?
C23 C24 C25 120.7(5) . . ?
C23 C24 H19 119.6 . . ?
C25 C24 H19 119.6 . . ?
C26 C25 C24 120.5(5) . . ?
C26 C25 H27 119.7 . . ?
C24 C25 H27 119.7 . . ?
C28 C26 C25 117.4(5) . . ?
C28 C26 C27 121.5(5) . . ?
C25 C26 C27 121.1(5) . . ?
C26 C27 H20 109.5 . . ?
C26 C27 H22 109.5 . . ?
H20 C27 H22 109.5 . . ?
C26 C27 H21 109.5 . . ?
H20 C27 H21 109.5 . . ?
H22 C27 H21 109.5 . . ?
C26 C28 C29 124.1(5) . . ?
C26 C28 H23 117.9 . . ?
C29 C28 H23 117.9 . . ?
C28 C29 C23 117.8(4) . . ?
C28 C29 C30 120.5(4) . . ?
C23 C29 C30 121.7(4) . . ?
C29 C30 H26 109.5 . . ?
C29 C30 H25 109.5 . . ?
H26 C30 H25 109.5 . . ?
C29 C30 H24 109.5 . . ?
H26 C30 H24 109.5 . . ?
H25 C30 H24 109.5 . . ?
C37 C31 C32 119.7(4) . . ?
C37 C31 S1 122.2(4) . . ?
C32 C31 S1 117.9(4) . . ?
C33 C32 C31 117.6(5) . . ?
C33 C32 C38 120.5(4) . . ?
C31 C32 C38 121.9(4) . . ?
C34 C33 C32 123.7(5) . . ?
C34 C33 H33 118.1 . . ?
C32 C33 H33 118.1 . . ?
C33 C34 C36 117.7(5) . . ?
C33 C34 C35 121.3(5) . . ?
C36 C34 C35 121.0(5) . . ?
C34 C35 H30 109.5 . . ?
C34 C35 H28 109.5 . . ?
H30 C35 H28 109.5 . . ?
C34 C35 H29 109.5 . . ?
H30 C35 H29 109.5 . . ?
H28 C35 H29 109.5 . . ?
C37 C36 C34 120.6(5) . . ?
C37 C36 H32 119.7 . . ?
C34 C36 H32 119.7 . . ?
C31 C37 C36 120.7(5) . . ?
C31 C37 H31 119.7 . . ?
C36 C37 H31 119.7 . . ?
C32 C38 H38A 109.5 . . ?
C32 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C32 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C40 C39 C39 120.2(10) . 7_556 ?
C40 C39 H39A 107.3 . . ?
C39 C39 H39A 107.3 7_556 . ?
C40 C39 H39B 107.3 . . ?
C39 C39 H39B 107.3 7_556 . ?
H39A C39 H39B 106.9 . . ?
C39 C40 C41 115.7(8) . . ?
C39 C40 H40A 108.4 . . ?
C41 C40 H40A 108.4 . . ?
C39 C40 H40B 108.3 . . ?
C41 C40 H40B 108.3 . . ?
H40A C40 H40B 107.4 . . ?
C40 C41 H41A 109.4 . . ?
C40 C41 H41B 109.5 . . ?
H41A C41 H41B 109.5 . . ?
C40 C41 H41C 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pt2 S2 C3 C4 100.0(4) . . . . ?
Ag2 S2 C3 C4 7.3(4) . . . . ?
Pt2 S2 C3 C8 -81.3(4) . . . . ?
Ag2 S2 C3 C8 -174.1(3) . . . . ?
C8 C3 C4 C5 0.7(8) . . . . ?
S2 C3 C4 C5 179.3(4) . . . . ?
C3 C4 C5 C6 -1.4(9) . . . . ?
C4 C5 C6 C7 1.6(9) . . . . ?
C4 C5 C6 C10 -178.9(6) . . . . ?
C5 C6 C7 C8 -1.3(8) . . . . ?
C10 C6 C7 C8 179.2(5) . . . . ?
C6 C7 C8 C3 0.6(7) . . . . ?
C6 C7 C8 C9 179.3(5) . . . . ?
C4 C3 C8 C7 -0.3(7) . . . . ?
S2 C3 C8 C7 -179.0(4) . . . . ?
C4 C3 C8 C9 -179.0(5) . . . . ?
S2 C3 C8 C9 2.3(6) . . . . ?
Pt1 S3 C15 C20 -82.2(4) . . . . ?
Ag2 S3 C15 C20 -174.3(3) . . . . ?
Pt1 S3 C15 C16 101.5(4) . . . . ?
Ag2 S3 C15 C16 9.4(4) . . . . ?
C20 C15 C16 C17 1.7(7) . . . . ?
S3 C15 C16 C17 177.9(4) . . . . ?
C15 C16 C17 C18 -1.2(8) . . . . ?
C16 C17 C18 C19 -0.5(8) . . . . ?
C16 C17 C18 C22 -180.0(5) . . . . ?
C17 C18 C19 C20 1.9(8) . . . . ?
C22 C18 C19 C20 -178.6(5) . . . . ?
C16 C15 C20 C19 -0.3(7) . . . . ?
S3 C15 C20 C19 -176.6(4) . . . . ?
C16 C15 C20 C21 179.1(5) . . . . ?
S3 C15 C20 C21 2.8(6) . . . . ?
C18 C19 C20 C15 -1.5(8) . . . . ?
C18 C19 C20 C21 179.0(5) . . . . ?
Pt1 S4 C23 C24 104.6(4) . . . . ?
Ag1 S4 C23 C24 12.4(4) . . . . ?
Pt1 S4 C23 C29 -77.8(4) . . . . ?
Ag1 S4 C23 C29 -170.0(3) . . . . ?
C29 C23 C24 C25 2.6(7) . . . . ?
S4 C23 C24 C25 -179.9(4) . . . . ?
C23 C24 C25 C26 -0.4(8) . . . . ?
C24 C25 C26 C28 -1.6(8) . . . . ?
C24 C25 C26 C27 178.0(5) . . . . ?
C25 C26 C28 C29 1.4(8) . . . . ?
C27 C26 C28 C29 -178.1(5) . . . . ?
C26 C28 C29 C23 0.7(8) . . . . ?
C26 C28 C29 C30 179.9(5) . . . . ?
C24 C23 C29 C28 -2.7(7) . . . . ?
S4 C23 C29 C28 179.7(4) . . . . ?
C24 C23 C29 C30 178.2(4) . . . . ?
S4 C23 C29 C30 0.5(6) . . . . ?
Pt2 S1 C31 C37 99.5(4) . . . . ?
Ag1 S1 C31 C37 2.3(4) . . . . ?
Pt2 S1 C31 C32 -85.0(4) . . . . ?
Ag1 S1 C31 C32 177.8(3) . . . . ?
C37 C31 C32 C33 1.2(7) . . . . ?
S1 C31 C32 C33 -174.4(4) . . . . ?
C37 C31 C32 C38 -179.6(4) . . . . ?
S1 C31 C32 C38 4.8(6) . . . . ?
C31 C32 C33 C34 -0.3(7) . . . . ?
C38 C32 C33 C34 -179.5(5) . . . . ?
C32 C33 C34 C36 -1.0(8) . . . . ?
C32 C33 C34 C35 178.0(5) . . . . ?
C33 C34 C36 C37 1.3(7) . . . . ?
C35 C34 C36 C37 -177.7(5) . . . . ?
C32 C31 C37 C36 -0.9(7) . . . . ?
S1 C31 C37 C36 174.5(4) . . . . ?
C34 C36 C37 C31 -0.4(7) . . . . ?
C39 C39 C40 C41 178.6(7) 7_556 . . . ?

_refine_diff_density_max         1.078
_refine_diff_density_min         -0.677
_refine_diff_density_rms         0.131

