# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 2173561'
loop_
_audit_author_name
_audit_author_address
'Snehadrinarayan Khatua'
;North Eastern Hill University
India
;
_audit_update_record             
;
2022-05-19 deposited with the CCDC.	2022-06-29 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C33 H29 F6 Ir N7 O2 P'
_chemical_formula_weight         892.80

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ir Ir -1.4442 7.9887 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   15.508(3)
_cell_length_b                   13.606(4)
_cell_length_c                   18.951(3)
_cell_angle_alpha                90
_cell_angle_beta                 112.56(2)
_cell_angle_gamma                90
_cell_volume                     3692.4(16)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    3437
_cell_measurement_theta_min      3.227
_cell_measurement_theta_max      29.234

_exptl_crystal_description       Plate
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.606
_exptl_crystal_F_000             1752
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.140
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.070
_exptl_absorpt_coefficient_mu    3.729
_shelx_estimated_absorpt_T_min   0.623
_shelx_estimated_absorpt_T_max   0.780
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.854
_exptl_absorpt_correction_T_max  0.914
_exptl_absorpt_process_details   'CrysAlis PRO; Agilent, 2011'

_exptl_special_details           
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            13635
_diffrn_reflns_av_unetI/netI     0.2359
_diffrn_reflns_av_R_equivalents  0.1194
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         3.267
_diffrn_reflns_theta_max         29.093
_diffrn_reflns_theta_full        26.000
_diffrn_measured_fraction_theta_max 0.844
_diffrn_measured_fraction_theta_full 0.990
_diffrn_reflns_Laue_measured_fraction_max 0.844
_diffrn_reflns_Laue_measured_fraction_full 0.990
_diffrn_reflns_point_group_measured_fraction_max 0.844
_diffrn_reflns_point_group_measured_fraction_full 0.990
_reflns_number_total             8371
_reflns_number_gt                3761
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlis PRO (Agilent, 2011)'
_computing_cell_refinement       'CrysAlis PRO'
_computing_data_reduction        'CrysAlis PRO'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1364P)²+37.4524P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_extinction_coef       0.0022(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         8371
_refine_ls_number_parameters     443
_refine_ls_number_restraints     12
_refine_ls_R_factor_all          0.2274
_refine_ls_R_factor_gt           0.1312
_refine_ls_wR_factor_ref         0.3778
_refine_ls_wR_factor_gt          0.3105
_refine_ls_goodness_of_fit_ref   1.060
_refine_ls_restrained_S_all      1.059
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C11 C 0.087(2) 0.724(3) 0.3569(18) 0.113(14) Uani 1 1 d . . . . .
H11A H 0.080771 0.655398 0.341517 0.136 Uiso 1 1 calc R U . . .
H11B H 0.122285 0.724836 0.411598 0.136 Uiso 1 1 calc R U . . .
C23 C 0.1365(16) 0.6812(19) 0.1089(16) 0.068(7) Uani 1 1 d . . . . .
H23 H 0.120536 0.712436 0.145799 0.081 Uiso 1 1 calc R U . . .
C24 C 0.067(2) 0.643(3) 0.0513(16) 0.109(15) Uani 1 1 d . . . . .
H24 H 0.005157 0.651532 0.046711 0.131 Uiso 1 1 calc R U . . .
C25 C 0.088(3) 0.588(3) -0.004(2) 0.128(16) Uani 1 1 d . . . . .
H25 H 0.041651 0.557168 -0.044889 0.153 Uiso 1 1 calc R U . . .
N7 N 0.2304(15) 0.6812(12) 0.1219(10) 0.054(5) Uani 1 1 d . . . . .
O1 O -0.0021(11) 0.7559(19) 0.3458(18) 0.146(14) Uani 1 1 d . U . . .
H1 H -0.005890 0.815198 0.337607 0.219 Uiso 1 1 calc R U . . .
O1W O -0.151(2) 0.724(4) 0.377(2) 0.24(2) Uani 1 1 d . . . . .
P1 P -0.1562(6) 0.6694(6) 0.1362(5) 0.085(2) Uani 1 1 d . . . . .
F1 F -0.070(2) 0.739(2) 0.1655(15) 0.191(14) Uani 1 1 d . . . . .
F2 F -0.0836(16) 0.581(2) 0.1389(17) 0.172(11) Uani 1 1 d . . . . .
F3 F -0.145(2) 0.643(3) 0.2145(13) 0.198(16) Uani 1 1 d . . . . .
F4 F -0.2404(11) 0.5894(14) 0.1055(11) 0.108(6) Uani 1 1 d . . . . .
F5 F -0.239(2) 0.753(2) 0.112(3) 0.28(3) Uani 1 1 d . . . . .
F6 F -0.1603(16) 0.686(2) 0.0550(14) 0.158(10) Uani 1 1 d . . . . .
C1 C 0.2897(15) 0.9193(16) 0.0803(13) 0.051(5) Uani 1 1 d . . . . .
C2 C 0.3117(17) 0.8762(16) 0.0224(14) 0.060(6) Uani 1 1 d . . . . .
H2 H 0.338463 0.813998 0.028697 0.073 Uiso 1 1 calc R U . . .
C3 C 0.293(2) 0.927(2) -0.0429(14) 0.070(7) Uani 1 1 d . . . . .
H3 H 0.305065 0.899461 -0.083012 0.084 Uiso 1 1 calc R U . . .
C4 C 0.255(2) 1.022(2) -0.0499(16) 0.092(11) Uani 1 1 d . . . . .
H4 H 0.243012 1.057424 -0.094680 0.110 Uiso 1 1 calc R U . . .
C5 C 0.2366(18) 1.062(2) 0.0073(16) 0.082(9) Uani 1 1 d . . . . .
H5A H 0.211813 1.125306 0.002488 0.098 Uiso 1 1 calc R U . . .
C6 C 0.2539(18) 1.0109(16) 0.0711(14) 0.061(6) Uani 1 1 d . . . . .
C7 C 0.2685(14) 0.9522(16) 0.1820(12) 0.048(5) Uani 1 1 d . . . . .
C8 C 0.2730(19) 0.9583(19) 0.2622(14) 0.069(7) Uani 1 1 d . . . . .
H8A H 0.242250 1.018009 0.268130 0.083 Uiso 1 1 calc R U . . .
H8B H 0.337809 0.961552 0.297285 0.083 Uiso 1 1 calc R U . . .
C9 C 0.1602(16) 0.865(2) 0.3104(13) 0.063(7) Uani 1 1 d . . . . .
H9 H 0.128440 0.917454 0.321016 0.076 Uiso 1 1 calc R U . . .
C10 C 0.1485(18) 0.772(2) 0.3202(16) 0.069(7) Uani 1 1 d . . . . .
C12 C 0.4959(14) 0.8695(18) 0.2980(13) 0.054(6) Uani 1 1 d . . . . .
H12 H 0.474472 0.910451 0.255442 0.065 Uiso 1 1 calc R U . . .
C13 C 0.5718(17) 0.901(2) 0.3593(16) 0.072(8) Uani 1 1 d . . . . .
H13 H 0.594840 0.964908 0.362904 0.086 Uiso 1 1 calc R U . . .
C14 C 0.610(3) 0.834(3) 0.414(2) 0.103(11) Uani 1 1 d . . . . .
H14 H 0.663199 0.851756 0.455616 0.124 Uiso 1 1 calc R U . . .
C15 C 0.5773(19) 0.738(2) 0.4113(16) 0.082(9) Uani 1 1 d . . . . .
H15 H 0.607907 0.691202 0.447812 0.098 Uiso 1 1 calc R U . . .
C16 C 0.4943(18) 0.720(3) 0.3497(16) 0.081(9) Uani 1 1 d . . . . .
C17 C 0.4505(15) 0.6255(15) 0.3368(12) 0.046(5) Uani 1 1 d . . . . .
C18 C 0.4844(18) 0.548(2) 0.3873(16) 0.075(8) Uani 1 1 d . . . . .
H18 H 0.536475 0.555867 0.432384 0.089 Uiso 1 1 calc R U . . .
C19 C 0.438(2) 0.453(2) 0.3689(18) 0.083(9) Uani 1 1 d . . . . .
H19 H 0.460034 0.398083 0.400303 0.099 Uiso 1 1 calc R U . . .
C20 C 0.358(2) 0.447(2) 0.3018(18) 0.080(8) Uani 1 1 d . . . . .
H20 H 0.325799 0.388047 0.288566 0.096 Uiso 1 1 calc R U . . .
C21 C 0.3256(17) 0.5250(19) 0.2561(14) 0.061(6) Uani 1 1 d . . . . .
H21 H 0.269221 0.519514 0.214418 0.073 Uiso 1 1 calc R U . . .
C22 C 0.3731(11) 0.6128(13) 0.2685(9) 0.029(4) Uiso 1 1 d . . . . .
C26 C 0.183(2) 0.581(2) 0.0056(16) 0.081(9) Uani 1 1 d . . . . .
H26 H 0.202274 0.545048 -0.027701 0.097 Uiso 1 1 calc R U . . .
C27 C 0.2457(18) 0.6304(13) 0.0660(14) 0.057(6) Uani 1 1 d . . . . .
C28 C 0.349(2) 0.6362(17) 0.0809(16) 0.083(9) Uani 1 1 d . . . . .
C29 C 0.386(2) 0.602(2) 0.0301(18) 0.088(9) Uani 1 1 d . . . . .
H29 H 0.348503 0.567168 -0.012865 0.106 Uiso 1 1 calc R U . . .
C30 C 0.475(3) 0.619(2) 0.0414(19) 0.098(12) Uani 1 1 d . . . . .
H30 H 0.497378 0.597213 0.004770 0.118 Uiso 1 1 calc R U . . .
C31 C 0.537(2) 0.6669(19) 0.107(2) 0.089(10) Uani 1 1 d . . . . .
H31 H 0.600716 0.674207 0.116715 0.107 Uiso 1 1 calc R U . . .
C32 C 0.497(2) 0.7027(19) 0.1547(18) 0.079(9) Uani 1 1 d . . . . .
H32 H 0.534164 0.738130 0.197501 0.095 Uiso 1 1 calc R U . . .
C33 C 0.4108(13) 0.6905(16) 0.1443(11) 0.043(5) Uiso 1 1 d . . . . .
N1 N 0.2965(13) 0.8790(12) 0.1510(8) 0.047(4) Uani 1 1 d . . . . .
N2 N 0.2525(12) 0.7809(10) 0.2755(11) 0.043(4) Uani 1 1 d . . . . .
N3 N 0.2058(14) 0.7185(17) 0.2943(11) 0.063(6) Uani 1 1 d . . . . .
N4 N 0.2269(16) 0.8708(17) 0.2818(13) 0.075(6) Uani 1 1 d . . . . .
N5 N 0.2393(13) 1.0322(13) 0.1392(12) 0.067(6) Uani 1 1 d . . . . .
H5 H 0.216707 1.085063 0.150180 0.080 Uiso 1 1 calc R U . . .
N6 N 0.4507(14) 0.7877(11) 0.2934(11) 0.053(5) Uani 1 1 d . U . . .
Ir1 Ir 0.33647(6) 0.73817(6) 0.20854(5) 0.0470(4) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C11 O1 1.38(4) . ?
C11 C10 1.53(3) . ?
C23 C24 1.31(4) . ?
C23 N7 1.38(3) . ?
C24 C25 1.43(5) . ?
C25 C26 1.42(4) . ?
N7 C27 1.36(3) . ?
N7 Ir1 1.98(2) . ?
P1 F3 1.47(2) . ?
P1 F6 1.53(2) . ?
P1 F1 1.56(2) . ?
P1 F4 1.626(19) . ?
P1 F2 1.63(3) . ?
P1 F5 1.64(3) . ?
C1 C6 1.35(3) . ?
C1 C2 1.40(3) . ?
C1 N1 1.41(2) . ?
C2 C3 1.35(3) . ?
C3 C4 1.40(4) . ?
C4 C5 1.34(4) . ?
C5 C6 1.33(3) . ?
C6 N5 1.42(3) . ?
C7 N1 1.31(2) . ?
C7 N5 1.33(3) . ?
C7 C8 1.50(3) . ?
C8 N4 1.51(3) . ?
C9 C10 1.30(4) . ?
C9 N4 1.34(3) . ?
C10 N3 1.38(3) . ?
C12 N6 1.30(3) . ?
C12 C13 1.37(3) . ?
C13 C14 1.34(4) . ?
C14 C15 1.39(4) . ?
C15 C16 1.39(4) . ?
C16 N6 1.38(4) . ?
C16 C17 1.43(4) . ?
C17 C18 1.39(3) . ?
C17 C22 1.40(3) . ?
C18 C19 1.46(4) . ?
C19 C20 1.40(4) . ?
C20 C21 1.33(4) . ?
C21 C22 1.38(3) . ?
C22 Ir1 2.007(18) . ?
C26 C27 1.36(3) . ?
C27 C28 1.52(4) . ?
C28 C29 1.38(3) . ?
C28 C33 1.42(3) . ?
C29 C30 1.34(4) . ?
C30 C31 1.41(4) . ?
C31 C32 1.38(3) . ?
C32 C33 1.28(3) . ?
C33 Ir1 2.077(19) . ?
N1 Ir1 2.174(15) . ?
N2 N3 1.25(3) . ?
N2 N4 1.31(2) . ?
N2 Ir1 2.217(15) . ?
N6 Ir1 2.00(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 C11 C10 124(3) . . ?
C24 C23 N7 129(3) . . ?
C23 C24 C25 118(3) . . ?
C26 C25 C24 118(3) . . ?
C27 N7 C23 110(2) . . ?
C27 N7 Ir1 120.4(17) . . ?
C23 N7 Ir1 129.1(16) . . ?
F3 P1 F6 173(2) . . ?
F3 P1 F1 92.0(14) . . ?
F6 P1 F1 88.0(14) . . ?
F3 P1 F4 88.2(12) . . ?
F6 P1 F4 91.2(13) . . ?
F1 P1 F4 175.2(16) . . ?
F3 P1 F2 88.8(19) . . ?
F6 P1 F2 84.4(15) . . ?
F1 P1 F2 86.9(16) . . ?
F4 P1 F2 88.2(12) . . ?
F3 P1 F5 103(2) . . ?
F6 P1 F5 83(2) . . ?
F1 P1 F5 98.8(17) . . ?
F4 P1 F5 85.9(13) . . ?
F2 P1 F5 166(2) . . ?
C6 C1 C2 120(2) . . ?
C6 C1 N1 111(2) . . ?
C2 C1 N1 129(2) . . ?
C3 C2 C1 118(2) . . ?
C2 C3 C4 120(2) . . ?
C5 C4 C3 121(2) . . ?
C6 C5 C4 119(3) . . ?
C5 C6 C1 122(2) . . ?
C5 C6 N5 132(2) . . ?
C1 C6 N5 106(2) . . ?
N1 C7 N5 116(2) . . ?
N1 C7 C8 127(2) . . ?
N5 C7 C8 116(2) . . ?
C7 C8 N4 111(2) . . ?
C10 C9 N4 106(2) . . ?
C9 C10 N3 109(2) . . ?
C9 C10 C11 129(3) . . ?
N3 C10 C11 122(3) . . ?
N6 C12 C13 126(2) . . ?
C14 C13 C12 115(3) . . ?
C13 C14 C15 124(3) . . ?
C14 C15 C16 114(3) . . ?
N6 C16 C15 123(3) . . ?
N6 C16 C17 114(2) . . ?
C15 C16 C17 122(3) . . ?
C18 C17 C22 120(2) . . ?
C18 C17 C16 123(2) . . ?
C22 C17 C16 117(2) . . ?
C17 C18 C19 119(3) . . ?
C20 C19 C18 117(3) . . ?
C21 C20 C19 122(3) . . ?
C20 C21 C22 122(2) . . ?
C21 C22 C17 118.6(19) . . ?
C21 C22 Ir1 128.7(16) . . ?
C17 C22 Ir1 112.1(14) . . ?
C27 C26 C25 116(3) . . ?
C26 C27 N7 129(3) . . ?
C26 C27 C28 123(2) . . ?
N7 C27 C28 108(2) . . ?
C29 C28 C33 116(3) . . ?
C29 C28 C27 123(3) . . ?
C33 C28 C27 120(2) . . ?
C30 C29 C28 121(3) . . ?
C29 C30 C31 123(2) . . ?
C32 C31 C30 114(2) . . ?
C33 C32 C31 124(3) . . ?
C32 C33 C28 122(2) . . ?
C32 C33 Ir1 130(2) . . ?
C28 C33 Ir1 108.1(16) . . ?
C7 N1 C1 102.3(17) . . ?
C7 N1 Ir1 121.6(14) . . ?
C1 N1 Ir1 136.1(14) . . ?
N3 N2 N4 112.3(17) . . ?
N3 N2 Ir1 121.1(12) . . ?
N4 N2 Ir1 124.3(14) . . ?
N2 N3 C10 105(2) . . ?
N2 N4 C9 107(2) . . ?
N2 N4 C8 121.9(19) . . ?
C9 N4 C8 131(2) . . ?
C7 N5 C6 104.5(18) . . ?
C12 N6 C16 116(2) . . ?
C12 N6 Ir1 129.1(16) . . ?
C16 N6 Ir1 114.7(16) . . ?
N7 Ir1 N6 175.0(7) . . ?
N7 Ir1 C22 95.8(6) . . ?
N6 Ir1 C22 81.9(6) . . ?
N7 Ir1 C33 82.1(8) . . ?
N6 Ir1 C33 93.3(8) . . ?
C22 Ir1 C33 88.1(7) . . ?
N7 Ir1 N1 86.7(6) . . ?
N6 Ir1 N1 95.8(7) . . ?
C22 Ir1 N1 175.9(6) . . ?
C33 Ir1 N1 95.5(7) . . ?
N7 Ir1 N2 95.4(7) . . ?
N6 Ir1 N2 89.1(7) . . ?
C22 Ir1 N2 90.0(6) . . ?
C33 Ir1 N2 176.7(7) . . ?
N1 Ir1 N2 86.5(6) . . ?

_refine_diff_density_max         4.494
_refine_diff_density_min         -3.826
_refine_diff_density_rms         0.284



_exptl_crystal_preparation       Luminescent
