# Electronic Supplementary Material (ESI) for Nanoscale.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_complexc1
_database_code_depnum_ccdc_archive 'CCDC 2244267'
loop_
_audit_author_name
_audit_author_address
'Anna jenczak'
;University
Poland
;

_audit_update_record             
;
2023-02-23 deposited with the CCDC.	2023-05-12 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT242_complexc1           
;
PROBLEM: Low    'MainMol' Ueq as Compared to Neighbors of       N009 Check
RESPONSE: The atom is located in a position where either thermal motion or multiple positions are possible. The enlarged displacement parameters are indicative of the probable thermal motion or disorder which results in this alert.
;
_vrf_PLAT242_complexc1_2         
;
PROBLEM: Low    'MainMol' Ueq as Compared to Neighbors of         C9 Check
RESPONSE: The atom is located in a position where either thermal motion or multiple positions are possible. The enlarged displacement parameters are indicative of the probable thermal motion or disorder which results in this alert.
;
_vrf_PLAT430_complexc1           
;
PROBLEM: Short Inter D...A Contact  O2       ..O2       .       2.74 Ang.
RESPONSE: Alert is the result of intermolecular bonding in beta-diketone units.
;
_vrf_PLAT910_complexc1           
;
PROBLEM: Missing # of FCF Reflection(s) Below Theta(Min).         14 Note
RESPONSE: Probably missing due to the beam stop (this is likely due to using Mo radiation and the geometry of our goniometer).
;
# publcif _publ_body_element loop end
_audit_creation_date             2023-02-23
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_shelx_SHELXL_version_number     2016/6
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C48 H60 Ag2 N4 O8, 2(N O3)'
_chemical_formula_sum            'C48 H60 Ag2 N6 O14'
_chemical_formula_weight         1160.76
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   17.9156(11)
_cell_length_b                   8.6942(4)
_cell_length_c                   18.8300(14)
_cell_angle_alpha                90
_cell_angle_beta                 117.921(8)
_cell_angle_gamma                90
_cell_volume                     2591.6(3)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    10141
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.7620
_cell_measurement_theta_min      3.6410
_shelx_estimated_absorpt_T_max   0.984
_shelx_estimated_absorpt_T_min   0.922
_exptl_absorpt_coefficient_mu    0.824
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.50512
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.102a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.487
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1192
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.02
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0293
_diffrn_reflns_av_unetI/netI     0.0316
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.870
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            23174
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.870
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.220
_diffrn_reflns_theta_min         3.481
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 16.1544
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.870
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     43.00  68.00   1.00    4.00    --   18.25-134.00-148.00   25
  2  ω     19.00  44.00   1.00    4.00    --   18.25-134.00  30.00   25
  3  ω    -68.00 -43.00   1.00    4.00    --  -19.04 134.00  98.00   25
  4  ω    -82.00 -35.00   1.00    4.00    --  -19.04 134.00 -81.00   47
  5  ω    -25.00  91.00   1.00    4.00    --   18.25  19.00-180.00  116
  6  ω      8.00  34.00   1.00    4.00    --  -19.04  37.00  30.00   26
  7  ω    -20.00  48.00   1.00    4.00    --  -19.04  57.00-150.00   68
  8  ω    -95.00 -40.00   1.00    4.00    --  -19.04-178.00 -60.00   55
  9  ω    -42.00   2.00   1.00    4.00    --  -19.04 -57.00-180.00   44
 10  ω    -83.00 -58.00   1.00    4.00    --  -19.04 -57.00  90.00   25
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4381
_reflns_number_total             6122
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.102a (Rigaku OD, 2021)'
_computing_data_collection       'CrysAlisPro 1.171.41.102a (Rigaku OD, 2021)'
_computing_data_reduction        'CrysAlisPro 1.171.41.102a (Rigaku OD, 2021)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2016/6 (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve 1.3 (Bourhis et al., 2015)'
_refine_diff_density_max         0.429
_refine_diff_density_min         -0.430
_refine_diff_density_rms         0.047
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     414
_refine_ls_number_reflns         6122
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0700
_refine_ls_R_factor_gt           0.0443
_refine_ls_restrained_S_all      1.014
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0360P)²+1.4941P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0899
_refine_ls_wR_factor_ref         0.1012
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups
2. Others
 Sof(C11)=Sof(H11D)=Sof(H11E)=Sof(H11F)=Sof(C12)=Sof(H12D)=Sof(H12E)=Sof(H12F)=
 Sof(C10)=Sof(H10D)=Sof(H10E)=Sof(H10F)=1-FVAR(1)
 Sof(C11A)=Sof(H11A)=Sof(H11B)=Sof(H11C)=Sof(C10A)=Sof(H10A)=Sof(H10B)=
 Sof(H10C)=Sof(C12A)=Sof(H12A)=Sof(H12B)=Sof(H12C)=FVAR(1)
 Sof(C22)=Sof(H22D)=Sof(H22E)=Sof(H22F)=Sof(C23)=Sof(H23D)=Sof(H23E)=Sof(H23F)=
 Sof(C24)=Sof(H24D)=Sof(H24E)=Sof(H24F)=1-FVAR(2)
 Sof(C24A)=Sof(H24A)=Sof(H24B)=Sof(H24C)=Sof(C23A)=Sof(H23A)=Sof(H23B)=
 Sof(H23C)=Sof(C22A)=Sof(H22A)=Sof(H22B)=Sof(H22C)=FVAR(2)
 Sof(O7)=Sof(O5)=Sof(O9)=1-FVAR(3)
 Sof(O8)=Sof(O10)=Sof(O6)=FVAR(3)
3.a Aromatic/amide H refined with riding coordinates:
 C14(H14), C7(H7), C19(H19), C4(H4), C2(H2), C13(H13), C1(H1A), C16(H16),
 C17(H17), C5(H5)
3.b Idealised Me refined as rotating group:
 C11A(H11A,H11B,H11C), C24A(H24A,H24B,H24C), C23A(H23A,H23B,H23C), C10A(H10A,
 H10B,H10C), C12A(H12A,H12B,H12C), C22A(H22A,H22B,H22C), C11(H11D,H11E,H11F),
 C12(H12D,H12E,H12F), C10(H10D,H10E,H10F), C22(H22D,H22E,H22F), C23(H23D,H23E,
 H23F), C24(H24D,H24E,H24F)
3.c Idealised tetrahedral OH refined as rotating group:
 O3(H3), O1(H1)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.48665(2) 0.52255(3) 0.41365(2) 0.07892(13) Uani 1 1 d . . . . .
O2 O 0.93241(14) 1.0747(3) 0.44040(18) 0.0994(9) Uani 1 1 d . . . . .
N2 N 0.37167(15) 0.3925(3) 0.37409(14) 0.0594(6) Uani 1 1 d . . . . .
O4 O -0.01851(15) 0.0327(3) 0.25139(17) 0.0927(8) Uani 1 1 d . . . . .
N1 N 0.59302(15) 0.6647(3) 0.43284(15) 0.0606(6) Uani 1 1 d . . . . .
O3 O 0.07279(13) 0.2528(3) 0.26212(18) 0.0935(8) Uani 1 1 d . . . . .
H3 H 0.028931 0.205157 0.249868 0.140 Uiso 1 1 calc R U . . .
O1 O 0.87121(13) 0.8573(3) 0.48413(19) 0.1007(9) Uani 1 1 d . . . . .
H1 H 0.907302 0.902386 0.476902 0.151 Uiso 1 1 calc R U . . .
C3 C 0.72699(16) 0.8406(3) 0.44299(15) 0.0484(6) Uani 1 1 d . . . . .
N009 N 0.6253(2) 0.2217(3) 0.5327(2) 0.0754(9) Uani 1 1 d . . . . .
C14 C 0.29596(16) 0.1620(3) 0.36525(16) 0.0514(6) Uani 1 1 d . . . . .
H14 H 0.297269 0.057464 0.376172 0.062 Uiso 1 1 calc R U . . .
C7 C 0.79159(17) 1.0626(3) 0.40672(17) 0.0529(6) Uani 1 1 d . . . . .
H7 H 0.739109 1.110446 0.381329 0.063 Uiso 1 1 calc R U . . .
C15 C 0.21993(16) 0.2380(3) 0.32586(15) 0.0482(6) Uani 1 1 d . . . . .
C8 C 0.86196(19) 1.1343(3) 0.40484(18) 0.0574(7) Uani 1 1 d . . . . .
C6 C 0.79876(16) 0.9268(3) 0.44433(17) 0.0538(6) Uani 1 1 d . . . . .
C19 C 0.12741(18) 0.0135(3) 0.31730(18) 0.0555(7) Uani 1 1 d . . . . .
H19 H 0.174738 -0.047688 0.346030 0.067 Uiso 1 1 calc R U . . .
C18 C 0.13699(17) 0.1629(3) 0.30122(16) 0.0532(6) Uani 1 1 d . . . . .
C4 C 0.64829(17) 0.9054(3) 0.41907(17) 0.0550(7) Uani 1 1 d . . . . .
H4 H 0.639118 1.009137 0.405844 0.066 Uiso 1 1 calc R U . . .
C2 C 0.73729(19) 0.6876(3) 0.46500(19) 0.0606(7) Uani 1 1 d . . . . .
H2 H 0.790106 0.641503 0.484681 0.073 Uiso 1 1 calc R U . . .
C13 C 0.36990(18) 0.2421(3) 0.38828(17) 0.0571(7) Uani 1 1 d . . . . .
H13 H 0.420852 0.189506 0.414846 0.068 Uiso 1 1 calc R U . . .
C1 C 0.6692(2) 0.6040(3) 0.4577(2) 0.0659(8) Uani 1 1 d . . . . .
H1A H 0.676748 0.500010 0.470680 0.079 Uiso 1 1 calc R U . . .
C16 C 0.22198(19) 0.3929(3) 0.30959(18) 0.0631(8) Uani 1 1 d . . . . .
H16 H 0.171952 0.447705 0.281711 0.076 Uiso 1 1 calc R U . . .
C17 C 0.2983(2) 0.4648(3) 0.3349(2) 0.0666(8) Uani 1 1 d . . . . .
H17 H 0.298669 0.569067 0.324091 0.080 Uiso 1 1 calc R U . . .
C20 C 0.0451(2) -0.0492(4) 0.29021(19) 0.0618(7) Uani 1 1 d . . . . .
C5 C 0.58395(18) 0.8143(4) 0.41513(18) 0.0614(7) Uani 1 1 d . . . . .
H5 H 0.531378 0.859074 0.399323 0.074 Uiso 1 1 calc R U . . .
O8 O 0.6951(13) 0.201(2) 0.573(2) 0.202(17) Uani 0.294(18) 1 d . . P A 1
C9 C 0.8534(2) 1.2834(3) 0.3603(2) 0.0685(8) Uani 1 1 d . . . . .
O10 O 0.5738(12) 0.192(4) 0.5448(18) 0.233(18) Uani 0.294(18) 1 d . . P A 1
C21 C 0.0306(2) -0.2134(4) 0.3055(2) 0.0698(9) Uani 1 1 d . . . . .
O6 O 0.5941(17) 0.2604(19) 0.4581(12) 0.114(8) Uani 0.294(18) 1 d . . P A 1
C11A C 0.8110(5) 1.3983(6) 0.3873(4) 0.100(3) Uani 0.757(11) 1 d . . P B 1
H11A H 0.752846 1.369886 0.367721 0.150 Uiso 0.757(11) 1 calc R U P B 1
H11B H 0.813960 1.497788 0.366593 0.150 Uiso 0.757(11) 1 calc R U P B 1
H11C H 0.838564 1.401767 0.444918 0.150 Uiso 0.757(11) 1 calc R U P B 1
C24A C 0.0552(9) -0.3047(10) 0.2504(8) 0.123(4) Uani 0.562(12) 1 d . . P C 1
H24A H 0.024998 -0.265449 0.196614 0.184 Uiso 0.562(12) 1 calc R U P C 1
H24B H 0.041190 -0.411091 0.250986 0.184 Uiso 0.562(12) 1 calc R U P C 1
H24C H 0.114836 -0.294930 0.268915 0.184 Uiso 0.562(12) 1 calc R U P C 1
C23A C 0.0781(9) -0.2543(18) 0.3881(7) 0.145(8) Uani 0.562(12) 1 d . . P C 1
H23A H 0.136498 -0.228830 0.406730 0.217 Uiso 0.562(12) 1 calc R U P C 1
H23B H 0.072926 -0.362833 0.394116 0.217 Uiso 0.562(12) 1 calc R U P C 1
H23C H 0.057028 -0.198916 0.419043 0.217 Uiso 0.562(12) 1 calc R U P C 1
C10A C 0.9445(4) 1.3364(7) 0.3803(6) 0.118(3) Uani 0.757(11) 1 d . . P B 1
H10A H 0.973909 1.369824 0.435256 0.177 Uiso 0.757(11) 1 calc R U P B 1
H10B H 0.941182 1.419805 0.345564 0.177 Uiso 0.757(11) 1 calc R U P B 1
H10C H 0.974471 1.252014 0.372481 0.177 Uiso 0.757(11) 1 calc R U P B 1
C12A C 0.8061(5) 1.2489(7) 0.2727(3) 0.094(2) Uani 0.757(11) 1 d . . P B 1
H12A H 0.836100 1.172769 0.259155 0.140 Uiso 0.757(11) 1 calc R U P B 1
H12B H 0.800624 1.341107 0.242604 0.140 Uiso 0.757(11) 1 calc R U P B 1
H12C H 0.750916 1.210630 0.259899 0.140 Uiso 0.757(11) 1 calc R U P B 1
C22A C -0.0672(5) -0.2393(9) 0.2686(8) 0.110(5) Uani 0.562(12) 1 d . . P C 1
H22A H -0.089308 -0.174573 0.295591 0.165 Uiso 0.562(12) 1 calc R U P C 1
H22B H -0.078110 -0.345050 0.275145 0.165 Uiso 0.562(12) 1 calc R U P C 1
H22C H -0.093915 -0.214155 0.212408 0.165 Uiso 0.562(12) 1 calc R U P C 1
C11 C 0.900(2) 1.412(2) 0.4209(14) 0.127(11) Uani 0.243(11) 1 d . . P B 2
H11D H 0.874874 1.424885 0.456039 0.190 Uiso 0.243(11) 1 calc R U P B 2
H11E H 0.894759 1.506602 0.392592 0.190 Uiso 0.243(11) 1 calc R U P B 2
H11F H 0.958218 1.385712 0.452002 0.190 Uiso 0.243(11) 1 calc R U P B 2
C12 C 0.7507(14) 1.342(3) 0.308(2) 0.20(2) Uani 0.243(11) 1 d . . P B 2
H12D H 0.748448 1.440358 0.283896 0.306 Uiso 0.243(11) 1 calc R U P B 2
H12E H 0.726643 1.350191 0.343910 0.306 Uiso 0.243(11) 1 calc R U P B 2
H12F H 0.719216 1.268319 0.266687 0.306 Uiso 0.243(11) 1 calc R U P B 2
C10 C 0.883(2) 1.278(3) 0.302(2) 0.150(14) Uani 0.243(11) 1 d . . P B 2
H10D H 0.941060 1.245018 0.326744 0.225 Uiso 0.243(11) 1 calc R U P B 2
H10E H 0.879344 1.379186 0.279205 0.225 Uiso 0.243(11) 1 calc R U P B 2
H10F H 0.849358 1.207881 0.259545 0.225 Uiso 0.243(11) 1 calc R U P B 2
C22 C -0.0238(9) -0.2104(11) 0.3510(9) 0.108(5) Uani 0.438(12) 1 d . . P C 2
H22D H 0.006931 -0.158311 0.401480 0.162 Uiso 0.438(12) 1 calc R U P C 2
H22E H -0.035659 -0.313906 0.360413 0.162 Uiso 0.438(12) 1 calc R U P C 2
H22F H -0.075857 -0.157238 0.318914 0.162 Uiso 0.438(12) 1 calc R U P C 2
C23 C 0.1173(12) -0.2949(16) 0.3715(11) 0.114(6) Uani 0.438(12) 1 d . . P C 2
H23D H 0.104892 -0.396378 0.383116 0.172 Uiso 0.438(12) 1 calc R U P C 2
H23E H 0.141506 -0.234862 0.419978 0.172 Uiso 0.438(12) 1 calc R U P C 2
H23F H 0.156738 -0.301416 0.350456 0.172 Uiso 0.438(12) 1 calc R U P C 2
C24 C -0.0022(11) -0.3118(15) 0.2386(7) 0.123(7) Uani 0.438(12) 1 d . . P C 2
H24D H -0.047474 -0.261094 0.193946 0.185 Uiso 0.438(12) 1 calc R U P C 2
H24E H -0.023034 -0.403912 0.251318 0.185 Uiso 0.438(12) 1 calc R U P C 2
H24F H 0.041563 -0.337733 0.224884 0.185 Uiso 0.438(12) 1 calc R U P C 2
O7 O 0.6951(5) 0.2019(11) 0.5462(7) 0.124(3) Uani 0.706(18) 1 d . . P A 2
O5 O 0.5740(7) 0.2712(13) 0.4734(8) 0.175(6) Uani 0.706(18) 1 d . . P A 2
O9 O 0.6084(8) 0.1983(5) 0.5894(8) 0.121(3) Uani 0.706(18) 1 d . . P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag1 3.0824(6) 3_666 ?
Ag1 N2 2.154(2) . ?
Ag1 N1 2.155(2) . ?
O2 C8 1.232(3) . ?
N2 C13 1.338(4) . ?
N2 C17 1.327(4) . ?
O4 C20 1.249(4) . ?
N1 C1 1.328(4) . ?
N1 C5 1.333(4) . ?
O3 H3 0.8200 . ?
O3 C18 1.297(3) . ?
O1 H1 0.8200 . ?
O1 C6 1.304(3) . ?
C3 C6 1.478(4) . ?
C3 C4 1.383(4) . ?
C3 C2 1.380(4) . ?
N009 O8 1.135(19) . ?
N009 O10 1.08(2) . ?
N009 O6 1.29(2) . ?
N009 O7 1.167(7) . ?
N009 O5 1.147(10) . ?
N009 O9 1.255(8) . ?
C14 H14 0.9300 . ?
C14 C15 1.377(4) . ?
C14 C13 1.375(4) . ?
C7 H7 0.9300 . ?
C7 C8 1.422(4) . ?
C7 C6 1.351(4) . ?
C15 C18 1.485(4) . ?
C15 C16 1.386(4) . ?
C8 C9 1.512(4) . ?
C19 H19 0.9300 . ?
C19 C18 1.363(4) . ?
C19 C20 1.424(4) . ?
C4 H4 0.9300 . ?
C4 C5 1.371(4) . ?
C2 H2 0.9300 . ?
C2 C1 1.370(4) . ?
C13 H13 0.9300 . ?
C1 H1A 0.9300 . ?
C16 H16 0.9300 . ?
C16 C17 1.370(4) . ?
C17 H17 0.9300 . ?
C20 C21 1.503(4) . ?
C5 H5 0.9300 . ?
C9 C11A 1.482(6) . ?
C9 C10A 1.563(6) . ?
C9 C12A 1.489(6) . ?
C9 C11 1.54(2) . ?
C9 C12 1.71(2) . ?
C9 C10 1.44(2) . ?
C21 C24A 1.526(10) . ?
C21 C23A 1.424(12) . ?
C21 C22A 1.570(7) . ?
C21 C22 1.570(10) . ?
C21 C23 1.628(19) . ?
C21 C24 1.404(10) . ?
C11A H11A 0.9600 . ?
C11A H11B 0.9600 . ?
C11A H11C 0.9600 . ?
C24A H24A 0.9600 . ?
C24A H24B 0.9600 . ?
C24A H24C 0.9600 . ?
C23A H23A 0.9600 . ?
C23A H23B 0.9600 . ?
C23A H23C 0.9600 . ?
C10A H10A 0.9600 . ?
C10A H10B 0.9600 . ?
C10A H10C 0.9600 . ?
C12A H12A 0.9600 . ?
C12A H12B 0.9600 . ?
C12A H12C 0.9600 . ?
C22A H22A 0.9600 . ?
C22A H22B 0.9600 . ?
C22A H22C 0.9600 . ?
C11 H11D 0.9600 . ?
C11 H11E 0.9600 . ?
C11 H11F 0.9600 . ?
C12 H12D 0.9600 . ?
C12 H12E 0.9600 . ?
C12 H12F 0.9600 . ?
C10 H10D 0.9600 . ?
C10 H10E 0.9600 . ?
C10 H10F 0.9600 . ?
C22 H22D 0.9600 . ?
C22 H22E 0.9600 . ?
C22 H22F 0.9600 . ?
C23 H23D 0.9600 . ?
C23 H23E 0.9600 . ?
C23 H23F 0.9600 . ?
C24 H24D 0.9600 . ?
C24 H24E 0.9600 . ?
C24 H24F 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Ag1 Ag1 87.07(6) . 3_666 ?
N2 Ag1 N1 170.53(9) . . ?
N1 Ag1 Ag1 101.99(7) . 3_666 ?
C13 N2 Ag1 123.5(2) . . ?
C17 N2 Ag1 118.81(19) . . ?
C17 N2 C13 117.7(2) . . ?
C1 N1 Ag1 120.9(2) . . ?
C1 N1 C5 117.4(2) . . ?
C5 N1 Ag1 121.5(2) . . ?
C18 O3 H3 109.5 . . ?
C6 O1 H1 109.5 . . ?
C4 C3 C6 123.0(2) . . ?
C2 C3 C6 119.4(2) . . ?
C2 C3 C4 117.6(2) . . ?
O8 N009 O6 124(2) . . ?
O10 N009 O8 127(2) . . ?
O10 N009 O6 108.4(17) . . ?
O7 N009 O9 116.8(7) . . ?
O5 N009 O7 123.8(10) . . ?
O5 N009 O9 119.1(9) . . ?
C15 C14 H14 120.3 . . ?
C13 C14 H14 120.3 . . ?
C13 C14 C15 119.4(2) . . ?
C8 C7 H7 119.0 . . ?
C6 C7 H7 119.0 . . ?
C6 C7 C8 121.9(2) . . ?
C14 C15 C18 123.4(2) . . ?
C14 C15 C16 117.6(2) . . ?
C16 C15 C18 119.0(2) . . ?
O2 C8 C7 119.8(3) . . ?
O2 C8 C9 118.3(3) . . ?
C7 C8 C9 121.9(3) . . ?
O1 C6 C3 113.5(2) . . ?
O1 C6 C7 122.1(2) . . ?
C7 C6 C3 124.4(2) . . ?
C18 C19 H19 119.9 . . ?
C18 C19 C20 120.1(3) . . ?
C20 C19 H19 119.9 . . ?
O3 C18 C15 113.8(2) . . ?
O3 C18 C19 122.0(3) . . ?
C19 C18 C15 124.2(3) . . ?
C3 C4 H4 120.5 . . ?
C5 C4 C3 119.1(3) . . ?
C5 C4 H4 120.5 . . ?
C3 C2 H2 120.2 . . ?
C1 C2 C3 119.6(3) . . ?
C1 C2 H2 120.2 . . ?
N2 C13 C14 122.8(3) . . ?
N2 C13 H13 118.6 . . ?
C14 C13 H13 118.6 . . ?
N1 C1 C2 123.0(3) . . ?
N1 C1 H1A 118.5 . . ?
C2 C1 H1A 118.5 . . ?
C15 C16 H16 120.3 . . ?
C17 C16 C15 119.5(3) . . ?
C17 C16 H16 120.3 . . ?
N2 C17 C16 123.0(3) . . ?
N2 C17 H17 118.5 . . ?
C16 C17 H17 118.5 . . ?
O4 C20 C19 120.0(3) . . ?
O4 C20 C21 117.6(3) . . ?
C19 C20 C21 122.5(3) . . ?
N1 C5 C4 123.3(3) . . ?
N1 C5 H5 118.4 . . ?
C4 C5 H5 118.4 . . ?
C8 C9 C10A 107.2(3) . . ?
C8 C9 C11 109.5(8) . . ?
C8 C9 C12 112.2(7) . . ?
C11A C9 C8 108.8(3) . . ?
C11A C9 C10A 111.3(5) . . ?
C11A C9 C12A 113.4(4) . . ?
C12A C9 C8 107.4(3) . . ?
C12A C9 C10A 108.4(5) . . ?
C11 C9 C12 105.8(17) . . ?
C10 C9 C8 115.1(10) . . ?
C10 C9 C11 109.1(15) . . ?
C10 C9 C12 104.7(19) . . ?
C20 C21 C24A 103.5(4) . . ?
C20 C21 C22A 107.9(4) . . ?
C20 C21 C22 107.2(4) . . ?
C20 C21 C23 111.8(6) . . ?
C24A C21 C22A 104.0(6) . . ?
C23A C21 C20 112.2(6) . . ?
C23A C21 C24A 113.4(9) . . ?
C23A C21 C22A 114.9(6) . . ?
C22 C21 C23 101.8(7) . . ?
C24 C21 C20 116.4(6) . . ?
C24 C21 C22 113.2(8) . . ?
C24 C21 C23 105.6(9) . . ?
C9 C11A H11A 109.5 . . ?
C9 C11A H11B 109.5 . . ?
C9 C11A H11C 109.5 . . ?
H11A C11A H11B 109.5 . . ?
H11A C11A H11C 109.5 . . ?
H11B C11A H11C 109.5 . . ?
C21 C24A H24A 109.5 . . ?
C21 C24A H24B 109.5 . . ?
C21 C24A H24C 109.5 . . ?
H24A C24A H24B 109.5 . . ?
H24A C24A H24C 109.5 . . ?
H24B C24A H24C 109.5 . . ?
C21 C23A H23A 109.5 . . ?
C21 C23A H23B 109.5 . . ?
C21 C23A H23C 109.5 . . ?
H23A C23A H23B 109.5 . . ?
H23A C23A H23C 109.5 . . ?
H23B C23A H23C 109.5 . . ?
C9 C10A H10A 109.5 . . ?
C9 C10A H10B 109.5 . . ?
C9 C10A H10C 109.5 . . ?
H10A C10A H10B 109.5 . . ?
H10A C10A H10C 109.5 . . ?
H10B C10A H10C 109.5 . . ?
C9 C12A H12A 109.5 . . ?
C9 C12A H12B 109.5 . . ?
C9 C12A H12C 109.5 . . ?
H12A C12A H12B 109.5 . . ?
H12A C12A H12C 109.5 . . ?
H12B C12A H12C 109.5 . . ?
C21 C22A H22A 109.5 . . ?
C21 C22A H22B 109.5 . . ?
C21 C22A H22C 109.5 . . ?
H22A C22A H22B 109.5 . . ?
H22A C22A H22C 109.5 . . ?
H22B C22A H22C 109.5 . . ?
C9 C11 H11D 109.5 . . ?
C9 C11 H11E 109.5 . . ?
C9 C11 H11F 109.5 . . ?
H11D C11 H11E 109.5 . . ?
H11D C11 H11F 109.5 . . ?
H11E C11 H11F 109.5 . . ?
C9 C12 H12D 109.5 . . ?
C9 C12 H12E 109.5 . . ?
C9 C12 H12F 109.5 . . ?
H12D C12 H12E 109.5 . . ?
H12D C12 H12F 109.5 . . ?
H12E C12 H12F 109.5 . . ?
C9 C10 H10D 109.5 . . ?
C9 C10 H10E 109.5 . . ?
C9 C10 H10F 109.5 . . ?
H10D C10 H10E 109.5 . . ?
H10D C10 H10F 109.5 . . ?
H10E C10 H10F 109.5 . . ?
C21 C22 H22D 109.5 . . ?
C21 C22 H22E 109.5 . . ?
C21 C22 H22F 109.5 . . ?
H22D C22 H22E 109.5 . . ?
H22D C22 H22F 109.5 . . ?
H22E C22 H22F 109.5 . . ?
C21 C23 H23D 109.5 . . ?
C21 C23 H23E 109.5 . . ?
C21 C23 H23F 109.5 . . ?
H23D C23 H23E 109.5 . . ?
H23D C23 H23F 109.5 . . ?
H23E C23 H23F 109.5 . . ?
C21 C24 H24D 109.5 . . ?
C21 C24 H24E 109.5 . . ?
C21 C24 H24F 109.5 . . ?
H24D C24 H24E 109.5 . . ?
H24D C24 H24F 109.5 . . ?
H24E C24 H24F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 N2 C13 C14 177.5(2) . . . . ?
Ag1 N2 C17 C16 -177.9(2) . . . . ?
Ag1 N1 C1 C2 175.0(2) . . . . ?
Ag1 N1 C5 C4 -173.5(2) . . . . ?
O2 C8 C9 C11A -127.2(5) . . . . ?
O2 C8 C9 C10A -6.7(6) . . . . ?
O2 C8 C9 C12A 109.7(5) . . . . ?
O2 C8 C9 C11 -67.8(13) . . . . ?
O2 C8 C9 C12 175.1(18) . . . . ?
O2 C8 C9 C10 55.5(18) . . . . ?
O4 C20 C21 C24A 107.9(7) . . . . ?
O4 C20 C21 C23A -129.5(9) . . . . ?
O4 C20 C21 C22A -1.9(6) . . . . ?
O4 C20 C21 C22 -57.4(8) . . . . ?
O4 C20 C21 C23 -168.2(7) . . . . ?
O4 C20 C21 C24 70.4(10) . . . . ?
C3 C4 C5 N1 -0.4(5) . . . . ?
C3 C2 C1 N1 -2.6(5) . . . . ?
C14 C15 C18 O3 -177.5(3) . . . . ?
C14 C15 C18 C19 2.4(4) . . . . ?
C14 C15 C16 C17 -1.9(4) . . . . ?
C7 C8 C9 C11A 52.7(5) . . . . ?
C7 C8 C9 C10A 173.2(5) . . . . ?
C7 C8 C9 C12A -70.5(5) . . . . ?
C7 C8 C9 C11 112.1(13) . . . . ?
C7 C8 C9 C12 -5.0(18) . . . . ?
C7 C8 C9 C10 -124.6(18) . . . . ?
C15 C14 C13 N2 0.0(4) . . . . ?
C15 C16 C17 N2 0.8(5) . . . . ?
C8 C7 C6 O1 3.2(5) . . . . ?
C8 C7 C6 C3 -175.0(3) . . . . ?
C6 C3 C4 C5 176.1(3) . . . . ?
C6 C3 C2 C1 -174.7(3) . . . . ?
C6 C7 C8 O2 -2.3(5) . . . . ?
C6 C7 C8 C9 177.8(3) . . . . ?
C19 C20 C21 C24A -71.3(7) . . . . ?
C19 C20 C21 C23A 51.3(9) . . . . ?
C19 C20 C21 C22A 178.9(6) . . . . ?
C19 C20 C21 C22 123.3(7) . . . . ?
C19 C20 C21 C23 12.6(8) . . . . ?
C19 C20 C21 C24 -108.9(10) . . . . ?
C18 C15 C16 C17 177.4(3) . . . . ?
C18 C19 C20 O4 0.3(5) . . . . ?
C18 C19 C20 C21 179.5(3) . . . . ?
C4 C3 C6 O1 166.3(3) . . . . ?
C4 C3 C6 C7 -15.4(4) . . . . ?
C4 C3 C2 C1 4.1(4) . . . . ?
C2 C3 C6 O1 -14.9(4) . . . . ?
C2 C3 C6 C7 163.4(3) . . . . ?
C2 C3 C4 C5 -2.6(4) . . . . ?
C13 N2 C17 C16 0.8(5) . . . . ?
C13 C14 C15 C18 -177.7(2) . . . . ?
C13 C14 C15 C16 1.5(4) . . . . ?
C1 N1 C5 C4 2.0(4) . . . . ?
C16 C15 C18 O3 3.3(4) . . . . ?
C16 C15 C18 C19 -176.8(3) . . . . ?
C17 N2 C13 C14 -1.1(4) . . . . ?
C20 C19 C18 O3 0.8(5) . . . . ?
C20 C19 C18 C15 -179.1(3) . . . . ?
C5 N1 C1 C2 -0.5(5) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;



_publcif_funding_html            
;
;
