# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_mb_rkj_c5r_0m
_database_code_depnum_ccdc_archive 'CCDC 1815096'
loop_
_audit_author_name
_audit_author_address
'Manish Bhattacharjee'
'Department of Chemistry, Indian Institute of Technology Kharagpur, Kharagpur 721302, India'
_audit_update_record             
;
2018-01-06 deposited with the CCDC.	2022-06-01 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C43 H46 Cl F6 P3 Ru'
_chemical_formula_weight         906.23

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Orthorhombic
_symmetry_space_group_name_H-M   P212121

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'
'-x+1/2, -y, z+1/2'

_cell_length_a                   10.4015(6)
_cell_length_b                   12.1513(6)
_cell_length_c                   31.7163(16)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     4008.7(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    46642
_cell_measurement_theta_min      1.79
_cell_measurement_theta_max      24.99

_exptl_crystal_description       rod
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.502
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1856
_exptl_absorpt_coefficient_mu    0.637
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  0.8832
_exptl_absorpt_correction_T_max  0.9391
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'bruker smart apex II CCD'
_diffrn_measurement_method       'w scan'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            46642
_diffrn_reflns_av_R_equivalents  0.0646
_diffrn_reflns_av_sigmaI/netI    0.0421
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_theta_min         1.79
_diffrn_reflns_theta_max         24.99
_reflns_number_total             7063
_reflns_number_gt                6578
_reflns_threshold_expression     >2σ(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2σ(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0313P)²+2.3035P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.02(2)
_refine_ls_number_reflns         7063
_refine_ls_number_parameters     491
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0354
_refine_ls_R_factor_gt           0.0313
_refine_ls_wR_factor_ref         0.0699
_refine_ls_wR_factor_gt          0.0677
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_restrained_S_all      1.024
_refine_ls_shift/su_max          0.032
_refine_ls_shift/su_mean         0.002

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.40534(2) 0.38554(2) 0.112922(8) 0.01325(7) Uani 1 1 d . . .
P3 P 1.11184(9) 0.89645(9) 0.16869(3) 0.0276(2) Uani 1 1 d . . .
P1 P 0.51570(8) 0.27903(8) 0.06470(3) 0.01422(19) Uani 1 1 d . . .
P2 P 0.46541(8) 0.53071(7) 0.06942(3) 0.01527(19) Uani 1 1 d . . .
Cl1 Cl 0.23366(7) 0.35755(7) 0.06382(3) 0.01785(19) Uani 1 1 d . . .
F5 F 1.0516(2) 0.9027(2) 0.12194(7) 0.0392(6) Uani 1 1 d . . .
F4 F 1.0630(4) 0.7731(2) 0.17243(11) 0.0824(11) Uani 1 1 d . . .
F2 F 1.1630(2) 1.0193(2) 0.16310(8) 0.0473(7) Uani 1 1 d . . .
F1 F 0.9775(2) 0.9357(3) 0.18700(8) 0.0583(8) Uani 1 1 d . . .
F3 F 1.2428(3) 0.8501(3) 0.15019(9) 0.0673(10) Uani 1 1 d . . .
F6 F 1.1702(2) 0.8918(2) 0.21521(7) 0.0356(5) Uani 1 1 d . . .
C7 C 0.6777(3) 0.3768(4) 0.17634(11) 0.0222(8) Uani 1 1 d . . .
H7A H 0.7135 0.4442 0.1657 0.033 Uiso 1 1 calc R . .
H7B H 0.7138 0.3157 0.1613 0.033 Uiso 1 1 calc R . .
H7C H 0.6973 0.3699 0.2058 0.033 Uiso 1 1 calc R . .
C10 C 0.0626(4) 0.3350(4) 0.20881(13) 0.0382(11) Uani 1 1 d . . .
H10A H 0.0995 0.2645 0.2152 0.057 Uiso 1 1 calc R . .
H10B H -0.0294 0.3289 0.2084 0.057 Uiso 1 1 calc R . .
H10C H 0.0877 0.3873 0.2300 0.057 Uiso 1 1 calc R . .
C18 C 0.6876(3) 0.1324(3) 0.10241(11) 0.0215(8) Uani 1 1 d . . .
H18 H 0.6144 0.0921 0.1090 0.026 Uiso 1 1 calc R . .
C2 C 0.4625(3) 0.4769(3) 0.16982(10) 0.0171(8) Uani 1 1 d . . .
H2 H 0.5090 0.5465 0.1665 0.021 Uiso 1 1 calc R . .
C1 C 0.5331(3) 0.3780(3) 0.17034(9) 0.0180(7) Uani 1 1 d . . .
C6 C 0.4621(3) 0.2779(3) 0.16712(10) 0.0174(8) Uani 1 1 d . . .
H6 H 0.5080 0.2090 0.1615 0.021 Uiso 1 1 calc R . .
C5 C 0.3264(3) 0.2791(3) 0.16535(11) 0.0168(8) Uani 1 1 d . . .
H5 H 0.2809 0.2111 0.1580 0.020 Uiso 1 1 calc R . .
C4 C 0.2564(3) 0.3796(3) 0.16661(9) 0.0161(7) Uani 1 1 d . . .
C8 C 0.1107(3) 0.3740(3) 0.16523(11) 0.0227(8) Uani 1 1 d . . .
H8 H 0.0876 0.3168 0.1448 0.027 Uiso 1 1 calc R . .
C9 C 0.0452(3) 0.4794(3) 0.15120(14) 0.0327(10) Uani 1 1 d . . .
H9A H 0.0593 0.5358 0.1719 0.049 Uiso 1 1 calc R . .
H9B H -0.0454 0.4666 0.1482 0.049 Uiso 1 1 calc R . .
H9C H 0.0803 0.5025 0.1246 0.049 Uiso 1 1 calc R . .
C3 C 0.3257(3) 0.4783(3) 0.16958(10) 0.0180(8) Uani 1 1 d . . .
H3 H 0.2809 0.5482 0.1651 0.022 Uiso 1 1 calc R . .
C13 C 0.6761(3) 0.2307(3) 0.07968(11) 0.0173(8) Uani 1 1 d . . .
C17 C 0.8076(3) 0.0946(3) 0.11514(13) 0.0277(9) Uani 1 1 d . . .
H17 H 0.8145 0.0292 0.1302 0.033 Uiso 1 1 calc R . .
C16 C 0.9168(3) 0.1544(3) 0.10535(11) 0.0242(8) Uani 1 1 d . . .
H16 H 0.9971 0.1295 0.1141 0.029 Uiso 1 1 calc R . .
C15 C 0.9069(3) 0.2505(3) 0.08268(11) 0.0211(8) Uani 1 1 d . . .
H15 H 0.9807 0.2901 0.0759 0.025 Uiso 1 1 calc R . .
C14 C 0.7876(3) 0.2888(3) 0.06990(11) 0.0198(8) Uani 1 1 d . . .
H14 H 0.7820 0.3539 0.0546 0.024 Uiso 1 1 calc R . .
C19 C 0.4433(3) 0.1503(3) 0.04729(10) 0.0166(8) Uani 1 1 d . . .
C20 C 0.4919(3) 0.1016(3) 0.01105(10) 0.0194(8) Uani 1 1 d . . .
H20 H 0.5556 0.1372 -0.0044 0.023 Uiso 1 1 calc R . .
C21 C 0.4461(3) -0.0003(3) -0.00243(12) 0.0206(8) Uani 1 1 d . . .
H21 H 0.4772 -0.0318 -0.0271 0.025 Uiso 1 1 calc R . .
C22 C 0.3537(3) -0.0543(3) 0.02145(12) 0.0212(8) Uani 1 1 d . . .
H22 H 0.3242 -0.1232 0.0130 0.025 Uiso 1 1 calc R . .
C23 C 0.3051(3) -0.0063(3) 0.05775(12) 0.0252(9) Uani 1 1 d . . .
H23 H 0.2436 -0.0431 0.0737 0.030 Uiso 1 1 calc R . .
C24 C 0.3479(3) 0.0964(3) 0.07034(11) 0.0209(8) Uani 1 1 d . . .
H24 H 0.3131 0.1296 0.0942 0.025 Uiso 1 1 calc R . .
C12 C 0.5369(3) 0.3589(3) 0.01595(10) 0.0178(8) Uani 1 1 d . . .
H12A H 0.6066 0.3277 -0.0005 0.021 Uiso 1 1 calc R . .
H12B H 0.4590 0.3549 -0.0008 0.021 Uiso 1 1 calc R . .
C11 C 0.5669(3) 0.4791(3) 0.02614(11) 0.0170(8) Uani 1 1 d . . .
H11A H 0.5528 0.5238 0.0012 0.020 Uiso 1 1 calc R . .
H11B H 0.6566 0.4858 0.0340 0.020 Uiso 1 1 calc R . .
C25 C 0.5657(3) 0.6373(3) 0.09401(10) 0.0162(8) Uani 1 1 d . . .
C26 C 0.6945(3) 0.6115(3) 0.10405(11) 0.0233(8) Uani 1 1 d . . .
H26 H 0.7280 0.5436 0.0962 0.028 Uiso 1 1 calc R . .
C27 C 0.7717(3) 0.6857(3) 0.12529(12) 0.0240(9) Uani 1 1 d . . .
H27 H 0.8564 0.6674 0.1316 0.029 Uiso 1 1 calc R . .
C28 C 0.7232(3) 0.7871(3) 0.13717(11) 0.0241(8) Uani 1 1 d . . .
H28 H 0.7750 0.8372 0.1514 0.029 Uiso 1 1 calc R . .
C29 C 0.5965(4) 0.8136(3) 0.12764(11) 0.0227(8) Uani 1 1 d . . .
H29 H 0.5635 0.8813 0.1359 0.027 Uiso 1 1 calc R . .
C30 C 0.5184(3) 0.7401(3) 0.10586(11) 0.0191(8) Uani 1 1 d . . .
H30 H 0.4344 0.7597 0.0992 0.023 Uiso 1 1 calc R . .
C31 C 0.3324(3) 0.6058(3) 0.04485(10) 0.0170(7) Uani 1 1 d . . .
C32 C 0.3172(3) 0.6105(3) 0.00117(11) 0.0209(8) Uani 1 1 d . . .
H32 H 0.3758 0.5754 -0.0164 0.025 Uiso 1 1 calc R . .
C33 C 0.2142(3) 0.6679(3) -0.01605(12) 0.0241(9) Uani 1 1 d . . .
H33 H 0.2045 0.6714 -0.0452 0.029 Uiso 1 1 calc R . .
C34 C 0.1260(3) 0.7198(3) 0.00986(13) 0.0249(9) Uani 1 1 d . . .
H34 H 0.0579 0.7586 -0.0019 0.030 Uiso 1 1 calc R . .
C35 C 0.1386(3) 0.7143(3) 0.05309(13) 0.0254(9) Uani 1 1 d . . .
H35 H 0.0792 0.7492 0.0704 0.030 Uiso 1 1 calc R . .
C36 C 0.2405(3) 0.6563(3) 0.07063(12) 0.0204(8) Uani 1 1 d . . .
H36 H 0.2477 0.6510 0.0998 0.025 Uiso 1 1 calc R . .
C39 C 0.6135(4) 0.5929(4) 0.25780(12) 0.0352(11) Uani 1 1 d . . .
H39 H 0.7023 0.5848 0.2569 0.042 Uiso 1 1 calc R . .
C40 C 0.5379(4) 0.5176(4) 0.27880(13) 0.0340(10) Uani 1 1 d . . .
H40 H 0.5769 0.4585 0.2923 0.041 Uiso 1 1 calc R . .
C41 C 0.4061(4) 0.5276(3) 0.28029(11) 0.0303(9) Uani 1 1 d . . .
H41 H 0.3577 0.4751 0.2945 0.036 Uiso 1 1 calc R . .
C42 C 0.3442(4) 0.6162(4) 0.26056(11) 0.0311(9) Uani 1 1 d . . .
C43 C 0.2016(4) 0.6299(4) 0.26223(13) 0.0371(10) Uani 1 1 d . . .
H43A H 0.1609 0.5601 0.2574 0.056 Uiso 1 1 calc R . .
H43B H 0.1750 0.6812 0.2409 0.056 Uiso 1 1 calc R . .
H43C H 0.1771 0.6571 0.2895 0.056 Uiso 1 1 calc R . .
C38 C 0.5543(4) 0.6808(4) 0.23820(12) 0.0363(11) Uani 1 1 d . . .
H38 H 0.6040 0.7329 0.2242 0.044 Uiso 1 1 calc R . .
C37 C 0.4228(4) 0.6922(3) 0.23906(11) 0.0302(10) Uani 1 1 d . . .
H37 H 0.3849 0.7513 0.2252 0.036 Uiso 1 1 calc R . .


_geom_special_details            
;
 All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell s.u.'s are taken
 into account individually in the estimation of s.u.'s in distances, angles
 and torsion angles; correlations between s.u.'s in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 C2 2.201(3) . ?
Ru1 C6 2.239(3) . ?
Ru1 C1 2.256(3) . ?
Ru1 C5 2.261(3) . ?
Ru1 C3 2.277(3) . ?
Ru1 C4 2.303(3) . ?
Ru1 P1 2.3091(9) . ?
Ru1 P2 2.3250(9) . ?
Ru1 Cl1 2.3938(8) . ?
P3 F4 1.587(3) . ?
P3 F1 1.586(3) . ?
P3 F3 1.587(3) . ?
P3 F2 1.594(3) . ?
P3 F6 1.596(2) . ?
P3 F5 1.611(2) . ?
P1 C19 1.821(3) . ?
P1 C13 1.831(3) . ?
P1 C12 1.839(3) . ?
P2 C31 1.831(3) . ?
P2 C25 1.837(3) . ?
P2 C11 1.841(3) . ?
C7 C1 1.517(4) . ?
C7 H7A 0.9600 . ?
C7 H7B 0.9600 . ?
C7 H7C 0.9600 . ?
C10 C8 1.545(5) . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C18 C17 1.390(5) . ?
C18 C13 1.400(5) . ?
C18 H18 0.9300 . ?
C2 C1 1.408(5) . ?
C2 C3 1.423(5) . ?
C2 H2 0.9800 . ?
C1 C6 1.426(5) . ?
C6 C5 1.413(5) . ?
C6 H6 0.9800 . ?
C5 C4 1.422(5) . ?
C5 H5 0.9800 . ?
C4 C3 1.403(5) . ?
C4 C8 1.518(4) . ?
C8 C9 1.517(5) . ?
C8 H8 0.9800 . ?
C9 H9A 0.9600 . ?
C9 H9B 0.9600 . ?
C9 H9C 0.9600 . ?
C3 H3 0.9800 . ?
C13 C14 1.393(5) . ?
C17 C16 1.384(5) . ?
C17 H17 0.9300 . ?
C16 C15 1.376(5) . ?
C16 H16 0.9300 . ?
C15 C14 1.386(5) . ?
C15 H15 0.9300 . ?
C14 H14 0.9300 . ?
C19 C20 1.389(5) . ?
C19 C24 1.396(5) . ?
C20 C21 1.394(5) . ?
C20 H20 0.9300 . ?
C21 C22 1.389(5) . ?
C21 H21 0.9300 . ?
C22 C23 1.386(5) . ?
C22 H22 0.9300 . ?
C23 C24 1.384(5) . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?
C12 C11 1.528(5) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C25 C30 1.394(5) . ?
C25 C26 1.413(4) . ?
C26 C27 1.382(5) . ?
C26 H26 0.9300 . ?
C27 C28 1.384(5) . ?
C27 H27 0.9300 . ?
C28 C29 1.389(5) . ?
C28 H28 0.9300 . ?
C29 C30 1.390(5) . ?
C29 H29 0.9300 . ?
C30 H30 0.9300 . ?
C31 C32 1.396(5) . ?
C31 C36 1.400(5) . ?
C32 C33 1.389(5) . ?
C32 H32 0.9300 . ?
C33 C34 1.384(5) . ?
C33 H33 0.9300 . ?
C34 C35 1.379(5) . ?
C34 H34 0.9300 . ?
C35 C36 1.389(5) . ?
C35 H35 0.9300 . ?
C36 H36 0.9300 . ?
C39 C40 1.378(6) . ?
C39 C38 1.380(6) . ?
C39 H39 0.9300 . ?
C40 C41 1.376(6) . ?
C40 H40 0.9300 . ?
C41 C42 1.402(5) . ?
C41 H41 0.9300 . ?
C42 C37 1.409(6) . ?
C42 C43 1.494(5) . ?
C43 H43A 0.9600 . ?
C43 H43B 0.9600 . ?
C43 H43C 0.9600 . ?
C38 C37 1.375(6) . ?
C38 H38 0.9300 . ?
C37 H37 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 Ru1 C6 66.03(12) . . ?
C2 Ru1 C1 36.80(14) . . ?
C6 Ru1 C1 37.00(13) . . ?
C2 Ru1 C5 77.51(14) . . ?
C6 Ru1 C5 36.59(12) . . ?
C1 Ru1 C5 66.24(12) . . ?
C2 Ru1 C3 37.01(12) . . ?
C6 Ru1 C3 77.23(14) . . ?
C1 Ru1 C3 66.24(13) . . ?
C5 Ru1 C3 64.58(13) . . ?
C2 Ru1 C4 65.89(12) . . ?
C6 Ru1 C4 65.87(13) . . ?
C1 Ru1 C4 78.34(11) . . ?
C5 Ru1 C4 36.28(13) . . ?
C3 Ru1 C4 35.67(13) . . ?
C2 Ru1 P1 133.75(9) . . ?
C6 Ru1 P1 92.88(9) . . ?
C1 Ru1 P1 102.66(9) . . ?
C5 Ru1 P1 110.31(10) . . ?
C3 Ru1 P1 168.79(9) . . ?
C4 Ru1 P1 143.75(10) . . ?
C2 Ru1 P2 91.79(10) . . ?
C6 Ru1 P2 145.88(9) . . ?
C1 Ru1 P2 110.58(10) . . ?
C5 Ru1 P2 165.48(10) . . ?
C3 Ru1 P2 100.98(10) . . ?
C4 Ru1 P2 130.05(10) . . ?
P1 Ru1 P2 84.18(3) . . ?
C2 Ru1 Cl1 143.79(9) . . ?
C6 Ru1 Cl1 127.82(10) . . ?
C1 Ru1 Cl1 163.48(9) . . ?
C5 Ru1 Cl1 97.25(9) . . ?
C3 Ru1 Cl1 108.21(9) . . ?
C4 Ru1 Cl1 88.56(8) . . ?
P1 Ru1 Cl1 81.97(3) . . ?
P2 Ru1 Cl1 85.54(3) . . ?
F4 P3 F1 88.6(2) . . ?
F4 P3 F3 88.1(2) . . ?
F1 P3 F3 176.64(19) . . ?
F4 P3 F2 177.73(19) . . ?
F1 P3 F2 93.03(17) . . ?
F3 P3 F2 90.27(17) . . ?
F4 P3 F6 91.10(15) . . ?
F1 P3 F6 90.39(13) . . ?
F3 P3 F6 90.17(14) . . ?
F2 P3 F6 90.51(14) . . ?
F4 P3 F5 89.36(15) . . ?
F1 P3 F5 88.87(13) . . ?
F3 P3 F5 90.60(13) . . ?
F2 P3 F5 89.05(13) . . ?
F6 P3 F5 179.12(15) . . ?
C19 P1 C13 100.36(15) . . ?
C19 P1 C12 104.36(15) . . ?
C13 P1 C12 106.18(16) . . ?
C19 P1 Ru1 118.46(11) . . ?
C13 P1 Ru1 117.44(12) . . ?
C12 P1 Ru1 108.69(11) . . ?
C31 P2 C25 104.96(15) . . ?
C31 P2 C11 106.58(15) . . ?
C25 P2 C11 103.37(15) . . ?
C31 P2 Ru1 115.31(11) . . ?
C25 P2 Ru1 115.82(11) . . ?
C11 P2 Ru1 109.77(11) . . ?
C1 C7 H7A 109.5 . . ?
C1 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
C1 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C8 C10 H10A 109.5 . . ?
C8 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C8 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C17 C18 C13 120.6(3) . . ?
C17 C18 H18 119.7 . . ?
C13 C18 H18 119.7 . . ?
C1 C2 C3 122.1(4) . . ?
C1 C2 Ru1 73.7(2) . . ?
C3 C2 Ru1 74.4(2) . . ?
C1 C2 H2 118.8 . . ?
C3 C2 H2 118.8 . . ?
Ru1 C2 H2 118.8 . . ?
C2 C1 C6 117.2(3) . . ?
C2 C1 C7 121.8(4) . . ?
C6 C1 C7 121.0(4) . . ?
C2 C1 Ru1 69.46(19) . . ?
C6 C1 Ru1 70.86(18) . . ?
C7 C1 Ru1 133.3(2) . . ?
C5 C6 C1 120.8(4) . . ?
C5 C6 Ru1 72.6(2) . . ?
C1 C6 Ru1 72.1(2) . . ?
C5 C6 H6 119.3 . . ?
C1 C6 H6 119.3 . . ?
Ru1 C6 H6 119.3 . . ?
C6 C5 C4 121.2(4) . . ?
C6 C5 Ru1 70.9(2) . . ?
C4 C5 Ru1 73.46(19) . . ?
C6 C5 H5 118.9 . . ?
C4 C5 H5 118.9 . . ?
Ru1 C5 H5 118.9 . . ?
C3 C4 C5 118.3(3) . . ?
C3 C4 C8 123.6(3) . . ?
C5 C4 C8 118.2(3) . . ?
C3 C4 Ru1 71.16(18) . . ?
C5 C4 Ru1 70.26(18) . . ?
C8 C4 Ru1 130.7(2) . . ?
C9 C8 C4 114.8(3) . . ?
C9 C8 C10 112.1(3) . . ?
C4 C8 C10 108.2(3) . . ?
C9 C8 H8 107.1 . . ?
C4 C8 H8 107.1 . . ?
C10 C8 H8 107.1 . . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C8 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C4 C3 C2 120.3(4) . . ?
C4 C3 Ru1 73.17(19) . . ?
C2 C3 Ru1 68.6(2) . . ?
C4 C3 H3 119.2 . . ?
C2 C3 H3 119.2 . . ?
Ru1 C3 H3 119.2 . . ?
C14 C13 C18 118.4(3) . . ?
C14 C13 P1 122.6(3) . . ?
C18 C13 P1 119.0(2) . . ?
C16 C17 C18 119.9(3) . . ?
C16 C17 H17 120.0 . . ?
C18 C17 H17 120.0 . . ?
C15 C16 C17 120.1(3) . . ?
C15 C16 H16 119.9 . . ?
C17 C16 H16 119.9 . . ?
C16 C15 C14 120.3(3) . . ?
C16 C15 H15 119.8 . . ?
C14 C15 H15 119.8 . . ?
C15 C14 C13 120.7(3) . . ?
C15 C14 H14 119.6 . . ?
C13 C14 H14 119.6 . . ?
C20 C19 C24 119.5(3) . . ?
C20 C19 P1 117.8(3) . . ?
C24 C19 P1 122.5(3) . . ?
C19 C20 C21 120.6(3) . . ?
C19 C20 H20 119.7 . . ?
C21 C20 H20 119.7 . . ?
C22 C21 C20 119.3(3) . . ?
C22 C21 H21 120.4 . . ?
C20 C21 H21 120.4 . . ?
C23 C22 C21 120.4(3) . . ?
C23 C22 H22 119.8 . . ?
C21 C22 H22 119.8 . . ?
C24 C23 C22 120.1(3) . . ?
C24 C23 H23 119.9 . . ?
C22 C23 H23 119.9 . . ?
C23 C24 C19 120.1(3) . . ?
C23 C24 H24 120.0 . . ?
C19 C24 H24 120.0 . . ?
C11 C12 P1 110.6(2) . . ?
C11 C12 H12A 109.5 . . ?
P1 C12 H12A 109.5 . . ?
C11 C12 H12B 109.5 . . ?
P1 C12 H12B 109.5 . . ?
H12A C12 H12B 108.1 . . ?
C12 C11 P2 111.5(2) . . ?
C12 C11 H11A 109.3 . . ?
P2 C11 H11A 109.3 . . ?
C12 C11 H11B 109.3 . . ?
P2 C11 H11B 109.3 . . ?
H11A C11 H11B 108.0 . . ?
C30 C25 C26 118.2(3) . . ?
C30 C25 P2 123.1(2) . . ?
C26 C25 P2 118.6(3) . . ?
C27 C26 C25 121.1(4) . . ?
C27 C26 H26 119.5 . . ?
C25 C26 H26 119.5 . . ?
C26 C27 C28 120.1(3) . . ?
C26 C27 H27 120.0 . . ?
C28 C27 H27 120.0 . . ?
C27 C28 C29 119.5(3) . . ?
C27 C28 H28 120.2 . . ?
C29 C28 H28 120.2 . . ?
C28 C29 C30 120.9(3) . . ?
C28 C29 H29 119.5 . . ?
C30 C29 H29 119.5 . . ?
C29 C30 C25 120.2(3) . . ?
C29 C30 H30 119.9 . . ?
C25 C30 H30 119.9 . . ?
C32 C31 C36 119.0(3) . . ?
C32 C31 P2 121.9(3) . . ?
C36 C31 P2 119.1(3) . . ?
C33 C32 C31 119.9(3) . . ?
C33 C32 H32 120.0 . . ?
C31 C32 H32 120.0 . . ?
C34 C33 C32 120.4(4) . . ?
C34 C33 H33 119.8 . . ?
C32 C33 H33 119.8 . . ?
C35 C34 C33 120.4(3) . . ?
C35 C34 H34 119.8 . . ?
C33 C34 H34 119.8 . . ?
C34 C35 C36 119.7(4) . . ?
C34 C35 H35 120.1 . . ?
C36 C35 H35 120.1 . . ?
C35 C36 C31 120.6(4) . . ?
C35 C36 H36 119.7 . . ?
C31 C36 H36 119.7 . . ?
C40 C39 C38 118.5(4) . . ?
C40 C39 H39 120.8 . . ?
C38 C39 H39 120.8 . . ?
C41 C40 C39 121.7(4) . . ?
C41 C40 H40 119.1 . . ?
C39 C40 H40 119.1 . . ?
C40 C41 C42 120.7(4) . . ?
C40 C41 H41 119.7 . . ?
C42 C41 H41 119.7 . . ?
C41 C42 C37 116.9(4) . . ?
C41 C42 C43 121.7(4) . . ?
C37 C42 C43 121.4(4) . . ?
C42 C43 H43A 109.5 . . ?
C42 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
C42 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C37 C38 C39 120.8(4) . . ?
C37 C38 H38 119.6 . . ?
C39 C38 H38 119.6 . . ?
C38 C37 C42 121.4(4) . . ?
C38 C37 H37 119.3 . . ?
C42 C37 H37 119.3 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2 Ru1 P1 C19 136.94(17) . . . . ?
C6 Ru1 P1 C19 77.93(15) . . . . ?
C1 Ru1 P1 C19 114.00(16) . . . . ?
C5 Ru1 P1 C19 44.92(16) . . . . ?
C3 Ru1 P1 C19 105.8(5) . . . . ?
C4 Ru1 P1 C19 26.52(19) . . . . ?
P2 Ru1 P1 C19 -136.17(12) . . . . ?
Cl1 Ru1 P1 C19 -49.87(12) . . . . ?
C2 Ru1 P1 C13 16.15(19) . . . . ?
C6 Ru1 P1 C13 -42.85(16) . . . . ?
C1 Ru1 P1 C13 -6.78(16) . . . . ?
C5 Ru1 P1 C13 -75.86(16) . . . . ?
C3 Ru1 P1 C13 -15.0(5) . . . . ?
C4 Ru1 P1 C13 -94.27(19) . . . . ?
P2 Ru1 P1 C13 103.05(13) . . . . ?
Cl1 Ru1 P1 C13 -170.65(13) . . . . ?
C2 Ru1 P1 C12 -104.31(17) . . . . ?
C6 Ru1 P1 C12 -163.32(15) . . . . ?
C1 Ru1 P1 C12 -127.24(15) . . . . ?
C5 Ru1 P1 C12 163.68(15) . . . . ?
C3 Ru1 P1 C12 -135.4(5) . . . . ?
C4 Ru1 P1 C12 145.27(17) . . . . ?
P2 Ru1 P1 C12 -17.41(12) . . . . ?
Cl1 Ru1 P1 C12 68.88(12) . . . . ?
C2 Ru1 P2 C31 -108.61(15) . . . . ?
C6 Ru1 P2 C31 -155.9(2) . . . . ?
C1 Ru1 P2 C31 -141.05(16) . . . . ?
C5 Ru1 P2 C31 -66.5(4) . . . . ?
C3 Ru1 P2 C31 -72.49(15) . . . . ?
C4 Ru1 P2 C31 -49.12(17) . . . . ?
P1 Ru1 P2 C31 117.58(13) . . . . ?
Cl1 Ru1 P2 C31 35.22(13) . . . . ?
C2 Ru1 P2 C25 14.48(15) . . . . ?
C6 Ru1 P2 C25 -32.8(2) . . . . ?
C1 Ru1 P2 C25 -17.95(16) . . . . ?
C5 Ru1 P2 C25 56.6(4) . . . . ?
C3 Ru1 P2 C25 50.61(15) . . . . ?
C4 Ru1 P2 C25 73.97(16) . . . . ?
P1 Ru1 P2 C25 -119.32(12) . . . . ?
Cl1 Ru1 P2 C25 158.32(12) . . . . ?
C2 Ru1 P2 C11 131.03(14) . . . . ?
C6 Ru1 P2 C11 83.8(2) . . . . ?
C1 Ru1 P2 C11 98.59(15) . . . . ?
C5 Ru1 P2 C11 173.1(4) . . . . ?
C3 Ru1 P2 C11 167.16(14) . . . . ?
C4 Ru1 P2 C11 -169.48(15) . . . . ?
P1 Ru1 P2 C11 -2.77(11) . . . . ?
Cl1 Ru1 P2 C11 -85.14(11) . . . . ?
C6 Ru1 C2 C1 30.15(19) . . . . ?
C5 Ru1 C2 C1 66.9(2) . . . . ?
C3 Ru1 C2 C1 131.0(3) . . . . ?
C4 Ru1 C2 C1 103.2(2) . . . . ?
P1 Ru1 C2 C1 -39.4(2) . . . . ?
P2 Ru1 C2 C1 -123.05(19) . . . . ?
Cl1 Ru1 C2 C1 152.06(16) . . . . ?
C6 Ru1 C2 C3 -100.8(3) . . . . ?
C1 Ru1 C2 C3 -131.0(3) . . . . ?
C5 Ru1 C2 C3 -64.1(2) . . . . ?
C4 Ru1 C2 C3 -27.8(2) . . . . ?
P1 Ru1 C2 C3 -170.38(18) . . . . ?
P2 Ru1 C2 C3 106.0(2) . . . . ?
Cl1 Ru1 C2 C3 21.1(3) . . . . ?
C3 C2 C1 C6 5.0(5) . . . . ?
Ru1 C2 C1 C6 -54.1(2) . . . . ?
C3 C2 C1 C7 -171.9(3) . . . . ?
Ru1 C2 C1 C7 129.0(3) . . . . ?
C3 C2 C1 Ru1 59.1(3) . . . . ?
C6 Ru1 C1 C2 -130.3(3) . . . . ?
C5 Ru1 C1 C2 -101.2(2) . . . . ?
C3 Ru1 C1 C2 -29.8(2) . . . . ?
C4 Ru1 C1 C2 -65.1(2) . . . . ?
P1 Ru1 C1 C2 151.97(18) . . . . ?
P2 Ru1 C1 C2 63.5(2) . . . . ?
Cl1 Ru1 C1 C2 -103.3(4) . . . . ?
C2 Ru1 C1 C6 130.3(3) . . . . ?
C5 Ru1 C1 C6 29.1(2) . . . . ?
C3 Ru1 C1 C6 100.5(2) . . . . ?
C4 Ru1 C1 C6 65.2(2) . . . . ?
P1 Ru1 C1 C6 -77.72(19) . . . . ?
P2 Ru1 C1 C6 -166.19(17) . . . . ?
Cl1 Ru1 C1 C6 27.0(5) . . . . ?
C2 Ru1 C1 C7 -114.8(5) . . . . ?
C6 Ru1 C1 C7 114.9(5) . . . . ?
C5 Ru1 C1 C7 144.0(5) . . . . ?
C3 Ru1 C1 C7 -144.5(5) . . . . ?
C4 Ru1 C1 C7 -179.9(5) . . . . ?
P1 Ru1 C1 C7 37.2(4) . . . . ?
P2 Ru1 C1 C7 -51.3(4) . . . . ?
Cl1 Ru1 C1 C7 141.9(3) . . . . ?
C2 C1 C6 C5 -2.6(5) . . . . ?
C7 C1 C6 C5 174.3(3) . . . . ?
Ru1 C1 C6 C5 -56.1(3) . . . . ?
C2 C1 C6 Ru1 53.4(2) . . . . ?
C7 C1 C6 Ru1 -129.7(3) . . . . ?
C2 Ru1 C6 C5 101.7(3) . . . . ?
C1 Ru1 C6 C5 131.6(3) . . . . ?
C3 Ru1 C6 C5 64.3(2) . . . . ?
C4 Ru1 C6 C5 28.6(2) . . . . ?
P1 Ru1 C6 C5 -121.0(2) . . . . ?
P2 Ru1 C6 C5 155.12(17) . . . . ?
Cl1 Ru1 C6 C5 -39.0(3) . . . . ?
C2 Ru1 C6 C1 -30.00(19) . . . . ?
C5 Ru1 C6 C1 -131.6(3) . . . . ?
C3 Ru1 C6 C1 -67.3(2) . . . . ?
C4 Ru1 C6 C1 -103.1(2) . . . . ?
P1 Ru1 C6 C1 107.34(18) . . . . ?
P2 Ru1 C6 C1 23.5(3) . . . . ?
Cl1 Ru1 C6 C1 -170.60(15) . . . . ?
C1 C6 C5 C4 0.1(5) . . . . ?
Ru1 C6 C5 C4 -55.7(3) . . . . ?
C1 C6 C5 Ru1 55.9(3) . . . . ?
C2 Ru1 C5 C6 -66.4(2) . . . . ?
C1 Ru1 C5 C6 -29.4(2) . . . . ?
C3 Ru1 C5 C6 -103.3(3) . . . . ?
C4 Ru1 C5 C6 -132.5(3) . . . . ?
P1 Ru1 C5 C6 65.9(2) . . . . ?
P2 Ru1 C5 C6 -109.8(4) . . . . ?
Cl1 Ru1 C5 C6 150.0(2) . . . . ?
C2 Ru1 C5 C4 66.1(2) . . . . ?
C6 Ru1 C5 C4 132.5(3) . . . . ?
C1 Ru1 C5 C4 103.1(2) . . . . ?
C3 Ru1 C5 C4 29.24(18) . . . . ?
P1 Ru1 C5 C4 -161.61(17) . . . . ?
P2 Ru1 C5 C4 22.7(5) . . . . ?
Cl1 Ru1 C5 C4 -77.53(19) . . . . ?
C6 C5 C4 C3 0.2(5) . . . . ?
Ru1 C5 C4 C3 -54.4(3) . . . . ?
C6 C5 C4 C8 -179.1(3) . . . . ?
Ru1 C5 C4 C8 126.4(3) . . . . ?
C6 C5 C4 Ru1 54.5(3) . . . . ?
C2 Ru1 C4 C3 28.8(2) . . . . ?
C6 Ru1 C4 C3 102.1(2) . . . . ?
C1 Ru1 C4 C3 65.3(2) . . . . ?
C5 Ru1 C4 C3 130.8(3) . . . . ?
P1 Ru1 C4 C3 160.87(17) . . . . ?
P2 Ru1 C4 C3 -41.9(2) . . . . ?
Cl1 Ru1 C4 C3 -124.8(2) . . . . ?
C2 Ru1 C4 C5 -102.1(2) . . . . ?
C6 Ru1 C4 C5 -28.8(2) . . . . ?
C1 Ru1 C4 C5 -65.5(2) . . . . ?
C3 Ru1 C4 C5 -130.8(3) . . . . ?
P1 Ru1 C4 C5 30.0(3) . . . . ?
P2 Ru1 C4 C5 -172.73(16) . . . . ?
Cl1 Ru1 C4 C5 104.33(19) . . . . ?
C2 Ru1 C4 C8 147.3(4) . . . . ?
C6 Ru1 C4 C8 -139.4(4) . . . . ?
C1 Ru1 C4 C8 -176.2(4) . . . . ?
C5 Ru1 C4 C8 -110.6(4) . . . . ?
C3 Ru1 C4 C8 118.5(5) . . . . ?
P1 Ru1 C4 C8 -80.6(4) . . . . ?
P2 Ru1 C4 C8 76.6(4) . . . . ?
Cl1 Ru1 C4 C8 -6.3(4) . . . . ?
C3 C4 C8 C9 21.6(5) . . . . ?
C5 C4 C8 C9 -159.2(3) . . . . ?
Ru1 C4 C8 C9 -71.8(5) . . . . ?
C3 C4 C8 C10 -104.4(4) . . . . ?
C5 C4 C8 C10 74.8(4) . . . . ?
Ru1 C4 C8 C10 162.2(3) . . . . ?
C5 C4 C3 C2 2.1(5) . . . . ?
C8 C4 C3 C2 -178.7(3) . . . . ?
Ru1 C4 C3 C2 -51.8(3) . . . . ?
C5 C4 C3 Ru1 53.9(3) . . . . ?
C8 C4 C3 Ru1 -126.9(3) . . . . ?
C1 C2 C3 C4 -4.9(5) . . . . ?
Ru1 C2 C3 C4 53.9(3) . . . . ?
C1 C2 C3 Ru1 -58.8(3) . . . . ?
C2 Ru1 C3 C4 -133.2(3) . . . . ?
C6 Ru1 C3 C4 -66.2(2) . . . . ?
C1 Ru1 C3 C4 -103.6(2) . . . . ?
C5 Ru1 C3 C4 -29.71(19) . . . . ?
P1 Ru1 C3 C4 -94.8(5) . . . . ?
P2 Ru1 C3 C4 148.63(18) . . . . ?
Cl1 Ru1 C3 C4 59.8(2) . . . . ?
C6 Ru1 C3 C2 67.0(2) . . . . ?
C1 Ru1 C3 C2 29.6(2) . . . . ?
C5 Ru1 C3 C2 103.5(3) . . . . ?
C4 Ru1 C3 C2 133.2(3) . . . . ?
P1 Ru1 C3 C2 38.4(6) . . . . ?
P2 Ru1 C3 C2 -78.2(2) . . . . ?
Cl1 Ru1 C3 C2 -167.1(2) . . . . ?
C17 C18 C13 C14 0.5(5) . . . . ?
C17 C18 C13 P1 -178.5(3) . . . . ?
C19 P1 C13 C14 137.9(3) . . . . ?
C12 P1 C13 C14 29.5(3) . . . . ?
Ru1 P1 C13 C14 -92.3(3) . . . . ?
C19 P1 C13 C18 -43.1(3) . . . . ?
C12 P1 C13 C18 -151.5(3) . . . . ?
Ru1 P1 C13 C18 86.8(3) . . . . ?
C13 C18 C17 C16 0.0(6) . . . . ?
C18 C17 C16 C15 -0.7(6) . . . . ?
C17 C16 C15 C14 0.7(5) . . . . ?
C16 C15 C14 C13 -0.1(5) . . . . ?
C18 C13 C14 C15 -0.5(5) . . . . ?
P1 C13 C14 C15 178.5(3) . . . . ?
C13 P1 C19 C20 -67.2(3) . . . . ?
C12 P1 C19 C20 42.7(3) . . . . ?
Ru1 P1 C19 C20 163.7(2) . . . . ?
C13 P1 C19 C24 108.6(3) . . . . ?
C12 P1 C19 C24 -141.6(3) . . . . ?
Ru1 P1 C19 C24 -20.6(3) . . . . ?
C24 C19 C20 C21 0.1(5) . . . . ?
P1 C19 C20 C21 176.0(2) . . . . ?
C19 C20 C21 C22 -1.8(5) . . . . ?
C20 C21 C22 C23 1.6(5) . . . . ?
C21 C22 C23 C24 0.4(5) . . . . ?
C22 C23 C24 C19 -2.1(5) . . . . ?
C20 C19 C24 C23 1.9(5) . . . . ?
P1 C19 C24 C23 -173.8(3) . . . . ?
C19 P1 C12 C11 166.5(2) . . . . ?
C13 P1 C12 C11 -88.0(2) . . . . ?
Ru1 P1 C12 C11 39.2(2) . . . . ?
P1 C12 C11 P2 -42.3(3) . . . . ?
C31 P2 C11 C12 -98.2(2) . . . . ?
C25 P2 C11 C12 151.4(2) . . . . ?
Ru1 P2 C11 C12 27.3(2) . . . . ?
C31 P2 C25 C30 24.0(3) . . . . ?
C11 P2 C25 C30 135.5(3) . . . . ?
Ru1 P2 C25 C30 -104.4(3) . . . . ?
C31 P2 C25 C26 -160.4(3) . . . . ?
C11 P2 C25 C26 -48.9(3) . . . . ?
Ru1 P2 C25 C26 71.2(3) . . . . ?
C30 C25 C26 C27 0.5(5) . . . . ?
P2 C25 C26 C27 -175.3(3) . . . . ?
C25 C26 C27 C28 0.1(5) . . . . ?
C26 C27 C28 C29 0.1(6) . . . . ?
C27 C28 C29 C30 -0.9(5) . . . . ?
C28 C29 C30 C25 1.4(5) . . . . ?
C26 C25 C30 C29 -1.2(5) . . . . ?
P2 C25 C30 C29 174.4(3) . . . . ?
C25 P2 C31 C32 113.0(3) . . . . ?
C11 P2 C31 C32 3.8(3) . . . . ?
Ru1 P2 C31 C32 -118.3(3) . . . . ?
C25 P2 C31 C36 -69.6(3) . . . . ?
C11 P2 C31 C36 -178.8(3) . . . . ?
Ru1 P2 C31 C36 59.1(3) . . . . ?
C36 C31 C32 C33 2.1(5) . . . . ?
P2 C31 C32 C33 179.5(3) . . . . ?
C31 C32 C33 C34 -0.5(5) . . . . ?
C32 C33 C34 C35 -0.6(6) . . . . ?
C33 C34 C35 C36 0.0(6) . . . . ?
C34 C35 C36 C31 1.7(5) . . . . ?
C32 C31 C36 C35 -2.8(5) . . . . ?
P2 C31 C36 C35 179.8(3) . . . . ?
C38 C39 C40 C41 0.5(6) . . . . ?
C39 C40 C41 C42 -0.5(6) . . . . ?
C40 C41 C42 C37 0.8(5) . . . . ?
C40 C41 C42 C43 -179.1(4) . . . . ?
C40 C39 C38 C37 -0.9(6) . . . . ?
C39 C38 C37 C42 1.2(6) . . . . ?
C41 C42 C37 C38 -1.2(5) . . . . ?
C43 C42 C37 C38 178.7(4) . . . . ?

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        24.99
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         0.483
_refine_diff_density_min         -0.379
_refine_diff_density_rms         0.063
