# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_002
_database_code_depnum_ccdc_archive 'CCDC 2145472'
loop_
_audit_author_name
_audit_author_address
'Jiazheng ZHOU'
;Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences
China
;
_audit_update_record             
;
2022-01-30 deposited with the CCDC.	2022-02-23 downloaded from the CCDC.
;
_audit_creation_date             2022-01-21
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'Ga8 Na4 S14'
_chemical_formula_sum            'Ga8 Na4 S14'
_chemical_formula_weight         1098.56
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   13.5260(4)
_cell_length_b                   11.4979(3)
_cell_length_c                   29.9592(9)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     4659.3(2)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    6992
_cell_measurement_temperature    302.0
_cell_measurement_theta_max      25.279
_cell_measurement_theta_min      2.72
_shelx_estimated_absorpt_T_max   0.533
_shelx_estimated_absorpt_T_min   0.273
_exptl_absorpt_coefficient_mu    10.424
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.5950
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1135 before and 0.0679 after correction. The Ratio of minimum to maximum transmission is 0.7980. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    3.132
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       irregular
_exptl_crystal_F_000             4128
_exptl_crystal_size_max          0.168
_exptl_crystal_size_mid          0.138
_exptl_crystal_size_min          0.069
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0730
_diffrn_reflns_av_unetI/netI     0.0447
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       38
_diffrn_reflns_limit_l_min       -38
_diffrn_reflns_number            44194
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.509
_diffrn_reflns_theta_min         2.029
_diffrn_ambient_temperature      302.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4374
_reflns_number_total             5331
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2015)'
_refine_diff_density_max         0.672
_refine_diff_density_min         -0.758
_refine_diff_density_rms         0.174
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.073
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     235
_refine_ls_number_reflns         5331
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0404
_refine_ls_R_factor_gt           0.0297
_refine_ls_restrained_S_all      1.073
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0143P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0522
_refine_ls_wR_factor_ref         0.0556
_refine_special_details          ?
_olex2_refinement_description    
;
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ga1 Ga 0.58186(3) 0.63561(4) 0.58265(2) 0.01308(10) Uani 1 1 d . . . . .
Ga2 Ga 0.35634(3) 0.55447(4) 0.63774(2) 0.01324(10) Uani 1 1 d . . . . .
Ga5 Ga 0.14841(3) 0.37888(4) 0.37499(2) 0.01382(10) Uani 1 1 d . . . . .
Ga8 Ga 0.40075(3) 0.37999(4) 0.16949(2) 0.01334(10) Uani 1 1 d . . . . .
Ga7 Ga 0.19748(3) 0.16133(4) 0.18388(2) 0.01328(10) Uani 1 1 d . . . . .
Ga6 Ga 0.22056(3) 0.40458(4) 0.25372(2) 0.01357(10) Uani 1 1 d . . . . .
Ga3 Ga 0.35835(3) 0.59757(4) 0.52582(2) 0.01549(10) Uani 1 1 d . . . . .
Ga4 Ga 0.21877(3) 0.61226(4) 0.44474(2) 0.01430(10) Uani 1 1 d . . . . .
S8 S 0.21262(7) 0.75482(9) 0.39047(3) 0.0136(2) Uani 1 1 d . . . . .
S3 S 0.24021(7) 0.70147(9) 0.63497(3) 0.0130(2) Uani 1 1 d . . . . .
S13 S 0.33400(7) 0.05082(9) 0.20285(3) 0.0133(2) Uani 1 1 d . . . . .
S9 S 0.02111(7) 0.26112(9) 0.35746(3) 0.0141(2) Uani 1 1 d . . . . .
S1 S 0.62087(7) 0.45755(9) 0.55118(3) 0.0148(2) Uani 1 1 d . . . . .
S10 S 0.20236(7) 0.49773(9) 0.32005(3) 0.0163(2) Uani 1 1 d . . . . .
S14 S 0.41608(7) 0.56305(9) 0.14372(3) 0.0168(2) Uani 1 1 d . . . . .
S5 S 0.48100(7) 0.72827(9) 0.53499(3) 0.0165(2) Uani 1 1 d . . . . .
S12 S 0.12844(7) 0.24391(9) 0.24387(3) 0.0170(2) Uani 1 1 d . . . . .
S4 S 0.33673(8) 0.45188(9) 0.57428(3) 0.0175(2) Uani 1 1 d . . . . .
S2 S 0.51076(7) 0.61284(9) 0.64905(3) 0.0161(2) Uani 1 1 d . . . . .
S11 S 0.38370(7) 0.37658(10) 0.24397(3) 0.0172(2) Uani 1 1 d . . . . .
S7 S 0.10463(8) 0.47314(9) 0.43787(3) 0.0183(2) Uani 1 1 d . . . . .
S6 S 0.21303(8) 0.68817(11) 0.51352(3) 0.0233(2) Uani 1 1 d . . . . .
Na1 Na -0.03645(13) 0.22920(17) 0.44482(5) 0.0305(4) Uani 1 1 d . . . . .
Na3 Na 0.56832(13) 0.81499(17) 0.69629(6) 0.0358(5) Uani 1 1 d . . . . .
Na4 Na 0.59339(15) 0.42688(16) 0.69242(6) 0.0353(5) Uani 1 1 d . . . . .
Na2 Na 0.37125(16) 0.9360(2) 0.54892(7) 0.0487(6) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ga1 S8 2.3159(10) 4_566 ?
Ga1 S1 2.3149(11) . ?
Ga1 S5 2.2440(10) . ?
Ga1 S2 2.2248(10) . ?
Ga2 S3 2.3089(11) . ?
Ga2 S13 2.3156(10) 7_566 ?
Ga2 S4 2.2532(10) . ?
Ga2 S2 2.2198(11) . ?
Ga5 S8 2.4049(10) 8_655 ?
Ga5 S9 2.2526(11) . ?
Ga5 S10 2.2603(10) . ?
Ga5 S7 2.2527(10) . ?
Ga8 S3 2.3626(10) 2_564 ?
Ga8 S9 2.2738(10) 6_656 ?
Ga8 S14 2.2515(11) . ?
Ga8 S11 2.2436(10) . ?
Ga7 S3 2.3120(10) 2_564 ?
Ga7 S13 2.3123(10) . ?
Ga7 S14 2.2547(11) 8_655 ?
Ga7 S12 2.2369(10) . ?
Ga6 S13 2.3863(10) 8_665 ?
Ga6 S10 2.2707(10) . ?
Ga6 S12 2.2478(11) . ?
Ga6 S11 2.2489(11) . ?
Ga6 Na4 3.5625(19) 5_666 ?
Ga3 S1 2.4089(10) 5_666 ?
Ga3 S5 2.2552(11) . ?
Ga3 S4 2.2359(11) . ?
Ga3 S6 2.2548(11) . ?
Ga4 S8 2.3102(10) . ?
Ga4 S1 2.3160(11) 5_666 ?
Ga4 S7 2.2326(11) . ?
Ga4 S6 2.2394(11) . ?
S8 Na3 3.348(2) 4_466 ?
S13 Na4 3.532(2) 7_565 ?
S9 Na1 2.7553(19) . ?
S9 Na4 2.804(2) 4_456 ?
S1 Na1 3.025(2) 4_556 ?
S10 Na3 2.857(2) 4_466 ?
S10 Na4 2.920(2) 5_666 ?
S14 Na3 2.947(2) 7_575 ?
S14 Na2 2.904(2) 7_575 ?
S5 Na1 2.8035(19) 8_665 ?
S5 Na2 2.843(2) . ?
S12 Na3 3.094(2) 2_564 ?
S12 Na4 2.779(2) 4_456 ?
S4 Na1 2.758(2) 4_556 ?
S4 Na2 2.920(2) 8_655 ?
S2 Na3 2.831(2) . ?
S2 Na4 2.740(2) . ?
S11 Na3 2.911(2) 5_666 ?
S11 Na4 2.972(2) 5_666 ?
S7 Na1 3.399(2) . ?
S7 Na2 3.348(3) 4_466 ?
S7 Na2 3.370(2) 8_655 ?
S6 Na1 2.857(2) 5_566 ?
S6 Na2 3.291(2) 8_655 ?
Na1 Na2 4.051(3) 4_466 ?
Na3 Na4 4.190(3) 3_656 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S1 Ga1 S8 116.66(4) . 4_566 ?
S5 Ga1 S8 115.29(4) . 4_566 ?
S5 Ga1 S1 107.41(4) . . ?
S2 Ga1 S8 94.77(4) . 4_566 ?
S2 Ga1 S1 111.01(4) . . ?
S2 Ga1 S5 111.23(4) . . ?
S3 Ga2 S13 108.91(4) . 7_566 ?
S4 Ga2 S3 105.83(4) . . ?
S4 Ga2 S13 114.94(4) . 7_566 ?
S2 Ga2 S3 115.11(4) . . ?
S2 Ga2 S13 98.76(4) . 7_566 ?
S2 Ga2 S4 113.44(4) . . ?
S9 Ga5 S8 106.62(4) . 8_655 ?
S9 Ga5 S10 116.13(4) . . ?
S9 Ga5 S7 106.45(4) . . ?
S10 Ga5 S8 104.28(4) . 8_655 ?
S7 Ga5 S8 109.24(4) . 8_655 ?
S7 Ga5 S10 113.77(4) . . ?
S9 Ga8 S3 100.61(4) 6_656 2_564 ?
S14 Ga8 S3 107.14(4) . 2_564 ?
S14 Ga8 S9 111.97(4) . 6_656 ?
S11 Ga8 S3 110.21(4) . 2_564 ?
S11 Ga8 S9 114.60(4) . 6_656 ?
S11 Ga8 S14 111.53(4) . . ?
S3 Ga7 S13 103.86(4) 2_564 . ?
S14 Ga7 S3 104.61(4) 8_655 2_564 ?
S14 Ga7 S13 113.57(4) 8_655 . ?
S12 Ga7 S3 111.82(4) . 2_564 ?
S12 Ga7 S13 111.66(4) . . ?
S12 Ga7 S14 110.92(4) . 8_655 ?
S13 Ga6 Na4 97.15(4) 8_665 5_666 ?
S10 Ga6 S13 101.13(4) . 8_665 ?
S10 Ga6 Na4 54.81(4) . 5_666 ?
S12 Ga6 S13 108.89(4) . 8_665 ?
S12 Ga6 S10 116.26(4) . . ?
S12 Ga6 S11 114.15(4) . . ?
S12 Ga6 Na4 153.91(4) . 5_666 ?
S11 Ga6 S13 108.75(4) . 8_665 ?
S11 Ga6 S10 106.71(4) . . ?
S11 Ga6 Na4 56.19(4) . 5_666 ?
S5 Ga3 S1 101.89(4) . 5_666 ?
S4 Ga3 S1 116.10(4) . 5_666 ?
S4 Ga3 S5 121.09(4) . . ?
S4 Ga3 S6 109.77(4) . . ?
S6 Ga3 S1 93.83(4) . 5_666 ?
S6 Ga3 S5 110.69(4) . . ?
S8 Ga4 S1 108.47(4) . 5_666 ?
S7 Ga4 S8 114.75(4) . . ?
S7 Ga4 S1 113.84(4) . 5_666 ?
S7 Ga4 S6 109.88(4) . . ?
S6 Ga4 S8 111.71(4) . . ?
S6 Ga4 S1 96.83(4) . 5_666 ?
Ga1 S8 Ga5 109.96(4) 4_466 8_665 ?
Ga1 S8 Na3 87.43(4) 4_466 4_466 ?
Ga5 S8 Na3 116.63(5) 8_665 4_466 ?
Ga4 S8 Ga1 99.71(4) . 4_466 ?
Ga4 S8 Ga5 121.90(4) . 8_665 ?
Ga4 S8 Na3 113.41(5) . 4_466 ?
Ga2 S3 Ga8 104.07(4) . 2_565 ?
Ga2 S3 Ga7 103.22(4) . 2_565 ?
Ga7 S3 Ga8 106.69(4) 2_565 2_565 ?
Ga2 S13 Ga6 102.12(4) 7_565 8_655 ?
Ga2 S13 Na4 80.43(4) 7_565 7_565 ?
Ga7 S13 Ga2 100.63(4) . 7_565 ?
Ga7 S13 Ga6 107.29(4) . 8_655 ?
Ga7 S13 Na4 137.03(5) . 7_565 ?
Ga6 S13 Na4 114.51(5) 8_655 7_565 ?
Ga5 S9 Ga8 105.59(4) . 6_556 ?
Ga5 S9 Na1 94.28(5) . . ?
Ga5 S9 Na4 108.73(6) . 4_456 ?
Ga8 S9 Na1 102.42(5) 6_556 . ?
Ga8 S9 Na4 121.59(6) 6_556 4_456 ?
Na1 S9 Na4 120.14(6) . 4_456 ?
Ga1 S1 Ga3 130.49(5) . 5_666 ?
Ga1 S1 Ga4 119.90(4) . 5_666 ?
Ga1 S1 Na1 116.82(5) . 4_556 ?
Ga3 S1 Na1 86.17(4) 5_666 4_556 ?
Ga4 S1 Ga3 81.38(3) 5_666 5_666 ?
Ga4 S1 Na1 114.25(5) 5_666 4_556 ?
Ga5 S10 Ga6 112.78(5) . . ?
Ga5 S10 Na3 112.06(5) . 4_466 ?
Ga5 S10 Na4 125.32(5) . 5_666 ?
Ga6 S10 Na3 105.93(5) . 4_466 ?
Ga6 S10 Na4 85.73(5) . 5_666 ?
Na3 S10 Na4 110.78(6) 4_466 5_666 ?
Ga8 S14 Ga7 102.87(4) . 8_665 ?
Ga8 S14 Na3 109.02(5) . 7_575 ?
Ga8 S14 Na2 108.64(6) . 7_575 ?
Ga7 S14 Na3 87.27(5) 8_665 7_575 ?
Ga7 S14 Na2 112.20(6) 8_665 7_575 ?
Na2 S14 Na3 131.81(7) 7_575 7_575 ?
Ga1 S5 Ga3 102.02(4) . . ?
Ga1 S5 Na1 116.89(6) . 8_665 ?
Ga1 S5 Na2 128.52(6) . . ?
Ga3 S5 Na1 94.71(5) . 8_665 ?
Ga3 S5 Na2 101.17(6) . . ?
Na1 S5 Na2 106.14(6) 8_665 . ?
Ga7 S12 Ga6 102.88(4) . . ?
Ga7 S12 Na3 84.03(5) . 2_564 ?
Ga7 S12 Na4 108.85(6) . 4_456 ?
Ga6 S12 Na3 135.82(6) . 2_564 ?
Ga6 S12 Na4 125.81(6) . 4_456 ?
Na4 S12 Na3 90.86(6) 4_456 2_564 ?
Ga2 S4 Na1 119.81(5) . 4_556 ?
Ga2 S4 Na2 111.45(6) . 8_655 ?
Ga3 S4 Ga2 98.06(4) . . ?
Ga3 S4 Na1 110.46(5) . 4_556 ?
Ga3 S4 Na2 90.22(5) . 8_655 ?
Na1 S4 Na2 119.88(7) 4_556 8_655 ?
Ga1 S2 Na3 103.39(5) . . ?
Ga1 S2 Na4 109.85(6) . . ?
Ga2 S2 Ga1 107.81(4) . . ?
Ga2 S2 Na3 125.69(6) . . ?
Ga2 S2 Na4 102.72(6) . . ?
Na4 S2 Na3 106.94(6) . . ?
Ga8 S11 Ga6 103.15(4) . . ?
Ga8 S11 Na3 126.99(6) . 5_666 ?
Ga8 S11 Na4 127.85(6) . 5_666 ?
Ga6 S11 Na3 104.31(5) . 5_666 ?
Ga6 S11 Na4 84.85(5) . 5_666 ?
Na3 S11 Na4 99.08(6) 5_666 5_666 ?
Ga5 S7 Na1 78.57(4) . . ?
Ga5 S7 Na2 119.78(5) . 4_466 ?
Ga5 S7 Na2 137.67(6) . 8_655 ?
Ga4 S7 Ga5 103.88(4) . . ?
Ga4 S7 Na1 166.87(5) . . ?
Ga4 S7 Na2 114.68(5) . 4_466 ?
Ga4 S7 Na2 86.15(5) . 8_655 ?
Na2 S7 Na1 73.79(5) 4_466 . ?
Na2 S7 Na1 83.65(5) 8_655 . ?
Na2 S7 Na2 90.81(6) 4_466 8_655 ?
Ga3 S6 Na1 144.18(6) . 5_566 ?
Ga3 S6 Na2 80.93(5) . 8_655 ?
Ga4 S6 Ga3 86.57(4) . . ?
Ga4 S6 Na1 124.09(5) . 5_566 ?
Ga4 S6 Na2 88.01(5) . 8_655 ?
Na1 S6 Na2 82.10(6) 5_566 8_655 ?
S9 Na1 S1 86.18(5) . 4_456 ?
S9 Na1 S5 147.16(8) . 8_655 ?
S9 Na1 S4 94.54(6) . 4_456 ?
S9 Na1 S7 70.93(5) . . ?
S9 Na1 S6 127.36(7) . 5_566 ?
S9 Na1 Na2 90.26(6) . 4_466 ?
S1 Na1 S7 101.14(6) 4_456 . ?
S1 Na1 Na2 152.79(7) 4_456 4_466 ?
S5 Na1 S1 76.76(5) 8_655 4_456 ?
S5 Na1 S7 84.95(5) 8_655 . ?
S5 Na1 S6 78.70(5) 8_655 5_566 ?
S5 Na1 Na2 92.38(6) 8_655 4_466 ?
S4 Na1 S1 84.83(6) 4_456 4_456 ?
S4 Na1 S5 111.32(7) 4_456 8_655 ?
S4 Na1 S7 163.65(7) 4_456 . ?
S4 Na1 S6 79.73(6) 4_456 5_566 ?
S4 Na1 Na2 122.36(6) 4_456 4_466 ?
S7 Na1 Na2 52.53(4) . 4_466 ?
S6 Na1 S1 143.77(7) 5_566 4_456 ?
S6 Na1 S7 102.81(6) 5_566 . ?
S6 Na1 Na2 53.57(5) 5_566 4_466 ?
S8 Na3 Na4 174.68(7) 4_566 3_656 ?
S10 Na3 S8 71.21(5) 4_566 4_566 ?
S10 Na3 S14 89.61(6) 4_566 7_576 ?
S10 Na3 S12 142.16(8) 4_566 2_565 ?
S10 Na3 S11 122.28(7) 4_566 5_666 ?
S10 Na3 Na4 103.66(6) 4_566 3_656 ?
S14 Na3 S8 96.11(6) 7_576 4_566 ?
S14 Na3 S12 75.48(5) 7_576 2_565 ?
S14 Na3 Na4 85.09(5) 7_576 3_656 ?
S12 Na3 S8 143.76(7) 2_565 4_566 ?
S12 Na3 Na4 41.55(4) 2_565 3_656 ?
S2 Na3 S8 64.87(5) . 4_566 ?
S2 Na3 S10 135.05(8) . 4_566 ?
S2 Na3 S14 86.06(6) . 7_576 ?
S2 Na3 S12 79.28(5) . 2_565 ?
S2 Na3 S11 75.37(5) . 5_666 ?
S2 Na3 Na4 120.43(6) . 3_656 ?
S11 Na3 S8 99.55(6) 5_666 4_566 ?
S11 Na3 S14 147.58(7) 5_666 7_576 ?
S11 Na3 S12 75.11(5) 5_666 2_565 ?
S11 Na3 Na4 81.92(5) 5_666 3_656 ?
Ga6 Na4 Na3 100.10(5) 5_666 3_646 ?
S13 Na4 Ga6 128.48(6) 7_566 5_666 ?
S13 Na4 Na3 55.48(4) 7_566 3_646 ?
S9 Na4 Ga6 155.10(7) 4_556 5_666 ?
S9 Na4 S13 75.92(5) 4_556 7_566 ?
S9 Na4 S10 119.39(8) 4_556 5_666 ?
S9 Na4 S11 164.63(8) 4_556 5_666 ?
S9 Na4 Na3 90.30(6) 4_556 3_646 ?
S10 Na4 Ga6 39.47(3) 5_666 5_666 ?
S10 Na4 S13 158.41(7) 5_666 7_566 ?
S10 Na4 S11 75.97(5) 5_666 5_666 ?
S10 Na4 Na3 133.39(6) 5_666 3_646 ?
S12 Na4 Ga6 87.29(5) 4_556 5_666 ?
S12 Na4 S13 99.21(6) 4_556 7_566 ?
S12 Na4 S9 83.15(6) 4_556 4_556 ?
S12 Na4 S10 97.83(6) 4_556 5_666 ?
S12 Na4 S11 94.54(6) 4_556 5_666 ?
S12 Na4 Na3 47.59(4) 4_556 3_646 ?
S2 Na4 Ga6 94.50(6) . 5_666 ?
S2 Na4 S13 65.18(5) . 7_566 ?
S2 Na4 S9 101.92(6) . 4_556 ?
S2 Na4 S10 95.37(6) . 5_666 ?
S2 Na4 S12 161.18(9) . 4_556 ?
S2 Na4 S11 75.72(6) . 5_666 ?
S2 Na4 Na3 113.83(7) . 3_646 ?
S11 Na4 Ga6 38.96(3) 5_666 5_666 ?
S11 Na4 S13 89.52(6) 5_666 7_566 ?
S11 Na4 Na3 77.16(5) 5_666 3_646 ?
S14 Na2 S4 86.93(6) 7_576 8_665 ?
S14 Na2 S7 71.73(6) 7_576 4_566 ?
S14 Na2 S7 160.87(9) 7_576 8_665 ?
S14 Na2 S6 112.60(7) 7_576 8_665 ?
S14 Na2 Na1 83.51(6) 7_576 4_566 ?
S5 Na2 S14 92.16(6) . 7_576 ?
S5 Na2 S4 126.42(9) . 8_665 ?
S5 Na2 S7 84.89(6) . 8_665 ?
S5 Na2 S7 77.71(6) . 4_566 ?
S5 Na2 S6 150.89(8) . 8_665 ?
S5 Na2 Na1 130.11(8) . 4_566 ?
S4 Na2 S7 110.02(7) 8_665 8_665 ?
S4 Na2 S7 149.11(8) 8_665 4_566 ?
S4 Na2 S6 72.25(5) 8_665 8_665 ?
S4 Na2 Na1 103.04(6) 8_665 4_566 ?
S7 Na2 S7 89.20(6) 4_566 8_665 ?
S7 Na2 Na1 84.01(6) 8_665 4_566 ?
S7 Na2 Na1 53.68(5) 4_566 4_566 ?
S6 Na2 S7 66.66(5) 8_665 8_665 ?
S6 Na2 S7 95.16(7) 8_665 4_566 ?
S6 Na2 Na1 44.32(4) 8_665 4_566 ?


_olex2_submission_special_instructions 'No special instructions were received'
