# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 2247975'
loop_
_audit_author_name
_audit_author_address
'Hanen Elgahami'
;chemistry
Tunisia
;
_audit_update_record             
;
2023-04-14 deposited with the CCDC.	2023-08-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C32 H72 Cd2 Cl6 P2'
_chemical_formula_weight         956.36

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.9722(12)
_cell_length_b                   15.4178(14)
_cell_length_c                   15.4260(15)
_cell_angle_alpha                68.708(2)
_cell_angle_beta                 73.198(3)
_cell_angle_gamma                74.391(2)
_cell_volume                     2496.4(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    9776
_cell_measurement_theta_min      1.442
_cell_measurement_theta_max      26.992

_exptl_crystal_description       prism
_exptl_crystal_colour            ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.272
_exptl_crystal_F_000             984
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_absorpt_coefficient_mu    1.255
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'APEXII Bruker-AXS'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            78565
_diffrn_reflns_av_unetI/netI     0.0448
_diffrn_reflns_av_R_equivalents  0.0605
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.442
_diffrn_reflns_theta_max         26.992
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.897
_diffrn_measured_fraction_theta_full 0.989
_diffrn_reflns_Laue_measured_fraction_max 0.897
_diffrn_reflns_Laue_measured_fraction_full 0.989
_diffrn_reflns_point_group_measured_fraction_max 0.897
_diffrn_reflns_point_group_measured_fraction_full 0.989
_reflns_number_total             9776
_reflns_number_gt                5121
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0852P)²+2.8578P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_extinction_coef       0.0060(7)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         9776
_refine_ls_number_parameters     388
_refine_ls_number_restraints     3
_refine_ls_R_factor_all          0.1361
_refine_ls_R_factor_gt           0.0602
_refine_ls_wR_factor_ref         0.2179
_refine_ls_wR_factor_gt          0.1521
_refine_ls_goodness_of_fit_ref   1.150
_refine_ls_restrained_S_all      1.154
_refine_ls_shift/su_max          0.1
_refine_ls_shift/su_mean         0.043

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cd1 Cd 0.64815(5) 0.49507(4) 0.50374(4) 0.0934(3) Uani 1 1 d . . . . .
Cd2 Cd 0.10554(7) 0.93259(4) 0.92986(4) 0.1178(3) Uani 1 1 d . . . . .
P1 P 0.0111(2) 0.68535(17) 0.29244(17) 0.1074(7) Uani 1 1 d . . . . .
P2 P 0.3357(2) 0.7184(2) 0.70665(19) 0.1264(8) Uani 1 1 d . . . . .
Cl1 Cl 0.48846(18) 0.40104(14) 0.60643(14) 0.1052(6) Uani 1 1 d . . . . .
Cl2 Cl 0.6929(2) 0.57995(18) 0.58775(19) 0.1229(7) Uani 1 1 d . . . . .
Cl3 Cl 0.81247(18) 0.4048(2) 0.42473(19) 0.1285(8) Uani 1 1 d . . . . .
Cl4 Cl 0.1163(3) 1.0103(2) 1.0441(2) 0.1477(10) Uani 1 1 d . . . . .
Cl5 Cl 0.1543(3) 0.76352(16) 0.98483(16) 0.1496(11) Uani 1 1 d . . . . .
Cl6 Cl 0.2005(3) 1.00795(17) 0.77078(17) 0.1611(12) Uani 1 1 d . . . . .
C5 C -0.0943(8) 0.7457(6) 0.2191(7) 0.114(3) Uani 1 1 d . . . . .
H5A H -0.112571 0.812112 0.215173 0.136 Uiso 1 1 calc R U . . .
H5B H -0.058079 0.741871 0.155340 0.136 Uiso 1 1 calc R U . . .
C9 C 0.0514(9) 0.5620(7) 0.2981(8) 0.139(3) Uani 1 1 d . . . . .
H9A H 0.114828 0.531702 0.332541 0.167 Uiso 1 1 calc R U . . .
H9B H -0.016420 0.531640 0.333832 0.167 Uiso 1 1 calc R U . . .
C21 C 0.3869(12) 0.7778(8) 0.7639(8) 0.148(4) Uani 1 1 d . . . . .
H21A H 0.359884 0.845460 0.738384 0.178 Uiso 1 1 calc R U . . .
H21B H 0.350554 0.758803 0.831291 0.178 Uiso 1 1 calc R U . . .
C1 C -0.0437(9) 0.6862(8) 0.4125(7) 0.137(3) Uani 1 1 d . . . . .
H1A H -0.109283 0.652126 0.440932 0.164 Uiso 1 1 calc R U . . .
H1B H 0.018544 0.652587 0.447765 0.164 Uiso 1 1 calc R U . . .
C29 C 0.3918(11) 0.7564(10) 0.5800(8) 0.161(4) Uani 1 1 d . . . . .
H29A H 0.474508 0.726267 0.567524 0.193 Uiso 1 1 calc R U . . .
H29B H 0.349517 0.732395 0.551184 0.193 Uiso 1 1 calc R U . . .
C25 C 0.3852(10) 0.5936(7) 0.7470(8) 0.145(4) Uani 1 1 d . . . . .
H25A H 0.353026 0.564587 0.715627 0.174 Uiso 1 1 calc R U . . .
H25B H 0.470957 0.580446 0.727108 0.174 Uiso 1 1 calc R U . . .
C6 C -0.2042(9) 0.7103(8) 0.2510(9) 0.151(4) Uani 1 1 d . . . . .
H6A H -0.243770 0.718046 0.312906 0.182 Uiso 1 1 calc R U . . .
H6B H -0.186398 0.643067 0.258498 0.182 Uiso 1 1 calc R U . . .
C17 C 0.1771(13) 0.7365(12) 0.7400(11) 0.203(6) Uani 1 1 d . . . . .
H17A H 0.152458 0.690822 0.723126 0.243 Uiso 1 1 calc R U . . .
H17B H 0.155840 0.719951 0.808865 0.243 Uiso 1 1 calc R U . . .
C22 C 0.5141(14) 0.7599(12) 0.7536(13) 0.195(6) Uani 1 1 d . . . . .
H22A H 0.549779 0.774000 0.686128 0.234 Uiso 1 1 calc R U . . .
H22B H 0.539406 0.692745 0.783066 0.234 Uiso 1 1 calc R U . . .
C2 C -0.0857(15) 0.7855(10) 0.4227(9) 0.193(6) Uani 1 1 d . . . . .
H2A H -0.019806 0.819145 0.392938 0.231 Uiso 1 1 calc R U . . .
H2B H -0.147500 0.818374 0.386906 0.231 Uiso 1 1 calc R U . . .
C10 C 0.0914(14) 0.5462(9) 0.2014(11) 0.194(6) Uani 1 1 d . . . . .
H10A H 0.030432 0.580421 0.164987 0.233 Uiso 1 1 calc R U . . .
H10B H 0.162842 0.572223 0.167450 0.233 Uiso 1 1 calc R U . . .
C26 C 0.3511(14) 0.5461(11) 0.8555(10) 0.199(6) Uani 1 1 d . . . . .
H26A H 0.364454 0.584700 0.887832 0.239 Uiso 1 1 calc R U . . .
H26B H 0.267111 0.543802 0.873302 0.239 Uiso 1 1 calc R U . . .
C13 C 0.1316(11) 0.7511(9) 0.2359(8) 0.154(4) Uani 1 1 d . . . . .
H13A H 0.160391 0.747175 0.171642 0.185 Uiso 1 1 calc R U . . .
H13B H 0.098078 0.817095 0.230487 0.185 Uiso 1 1 calc R U . . .
C3 C -0.1310(17) 0.7926(14) 0.5184(11) 0.227(7) Uani 1 1 d . . . . .
H3A H -0.192080 0.754119 0.550386 0.272 Uiso 1 1 calc R U . . .
H3B H -0.066999 0.765084 0.552546 0.272 Uiso 1 1 calc R U . . .
C7 C -0.2911(12) 0.7622(12) 0.1801(12) 0.196(6) Uani 1 1 d . . . . .
H7A H -0.366004 0.740276 0.209111 0.235 Uiso 1 1 calc R U . . .
H7B H -0.306465 0.829586 0.171373 0.235 Uiso 1 1 calc R U . . .
C18 C 0.1099(14) 0.8221(13) 0.7052(14) 0.215(7) Uani 1 1 d . . . . .
H18A H 0.120018 0.835025 0.637275 0.258 Uiso 1 1 calc R U . . .
H18B H 0.140406 0.870010 0.713779 0.258 Uiso 1 1 calc R U . . .
C19 C -0.0232(14) 0.8332(14) 0.7494(16) 0.239(9) Uani 1 1 d . . . . .
H19A H -0.057658 0.793127 0.732286 0.287 Uiso 1 1 calc R U . . .
H19B H -0.034558 0.812177 0.818254 0.287 Uiso 1 1 calc R U . . .
C11 C 0.1153(19) 0.4460(11) 0.2067(14) 0.255(10) Uani 1 1 d . . . . .
H11A H 0.183315 0.412387 0.235366 0.306 Uiso 1 1 calc R U . . .
H11B H 0.047347 0.417172 0.246017 0.306 Uiso 1 1 calc R U . . .
C14 C 0.2291(12) 0.7270(12) 0.2763(10) 0.188(5) Uani 1 1 d . . . . .
H14A H 0.258136 0.659251 0.291126 0.226 Uiso 1 1 calc R U . . .
H14B H 0.205982 0.742613 0.335314 0.226 Uiso 1 1 calc R U . . .
C27 C 0.421(2) 0.4463(12) 0.8890(16) 0.274(13) Uani 1 1 d . . . . .
H27A H 0.384425 0.418791 0.955254 0.329 Uiso 1 1 calc R U . . .
H27B H 0.408555 0.410198 0.853671 0.329 Uiso 1 1 calc R U . . .
C30 C 0.3845(18) 0.8586(12) 0.5307(12) 0.247(10) Uani 1 1 d . . . . .
H30A H 0.429559 0.884203 0.555676 0.296 Uiso 1 1 calc R U . . .
H30B H 0.302458 0.890806 0.541268 0.296 Uiso 1 1 calc R U . . .
C16 C 0.310(3) 0.863(2) 0.228(3) 0.44(3) Uani 1 1 d D . . . .
H16A H 0.224956 0.880453 0.240285 0.653 Uiso 1 1 calc R U . . .
H16B H 0.343669 0.915229 0.179854 0.653 Uiso 1 1 calc R U . . .
H16C H 0.336833 0.849151 0.285371 0.653 Uiso 1 1 calc R U . . .
C4 C -0.179(2) 0.8839(16) 0.5264(15) 0.305(14) Uani 1 1 d . . . . .
H4A H -0.121674 0.924460 0.491221 0.458 Uiso 1 1 calc R U . . .
H4B H -0.197827 0.880843 0.592187 0.458 Uiso 1 1 calc R U . . .
H4C H -0.249470 0.908865 0.501175 0.458 Uiso 1 1 calc R U . . .
C31 C 0.437(3) 0.8759(19) 0.4190(16) 0.303(14) Uani 1 1 d D . . . .
H31A H 0.456480 0.817704 0.402698 0.363 Uiso 1 1 calc R U . . .
H31B H 0.382707 0.922588 0.381002 0.363 Uiso 1 1 calc R U . . .
C20 C -0.084(2) 0.929(2) 0.718(2) 0.369(19) Uani 1 1 d . . . . .
H20A H -0.055805 0.968038 0.741345 0.553 Uiso 1 1 calc R U . . .
H20B H -0.167393 0.932256 0.742935 0.553 Uiso 1 1 calc R U . . .
H20C H -0.067803 0.951852 0.650053 0.553 Uiso 1 1 calc R U . . .
C12 C 0.140(3) 0.4391(16) 0.1092(18) 0.363(18) Uani 1 1 d . . . . .
H12A H 0.183613 0.377293 0.108323 0.544 Uiso 1 1 calc R U . . .
H12B H 0.184909 0.486175 0.065399 0.544 Uiso 1 1 calc R U . . .
H12C H 0.065805 0.449453 0.090813 0.544 Uiso 1 1 calc R U . . .
C8 C -0.247(2) 0.748(2) 0.0856(17) 0.347(18) Uani 1 1 d . . . . .
H8A H -0.167793 0.760756 0.059866 0.521 Uiso 1 1 calc R U . . .
H8B H -0.297899 0.789630 0.043691 0.521 Uiso 1 1 calc R U . . .
H8C H -0.246201 0.683314 0.091877 0.521 Uiso 1 1 calc R U . . .
C28 C 0.536(2) 0.431(2) 0.884(2) 0.40(2) Uani 1 1 d . . . . .
H28A H 0.577547 0.428761 0.820966 0.602 Uiso 1 1 calc R U . . .
H28B H 0.558681 0.372140 0.929885 0.602 Uiso 1 1 calc R U . . .
H28C H 0.554798 0.481671 0.895865 0.602 Uiso 1 1 calc R U . . .
C23 C 0.565(2) 0.8132(18) 0.7940(19) 0.275(11) Uani 1 1 d D . . . .
H23A H 0.647592 0.783352 0.789545 0.330 Uiso 1 1 calc R U . . .
H23B H 0.563841 0.875640 0.747435 0.330 Uiso 1 1 calc R U . . .
C24 C 0.532(3) 0.829(3) 0.876(2) 0.42(2) Uani 1 1 d D . . . .
H24A H 0.475138 0.886679 0.871553 0.636 Uiso 1 1 calc R U . . .
H24B H 0.600520 0.834411 0.893203 0.636 Uiso 1 1 calc R U . . .
H24C H 0.497756 0.777324 0.923613 0.636 Uiso 1 1 calc R U . . .
C32 C 0.529(2) 0.907(3) 0.411(2) 0.40(2) Uani 1 1 d D . . . .
H32A H 0.521195 0.972349 0.372924 0.606 Uiso 1 1 calc R U . . .
H32B H 0.597700 0.870794 0.381186 0.606 Uiso 1 1 calc R U . . .
H32C H 0.537318 0.901086 0.473097 0.606 Uiso 1 1 calc R U . . .
C15 C 0.3438(19) 0.7879(14) 0.198(2) 0.313(17) Uani 1 1 d D . . . .
H15A H 0.421900 0.753260 0.208367 0.376 Uiso 1 1 calc R U . . .
H15B H 0.341315 0.803593 0.131644 0.376 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cd1 Cl3 2.380(2) . ?
Cd1 Cl2 2.385(2) . ?
Cd1 Cl1 2.518(2) . ?
Cd1 Cl1 2.520(2) 2_666 ?
Cd2 Cl6 2.386(2) . ?
Cd2 Cl5 2.391(2) . ?
Cd2 Cl4 2.511(3) . ?
Cd2 Cl4 2.524(3) 2_577 ?
P1 C1 1.781(11) . ?
P1 C5 1.780(9) . ?
P1 C13 1.813(11) . ?
P1 C9 1.807(11) . ?
P2 C25 1.781(11) . ?
P2 C21 1.788(12) . ?
P2 C17 1.789(15) . ?
P2 C29 1.798(12) . ?
C5 C6 1.446(13) . ?
C9 C10 1.517(17) . ?
C21 C22 1.444(16) . ?
C1 C2 1.529(16) . ?
C29 C30 1.471(18) . ?
C25 C26 1.542(17) . ?
C6 C7 1.579(17) . ?
C17 C18 1.357(19) . ?
C22 C23 1.51(2) . ?
C2 C3 1.452(18) . ?
C10 C11 1.469(18) . ?
C26 C27 1.52(2) . ?
C13 C14 1.381(15) . ?
C3 C4 1.41(2) . ?
C7 C8 1.48(3) . ?
C18 C19 1.53(2) . ?
C19 C20 1.43(3) . ?
C11 C12 1.48(3) . ?
C14 C15 1.77(3) . ?
C27 C28 1.31(3) . ?
C30 C31 1.60(3) . ?
C16 C15 1.328(19) . ?
C31 C32 1.276(17) . ?
C23 C24 1.302(17) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl3 Cd1 Cl2 116.59(8) . . ?
Cl3 Cd1 Cl1 112.66(9) . . ?
Cl2 Cd1 Cl1 110.99(9) . . ?
Cl3 Cd1 Cl1 111.06(9) . 2_666 ?
Cl2 Cd1 Cl1 112.06(8) . 2_666 ?
Cl1 Cd1 Cl1 90.61(6) . 2_666 ?
Cl6 Cd2 Cl5 116.17(8) . . ?
Cl6 Cd2 Cl4 111.72(12) . . ?
Cl5 Cd2 Cl4 113.84(10) . . ?
Cl6 Cd2 Cl4 110.83(12) . 2_577 ?
Cl5 Cd2 Cl4 111.33(12) . 2_577 ?
Cl4 Cd2 Cl4 90.04(9) . 2_577 ?
C1 P1 C5 113.5(5) . . ?
C1 P1 C13 110.0(5) . . ?
C5 P1 C13 103.2(5) . . ?
C1 P1 C9 105.9(5) . . ?
C5 P1 C9 109.8(5) . . ?
C13 P1 C9 114.6(6) . . ?
C25 P2 C21 111.5(6) . . ?
C25 P2 C17 105.7(7) . . ?
C21 P2 C17 108.4(7) . . ?
C25 P2 C29 106.6(6) . . ?
C21 P2 C29 111.0(6) . . ?
C17 P2 C29 113.5(7) . . ?
Cd1 Cl1 Cd1 89.39(6) . 2_666 ?
Cd2 Cl4 Cd2 89.97(9) . 2_577 ?
C6 C5 P1 115.1(7) . . ?
C10 C9 P1 114.0(8) . . ?
C22 C21 P2 114.9(10) . . ?
C2 C1 P1 113.9(8) . . ?
C30 C29 P2 118.0(10) . . ?
C26 C25 P2 115.5(8) . . ?
C5 C6 C7 112.9(10) . . ?
C18 C17 P2 121.1(14) . . ?
C21 C22 C23 117.9(16) . . ?
C3 C2 C1 117.4(13) . . ?
C11 C10 C9 113.6(13) . . ?
C27 C26 C25 113.3(13) . . ?
C14 C13 P1 120.0(10) . . ?
C4 C3 C2 116.8(17) . . ?
C8 C7 C6 114.8(17) . . ?
C17 C18 C19 116.4(18) . . ?
C20 C19 C18 112(2) . . ?
C12 C11 C10 109.2(16) . . ?
C13 C14 C15 110.9(13) . . ?
C28 C27 C26 121(3) . . ?
C29 C30 C31 109.4(16) . . ?
C32 C31 C30 99(2) . . ?
C24 C23 C22 131(3) . . ?
C16 C15 C14 97(3) . . ?

_refine_diff_density_max         0.634
_refine_diff_density_min         -0.595
_refine_diff_density_rms         0.147

