# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_0916_sq
_database_code_depnum_ccdc_archive 'CCDC 2145057'
loop_
_audit_author_name
_audit_author_address
'Jian-Jun Liu'
;Qujing Normal University
China
;
_audit_update_record             
;
2022-01-28 deposited with the CCDC.	2022-04-28 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C45 H25 Eu N4 O13'
_chemical_formula_sum            'C45 H25 Eu N4 O13'
_chemical_formula_weight         981.65

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      tetragonal
_space_group_IT_number           88
_space_group_name_H-M_alt        'I 41/a'
_space_group_name_Hall           '-I 4ad'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y+3/4, x+1/4, z+1/4'
'-x, -y+1/2, z'
'y+1/4, -x+1/4, z+1/4'
'x+1/2, y+1/2, z+1/2'
'-y+5/4, x+3/4, z+3/4'
'-x+1/2, -y+1, z+1/2'
'y+3/4, -x+3/4, z+3/4'
'-x, -y, -z'
'y-3/4, -x-1/4, -z-1/4'
'x, y-1/2, -z'
'-y-1/4, x-1/4, -z-1/4'
'-x+1/2, -y+1/2, -z+1/2'
'y-1/4, -x+1/4, -z+1/4'
'x+1/2, y, -z+1/2'
'-y+1/4, x+1/4, -z+1/4'

_cell_length_a                   38.2925(7)
_cell_length_b                   38.2925(7)
_cell_length_c                   16.4164(4)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     24071.6(11)
_cell_formula_units_Z            16
_cell_measurement_temperature    153(2)
_cell_measurement_reflns_used    23247
_cell_measurement_theta_min      1.72
_cell_measurement_theta_max      24.71

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.083
_exptl_crystal_F_000             7840
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_exptl_absorpt_coefficient_mu    1.092
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.99006
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   '(SADABS; Bruker, 2004)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      153(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            86154
_diffrn_reflns_av_unetI/netI     0.0710
_diffrn_reflns_av_R_equivalents  0.1099
_diffrn_reflns_limit_h_min       -45
_diffrn_reflns_limit_h_max       45
_diffrn_reflns_limit_k_min       -45
_diffrn_reflns_limit_k_max       43
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.718
_diffrn_reflns_theta_max         25.027
_diffrn_reflns_theta_full        25.027
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             10617
_reflns_number_gt                7795
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SMART'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          SQUEEZE
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0752P)²+20.8244P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         10617
_refine_ls_number_parameters     570
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0761
_refine_ls_R_factor_gt           0.0508
_refine_ls_wR_factor_ref         0.1360
_refine_ls_wR_factor_gt          0.1264
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_restrained_S_all      1.031
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.73582(2) 0.02773(2) 0.47484(2) 0.02019(10) Uani 1 1 d . . . . .
O1 O 0.69989(10) 0.02351(10) 0.3627(2) 0.0342(9) Uani 1 1 d . . . . .
O2 O 0.71722(10) 0.01424(11) 0.2354(2) 0.0364(10) Uani 1 1 d . . . . .
O3 O 0.58117(13) -0.06052(14) 0.4030(3) 0.0745(17) Uani 1 1 d . . . . .
O4 O 0.55977(11) 0.05036(13) 0.3208(3) 0.0558(13) Uani 1 1 d . . . . .
O5 O 0.76808(12) 0.07152(10) 0.2738(2) 0.0463(11) Uani 1 1 d . . . . .
O6 O 0.76164(11) 0.07381(10) 0.4089(2) 0.0393(10) Uani 1 1 d . . . . .
O7 O 0.72029(12) 0.19172(11) 0.4351(3) 0.0507(12) Uani 1 1 d . . . . .
O8 O 0.83321(13) 0.20989(12) 0.5140(3) 0.0569(13) Uani 1 1 d . . . . .
O9 O 0.66514(15) 0.32369(14) 0.7065(3) 0.0692(15) Uani 1 1 d . . . . .
O10 O 0.77378(14) 0.32514(11) 0.8180(3) 0.0628(14) Uani 1 1 d . . . . .
O11 O 0.76221(10) 0.45240(10) 0.7625(2) 0.0333(9) Uani 1 1 d . . . . .
O12 O 0.74921(9) 0.47169(9) 0.8845(2) 0.0233(8) Uani 1 1 d . . . . .
O13 O 0.71231(12) 0.08062(11) 0.5323(2) 0.0480(11) Uani 1 1 d . . . . .
N1 N 0.57068(12) -0.00517(14) 0.3629(3) 0.0411(13) Uani 1 1 d . . . . .
N2 N 0.77716(14) 0.20205(12) 0.4709(3) 0.0403(13) Uani 1 1 d . . . . .
N3 N 0.72101(16) 0.32723(13) 0.7555(3) 0.0451(14) Uani 1 1 d . . . . .
N4 N 0.67446(13) 0.12413(13) 0.5627(3) 0.0459(13) Uani 1 1 d . . . . .
C1 C 0.69492(14) 0.01450(14) 0.2899(3) 0.0274(13) Uani 1 1 d . . . . .
C2 C 0.65885(14) 0.00227(15) 0.2691(3) 0.0306(13) Uani 1 1 d . . . . .
C3 C 0.65282(15) -0.01260(16) 0.1923(3) 0.0368(14) Uani 1 1 d . . . . .
H3 H 0.6712 -0.0139 0.1537 0.044 Uiso 1 1 calc R U . . .
C4 C 0.61974(16) -0.02541(18) 0.1727(4) 0.0479(17) Uani 1 1 d . . . . .
H4 H 0.6155 -0.0353 0.1205 0.057 Uiso 1 1 calc R U . . .
C5 C 0.59304(16) -0.02366(18) 0.2299(4) 0.0463(17) Uani 1 1 d . . . . .
H5 H 0.5708 -0.0332 0.2176 0.056 Uiso 1 1 calc R U . . .
C6 C 0.59878(15) -0.00815(17) 0.3040(3) 0.0384(15) Uani 1 1 d . . . . .
C7 C 0.63185(14) 0.00475(16) 0.3244(3) 0.0352(14) Uani 1 1 d . . . . .
H7 H 0.6357 0.0152 0.3762 0.042 Uiso 1 1 calc R U . . .
C8 C 0.56363(17) -0.0350(2) 0.4095(4) 0.0472(17) Uani 1 1 d . . . . .
C9 C 0.53437(15) -0.03203(17) 0.4683(4) 0.0407(15) Uani 1 1 d . . . . .
C10 C 0.51443(15) -0.00095(17) 0.4722(4) 0.0389(15) Uani 1 1 d . . . . .
C11 C 0.52178(14) 0.02784(17) 0.4216(4) 0.0394(15) Uani 1 1 d . . . . .
C12 C 0.55147(15) 0.02616(18) 0.3657(4) 0.0413(16) Uani 1 1 d . . . . .
C13 C 0.50174(16) 0.05756(18) 0.4261(4) 0.0453(16) Uani 1 1 d . . . . .
H13 H 0.5070 0.0769 0.3919 0.054 Uiso 1 1 calc R U . . .
C14 C 0.52642(17) -0.05971(18) 0.5191(4) 0.0481(17) Uani 1 1 d . . . . .
H14 H 0.5401 -0.0804 0.5170 0.058 Uiso 1 1 calc R U . . .
C15 C 0.77075(17) 0.08622(15) 0.3423(4) 0.0390(15) Uani 1 1 d . . . . .
C16 C 0.78453(16) 0.12292(14) 0.3429(3) 0.0348(14) Uani 1 1 d . . . . .
C17 C 0.80632(16) 0.13542(15) 0.2794(3) 0.0381(15) Uani 1 1 d . . . . .
H17 H 0.8119 0.1207 0.2346 0.046 Uiso 1 1 calc R U . . .
C18 C 0.81937(18) 0.16904(16) 0.2828(4) 0.0460(17) Uani 1 1 d . . . . .
H18 H 0.8349 0.1770 0.2416 0.055 Uiso 1 1 calc R U . . .
C19 C 0.81007(17) 0.19103(16) 0.3452(4) 0.0435(16) Uani 1 1 d . . . . .
H19 H 0.8181 0.2145 0.3459 0.052 Uiso 1 1 calc R U . . .
C20 C 0.78884(18) 0.17856(15) 0.4074(4) 0.0425(16) Uani 1 1 d . . . . .
C21 C 0.77708(15) 0.14444(14) 0.4067(3) 0.0331(14) Uani 1 1 d . . . . .
H21 H 0.7637 0.1359 0.4511 0.040 Uiso 1 1 calc R U . . .
C22 C 0.74062(18) 0.20748(15) 0.4783(4) 0.0409(15) Uani 1 1 d . . . . .
C23 C 0.8026(2) 0.21678(16) 0.5216(4) 0.0479(17) Uani 1 1 d . . . . .
C24 C 0.78993(18) 0.24100(15) 0.5860(4) 0.0417(16) Uani 1 1 d . . . . .
C25 C 0.75354(18) 0.24931(14) 0.5888(4) 0.0400(15) Uani 1 1 d . . . . .
C26 C 0.72901(18) 0.23398(15) 0.5379(4) 0.0400(15) Uani 1 1 d . . . . .
C27 C 0.69446(18) 0.24296(15) 0.5420(4) 0.0440(16) Uani 1 1 d . . . . .
H27 H 0.6780 0.2317 0.5077 0.053 Uiso 1 1 calc R U . . .
C28 C 0.68335(19) 0.26898(15) 0.5971(4) 0.0455(16) Uani 1 1 d . . . . .
H28 H 0.6595 0.2758 0.5980 0.055 Uiso 1 1 calc R U . . .
C29 C 0.70645(17) 0.28440(15) 0.6492(4) 0.0397(15) Uani 1 1 d . . . . .
C30 C 0.74182(18) 0.27467(15) 0.6474(3) 0.0399(16) Uani 1 1 d . . . . .
C31 C 0.7665(2) 0.28915(15) 0.7021(4) 0.0463(18) Uani 1 1 d . . . . .
C32 C 0.8018(2) 0.27973(16) 0.6989(4) 0.0474(17) Uani 1 1 d . . . . .
H32 H 0.8180 0.2896 0.7362 0.057 Uiso 1 1 calc R U . . .
C33 C 0.81309(19) 0.25535(16) 0.6397(4) 0.0509(18) Uani 1 1 d . . . . .
H33 H 0.8370 0.2489 0.6373 0.061 Uiso 1 1 calc R U . . .
C34 C 0.7550(2) 0.31495(16) 0.7639(4) 0.0459(17) Uani 1 1 d . . . . .
C35 C 0.6944(2) 0.31307(17) 0.7050(4) 0.0511(19) Uani 1 1 d . . . . .
C36 C 0.71185(19) 0.35762(16) 0.8051(4) 0.0464(17) Uani 1 1 d . . . . .
C37 C 0.68610(19) 0.35620(18) 0.8624(4) 0.0534(19) Uani 1 1 d . . . . .
H37 H 0.6726 0.3356 0.8691 0.064 Uiso 1 1 calc R U . . .
C38 C 0.67980(18) 0.38525(17) 0.9107(4) 0.0504(18) Uani 1 1 d . . . . .
H38 H 0.6616 0.3846 0.9500 0.060 Uiso 1 1 calc R U . . .
C39 C 0.69960(16) 0.41492(15) 0.9023(3) 0.0354(14) Uani 1 1 d . . . . .
H39 H 0.6958 0.4342 0.9377 0.043 Uiso 1 1 calc R U . . .
C40 C 0.72511(15) 0.41697(13) 0.8423(3) 0.0279(13) Uani 1 1 d . . . . .
C41 C 0.74687(14) 0.44813(13) 0.8288(3) 0.0251(12) Uani 1 1 d . . . . .
C42 C 0.73070(17) 0.38812(15) 0.7927(3) 0.0373(15) Uani 1 1 d . . . . .
H42 H 0.7475 0.3893 0.7502 0.045 Uiso 1 1 calc R U . . .
C43 C 0.69511(16) 0.10716(17) 0.5130(4) 0.0430(16) Uani 1 1 d . . . . .
H43 H 0.6972 0.1155 0.4587 0.052 Uiso 1 1 calc R U . . .
C44 C 0.66873(19) 0.1137(2) 0.6453(4) 0.063(2) Uani 1 1 d . . . . .
H44A H 0.6440 0.1082 0.6531 0.094 Uiso 1 1 calc R U . . .
H44B H 0.6754 0.1328 0.6819 0.094 Uiso 1 1 calc R U . . .
H44C H 0.6829 0.0930 0.6574 0.094 Uiso 1 1 calc R U . . .
C45 C 0.6550(2) 0.1539(2) 0.5356(5) 0.079(3) Uani 1 1 d . . . . .
H45A H 0.6606 0.1588 0.4785 0.118 Uiso 1 1 calc R U . . .
H45B H 0.6610 0.1742 0.5692 0.118 Uiso 1 1 calc R U . . .
H45C H 0.6299 0.1491 0.5407 0.118 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O6 2.294(4) . ?
Eu1 O1 2.304(4) . ?
Eu1 O2 2.323(4) 2_545 ?
Eu1 O5 2.367(4) 2_545 ?
Eu1 O12 2.380(3) 13_656 ?
Eu1 O13 2.409(4) . ?
Eu1 O11 2.448(4) 16_646 ?
Eu1 O12 2.657(3) 16_646 ?
Eu1 C41 2.927(5) 16_646 ?
Eu1 Eu1 4.43709(16) 2_545 ?
Eu1 Eu1 4.43712(16) 8_554 ?
O1 C1 1.258(6) . ?
O2 C1 1.237(6) . ?
O2 Eu1 2.323(4) 8_554 ?
O3 C8 1.191(8) . ?
O4 C12 1.225(7) . ?
O5 C15 1.262(7) . ?
O5 Eu1 2.367(4) 8_554 ?
O6 C15 1.242(7) . ?
O7 C22 1.214(7) . ?
O8 C23 1.208(8) . ?
O9 C35 1.193(9) . ?
O10 C34 1.208(7) . ?
O11 C41 1.247(6) . ?
O11 Eu1 2.448(4) 14_666 ?
O12 C41 1.288(6) . ?
O12 Eu1 2.380(3) 13_656 ?
O12 Eu1 2.657(3) 14_666 ?
O13 C43 1.252(7) . ?
N1 C8 1.401(8) . ?
N1 C12 1.408(8) . ?
N1 C6 1.451(7) . ?
N2 C23 1.400(8) . ?
N2 C22 1.420(8) . ?
N2 C20 1.448(7) . ?
N3 C34 1.390(9) . ?
N3 C35 1.421(9) . ?
N3 C36 1.463(8) . ?
N4 C43 1.309(7) . ?
N4 C44 1.430(8) . ?
N4 C45 1.434(8) . ?
C1 C2 1.498(7) . ?
C2 C7 1.379(8) . ?
C2 C3 1.403(8) . ?
C3 C4 1.396(8) . ?
C4 C5 1.390(8) . ?
C5 C6 1.371(8) . ?
C6 C7 1.400(8) . ?
C8 C9 1.484(9) . ?
C9 C14 1.382(9) . ?
C9 C10 1.415(9) . ?
C10 C11 1.408(8) . ?
C10 C10 1.436(12) 9_656 ?
C11 C13 1.375(9) . ?
C11 C12 1.463(8) . ?
C13 C14 1.406(8) 9_656 ?
C14 C13 1.406(8) 9_656 ?
C15 C16 1.501(8) . ?
C16 C21 1.363(7) . ?
C16 C17 1.418(8) . ?
C17 C18 1.382(8) . ?
C18 C19 1.373(8) . ?
C19 C20 1.389(8) . ?
C20 C21 1.382(8) . ?
C22 C26 1.478(8) . ?
C23 C24 1.488(9) . ?
C24 C33 1.366(9) . ?
C24 C25 1.430(9) . ?
C25 C26 1.388(8) . ?
C25 C30 1.438(8) . ?
C26 C27 1.368(9) . ?
C27 C28 1.412(8) . ?
C28 C29 1.365(8) . ?
C29 C30 1.405(9) . ?
C29 C35 1.502(9) . ?
C30 C31 1.416(9) . ?
C31 C32 1.401(10) . ?
C31 C34 1.482(9) . ?
C32 C33 1.415(9) . ?
C36 C37 1.363(8) . ?
C36 C42 1.388(8) . ?
C37 C38 1.387(9) . ?
C38 C39 1.373(8) . ?
C39 C40 1.389(7) . ?
C40 C42 1.389(7) . ?
C40 C41 1.472(7) . ?
C41 Eu1 2.927(5) 14_666 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O6 Eu1 O1 86.23(14) . . ?
O6 Eu1 O2 143.39(14) . 2_545 ?
O1 Eu1 O2 89.39(14) . 2_545 ?
O6 Eu1 O5 132.84(15) . 2_545 ?
O1 Eu1 O5 72.92(13) . 2_545 ?
O2 Eu1 O5 79.52(15) 2_545 2_545 ?
O6 Eu1 O12 110.29(13) . 13_656 ?
O1 Eu1 O12 156.94(12) . 13_656 ?
O2 Eu1 O12 86.38(12) 2_545 13_656 ?
O5 Eu1 O12 84.02(13) 2_545 13_656 ?
O6 Eu1 O13 72.48(15) . . ?
O1 Eu1 O13 98.55(14) . . ?
O2 Eu1 O13 143.98(14) 2_545 . ?
O5 Eu1 O13 69.62(16) 2_545 . ?
O12 Eu1 O13 72.68(12) 13_656 . ?
O6 Eu1 O11 79.06(14) . 16_646 ?
O1 Eu1 O11 128.89(12) . 16_646 ?
O2 Eu1 O11 75.68(13) 2_545 16_646 ?
O5 Eu1 O11 146.08(14) 2_545 16_646 ?
O12 Eu1 O11 71.76(12) 13_656 16_646 ?
O13 Eu1 O11 122.14(14) . 16_646 ?
O6 Eu1 O12 74.54(12) . 16_646 ?
O1 Eu1 O12 78.29(12) . 16_646 ?
O2 Eu1 O12 68.99(12) 2_545 16_646 ?
O5 Eu1 O12 137.15(13) 2_545 16_646 ?
O12 Eu1 O12 120.78(10) 13_656 16_646 ?
O13 Eu1 O12 147.01(13) . 16_646 ?
O11 Eu1 O12 50.64(11) 16_646 16_646 ?
O6 Eu1 C41 78.24(14) . 16_646 ?
O1 Eu1 C41 104.32(14) . 16_646 ?
O2 Eu1 C41 67.72(14) 2_545 16_646 ?
O5 Eu1 C41 147.20(15) 2_545 16_646 ?
O12 Eu1 C41 95.01(13) 13_656 16_646 ?
O13 Eu1 C41 141.27(16) . 16_646 ?
O11 Eu1 C41 24.84(12) 16_646 16_646 ?
O12 Eu1 C41 26.09(12) 16_646 16_646 ?
O6 Eu1 Eu1 139.90(9) . 2_545 ?
O1 Eu1 Eu1 130.09(9) . 2_545 ?
O2 Eu1 Eu1 64.53(9) 2_545 2_545 ?
O5 Eu1 Eu1 61.40(9) 2_545 2_545 ?
O12 Eu1 Eu1 30.00(8) 13_656 2_545 ?
O13 Eu1 Eu1 84.17(10) . 2_545 ?
O11 Eu1 Eu1 86.94(9) 16_646 2_545 ?
O12 Eu1 Eu1 123.20(7) 16_646 2_545 ?
C41 Eu1 Eu1 103.48(10) 16_646 2_545 ?
O6 Eu1 Eu1 59.84(9) . 8_554 ?
O1 Eu1 Eu1 57.90(9) . 8_554 ?
O2 Eu1 Eu1 87.31(9) 2_545 8_554 ?
O5 Eu1 Eu1 129.13(10) 2_545 8_554 ?
O12 Eu1 Eu1 144.25(8) 13_656 8_554 ?
O13 Eu1 Eu1 126.55(10) . 8_554 ?
O11 Eu1 Eu1 72.58(8) 16_646 8_554 ?
O12 Eu1 Eu1 26.59(7) 16_646 8_554 ?
C41 Eu1 Eu1 50.37(10) 16_646 8_554 ?
Eu1 Eu1 Eu1 148.818(6) 2_545 8_554 ?
C1 O1 Eu1 150.3(4) . . ?
C1 O2 Eu1 138.0(3) . 8_554 ?
C15 O5 Eu1 134.7(4) . 8_554 ?
C15 O6 Eu1 146.1(4) . . ?
C41 O11 Eu1 99.6(3) . 14_666 ?
C41 O12 Eu1 135.5(3) . 13_656 ?
C41 O12 Eu1 88.7(3) . 14_666 ?
Eu1 O12 Eu1 123.41(13) 13_656 14_666 ?
C43 O13 Eu1 141.3(4) . . ?
C8 N1 C12 125.2(5) . . ?
C8 N1 C6 116.3(5) . . ?
C12 N1 C6 118.4(5) . . ?
C23 N2 C22 125.2(5) . . ?
C23 N2 C20 117.6(6) . . ?
C22 N2 C20 117.2(5) . . ?
C34 N3 C35 126.8(6) . . ?
C34 N3 C36 116.0(5) . . ?
C35 N3 C36 117.2(6) . . ?
C43 N4 C44 123.1(6) . . ?
C43 N4 C45 121.1(6) . . ?
C44 N4 C45 115.8(6) . . ?
O2 C1 O1 125.8(5) . . ?
O2 C1 C2 118.0(5) . . ?
O1 C1 C2 116.2(5) . . ?
C7 C2 C3 119.8(5) . . ?
C7 C2 C1 121.3(5) . . ?
C3 C2 C1 118.9(5) . . ?
C4 C3 C2 119.9(5) . . ?
C5 C4 C3 119.7(6) . . ?
C6 C5 C4 120.1(6) . . ?
C5 C6 C7 120.7(5) . . ?
C5 C6 N1 120.4(5) . . ?
C7 C6 N1 118.9(5) . . ?
C2 C7 C6 119.7(5) . . ?
O3 C8 N1 120.8(6) . . ?
O3 C8 C9 123.2(6) . . ?
N1 C8 C9 116.0(6) . . ?
C14 C9 C10 119.9(6) . . ?
C14 C9 C8 120.0(6) . . ?
C10 C9 C8 120.1(6) . . ?
C11 C10 C9 121.6(6) . . ?
C11 C10 C10 119.3(7) . 9_656 ?
C9 C10 C10 119.1(7) . 9_656 ?
C13 C11 C10 120.3(6) . . ?
C13 C11 C12 120.3(6) . . ?
C10 C11 C12 119.4(6) . . ?
O4 C12 N1 119.3(6) . . ?
O4 C12 C11 123.1(6) . . ?
N1 C12 C11 117.6(6) . . ?
C11 C13 C14 120.7(6) . 9_656 ?
C9 C14 C13 120.6(6) . 9_656 ?
O6 C15 O5 126.3(6) . . ?
O6 C15 C16 116.8(5) . . ?
O5 C15 C16 116.9(5) . . ?
C21 C16 C17 119.0(5) . . ?
C21 C16 C15 119.8(5) . . ?
C17 C16 C15 121.2(5) . . ?
C18 C17 C16 119.8(5) . . ?
C19 C18 C17 120.5(6) . . ?
C18 C19 C20 119.3(5) . . ?
C21 C20 C19 120.6(5) . . ?
C21 C20 N2 119.5(5) . . ?
C19 C20 N2 119.7(5) . . ?
C16 C21 C20 120.6(5) . . ?
O7 C22 N2 120.6(6) . . ?
O7 C22 C26 122.3(6) . . ?
N2 C22 C26 117.0(6) . . ?
O8 C23 N2 121.8(6) . . ?
O8 C23 C24 121.7(6) . . ?
N2 C23 C24 116.5(7) . . ?
C33 C24 C25 121.5(6) . . ?
C33 C24 C23 119.8(7) . . ?
C25 C24 C23 118.7(6) . . ?
C26 C25 C24 123.1(6) . . ?
C26 C25 C30 118.5(6) . . ?
C24 C25 C30 118.4(6) . . ?
C27 C26 C25 121.2(6) . . ?
C27 C26 C22 119.7(6) . . ?
C25 C26 C22 119.1(6) . . ?
C26 C27 C28 120.0(6) . . ?
C29 C28 C27 120.8(7) . . ?
C28 C29 C30 119.8(6) . . ?
C28 C29 C35 120.0(6) . . ?
C30 C29 C35 120.2(6) . . ?
C29 C30 C31 121.7(6) . . ?
C29 C30 C25 119.6(6) . . ?
C31 C30 C25 118.7(6) . . ?
C32 C31 C30 121.3(6) . . ?
C32 C31 C34 118.9(6) . . ?
C30 C31 C34 119.8(7) . . ?
C31 C32 C33 119.3(6) . . ?
C24 C33 C32 120.7(7) . . ?
O10 C34 N3 121.4(6) . . ?
O10 C34 C31 122.8(7) . . ?
N3 C34 C31 115.8(6) . . ?
O9 C35 N3 122.1(6) . . ?
O9 C35 C29 123.4(7) . . ?
N3 C35 C29 114.5(7) . . ?
C37 C36 C42 120.7(6) . . ?
C37 C36 N3 121.7(6) . . ?
C42 C36 N3 117.6(5) . . ?
C36 C37 C38 119.2(6) . . ?
C39 C38 C37 120.7(6) . . ?
C38 C39 C40 120.4(5) . . ?
C42 C40 C39 118.6(5) . . ?
C42 C40 C41 118.0(5) . . ?
C39 C40 C41 123.4(5) . . ?
O11 C41 O12 119.6(5) . . ?
O11 C41 C40 120.3(5) . . ?
O12 C41 C40 120.0(5) . . ?
O11 C41 Eu1 55.5(3) . 14_666 ?
O12 C41 Eu1 65.2(3) . 14_666 ?
C40 C41 Eu1 167.0(4) . 14_666 ?
C36 C42 C40 120.2(5) . . ?
O13 C43 N4 124.2(6) . . ?

_refine_diff_density_max         0.869
_refine_diff_density_min         -0.633
_refine_diff_density_rms         0.107




