# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 2325966'
loop_
_audit_author_name
_audit_author_address
'Kazuhiro Uemura'
;Gifu University
Japan
;
_audit_update_record             
;
2024-01-17 deposited with the CCDC.	2024-07-18 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C60 H88 Cl8 Cu N10 O4 P2 Pt2 Rh2'
_chemical_formula_weight         2018.48

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   12.3638(3)
_cell_length_b                   23.3713(7)
_cell_length_c                   13.5306(4)
_cell_angle_alpha                90
_cell_angle_beta                 108.696(3)
_cell_angle_gamma                90
_cell_volume                     3703.47(19)
_cell_formula_units_Z            2
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    21594
_cell_measurement_theta_min      1.8210
_cell_measurement_theta_max      30.8620

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.810
_exptl_crystal_F_000             1982
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.700
_exptl_crystal_size_mid          0.500
_exptl_crystal_size_min          0.350
_exptl_absorpt_coefficient_mu    4.864
_shelx_estimated_absorpt_T_min   0.132
_shelx_estimated_absorpt_T_max   0.281
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.37861
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.40.53 (Rigaku Oxford Diffraction, 2019)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_oxdiff_exptl_absorpt_empirical_full_min 0.648
_oxdiff_exptl_absorpt_empirical_full_max 1.911
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
- Detector area scaling
;
_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_measurement_device_type  
'dtrek-CrysAlisPro-abstract goniometer imported rigaku-d*trek images'
_diffrn_measurement_method       'profile data from φ-scans'
_diffrn_detector_area_resol_mean 14.7059
_diffrn_reflns_number            28662
_diffrn_reflns_av_unetI/netI     0.0188
_diffrn_reflns_av_R_equivalents  0.0197
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         1.743
_diffrn_reflns_theta_max         27.497
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             8483
_reflns_number_gt                8016
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_cell_refinement       'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_data_reduction        'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_publication_material  
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'

_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1000P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         8483
_refine_ls_number_parameters     412
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0232
_refine_ls_R_factor_gt           0.0211
_refine_ls_wR_factor_ref         0.0923
_refine_ls_wR_factor_gt          0.0898
_refine_ls_goodness_of_fit_ref   0.807
_refine_ls_restrained_S_all      0.807
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.76434(2) 0.43796(2) 0.46242(2) 0.01356(6) Uani 1 1 d . . . . .
Rh1 Rh 0.56395(2) 0.38790(2) 0.34685(2) 0.01039(7) Uani 1 1 d . . . . .
Cu1 Cu 1.000000 0.500000 0.500000 0.02184(13) Uani 1 2 d S . P . .
Cl2 Cl 0.46781(6) 0.42407(4) 0.45572(6) 0.01931(15) Uani 1 1 d . . . . .
Cl1 Cl 0.60789(6) 0.30222(3) 0.44083(6) 0.01997(15) Uani 1 1 d . . . . .
P1 P 0.40405(6) 0.34970(3) 0.23489(5) 0.01073(14) Uani 1 1 d . . . . .
Cl3 Cl 1.03320(8) 0.46539(4) 0.66480(7) 0.0322(2) Uani 1 1 d . . . . .
Cl4 Cl 0.90874(7) 0.57882(4) 0.53998(7) 0.02867(19) Uani 1 1 d . . . . .
O2 O 0.64957(17) 0.36129(10) 0.24895(17) 0.0194(5) Uani 1 1 d . . . . .
O1 O 0.53492(18) 0.46411(10) 0.26672(17) 0.0182(4) Uani 1 1 d . . . . .
N3 N 0.6905(2) 0.50679(12) 0.3818(2) 0.0172(5) Uani 1 1 d . . . . .
H3 H 0.725041 0.539741 0.401760 0.021 Uiso 1 1 calc R U . . .
N1 N 0.8439(2) 0.36876(13) 0.5481(2) 0.0257(6) Uani 1 1 d . . . . .
H1 H 0.818813 0.364127 0.603837 0.039 Uiso 1 1 calc R U . . .
H1A H 0.920754 0.374598 0.570852 0.039 Uiso 1 1 calc R U . . .
H1B H 0.827587 0.336809 0.507524 0.039 Uiso 1 1 calc R U . . .
N4 N 0.8097(2) 0.40943(14) 0.3403(2) 0.0241(6) Uani 1 1 d . . . . .
H4 H 0.879117 0.418614 0.341433 0.029 Uiso 1 1 calc R U . . .
N2 N 0.7305(2) 0.47147(12) 0.5902(2) 0.0180(5) Uani 1 1 d . . . . .
H2 H 0.656573 0.483410 0.571006 0.027 Uiso 1 1 calc R U . . .
H2A H 0.777661 0.501676 0.615521 0.027 Uiso 1 1 calc R U . . .
H2B H 0.742228 0.444137 0.640407 0.027 Uiso 1 1 calc R U . . .
C16 C 0.3788(3) 0.30953(14) 0.0296(2) 0.0181(6) Uani 1 1 d . . . . .
H16 H 0.321468 0.337883 0.004558 0.022 Uiso 1 1 calc R U . . .
C28 C 0.3268(3) 0.43678(12) 0.0856(3) 0.0165(6) Uani 1 1 d . . . . .
H28 H 0.391288 0.428081 0.064660 0.020 Uiso 1 1 calc R U . . .
C6 C 0.7510(2) 0.37954(13) 0.2605(2) 0.0148(6) Uani 1 1 d . . . . .
C4 C 0.4320(3) 0.57542(15) 0.2423(3) 0.0220(6) Uani 1 1 d . . . . .
H4A H 0.398485 0.606803 0.194246 0.033 Uiso 1 1 calc R U . . .
H4B H 0.432481 0.585567 0.312729 0.033 Uiso 1 1 calc R U . . .
H4C H 0.386701 0.540621 0.219373 0.033 Uiso 1 1 calc R U . . .
C11 C 0.4362(2) 0.30531(13) 0.1362(2) 0.0146(6) Uani 1 1 d . . . . .
C7 C 0.7996(2) 0.36136(13) 0.1739(2) 0.0152(6) Uani 1 1 d . . . . .
C25 C 0.1433(2) 0.46687(14) 0.1524(3) 0.0194(6) Uani 1 1 d . . . . .
H25 H 0.082784 0.478178 0.177084 0.023 Uiso 1 1 calc R U . . .
C26 C 0.1601(3) 0.49507(14) 0.0685(3) 0.0212(6) Uani 1 1 d . . . . .
H26 H 0.109297 0.524621 0.033762 0.025 Uiso 1 1 calc R U . . .
C17 C 0.3134(2) 0.30269(12) 0.2815(2) 0.0130(5) Uani 1 1 d . . . . .
C12 C 0.5196(3) 0.26218(14) 0.1723(2) 0.0187(6) Uani 1 1 d . . . . .
H12 H 0.557772 0.258081 0.244982 0.022 Uiso 1 1 calc R U . . .
C9 C 0.7046(3) 0.36698(15) 0.0688(2) 0.0210(6) Uani 1 1 d . . . . .
H9 H 0.644163 0.339200 0.065348 0.031 Uiso 1 1 calc R U . . .
H9A H 0.736030 0.359562 0.012073 0.031 Uiso 1 1 calc R U . . .
H9B H 0.672962 0.405770 0.061707 0.031 Uiso 1 1 calc R U . . .
C23 C 0.3071(2) 0.40628(13) 0.1673(2) 0.0131(5) Uani 1 1 d . . . . .
C24 C 0.2146(2) 0.42218(14) 0.2006(2) 0.0170(6) Uani 1 1 d . . . . .
H24 H 0.200821 0.402163 0.256465 0.020 Uiso 1 1 calc R U . . .
C15 C 0.4045(3) 0.27250(15) -0.0412(2) 0.0226(7) Uani 1 1 d . . . . .
H15 H 0.364439 0.275566 -0.113701 0.027 Uiso 1 1 calc R U . . .
C21 C 0.2346(3) 0.26760(15) 0.4111(2) 0.0229(7) Uani 1 1 d . . . . .
H21 H 0.235159 0.266947 0.481470 0.028 Uiso 1 1 calc R U . . .
C27 C 0.2516(3) 0.47989(15) 0.0352(2) 0.0217(7) Uani 1 1 d . . . . .
H27 H 0.262860 0.499161 -0.022489 0.026 Uiso 1 1 calc R U . . .
C1 C 0.5967(2) 0.50826(13) 0.3026(2) 0.0134(5) Uani 1 1 d . . . . .
C20 C 0.1550(3) 0.23522(15) 0.3378(3) 0.0228(7) Uani 1 1 d . . . . .
H20 H 0.101181 0.212653 0.357209 0.027 Uiso 1 1 calc R U . . .
C10 C 0.8386(3) 0.29837(14) 0.1929(3) 0.0219(6) Uani 1 1 d . . . . .
H10 H 0.775605 0.274959 0.199802 0.033 Uiso 1 1 calc R U . . .
H10A H 0.903821 0.295679 0.257163 0.033 Uiso 1 1 calc R U . . .
H10B H 0.861004 0.284516 0.133970 0.033 Uiso 1 1 calc R U . . .
C18 C 0.2327(3) 0.26935(14) 0.2066(2) 0.0188(6) Uani 1 1 d . . . . .
H18 H 0.231664 0.269673 0.136136 0.023 Uiso 1 1 calc R U . . .
C19 C 0.1546(3) 0.23606(15) 0.2350(3) 0.0211(6) Uani 1 1 d . . . . .
H19 H 0.100582 0.213675 0.183924 0.025 Uiso 1 1 calc R U . . .
C14 C 0.4891(3) 0.23121(15) -0.0047(2) 0.0214(6) Uani 1 1 d . . . . .
H14 H 0.508005 0.206635 -0.052664 0.026 Uiso 1 1 calc R U . . .
C22 C 0.3144(3) 0.30136(14) 0.3846(2) 0.0193(6) Uani 1 1 d . . . . .
H22 H 0.368848 0.323178 0.436510 0.023 Uiso 1 1 calc R U . . .
C2 C 0.5551(3) 0.56484(12) 0.2433(3) 0.0161(6) Uani 1 1 d . . . . .
C13 C 0.5464(3) 0.22581(14) 0.1027(3) 0.0211(6) Uani 1 1 d . . . . .
H13 H 0.603434 0.197291 0.127554 0.025 Uiso 1 1 calc R U . . .
C5 C 0.5594(3) 0.55670(15) 0.1323(3) 0.0254(7) Uani 1 1 d . . . . .
H5 H 0.509116 0.525030 0.098670 0.038 Uiso 1 1 calc R U . . .
H5A H 0.637852 0.547979 0.135121 0.038 Uiso 1 1 calc R U . . .
H5B H 0.533995 0.591887 0.092207 0.038 Uiso 1 1 calc R U . . .
C8 C 0.9016(3) 0.39887(17) 0.1734(3) 0.0251(7) Uani 1 1 d . . . . .
H8 H 0.930220 0.386336 0.117215 0.038 Uiso 1 1 calc R U . . .
H8A H 0.962415 0.395271 0.240550 0.038 Uiso 1 1 calc R U . . .
H8B H 0.877217 0.438905 0.162018 0.038 Uiso 1 1 calc R U . . .
N5 N 0.8474(3) 0.38026(17) 0.7813(3) 0.0418(9) Uani 1 1 d . . . . .
C29 C 0.9296(4) 0.36721(18) 0.8399(3) 0.0380(9) Uani 1 1 d . . . . .
C3 C 0.6309(3) 0.61576(15) 0.2943(3) 0.0276(8) Uani 1 1 d . . . . .
H3A H 0.607047 0.649745 0.250268 0.041 Uiso 1 1 calc R U . . .
H3B H 0.710720 0.606899 0.302079 0.041 Uiso 1 1 calc R U . . .
H3C H 0.623474 0.623135 0.363127 0.041 Uiso 1 1 calc R U . . .
C30 C 1.0396(6) 0.3526(3) 0.9155(5) 0.100(3) Uani 1 1 d . . . . .
H30 H 1.092080 0.340293 0.878557 0.149 Uiso 1 1 calc R U . . .
H30A H 1.029608 0.321511 0.960322 0.149 Uiso 1 1 calc R U . . .
H30B H 1.071246 0.386209 0.958325 0.149 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N3 1.993(3) . ?
Pt1 N4 2.021(3) . ?
Pt1 N1 2.048(3) . ?
Pt1 N2 2.059(3) . ?
Pt1 Rh1 2.7328(2) . ?
Pt1 Cu1 3.14655(12) . ?
Rh1 O2 2.040(2) . ?
Rh1 O1 2.056(2) . ?
Rh1 P1 2.2541(7) . ?
Rh1 Cl2 2.3280(8) . ?
Rh1 Cl1 2.3407(7) . ?
Cu1 Cl3 2.2822(10) . ?
Cu1 Cl3 2.2822(10) 3_766 ?
Cu1 Cl4 2.3132(9) . ?
Cu1 Cl4 2.3132(9) 3_766 ?
P1 C17 1.820(3) . ?
P1 C23 1.822(3) . ?
P1 C11 1.832(3) . ?
O2 C6 1.285(3) . ?
O1 C1 1.283(4) . ?
N3 C1 1.303(4) . ?
N3 H3 0.8800 . ?
N1 H1 0.9100 . ?
N1 H1A 0.9100 . ?
N1 H1B 0.9100 . ?
N4 C6 1.295(4) . ?
N4 H4 0.8800 . ?
N2 H2 0.9100 . ?
N2 H2A 0.9100 . ?
N2 H2B 0.9100 . ?
C16 C11 1.391(4) . ?
C16 C15 1.401(4) . ?
C16 H16 0.9500 . ?
C28 C27 1.392(4) . ?
C28 C23 1.400(4) . ?
C28 H28 0.9500 . ?
C6 C7 1.539(4) . ?
C4 C2 1.537(4) . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C11 C12 1.413(4) . ?
C7 C9 1.532(4) . ?
C7 C8 1.538(4) . ?
C7 C10 1.545(4) . ?
C25 C26 1.385(5) . ?
C25 C24 1.387(5) . ?
C25 H25 0.9500 . ?
C26 C27 1.390(5) . ?
C26 H26 0.9500 . ?
C17 C22 1.391(4) . ?
C17 C18 1.408(4) . ?
C12 C13 1.385(5) . ?
C12 H12 0.9500 . ?
C9 H9 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C23 C24 1.407(4) . ?
C24 H24 0.9500 . ?
C15 C14 1.391(5) . ?
C15 H15 0.9500 . ?
C21 C20 1.378(5) . ?
C21 C22 1.397(4) . ?
C21 H21 0.9500 . ?
C27 H27 0.9500 . ?
C1 C2 1.547(4) . ?
C20 C19 1.388(5) . ?
C20 H20 0.9500 . ?
C10 H10 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C18 C19 1.386(4) . ?
C18 H18 0.9500 . ?
C19 H19 0.9500 . ?
C14 C13 1.403(5) . ?
C14 H14 0.9500 . ?
C22 H22 0.9500 . ?
C2 C5 1.531(5) . ?
C2 C3 1.535(4) . ?
C13 H13 0.9500 . ?
C5 H5 0.9800 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C8 H8 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
N5 C29 1.113(5) . ?
C29 C30 1.456(6) . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C30 H30 0.9800 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Pt1 N4 90.97(12) . . ?
N3 Pt1 N1 178.30(10) . . ?
N4 Pt1 N1 89.61(13) . . ?
N3 Pt1 N2 88.39(11) . . ?
N4 Pt1 N2 175.04(11) . . ?
N1 Pt1 N2 90.89(11) . . ?
N3 Pt1 Rh1 81.96(7) . . ?
N4 Pt1 Rh1 80.17(7) . . ?
N1 Pt1 Rh1 99.72(8) . . ?
N2 Pt1 Rh1 104.60(7) . . ?
N3 Pt1 Cu1 87.38(7) . . ?
N4 Pt1 Cu1 78.40(8) . . ?
N1 Pt1 Cu1 91.17(9) . . ?
N2 Pt1 Cu1 96.66(7) . . ?
Rh1 Pt1 Cu1 155.845(6) . . ?
O2 Rh1 O1 87.76(10) . . ?
O2 Rh1 P1 88.20(6) . . ?
O1 Rh1 P1 91.23(6) . . ?
O2 Rh1 Cl2 176.46(7) . . ?
O1 Rh1 Cl2 88.90(7) . . ?
P1 Rh1 Cl2 93.06(3) . . ?
O2 Rh1 Cl1 90.78(7) . . ?
O1 Rh1 Cl1 176.81(6) . . ?
P1 Rh1 Cl1 91.55(3) . . ?
Cl2 Rh1 Cl1 92.50(3) . . ?
O2 Rh1 Pt1 86.45(6) . . ?
O1 Rh1 Pt1 84.48(6) . . ?
P1 Rh1 Pt1 173.27(2) . . ?
Cl2 Rh1 Pt1 92.04(2) . . ?
Cl1 Rh1 Pt1 92.600(19) . . ?
Cl3 Cu1 Cl3 180.00(5) . 3_766 ?
Cl3 Cu1 Cl4 90.13(4) . . ?
Cl3 Cu1 Cl4 89.87(4) 3_766 . ?
Cl3 Cu1 Cl4 89.87(4) . 3_766 ?
Cl3 Cu1 Cl4 90.13(4) 3_766 3_766 ?
Cl4 Cu1 Cl4 180.00(3) . 3_766 ?
Cl3 Cu1 Pt1 97.94(2) . 3_766 ?
Cl3 Cu1 Pt1 82.06(2) 3_766 3_766 ?
Cl4 Cu1 Pt1 95.22(2) . 3_766 ?
Cl4 Cu1 Pt1 84.78(2) 3_766 3_766 ?
Cl3 Cu1 Pt1 82.06(2) . . ?
Cl3 Cu1 Pt1 97.94(2) 3_766 . ?
Cl4 Cu1 Pt1 84.78(2) . . ?
Cl4 Cu1 Pt1 95.22(2) 3_766 . ?
Pt1 Cu1 Pt1 180.0 3_766 . ?
C17 P1 C23 103.48(13) . . ?
C17 P1 C11 102.26(14) . . ?
C23 P1 C11 107.85(13) . . ?
C17 P1 Rh1 120.71(9) . . ?
C23 P1 Rh1 110.12(9) . . ?
C11 P1 Rh1 111.46(9) . . ?
C6 O2 Rh1 120.56(19) . . ?
C1 O1 Rh1 120.99(19) . . ?
C1 N3 Pt1 127.0(2) . . ?
C1 N3 H3 116.5 . . ?
Pt1 N3 H3 116.5 . . ?
Pt1 N1 H1 109.5 . . ?
Pt1 N1 H1A 109.5 . . ?
H1 N1 H1A 109.5 . . ?
Pt1 N1 H1B 109.5 . . ?
H1 N1 H1B 109.5 . . ?
H1A N1 H1B 109.5 . . ?
C6 N4 Pt1 129.1(2) . . ?
C6 N4 H4 115.4 . . ?
Pt1 N4 H4 115.4 . . ?
Pt1 N2 H2 109.5 . . ?
Pt1 N2 H2A 109.5 . . ?
H2 N2 H2A 109.5 . . ?
Pt1 N2 H2B 109.5 . . ?
H2 N2 H2B 109.5 . . ?
H2A N2 H2B 109.5 . . ?
C11 C16 C15 120.8(3) . . ?
C11 C16 H16 119.6 . . ?
C15 C16 H16 119.6 . . ?
C27 C28 C23 119.8(3) . . ?
C27 C28 H28 120.1 . . ?
C23 C28 H28 120.1 . . ?
O2 C6 N4 123.0(3) . . ?
O2 C6 C7 114.8(3) . . ?
N4 C6 C7 122.1(3) . . ?
C2 C4 H4A 109.5 . . ?
C2 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
C2 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C16 C11 C12 118.8(3) . . ?
C16 C11 P1 123.9(2) . . ?
C12 C11 P1 117.2(2) . . ?
C9 C7 C8 109.4(3) . . ?
C9 C7 C6 108.2(2) . . ?
C8 C7 C6 111.5(3) . . ?
C9 C7 C10 110.0(3) . . ?
C8 C7 C10 109.4(3) . . ?
C6 C7 C10 108.2(2) . . ?
C26 C25 C24 120.3(3) . . ?
C26 C25 H25 119.8 . . ?
C24 C25 H25 119.8 . . ?
C25 C26 C27 119.6(3) . . ?
C25 C26 H26 120.2 . . ?
C27 C26 H26 120.2 . . ?
C22 C17 C18 119.1(3) . . ?
C22 C17 P1 123.5(2) . . ?
C18 C17 P1 117.2(2) . . ?
C13 C12 C11 120.7(3) . . ?
C13 C12 H12 119.7 . . ?
C11 C12 H12 119.7 . . ?
C7 C9 H9 109.5 . . ?
C7 C9 H9A 109.5 . . ?
H9 C9 H9A 109.5 . . ?
C7 C9 H9B 109.5 . . ?
H9 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C28 C23 C24 118.9(3) . . ?
C28 C23 P1 120.8(2) . . ?
C24 C23 P1 120.2(2) . . ?
C25 C24 C23 120.5(3) . . ?
C25 C24 H24 119.7 . . ?
C23 C24 H24 119.7 . . ?
C14 C15 C16 119.7(3) . . ?
C14 C15 H15 120.1 . . ?
C16 C15 H15 120.1 . . ?
C20 C21 C22 121.7(3) . . ?
C20 C21 H21 119.1 . . ?
C22 C21 H21 119.1 . . ?
C26 C27 C28 120.8(3) . . ?
C26 C27 H27 119.6 . . ?
C28 C27 H27 119.6 . . ?
O1 C1 N3 123.7(3) . . ?
O1 C1 C2 115.6(2) . . ?
N3 C1 C2 120.6(3) . . ?
C21 C20 C19 119.0(3) . . ?
C21 C20 H20 120.5 . . ?
C19 C20 H20 120.5 . . ?
C7 C10 H10 109.5 . . ?
C7 C10 H10A 109.5 . . ?
H10 C10 H10A 109.5 . . ?
C7 C10 H10B 109.5 . . ?
H10 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C19 C18 C17 120.5(3) . . ?
C19 C18 H18 119.8 . . ?
C17 C18 H18 119.8 . . ?
C18 C19 C20 120.4(3) . . ?
C18 C19 H19 119.8 . . ?
C20 C19 H19 119.8 . . ?
C15 C14 C13 120.1(3) . . ?
C15 C14 H14 119.9 . . ?
C13 C14 H14 119.9 . . ?
C17 C22 C21 119.3(3) . . ?
C17 C22 H22 120.3 . . ?
C21 C22 H22 120.3 . . ?
C5 C2 C3 109.2(3) . . ?
C5 C2 C4 110.9(3) . . ?
C3 C2 C4 109.9(3) . . ?
C5 C2 C1 107.0(3) . . ?
C3 C2 C1 112.1(3) . . ?
C4 C2 C1 107.8(3) . . ?
C12 C13 C14 119.8(3) . . ?
C12 C13 H13 120.1 . . ?
C14 C13 H13 120.1 . . ?
C2 C5 H5 109.5 . . ?
C2 C5 H5A 109.5 . . ?
H5 C5 H5A 109.5 . . ?
C2 C5 H5B 109.5 . . ?
H5 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C7 C8 H8 109.5 . . ?
C7 C8 H8A 109.5 . . ?
H8 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
N5 C29 C30 177.2(6) . . ?
C2 C3 H3A 109.5 . . ?
C2 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
C2 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C29 C30 H30 109.5 . . ?
C29 C30 H30A 109.5 . . ?
H30 C30 H30A 109.5 . . ?
C29 C30 H30B 109.5 . . ?
H30 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 O2 C6 N4 8.7(4) . . . . ?
Rh1 O2 C6 C7 -173.33(19) . . . . ?
Pt1 N4 C6 O2 -2.2(5) . . . . ?
Pt1 N4 C6 C7 -180.0(2) . . . . ?
C15 C16 C11 C12 -1.2(5) . . . . ?
C15 C16 C11 P1 -177.2(2) . . . . ?
C17 P1 C11 C16 98.4(3) . . . . ?
C23 P1 C11 C16 -10.3(3) . . . . ?
Rh1 P1 C11 C16 -131.3(2) . . . . ?
C17 P1 C11 C12 -77.7(2) . . . . ?
C23 P1 C11 C12 173.6(2) . . . . ?
Rh1 P1 C11 C12 52.6(2) . . . . ?
O2 C6 C7 C9 41.7(4) . . . . ?
N4 C6 C7 C9 -140.3(3) . . . . ?
O2 C6 C7 C8 162.2(3) . . . . ?
N4 C6 C7 C8 -19.8(4) . . . . ?
O2 C6 C7 C10 -77.4(3) . . . . ?
N4 C6 C7 C10 100.5(4) . . . . ?
C24 C25 C26 C27 -2.6(5) . . . . ?
C23 P1 C17 C22 -103.1(3) . . . . ?
C11 P1 C17 C22 144.9(3) . . . . ?
Rh1 P1 C17 C22 20.5(3) . . . . ?
C23 P1 C17 C18 72.0(3) . . . . ?
C11 P1 C17 C18 -40.0(3) . . . . ?
Rh1 P1 C17 C18 -164.3(2) . . . . ?
C16 C11 C12 C13 1.9(4) . . . . ?
P1 C11 C12 C13 178.2(2) . . . . ?
C27 C28 C23 C24 -3.5(4) . . . . ?
C27 C28 C23 P1 -179.9(2) . . . . ?
C17 P1 C23 C28 -152.9(2) . . . . ?
C11 P1 C23 C28 -45.1(3) . . . . ?
Rh1 P1 C23 C28 76.8(2) . . . . ?
C17 P1 C23 C24 30.7(3) . . . . ?
C11 P1 C23 C24 138.6(2) . . . . ?
Rh1 P1 C23 C24 -99.6(2) . . . . ?
C26 C25 C24 C23 2.3(5) . . . . ?
C28 C23 C24 C25 0.8(4) . . . . ?
P1 C23 C24 C25 177.2(2) . . . . ?
C11 C16 C15 C14 -0.5(5) . . . . ?
C25 C26 C27 C28 -0.2(5) . . . . ?
C23 C28 C27 C26 3.3(5) . . . . ?
Rh1 O1 C1 N3 10.5(4) . . . . ?
Rh1 O1 C1 C2 -171.4(2) . . . . ?
Pt1 N3 C1 O1 2.3(4) . . . . ?
Pt1 N3 C1 C2 -175.6(2) . . . . ?
C22 C21 C20 C19 0.3(5) . . . . ?
C22 C17 C18 C19 0.6(5) . . . . ?
P1 C17 C18 C19 -174.8(3) . . . . ?
C17 C18 C19 C20 0.1(5) . . . . ?
C21 C20 C19 C18 -0.5(5) . . . . ?
C16 C15 C14 C13 1.5(5) . . . . ?
C18 C17 C22 C21 -0.8(5) . . . . ?
P1 C17 C22 C21 174.3(2) . . . . ?
C20 C21 C22 C17 0.4(5) . . . . ?
O1 C1 C2 C5 -62.8(3) . . . . ?
N3 C1 C2 C5 115.3(3) . . . . ?
O1 C1 C2 C3 177.6(3) . . . . ?
N3 C1 C2 C3 -4.4(4) . . . . ?
O1 C1 C2 C4 56.6(3) . . . . ?
N3 C1 C2 C4 -125.4(3) . . . . ?
C11 C12 C13 C14 -0.9(5) . . . . ?
C15 C14 C13 C12 -0.8(5) . . . . ?

_refine_diff_density_max         0.574
_refine_diff_density_min         -1.771
_refine_diff_density_rms         0.189



