# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 2211477'
loop_
_audit_author_name
_audit_author_address
'Pablo Albores'
;Universidad de Buenos Airea
Argentina
;
_audit_update_record             
;
2022-10-06 deposited with the CCDC.	2022-11-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C33.33 H57.33 Co2.67 N2.67 O12'
_chemical_formula_weight         844.63

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   13.6175(5)
_cell_length_b                   11.0711(3)
_cell_length_c                   20.4071(7)
_cell_angle_alpha                90.0
_cell_angle_beta                 105.529(3)
_cell_angle_gamma                90.0
_cell_volume                     2964.29(17)
_cell_formula_units_Z            3
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    6347
_cell_measurement_theta_min      3.7220
_cell_measurement_theta_max      28.4530
_exptl_crystal_description       block
_exptl_crystal_colour            purple
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.419
_exptl_crystal_F_000             1332
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.08
_exptl_absorpt_coefficient_mu    1.169
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_T_min  0.91404
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.95a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_source_type              'Enhance (Mo) X-ray Source'
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 16.1158
_diffrn_reflns_number            18833
_diffrn_reflns_av_unetI/netI     0.0552
_diffrn_reflns_av_R_equivalents  0.0486
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         3.437
_diffrn_reflns_theta_max         26.994
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.985
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.985
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             6367
_reflns_number_gt                4583
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_cell_refinement       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1118P)²+8.4195P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6367
_refine_ls_number_parameters     352
_refine_ls_number_restraints     180
_refine_ls_R_factor_all          0.0934
_refine_ls_R_factor_gt           0.0661
_refine_ls_wR_factor_ref         0.2214
_refine_ls_wR_factor_gt          0.1935
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_restrained_S_all      1.074
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.6865(4) 0.6960(4) 0.5717(2) 0.0320(10) Uani 1 1 d . . . . .
C2 C 0.7085(4) 0.8097(5) 0.5346(3) 0.0381(12) Uani 1 1 d . . . . .
C3 C 0.7068(6) 0.7708(7) 0.4621(3) 0.0608(18) Uani 1 1 d . . . . .
H3A H 0.6407 0.7393 0.4396 0.091 Uiso 1 1 calc R U . . .
H3B H 0.7214 0.8392 0.4374 0.091 Uiso 1 1 calc R U . . .
H3C H 0.7574 0.7094 0.4641 0.091 Uiso 1 1 calc R U . . .
C4 C 0.8128(5) 0.8588(6) 0.5693(3) 0.0529(16) Uani 1 1 d . . . . .
H4A H 0.8631 0.7976 0.5705 0.079 Uiso 1 1 calc R U . . .
H4B H 0.8267 0.9277 0.5447 0.079 Uiso 1 1 calc R U . . .
H4C H 0.8148 0.8825 0.6149 0.079 Uiso 1 1 calc R U . . .
C5 C 0.6273(5) 0.9064(6) 0.5324(4) 0.065(2) Uani 1 1 d . . . . .
H5A H 0.5612 0.8744 0.5102 0.098 Uiso 1 1 calc R U . . .
H5B H 0.6289 0.9302 0.5779 0.098 Uiso 1 1 calc R U . . .
H5C H 0.6408 0.9754 0.5076 0.098 Uiso 1 1 calc R U . . .
C6 C 0.4383(4) 0.5194(5) 0.7063(3) 0.0346(11) Uani 1 1 d . . . . .
C7 C 0.3651(5) 0.5146(5) 0.7502(3) 0.0514(15) Uani 1 1 d D U . . .
C8A C 0.2604(11) 0.5549(17) 0.7277(9) 0.123(5) Uani 0.5 1 d D U P A 1
H8A1 H 0.2308 0.5278 0.6819 0.184 Uiso 0.5 1 calc R U P A 1
H8A2 H 0.2225 0.5222 0.7570 0.184 Uiso 0.5 1 calc R U P A 1
H8A3 H 0.2583 0.6415 0.7291 0.184 Uiso 0.5 1 calc R U P A 1
C9A C 0.3370(13) 0.3981(11) 0.7732(10) 0.083(4) Uani 0.5 1 d D U P A 1
H9A1 H 0.3222 0.3420 0.7360 0.124 Uiso 0.5 1 calc R U P A 1
H9A2 H 0.3924 0.3678 0.8091 0.124 Uiso 0.5 1 calc R U P A 1
H9A3 H 0.2778 0.4077 0.7898 0.124 Uiso 0.5 1 calc R U P A 1
C10A C 0.3803(12) 0.5694(15) 0.8156(7) 0.097(4) Uani 0.5 1 d D U P A 1
H10A H 0.4488 0.5547 0.8423 0.146 Uiso 0.5 1 calc R U P A 1
H10B H 0.3690 0.6549 0.8102 0.146 Uiso 0.5 1 calc R U P A 1
H10C H 0.3333 0.5355 0.8381 0.146 Uiso 0.5 1 calc R U P A 1
C8B C 0.3286(13) 0.6412(11) 0.7612(10) 0.083(4) Uani 0.5 1 d D U P A 2
H8B1 H 0.2821 0.6368 0.7892 0.124 Uiso 0.5 1 calc R U P A 2
H8B2 H 0.3860 0.6903 0.7834 0.124 Uiso 0.5 1 calc R U P A 2
H8B3 H 0.2946 0.6764 0.7181 0.124 Uiso 0.5 1 calc R U P A 2
C9B C 0.2754(11) 0.4340(16) 0.7102(10) 0.097(4) Uani 0.5 1 d D U P A 2
H9B1 H 0.2255 0.4270 0.7355 0.146 Uiso 0.5 1 calc R U P A 2
H9B2 H 0.2446 0.4700 0.6668 0.146 Uiso 0.5 1 calc R U P A 2
H9B3 H 0.3007 0.3552 0.7037 0.146 Uiso 0.5 1 calc R U P A 2
C10B C 0.4236(15) 0.4558(18) 0.8169(8) 0.123(5) Uani 0.5 1 d D U P A 2
H10D H 0.3802 0.4504 0.8470 0.184 Uiso 0.5 1 calc R U P A 2
H10E H 0.4449 0.3763 0.8080 0.184 Uiso 0.5 1 calc R U P A 2
H10F H 0.4823 0.5038 0.8378 0.184 Uiso 0.5 1 calc R U P A 2
C12 C 0.6107(4) 0.2954(5) 0.5850(3) 0.0432(13) Uani 1 1 d . . . . .
H12A H 0.5920 0.2599 0.5399 0.052 Uiso 1 1 calc R U . . .
H12B H 0.5541 0.2841 0.6049 0.052 Uiso 1 1 calc R U . . .
C13 C 0.7049(4) 0.2315(5) 0.6288(3) 0.0401(12) Uani 1 1 d . . . . .
H13A H 0.6850 0.1609 0.6503 0.048 Uiso 1 1 calc R U . . .
H13B H 0.7485 0.2055 0.6008 0.048 Uiso 1 1 calc R U . . .
C14 C 0.7099(4) 0.4678(5) 0.7544(3) 0.0354(11) Uani 1 1 d . . . . .
H14A H 0.6600 0.4859 0.7792 0.042 Uiso 1 1 calc R U . . .
H14B H 0.7771 0.4861 0.7836 0.042 Uiso 1 1 calc R U . . .
C15 C 0.7037(4) 0.3359(5) 0.7346(3) 0.0372(11) Uani 1 1 d . . . . .
H15A H 0.7337 0.2863 0.7741 0.045 Uiso 1 1 calc R U . . .
H15B H 0.6331 0.3121 0.7165 0.045 Uiso 1 1 calc R U . . .
C16 C 0.8688(4) 0.2855(5) 0.7124(3) 0.0390(12) Uani 1 1 d . . . . .
H16A H 0.8962 0.2448 0.6790 0.047 Uiso 1 1 calc R U . . .
H16B H 0.8741 0.2313 0.7505 0.047 Uiso 1 1 calc R U . . .
C17 C 0.9272(4) 0.3991(5) 0.7358(3) 0.0354(11) Uani 1 1 d . . . . .
C18 C 1.0125(4) 0.4058(5) 0.7906(3) 0.0442(13) Uani 1 1 d . . . . .
H18 H 1.0381 0.3370 0.8155 0.053 Uiso 1 1 calc R U . . .
C19 C 1.0592(5) 0.5164(6) 0.8075(4) 0.0534(16) Uani 1 1 d . . . . .
H19 H 1.1164 0.5228 0.8444 0.064 Uiso 1 1 calc R U . . .
C20 C 1.0207(4) 0.6173(5) 0.7697(3) 0.0486(14) Uani 1 1 d . . . . .
H20 H 1.0513 0.6923 0.7808 0.058 Uiso 1 1 calc R U . . .
C21 C 0.9362(4) 0.6048(5) 0.7152(3) 0.0377(12) Uani 1 1 d . . . . .
H21 H 0.9107 0.6723 0.6889 0.045 Uiso 1 1 calc R U . . .
C22 C 0.8320(4) 0.3994(6) 0.5151(3) 0.0466(13) Uani 1 1 d . U . . .
C23 C 0.8967(8) 0.3040(9) 0.4918(5) 0.095(3) Uani 1 1 d . U . . .
C24A C 0.9350(8) 0.3536(11) 0.4334(5) 0.108(3) Uani 1 1 d . U . B 1
H24A H 0.8786 0.3853 0.3988 0.162 Uiso 1 1 calc R U . B 1
H24B H 0.9836 0.4167 0.4500 0.162 Uiso 1 1 calc R U . B 1
H24C H 0.9669 0.2899 0.4146 0.162 Uiso 1 1 calc R U . B 1
C25A C 0.9768(11) 0.2543(15) 0.5462(6) 0.173(5) Uani 1 1 d . U . C 1
H25A H 0.9484 0.2246 0.5814 0.259 Uiso 1 1 calc R U . C 1
H25B H 1.0093 0.1892 0.5290 0.259 Uiso 1 1 calc R U . C 1
H25C H 1.0260 0.3160 0.5644 0.259 Uiso 1 1 calc R U . C 1
C26A C 0.8160(13) 0.2041(13) 0.4597(8) 0.168(5) Uani 1 1 d . U . D 1
H26A H 0.7633 0.2389 0.4236 0.252 Uiso 1 1 calc R U . D 1
H26B H 0.8487 0.1400 0.4419 0.252 Uiso 1 1 calc R U . D 1
H26C H 0.7866 0.1726 0.4940 0.252 Uiso 1 1 calc R U . D 1
N1 N 0.8899(3) 0.4981(4) 0.6991(2) 0.0322(9) Uani 1 1 d . . . . .
N2 N 0.7607(3) 0.3188(4) 0.6817(2) 0.0327(9) Uani 1 1 d . . . . .
O1 O 0.6906(2) 0.5386(3) 0.69446(17) 0.0294(7) Uani 1 1 d . . . . .
O2 O 0.6293(2) 0.4209(3) 0.57997(17) 0.0333(8) Uani 1 1 d . . . . .
O3 O 0.4725(3) 0.4239(3) 0.6879(2) 0.0427(9) Uani 1 1 d . . . . .
O4 O 0.4661(3) 0.6204(3) 0.68781(19) 0.0391(8) Uani 1 1 d . . . . .
O5 O 0.5991(3) 0.6810(3) 0.57852(19) 0.0387(8) Uani 1 1 d . . . . .
O6 O 0.7609(3) 0.6240(3) 0.59140(18) 0.0362(8) Uani 1 1 d . . . . .
O7 O 0.4196(3) 0.5127(4) 0.5486(2) 0.0499(11) Uani 1 1 d D . . . .
H1O7 H 0.3593 0.5173 0.5512 0.075 Uiso 1 1 d DR U . . .
H2O7 H 0.4016 0.5339 0.5077 0.075 Uiso 1 1 d DR U . . .
O8 O 0.8329(3) 0.3904(3) 0.5781(2) 0.0411(9) Uani 1 1 d . . . . .
O9 O 0.7826(4) 0.4718(5) 0.4741(2) 0.0624(13) Uani 1 1 d . . . . .
Co1 Co 0.75970(5) 0.47007(6) 0.63402(3) 0.0278(2) Uani 1 1 d . . . . .
Co2 Co 0.54633(5) 0.53913(6) 0.62536(3) 0.0298(2) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O5 1.246(6) . ?
C1 O6 1.267(6) . ?
C1 C2 1.539(7) . ?
C2 C4 1.509(8) . ?
C2 C5 1.532(8) . ?
C2 C3 1.534(8) . ?
C6 O3 1.255(6) . ?
C6 O4 1.270(6) . ?
C6 C7 1.508(8) . ?
C6 Co2 2.499(5) . ?
C7 C10A 1.430(13) . ?
C7 C8A 1.447(13) . ?
C7 C9A 1.459(11) . ?
C7 C8B 1.525(11) . ?
C7 C10B 1.526(13) . ?
C7 C9B 1.556(12) . ?
C12 O2 1.422(6) . ?
C12 C13 1.527(7) . ?
C13 N2 1.496(6) . ?
C14 O1 1.417(6) . ?
C14 C15 1.512(7) . ?
C15 N2 1.500(7) . ?
C16 N2 1.485(6) . ?
C16 C17 1.496(7) . ?
C17 N1 1.348(6) . ?
C17 C18 1.382(7) . ?
C18 C19 1.380(8) . ?
C19 C20 1.379(9) . ?
C20 C21 1.377(8) . ?
C21 N1 1.339(7) . ?
C22 O9 1.222(7) . ?
C22 O8 1.286(7) . ?
C22 C23 1.531(9) . ?
C23 C25A 1.441(14) . ?
C23 C24A 1.525(13) . ?
C23 C26A 1.573(17) . ?
N1 Co1 1.934(4) . ?
N2 Co1 1.935(4) . ?
O1 Co1 1.899(3) . ?
O1 Co2 2.089(3) . ?
O2 Co1 1.902(3) . ?
O2 Co2 2.099(4) . ?
O3 Co2 2.225(4) . ?
O4 Co2 2.090(4) . ?
O5 Co2 2.065(4) . ?
O6 Co1 1.915(3) . ?
O7 Co2 2.018(4) . ?
O8 Co1 1.918(4) . ?
Co1 Co2 2.9637(9) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 C1 O6 126.0(5) . . ?
O5 C1 C2 118.8(4) . . ?
O6 C1 C2 115.3(4) . . ?
C4 C2 C5 110.1(5) . . ?
C4 C2 C3 108.9(5) . . ?
C5 C2 C3 110.1(6) . . ?
C4 C2 C1 110.2(4) . . ?
C5 C2 C1 110.7(5) . . ?
C3 C2 C1 106.9(5) . . ?
O3 C6 O4 119.2(5) . . ?
O3 C6 C7 120.4(5) . . ?
O4 C6 C7 120.4(5) . . ?
O3 C6 Co2 62.8(3) . . ?
O4 C6 Co2 56.7(3) . . ?
C7 C6 Co2 174.3(4) . . ?
C10A C7 C8A 92.8(10) . . ?
C10A C7 C9A 93.4(9) . . ?
C8A C7 C9A 93.1(9) . . ?
C10A C7 C6 125.8(8) . . ?
C8A C7 C6 123.5(9) . . ?
C9A C7 C6 119.7(7) . . ?
C6 C7 C8B 110.4(7) . . ?
C6 C7 C10B 106.0(8) . . ?
C8B C7 C10B 111.9(8) . . ?
C6 C7 C9B 105.1(8) . . ?
C8B C7 C9B 111.3(8) . . ?
C10B C7 C9B 111.9(9) . . ?
O2 C12 C13 110.9(4) . . ?
N2 C13 C12 107.9(4) . . ?
O1 C14 C15 108.6(4) . . ?
N2 C15 C14 108.2(4) . . ?
N2 C16 C17 107.9(4) . . ?
N1 C17 C18 121.1(5) . . ?
N1 C17 C16 114.6(4) . . ?
C18 C17 C16 124.3(5) . . ?
C19 C18 C17 118.8(5) . . ?
C20 C19 C18 119.9(5) . . ?
C21 C20 C19 118.8(5) . . ?
N1 C21 C20 121.6(5) . . ?
O9 C22 O8 126.3(5) . . ?
O9 C22 C23 119.7(6) . . ?
O8 C22 C23 113.9(6) . . ?
C25A C23 C24A 113.1(9) . . ?
C25A C23 C22 113.8(8) . . ?
C24A C23 C22 109.9(7) . . ?
C25A C23 C26A 110.7(12) . . ?
C24A C23 C26A 105.9(9) . . ?
C22 C23 C26A 102.6(8) . . ?
C21 N1 C17 119.9(4) . . ?
C21 N1 Co1 126.5(4) . . ?
C17 N1 Co1 113.0(3) . . ?
C16 N2 C13 113.5(4) . . ?
C16 N2 C15 111.9(4) . . ?
C13 N2 C15 109.9(4) . . ?
C16 N2 Co1 107.4(3) . . ?
C13 N2 Co1 105.2(3) . . ?
C15 N2 Co1 108.5(3) . . ?
C14 O1 Co1 109.3(3) . . ?
C14 O1 Co2 120.6(3) . . ?
Co1 O1 Co2 95.90(14) . . ?
C12 O2 Co1 113.3(3) . . ?
C12 O2 Co2 116.7(3) . . ?
Co1 O2 Co2 95.45(15) . . ?
C6 O3 Co2 87.1(3) . . ?
C6 O4 Co2 92.8(3) . . ?
C1 O5 Co2 127.9(3) . . ?
C1 O6 Co1 126.9(3) . . ?
C22 O8 Co1 133.8(4) . . ?
O1 Co1 O2 86.71(15) . . ?
O1 Co1 O6 90.32(15) . . ?
O2 Co1 O6 96.40(15) . . ?
O1 Co1 O8 175.39(15) . . ?
O2 Co1 O8 94.39(16) . . ?
O6 Co1 O8 94.00(16) . . ?
O1 Co1 N1 90.74(17) . . ?
O2 Co1 N1 170.33(17) . . ?
O6 Co1 N1 92.94(17) . . ?
O8 Co1 N1 87.44(17) . . ?
O1 Co1 N2 87.54(16) . . ?
O2 Co1 N2 85.61(16) . . ?
O6 Co1 N2 176.98(17) . . ?
O8 Co1 N2 88.08(17) . . ?
N1 Co1 N2 84.96(17) . . ?
O1 Co1 Co2 44.51(10) . . ?
O2 Co1 Co2 44.85(11) . . ?
O6 Co1 Co2 82.59(10) . . ?
O8 Co1 Co2 137.74(12) . . ?
N1 Co1 Co2 134.70(13) . . ?
N2 Co1 Co2 97.35(13) . . ?
O7 Co2 O5 94.70(16) . . ?
O7 Co2 O1 167.96(16) . . ?
O5 Co2 O1 86.20(14) . . ?
O7 Co2 O4 93.32(16) . . ?
O5 Co2 O4 104.98(14) . . ?
O1 Co2 O4 98.05(14) . . ?
O7 Co2 O2 90.95(16) . . ?
O5 Co2 O2 88.54(14) . . ?
O1 Co2 O2 77.07(13) . . ?
O4 Co2 O2 165.41(15) . . ?
O7 Co2 O3 86.47(16) . . ?
O5 Co2 O3 165.48(15) . . ?
O1 Co2 O3 95.67(14) . . ?
O4 Co2 O3 60.50(14) . . ?
O2 Co2 O3 105.92(14) . . ?
O7 Co2 C6 88.19(16) . . ?
O5 Co2 C6 135.40(16) . . ?
O1 Co2 C6 99.61(15) . . ?
O4 Co2 C6 30.50(15) . . ?
O2 Co2 C6 135.98(16) . . ?
O3 Co2 C6 30.09(16) . . ?
O7 Co2 Co1 129.05(13) . . ?
O5 Co2 Co1 76.50(10) . . ?
O1 Co2 Co1 39.59(9) . . ?
O4 Co2 Co1 137.60(11) . . ?
O2 Co2 Co1 39.70(9) . . ?
O3 Co2 Co1 113.82(10) . . ?
C6 Co2 Co1 132.80(12) . . ?

_refine_diff_density_max         1.889
_refine_diff_density_min         -1.755
_refine_diff_density_rms         0.122



_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: acetonitrile'
_exptl_crystal_preparation       'Magnetic properties'
