# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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#######################################################################

data_eu_2
_database_code_depnum_ccdc_archive 'CCDC 2077564'
loop_
_audit_author_name
_audit_author_address
'Wei Liu'
;Lanzhou University
China
;
_audit_update_record             
;
2022-07-19 deposited with the CCDC.	2022-07-19 downloaded from the CCDC.
;
_audit_creation_date             2022-07-16
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C23 H19 Eu N2 O11, 2(C3 H7 N O)'
_chemical_formula_sum            'C29 H33 Eu N4 O13'
_chemical_formula_weight         797.55
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.6558(4)
_cell_length_b                   11.8403(3)
_cell_length_c                   14.3912(9)
_cell_angle_alpha                91.242(4)
_cell_angle_beta                 90.620(4)
_cell_angle_gamma                91.585(3)
_cell_volume                     1644.19(13)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    6020
_cell_measurement_temperature    150.00(10)
_cell_measurement_theta_max      28.8300
_cell_measurement_theta_min      2.5730
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    1.977
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.89058
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.38.43f (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.611
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             804
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.08
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0430
_diffrn_reflns_av_unetI/netI     0.0711
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            11952
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.024
_diffrn_reflns_theta_max         25.024
_diffrn_reflns_theta_min         2.110
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      150.00(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 5.2684
_diffrn_detector_type            AtlasS2
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -56.00  37.00   1.00    1.50    --   11.90 -57.00  60.00   93
  2  ω    -15.00  79.00   1.00    1.50    --   11.90  77.00 -30.00   94
  3  ω     37.00  64.00   1.00    1.50    --   11.90 178.00  30.00   27
  4  ω    -16.00  85.00   1.00    1.50    --   11.90  57.00-150.00  101
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, AtlasS2'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0388265000
_diffrn_orient_matrix_UB_12      -0.0398029000
_diffrn_orient_matrix_UB_13      -0.0279427000
_diffrn_orient_matrix_UB_21      0.0374625000
_diffrn_orient_matrix_UB_22      0.0171738000
_diffrn_orient_matrix_UB_23      -0.0396444000
_diffrn_orient_matrix_UB_31      0.0499001000
_diffrn_orient_matrix_UB_32      -0.0413998000
_diffrn_orient_matrix_UB_33      0.0088503000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5165
_reflns_number_total             5805
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         4.161
_refine_diff_density_min         -1.117
_refine_diff_density_rms         0.168
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.072
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     472
_refine_ls_number_reflns         5805
_refine_ls_number_restraints     132
_refine_ls_R_factor_all          0.0587
_refine_ls_R_factor_gt           0.0513
_refine_ls_restrained_S_all      1.062
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0562P)²+7.3745P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1215
_refine_ls_wR_factor_ref         0.1281
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H,H) groups
2. Uiso/Uaniso restraints and constraints
N3 \\sim C27 \\sim C28 \\sim C29 \\sim N3A \\sim C27A \\sim C29A \\sim C28A:
within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
3. Rigid body (RIGU) restrains
 O6, N3, C27, C28, C29, N3A, C27A, C29A, C28A
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
4. Same fragment restrains
{N3, C27, C28, C29} sigma for 1-2: 0.01, 1-3: 0.02
as in
{N3A, C27A, C29A, C28A}
5. Others
 Sof(N3A)=Sof(C27A)=Sof(H27A)=Sof(C29A)=Sof(H29D)=Sof(H29E)=Sof(H29F)=
 Sof(C28A)=Sof(H28D)=Sof(H28E)=Sof(H28F)=1-FVAR(1)
 Sof(N3)=Sof(C27)=Sof(H27)=Sof(C28)=Sof(H28A)=Sof(H28B)=Sof(H28C)=Sof(C29)=
 Sof(H29A)=Sof(H29B)=Sof(H29C)=FVAR(1)
6.a Free rotating group:
 O5(H5A,H5B)
6.b Rotating group:
 O3(H3A,H3B), O4(H4A,H4B)
6.c Aromatic/amide H refined with riding coordinates:
 C1(H1), C4(H4), C5(H5), C8(H8), C9(H9), C12(H12), C13(H13), C14(H14),
 C15(H15), C18(H18), C19(H19), C22(H22), C23(H23), C27(H27), C27A(H27A),
 C24(H24)
6.d Idealised Me refined as rotating group:
 C28(H28A,H28B,H28C), C29(H29A,H29B,H29C), C29A(H29D,H29E,H29F), C28A(H28D,
 H28E,H28F), C25(H25A,H25B,H25C), C26(H26A,H26B,H26C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.74870(3) 0.49810(2) 0.52844(2) 0.01443(13) Uani 1 1 d . . . . .
O1 O 0.7246(7) 0.1693(4) 0.5320(5) 0.0513(17) Uani 1 1 d . . . . .
O2 O 0.8371(5) 0.3184(4) 0.4715(3) 0.0243(11) Uani 1 1 d . . . . .
O3 O 0.6081(5) 0.3464(4) 0.6056(4) 0.0276(11) Uani 1 1 d . . . . .
H3A H 0.629459 0.282177 0.583197 0.041 Uiso 1 1 d R U . . .
H3B H 0.631229 0.344237 0.662757 0.041 Uiso 1 1 d R U . . .
O4 O 0.8945(5) 0.6588(4) 0.5907(4) 0.0286(11) Uani 1 1 d . . . . .
H4A H 0.976841 0.652947 0.570733 0.043 Uiso 1 1 d R U . . .
H4B H 0.866691 0.720137 0.567964 0.043 Uiso 1 1 d R U . . .
O5 O 0.6537(5) 0.6692(4) 0.4671(4) 0.0276(11) Uani 1 1 d G . . . .
H5A H 0.577738 0.673490 0.437189 0.041 Uiso 1 1 d G U . . .
H5B H 0.675731 0.737277 0.481908 0.041 Uiso 1 1 d G U . . .
O8 O 0.5858(5) 0.4466(4) 0.4141(3) 0.0222(10) Uani 1 1 d . . . . .
O9 O 0.3786(5) 0.4154(4) 0.3487(3) 0.0279(11) Uani 1 1 d . . . . .
O10 O 0.8792(5) 0.1459(4) 0.0451(3) 0.0279(11) Uani 1 1 d . . . . .
O11 O 0.6234(4) -0.1336(4) 0.0511(3) 0.0253(11) Uani 1 1 d . . . . .
O12 O 0.9005(4) -0.4647(4) 0.4059(3) 0.0197(10) Uani 1 1 d . . . . .
O13 O 1.1106(4) -0.4273(4) 0.3500(3) 0.0241(11) Uani 1 1 d . . . . .
N1 N 0.6649(5) 0.0999(4) -0.0157(4) 0.0176(11) Uani 1 1 d . . . . .
N2 N 0.8404(5) -0.1019(4) -0.0062(4) 0.0166(11) Uani 1 1 d . . . . .
C1 C 0.8177(9) 0.2140(6) 0.4874(6) 0.0359(19) Uani 1 1 d . . . . .
H1 H 0.882159 0.165508 0.462083 0.043 Uiso 1 1 calc R U . . .
C2 C 0.5080(7) 0.4044(5) 0.3512(5) 0.0196(14) Uani 1 1 d . . . . .
C3 C 0.5701(7) 0.3367(5) 0.2733(4) 0.0181(14) Uani 1 1 d . . . . .
C4 C 0.7121(6) 0.3454(5) 0.2561(4) 0.0184(14) Uani 1 1 d . . . . .
H4 H 0.769130 0.392026 0.293647 0.022 Uiso 1 1 calc R U . . .
C5 C 0.7674(7) 0.2848(5) 0.1833(5) 0.0205(14) Uani 1 1 d . . . . .
H5 H 0.861880 0.291541 0.171947 0.025 Uiso 1 1 calc R U . . .
C6 C 0.6841(7) 0.2130(5) 0.1259(5) 0.0186(14) Uani 1 1 d . . . . .
C7 C 0.7523(7) 0.1500(5) 0.0493(5) 0.0185(14) Uani 1 1 d . . . . .
C8 C 0.5427(7) 0.2023(6) 0.1453(5) 0.0244(15) Uani 1 1 d . . . . .
H8 H 0.485968 0.153186 0.109638 0.029 Uiso 1 1 calc R U . . .
C9 C 0.4870(7) 0.2650(6) 0.2180(5) 0.0248(15) Uani 1 1 d . . . . .
H9 H 0.392564 0.258609 0.229575 0.030 Uiso 1 1 calc R U . . .
C10 C 0.7141(6) 0.0421(5) -0.0966(4) 0.0154(13) Uani 1 1 d . . . . .
C11 C 0.7979(6) -0.0517(5) -0.0920(4) 0.0168(13) Uani 1 1 d . . . . .
C12 C 0.8460(7) -0.1011(5) -0.1750(4) 0.0202(14) Uani 1 1 d . . . . .
H12 H 0.903188 -0.162923 -0.172235 0.024 Uiso 1 1 calc R U . . .
C13 C 0.8104(8) -0.0600(6) -0.2591(5) 0.0322(17) Uani 1 1 d . . . . .
H13 H 0.843651 -0.093532 -0.313194 0.039 Uiso 1 1 calc R U . . .
C14 C 0.7243(8) 0.0318(6) -0.2647(5) 0.0310(17) Uani 1 1 d . . . . .
H14 H 0.698116 0.059118 -0.322188 0.037 Uiso 1 1 calc R U . . .
C15 C 0.6780(7) 0.0823(5) -0.1830(5) 0.0226(15) Uani 1 1 d . . . . .
H15 H 0.621539 0.144451 -0.186437 0.027 Uiso 1 1 calc R U . . .
C16 C 0.7504(7) -0.1438(5) 0.0567(5) 0.0187(14) Uani 1 1 d . . . . .
C17 C 0.8148(7) -0.2091(5) 0.1340(4) 0.0186(14) Uani 1 1 d . . . . .
C18 C 0.7263(6) -0.2807(5) 0.1844(4) 0.0183(14) Uani 1 1 d . . . . .
H18 H 0.631856 -0.283981 0.170736 0.022 Uiso 1 1 calc R U . . .
C19 C 0.7795(7) -0.3474(5) 0.2553(4) 0.0189(14) Uani 1 1 d . . . . .
H19 H 0.720132 -0.394061 0.288702 0.023 Uiso 1 1 calc R U . . .
C20 C 0.9210(6) -0.3439(5) 0.2756(4) 0.0167(13) Uani 1 1 d . . . . .
C21 C 0.9816(7) -0.4171(5) 0.3487(4) 0.0166(13) Uani 1 1 d . . . . .
C22 C 1.0079(7) -0.2710(5) 0.2265(5) 0.0224(15) Uani 1 1 d . . . . .
H22 H 1.102187 -0.267157 0.240356 0.027 Uiso 1 1 calc R U . . .
C23 C 0.9547(7) -0.2035(6) 0.1566(5) 0.0235(15) Uani 1 1 d . . . . .
H23 H 1.013745 -0.154533 0.125094 0.028 Uiso 1 1 calc R U . . .
O6 O 0.6136(7) 0.3698(5) 0.7978(5) 0.0555(17) Uani 1 1 d . . . . .
N3 N 0.6764(18) 0.4869(13) 0.9139(10) 0.053(3) Uani 0.498(10) 1 d D U P A 1
C27 C 0.701(4) 0.460(3) 0.8208(13) 0.053(4) Uani 0.498(10) 1 d D U P A 1
H27 H 0.764209 0.496503 0.782106 0.063 Uiso 0.498(10) 1 calc R U P A 1
C28 C 0.569(2) 0.4550(19) 0.9742(15) 0.074(6) Uani 0.498(10) 1 d D U P A 1
H28A H 0.490760 0.502125 0.964281 0.111 Uiso 0.498(10) 1 calc R U P A 1
H28B H 0.600424 0.463827 1.037411 0.111 Uiso 0.498(10) 1 calc R U P A 1
H28C H 0.541579 0.377500 0.961810 0.111 Uiso 0.498(10) 1 calc R U P A 1
C29 C 0.766(3) 0.5785(18) 0.9422(16) 0.074(5) Uani 0.498(10) 1 d D U P A 1
H29A H 0.840785 0.550946 0.978782 0.111 Uiso 0.498(10) 1 calc R U P A 1
H29B H 0.714844 0.631710 0.978748 0.111 Uiso 0.498(10) 1 calc R U P A 1
H29C H 0.801884 0.615072 0.888395 0.111 Uiso 0.498(10) 1 calc R U P A 1
N3A N 0.7739(18) 0.4839(13) 0.8988(10) 0.055(3) Uani 0.502(10) 1 d D U P A 2
C27A C 0.686(4) 0.440(3) 0.8281(13) 0.051(4) Uani 0.502(10) 1 d D U P A 2
H27A H 0.686796 0.495787 0.783322 0.061 Uiso 0.502(10) 1 calc R U P A 2
C29A C 0.867(3) 0.5765(18) 0.9048(19) 0.083(6) Uani 0.502(10) 1 d D U P A 2
H29D H 0.885531 0.603598 0.843635 0.125 Uiso 0.502(10) 1 calc R U P A 2
H29E H 0.952444 0.553782 0.933062 0.125 Uiso 0.502(10) 1 calc R U P A 2
H29F H 0.828241 0.635696 0.941951 0.125 Uiso 0.502(10) 1 calc R U P A 2
C28A C 0.775(2) 0.4035(16) 0.9700(13) 0.066(5) Uani 0.502(10) 1 d D U P A 2
H28D H 0.713921 0.340882 0.953159 0.098 Uiso 0.502(10) 1 calc R U P A 2
H28E H 0.744680 0.437859 1.027009 0.098 Uiso 0.502(10) 1 calc R U P A 2
H28F H 0.867418 0.377055 0.978296 0.098 Uiso 0.502(10) 1 calc R U P A 2
O7 O 0.8200(7) 0.8579(5) 0.4959(5) 0.0607(19) Uani 1 1 d . . . . .
N4 N 0.7477(8) 0.9601(6) 0.3722(5) 0.0458(18) Uani 1 1 d . . . . .
C24 C 0.8434(10) 0.9140(7) 0.4225(7) 0.049(2) Uani 1 1 d . . . . .
H24 H 0.934795 0.922519 0.403607 0.059 Uiso 1 1 calc R U . . .
C25 C 0.6047(10) 0.9469(9) 0.3954(10) 0.075(4) Uani 1 1 d . . . . .
H25A H 0.557649 0.900798 0.348672 0.112 Uiso 1 1 calc R U . . .
H25B H 0.563507 1.019771 0.398746 0.112 Uiso 1 1 calc R U . . .
H25C H 0.596855 0.911386 0.454556 0.112 Uiso 1 1 calc R U . . .
C26 C 0.7773(14) 1.0248(9) 0.2908(7) 0.076(4) Uani 1 1 d . . . . .
H26A H 0.756261 1.102561 0.302757 0.114 Uiso 1 1 calc R U . . .
H26B H 0.721695 0.995797 0.239528 0.114 Uiso 1 1 calc R U . . .
H26C H 0.873565 1.019318 0.275981 0.114 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O2 2.443(4) . ?
Eu1 O3 2.507(5) . ?
Eu1 O4 2.481(5) . ?
Eu1 O5 2.427(4) . ?
Eu1 O8 2.324(5) . ?
Eu1 O9 2.393(4) 2_666 ?
Eu1 O12 2.347(4) 1_565 ?
Eu1 O13 2.385(4) 2_756 ?
Eu1 C2 3.263(6) 2_666 ?
O1 C1 1.225(9) . ?
O2 C1 1.271(9) . ?
O3 H3A 0.8513 . ?
O3 H3B 0.8509 . ?
O4 H4A 0.8522 . ?
O4 H4B 0.8520 . ?
O5 H5A 0.8497 . ?
O5 H5B 0.8498 . ?
O8 C2 1.256(8) . ?
O9 C2 1.260(8) . ?
O10 C7 1.231(8) . ?
O11 C16 1.238(8) . ?
O12 C21 1.272(7) . ?
O13 C21 1.254(8) . ?
N1 C7 1.367(8) . ?
N1 C10 1.430(8) . ?
N2 C11 1.443(8) . ?
N2 C16 1.354(8) . ?
C1 H1 0.9300 . ?
C2 C3 1.502(9) . ?
C3 C4 1.397(9) . ?
C3 C9 1.385(9) . ?
C4 H4 0.9300 . ?
C4 C5 1.378(9) . ?
C5 H5 0.9300 . ?
C5 C6 1.402(9) . ?
C6 C7 1.488(9) . ?
C6 C8 1.399(9) . ?
C8 H8 0.9300 . ?
C8 C9 1.391(10) . ?
C9 H9 0.9300 . ?
C10 C11 1.394(8) . ?
C10 C15 1.385(9) . ?
C11 C12 1.408(9) . ?
C12 H12 0.9300 . ?
C12 C13 1.359(10) . ?
C13 H13 0.9300 . ?
C13 C14 1.390(11) . ?
C14 H14 0.9300 . ?
C14 C15 1.392(10) . ?
C15 H15 0.9300 . ?
C16 C17 1.507(9) . ?
C17 C18 1.405(9) . ?
C17 C23 1.386(9) . ?
C18 H18 0.9300 . ?
C18 C19 1.405(9) . ?
C19 H19 0.9300 . ?
C19 C20 1.393(9) . ?
C20 C21 1.502(9) . ?
C20 C22 1.396(9) . ?
C22 H22 0.9300 . ?
C22 C23 1.400(9) . ?
C23 H23 0.9300 . ?
O6 C27 1.38(3) . ?
O6 C27A 1.15(3) . ?
N3 C27 1.39(2) . ?
N3 C28 1.41(2) . ?
N3 C29 1.418(19) . ?
C27 H27 0.9300 . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C29 H29A 0.9600 . ?
C29 H29B 0.9600 . ?
C29 H29C 0.9600 . ?
N3A C27A 1.40(2) . ?
N3A C29A 1.40(2) . ?
N3A C28A 1.414(18) . ?
C27A H27A 0.9300 . ?
C29A H29D 0.9600 . ?
C29A H29E 0.9600 . ?
C29A H29F 0.9600 . ?
C28A H28D 0.9600 . ?
C28A H28E 0.9600 . ?
C28A H28F 0.9600 . ?
O7 C24 1.279(11) . ?
N4 C24 1.306(11) . ?
N4 C25 1.430(13) . ?
N4 C26 1.440(12) . ?
C24 H24 0.9300 . ?
C25 H25A 0.9600 . ?
C25 H25B 0.9600 . ?
C25 H25C 0.9600 . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Eu1 O3 73.77(16) . . ?
O2 Eu1 O4 124.84(16) . . ?
O2 Eu1 C2 139.98(15) . 2_666 ?
O3 Eu1 C2 66.74(16) . 2_666 ?
O4 Eu1 O3 132.56(17) . . ?
O4 Eu1 C2 88.25(16) . 2_666 ?
O5 Eu1 O2 139.06(17) . . ?
O5 Eu1 O3 124.30(16) . . ?
O5 Eu1 O4 72.99(16) . . ?
O5 Eu1 C2 66.22(17) . 2_666 ?
O8 Eu1 O2 78.43(16) . . ?
O8 Eu1 O3 77.65(16) . . ?
O8 Eu1 O4 143.27(16) . . ?
O8 Eu1 O5 71.79(16) . . ?
O8 Eu1 O9 105.75(16) . 2_666 ?
O8 Eu1 O12 86.22(16) . 1_565 ?
O8 Eu1 O13 143.79(16) . 2_756 ?
O8 Eu1 C2 86.97(16) . 2_666 ?
O9 Eu1 O2 143.54(16) 2_666 . ?
O9 Eu1 O3 71.97(17) 2_666 . ?
O9 Eu1 O4 73.18(16) 2_666 . ?
O9 Eu1 O5 73.14(18) 2_666 . ?
O9 Eu1 C2 18.78(16) 2_666 2_666 ?
O12 Eu1 O2 71.79(15) 1_565 . ?
O12 Eu1 O3 144.22(16) 1_565 . ?
O12 Eu1 O4 77.04(16) 1_565 . ?
O12 Eu1 O5 78.72(16) 1_565 . ?
O12 Eu1 O9 143.71(16) 1_565 2_666 ?
O12 Eu1 O13 105.49(15) 1_565 2_756 ?
O12 Eu1 C2 144.66(15) 1_565 2_666 ?
O13 Eu1 O2 73.31(17) 2_756 . ?
O13 Eu1 O3 73.09(15) 2_756 . ?
O13 Eu1 O4 72.80(16) 2_756 . ?
O13 Eu1 O5 143.48(17) 2_756 . ?
O13 Eu1 O9 85.08(17) 2_756 2_666 ?
O13 Eu1 C2 100.34(16) 2_756 2_666 ?
C1 O2 Eu1 137.4(5) . . ?
Eu1 O3 H3A 109.4 . . ?
Eu1 O3 H3B 109.4 . . ?
H3A O3 H3B 104.6 . . ?
Eu1 O4 H4A 109.4 . . ?
Eu1 O4 H4B 109.5 . . ?
H4A O4 H4B 104.4 . . ?
Eu1 O5 H5A 125.8 . . ?
Eu1 O5 H5B 128.0 . . ?
H5A O5 H5B 104.5 . . ?
C2 O8 Eu1 170.9(4) . . ?
C2 O9 Eu1 123.5(4) . 2_666 ?
C21 O12 Eu1 164.2(4) . 1_545 ?
C21 O13 Eu1 127.9(4) . 2_756 ?
C7 N1 C10 122.5(5) . . ?
C16 N2 C11 123.6(5) . . ?
O1 C1 O2 128.0(8) . . ?
O1 C1 H1 116.0 . . ?
O2 C1 H1 116.0 . . ?
O8 C2 Eu1 86.3(4) . 2_666 ?
O8 C2 O9 123.8(6) . . ?
O8 C2 C3 119.3(6) . . ?
O9 C2 Eu1 37.7(3) . 2_666 ?
O9 C2 C3 116.9(6) . . ?
C3 C2 Eu1 154.1(4) . 2_666 ?
C4 C3 C2 120.4(6) . . ?
C9 C3 C2 120.3(6) . . ?
C9 C3 C4 119.3(6) . . ?
C3 C4 H4 120.0 . . ?
C5 C4 C3 119.9(6) . . ?
C5 C4 H4 120.0 . . ?
C4 C5 H5 119.3 . . ?
C4 C5 C6 121.3(6) . . ?
C6 C5 H5 119.3 . . ?
C5 C6 C7 117.9(6) . . ?
C8 C6 C5 118.4(6) . . ?
C8 C6 C7 123.7(6) . . ?
O10 C7 N1 123.1(6) . . ?
O10 C7 C6 121.2(6) . . ?
N1 C7 C6 115.6(5) . . ?
C6 C8 H8 120.0 . . ?
C9 C8 C6 120.0(6) . . ?
C9 C8 H8 120.0 . . ?
C3 C9 C8 121.0(6) . . ?
C3 C9 H9 119.5 . . ?
C8 C9 H9 119.5 . . ?
C11 C10 N1 122.8(6) . . ?
C15 C10 N1 118.3(5) . . ?
C15 C10 C11 118.8(6) . . ?
C10 C11 N2 123.8(6) . . ?
C10 C11 C12 119.2(6) . . ?
C12 C11 N2 117.0(5) . . ?
C11 C12 H12 119.4 . . ?
C13 C12 C11 121.1(7) . . ?
C13 C12 H12 119.4 . . ?
C12 C13 H13 119.9 . . ?
C12 C13 C14 120.3(7) . . ?
C14 C13 H13 119.9 . . ?
C13 C14 H14 120.5 . . ?
C13 C14 C15 119.0(6) . . ?
C15 C14 H14 120.5 . . ?
C10 C15 C14 121.5(6) . . ?
C10 C15 H15 119.2 . . ?
C14 C15 H15 119.2 . . ?
O11 C16 N2 123.6(6) . . ?
O11 C16 C17 121.0(6) . . ?
N2 C16 C17 115.3(5) . . ?
C18 C17 C16 117.1(6) . . ?
C23 C17 C16 123.8(6) . . ?
C23 C17 C18 119.0(6) . . ?
C17 C18 H18 119.8 . . ?
C17 C18 C19 120.4(6) . . ?
C19 C18 H18 119.8 . . ?
C18 C19 H19 119.9 . . ?
C20 C19 C18 120.2(6) . . ?
C20 C19 H19 119.9 . . ?
C19 C20 C21 121.4(5) . . ?
C19 C20 C22 119.1(6) . . ?
C22 C20 C21 119.5(6) . . ?
O12 C21 C20 118.7(6) . . ?
O13 C21 O12 123.6(6) . . ?
O13 C21 C20 117.6(5) . . ?
C20 C22 H22 119.6 . . ?
C20 C22 C23 120.8(6) . . ?
C23 C22 H22 119.6 . . ?
C17 C23 C22 120.5(6) . . ?
C17 C23 H23 119.8 . . ?
C22 C23 H23 119.8 . . ?
C27 N3 C28 132.3(19) . . ?
C27 N3 C29 108.7(17) . . ?
C28 N3 C29 117.8(14) . . ?
O6 C27 N3 106(2) . . ?
O6 C27 H27 127.0 . . ?
N3 C27 H27 127.0 . . ?
N3 C28 H28A 109.5 . . ?
N3 C28 H28B 109.5 . . ?
N3 C28 H28C 109.5 . . ?
H28A C28 H28B 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
N3 C29 H29A 109.5 . . ?
N3 C29 H29B 109.5 . . ?
N3 C29 H29C 109.5 . . ?
H29A C29 H29B 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C27A N3A C29A 133.3(18) . . ?
C27A N3A C28A 107.2(17) . . ?
C29A N3A C28A 118.8(15) . . ?
O6 C27A N3A 151(3) . . ?
O6 C27A H27A 104.6 . . ?
N3A C27A H27A 104.6 . . ?
N3A C29A H29D 109.5 . . ?
N3A C29A H29E 109.5 . . ?
N3A C29A H29F 109.5 . . ?
H29D C29A H29E 109.5 . . ?
H29D C29A H29F 109.5 . . ?
H29E C29A H29F 109.5 . . ?
N3A C28A H28D 109.5 . . ?
N3A C28A H28E 109.5 . . ?
N3A C28A H28F 109.5 . . ?
H28D C28A H28E 109.5 . . ?
H28D C28A H28F 109.5 . . ?
H28E C28A H28F 109.5 . . ?
C24 N4 C25 120.6(8) . . ?
C24 N4 C26 123.4(9) . . ?
C25 N4 C26 116.0(9) . . ?
O7 C24 N4 124.5(9) . . ?
O7 C24 H24 117.7 . . ?
N4 C24 H24 117.7 . . ?
N4 C25 H25A 109.5 . . ?
N4 C25 H25B 109.5 . . ?
N4 C25 H25C 109.5 . . ?
H25A C25 H25B 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
N4 C26 H26A 109.5 . . ?
N4 C26 H26B 109.5 . . ?
N4 C26 H26C 109.5 . . ?
H26A C26 H26B 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
O3 H3A O1 0.85 1.79 2.616(8) 162.3 . yes
O3 H3B O6 0.85 1.97 2.774(8) 157.0 . yes
O4 H4A O2 0.85 1.93 2.759(7) 165.2 2_766 yes
O4 H4B O7 0.85 2.01 2.855(7) 170.5 . yes
O5 H5A O3 0.85 1.90 2.726(7) 164.3 2_666 yes
O5 H5B O7 0.85 1.97 2.737(8) 149.0 . yes

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O2 C1 O1 12.4(14) . . . . ?
Eu1 O9 C2 O8 -6.9(9) 2_666 . . . ?
Eu1 O9 C2 C3 173.3(4) 2_666 . . . ?
Eu1 O12 C21 O13 105.7(15) 1_545 . . . ?
Eu1 O12 C21 C20 -74.0(17) 1_545 . . . ?
Eu1 O13 C21 O12 -14.9(9) 2_756 . . . ?
Eu1 O13 C21 C20 164.8(4) 2_756 . . . ?
Eu1 C2 C3 C4 171.8(7) 2_666 . . . ?
Eu1 C2 C3 C9 -8.2(13) 2_666 . . . ?
O8 C2 C3 C4 -17.4(9) . . . . ?
O8 C2 C3 C9 162.6(6) . . . . ?
O9 C2 C3 C4 162.4(6) . . . . ?
O9 C2 C3 C9 -17.6(9) . . . . ?
O11 C16 C17 C18 15.8(9) . . . . ?
O11 C16 C17 C23 -165.3(7) . . . . ?
N1 C10 C11 N2 1.8(9) . . . . ?
N1 C10 C11 C12 -177.7(6) . . . . ?
N1 C10 C15 C14 178.7(6) . . . . ?
N2 C11 C12 C13 179.4(6) . . . . ?
N2 C16 C17 C18 -162.0(6) . . . . ?
N2 C16 C17 C23 17.0(9) . . . . ?
C2 C3 C4 C5 -178.6(6) . . . . ?
C2 C3 C9 C8 179.6(6) . . . . ?
C3 C4 C5 C6 -0.5(10) . . . . ?
C4 C3 C9 C8 -0.4(10) . . . . ?
C4 C5 C6 C7 -179.6(6) . . . . ?
C4 C5 C6 C8 -1.3(10) . . . . ?
C5 C6 C7 O10 11.6(9) . . . . ?
C5 C6 C7 N1 -167.2(6) . . . . ?
C5 C6 C8 C9 2.3(10) . . . . ?
C6 C8 C9 C3 -1.4(11) . . . . ?
C7 N1 C10 C11 60.5(8) . . . . ?
C7 N1 C10 C15 -118.7(7) . . . . ?
C7 C6 C8 C9 -179.6(6) . . . . ?
C8 C6 C7 O10 -166.6(6) . . . . ?
C8 C6 C7 N1 14.7(9) . . . . ?
C9 C3 C4 C5 1.4(10) . . . . ?
C10 N1 C7 O10 -2.7(9) . . . . ?
C10 N1 C7 C6 176.1(5) . . . . ?
C10 C11 C12 C13 -1.0(10) . . . . ?
C11 N2 C16 O11 -7.1(10) . . . . ?
C11 N2 C16 C17 170.6(5) . . . . ?
C11 C10 C15 C14 -0.5(10) . . . . ?
C11 C12 C13 C14 -0.4(11) . . . . ?
C12 C13 C14 C15 1.4(11) . . . . ?
C13 C14 C15 C10 -0.9(10) . . . . ?
C15 C10 C11 N2 -179.0(6) . . . . ?
C15 C10 C11 C12 1.5(9) . . . . ?
C16 N2 C11 C10 58.9(9) . . . . ?
C16 N2 C11 C12 -121.6(7) . . . . ?
C16 C17 C18 C19 177.7(6) . . . . ?
C16 C17 C23 C22 -176.9(6) . . . . ?
C17 C18 C19 C20 -0.6(10) . . . . ?
C18 C17 C23 C22 2.1(10) . . . . ?
C18 C19 C20 C21 -178.0(6) . . . . ?
C18 C19 C20 C22 1.9(10) . . . . ?
C19 C20 C21 O12 -14.9(9) . . . . ?
C19 C20 C21 O13 165.4(6) . . . . ?
C19 C20 C22 C23 -1.1(10) . . . . ?
C20 C22 C23 C17 -0.9(11) . . . . ?
C21 C20 C22 C23 178.7(6) . . . . ?
C22 C20 C21 O12 165.3(6) . . . . ?
C22 C20 C21 O13 -14.4(9) . . . . ?
C23 C17 C18 C19 -1.3(10) . . . . ?
C28 N3 C27 O6 -14(4) . . . . ?
C29 N3 C27 O6 179(2) . . . . ?
C29A N3A C27A O6 169(6) . . . . ?
C28A N3A C27A O6 -1(8) . . . . ?
C25 N4 C24 O7 -2.2(14) . . . . ?
C26 N4 C24 O7 178.7(9) . . . . ?

# start Validation Reply Form
_vrf_PLAT971_eu_2                
;
PROBLEM: Check Calcd Resid. Dens.  1.03Ang From Eu1             4.33 eA-3
RESPONSE:  It's a very common phenomenon to have residual 
electron density peaks around heavy atoms. 
We did several absorption correction, but failed. 
In addition, there was a residual peak of 1.66 eA-3 near C29a, 
which was caused by disordered DMF molecules.
;
# end Validation Reply Form

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.276
_oxdiff_exptl_absorpt_empirical_full_min 0.841
