# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_CW-633
_database_code_depnum_ccdc_archive 'CCDC 2129082'
loop_
_audit_author_name
_audit_author_address
'Wilhelm Klein'
;Technische Universitaet Muenchen
Germany
;
_audit_update_record             
;
2022-03-17 deposited with the CCDC.	2022-03-30 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_formula_moiety         'C54 H140 Cu2 Ge18 N4 Si16'
_chemical_formula_sum            'C54 H140 Cu2 Ge18 N4 Si16'
_chemical_formula_weight         2728.83

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'I 2/c'
_space_group_name_Hall           '-I 2yc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, -y+1/2, z'

_cell_length_a                   16.6540(4)
_cell_length_b                   27.2393(8)
_cell_length_c                   27.6288(6)
_cell_angle_alpha                90
_cell_angle_beta                 103.416(2)
_cell_angle_gamma                90
_cell_volume                     12191.6(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    186016
_cell_measurement_theta_min      2.31
_cell_measurement_theta_max      33.15

_exptl_crystal_description       block
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.487
_exptl_crystal_F_000             5400
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_exptl_absorpt_coefficient_mu    4.887
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.856
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_process_details   'STOE X-AREA 1.76'

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'Genix 3D HF Mo'
_diffrn_source_voltage           50
_diffrn_source_current           1.000
_diffrn_source_power             0.050
_diffrn_radiation_monochromator  'Graded multilayer mirror'
_diffrn_radiation_collimation    '0.6 mm diameter'
_diffrn_measurement_device_type  'STOE StadiVari'
_diffrn_measurement_method       'ω scans'
_diffrn_detector                 Pilatus300K
_diffrn_detector_area_resol_mean 5.81
_diffrn_reflns_number            122568
_diffrn_reflns_av_unetI/netI     0.0354
_diffrn_reflns_av_R_equivalents  0.0973
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -33
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_theta_min         2.768
_diffrn_reflns_theta_max         26.000
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             11984
_reflns_number_gt                9236
_reflns_threshold_expression     'I > 2σ(I)'

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
;

_computing_data_collection       'STOE X-AREA 1.76'
_computing_cell_refinement       'STOE X-AREA 1.76'
_computing_data_reduction        'STOE X-AREA 1.76'
_computing_structure_solution    SHELXS-86
_computing_structure_refinement  SHELXL-2014/7
_computing_molecular_graphics    'DIAMOND 3.2k'
_computing_publication_material  'Microsoft NOTEPAD 6.1.7601.18917'

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0254P)²+42.8875P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         11984
_refine_ls_number_parameters     564
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0546
_refine_ls_R_factor_gt           0.0311
_refine_ls_wR_factor_ref         0.0818
_refine_ls_wR_factor_gt          0.0689
_refine_ls_goodness_of_fit_ref   1.134
_refine_ls_restrained_S_all      1.134
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.46649(2) 0.09875(2) 0.20605(2) 0.02696(10) Uani 1 1 d . . . . .
Ge2 Ge 0.50433(3) 0.05005(2) 0.13009(2) 0.02923(10) Uani 1 1 d . . . . .
Ge3 Ge 0.38860(3) 0.11304(2) 0.07986(2) 0.02808(10) Uani 1 1 d . . . . .
Ge4 Ge 0.36970(3) 0.16659(2) 0.15660(2) 0.02937(10) Uani 1 1 d . . . . .
Ge5 Ge 0.31430(3) 0.09948(2) 0.20931(2) 0.03154(10) Uani 1 1 d . . . . .
Ge6 Ge 0.42319(3) 0.00854(2) 0.18861(2) 0.03110(10) Uani 1 1 d . . . . .
Ge7 Ge 0.35587(3) 0.02125(2) 0.08511(2) 0.03119(10) Uani 1 1 d . . . . .
Ge8 Ge 0.25094(3) 0.11000(2) 0.10725(2) 0.03285(11) Uani 1 1 d . . . . .
Ge9 Ge 0.27367(3) 0.02711(2) 0.15058(2) 0.03055(10) Uani 1 1 d . . . . .
Cu Cu 0.51340(3) 0.14267(2) 0.14024(2) 0.03198(12) Uani 1 1 d . . . . .
C1 C 0.6094(3) 0.18397(15) 0.14026(17) 0.0360(10) Uani 1 1 d . . . . .
N1 N 0.6787(2) 0.17194(13) 0.12531(15) 0.0401(9) Uani 1 1 d . . . . .
C2 C 0.7333(3) 0.21094(19) 0.1319(2) 0.0584(15) Uani 1 1 d . . . . .
H2 H 0.7860 0.2115 0.1242 0.070 Uiso 1 1 calc R U . . .
C3 C 0.6976(3) 0.24747(19) 0.1510(2) 0.0614(16) Uani 1 1 d . . . . .
H3 H 0.7201 0.2792 0.1595 0.074 Uiso 1 1 calc R U . . .
N2 N 0.6222(2) 0.23094(13) 0.15614(17) 0.0476(10) Uani 1 1 d . . . . .
C4 C 0.6973(3) 0.12267(17) 0.1086(2) 0.0507(13) Uani 1 1 d . . . . .
H4 H 0.6442 0.1040 0.0993 0.061 Uiso 1 1 calc R U . . .
C5 C 0.7538(4) 0.0955(2) 0.1511(3) 0.078(2) Uani 1 1 d . . . . .
H5A H 0.8076 0.1120 0.1597 0.117 Uiso 1 1 calc R U . . .
H5B H 0.7612 0.0617 0.1409 0.117 Uiso 1 1 calc R U . . .
H5C H 0.7293 0.0954 0.1801 0.117 Uiso 1 1 calc R U . . .
C6 C 0.7328(4) 0.1257(2) 0.0627(3) 0.078(2) Uani 1 1 d . . . . .
H6A H 0.6949 0.1441 0.0365 0.116 Uiso 1 1 calc R U . . .
H6B H 0.7400 0.0924 0.0507 0.116 Uiso 1 1 calc R U . . .
H6C H 0.7864 0.1424 0.0712 0.116 Uiso 1 1 calc R U . . .
C7 C 0.5662(3) 0.26038(17) 0.1788(2) 0.0565(15) Uani 1 1 d . . . . .
H7 H 0.5170 0.2398 0.1800 0.068 Uiso 1 1 calc R U . . .
C8 C 0.6088(5) 0.2745(3) 0.2321(2) 0.082(2) Uani 1 1 d . . . . .
H8A H 0.6270 0.2447 0.2514 0.123 Uiso 1 1 calc R U . . .
H8B H 0.5701 0.2926 0.2473 0.123 Uiso 1 1 calc R U . . .
H8C H 0.6568 0.2952 0.2317 0.123 Uiso 1 1 calc R U . . .
C9 C 0.5365(4) 0.3055(2) 0.1476(3) 0.081(2) Uani 1 1 d . . . . .
H9A H 0.5839 0.3261 0.1457 0.122 Uiso 1 1 calc R U . . .
H9B H 0.4986 0.3242 0.1629 0.122 Uiso 1 1 calc R U . . .
H9C H 0.5077 0.2954 0.1140 0.122 Uiso 1 1 calc R U . . .
Si1 Si 0.17001(7) -0.03105(4) 0.15717(4) 0.0308(2) Uani 1 1 d . . . . .
Si2 Si 0.05354(7) 0.01759(5) 0.15816(5) 0.0395(3) Uani 1 1 d . . . . .
C10 C 0.0193(3) 0.0525(2) 0.0984(2) 0.0675(17) Uani 1 1 d . . . . .
H10A H 0.0006 0.0294 0.0709 0.101 Uiso 1 1 calc R U . . .
H10B H 0.0656 0.0718 0.0923 0.101 Uiso 1 1 calc R U . . .
H10C H -0.0262 0.0745 0.1008 0.101 Uiso 1 1 calc R U . . .
C11 C 0.0791(3) 0.06301(18) 0.2109(2) 0.0487(12) Uani 1 1 d . . . . .
H11A H 0.1240 0.0845 0.2062 0.073 Uiso 1 1 calc R U . . .
H11B H 0.0965 0.0453 0.2425 0.073 Uiso 1 1 calc R U . . .
H11C H 0.0302 0.0829 0.2113 0.073 Uiso 1 1 calc R U . . .
C12 C -0.0350(3) -0.0215(2) 0.1664(2) 0.0653(16) Uani 1 1 d . . . . .
H12A H -0.0815 -0.0004 0.1691 0.098 Uiso 1 1 calc R U . . .
H12B H -0.0179 -0.0412 0.1967 0.098 Uiso 1 1 calc R U . . .
H12C H -0.0520 -0.0434 0.1376 0.098 Uiso 1 1 calc R U . . .
Si3 Si 0.22122(8) -0.07311(5) 0.23282(5) 0.0402(3) Uani 1 1 d . . . . .
C13 C 0.2540(4) -0.02730(19) 0.28473(18) 0.0551(14) Uani 1 1 d . . . . .
H13A H 0.2726 -0.0448 0.3164 0.083 Uiso 1 1 calc R U . . .
H13B H 0.2072 -0.0061 0.2864 0.083 Uiso 1 1 calc R U . . .
H13C H 0.2993 -0.0072 0.2784 0.083 Uiso 1 1 calc R U . . .
C14 C 0.3114(4) -0.1122(2) 0.2294(2) 0.0634(16) Uani 1 1 d . . . . .
H14A H 0.3528 -0.0923 0.2184 0.095 Uiso 1 1 calc R U . . .
H14B H 0.2933 -0.1390 0.2056 0.095 Uiso 1 1 calc R U . . .
H14C H 0.3355 -0.1260 0.2623 0.095 Uiso 1 1 calc R U . . .
C15 C 0.1373(4) -0.1141(2) 0.2455(2) 0.0643(16) Uani 1 1 d . . . . .
H15A H 0.1187 -0.1365 0.2174 0.096 Uiso 1 1 calc R U . . .
H15B H 0.0908 -0.0940 0.2500 0.096 Uiso 1 1 calc R U . . .
H15C H 0.1589 -0.1332 0.2758 0.096 Uiso 1 1 calc R U . . .
Si4 Si 0.15261(9) -0.08473(5) 0.08849(5) 0.0435(3) Uani 1 1 d . . . . .
C16 C 0.1192(5) -0.0509(2) 0.0289(2) 0.094(3) Uani 1 1 d . . . . .
H16A H 0.1588 -0.0246 0.0275 0.141 Uiso 1 1 calc R U . . .
H16B H 0.0645 -0.0366 0.0268 0.141 Uiso 1 1 calc R U . . .
H16C H 0.1167 -0.0735 0.0011 0.141 Uiso 1 1 calc R U . . .
C17 C 0.0719(4) -0.1314(2) 0.0942(3) 0.0757(19) Uani 1 1 d . . . . .
H17A H 0.0203 -0.1145 0.0951 0.113 Uiso 1 1 calc R U . . .
H17B H 0.0909 -0.1502 0.1250 0.113 Uiso 1 1 calc R U . . .
H17C H 0.0624 -0.1536 0.0656 0.113 Uiso 1 1 calc R U . . .
C18 C 0.2505(4) -0.1173(2) 0.0873(2) 0.0671(16) Uani 1 1 d . . . . .
H18A H 0.2424 -0.1374 0.0571 0.101 Uiso 1 1 calc R U . . .
H18B H 0.2664 -0.1384 0.1167 0.101 Uiso 1 1 calc R U . . .
H18C H 0.2942 -0.0932 0.0873 0.101 Uiso 1 1 calc R U . . .
Si5 Si 0.35216(9) 0.13686(4) -0.00676(4) 0.0376(3) Uani 1 1 d . . . . .
Si6 Si 0.31877(18) 0.21820(9) -0.01443(11) 0.0393(7) Uani 0.466(2) 1 d . . P A
1
C19 C 0.3867(17) 0.2574(11) 0.0288(12) 0.063(6) Uani 0.466(2) 1 d . . P A 1
H19A H 0.3709 0.2918 0.0215 0.094 Uiso 0.466(2) 1 calc R U P A 1
H19B H 0.4436 0.2524 0.0258 0.094 Uiso 0.466(2) 1 calc R U P A 1
H19C H 0.3826 0.2495 0.0628 0.094 Uiso 0.466(2) 1 calc R U P A 1
C20 C 0.323(2) 0.2438(14) -0.0820(14) 0.054(6) Uani 0.466(2) 1 d . . P A 1
H20A H 0.2873 0.2239 -0.1077 0.081 Uiso 0.466(2) 1 calc R U P A 1
H20B H 0.3802 0.2419 -0.0860 0.081 Uiso 0.466(2) 1 calc R U P A 1
H20C H 0.3047 0.2780 -0.0852 0.081 Uiso 0.466(2) 1 calc R U P A 1
C21 C 0.2129(7) 0.2241(4) -0.0039(6) 0.067(4) Uani 0.466(2) 1 d . . P A 1
H21A H 0.2060 0.2008 0.0220 0.100 Uiso 0.466(2) 1 calc R U P A 1
H21B H 0.1722 0.2169 -0.0348 0.100 Uiso 0.466(2) 1 calc R U P A 1
H21C H 0.2046 0.2576 0.0069 0.100 Uiso 0.466(2) 1 calc R U P A 1
Si7 Si 0.25788(17) 0.08603(9) -0.05512(10) 0.0368(7) Uani 0.466(2) 1 d . . P A
1
C22 C 0.2177(8) 0.1175(4) -0.1172(4) 0.048(3) Uani 0.466(2) 1 d . . P A 1
H22A H 0.2639 0.1250 -0.1323 0.071 Uiso 0.466(2) 1 calc R U P A 1
H22B H 0.1897 0.1481 -0.1120 0.071 Uiso 0.466(2) 1 calc R U P A 1
H22C H 0.1786 0.0958 -0.1392 0.071 Uiso 0.466(2) 1 calc R U P A 1
C23 C 0.169(2) 0.0755(17) -0.0253(16) 0.055(9) Uani 0.466(2) 1 d . . P A 1
H23A H 0.1250 0.0584 -0.0488 0.082 Uiso 0.466(2) 1 calc R U P A 1
H23B H 0.1490 0.1071 -0.0163 0.082 Uiso 0.466(2) 1 calc R U P A 1
H23C H 0.1878 0.0554 0.0046 0.082 Uiso 0.466(2) 1 calc R U P A 1
C24 C 0.2975(9) 0.0242(4) -0.0659(5) 0.049(3) Uani 0.466(2) 1 d . . P A 1
H24A H 0.3166 0.0074 -0.0339 0.073 Uiso 0.466(2) 1 calc R U P A 1
H24B H 0.3435 0.0276 -0.0822 0.073 Uiso 0.466(2) 1 calc R U P A 1
H24C H 0.2532 0.0051 -0.0871 0.073 Uiso 0.466(2) 1 calc R U P A 1
Si8 Si 0.48394(17) 0.12806(9) -0.03700(10) 0.0348(6) Uani 0.466(2) 1 d . . P A
1
C25 C 0.4595(9) 0.1222(6) -0.1066(5) 0.056(4) Uani 0.466(2) 1 d . . P A 1
H25A H 0.5110 0.1197 -0.1178 0.084 Uiso 0.466(2) 1 calc R U P A 1
H25B H 0.4285 0.1511 -0.1216 0.084 Uiso 0.466(2) 1 calc R U P A 1
H25C H 0.4262 0.0926 -0.1166 0.084 Uiso 0.466(2) 1 calc R U P A 1
C26 C 0.5408(15) 0.0715(10) -0.0115(12) 0.045(5) Uani 0.466(2) 1 d . . P A 1
H26A H 0.5899 0.0679 -0.0251 0.068 Uiso 0.466(2) 1 calc R U P A 1
H26B H 0.5049 0.0429 -0.0208 0.068 Uiso 0.466(2) 1 calc R U P A 1
H26C H 0.5577 0.0739 0.0248 0.068 Uiso 0.466(2) 1 calc R U P A 1
C27 C 0.5520(6) 0.1829(4) -0.0187(5) 0.051(3) Uani 0.466(2) 1 d . . P A 1
H27A H 0.5601 0.1887 0.0171 0.076 Uiso 0.466(2) 1 calc R U P A 1
H27B H 0.5259 0.2118 -0.0370 0.076 Uiso 0.466(2) 1 calc R U P A 1
H27C H 0.6055 0.1770 -0.0267 0.076 Uiso 0.466(2) 1 calc R U P A 1
Si9 Si 0.39079(15) 0.21795(8) -0.01257(9) 0.0378(6) Uani 0.534(2) 1 d . . P A 2
C28 C 0.3596(13) 0.2605(9) 0.0347(10) 0.053(4) Uani 0.534(2) 1 d . . P A 2
H28A H 0.3863 0.2497 0.0684 0.079 Uiso 0.534(2) 1 calc R U P A 2
H28B H 0.2996 0.2596 0.0304 0.079 Uiso 0.534(2) 1 calc R U P A 2
H28C H 0.3771 0.2941 0.0296 0.079 Uiso 0.534(2) 1 calc R U P A 2
C29 C 0.346(2) 0.2394(13) -0.0743(13) 0.072(9) Uani 0.534(2) 1 d . . P A 2
H29A H 0.2868 0.2444 -0.0782 0.108 Uiso 0.534(2) 1 calc R U P A 2
H29B H 0.3555 0.2150 -0.0985 0.108 Uiso 0.534(2) 1 calc R U P A 2
H29C H 0.3721 0.2705 -0.0800 0.108 Uiso 0.534(2) 1 calc R U P A 2
C30 C 0.5059(6) 0.2188(4) 0.0006(4) 0.058(3) Uani 0.534(2) 1 d . . P A 2
H30A H 0.5253 0.2529 0.0026 0.087 Uiso 0.534(2) 1 calc R U P A 2
H30B H 0.5243 0.2019 -0.0263 0.087 Uiso 0.534(2) 1 calc R U P A 2
H30C H 0.5286 0.2022 0.0322 0.087 Uiso 0.534(2) 1 calc R U P A 2
Si10 Si 0.19904(14) 0.13459(8) -0.03768(9) 0.0343(6) Uani 0.534(2) 1 d . . P A
2
C31 C 0.1785(7) 0.1402(4) -0.1079(4) 0.051(3) Uani 0.534(2) 1 d . . P A 2
H31A H 0.1994 0.1109 -0.1216 0.077 Uiso 0.534(2) 1 calc R U P A 2
H31B H 0.2065 0.1694 -0.1166 0.077 Uiso 0.534(2) 1 calc R U P A 2
H31C H 0.1190 0.1431 -0.1218 0.077 Uiso 0.534(2) 1 calc R U P A 2
C32 C 0.151(2) 0.0768(12) -0.0239(15) 0.049(6) Uani 0.534(2) 1 d . . P A 2
H32A H 0.0910 0.0793 -0.0353 0.073 Uiso 0.534(2) 1 calc R U P A 2
H32B H 0.1660 0.0707 0.0120 0.073 Uiso 0.534(2) 1 calc R U P A 2
H32C H 0.1711 0.0496 -0.0412 0.073 Uiso 0.534(2) 1 calc R U P A 2
C33 C 0.1462(5) 0.1867(3) -0.0128(4) 0.052(3) Uani 0.534(2) 1 d . . P A 2
H33A H 0.0871 0.1862 -0.0286 0.078 Uiso 0.534(2) 1 calc R U P A 2
H33B H 0.1701 0.2179 -0.0200 0.078 Uiso 0.534(2) 1 calc R U P A 2
H33C H 0.1539 0.1830 0.0233 0.078 Uiso 0.534(2) 1 calc R U P A 2
Si11 Si 0.40693(14) 0.08294(8) -0.05188(8) 0.0342(6) Uani 0.534(2) 1 d . . P A
2
C34 C 0.4131(8) 0.1111(4) -0.1132(4) 0.052(3) Uani 0.534(2) 1 d . . P A 2
H34A H 0.4346 0.0869 -0.1331 0.078 Uiso 0.534(2) 1 calc R U P A 2
H34B H 0.4500 0.1396 -0.1072 0.078 Uiso 0.534(2) 1 calc R U P A 2
H34C H 0.3579 0.1216 -0.1312 0.078 Uiso 0.534(2) 1 calc R U P A 2
C35 C 0.5139(11) 0.0687(11) -0.0146(11) 0.051(6) Uani 0.534(2) 1 d . . P A 2
H35A H 0.5402 0.0451 -0.0328 0.076 Uiso 0.534(2) 1 calc R U P A 2
H35B H 0.5107 0.0546 0.0176 0.076 Uiso 0.534(2) 1 calc R U P A 2
H35C H 0.5466 0.0989 -0.0091 0.076 Uiso 0.534(2) 1 calc R U P A 2
C36 C 0.3434(6) 0.0251(4) -0.0652(4) 0.039(3) Uani 0.534(2) 1 d . . P A 2
H36A H 0.2889 0.0329 -0.0861 0.059 Uiso 0.534(2) 1 calc R U P A 2
H36B H 0.3370 0.0107 -0.0338 0.059 Uiso 0.534(2) 1 calc R U P A 2
H36C H 0.3714 0.0015 -0.0825 0.059 Uiso 0.534(2) 1 calc R U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 Ge1 2.4259(8) 2_655 ?
Ge1 Cu 2.4511(7) . ?
Ge1 Ge5 2.5570(6) . ?
Ge1 Ge6 2.5747(6) . ?
Ge1 Ge4 2.6187(6) . ?
Ge1 Ge2 2.6786(6) . ?
Ge2 Cu 2.5392(6) . ?
Ge2 Ge6 2.5947(6) . ?
Ge2 Ge7 2.6168(6) . ?
Ge2 Ge3 2.7100(6) . ?
Ge3 Si5 2.4172(13) . ?
Ge3 Cu 2.4790(6) . ?
Ge3 Ge7 2.5705(6) . ?
Ge3 Ge8 2.5769(6) . ?
Ge3 Ge4 2.6517(6) . ?
Ge4 Cu 2.6188(7) . ?
Ge4 Ge8 2.6259(6) . ?
Ge4 Ge5 2.6339(6) . ?
Ge5 Ge9 2.5429(6) . ?
Ge5 Ge8 2.7867(6) . ?
Ge6 Ge9 2.5192(6) . ?
Ge6 Ge7 2.8403(6) . ?
Ge7 Ge9 2.5141(6) . ?
Ge8 Ge9 2.5424(6) . ?
Ge9 Si1 2.3810(12) . ?
Cu C1 1.955(4) . ?
C1 N2 1.353(5) . ?
C1 N1 1.353(6) . ?
N1 C2 1.383(6) . ?
N1 C4 1.476(6) . ?
C2 C3 1.330(8) . ?
C2 H2 0.9500 . ?
C3 N2 1.372(6) . ?
C3 H3 0.9500 . ?
N2 C7 1.475(6) . ?
C4 C5 1.516(8) . ?
C4 C6 1.520(7) . ?
C4 H4 1.0000 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 C9 1.517(8) . ?
C7 C8 1.528(9) . ?
C7 H7 1.0000 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
Si1 Si2 2.3544(17) . ?
Si1 Si4 2.3593(17) . ?
Si1 Si3 2.3625(17) . ?
Si2 C10 1.875(6) . ?
Si2 C12 1.875(5) . ?
Si2 C11 1.883(5) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
Si3 C14 1.861(6) . ?
Si3 C13 1.884(5) . ?
Si3 C15 1.885(5) . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
Si4 C16 1.856(6) . ?
Si4 C18 1.863(6) . ?
Si4 C17 1.883(6) . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
Si5 Si11 2.252(2) . ?
Si5 Si7 2.279(3) . ?
Si5 Si6 2.282(3) . ?
Si5 Si9 2.317(2) . ?
Si5 Si10 2.495(3) . ?
Si5 Si8 2.534(3) . ?
Si6 C19 1.79(3) . ?
Si6 C21 1.860(12) . ?
Si6 C20 2.01(3) . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
Si7 C24 1.856(13) . ?
Si7 C23 1.87(4) . ?
Si7 C22 1.895(11) . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
Si8 C26 1.86(3) . ?
Si8 C27 1.873(11) . ?
Si8 C25 1.877(14) . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
Si9 C29 1.79(3) . ?
Si9 C30 1.867(10) . ?
Si9 C28 1.906(17) . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
Si10 C32 1.84(4) . ?
Si10 C33 1.882(9) . ?
Si10 C31 1.897(10) . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
Si11 C35 1.88(2) . ?
Si11 C34 1.885(12) . ?
Si11 C36 1.886(11) . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ge1 Ge1 Cu 126.22(2) 2_655 . ?
Ge1 Ge1 Ge5 101.21(3) 2_655 . ?
Cu Ge1 Ge5 120.76(2) . . ?
Ge1 Ge1 Ge6 103.364(14) 2_655 . ?
Cu Ge1 Ge6 116.79(2) . . ?
Ge5 Ge1 Ge6 77.121(18) . . ?
Ge1 Ge1 Ge4 127.362(17) 2_655 . ?
Cu Ge1 Ge4 62.098(18) . . ?
Ge5 Ge1 Ge4 61.166(17) . . ?
Ge6 Ge1 Ge4 117.65(2) . . ?
Ge1 Ge1 Ge2 130.32(2) 2_655 . ?
Cu Ge1 Ge2 59.140(17) . . ?
Ge5 Ge1 Ge2 116.53(2) . . ?
Ge6 Ge1 Ge2 59.158(16) . . ?
Ge4 Ge1 Ge2 99.724(19) . . ?
Cu Ge2 Ge6 112.98(2) . . ?
Cu Ge2 Ge7 112.07(2) . . ?
Ge6 Ge2 Ge7 66.047(17) . . ?
Cu Ge2 Ge1 55.960(17) . . ?
Ge6 Ge2 Ge1 58.424(16) . . ?
Ge7 Ge2 Ge1 98.770(19) . . ?
Cu Ge2 Ge3 56.250(17) . . ?
Ge6 Ge2 Ge3 100.587(19) . . ?
Ge7 Ge2 Ge3 57.673(16) . . ?
Ge1 Ge2 Ge3 79.575(17) . . ?
Si5 Ge3 Cu 123.89(4) . . ?
Si5 Ge3 Ge7 108.01(3) . . ?
Cu Ge3 Ge7 115.75(2) . . ?
Si5 Ge3 Ge8 105.27(4) . . ?
Cu Ge3 Ge8 118.49(2) . . ?
Ge7 Ge3 Ge8 74.772(18) . . ?
Si5 Ge3 Ge4 126.51(3) . . ?
Cu Ge3 Ge4 61.273(18) . . ?
Ge7 Ge3 Ge4 115.08(2) . . ?
Ge8 Ge3 Ge4 60.273(17) . . ?
Si5 Ge3 Ge2 131.48(4) . . ?
Cu Ge3 Ge2 58.391(17) . . ?
Ge7 Ge3 Ge2 59.343(16) . . ?
Ge8 Ge3 Ge2 113.87(2) . . ?
Ge4 Ge3 Ge2 98.105(19) . . ?
Ge1 Ge4 Cu 55.807(17) . . ?
Ge1 Ge4 Ge8 98.914(19) . . ?
Cu Ge4 Ge8 111.88(2) . . ?
Ge1 Ge4 Ge5 58.261(16) . . ?
Cu Ge4 Ge5 111.97(2) . . ?
Ge8 Ge4 Ge5 63.985(17) . . ?
Ge1 Ge4 Ge3 81.731(17) . . ?
Cu Ge4 Ge3 56.110(17) . . ?
Ge8 Ge4 Ge3 58.451(16) . . ?
Ge5 Ge4 Ge3 100.493(18) . . ?
Ge9 Ge5 Ge1 95.206(19) . . ?
Ge9 Ge5 Ge4 105.11(2) . . ?
Ge1 Ge5 Ge4 60.573(16) . . ?
Ge9 Ge5 Ge8 56.761(16) . . ?
Ge1 Ge5 Ge8 96.37(2) . . ?
Ge4 Ge5 Ge8 57.869(16) . . ?
Ge9 Ge6 Ge1 95.348(19) . . ?
Ge9 Ge6 Ge2 105.06(2) . . ?
Ge1 Ge6 Ge2 62.418(16) . . ?
Ge9 Ge6 Ge7 55.562(16) . . ?
Ge1 Ge6 Ge7 95.745(18) . . ?
Ge2 Ge6 Ge7 57.349(16) . . ?
Ge9 Ge7 Ge3 97.86(2) . . ?
Ge9 Ge7 Ge2 104.56(2) . . ?
Ge3 Ge7 Ge2 62.984(16) . . ?
Ge9 Ge7 Ge6 55.732(16) . . ?
Ge3 Ge7 Ge6 97.818(18) . . ?
Ge2 Ge7 Ge6 56.603(16) . . ?
Ge9 Ge8 Ge3 96.978(19) . . ?
Ge9 Ge8 Ge4 105.36(2) . . ?
Ge3 Ge8 Ge4 61.275(16) . . ?
Ge9 Ge8 Ge5 56.780(16) . . ?
Ge3 Ge8 Ge5 98.436(19) . . ?
Ge4 Ge8 Ge5 58.146(16) . . ?
Si1 Ge9 Ge7 122.56(3) . . ?
Si1 Ge9 Ge6 119.90(3) . . ?
Ge7 Ge9 Ge6 68.707(18) . . ?
Si1 Ge9 Ge8 126.55(3) . . ?
Ge7 Ge9 Ge8 76.353(19) . . ?
Ge6 Ge9 Ge8 113.55(2) . . ?
Si1 Ge9 Ge5 123.87(3) . . ?
Ge7 Ge9 Ge5 113.56(2) . . ?
Ge6 Ge9 Ge5 78.381(18) . . ?
Ge8 Ge9 Ge5 66.459(18) . . ?
C1 Cu Ge1 133.01(13) . . ?
C1 Cu Ge3 138.21(13) . . ?
Ge1 Cu Ge3 88.77(2) . . ?
C1 Cu Ge2 126.84(13) . . ?
Ge1 Cu Ge2 64.901(18) . . ?
Ge3 Cu Ge2 65.359(18) . . ?
C1 Cu Ge4 129.56(13) . . ?
Ge1 Cu Ge4 62.094(18) . . ?
Ge3 Cu Ge4 62.617(18) . . ?
Ge2 Cu Ge4 103.47(2) . . ?
N2 C1 N1 104.3(4) . . ?
N2 C1 Cu 127.7(3) . . ?
N1 C1 Cu 128.0(3) . . ?
C1 N1 C2 110.8(4) . . ?
C1 N1 C4 124.9(4) . . ?
C2 N1 C4 124.1(4) . . ?
C3 C2 N1 106.6(4) . . ?
C3 C2 H2 126.7 . . ?
N1 C2 H2 126.7 . . ?
C2 C3 N2 107.5(4) . . ?
C2 C3 H3 126.3 . . ?
N2 C3 H3 126.3 . . ?
C1 N2 C3 110.8(4) . . ?
C1 N2 C7 125.8(4) . . ?
C3 N2 C7 123.3(4) . . ?
N1 C4 C5 109.8(5) . . ?
N1 C4 C6 111.3(4) . . ?
C5 C4 C6 112.4(5) . . ?
N1 C4 H4 107.7 . . ?
C5 C4 H4 107.7 . . ?
C6 C4 H4 107.7 . . ?
C4 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C4 C6 H6A 109.5 . . ?
C4 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
C4 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
N2 C7 C9 110.7(5) . . ?
N2 C7 C8 110.3(5) . . ?
C9 C7 C8 111.2(5) . . ?
N2 C7 H7 108.2 . . ?
C9 C7 H7 108.2 . . ?
C8 C7 H7 108.2 . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C7 C9 H9A 109.5 . . ?
C7 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C7 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
Si2 Si1 Si4 114.22(7) . . ?
Si2 Si1 Si3 113.07(7) . . ?
Si4 Si1 Si3 111.27(6) . . ?
Si2 Si1 Ge9 103.91(5) . . ?
Si4 Si1 Ge9 107.87(6) . . ?
Si3 Si1 Ge9 105.72(5) . . ?
C10 Si2 C12 107.9(3) . . ?
C10 Si2 C11 108.4(3) . . ?
C12 Si2 C11 108.8(3) . . ?
C10 Si2 Si1 111.0(2) . . ?
C12 Si2 Si1 110.8(2) . . ?
C11 Si2 Si1 109.86(16) . . ?
Si2 C10 H10A 109.5 . . ?
Si2 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
Si2 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
Si2 C11 H11A 109.5 . . ?
Si2 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
Si2 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Si2 C12 H12A 109.5 . . ?
Si2 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
Si2 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C14 Si3 C13 108.9(3) . . ?
C14 Si3 C15 108.2(3) . . ?
C13 Si3 C15 110.3(3) . . ?
C14 Si3 Si1 111.24(19) . . ?
C13 Si3 Si1 109.50(17) . . ?
C15 Si3 Si1 108.8(2) . . ?
Si3 C13 H13A 109.5 . . ?
Si3 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
Si3 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
Si3 C14 H14A 109.5 . . ?
Si3 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
Si3 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
Si3 C15 H15A 109.5 . . ?
Si3 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
Si3 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C16 Si4 C18 107.7(3) . . ?
C16 Si4 C17 109.7(3) . . ?
C18 Si4 C17 109.0(3) . . ?
C16 Si4 Si1 111.1(2) . . ?
C18 Si4 Si1 111.41(19) . . ?
C17 Si4 Si1 107.9(2) . . ?
Si4 C16 H16A 109.5 . . ?
Si4 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
Si4 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
Si4 C17 H17A 109.5 . . ?
Si4 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
Si4 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
Si4 C18 H18A 109.5 . . ?
Si4 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
Si4 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
Si7 Si5 Si6 114.55(11) . . ?
Si11 Si5 Si9 115.40(10) . . ?
Si11 Si5 Ge3 109.40(8) . . ?
Si7 Si5 Ge3 113.45(8) . . ?
Si6 Si5 Ge3 110.62(9) . . ?
Si9 Si5 Ge3 108.33(8) . . ?
Si11 Si5 Si10 107.91(9) . . ?
Si9 Si5 Si10 106.15(9) . . ?
Ge3 Si5 Si10 109.52(8) . . ?
Si7 Si5 Si8 106.31(11) . . ?
Si6 Si5 Si8 105.80(10) . . ?
Ge3 Si5 Si8 105.26(8) . . ?
C19 Si6 C21 108.5(7) . . ?
C19 Si6 C20 105.0(16) . . ?
C21 Si6 C20 110.9(11) . . ?
C19 Si6 Si5 114.5(10) . . ?
C21 Si6 Si5 106.8(4) . . ?
C20 Si6 Si5 111.2(11) . . ?
Si6 C19 H19A 109.5 . . ?
Si6 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
Si6 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
Si6 C20 H20A 109.5 . . ?
Si6 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
Si6 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si6 C21 H21A 109.5 . . ?
Si6 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
Si6 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C24 Si7 C23 106.1(14) . . ?
C24 Si7 C22 109.3(6) . . ?
C23 Si7 C22 108.6(14) . . ?
C24 Si7 Si5 115.0(4) . . ?
C23 Si7 Si5 110.0(12) . . ?
C22 Si7 Si5 107.8(4) . . ?
Si7 C22 H22A 109.5 . . ?
Si7 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
Si7 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
Si7 C23 H23A 109.5 . . ?
Si7 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
Si7 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
Si7 C24 H24A 109.5 . . ?
Si7 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
Si7 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C26 Si8 C27 109.6(9) . . ?
C26 Si8 C25 106.7(11) . . ?
C27 Si8 C25 108.6(6) . . ?
C26 Si8 Si5 111.0(7) . . ?
C27 Si8 Si5 110.6(4) . . ?
C25 Si8 Si5 110.3(5) . . ?
Si8 C25 H25A 109.5 . . ?
Si8 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
Si8 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
Si8 C26 H26A 109.5 . . ?
Si8 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
Si8 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
Si8 C27 H27A 109.5 . . ?
Si8 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
Si8 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C29 Si9 C30 111.1(13) . . ?
C29 Si9 C28 109.6(15) . . ?
C30 Si9 C28 106.8(8) . . ?
C29 Si9 Si5 108.4(13) . . ?
C30 Si9 Si5 106.7(3) . . ?
C28 Si9 Si5 114.1(7) . . ?
Si9 C28 H28A 109.5 . . ?
Si9 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
Si9 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
Si9 C29 H29A 109.5 . . ?
Si9 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
Si9 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
Si9 C30 H30A 109.5 . . ?
Si9 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
Si9 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C32 Si10 C33 107.9(13) . . ?
C32 Si10 C31 107.2(12) . . ?
C33 Si10 C31 109.0(5) . . ?
C32 Si10 Si5 114.0(11) . . ?
C33 Si10 Si5 112.6(3) . . ?
C31 Si10 Si5 106.0(4) . . ?
Si10 C31 H31A 109.5 . . ?
Si10 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
Si10 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
Si10 C32 H32A 109.5 . . ?
Si10 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
Si10 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
Si10 C33 H33A 109.5 . . ?
Si10 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
Si10 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C35 Si11 C34 109.5(9) . . ?
C35 Si11 C36 110.6(9) . . ?
C34 Si11 C36 108.1(5) . . ?
C35 Si11 Si5 106.6(8) . . ?
C34 Si11 Si5 110.2(4) . . ?
C36 Si11 Si5 111.8(3) . . ?
Si11 C34 H34A 109.5 . . ?
Si11 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
Si11 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
Si11 C35 H35A 109.5 . . ?
Si11 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
Si11 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
Si11 C36 H36A 109.5 . . ?
Si11 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
Si11 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?

_refine_diff_density_max         0.626
_refine_diff_density_min         -0.484
_refine_diff_density_rms         0.101




#============================================================================== 
# END of CIF  
#============================================================================== 
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: Diethyl ether'
_refine_special_details          SQUEEZE
