# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_1
_database_code_depnum_ccdc_archive 'CCDC 2232226'
loop_
_audit_author_name
_audit_author_address
'Miriding Mutailipu'
;Chinese academic of science
China
;
_audit_update_record             
;
2022-12-22 deposited with the CCDC.	2023-02-22 downloaded from the CCDC.
;
_audit_creation_date             2021-03-04
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_shelx_SHELXL_version_number     2016/6
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'B6 O12 Sr Zn2'
_chemical_formula_sum            'B6 O12 Sr Zn2'
_chemical_formula_weight         475.22
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sr Sr -1.5307 3.2498 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   6.5206(4)
_cell_length_b                   6.5408(4)
_cell_length_c                   11.4026(7)
_cell_angle_alpha                79.290(2)
_cell_angle_beta                 83.151(2)
_cell_angle_gamma                61.048(2)
_cell_volume                     417.89(5)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    2811
_cell_measurement_temperature    273.15
_cell_measurement_theta_max      27.45
_cell_measurement_theta_min      3.57
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    12.132
_exptl_absorpt_correction_T_max  0.7455
_exptl_absorpt_correction_T_min  0.5608
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0829 before and 0.0552 after correction.
The Ratio of minimum to maximum transmission is 0.7522.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    3.777
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             448
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0456
_diffrn_reflns_av_unetI/netI     0.0542
_diffrn_reflns_Laue_measured_fraction_full 0.986
_diffrn_reflns_Laue_measured_fraction_max 0.988
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            5598
_diffrn_reflns_point_group_measured_fraction_full 0.986
_diffrn_reflns_point_group_measured_fraction_max 0.988
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.464
_diffrn_reflns_theta_min         1.819
_diffrn_ambient_temperature      273.15
_diffrn_detector                 'CCD area detector'
_diffrn_detector_area_resol_mean 5.6
_diffrn_detector_type            'Bruker SMART CCD 6000 area detector'
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'sealed X-ray tube'
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_target            Mo
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                1608
_reflns_number_total             1907
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.296
_refine_diff_density_min         -0.960
_refine_diff_density_rms         0.216
_refine_ls_extinction_coef       0.0067(14)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2016/6 (Sheldrick 2016)'
_refine_ls_goodness_of_fit_ref   1.104
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     191
_refine_ls_number_reflns         1907
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0439
_refine_ls_R_factor_gt           0.0359
_refine_ls_restrained_S_all      1.104
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0253P)²+1.3512P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0778
_refine_ls_wR_factor_ref         0.0828
_refine_special_details          ?
_olex2_refinement_description    
;
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sr1 Sr -0.32406(9) 0.71002(8) 0.90833(4) 0.00966(16) Uani 1 1 d . . . . .
Zn1 Zn 1.01463(11) -0.22123(11) 0.42436(5) 0.01067(18) Uani 1 1 d . . . . .
Zn2 Zn 0.49621(11) -0.28498(11) 0.60257(5) 0.01109(18) Uani 1 1 d . . . . .
B1 B 1.2487(11) 0.4408(10) 0.6293(6) 0.0119(12) Uani 1 1 d . . . . .
B2 B 0.7265(11) -0.0174(11) 0.6261(6) 0.0131(12) Uani 1 1 d . . . . .
B3 B 0.1594(11) 0.8472(10) 0.8778(5) 0.0078(11) Uani 1 1 d . . . . .
B4 B 1.0852(11) 0.2597(10) 0.8142(5) 0.0099(12) Uani 1 1 d . . . . .
B5 B 0.3325(11) 0.4371(10) 0.8357(5) 0.0068(11) Uani 1 1 d . . . . .
B6 B 0.7692(10) 0.1478(10) 0.8176(5) 0.0085(12) Uani 1 1 d . . . . .
O1 O 0.5374(6) 0.2117(6) 0.8653(3) 0.0083(7) Uani 1 1 d . . . . .
O2 O 0.2375(7) 1.0089(6) 0.8538(3) 0.0125(8) Uani 1 1 d . . . . .
O3 O 1.3329(7) 0.5307(6) 0.7000(3) 0.0094(7) Uani 1 1 d . . . . .
O4 O 1.1252(6) 0.4125(6) 0.8706(3) 0.0087(7) Uani 1 1 d . . . . .
O5 O 1.2621(7) 0.4908(6) 0.5077(3) 0.0117(8) Uani 1 1 d . . . . .
O6 O 0.3307(7) 0.6152(6) 0.8986(3) 0.0099(8) Uani 1 1 d . . . . .
O7 O 0.8423(7) 0.3189(6) 0.8217(3) 0.0102(8) Uani 1 1 d . . . . .
O8 O -0.0741(7) 0.9128(6) 0.8797(3) 0.0117(8) Uani 1 1 d . . . . .
O9 O 0.7521(7) 0.0230(6) 0.5019(3) 0.0114(8) Uani 1 1 d . . . . .
O10 O 0.6539(7) -0.1700(6) 0.6837(3) 0.0131(8) Uani 1 1 d . . . . .
O11 O 1.1498(7) 0.3021(6) 0.6791(3) 0.0119(8) Uani 1 1 d . . . . .
O12 O 0.7896(7) 0.1122(6) 0.6849(3) 0.0117(8) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sr1 B3 3.083(6) 1_455 ?
Sr1 B5 2.902(6) 2_567 ?
Sr1 O1 2.794(3) 2_567 ?
Sr1 O1 2.909(3) 1_465 ?
Sr1 O2 2.635(4) 1_455 ?
Sr1 O4 2.775(4) 2_667 ?
Sr1 O4 2.654(4) 1_455 ?
Sr1 O6 2.627(4) 1_455 ?
Sr1 O6 2.774(4) 2_567 ?
Sr1 O7 2.587(4) 1_455 ?
Sr1 O8 2.516(4) . ?
Sr1 O10 2.535(4) 1_465 ?
Zn1 O5 1.953(4) 1_545 ?
Zn1 O9 1.945(4) . ?
Zn1 O11 1.976(4) 2_756 ?
Zn1 O12 1.965(4) 2_756 ?
Zn2 O3 2.070(4) 1_445 ?
Zn2 O5 1.995(4) 2_756 ?
Zn2 O9 1.998(4) 2_656 ?
Zn2 O10 1.927(4) . ?
B1 O3 1.375(8) . ?
B1 O5 1.366(7) . ?
B1 O11 1.359(7) . ?
B2 O9 1.396(7) . ?
B2 O10 1.338(7) . ?
B2 O12 1.398(8) . ?
B3 O2 1.354(7) . ?
B3 O6 1.377(7) . ?
B3 O8 1.366(7) . ?
B4 O2 1.462(7) 1_645 ?
B4 O4 1.418(7) . ?
B4 O7 1.433(7) . ?
B4 O11 1.558(7) . ?
B5 O1 1.445(7) . ?
B5 O3 1.555(6) 1_455 ?
B5 O4 1.439(7) 1_455 ?
B5 O6 1.472(7) . ?
B6 O1 1.425(7) . ?
B6 O7 1.423(7) . ?
B6 O8 1.468(7) 1_645 ?
B6 O12 1.553(7) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
B5 Sr1 B3 94.93(16) 2_567 1_455 ?
B5 Sr1 O1 108.30(13) 2_567 1_465 ?
O1 Sr1 B3 87.73(13) 1_465 1_455 ?
O1 Sr1 B3 75.02(13) 2_567 1_455 ?
O1 Sr1 B5 29.32(13) 2_567 2_567 ?
O1 Sr1 O1 85.99(10) 2_567 1_465 ?
O2 Sr1 B3 25.90(13) 1_455 1_455 ?
O2 Sr1 B5 105.77(15) 1_455 2_567 ?
O2 Sr1 O1 78.64(11) 1_455 2_567 ?
O2 Sr1 O1 62.13(11) 1_455 1_465 ?
O2 Sr1 O4 127.50(11) 1_455 2_667 ?
O2 Sr1 O4 157.23(12) 1_455 1_455 ?
O2 Sr1 O6 107.52(11) 1_455 2_567 ?
O4 Sr1 B3 147.62(13) 1_455 1_455 ?
O4 Sr1 B3 123.22(13) 2_667 1_455 ?
O4 Sr1 B5 96.05(14) 1_455 2_567 ?
O4 Sr1 B5 29.26(14) 2_667 2_567 ?
O4 Sr1 O1 124.00(11) 1_455 2_567 ?
O4 Sr1 O1 117.19(11) 1_455 1_465 ?
O4 Sr1 O1 49.94(10) 2_667 2_567 ?
O4 Sr1 O1 99.73(10) 2_667 1_465 ?
O4 Sr1 O4 75.19(11) 1_455 2_667 ?
O4 Sr1 O6 88.16(11) 1_455 2_567 ?
O6 Sr1 B3 26.38(13) 1_455 1_455 ?
O6 Sr1 B3 86.35(13) 2_567 1_455 ?
O6 Sr1 B5 87.27(14) 1_455 2_567 ?
O6 Sr1 B5 29.96(13) 2_567 2_567 ?
O6 Sr1 O1 78.96(11) 1_455 2_567 ?
O6 Sr1 O1 50.93(10) 2_567 2_567 ?
O6 Sr1 O1 114.09(11) 1_455 1_465 ?
O6 Sr1 O1 136.53(10) 2_567 1_465 ?
O6 Sr1 O2 52.06(11) 1_455 1_455 ?
O6 Sr1 O4 115.91(11) 1_455 2_667 ?
O6 Sr1 O4 50.66(11) 2_567 2_667 ?
O6 Sr1 O4 124.32(11) 1_455 1_455 ?
O6 Sr1 O6 68.22(13) 1_455 2_567 ?
O7 Sr1 B3 94.39(14) 1_455 1_455 ?
O7 Sr1 B5 103.44(14) 1_455 2_567 ?
O7 Sr1 O1 125.53(11) 1_455 2_567 ?
O7 Sr1 O1 147.89(11) 1_455 1_465 ?
O7 Sr1 O2 113.60(13) 1_455 1_455 ?
O7 Sr1 O4 53.41(12) 1_455 1_455 ?
O7 Sr1 O4 105.66(11) 1_455 2_667 ?
O7 Sr1 O6 75.55(11) 1_455 2_567 ?
O7 Sr1 O6 71.71(12) 1_455 1_455 ?
O8 Sr1 B3 137.49(13) . 1_455 ?
O8 Sr1 B5 104.00(15) . 2_567 ?
O8 Sr1 O1 50.35(11) . 1_465 ?
O8 Sr1 O1 104.49(11) . 2_567 ?
O8 Sr1 O2 111.59(12) . 1_455 ?
O8 Sr1 O4 77.27(12) . 2_667 ?
O8 Sr1 O4 68.08(11) . 1_455 ?
O8 Sr1 O6 162.84(12) . 1_455 ?
O8 Sr1 O6 127.16(12) . 2_567 ?
O8 Sr1 O7 116.92(12) . 1_455 ?
O8 Sr1 O10 80.98(13) . 1_465 ?
O10 Sr1 B3 80.48(14) 1_465 1_455 ?
O10 Sr1 B5 174.90(15) 1_465 2_567 ?
O10 Sr1 O1 148.82(11) 1_465 2_567 ?
O10 Sr1 O1 73.93(11) 1_465 1_465 ?
O10 Sr1 O2 70.98(12) 1_465 1_455 ?
O10 Sr1 O4 86.78(12) 1_465 1_455 ?
O10 Sr1 O4 155.71(12) 1_465 2_667 ?
O10 Sr1 O6 146.43(12) 1_465 2_567 ?
O10 Sr1 O6 87.63(12) 1_465 1_455 ?
O10 Sr1 O7 74.85(12) 1_465 1_455 ?
O5 Zn1 O11 110.00(16) 1_545 2_756 ?
O5 Zn1 O12 99.11(16) 1_545 2_756 ?
O9 Zn1 O5 124.91(15) . 1_545 ?
O9 Zn1 O11 101.30(16) . 2_756 ?
O9 Zn1 O12 115.01(15) . 2_756 ?
O12 Zn1 O11 105.34(16) 2_756 2_756 ?
O3 Zn2 Sr1 83.28(11) 1_445 1_645 ?
O5 Zn2 Sr1 118.95(12) 2_756 1_645 ?
O5 Zn2 O3 108.44(15) 2_756 1_445 ?
O5 Zn2 O9 105.73(15) 2_756 2_656 ?
O9 Zn2 Sr1 129.55(11) 2_656 1_645 ?
O9 Zn2 O3 104.64(15) 2_656 1_445 ?
O10 Zn2 Sr1 36.87(11) . 1_645 ?
O10 Zn2 O3 120.03(15) . 1_445 ?
O10 Zn2 O5 105.68(17) . 2_756 ?
O10 Zn2 O9 111.51(16) . 2_656 ?
O5 B1 O3 120.4(5) . . ?
O11 B1 O3 120.7(5) . . ?
O11 B1 O5 119.0(6) . . ?
O9 B2 Sr1 160.4(4) . 1_645 ?
O9 B2 O12 113.6(5) . . ?
O10 B2 Sr1 38.6(3) . 1_645 ?
O10 B2 O9 123.3(6) . . ?
O10 B2 O12 123.0(5) . . ?
O12 B2 Sr1 84.8(3) . 1_645 ?
O2 B3 Sr1 58.2(3) . 1_655 ?
O2 B3 O6 115.5(5) . . ?
O2 B3 O8 121.5(5) . . ?
O6 B3 Sr1 58.0(3) . 1_655 ?
O8 B3 Sr1 172.4(4) . 1_655 ?
O8 B3 O6 123.0(5) . . ?
O2 B4 Sr1 140.9(4) 1_645 1_655 ?
O2 B4 O11 105.3(4) 1_645 . ?
O4 B4 Sr1 57.3(2) . 1_655 ?
O4 B4 O2 113.8(5) . 1_645 ?
O4 B4 O7 111.5(4) . . ?
O4 B4 O11 106.7(4) . . ?
O7 B4 Sr1 54.7(2) . 1_655 ?
O7 B4 O2 112.3(4) . 1_645 ?
O7 B4 O11 106.6(4) . . ?
O11 B4 Sr1 113.7(3) . 1_655 ?
O1 B5 Sr1 71.2(3) . 2_567 ?
O1 B5 O3 111.2(4) . 1_455 ?
O1 B5 O6 110.3(5) . . ?
O3 B5 Sr1 176.6(3) 1_455 2_567 ?
O4 B5 Sr1 70.5(3) 1_455 2_567 ?
O4 B5 O1 109.2(4) 1_455 . ?
O4 B5 O3 110.4(4) 1_455 1_455 ?
O4 B5 O6 109.3(4) 1_455 . ?
O6 B5 Sr1 70.2(2) . 2_567 ?
O6 B5 O3 106.5(4) . 1_455 ?
O1 B6 Sr1 66.3(3) . 1_645 ?
O1 B6 O8 107.6(4) . 1_645 ?
O1 B6 O12 110.7(5) . . ?
O7 B6 Sr1 158.2(4) . 1_645 ?
O7 B6 O1 113.5(4) . . ?
O7 B6 O8 113.1(5) . 1_645 ?
O7 B6 O12 107.1(4) . . ?
O8 B6 Sr1 50.7(2) 1_645 1_645 ?
O8 B6 O12 104.3(4) 1_645 . ?
O12 B6 Sr1 92.4(3) . 1_645 ?
Sr1 O1 Sr1 94.01(10) 2_567 1_645 ?
B5 O1 Sr1 79.5(3) . 2_567 ?
B5 O1 Sr1 139.9(3) . 1_645 ?
B6 O1 Sr1 133.9(3) . 2_567 ?
B6 O1 Sr1 87.1(3) . 1_645 ?
B6 O1 B5 125.6(4) . . ?
B3 O2 Sr1 95.9(3) . 1_655 ?
B3 O2 B4 123.2(4) . 1_465 ?
B4 O2 Sr1 140.9(3) 1_465 1_655 ?
B1 O3 Zn2 113.0(3) . 1_665 ?
B1 O3 B5 114.9(4) . 1_655 ?
B5 O3 Zn2 130.9(3) 1_655 1_665 ?
Sr1 O4 Sr1 104.81(11) 1_655 2_667 ?
B4 O4 Sr1 95.9(3) . 1_655 ?
B4 O4 Sr1 124.6(3) . 2_667 ?
B4 O4 B5 118.3(4) . 1_655 ?
B5 O4 Sr1 80.3(3) 1_655 2_667 ?
B5 O4 Sr1 134.9(3) 1_655 1_655 ?
Zn1 O5 Zn2 113.18(17) 1_565 2_756 ?
B1 O5 Zn1 119.9(3) . 1_565 ?
B1 O5 Zn2 126.8(3) . 2_756 ?
Sr1 O6 Sr1 111.78(13) 1_655 2_567 ?
B3 O6 Sr1 95.6(3) . 1_655 ?
B3 O6 Sr1 124.4(3) . 2_567 ?
B3 O6 B5 120.5(4) . . ?
B5 O6 Sr1 127.2(3) . 1_655 ?
B5 O6 Sr1 79.8(3) . 2_567 ?
B4 O7 Sr1 98.4(3) . 1_655 ?
B6 O7 Sr1 136.6(3) . 1_655 ?
B6 O7 B4 121.6(4) . . ?
B3 O8 Sr1 137.1(3) . . ?
B3 O8 B6 117.7(4) . 1_465 ?
B6 O8 Sr1 102.4(3) 1_465 . ?
Zn1 O9 Zn2 117.32(18) . 2_656 ?
B2 O9 Zn1 118.0(3) . . ?
B2 O9 Zn2 123.5(3) . 2_656 ?
Zn2 O10 Sr1 115.99(16) . 1_645 ?
B2 O10 Sr1 122.1(4) . 1_645 ?
B2 O10 Zn2 121.6(4) . . ?
B1 O11 Zn1 118.9(4) . 2_756 ?
B1 O11 B4 125.6(5) . . ?
B4 O11 Zn1 112.8(3) . 2_756 ?
B2 O12 Zn1 109.0(3) . 2_756 ?
B2 O12 B6 133.0(4) . . ?
B6 O12 Zn1 117.2(3) . 2_756 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Sr1 B2 O9 Zn1 -52.7(14) 1_645 . . . ?
Sr1 B2 O9 Zn2 114.9(11) 1_645 . . 2_656 ?
Sr1 B2 O10 Zn2 173.3(5) 1_645 . . . ?
Sr1 B2 O12 Zn1 154.39(19) 1_645 . . 2_756 ?
Sr1 B2 O12 B6 -14.3(5) 1_645 . . . ?
Sr1 B3 O2 B4 -178.8(5) 1_655 . . 1_465 ?
Sr1 B3 O6 Sr1 121.3(3) 1_655 . . 2_567 ?
Sr1 B3 O6 B5 -139.8(4) 1_655 . . . ?
Sr1 B4 O4 Sr1 112.6(3) 1_655 . . 2_667 ?
Sr1 B4 O4 B5 -149.5(4) 1_655 . . 1_655 ?
Sr1 B4 O7 B6 -162.5(5) 1_655 . . . ?
Sr1 B4 O11 Zn1 -93.9(3) 1_655 . . 2_756 ?
Sr1 B4 O11 B1 67.4(6) 1_655 . . . ?
Sr1 B5 O1 Sr1 83.7(4) 2_567 . . 1_645 ?
Sr1 B5 O1 B6 -137.3(5) 2_567 . . . ?
Sr1 B5 O6 Sr1 109.7(3) 2_567 . . 1_655 ?
Sr1 B5 O6 B3 -124.1(4) 2_567 . . . ?
Sr1 B6 O1 Sr1 92.8(3) 1_645 . . 2_567 ?
Sr1 B6 O1 B5 -155.0(5) 1_645 . . . ?
Sr1 B6 O7 Sr1 -78.9(11) 1_645 . . 1_655 ?
Sr1 B6 O7 B4 75.4(11) 1_645 . . . ?
Sr1 B6 O12 Zn1 -152.5(2) 1_645 . . 2_756 ?
Sr1 B6 O12 B2 15.5(6) 1_645 . . . ?
O1 B5 O6 Sr1 49.6(5) . . . 1_655 ?
O1 B5 O6 Sr1 -60.1(3) . . . 2_567 ?
O1 B5 O6 B3 175.7(4) . . . . ?
O1 B6 O7 Sr1 5.7(7) . . . 1_655 ?
O1 B6 O7 B4 160.1(4) . . . . ?
O1 B6 O12 Zn1 142.0(3) . . . 2_756 ?
O1 B6 O12 B2 -50.0(7) . . . . ?
O2 B3 O6 Sr1 130.9(4) . . . 2_567 ?
O2 B3 O6 Sr1 9.6(5) . . . 1_655 ?
O2 B3 O6 B5 -130.2(5) . . . . ?
O2 B3 O8 Sr1 176.9(3) . . . . ?
O2 B3 O8 B6 20.0(7) . . . 1_465 ?
O2 B4 O4 Sr1 -136.5(4) 1_645 . . 1_655 ?
O2 B4 O4 Sr1 -23.9(6) 1_645 . . 2_667 ?
O2 B4 O4 B5 74.1(6) 1_645 . . 1_655 ?
O2 B4 O7 Sr1 137.6(4) 1_645 . . 1_655 ?
O2 B4 O7 B6 -25.0(7) 1_645 . . . ?
O2 B4 O11 Zn1 83.7(4) 1_645 . . 2_756 ?
O2 B4 O11 B1 -115.0(5) 1_645 . . . ?
O3 B1 O5 Zn1 -86.1(6) . . . 1_565 ?
O3 B1 O5 Zn2 98.8(5) . . . 2_756 ?
O3 B1 O11 Zn1 170.0(4) . . . 2_756 ?
O3 B1 O11 B4 9.7(8) . . . . ?
O3 B5 O1 Sr1 -98.9(5) 1_455 . . 1_645 ?
O3 B5 O1 Sr1 177.5(4) 1_455 . . 2_567 ?
O3 B5 O1 B6 40.2(7) 1_455 . . . ?
O3 B5 O6 Sr1 -71.2(5) 1_455 . . 1_655 ?
O3 B5 O6 Sr1 179.1(4) 1_455 . . 2_567 ?
O3 B5 O6 B3 55.0(6) 1_455 . . . ?
O4 B4 O7 Sr1 8.4(4) . . . 1_655 ?
O4 B4 O7 B6 -154.1(4) . . . . ?
O4 B4 O11 Zn1 -155.0(3) . . . 2_756 ?
O4 B4 O11 B1 6.3(7) . . . . ?
O4 B5 O1 Sr1 -60.5(3) 1_455 . . 2_567 ?
O4 B5 O1 Sr1 23.1(7) 1_455 . . 1_645 ?
O4 B5 O1 B6 162.2(5) 1_455 . . . ?
O4 B5 O6 Sr1 169.6(3) 1_455 . . 1_655 ?
O4 B5 O6 Sr1 59.9(3) 1_455 . . 2_567 ?
O4 B5 O6 B3 -64.2(6) 1_455 . . . ?
O5 B1 O3 Zn2 -4.6(6) . . . 1_665 ?
O5 B1 O3 B5 -173.3(5) . . . 1_655 ?
O5 B1 O11 Zn1 -9.7(7) . . . 2_756 ?
O5 B1 O11 B4 -169.9(5) . . . . ?
O6 B3 O2 Sr1 -9.5(5) . . . 1_655 ?
O6 B3 O2 B4 171.7(5) . . . 1_465 ?
O6 B3 O8 Sr1 -2.4(8) . . . . ?
O6 B3 O8 B6 -159.3(5) . . . 1_465 ?
O6 B5 O1 Sr1 59.6(3) . . . 2_567 ?
O6 B5 O1 Sr1 143.2(3) . . . 1_645 ?
O6 B5 O1 B6 -77.7(6) . . . . ?
O7 B4 O4 Sr1 -8.2(4) . . . 1_655 ?
O7 B4 O4 Sr1 104.4(4) . . . 2_667 ?
O7 B4 O4 B5 -157.7(4) . . . 1_655 ?
O7 B4 O11 Zn1 -35.7(5) . . . 2_756 ?
O7 B4 O11 B1 125.5(5) . . . . ?
O7 B6 O1 Sr1 -63.4(6) . . . 2_567 ?
O7 B6 O1 Sr1 -156.1(4) . . . 1_645 ?
O7 B6 O1 B5 48.8(7) . . . . ?
O7 B6 O12 Zn1 17.7(5) . . . 2_756 ?
O7 B6 O12 B2 -174.3(5) . . . . ?
O8 B3 O2 Sr1 171.1(5) . . . 1_655 ?
O8 B3 O2 B4 -7.7(8) . . . 1_465 ?
O8 B3 O6 Sr1 -171.1(5) . . . 1_655 ?
O8 B3 O6 Sr1 -49.8(7) . . . 2_567 ?
O8 B3 O6 B5 49.1(7) . . . . ?
O8 B6 O1 Sr1 -30.1(4) 1_645 . . 1_645 ?
O8 B6 O1 Sr1 62.7(6) 1_645 . . 2_567 ?
O8 B6 O1 B5 174.9(4) 1_645 . . . ?
O8 B6 O7 Sr1 -117.3(4) 1_645 . . 1_655 ?
O8 B6 O7 B4 37.1(6) 1_645 . . . ?
O8 B6 O12 Zn1 -102.5(4) 1_645 . . 2_756 ?
O8 B6 O12 B2 65.5(7) 1_645 . . . ?
O9 B2 O10 Sr1 169.3(4) . . . 1_645 ?
O9 B2 O10 Zn2 -17.3(8) . . . . ?
O9 B2 O12 Zn1 -18.5(6) . . . 2_756 ?
O9 B2 O12 B6 172.8(5) . . . . ?
O10 B2 O9 Zn1 -72.8(7) . . . . ?
O10 B2 O9 Zn2 94.8(6) . . . 2_656 ?
O10 B2 O12 Zn1 160.0(5) . . . 2_756 ?
O10 B2 O12 B6 -8.7(9) . . . . ?
O11 B1 O3 Zn2 175.7(4) . . . 1_665 ?
O11 B1 O3 B5 7.0(7) . . . 1_655 ?
O11 B1 O5 Zn1 93.5(5) . . . 1_565 ?
O11 B1 O5 Zn2 -81.6(6) . . . 2_756 ?
O11 B4 O4 Sr1 -139.6(3) . . . 2_667 ?
O11 B4 O4 Sr1 107.8(3) . . . 1_655 ?
O11 B4 O4 B5 -41.7(6) . . . 1_655 ?
O11 B4 O7 Sr1 -107.6(3) . . . 1_655 ?
O11 B4 O7 B6 89.9(5) . . . . ?
O12 B2 O9 Zn1 105.6(5) . . . . ?
O12 B2 O9 Zn2 -86.7(6) . . . 2_656 ?
O12 B2 O10 Sr1 -9.0(7) . . . 1_645 ?
O12 B2 O10 Zn2 164.3(4) . . . . ?
O12 B6 O1 Sr1 83.3(3) . . . 1_645 ?
O12 B6 O1 Sr1 176.1(2) . . . 2_567 ?
O12 B6 O1 B5 -71.7(6) . . . . ?
O12 B6 O7 Sr1 128.3(4) . . . 1_655 ?
O12 B6 O7 B4 -77.3(6) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
