# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_cmpnd_2
_database_code_depnum_ccdc_archive 'CCDC 2206804'
loop_
_audit_author_name
_audit_author_address
'Pilar Garcia-Orduna'
;Instituto de Sintesis Quimica y Catalisis Homogenea (ISQCH, CSIC and  Univ Zaragoza)
Spain
;
_audit_update_record             
;
2022-09-12 deposited with the CCDC.	2022-11-24 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C37 H33 F3 N4 P Rh,2(F6 Sb),2(C H2 Cl2)'
_chemical_formula_sum            'C39 H37 Cl4 F15 N4 P Rh Sb2'
_chemical_formula_weight         1365.90

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.2805(9)
_cell_length_b                   13.6365(9)
_cell_length_c                   14.6021(10)
_cell_angle_alpha                96.0690(10)
_cell_angle_beta                 102.032(2)
_cell_angle_gamma                92.269(2)
_cell_volume                     2373.4(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    6927
_cell_measurement_theta_min      2.340
_cell_measurement_theta_max      26.745

_exptl_crystal_description       prism
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.911
_exptl_crystal_F_000             1328
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.115
_exptl_crystal_size_min          0.070
_exptl_absorpt_coefficient_mu    1.826
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.7569
_exptl_absorpt_correction_T_max  0.8373

_exptl_absorpt_process_details   
;
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10
;
_exptl_absorpt_special_details   ?


_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX CCD system'
_diffrn_measurement_method       'narrow ω frames'
_diffrn_detector_area_resol_mean 8.26
_diffrn_reflns_number            32424
_diffrn_reflns_av_unetI/netI     0.0632
_diffrn_reflns_av_R_equivalents  0.0436
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         1.436
_diffrn_reflns_theta_max         29.187
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.978
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.978
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             12574
_reflns_number_gt                9063
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'SMART in APEX2 v. 2008.4 (Bruker AXS, 2008)'
_computing_cell_refinement       'SAINT+ in APEX3 v. 2017.3 (Bruker AXS, 2008)'
_computing_data_reduction        'SAINT+ in APEX3 v. 2017.3 (Bruker AXS, 2008)'
_computing_structure_solution    'SHELXS-2013 (Sheldrick, 2013)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'ORTEP-3 (farrugia, 2012)'
_computing_publication_material  'XCIF program, PLATON(Spek, 1998)'


_refine_special_details          
;
Hydrogen atoms have been observed in Fourier difference maps. However, in
order to decrease the number of refined parameters, they have been 
included in the model in observed positions and refined with a riding
model.

At the end of the refinement, when convergence is achieved highest 
residual density peaks are observed close to Sb atoms. They have no chemical
sense.

;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0526P)²+4.4625P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         12574
_refine_ls_number_parameters     597
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0800
_refine_ls_R_factor_gt           0.0485
_refine_ls_wR_factor_ref         0.1180
_refine_ls_wR_factor_gt          0.1051
_refine_ls_goodness_of_fit_ref   1.016
_refine_ls_restrained_S_all      1.016
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh Rh 0.72209(3) 0.74945(2) 0.25612(2) 0.01373(8) Uani 1 1 d . . . . .
P P 0.89969(9) 0.80996(8) 0.25739(7) 0.0132(2) Uani 1 1 d . . . . .
N1 N 0.6435(3) 0.8623(3) 0.1898(2) 0.0158(7) Uani 1 1 d . . . . .
N2 N 0.5550(3) 0.7069(3) 0.2538(2) 0.0168(7) Uani 1 1 d . . . . .
N3 N 0.7834(3) 0.6336(3) 0.3223(3) 0.0163(7) Uani 1 1 d . . . . .
N4 N 0.7065(3) 0.6605(3) 0.1212(3) 0.0188(8) Uani 1 1 d . . . . .
C1 C 1.0028(4) 0.8045(3) 0.3662(3) 0.0150(8) Uani 1 1 d . . . . .
C2 C 1.0037(4) 0.8702(3) 0.4467(3) 0.0201(9) Uani 1 1 d . . . . .
H2 H 0.951220 0.919654 0.444978 0.024 Uiso 1 1 calc R U . . .
C3 C 1.0810(4) 0.8629(4) 0.5287(3) 0.0246(10) Uani 1 1 d . . . . .
H3 H 1.081403 0.908159 0.582930 0.030 Uiso 1 1 calc R U . . .
C4 C 1.1573(4) 0.7919(4) 0.5336(3) 0.0261(11) Uani 1 1 d . . . . .
H4 H 1.209422 0.787362 0.590752 0.031 Uiso 1 1 calc R U . . .
C5 C 1.1574(4) 0.7271(4) 0.4544(3) 0.0276(11) Uani 1 1 d . . . . .
H5 H 1.210562 0.678212 0.457043 0.033 Uiso 1 1 calc R U . . .
C6 C 1.0806(4) 0.7324(3) 0.3707(3) 0.0202(9) Uani 1 1 d . . . . .
H6 H 1.081147 0.687137 0.316733 0.024 Uiso 1 1 calc R U . . .
C7 C 0.9632(4) 0.7487(3) 0.1668(3) 0.0163(9) Uani 1 1 d . . . . .
C8 C 1.0190(4) 0.8023(3) 0.1123(3) 0.0195(9) Uani 1 1 d . . . . .
H8 H 1.019498 0.872378 0.119484 0.023 Uiso 1 1 calc R U . . .
C9 C 1.0737(4) 0.7549(4) 0.0479(3) 0.0242(10) Uani 1 1 d . . . . .
H9 H 1.110297 0.792229 0.010512 0.029 Uiso 1 1 calc R U . . .
C10 C 1.0748(4) 0.6525(4) 0.0383(3) 0.0263(11) Uani 1 1 d . . . . .
H10 H 1.112824 0.619765 -0.005303 0.032 Uiso 1 1 calc R U . . .
C11 C 1.0208(4) 0.5983(4) 0.0920(3) 0.0236(10) Uani 1 1 d . . . . .
H11 H 1.022261 0.528319 0.085313 0.028 Uiso 1 1 calc R U . . .
C12 C 0.9643(4) 0.6450(3) 0.1557(3) 0.0177(9) Uani 1 1 d . . . . .
H12 H 0.926430 0.606964 0.191761 0.021 Uiso 1 1 calc R U . . .
C13 C 0.8996(4) 0.9380(3) 0.2338(3) 0.0154(8) Uani 1 1 d . . . . .
C14 C 0.9928(4) 1.0020(3) 0.2709(3) 0.0198(9) Uani 1 1 d . . . . .
H14 H 1.054900 0.979652 0.312127 0.024 Uiso 1 1 calc R U . . .
C15 C 0.9964(4) 1.0985(3) 0.2483(3) 0.0232(10) Uani 1 1 d . . . . .
H15 H 1.061384 1.141150 0.272683 0.028 Uiso 1 1 calc R U . . .
C16 C 0.9059(4) 1.1318(3) 0.1907(3) 0.0250(10) Uani 1 1 d . . . . .
H16 H 0.906904 1.198363 0.177131 0.030 Uiso 1 1 calc R U . . .
C17 C 0.8124(4) 1.0681(3) 0.1522(3) 0.0221(10) Uani 1 1 d . . . . .
H17 H 0.750549 1.091526 0.111607 0.026 Uiso 1 1 calc R U . . .
C18 C 0.8081(4) 0.9706(3) 0.1721(3) 0.0154(8) Uani 1 1 d . . . . .
C19 C 0.7058(4) 0.9053(3) 0.1238(3) 0.0171(9) Uani 1 1 d . . . . .
H19A H 0.654579 0.944286 0.082414 0.021 Uiso 1 1 calc R U . . .
H19B H 0.728577 0.850487 0.083250 0.021 Uiso 1 1 calc R U . . .
C20 C 0.5354(4) 0.8145(3) 0.1318(3) 0.0193(9) Uani 1 1 d . . . . .
H20A H 0.549160 0.773306 0.075866 0.023 Uiso 1 1 calc R U . . .
H20B H 0.484726 0.865886 0.109766 0.023 Uiso 1 1 calc R U . . .
C21 C 0.4825(4) 0.7514(3) 0.1910(3) 0.0184(9) Uani 1 1 d . . . . .
C22 C 0.3675(4) 0.7356(4) 0.1813(3) 0.0254(10) Uani 1 1 d . . . . .
H22 H 0.316682 0.766856 0.136946 0.030 Uiso 1 1 calc R U . . .
C23 C 0.3298(4) 0.6732(4) 0.2381(4) 0.0289(11) Uani 1 1 d . . . . .
H23 H 0.251946 0.660544 0.232513 0.035 Uiso 1 1 calc R U . . .
C24 C 0.4037(4) 0.6297(4) 0.3022(3) 0.0263(11) Uani 1 1 d . . . . .
H24 H 0.377863 0.586904 0.341501 0.032 Uiso 1 1 calc R U . . .
C25 C 0.5169(4) 0.6489(3) 0.3093(3) 0.0220(10) Uani 1 1 d . . . . .
H25 H 0.568596 0.619902 0.354941 0.026 Uiso 1 1 calc R U . . .
C26 C 0.6190(4) 0.9440(3) 0.2609(3) 0.0179(9) Uani 1 1 d . . . . .
H26A H 0.651105 1.008139 0.249456 0.021 Uiso 1 1 calc R U . . .
H26B H 0.537260 0.948222 0.252554 0.021 Uiso 1 1 calc R U . . .
C27 C 0.6673(4) 0.9242(3) 0.3596(3) 0.0160(9) Uani 1 1 d . . . . .
C28 C 0.7206(4) 0.8374(3) 0.3751(3) 0.0158(8) Uani 1 1 d . . . . .
C29 C 0.7560(4) 0.8155(4) 0.4677(3) 0.0197(9) Uani 1 1 d . . . . .
H29 H 0.791256 0.755993 0.479755 0.024 Uiso 1 1 calc R U . . .
C30 C 0.7390(4) 0.8817(4) 0.5422(3) 0.0219(10) Uani 1 1 d . . . . .
H30 H 0.762675 0.866778 0.605125 0.026 Uiso 1 1 calc R U . . .
C31 C 0.6882(4) 0.9685(3) 0.5259(3) 0.0174(9) Uani 1 1 d . . . . .
C32 C 0.6524(4) 0.9905(3) 0.4350(3) 0.0170(9) Uani 1 1 d . . . . .
H32 H 0.617631 1.050371 0.423731 0.020 Uiso 1 1 calc R U . . .
C33 C 0.6682(4) 1.0371(4) 0.6073(3) 0.0233(10) Uani 1 1 d . . . . .
C34 C 0.8128(4) 0.5655(4) 0.3531(3) 0.0218(10) Uani 1 1 d . . . . .
C35 C 0.8508(5) 0.4758(4) 0.3932(4) 0.0390(14) Uani 1 1 d . . . . .
H35A H 0.835985 0.477172 0.456714 0.059 Uiso 1 1 calc R U . . .
H35B H 0.931102 0.472444 0.396584 0.059 Uiso 1 1 calc R U . . .
H35C H 0.810837 0.417764 0.353248 0.059 Uiso 1 1 calc R U . . .
C36 C 0.7004(4) 0.6178(4) 0.0494(3) 0.0238(10) Uani 1 1 d . . . . .
C37 C 0.6971(5) 0.5660(4) -0.0437(4) 0.0351(13) Uani 1 1 d . . . . .
H37A H 0.699746 0.614217 -0.088544 0.053 Uiso 1 1 calc R U . . .
H37B H 0.628071 0.523722 -0.064206 0.053 Uiso 1 1 calc R U . . .
H37C H 0.761407 0.525191 -0.040997 0.053 Uiso 1 1 calc R U . . .
F1 F 0.7611(3) 1.0775(3) 0.6642(2) 0.0482(10) Uani 1 1 d . . . . .
F2 F 0.6072(3) 1.1130(2) 0.5810(2) 0.0421(8) Uani 1 1 d . . . . .
F3 F 0.6111(3) 0.9914(2) 0.6611(2) 0.0380(8) Uani 1 1 d . . . . .
Sb1 Sb 0.63158(3) 0.33762(3) 0.12407(2) 0.02973(10) Uani 1 1 d . . . . .
F4 F 0.6818(3) 0.2394(2) 0.0452(2) 0.0466(9) Uani 1 1 d . . . . .
F5 F 0.5811(3) 0.4369(3) 0.1996(3) 0.0610(11) Uani 1 1 d . . . . .
F6 F 0.5026(4) 0.2579(3) 0.1164(3) 0.0640(12) Uani 1 1 d . . . . .
F7 F 0.7598(3) 0.4183(3) 0.1264(3) 0.0504(9) Uani 1 1 d . . . . .
F8 F 0.5578(3) 0.3894(2) 0.0159(2) 0.0415(8) Uani 1 1 d . . . . .
F9 F 0.7031(3) 0.2826(3) 0.2312(2) 0.0514(10) Uani 1 1 d . . . . .
Sb2 Sb 0.85500(3) 0.60839(2) 0.69228(2) 0.02645(9) Uani 1 1 d . . . . .
F10 F 0.9615(3) 0.6504(3) 0.8000(3) 0.0658(13) Uani 1 1 d . . . . .
F11 F 0.7477(4) 0.5639(3) 0.5831(3) 0.0743(14) Uani 1 1 d . . . . .
F12 F 0.7668(4) 0.5515(3) 0.7631(3) 0.0632(12) Uani 1 1 d . . . . .
F13 F 0.9411(4) 0.6655(3) 0.6188(4) 0.0735(15) Uani 1 1 d . . . . .
F14 F 0.7828(3) 0.7262(2) 0.7033(2) 0.0342(7) Uani 1 1 d . . . . .
F15 F 0.9249(4) 0.4900(3) 0.6779(3) 0.0636(12) Uani 1 1 d . . . . .
C51 C 0.2881(6) 0.1190(4) 0.1510(4) 0.0419(15) Uani 1 1 d . . . . .
H51A H 0.271793 0.118343 0.214495 0.050 Uiso 1 1 calc R U . . .
H51B H 0.358037 0.160231 0.157295 0.050 Uiso 1 1 calc R U . . .
Cl1 Cl 0.30605(17) -0.00287(12) 0.10437(11) 0.0547(5) Uani 1 1 d . . . . .
Cl2 Cl 0.17804(14) 0.17068(13) 0.07729(10) 0.0458(4) Uani 1 1 d . . . . .
C52 C 0.5177(6) 0.6523(5) 0.6300(6) 0.061(2) Uani 1 1 d . . . . .
H52A H 0.525241 0.637491 0.695871 0.073 Uiso 1 1 calc R U . . .
H52B H 0.589060 0.638892 0.611070 0.073 Uiso 1 1 calc R U . . .
Cl3 Cl 0.41193(15) 0.57381(13) 0.55779(11) 0.0505(4) Uani 1 1 d . . . . .
Cl4 Cl 0.4951(2) 0.77580(16) 0.6257(2) 0.1011(10) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh C28 2.007(4) . ?
Rh N3 2.028(4) . ?
Rh N1 2.069(4) . ?
Rh N2 2.102(4) . ?
Rh N4 2.170(4) . ?
Rh P 2.2968(12) . ?
P C13 1.815(4) . ?
P C7 1.818(4) . ?
P C1 1.823(4) . ?
N1 C19 1.499(6) . ?
N1 C20 1.500(5) . ?
N1 C26 1.524(5) . ?
N2 C25 1.329(6) . ?
N2 C21 1.350(6) . ?
N3 C34 1.114(6) . ?
N4 C36 1.131(6) . ?
C1 C6 1.395(6) . ?
C1 C2 1.399(6) . ?
C2 C3 1.379(6) . ?
C2 H2 0.9500 . ?
C3 C4 1.371(7) . ?
C3 H3 0.9500 . ?
C4 C5 1.379(7) . ?
C4 H4 0.9500 . ?
C5 C6 1.389(6) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C8 1.395(6) . ?
C7 C12 1.407(6) . ?
C8 C9 1.387(6) . ?
C8 H8 0.9500 . ?
C9 C10 1.389(7) . ?
C9 H9 0.9500 . ?
C10 C11 1.378(7) . ?
C10 H10 0.9500 . ?
C11 C12 1.391(6) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C14 1.389(6) . ?
C13 C18 1.405(6) . ?
C14 C15 1.390(6) . ?
C14 H14 0.9500 . ?
C15 C16 1.372(7) . ?
C15 H15 0.9500 . ?
C16 C17 1.391(7) . ?
C16 H16 0.9500 . ?
C17 C18 1.391(6) . ?
C17 H17 0.9500 . ?
C18 C19 1.510(6) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 C21 1.502(6) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C21 C22 1.395(6) . ?
C22 C23 1.380(7) . ?
C22 H22 0.9500 . ?
C23 C24 1.362(7) . ?
C23 H23 0.9500 . ?
C24 C25 1.385(7) . ?
C24 H24 0.9500 . ?
C25 H25 0.9500 . ?
C26 C27 1.497(6) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C27 C28 1.393(6) . ?
C27 C32 1.397(6) . ?
C28 C29 1.399(6) . ?
C29 C30 1.394(6) . ?
C29 H29 0.9500 . ?
C30 C31 1.379(7) . ?
C30 H30 0.9500 . ?
C31 C32 1.377(6) . ?
C31 C33 1.500(6) . ?
C32 H32 0.9500 . ?
C33 F1 1.325(5) . ?
C33 F3 1.340(6) . ?
C33 F2 1.344(6) . ?
C34 C35 1.462(7) . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
C36 C37 1.456(7) . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
Sb1 F6 1.862(4) . ?
Sb1 F5 1.863(3) . ?
Sb1 F8 1.872(3) . ?
Sb1 F9 1.873(3) . ?
Sb1 F7 1.877(4) . ?
Sb1 F4 1.880(3) . ?
Sb2 F10 1.845(4) . ?
Sb2 F12 1.848(4) . ?
Sb2 F13 1.861(4) . ?
Sb2 F15 1.871(4) . ?
Sb2 F11 1.872(4) . ?
Sb2 F14 1.874(3) . ?
C51 Cl2 1.764(6) . ?
C51 Cl1 1.768(6) . ?
C51 H51A 0.9900 . ?
C51 H51B 0.9900 . ?
C52 Cl4 1.723(7) . ?
C52 Cl3 1.740(7) . ?
C52 H52A 0.9900 . ?
C52 H52B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C28 Rh N3 95.16(16) . . ?
C28 Rh N1 84.30(16) . . ?
N3 Rh N1 174.12(15) . . ?
C28 Rh N2 86.84(16) . . ?
N3 Rh N2 94.02(15) . . ?
N1 Rh N2 80.10(15) . . ?
C28 Rh N4 173.81(16) . . ?
N3 Rh N4 89.56(14) . . ?
N1 Rh N4 90.59(14) . . ?
N2 Rh N4 88.84(14) . . ?
C28 Rh P 90.81(13) . . ?
N3 Rh P 90.69(11) . . ?
N1 Rh P 95.17(11) . . ?
N2 Rh P 174.91(11) . . ?
N4 Rh P 93.15(10) . . ?
C13 P C7 103.8(2) . . ?
C13 P C1 107.1(2) . . ?
C7 P C1 103.7(2) . . ?
C13 P Rh 110.56(15) . . ?
C7 P Rh 114.77(15) . . ?
C1 P Rh 115.88(14) . . ?
C19 N1 C20 107.5(3) . . ?
C19 N1 C26 110.0(3) . . ?
C20 N1 C26 109.1(3) . . ?
C19 N1 Rh 113.8(3) . . ?
C20 N1 Rh 104.7(3) . . ?
C26 N1 Rh 111.5(3) . . ?
C25 N2 C21 119.7(4) . . ?
C25 N2 Rh 127.7(3) . . ?
C21 N2 Rh 112.4(3) . . ?
C34 N3 Rh 174.8(4) . . ?
C36 N4 Rh 176.8(4) . . ?
C6 C1 C2 118.9(4) . . ?
C6 C1 P 120.0(3) . . ?
C2 C1 P 121.1(3) . . ?
C3 C2 C1 119.9(4) . . ?
C3 C2 H2 120.1 . . ?
C1 C2 H2 120.1 . . ?
C4 C3 C2 121.4(4) . . ?
C4 C3 H3 119.3 . . ?
C2 C3 H3 119.3 . . ?
C3 C4 C5 119.2(4) . . ?
C3 C4 H4 120.4 . . ?
C5 C4 H4 120.4 . . ?
C4 C5 C6 120.8(4) . . ?
C4 C5 H5 119.6 . . ?
C6 C5 H5 119.6 . . ?
C5 C6 C1 119.8(4) . . ?
C5 C6 H6 120.1 . . ?
C1 C6 H6 120.1 . . ?
C8 C7 C12 118.6(4) . . ?
C8 C7 P 121.5(3) . . ?
C12 C7 P 119.7(3) . . ?
C9 C8 C7 121.0(4) . . ?
C9 C8 H8 119.5 . . ?
C7 C8 H8 119.5 . . ?
C8 C9 C10 119.7(5) . . ?
C8 C9 H9 120.1 . . ?
C10 C9 H9 120.1 . . ?
C11 C10 C9 120.1(4) . . ?
C11 C10 H10 120.0 . . ?
C9 C10 H10 120.0 . . ?
C10 C11 C12 120.7(4) . . ?
C10 C11 H11 119.7 . . ?
C12 C11 H11 119.7 . . ?
C11 C12 C7 119.9(4) . . ?
C11 C12 H12 120.1 . . ?
C7 C12 H12 120.1 . . ?
C14 C13 C18 119.8(4) . . ?
C14 C13 P 120.3(3) . . ?
C18 C13 P 119.8(3) . . ?
C13 C14 C15 120.8(4) . . ?
C13 C14 H14 119.6 . . ?
C15 C14 H14 119.6 . . ?
C16 C15 C14 119.7(4) . . ?
C16 C15 H15 120.1 . . ?
C14 C15 H15 120.1 . . ?
C15 C16 C17 120.1(4) . . ?
C15 C16 H16 120.0 . . ?
C17 C16 H16 120.0 . . ?
C16 C17 C18 121.1(4) . . ?
C16 C17 H17 119.4 . . ?
C18 C17 H17 119.4 . . ?
C17 C18 C13 118.5(4) . . ?
C17 C18 C19 117.6(4) . . ?
C13 C18 C19 123.8(4) . . ?
N1 C19 C18 114.4(3) . . ?
N1 C19 H19A 108.7 . . ?
C18 C19 H19A 108.7 . . ?
N1 C19 H19B 108.7 . . ?
C18 C19 H19B 108.7 . . ?
H19A C19 H19B 107.6 . . ?
N1 C20 C21 109.1(3) . . ?
N1 C20 H20A 109.9 . . ?
C21 C20 H20A 109.9 . . ?
N1 C20 H20B 109.9 . . ?
C21 C20 H20B 109.9 . . ?
H20A C20 H20B 108.3 . . ?
N2 C21 C22 121.2(4) . . ?
N2 C21 C20 114.9(4) . . ?
C22 C21 C20 123.9(4) . . ?
C23 C22 C21 118.1(5) . . ?
C23 C22 H22 121.0 . . ?
C21 C22 H22 121.0 . . ?
C24 C23 C22 120.4(5) . . ?
C24 C23 H23 119.8 . . ?
C22 C23 H23 119.8 . . ?
C23 C24 C25 119.0(5) . . ?
C23 C24 H24 120.5 . . ?
C25 C24 H24 120.5 . . ?
N2 C25 C24 121.6(5) . . ?
N2 C25 H25 119.2 . . ?
C24 C25 H25 119.2 . . ?
C27 C26 N1 110.8(3) . . ?
C27 C26 H26A 109.5 . . ?
N1 C26 H26A 109.5 . . ?
C27 C26 H26B 109.5 . . ?
N1 C26 H26B 109.5 . . ?
H26A C26 H26B 108.1 . . ?
C28 C27 C32 120.9(4) . . ?
C28 C27 C26 119.6(4) . . ?
C32 C27 C26 119.4(4) . . ?
C27 C28 C29 118.9(4) . . ?
C27 C28 Rh 113.6(3) . . ?
C29 C28 Rh 127.1(3) . . ?
C30 C29 C28 119.4(4) . . ?
C30 C29 H29 120.3 . . ?
C28 C29 H29 120.3 . . ?
C31 C30 C29 121.0(4) . . ?
C31 C30 H30 119.5 . . ?
C29 C30 H30 119.5 . . ?
C32 C31 C30 120.1(4) . . ?
C32 C31 C33 120.0(4) . . ?
C30 C31 C33 119.8(4) . . ?
C31 C32 C27 119.6(4) . . ?
C31 C32 H32 120.2 . . ?
C27 C32 H32 120.2 . . ?
F1 C33 F3 106.4(4) . . ?
F1 C33 F2 105.7(4) . . ?
F3 C33 F2 104.7(4) . . ?
F1 C33 C31 113.5(4) . . ?
F3 C33 C31 112.2(4) . . ?
F2 C33 C31 113.7(4) . . ?
N3 C34 C35 179.7(6) . . ?
C34 C35 H35A 109.5 . . ?
C34 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C34 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
N4 C36 C37 177.2(6) . . ?
C36 C37 H37A 109.5 . . ?
C36 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C36 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
F6 Sb1 F5 91.0(2) . . ?
F6 Sb1 F8 87.80(17) . . ?
F5 Sb1 F8 90.17(16) . . ?
F6 Sb1 F9 90.86(19) . . ?
F5 Sb1 F9 90.62(17) . . ?
F8 Sb1 F9 178.45(17) . . ?
F6 Sb1 F7 177.63(17) . . ?
F5 Sb1 F7 89.96(18) . . ?
F8 Sb1 F7 90.04(16) . . ?
F9 Sb1 F7 91.29(17) . . ?
F6 Sb1 F4 89.40(19) . . ?
F5 Sb1 F4 178.51(17) . . ?
F8 Sb1 F4 88.41(14) . . ?
F9 Sb1 F4 90.80(15) . . ?
F7 Sb1 F4 89.56(17) . . ?
F10 Sb2 F12 90.5(2) . . ?
F10 Sb2 F13 90.7(2) . . ?
F12 Sb2 F13 178.8(2) . . ?
F10 Sb2 F15 90.21(19) . . ?
F12 Sb2 F15 90.18(19) . . ?
F13 Sb2 F15 90.16(18) . . ?
F10 Sb2 F11 179.19(19) . . ?
F12 Sb2 F11 89.3(2) . . ?
F13 Sb2 F11 89.5(2) . . ?
F15 Sb2 F11 89.0(2) . . ?
F10 Sb2 F14 91.31(16) . . ?
F12 Sb2 F14 90.21(17) . . ?
F13 Sb2 F14 89.42(15) . . ?
F15 Sb2 F14 178.43(17) . . ?
F11 Sb2 F14 89.48(17) . . ?
Cl2 C51 Cl1 110.9(3) . . ?
Cl2 C51 H51A 109.5 . . ?
Cl1 C51 H51A 109.5 . . ?
Cl2 C51 H51B 109.5 . . ?
Cl1 C51 H51B 109.5 . . ?
H51A C51 H51B 108.0 . . ?
Cl4 C52 Cl3 113.6(4) . . ?
Cl4 C52 H52A 108.9 . . ?
Cl3 C52 H52A 108.9 . . ?
Cl4 C52 H52B 108.9 . . ?
Cl3 C52 H52B 108.9 . . ?
H52A C52 H52B 107.7 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C13 P C1 C6 -132.4(4) . . . . ?
C7 P C1 C6 -23.0(4) . . . . ?
Rh P C1 C6 103.7(4) . . . . ?
C13 P C1 C2 49.2(4) . . . . ?
C7 P C1 C2 158.6(4) . . . . ?
Rh P C1 C2 -74.7(4) . . . . ?
C6 C1 C2 C3 0.1(7) . . . . ?
P C1 C2 C3 178.5(4) . . . . ?
C1 C2 C3 C4 -0.5(7) . . . . ?
C2 C3 C4 C5 0.8(8) . . . . ?
C3 C4 C5 C6 -0.7(8) . . . . ?
C4 C5 C6 C1 0.4(8) . . . . ?
C2 C1 C6 C5 -0.1(7) . . . . ?
P C1 C6 C5 -178.5(4) . . . . ?
C13 P C7 C8 13.2(4) . . . . ?
C1 P C7 C8 -98.6(4) . . . . ?
Rh P C7 C8 134.0(3) . . . . ?
C13 P C7 C12 -171.9(3) . . . . ?
C1 P C7 C12 76.3(4) . . . . ?
Rh P C7 C12 -51.1(4) . . . . ?
C12 C7 C8 C9 0.6(6) . . . . ?
P C7 C8 C9 175.5(3) . . . . ?
C7 C8 C9 C10 -1.1(7) . . . . ?
C8 C9 C10 C11 0.6(7) . . . . ?
C9 C10 C11 C12 0.4(7) . . . . ?
C10 C11 C12 C7 -0.9(7) . . . . ?
C8 C7 C12 C11 0.4(6) . . . . ?
P C7 C12 C11 -174.6(3) . . . . ?
C7 P C13 C14 -85.6(4) . . . . ?
C1 P C13 C14 23.7(4) . . . . ?
Rh P C13 C14 150.8(3) . . . . ?
C7 P C13 C18 89.5(4) . . . . ?
C1 P C13 C18 -161.1(3) . . . . ?
Rh P C13 C18 -34.0(4) . . . . ?
C18 C13 C14 C15 0.6(6) . . . . ?
P C13 C14 C15 175.8(4) . . . . ?
C13 C14 C15 C16 1.7(7) . . . . ?
C14 C15 C16 C17 -2.4(7) . . . . ?
C15 C16 C17 C18 1.0(7) . . . . ?
C16 C17 C18 C13 1.3(7) . . . . ?
C16 C17 C18 C19 -177.3(4) . . . . ?
C14 C13 C18 C17 -2.1(6) . . . . ?
P C13 C18 C17 -177.3(3) . . . . ?
C14 C13 C18 C19 176.4(4) . . . . ?
P C13 C18 C19 1.2(6) . . . . ?
C20 N1 C19 C18 170.5(4) . . . . ?
C26 N1 C19 C18 51.8(5) . . . . ?
Rh N1 C19 C18 -74.1(4) . . . . ?
C17 C18 C19 N1 -121.1(4) . . . . ?
C13 C18 C19 N1 60.4(5) . . . . ?
C19 N1 C20 C21 167.4(3) . . . . ?
C26 N1 C20 C21 -73.4(4) . . . . ?
Rh N1 C20 C21 46.0(4) . . . . ?
C25 N2 C21 C22 -1.8(6) . . . . ?
Rh N2 C21 C22 -177.6(3) . . . . ?
C25 N2 C21 C20 -179.6(4) . . . . ?
Rh N2 C21 C20 4.5(5) . . . . ?
N1 C20 C21 N2 -34.5(5) . . . . ?
N1 C20 C21 C22 147.7(4) . . . . ?
N2 C21 C22 C23 0.2(7) . . . . ?
C20 C21 C22 C23 177.9(4) . . . . ?
C21 C22 C23 C24 0.7(7) . . . . ?
C22 C23 C24 C25 -0.1(8) . . . . ?
C21 N2 C25 C24 2.4(7) . . . . ?
Rh N2 C25 C24 177.6(3) . . . . ?
C23 C24 C25 N2 -1.5(7) . . . . ?
C19 N1 C26 C27 -122.3(4) . . . . ?
C20 N1 C26 C27 120.0(4) . . . . ?
Rh N1 C26 C27 4.9(4) . . . . ?
N1 C26 C27 C28 -3.1(6) . . . . ?
N1 C26 C27 C32 -179.2(4) . . . . ?
C32 C27 C28 C29 2.1(7) . . . . ?
C26 C27 C28 C29 -174.0(4) . . . . ?
C32 C27 C28 Rh 175.7(3) . . . . ?
C26 C27 C28 Rh -0.4(5) . . . . ?
C27 C28 C29 C30 -1.2(7) . . . . ?
Rh C28 C29 C30 -173.8(3) . . . . ?
C28 C29 C30 C31 -0.2(7) . . . . ?
C29 C30 C31 C32 0.7(7) . . . . ?
C29 C30 C31 C33 178.3(4) . . . . ?
C30 C31 C32 C27 0.2(7) . . . . ?
C33 C31 C32 C27 -177.4(4) . . . . ?
C28 C27 C32 C31 -1.7(7) . . . . ?
C26 C27 C32 C31 174.5(4) . . . . ?
C32 C31 C33 F1 -116.1(5) . . . . ?
C30 C31 C33 F1 66.3(6) . . . . ?
C32 C31 C33 F3 123.2(5) . . . . ?
C30 C31 C33 F3 -54.4(6) . . . . ?
C32 C31 C33 F2 4.6(6) . . . . ?
C30 C31 C33 F2 -172.9(4) . . . . ?

_refine_diff_density_max         2.977
_refine_diff_density_min         -1.679
_refine_diff_density_rms         0.147


_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: dichloromethane/acetone'
