# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_syy_co_sq
_database_code_depnum_ccdc_archive 'CCDC 2233938'
loop_
_audit_author_name
_audit_author_address
'Qi Liu'
;Changzhou University
China
;
_audit_update_record             
;
2023-01-02 deposited with the CCDC.	2023-05-10 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         
'C24 H26 Co N10 O8, 2(C9 H4 N4 O2), C10 H4 O8 [+ solvent]'
_chemical_formula_sum            'C52 H38 Co N18 O20'
_chemical_formula_weight         1293.93

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.1717(13)
_cell_length_b                   10.5650(13)
_cell_length_c                   18.044(2)
_cell_angle_alpha                74.318(4)
_cell_angle_beta                 86.913(4)
_cell_angle_gamma                73.682(4)
_cell_volume                     1615.0(4)
_cell_formula_units_Z            1
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    5744
_cell_measurement_theta_min      2.31
_cell_measurement_theta_max      23.99

_exptl_crystal_description       block
_exptl_crystal_colour            pink
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.330
_exptl_crystal_F_000             663
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.050
_exptl_crystal_size_mid          0.040
_exptl_crystal_size_min          0.020
_exptl_absorpt_coefficient_mu    0.349
_shelx_estimated_absorpt_T_min   0.983
_shelx_estimated_absorpt_T_max   0.993
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6823
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            25601
_diffrn_reflns_av_unetI/netI     0.0963
_diffrn_reflns_av_R_equivalents  0.0690
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         2.084
_diffrn_reflns_theta_max         27.611
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             7474
_reflns_number_gt                4242
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0947P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         7474
_refine_ls_number_parameters     409
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1295
_refine_ls_R_factor_gt           0.0627
_refine_ls_wR_factor_ref         0.1745
_refine_ls_wR_factor_gt          0.1509
_refine_ls_goodness_of_fit_ref   1.004
_refine_ls_restrained_S_all      1.004
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.5012(4) 0.4941(3) 0.32419(15) 0.0436(8) Uani 1 1 d . . . . .
H1 H 0.6003 0.4387 0.3258 0.052 Uiso 1 1 calc R U . . .
C2 C 0.2758(4) 0.6207(3) 0.28340(17) 0.0518(9) Uani 1 1 d . . . . .
H2 H 0.1903 0.6676 0.2517 0.062 Uiso 1 1 calc R U . . .
C3 C 0.3990(4) 0.4213(3) 0.17123(16) 0.0447(8) Uani 1 1 d . . . . .
C4 C 0.4970(3) 0.6297(3) 0.13759(15) 0.0369(7) Uani 1 1 d . . . . .
C5 C 0.5244(3) 0.6135(3) 0.05849(15) 0.0340(7) Uani 1 1 d . . . . .
C6 C 0.5877(4) 0.7017(3) 0.00589(16) 0.0401(7) Uani 1 1 d . . . . .
H6 H 0.6146 0.7705 0.0202 0.048 Uiso 1 1 calc R U . . .
C7 C 0.6124(4) 0.6891(3) -0.06960(16) 0.0430(8) Uani 1 1 d . . . . .
H7 H 0.6543 0.7504 -0.1051 0.052 Uiso 1 1 calc R U . . .
C8 C 0.5756(3) 0.5882(3) -0.09125(14) 0.0339(7) Uani 1 1 d . . . . .
C9 C 0.5128(3) 0.4942(3) -0.03835(14) 0.0300(6) Uani 1 1 d . . . . .
C10 C 0.6839(4) 0.8196(3) 0.27774(16) 0.0456(8) Uani 1 1 d . . . . .
H10 H 0.7136 0.7358 0.2659 0.055 Uiso 1 1 calc R U . . .
C11 C 0.6506(4) 1.0314(3) 0.2723(2) 0.0555(9) Uani 1 1 d . . . . .
H11 H 0.6525 1.1222 0.2557 0.067 Uiso 1 1 calc R U . . .
C12 C 0.7116(3) 0.9887(3) 0.09967(16) 0.0338(7) Uani 1 1 d . . . . .
C13 C 0.9507(3) 0.9395(3) 0.17808(16) 0.0358(7) Uani 1 1 d . . . . .
C14 C 1.0348(3) 0.9633(3) 0.10510(15) 0.0323(6) Uani 1 1 d . . . . .
C15 C 0.9581(3) 0.9914(3) 0.03444(15) 0.0301(6) Uani 1 1 d . . . . .
C16 C 0.8014(3) 1.0032(3) 0.02942(15) 0.0312(6) Uani 1 1 d . . . . .
C17 C 1.1868(3) 0.9533(3) 0.10809(16) 0.0394(7) Uani 1 1 d . . . . .
H17 H 1.2353 0.9346 0.1553 0.047 Uiso 1 1 calc R U . . .
C18 C 1.2689(3) 0.9709(3) 0.04044(16) 0.0379(7) Uani 1 1 d . . . . .
H18 H 1.3718 0.9651 0.0428 0.045 Uiso 1 1 calc R U . . .
C19 C 0.8396(5) 0.3706(4) 0.4848(2) 0.0567(9) Uani 1 1 d . . . . .
H19 H 0.8347 0.3098 0.5324 0.068 Uiso 1 1 calc R U . . .
C20 C 0.9917(6) 0.4555(6) 0.3805(3) 0.127(2) Uani 1 1 d . . . . .
H20A H 1.0630 0.4042 0.3512 0.191 Uiso 1 1 calc R U . . .
H20B H 1.0278 0.5289 0.3871 0.191 Uiso 1 1 calc R U . . .
H20C H 0.8949 0.4926 0.3538 0.191 Uiso 1 1 calc R U . . .
C21 C 1.1142(6) 0.2758(6) 0.4948(4) 0.137(2) Uani 1 1 d . . . . .
H21A H 1.1716 0.3282 0.5100 0.205 Uiso 1 1 calc R U . . .
H21B H 1.1735 0.2255 0.4612 0.205 Uiso 1 1 calc R U . . .
H21C H 1.0893 0.2131 0.5397 0.205 Uiso 1 1 calc R U . . .
C22 C 0.0755(4) 0.5658(3) 0.93568(19) 0.0500(8) Uani 1 1 d . . . . .
C23 C 0.0579(4) 0.6012(3) 1.0050(2) 0.0559(9) Uani 1 1 d . . . . .
H23 H 0.0971 0.6714 1.0089 0.067 Uiso 1 1 calc R U . . .
C24 C -0.0145(4) 0.5395(3) 1.0695(2) 0.0528(9) Uani 1 1 d . . . . .
C25 C -0.0154(6) 0.5975(4) 1.1384(2) 0.0753(12) Uani 1 1 d . . . . .
C26 C 0.1620(5) 0.6468(5) 0.8752(3) 0.0758(12) Uani 1 1 d . . . . .
Co1 Co 0.5000 0.5000 0.5000 0.03350(19) Uani 1 2 d S . P . .
N1 N 0.4294(3) 0.5345(2) 0.38193(12) 0.038 Uani 1 1 d . . . . .
N2 N 0.2862(3) 0.6171(3) 0.35598(13) 0.0547(8) Uani 1 1 d . . . . .
N3 N 0.4062(3) 0.5470(2) 0.26158(12) 0.0415(6) Uani 1 1 d . . . . .
N4 N 0.4367(3) 0.5319(2) 0.18743(12) 0.0388(6) Uani 1 1 d . . . . .
N5 N 0.5864(4) 0.9798(3) 0.33378(17) 0.0654(9) Uani 1 1 d . . . . .
N6 N 0.6075(4) 0.8432(3) 0.33692(15) 0.0591(8) Uani 1 1 d . . . . .
N7 N 0.7144(3) 0.9352(2) 0.23558(12) 0.0360(6) Uani 1 1 d . . . . .
N8 N 0.7959(3) 0.9516(2) 0.16895(12) 0.0336(6) Uani 1 1 d . . . . .
N9 N 0.9756(4) 0.3670(4) 0.4549(2) 0.0727(9) Uani 1 1 d . . . . .
O1 O 0.3514(4) 0.3429(2) 0.22096(12) 0.0756(8) Uani 1 1 d . . . . .
O2 O 0.5220(3) 0.7193(2) 0.15941(11) 0.0552(6) Uani 1 1 d . . . . .
O3 O 0.5762(2) 1.0051(2) 0.10107(11) 0.0465(5) Uani 1 1 d . . . . .
O4 O 1.0066(2) 0.9102(2) 0.24167(11) 0.0511(6) Uani 1 1 d . . . . .
O5 O 0.7205(3) 0.4480(2) 0.45409(12) 0.0536(6) Uani 1 1 d . . . . .
O6 O 0.5070(3) 0.6968(2) 0.47491(11) 0.0569(6) Uani 1 1 d . . . . .
H6A H 0.5180 0.7424 0.4200 0.085 Uiso 1 1 d R U . . .
H6B H 0.5855 0.7180 0.4538 0.085 Uiso 1 1 d R U . . .
O7 O 0.1833(4) 0.7493(3) 0.8835(2) 0.1099(12) Uani 1 1 d . . . . .
O8 O 0.2183(4) 0.5969(4) 0.8197(2) 0.1087(11) Uani 1 1 d . . . . .
H8 H 0.1672 0.5496 0.8113 0.163 Uiso 1 1 calc R U . . .
O9 O 0.0784(5) 0.6614(3) 1.13901(17) 0.1108(13) Uani 1 1 d . . . . .
O10 O -0.1102(4) 0.5789(4) 1.1911(2) 0.1207(13) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.308(3) . ?
C1 N3 1.356(4) . ?
C1 H1 0.9300 . ?
C2 N2 1.308(4) . ?
C2 N3 1.335(4) . ?
C2 H2 0.9300 . ?
C3 O1 1.201(3) . ?
C3 N4 1.412(4) . ?
C3 C8 1.475(4) 2_665 ?
C4 O2 1.199(3) . ?
C4 N4 1.395(4) . ?
C4 C5 1.483(4) . ?
C5 C6 1.369(4) . ?
C5 C9 1.414(4) 2_665 ?
C6 C7 1.404(4) . ?
C6 H6 0.9300 . ?
C7 C8 1.358(4) . ?
C7 H7 0.9300 . ?
C8 C9 1.407(4) . ?
C8 C3 1.475(4) 2_665 ?
C9 C5 1.414(4) 2_665 ?
C9 C9 1.423(5) 2_665 ?
C10 N6 1.288(4) . ?
C10 N7 1.347(4) . ?
C10 H10 0.9300 . ?
C11 N5 1.287(4) . ?
C11 N7 1.342(4) . ?
C11 H11 0.9300 . ?
C12 O3 1.205(3) . ?
C12 N8 1.408(3) . ?
C12 C16 1.470(4) . ?
C13 O4 1.207(3) . ?
C13 N8 1.404(4) . ?
C13 C14 1.488(4) . ?
C14 C17 1.370(4) . ?
C14 C15 1.409(4) . ?
C15 C16 1.413(4) . ?
C15 C15 1.422(5) 2_775 ?
C16 C18 1.372(4) 2_775 ?
C17 C18 1.396(4) . ?
C17 H17 0.9300 . ?
C18 C16 1.372(4) 2_775 ?
C18 H18 0.9300 . ?
C19 O5 1.219(4) . ?
C19 N9 1.327(5) . ?
C19 H19 0.9300 . ?
C20 N9 1.440(6) . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C21 N9 1.449(6) . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 C23 1.388(4) . ?
C22 C24 1.405(5) 2_567 ?
C22 C26 1.528(6) . ?
C23 C24 1.405(5) . ?
C23 H23 0.9300 . ?
C24 C22 1.405(5) 2_567 ?
C24 C25 1.525(5) . ?
C25 O9 1.236(5) . ?
C25 O10 1.266(6) . ?
C26 O7 1.201(5) . ?
C26 O8 1.275(5) . ?
Co1 O6 2.024(2) . ?
Co1 O6 2.024(2) 2_666 ?
Co1 O5 2.126(2) . ?
Co1 O5 2.126(2) 2_666 ?
Co1 N1 2.165(2) 2_666 ?
Co1 N1 2.165(2) . ?
N1 N2 1.381(4) . ?
N3 N4 1.394(3) . ?
N5 N6 1.387(4) . ?
N7 N8 1.378(3) . ?
O6 H6A 0.9913 . ?
O6 H6B 0.8534 . ?
O8 H8 0.8200 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 N3 108.2(3) . . ?
N1 C1 H1 125.9 . . ?
N3 C1 H1 125.9 . . ?
N2 C2 N3 109.9(3) . . ?
N2 C2 H2 125.0 . . ?
N3 C2 H2 125.0 . . ?
O1 C3 N4 120.2(2) . . ?
O1 C3 C8 124.8(3) . 2_665 ?
N4 C3 C8 115.0(2) . 2_665 ?
O2 C4 N4 120.3(2) . . ?
O2 C4 C5 124.5(3) . . ?
N4 C4 C5 115.2(2) . . ?
C6 C5 C9 120.5(2) . 2_665 ?
C6 C5 C4 119.7(2) . . ?
C9 C5 C4 119.8(2) 2_665 . ?
C5 C6 C7 120.5(3) . . ?
C5 C6 H6 119.8 . . ?
C7 C6 H6 119.8 . . ?
C8 C7 C6 120.5(3) . . ?
C8 C7 H7 119.7 . . ?
C6 C7 H7 119.7 . . ?
C7 C8 C9 120.6(2) . . ?
C7 C8 C3 119.3(2) . 2_665 ?
C9 C8 C3 120.1(2) . 2_665 ?
C8 C9 C5 122.1(2) . 2_665 ?
C8 C9 C9 119.5(3) . 2_665 ?
C5 C9 C9 118.4(3) 2_665 2_665 ?
N6 C10 N7 109.5(3) . . ?
N6 C10 H10 125.2 . . ?
N7 C10 H10 125.2 . . ?
N5 C11 N7 110.3(3) . . ?
N5 C11 H11 124.9 . . ?
N7 C11 H11 124.9 . . ?
O3 C12 N8 120.0(3) . . ?
O3 C12 C16 124.9(3) . . ?
N8 C12 C16 115.1(2) . . ?
O4 C13 N8 120.2(3) . . ?
O4 C13 C14 124.8(3) . . ?
N8 C13 C14 115.0(2) . . ?
C17 C14 C15 121.2(2) . . ?
C17 C14 C13 119.3(2) . . ?
C15 C14 C13 119.4(3) . . ?
C14 C15 C16 122.6(2) . . ?
C14 C15 C15 118.5(3) . 2_775 ?
C16 C15 C15 118.9(3) . 2_775 ?
C18 C16 C15 120.8(2) 2_775 . ?
C18 C16 C12 119.3(3) 2_775 . ?
C15 C16 C12 119.9(2) . . ?
C14 C17 C18 120.2(3) . . ?
C14 C17 H17 119.9 . . ?
C18 C17 H17 119.9 . . ?
C16 C18 C17 120.3(3) 2_775 . ?
C16 C18 H18 119.9 2_775 . ?
C17 C18 H18 119.9 . . ?
O5 C19 N9 124.4(4) . . ?
O5 C19 H19 117.8 . . ?
N9 C19 H19 117.8 . . ?
N9 C20 H20A 109.5 . . ?
N9 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
N9 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
N9 C21 H21A 109.5 . . ?
N9 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
N9 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C23 C22 C24 116.7(3) . 2_567 ?
C23 C22 C26 114.6(3) . . ?
C24 C22 C26 128.7(3) 2_567 . ?
C22 C23 C24 125.1(3) . . ?
C22 C23 H23 117.4 . . ?
C24 C23 H23 117.4 . . ?
C23 C24 C22 118.2(3) . 2_567 ?
C23 C24 C25 114.0(3) . . ?
C22 C24 C25 127.8(4) 2_567 . ?
O9 C25 O10 123.6(4) . . ?
O9 C25 C24 116.9(5) . . ?
O10 C25 C24 119.5(4) . . ?
O7 C26 O8 122.1(5) . . ?
O7 C26 C22 120.0(4) . . ?
O8 C26 C22 117.8(4) . . ?
O6 Co1 O6 180.0 . 2_666 ?
O6 Co1 O5 88.87(9) . . ?
O6 Co1 O5 91.13(9) 2_666 . ?
O6 Co1 O5 91.13(9) . 2_666 ?
O6 Co1 O5 88.87(9) 2_666 2_666 ?
O5 Co1 O5 180.0 . 2_666 ?
O6 Co1 N1 90.98(9) . 2_666 ?
O6 Co1 N1 89.02(9) 2_666 2_666 ?
O5 Co1 N1 97.40(9) . 2_666 ?
O5 Co1 N1 82.60(9) 2_666 2_666 ?
O6 Co1 N1 89.02(9) . . ?
O6 Co1 N1 90.98(9) 2_666 . ?
O5 Co1 N1 82.60(9) . . ?
O5 Co1 N1 97.40(9) 2_666 . ?
N1 Co1 N1 180.00(13) 2_666 . ?
C1 N1 N2 108.2(2) . . ?
C1 N1 Co1 131.8(2) . . ?
N2 N1 Co1 119.93(16) . . ?
C2 N2 N1 106.6(2) . . ?
C2 N3 C1 107.0(2) . . ?
C2 N3 N4 125.4(3) . . ?
C1 N3 N4 127.6(3) . . ?
N3 N4 C4 116.3(2) . . ?
N3 N4 C3 115.9(2) . . ?
C4 N4 C3 127.8(2) . . ?
C11 N5 N6 106.7(3) . . ?
C10 N6 N5 107.6(3) . . ?
C11 N7 C10 105.9(3) . . ?
C11 N7 N8 126.8(2) . . ?
C10 N7 N8 127.2(2) . . ?
N7 N8 C13 116.0(2) . . ?
N7 N8 C12 116.0(2) . . ?
C13 N8 C12 127.8(2) . . ?
C19 N9 C20 120.9(4) . . ?
C19 N9 C21 122.2(4) . . ?
C20 N9 C21 116.8(4) . . ?
C19 O5 Co1 130.3(2) . . ?
Co1 O6 H6A 116.7 . . ?
Co1 O6 H6B 119.4 . . ?
H6A O6 H6B 52.7 . . ?
C26 O8 H8 109.5 . . ?

_refine_diff_density_max         0.433
_refine_diff_density_min         -0.369
_refine_diff_density_rms         0.058



