# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_audit_block_doi                 10.5517/ccdc.csd.cc21h1l6
_database_code_depnum_ccdc_archive 'CCDC 1891297'
loop_
_audit_author_name
_audit_author_address
'Meng Yinshan'
;Peking University
China
;
_audit_update_record             
;
2019-01-16 deposited with the CCDC.	2023-05-31 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C32 H51 Au Cl2 F O1.50 P2'
_chemical_formula_weight         808.53

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.4363(3)
_cell_length_b                   12.6303(3)
_cell_length_c                   15.7917(4)
_cell_angle_alpha                67.371(2)
_cell_angle_beta                 73.525(2)
_cell_angle_gamma                69.303(2)
_cell_volume                     1940.54(8)
_cell_formula_units_Z            2
_cell_measurement_temperature    180.00(10)
_cell_measurement_reflns_used    15462
_cell_measurement_theta_min      3.3000
_cell_measurement_theta_max      28.1310

_exptl_crystal_description       block
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.15
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.384
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             814
_exptl_absorpt_coefficient_mu    4.038
_exptl_absorpt_correction_T_min  0.68100
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      180.00(10)
_diffrn_radiation_wavelength     0.7107
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_monochromator  mirror
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_detector_area_resol_mean 10.3914
_diffrn_measurement_method       ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            28450
_diffrn_reflns_av_R_equivalents  0.0439
_diffrn_reflns_av_sigmaI/netI    0.0375
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         2.83
_diffrn_reflns_theta_max         25.00
_reflns_number_total             6823
_reflns_number_gt                6327
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0696P)²+8.2586P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6823
_refine_ls_number_parameters     397
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0486
_refine_ls_R_factor_gt           0.0447
_refine_ls_wR_factor_ref         0.1243
_refine_ls_wR_factor_gt          0.1214
_refine_ls_goodness_of_fit_ref   1.100
_refine_ls_restrained_S_all      1.100
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 1.0807(6) 0.1618(5) 0.0981(4) 0.0215(12) Uani 1 1 d . A 1
C2 C 1.0092(6) 0.2295(5) 0.0274(4) 0.0250(13) Uani 1 1 d . A 1
C3 C 1.0752(6) 0.2672(6) -0.0625(5) 0.0292(14) Uani 1 1 d . A 1
H3A H 1.0299 0.3141 -0.1110 0.035 Uiso 1 1 calc R A 1
C4 C 1.2050(7) 0.2371(6) -0.0814(5) 0.0342(15) Uani 1 1 d . A 1
H4A H 1.2467 0.2629 -0.1422 0.041 Uiso 1 1 calc R A 1
C5 C 1.2745(6) 0.1675(6) -0.0093(5) 0.0296(14) Uani 1 1 d . A 1
H5A H 1.3627 0.1463 -0.0226 0.035 Uiso 1 1 calc R A 1
C6 C 1.2135(6) 0.1298(5) 0.0817(4) 0.0225(12) Uani 1 1 d . A 1
C7 C 1.2833(6) 0.0601(6) 0.1637(4) 0.0266(13) Uani 1 1 d . A 1
C8 C 1.2080(6) -0.0260(6) 0.2356(4) 0.0250(13) Uani 1 1 d . A 1
C9 C 1.2638(7) -0.1374(6) 0.2916(5) 0.0337(15) Uani 1 1 d . A 1
H9A H 1.3517 -0.1666 0.2841 0.040 Uiso 1 1 calc R A 1
C10 C 1.1888(7) -0.2060(6) 0.3593(5) 0.0398(17) Uani 1 1 d . A 1
H10A H 1.2272 -0.2809 0.3971 0.048 Uiso 1 1 calc R A 1
C11 C 1.0589(7) -0.1655(6) 0.3715(5) 0.0351(15) Uani 1 1 d . A 1
H11A H 1.0108 -0.2130 0.4178 0.042 Uiso 1 1 calc R A 1
C12 C 0.9973(6) -0.0534(6) 0.3151(4) 0.0281(14) Uani 1 1 d . A 1
C13 C 1.0754(6) 0.0141(6) 0.2472(4) 0.0233(12) Uani 1 1 d . A 1
C14 C 0.7803(7) 0.2430(6) -0.0419(5) 0.0305(14) Uani 1 1 d . A 1
C15 C 0.7821(9) 0.3365(7) -0.1381(6) 0.049(2) Uani 1 1 d . A 1
H15A H 0.7543 0.3127 -0.1782 0.073 Uiso 1 1 calc R A 1
H15B H 0.8668 0.3437 -0.1635 0.073 Uiso 1 1 calc R A 1
H15C H 0.7263 0.4120 -0.1331 0.073 Uiso 1 1 calc R A 1
C16 C 0.6467(7) 0.2319(7) -0.0028(6) 0.0452(19) Uani 1 1 d . A 1
H16A H 0.6162 0.2167 -0.0465 0.068 Uiso 1 1 calc R A 1
H16B H 0.5926 0.3047 0.0084 0.068 Uiso 1 1 calc R A 1
H16C H 0.6466 0.1671 0.0547 0.068 Uiso 1 1 calc R A 1
C17 C 0.8658(8) 0.1222(7) -0.0511(6) 0.0419(18) Uani 1 1 d . A 1
H17A H 0.8415 0.1047 -0.0966 0.063 Uiso 1 1 calc R A 1
H17B H 0.8570 0.0611 0.0079 0.063 Uiso 1 1 calc R A 1
H17C H 0.9525 0.1248 -0.0703 0.063 Uiso 1 1 calc R A 1
C18 C 0.7839(7) 0.4312(6) 0.0423(5) 0.0330(15) Uani 1 1 d . A 1
C19 C 0.8490(8) 0.5114(6) -0.0417(6) 0.0422(18) Uani 1 1 d . A 1
H19A H 0.8181 0.5913 -0.0387 0.063 Uiso 1 1 calc R A 1
H19B H 0.8313 0.5107 -0.0973 0.063 Uiso 1 1 calc R A 1
H19C H 0.9389 0.4833 -0.0425 0.063 Uiso 1 1 calc R A 1
C20 C 0.6397(7) 0.4817(7) 0.0472(7) 0.051(2) Uani 1 1 d . A 1
H20A H 0.6150 0.5638 0.0443 0.077 Uiso 1 1 calc R A 1
H20B H 0.5979 0.4369 0.1047 0.077 Uiso 1 1 calc R A 1
H20C H 0.6160 0.4759 -0.0042 0.077 Uiso 1 1 calc R A 1
C21 C 0.8183(7) 0.4290(6) 0.1302(6) 0.0394(17) Uani 1 1 d . A 1
H21A H 0.7958 0.5091 0.1318 0.059 Uiso 1 1 calc R A 1
H21B H 0.9079 0.3940 0.1294 0.059 Uiso 1 1 calc R A 1
H21C H 0.7729 0.3827 0.1844 0.059 Uiso 1 1 calc R A 1
C22 C 0.7774(7) 0.0558(7) 0.4328(5) 0.0341(16) Uani 1 1 d . A 1
C23 C 0.8265(8) 0.1667(7) 0.3976(6) 0.0436(18) Uani 1 1 d . A 1
H23A H 0.8059 0.2006 0.4467 0.065 Uiso 1 1 calc R A 1
H23B H 0.7873 0.2245 0.3457 0.065 Uiso 1 1 calc R A 1
H23C H 0.9168 0.1442 0.3784 0.065 Uiso 1 1 calc R A 1
C24 C 0.6332(8) 0.0943(9) 0.4589(6) 0.052(2) Uani 1 1 d . A 1
H24A H 0.6102 0.1238 0.5107 0.078 Uiso 1 1 calc R A 1
H24B H 0.6007 0.0272 0.4756 0.078 Uiso 1 1 calc R A 1
H24C H 0.5980 0.1562 0.4067 0.078 Uiso 1 1 calc R A 1
C25 C 0.8374(9) -0.0344(8) 0.5187(5) 0.047(2) Uani 1 1 d . A 1
H25A H 0.8104 0.0003 0.5679 0.071 Uiso 1 1 calc R A 1
H25B H 0.9281 -0.0537 0.5022 0.071 Uiso 1 1 calc R A 1
H25C H 0.8107 -0.1057 0.5392 0.071 Uiso 1 1 calc R A 1
C26 C 0.7585(7) -0.1279(7) 0.3505(5) 0.0390(17) Uani 1 1 d . A 1
C27 C 0.6249(8) -0.0693(8) 0.3240(6) 0.051(2) Uani 1 1 d . A 1
H27A H 0.5877 -0.1303 0.3314 0.076 Uiso 1 1 calc R A 1
H27B H 0.6313 -0.0186 0.2603 0.076 Uiso 1 1 calc R A 1
H27C H 0.5727 -0.0227 0.3637 0.076 Uiso 1 1 calc R A 1
C28 C 0.7464(9) -0.2164(8) 0.4498(5) 0.049(2) Uani 1 1 d . A 1
H28A H 0.7134 -0.2773 0.4512 0.074 Uiso 1 1 calc R A 1
H28B H 0.6900 -0.1748 0.4919 0.074 Uiso 1 1 calc R A 1
H28C H 0.8284 -0.2523 0.4681 0.074 Uiso 1 1 calc R A 1
C29 C 0.8419(9) -0.1919(8) 0.2809(6) 0.051(2) Uani 1 1 d . A 1
H29A H 0.8116 -0.2571 0.2879 0.076 Uiso 1 1 calc R A 1
H29B H 0.9277 -0.2218 0.2920 0.076 Uiso 1 1 calc R A 1
H29C H 0.8390 -0.1371 0.2188 0.076 Uiso 1 1 calc R A 1
C30 C 1.2840(7) 0.1482(7) 0.2091(5) 0.0391(17) Uani 1 1 d . A 1
H30A H 1.3301 0.2033 0.1653 0.059 Uiso 1 1 calc R A 1
H30B H 1.3240 0.1049 0.2631 0.059 Uiso 1 1 calc R A 1
H30C H 1.1984 0.1914 0.2271 0.059 Uiso 1 1 calc R A 1
C31 C 1.4191(6) -0.0071(7) 0.1347(5) 0.0373(16) Uani 1 1 d . A 1
H31A H 1.4192 -0.0619 0.1061 0.056 Uiso 1 1 calc R A 1
H31B H 1.4595 -0.0505 0.1885 0.056 Uiso 1 1 calc R A 1
H31C H 1.4645 0.0486 0.0910 0.056 Uiso 1 1 calc R A 1
O1 O 1.0200(4) 0.1265(4) 0.1902(3) 0.0214(8) Uani 1 1 d . A 1
P1 P 0.83348(15) 0.27169(14) 0.04769(11) 0.0231(3) Uani 1 1 d . A 1
P2 P 0.82311(16) -0.00153(16) 0.33234(11) 0.0265(4) Uani 1 1 d . A 1
Au1 Au 0.78189(2) 0.14601(2) 0.194194(16) 0.02744(11) Uani 1 1 d . A 1
O3 O 0.4814(10) 0.3264(10) -0.1862(9) 0.055(3) Uani 0.50 1 d P B 1
F1 F 0.5175(17) 0.3444(13) -0.4543(13) 0.113(6) Uani 0.50 1 d P C 1
F2 F 0.3991(18) 0.3274(16) -0.3045(11) 0.114(6) Uani 0.50 1 d P D 1
Cl4 Cl 1.4225(8) -0.6784(6) 0.2748(5) 0.097(2) Uani 0.50 1 d P E 1
Cl3 Cl 1.2827(12) -0.5138(6) 0.3662(5) 0.138(4) Uani 0.50 1 d P E 1
Cl2 Cl 1.0031(12) -0.4211(13) 0.7078(7) 0.160(5) Uani 0.50 1 d P F 1
Cl1 Cl 1.0740(17) -0.4741(8) 0.5459(7) 0.205(7) Uani 0.50 1 d P F 1
C33 C 1.427(2) -0.5894(16) 0.3230(12) 0.062(5) Uani 0.50 1 d P E 1
H33A H 1.4707 -0.5324 0.2776 0.074 Uiso 0.50 1 calc PR E 1
H33B H 1.4751 -0.6349 0.3732 0.074 Uiso 0.50 1 calc PR E 1
C32 C 1.117(4) -0.461(2) 0.638(3) 0.128(13) Uani 0.50 1 d P F 1
H32A H 1.1700 -0.5380 0.6704 0.154 Uiso 0.50 1 calc PR F 1
H32B H 1.1669 -0.4044 0.6141 0.154 Uiso 0.50 1 calc PR F 1


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.391(9) . ?
C1 O1 1.394(7) . ?
C1 C6 1.400(8) . ?
C2 C3 1.392(9) . ?
C2 P1 1.853(6) . ?
C3 C4 1.369(10) . ?
C3 H3A 0.9300 . ?
C4 C5 1.396(10) . ?
C4 H4A 0.9300 . ?
C5 C6 1.385(9) . ?
C5 H5A 0.9300 . ?
C6 C7 1.518(9) . ?
C7 C31 1.519(9) . ?
C7 C8 1.539(9) . ?
C7 C30 1.541(9) . ?
C8 C9 1.378(9) . ?
C8 C13 1.401(9) . ?
C9 C10 1.386(11) . ?
C9 H9A 0.9300 . ?
C10 C11 1.372(11) . ?
C10 H10A 0.9300 . ?
C11 C12 1.406(10) . ?
C11 H11A 0.9300 . ?
C12 C13 1.402(9) . ?
C12 P2 1.838(7) . ?
C13 O1 1.390(7) . ?
C14 C16 1.512(11) . ?
C14 C15 1.523(11) . ?
C14 C17 1.530(10) . ?
C14 P1 1.882(6) . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C18 C19 1.509(11) . ?
C18 C20 1.534(10) . ?
C18 C21 1.536(10) . ?
C18 P1 1.864(7) . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 C24 1.526(10) . ?
C22 C23 1.538(10) . ?
C22 C25 1.547(11) . ?
C22 P2 1.860(7) . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
C25 H25A 0.9600 . ?
C25 H25B 0.9600 . ?
C25 H25C 0.9600 . ?
C26 C29 1.522(11) . ?
C26 C28 1.538(10) . ?
C26 C27 1.543(11) . ?
C26 P2 1.881(7) . ?
C27 H27A 0.9600 . ?
C27 H27B 0.9600 . ?
C27 H27C 0.9600 . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C29 H29A 0.9600 . ?
C29 H29B 0.9600 . ?
C29 H29C 0.9600 . ?
C30 H30A 0.9600 . ?
C30 H30B 0.9600 . ?
C30 H30C 0.9600 . ?
C31 H31A 0.9600 . ?
C31 H31B 0.9600 . ?
C31 H31C 0.9600 . ?
P1 Au1 2.2983(16) . ?
P2 Au1 2.2996(17) . ?
Cl4 C33 1.602(19) . ?
Cl3 C33 1.68(2) . ?
Cl2 C32 1.52(4) . ?
Cl1 C32 1.75(4) . ?
C33 H33A 0.9700 . ?
C33 H33B 0.9700 . ?
C32 H32A 0.9700 . ?
C32 H32B 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 O1 119.9(5) . . ?
C2 C1 C6 122.8(6) . . ?
O1 C1 C6 117.3(5) . . ?
C3 C2 C1 117.1(6) . . ?
C3 C2 P1 119.5(5) . . ?
C1 C2 P1 123.4(5) . . ?
C4 C3 C2 121.8(6) . . ?
C4 C3 H3A 119.1 . . ?
C2 C3 H3A 119.1 . . ?
C3 C4 C5 119.9(6) . . ?
C3 C4 H4A 120.1 . . ?
C5 C4 H4A 120.1 . . ?
C6 C5 C4 120.7(6) . . ?
C6 C5 H5A 119.7 . . ?
C4 C5 H5A 119.7 . . ?
C5 C6 C1 117.7(6) . . ?
C5 C6 C7 123.2(5) . . ?
C1 C6 C7 119.1(5) . . ?
C6 C7 C31 112.1(5) . . ?
C6 C7 C8 107.8(5) . . ?
C31 C7 C8 111.1(5) . . ?
C6 C7 C30 108.6(5) . . ?
C31 C7 C30 109.2(5) . . ?
C8 C7 C30 108.0(5) . . ?
C9 C8 C13 118.6(6) . . ?
C9 C8 C7 123.6(6) . . ?
C13 C8 C7 117.8(5) . . ?
C8 C9 C10 120.0(7) . . ?
C8 C9 H9A 120.0 . . ?
C10 C9 H9A 120.0 . . ?
C11 C10 C9 121.2(6) . . ?
C11 C10 H10A 119.4 . . ?
C9 C10 H10A 119.4 . . ?
C10 C11 C12 121.1(7) . . ?
C10 C11 H11A 119.5 . . ?
C12 C11 H11A 119.5 . . ?
C13 C12 C11 116.5(6) . . ?
C13 C12 P2 123.3(5) . . ?
C11 C12 P2 120.2(5) . . ?
O1 C13 C8 118.2(5) . . ?
O1 C13 C12 119.2(5) . . ?
C8 C13 C12 122.6(6) . . ?
C16 C14 C15 109.0(6) . . ?
C16 C14 C17 108.0(6) . . ?
C15 C14 C17 109.1(6) . . ?
C16 C14 P1 106.9(5) . . ?
C15 C14 P1 116.4(5) . . ?
C17 C14 P1 107.2(5) . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C14 C16 H16A 109.5 . . ?
C14 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C14 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C14 C17 H17A 109.5 . . ?
C14 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C14 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C19 C18 C20 109.3(6) . . ?
C19 C18 C21 108.7(6) . . ?
C20 C18 C21 108.7(6) . . ?
C19 C18 P1 115.1(5) . . ?
C20 C18 P1 110.0(5) . . ?
C21 C18 P1 104.9(5) . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C18 C20 H20A 109.5 . . ?
C18 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C18 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C18 C21 H21A 109.5 . . ?
C18 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C18 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C24 C22 C23 108.6(7) . . ?
C24 C22 C25 110.5(6) . . ?
C23 C22 C25 108.9(6) . . ?
C24 C22 P2 109.9(5) . . ?
C23 C22 P2 105.4(5) . . ?
C25 C22 P2 113.4(5) . . ?
C22 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C22 C24 H24A 109.5 . . ?
C22 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C22 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C22 C25 H25A 109.5 . . ?
C22 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C22 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C29 C26 C28 111.0(7) . . ?
C29 C26 C27 108.1(7) . . ?
C28 C26 C27 108.2(6) . . ?
C29 C26 P2 107.0(5) . . ?
C28 C26 P2 116.2(5) . . ?
C27 C26 P2 106.0(6) . . ?
C26 C27 H27A 109.5 . . ?
C26 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C26 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C26 C28 H28A 109.5 . . ?
C26 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C26 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C26 C29 H29A 109.5 . . ?
C26 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C26 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C7 C30 H30A 109.5 . . ?
C7 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C7 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C7 C31 H31A 109.5 . . ?
C7 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C7 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C13 O1 C1 117.2(4) . . ?
C2 P1 C18 104.7(3) . . ?
C2 P1 C14 109.0(3) . . ?
C18 P1 C14 114.7(3) . . ?
C2 P1 Au1 103.6(2) . . ?
C18 P1 Au1 113.0(2) . . ?
C14 P1 Au1 110.9(2) . . ?
C12 P2 C22 104.5(3) . . ?
C12 P2 C26 109.3(3) . . ?
C22 P2 C26 115.0(3) . . ?
C12 P2 Au1 103.5(2) . . ?
C22 P2 Au1 113.3(3) . . ?
C26 P2 Au1 110.4(2) . . ?
P1 Au1 P2 155.37(6) . . ?
Cl4 C33 Cl3 114.2(14) . . ?
Cl4 C33 H33A 108.7 . . ?
Cl3 C33 H33A 108.7 . . ?
Cl4 C33 H33B 108.7 . . ?
Cl3 C33 H33B 108.7 . . ?
H33A C33 H33B 107.6 . . ?
Cl2 C32 Cl1 113(2) . . ?
Cl2 C32 H32A 109.1 . . ?
Cl1 C32 H32A 109.1 . . ?
Cl2 C32 H32B 109.1 . . ?
Cl1 C32 H32B 109.1 . . ?
H32A C32 H32B 107.8 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C1 C2 C3 176.7(5) . . . . ?
C6 C1 C2 C3 -1.0(9) . . . . ?
O1 C1 C2 P1 -2.8(8) . . . . ?
C6 C1 C2 P1 179.5(4) . . . . ?
C1 C2 C3 C4 1.4(9) . . . . ?
P1 C2 C3 C4 -179.1(5) . . . . ?
C2 C3 C4 C5 -0.5(10) . . . . ?
C3 C4 C5 C6 -0.9(10) . . . . ?
C4 C5 C6 C1 1.3(9) . . . . ?
C4 C5 C6 C7 -176.4(6) . . . . ?
C2 C1 C6 C5 -0.3(9) . . . . ?
O1 C1 C6 C5 -178.1(5) . . . . ?
C2 C1 C6 C7 177.4(5) . . . . ?
O1 C1 C6 C7 -0.3(8) . . . . ?
C5 C6 C7 C31 -24.2(8) . . . . ?
C1 C6 C7 C31 158.1(6) . . . . ?
C5 C6 C7 C8 -146.8(6) . . . . ?
C1 C6 C7 C8 35.6(7) . . . . ?
C5 C6 C7 C30 96.5(7) . . . . ?
C1 C6 C7 C30 -81.2(7) . . . . ?
C6 C7 C8 C9 146.2(6) . . . . ?
C31 C7 C8 C9 23.0(8) . . . . ?
C30 C7 C8 C9 -96.7(7) . . . . ?
C6 C7 C8 C13 -36.9(7) . . . . ?
C31 C7 C8 C13 -160.1(6) . . . . ?
C30 C7 C8 C13 80.2(7) . . . . ?
C13 C8 C9 C10 -1.6(10) . . . . ?
C7 C8 C9 C10 175.3(6) . . . . ?
C8 C9 C10 C11 0.4(11) . . . . ?
C9 C10 C11 C12 0.7(11) . . . . ?
C10 C11 C12 C13 -0.6(10) . . . . ?
C10 C11 C12 P2 179.6(6) . . . . ?
C9 C8 C13 O1 -179.9(5) . . . . ?
C7 C8 C13 O1 3.1(8) . . . . ?
C9 C8 C13 C12 1.6(9) . . . . ?
C7 C8 C13 C12 -175.4(5) . . . . ?
C11 C12 C13 O1 -179.0(5) . . . . ?
P2 C12 C13 O1 0.8(8) . . . . ?
C11 C12 C13 C8 -0.6(9) . . . . ?
P2 C12 C13 C8 179.2(5) . . . . ?
C8 C13 O1 C1 37.1(7) . . . . ?
C12 C13 O1 C1 -144.3(5) . . . . ?
C2 C1 O1 C13 143.5(5) . . . . ?
C6 C1 O1 C13 -38.7(7) . . . . ?
C3 C2 P1 C18 -76.4(6) . . . . ?
C1 C2 P1 C18 103.0(5) . . . . ?
C3 C2 P1 C14 46.7(6) . . . . ?
C1 C2 P1 C14 -133.8(5) . . . . ?
C3 C2 P1 Au1 164.9(5) . . . . ?
C1 C2 P1 Au1 -15.6(5) . . . . ?
C19 C18 P1 C2 49.7(6) . . . . ?
C20 C18 P1 C2 173.7(6) . . . . ?
C21 C18 P1 C2 -69.6(5) . . . . ?
C19 C18 P1 C14 -69.7(6) . . . . ?
C20 C18 P1 C14 54.3(7) . . . . ?
C21 C18 P1 C14 171.0(5) . . . . ?
C19 C18 P1 Au1 161.8(5) . . . . ?
C20 C18 P1 Au1 -74.2(6) . . . . ?
C21 C18 P1 Au1 42.5(5) . . . . ?
C16 C14 P1 C2 158.5(5) . . . . ?
C15 C14 P1 C2 -79.4(6) . . . . ?
C17 C14 P1 C2 43.0(6) . . . . ?
C16 C14 P1 C18 -84.5(6) . . . . ?
C15 C14 P1 C18 37.6(7) . . . . ?
C17 C14 P1 C18 159.9(5) . . . . ?
C16 C14 P1 Au1 45.0(5) . . . . ?
C15 C14 P1 Au1 167.1(5) . . . . ?
C17 C14 P1 Au1 -70.5(5) . . . . ?
C13 C12 P2 C22 -99.3(6) . . . . ?
C11 C12 P2 C22 80.6(6) . . . . ?
C13 C12 P2 C26 137.2(5) . . . . ?
C11 C12 P2 C26 -43.0(6) . . . . ?
C13 C12 P2 Au1 19.5(6) . . . . ?
C11 C12 P2 Au1 -160.7(5) . . . . ?
C24 C22 P2 C12 -176.2(6) . . . . ?
C23 C22 P2 C12 67.0(6) . . . . ?
C25 C22 P2 C12 -52.0(6) . . . . ?
C24 C22 P2 C26 -56.3(7) . . . . ?
C23 C22 P2 C26 -173.2(5) . . . . ?
C25 C22 P2 C26 67.8(6) . . . . ?
C24 C22 P2 Au1 71.9(6) . . . . ?
C23 C22 P2 Au1 -44.9(6) . . . . ?
C25 C22 P2 Au1 -163.9(4) . . . . ?
C29 C26 P2 C12 -42.0(6) . . . . ?
C28 C26 P2 C12 82.6(7) . . . . ?
C27 C26 P2 C12 -157.1(5) . . . . ?
C29 C26 P2 C22 -159.1(6) . . . . ?
C28 C26 P2 C22 -34.5(8) . . . . ?
C27 C26 P2 C22 85.7(6) . . . . ?
C29 C26 P2 Au1 71.2(6) . . . . ?
C28 C26 P2 Au1 -164.2(6) . . . . ?
C27 C26 P2 Au1 -43.9(5) . . . . ?
C2 P1 Au1 P2 1.9(3) . . . . ?
C18 P1 Au1 P2 -110.8(3) . . . . ?
C14 P1 Au1 P2 118.7(3) . . . . ?
C12 P2 Au1 P1 -4.6(3) . . . . ?
C22 P2 Au1 P1 107.9(3) . . . . ?
C26 P2 Au1 P1 -121.5(3) . . . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         3.496
_refine_diff_density_min         -0.709
_refine_diff_density_rms         0.165
