# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_cg-01-77
_database_code_depnum_ccdc_archive 'CCDC 2218137'
loop_
_audit_author_name
_audit_author_address
'Claudia Giarrusso'
;Monash University 
Australia
;
_audit_update_record             
;
2022-11-07 deposited with the CCDC.	2023-05-11 downloaded from the CCDC.
;
_audit_creation_date             2022-05-25
_audit_creation_method           
;
Olex2 1.3-ac4
(compiled 2019.04.23 svn.r3594 for Rigaku Oxford Diffraction, GUI svn.r5739)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C33 H54 Ag N3 Si2'
_chemical_formula_sum            'C33 H54 Ag N3 Si2'
_chemical_formula_weight         656.84
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C20 H20 Ag1 N1 Si1'
_chemical_oxdiff_usercomment     Dipp
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   12.90827(13)
_cell_length_b                   13.42943(13)
_cell_length_c                   21.6307(2)
_cell_angle_alpha                90
_cell_angle_beta                 104.1928(9)
_cell_angle_gamma                90
_cell_volume                     3635.24(6)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    20318
_cell_measurement_temperature    122.99(11)
_cell_measurement_theta_max      79.7280
_cell_measurement_theta_min      3.6090
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    5.244
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.53534
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.113a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.200
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             1392
_exptl_crystal_size_max          0.271
_exptl_crystal_size_mid          0.104
_exptl_crystal_size_min          0.021
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0681
_diffrn_reflns_av_unetI/netI     0.0401
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.971
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            38136
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.971
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         80.301
_diffrn_reflns_theta_min         3.642
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      122.99(11)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.971
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -70.00  21.00   0.50    0.60    --  -50.61  76.00  82.00  182
  2  ω   -121.00 -31.00   0.50    0.60    --  -50.61 -76.00 -43.00  180
  3  ω    -20.00  70.00   0.50    0.60    --   50.61 -76.00 -43.00  180
  4  ω     32.00 122.00   0.50    0.60    --   50.61  76.00  82.00  180
  5  ω   -109.00 -18.00   0.50    2.40    --  -90.00  76.00  82.00  182
  6  ω   -161.00 -71.00   0.50    2.40    --  -90.00 -76.00 -43.00  180
  7  ω     92.00 178.00   0.50    2.40    --  111.50  76.00  82.00  172
  8  ω     49.00 112.00   0.50    2.40    --  111.50 -76.00 -43.00  126
  9  ω   -120.00 -81.00   0.50    0.60    --  -50.61-125.00-180.00   78
 10  ω   -121.00 -75.00   0.50    0.60    --  -50.61-125.00 120.00   92
 11  ω    -68.00 -37.00   0.50    2.40    --  -90.00  30.00 -60.00   62
 12  ω     41.00  66.00   0.50    2.40    --  111.50 -30.00 -30.00   50
 13  ω     41.00  66.00   0.50    2.40    --  111.50 -45.00-120.00   50
 14  ω     40.00  65.00   0.50    2.40    --  111.50 -30.00 120.00   50
 15  ω     43.00  75.00   0.50    2.40    --  111.50 -45.00-150.00   64
 16  ω     40.00  65.00   0.50    2.40    --  111.50 -30.00 150.00   50
 17  ω     43.00  95.00   0.50    2.40    --  111.50 -94.00 120.00  104
 18  ω     41.00  73.00   0.50    2.40    --  111.50 -45.00 -60.00   64
 19  ω     41.00  66.00   0.50    2.40    --  111.50 -45.00 150.00   50
 20  ω    110.00 177.00   0.50    2.40    --  111.50  61.00   0.00  134
 21  ω     42.00  69.00   0.50    2.40    --  111.50 -45.00 -30.00   54
 22  ω     44.00  76.00   0.50    2.40    --  111.50 -45.00  30.00   64
 23  ω     40.00  66.00   0.50    2.40    --  111.50 -30.00   0.00   52
 24  ω     50.00  76.00   0.50    2.40    --  111.50 -45.00-180.00   52
 25  ω     40.00  65.00   0.50    2.40    --  111.50 -30.00-150.00   50
 26  ω     41.00  67.00   0.50    2.40    --  111.50-125.00  90.00   52
 27  ω     73.00 111.00   0.50    2.40    --  111.50-125.00  90.00   76
 28  ω     70.00 125.00   0.50    2.40    --  111.50 -77.00  90.00  110
 29  ω     63.00 118.00   0.50    2.40    --  111.50   0.00  60.00  110
 30  ω     41.00  68.00   0.50    2.40    --  111.50 -45.00  90.00   54
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0755336000
_diffrn_orient_matrix_UB_12      0.0902637000
_diffrn_orient_matrix_UB_13      0.0072053000
_diffrn_orient_matrix_UB_21      -0.0340456000
_diffrn_orient_matrix_UB_22      0.0321444000
_diffrn_orient_matrix_UB_23      0.0605825000
_diffrn_orient_matrix_UB_31      0.0909360000
_diffrn_orient_matrix_UB_32      -0.0629799000
_diffrn_orient_matrix_UB_33      0.0410685000
_diffrn_oxdiff_digest_frames     
;
0188cb173b55ea7fcdbd980d01366506b602904eb9f
;
_diffrn_oxdiff_digest_hkl        
;
01a9036af772e9099cc7347b4ccc763e6d446e
;
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'PhotonJet (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                6724
_reflns_number_total             7733
_reflns_odcompleteness_completeness 99.43
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     74.33
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.113a (Rigaku OD, 2021)'
_computing_data_collection       'CrysAlisPro 1.171.41.113a (Rigaku OD, 2021)'
_computing_data_reduction        'CrysAlisPro 1.171.41.113a (Rigaku OD, 2021)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_refine_diff_density_max         1.533
_refine_diff_density_min         -1.153
_refine_diff_density_rms         0.100
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.057
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     366
_refine_ls_number_reflns         7733
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0486
_refine_ls_R_factor_gt           0.0424
_refine_ls_restrained_S_all      1.057
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0733P)²+1.7326P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1156
_refine_ls_wR_factor_ref         0.1201
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C10(H10), C13(H13), C25(H25), C22(H22)
2.b Aromatic/amide H refined with riding coordinates:
 C8(H8), C20(H20), C18(H18), C6(H6), C7(H7), C2(H2), C19(H19), C3(H3)
2.c Idealised Me refined as rotating group:
 C28(H28A,H28B,H28C), C32(H32A,H32B,H32C), C33(H33A,H33B,H33C), C29(H29A,H29B,
 H29C), C30(H30A,H30B,H30C), C31(H31A,H31B,H31C), C27(H27A,H27B,H27C), C26(H26A,
 H26B,H26C), C12(H12A,H12B,H12C), C14(H14A,H14B,H14C), C11(H11A,H11B,H11C),
 C15(H15A,H15B,H15C), C23(H23A,H23B,H23C), C24(H24A,H24B,H24C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.01009(2) 0.24969(2) 0.25154(2) 0.02312(9) Uani 1 1 d . . . . .
Si2 Si 0.00687(6) 0.16671(5) 0.11033(3) 0.02580(15) Uani 1 1 d . . . . .
Si1 Si -0.13084(6) 0.34460(5) 0.12610(3) 0.02386(15) Uani 1 1 d . . . . .
N2 N 0.02006(17) 0.30690(17) 0.39130(9) 0.0266(4) Uani 1 1 d . . . . .
N1 N -0.0404(2) 0.25431(14) 0.15245(11) 0.0258(5) Uani 1 1 d . . . . .
C1 C 0.0592(2) 0.24998(16) 0.35047(14) 0.0241(6) Uani 1 1 d . . . . .
C16 C 0.1956(2) 0.11629(18) 0.36659(11) 0.0247(5) Uani 1 1 d . . . . .
C4 C -0.0608(2) 0.38304(19) 0.37383(11) 0.0247(5) Uani 1 1 d . . . . .
N3 N 0.13352(16) 0.19283(16) 0.38758(9) 0.0248(4) Uani 1 1 d . . . . .
C5 C -0.1683(2) 0.35511(19) 0.35792(12) 0.0276(5) Uani 1 1 d . . . . .
C8 C -0.1060(2) 0.5553(2) 0.35982(13) 0.0311(5) Uani 1 1 d . . . . .
H8 H -0.085977 0.623422 0.360084 0.037 Uiso 1 1 calc R . . . .
C20 C 0.2229(2) -0.0557(2) 0.34876(14) 0.0361(6) Uani 1 1 d . . . . .
H20 H 0.200251 -0.123125 0.347120 0.043 Uiso 1 1 calc R . . . .
C9 C -0.0272(2) 0.48220(19) 0.37473(12) 0.0281(5) Uani 1 1 d . . . . .
C18 C 0.3528(2) 0.0648(2) 0.33636(13) 0.0336(6) Uani 1 1 d . . . . .
H18 H 0.418613 0.079731 0.326188 0.040 Uiso 1 1 calc R . . . .
C21 C 0.1588(2) 0.0180(2) 0.36487(12) 0.0304(5) Uani 1 1 d . . . . .
C6 C -0.2436(2) 0.4314(2) 0.34342(13) 0.0321(6) Uani 1 1 d . . . . .
H6 H -0.317456 0.415102 0.332464 0.038 Uiso 1 1 calc R . . . .
C7 C -0.2134(2) 0.5297(2) 0.34461(13) 0.0329(6) Uani 1 1 d . . . . .
H7 H -0.266276 0.580359 0.334965 0.039 Uiso 1 1 calc R . . . .
C28 C 0.1125(2) 0.2169(2) 0.07237(14) 0.0368(6) Uani 1 1 d . . . . .
H28A H 0.086169 0.277590 0.048466 0.055 Uiso 1 1 calc GR . . . .
H28B H 0.129344 0.166963 0.043276 0.055 Uiso 1 1 calc GR . . . .
H28C H 0.177092 0.232398 0.105581 0.055 Uiso 1 1 calc GR . . . .
C32 C -0.2716(2) 0.2944(2) 0.11052(12) 0.0319(6) Uani 1 1 d . . . . .
H32A H -0.279229 0.237550 0.081339 0.048 Uiso 1 1 calc GR . . . .
H32B H -0.322313 0.346648 0.091300 0.048 Uiso 1 1 calc GR . . . .
H32C H -0.286257 0.272942 0.150840 0.048 Uiso 1 1 calc GR . . . .
C2 C 0.0715(2) 0.2848(2) 0.45381(12) 0.0340(6) Uani 1 1 d . . . . .
H2 H 0.058763 0.314614 0.491105 0.041 Uiso 1 1 calc R . . . .
C17 C 0.2920(2) 0.14236(18) 0.35237(11) 0.0254(5) Uani 1 1 d . . . . .
C33 C -0.1261(3) 0.4464(2) 0.18583(13) 0.0360(6) Uani 1 1 d . . . . .
H33A H -0.139184 0.418325 0.225039 0.054 Uiso 1 1 calc GR . . . .
H33B H -0.181010 0.496108 0.168362 0.054 Uiso 1 1 calc GR . . . .
H33C H -0.055500 0.477994 0.195363 0.054 Uiso 1 1 calc GR . . . .
C10 C 0.0901(2) 0.5117(2) 0.39098(13) 0.0351(6) Uani 1 1 d . . . . .
H10 H 0.133538 0.449166 0.398095 0.042 Uiso 1 1 calc R . . . .
C19 C 0.3194(2) -0.0324(2) 0.33502(14) 0.0370(6) Uani 1 1 d . . . . .
H19 H 0.362720 -0.083885 0.324626 0.044 Uiso 1 1 calc R . . . .
C13 C -0.2040(3) 0.24702(19) 0.35692(16) 0.0357(7) Uani 1 1 d . . . . .
H13 H -0.140285 0.203674 0.358952 0.043 Uiso 1 1 calc R . . . .
C29 C 0.0680(3) 0.0595(2) 0.16178(15) 0.0424(7) Uani 1 1 d . . . . .
H29A H 0.122462 0.084349 0.198437 0.064 Uiso 1 1 calc GR . . . .
H29B H 0.101239 0.013820 0.136974 0.064 Uiso 1 1 calc GR . . . .
H29C H 0.012475 0.024200 0.176854 0.064 Uiso 1 1 calc GR . . . .
C30 C -0.1005(3) 0.1128(2) 0.04339(14) 0.0385(7) Uani 1 1 d . . . . .
H30A H -0.153514 0.078199 0.061153 0.058 Uiso 1 1 calc GR . . . .
H30B H -0.068331 0.065545 0.018998 0.058 Uiso 1 1 calc GR . . . .
H30C H -0.135414 0.166526 0.015254 0.058 Uiso 1 1 calc GR . . . .
C31 C -0.1128(2) 0.4067(2) 0.05129(13) 0.0326(6) Uani 1 1 d . . . . .
H31A H -0.042121 0.438003 0.059824 0.049 Uiso 1 1 calc GR . . . .
H31B H -0.168091 0.457619 0.037635 0.049 Uiso 1 1 calc GR . . . .
H31C H -0.118817 0.356839 0.017528 0.049 Uiso 1 1 calc GR . . . .
C25 C 0.3307(3) 0.24900(18) 0.35338(15) 0.0321(6) Uani 1 1 d . . . . .
H25 H 0.286029 0.290701 0.375078 0.038 Uiso 1 1 calc R . . . .
C3 C 0.1428(2) 0.2130(2) 0.45138(12) 0.0342(6) Uani 1 1 d . . . . .
H3 H 0.190382 0.182055 0.486667 0.041 Uiso 1 1 calc R . . . .
C27 C 0.3151(3) 0.2871(3) 0.28549(15) 0.0480(8) Uani 1 1 d . . . . .
H27A H 0.359212 0.247921 0.263471 0.072 Uiso 1 1 calc GR . . . .
H27B H 0.336308 0.357246 0.286409 0.072 Uiso 1 1 calc GR . . . .
H27C H 0.239739 0.280621 0.262838 0.072 Uiso 1 1 calc GR . . . .
C26 C 0.4473(3) 0.2602(2) 0.39009(17) 0.0449(8) Uani 1 1 d . . . . .
H26A H 0.456675 0.232963 0.433146 0.067 Uiso 1 1 calc GR . . . .
H26B H 0.466940 0.330814 0.392842 0.067 Uiso 1 1 calc GR . . . .
H26C H 0.493257 0.223865 0.367831 0.067 Uiso 1 1 calc GR . . . .
C12 C 0.1179(3) 0.5681(4) 0.33586(17) 0.0707(13) Uani 1 1 d . . . . .
H12A H 0.103432 0.525689 0.297840 0.106 Uiso 1 1 calc GR . . . .
H12B H 0.193760 0.586236 0.347521 0.106 Uiso 1 1 calc GR . . . .
H12C H 0.074369 0.628621 0.326860 0.106 Uiso 1 1 calc GR . . . .
C14 C -0.2474(3) 0.2242(3) 0.41483(15) 0.0468(8) Uani 1 1 d . . . . .
H14A H -0.191384 0.236075 0.453832 0.070 Uiso 1 1 calc GR . . . .
H14B H -0.270030 0.154458 0.413414 0.070 Uiso 1 1 calc GR . . . .
H14C H -0.308616 0.267551 0.414504 0.070 Uiso 1 1 calc GR . . . .
C11 C 0.1198(3) 0.5728(3) 0.45224(16) 0.0516(9) Uani 1 1 d . . . . .
H11A H 0.082682 0.637053 0.445395 0.077 Uiso 1 1 calc GR . . . .
H11B H 0.197141 0.584006 0.464149 0.077 Uiso 1 1 calc GR . . . .
H11C H 0.098517 0.536681 0.486525 0.077 Uiso 1 1 calc GR . . . .
C22 C 0.0535(2) -0.0086(2) 0.38044(14) 0.0395(7) Uani 1 1 d . . . . .
H22 H 0.023490 0.053871 0.394221 0.047 Uiso 1 1 calc R . . . .
C15 C -0.2870(4) 0.2229(3) 0.29580(16) 0.0699(14) Uani 1 1 d . . . . .
H15A H -0.353747 0.257842 0.295599 0.105 Uiso 1 1 calc GR . . . .
H15B H -0.300047 0.150936 0.293301 0.105 Uiso 1 1 calc GR . . . .
H15C H -0.260829 0.244309 0.259062 0.105 Uiso 1 1 calc GR . . . .
C23 C 0.0702(3) -0.0821(3) 0.43561(18) 0.0630(11) Uani 1 1 d . . . . .
H23A H 0.095094 -0.145869 0.422546 0.095 Uiso 1 1 calc GR . . . .
H23B H 0.002472 -0.092203 0.447622 0.095 Uiso 1 1 calc GR . . . .
H23C H 0.123626 -0.055683 0.472175 0.095 Uiso 1 1 calc GR . . . .
C24 C -0.0267(3) -0.0470(4) 0.32118(17) 0.0711(13) Uani 1 1 d . . . . .
H24A H -0.037752 0.003723 0.287621 0.107 Uiso 1 1 calc GR . . . .
H24B H -0.094745 -0.061427 0.331726 0.107 Uiso 1 1 calc GR . . . .
H24C H 0.001050 -0.107927 0.306135 0.107 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.083(2) . ?
Ag1 C1 2.078(3) . ?
Si2 N1 1.691(2) . ?
Si2 C28 1.881(3) . ?
Si2 C29 1.872(3) . ?
Si2 C30 1.886(3) . ?
Si1 N1 1.683(2) . ?
Si1 C32 1.889(3) . ?
Si1 C33 1.871(3) . ?
Si1 C31 1.885(3) . ?
N2 C1 1.356(3) . ?
N2 C4 1.444(3) . ?
N2 C2 1.384(3) . ?
C1 N3 1.333(3) . ?
C16 N3 1.443(3) . ?
C16 C21 1.400(4) . ?
C16 C17 1.398(4) . ?
C4 C5 1.396(4) . ?
C4 C9 1.399(4) . ?
N3 C3 1.382(3) . ?
C5 C6 1.394(4) . ?
C5 C13 1.522(3) . ?
C8 C9 1.394(4) . ?
C8 C7 1.387(4) . ?
C20 C21 1.388(4) . ?
C20 C19 1.386(4) . ?
C9 C10 1.520(4) . ?
C18 C17 1.397(4) . ?
C18 C19 1.373(4) . ?
C21 C22 1.520(4) . ?
C6 C7 1.375(4) . ?
C2 C3 1.344(4) . ?
C17 C25 1.515(3) . ?
C10 C12 1.528(5) . ?
C10 C11 1.526(4) . ?
C13 C14 1.523(4) . ?
C13 C15 1.519(5) . ?
C25 C27 1.521(4) . ?
C25 C26 1.527(5) . ?
C22 C23 1.523(4) . ?
C22 C24 1.526(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Ag1 N1 178.13(8) . . ?
N1 Si2 C28 112.45(13) . . ?
N1 Si2 C29 111.73(13) . . ?
N1 Si2 C30 112.73(13) . . ?
C28 Si2 C30 106.11(13) . . ?
C29 Si2 C28 106.86(14) . . ?
C29 Si2 C30 106.52(15) . . ?
N1 Si1 C32 111.11(13) . . ?
N1 Si1 C33 112.94(12) . . ?
N1 Si1 C31 112.85(13) . . ?
C33 Si1 C32 104.55(13) . . ?
C33 Si1 C31 106.22(13) . . ?
C31 Si1 C32 108.70(12) . . ?
C1 N2 C4 126.2(2) . . ?
C1 N2 C2 110.5(2) . . ?
C2 N2 C4 123.4(2) . . ?
Si2 N1 Ag1 118.07(12) . . ?
Si1 N1 Ag1 112.72(12) . . ?
Si1 N1 Si2 129.11(15) . . ?
N2 C1 Ag1 127.12(19) . . ?
N3 C1 Ag1 127.75(19) . . ?
N3 C1 N2 105.1(2) . . ?
C21 C16 N3 118.0(2) . . ?
C17 C16 N3 118.9(2) . . ?
C17 C16 C21 123.0(2) . . ?
C5 C4 N2 119.0(2) . . ?
C5 C4 C9 123.1(2) . . ?
C9 C4 N2 117.9(2) . . ?
C1 N3 C16 126.4(2) . . ?
C1 N3 C3 111.2(2) . . ?
C3 N3 C16 122.3(2) . . ?
C4 C5 C13 122.6(2) . . ?
C6 C5 C4 117.0(2) . . ?
C6 C5 C13 120.4(3) . . ?
C7 C8 C9 120.7(2) . . ?
C19 C20 C21 121.1(3) . . ?
C4 C9 C10 122.6(2) . . ?
C8 C9 C4 117.4(2) . . ?
C8 C9 C10 120.0(2) . . ?
C19 C18 C17 121.5(3) . . ?
C16 C21 C22 122.1(3) . . ?
C20 C21 C16 117.3(2) . . ?
C20 C21 C22 120.5(3) . . ?
C7 C6 C5 121.5(3) . . ?
C6 C7 C8 120.3(3) . . ?
C3 C2 N2 106.5(2) . . ?
C16 C17 C25 122.8(2) . . ?
C18 C17 C16 116.9(2) . . ?
C18 C17 C25 120.3(2) . . ?
C9 C10 C12 111.1(3) . . ?
C9 C10 C11 111.4(2) . . ?
C11 C10 C12 110.7(3) . . ?
C18 C19 C20 120.2(3) . . ?
C5 C13 C14 110.6(2) . . ?
C15 C13 C5 111.3(3) . . ?
C15 C13 C14 110.5(3) . . ?
C17 C25 C27 109.8(2) . . ?
C17 C25 C26 112.3(2) . . ?
C27 C25 C26 110.5(3) . . ?
C2 C3 N3 106.7(2) . . ?
C21 C22 C23 111.4(3) . . ?
C21 C22 C24 110.6(3) . . ?
C23 C22 C24 112.1(3) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 2.646
_oxdiff_exptl_absorpt_empirical_full_min 0.503
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_cg-01-35_auto
_database_code_depnum_ccdc_archive 'CCDC 2218138'
loop_
_audit_author_name
_audit_author_address
'Claudia Giarrusso'
;Monash University
Australia
;
_audit_update_record             
;
2022-11-08 deposited with the CCDC.	2023-05-11 downloaded from the CCDC.
;
_audit_creation_date             2022-05-25
_audit_creation_method           
;
Olex2 1.3-ac4
(compiled 2019.04.23 svn.r3594 for Rigaku Oxford Diffraction, GUI svn.r5739)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C29 H50 Ag N3 Si2'
_chemical_formula_sum            'C29 H50 Ag N3 Si2'
_chemical_formula_weight         604.77
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C29 H50 Ag1 N3 Si2'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   20.2489(8)
_cell_length_b                   12.2700(5)
_cell_length_c                   12.8905(6)
_cell_angle_alpha                90
_cell_angle_beta                 105.751(4)
_cell_angle_gamma                90
_cell_volume                     3082.4(2)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    14198
_cell_measurement_temperature    123.00(10)
_cell_measurement_theta_max      32.6620
_cell_measurement_theta_min      3.4870
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    0.753
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.438
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.113a (Rigaku Oxford Diffraction, 2021)
Numerical absorption correction based on gaussian integration over
a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.303
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             1280
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
-1 0 0 0.0547
1 0 0 0.0547
0 0 -1 0.2599
0 0 1 0.2169
0 1 0 0.0818
0 -1 0 0.0818

_exptl_crystal_size_max          0.526
_exptl_crystal_size_mid          0.164
_exptl_crystal_size_min          0.109
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
-0.9994 -0.0018 -0.0002 0.0098 0.0011 0.0350
0.9994 0.0018 0.0002 -0.0098 -0.0011 -0.0350
0.0014 -0.0028 -1.0002 -0.0177 -0.0495 0.0225
-0.0014 0.0028 1.0002 0.0177 0.0495 -0.0225
-0.0055 1.0003 -0.0007 -0.0507 0.0243 0.0134
0.0055 -1.0003 0.0007 0.0507 -0.0243 -0.0134

_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0678
_diffrn_reflns_av_unetI/netI     0.0383
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            19847
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.275
_diffrn_reflns_theta_min         3.321
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      123.00(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     -6.00  55.00   0.50    2.10    --   25.27  57.00  60.00  122
  2  ω     42.00 108.00   0.50    2.10    --   25.27 178.00-150.00  132
  3  ω     42.00 108.00   0.50    2.10    --   25.27 178.00-120.00  132
  4  ω     42.00 108.00   0.50    2.10    --   25.27 178.00 -90.00  132
  5  ω    -59.00  48.00   0.50    2.10    --   25.27 -38.00  60.00  214
  6  ω      0.00  81.00   0.50    2.10    --   25.27-108.00 -74.00  162
  7  ω     39.00 108.00   0.50    2.10    --   25.27-178.00-180.00  138
  8  ω    -23.00  25.00   0.50    2.10    --  -24.95 -99.00 120.00   96
  9  ω   -117.00 -63.00   0.50    2.10    --  -24.95-178.00  90.00  108
 10  ω    -80.00 -21.00   0.50    2.10    --  -24.95 108.00  23.00  118
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0096697000
_diffrn_orient_matrix_UB_12      -0.0507499000
_diffrn_orient_matrix_UB_13      0.0178538000
_diffrn_orient_matrix_UB_21      -0.0011057000
_diffrn_orient_matrix_UB_22      0.0243635000
_diffrn_orient_matrix_UB_23      0.0493982000
_diffrn_orient_matrix_UB_31      -0.0350570000
_diffrn_orient_matrix_UB_32      0.0132020000
_diffrn_orient_matrix_UB_33      -0.0225673000
_diffrn_oxdiff_digest_frames     
;
01451d7f672f1176663307a4f840003c7901354cb38
;
_diffrn_oxdiff_digest_hkl        
;
01f76458f723928ad1e1bc00bb52ae8c92d66f
;
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'PhotonJet (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3500
_reflns_number_total             3815
_reflns_odcompleteness_completeness 99.73
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     28.22
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.113a (Rigaku OD, 2021)'
_computing_data_collection       'CrysAlisPro 1.171.41.113a (Rigaku OD, 2021)'
_computing_data_reduction        'CrysAlisPro 1.171.41.113a (Rigaku OD, 2021)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         1.426
_refine_diff_density_min         -1.362
_refine_diff_density_rms         0.109
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     163
_refine_ls_number_reflns         3815
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0425
_refine_ls_R_factor_gt           0.0396
_refine_ls_restrained_S_all      1.068
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0804P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1087
_refine_ls_wR_factor_ref         0.1107
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C5(H5), C7(H7), C10(H10)
2.b Secondary CH2 refined with riding coordinates:
 C4(H4A,H4B), C6(H6A,H6B), C8(H8A,H8B), C9(H9A,H9B), C11(H11A,H11B), C12(H12A,
 H12B)
2.c Aromatic/amide H refined with riding coordinates:
 C2(H2)
2.d Idealised Me refined as rotating group:
 C13(H13A,H13B,H13C), C14(H14A,H14B,H14C), C15(H15A,H15B,H15C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.500000 0.41420(2) 0.750000 0.02259(10) Uani 1 2 d S T P . .
Si1 Si 0.49551(3) 0.18903(4) 0.62862(5) 0.02484(15) Uani 1 1 d . . . . .
N1 N 0.500000 0.24534(19) 0.750000 0.0230(5) Uani 1 2 d S T P . .
N2 N 0.55522(8) 0.65138(13) 0.76570(14) 0.0229(3) Uani 1 1 d . . . . .
C1 C 0.500000 0.5835(2) 0.750000 0.0214(6) Uani 1 2 d S T P . .
C2 C 0.53412(11) 0.75965(16) 0.75931(17) 0.0271(4) Uani 1 1 d . . . . .
H2 H 0.562858 0.821990 0.766783 0.033 Uiso 1 1 calc R . . . .
C3 C 0.62731(10) 0.61297(18) 0.78678(17) 0.0236(4) Uani 1 1 d . . . . .
C4 C 0.64575(10) 0.54244(17) 0.88942(17) 0.0251(4) Uani 1 1 d . . . . .
H4A H 0.614118 0.479470 0.880253 0.030 Uiso 1 1 calc R . . . .
H4B H 0.640773 0.585932 0.951548 0.030 Uiso 1 1 calc R . . . .
C5 C 0.72026(11) 0.50164(18) 0.91111(19) 0.0301(5) Uani 1 1 d . . . . .
H5 H 0.732104 0.455305 0.977418 0.036 Uiso 1 1 calc R . . . .
C6 C 0.76907(13) 0.6000(2) 0.9270(2) 0.0355(5) Uani 1 1 d . . . . .
H6A H 0.764920 0.643549 0.989596 0.043 Uiso 1 1 calc R . . . .
H6B H 0.817084 0.574359 0.941595 0.043 Uiso 1 1 calc R . . . .
C7 C 0.75079(11) 0.6702(2) 0.8255(2) 0.0367(5) Uani 1 1 d . . . . .
H7 H 0.782425 0.734331 0.836275 0.044 Uiso 1 1 calc R . . . .
C8 C 0.67624(11) 0.71102(17) 0.8034(2) 0.0309(5) Uani 1 1 d . . . . .
H8A H 0.671222 0.755203 0.865123 0.037 Uiso 1 1 calc R . . . .
H8B H 0.664670 0.757599 0.738295 0.037 Uiso 1 1 calc R . . . .
C9 C 0.63577(10) 0.54598(18) 0.69033(17) 0.0267(4) Uani 1 1 d . . . . .
H9A H 0.603995 0.483035 0.678011 0.032 Uiso 1 1 calc R . . . .
H9B H 0.624164 0.591695 0.624584 0.032 Uiso 1 1 calc R . . . .
C10 C 0.70994(11) 0.5053(2) 0.7125(2) 0.0329(5) Uani 1 1 d . . . . .
H10 H 0.714933 0.461410 0.649636 0.040 Uiso 1 1 calc R . . . .
C11 C 0.75852(13) 0.6038(2) 0.7289(2) 0.0401(6) Uani 1 1 d . . . . .
H11A H 0.806524 0.578582 0.742076 0.048 Uiso 1 1 calc R . . . .
H11B H 0.747190 0.649819 0.663379 0.048 Uiso 1 1 calc R . . . .
C12 C 0.72725(12) 0.4340(2) 0.8138(2) 0.0330(5) Uani 1 1 d . . . . .
H12A H 0.774733 0.406139 0.827691 0.040 Uiso 1 1 calc R . . . .
H12B H 0.695714 0.370813 0.802989 0.040 Uiso 1 1 calc R . . . .
C13 C 0.54491(14) 0.2711(2) 0.5516(2) 0.0430(6) Uani 1 1 d . . . . .
H13A H 0.523982 0.343389 0.535696 0.065 Uiso 1 1 calc GR . . . .
H13B H 0.543906 0.233795 0.484000 0.065 Uiso 1 1 calc GR . . . .
H13C H 0.592557 0.278985 0.595037 0.065 Uiso 1 1 calc GR . . . .
C14 C 0.53330(13) 0.0468(2) 0.6416(2) 0.0377(5) Uani 1 1 d . . . . .
H14A H 0.573973 0.044113 0.703583 0.057 Uiso 1 1 calc GR . . . .
H14B H 0.546308 0.028374 0.575860 0.057 Uiso 1 1 calc GR . . . .
H14C H 0.499157 -0.005569 0.652124 0.057 Uiso 1 1 calc GR . . . .
C15 C 0.40469(13) 0.1807(2) 0.5404(2) 0.0397(6) Uani 1 1 d . . . . .
H15A H 0.379418 0.125566 0.569156 0.060 Uiso 1 1 calc GR . . . .
H15B H 0.405127 0.160549 0.467011 0.060 Uiso 1 1 calc GR . . . .
H15C H 0.382302 0.251699 0.539097 0.060 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.072(2) . ?
Ag1 C1 2.077(2) . ?
Si1 N1 1.6901(11) . ?
Si1 C13 1.881(2) . ?
Si1 C14 1.894(2) . ?
Si1 C15 1.884(3) . ?
N2 C1 1.365(2) . ?
N2 C2 1.391(3) . ?
N2 C3 1.487(2) . ?
C2 C2 1.337(4) 2_656 ?
C3 C4 1.540(3) . ?
C3 C8 1.536(3) . ?
C3 C9 1.538(3) . ?
C4 C5 1.541(3) . ?
C5 C6 1.538(3) . ?
C5 C12 1.542(3) . ?
C6 C7 1.526(4) . ?
C7 C8 1.542(3) . ?
C7 C11 1.531(4) . ?
C9 C10 1.534(3) . ?
C10 C11 1.537(3) . ?
C10 C12 1.531(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 C1 180.0 . . ?
N1 Si1 C13 111.52(10) . . ?
N1 Si1 C14 112.07(11) . . ?
N1 Si1 C15 112.30(9) . . ?
C13 Si1 C14 106.26(13) . . ?
C13 Si1 C15 106.38(13) . . ?
C15 Si1 C14 107.94(11) . . ?
Si1 N1 Ag1 114.13(8) . . ?
Si1 N1 Ag1 114.13(8) 2_656 . ?
Si1 N1 Si1 131.75(15) . 2_656 ?
C1 N2 C2 110.38(17) . . ?
C1 N2 C3 123.89(16) . . ?
C2 N2 C3 125.73(17) . . ?
N2 C1 Ag1 127.63(11) . . ?
N2 C1 Ag1 127.63(11) 2_656 . ?
N2 C1 N2 104.7(2) . 2_656 ?
C2 C2 N2 107.25(11) 2_656 . ?
N2 C3 C4 109.40(16) . . ?
N2 C3 C8 109.95(17) . . ?
N2 C3 C9 109.92(16) . . ?
C8 C3 C4 108.86(18) . . ?
C8 C3 C9 108.82(17) . . ?
C9 C3 C4 109.87(18) . . ?
C3 C4 C5 109.60(17) . . ?
C4 C5 C12 109.18(19) . . ?
C6 C5 C4 109.36(18) . . ?
C6 C5 C12 109.5(2) . . ?
C7 C6 C5 109.3(2) . . ?
C6 C7 C8 109.8(2) . . ?
C6 C7 C11 110.0(2) . . ?
C11 C7 C8 109.5(2) . . ?
C3 C8 C7 109.48(18) . . ?
C10 C9 C3 109.99(17) . . ?
C9 C10 C11 109.1(2) . . ?
C12 C10 C9 109.29(18) . . ?
C12 C10 C11 110.0(2) . . ?
C7 C11 C10 109.2(2) . . ?
C10 C12 C5 109.66(18) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 2.154
_oxdiff_exptl_absorpt_empirical_full_min 0.512
