# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_23_a
_database_code_depnum_ccdc_archive 'CCDC 2193753'
loop_
_audit_author_name
_audit_author_address
JIANG
;zhejiang normal university
China
;
_audit_update_record             
;
2022-07-30 deposited with the CCDC.	2022-11-01 downloaded from the CCDC.
;
_audit_creation_date             2022-07-29
_audit_creation_method           
;
Olex2 1.5
(compiled 2021.08.20 svn.r13c46975 for OlexSys, GUI svn.r6392)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '2(F6 Sb), C72 H60 Ag2 P4 S4, 2(C H2 Cl2)'
_chemical_formula_sum            'C74 H64 Ag2 Cl4 F12 P0.50 S8 Sb2'
_chemical_formula_weight         2054.25
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   11.425(2)
_cell_length_b                   16.178(4)
_cell_length_c                   22.012(5)
_cell_angle_alpha                90
_cell_angle_beta                 96.707(8)
_cell_angle_gamma                90
_cell_volume                     4040.4(15)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    7458
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      25.06
_cell_measurement_theta_min      2.68
_shelx_estimated_absorpt_T_max   0.860
_shelx_estimated_absorpt_T_min   0.860
_exptl_absorpt_coefficient_mu    1.556
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_correction_T_min  0.6414
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0796 before and 0.0489 after correction.
The Ratio of minimum to maximum transmission is 0.8607.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.689
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2031
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0401
_diffrn_reflns_av_unetI/netI     0.0375
_diffrn_reflns_Laue_measured_fraction_full 0.984
_diffrn_reflns_Laue_measured_fraction_max 0.984
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            24003
_diffrn_reflns_point_group_measured_fraction_full 0.984
_diffrn_reflns_point_group_measured_fraction_max 0.984
_diffrn_reflns_theta_full        25.078
_diffrn_reflns_theta_max         25.078
_diffrn_reflns_theta_min         2.734
_diffrn_ambient_temperature      298.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'BRUKER D8 VENTURE'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5466
_reflns_number_total             7075
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (?, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.093
_refine_diff_density_min         -0.803
_refine_diff_density_rms         0.087
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     460
_refine_ls_number_reflns         7075
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0718
_refine_ls_R_factor_gt           0.0542
_refine_ls_restrained_S_all      1.034
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0885P)²+7.1011P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1496
_refine_ls_wR_factor_ref         0.1653
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C01E(H01A,H01B)
2.b Aromatic/amide H refined with riding coordinates:
 C009(H009), C00E(H00E), C00H(H00H), C00I(H00I), C00J(H00J), C00K(H00K),
 C00L(H00L), C00M(H00M), C00N(H00N), C00O(H00O), C00P(H00P), C00Q(H00Q),
 C00R(H00R), C00S(H00S), C00T(H00T), C00U(H00U), C00V(H00V), C00W(H00W),
 C00X(H00X), C00Y(H00Y), C00Z(H00Z), C010(H010), C011(H011), C012(H012),
 C013(H013), C014(H014), C016(H016), C017(H017), C018(H018), C019(H019)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb01 Sb 0.27453(4) 0.93910(3) 0.62312(2) 0.06910(18) Uani 1 1 d . . . . .
Ag02 Ag 0.95067(6) 0.54121(3) 0.42624(2) 0.0771(2) Uani 1 1 d . . . . .
P003 P 0.85152(11) 0.65430(8) 0.54634(6) 0.0438(3) Uani 1 1 d . . . . .
S004 S 0.84552(13) 0.53515(8) 0.52079(7) 0.0540(3) Uani 1 1 d . . . . .
P005 P 0.79569(12) 0.56791(8) 0.28387(6) 0.0471(3) Uani 1 1 d . . . . .
S006 S 0.96273(13) 0.57989(12) 0.32107(7) 0.0676(4) Uani 1 1 d . . . . .
Cl00 Cl 0.2959(3) 0.7303(3) 0.81681(18) 0.1711(14) Uani 1 1 d . . . . .
Cl1 Cl 0.2966(4) 0.8985(3) 0.8595(2) 0.1793(15) Uani 1 1 d . . . . .
C009 C 1.0688(5) 0.6826(3) 0.5078(3) 0.0574(13) Uani 1 1 d . . . . .
H009 H 1.092558 0.635978 0.530679 0.069 Uiso 1 1 calc R U . . .
C00A C 0.9533(4) 0.7122(3) 0.5062(2) 0.0466(11) Uani 1 1 d . . . . .
C00B C 0.8972(5) 0.6654(3) 0.6270(2) 0.0506(12) Uani 1 1 d . . . . .
C00C C 0.7884(5) 0.5346(3) 0.2053(2) 0.0551(13) Uani 1 1 d . . . . .
C00D C 0.7165(4) 0.6647(3) 0.2831(2) 0.0496(12) Uani 1 1 d . . . . .
C00E C 0.8829(6) 0.5498(4) 0.1722(3) 0.0720(17) Uani 1 1 d . . . . .
H00E H 0.952273 0.572850 0.191316 0.086 Uiso 1 1 calc R U . . .
C00F C 0.7176(5) 0.4933(3) 0.3242(2) 0.0541(13) Uani 1 1 d . . . . .
C00G C 0.7093(4) 0.7021(3) 0.5294(2) 0.0517(12) Uani 1 1 d . . . . .
C00H C 0.9700(5) 0.7288(4) 0.6496(3) 0.0652(15) Uani 1 1 d . . . . .
H00H H 0.998693 0.766199 0.622880 0.078 Uiso 1 1 calc R U . . .
C00I C 1.1471(6) 0.7236(5) 0.4750(4) 0.0794(19) Uani 1 1 d . . . . .
H00I H 1.223399 0.703743 0.474630 0.095 Uiso 1 1 calc R U . . .
C00J C 0.6862(6) 0.4997(4) 0.1764(3) 0.0719(17) Uani 1 1 d . . . . .
H00J H 0.623284 0.488322 0.198366 0.086 Uiso 1 1 calc R U . . .
C00K C 0.7380(7) 0.7169(4) 0.3318(3) 0.0761(18) Uani 1 1 d . . . . .
H00K H 0.793508 0.702638 0.364408 0.091 Uiso 1 1 calc R U . . .
C00L C 0.9207(5) 0.7836(4) 0.4741(3) 0.0624(14) Uani 1 1 d . . . . .
H00L H 0.844845 0.804492 0.474080 0.075 Uiso 1 1 calc R U . . .
C00M C 0.6148(7) 0.5114(5) 0.3477(4) 0.081(2) Uani 1 1 d . . . . .
H00M H 0.579581 0.562960 0.341387 0.097 Uiso 1 1 calc R U . . .
C00N C 0.6296(5) 0.6720(5) 0.4839(3) 0.0767(19) Uani 1 1 d . . . . .
H00N H 0.646137 0.623714 0.463612 0.092 Uiso 1 1 calc R U . . .
C00O C 0.7639(7) 0.4146(4) 0.3317(3) 0.0756(18) Uani 1 1 d . . . . .
H00O H 0.833163 0.401747 0.315390 0.091 Uiso 1 1 calc R U . . .
C00P C 0.6815(6) 0.7713(4) 0.5605(4) 0.080(2) Uani 1 1 d . . . . .
H00P H 0.733759 0.790755 0.592959 0.097 Uiso 1 1 calc R U . . .
C00Q C 0.8561(7) 0.6104(5) 0.6681(3) 0.0773(18) Uani 1 1 d . . . . .
H00Q H 0.807723 0.566562 0.653907 0.093 Uiso 1 1 calc R U . . .
C00R C 0.4993(6) 0.7837(5) 0.4974(4) 0.086(2) Uani 1 1 d . . . . .
H00R H 0.429482 0.811960 0.485654 0.103 Uiso 1 1 calc R U . . .
C00S C 1.1113(7) 0.7941(5) 0.4429(4) 0.084(2) Uani 1 1 d . . . . .
H00S H 1.164418 0.821974 0.421275 0.101 Uiso 1 1 calc R U . . .
C00T C 0.6784(8) 0.4817(5) 0.1141(4) 0.092(2) Uani 1 1 d . . . . .
H00T H 0.609554 0.458899 0.094255 0.110 Uiso 1 1 calc R U . . .
C00U C 0.8723(9) 0.5300(6) 0.1102(3) 0.095(3) Uani 1 1 d . . . . .
H00U H 0.935298 0.539322 0.087871 0.113 Uiso 1 1 calc R U . . .
C00V C 0.9996(7) 0.8238(5) 0.4422(3) 0.082(2) Uani 1 1 d . . . . .
H00V H 0.976908 0.871308 0.420126 0.098 Uiso 1 1 calc R U . . .
C00W C 1.0007(7) 0.7370(5) 0.7120(3) 0.087(2) Uani 1 1 d . . . . .
H00W H 1.050169 0.779802 0.726991 0.105 Uiso 1 1 calc R U . . .
C00X C 0.6782(8) 0.7902(5) 0.3329(4) 0.095(2) Uani 1 1 d . . . . .
H00X H 0.693316 0.825097 0.366474 0.114 Uiso 1 1 calc R U . . .
C00Y C 0.9593(8) 0.6833(6) 0.7513(3) 0.092(2) Uani 1 1 d . . . . .
H00Y H 0.980636 0.689605 0.793155 0.110 Uiso 1 1 calc R U . . .
C00Z C 0.5764(6) 0.8127(5) 0.5442(4) 0.093(2) Uani 1 1 d . . . . .
H00Z H 0.558701 0.860197 0.565142 0.112 Uiso 1 1 calc R U . . .
C010 C 0.6345(7) 0.6859(5) 0.2359(3) 0.090(2) Uani 1 1 d . . . . .
H010 H 0.617383 0.650679 0.202650 0.108 Uiso 1 1 calc R U . . .
C011 C 0.5988(8) 0.8122(5) 0.2865(5) 0.095(2) Uani 1 1 d . . . . .
H011 H 0.559184 0.862291 0.287536 0.114 Uiso 1 1 calc R U . . .
C012 C 0.7096(9) 0.3551(5) 0.3628(4) 0.102(3) Uani 1 1 d . . . . .
H012 H 0.740364 0.301859 0.366097 0.122 Uiso 1 1 calc R U . . .
C013 C 0.7716(10) 0.4974(6) 0.0822(4) 0.104(3) Uani 1 1 d . . . . .
H013 H 0.765383 0.485467 0.040599 0.125 Uiso 1 1 calc R U . . .
C014 C 0.8880(8) 0.6212(6) 0.7308(3) 0.097(3) Uani 1 1 d . . . . .
H014 H 0.859504 0.585062 0.758461 0.117 Uiso 1 1 calc R U . . .
F015 F 0.3708(9) 0.8521(6) 0.6506(5) 0.225(4) Uani 1 1 d . . . . .
C016 C 0.5243(6) 0.7128(6) 0.4676(4) 0.100(3) Uani 1 1 d . . . . .
H016 H 0.470440 0.692003 0.436394 0.120 Uiso 1 1 calc R U . . .
C017 C 0.6105(10) 0.3740(6) 0.3887(4) 0.108(3) Uani 1 1 d . . . . .
H017 H 0.575504 0.334291 0.411263 0.130 Uiso 1 1 calc R U . . .
C018 C 0.5631(9) 0.4498(7) 0.3818(5) 0.113(3) Uani 1 1 d . . . . .
H018 H 0.495413 0.462183 0.399727 0.135 Uiso 1 1 calc R U . . .
C019 C 0.5764(9) 0.7614(6) 0.2382(5) 0.120(3) Uani 1 1 d . . . . .
H019 H 0.521213 0.776865 0.205814 0.144 Uiso 1 1 calc R U . . .
F01A F 0.1906(8) 1.0280(6) 0.6027(7) 0.265(6) Uani 1 1 d . . . . .
F01B F 0.3782(11) 0.9909(7) 0.6727(9) 0.361(11) Uani 1 1 d . . . . .
F01C F 0.3506(12) 0.9427(13) 0.5619(6) 0.418(14) Uani 1 1 d . . . . .
F01D F 0.1812(9) 0.9029(13) 0.6718(7) 0.388(12) Uani 1 1 d . . . . .
C01E C 0.307(2) 0.8360(11) 0.8019(7) 0.225(9) Uani 1 1 d . . . . .
H01A H 0.381531 0.845893 0.786543 0.270 Uiso 1 1 calc R U . . .
H01B H 0.245005 0.850303 0.769473 0.270 Uiso 1 1 calc R U . . .
F5 F 0.1713(16) 0.8934(12) 0.5691(7) 0.403(11) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb01 F015 1.844(7) . ?
Sb01 F01A 1.758(7) . ?
Sb01 F01B 1.731(9) . ?
Sb01 F01C 1.687(9) . ?
Sb01 F01D 1.701(9) . ?
Sb01 F5 1.739(10) . ?
Ag02 S004 2.7699(16) 3_766 ?
Ag02 S004 2.5235(16) . ?
Ag02 S006 2.4175(17) . ?
P003 S004 2.0068(19) . ?
P003 C00A 1.803(5) . ?
P003 C00B 1.800(5) . ?
P003 C00G 1.799(5) . ?
P005 S006 1.996(2) . ?
P005 C00C 1.805(5) . ?
P005 C00D 1.807(5) . ?
P005 C00F 1.796(6) . ?
Cl00 C01E 1.748(17) . ?
Cl1 C01E 1.636(17) . ?
C009 H009 0.9300 . ?
C009 C00A 1.400(7) . ?
C009 C00I 1.383(9) . ?
C00A C00L 1.383(8) . ?
C00B C00H 1.376(8) . ?
C00B C00Q 1.389(9) . ?
C00C C00E 1.392(9) . ?
C00C C00J 1.383(9) . ?
C00D C00K 1.364(8) . ?
C00D C010 1.360(8) . ?
C00E H00E 0.9300 . ?
C00E C00U 1.395(10) . ?
C00F C00M 1.369(9) . ?
C00F C00O 1.381(9) . ?
C00G C00N 1.364(8) . ?
C00G C00P 1.369(8) . ?
C00H H00H 0.9300 . ?
C00H C00W 1.384(9) . ?
C00I H00I 0.9300 . ?
C00I C00S 1.379(11) . ?
C00J H00J 0.9300 . ?
C00J C00T 1.395(10) . ?
C00K H00K 0.9300 . ?
C00K C00X 1.370(10) . ?
C00L H00L 0.9300 . ?
C00L C00V 1.368(9) . ?
C00M H00M 0.9300 . ?
C00M C018 1.416(11) . ?
C00N H00N 0.9300 . ?
C00N C016 1.381(10) . ?
C00O H00O 0.9300 . ?
C00O C012 1.371(11) . ?
C00P H00P 0.9300 . ?
C00P C00Z 1.386(9) . ?
C00Q H00Q 0.9300 . ?
C00Q C014 1.397(10) . ?
C00R H00R 0.9300 . ?
C00R C00Z 1.358(11) . ?
C00R C016 1.368(11) . ?
C00S H00S 0.9300 . ?
C00S C00V 1.362(11) . ?
C00T H00T 0.9300 . ?
C00T C013 1.366(13) . ?
C00U H00U 0.9300 . ?
C00U C013 1.347(13) . ?
C00V H00V 0.9300 . ?
C00W H00W 0.9300 . ?
C00W C00Y 1.349(12) . ?
C00X H00X 0.9300 . ?
C00X C011 1.333(11) . ?
C00Y H00Y 0.9300 . ?
C00Y C014 1.339(12) . ?
C00Z H00Z 0.9300 . ?
C010 H010 0.9300 . ?
C010 C019 1.393(11) . ?
C011 H011 0.9300 . ?
C011 C019 1.344(12) . ?
C012 H012 0.9300 . ?
C012 C017 1.361(13) . ?
C013 H013 0.9300 . ?
C014 H014 0.9300 . ?
C016 H016 0.9300 . ?
C017 H017 0.9300 . ?
C017 C018 1.342(14) . ?
C018 H018 0.9300 . ?
C019 H019 0.9300 . ?
C01E H01A 0.9700 . ?
C01E H01B 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
F01A Sb01 F015 174.3(6) . . ?
F01B Sb01 F015 79.9(6) . . ?
F01B Sb01 F01A 94.5(6) . . ?
F01B Sb01 F5 175.4(9) . . ?
F01C Sb01 F015 86.9(5) . . ?
F01C Sb01 F01A 94.8(6) . . ?
F01C Sb01 F01B 96.2(10) . . ?
F01C Sb01 F01D 159.0(12) . . ?
F01C Sb01 F5 80.8(9) . . ?
F01D Sb01 F015 85.7(6) . . ?
F01D Sb01 F01A 94.6(7) . . ?
F01D Sb01 F01B 101.7(10) . . ?
F01D Sb01 F5 81.9(9) . . ?
F5 Sb01 F015 103.4(8) . . ?
F5 Sb01 F01A 82.3(8) . . ?
S004 Ag02 S004 95.35(5) . 3_766 ?
S006 Ag02 S004 152.34(6) . . ?
S006 Ag02 S004 112.29(5) . 3_766 ?
C00A P003 S004 111.39(17) . . ?
C00B P003 S004 111.66(19) . . ?
C00B P003 C00A 107.6(2) . . ?
C00G P003 S004 110.78(19) . . ?
C00G P003 C00A 107.1(2) . . ?
C00G P003 C00B 108.2(2) . . ?
Ag02 S004 Ag02 84.65(5) . 3_766 ?
P003 S004 Ag02 100.94(7) . . ?
P003 S004 Ag02 108.11(7) . 3_766 ?
C00C P005 S006 110.9(2) . . ?
C00C P005 C00D 106.4(2) . . ?
C00D P005 S006 111.93(19) . . ?
C00F P005 S006 111.65(18) . . ?
C00F P005 C00C 107.6(3) . . ?
C00F P005 C00D 108.0(3) . . ?
P005 S006 Ag02 102.07(8) . . ?
C00A C009 H009 120.4 . . ?
C00I C009 H009 120.4 . . ?
C00I C009 C00A 119.2(6) . . ?
C009 C00A P003 118.0(4) . . ?
C00L C00A P003 122.3(4) . . ?
C00L C00A C009 119.7(5) . . ?
C00H C00B P003 121.6(4) . . ?
C00H C00B C00Q 118.6(5) . . ?
C00Q C00B P003 119.8(5) . . ?
C00E C00C P005 119.8(5) . . ?
C00J C00C P005 120.2(5) . . ?
C00J C00C C00E 119.8(6) . . ?
C00K C00D P005 119.0(4) . . ?
C010 C00D P005 121.7(5) . . ?
C010 C00D C00K 119.2(6) . . ?
C00C C00E H00E 120.4 . . ?
C00C C00E C00U 119.1(7) . . ?
C00U C00E H00E 120.4 . . ?
C00M C00F P005 122.7(5) . . ?
C00M C00F C00O 119.0(6) . . ?
C00O C00F P005 118.3(5) . . ?
C00N C00G P003 120.5(5) . . ?
C00N C00G C00P 119.1(6) . . ?
C00P C00G P003 120.3(4) . . ?
C00B C00H H00H 119.9 . . ?
C00B C00H C00W 120.2(7) . . ?
C00W C00H H00H 119.9 . . ?
C009 C00I H00I 120.2 . . ?
C00S C00I C009 119.5(6) . . ?
C00S C00I H00I 120.2 . . ?
C00C C00J H00J 120.3 . . ?
C00C C00J C00T 119.4(7) . . ?
C00T C00J H00J 120.3 . . ?
C00D C00K H00K 119.8 . . ?
C00D C00K C00X 120.4(7) . . ?
C00X C00K H00K 119.8 . . ?
C00A C00L H00L 119.8 . . ?
C00V C00L C00A 120.3(6) . . ?
C00V C00L H00L 119.8 . . ?
C00F C00M H00M 120.7 . . ?
C00F C00M C018 118.6(8) . . ?
C018 C00M H00M 120.7 . . ?
C00G C00N H00N 119.8 . . ?
C00G C00N C016 120.4(7) . . ?
C016 C00N H00N 119.8 . . ?
C00F C00O H00O 119.4 . . ?
C012 C00O C00F 121.2(8) . . ?
C012 C00O H00O 119.4 . . ?
C00G C00P H00P 119.7 . . ?
C00G C00P C00Z 120.7(7) . . ?
C00Z C00P H00P 119.7 . . ?
C00B C00Q H00Q 120.2 . . ?
C00B C00Q C014 119.6(7) . . ?
C014 C00Q H00Q 120.2 . . ?
C00Z C00R H00R 120.0 . . ?
C00Z C00R C016 120.0(7) . . ?
C016 C00R H00R 120.0 . . ?
C00I C00S H00S 119.4 . . ?
C00V C00S C00I 121.2(6) . . ?
C00V C00S H00S 119.4 . . ?
C00J C00T H00T 119.9 . . ?
C013 C00T C00J 120.2(8) . . ?
C013 C00T H00T 119.9 . . ?
C00E C00U H00U 119.7 . . ?
C013 C00U C00E 120.7(8) . . ?
C013 C00U H00U 119.7 . . ?
C00L C00V H00V 120.0 . . ?
C00S C00V C00L 120.0(7) . . ?
C00S C00V H00V 120.0 . . ?
C00H C00W H00W 119.7 . . ?
C00Y C00W C00H 120.5(8) . . ?
C00Y C00W H00W 119.7 . . ?
C00K C00X H00X 119.6 . . ?
C011 C00X C00K 120.9(7) . . ?
C011 C00X H00X 119.6 . . ?
C00W C00Y H00Y 119.6 . . ?
C014 C00Y C00W 120.8(7) . . ?
C014 C00Y H00Y 119.6 . . ?
C00P C00Z H00Z 120.2 . . ?
C00R C00Z C00P 119.7(7) . . ?
C00R C00Z H00Z 120.2 . . ?
C00D C010 H010 120.6 . . ?
C00D C010 C019 118.8(7) . . ?
C019 C010 H010 120.6 . . ?
C00X C011 H011 120.3 . . ?
C00X C011 C019 119.5(7) . . ?
C019 C011 H011 120.3 . . ?
C00O C012 H012 120.0 . . ?
C017 C012 C00O 119.9(8) . . ?
C017 C012 H012 120.0 . . ?
C00T C013 H013 119.6 . . ?
C00U C013 C00T 120.8(7) . . ?
C00U C013 H013 119.6 . . ?
C00Q C014 H014 119.8 . . ?
C00Y C014 C00Q 120.4(8) . . ?
C00Y C014 H014 119.8 . . ?
C00N C016 H016 120.0 . . ?
C00R C016 C00N 120.0(7) . . ?
C00R C016 H016 120.0 . . ?
C012 C017 H017 119.9 . . ?
C018 C017 C012 120.1(8) . . ?
C018 C017 H017 119.9 . . ?
C00M C018 H018 119.5 . . ?
C017 C018 C00M 121.0(9) . . ?
C017 C018 H018 119.5 . . ?
C010 C019 H019 119.4 . . ?
C011 C019 C010 121.2(8) . . ?
C011 C019 H019 119.4 . . ?
Cl00 C01E H01A 108.2 . . ?
Cl00 C01E H01B 108.2 . . ?
Cl1 C01E Cl00 116.5(9) . . ?
Cl1 C01E H01A 108.2 . . ?
Cl1 C01E H01B 108.2 . . ?
H01A C01E H01B 107.3 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P003 C00A C00L C00V -177.4(5) . . . . ?
P003 C00B C00H C00W 178.1(5) . . . . ?
P003 C00B C00Q C014 -177.4(6) . . . . ?
P003 C00G C00N C016 -174.7(6) . . . . ?
P003 C00G C00P C00Z 174.3(6) . . . . ?
S004 P003 C00A C009 -53.3(4) . . . . ?
S004 P003 C00A C00L 126.3(4) . . . . ?
S004 P003 C00B C00H 141.9(4) . . . . ?
S004 P003 C00B C00Q -39.8(5) . . . . ?
S004 P003 C00G C00N -25.4(6) . . . . ?
S004 P003 C00G C00P 157.3(5) . . . . ?
P005 C00C C00E C00U -174.7(5) . . . . ?
P005 C00C C00J C00T 173.9(5) . . . . ?
P005 C00D C00K C00X -179.2(6) . . . . ?
P005 C00D C010 C019 179.9(7) . . . . ?
P005 C00F C00M C018 -176.4(6) . . . . ?
P005 C00F C00O C012 179.1(6) . . . . ?
S006 P005 C00C C00E -23.7(5) . . . . ?
S006 P005 C00C C00J 161.1(5) . . . . ?
S006 P005 C00D C00K -38.0(5) . . . . ?
S006 P005 C00D C010 143.4(6) . . . . ?
S006 P005 C00F C00M 124.8(5) . . . . ?
S006 P005 C00F C00O -55.1(5) . . . . ?
C009 C00A C00L C00V 2.3(9) . . . . ?
C009 C00I C00S C00V -0.8(11) . . . . ?
C00A P003 C00B C00H 19.4(5) . . . . ?
C00A P003 C00B C00Q -162.3(5) . . . . ?
C00A P003 C00G C00N 96.2(6) . . . . ?
C00A P003 C00G C00P -81.1(6) . . . . ?
C00A C009 C00I C00S 2.0(10) . . . . ?
C00A C00L C00V C00S -1.0(11) . . . . ?
C00B P003 C00A C009 69.4(5) . . . . ?
C00B P003 C00A C00L -111.0(5) . . . . ?
C00B P003 C00G C00N -148.1(5) . . . . ?
C00B P003 C00G C00P 34.6(6) . . . . ?
C00B C00H C00W C00Y -0.3(11) . . . . ?
C00B C00Q C014 C00Y -1.2(12) . . . . ?
C00C P005 C00D C00K -159.3(5) . . . . ?
C00C P005 C00D C010 22.1(6) . . . . ?
C00C P005 C00F C00M -113.3(6) . . . . ?
C00C P005 C00F C00O 66.9(5) . . . . ?
C00C C00E C00U C013 0.7(11) . . . . ?
C00C C00J C00T C013 0.9(11) . . . . ?
C00D P005 C00C C00E 98.3(5) . . . . ?
C00D P005 C00C C00J -76.9(5) . . . . ?
C00D P005 C00F C00M 1.3(6) . . . . ?
C00D P005 C00F C00O -178.6(5) . . . . ?
C00D C00K C00X C011 -0.4(13) . . . . ?
C00D C010 C019 C011 -1.2(16) . . . . ?
C00E C00C C00J C00T -1.3(10) . . . . ?
C00E C00U C013 C00T -1.2(13) . . . . ?
C00F P005 C00C C00E -146.1(5) . . . . ?
C00F P005 C00C C00J 38.7(6) . . . . ?
C00F P005 C00D C00K 85.3(5) . . . . ?
C00F P005 C00D C010 -93.3(6) . . . . ?
C00F C00M C018 C017 -3.1(14) . . . . ?
C00F C00O C012 C017 -2.4(12) . . . . ?
C00G P003 C00A C009 -174.6(4) . . . . ?
C00G P003 C00A C00L 5.1(5) . . . . ?
C00G P003 C00B C00H -96.0(5) . . . . ?
C00G P003 C00B C00Q 82.4(5) . . . . ?
C00G C00N C016 C00R -0.2(13) . . . . ?
C00G C00P C00Z C00R 1.0(13) . . . . ?
C00H C00B C00Q C014 0.9(10) . . . . ?
C00H C00W C00Y C014 0.0(12) . . . . ?
C00I C009 C00A P003 176.9(5) . . . . ?
C00I C009 C00A C00L -2.7(8) . . . . ?
C00I C00S C00V C00L 0.3(12) . . . . ?
C00J C00C C00E C00U 0.5(10) . . . . ?
C00J C00T C013 C00U 0.4(13) . . . . ?
C00K C00D C010 C019 1.3(12) . . . . ?
C00K C00X C011 C019 0.5(15) . . . . ?
C00M C00F C00O C012 -0.8(10) . . . . ?
C00N C00G C00P C00Z -3.1(11) . . . . ?
C00O C00F C00M C018 3.4(11) . . . . ?
C00O C012 C017 C018 2.7(14) . . . . ?
C00P C00G C00N C016 2.7(11) . . . . ?
C00Q C00B C00H C00W -0.2(9) . . . . ?
C00W C00Y C014 C00Q 0.7(13) . . . . ?
C00X C011 C019 C010 0.3(17) . . . . ?
C00Z C00R C016 C00N -1.9(14) . . . . ?
C010 C00D C00K C00X -0.5(11) . . . . ?
C012 C017 C018 C00M 0.0(15) . . . . ?
C016 C00R C00Z C00P 1.5(14) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
