# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
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# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_hd777c_0ma_a
_database_code_depnum_ccdc_archive 'CCDC 2310779'
loop_
_audit_author_name
_audit_author_address
'Harsha Harsha'
;Indian Institute of Technology Delhi
India
;
_audit_update_record             
;
2023-11-28 deposited with the CCDC.	2024-04-29 downloaded from the CCDC.
;
_audit_creation_date             2023-06-20
_audit_creation_method           
;
Olex2 1.5
(compiled 2023.03.06 svn.rbb2c1857 for OlexSys, GUI svn.r6748)
;
_shelx_SHELXL_version_number     2019/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C19 H15 Cl2 N O3'
_chemical_formula_sum            'C19 H15 Cl2 N O3'
_chemical_formula_weight         376.22
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   16.1234(10)
_cell_length_b                   11.9822(7)
_cell_length_c                   8.9939(6)
_cell_angle_alpha                90
_cell_angle_beta                 94.945(2)
_cell_angle_gamma                90
_cell_volume                     1731.10(19)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    7619
_cell_measurement_temperature    300(2)
_cell_measurement_theta_max      24.74
_cell_measurement_theta_min      2.54
_shelx_estimated_absorpt_T_max   0.996
_shelx_estimated_absorpt_T_min   0.995
_exptl_absorpt_coefficient_mu    0.393
_exptl_absorpt_correction_T_max  0.996
_exptl_absorpt_correction_T_min  0.995
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0859 before and 0.0664 after correction.
The Ratio of minimum to maximum transmission is 0.8713.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   .
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.444
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             776
_exptl_crystal_size_max          0.014
_exptl_crystal_size_mid          0.012
_exptl_crystal_size_min          0.011
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0667
_diffrn_reflns_av_unetI/netI     0.0353
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            30352
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.413
_diffrn_reflns_theta_min         2.120
_diffrn_ambient_temperature      300.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2579
_reflns_number_total             3187
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    ?
_refine_diff_density_max         0.276
_refine_diff_density_min         -0.240
_refine_diff_density_rms         0.038
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.070
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     228
_refine_ls_number_reflns         3187
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0491
_refine_ls_R_factor_gt           0.0390
_refine_ls_restrained_S_all      1.070
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0474P)²+0.4970P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1021
_refine_ls_wR_factor_ref         0.1091
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C8(H8A,H8B)
2.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C6(H6), C17(H17), C19(H19)
2.c Idealised Me refined as rotating group:
 C14(H14A,H14B,H14C), C15(H15A,H15B,H15C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cl1_1 Cl 0.42508(4) 0.25280(5) -0.06326(7) 0.0681(2) Uani 1 1 d . . . . .
Cl2_1 Cl 0.63921(4) 0.48218(6) 0.29942(9) 0.0752(2) Uani 1 1 d . . . . .
O1_1 O 0.21902(10) 0.46590(12) 0.42842(19) 0.0601(4) Uani 1 1 d . . . . .
O2_1 O 0.15203(9) 0.43094(12) 0.07790(19) 0.0581(4) Uani 1 1 d . . . . .
O3_1 O 0.34266(10) 0.65735(13) 0.3499(2) 0.0622(4) Uani 1 1 d . . . . .
N1_1 N 0.28734(10) 0.38393(12) 0.09439(19) 0.0444(4) Uani 1 1 d . . . . .
C1_1 C 0.11336(12) 0.57730(17) 0.5170(2) 0.0468(5) Uani 1 1 d . . . . .
C2_1 C 0.05385(14) 0.6587(2) 0.4861(3) 0.0574(6) Uani 1 1 d . . . . .
H2_1 H 0.052052 0.697006 0.395961 0.069 Uiso 1 1 calc R U . . .
C3_1 C -0.00324(17) 0.6839(3) 0.5876(3) 0.0752(8) Uani 1 1 d . . . . .
H3_1 H -0.043168 0.738843 0.565363 0.090 Uiso 1 1 calc R U . . .
C4_1 C -0.00087(19) 0.6283(3) 0.7199(4) 0.0818(9) Uani 1 1 d . . . . .
H4_1 H -0.039848 0.644529 0.787266 0.098 Uiso 1 1 calc R U . . .
C5_1 C 0.0587(2) 0.5485(3) 0.7545(3) 0.0833(9) Uani 1 1 d . . . . .
H5_1 H 0.060781 0.511907 0.845892 0.100 Uiso 1 1 calc R U . . .
C6_1 C 0.11597(17) 0.5224(2) 0.6530(3) 0.0672(7) Uani 1 1 d . . . . .
H6_1 H 0.156135 0.468041 0.676321 0.081 Uiso 1 1 calc R U . . .
C7_1 C 0.17284(12) 0.54537(16) 0.4070(2) 0.0436(4) Uani 1 1 d . . . . .
C8_1 C 0.17536(12) 0.61314(16) 0.2661(2) 0.0433(5) Uani 1 1 d . . . . .
H8A_1 H 0.184161 0.691056 0.292203 0.052 Uiso 1 1 calc R U . . .
H8B_1 H 0.122157 0.607066 0.207559 0.052 Uiso 1 1 calc R U . . .
C9_1 C 0.24458(12) 0.57410(15) 0.1720(2) 0.0412(4) Uani 1 1 d . . . . .
C10_1 C 0.22376(12) 0.45761(16) 0.1124(2) 0.0431(4) Uani 1 1 d . . . . .
C11_1 C 0.37134(12) 0.41151(14) 0.1300(2) 0.0391(4) Uani 1 1 d . . . . .
C12_1 C 0.39272(12) 0.50262(15) 0.2230(2) 0.0403(4) Uani 1 1 d . . . . .
C13_1 C 0.32780(12) 0.58210(15) 0.2616(2) 0.0432(5) Uani 1 1 d . . . . .
C14_1 C 0.24825(15) 0.65166(18) 0.0354(3) 0.0557(6) Uani 1 1 d . . . . .
H14A_1 H 0.289985 0.625084 -0.025845 0.084 Uiso 1 1 calc R U . . .
H14B_1 H 0.261955 0.726038 0.068747 0.084 Uiso 1 1 calc R U . . .
H14C_1 H 0.195077 0.652039 -0.021560 0.084 Uiso 1 1 calc R U . . .
C15_1 C 0.26065(15) 0.26681(17) 0.0688(3) 0.0673(7) Uani 1 1 d . . . . .
H15A_1 H 0.303715 0.217495 0.109580 0.101 Uiso 1 1 calc R U . . .
H15B_1 H 0.250298 0.253569 -0.036406 0.101 Uiso 1 1 calc R U . . .
H15C_1 H 0.210643 0.253381 0.116732 0.101 Uiso 1 1 calc R U . . .
C16_1 C 0.43788(13) 0.35163(15) 0.0773(2) 0.0447(5) Uani 1 1 d . . . . .
C17_1 C 0.51925(13) 0.37302(17) 0.1301(2) 0.0491(5) Uani 1 1 d . . . . .
H17_1 H 0.562002 0.329748 0.097482 0.059 Uiso 1 1 calc R U . . .
C18_1 C 0.53758(13) 0.45783(17) 0.2306(3) 0.0501(5) Uani 1 1 d . . . . .
C19_1 C 0.47463(13) 0.52550(17) 0.2740(2) 0.0473(5) Uani 1 1 d . . . . .
H19_1 H 0.487052 0.585896 0.336984 0.057 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cl1_1 C16_1 1.732(2) . ?
Cl2_1 C18_1 1.726(2) . ?
O1_1 C7_1 1.214(2) . ?
O2_1 C10_1 1.214(2) . ?
O3_1 C13_1 1.212(2) . ?
N1_1 C10_1 1.373(2) . ?
N1_1 C11_1 1.404(2) . ?
N1_1 C15_1 1.480(2) . ?
C1_1 C2_1 1.379(3) . ?
C1_1 C6_1 1.386(3) . ?
C1_1 C7_1 1.486(3) . ?
C2_1 H2_1 0.9300 . ?
C2_1 C3_1 1.385(3) . ?
C3_1 H3_1 0.9300 . ?
C3_1 C4_1 1.362(4) . ?
C4_1 H4_1 0.9300 . ?
C4_1 C5_1 1.372(5) . ?
C5_1 H5_1 0.9300 . ?
C5_1 C6_1 1.388(4) . ?
C6_1 H6_1 0.9300 . ?
C7_1 C8_1 1.508(3) . ?
C8_1 H8A_1 0.9700 . ?
C8_1 H8B_1 0.9700 . ?
C8_1 C9_1 1.531(3) . ?
C9_1 C10_1 1.522(3) . ?
C9_1 C13_1 1.507(3) . ?
C9_1 C14_1 1.546(3) . ?
C11_1 C12_1 1.400(3) . ?
C11_1 C16_1 1.407(3) . ?
C12_1 C13_1 1.478(3) . ?
C12_1 C19_1 1.388(3) . ?
C14_1 H14A_1 0.9600 . ?
C14_1 H14B_1 0.9600 . ?
C14_1 H14C_1 0.9600 . ?
C15_1 H15A_1 0.9600 . ?
C15_1 H15B_1 0.9600 . ?
C15_1 H15C_1 0.9600 . ?
C16_1 C17_1 1.380(3) . ?
C17_1 H17_1 0.9300 . ?
C17_1 C18_1 1.375(3) . ?
C18_1 C19_1 1.382(3) . ?
C19_1 H19_1 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C10_1 N1_1 C11_1 122.48(15) . . ?
C10_1 N1_1 C15_1 114.71(17) . . ?
C11_1 N1_1 C15_1 121.36(16) . . ?
C2_1 C1_1 C6_1 118.7(2) . . ?
C2_1 C1_1 C7_1 121.7(2) . . ?
C6_1 C1_1 C7_1 119.6(2) . . ?
C1_1 C2_1 H2_1 119.6 . . ?
C1_1 C2_1 C3_1 120.8(3) . . ?
C3_1 C2_1 H2_1 119.6 . . ?
C2_1 C3_1 H3_1 120.0 . . ?
C4_1 C3_1 C2_1 119.9(3) . . ?
C4_1 C3_1 H3_1 120.0 . . ?
C3_1 C4_1 H4_1 119.8 . . ?
C3_1 C4_1 C5_1 120.3(3) . . ?
C5_1 C4_1 H4_1 119.8 . . ?
C4_1 C5_1 H5_1 120.0 . . ?
C4_1 C5_1 C6_1 120.0(3) . . ?
C6_1 C5_1 H5_1 120.0 . . ?
C1_1 C6_1 C5_1 120.1(3) . . ?
C1_1 C6_1 H6_1 119.9 . . ?
C5_1 C6_1 H6_1 119.9 . . ?
O1_1 C7_1 C1_1 121.23(19) . . ?
O1_1 C7_1 C8_1 119.68(18) . . ?
C1_1 C7_1 C8_1 119.09(17) . . ?
C7_1 C8_1 H8A_1 109.2 . . ?
C7_1 C8_1 H8B_1 109.2 . . ?
C7_1 C8_1 C9_1 111.94(16) . . ?
H8A_1 C8_1 H8B_1 107.9 . . ?
C9_1 C8_1 H8A_1 109.2 . . ?
C9_1 C8_1 H8B_1 109.2 . . ?
C8_1 C9_1 C14_1 109.61(16) . . ?
C10_1 C9_1 C8_1 109.03(15) . . ?
C10_1 C9_1 C14_1 107.07(17) . . ?
C13_1 C9_1 C8_1 110.05(17) . . ?
C13_1 C9_1 C10_1 113.93(15) . . ?
C13_1 C9_1 C14_1 107.05(16) . . ?
O2_1 C10_1 N1_1 120.34(18) . . ?
O2_1 C10_1 C9_1 120.49(17) . . ?
N1_1 C10_1 C9_1 119.14(17) . . ?
N1_1 C11_1 C16_1 123.49(17) . . ?
C12_1 C11_1 N1_1 120.20(17) . . ?
C12_1 C11_1 C16_1 116.31(17) . . ?
C11_1 C12_1 C13_1 119.97(17) . . ?
C19_1 C12_1 C11_1 122.01(18) . . ?
C19_1 C12_1 C13_1 117.90(17) . . ?
O3_1 C13_1 C9_1 120.94(17) . . ?
O3_1 C13_1 C12_1 121.96(18) . . ?
C12_1 C13_1 C9_1 116.70(16) . . ?
C9_1 C14_1 H14A_1 109.5 . . ?
C9_1 C14_1 H14B_1 109.5 . . ?
C9_1 C14_1 H14C_1 109.5 . . ?
H14A_1 C14_1 H14B_1 109.5 . . ?
H14A_1 C14_1 H14C_1 109.5 . . ?
H14B_1 C14_1 H14C_1 109.5 . . ?
N1_1 C15_1 H15A_1 109.5 . . ?
N1_1 C15_1 H15B_1 109.5 . . ?
N1_1 C15_1 H15C_1 109.5 . . ?
H15A_1 C15_1 H15B_1 109.5 . . ?
H15A_1 C15_1 H15C_1 109.5 . . ?
H15B_1 C15_1 H15C_1 109.5 . . ?
C11_1 C16_1 Cl1_1 123.27(16) . . ?
C17_1 C16_1 Cl1_1 115.34(15) . . ?
C17_1 C16_1 C11_1 121.29(18) . . ?
C16_1 C17_1 H17_1 119.8 . . ?
C18_1 C17_1 C16_1 120.49(19) . . ?
C18_1 C17_1 H17_1 119.8 . . ?
C17_1 C18_1 Cl2_1 120.29(16) . . ?
C17_1 C18_1 C19_1 119.88(19) . . ?
C19_1 C18_1 Cl2_1 119.81(17) . . ?
C12_1 C19_1 H19_1 120.3 . . ?
C18_1 C19_1 C12_1 119.46(19) . . ?
C18_1 C19_1 H19_1 120.3 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Cl1_1 C16_1 C17_1 C18_1 173.27(17) . . . . ?
Cl2_1 C18_1 C19_1 C12_1 -177.38(16) . . . . ?
O1_1 C7_1 C8_1 C9_1 -4.6(3) . . . . ?
N1_1 C11_1 C12_1 C13_1 -11.1(3) . . . . ?
N1_1 C11_1 C12_1 C19_1 172.87(18) . . . . ?
N1_1 C11_1 C16_1 Cl1_1 11.9(3) . . . . ?
N1_1 C11_1 C16_1 C17_1 -171.73(19) . . . . ?
C1_1 C2_1 C3_1 C4_1 0.2(4) . . . . ?
C1_1 C7_1 C8_1 C9_1 175.58(17) . . . . ?
C2_1 C1_1 C6_1 C5_1 0.9(3) . . . . ?
C2_1 C1_1 C7_1 O1_1 -172.1(2) . . . . ?
C2_1 C1_1 C7_1 C8_1 7.8(3) . . . . ?
C2_1 C3_1 C4_1 C5_1 1.1(4) . . . . ?
C3_1 C4_1 C5_1 C6_1 -1.3(4) . . . . ?
C4_1 C5_1 C6_1 C1_1 0.4(4) . . . . ?
C6_1 C1_1 C2_1 C3_1 -1.1(3) . . . . ?
C6_1 C1_1 C7_1 O1_1 6.3(3) . . . . ?
C6_1 C1_1 C7_1 C8_1 -173.86(19) . . . . ?
C7_1 C1_1 C2_1 C3_1 177.3(2) . . . . ?
C7_1 C1_1 C6_1 C5_1 -177.6(2) . . . . ?
C7_1 C8_1 C9_1 C10_1 67.1(2) . . . . ?
C7_1 C8_1 C9_1 C13_1 -58.5(2) . . . . ?
C7_1 C8_1 C9_1 C14_1 -175.95(17) . . . . ?
C8_1 C9_1 C10_1 O2_1 35.0(3) . . . . ?
C8_1 C9_1 C10_1 N1_1 -146.69(18) . . . . ?
C8_1 C9_1 C13_1 O3_1 -35.8(2) . . . . ?
C8_1 C9_1 C13_1 C12_1 151.45(16) . . . . ?
C10_1 N1_1 C11_1 C12_1 17.9(3) . . . . ?
C10_1 N1_1 C11_1 C16_1 -162.33(19) . . . . ?
C10_1 C9_1 C13_1 O3_1 -158.57(19) . . . . ?
C10_1 C9_1 C13_1 C12_1 28.7(2) . . . . ?
C11_1 N1_1 C10_1 O2_1 178.83(19) . . . . ?
C11_1 N1_1 C10_1 C9_1 0.5(3) . . . . ?
C11_1 C12_1 C13_1 O3_1 174.7(2) . . . . ?
C11_1 C12_1 C13_1 C9_1 -12.6(3) . . . . ?
C11_1 C12_1 C19_1 C18_1 1.0(3) . . . . ?
C11_1 C16_1 C17_1 C18_1 -3.4(3) . . . . ?
C12_1 C11_1 C16_1 Cl1_1 -168.27(15) . . . . ?
C12_1 C11_1 C16_1 C17_1 8.1(3) . . . . ?
C13_1 C9_1 C10_1 O2_1 158.31(19) . . . . ?
C13_1 C9_1 C10_1 N1_1 -23.3(3) . . . . ?
C13_1 C12_1 C19_1 C18_1 -175.03(19) . . . . ?
C14_1 C9_1 C10_1 O2_1 -83.5(2) . . . . ?
C14_1 C9_1 C10_1 N1_1 94.8(2) . . . . ?
C14_1 C9_1 C13_1 O3_1 83.3(2) . . . . ?
C14_1 C9_1 C13_1 C12_1 -89.50(19) . . . . ?
C15_1 N1_1 C10_1 O2_1 -14.7(3) . . . . ?
C15_1 N1_1 C10_1 C9_1 166.9(2) . . . . ?
C15_1 N1_1 C11_1 C12_1 -147.7(2) . . . . ?
C15_1 N1_1 C11_1 C16_1 32.1(3) . . . . ?
C16_1 C11_1 C12_1 C13_1 169.04(17) . . . . ?
C16_1 C11_1 C12_1 C19_1 -7.0(3) . . . . ?
C16_1 C17_1 C18_1 Cl2_1 178.52(16) . . . . ?
C16_1 C17_1 C18_1 C19_1 -2.9(3) . . . . ?
C17_1 C18_1 C19_1 C12_1 4.1(3) . . . . ?
C19_1 C12_1 C13_1 O3_1 -9.2(3) . . . . ?
C19_1 C12_1 C13_1 C9_1 163.52(18) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
