# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_cu_230727c_a
_database_code_depnum_ccdc_archive 'CCDC 2312365'
loop_
_audit_author_name
_audit_author_address
'Zi-Jian Yao'
;Shanghai Institute of Technology
China
;
_audit_update_record             
;
2023-12-06 deposited with the CCDC.	2023-12-28 downloaded from the CCDC.
;
_audit_creation_date             2023-07-30
_audit_creation_method           
; 
Olex2 1.2-beta 
(compiled 2015.09.30 svn.r3233 for OlexSys, GUI svn.r5103) 
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C29 H29 Cl N2 O2 Ru'
_chemical_formula_sum            'C29 H29 Cl N2 O2 Ru'
_chemical_formula_weight         574.06
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru 0.0552 3.2960 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   26.2188(18)
_cell_length_b                   12.3812(8)
_cell_length_c                   16.2184(11)
_cell_angle_alpha                90
_cell_angle_beta                 99.153(2)
_cell_angle_gamma                90
_cell_volume                     5197.8(6)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    9299
_cell_measurement_temperature    203(2)
_cell_measurement_theta_max      72.23
_cell_measurement_theta_min      3.41
_shelx_estimated_absorpt_T_max   0.643
_shelx_estimated_absorpt_T_min   0.264
_exptl_absorpt_coefficient_mu    6.052
_exptl_absorpt_correction_T_max  0.6225
_exptl_absorpt_correction_T_min  0.3697
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
; 
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. 
wR2(int) was 0.1496 before and 0.0758 after correction. 
The Ratio of minimum to maximum transmission is 0.5939. 
The λ/2 correction factor is Not present. 
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.467
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             2352
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.08
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0465
_diffrn_reflns_av_unetI/netI     0.0282
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       32
_diffrn_reflns_limit_h_min       -32
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            37396
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         72.218
_diffrn_reflns_theta_min         3.415
_diffrn_ambient_temperature      203.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4896
_reflns_number_total             5095
_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         1.361
_refine_diff_density_min         -1.249
_refine_diff_density_rms         0.113
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     320
_refine_ls_number_reflns         5095
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0361
_refine_ls_R_factor_gt           0.0350
_refine_ls_restrained_S_all      1.042
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0750P)²+7.5580P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1022
_refine_ls_wR_factor_ref         0.1035
_refine_special_details          ?
_olex2_refinement_description    
; 
1. Fixed Uiso 
 At 1.2 times of: 
  All C(H) groups 
 At 1.5 times of: 
  All C(H,H,H) groups 
2.a Ternary CH refined with riding coordinates: 
 C21(H21), C22(H22), C24(H24), C25(H25), C26(H26) 
2.b Aromatic/amide H refined with riding coordinates: 
 C2(H2), C3(H3), C5(H5), C6(H6), C8(H8), C11(H11), C12(H12), C13(H13), 
 C14(H14), C16(H16), C17(H17), C18(H18) 
2.c Idealised Me refined as rotating group: 
 C19(H19A,H19B,H19C), C27(H27A,H27B,H27C), C28(H28A,H28B,H28C), C29(H29A,H29B, 
 H29C) 
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.56161(2) 0.65804(2) 0.57667(2) 0.01754(10) Uani 1 1 d . . . . .
Cl1 Cl 0.53256(2) 0.73467(5) 0.44082(4) 0.02716(15) Uani 1 1 d . . . . .
O1 O 0.60133(6) 0.54822(13) 0.51565(11) 0.0219(4) Uani 1 1 d . . . . .
O2 O 0.76646(8) 0.27013(16) 0.37066(17) 0.0420(5) Uani 1 1 d . . . . .
N1 N 0.66877(8) 0.66969(16) 0.53983(16) 0.0243(5) Uani 1 1 d . . . . .
N2 N 0.63290(7) 0.73336(16) 0.57321(14) 0.0206(4) Uani 1 1 d . . . . .
C1 C 0.68101(9) 0.49991(19) 0.47521(16) 0.0217(5) Uani 1 1 d . . . . .
C2 C 0.66594(10) 0.3915(2) 0.46682(19) 0.0289(6) Uani 1 1 d . . . . .
H2 H 0.634962 0.369114 0.485182 0.035 Uiso 1 1 calc R . . . .
C3 C 0.69522(11) 0.3171(2) 0.4324(2) 0.0332(6) Uani 1 1 d . . . . .
H3 H 0.684409 0.243842 0.427026 0.040 Uiso 1 1 calc R . . . .
C4 C 0.74056(11) 0.3489(2) 0.4057(2) 0.0287(6) Uani 1 1 d . . . . .
C5 C 0.75675(10) 0.4557(2) 0.41496(19) 0.0304(6) Uani 1 1 d . . . . .
H5 H 0.788140 0.477628 0.397706 0.036 Uiso 1 1 calc R . . . .
C6 C 0.72684(10) 0.5300(2) 0.44950(18) 0.0276(5) Uani 1 1 d . . . . .
H6 H 0.737960 0.602942 0.455689 0.033 Uiso 1 1 calc R . . . .
C7 C 0.64817(9) 0.57771(19) 0.51198(16) 0.0208(5) Uani 1 1 d . . . . .
C8 C 0.65123(10) 0.8238(2) 0.60320(19) 0.0266(6) Uani 1 1 d . . . . .
H8 H 0.687171 0.836417 0.605565 0.032 Uiso 1 1 calc R . . . .
C9 C 0.62005(9) 0.90920(19) 0.63422(18) 0.0249(5) Uani 1 1 d . . . . .
C10 C 0.63460(10) 0.95173(19) 0.71668(18) 0.0256(5) Uani 1 1 d . . . . .
C11 C 0.67874(11) 0.9157(2) 0.7720(2) 0.0328(6) Uani 1 1 d . . . . .
H11 H 0.699443 0.859293 0.755258 0.039 Uiso 1 1 calc R . . . .
C12 C 0.69171(14) 0.9612(3) 0.8491(2) 0.0446(8) Uani 1 1 d . . . . .
H12 H 0.721919 0.937527 0.884792 0.053 Uiso 1 1 calc R . . . .
C13 C 0.66104(16) 1.0426(3) 0.8764(2) 0.0508(9) Uani 1 1 d . . . . .
H13 H 0.670454 1.073153 0.930426 0.061 Uiso 1 1 calc R . . . .
C14 C 0.61768(13) 1.0778(3) 0.8255(2) 0.0423(7) Uani 1 1 d . . . . .
H14 H 0.596749 1.131920 0.844839 0.051 Uiso 1 1 calc R . . . .
C15 C 0.60362(11) 1.0346(2) 0.74428(19) 0.0305(6) Uani 1 1 d . . . . .
C16 C 0.56017(11) 1.0742(2) 0.6887(2) 0.0355(7) Uani 1 1 d . . . . .
H16 H 0.539182 1.129107 0.706732 0.043 Uiso 1 1 calc R . . . .
C17 C 0.54837(11) 1.0338(2) 0.6097(2) 0.0362(7) Uani 1 1 d . . . . .
H17 H 0.519744 1.062268 0.572766 0.043 Uiso 1 1 calc R . . . .
C18 C 0.57798(11) 0.9508(2) 0.58223(19) 0.0302(6) Uani 1 1 d . . . . .
H18 H 0.568934 0.922970 0.527261 0.036 Uiso 1 1 calc R . . . .
C19 C 0.81302(15) 0.3000(3) 0.3417(3) 0.0654(13) Uani 1 1 d . . . . .
H19A H 0.805938 0.358964 0.301228 0.098 Uiso 1 1 calc GR . . . .
H19B H 0.826659 0.237691 0.315019 0.098 Uiso 1 1 calc GR . . . .
H19C H 0.838491 0.323914 0.389105 0.098 Uiso 1 1 calc GR . . . .
C20 C 0.56599(10) 0.5507(2) 0.68404(16) 0.0244(5) Uani 1 1 d . . . . .
C21 C 0.57306(11) 0.65933(19) 0.71071(18) 0.0251(6) Uani 1 1 d . . . . .
H21 H 0.607386 0.681952 0.741921 0.030 Uiso 1 1 calc R . . . .
C22 C 0.53573(10) 0.7398(2) 0.68277(17) 0.0252(5) Uani 1 1 d . . . . .
H22 H 0.545281 0.817340 0.693399 0.030 Uiso 1 1 calc R . . . .
C23 C 0.49149(9) 0.7156(2) 0.62449(17) 0.0260(5) Uani 1 1 d . . . . .
C24 C 0.48421(9) 0.6067(2) 0.59714(17) 0.0265(5) Uani 1 1 d . . . . .
H24 H 0.457470 0.590806 0.547456 0.032 Uiso 1 1 calc R . . . .
C25 C 0.51999(10) 0.5262(2) 0.62654(18) 0.0259(5) Uani 1 1 d . . . . .
H25 H 0.517617 0.454964 0.597143 0.031 Uiso 1 1 calc R . . . .
C26 C 0.60531(11) 0.4616(2) 0.70784(19) 0.0322(6) Uani 1 1 d . . . . .
H26 H 0.604725 0.413795 0.657990 0.039 Uiso 1 1 calc R . . . .
C27 C 0.66019(12) 0.5028(3) 0.7323(2) 0.0414(7) Uani 1 1 d . . . . .
H27A H 0.669417 0.548025 0.687351 0.062 Uiso 1 1 calc GR . . . .
H27B H 0.683982 0.441350 0.741736 0.062 Uiso 1 1 calc GR . . . .
H27C H 0.662583 0.545505 0.783645 0.062 Uiso 1 1 calc GR . . . .
C28 C 0.58817(15) 0.3936(3) 0.7774(3) 0.0527(9) Uani 1 1 d . . . . .
H28A H 0.612459 0.333820 0.791668 0.079 Uiso 1 1 calc GR . . . .
H28B H 0.553523 0.364674 0.758240 0.079 Uiso 1 1 calc GR . . . .
H28C H 0.587556 0.438865 0.826810 0.079 Uiso 1 1 calc GR . . . .
C29 C 0.45349(11) 0.8013(3) 0.5908(2) 0.0378(7) Uani 1 1 d . . . . .
H29A H 0.421733 0.792430 0.614862 0.057 Uiso 1 1 calc GR . . . .
H29B H 0.445507 0.794952 0.529909 0.057 Uiso 1 1 calc GR . . . .
H29C H 0.468364 0.872646 0.605700 0.057 Uiso 1 1 calc GR . . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 Cl1 2.4084(6) . ?
Ru1 O1 2.0592(17) . ?
Ru1 N2 2.0975(19) . ?
Ru1 C20 2.179(3) . ?
Ru1 C21 2.147(3) . ?
Ru1 C22 2.195(2) . ?
Ru1 C23 2.223(2) . ?
Ru1 C24 2.202(2) . ?
Ru1 C25 2.189(2) . ?
O1 C7 1.292(3) . ?
O2 C4 1.363(3) . ?
O2 C19 1.424(4) . ?
N1 N2 1.400(3) . ?
N1 C7 1.310(3) . ?
N2 C8 1.283(3) . ?
C1 C2 1.399(3) . ?
C1 C6 1.384(3) . ?
C1 C7 1.479(3) . ?
C2 H2 0.9500 . ?
C2 C3 1.373(4) . ?
C3 H3 0.9500 . ?
C3 C4 1.386(4) . ?
C4 C5 1.390(4) . ?
C5 H5 0.9500 . ?
C5 C6 1.383(4) . ?
C6 H6 0.9500 . ?
C8 H8 0.9500 . ?
C8 C9 1.473(4) . ?
C9 C10 1.431(4) . ?
C9 C18 1.377(4) . ?
C10 C11 1.419(4) . ?
C10 C15 1.424(4) . ?
C11 H11 0.9500 . ?
C11 C12 1.364(5) . ?
C12 H12 0.9500 . ?
C12 C13 1.404(5) . ?
C13 H13 0.9500 . ?
C13 C14 1.366(5) . ?
C14 H14 0.9500 . ?
C14 C15 1.415(4) . ?
C15 C16 1.423(4) . ?
C16 H16 0.9500 . ?
C16 C17 1.365(5) . ?
C17 H17 0.9500 . ?
C17 C18 1.402(4) . ?
C18 H18 0.9500 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 C21 1.416(3) . ?
C20 C25 1.435(4) . ?
C20 C26 1.518(4) . ?
C21 H21 1.0000 . ?
C21 C22 1.420(4) . ?
C22 H22 1.0000 . ?
C22 C23 1.407(4) . ?
C23 C24 1.422(4) . ?
C23 C29 1.498(4) . ?
C24 H24 1.0000 . ?
C24 C25 1.399(4) . ?
C25 H25 1.0000 . ?
C26 H26 1.0000 . ?
C26 C27 1.519(4) . ?
C26 C28 1.531(4) . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Ru1 Cl1 86.04(5) . . ?
O1 Ru1 N2 76.10(7) . . ?
O1 Ru1 C20 90.86(8) . . ?
O1 Ru1 C21 119.45(9) . . ?
O1 Ru1 C22 157.57(9) . . ?
O1 Ru1 C23 152.70(9) . . ?
O1 Ru1 C24 115.51(9) . . ?
O1 Ru1 C25 90.30(9) . . ?
N2 Ru1 Cl1 87.36(6) . . ?
N2 Ru1 C20 111.02(9) . . ?
N2 Ru1 C21 92.42(9) . . ?
N2 Ru1 C22 101.76(9) . . ?
N2 Ru1 C23 131.06(9) . . ?
N2 Ru1 C24 168.25(9) . . ?
N2 Ru1 C25 147.17(9) . . ?
C20 Ru1 Cl1 160.07(7) . . ?
C20 Ru1 C22 68.80(10) . . ?
C20 Ru1 C23 81.83(10) . . ?
C20 Ru1 C24 68.66(10) . . ?
C20 Ru1 C25 38.35(10) . . ?
C21 Ru1 Cl1 153.68(7) . . ?
C21 Ru1 C20 38.20(9) . . ?
C21 Ru1 C22 38.15(10) . . ?
C21 Ru1 C23 68.56(10) . . ?
C21 Ru1 C24 80.39(11) . . ?
C21 Ru1 C25 68.21(10) . . ?
C22 Ru1 Cl1 116.31(7) . . ?
C22 Ru1 C23 37.14(10) . . ?
C22 Ru1 C24 66.89(10) . . ?
C23 Ru1 Cl1 91.96(7) . . ?
C24 Ru1 Cl1 94.97(8) . . ?
C24 Ru1 C23 37.49(11) . . ?
C25 Ru1 Cl1 121.88(8) . . ?
C25 Ru1 C22 79.61(10) . . ?
C25 Ru1 C23 67.74(10) . . ?
C25 Ru1 C24 37.17(10) . . ?
C7 O1 Ru1 113.12(15) . . ?
C4 O2 C19 117.5(2) . . ?
C7 N1 N2 110.93(19) . . ?
N1 N2 Ru1 114.59(14) . . ?
C8 N2 Ru1 131.25(18) . . ?
C8 N2 N1 113.8(2) . . ?
C2 C1 C7 119.4(2) . . ?
C6 C1 C2 118.3(2) . . ?
C6 C1 C7 122.4(2) . . ?
C1 C2 H2 119.5 . . ?
C3 C2 C1 121.1(2) . . ?
C3 C2 H2 119.5 . . ?
C2 C3 H3 120.0 . . ?
C2 C3 C4 119.9(2) . . ?
C4 C3 H3 120.0 . . ?
O2 C4 C3 115.8(2) . . ?
O2 C4 C5 124.2(3) . . ?
C3 C4 C5 119.9(2) . . ?
C4 C5 H5 120.2 . . ?
C6 C5 C4 119.5(2) . . ?
C6 C5 H5 120.2 . . ?
C1 C6 H6 119.4 . . ?
C5 C6 C1 121.3(2) . . ?
C5 C6 H6 119.4 . . ?
O1 C7 N1 125.0(2) . . ?
O1 C7 C1 116.9(2) . . ?
N1 C7 C1 118.1(2) . . ?
N2 C8 H8 117.9 . . ?
N2 C8 C9 124.1(2) . . ?
C9 C8 H8 117.9 . . ?
C10 C9 C8 120.2(2) . . ?
C18 C9 C8 119.6(3) . . ?
C18 C9 C10 120.2(2) . . ?
C11 C10 C9 123.0(2) . . ?
C11 C10 C15 118.4(3) . . ?
C15 C10 C9 118.6(2) . . ?
C10 C11 H11 119.7 . . ?
C12 C11 C10 120.6(3) . . ?
C12 C11 H11 119.7 . . ?
C11 C12 H12 119.5 . . ?
C11 C12 C13 120.9(3) . . ?
C13 C12 H12 119.5 . . ?
C12 C13 H13 119.9 . . ?
C14 C13 C12 120.1(3) . . ?
C14 C13 H13 119.9 . . ?
C13 C14 H14 119.7 . . ?
C13 C14 C15 120.7(3) . . ?
C15 C14 H14 119.7 . . ?
C14 C15 C10 119.2(3) . . ?
C14 C15 C16 121.6(3) . . ?
C16 C15 C10 119.2(3) . . ?
C15 C16 H16 119.7 . . ?
C17 C16 C15 120.6(3) . . ?
C17 C16 H16 119.7 . . ?
C16 C17 H17 119.6 . . ?
C16 C17 C18 120.8(3) . . ?
C18 C17 H17 119.6 . . ?
C9 C18 C17 120.7(3) . . ?
C9 C18 H18 119.7 . . ?
C17 C18 H18 119.7 . . ?
O2 C19 H19A 109.5 . . ?
O2 C19 H19B 109.5 . . ?
O2 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C21 C20 Ru1 69.67(15) . . ?
C21 C20 C25 117.1(2) . . ?
C21 C20 C26 124.2(2) . . ?
C25 C20 Ru1 71.19(15) . . ?
C25 C20 C26 118.6(2) . . ?
C26 C20 Ru1 126.44(18) . . ?
Ru1 C21 H21 119.0 . . ?
C20 C21 Ru1 72.13(16) . . ?
C20 C21 H21 119.0 . . ?
C20 C21 C22 121.3(3) . . ?
C22 C21 Ru1 72.77(16) . . ?
C22 C21 H21 119.0 . . ?
Ru1 C22 H22 118.5 . . ?
C21 C22 Ru1 69.08(15) . . ?
C21 C22 H22 118.5 . . ?
C23 C22 Ru1 72.52(15) . . ?
C23 C22 C21 121.1(2) . . ?
C23 C22 H22 118.5 . . ?
C22 C23 Ru1 70.35(14) . . ?
C22 C23 C24 117.9(2) . . ?
C22 C23 C29 121.5(3) . . ?
C24 C23 Ru1 70.44(13) . . ?
C24 C23 C29 120.6(3) . . ?
C29 C23 Ru1 129.70(19) . . ?
Ru1 C24 H24 118.7 . . ?
C23 C24 Ru1 72.08(13) . . ?
C23 C24 H24 118.7 . . ?
C25 C24 Ru1 70.91(14) . . ?
C25 C24 C23 121.3(2) . . ?
C25 C24 H24 118.7 . . ?
Ru1 C25 H25 118.6 . . ?
C20 C25 Ru1 70.46(14) . . ?
C20 C25 H25 118.6 . . ?
C24 C25 Ru1 71.92(15) . . ?
C24 C25 C20 121.3(2) . . ?
C24 C25 H25 118.6 . . ?
C20 C26 H26 107.6 . . ?
C20 C26 C27 113.5(2) . . ?
C20 C26 C28 108.7(2) . . ?
C27 C26 H26 107.6 . . ?
C27 C26 C28 111.7(3) . . ?
C28 C26 H26 107.6 . . ?
C26 C27 H27A 109.5 . . ?
C26 C27 H27B 109.5 . . ?
C26 C27 H27C 109.5 . . ?
H27A C27 H27B 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C26 C28 H28A 109.5 . . ?
C26 C28 H28B 109.5 . . ?
C26 C28 H28C 109.5 . . ?
H28A C28 H28B 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C23 C29 H29A 109.5 . . ?
C23 C29 H29B 109.5 . . ?
C23 C29 H29C 109.5 . . ?
H29A C29 H29B 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ru1 O1 C7 N1 -3.2(3) . . . . ?
Ru1 O1 C7 C1 175.27(17) . . . . ?
Ru1 N2 C8 C9 -13.6(4) . . . . ?
Ru1 C20 C21 C22 55.9(2) . . . . ?
Ru1 C20 C25 C24 -53.0(2) . . . . ?
Ru1 C20 C26 C27 65.5(3) . . . . ?
Ru1 C20 C26 C28 -169.6(2) . . . . ?
Ru1 C21 C22 C23 52.6(2) . . . . ?
Ru1 C22 C23 C24 53.8(2) . . . . ?
Ru1 C22 C23 C29 -125.2(2) . . . . ?
Ru1 C23 C24 C25 53.2(2) . . . . ?
Ru1 C24 C25 C20 52.4(2) . . . . ?
O2 C4 C5 C6 178.4(3) . . . . ?
N1 N2 C8 C9 173.8(3) . . . . ?
N2 N1 C7 O1 -1.0(4) . . . . ?
N2 N1 C7 C1 -179.4(2) . . . . ?
N2 C8 C9 C10 126.0(3) . . . . ?
N2 C8 C9 C18 -56.5(4) . . . . ?
C1 C2 C3 C4 0.2(5) . . . . ?
C2 C1 C6 C5 1.1(4) . . . . ?
C2 C1 C7 O1 -16.6(4) . . . . ?
C2 C1 C7 N1 162.0(3) . . . . ?
C2 C3 C4 O2 -178.5(3) . . . . ?
C2 C3 C4 C5 1.1(5) . . . . ?
C3 C4 C5 C6 -1.2(5) . . . . ?
C4 C5 C6 C1 0.1(5) . . . . ?
C6 C1 C2 C3 -1.3(4) . . . . ?
C6 C1 C7 O1 164.3(2) . . . . ?
C6 C1 C7 N1 -17.2(4) . . . . ?
C7 N1 N2 Ru1 4.6(3) . . . . ?
C7 N1 N2 C8 178.6(2) . . . . ?
C7 C1 C2 C3 179.5(3) . . . . ?
C7 C1 C6 C5 -179.7(3) . . . . ?
C8 C9 C10 C11 0.2(4) . . . . ?
C8 C9 C10 C15 179.7(2) . . . . ?
C8 C9 C18 C17 -178.6(3) . . . . ?
C9 C10 C11 C12 178.0(3) . . . . ?
C9 C10 C15 C14 -179.7(3) . . . . ?
C9 C10 C15 C16 -1.5(4) . . . . ?
C10 C9 C18 C17 -1.1(4) . . . . ?
C10 C11 C12 C13 1.8(5) . . . . ?
C10 C15 C16 C17 -0.4(4) . . . . ?
C11 C10 C15 C14 -0.2(4) . . . . ?
C11 C10 C15 C16 178.0(3) . . . . ?
C11 C12 C13 C14 -0.4(6) . . . . ?
C12 C13 C14 C15 -1.2(6) . . . . ?
C13 C14 C15 C10 1.5(5) . . . . ?
C13 C14 C15 C16 -176.7(3) . . . . ?
C14 C15 C16 C17 177.8(3) . . . . ?
C15 C10 C11 C12 -1.4(4) . . . . ?
C15 C16 C17 C18 1.6(5) . . . . ?
C16 C17 C18 C9 -0.9(4) . . . . ?
C18 C9 C10 C11 -177.3(3) . . . . ?
C18 C9 C10 C15 2.2(4) . . . . ?
C19 O2 C4 C3 179.5(3) . . . . ?
C19 O2 C4 C5 -0.1(5) . . . . ?
C20 C21 C22 Ru1 -55.6(2) . . . . ?
C20 C21 C22 C23 -3.0(4) . . . . ?
C21 C20 C25 Ru1 54.1(2) . . . . ?
C21 C20 C25 C24 1.1(4) . . . . ?
C21 C20 C26 C27 -23.4(4) . . . . ?
C21 C20 C26 C28 101.5(3) . . . . ?
C21 C22 C23 Ru1 -51.1(2) . . . . ?
C21 C22 C23 C24 2.7(4) . . . . ?
C21 C22 C23 C29 -176.3(3) . . . . ?
C22 C23 C24 Ru1 -53.7(2) . . . . ?
C22 C23 C24 C25 -0.5(4) . . . . ?
C23 C24 C25 Ru1 -53.8(2) . . . . ?
C23 C24 C25 C20 -1.4(4) . . . . ?
C25 C20 C21 Ru1 -54.9(2) . . . . ?
C25 C20 C21 C22 1.1(4) . . . . ?
C25 C20 C26 C27 152.4(3) . . . . ?
C25 C20 C26 C28 -82.7(3) . . . . ?
C26 C20 C21 Ru1 120.9(3) . . . . ?
C26 C20 C21 C22 176.9(3) . . . . ?
C26 C20 C25 Ru1 -121.9(2) . . . . ?
C26 C20 C25 C24 -175.0(2) . . . . ?
C29 C23 C24 Ru1 125.3(2) . . . . ?
C29 C23 C24 C25 178.5(3) . . . . ?

_shelx_SHELXL_version_number     2019/2
_olex2_submission_special_instructions 'No special instructions were received'
