# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_C5H10N2Cl5Pb2
_database_code_depnum_ccdc_archive 'CCDC 2167972'
loop_
_audit_author_name
_audit_author_address
'Yuyin Wang'
;Jining University
China
;
_audit_update_record             
;
2022-04-21 deposited with the CCDC.	2022-08-18 downloaded from the CCDC.
;
#================================================

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         C5H10N2Cl5Pb2
_chemical_formula_sum            'C5 H10 Cl5 N2 Pb2'
_chemical_formula_weight         689.80

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0030 0.0020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1480 0.1590 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0060 0.0030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3940 10.1110 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'-x-1/2, y-1/2, z'
'x, -y-1/2, z-1/2'

_cell_length_a                   16.358(19)
_cell_length_b                   8.262(10)
_cell_length_c                   20.20(2)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     2730(5)
_cell_formula_units_Z            8
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    9922
_cell_measurement_theta_min      2.32
_cell_measurement_theta_max      24.29

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    3.357
_exptl_crystal_F_000             2423
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.08
_exptl_absorpt_coefficient_mu    25.580
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.3993
_exptl_absorpt_correction_T_max  0.7291
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'Bruker SMART CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            32913
_diffrn_reflns_av_unetI/netI     0.0619
_diffrn_reflns_av_R_equivalents  0.1070
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_theta_min         2.370
_diffrn_reflns_theta_max         28.817
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             3538
_reflns_number_gt                2496
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'APEX2 Software Suite (Bruker,2005)'
_computing_cell_refinement       'APEX2 Software Suite (Bruker,2005)'
_computing_data_reduction        'APEX2 Software Suite (Bruker,2005)'
_computing_structure_solution    'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0133P)²+26.3902P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_extinction_coef       0.00064(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         3538
_refine_ls_number_parameters     123
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0652
_refine_ls_R_factor_gt           0.0368
_refine_ls_wR_factor_ref         0.0938
_refine_ls_wR_factor_gt          0.0820
_refine_ls_goodness_of_fit_ref   1.061
_refine_ls_restrained_S_all      1.061
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pb1 Pb 0.28918(2) 0.36446(4) 0.22882(2) 0.02856(12) Uani 1 1 d . . . . .
Pb2 Pb 0.03918(2) 0.51814(4) 0.25031(2) 0.02631(12) Uani 1 1 d . . . . .
Cl1 Cl 0.12393(14) 0.1930(3) 0.23372(14) 0.0363(6) Uani 1 1 d . . . . .
Cl2 Cl 0.20618(14) 0.5375(3) 0.32386(12) 0.0305(5) Uani 1 1 d . . . . .
Cl3 Cl 0.43516(14) 0.3426(3) 0.33338(11) 0.0285(5) Uani 1 1 d . . . . .
Cl4 Cl 0.46465(15) 0.3436(3) 0.15340(12) 0.0322(5) Uani 1 1 d . . . . .
Cl7 Cl 0.19446(16) 0.5428(3) 0.14280(12) 0.0345(6) Uani 1 1 d . . . . .
N1 N 0.0671(6) 0.1812(12) 0.4857(5) 0.044(2) Uani 1 1 d . . . . .
N2 N 0.1896(8) 0.2431(15) 0.4369(6) 0.067(3) Uani 1 1 d . . . . .
H2 H 0.222874 0.224949 0.404778 0.081 Uiso 1 1 calc R U . . .
C1 C 0.1223(8) 0.1706(13) 0.4377(5) 0.040(3) Uani 1 1 d . . . . .
H1 H 0.110063 0.104200 0.401895 0.048 Uiso 1 1 calc R U . . .
C2 C 0.2125(10) 0.353(2) 0.4866(9) 0.079(5) Uiso 1 1 d . . . . .
H2A H 0.245642 0.438264 0.467551 0.094 Uiso 1 1 calc R U . . .
H2B H 0.244885 0.297440 0.519799 0.094 Uiso 1 1 calc R U . . .
C4 C 0.1383(11) 0.4245(17) 0.5182(9) 0.090(6) Uani 1 1 d . . . . .
H4A H 0.111090 0.495780 0.487024 0.108 Uiso 1 1 calc R U . . .
H4B H 0.154243 0.488003 0.556426 0.108 Uiso 1 1 calc R U . . .
C6 C -0.0083(8) 0.0755(15) 0.4832(6) 0.051(3) Uani 1 1 d . . . . .
H6A H -0.053640 0.130444 0.504458 0.061 Uiso 1 1 calc R U . . .
H6B H -0.023130 0.054522 0.437508 0.061 Uiso 1 1 calc R U . . .
C8 C 0.0794(8) 0.2901(16) 0.5397(6) 0.053(3) Uani 1 1 d . . . . .
H8A H 0.102013 0.232193 0.577195 0.064 Uiso 1 1 calc R U . . .
H8B H 0.027559 0.336933 0.552966 0.064 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pb1 Cl2 2.752(3) . ?
Pb1 Cl7 2.755(3) . ?
Pb1 Cl1 3.054(4) . ?
Pb1 Cl1 3.065(4) 7_665 ?
Pb1 Cl7 3.187(4) 7_655 ?
Pb1 Cl3 3.193(3) . ?
Pb1 Cl4 3.254(4) . ?
Pb1 Cl2 3.315(4) 7_655 ?
Pb1 Pb2 4.032(3) 7_655 ?
Pb1 Pb2 4.303(5) 6_656 ?
Pb1 Pb2 4.304(5) . ?
Pb1 Pb1 4.325(5) 7_665 ?
Pb2 Cl4 2.711(3) 6_556 ?
Pb2 Cl3 2.803(3) 6_556 ?
Pb2 Cl1 3.042(4) . ?
Pb2 Cl1 3.051(4) 4 ?
Pb2 Cl2 3.114(4) . ?
Pb2 Cl3 3.190(4) 7_665 ?
Pb2 Cl4 3.327(4) 7_665 ?
Pb2 Cl7 3.348(4) . ?
Pb2 Pb2 4.325(5) 4_545 ?
N1 C1 1.327(14) . ?
N1 C8 1.428(15) . ?
N1 C6 1.511(16) . ?
N2 C1 1.253(15) . ?
N2 C2 1.404(19) . ?
N2 H2 0.8600 . ?
C1 H1 0.9300 . ?
C2 C4 1.49(2) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C4 C8 1.53(2) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C6 C6 1.45(2) 5_556 ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl2 Pb1 Cl7 83.38(10) . . ?
Cl2 Pb1 Cl1 77.40(9) . . ?
Cl7 Pb1 Cl1 76.74(10) . . ?
Cl2 Pb1 Cl1 75.29(9) . 7_665 ?
Cl7 Pb1 Cl1 78.91(10) . 7_665 ?
Cl1 Pb1 Cl1 145.11(6) . 7_665 ?
Cl2 Pb1 Cl7 148.78(7) . 7_655 ?
Cl7 Pb1 Cl7 98.59(10) . 7_655 ?
Cl1 Pb1 Cl7 72.85(8) . 7_655 ?
Cl1 Pb1 Cl7 135.82(8) 7_665 7_655 ?
Cl2 Pb1 Cl3 86.39(10) . . ?
Cl7 Pb1 Cl3 150.24(8) . . ?
Cl1 Pb1 Cl3 127.90(8) . . ?
Cl1 Pb1 Cl3 71.46(8) 7_665 . ?
Cl7 Pb1 Cl3 104.51(8) 7_655 . ?
Cl2 Pb1 Cl4 142.12(7) . . ?
Cl7 Pb1 Cl4 103.25(10) . . ?
Cl1 Pb1 Cl4 140.48(8) . . ?
Cl1 Pb1 Cl4 69.70(8) 7_665 . ?
Cl7 Pb1 Cl4 68.06(7) 7_655 . ?
Cl3 Pb1 Cl4 69.33(10) . . ?
Cl2 Pb1 Cl2 91.76(10) . 7_655 ?
Cl7 Pb1 Cl2 144.48(8) . 7_655 ?
Cl1 Pb1 Cl2 67.88(8) . 7_655 ?
Cl1 Pb1 Cl2 133.81(8) 7_665 7_655 ?
Cl7 Pb1 Cl2 68.55(10) 7_655 7_655 ?
Cl3 Pb1 Cl2 63.49(7) . 7_655 ?
Cl4 Pb1 Cl2 101.99(7) . 7_655 ?
Cl2 Pb1 Pb2 129.58(7) . 7_655 ?
Cl7 Pb1 Pb2 147.03(6) . 7_655 ?
Cl1 Pb1 Pb2 106.48(10) . 7_655 ?
Cl1 Pb1 Pb2 107.58(10) 7_665 7_655 ?
Cl7 Pb1 Pb2 53.73(7) 7_655 7_655 ?
Cl3 Pb1 Pb2 50.79(6) . 7_655 ?
Cl4 Pb1 Pb2 53.03(7) . 7_655 ?
Cl2 Pb1 Pb2 48.96(6) 7_655 7_655 ?
Cl2 Pb1 Pb2 104.31(7) . 6_656 ?
Cl7 Pb1 Pb2 116.01(8) . 6_656 ?
Cl1 Pb1 Pb2 167.19(5) . 6_656 ?
Cl1 Pb1 Pb2 45.16(5) 7_665 6_656 ?
Cl7 Pb1 Pb2 102.69(6) 7_655 6_656 ?
Cl3 Pb1 Pb2 40.64(6) . 6_656 ?
Cl4 Pb1 Pb2 39.03(6) . 6_656 ?
Cl2 Pb1 Pb2 99.32(5) 7_655 6_656 ?
Pb2 Pb1 Pb2 62.42(7) 7_655 6_656 ?
Cl2 Pb1 Pb2 46.18(5) . . ?
Cl7 Pb1 Pb2 51.06(7) . . ?
Cl1 Pb1 Pb2 44.97(8) . . ?
Cl1 Pb1 Pb2 100.14(8) 7_665 . ?
Cl7 Pb1 Pb2 112.39(5) 7_655 . ?
Cl3 Pb1 Pb2 131.34(7) . . ?
Cl4 Pb1 Pb2 154.28(5) . . ?
Cl2 Pb1 Pb2 101.76(5) 7_655 . ?
Pb2 Pb1 Pb2 149.33(3) 7_655 . ?
Pb2 Pb1 Pb2 143.72(6) 6_656 . ?
Cl2 Pb1 Pb1 50.02(6) . 7_665 ?
Cl7 Pb1 Pb1 47.36(6) . 7_665 ?
Cl1 Pb1 Pb1 100.42(8) . 7_665 ?
Cl1 Pb1 Pb1 44.91(8) 7_665 7_665 ?
Cl7 Pb1 Pb1 145.23(6) 7_655 7_665 ?
Cl3 Pb1 Pb1 106.01(5) . 7_665 ?
Cl4 Pb1 Pb1 108.18(5) . 7_665 ?
Cl2 Pb1 Pb1 141.73(6) 7_655 7_665 ?
Pb2 Pb1 Pb1 152.14(2) 7_655 7_665 ?
Pb2 Pb1 Pb1 89.99(6) 6_656 7_665 ?
Pb2 Pb1 Pb1 55.713(10) . 7_665 ?
Cl4 Pb2 Cl3 83.36(10) 6_556 6_556 ?
Cl4 Pb2 Cl1 79.29(10) 6_556 . ?
Cl3 Pb2 Cl1 75.71(10) 6_556 . ?
Cl4 Pb2 Cl1 77.45(9) 6_556 4 ?
Cl3 Pb2 Cl1 77.17(10) 6_556 4 ?
Cl1 Pb2 Cl1 145.93(6) . 4 ?
Cl4 Pb2 Cl2 94.57(10) 6_556 . ?
Cl3 Pb2 Cl2 147.88(7) 6_556 . ?
Cl1 Pb2 Cl2 72.43(8) . . ?
Cl1 Pb2 Cl2 133.82(9) 4 . ?
Cl4 Pb2 Cl3 97.40(10) 6_556 7_665 ?
Cl3 Pb2 Cl3 146.30(6) 6_556 7_665 ?
Cl1 Pb2 Cl3 137.74(8) . 7_665 ?
Cl1 Pb2 Cl3 70.22(8) 4 7_665 ?
Cl2 Pb2 Cl3 65.82(7) . 7_665 ?
Cl4 Pb2 Cl4 147.54(6) 6_556 7_665 ?
Cl3 Pb2 Cl4 92.97(9) 6_556 7_665 ?
Cl1 Pb2 Cl4 131.12(9) . 7_665 ?
Cl1 Pb2 Cl4 70.31(8) 4 7_665 ?
Cl2 Pb2 Cl4 104.82(7) . 7_665 ?
Cl3 Pb2 Cl4 68.46(10) 7_665 7_665 ?
Cl4 Pb2 Cl7 147.02(7) 6_556 . ?
Cl3 Pb2 Cl7 95.78(10) 6_556 . ?
Cl1 Pb2 Cl7 68.68(8) . . ?
Cl1 Pb2 Cl7 134.69(8) 4 . ?
Cl2 Pb2 Cl7 68.95(10) . . ?
Cl3 Pb2 Cl7 100.97(7) 7_665 . ?
Cl4 Pb2 Cl7 65.38(7) 7_665 . ?
Cl4 Pb2 Pb1 140.17(6) 6_556 7_665 ?
Cl3 Pb2 Pb1 136.47(7) 6_556 7_665 ?
Cl1 Pb2 Pb1 107.31(10) . 7_665 ?
Cl1 Pb2 Pb1 106.52(10) 4 7_665 ?
Cl2 Pb2 Pb1 53.41(7) . 7_665 ?
Cl3 Pb2 Pb1 50.86(6) 7_665 7_665 ?
Cl4 Pb2 Pb1 51.41(6) 7_665 7_665 ?
Cl7 Pb2 Pb1 50.12(6) . 7_665 ?
Cl4 Pb2 Pb1 49.11(6) 6_556 6_556 ?
Cl3 Pb2 Pb1 47.89(6) 6_556 6_556 ?
Cl1 Pb2 Pb1 100.56(8) . 6_556 ?
Cl1 Pb2 Pb1 45.43(8) 4 6_556 ?
Cl2 Pb2 Pb1 143.35(7) . 6_556 ?
Cl3 Pb2 Pb1 108.75(5) 7_665 6_556 ?
Cl4 Pb2 Pb1 106.15(5) 7_665 6_556 ?
Cl7 Pb2 Pb1 143.37(6) . 6_556 ?
Pb1 Pb2 Pb1 151.85(2) 7_665 6_556 ?
Cl4 Pb2 Pb1 110.04(7) 6_556 . ?
Cl3 Pb2 Pb1 111.30(8) 6_556 . ?
Cl1 Pb2 Pb1 45.19(5) . . ?
Cl1 Pb2 Pb1 168.88(5) 4 . ?
Cl2 Pb2 Pb1 39.62(6) . . ?
Cl3 Pb2 Pb1 100.13(6) 7_665 . ?
Cl4 Pb2 Pb1 101.36(5) 7_665 . ?
Cl7 Pb2 Pb1 39.80(6) . . ?
Pb1 Pb2 Pb1 62.41(7) 7_665 . ?
Pb1 Pb2 Pb1 145.68(6) 6_556 . ?
Cl4 Pb2 Pb2 50.26(6) 6_556 4_545 ?
Cl3 Pb2 Pb2 47.47(5) 6_556 4_545 ?
Cl1 Pb2 Pb2 44.86(8) . 4_545 ?
Cl1 Pb2 Pb2 101.15(8) 4 4_545 ?
Cl2 Pb2 Pb2 108.09(5) . 4_545 ?
Cl3 Pb2 Pb2 147.46(6) 7_665 4_545 ?
Cl4 Pb2 Pb2 139.87(6) 7_665 4_545 ?
Cl7 Pb2 Pb2 106.32(5) . 4_545 ?
Pb1 Pb2 Pb2 152.10(3) 7_665 4_545 ?
Pb1 Pb2 Pb2 55.721(10) 6_556 4_545 ?
Pb1 Pb2 Pb2 89.97(5) . 4_545 ?
Pb2 Cl1 Pb2 90.46(10) . 4_545 ?
Pb2 Cl1 Pb1 89.84(10) . . ?
Pb2 Cl1 Pb1 175.72(11) 4_545 . ?
Pb2 Cl1 Pb1 175.51(11) . 7_655 ?
Pb2 Cl1 Pb1 89.41(10) 4_545 7_655 ?
Pb1 Cl1 Pb1 89.96(10) . 7_655 ?
Pb1 Cl2 Pb2 94.20(10) . . ?
Pb1 Cl2 Pb1 90.46(10) . 7_665 ?
Pb2 Cl2 Pb1 77.62(6) . 7_665 ?
Pb2 Cl3 Pb2 92.16(9) 6_656 7_655 ?
Pb2 Cl3 Pb1 91.47(10) 6_656 . ?
Pb2 Cl3 Pb1 78.35(7) 7_655 . ?
Pb2 Cl4 Pb1 91.87(9) 6_656 . ?
Pb2 Cl4 Pb2 90.93(10) 6_656 7_655 ?
Pb1 Cl4 Pb2 75.56(6) . 7_655 ?
Pb1 Cl7 Pb1 93.14(10) . 7_665 ?
Pb1 Cl7 Pb2 89.14(10) . . ?
Pb1 Cl7 Pb2 76.15(7) 7_665 . ?
C1 N1 C8 120.2(10) . . ?
C1 N1 C6 119.5(10) . . ?
C8 N1 C6 120.3(9) . . ?
C1 N2 C2 122.2(12) . . ?
C1 N2 H2 118.9 . . ?
C2 N2 H2 118.9 . . ?
N2 C1 N1 125.2(11) . . ?
N2 C1 H1 117.4 . . ?
N1 C1 H1 117.4 . . ?
N2 C2 C4 110.2(13) . . ?
N2 C2 H2A 109.6 . . ?
C4 C2 H2A 109.6 . . ?
N2 C2 H2B 109.6 . . ?
C4 C2 H2B 109.6 . . ?
H2A C2 H2B 108.1 . . ?
C2 C4 C8 110.2(12) . . ?
C2 C4 H4A 109.6 . . ?
C8 C4 H4A 109.6 . . ?
C2 C4 H4B 109.6 . . ?
C8 C4 H4B 109.6 . . ?
H4A C4 H4B 108.1 . . ?
C6 C6 N1 109.3(13) 5_556 . ?
C6 C6 H6A 109.8 5_556 . ?
N1 C6 H6A 109.8 . . ?
C6 C6 H6B 109.8 5_556 . ?
N1 C6 H6B 109.8 . . ?
H6A C6 H6B 108.3 . . ?
N1 C8 C4 109.2(10) . . ?
N1 C8 H8A 109.8 . . ?
C4 C8 H8A 109.8 . . ?
N1 C8 H8B 109.8 . . ?
C4 C8 H8B 109.8 . . ?
H8A C8 H8B 108.3 . . ?

_refine_diff_density_max         2.046
_refine_diff_density_min         -1.411
_refine_diff_density_rms         0.285



