# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_tb
_database_code_depnum_ccdc_archive 'CCDC 2030987'
loop_
_audit_author_name
_audit_author_address
tb
;NingXia University
China
;
_audit_update_record             
;
2020-09-09 deposited with the CCDC.	2022-01-24 downloaded from the CCDC.
;
_audit_creation_date             2019-06-07
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C44 H26 F9 N4 O6 Tb'
_chemical_formula_sum            'C44 H26 F9 N4 O6 Tb'
_chemical_formula_weight         1036.61
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C11 H10 N O'
_chemical_oxdiff_usercomment     C4A-C4-MGCL2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -9.1472 9.1891 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   10.9811(3)
_cell_length_b                   27.1423(8)
_cell_length_c                   27.9453(5)
_cell_angle_alpha                90
_cell_angle_beta                 93.546(2)
_cell_angle_gamma                90
_cell_volume                     8313.2(4)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    7580
_cell_measurement_temperature    180.01(10)
_cell_measurement_theta_max      70.3760
_cell_measurement_theta_min      4.0210
_shelx_estimated_absorpt_T_max   0.405
_shelx_estimated_absorpt_T_min   0.288
_exptl_absorpt_coefficient_mu    9.207
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.67121
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    1.656
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             4096
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.12
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0397
_diffrn_reflns_av_unetI/netI     0.0568
_diffrn_reflns_Laue_measured_fraction_full 0.990
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            27012
_diffrn_reflns_point_group_measured_fraction_full 0.990
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_theta_full        66.596
_diffrn_reflns_theta_max         66.596
_diffrn_reflns_theta_min         3.563
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      180.01(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 10.6525
_diffrn_detector_type            Atlas
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -92.00  -2.00   1.00   12.50    --  -39.95 125.00 -60.00   90
  2  ω    -63.00  33.00   1.00   12.50    --  -39.95  38.00-120.00   96
  3  ω    143.00 170.00   1.00   35.00    --  105.48  30.00 -90.00   27
  4  ω     77.00 142.00   1.00   35.00    --  105.48  77.00   0.00   65
  5  ω     83.00 178.00   1.00   35.00    --  105.48  45.00 -60.00   95
  6  ω     34.00 120.00   1.00   35.00    --  105.48 -61.00 150.00   86
  7  ω    104.00 178.00   1.00   35.00    --  105.48 125.00-150.00   74
  8  ω     80.00 138.00   1.00   35.00    --  105.48  30.00 -90.00   58
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at home/near, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0866839000
_diffrn_orient_matrix_UB_12      0.0176872000
_diffrn_orient_matrix_UB_13      0.0377779000
_diffrn_orient_matrix_UB_21      0.0995018000
_diffrn_orient_matrix_UB_22      0.0351566000
_diffrn_orient_matrix_UB_23      0.0210077000
_diffrn_orient_matrix_UB_31      -0.0486249000
_diffrn_orient_matrix_UB_32      0.0409018000
_diffrn_orient_matrix_UB_33      -0.0343364000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                9593
_reflns_number_total             14523
_reflns_odcompleteness_completeness 98.88
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.49
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_collection       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    ?
_refine_diff_density_max         0.928
_refine_diff_density_min         -1.289
_refine_diff_density_rms         0.087
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1153
_refine_ls_number_reflns         14523
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1050
_refine_ls_R_factor_gt           0.0657
_refine_ls_restrained_S_all      1.036
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0648P)²+29.7773P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1532
_refine_ls_wR_factor_ref         0.1734
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C45(H45), C46(H46), C47(H47), C52(H52), C53(H53), C54(H54), C56(H56),
 C57(H57), C59(H59), C60(H60), C61(H61), C62(H62), C63(H63), C66(H66), C69(H69),
  C70(H70), C71(H71), C72(H72), C73(H73), C76(H76), C79(H79), C80(H80),
 C81(H81), C82(H82), C83(H83), C86(H86), C1(H1), C2(H2), C3(H3), C8(H8), C9(H9),
  C10(H10), C13(H13), C14(H14), C15(H15), C16(H16), C17(H17), C18(H18),
 C19(H19), C21(H21), C25(H25), C26(H26), C27(H27), C28(H28), C29(H29), C32(H32),
  C35(H35), C36(H36), C37(H37), C38(H38), C39(H39), C42(H42)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Tb1 Tb 0.23923(4) 0.69237(2) 0.52285(2) 0.05376(15) Uani 1 1 d . . . . .
F10 F 0.1703(8) 0.8357(3) 0.6685(2) 0.129(3) Uani 1 1 d . . . . .
F11 F 0.1390(9) 0.7614(3) 0.6809(2) 0.149(3) Uani 1 1 d . . . . .
F12 F 0.3173(7) 0.7861(4) 0.6761(2) 0.140(3) Uani 1 1 d . . . . .
F13 F -0.1997(6) 0.6790(4) 0.4027(2) 0.148(4) Uani 1 1 d . . . . .
F14 F -0.0692(11) 0.7311(3) 0.3908(3) 0.189(5) Uani 1 1 d . . . . .
F15 F -0.0350(6) 0.6573(3) 0.3760(2) 0.109(2) Uani 1 1 d . . . . .
F16 F 0.3402(9) 0.7560(4) 0.3697(2) 0.145(3) Uani 1 1 d . . . . .
F17 F 0.5288(9) 0.7637(3) 0.3773(2) 0.151(4) Uani 1 1 d . . . . .
F18 F 0.4500(9) 0.6939(2) 0.3659(2) 0.131(3) Uani 1 1 d . . . . .
O7 O 0.0906(6) 0.6826(2) 0.4598(2) 0.0691(16) Uani 1 1 d . . . . .
O8 O 0.0566(5) 0.6704(2) 0.55555(19) 0.0607(15) Uani 1 1 d . . . . .
O9 O 0.2344(5) 0.7378(2) 0.5944(2) 0.0665(15) Uani 1 1 d . . . . .
O10 O 0.1760(6) 0.7714(2) 0.5037(2) 0.0700(16) Uani 1 1 d . . . . .
O11 O 0.3384(5) 0.7021(2) 0.45190(18) 0.0640(15) Uani 1 1 d . . . . .
O12 O 0.4397(5) 0.7165(2) 0.54268(18) 0.0575(14) Uani 1 1 d . . . . .
N00E N 0.3148(5) 0.6294(3) 0.5873(2) 0.0514(16) Uani 1 1 d . . . . .
N00H N 0.2738(6) 0.6041(3) 0.4946(2) 0.0566(17) Uani 1 1 d . . . . .
N00N N 0.4491(7) 0.4648(3) 0.6262(3) 0.076(2) Uani 1 1 d . . . . .
N00X N 0.3960(7) 0.4365(3) 0.5302(3) 0.074(2) Uani 1 1 d . . . . .
C45 C 0.3349(8) 0.6420(4) 0.6330(3) 0.063(2) Uani 1 1 d . . . . .
H45 H 0.3185 0.6743 0.6417 0.076 Uiso 1 1 calc R . . . .
C46 C 0.3792(8) 0.6096(4) 0.6686(3) 0.064(2) Uani 1 1 d . . . . .
H46 H 0.3903 0.6200 0.7003 0.076 Uiso 1 1 calc R . . . .
C47 C 0.4058(7) 0.5627(4) 0.6562(3) 0.063(2) Uani 1 1 d . . . . .
H47 H 0.4379 0.5407 0.6791 0.075 Uiso 1 1 calc R . . . .
C48 C 0.3844(7) 0.5478(3) 0.6081(3) 0.056(2) Uani 1 1 d . . . . .
C49 C 0.4055(7) 0.4973(3) 0.5929(3) 0.062(2) Uani 1 1 d . . . . .
C50 C 0.3805(7) 0.4830(3) 0.5456(3) 0.060(2) Uani 1 1 d . . . . .
C51 C 0.3344(7) 0.5197(3) 0.5103(3) 0.058(2) Uani 1 1 d . . . . .
C52 C 0.3099(8) 0.5081(4) 0.4627(3) 0.071(3) Uani 1 1 d . . . . .
H52 H 0.3219 0.4761 0.4519 0.085 Uiso 1 1 calc R . . . .
C53 C 0.2677(9) 0.5438(4) 0.4312(3) 0.074(3) Uani 1 1 d . . . . .
H53 H 0.2511 0.5366 0.3989 0.088 Uiso 1 1 calc R . . . .
C54 C 0.2501(8) 0.5917(4) 0.4487(3) 0.066(2) Uani 1 1 d . . . . .
H54 H 0.2207 0.6158 0.4274 0.080 Uiso 1 1 calc R . . . .
C55 C 0.3397(6) 0.5824(3) 0.5751(3) 0.0480(18) Uani 1 1 d . . . . .
C56 C 0.4648(10) 0.4196(4) 0.6118(4) 0.090(3) Uani 1 1 d . . . . .
H56 H 0.4950 0.3962 0.6337 0.108 Uiso 1 1 calc R . . . .
C57 C 0.4371(10) 0.4056(4) 0.5638(5) 0.087(3) Uani 1 1 d . . . . .
H57 H 0.4484 0.3728 0.5554 0.104 Uiso 1 1 calc R . . . .
C58 C 0.3147(7) 0.5684(3) 0.5248(3) 0.0525(19) Uani 1 1 d . . . . .
C59 C 0.0212(15) 0.8270(5) 0.4488(4) 0.123(5) Uani 1 1 d . . . . .
H59 H 0.0423 0.7955 0.4393 0.148 Uiso 1 1 calc R . . . .
C60 C -0.0557(17) 0.8566(6) 0.4185(5) 0.145(6) Uani 1 1 d . . . . .
H60 H -0.0889 0.8440 0.3896 0.174 Uiso 1 1 calc R . . . .
C61 C -0.0812(15) 0.9032(6) 0.4314(6) 0.125(5) Uani 1 1 d . . . . .
H61 H -0.1323 0.9223 0.4111 0.150 Uiso 1 1 calc R . . . .
C62 C -0.0347(11) 0.9227(4) 0.4728(6) 0.102(4) Uani 1 1 d . . . . .
H62 H -0.0493 0.9555 0.4801 0.123 Uiso 1 1 calc R . . . .
C63 C 0.0380(9) 0.8922(4) 0.5058(5) 0.094(4) Uani 1 1 d . . . . .
H63 H 0.0666 0.9040 0.5357 0.112 Uiso 1 1 calc R . . . .
C64 C 0.0634(9) 0.8448(3) 0.4911(4) 0.074(3) Uani 1 1 d . . . . .
C65 C 0.1345(9) 0.8093(4) 0.5228(4) 0.072(3) Uani 1 1 d . . . . .
C66 C 0.1482(9) 0.8167(4) 0.5728(4) 0.073(3) Uani 1 1 d . . . . .
H66 H 0.1236 0.8465 0.5854 0.087 Uiso 1 1 calc R . . . .
C67 C 0.1972(8) 0.7809(4) 0.6039(3) 0.068(2) Uani 1 1 d . . . . .
C68 C 0.2073(11) 0.7909(4) 0.6575(4) 0.079(3) Uani 1 1 d . . . . .
C69 C -0.2555(8) 0.6356(4) 0.5688(4) 0.070(2) Uani 1 1 d . . . . .
H69 H -0.2801 0.6273 0.5374 0.083 Uiso 1 1 calc R . . . .
C70 C -0.3302(9) 0.6260(4) 0.6053(4) 0.087(3) Uani 1 1 d . . . . .
H70 H -0.4035 0.6095 0.5987 0.105 Uiso 1 1 calc R . . . .
C71 C -0.2990(10) 0.6399(5) 0.6502(4) 0.100(4) Uani 1 1 d . . . . .
H71 H -0.3510 0.6332 0.6744 0.120 Uiso 1 1 calc R . . . .
C72 C -0.1888(9) 0.6643(5) 0.6612(4) 0.089(3) Uani 1 1 d . . . . .
H72 H -0.1680 0.6748 0.6923 0.107 Uiso 1 1 calc R . . . .
C73 C -0.1130(8) 0.6724(4) 0.6257(4) 0.074(3) Uani 1 1 d . . . . .
H73 H -0.0389 0.6882 0.6330 0.089 Uiso 1 1 calc R . . . .
C74 C -0.1422(7) 0.6581(3) 0.5790(3) 0.064(2) Uani 1 1 d . . . . .
C75 C -0.0555(8) 0.6676(3) 0.5418(3) 0.066(2) Uani 1 1 d . . . . .
C76 C -0.0997(9) 0.6742(4) 0.4936(3) 0.074(3) Uani 1 1 d . . . . .
H76 H -0.1836 0.6737 0.4864 0.088 Uiso 1 1 calc R . . . .
C77 C -0.0244(9) 0.6811(3) 0.4571(3) 0.068(2) Uani 1 1 d . . . . .
C78 C -0.0813(10) 0.6877(5) 0.4068(4) 0.082(3) Uani 1 1 d . . . . .
C79 C 0.6044(9) 0.7648(4) 0.6036(3) 0.081(3) Uani 1 1 d . . . . .
H79 H 0.5362 0.7499 0.6155 0.097 Uiso 1 1 calc R . . . .
C80 C 0.6874(11) 0.7867(5) 0.6348(4) 0.106(4) Uani 1 1 d . . . . .
H80 H 0.6749 0.7870 0.6674 0.128 Uiso 1 1 calc R . . . .
C81 C 0.7915(11) 0.8087(5) 0.6179(4) 0.100(4) Uani 1 1 d . . . . .
H81 H 0.8493 0.8238 0.6388 0.120 Uiso 1 1 calc R . . . .
C82 C 0.8053(9) 0.8073(4) 0.5699(4) 0.090(3) Uani 1 1 d . . . . .
H82 H 0.8745 0.8213 0.5579 0.108 Uiso 1 1 calc R . . . .
C83 C 0.7206(9) 0.7858(4) 0.5386(4) 0.079(3) Uani 1 1 d . . . . .
H83 H 0.7322 0.7861 0.5059 0.095 Uiso 1 1 calc R . . . .
C84 C 0.6179(8) 0.7638(3) 0.5552(3) 0.057(2) Uani 1 1 d . . . . .
C85 C 0.5209(8) 0.7416(3) 0.5233(3) 0.059(2) Uani 1 1 d . . . . .
C86 C 0.5180(9) 0.7470(3) 0.4726(3) 0.068(2) Uani 1 1 d . . . . .
H86 H 0.5799 0.7650 0.4596 0.081 Uiso 1 1 calc R . . . .
C87 C 0.4296(9) 0.7275(3) 0.4424(3) 0.059(2) Uani 1 1 d . . . . .
C88 C 0.4381(12) 0.7358(4) 0.3887(3) 0.082(3) Uani 1 1 d . . . . .
Tb2 Tb 0.32798(5) 0.51677(2) 0.80471(2) 0.05738(15) Uani 1 1 d . . . . .
F1 F 0.7560(9) 0.6307(3) 0.7831(4) 0.178(4) Uani 1 1 d . . . . .
F2 F 0.5840(10) 0.6650(3) 0.7732(4) 0.163(4) Uani 1 1 d . . . . .
F3 F 0.6463(10) 0.6380(3) 0.8403(3) 0.168(4) Uani 1 1 d . . . . .
F4 F -0.0991(6) 0.5238(3) 0.8342(2) 0.109(2) Uani 1 1 d . . . . .
F5 F -0.1504(5) 0.4487(3) 0.8323(2) 0.105(2) Uani 1 1 d . . . . .
F6 F -0.0546(5) 0.4778(3) 0.89445(19) 0.0964(19) Uani 1 1 d . . . . .
F7 F 0.0212(11) 0.6758(3) 0.7476(4) 0.212(6) Uani 1 1 d . . . . .
F8 F 0.1826(11) 0.6889(3) 0.7784(6) 0.219(7) Uani 1 1 d . . . . .
F9 F 0.0682(15) 0.6629(4) 0.8173(4) 0.228(7) Uani 1 1 d . . . . .
O1 O 0.4722(7) 0.5777(2) 0.7954(2) 0.085(2) Uani 1 1 d . . . . .
O2 O 0.4910(5) 0.4838(2) 0.76319(19) 0.0628(15) Uani 1 1 d . . . . .
O3 O 0.1445(5) 0.4983(2) 0.8389(2) 0.0625(15) Uani 1 1 d . . . . .
O4 O 0.2820(5) 0.4334(2) 0.7900(2) 0.0620(14) Uani 1 1 d . . . . .
O5 O 0.2198(6) 0.5899(2) 0.7953(2) 0.0770(19) Uani 1 1 d . . . . .
O6 O 0.2254(5) 0.5152(2) 0.73037(19) 0.0615(14) Uani 1 1 d . . . . .
N00P N 0.3675(7) 0.5614(3) 0.8859(2) 0.0656(19) Uani 1 1 d . . . . .
N00R N 0.4617(7) 0.4716(3) 0.8684(2) 0.068(2) Uani 1 1 d . . . . .
N01F N 0.7400(8) 0.4836(4) 1.0084(3) 0.085(2) Uani 1 1 d . . . . .
N014 N 0.6500(8) 0.5797(4) 1.0246(3) 0.087(3) Uani 1 1 d . . . . .
C1 C 0.4982(9) 0.4251(4) 0.8611(3) 0.073(3) Uani 1 1 d . . . . .
H1 H 0.4647 0.4080 0.8346 0.088 Uiso 1 1 calc R . . . .
C2 C 0.5828(11) 0.4019(5) 0.8913(4) 0.099(4) Uani 1 1 d . . . . .
H2 H 0.6013 0.3689 0.8868 0.118 Uiso 1 1 calc R . . . .
C3 C 0.6424(9) 0.4288(4) 0.9298(4) 0.080(3) Uani 1 1 d . . . . .
H3 H 0.7038 0.4142 0.9493 0.096 Uiso 1 1 calc R . . . .
C4 C 0.6550(8) 0.5057(4) 0.9789(3) 0.067(2) Uani 1 1 d . . . . .
C5 C 0.6078(9) 0.4775(4) 0.9379(3) 0.070(2) Uani 1 1 d . . . . .
C6 C 0.6114(8) 0.5524(4) 0.9873(3) 0.066(2) Uani 1 1 d . . . . .
C7 C 0.5168(10) 0.5735(4) 0.9552(3) 0.073(3) Uani 1 1 d . . . . .
C8 C 0.4601(11) 0.6187(4) 0.9637(4) 0.088(3) Uani 1 1 d . . . . .
H8 H 0.4904 0.6385 0.9888 0.105 Uiso 1 1 calc R . . . .
C9 C 0.3577(10) 0.6346(4) 0.9346(3) 0.082(3) Uani 1 1 d . . . . .
H9 H 0.3169 0.6637 0.9411 0.098 Uiso 1 1 calc R . . . .
C10 C 0.3208(9) 0.6048(3) 0.8959(3) 0.069(2) Uani 1 1 d . . . . .
H10 H 0.2578 0.6165 0.8752 0.083 Uiso 1 1 calc R . . . .
C11 C 0.4671(9) 0.5460(3) 0.9157(3) 0.066(2) Uani 1 1 d . . . . .
C12 C 0.5138(9) 0.4977(3) 0.9066(3) 0.066(2) Uani 1 1 d . . . . .
C13 C 0.7813(10) 0.5104(5) 1.0454(4) 0.088(3) Uani 1 1 d . . . . .
H13 H 0.8413 0.4973 1.0667 0.105 Uiso 1 1 calc R . . . .
C14 C 0.7372(10) 0.5578(5) 1.0534(4) 0.089(3) Uani 1 1 d . . . . .
H14 H 0.7696 0.5751 1.0799 0.107 Uiso 1 1 calc R . . . .
C15 C 0.7794(10) 0.4657(5) 0.7105(3) 0.089(3) Uani 1 1 d . . . . .
H15 H 0.8075 0.4979 0.7083 0.106 Uiso 1 1 calc R . . . .
C16 C 0.8465(10) 0.4270(6) 0.6916(4) 0.102(4) Uani 1 1 d . . . . .
H16 H 0.9186 0.4338 0.6771 0.122 Uiso 1 1 calc R . . . .
C17 C 0.8072(10) 0.3791(6) 0.6943(4) 0.097(4) Uani 1 1 d . . . . .
H17 H 0.8514 0.3536 0.6814 0.116 Uiso 1 1 calc R . . . .
C18 C 0.7008(10) 0.3695(5) 0.7164(4) 0.096(4) Uani 1 1 d . . . . .
H18 H 0.6734 0.3372 0.7191 0.116 Uiso 1 1 calc R . . . .
C19 C 0.6349(9) 0.4079(4) 0.7346(4) 0.083(3) Uani 1 1 d . . . . .
H19 H 0.5630 0.4008 0.7491 0.099 Uiso 1 1 calc R . . . .
C20 C 0.5964(9) 0.4957(4) 0.7530(3) 0.064(2) Uani 1 1 d . . . . .
C21 C 0.6460(10) 0.5425(4) 0.7633(4) 0.080(3) Uani 1 1 d . . . . .
H21 H 0.7264 0.5489 0.7566 0.096 Uiso 1 1 calc R . . . .
C22 C 0.5792(11) 0.5788(4) 0.7830(3) 0.077(3) Uani 1 1 d . . . . .
C23 C 0.6375(16) 0.6289(6) 0.7951(6) 0.125(5) Uani 1 1 d . . . . .
C24 C 0.6716(8) 0.4562(4) 0.7322(3) 0.069(3) Uani 1 1 d . . . . .
C25 C 0.2977(10) 0.3498(4) 0.7375(4) 0.083(3) Uani 1 1 d . . . . .
H25 H 0.3609 0.3726 0.7388 0.100 Uiso 1 1 calc R . . . .
C26 C 0.3138(13) 0.3058(5) 0.7153(4) 0.106(4) Uani 1 1 d . . . . .
H26 H 0.3866 0.2991 0.7013 0.127 Uiso 1 1 calc R . . . .
C27 C 0.2190(13) 0.2703(4) 0.7137(4) 0.094(4) Uani 1 1 d . . . . .
H27 H 0.2295 0.2395 0.6999 0.113 Uiso 1 1 calc R . . . .
C28 C 0.1149(13) 0.2822(4) 0.7323(4) 0.097(4) Uani 1 1 d . . . . .
H28 H 0.0500 0.2602 0.7298 0.117 Uiso 1 1 calc R . . . .
C29 C 0.1002(10) 0.3278(3) 0.7560(3) 0.076(3) Uani 1 1 d . . . . .
H29 H 0.0279 0.3348 0.7703 0.091 Uiso 1 1 calc R . . . .
C30 C 0.1925(8) 0.3613(3) 0.7578(3) 0.059(2) Uani 1 1 d . . . . .
C31 C 0.1839(8) 0.4095(3) 0.7831(3) 0.055(2) Uani 1 1 d . . . . .
C32 C 0.0715(8) 0.4263(3) 0.7998(3) 0.062(2) Uani 1 1 d . . . . .
H32 H 0.0011 0.4083 0.7918 0.074 Uiso 1 1 calc R . . . .
C33 C 0.0626(8) 0.4673(3) 0.8265(3) 0.061(2) Uani 1 1 d . . . . .
C34 C -0.0608(10) 0.4795(4) 0.8468(3) 0.076(3) Uani 1 1 d . . . . .
C35 C 0.1444(8) 0.4747(3) 0.6452(3) 0.066(2) Uani 1 1 d . . . . .
H35 H 0.1897 0.4558 0.6676 0.079 Uiso 1 1 calc R . . . .
C36 C 0.1139(9) 0.4557(4) 0.5993(3) 0.075(3) Uani 1 1 d . . . . .
H36 H 0.1372 0.4240 0.5913 0.090 Uiso 1 1 calc R . . . .
C37 C 0.0493(9) 0.4846(4) 0.5666(3) 0.080(3) Uani 1 1 d . . . . .
H37 H 0.0294 0.4722 0.5361 0.096 Uiso 1 1 calc R . . . .
C38 C 0.0138(10) 0.5307(5) 0.5777(4) 0.093(4) Uani 1 1 d . . . . .
H38 H -0.0300 0.5496 0.5549 0.111 Uiso 1 1 calc R . . . .
C39 C 0.0424(9) 0.5499(4) 0.6230(3) 0.078(3) Uani 1 1 d . . . . .
H39 H 0.0184 0.5816 0.6306 0.093 Uiso 1 1 calc R . . . .
C40 C 0.1074(8) 0.5211(3) 0.6569(3) 0.056(2) Uani 1 1 d . . . . .
C41 C 0.1450(7) 0.5406(3) 0.7061(3) 0.0513(19) Uani 1 1 d . . . . .
C42 C 0.1008(8) 0.5856(3) 0.7225(3) 0.063(2) Uani 1 1 d . . . . .
H42 H 0.0405 0.6019 0.7038 0.076 Uiso 1 1 calc R . . . .
C43 C 0.1427(8) 0.6062(3) 0.7646(3) 0.063(2) Uani 1 1 d . . . . .
C44 C 0.0981(12) 0.6569(4) 0.7769(4) 0.083(3) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Tb1 O7 2.342(6) . ?
Tb1 O8 2.332(5) . ?
Tb1 O9 2.353(6) . ?
Tb1 O10 2.309(6) . ?
Tb1 O11 2.335(5) . ?
Tb1 O12 2.330(5) . ?
Tb1 N00E 2.582(6) . ?
Tb1 N00H 2.559(7) . ?
F10 C68 1.323(11) . ?
F11 C68 1.301(12) . ?
F12 C68 1.293(13) . ?
F13 C78 1.319(12) . ?
F14 C78 1.272(13) . ?
F15 C78 1.317(12) . ?
F16 C88 1.291(13) . ?
F17 C88 1.306(12) . ?
F18 C88 1.315(12) . ?
O7 C77 1.262(11) . ?
O8 C75 1.269(10) . ?
O9 C67 1.270(11) . ?
O10 C65 1.257(11) . ?
O11 C87 1.258(10) . ?
O12 C85 1.270(9) . ?
N00E C45 1.328(10) . ?
N00E C55 1.351(10) . ?
N00H C54 1.336(10) . ?
N00H C58 1.344(10) . ?
N00N C49 1.349(11) . ?
N00N C56 1.306(13) . ?
N00X C50 1.349(11) . ?
N00X C57 1.318(12) . ?
C45 H45 0.9300 . ?
C45 C46 1.392(12) . ?
C46 H46 0.9300 . ?
C46 C47 1.357(12) . ?
C47 H47 0.9300 . ?
C47 C48 1.409(12) . ?
C48 C49 1.457(12) . ?
C48 C55 1.386(11) . ?
C49 C50 1.390(12) . ?
C50 C51 1.470(12) . ?
C51 C52 1.377(12) . ?
C51 C58 1.402(11) . ?
C52 H52 0.9300 . ?
C52 C53 1.371(13) . ?
C53 H53 0.9300 . ?
C53 C54 1.405(12) . ?
C54 H54 0.9300 . ?
C55 C58 1.465(10) . ?
C56 H56 0.9300 . ?
C56 C57 1.410(15) . ?
C57 H57 0.9300 . ?
C59 H59 0.9300 . ?
C59 C60 1.409(17) . ?
C59 C64 1.334(16) . ?
C60 H60 0.9300 . ?
C60 C61 1.350(19) . ?
C61 H61 0.9300 . ?
C61 C62 1.344(18) . ?
C62 H62 0.9300 . ?
C62 C63 1.442(16) . ?
C63 H63 0.9300 . ?
C63 C64 1.385(14) . ?
C64 C65 1.496(14) . ?
C65 C66 1.410(13) . ?
C66 H66 0.9300 . ?
C66 C67 1.389(13) . ?
C67 C68 1.520(13) . ?
C69 H69 0.9300 . ?
C69 C70 1.374(13) . ?
C69 C74 1.398(12) . ?
C70 H70 0.9300 . ?
C70 C71 1.334(14) . ?
C71 H71 0.9300 . ?
C71 C72 1.396(14) . ?
C72 H72 0.9300 . ?
C72 C73 1.351(13) . ?
C73 H73 0.9300 . ?
C73 C74 1.380(12) . ?
C74 C75 1.476(12) . ?
C75 C76 1.415(12) . ?
C76 H76 0.9300 . ?
C76 C77 1.364(13) . ?
C77 C78 1.513(13) . ?
C79 H79 0.9300 . ?
C79 C80 1.360(13) . ?
C79 C84 1.371(11) . ?
C80 H80 0.9300 . ?
C80 C81 1.398(15) . ?
C81 H81 0.9300 . ?
C81 C82 1.362(15) . ?
C82 H82 0.9300 . ?
C82 C83 1.367(14) . ?
C83 H83 0.9300 . ?
C83 C84 1.382(12) . ?
C84 C85 1.475(12) . ?
C85 C86 1.421(11) . ?
C86 H86 0.9300 . ?
C86 C87 1.355(12) . ?
C87 C88 1.525(12) . ?
Tb2 O1 2.316(7) . ?
Tb2 O2 2.368(6) . ?
Tb2 O3 2.338(6) . ?
Tb2 O4 2.349(6) . ?
Tb2 O5 2.320(6) . ?
Tb2 O6 2.302(5) . ?
Tb2 N00P 2.585(7) . ?
Tb2 N00R 2.552(7) . ?
F1 C23 1.365(17) . ?
F2 C23 1.278(19) . ?
F3 C23 1.285(16) . ?
F4 C34 1.317(12) . ?
F5 C34 1.334(11) . ?
F6 C34 1.329(11) . ?
F7 C44 1.249(12) . ?
F8 C44 1.271(15) . ?
F9 C44 1.207(13) . ?
O1 C22 1.246(12) . ?
O2 C20 1.251(10) . ?
O3 C33 1.265(10) . ?
O4 C31 1.262(10) . ?
O5 C43 1.249(10) . ?
O6 C41 1.280(9) . ?
N00P C10 1.322(11) . ?
N00P C11 1.396(11) . ?
N00R C1 1.343(11) . ?
N00R C12 1.374(11) . ?
N01F C4 1.346(11) . ?
N01F C13 1.322(13) . ?
N014 C6 1.326(11) . ?
N014 C14 1.350(13) . ?
C1 H1 0.9300 . ?
C1 C2 1.369(13) . ?
C2 H2 0.9300 . ?
C2 C3 1.425(14) . ?
C3 H3 0.9300 . ?
C3 C5 1.395(13) . ?
C4 C5 1.448(13) . ?
C4 C6 1.381(13) . ?
C5 C12 1.422(12) . ?
C6 C7 1.448(13) . ?
C7 C8 1.401(14) . ?
C7 C11 1.415(12) . ?
C8 H8 0.9300 . ?
C8 C9 1.414(14) . ?
C9 H9 0.9300 . ?
C9 C10 1.392(12) . ?
C10 H10 0.9300 . ?
C11 C12 1.437(12) . ?
C13 H13 0.9300 . ?
C13 C14 1.398(16) . ?
C14 H14 0.9300 . ?
C15 H15 0.9300 . ?
C15 C16 1.405(16) . ?
C15 C24 1.388(13) . ?
C16 H16 0.9300 . ?
C16 C17 1.373(17) . ?
C17 H17 0.9300 . ?
C17 C18 1.381(15) . ?
C18 H18 0.9300 . ?
C18 C19 1.384(14) . ?
C19 H19 0.9300 . ?
C19 C24 1.375(14) . ?
C20 C21 1.406(13) . ?
C20 C24 1.492(13) . ?
C21 H21 0.9300 . ?
C21 C22 1.364(14) . ?
C22 C23 1.530(16) . ?
C25 H25 0.9300 . ?
C25 C26 1.362(14) . ?
C25 C30 1.355(12) . ?
C26 H26 0.9300 . ?
C26 C27 1.417(17) . ?
C27 H27 0.9300 . ?
C27 C28 1.325(16) . ?
C28 H28 0.9300 . ?
C28 C29 1.417(14) . ?
C29 H29 0.9300 . ?
C29 C30 1.360(12) . ?
C30 C31 1.492(11) . ?
C31 C32 1.422(11) . ?
C32 H32 0.9300 . ?
C32 C33 1.347(11) . ?
C33 C34 1.537(13) . ?
C35 H35 0.9300 . ?
C35 C36 1.402(12) . ?
C35 C40 1.369(12) . ?
C36 H36 0.9300 . ?
C36 C37 1.368(14) . ?
C37 H37 0.9300 . ?
C37 C38 1.353(14) . ?
C38 H38 0.9300 . ?
C38 C39 1.385(12) . ?
C39 H39 0.9300 . ?
C39 C40 1.391(12) . ?
C40 C41 1.507(11) . ?
C41 C42 1.401(12) . ?
C42 H42 0.9300 . ?
C42 C43 1.357(12) . ?
C43 C44 1.505(13) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O7 Tb1 O9 130.4(2) . . ?
O7 Tb1 N00E 128.9(2) . . ?
O7 Tb1 N00H 76.8(2) . . ?
O8 Tb1 O7 71.9(2) . . ?
O8 Tb1 O9 74.7(2) . . ?
O8 Tb1 O11 145.0(2) . . ?
O8 Tb1 N00E 78.74(19) . . ?
O8 Tb1 N00H 91.7(2) . . ?
O9 Tb1 N00E 77.2(2) . . ?
O9 Tb1 N00H 139.9(2) . . ?
O10 Tb1 O7 75.3(2) . . ?
O10 Tb1 O8 94.3(2) . . ?
O10 Tb1 O9 71.8(2) . . ?
O10 Tb1 O11 81.2(2) . . ?
O10 Tb1 O12 93.4(2) . . ?
O10 Tb1 N00E 148.9(2) . . ?
O10 Tb1 N00H 148.0(2) . . ?
O11 Tb1 O7 73.4(2) . . ?
O11 Tb1 O9 134.3(2) . . ?
O11 Tb1 N00E 121.3(2) . . ?
O11 Tb1 N00H 76.0(2) . . ?
O12 Tb1 O7 144.59(19) . . ?
O12 Tb1 O8 143.23(18) . . ?
O12 Tb1 O9 73.8(2) . . ?
O12 Tb1 O11 71.77(19) . . ?
O12 Tb1 N00E 76.24(19) . . ?
O12 Tb1 N00H 100.4(2) . . ?
N00H Tb1 N00E 63.1(2) . . ?
C77 O7 Tb1 134.2(6) . . ?
C75 O8 Tb1 137.6(6) . . ?
C67 O9 Tb1 133.1(6) . . ?
C65 O10 Tb1 140.6(6) . . ?
C87 O11 Tb1 131.3(5) . . ?
C85 O12 Tb1 136.6(5) . . ?
C45 N00E Tb1 121.8(6) . . ?
C45 N00E C55 117.5(7) . . ?
C55 N00E Tb1 120.7(5) . . ?
C54 N00H Tb1 120.5(6) . . ?
C54 N00H C58 117.4(7) . . ?
C58 N00H Tb1 122.1(5) . . ?
C56 N00N C49 116.7(9) . . ?
C57 N00X C50 114.4(9) . . ?
N00E C45 H45 118.1 . . ?
N00E C45 C46 123.7(9) . . ?
C46 C45 H45 118.1 . . ?
C45 C46 H46 120.6 . . ?
C47 C46 C45 118.7(8) . . ?
C47 C46 H46 120.6 . . ?
C46 C47 H47 120.4 . . ?
C46 C47 C48 119.2(8) . . ?
C48 C47 H47 120.4 . . ?
C47 C48 C49 121.9(8) . . ?
C55 C48 C47 118.1(8) . . ?
C55 C48 C49 120.0(8) . . ?
N00N C49 C48 118.1(8) . . ?
N00N C49 C50 121.0(9) . . ?
C50 C49 C48 121.0(8) . . ?
N00X C50 C49 123.0(9) . . ?
N00X C50 C51 117.7(8) . . ?
C49 C50 C51 119.3(8) . . ?
C52 C51 C50 122.1(8) . . ?
C52 C51 C58 118.2(8) . . ?
C58 C51 C50 119.7(8) . . ?
C51 C52 H52 120.2 . . ?
C53 C52 C51 119.7(9) . . ?
C53 C52 H52 120.2 . . ?
C52 C53 H53 120.7 . . ?
C52 C53 C54 118.6(9) . . ?
C54 C53 H53 120.7 . . ?
N00H C54 C53 122.9(9) . . ?
N00H C54 H54 118.5 . . ?
C53 C54 H54 118.5 . . ?
N00E C55 C48 122.7(7) . . ?
N00E C55 C58 117.3(7) . . ?
C48 C55 C58 120.0(8) . . ?
N00N C56 H56 119.2 . . ?
N00N C56 C57 121.6(10) . . ?
C57 C56 H56 119.2 . . ?
N00X C57 C56 123.3(10) . . ?
N00X C57 H57 118.3 . . ?
C56 C57 H57 118.3 . . ?
N00H C58 C51 123.2(7) . . ?
N00H C58 C55 116.7(7) . . ?
C51 C58 C55 120.1(8) . . ?
C60 C59 H59 120.3 . . ?
C64 C59 H59 120.3 . . ?
C64 C59 C60 119.3(14) . . ?
C59 C60 H60 120.0 . . ?
C61 C60 C59 120.0(16) . . ?
C61 C60 H60 120.0 . . ?
C60 C61 H61 119.2 . . ?
C62 C61 C60 121.6(16) . . ?
C62 C61 H61 119.2 . . ?
C61 C62 H62 120.3 . . ?
C61 C62 C63 119.4(13) . . ?
C63 C62 H62 120.3 . . ?
C62 C63 H63 121.4 . . ?
C64 C63 C62 117.2(12) . . ?
C64 C63 H63 121.4 . . ?
C59 C64 C63 122.2(11) . . ?
C59 C64 C65 115.7(10) . . ?
C63 C64 C65 122.0(11) . . ?
O10 C65 C64 117.6(9) . . ?
O10 C65 C66 121.2(10) . . ?
C66 C65 C64 121.1(9) . . ?
C65 C66 H66 118.9 . . ?
C67 C66 C65 122.2(9) . . ?
C67 C66 H66 118.9 . . ?
O9 C67 C66 129.0(9) . . ?
O9 C67 C68 111.5(9) . . ?
C66 C67 C68 119.5(9) . . ?
F10 C68 C67 112.9(9) . . ?
F11 C68 F10 104.7(9) . . ?
F11 C68 C67 112.0(9) . . ?
F12 C68 F10 107.0(10) . . ?
F12 C68 F11 106.8(10) . . ?
F12 C68 C67 112.9(9) . . ?
C70 C69 H69 120.2 . . ?
C70 C69 C74 119.7(9) . . ?
C74 C69 H69 120.2 . . ?
C69 C70 H70 119.5 . . ?
C71 C70 C69 120.9(10) . . ?
C71 C70 H70 119.5 . . ?
C70 C71 H71 119.7 . . ?
C70 C71 C72 120.6(10) . . ?
C72 C71 H71 119.7 . . ?
C71 C72 H72 120.6 . . ?
C73 C72 C71 118.8(10) . . ?
C73 C72 H72 120.6 . . ?
C72 C73 H73 119.0 . . ?
C72 C73 C74 121.9(9) . . ?
C74 C73 H73 119.0 . . ?
C69 C74 C75 122.4(9) . . ?
C73 C74 C69 118.0(8) . . ?
C73 C74 C75 119.6(8) . . ?
O8 C75 C74 116.9(8) . . ?
O8 C75 C76 123.4(8) . . ?
C76 C75 C74 119.7(8) . . ?
C75 C76 H76 118.7 . . ?
C77 C76 C75 122.7(9) . . ?
C77 C76 H76 118.7 . . ?
O7 C77 C76 127.7(9) . . ?
O7 C77 C78 113.9(9) . . ?
C76 C77 C78 118.4(9) . . ?
F13 C78 C77 114.1(9) . . ?
F14 C78 F13 105.0(10) . . ?
F14 C78 F15 107.2(10) . . ?
F14 C78 C77 113.0(10) . . ?
F15 C78 F13 104.5(10) . . ?
F15 C78 C77 112.3(9) . . ?
C80 C79 H79 118.9 . . ?
C80 C79 C84 122.2(9) . . ?
C84 C79 H79 118.9 . . ?
C79 C80 H80 120.0 . . ?
C79 C80 C81 120.0(10) . . ?
C81 C80 H80 120.0 . . ?
C80 C81 H81 121.2 . . ?
C82 C81 C80 117.6(10) . . ?
C82 C81 H81 121.2 . . ?
C81 C82 H82 119.0 . . ?
C81 C82 C83 122.1(10) . . ?
C83 C82 H82 119.0 . . ?
C82 C83 H83 119.8 . . ?
C82 C83 C84 120.5(9) . . ?
C84 C83 H83 119.8 . . ?
C79 C84 C83 117.6(9) . . ?
C79 C84 C85 119.1(8) . . ?
C83 C84 C85 123.2(8) . . ?
O12 C85 C84 117.5(7) . . ?
O12 C85 C86 120.5(8) . . ?
C86 C85 C84 122.0(8) . . ?
C85 C86 H86 118.3 . . ?
C87 C86 C85 123.4(8) . . ?
C87 C86 H86 118.3 . . ?
O11 C87 C86 129.3(8) . . ?
O11 C87 C88 112.7(8) . . ?
C86 C87 C88 118.0(9) . . ?
F16 C88 F17 106.3(10) . . ?
F16 C88 F18 105.9(10) . . ?
F16 C88 C87 111.5(9) . . ?
F17 C88 F18 106.4(10) . . ?
F17 C88 C87 114.8(9) . . ?
F18 C88 C87 111.3(8) . . ?
O1 Tb2 O2 70.8(2) . . ?
O1 Tb2 O3 144.3(2) . . ?
O1 Tb2 O4 144.0(2) . . ?
O1 Tb2 O5 74.0(3) . . ?
O1 Tb2 N00P 71.7(2) . . ?
O1 Tb2 N00R 93.1(3) . . ?
O2 Tb2 N00P 121.1(2) . . ?
O2 Tb2 N00R 75.0(2) . . ?
O3 Tb2 O2 144.7(2) . . ?
O3 Tb2 O4 71.6(2) . . ?
O3 Tb2 N00P 81.0(2) . . ?
O3 Tb2 N00R 94.9(2) . . ?
O4 Tb2 O2 73.2(2) . . ?
O4 Tb2 N00P 128.8(2) . . ?
O4 Tb2 N00R 76.5(2) . . ?
O5 Tb2 O2 131.7(2) . . ?
O5 Tb2 O3 77.4(2) . . ?
O5 Tb2 O4 134.5(2) . . ?
O5 Tb2 N00P 75.9(2) . . ?
O5 Tb2 N00R 139.4(2) . . ?
O6 Tb2 O1 102.2(2) . . ?
O6 Tb2 O2 83.9(2) . . ?
O6 Tb2 O3 88.8(2) . . ?
O6 Tb2 O4 74.7(2) . . ?
O6 Tb2 O5 72.3(2) . . ?
O6 Tb2 N00P 147.9(2) . . ?
O6 Tb2 N00R 148.2(2) . . ?
N00R Tb2 N00P 63.5(2) . . ?
C22 O1 Tb2 135.3(7) . . ?
C20 O2 Tb2 138.8(6) . . ?
C33 O3 Tb2 130.3(5) . . ?
C31 O4 Tb2 134.0(5) . . ?
C43 O5 Tb2 134.6(6) . . ?
C41 O6 Tb2 138.6(5) . . ?
C10 N00P Tb2 123.8(6) . . ?
C10 N00P C11 116.2(8) . . ?
C11 N00P Tb2 117.8(6) . . ?
C1 N00R Tb2 120.6(5) . . ?
C1 N00R C12 119.3(8) . . ?
C12 N00R Tb2 119.1(6) . . ?
C13 N01F C4 115.2(10) . . ?
C6 N014 C14 113.7(10) . . ?
N00R C1 H1 118.8 . . ?
N00R C1 C2 122.3(9) . . ?
C2 C1 H1 118.8 . . ?
C1 C2 H2 120.3 . . ?
C1 C2 C3 119.5(10) . . ?
C3 C2 H2 120.3 . . ?
C2 C3 H3 120.3 . . ?
C5 C3 C2 119.3(9) . . ?
C5 C3 H3 120.3 . . ?
N01F C4 C5 116.7(9) . . ?
N01F C4 C6 122.6(9) . . ?
C6 C4 C5 120.7(8) . . ?
C3 C5 C4 122.7(9) . . ?
C3 C5 C12 117.4(9) . . ?
C12 C5 C4 119.6(9) . . ?
N014 C6 C4 123.3(9) . . ?
N014 C6 C7 116.6(10) . . ?
C4 C6 C7 120.0(8) . . ?
C8 C7 C6 123.4(9) . . ?
C8 C7 C11 116.0(10) . . ?
C11 C7 C6 120.1(9) . . ?
C7 C8 H8 119.4 . . ?
C7 C8 C9 121.1(9) . . ?
C9 C8 H8 119.4 . . ?
C8 C9 H9 121.6 . . ?
C10 C9 C8 116.8(9) . . ?
C10 C9 H9 121.6 . . ?
N00P C10 C9 125.7(9) . . ?
N00P C10 H10 117.1 . . ?
C9 C10 H10 117.1 . . ?
N00P C11 C7 123.9(9) . . ?
N00P C11 C12 116.2(8) . . ?
C7 C11 C12 119.8(9) . . ?
N00R C12 C5 122.0(9) . . ?
N00R C12 C11 118.2(8) . . ?
C5 C12 C11 119.7(8) . . ?
N01F C13 H13 119.2 . . ?
N01F C13 C14 121.6(11) . . ?
C14 C13 H13 119.2 . . ?
N014 C14 C13 123.5(10) . . ?
N014 C14 H14 118.3 . . ?
C13 C14 H14 118.3 . . ?
C16 C15 H15 119.8 . . ?
C24 C15 H15 119.8 . . ?
C24 C15 C16 120.4(12) . . ?
C15 C16 H16 119.5 . . ?
C17 C16 C15 121.0(11) . . ?
C17 C16 H16 119.5 . . ?
C16 C17 H17 120.6 . . ?
C16 C17 C18 118.8(12) . . ?
C18 C17 H17 120.6 . . ?
C17 C18 H18 120.1 . . ?
C17 C18 C19 119.9(13) . . ?
C19 C18 H18 120.1 . . ?
C18 C19 H19 118.7 . . ?
C24 C19 C18 122.6(10) . . ?
C24 C19 H19 118.7 . . ?
O2 C20 C21 122.5(9) . . ?
O2 C20 C24 116.5(9) . . ?
C21 C20 C24 120.8(9) . . ?
C20 C21 H21 119.2 . . ?
C22 C21 C20 121.6(10) . . ?
C22 C21 H21 119.2 . . ?
O1 C22 C21 129.4(10) . . ?
O1 C22 C23 110.4(11) . . ?
C21 C22 C23 120.1(12) . . ?
F1 C23 C22 111.8(14) . . ?
F2 C23 F1 105.7(12) . . ?
F2 C23 F3 109.0(15) . . ?
F2 C23 C22 113.7(14) . . ?
F3 C23 F1 102.7(14) . . ?
F3 C23 C22 113.2(12) . . ?
C15 C24 C20 123.0(10) . . ?
C19 C24 C15 117.4(11) . . ?
C19 C24 C20 119.6(8) . . ?
C26 C25 H25 119.0 . . ?
C30 C25 H25 119.0 . . ?
C30 C25 C26 122.0(11) . . ?
C25 C26 H26 120.2 . . ?
C25 C26 C27 119.6(11) . . ?
C27 C26 H26 120.2 . . ?
C26 C27 H27 120.9 . . ?
C28 C27 C26 118.2(11) . . ?
C28 C27 H27 120.9 . . ?
C27 C28 H28 119.3 . . ?
C27 C28 C29 121.5(12) . . ?
C29 C28 H28 119.3 . . ?
C28 C29 H29 120.2 . . ?
C30 C29 C28 119.7(11) . . ?
C30 C29 H29 120.2 . . ?
C25 C30 C29 118.9(9) . . ?
C25 C30 C31 118.7(8) . . ?
C29 C30 C31 122.3(8) . . ?
O4 C31 C30 116.5(8) . . ?
O4 C31 C32 122.3(8) . . ?
C32 C31 C30 121.2(8) . . ?
C31 C32 H32 118.6 . . ?
C33 C32 C31 122.8(9) . . ?
C33 C32 H32 118.6 . . ?
O3 C33 C32 128.9(9) . . ?
O3 C33 C34 112.5(7) . . ?
C32 C33 C34 118.6(9) . . ?
F4 C34 F5 105.9(9) . . ?
F4 C34 F6 107.2(8) . . ?
F4 C34 C33 111.9(9) . . ?
F5 C34 C33 113.7(8) . . ?
F6 C34 F5 106.0(9) . . ?
F6 C34 C33 111.7(8) . . ?
C36 C35 H35 120.0 . . ?
C40 C35 H35 120.0 . . ?
C40 C35 C36 120.0(9) . . ?
C35 C36 H36 120.5 . . ?
C37 C36 C35 118.9(10) . . ?
C37 C36 H36 120.5 . . ?
C36 C37 H37 119.3 . . ?
C38 C37 C36 121.4(9) . . ?
C38 C37 H37 119.3 . . ?
C37 C38 H38 119.8 . . ?
C37 C38 C39 120.3(10) . . ?
C39 C38 H38 119.8 . . ?
C38 C39 H39 120.4 . . ?
C38 C39 C40 119.3(10) . . ?
C40 C39 H39 120.4 . . ?
C35 C40 C39 120.0(8) . . ?
C35 C40 C41 118.2(8) . . ?
C39 C40 C41 121.7(8) . . ?
O6 C41 C40 115.8(7) . . ?
O6 C41 C42 122.5(7) . . ?
C42 C41 C40 121.5(7) . . ?
C41 C42 H42 118.7 . . ?
C43 C42 C41 122.5(8) . . ?
C43 C42 H42 118.7 . . ?
O5 C43 C42 128.9(9) . . ?
O5 C43 C44 112.5(8) . . ?
C42 C43 C44 118.5(9) . . ?
F7 C44 F8 101.7(13) . . ?
F7 C44 C43 116.4(9) . . ?
F8 C44 C43 112.6(11) . . ?
F9 C44 F7 110.1(12) . . ?
F9 C44 F8 96.7(12) . . ?
F9 C44 C43 116.6(11) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.630
_oxdiff_exptl_absorpt_empirical_full_min 0.743
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_eumxf
_database_code_depnum_ccdc_archive 'CCDC 2030986'
loop_
_audit_author_name
_audit_author_address
eu
;NingXia University
China
;
_audit_update_record             
;
2020-09-09 deposited with the CCDC.	2022-01-24 downloaded from the CCDC.
;
_audit_creation_date             2020-06-09
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C44 H26 Eu F9 N4 O6'
_chemical_formula_sum            'C44 H26 Eu F9 N4 O6'
_chemical_formula_weight         1029.65
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   11.0774(10)
_cell_length_b                   27.429(2)
_cell_length_c                   28.137(3)
_cell_angle_alpha                90
_cell_angle_beta                 93.525(3)
_cell_angle_gamma                90
_cell_volume                     8533.1(13)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    9609
_cell_measurement_temperature    298.0
_cell_measurement_theta_max      24.44
_cell_measurement_theta_min      2.34
_shelx_estimated_absorpt_T_max   0.859
_shelx_estimated_absorpt_T_min   0.835
_exptl_absorpt_coefficient_mu    1.562
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.603
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             4080
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0484
_diffrn_reflns_av_unetI/netI     0.0272
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       35
_diffrn_reflns_limit_k_min       -35
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_number            185259
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.496
_diffrn_reflns_theta_min         1.652
_diffrn_ambient_temperature      298.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                15086
_reflns_number_total             19572
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         1.222
_refine_diff_density_min         -0.743
_refine_diff_density_rms         0.068
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.095
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1321
_refine_ls_number_reflns         19572
_refine_ls_number_restraints     330
_refine_ls_R_factor_all          0.0696
_refine_ls_R_factor_gt           0.0494
_refine_ls_restrained_S_all      1.112
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0411P)²+11.1822P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1081
_refine_ls_wR_factor_ref         0.1167
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2. Restrained distances
 F9-F7 \\sim F8-F7 \\sim F9-F8
 with sigma of 0.02
 F9A-F7A \\sim F8A-F7A \\sim F9A-F8A
 with sigma of 0.02
 F8-C21 \\sim F7-C21 \\sim F9-C21
 with sigma of 0.02
 F8A-C21 \\sim F7A-C21 \\sim F9A-C21
 with sigma of 0.02
 F16A-C65 \\sim F18-C65 \\sim F18A-C65 \\sim F17-C65 \\sim F17A-C65 \\sim
F16-C65
 with sigma of 0.02
 F18A-F16A \\sim F18A-F17A \\sim F17A-F16A
 with sigma of 0.02
 F15A-C55 \\sim F13-C55 \\sim F13A-C55 \\sim F14-C55 \\sim F14A-C55 \\sim
F15-C55
 with sigma of 0.02
 F13-F14 \\sim F13-F15 \\sim F14-F15
 with sigma of 0.02
 F13A-F14A \\sim F13A-F15A \\sim F14A-F15A
 with sigma of 0.02
 F11A-C45 \\sim F10-C45 \\sim F10A-C45 \\sim F12-C45 \\sim F12A-C45 \\sim
F11-C45
 with sigma of 0.02
 F10-F11 \\sim F10-F12 \\sim F11-F12
 with sigma of 0.02
 F10A-F11A \\sim F10A-F12A \\sim F11A-F12A
 with sigma of 0.02
 F1-C1 \\sim F1A-C1 \\sim F3-C1 \\sim F3A-C1 \\sim F2-C1 \\sim F2A-C1
 with sigma of 0.02
 F1-F2 \\sim F1-F3 \\sim F2-F3
 with sigma of 0.02
 F1A-F2A \\sim F1A-F3A \\sim F2A-F3A
 with sigma of 0.02
 F6A-C11 \\sim F5-C11 \\sim F5A-C11 \\sim F6-C11 \\sim F4A-C11 \\sim F4-C11
 with sigma of 0.02
 F4-F5 \\sim F4-F6 \\sim F5-F6
 with sigma of 0.02
 F4A-F5A \\sim F4A-F6A \\sim F5A-F6A
 with sigma of 0.02
3. Rigid body (RIGU) restrains
 C65, F17A, F18A, F16A
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
 C65, F18, F16, F17
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
 C21, F9, F8, F7
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
 C21, F8A, F7A, F9A
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
 C55, F14A, F13A, F15A
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
 C55, F14, F13, F15
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
 C45, F12A, F10A, F11A
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
 C45, F12, F10, F11
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
 C1, F1A, F2A, F3A
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
 C1, F3, F1, F2
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
 C11, F5A, F6A, F4A
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
 C11, F5, F6, F4
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
4. Others
 Sof(F9A)=Sof(F8A)=Sof(F7A)=1-FVAR(1)
 Sof(F7)=Sof(F8)=Sof(F9)=FVAR(1)
 Sof(F18A)=Sof(F16A)=Sof(F17A)=1-FVAR(2)
 Sof(F16)=Sof(F17)=Sof(F18)=FVAR(2)
 Sof(F14A)=Sof(F13A)=Sof(F15A)=1-FVAR(3)
 Sof(F13)=Sof(F14)=Sof(F15)=FVAR(3)
 Sof(F12A)=Sof(F10A)=Sof(F11A)=1-FVAR(4)
 Sof(F10)=Sof(F11)=Sof(F12)=FVAR(4)
 Sof(F3A)=Sof(F1A)=Sof(F2A)=1-FVAR(5)
 Sof(F1)=Sof(F2)=Sof(F3)=FVAR(5)
 Sof(F5A)=Sof(F6A)=Sof(F4A)=1-FVAR(6)
 Sof(F4)=Sof(F5)=Sof(F6)=FVAR(6)
5.a Aromatic/amide H refined with riding coordinates:
 C3(H3), C6(H6), C7(H7), C8(H8), C9(H9), C10(H10), C13(H13), C16(H16),
 C17(H17), C18(H18), C19(H19), C20(H20), C23(H23), C26(H26), C27(H27), C28(H28),
  C29(H29), C30(H30), C31(H31), C32(H32), C33(H33), C40(H40), C41(H41),
 C42(H42), C43(H43), C44(H44), C47(H47), C50(H50), C51(H51), C52(H52), C53(H53),
  C54(H54), C57(H57), C60(H60), C61(H61), C62(H62), C63(H63), C64(H64),
 C67(H67), C70(H70), C71(H71), C72(H72), C73(H73), C74(H74), C75(H75), C76(H76),
  C77(H77), C84(H84), C85(H85), C86(H86), C87(H87), C88(H88)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.17660(2) 0.48268(2) 0.69528(2) 0.05614(7) Uani 1 1 d . . . . .
F1 F -0.1365(10) 0.3616(3) 0.6592(3) 0.185(4) Uani 0.862(13) 1 d D U P A 1
F2 F -0.2478(7) 0.3682(3) 0.7160(5) 0.205(4) Uani 0.862(13) 1 d D U P A 1
F3 F -0.0758(8) 0.3354(2) 0.7268(4) 0.185(4) Uani 0.862(13) 1 d D U P A 1
F4 F 0.5898(16) 0.4781(4) 0.6652(5) 0.115(3) Uani 0.71(5) 1 d D U P B 1
F5 F 0.6483(8) 0.5518(5) 0.6699(7) 0.106(3) Uani 0.71(5) 1 d D U P B 1
F6 F 0.5597(17) 0.5261(6) 0.6049(3) 0.122(4) Uani 0.71(5) 1 d D U P B 1
F7 F 0.3146(10) 0.3116(3) 0.7232(6) 0.171(6) Uani 0.590(17) 1 d D U P C 1
F8 F 0.4502(17) 0.3409(5) 0.6830(4) 0.182(7) Uani 0.590(17) 1 d D U P C 1
F9 F 0.4876(13) 0.3249(4) 0.7555(4) 0.157(5) Uani 0.590(17) 1 d D U P C 1
O1 O 0.0340(4) 0.42109(14) 0.70576(15) 0.0931(12) Uani 1 1 d . . . . .
O2 O 0.0120(3) 0.51433(12) 0.73683(12) 0.0710(9) Uani 1 1 d . . . . .
O3 O 0.3585(3) 0.50271(12) 0.65979(11) 0.0683(8) Uani 1 1 d . . . . .
O4 O 0.2203(3) 0.56659(11) 0.70958(12) 0.0646(8) Uani 1 1 d . . . . .
O5 O 0.2892(4) 0.41056(12) 0.70489(12) 0.0810(10) Uani 1 1 d . . . . .
O6 O 0.2800(3) 0.48415(11) 0.77034(11) 0.0668(8) Uani 1 1 d . . . . .
N1 N 0.1331(4) 0.43802(14) 0.61392(13) 0.0675(10) Uani 1 1 d . . . . .
N2 N 0.0378(4) 0.52645(15) 0.63130(14) 0.0703(11) Uani 1 1 d . . . . .
N3 N -0.1469(5) 0.4190(2) 0.47624(18) 0.1034(17) Uani 1 1 d . . . . .
N4 N -0.2380(4) 0.5134(2) 0.49301(17) 0.0959(16) Uani 1 1 d . . . . .
C1 C -0.1338(8) 0.3713(3) 0.7045(3) 0.134(2) Uani 1 1 d D U . . .
C2 C -0.0744(6) 0.4198(2) 0.7156(2) 0.0847(16) Uani 1 1 d . . . . .
C3 C -0.1412(5) 0.4559(2) 0.7344(2) 0.0892(17) Uani 1 1 d . . . . .
H3 H -0.221514 0.449557 0.739997 0.107 Uiso 1 1 calc R . . . .
C4 C -0.0935(5) 0.5027(2) 0.74571(16) 0.0699(13) Uani 1 1 d . . . . .
C5 C -0.1701(4) 0.5406(2) 0.76680(17) 0.0761(14) Uani 1 1 d . . . . .
C6 C -0.2763(6) 0.5306(3) 0.7876(2) 0.109(2) Uani 1 1 d . . . . .
H6 H -0.303380 0.498605 0.789076 0.130 Uiso 1 1 calc R . . . .
C7 C -0.3428(7) 0.5673(4) 0.8060(3) 0.133(3) Uani 1 1 d . . . . .
H7 H -0.413757 0.559721 0.820396 0.159 Uiso 1 1 calc R . . . .
C8 C -0.3075(7) 0.6143(4) 0.8037(3) 0.121(3) Uani 1 1 d . . . . .
H8 H -0.354405 0.638889 0.815964 0.145 Uiso 1 1 calc R . . . .
C9 C -0.2012(7) 0.6256(3) 0.7831(3) 0.120(2) Uani 1 1 d . . . . .
H9 H -0.175492 0.657773 0.781303 0.144 Uiso 1 1 calc R . . . .
C10 C -0.1331(6) 0.5882(3) 0.7651(2) 0.0972(19) Uani 1 1 d . . . . .
H10 H -0.060770 0.595588 0.751534 0.117 Uiso 1 1 calc R . . . .
C11 C 0.5587(4) 0.5241(2) 0.65157(19) 0.0822(11) Uani 1 1 d D U . . .
C12 C 0.4382(4) 0.53449(18) 0.67155(16) 0.0621(11) Uani 1 1 d . . . . .
C13 C 0.4264(4) 0.57549(18) 0.69802(18) 0.0701(13) Uani 1 1 d . . . . .
H13 H 0.494786 0.594409 0.705119 0.084 Uiso 1 1 calc R . . . .
C14 C 0.3151(4) 0.59086(16) 0.71534(16) 0.0596(11) Uani 1 1 d . . . . .
C15 C 0.3057(5) 0.63903(17) 0.73985(17) 0.0660(12) Uani 1 1 d . . . . .
C16 C 0.2004(6) 0.6506(2) 0.7592(2) 0.101(2) Uani 1 1 d . . . . .
H16 H 0.137267 0.628154 0.758290 0.121 Uiso 1 1 calc R . . . .
C17 C 0.1864(8) 0.6956(3) 0.7804(3) 0.131(3) Uani 1 1 d . . . . .
H17 H 0.113263 0.703284 0.793099 0.157 Uiso 1 1 calc R . . . .
C18 C 0.2768(9) 0.7286(2) 0.7830(3) 0.114(2) Uani 1 1 d . . . . .
H18 H 0.266136 0.758946 0.796826 0.136 Uiso 1 1 calc R . . . .
C19 C 0.3823(8) 0.7168(2) 0.7652(3) 0.115(2) Uani 1 1 d . . . . .
H19 H 0.445982 0.738927 0.767393 0.138 Uiso 1 1 calc R . . . .
C20 C 0.3978(6) 0.67232(19) 0.7435(2) 0.0858(16) Uani 1 1 d . . . . .
H20 H 0.471661 0.664859 0.731315 0.103 Uiso 1 1 calc R . . . .
C21 C 0.4082(6) 0.3431(2) 0.7240(2) 0.0952(15) Uani 1 1 d D U . . .
C22 C 0.3621(4) 0.39361(17) 0.73646(18) 0.0662(12) Uani 1 1 d . . . . .
C23 C 0.4000(5) 0.41450(19) 0.77889(18) 0.0721(13) Uani 1 1 d . . . . .
H23 H 0.458365 0.398277 0.798102 0.087 Uiso 1 1 calc R . . . .
C24 C 0.3561(4) 0.45877(18) 0.79497(16) 0.0605(11) Uani 1 1 d . . . . .
C25 C 0.3927(4) 0.47770(18) 0.84347(16) 0.0611(11) Uani 1 1 d . . . . .
C26 C 0.4544(5) 0.4496(2) 0.87774(19) 0.0894(17) Uani 1 1 d . . . . .
H26 H 0.478197 0.418147 0.870161 0.107 Uiso 1 1 calc R . . . .
C27 C 0.4811(7) 0.4674(3) 0.9229(2) 0.111(2) Uani 1 1 d . . . . .
H27 H 0.520254 0.447717 0.945956 0.134 Uiso 1 1 calc R . . . .
C28 C 0.4501(6) 0.5136(3) 0.9336(2) 0.101(2) Uani 1 1 d . . . . .
H28 H 0.470028 0.525744 0.963880 0.121 Uiso 1 1 calc R . . . .
C29 C 0.3895(5) 0.5430(2) 0.9003(2) 0.0881(16) Uani 1 1 d . . . . .
H29 H 0.368879 0.574838 0.907840 0.106 Uiso 1 1 calc R . . . .
C30 C 0.3598(5) 0.52434(19) 0.85540(19) 0.0722(13) Uani 1 1 d . . . . .
H30 H 0.317071 0.543558 0.832943 0.087 Uiso 1 1 calc R . . . .
C31 C 0.1813(5) 0.39545(19) 0.60443(19) 0.0789(14) Uani 1 1 d . . . . .
H31 H 0.244376 0.384228 0.624871 0.095 Uiso 1 1 calc R . . . .
C32 C 0.1438(6) 0.3660(2) 0.5656(2) 0.0952(18) Uani 1 1 d . . . . .
H32 H 0.183702 0.337030 0.559448 0.114 Uiso 1 1 calc R . . . .
C33 C 0.0452(6) 0.3814(2) 0.5368(2) 0.0934(18) Uani 1 1 d . . . . .
H33 H 0.015207 0.361859 0.511750 0.112 Uiso 1 1 calc R . . . .
C34 C -0.0087(5) 0.4260(2) 0.54520(18) 0.0756(14) Uani 1 1 d . . . . .
C35 C 0.0375(4) 0.45343(18) 0.58450(16) 0.0663(12) Uani 1 1 d . . . . .
C36 C -0.1086(5) 0.4466(2) 0.51423(18) 0.0798(15) Uani 1 1 d . . . . .
C37 C -0.1523(4) 0.4925(2) 0.52211(18) 0.0755(14) Uani 1 1 d . . . . .
C38 C -0.1040(5) 0.5206(2) 0.56227(18) 0.0750(14) Uani 1 1 d . . . . .
C39 C -0.0119(4) 0.50089(19) 0.59351(16) 0.0654(11) Uani 1 1 d . . . . .
C40 C -0.1414(5) 0.5678(2) 0.5708(2) 0.0910(18) Uani 1 1 d . . . . .
H40 H -0.203556 0.581543 0.551537 0.109 Uiso 1 1 calc R . . . .
C41 C -0.0875(6) 0.5944(3) 0.6076(2) 0.104(2) Uani 1 1 d . . . . .
H41 H -0.108305 0.626840 0.612077 0.125 Uiso 1 1 calc R . . . .
C42 C -0.0010(5) 0.5718(2) 0.6379(2) 0.0893(17) Uani 1 1 d . . . . .
H42 H 0.031371 0.589127 0.664022 0.107 Uiso 1 1 calc R . . . .
C43 C -0.2326(7) 0.4400(3) 0.4482(2) 0.111(2) Uani 1 1 d . . . . .
H43 H -0.264150 0.422861 0.421826 0.133 Uiso 1 1 calc R . . . .
C44 C -0.2782(6) 0.4869(3) 0.4564(2) 0.110(2) Uani 1 1 d . . . . .
H44 H -0.338254 0.499585 0.435348 0.132 Uiso 1 1 calc R . . . .
Eu2 Eu 0.26098(2) 0.30809(2) 0.97878(2) 0.05948(7) Uani 1 1 d . . . . .
F10 F 0.3667(10) 0.2373(3) 0.8218(2) 0.155(3) Uani 0.838(13) 1 d D U P D 1
F11 F 0.1846(7) 0.2162(4) 0.8258(3) 0.175(4) Uani 0.838(13) 1 d D U P D 1
F12 F 0.3270(7) 0.1648(2) 0.8335(2) 0.139(3) Uani 0.838(13) 1 d D U P D 1
F13 F 0.1528(7) 0.2463(3) 1.1318(2) 0.164(3) Uani 0.865(12) 1 d D U P E 1
F14 F 0.0482(9) 0.30860(19) 1.1344(2) 0.147(3) Uani 0.865(12) 1 d D U P E 1
F15 F -0.0347(8) 0.2403(3) 1.12381(19) 0.156(3) Uani 0.865(12) 1 d D U P E 1
F16 F 0.616(2) 0.2675(4) 1.0996(8) 0.131(6) Uani 0.39(2) 1 d D U P F 1
F17 F 0.520(2) 0.3297(11) 1.1280(8) 0.148(7) Uani 0.39(2) 1 d D U P F 1
F18 F 0.6920(11) 0.3343(6) 1.0975(6) 0.106(4) Uani 0.39(2) 1 d D U P F 1
O7 O 0.2676(3) 0.26210(14) 0.90704(12) 0.0778(9) Uani 1 1 d . . . . .
O8 O 0.3264(4) 0.22903(14) 0.99745(13) 0.0849(10) Uani 1 1 d . . . . .
O9 O 0.1591(3) 0.29856(14) 1.04948(12) 0.0788(10) Uani 1 1 d . . . . .
O10 O 0.0610(3) 0.28269(14) 0.95921(11) 0.0742(9) Uani 1 1 d . . . . .
O11 O 0.4103(3) 0.31922(14) 1.04225(12) 0.0815(10) Uani 1 1 d . . . . .
O12 O 0.4451(3) 0.33066(14) 0.94665(11) 0.0723(9) Uani 1 1 d . . . . .
N5 N 0.1839(3) 0.37088(14) 0.91428(13) 0.0588(9) Uani 1 1 d . . . . .
N6 N 0.2257(3) 0.39680(15) 1.00644(13) 0.0656(10) Uani 1 1 d . . . . .
N7 N 0.0518(5) 0.5335(2) 0.87361(18) 0.0920(14) Uani 1 1 d . . . . .
N8 N 0.1043(4) 0.56225(18) 0.96942(19) 0.0896(14) Uani 1 1 d . . . . .
C45 C 0.2938(6) 0.2099(2) 0.8442(2) 0.0964(14) Uani 1 1 d D U . . .
C46 C 0.3031(5) 0.2203(2) 0.89733(18) 0.0723(13) Uani 1 1 d . . . . .
C47 C 0.3508(5) 0.1848(2) 0.9280(2) 0.0814(15) Uani 1 1 d . . . . .
H47 H 0.373744 0.155077 0.915385 0.098 Uiso 1 1 calc R . . . .
C48 C 0.3657(5) 0.19193(19) 0.9771(2) 0.0752(14) Uani 1 1 d . . . . .
C49 C 0.4358(5) 0.15643(19) 1.0088(2) 0.0822(15) Uani 1 1 d . . . . .
C50 C 0.4576(6) 0.1090(2) 0.9946(3) 0.101(2) Uani 1 1 d . . . . .
H50 H 0.426425 0.097325 0.965359 0.121 Uiso 1 1 calc R . . . .
C51 C 0.5286(8) 0.0791(3) 1.0261(4) 0.124(3) Uani 1 1 d . . . . .
H51 H 0.541994 0.046798 1.017946 0.149 Uiso 1 1 calc R . . . .
C52 C 0.5770(10) 0.0963(4) 1.0675(4) 0.151(4) Uani 1 1 d . . . . .
H52 H 0.625345 0.076237 1.087348 0.181 Uiso 1 1 calc R . . . .
C53 C 0.5556(11) 0.1429(4) 1.0805(3) 0.179(5) Uani 1 1 d . . . . .
H53 H 0.590431 0.154995 1.109051 0.215 Uiso 1 1 calc R . . . .
C54 C 0.4815(8) 0.1726(3) 1.0513(3) 0.128(3) Uani 1 1 d . . . . .
H54 H 0.463275 0.203995 1.061225 0.153 Uiso 1 1 calc R . . . .
C55 C 0.0588(7) 0.2670(2) 1.1125(2) 0.0986(15) Uani 1 1 d D U . . .
C56 C 0.0687(5) 0.27413(18) 1.05901(16) 0.0687(12) Uani 1 1 d . . . . .
C57 C -0.0192(5) 0.25429(19) 1.02881(19) 0.0786(14) Uani 1 1 d . . . . .
H57 H -0.081147 0.236754 1.041686 0.094 Uiso 1 1 calc R . . . .
C58 C -0.0199(4) 0.25926(17) 0.97899(17) 0.0659(12) Uani 1 1 d . . . . .
C59 C -0.1161(4) 0.23654(18) 0.94701(19) 0.0709(13) Uani 1 1 d . . . . .
C60 C -0.2194(6) 0.2158(2) 0.9641(3) 0.1001(19) Uani 1 1 d . . . . .
H60 H -0.230413 0.216135 0.996624 0.120 Uiso 1 1 calc R . . . .
C61 C -0.3065(7) 0.1947(3) 0.9328(3) 0.124(3) Uani 1 1 d . . . . .
H61 H -0.376601 0.181754 0.944325 0.149 Uiso 1 1 calc R . . . .
C62 C -0.2893(8) 0.1930(3) 0.8859(3) 0.137(3) Uani 1 1 d . . . . .
H62 H -0.346678 0.178045 0.865281 0.164 Uiso 1 1 calc R . . . .
C63 C -0.1889(8) 0.2129(3) 0.8684(3) 0.137(3) Uani 1 1 d . . . . .
H63 H -0.177883 0.211780 0.835936 0.165 Uiso 1 1 calc R . . . .
C64 C -0.1036(6) 0.2347(3) 0.8990(2) 0.105(2) Uani 1 1 d . . . . .
H64 H -0.035652 0.248660 0.886738 0.126 Uiso 1 1 calc R . . . .
C65 C 0.5807(6) 0.3126(2) 1.0949(2) 0.0951(13) Uani 1 1 d D U . . .
C66 C 0.5231(5) 0.31992(19) 1.04431(19) 0.0743(14) Uani 1 1 d . . . . .
C67 C 0.5976(5) 0.3267(2) 1.0081(2) 0.0831(15) Uani 1 1 d . . . . .
H67 H 0.680704 0.327329 1.015314 0.100 Uiso 1 1 calc R . . . .
C68 C 0.5547(4) 0.33285(19) 0.96050(19) 0.0694(12) Uani 1 1 d . . . . .
C69 C 0.6414(4) 0.34236(19) 0.92321(19) 0.0696(12) Uani 1 1 d . . . . .
C70 C 0.7530(5) 0.3644(2) 0.9334(2) 0.0896(17) Uani 1 1 d . . . . .
H70 H 0.777075 0.372615 0.964643 0.108 Uiso 1 1 calc R . . . .
C71 C 0.8275(5) 0.3741(3) 0.8976(3) 0.113(2) Uani 1 1 d . . . . .
H71 H 0.899992 0.390475 0.904457 0.136 Uiso 1 1 calc R . . . .
C72 C 0.7973(6) 0.3603(3) 0.8524(3) 0.123(3) Uani 1 1 d . . . . .
H72 H 0.849819 0.366394 0.828519 0.148 Uiso 1 1 calc R . . . .
C73 C 0.6893(6) 0.3373(3) 0.8416(2) 0.110(2) Uani 1 1 d . . . . .
H73 H 0.668683 0.327597 0.810514 0.132 Uiso 1 1 calc R . . . .
C74 C 0.6118(5) 0.3286(2) 0.8766(2) 0.0864(16) Uani 1 1 d . . . . .
H74 H 0.538337 0.313192 0.868995 0.104 Uiso 1 1 calc R . . . .
C75 C 0.1634(4) 0.3581(2) 0.86890(16) 0.0683(12) Uani 1 1 d . . . . .
H75 H 0.179294 0.325994 0.860621 0.082 Uiso 1 1 calc R . . . .
C76 C 0.1199(5) 0.3896(2) 0.83292(17) 0.0750(14) Uani 1 1 d . . . . .
H76 H 0.107694 0.378925 0.801606 0.090 Uiso 1 1 calc R . . . .
C77 C 0.0957(4) 0.4366(2) 0.84528(17) 0.0712(13) Uani 1 1 d . . . . .
H77 H 0.065593 0.458469 0.822213 0.085 Uiso 1 1 calc R . . . .
C78 C 0.1160(4) 0.45204(19) 0.89262(16) 0.0627(11) Uani 1 1 d . . . . .
C79 C 0.1613(4) 0.41754(17) 0.92605(15) 0.0568(10) Uani 1 1 d . . . . .
C80 C 0.0953(4) 0.5019(2) 0.9075(2) 0.0735(13) Uani 1 1 d . . . . .
C81 C 0.1209(4) 0.51584(19) 0.9543(2) 0.0722(13) Uani 1 1 d . . . . .
C82 C 0.1655(4) 0.48027(18) 0.98949(18) 0.0666(12) Uani 1 1 d . . . . .
C83 C 0.1847(4) 0.43173(17) 0.97566(16) 0.0591(11) Uani 1 1 d . . . . .
C84 C 0.1899(5) 0.4918(2) 1.0375(2) 0.0807(15) Uani 1 1 d . . . . .
H84 H 0.178025 0.523514 1.047979 0.097 Uiso 1 1 calc R . . . .
C85 C 0.2308(6) 0.4572(2) 1.0688(2) 0.0894(17) Uani 1 1 d . . . . .
H85 H 0.247587 0.464611 1.100727 0.107 Uiso 1 1 calc R . . . .
C86 C 0.2470(5) 0.4101(2) 1.05175(18) 0.0796(15) Uani 1 1 d . . . . .
H86 H 0.274432 0.386375 1.073422 0.095 Uiso 1 1 calc R . . . .
C87 C 0.0372(6) 0.5780(3) 0.8883(3) 0.110(2) Uani 1 1 d . . . . .
H87 H 0.007662 0.601134 0.866393 0.132 Uiso 1 1 calc R . . . .
C88 C 0.0642(6) 0.5927(3) 0.9360(3) 0.113(2) Uani 1 1 d . . . . .
H88 H 0.053145 0.625268 0.943940 0.135 Uiso 1 1 calc R . . . .
F9A F 0.402(2) 0.3139(6) 0.7592(6) 0.150(7) Uani 0.410(17) 1 d D U P C 2
F8A F 0.5252(10) 0.3450(5) 0.7176(7) 0.144(6) Uani 0.410(17) 1 d D U P C 2
F7A F 0.3620(16) 0.3243(5) 0.6871(5) 0.129(6) Uani 0.410(17) 1 d D U P C 2
F18A F 0.5432(17) 0.3466(4) 1.1239(5) 0.122(4) Uani 0.61(2) 1 d D U P F 2
F16A F 0.6957(8) 0.3113(9) 1.0999(6) 0.188(6) Uani 0.61(2) 1 d D U P F 2
F17A F 0.5395(18) 0.2723(4) 1.1147(4) 0.133(4) Uani 0.61(2) 1 d D U P F 2
F14A F -0.042(3) 0.2866(15) 1.1236(12) 0.132(12) Uani 0.135(12) 1 d D U P E 2
F13A F 0.145(3) 0.2890(16) 1.1383(13) 0.145(13) Uani 0.135(12) 1 d D U P E 2
F15A F 0.060(4) 0.2226(6) 1.1269(11) 0.107(9) Uani 0.135(12) 1 d D U P E 2
F12A F 0.192(3) 0.1870(13) 0.8310(14) 0.136(11) Uani 0.162(13) 1 d D U P D 2
F10A F 0.360(3) 0.1886(14) 0.8157(13) 0.164(12) Uani 0.162(13) 1 d D U P D 2
F11A F 0.267(4) 0.2479(8) 0.8168(9) 0.111(8) Uani 0.162(13) 1 d D U P D 2
F3A F -0.172(4) 0.3502(15) 0.7420(9) 0.141(10) Uani 0.138(13) 1 d D U P A 2
F1A F -0.075(4) 0.3377(14) 0.6824(16) 0.158(12) Uani 0.138(13) 1 d D U P A 2
F2A F -0.231(3) 0.3796(12) 0.6763(14) 0.136(10) Uani 0.138(13) 1 d D U P A 2
F5A F 0.629(3) 0.4873(10) 0.6614(11) 0.105(6) Uani 0.29(5) 1 d D U P B 2
F6A F 0.636(3) 0.5621(10) 0.6499(17) 0.116(7) Uani 0.29(5) 1 d D U P B 2
F4A F 0.534(4) 0.5181(12) 0.6036(5) 0.090(6) Uani 0.29(5) 1 d D U P B 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.344(4) . ?
Eu1 O2 2.389(3) . ?
Eu1 O3 2.368(3) . ?
Eu1 O4 2.381(3) . ?
Eu1 O5 2.345(3) . ?
Eu1 O6 2.340(3) . ?
Eu1 N1 2.615(4) . ?
Eu1 N2 2.590(4) . ?
F1 C1 1.300(9) . ?
F2 C1 1.326(9) . ?
F3 C1 1.314(9) . ?
F4 C11 1.357(8) . ?
F5 C11 1.328(7) . ?
F6 C11 1.314(9) . ?
F7 C21 1.348(10) . ?
F8 C21 1.273(9) . ?
F9 C21 1.308(9) . ?
O1 C2 1.249(7) . ?
O2 C4 1.251(6) . ?
O3 C12 1.270(5) . ?
O4 C14 1.246(5) . ?
O5 C22 1.253(6) . ?
O6 C24 1.267(5) . ?
N1 C31 1.318(6) . ?
N1 C35 1.370(6) . ?
N2 C39 1.361(6) . ?
N2 C42 1.332(6) . ?
N3 C36 1.357(7) . ?
N3 C43 1.328(9) . ?
N4 C37 1.343(7) . ?
N4 C44 1.315(8) . ?
C1 C2 1.510(9) . ?
C1 F3A 1.299(15) . ?
C1 F1A 1.308(16) . ?
C1 F2A 1.320(16) . ?
C2 C3 1.361(8) . ?
C3 H3 0.9300 . ?
C3 C4 1.416(8) . ?
C4 C5 1.489(8) . ?
C5 C6 1.374(8) . ?
C5 C10 1.369(9) . ?
C6 H6 0.9300 . ?
C6 C7 1.368(11) . ?
C7 H7 0.9300 . ?
C7 C8 1.350(12) . ?
C8 H8 0.9300 . ?
C8 C9 1.380(11) . ?
C9 H9 0.9300 . ?
C9 C10 1.387(9) . ?
C10 H10 0.9300 . ?
C11 C12 1.507(7) . ?
C11 F5A 1.296(13) . ?
C11 F6A 1.349(13) . ?
C11 F4A 1.369(13) . ?
C12 C13 1.359(6) . ?
C13 H13 0.9300 . ?
C13 C14 1.417(6) . ?
C14 C15 1.497(6) . ?
C15 C16 1.355(7) . ?
C15 C20 1.368(7) . ?
C16 H16 0.9300 . ?
C16 C17 1.385(9) . ?
C17 H17 0.9300 . ?
C17 C18 1.348(10) . ?
C18 H18 0.9300 . ?
C18 C19 1.339(10) . ?
C19 H19 0.9300 . ?
C19 C20 1.379(8) . ?
C20 H20 0.9300 . ?
C21 C22 1.524(7) . ?
C21 F9A 1.278(12) . ?
C21 F8A 1.320(11) . ?
C21 F7A 1.243(11) . ?
C22 C23 1.367(7) . ?
C23 H23 0.9300 . ?
C23 C24 1.394(7) . ?
C24 C25 1.493(6) . ?
C25 C26 1.382(7) . ?
C25 C30 1.377(7) . ?
C26 H26 0.9300 . ?
C26 C27 1.377(8) . ?
C27 H27 0.9300 . ?
C27 C28 1.351(9) . ?
C28 H28 0.9300 . ?
C28 C29 1.380(9) . ?
C29 H29 0.9300 . ?
C29 C30 1.383(7) . ?
C30 H30 0.9300 . ?
C31 H31 0.9300 . ?
C31 C32 1.401(7) . ?
C32 H32 0.9300 . ?
C32 C33 1.386(8) . ?
C33 H33 0.9300 . ?
C33 C34 1.389(8) . ?
C34 C35 1.407(7) . ?
C34 C36 1.477(8) . ?
C35 C39 1.441(7) . ?
C36 C37 1.372(8) . ?
C37 C38 1.443(7) . ?
C38 C39 1.413(7) . ?
C38 C40 1.384(8) . ?
C40 H40 0.9300 . ?
C40 C41 1.372(8) . ?
C41 H41 0.9300 . ?
C41 C42 1.388(7) . ?
C42 H42 0.9300 . ?
C43 H43 0.9300 . ?
C43 C44 1.406(10) . ?
C44 H44 0.9300 . ?
Eu2 O7 2.385(3) . ?
Eu2 O8 2.336(4) . ?
Eu2 O9 2.361(3) . ?
Eu2 O10 2.355(3) . ?
Eu2 O11 2.378(3) . ?
Eu2 O12 2.364(3) . ?
Eu2 N5 2.608(4) . ?
Eu2 N6 2.592(4) . ?
F10 C45 1.295(7) . ?
F11 C45 1.297(8) . ?
F12 C45 1.331(7) . ?
F13 C55 1.276(8) . ?
F14 C55 1.306(7) . ?
F15 C55 1.322(7) . ?
F16 C65 1.301(10) . ?
F17 C65 1.269(12) . ?
F18 C65 1.367(11) . ?
O7 C46 1.248(6) . ?
O8 C48 1.258(6) . ?
O9 C56 1.247(6) . ?
O10 C58 1.260(5) . ?
O11 C66 1.247(6) . ?
O12 C68 1.253(5) . ?
N5 C75 1.330(6) . ?
N5 C79 1.349(6) . ?
N6 C83 1.351(6) . ?
N6 C86 1.333(6) . ?
N7 C80 1.355(7) . ?
N7 C87 1.301(9) . ?
N8 C81 1.358(7) . ?
N8 C88 1.316(8) . ?
C45 C46 1.520(8) . ?
C45 F12A 1.319(15) . ?
C45 F10A 1.265(14) . ?
C45 F11A 1.318(14) . ?
C46 C47 1.384(8) . ?
C47 H47 0.9300 . ?
C47 C48 1.397(8) . ?
C48 C49 1.503(8) . ?
C49 C50 1.385(8) . ?
C49 C54 1.346(9) . ?
C50 H50 0.9300 . ?
C50 C51 1.412(10) . ?
C51 H51 0.9300 . ?
C51 C52 1.337(12) . ?
C52 H52 0.9300 . ?
C52 C53 1.355(12) . ?
C53 H53 0.9300 . ?
C53 C54 1.390(10) . ?
C54 H54 0.9300 . ?
C55 C56 1.530(7) . ?
C55 F14A 1.293(15) . ?
C55 F13A 1.307(15) . ?
C55 F15A 1.281(15) . ?
C56 C57 1.365(7) . ?
C57 H57 0.9300 . ?
C57 C58 1.408(7) . ?
C58 C59 1.488(7) . ?
C59 C60 1.390(7) . ?
C59 C64 1.366(8) . ?
C60 H60 0.9300 . ?
C60 C61 1.392(9) . ?
C61 H61 0.9300 . ?
C61 C62 1.346(10) . ?
C62 H62 0.9300 . ?
C62 C63 1.358(10) . ?
C63 H63 0.9300 . ?
C63 C64 1.376(9) . ?
C64 H64 0.9300 . ?
C65 C66 1.538(7) . ?
C65 F18A 1.324(9) . ?
C65 F16A 1.273(10) . ?
C65 F17A 1.331(9) . ?
C66 C67 1.362(8) . ?
C67 H67 0.9300 . ?
C67 C68 1.405(7) . ?
C68 C69 1.489(7) . ?
C69 C70 1.391(7) . ?
C69 C74 1.385(7) . ?
C70 H70 0.9300 . ?
C70 C71 1.367(8) . ?
C71 H71 0.9300 . ?
C71 C72 1.349(9) . ?
C72 H72 0.9300 . ?
C72 C73 1.370(9) . ?
C73 H73 0.9300 . ?
C73 C74 1.365(8) . ?
C74 H74 0.9300 . ?
C75 H75 0.9300 . ?
C75 C76 1.394(7) . ?
C76 H76 0.9300 . ?
C76 C77 1.368(7) . ?
C77 H77 0.9300 . ?
C77 C78 1.402(7) . ?
C78 C79 1.405(6) . ?
C78 C80 1.453(7) . ?
C79 C83 1.457(6) . ?
C80 C81 1.385(7) . ?
C81 C82 1.453(7) . ?
C82 C83 1.407(7) . ?
C82 C84 1.397(7) . ?
C84 H84 0.9300 . ?
C84 C85 1.355(8) . ?
C85 H85 0.9300 . ?
C85 C86 1.392(8) . ?
C86 H86 0.9300 . ?
C87 H87 0.9300 . ?
C87 C88 1.416(10) . ?
C88 H88 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O2 70.10(13) . . ?
O1 Eu1 O3 144.87(13) . . ?
O1 Eu1 O4 143.80(13) . . ?
O1 Eu1 O5 74.65(15) . . ?
O1 Eu1 N1 71.52(14) . . ?
O1 Eu1 N2 92.62(15) . . ?
O2 Eu1 N1 119.56(12) . . ?
O2 Eu1 N2 74.53(12) . . ?
O3 Eu1 O2 144.79(11) . . ?
O3 Eu1 O4 71.20(11) . . ?
O3 Eu1 N1 81.68(12) . . ?
O3 Eu1 N2 94.78(13) . . ?
O4 Eu1 O2 73.70(11) . . ?
O4 Eu1 N1 128.71(12) . . ?
O4 Eu1 N2 77.00(12) . . ?
O5 Eu1 O2 131.80(13) . . ?
O5 Eu1 O3 77.53(13) . . ?
O5 Eu1 O4 134.01(12) . . ?
O5 Eu1 N1 76.93(12) . . ?
O5 Eu1 N2 139.46(12) . . ?
O6 Eu1 O1 101.25(14) . . ?
O6 Eu1 O2 84.15(11) . . ?
O6 Eu1 O3 89.70(12) . . ?
O6 Eu1 O4 75.39(11) . . ?
O6 Eu1 O5 71.53(11) . . ?
O6 Eu1 N1 148.41(12) . . ?
O6 Eu1 N2 148.89(12) . . ?
N2 Eu1 N1 62.55(12) . . ?
C2 O1 Eu1 135.4(4) . . ?
C4 O2 Eu1 139.0(3) . . ?
C12 O3 Eu1 130.2(3) . . ?
C14 O4 Eu1 134.4(3) . . ?
C22 O5 Eu1 135.2(3) . . ?
C24 O6 Eu1 139.2(3) . . ?
C31 N1 Eu1 122.5(3) . . ?
C31 N1 C35 117.3(4) . . ?
C35 N1 Eu1 118.6(3) . . ?
C39 N2 Eu1 119.9(3) . . ?
C42 N2 Eu1 121.3(3) . . ?
C42 N2 C39 118.0(4) . . ?
C43 N3 C36 113.7(7) . . ?
C44 N4 C37 115.8(7) . . ?
F1 C1 F2 105.3(8) . . ?
F1 C1 F3 107.2(8) . . ?
F1 C1 C2 111.6(7) . . ?
F2 C1 C2 114.5(8) . . ?
F3 C1 F2 106.2(8) . . ?
F3 C1 C2 111.5(7) . . ?
F3A C1 C2 112.6(19) . . ?
F3A C1 F1A 105.8(17) . . ?
F3A C1 F2A 105.4(16) . . ?
F1A C1 C2 120(2) . . ?
F1A C1 F2A 104.7(16) . . ?
F2A C1 C2 107.7(17) . . ?
O1 C2 C1 113.0(6) . . ?
O1 C2 C3 128.3(6) . . ?
C3 C2 C1 118.8(6) . . ?
C2 C3 H3 118.6 . . ?
C2 C3 C4 122.8(5) . . ?
C4 C3 H3 118.6 . . ?
O2 C4 C3 121.8(5) . . ?
O2 C4 C5 117.5(5) . . ?
C3 C4 C5 120.7(5) . . ?
C6 C5 C4 123.6(6) . . ?
C10 C5 C4 118.2(5) . . ?
C10 C5 C6 118.2(6) . . ?
C5 C6 H6 119.7 . . ?
C7 C6 C5 120.6(8) . . ?
C7 C6 H6 119.7 . . ?
C6 C7 H7 119.3 . . ?
C8 C7 C6 121.4(8) . . ?
C8 C7 H7 119.3 . . ?
C7 C8 H8 120.3 . . ?
C7 C8 C9 119.4(8) . . ?
C9 C8 H8 120.3 . . ?
C8 C9 H9 120.5 . . ?
C8 C9 C10 119.1(8) . . ?
C10 C9 H9 120.5 . . ?
C5 C10 C9 121.4(7) . . ?
C5 C10 H10 119.3 . . ?
C9 C10 H10 119.3 . . ?
F4 C11 C12 106.5(8) . . ?
F5 C11 F4 104.5(6) . . ?
F5 C11 C12 113.9(7) . . ?
F6 C11 F4 107.6(8) . . ?
F6 C11 F5 108.3(8) . . ?
F6 C11 C12 115.3(9) . . ?
F5A C11 C12 127.1(17) . . ?
F5A C11 F6A 103.6(12) . . ?
F5A C11 F4A 101.3(14) . . ?
F6A C11 C12 116.4(14) . . ?
F6A C11 F4A 98.5(13) . . ?
F4A C11 C12 105.3(17) . . ?
O3 C12 C11 113.0(4) . . ?
O3 C12 C13 128.5(5) . . ?
C13 C12 C11 118.5(4) . . ?
C12 C13 H13 118.3 . . ?
C12 C13 C14 123.3(4) . . ?
C14 C13 H13 118.3 . . ?
O4 C14 C13 122.7(4) . . ?
O4 C14 C15 116.7(4) . . ?
C13 C14 C15 120.5(4) . . ?
C16 C15 C14 118.5(5) . . ?
C16 C15 C20 118.0(5) . . ?
C20 C15 C14 123.4(5) . . ?
C15 C16 H16 119.9 . . ?
C15 C16 C17 120.2(7) . . ?
C17 C16 H16 119.9 . . ?
C16 C17 H17 119.3 . . ?
C18 C17 C16 121.3(7) . . ?
C18 C17 H17 119.3 . . ?
C17 C18 H18 120.7 . . ?
C19 C18 C17 118.7(7) . . ?
C19 C18 H18 120.7 . . ?
C18 C19 H19 119.5 . . ?
C18 C19 C20 120.9(7) . . ?
C20 C19 H19 119.5 . . ?
C15 C20 C19 120.8(6) . . ?
C15 C20 H20 119.6 . . ?
C19 C20 H20 119.6 . . ?
F7 C21 C22 108.6(7) . . ?
F8 C21 F7 106.0(8) . . ?
F8 C21 F9 109.1(8) . . ?
F8 C21 C22 113.5(7) . . ?
F9 C21 F7 104.5(8) . . ?
F9 C21 C22 114.4(7) . . ?
F9A C21 C22 111.0(9) . . ?
F9A C21 F8A 103.3(9) . . ?
F8A C21 C22 110.0(8) . . ?
F7A C21 C22 116.2(7) . . ?
F7A C21 F9A 110.4(10) . . ?
F7A C21 F8A 105.0(9) . . ?
O5 C22 C21 112.7(4) . . ?
O5 C22 C23 127.9(5) . . ?
C23 C22 C21 119.5(5) . . ?
C22 C23 H23 118.2 . . ?
C22 C23 C24 123.7(4) . . ?
C24 C23 H23 118.2 . . ?
O6 C24 C23 122.4(4) . . ?
O6 C24 C25 116.3(4) . . ?
C23 C24 C25 121.3(4) . . ?
C26 C25 C24 122.6(5) . . ?
C30 C25 C24 119.0(4) . . ?
C30 C25 C26 118.4(5) . . ?
C25 C26 H26 119.5 . . ?
C27 C26 C25 121.0(6) . . ?
C27 C26 H26 119.5 . . ?
C26 C27 H27 120.2 . . ?
C28 C27 C26 119.6(6) . . ?
C28 C27 H27 120.2 . . ?
C27 C28 H28 119.4 . . ?
C27 C28 C29 121.2(6) . . ?
C29 C28 H28 119.4 . . ?
C28 C29 H29 120.6 . . ?
C28 C29 C30 118.7(6) . . ?
C30 C29 H29 120.6 . . ?
C25 C30 C29 121.0(5) . . ?
C25 C30 H30 119.5 . . ?
C29 C30 H30 119.5 . . ?
N1 C31 H31 117.8 . . ?
N1 C31 C32 124.4(5) . . ?
C32 C31 H31 117.8 . . ?
C31 C32 H32 121.1 . . ?
C33 C32 C31 117.7(6) . . ?
C33 C32 H32 121.1 . . ?
C32 C33 H33 120.0 . . ?
C32 C33 C34 120.1(5) . . ?
C34 C33 H33 120.0 . . ?
C33 C34 C35 117.7(5) . . ?
C33 C34 C36 123.4(5) . . ?
C35 C34 C36 118.9(5) . . ?
N1 C35 C34 122.7(5) . . ?
N1 C35 C39 117.4(4) . . ?
C34 C35 C39 119.8(5) . . ?
N3 C36 C34 116.0(6) . . ?
N3 C36 C37 122.9(6) . . ?
C37 C36 C34 120.9(5) . . ?
N4 C37 C36 122.4(5) . . ?
N4 C37 C38 117.7(6) . . ?
C36 C37 C38 120.0(5) . . ?
C39 C38 C37 120.1(5) . . ?
C40 C38 C37 122.4(5) . . ?
C40 C38 C39 117.6(5) . . ?
N2 C39 C35 117.6(4) . . ?
N2 C39 C38 122.0(5) . . ?
C38 C39 C35 120.3(5) . . ?
C38 C40 H40 119.8 . . ?
C41 C40 C38 120.5(5) . . ?
C41 C40 H40 119.8 . . ?
C40 C41 H41 120.8 . . ?
C40 C41 C42 118.5(6) . . ?
C42 C41 H41 120.8 . . ?
N2 C42 C41 123.3(6) . . ?
N2 C42 H42 118.4 . . ?
C41 C42 H42 118.4 . . ?
N3 C43 H43 118.2 . . ?
N3 C43 C44 123.5(6) . . ?
C44 C43 H43 118.2 . . ?
N4 C44 C43 121.6(7) . . ?
N4 C44 H44 119.2 . . ?
C43 C44 H44 119.2 . . ?
O7 Eu2 N5 77.64(12) . . ?
O7 Eu2 N6 139.78(12) . . ?
O8 Eu2 O7 70.98(12) . . ?
O8 Eu2 O9 82.28(13) . . ?
O8 Eu2 O10 93.00(14) . . ?
O8 Eu2 O11 76.03(14) . . ?
O8 Eu2 O12 93.79(13) . . ?
O8 Eu2 N5 148.59(12) . . ?
O8 Eu2 N6 148.71(12) . . ?
O9 Eu2 O7 134.07(13) . . ?
O9 Eu2 O11 74.23(12) . . ?
O9 Eu2 O12 145.05(12) . . ?
O9 Eu2 N5 120.41(12) . . ?
O9 Eu2 N6 76.24(13) . . ?
O10 Eu2 O7 73.92(12) . . ?
O10 Eu2 O9 70.89(12) . . ?
O10 Eu2 O11 144.54(12) . . ?
O10 Eu2 O12 144.04(11) . . ?
O10 Eu2 N5 76.67(11) . . ?
O10 Eu2 N6 101.00(12) . . ?
O11 Eu2 O7 130.34(13) . . ?
O11 Eu2 N5 128.37(13) . . ?
O11 Eu2 N6 76.40(12) . . ?
O12 Eu2 O7 75.10(12) . . ?
O12 Eu2 O11 71.14(12) . . ?
O12 Eu2 N5 79.29(11) . . ?
O12 Eu2 N6 91.06(13) . . ?
N6 Eu2 N5 62.60(12) . . ?
C46 O7 Eu2 134.2(3) . . ?
C48 O8 Eu2 139.5(4) . . ?
C56 O9 Eu2 132.2(3) . . ?
C58 O10 Eu2 137.1(3) . . ?
C66 O11 Eu2 133.3(3) . . ?
C68 O12 Eu2 137.3(3) . . ?
C75 N5 Eu2 121.5(3) . . ?
C75 N5 C79 117.6(4) . . ?
C79 N5 Eu2 120.9(3) . . ?
C83 N6 Eu2 121.6(3) . . ?
C86 N6 Eu2 121.5(3) . . ?
C86 N6 C83 116.8(4) . . ?
C87 N7 C80 115.0(6) . . ?
C88 N8 C81 114.8(6) . . ?
F10 C45 F11 108.8(7) . . ?
F10 C45 F12 104.0(6) . . ?
F10 C45 C46 111.3(6) . . ?
F11 C45 F12 107.3(7) . . ?
F11 C45 C46 111.9(6) . . ?
F12 C45 C46 113.1(5) . . ?
F12A C45 C46 111.8(19) . . ?
F10A C45 C46 135(2) . . ?
F10A C45 F12A 97.0(18) . . ?
F10A C45 F11A 96.7(16) . . ?
F11A C45 C46 115.2(14) . . ?
F11A C45 F12A 93.1(15) . . ?
O7 C46 C45 112.6(5) . . ?
O7 C46 C47 128.6(5) . . ?
C47 C46 C45 118.8(5) . . ?
C46 C47 H47 118.8 . . ?
C46 C47 C48 122.4(5) . . ?
C48 C47 H47 118.8 . . ?
O8 C48 C47 122.7(5) . . ?
O8 C48 C49 115.9(5) . . ?
C47 C48 C49 121.4(5) . . ?
C50 C49 C48 122.1(6) . . ?
C54 C49 C48 117.7(6) . . ?
C54 C49 C50 120.2(7) . . ?
C49 C50 H50 121.1 . . ?
C49 C50 C51 117.7(7) . . ?
C51 C50 H50 121.1 . . ?
C50 C51 H51 119.3 . . ?
C52 C51 C50 121.3(8) . . ?
C52 C51 H51 119.3 . . ?
C51 C52 H52 120.0 . . ?
C51 C52 C53 120.1(9) . . ?
C53 C52 H52 120.0 . . ?
C52 C53 H53 120.0 . . ?
C52 C53 C54 120.0(10) . . ?
C54 C53 H53 120.0 . . ?
C49 C54 C53 120.5(8) . . ?
C49 C54 H54 119.7 . . ?
C53 C54 H54 119.7 . . ?
F13 C55 F14 106.4(6) . . ?
F13 C55 F15 106.4(6) . . ?
F13 C55 C56 111.7(6) . . ?
F14 C55 F15 106.0(6) . . ?
F14 C55 C56 111.5(5) . . ?
F15 C55 C56 114.3(6) . . ?
F14A C55 C56 107.4(15) . . ?
F14A C55 F13A 106.4(14) . . ?
F13A C55 C56 113.2(19) . . ?
F15A C55 C56 115.6(14) . . ?
F15A C55 F14A 108.0(14) . . ?
F15A C55 F13A 105.8(14) . . ?
O9 C56 C55 112.8(5) . . ?
O9 C56 C57 129.1(5) . . ?
C57 C56 C55 118.1(5) . . ?
C56 C57 H57 118.6 . . ?
C56 C57 C58 122.8(5) . . ?
C58 C57 H57 118.6 . . ?
O10 C58 C57 121.9(5) . . ?
O10 C58 C59 116.7(4) . . ?
C57 C58 C59 121.5(5) . . ?
C60 C59 C58 122.4(5) . . ?
C64 C59 C58 120.1(5) . . ?
C64 C59 C60 117.6(5) . . ?
C59 C60 H60 119.9 . . ?
C59 C60 C61 120.3(7) . . ?
C61 C60 H60 119.9 . . ?
C60 C61 H61 120.0 . . ?
C62 C61 C60 120.0(7) . . ?
C62 C61 H61 120.0 . . ?
C61 C62 H62 119.6 . . ?
C61 C62 C63 120.7(7) . . ?
C63 C62 H62 119.6 . . ?
C62 C63 H63 120.2 . . ?
C62 C63 C64 119.6(7) . . ?
C64 C63 H63 120.2 . . ?
C59 C64 C63 121.8(6) . . ?
C59 C64 H64 119.1 . . ?
C63 C64 H64 119.1 . . ?
F16 C65 F18 98.2(12) . . ?
F16 C65 C66 108.8(9) . . ?
F17 C65 F16 116.6(14) . . ?
F17 C65 F18 108.4(15) . . ?
F17 C65 C66 115.0(14) . . ?
F18 C65 C66 108.2(8) . . ?
F18A C65 C66 110.5(9) . . ?
F18A C65 F17A 101.6(8) . . ?
F16A C65 C66 117.4(9) . . ?
F16A C65 F18A 107.6(10) . . ?
F16A C65 F17A 107.4(8) . . ?
F17A C65 C66 111.2(6) . . ?
O11 C66 C65 113.5(5) . . ?
O11 C66 C67 128.2(5) . . ?
C67 C66 C65 118.3(5) . . ?
C66 C67 H67 118.5 . . ?
C66 C67 C68 123.0(5) . . ?
C68 C67 H67 118.5 . . ?
O12 C68 C67 123.8(5) . . ?
O12 C68 C69 116.3(4) . . ?
C67 C68 C69 119.9(5) . . ?
C70 C69 C68 122.3(5) . . ?
C74 C69 C68 119.6(5) . . ?
C74 C69 C70 118.0(5) . . ?
C69 C70 H70 120.0 . . ?
C71 C70 C69 120.1(6) . . ?
C71 C70 H70 120.0 . . ?
C70 C71 H71 119.5 . . ?
C72 C71 C70 121.0(6) . . ?
C72 C71 H71 119.5 . . ?
C71 C72 H72 120.0 . . ?
C71 C72 C73 120.0(7) . . ?
C73 C72 H72 120.0 . . ?
C72 C73 H73 120.0 . . ?
C74 C73 C72 120.1(7) . . ?
C74 C73 H73 120.0 . . ?
C69 C74 H74 119.6 . . ?
C73 C74 C69 120.8(5) . . ?
C73 C74 H74 119.6 . . ?
N5 C75 H75 117.8 . . ?
N5 C75 C76 124.4(5) . . ?
C76 C75 H75 117.8 . . ?
C75 C76 H76 121.2 . . ?
C77 C76 C75 117.7(5) . . ?
C77 C76 H76 121.2 . . ?
C76 C77 H77 119.9 . . ?
C76 C77 C78 120.2(5) . . ?
C78 C77 H77 119.9 . . ?
C77 C78 C79 117.5(5) . . ?
C77 C78 C80 122.6(5) . . ?
C79 C78 C80 119.8(4) . . ?
N5 C79 C78 122.6(4) . . ?
N5 C79 C83 117.6(4) . . ?
C78 C79 C83 119.8(4) . . ?
N7 C80 C78 117.0(5) . . ?
N7 C80 C81 122.5(5) . . ?
C81 C80 C78 120.5(5) . . ?
N8 C81 C80 122.1(5) . . ?
N8 C81 C82 117.6(5) . . ?
C80 C81 C82 120.2(5) . . ?
C83 C82 C81 119.9(5) . . ?
C84 C82 C81 122.9(5) . . ?
C84 C82 C83 117.3(5) . . ?
N6 C83 C79 117.2(4) . . ?
N6 C83 C82 123.0(4) . . ?
C82 C83 C79 119.8(4) . . ?
C82 C84 H84 119.8 . . ?
C85 C84 C82 120.4(5) . . ?
C85 C84 H84 119.8 . . ?
C84 C85 H85 120.9 . . ?
C84 C85 C86 118.2(5) . . ?
C86 C85 H85 120.9 . . ?
N6 C86 C85 124.3(5) . . ?
N6 C86 H86 117.9 . . ?
C85 C86 H86 117.9 . . ?
N7 C87 H87 118.5 . . ?
N7 C87 C88 123.1(6) . . ?
C88 C87 H87 118.5 . . ?
N8 C88 C87 122.6(7) . . ?
N8 C88 H88 118.7 . . ?
C87 C88 H88 118.7 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O1 C2 C1 163.6(5) . . . . ?
Eu1 O1 C2 C3 -16.3(10) . . . . ?
Eu1 O2 C4 C3 8.5(8) . . . . ?
Eu1 O2 C4 C5 -168.9(3) . . . . ?
Eu1 O3 C12 C11 159.3(3) . . . . ?
Eu1 O3 C12 C13 -22.4(7) . . . . ?
Eu1 O4 C14 C13 23.4(7) . . . . ?
Eu1 O4 C14 C15 -159.3(3) . . . . ?
Eu1 O5 C22 C21 179.2(4) . . . . ?
Eu1 O5 C22 C23 0.6(9) . . . . ?
Eu1 O6 C24 C23 -2.3(8) . . . . ?
Eu1 O6 C24 C25 -179.7(3) . . . . ?
Eu1 N1 C31 C32 167.3(5) . . . . ?
Eu1 N1 C35 C34 -166.4(4) . . . . ?
Eu1 N1 C35 C39 16.9(5) . . . . ?
Eu1 N2 C39 C35 -14.8(6) . . . . ?
Eu1 N2 C39 C38 168.8(4) . . . . ?
Eu1 N2 C42 C41 -171.4(5) . . . . ?
F1 C1 C2 O1 -62.8(10) . . . . ?
F1 C1 C2 C3 117.1(9) . . . . ?
F2 C1 C2 O1 177.8(9) . . . . ?
F2 C1 C2 C3 -2.4(12) . . . . ?
F3 C1 C2 O1 57.1(9) . . . . ?
F3 C1 C2 C3 -123.0(8) . . . . ?
F4 C11 C12 O3 -54.3(8) . . . . ?
F4 C11 C12 C13 127.2(8) . . . . ?
F5 C11 C12 O3 -168.9(10) . . . . ?
F5 C11 C12 C13 12.5(12) . . . . ?
F6 C11 C12 O3 65.0(10) . . . . ?
F6 C11 C12 C13 -113.5(9) . . . . ?
F7 C21 C22 O5 -65.8(10) . . . . ?
F7 C21 C22 C23 113.0(9) . . . . ?
F8 C21 C22 O5 51.9(12) . . . . ?
F8 C21 C22 C23 -129.4(11) . . . . ?
F9 C21 C22 O5 177.9(10) . . . . ?
F9 C21 C22 C23 -3.3(12) . . . . ?
O1 C2 C3 C4 0.3(10) . . . . ?
O2 C4 C5 C6 -165.6(5) . . . . ?
O2 C4 C5 C10 15.0(7) . . . . ?
O3 C12 C13 C14 -3.5(9) . . . . ?
O4 C14 C15 C16 7.9(7) . . . . ?
O4 C14 C15 C20 -171.7(5) . . . . ?
O5 C22 C23 C24 3.5(9) . . . . ?
O6 C24 C25 C26 166.3(5) . . . . ?
O6 C24 C25 C30 -11.1(6) . . . . ?
N1 C31 C32 C33 -3.6(10) . . . . ?
N1 C35 C39 N2 -1.6(7) . . . . ?
N1 C35 C39 C38 174.9(4) . . . . ?
N3 C36 C37 N4 1.0(8) . . . . ?
N3 C36 C37 C38 -177.6(5) . . . . ?
N3 C43 C44 N4 0.0(11) . . . . ?
N4 C37 C38 C39 -178.8(5) . . . . ?
N4 C37 C38 C40 -1.2(8) . . . . ?
C1 C2 C3 C4 -179.6(6) . . . . ?
C2 C3 C4 O2 3.6(9) . . . . ?
C2 C3 C4 C5 -179.1(5) . . . . ?
C3 C4 C5 C6 17.1(8) . . . . ?
C3 C4 C5 C10 -162.4(5) . . . . ?
C4 C5 C6 C7 -179.6(6) . . . . ?
C4 C5 C10 C9 178.6(6) . . . . ?
C5 C6 C7 C8 1.1(12) . . . . ?
C6 C5 C10 C9 -0.9(9) . . . . ?
C6 C7 C8 C9 -1.1(13) . . . . ?
C7 C8 C9 C10 0.1(12) . . . . ?
C8 C9 C10 C5 0.9(11) . . . . ?
C10 C5 C6 C7 -0.1(10) . . . . ?
C11 C12 C13 C14 174.8(5) . . . . ?
C12 C13 C14 O4 3.6(8) . . . . ?
C12 C13 C14 C15 -173.5(5) . . . . ?
C13 C14 C15 C16 -174.8(5) . . . . ?
C13 C14 C15 C20 5.6(7) . . . . ?
C14 C15 C16 C17 -177.2(6) . . . . ?
C14 C15 C20 C19 177.8(5) . . . . ?
C15 C16 C17 C18 -1.0(13) . . . . ?
C16 C15 C20 C19 -1.8(9) . . . . ?
C16 C17 C18 C19 -1.0(13) . . . . ?
C17 C18 C19 C20 1.6(12) . . . . ?
C18 C19 C20 C15 -0.2(11) . . . . ?
C20 C15 C16 C17 2.4(10) . . . . ?
C21 C22 C23 C24 -175.0(5) . . . . ?
C22 C23 C24 O6 -2.7(8) . . . . ?
C22 C23 C24 C25 174.5(5) . . . . ?
C23 C24 C25 C26 -11.1(7) . . . . ?
C23 C24 C25 C30 171.5(5) . . . . ?
C24 C25 C26 C27 -176.5(6) . . . . ?
C24 C25 C30 C29 178.6(5) . . . . ?
C25 C26 C27 C28 -2.2(11) . . . . ?
C26 C25 C30 C29 1.1(8) . . . . ?
C26 C27 C28 C29 1.5(12) . . . . ?
C27 C28 C29 C30 0.4(10) . . . . ?
C28 C29 C30 C25 -1.7(8) . . . . ?
C30 C25 C26 C27 0.8(9) . . . . ?
C31 N1 C35 C34 -0.6(7) . . . . ?
C31 N1 C35 C39 -177.3(5) . . . . ?
C31 C32 C33 C34 3.5(9) . . . . ?
C32 C33 C34 C35 -2.2(9) . . . . ?
C32 C33 C34 C36 175.7(5) . . . . ?
C33 C34 C35 N1 0.7(8) . . . . ?
C33 C34 C35 C39 177.3(5) . . . . ?
C33 C34 C36 N3 0.4(8) . . . . ?
C33 C34 C36 C37 -174.9(5) . . . . ?
C34 C35 C39 N2 -178.4(4) . . . . ?
C34 C35 C39 C38 -1.9(7) . . . . ?
C34 C36 C37 N4 176.0(5) . . . . ?
C34 C36 C37 C38 -2.6(8) . . . . ?
C35 N1 C31 C32 2.1(8) . . . . ?
C35 C34 C36 N3 178.3(5) . . . . ?
C35 C34 C36 C37 3.0(8) . . . . ?
C36 N3 C43 C44 1.2(10) . . . . ?
C36 C34 C35 N1 -177.3(4) . . . . ?
C36 C34 C35 C39 -0.7(7) . . . . ?
C36 C37 C38 C39 -0.1(8) . . . . ?
C36 C37 C38 C40 177.5(5) . . . . ?
C37 N4 C44 C43 -0.7(9) . . . . ?
C37 C38 C39 N2 178.7(5) . . . . ?
C37 C38 C39 C35 2.4(7) . . . . ?
C37 C38 C40 C41 -175.6(6) . . . . ?
C38 C40 C41 C42 -4.6(10) . . . . ?
C39 N2 C42 C41 -1.4(9) . . . . ?
C39 C38 C40 C41 2.0(9) . . . . ?
C40 C38 C39 N2 1.1(8) . . . . ?
C40 C38 C39 C35 -175.3(5) . . . . ?
C40 C41 C42 N2 4.4(11) . . . . ?
C42 N2 C39 C35 175.1(5) . . . . ?
C42 N2 C39 C38 -1.4(8) . . . . ?
C43 N3 C36 C34 -176.9(5) . . . . ?
C43 N3 C36 C37 -1.7(8) . . . . ?
C44 N4 C37 C36 0.2(8) . . . . ?
C44 N4 C37 C38 178.9(5) . . . . ?
Eu2 O7 C46 C45 -176.3(4) . . . . ?
Eu2 O7 C46 C47 1.7(9) . . . . ?
Eu2 O8 C48 C47 -18.3(9) . . . . ?
Eu2 O8 C48 C49 158.8(4) . . . . ?
Eu2 O9 C56 C55 162.2(4) . . . . ?
Eu2 O9 C56 C57 -18.4(8) . . . . ?
Eu2 O10 C58 C57 21.3(8) . . . . ?
Eu2 O10 C58 C59 -158.1(4) . . . . ?
Eu2 O11 C66 C65 -162.1(4) . . . . ?
Eu2 O11 C66 C67 18.7(9) . . . . ?
Eu2 O12 C68 C67 -9.4(9) . . . . ?
Eu2 O12 C68 C69 170.3(3) . . . . ?
Eu2 N5 C75 C76 178.6(4) . . . . ?
Eu2 N5 C79 C78 -177.9(3) . . . . ?
Eu2 N5 C79 C83 1.6(5) . . . . ?
Eu2 N6 C83 C79 -0.2(5) . . . . ?
Eu2 N6 C83 C82 -179.5(3) . . . . ?
Eu2 N6 C86 C85 179.5(5) . . . . ?
F10 C45 C46 O7 65.9(8) . . . . ?
F10 C45 C46 C47 -112.4(8) . . . . ?
F11 C45 C46 O7 -56.1(9) . . . . ?
F11 C45 C46 C47 125.6(8) . . . . ?
F12 C45 C46 O7 -177.5(6) . . . . ?
F12 C45 C46 C47 4.2(9) . . . . ?
F13 C55 C56 O9 -57.7(8) . . . . ?
F13 C55 C56 C57 122.9(7) . . . . ?
F14 C55 C56 O9 61.2(8) . . . . ?
F14 C55 C56 C57 -118.2(7) . . . . ?
F15 C55 C56 O9 -178.6(7) . . . . ?
F15 C55 C56 C57 1.9(9) . . . . ?
F16 C65 C66 O11 100.4(16) . . . . ?
F16 C65 C66 C67 -80.3(16) . . . . ?
F17 C65 C66 O11 -32.5(18) . . . . ?
F17 C65 C66 C67 146.9(18) . . . . ?
F18 C65 C66 O11 -153.9(9) . . . . ?
F18 C65 C66 C67 25.5(11) . . . . ?
O7 C46 C47 C48 0.2(9) . . . . ?
O8 C48 C49 C50 163.1(5) . . . . ?
O8 C48 C49 C54 -19.3(8) . . . . ?
O9 C56 C57 C58 -0.2(9) . . . . ?
O10 C58 C59 C60 -170.5(5) . . . . ?
O10 C58 C59 C64 10.6(8) . . . . ?
O11 C66 C67 C68 -2.0(10) . . . . ?
O12 C68 C69 C70 153.8(5) . . . . ?
O12 C68 C69 C74 -26.8(7) . . . . ?
N5 C75 C76 C77 -0.6(7) . . . . ?
N5 C79 C83 N6 -0.9(6) . . . . ?
N5 C79 C83 C82 178.4(4) . . . . ?
N7 C80 C81 N8 -0.1(8) . . . . ?
N7 C80 C81 C82 178.9(5) . . . . ?
N7 C87 C88 N8 -1.2(12) . . . . ?
N8 C81 C82 C83 -179.8(4) . . . . ?
N8 C81 C82 C84 0.8(7) . . . . ?
C45 C46 C47 C48 178.1(5) . . . . ?
C46 C47 C48 O8 7.1(9) . . . . ?
C46 C47 C48 C49 -169.9(5) . . . . ?
C47 C48 C49 C50 -19.8(8) . . . . ?
C47 C48 C49 C54 157.9(6) . . . . ?
C48 C49 C50 C51 177.5(5) . . . . ?
C48 C49 C54 C53 -174.6(8) . . . . ?
C49 C50 C51 C52 -2.3(11) . . . . ?
C50 C49 C54 C53 3.1(13) . . . . ?
C50 C51 C52 C53 1.8(16) . . . . ?
C51 C52 C53 C54 1.2(18) . . . . ?
C52 C53 C54 C49 -3.7(17) . . . . ?
C54 C49 C50 C51 -0.2(9) . . . . ?
C55 C56 C57 C58 179.1(5) . . . . ?
C56 C57 C58 O10 -0.3(8) . . . . ?
C56 C57 C58 C59 179.1(5) . . . . ?
C57 C58 C59 C60 10.1(8) . . . . ?
C57 C58 C59 C64 -168.7(6) . . . . ?
C58 C59 C60 C61 -179.5(6) . . . . ?
C58 C59 C64 C63 178.2(7) . . . . ?
C59 C60 C61 C62 1.9(13) . . . . ?
C60 C59 C64 C63 -0.7(11) . . . . ?
C60 C61 C62 C63 -1.8(15) . . . . ?
C61 C62 C63 C64 0.4(16) . . . . ?
C62 C63 C64 C59 0.8(14) . . . . ?
C64 C59 C60 C61 -0.6(10) . . . . ?
C65 C66 C67 C68 178.8(5) . . . . ?
C66 C67 C68 O12 -3.0(9) . . . . ?
C66 C67 C68 C69 177.2(5) . . . . ?
C67 C68 C69 C70 -26.4(8) . . . . ?
C67 C68 C69 C74 153.0(5) . . . . ?
C68 C69 C70 C71 -177.4(6) . . . . ?
C68 C69 C74 C73 179.4(6) . . . . ?
C69 C70 C71 C72 -3.5(12) . . . . ?
C70 C69 C74 C73 -1.2(9) . . . . ?
C70 C71 C72 C73 1.7(13) . . . . ?
C71 C72 C73 C74 0.4(13) . . . . ?
C72 C73 C74 C69 -0.6(11) . . . . ?
C74 C69 C70 C71 3.2(9) . . . . ?
C75 N5 C79 C78 1.1(6) . . . . ?
C75 N5 C79 C83 -179.5(4) . . . . ?
C75 C76 C77 C78 0.7(7) . . . . ?
C76 C77 C78 C79 -0.1(7) . . . . ?
C76 C77 C78 C80 178.1(4) . . . . ?
C77 C78 C79 N5 -0.8(6) . . . . ?
C77 C78 C79 C83 179.7(4) . . . . ?
C77 C78 C80 N7 1.6(7) . . . . ?
C77 C78 C80 C81 -177.6(4) . . . . ?
C78 C79 C83 N6 178.6(4) . . . . ?
C78 C79 C83 C82 -2.1(6) . . . . ?
C78 C80 C81 N8 179.1(5) . . . . ?
C78 C80 C81 C82 -1.9(7) . . . . ?
C79 N5 C75 C76 -0.3(7) . . . . ?
C79 C78 C80 N7 179.8(4) . . . . ?
C79 C78 C80 C81 0.6(7) . . . . ?
C80 N7 C87 C88 -0.1(10) . . . . ?
C80 C78 C79 N5 -179.1(4) . . . . ?
C80 C78 C79 C83 1.4(6) . . . . ?
C80 C81 C82 C83 1.2(7) . . . . ?
C80 C81 C82 C84 -178.3(5) . . . . ?
C81 N8 C88 C87 1.8(10) . . . . ?
C81 C82 C83 N6 -179.9(4) . . . . ?
C81 C82 C83 C79 0.8(6) . . . . ?
C81 C82 C84 C85 179.7(5) . . . . ?
C82 C84 C85 C86 -0.3(9) . . . . ?
C83 N6 C86 C85 -0.7(8) . . . . ?
C83 C82 C84 C85 0.2(8) . . . . ?
C84 C82 C83 N6 -0.4(7) . . . . ?
C84 C82 C83 C79 -179.7(4) . . . . ?
C84 C85 C86 N6 0.5(10) . . . . ?
C86 N6 C83 C79 179.9(4) . . . . ?
C86 N6 C83 C82 0.6(7) . . . . ?
C87 N7 C80 C78 -178.5(5) . . . . ?
C87 N7 C80 C81 0.7(8) . . . . ?
C88 N8 C81 C80 -1.1(8) . . . . ?
C88 N8 C81 C82 179.8(5) . . . . ?
F9A C21 C22 O5 -132.4(12) . . . . ?
F9A C21 C22 C23 46.4(13) . . . . ?
F8A C21 C22 O5 114.0(11) . . . . ?
F8A C21 C22 C23 -67.3(12) . . . . ?
F7A C21 C22 O5 -5.1(13) . . . . ?
F7A C21 C22 C23 173.6(12) . . . . ?
F18A C65 C66 O11 -58.3(10) . . . . ?
F18A C65 C66 C67 121.0(9) . . . . ?
F16A C65 C66 O11 177.9(13) . . . . ?
F16A C65 C66 C67 -2.7(15) . . . . ?
F17A C65 C66 O11 53.8(12) . . . . ?
F17A C65 C66 C67 -126.9(11) . . . . ?
F14A C55 C56 O9 119(2) . . . . ?
F14A C55 C56 C57 -60(2) . . . . ?
F13A C55 C56 O9 2(2) . . . . ?
F13A C55 C56 C57 -177(2) . . . . ?
F15A C55 C56 O9 -120(2) . . . . ?
F15A C55 C56 C57 60(2) . . . . ?
F12A C45 C46 O7 -95(2) . . . . ?
F12A C45 C46 C47 86(2) . . . . ?
F10A C45 C46 O7 139(3) . . . . ?
F10A C45 C46 C47 -39(3) . . . . ?
F11A C45 C46 O7 9(2) . . . . ?
F11A C45 C46 C47 -169(2) . . . . ?
F3A C1 C2 O1 119(2) . . . . ?
F3A C1 C2 C3 -61(3) . . . . ?
F1A C1 C2 O1 -6(3) . . . . ?
F1A C1 C2 C3 174(3) . . . . ?
F2A C1 C2 O1 -125(2) . . . . ?
F2A C1 C2 C3 55(2) . . . . ?
F5A C11 C12 O3 -65(2) . . . . ?
F5A C11 C12 C13 116.9(19) . . . . ?
F6A C11 C12 O3 161(3) . . . . ?
F6A C11 C12 C13 -18(3) . . . . ?
F4A C11 C12 O3 52.9(17) . . . . ?
F4A C11 C12 C13 -125.7(16) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
