# Supplementary Information (SI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_database_code_depnum_ccdc_archive 'CCDC 2357649'
loop_
_audit_author_name
_audit_author_address
'Konstantin Lyssenko'
;Chemical Department MSU
Russia
;
_audit_update_record             
;
2024-05-23 deposited with the CCDC.	2024-08-06 downloaded from the CCDC.
;
_audit_creation_date             2023-09-05
_audit_creation_method           
;
Olex2 1.5
(compiled 2023.03.06 svn.rbb2c1857 for OlexSys, GUI svn.r6748)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C32 H28 Eu F2 N7 O11, C2 H3 N'
_chemical_formula_sum            'C34 H31 Eu F2 N8 O11'
_chemical_formula_weight         917.63
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   18.3692(5)
_cell_length_b                   17.0513(4)
_cell_length_c                   23.5281(8)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     7369.4(4)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    9835
_cell_measurement_temperature    107.00
_cell_measurement_theta_max      30.23
_cell_measurement_theta_min      2.38
_shelx_estimated_absorpt_T_max   0.788
_shelx_estimated_absorpt_T_min   0.593
_exptl_absorpt_coefficient_mu    1.783
_exptl_absorpt_correction_T_max  0.6478
_exptl_absorpt_correction_T_min  0.5095
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1325 before and 0.0734 after correction.
The Ratio of minimum to maximum transmission is 0.7865.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.654
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             3680
_exptl_crystal_size_max          0.327
_exptl_crystal_size_mid          0.284
_exptl_crystal_size_min          0.14
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0836
_diffrn_reflns_av_unetI/netI     0.0489
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            70545
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.997
_diffrn_reflns_theta_min         1.731
_diffrn_ambient_temperature      107.00
_diffrn_detector                 'Photon III detector'
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 Quest with Photon III detector'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_type              'Incoatec I\ms'
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                7993
_reflns_number_total             9788
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         1.254
_refine_diff_density_min         -0.502
_refine_diff_density_rms         0.111
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     510
_refine_ls_number_reflns         9788
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0438
_refine_ls_R_factor_gt           0.0334
_refine_ls_restrained_S_all      1.028
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0191P)²+12.4834P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0726
_refine_ls_wR_factor_ref         0.0796
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C24(H24A,H24B), C34(H34A,H34B)
2.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C6(H6), C7(H7), C10(H10), C18(H18), C19(H19), C21(H21), C22(H22),
 C29(H29), C30(H30), C32(H32), C33(H33)
2.c Idealised Me refined as rotating group:
 C01H(H01A,H01B,H01C), C23(H23A,H23B,H23C), C25(H25A,H25B,H25C), C35(H35A,H35B,
 H35C), C2S(H2SA,H2SB,H2SC)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.56735(2) 0.41079(2) 0.29002(2) 0.01172(4) Uani 1 1 d . . . . .
F1 F 0.29070(9) 0.50285(12) 0.46375(8) 0.0259(4) Uani 1 1 d . . . . .
F2 F 0.59976(10) 0.30544(11) 0.56194(7) 0.0261(4) Uani 1 1 d . . . . .
O1N O 0.66787(12) 0.39749(13) 0.21768(9) 0.0214(5) Uani 1 1 d . . . . .
O2N O 0.59345(11) 0.49358(13) 0.20535(9) 0.0209(4) Uani 1 1 d . . . . .
O3N O 0.67517(12) 0.46752(15) 0.14074(9) 0.0271(5) Uani 1 1 d . . . . .
O004 O 0.65477(10) 0.31033(11) 0.31673(8) 0.0148(4) Uani 1 1 d . . . . .
O4N O 0.48665(11) 0.29655(12) 0.30509(9) 0.0198(4) Uani 1 1 d . . . . .
O5N O 0.53211(11) 0.31028(12) 0.22087(9) 0.0191(4) Uani 1 1 d . . . . .
O6N O 0.46377(12) 0.20916(13) 0.23977(11) 0.0288(5) Uani 1 1 d . . . . .
O7N O 0.68039(11) 0.47631(12) 0.32696(9) 0.0177(4) Uani 1 1 d . . . . .
O8N O 0.58227(11) 0.54426(12) 0.33684(9) 0.0208(4) Uani 1 1 d . . . . .
O009 O 0.45726(10) 0.46414(12) 0.25018(8) 0.0155(4) Uani 1 1 d . . . . .
O9N O 0.68392(12) 0.58751(13) 0.37249(10) 0.0248(5) Uani 1 1 d . . . . .
N1 N 0.46113(12) 0.45102(13) 0.35903(10) 0.0129(4) Uani 1 1 d . . . . .
N1N N 0.64663(13) 0.45326(15) 0.18640(10) 0.0171(5) Uani 1 1 d . . . . .
N2N N 0.49299(13) 0.26968(14) 0.25472(11) 0.0188(5) Uani 1 1 d . . . . .
N3N N 0.64965(13) 0.53793(14) 0.34607(10) 0.0175(5) Uani 1 1 d . . . . .
N12 N 0.57948(12) 0.37535(13) 0.39664(10) 0.0128(4) Uani 1 1 d . . . . .
N16 N 0.36306(12) 0.54875(14) 0.24770(10) 0.0140(5) Uani 1 1 d . . . . .
N27 N 0.75583(12) 0.29674(14) 0.37046(10) 0.0151(5) Uani 1 1 d . . . . .
C01H C 0.92031(18) 0.3849(2) 0.56738(14) 0.0297(8) Uani 1 1 d . . . . .
H01A H 0.937568 0.337431 0.586605 0.044 Uiso 1 1 calc R U . . .
H01B H 0.889234 0.414970 0.593294 0.044 Uiso 1 1 calc R U . . .
H01C H 0.962121 0.417012 0.556064 0.044 Uiso 1 1 calc R U . . .
C2 C 0.40271(15) 0.48817(16) 0.33896(12) 0.0140(5) Uani 1 1 d . . . . .
C3 C 0.34256(15) 0.50633(16) 0.37347(12) 0.0158(5) Uani 1 1 d . . . . .
H3 H 0.300709 0.531613 0.358409 0.019 Uiso 1 1 calc R U . . .
C4 C 0.34676(15) 0.48620(17) 0.42935(13) 0.0182(6) Uani 1 1 d . . . . .
C5 C 0.40732(15) 0.44938(16) 0.45313(12) 0.0143(5) Uani 1 1 d . . . . .
C6 C 0.41389(16) 0.42840(17) 0.51183(12) 0.0167(6) Uani 1 1 d . . . . .
H6 H 0.375719 0.441097 0.537467 0.020 Uiso 1 1 calc R U . . .
C7 C 0.47358(16) 0.39084(17) 0.53122(12) 0.0171(6) Uani 1 1 d . . . . .
H7 H 0.477371 0.377670 0.570342 0.021 Uiso 1 1 calc R U . . .
C8 C 0.53139(15) 0.37074(16) 0.49278(12) 0.0147(5) Uani 1 1 d . . . . .
C9 C 0.59364(16) 0.32858(17) 0.50771(12) 0.0175(6) Uani 1 1 d . . . . .
C10 C 0.64657(16) 0.30971(17) 0.46971(12) 0.0179(6) Uani 1 1 d . . . . .
H10 H 0.688078 0.280171 0.480750 0.022 Uiso 1 1 calc R U . . .
C11 C 0.63751(15) 0.33552(16) 0.41372(12) 0.0145(5) Uani 1 1 d . . . . .
C13 C 0.52694(15) 0.39234(16) 0.43491(12) 0.0138(5) Uani 1 1 d . . . . .
C14 C 0.46373(15) 0.43256(15) 0.41431(11) 0.0125(5) Uani 1 1 d . . . . .
C15 C 0.40882(15) 0.50209(16) 0.27559(12) 0.0147(5) Uani 1 1 d . . . . .
C17 C 0.32039(15) 0.60845(16) 0.27550(12) 0.0147(5) Uani 1 1 d . . . . .
C18 C 0.35558(16) 0.66869(17) 0.30375(12) 0.0165(6) Uani 1 1 d . . . . .
H18 H 0.407234 0.671313 0.304144 0.020 Uiso 1 1 calc R U . . .
C19 C 0.31458(16) 0.72508(17) 0.33141(12) 0.0169(6) Uani 1 1 d . . . . .
H19 H 0.338528 0.766993 0.350335 0.020 Uiso 1 1 calc R U . . .
C20 C 0.23877(16) 0.72148(17) 0.33201(12) 0.0179(6) Uani 1 1 d . . . . .
C21 C 0.20463(15) 0.66092(17) 0.30272(12) 0.0171(6) Uani 1 1 d . . . . .
H21 H 0.152980 0.658174 0.302263 0.021 Uiso 1 1 calc R U . . .
C22 C 0.24482(15) 0.60453(17) 0.27421(12) 0.0159(5) Uani 1 1 d . . . . .
H22 H 0.221007 0.563665 0.254014 0.019 Uiso 1 1 calc R U . . .
C23 C 0.19614(18) 0.78372(19) 0.36310(14) 0.0256(7) Uani 1 1 d . . . . .
H23A H 0.144518 0.779466 0.353054 0.038 Uiso 1 1 calc R U . . .
H23B H 0.214289 0.835662 0.352288 0.038 Uiso 1 1 calc R U . . .
H23C H 0.201918 0.776461 0.404176 0.038 Uiso 1 1 calc R U . . .
C24 C 0.36692(16) 0.55194(17) 0.18477(12) 0.0170(6) Uani 1 1 d . . . . .
H24A H 0.317705 0.562217 0.169314 0.020 Uiso 1 1 calc R U . . .
H24B H 0.383369 0.500482 0.170123 0.020 Uiso 1 1 calc R U . . .
C25 C 0.41885(18) 0.6155(2) 0.16425(14) 0.0261(7) Uani 1 1 d . . . . .
H25A H 0.417536 0.618140 0.122650 0.039 Uiso 1 1 calc R U . . .
H25B H 0.468418 0.603180 0.176786 0.039 Uiso 1 1 calc R U . . .
H25C H 0.404030 0.666238 0.180097 0.039 Uiso 1 1 calc R U . . .
C26 C 0.68535(15) 0.31371(16) 0.36397(12) 0.0145(5) Uani 1 1 d . . . . .
C28 C 0.79718(15) 0.31938(17) 0.41960(12) 0.0161(5) Uani 1 1 d . . . . .
C29 C 0.79967(15) 0.39710(17) 0.43634(13) 0.0185(6) Uani 1 1 d . . . . .
H29 H 0.774255 0.435924 0.415250 0.022 Uiso 1 1 calc R U . . .
C30 C 0.83942(16) 0.41804(19) 0.48404(14) 0.0225(6) Uani 1 1 d . . . . .
H30 H 0.840875 0.471402 0.495587 0.027 Uiso 1 1 calc R U . . .
C31 C 0.87707(16) 0.3622(2) 0.51512(13) 0.0223(6) Uani 1 1 d . . . . .
C32 C 0.87545(16) 0.28472(19) 0.49687(13) 0.0231(7) Uani 1 1 d . . . . .
H32 H 0.902011 0.246134 0.517314 0.028 Uiso 1 1 calc R U . . .
C33 C 0.83561(16) 0.26265(18) 0.44918(13) 0.0195(6) Uani 1 1 d . . . . .
H33 H 0.834776 0.209491 0.437101 0.023 Uiso 1 1 calc R U . . .
C34 C 0.79637(16) 0.26982(17) 0.32009(12) 0.0171(6) Uani 1 1 d . . . . .
H34A H 0.763024 0.241039 0.294448 0.021 Uiso 1 1 calc R U . . .
H34B H 0.835331 0.233285 0.332097 0.021 Uiso 1 1 calc R U . . .
C35 C 0.82980(17) 0.33826(18) 0.28836(13) 0.0211(6) Uani 1 1 d . . . . .
H35A H 0.852495 0.319277 0.253259 0.032 Uiso 1 1 calc R U . . .
H35B H 0.866764 0.363307 0.312286 0.032 Uiso 1 1 calc R U . . .
H35C H 0.791771 0.376439 0.279001 0.032 Uiso 1 1 calc R U . . .
N1S N 0.5956(3) 0.3751(3) 0.00689(19) 0.0640(12) Uani 1 1 d . . . . .
C1S C 0.5599(3) 0.3819(3) 0.04629(19) 0.0446(10) Uani 1 1 d . . . . .
C2S C 0.5144(2) 0.3905(3) 0.09601(18) 0.0482(11) Uani 1 1 d . . . . .
H2SA H 0.463131 0.390960 0.084521 0.072 Uiso 1 1 calc R U . . .
H2SB H 0.526194 0.439937 0.115221 0.072 Uiso 1 1 calc R U . . .
H2SC H 0.523054 0.346612 0.122000 0.072 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1N 2.521(2) . ?
Eu1 O2N 2.488(2) . ?
Eu1 O004 2.4306(19) . ?
Eu1 O4N 2.474(2) . ?
Eu1 O5N 2.450(2) . ?
Eu1 O7N 2.513(2) . ?
Eu1 O8N 2.543(2) . ?
Eu1 O009 2.4074(19) . ?
Eu1 N1 2.630(2) . ?
Eu1 N1N 2.931(2) . ?
Eu1 N2N 2.889(2) . ?
Eu1 N12 2.590(2) . ?
F1 C4 1.340(3) . ?
F2 C9 1.340(3) . ?
O1N N1N 1.264(3) . ?
O2N N1N 1.275(3) . ?
O3N N1N 1.220(3) . ?
O004 C26 1.247(3) . ?
O4N N2N 1.276(3) . ?
O5N N2N 1.277(3) . ?
O6N N2N 1.215(3) . ?
O7N N3N 1.275(3) . ?
O8N N3N 1.261(3) . ?
O009 C15 1.252(3) . ?
O9N N3N 1.224(3) . ?
N1 C2 1.333(3) . ?
N1 C14 1.339(3) . ?
N12 C11 1.326(3) . ?
N12 C13 1.351(3) . ?
N16 C15 1.331(4) . ?
N16 C17 1.442(3) . ?
N16 C24 1.483(4) . ?
N27 C26 1.335(4) . ?
N27 C28 1.436(4) . ?
N27 C34 1.473(4) . ?
C01H H01A 0.9800 . ?
C01H H01B 0.9800 . ?
C01H H01C 0.9800 . ?
C01H C31 1.514(4) . ?
C2 C3 1.406(4) . ?
C2 C15 1.514(4) . ?
C3 H3 0.9500 . ?
C3 C4 1.361(4) . ?
C4 C5 1.394(4) . ?
C5 C6 1.432(4) . ?
C5 C14 1.411(4) . ?
C6 H6 0.9500 . ?
C6 C7 1.349(4) . ?
C7 H7 0.9500 . ?
C7 C8 1.436(4) . ?
C8 C9 1.396(4) . ?
C8 C13 1.413(4) . ?
C9 C10 1.359(4) . ?
C10 H10 0.9500 . ?
C10 C11 1.399(4) . ?
C11 C26 1.510(4) . ?
C13 C14 1.433(4) . ?
C17 C18 1.384(4) . ?
C17 C22 1.390(4) . ?
C18 H18 0.9500 . ?
C18 C19 1.384(4) . ?
C19 H19 0.9500 . ?
C19 C20 1.394(4) . ?
C20 C21 1.391(4) . ?
C20 C23 1.508(4) . ?
C21 H21 0.9500 . ?
C21 C22 1.385(4) . ?
C22 H22 0.9500 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
C24 C25 1.523(4) . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C28 C29 1.383(4) . ?
C28 C33 1.385(4) . ?
C29 H29 0.9500 . ?
C29 C30 1.386(4) . ?
C30 H30 0.9500 . ?
C30 C31 1.385(5) . ?
C31 C32 1.390(4) . ?
C32 H32 0.9500 . ?
C32 C33 1.391(4) . ?
C33 H33 0.9500 . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
C34 C35 1.515(4) . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
N1S C1S 1.141(6) . ?
C1S C2S 1.445(6) . ?
C2S H2SA 0.9800 . ?
C2S H2SB 0.9800 . ?
C2S H2SC 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1N Eu1 O8N 107.10(7) . . ?
O1N Eu1 N1 169.64(7) . . ?
O1N Eu1 N1N 25.42(7) . . ?
O1N Eu1 N2N 94.43(7) . . ?
O1N Eu1 N12 124.74(7) . . ?
O2N Eu1 O1N 50.92(7) . . ?
O2N Eu1 O7N 82.28(7) . . ?
O2N Eu1 O8N 79.54(7) . . ?
O2N Eu1 N1 119.30(7) . . ?
O2N Eu1 N1N 25.58(7) . . ?
O2N Eu1 N2N 109.48(7) . . ?
O2N Eu1 N12 153.04(7) . . ?
O004 Eu1 O1N 68.12(7) . . ?
O004 Eu1 O2N 118.66(7) . . ?
O004 Eu1 O4N 78.69(7) . . ?
O004 Eu1 O5N 81.57(7) . . ?
O004 Eu1 O7N 71.21(6) . . ?
O004 Eu1 O8N 116.58(7) . . ?
O004 Eu1 N1 120.95(7) . . ?
O004 Eu1 N1N 93.50(7) . . ?
O004 Eu1 N2N 78.45(7) . . ?
O004 Eu1 N12 61.85(7) . . ?
O4N Eu1 O1N 117.70(7) . . ?
O4N Eu1 O2N 132.62(7) . . ?
O4N Eu1 O7N 142.72(7) . . ?
O4N Eu1 O8N 135.00(7) . . ?
O4N Eu1 N1 70.86(7) . . ?
O4N Eu1 N1N 127.71(7) . . ?
O4N Eu1 N2N 26.08(7) . . ?
O4N Eu1 N12 74.27(7) . . ?
O5N Eu1 O1N 71.48(7) . . ?
O5N Eu1 O2N 85.19(7) . . ?
O5N Eu1 O4N 52.12(7) . . ?
O5N Eu1 O7N 139.38(7) . . ?
O5N Eu1 O8N 160.40(7) . . ?
O5N Eu1 N1 113.36(7) . . ?
O5N Eu1 N1N 75.63(7) . . ?
O5N Eu1 N2N 26.05(7) . . ?
O5N Eu1 N12 120.18(7) . . ?
O7N Eu1 O1N 70.63(7) . . ?
O7N Eu1 O8N 50.46(6) . . ?
O7N Eu1 N1 106.47(7) . . ?
O7N Eu1 N1N 76.55(7) . . ?
O7N Eu1 N2N 149.36(7) . . ?
O7N Eu1 N12 72.40(7) . . ?
O8N Eu1 N1 65.10(7) . . ?
O8N Eu1 N1N 94.92(7) . . ?
O8N Eu1 N2N 157.04(7) . . ?
O8N Eu1 N12 77.29(7) . . ?
O009 Eu1 O1N 112.73(7) . . ?
O009 Eu1 O2N 68.64(7) . . ?
O009 Eu1 O004 157.21(7) . . ?
O009 Eu1 O4N 81.37(7) . . ?
O009 Eu1 O5N 77.51(7) . . ?
O009 Eu1 O7N 131.36(7) . . ?
O009 Eu1 O8N 85.47(7) . . ?
O009 Eu1 N1 61.22(7) . . ?
O009 Eu1 N1N 90.01(7) . . ?
O009 Eu1 N2N 78.79(7) . . ?
O009 Eu1 N12 122.51(7) . . ?
N1 Eu1 N1N 144.88(7) . . ?
N1 Eu1 N2N 92.52(7) . . ?
N2N Eu1 N1N 101.63(7) . . ?
N12 Eu1 N1 61.74(7) . . ?
N12 Eu1 N1N 145.15(7) . . ?
N12 Eu1 N2N 97.17(7) . . ?
N1N O1N Eu1 95.70(16) . . ?
N1N O2N Eu1 96.99(16) . . ?
C26 O004 Eu1 119.71(17) . . ?
N2N O4N Eu1 95.45(16) . . ?
N2N O5N Eu1 96.54(16) . . ?
N3N O7N Eu1 97.03(15) . . ?
N3N O8N Eu1 95.95(16) . . ?
C15 O009 Eu1 127.32(18) . . ?
C2 N1 Eu1 120.17(18) . . ?
C2 N1 C14 119.0(2) . . ?
C14 N1 Eu1 120.80(18) . . ?
O1N N1N Eu1 58.88(13) . . ?
O1N N1N O2N 116.0(2) . . ?
O2N N1N Eu1 57.42(13) . . ?
O3N N1N Eu1 174.5(2) . . ?
O3N N1N O1N 122.0(3) . . ?
O3N N1N O2N 122.0(3) . . ?
O4N N2N Eu1 58.47(13) . . ?
O4N N2N O5N 115.8(2) . . ?
O5N N2N Eu1 57.42(13) . . ?
O6N N2N Eu1 178.0(2) . . ?
O6N N2N O4N 122.2(3) . . ?
O6N N2N O5N 121.9(3) . . ?
O7N N3N Eu1 57.61(13) . . ?
O8N N3N Eu1 58.92(14) . . ?
O8N N3N O7N 116.4(2) . . ?
O9N N3N Eu1 175.7(2) . . ?
O9N N3N O7N 121.4(2) . . ?
O9N N3N O8N 122.2(3) . . ?
C11 N12 Eu1 118.83(18) . . ?
C11 N12 C13 118.8(2) . . ?
C13 N12 Eu1 122.27(17) . . ?
C15 N16 C17 122.8(2) . . ?
C15 N16 C24 119.0(2) . . ?
C17 N16 C24 116.9(2) . . ?
C26 N27 C28 123.1(2) . . ?
C26 N27 C34 117.8(2) . . ?
C28 N27 C34 117.7(2) . . ?
H01A C01H H01B 109.5 . . ?
H01A C01H H01C 109.5 . . ?
H01B C01H H01C 109.5 . . ?
C31 C01H H01A 109.5 . . ?
C31 C01H H01B 109.5 . . ?
C31 C01H H01C 109.5 . . ?
N1 C2 C3 122.2(3) . . ?
N1 C2 C15 111.3(2) . . ?
C3 C2 C15 126.3(3) . . ?
C2 C3 H3 121.4 . . ?
C4 C3 C2 117.3(3) . . ?
C4 C3 H3 121.4 . . ?
F1 C4 C3 119.1(3) . . ?
F1 C4 C5 117.8(3) . . ?
C3 C4 C5 123.1(3) . . ?
C4 C5 C6 124.5(3) . . ?
C4 C5 C14 114.7(3) . . ?
C14 C5 C6 120.8(3) . . ?
C5 C6 H6 119.6 . . ?
C7 C6 C5 120.9(3) . . ?
C7 C6 H6 119.6 . . ?
C6 C7 H7 120.0 . . ?
C6 C7 C8 120.1(3) . . ?
C8 C7 H7 120.0 . . ?
C9 C8 C7 124.8(3) . . ?
C9 C8 C13 115.1(3) . . ?
C13 C8 C7 120.1(3) . . ?
F2 C9 C8 117.4(3) . . ?
F2 C9 C10 119.8(3) . . ?
C10 C9 C8 122.8(3) . . ?
C9 C10 H10 121.3 . . ?
C9 C10 C11 117.4(3) . . ?
C11 C10 H10 121.3 . . ?
N12 C11 C10 122.8(3) . . ?
N12 C11 C26 111.0(2) . . ?
C10 C11 C26 125.7(3) . . ?
N12 C13 C8 123.0(3) . . ?
N12 C13 C14 117.1(2) . . ?
C8 C13 C14 119.8(3) . . ?
N1 C14 C5 123.7(3) . . ?
N1 C14 C13 118.0(2) . . ?
C5 C14 C13 118.3(2) . . ?
O009 C15 N16 121.5(3) . . ?
O009 C15 C2 116.2(2) . . ?
N16 C15 C2 122.2(2) . . ?
C18 C17 N16 119.2(2) . . ?
C18 C17 C22 120.8(3) . . ?
C22 C17 N16 119.9(3) . . ?
C17 C18 H18 120.4 . . ?
C17 C18 C19 119.2(3) . . ?
C19 C18 H18 120.4 . . ?
C18 C19 H19 119.4 . . ?
C18 C19 C20 121.2(3) . . ?
C20 C19 H19 119.4 . . ?
C19 C20 C23 119.5(3) . . ?
C21 C20 C19 118.6(3) . . ?
C21 C20 C23 121.9(3) . . ?
C20 C21 H21 119.5 . . ?
C22 C21 C20 121.0(3) . . ?
C22 C21 H21 119.5 . . ?
C17 C22 H22 120.4 . . ?
C21 C22 C17 119.2(3) . . ?
C21 C22 H22 120.4 . . ?
C20 C23 H23A 109.5 . . ?
C20 C23 H23B 109.5 . . ?
C20 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
N16 C24 H24A 109.2 . . ?
N16 C24 H24B 109.2 . . ?
N16 C24 C25 111.9(2) . . ?
H24A C24 H24B 107.9 . . ?
C25 C24 H24A 109.2 . . ?
C25 C24 H24B 109.2 . . ?
C24 C25 H25A 109.5 . . ?
C24 C25 H25B 109.5 . . ?
C24 C25 H25C 109.5 . . ?
H25A C25 H25B 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
O004 C26 Eu1 40.74(13) . . ?
O004 C26 N27 121.9(3) . . ?
O004 C26 C11 116.1(2) . . ?
N27 C26 Eu1 145.28(19) . . ?
N27 C26 C11 121.9(2) . . ?
C11 C26 Eu1 84.32(15) . . ?
C29 C28 N27 120.3(3) . . ?
C29 C28 C33 120.6(3) . . ?
C33 C28 N27 119.1(3) . . ?
C28 C29 H29 120.2 . . ?
C28 C29 C30 119.7(3) . . ?
C30 C29 H29 120.2 . . ?
C29 C30 H30 119.6 . . ?
C31 C30 C29 120.9(3) . . ?
C31 C30 H30 119.6 . . ?
C30 C31 C01H 121.0(3) . . ?
C30 C31 C32 118.7(3) . . ?
C32 C31 C01H 120.3(3) . . ?
C31 C32 H32 119.4 . . ?
C31 C32 C33 121.2(3) . . ?
C33 C32 H32 119.4 . . ?
C28 C33 C32 119.0(3) . . ?
C28 C33 H33 120.5 . . ?
C32 C33 H33 120.5 . . ?
N27 C34 H34A 109.4 . . ?
N27 C34 H34B 109.4 . . ?
N27 C34 C35 111.2(2) . . ?
H34A C34 H34B 108.0 . . ?
C35 C34 H34A 109.4 . . ?
C35 C34 H34B 109.4 . . ?
C34 C35 H35A 109.5 . . ?
C34 C35 H35B 109.5 . . ?
C34 C35 H35C 109.5 . . ?
H35A C35 H35B 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
N1S C1S C2S 179.7(6) . . ?
C1S C2S H2SA 109.5 . . ?
C1S C2S H2SB 109.5 . . ?
C1S C2S H2SC 109.5 . . ?
H2SA C2S H2SB 109.5 . . ?
H2SA C2S H2SC 109.5 . . ?
H2SB C2S H2SC 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O1N N1N O2N 6.2(2) . . . . ?
Eu1 O1N N1N O3N -173.6(2) . . . . ?
Eu1 O2N N1N O1N -6.3(2) . . . . ?
Eu1 O2N N1N O3N 173.5(2) . . . . ?
Eu1 O004 C26 N27 -139.5(2) . . . . ?
Eu1 O004 C26 C11 42.4(3) . . . . ?
Eu1 O4N N2N O5N -2.1(2) . . . . ?
Eu1 O4N N2N O6N 177.8(2) . . . . ?
Eu1 O5N N2N O4N 2.1(2) . . . . ?
Eu1 O5N N2N O6N -177.8(2) . . . . ?
Eu1 O7N N3N O8N -4.1(2) . . . . ?
Eu1 O7N N3N O9N 175.1(2) . . . . ?
Eu1 O8N N3N O7N 4.0(2) . . . . ?
Eu1 O8N N3N O9N -175.1(2) . . . . ?
Eu1 O009 C15 N16 158.74(19) . . . . ?
Eu1 O009 C15 C2 -24.7(3) . . . . ?
Eu1 N1 C2 C3 175.8(2) . . . . ?
Eu1 N1 C2 C15 -0.5(3) . . . . ?
Eu1 N1 C14 C5 -177.2(2) . . . . ?
Eu1 N1 C14 C13 1.8(3) . . . . ?
Eu1 N12 C11 C10 -176.0(2) . . . . ?
Eu1 N12 C11 C26 -3.4(3) . . . . ?
Eu1 N12 C13 C8 177.5(2) . . . . ?
Eu1 N12 C13 C14 -1.1(3) . . . . ?
F1 C4 C5 C6 -0.3(4) . . . . ?
F1 C4 C5 C14 179.1(2) . . . . ?
F2 C9 C10 C11 -179.8(3) . . . . ?
N1 C2 C3 C4 1.7(4) . . . . ?
N1 C2 C15 O009 14.4(3) . . . . ?
N1 C2 C15 N16 -169.1(3) . . . . ?
N12 C11 C26 Eu1 2.4(2) . . . . ?
N12 C11 C26 O004 -23.8(3) . . . . ?
N12 C11 C26 N27 158.1(3) . . . . ?
N12 C13 C14 N1 -0.5(4) . . . . ?
N12 C13 C14 C5 178.6(2) . . . . ?
N16 C17 C18 C19 -178.7(2) . . . . ?
N16 C17 C22 C21 177.9(2) . . . . ?
N27 C28 C29 C30 179.6(3) . . . . ?
N27 C28 C33 C32 -179.8(3) . . . . ?
C01H C31 C32 C33 179.5(3) . . . . ?
C2 N1 C14 C5 0.8(4) . . . . ?
C2 N1 C14 C13 179.7(2) . . . . ?
C2 C3 C4 F1 179.7(2) . . . . ?
C2 C3 C4 C5 0.3(4) . . . . ?
C3 C2 C15 O009 -161.8(3) . . . . ?
C3 C2 C15 N16 14.8(4) . . . . ?
C3 C4 C5 C6 179.1(3) . . . . ?
C3 C4 C5 C14 -1.6(4) . . . . ?
C4 C5 C6 C7 178.1(3) . . . . ?
C4 C5 C14 N1 1.0(4) . . . . ?
C4 C5 C14 C13 -177.9(2) . . . . ?
C5 C6 C7 C8 -0.5(4) . . . . ?
C6 C5 C14 N1 -179.6(3) . . . . ?
C6 C5 C14 C13 1.4(4) . . . . ?
C6 C7 C8 C9 -176.6(3) . . . . ?
C6 C7 C8 C13 1.9(4) . . . . ?
C7 C8 C9 F2 -0.2(4) . . . . ?
C7 C8 C9 C10 178.9(3) . . . . ?
C7 C8 C13 N12 179.9(3) . . . . ?
C7 C8 C13 C14 -1.6(4) . . . . ?
C8 C9 C10 C11 1.1(4) . . . . ?
C8 C13 C14 N1 -179.1(2) . . . . ?
C8 C13 C14 C5 0.0(4) . . . . ?
C9 C8 C13 N12 -1.4(4) . . . . ?
C9 C8 C13 C14 177.1(3) . . . . ?
C9 C10 C11 N12 -1.5(4) . . . . ?
C9 C10 C11 C26 -173.0(3) . . . . ?
C10 C11 C26 Eu1 174.8(3) . . . . ?
C10 C11 C26 O004 148.5(3) . . . . ?
C10 C11 C26 N27 -29.5(4) . . . . ?
C11 N12 C13 C8 1.1(4) . . . . ?
C11 N12 C13 C14 -177.5(2) . . . . ?
C13 N12 C11 C10 0.5(4) . . . . ?
C13 N12 C11 C26 173.1(2) . . . . ?
C13 C8 C9 F2 -178.8(2) . . . . ?
C13 C8 C9 C10 0.3(4) . . . . ?
C14 N1 C2 C3 -2.2(4) . . . . ?
C14 N1 C2 C15 -178.5(2) . . . . ?
C14 C5 C6 C7 -1.2(4) . . . . ?
C15 N16 C17 C18 61.3(4) . . . . ?
C15 N16 C17 C22 -118.1(3) . . . . ?
C15 N16 C24 C25 -90.4(3) . . . . ?
C15 C2 C3 C4 177.4(3) . . . . ?
C17 N16 C15 O009 -162.8(3) . . . . ?
C17 N16 C15 C2 20.8(4) . . . . ?
C17 N16 C24 C25 76.9(3) . . . . ?
C17 C18 C19 C20 1.0(4) . . . . ?
C18 C17 C22 C21 -1.4(4) . . . . ?
C18 C19 C20 C21 -1.8(4) . . . . ?
C18 C19 C20 C23 179.4(3) . . . . ?
C19 C20 C21 C22 1.0(4) . . . . ?
C20 C21 C22 C17 0.6(4) . . . . ?
C22 C17 C18 C19 0.6(4) . . . . ?
C23 C20 C21 C22 179.7(3) . . . . ?
C24 N16 C15 O009 3.7(4) . . . . ?
C24 N16 C15 C2 -172.7(2) . . . . ?
C24 N16 C17 C18 -105.6(3) . . . . ?
C24 N16 C17 C22 75.1(3) . . . . ?
C26 N27 C28 C29 -54.6(4) . . . . ?
C26 N27 C28 C33 126.7(3) . . . . ?
C26 N27 C34 C35 90.1(3) . . . . ?
C28 N27 C26 Eu1 114.9(3) . . . . ?
C28 N27 C26 O004 162.9(3) . . . . ?
C28 N27 C26 C11 -19.1(4) . . . . ?
C28 N27 C34 C35 -76.5(3) . . . . ?
C28 C29 C30 C31 0.3(5) . . . . ?
C29 C28 C33 C32 1.5(4) . . . . ?
C29 C30 C31 C01H -179.8(3) . . . . ?
C29 C30 C31 C32 1.3(5) . . . . ?
C30 C31 C32 C33 -1.5(5) . . . . ?
C31 C32 C33 C28 0.1(5) . . . . ?
C33 C28 C29 C30 -1.7(4) . . . . ?
C34 N27 C26 Eu1 -51.0(4) . . . . ?
C34 N27 C26 O004 -2.9(4) . . . . ?
C34 N27 C26 C11 175.0(2) . . . . ?
C34 N27 C28 C29 111.2(3) . . . . ?
C34 N27 C28 C33 -67.5(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a_a
_database_code_depnum_ccdc_archive 'CCDC 2357650'
loop_
_audit_author_name
_audit_author_address
'Konstantin Lyssenko'
;Chemical Department MSU
Russia
;
_audit_update_record             
;
2024-05-23 deposited with the CCDC.	2024-08-06 downloaded from the CCDC.
;
_audit_creation_date             2023-09-15
_audit_creation_method           
;
Olex2 1.5
(compiled 2023.03.06 svn.rbb2c1857 for OlexSys, GUI svn.r6748)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C32 H30 Eu N7 O11, 2(C2 H3 N)'
_chemical_formula_sum            'C36 H36 Eu N9 O11'
_chemical_formula_weight         922.70
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   12.3294(16)
_cell_length_b                   17.073(2)
_cell_length_c                   19.259(3)
_cell_angle_alpha                90
_cell_angle_beta                 102.892(3)
_cell_angle_gamma                90
_cell_volume                     3951.7(9)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    3751
_cell_measurement_temperature    120.00
_cell_measurement_theta_max      24.182
_cell_measurement_theta_min      2.476
_shelx_estimated_absorpt_T_max   0.879
_shelx_estimated_absorpt_T_min   0.801
_exptl_absorpt_coefficient_mu    1.657
_exptl_absorpt_correction_T_max  0.8622
_exptl_absorpt_correction_T_min  0.7132
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1250 before and 0.0685 after correction.
The Ratio of minimum to maximum transmission is 0.8272.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_lustre     .
_exptl_crystal_colour_modifier   .
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.551
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1864
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.08
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0934
_diffrn_reflns_av_unetI/netI     0.1087
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            35210
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.000
_diffrn_reflns_theta_min         1.612
_diffrn_ambient_temperature      120.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker D8 Quest with Photon III detector'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                7799
_reflns_number_total             10508
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       'APEX3 (Bruker, 2019)'
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'olex2.solve 1.5 (Bourhis et al., 2015)'
_refine_diff_density_max         1.338
_refine_diff_density_min         -1.388
_refine_diff_density_rms         0.157
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.002
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     520
_refine_ls_number_reflns         10508
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0724
_refine_ls_R_factor_gt           0.0518
_refine_ls_restrained_S_all      1.002
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'w=1/[σ²(Fo²)] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1113
_refine_ls_wR_factor_ref         0.1249
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C31(H31A,H31B), C21(H21A,H21B)
2.b Aromatic/amide H refined with riding coordinates:
 C29(H29), C2(H2), C28(H28), C3(H3), C19(H19), C18(H18), C16(H16), C5(H5),
 C15(H15), C8(H8), C26(H26), C25(H25), C6(H6), C9(H9)
2.c Idealised Me refined as rotating group:
 C20(H20A,H20B,H20C), C32(H32A,H32B,H32C), C30(H30A,H30B,H30C), C22(H22A,H22B,
 H22C), C4S(H4SA,H4SB,H4SC), C2S(H2SA,H2SB,H2SC)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.60872(2) 0.76980(2) 0.61457(2) 0.01732(7) Uani 1 1 d . . . . .
O8N O 0.4694(3) 0.67667(18) 0.65020(18) 0.0252(7) Uani 1 1 d . . . . .
O5N O 0.7739(3) 0.74761(19) 0.56443(18) 0.0258(7) Uani 1 1 d . . . . .
O2 O 0.7421(3) 0.74141(18) 0.72248(17) 0.0232(7) Uani 1 1 d . . . . .
O7N O 0.4009(3) 0.76958(18) 0.57741(18) 0.0254(7) Uani 1 1 d . . . . .
O1 O 0.5520(3) 0.82773(17) 0.49754(17) 0.0216(7) Uani 1 1 d . . . . .
O4N O 0.7596(3) 0.86345(19) 0.60648(17) 0.0264(7) Uani 1 1 d . . . . .
O9N O 0.2910(3) 0.6817(2) 0.6064(2) 0.0341(9) Uani 1 1 d . . . . .
N2 N 0.6845(3) 0.6280(2) 0.63321(19) 0.0175(7) Uani 1 1 d . . . . .
O2N O 0.5402(3) 0.8289(2) 0.71856(17) 0.0326(8) Uani 1 1 d . . . . .
O1N O 0.5492(3) 0.90680(19) 0.63223(18) 0.0325(8) Uani 1 1 d . . . . .
O3N O 0.4939(3) 0.9519(2) 0.72335(18) 0.0365(9) Uani 1 1 d . . . . .
N3 N 0.4111(3) 0.8304(2) 0.40002(19) 0.0214(8) Uani 1 1 d . . . . .
N1 N 0.5568(3) 0.6771(2) 0.50917(19) 0.0184(7) Uani 1 1 d . . . . .
N4 N 0.8164(3) 0.6637(2) 0.81506(19) 0.0200(8) Uani 1 1 d . . . . .
O6N O 0.8790(3) 0.8413(2) 0.5410(2) 0.0461(11) Uani 1 1 d . . . . .
N3N N 0.3844(3) 0.7091(2) 0.6114(2) 0.0259(9) Uani 1 1 d . . . . .
N1N N 0.5267(3) 0.8969(2) 0.6927(2) 0.0253(8) Uani 1 1 d . . . . .
N2N N 0.8065(3) 0.8185(2) 0.5698(2) 0.0270(9) Uani 1 1 d . . . . .
C29 C 0.9336(4) 0.5609(3) 0.8791(2) 0.0212(9) Uani 1 1 d . . . . .
H29 H 0.997309 0.591151 0.876673 0.025 Uiso 1 1 calc R U . . .
C1 C 0.4998(3) 0.7038(3) 0.4468(2) 0.0181(8) Uani 1 1 d . . . . .
C10 C 0.7544(4) 0.6073(3) 0.6934(2) 0.0199(9) Uani 1 1 d . . . . .
C12 C 0.6679(4) 0.5775(2) 0.5772(2) 0.0184(9) Uani 1 1 d . . . . .
C24 C 0.8279(4) 0.5885(3) 0.8499(2) 0.0213(9) Uani 1 1 d . . . . .
C14 C 0.3142(4) 0.7931(3) 0.3579(2) 0.0202(9) Uani 1 1 d . . . . .
C23 C 0.7705(3) 0.6748(3) 0.7467(2) 0.0205(9) Uani 1 1 d . . . . .
C2 C 0.4761(4) 0.6585(3) 0.3848(2) 0.0217(9) Uani 1 1 d . . . . .
H2 H 0.433041 0.679284 0.341555 0.026 Uiso 1 1 calc R U . . .
C28 C 0.9451(4) 0.4879(3) 0.9120(2) 0.0220(9) Uani 1 1 d . . . . .
H28 H 1.017237 0.468472 0.932739 0.026 Uiso 1 1 calc R U . . .
C7 C 0.7209(4) 0.5045(3) 0.5808(2) 0.0222(9) Uani 1 1 d . . . . .
C27 C 0.8516(4) 0.4427(3) 0.9148(3) 0.0256(10) Uani 1 1 d . . . . .
C31 C 0.8370(4) 0.7337(3) 0.8617(2) 0.0220(9) Uani 1 1 d . . . . .
H31A H 0.862920 0.777404 0.835745 0.026 Uiso 1 1 calc R U . . .
H31B H 0.896371 0.721892 0.904259 0.026 Uiso 1 1 calc R U . . .
C3 C 0.5165(4) 0.5834(3) 0.3878(2) 0.0223(9) Uani 1 1 d . . . . .
H3 H 0.500354 0.551192 0.346485 0.027 Uiso 1 1 calc R U . . .
C19 C 0.2368(4) 0.7592(3) 0.3917(2) 0.0237(10) Uani 1 1 d . . . . .
H19 H 0.247972 0.760648 0.442089 0.028 Uiso 1 1 calc R U . . .
C18 C 0.1437(4) 0.7236(3) 0.3506(3) 0.0237(9) Uani 1 1 d . . . . .
H18 H 0.091078 0.700228 0.373586 0.028 Uiso 1 1 calc R U . . .
C11 C 0.5968(3) 0.6032(2) 0.5118(2) 0.0177(8) Uani 1 1 d . . . . .
C4 C 0.5815(4) 0.5540(3) 0.4518(2) 0.0205(9) Uani 1 1 d . . . . .
C16 C 0.2022(4) 0.7559(3) 0.2446(3) 0.0288(11) Uani 1 1 d . . . . .
H16 H 0.190244 0.754741 0.194154 0.035 Uiso 1 1 calc R U . . .
C13 C 0.4862(4) 0.7921(3) 0.4492(2) 0.0195(9) Uani 1 1 d . . . . .
C5 C 0.6341(4) 0.4786(3) 0.4573(2) 0.0229(9) Uani 1 1 d . . . . .
H5 H 0.620748 0.444615 0.417222 0.028 Uiso 1 1 calc R U . . .
C15 C 0.2964(4) 0.7924(3) 0.2842(2) 0.0252(10) Uani 1 1 d . . . . .
H15 H 0.348181 0.816654 0.261150 0.030 Uiso 1 1 calc R U . . .
C8 C 0.7954(4) 0.4854(3) 0.6450(3) 0.0275(10) Uani 1 1 d . . . . .
H8 H 0.833958 0.436840 0.649462 0.033 Uiso 1 1 calc R U . . .
C21 C 0.4132(4) 0.9170(3) 0.4005(2) 0.0251(10) Uani 1 1 d . . . . .
H21A H 0.382318 0.936650 0.351746 0.030 Uiso 1 1 calc R U . . .
H21B H 0.491157 0.935224 0.415234 0.030 Uiso 1 1 calc R U . . .
C17 C 0.1249(4) 0.7209(3) 0.2774(3) 0.0274(10) Uani 1 1 d . . . . .
C26 C 0.7470(4) 0.4724(3) 0.8841(3) 0.0276(10) Uani 1 1 d . . . . .
H26 H 0.682722 0.442057 0.885010 0.033 Uiso 1 1 calc R U . . .
C20 C 0.0233(4) 0.6810(3) 0.2334(3) 0.0352(12) Uani 1 1 d . . . . .
H20A H -0.008578 0.645875 0.263840 0.053 Uiso 1 1 calc R U . . .
H20B H 0.044419 0.650646 0.195297 0.053 Uiso 1 1 calc R U . . .
H20C H -0.031914 0.720602 0.212501 0.053 Uiso 1 1 calc R U . . .
C25 C 0.7349(4) 0.5459(3) 0.8520(3) 0.0263(10) Uani 1 1 d . . . . .
H25 H 0.662956 0.566086 0.831864 0.032 Uiso 1 1 calc R U . . .
C32 C 0.7325(4) 0.7583(3) 0.8850(3) 0.0335(12) Uani 1 1 d . . . . .
H32A H 0.674670 0.772154 0.842992 0.050 Uiso 1 1 calc R U . . .
H32B H 0.748810 0.803688 0.916691 0.050 Uiso 1 1 calc R U . . .
H32C H 0.706322 0.714852 0.910237 0.050 Uiso 1 1 calc R U . . .
C6 C 0.7017(4) 0.4556(3) 0.5183(3) 0.0260(10) Uani 1 1 d . . . . .
H6 H 0.737605 0.406110 0.520437 0.031 Uiso 1 1 calc R U . . .
N2S N 0.9778(5) 0.5911(3) 0.4334(3) 0.0585(16) Uani 1 1 d . . . . .
C9 C 0.8124(4) 0.5364(3) 0.7010(3) 0.0267(10) Uani 1 1 d . . . . .
H9 H 0.862967 0.523863 0.744490 0.032 Uiso 1 1 calc R U . . .
C30 C 0.8639(4) 0.3630(3) 0.9498(3) 0.0316(11) Uani 1 1 d . . . . .
H30A H 0.916879 0.331540 0.930549 0.047 Uiso 1 1 calc R U . . .
H30B H 0.791526 0.336584 0.940311 0.047 Uiso 1 1 calc R U . . .
H30C H 0.891407 0.369083 1.001372 0.047 Uiso 1 1 calc R U . . .
C3S C 0.9876(5) 0.6059(4) 0.4909(4) 0.0420(14) Uani 1 1 d . . . . .
C22 C 0.3462(5) 0.9505(3) 0.4510(3) 0.0382(13) Uani 1 1 d . . . . .
H22A H 0.268726 0.933077 0.436178 0.057 Uiso 1 1 calc R U . . .
H22B H 0.348962 1.007849 0.449707 0.057 Uiso 1 1 calc R U . . .
H22C H 0.377690 0.932207 0.499495 0.057 Uiso 1 1 calc R U . . .
N1S N 1.0787(6) 0.5616(5) 0.7480(4) 0.082(2) Uani 1 1 d . . . . .
C4S C 1.0018(5) 0.6254(4) 0.5664(4) 0.0559(18) Uani 1 1 d . . . . .
H4SA H 0.942315 0.661056 0.572490 0.084 Uiso 1 1 calc R U . . .
H4SB H 1.074094 0.650937 0.583476 0.084 Uiso 1 1 calc R U . . .
H4SC H 0.998657 0.577451 0.593796 0.084 Uiso 1 1 calc R U . . .
C1S C 1.1406(6) 0.5182(5) 0.7364(4) 0.061(2) Uani 1 1 d . . . . .
C2S C 1.2212(6) 0.4606(5) 0.7225(5) 0.082(3) Uani 1 1 d . . . . .
H2SA H 1.192766 0.436096 0.675992 0.122 Uiso 1 1 calc R U . . .
H2SB H 1.232944 0.420299 0.759705 0.122 Uiso 1 1 calc R U . . .
H2SC H 1.291981 0.486786 0.722600 0.122 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O8N 2.545(3) . ?
Eu1 O5N 2.470(3) . ?
Eu1 O2 2.394(3) . ?
Eu1 O7N 2.502(3) . ?
Eu1 O1 2.417(3) . ?
Eu1 O4N 2.484(3) . ?
Eu1 N2 2.591(4) . ?
Eu1 O2N 2.549(3) . ?
Eu1 O1N 2.497(3) . ?
Eu1 N1 2.541(4) . ?
Eu1 N3N 2.941(4) . ?
Eu1 N2N 2.884(4) . ?
O8N N3N 1.270(5) . ?
O5N N2N 1.272(5) . ?
O2 C23 1.249(5) . ?
O7N N3N 1.263(5) . ?
O1 C13 1.248(5) . ?
O4N N2N 1.267(5) . ?
O9N N3N 1.227(5) . ?
N2 C10 1.329(5) . ?
N2 C12 1.359(5) . ?
O2N N1N 1.259(5) . ?
O1N N1N 1.268(5) . ?
O3N N1N 1.225(5) . ?
N3 C14 1.434(6) . ?
N3 C13 1.339(6) . ?
N3 C21 1.478(6) . ?
N1 C1 1.331(5) . ?
N1 C11 1.350(5) . ?
N4 C24 1.441(5) . ?
N4 C23 1.326(6) . ?
N4 C31 1.483(5) . ?
O6N N2N 1.216(5) . ?
C29 H29 0.9500 . ?
C29 C24 1.383(6) . ?
C29 C28 1.391(6) . ?
C1 C2 1.398(6) . ?
C1 C13 1.518(6) . ?
C10 C23 1.527(6) . ?
C10 C9 1.397(6) . ?
C12 C7 1.402(6) . ?
C12 C11 1.434(6) . ?
C24 C25 1.366(6) . ?
C14 C19 1.394(6) . ?
C14 C15 1.387(6) . ?
C2 H2 0.9500 . ?
C2 C3 1.373(6) . ?
C28 H28 0.9500 . ?
C28 C27 1.398(6) . ?
C7 C8 1.404(7) . ?
C7 C6 1.441(6) . ?
C27 C26 1.389(7) . ?
C27 C30 1.512(7) . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C31 C32 1.515(6) . ?
C3 H3 0.9500 . ?
C3 C4 1.405(6) . ?
C19 H19 0.9500 . ?
C19 C18 1.382(6) . ?
C18 H18 0.9500 . ?
C18 C17 1.378(7) . ?
C11 C4 1.408(6) . ?
C4 C5 1.434(6) . ?
C16 H16 0.9500 . ?
C16 C15 1.388(7) . ?
C16 C17 1.390(7) . ?
C5 H5 0.9500 . ?
C5 C6 1.339(7) . ?
C15 H15 0.9500 . ?
C8 H8 0.9500 . ?
C8 C9 1.366(6) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C21 C22 1.520(6) . ?
C17 C20 1.509(7) . ?
C26 H26 0.9500 . ?
C26 C25 1.392(7) . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C25 H25 0.9500 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C6 H6 0.9500 . ?
N2S C3S 1.116(8) . ?
C9 H9 0.9500 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C3S C4S 1.464(9) . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
N1S C1S 1.122(10) . ?
C4S H4SA 0.9800 . ?
C4S H4SB 0.9800 . ?
C4S H4SC 0.9800 . ?
C1S C2S 1.465(11) . ?
C2S H2SA 0.9800 . ?
C2S H2SB 0.9800 . ?
C2S H2SC 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O8N Eu1 N2 67.84(10) . . ?
O8N Eu1 O2N 70.95(11) . . ?
O8N Eu1 N3N 25.48(11) . . ?
O8N Eu1 N2N 158.01(11) . . ?
O5N Eu1 O8N 132.43(10) . . ?
O5N Eu1 O7N 140.27(11) . . ?
O5N Eu1 O4N 51.68(10) . . ?
O5N Eu1 N2 66.91(10) . . ?
O5N Eu1 O2N 144.54(12) . . ?
O5N Eu1 O1N 119.32(11) . . ?
O5N Eu1 N1 71.01(11) . . ?
O5N Eu1 N3N 142.32(11) . . ?
O5N Eu1 N2N 26.04(11) . . ?
O2 Eu1 O8N 90.78(11) . . ?
O2 Eu1 O5N 80.91(11) . . ?
O2 Eu1 O7N 135.16(11) . . ?
O2 Eu1 O1 153.10(11) . . ?
O2 Eu1 O4N 78.81(11) . . ?
O2 Eu1 N2 62.23(11) . . ?
O2 Eu1 O2N 71.46(11) . . ?
O2 Eu1 O1N 103.71(11) . . ?
O2 Eu1 N1 124.68(11) . . ?
O2 Eu1 N3N 114.02(11) . . ?
O2 Eu1 N2N 81.66(11) . . ?
O7N Eu1 O8N 50.68(10) . . ?
O7N Eu1 N2 110.65(11) . . ?
O7N Eu1 O2N 74.19(11) . . ?
O7N Eu1 N1 73.22(11) . . ?
O7N Eu1 N3N 25.22(11) . . ?
O7N Eu1 N2N 142.68(11) . . ?
O1 Eu1 O8N 115.79(11) . . ?
O1 Eu1 O5N 77.89(11) . . ?
O1 Eu1 O7N 70.69(10) . . ?
O1 Eu1 O4N 75.10(11) . . ?
O1 Eu1 N2 122.13(10) . . ?
O1 Eu1 O2N 119.53(10) . . ?
O1 Eu1 O1N 73.21(10) . . ?
O1 Eu1 N1 62.69(11) . . ?
O1 Eu1 N3N 92.87(11) . . ?
O1 Eu1 N2N 72.02(11) . . ?
O4N Eu1 O8N 168.26(11) . . ?
O4N Eu1 O7N 135.77(10) . . ?
O4N Eu1 N2 111.00(11) . . ?
O4N Eu1 O2N 100.28(11) . . ?
O4N Eu1 O1N 69.66(11) . . ?
O4N Eu1 N1 114.17(11) . . ?
O4N Eu1 N3N 159.93(11) . . ?
O4N Eu1 N2N 25.95(11) . . ?
N2 Eu1 N3N 88.96(11) . . ?
N2 Eu1 N2N 90.46(11) . . ?
O2N Eu1 N2 115.70(11) . . ?
O2N Eu1 N3N 71.39(12) . . ?
O2N Eu1 N2N 124.82(12) . . ?
O1N Eu1 O8N 108.18(11) . . ?
O1N Eu1 O7N 74.17(12) . . ?
O1N Eu1 N2 164.61(11) . . ?
O1N Eu1 O2N 50.44(11) . . ?
O1N Eu1 N1 131.54(12) . . ?
O1N Eu1 N3N 91.68(11) . . ?
O1N Eu1 N2N 93.69(12) . . ?
N1 Eu1 O8N 76.20(11) . . ?
N1 Eu1 N2 63.08(11) . . ?
N1 Eu1 O2N 143.70(12) . . ?
N1 Eu1 N3N 72.31(11) . . ?
N1 Eu1 N2N 91.13(11) . . ?
N2N Eu1 N3N 161.66(12) . . ?
N3N O8N Eu1 95.0(2) . . ?
N2N O5N Eu1 95.5(2) . . ?
C23 O2 Eu1 126.1(3) . . ?
N3N O7N Eu1 97.2(3) . . ?
C13 O1 Eu1 120.0(3) . . ?
N2N O4N Eu1 94.9(3) . . ?
C10 N2 Eu1 120.9(3) . . ?
C10 N2 C12 118.5(4) . . ?
C12 N2 Eu1 119.8(3) . . ?
N1N O2N Eu1 95.3(2) . . ?
N1N O1N Eu1 97.6(3) . . ?
C14 N3 C21 117.3(4) . . ?
C13 N3 C14 122.7(4) . . ?
C13 N3 C21 118.4(4) . . ?
C1 N1 Eu1 119.7(3) . . ?
C1 N1 C11 118.0(4) . . ?
C11 N1 Eu1 121.8(3) . . ?
C24 N4 C31 116.7(4) . . ?
C23 N4 C24 124.5(4) . . ?
C23 N4 C31 117.6(4) . . ?
O8N N3N Eu1 59.5(2) . . ?
O7N N3N Eu1 57.6(2) . . ?
O7N N3N O8N 117.0(4) . . ?
O9N N3N Eu1 176.2(3) . . ?
O9N N3N O8N 121.1(4) . . ?
O9N N3N O7N 121.8(4) . . ?
O2N N1N Eu1 59.5(2) . . ?
O2N N1N O1N 116.7(4) . . ?
O1N N1N Eu1 57.2(2) . . ?
O3N N1N Eu1 177.4(3) . . ?
O3N N1N O2N 123.1(4) . . ?
O3N N1N O1N 120.3(4) . . ?
O5N N2N Eu1 58.5(2) . . ?
O4N N2N Eu1 59.1(2) . . ?
O4N N2N O5N 116.5(4) . . ?
O6N N2N Eu1 170.0(4) . . ?
O6N N2N O5N 121.3(4) . . ?
O6N N2N O4N 122.2(4) . . ?
C24 C29 H29 120.6 . . ?
C24 C29 C28 118.8(4) . . ?
C28 C29 H29 120.6 . . ?
N1 C1 C2 123.3(4) . . ?
N1 C1 C13 110.6(4) . . ?
C2 C1 C13 124.9(4) . . ?
N2 C10 C23 110.3(4) . . ?
N2 C10 C9 122.6(4) . . ?
C9 C10 C23 126.7(4) . . ?
N2 C12 C7 122.6(4) . . ?
N2 C12 C11 117.2(4) . . ?
C7 C12 C11 120.1(4) . . ?
C29 C24 N4 118.6(4) . . ?
C25 C24 N4 119.5(4) . . ?
C25 C24 C29 121.8(4) . . ?
C19 C14 N3 119.4(4) . . ?
C15 C14 N3 120.2(4) . . ?
C15 C14 C19 120.3(4) . . ?
O2 C23 N4 121.5(4) . . ?
O2 C23 C10 116.9(4) . . ?
N4 C23 C10 121.5(4) . . ?
C1 C2 H2 120.8 . . ?
C3 C2 C1 118.5(4) . . ?
C3 C2 H2 120.8 . . ?
C29 C28 H28 119.6 . . ?
C29 C28 C27 120.8(4) . . ?
C27 C28 H28 119.6 . . ?
C12 C7 C8 117.1(4) . . ?
C12 C7 C6 119.2(4) . . ?
C8 C7 C6 123.6(4) . . ?
C28 C27 C30 120.8(4) . . ?
C26 C27 C28 118.5(4) . . ?
C26 C27 C30 120.7(4) . . ?
N4 C31 H31A 109.4 . . ?
N4 C31 H31B 109.4 . . ?
N4 C31 C32 111.1(4) . . ?
H31A C31 H31B 108.0 . . ?
C32 C31 H31A 109.4 . . ?
C32 C31 H31B 109.4 . . ?
C2 C3 H3 120.0 . . ?
C2 C3 C4 120.1(4) . . ?
C4 C3 H3 120.0 . . ?
C14 C19 H19 120.5 . . ?
C18 C19 C14 119.0(4) . . ?
C18 C19 H19 120.5 . . ?
C19 C18 H18 119.0 . . ?
C17 C18 C19 121.9(4) . . ?
C17 C18 H18 119.0 . . ?
N1 C11 C12 117.7(4) . . ?
N1 C11 C4 123.1(4) . . ?
C4 C11 C12 118.8(4) . . ?
C3 C4 C11 116.9(4) . . ?
C3 C4 C5 123.1(4) . . ?
C11 C4 C5 120.0(4) . . ?
C15 C16 H16 119.4 . . ?
C15 C16 C17 121.2(5) . . ?
C17 C16 H16 119.4 . . ?
O1 C13 Eu1 40.4(2) . . ?
O1 C13 N3 121.5(4) . . ?
O1 C13 C1 116.7(4) . . ?
N3 C13 Eu1 148.6(3) . . ?
N3 C13 C1 121.7(4) . . ?
C1 C13 Eu1 83.3(2) . . ?
C4 C5 H5 119.6 . . ?
C6 C5 C4 120.7(4) . . ?
C6 C5 H5 119.6 . . ?
C14 C15 C16 119.2(4) . . ?
C14 C15 H15 120.4 . . ?
C16 C15 H15 120.4 . . ?
C7 C8 H8 119.9 . . ?
C9 C8 C7 120.1(4) . . ?
C9 C8 H8 119.9 . . ?
N3 C21 H21A 109.3 . . ?
N3 C21 H21B 109.3 . . ?
N3 C21 C22 111.7(4) . . ?
H21A C21 H21B 107.9 . . ?
C22 C21 H21A 109.3 . . ?
C22 C21 H21B 109.3 . . ?
C18 C17 C16 118.4(5) . . ?
C18 C17 C20 121.3(5) . . ?
C16 C17 C20 120.4(5) . . ?
C27 C26 H26 119.5 . . ?
C27 C26 C25 121.0(4) . . ?
C25 C26 H26 119.5 . . ?
C17 C20 H20A 109.5 . . ?
C17 C20 H20B 109.5 . . ?
C17 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C24 C25 C26 119.1(4) . . ?
C24 C25 H25 120.5 . . ?
C26 C25 H25 120.5 . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C7 C6 H6 119.5 . . ?
C5 C6 C7 121.1(4) . . ?
C5 C6 H6 119.5 . . ?
C10 C9 H9 120.5 . . ?
C8 C9 C10 119.0(5) . . ?
C8 C9 H9 120.5 . . ?
C27 C30 H30A 109.5 . . ?
C27 C30 H30B 109.5 . . ?
C27 C30 H30C 109.5 . . ?
H30A C30 H30B 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
N2S C3S C4S 179.3(8) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C3S C4S H4SA 109.5 . . ?
C3S C4S H4SB 109.5 . . ?
C3S C4S H4SC 109.5 . . ?
H4SA C4S H4SB 109.5 . . ?
H4SA C4S H4SC 109.5 . . ?
H4SB C4S H4SC 109.5 . . ?
N1S C1S C2S 178.8(9) . . ?
C1S C2S H2SA 109.5 . . ?
C1S C2S H2SB 109.5 . . ?
C1S C2S H2SC 109.5 . . ?
H2SA C2S H2SB 109.5 . . ?
H2SA C2S H2SC 109.5 . . ?
H2SB C2S H2SC 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O8N N3N O7N -2.9(4) . . . . ?
Eu1 O8N N3N O9N 175.7(4) . . . . ?
Eu1 O5N N2N O4N 11.6(4) . . . . ?
Eu1 O5N N2N O6N -168.3(4) . . . . ?
Eu1 O2 C23 N4 -158.6(3) . . . . ?
Eu1 O2 C23 C10 23.9(5) . . . . ?
Eu1 O7N N3N O8N 3.0(4) . . . . ?
Eu1 O7N N3N O9N -175.6(4) . . . . ?
Eu1 O1 C13 N3 145.6(3) . . . . ?
Eu1 O1 C13 C1 -37.6(4) . . . . ?
Eu1 O4N N2N O5N -11.5(4) . . . . ?
Eu1 O4N N2N O6N 168.4(4) . . . . ?
Eu1 N2 C10 C23 5.1(4) . . . . ?
Eu1 N2 C10 C9 -168.3(3) . . . . ?
Eu1 N2 C12 C7 169.8(3) . . . . ?
Eu1 N2 C12 C11 -7.4(5) . . . . ?
Eu1 O2N N1N O1N 0.5(4) . . . . ?
Eu1 O2N N1N O3N -179.2(4) . . . . ?
Eu1 O1N N1N O2N -0.5(4) . . . . ?
Eu1 O1N N1N O3N 179.2(4) . . . . ?
Eu1 N1 C1 C2 174.4(3) . . . . ?
Eu1 N1 C1 C13 6.0(4) . . . . ?
Eu1 N1 C11 C12 1.6(5) . . . . ?
Eu1 N1 C11 C4 -171.5(3) . . . . ?
N2 C10 C23 O2 -17.3(5) . . . . ?
N2 C10 C23 N4 165.2(4) . . . . ?
N2 C10 C9 C8 -1.3(7) . . . . ?
N2 C12 C7 C8 -1.5(6) . . . . ?
N2 C12 C7 C6 -178.0(4) . . . . ?
N2 C12 C11 N1 3.9(6) . . . . ?
N2 C12 C11 C4 177.3(4) . . . . ?
N3 C14 C19 C18 179.9(4) . . . . ?
N3 C14 C15 C16 179.9(4) . . . . ?
N1 C1 C2 C3 -2.1(6) . . . . ?
N1 C1 C13 Eu1 -4.2(3) . . . . ?
N1 C1 C13 O1 19.3(5) . . . . ?
N1 C1 C13 N3 -163.9(4) . . . . ?
N1 C11 C4 C3 -3.4(6) . . . . ?
N1 C11 C4 C5 174.9(4) . . . . ?
N4 C24 C25 C26 178.2(4) . . . . ?
C29 C24 C25 C26 -0.3(7) . . . . ?
C29 C28 C27 C26 0.0(7) . . . . ?
C29 C28 C27 C30 179.3(4) . . . . ?
C1 N1 C11 C12 173.6(4) . . . . ?
C1 N1 C11 C4 0.5(6) . . . . ?
C1 C2 C3 C4 -1.0(6) . . . . ?
C10 N2 C12 C7 0.6(6) . . . . ?
C10 N2 C12 C11 -176.7(4) . . . . ?
C12 N2 C10 C23 174.2(3) . . . . ?
C12 N2 C10 C9 0.8(6) . . . . ?
C12 C7 C8 C9 1.0(7) . . . . ?
C12 C7 C6 C5 -0.2(7) . . . . ?
C12 C11 C4 C3 -176.4(4) . . . . ?
C12 C11 C4 C5 1.9(6) . . . . ?
C24 N4 C23 O2 165.1(4) . . . . ?
C24 N4 C23 C10 -17.5(6) . . . . ?
C24 N4 C31 C32 -86.4(5) . . . . ?
C24 C29 C28 C27 0.8(7) . . . . ?
C14 N3 C13 Eu1 -115.8(6) . . . . ?
C14 N3 C13 O1 -160.5(4) . . . . ?
C14 N3 C13 C1 22.9(6) . . . . ?
C14 N3 C21 C22 80.0(5) . . . . ?
C14 C19 C18 C17 -0.3(7) . . . . ?
C23 N4 C24 C29 117.7(5) . . . . ?
C23 N4 C24 C25 -60.9(6) . . . . ?
C23 N4 C31 C32 81.9(5) . . . . ?
C23 C10 C9 C8 -173.5(4) . . . . ?
C2 C1 C13 Eu1 -172.3(4) . . . . ?
C2 C1 C13 O1 -148.8(4) . . . . ?
C2 C1 C13 N3 27.9(6) . . . . ?
C2 C3 C4 C11 3.5(6) . . . . ?
C2 C3 C4 C5 -174.6(4) . . . . ?
C28 C29 C24 N4 -179.2(4) . . . . ?
C28 C29 C24 C25 -0.6(7) . . . . ?
C28 C27 C26 C25 -0.9(7) . . . . ?
C7 C12 C11 N1 -173.5(4) . . . . ?
C7 C12 C11 C4 -0.1(6) . . . . ?
C7 C8 C9 C10 0.3(7) . . . . ?
C27 C26 C25 C24 1.1(7) . . . . ?
C31 N4 C24 C29 -74.9(5) . . . . ?
C31 N4 C24 C25 106.5(5) . . . . ?
C31 N4 C23 O2 -2.2(6) . . . . ?
C31 N4 C23 C10 175.1(4) . . . . ?
C3 C4 C5 C6 175.2(4) . . . . ?
C19 C14 C15 C16 -1.6(7) . . . . ?
C19 C18 C17 C16 -0.5(7) . . . . ?
C19 C18 C17 C20 179.4(4) . . . . ?
C11 N1 C1 C2 2.3(6) . . . . ?
C11 N1 C1 C13 -166.1(3) . . . . ?
C11 C12 C7 C8 175.7(4) . . . . ?
C11 C12 C7 C6 -0.8(6) . . . . ?
C11 C4 C5 C6 -2.9(7) . . . . ?
C4 C5 C6 C7 2.0(7) . . . . ?
C13 N3 C14 C19 60.5(6) . . . . ?
C13 N3 C14 C15 -121.0(5) . . . . ?
C13 N3 C21 C22 -86.1(5) . . . . ?
C13 C1 C2 C3 164.7(4) . . . . ?
C15 C14 C19 C18 1.4(7) . . . . ?
C15 C16 C17 C18 0.3(7) . . . . ?
C15 C16 C17 C20 -179.6(5) . . . . ?
C8 C7 C6 C5 -176.5(4) . . . . ?
C21 N3 C14 C19 -104.9(5) . . . . ?
C21 N3 C14 C15 73.6(5) . . . . ?
C21 N3 C13 Eu1 49.5(7) . . . . ?
C21 N3 C13 O1 4.7(6) . . . . ?
C21 N3 C13 C1 -171.9(4) . . . . ?
C17 C16 C15 C14 0.7(7) . . . . ?
C6 C7 C8 C9 177.3(4) . . . . ?
C9 C10 C23 O2 155.7(4) . . . . ?
C9 C10 C23 N4 -21.8(7) . . . . ?
C30 C27 C26 C25 179.7(5) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a_CCDC1
_database_code_depnum_ccdc_archive 'CCDC 2357651'
loop_
_audit_author_name
_audit_author_address
'Konstantin Lyssenko'
;Chemical Department MSU
Russia
;
_audit_update_record             
;
2024-05-23 deposited with the CCDC.	2024-08-06 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C40 H40 Cl2 Eu N11 O11'
_chemical_formula_weight         1073.69

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   11.7783(4)
_cell_length_b                   15.3608(6)
_cell_length_c                   25.6294(10)
_cell_angle_alpha                90
_cell_angle_beta                 98.3200(10)
_cell_angle_gamma                90
_cell_volume                     4588.2(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    120(2)
_cell_measurement_reflns_used    9987
_cell_measurement_theta_min      2.243
_cell_measurement_theta_max      30.21


_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.554
_exptl_crystal_F_000             2168
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.320
_exptl_crystal_size_mid          0.180
_exptl_crystal_size_min          0.120
_exptl_absorpt_coefficient_mu    1.553
_shelx_estimated_absorpt_T_min   0.636
_shelx_estimated_absorpt_T_max   0.836
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5934
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_process_details   
;
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      120(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_detector                 'Photon III detector'
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 Quest with Photon III detector'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_type              'Incoatec I\ms'
_diffrn_reflns_number            44281
_diffrn_reflns_av_unetI/netI     0.0556
_diffrn_reflns_av_R_equivalents  0.0594
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_theta_min         1.550
_diffrn_reflns_theta_max         28.999
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             12190
_reflns_number_gt                9704
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0294P)²+3.6827P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         12190
_refine_ls_number_parameters     590
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0537
_refine_ls_R_factor_gt           0.0370
_refine_ls_wR_factor_ref         0.0810
_refine_ls_wR_factor_gt          0.0756
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_restrained_S_all      1.019
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.04772(2) 0.21606(2) 0.39039(2) 0.01383(4) Uani 1 1 d . . . . .
Cl1 Cl -0.05733(7) 0.66647(4) 0.37267(3) 0.02166(15) Uani 1 1 d . . . . .
O1 O -0.11419(17) 0.26934(13) 0.33115(8) 0.0180(4) Uani 1 1 d . . . . .
O1N O 0.11400(19) 0.25175(15) 0.30544(8) 0.0253(5) Uani 1 1 d . . . . .
N1 N 0.02365(19) 0.38146(15) 0.38367(9) 0.0147(5) Uani 1 1 d . . . . .
N1N N 0.2197(3) 0.2582(2) 0.32417(12) 0.0339(7) Uani 1 1 d . . . . .
Cl2 Cl 0.31948(6) 0.46615(5) 0.60460(3) 0.01982(15) Uani 1 1 d . . . . .
O2 O 0.14020(17) 0.14271(13) 0.46955(8) 0.0184(4) Uani 1 1 d . . . . .
N2 N 0.1588(2) 0.31079(15) 0.46486(9) 0.0138(5) Uani 1 1 d . . . . .
O2N O 0.2434(2) 0.25687(18) 0.37404(9) 0.0343(6) Uani 1 1 d . . . . .
N2N N 0.0690(3) 0.05254(19) 0.33419(11) 0.0393(8) Uani 1 1 d . U . . .
C2 C -0.0479(2) 0.41325(18) 0.34364(11) 0.0150(5) Uani 1 1 d . . . . .
N3 N -0.1484(2) 0.35486(16) 0.25911(9) 0.0179(5) Uani 1 1 d . . . . .
N3N N -0.1397(2) 0.19347(17) 0.45202(11) 0.0236(6) Uani 1 1 d . . . . .
C3 C -0.0741(2) 0.50193(18) 0.33883(11) 0.0173(6) Uani 1 1 d . . . . .
H3A H -0.125300 0.523253 0.309566 0.021 Uiso 1 1 calc R U . . .
O3N O 0.2935(3) 0.2647(3) 0.29605(12) 0.0666(10) Uani 1 1 d . . . . .
N4 N 0.3092(2) 0.12615(15) 0.52204(9) 0.0171(5) Uani 1 1 d . . . . .
O4N O -0.0232(2) 0.09183(17) 0.33000(10) 0.0373(6) Uani 1 1 d . U . . .
C4 C -0.0243(2) 0.55705(18) 0.37717(11) 0.0161(6) Uani 1 1 d . . . . .
O5N O 0.1545(3) 0.08638(17) 0.36310(10) 0.0435(7) Uani 1 1 d . . . . .
C5 C 0.0513(2) 0.52621(18) 0.42134(11) 0.0142(5) Uani 1 1 d . . . . .
O6N O 0.0810(3) -0.01715(19) 0.31147(12) 0.0700(11) Uani 1 1 d . . . . .
C6 C 0.1007(2) 0.57846(18) 0.46474(11) 0.0170(6) Uani 1 1 d . . . . .
H6A H 0.085852 0.639262 0.464509 0.020 Uiso 1 1 calc R U . . .
O7N O -0.10836(18) 0.13260(13) 0.42424(8) 0.0222(5) Uani 1 1 d . . . . .
C7 C 0.1686(2) 0.54240(18) 0.50627(11) 0.0169(6) Uani 1 1 d . . . . .
H7A H 0.200878 0.578350 0.534763 0.020 Uiso 1 1 calc R U . . .
O8N O -0.08353(19) 0.26431(13) 0.45293(9) 0.0231(5) Uani 1 1 d . . . . .
C8 C 0.1925(2) 0.45112(18) 0.50796(11) 0.0149(5) Uani 1 1 d . . . . .
O9N O -0.2190(2) 0.18469(18) 0.47727(12) 0.0462(7) Uani 1 1 d . . . . .
C9 C 0.2597(2) 0.40802(19) 0.54989(11) 0.0155(6) Uani 1 1 d . . . . .
C10 C 0.2772(2) 0.31903(18) 0.54904(11) 0.0150(5) Uani 1 1 d . . . . .
H10A H 0.323112 0.290222 0.577378 0.018 Uiso 1 1 calc R U . . .
C11 C 0.2247(2) 0.27295(18) 0.50493(11) 0.0150(5) Uani 1 1 d . . . . .
C12 C 0.1447(2) 0.39802(17) 0.46588(10) 0.0129(5) Uani 1 1 d . . . . .
C13 C 0.0721(2) 0.43574(18) 0.42155(10) 0.0136(5) Uani 1 1 d . . . . .
C14 C -0.1053(2) 0.34174(19) 0.30954(11) 0.0169(6) Uani 1 1 d . . . . .
C15 C -0.1214(3) 0.4303(2) 0.22963(11) 0.0206(6) Uani 1 1 d . . . . .
C16 C -0.0085(3) 0.4501(2) 0.22650(11) 0.0225(6) Uani 1 1 d . . . . .
H15A H 0.051715 0.414768 0.243764 0.027 Uiso 1 1 calc R U . . .
C17 C 0.0161(3) 0.5228(2) 0.19761(13) 0.0302(8) Uani 1 1 d . . . . .
H16A H 0.093717 0.537551 0.195757 0.036 Uiso 1 1 calc R U . . .
C18 C -0.0714(3) 0.5742(2) 0.17146(13) 0.0338(8) Uani 1 1 d . . . . .
C19 C -0.1836(3) 0.5526(2) 0.17556(13) 0.0327(8) Uani 1 1 d . . . . .
H18A H -0.244063 0.587446 0.158090 0.039 Uiso 1 1 calc R U . . .
C20 C -0.2098(3) 0.4816(2) 0.20440(12) 0.0256(7) Uani 1 1 d . . . . .
H19A H -0.287460 0.467870 0.207007 0.031 Uiso 1 1 calc R U . . .
C21 C -0.0451(4) 0.6507(3) 0.13822(16) 0.0510(12) Uani 1 1 d . . . . .
H20A H 0.036951 0.664383 0.145751 0.076 Uiso 1 1 calc R U . . .
H20B H -0.089857 0.701279 0.146535 0.076 Uiso 1 1 calc R U . . .
H20C H -0.065129 0.636055 0.100805 0.076 Uiso 1 1 calc R U . . .
C22 C -0.2119(3) 0.2824(2) 0.23028(12) 0.0230(6) Uani 1 1 d . . . . .
H21A H -0.263913 0.306075 0.199784 0.028 Uiso 1 1 calc R U . . .
H21B H -0.259534 0.253060 0.253814 0.028 Uiso 1 1 calc R U . . .
C23 C -0.1317(3) 0.2162(2) 0.21078(13) 0.0302(7) Uani 1 1 d . . . . .
H22A H -0.177106 0.170177 0.191118 0.045 Uiso 1 1 calc R U . . .
H22B H -0.082511 0.190561 0.240990 0.045 Uiso 1 1 calc R U . . .
H22C H -0.083998 0.245045 0.187673 0.045 Uiso 1 1 calc R U . . .
C24 C 0.2248(2) 0.17527(18) 0.49813(10) 0.0148(5) Uani 1 1 d . . . . .
C25 C 0.4187(2) 0.16000(18) 0.54521(11) 0.0159(6) Uani 1 1 d . . . . .
C26 C 0.4601(3) 0.1423(2) 0.59743(12) 0.0203(6) Uani 1 1 d . . . . .
H25A H 0.416506 0.107911 0.618132 0.024 Uiso 1 1 calc R U . . .
C27 C 0.5657(3) 0.1754(2) 0.61910(13) 0.0244(7) Uani 1 1 d . . . . .
H26A H 0.594426 0.163178 0.654922 0.029 Uiso 1 1 calc R U . . .
C28 C 0.6308(3) 0.2260(2) 0.58956(13) 0.0251(7) Uani 1 1 d . . . . .
C29 C 0.5873(3) 0.2420(2) 0.53698(13) 0.0242(7) Uani 1 1 d . . . . .
H28A H 0.630213 0.276751 0.516181 0.029 Uiso 1 1 calc R U . . .
C30 C 0.4835(3) 0.20843(19) 0.51464(12) 0.0206(6) Uani 1 1 d . . . . .
H29A H 0.456273 0.218324 0.478402 0.025 Uiso 1 1 calc R U . . .
C31 C 0.7465(3) 0.2605(2) 0.61275(16) 0.0377(9) Uani 1 1 d . . . . .
H30A H 0.760450 0.247624 0.650585 0.057 Uiso 1 1 calc R U . . .
H30B H 0.748530 0.323649 0.607445 0.057 Uiso 1 1 calc R U . . .
H30C H 0.805880 0.232782 0.595357 0.057 Uiso 1 1 calc R U . . .
C32 C 0.2996(3) 0.03029(19) 0.51651(12) 0.0226(6) Uani 1 1 d . . . . .
H31A H 0.218578 0.012728 0.515937 0.027 Uiso 1 1 calc R U . . .
H31B H 0.345692 0.002177 0.547313 0.027 Uiso 1 1 calc R U . . .
C33 C 0.3412(3) -0.0005(2) 0.46650(14) 0.0299(8) Uani 1 1 d . . . . .
H32A H 0.336259 -0.064131 0.464447 0.045 Uiso 1 1 calc R U . . .
H32B H 0.421067 0.017620 0.466769 0.045 Uiso 1 1 calc R U . . .
H32C H 0.293248 0.025036 0.435888 0.045 Uiso 1 1 calc R U . . .
N3S N -0.1393(3) 0.85157(19) 0.38996(11) 0.0333(7) Uani 1 1 d . . . . .
C5S C -0.0630(3) 0.8888(2) 0.41082(12) 0.0249(7) Uani 1 1 d . . . . .
N4S N -0.1003(3) -0.0957(2) 0.19406(14) 0.0524(10) Uani 1 1 d . . . . .
C8S C 0.0152(3) -0.1919(2) 0.26553(14) 0.0357(9) Uani 1 1 d . . . . .
H8SA H -0.010574 -0.180688 0.299586 0.043 Uiso 1 1 calc R U . . .
H8SB H 0.097028 -0.178119 0.267980 0.043 Uiso 1 1 calc R U . . .
H8SC H 0.002879 -0.253393 0.256178 0.043 Uiso 1 1 calc R U . . .
C7S C -0.0503(3) -0.1373(3) 0.22490(14) 0.0353(8) Uani 1 1 d . . . . .
C4S C 0.1187(4) 0.0835(3) 0.19977(17) 0.0455(10) Uani 1 1 d . . . . .
H4SA H 0.073361 0.054766 0.223943 0.055 Uiso 1 1 calc R U . . .
H4SB H 0.069045 0.097920 0.166857 0.055 Uiso 1 1 calc R U . . .
H4SC H 0.152587 0.136993 0.216086 0.055 Uiso 1 1 calc R U . . .
C6S C 0.0327(3) 0.9369(2) 0.43899(15) 0.0397(9) Uani 1 1 d . . . . .
H6SA H 0.103909 0.918787 0.426501 0.048 Uiso 1 1 calc R U . . .
H6SB H 0.038233 0.925038 0.476842 0.048 Uiso 1 1 calc R U . . .
H6SC H 0.020775 0.999381 0.432663 0.048 Uiso 1 1 calc R U . . .
C3S C 0.2100(4) 0.0252(3) 0.18849(16) 0.0454(10) Uani 1 1 d . . . . .
N2S N 0.2784(4) -0.0198(3) 0.17884(17) 0.0714(14) Uani 1 1 d . . . . .
N1S N 0.6024(4) 0.4493(3) 0.55310(19) 0.0684(12) Uani 1 1 d . . . . .
C1S C 0.5780(4) 0.5187(3) 0.56402(17) 0.0440(10) Uani 1 1 d . . . . .
C2S C 0.5463(4) 0.6051(3) 0.57838(18) 0.0508(11) Uani 1 1 d . . . . .
H2SC H 0.611547 0.632688 0.600303 0.061 Uiso 1 1 calc R U . . .
H2SA H 0.481249 0.601687 0.598206 0.061 Uiso 1 1 calc R U . . .
H2SB H 0.524514 0.639827 0.546408 0.061 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.4029(19) . ?
Eu1 O2 2.4356(19) . ?
Eu1 O2N 2.482(2) . ?
Eu1 O8N 2.495(2) . ?
Eu1 O1N 2.479(2) . ?
Eu1 O7N 2.497(2) . ?
Eu1 O5N 2.508(2) . ?
Eu1 O4N 2.522(2) . ?
Eu1 N1 2.560(2) . ?
Eu1 N2 2.598(2) . ?
Eu1 N3N 2.915(3) . ?
Eu1 N1N 2.898(3) . ?
Cl1 C4 1.725(3) . ?
O1 C14 1.253(3) . ?
O1N N1N 1.272(4) . ?
N1 C2 1.323(3) . ?
N1 C13 1.343(3) . ?
N1N O3N 1.210(4) . ?
N1N O2N 1.269(4) . ?
Cl2 C9 1.724(3) . ?
O2 C24 1.253(3) . ?
N2 C11 1.328(4) . ?
N2 C12 1.351(3) . ?
N2N O4N 1.234(4) . ?
N2N O6N 1.236(4) . ?
N2N O5N 1.271(4) . ?
C2 C3 1.398(4) . ?
C2 C14 1.502(4) . ?
N3 C14 1.334(3) . ?
N3 C15 1.444(4) . ?
N3 C22 1.477(4) . ?
N3N O9N 1.218(3) . ?
N3N O7N 1.262(3) . ?
N3N O8N 1.272(3) . ?
C3 C4 1.364(4) . ?
C3 H3A 0.9500 . ?
N4 C24 1.325(4) . ?
N4 C25 1.437(4) . ?
N4 C32 1.482(4) . ?
C4 C5 1.417(4) . ?
C5 C13 1.411(4) . ?
C5 C6 1.426(4) . ?
C6 C7 1.354(4) . ?
C6 H6A 0.9500 . ?
C7 C8 1.429(4) . ?
C7 H7A 0.9500 . ?
C8 C12 1.403(4) . ?
C8 C9 1.405(4) . ?
C9 C10 1.383(4) . ?
C10 C11 1.400(4) . ?
C10 H10A 0.9500 . ?
C11 C24 1.510(4) . ?
C12 C13 1.441(4) . ?
C15 C16 1.379(4) . ?
C15 C20 1.389(4) . ?
C16 C17 1.393(4) . ?
C16 H15A 0.9500 . ?
C17 C18 1.390(5) . ?
C17 H16A 0.9500 . ?
C18 C19 1.381(5) . ?
C18 C21 1.510(5) . ?
C19 C20 1.377(5) . ?
C19 H18A 0.9500 . ?
C20 H19A 0.9500 . ?
C21 H20A 0.9800 . ?
C21 H20B 0.9800 . ?
C21 H20C 0.9800 . ?
C22 C23 1.521(4) . ?
C22 H21A 0.9900 . ?
C22 H21B 0.9900 . ?
C23 H22A 0.9800 . ?
C23 H22B 0.9800 . ?
C23 H22C 0.9800 . ?
C25 C30 1.387(4) . ?
C25 C26 1.383(4) . ?
C26 C27 1.384(4) . ?
C26 H25A 0.9500 . ?
C27 C28 1.391(5) . ?
C27 H26A 0.9500 . ?
C28 C29 1.392(5) . ?
C28 C31 1.502(5) . ?
C29 C30 1.373(4) . ?
C29 H28A 0.9500 . ?
C30 H29A 0.9500 . ?
C31 H30A 0.9800 . ?
C31 H30B 0.9800 . ?
C31 H30C 0.9800 . ?
C32 C33 1.513(5) . ?
C32 H31A 0.9900 . ?
C32 H31B 0.9900 . ?
C33 H32A 0.9800 . ?
C33 H32B 0.9800 . ?
C33 H32C 0.9800 . ?
N3S C5S 1.132(4) . ?
C5S C6S 1.450(5) . ?
N4S C7S 1.116(5) . ?
C8S C7S 1.466(5) . ?
C8S H8SA 0.9800 . ?
C8S H8SB 0.9800 . ?
C8S H8SC 0.9800 . ?
C4S C3S 1.460(6) . ?
C4S H4SA 0.9800 . ?
C4S H4SB 0.9800 . ?
C4S H4SC 0.9800 . ?
C6S H6SA 0.9800 . ?
C6S H6SB 0.9800 . ?
C6S H6SC 0.9800 . ?
C3S N2S 1.115(5) . ?
N1S C1S 1.149(6) . ?
C1S C2S 1.442(6) . ?
C2S H2SC 0.9800 . ?
C2S H2SA 0.9800 . ?
C2S H2SB 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O2 154.46(7) . . ?
O1 Eu1 O2N 118.60(8) . . ?
O2 Eu1 O2N 86.74(8) . . ?
O1 Eu1 O8N 78.23(7) . . ?
O2 Eu1 O8N 81.16(7) . . ?
O2N Eu1 O8N 135.26(8) . . ?
O1 Eu1 O1N 72.04(7) . . ?
O2 Eu1 O1N 132.40(7) . . ?
O2N Eu1 O1N 51.50(8) . . ?
O8N Eu1 O1N 143.31(7) . . ?
O1 Eu1 O7N 80.65(7) . . ?
O2 Eu1 O7N 74.70(7) . . ?
O2N Eu1 O7N 159.47(8) . . ?
O8N Eu1 O7N 51.22(7) . . ?
O1N Eu1 O7N 139.46(7) . . ?
O1 Eu1 O5N 118.57(8) . . ?
O2 Eu1 O5N 71.53(7) . . ?
O2N Eu1 O5N 68.80(10) . . ?
O8N Eu1 O5N 142.86(8) . . ?
O1N Eu1 O5N 72.32(8) . . ?
O7N Eu1 O5N 96.49(9) . . ?
O1 Eu1 O4N 73.02(8) . . ?
O2 Eu1 O4N 103.27(8) . . ?
O2N Eu1 O4N 108.69(8) . . ?
O8N Eu1 O4N 115.99(8) . . ?
O1N Eu1 O4N 75.32(8) . . ?
O7N Eu1 O4N 68.27(8) . . ?
O5N Eu1 O4N 50.41(9) . . ?
O1 Eu1 N1 63.21(7) . . ?
O2 Eu1 N1 123.17(7) . . ?
O2N Eu1 N1 80.47(8) . . ?
O8N Eu1 N1 71.07(7) . . ?
O1N Eu1 N1 76.54(7) . . ?
O7N Eu1 N1 116.94(7) . . ?
O5N Eu1 N1 145.54(9) . . ?
O4N Eu1 N1 133.33(8) . . ?
O1 Eu1 N2 122.87(7) . . ?
O2 Eu1 N2 61.98(7) . . ?
O2N Eu1 N2 66.51(8) . . ?
O8N Eu1 N2 69.79(7) . . ?
O1N Eu1 N2 109.41(7) . . ?
O7N Eu1 N2 110.49(7) . . ?
O5N Eu1 N2 115.48(8) . . ?
O4N Eu1 N2 164.05(8) . . ?
N1 Eu1 N2 62.13(7) . . ?
O1 Eu1 N3N 77.82(7) . . ?
O2 Eu1 N3N 77.06(7) . . ?
O2N Eu1 N3N 156.36(8) . . ?
O8N Eu1 N3N 25.72(7) . . ?
O1N Eu1 N3N 149.52(8) . . ?
O7N Eu1 N3N 25.50(7) . . ?
O5N Eu1 N3N 120.40(9) . . ?
O4N Eu1 N3N 91.89(8) . . ?
N1 Eu1 N3N 93.99(7) . . ?
N2 Eu1 N3N 90.51(7) . . ?
O1 Eu1 N1N 96.42(8) . . ?
O2 Eu1 N1N 108.97(8) . . ?
O2N Eu1 N1N 25.82(8) . . ?
O8N Eu1 N1N 149.36(8) . . ?
O1N Eu1 N1N 25.88(8) . . ?
O7N Eu1 N1N 158.47(8) . . ?
O5N Eu1 N1N 66.00(10) . . ?
O4N Eu1 N1N 90.41(9) . . ?
N1 Eu1 N1N 79.55(8) . . ?
N2 Eu1 N1N 89.12(8) . . ?
N3N Eu1 N1N 172.86(8) . . ?
C14 O1 Eu1 118.18(18) . . ?
N1N O1N Eu1 95.82(18) . . ?
C2 N1 C13 119.2(2) . . ?
C2 N1 Eu1 118.06(18) . . ?
C13 N1 Eu1 122.43(18) . . ?
O3N N1N O1N 122.0(3) . . ?
O3N N1N O2N 121.9(3) . . ?
O1N N1N O2N 116.1(3) . . ?
O3N N1N Eu1 171.8(3) . . ?
O1N N1N Eu1 58.30(15) . . ?
O2N N1N Eu1 58.43(16) . . ?
C24 O2 Eu1 121.64(17) . . ?
C11 N2 C12 118.6(2) . . ?
C11 N2 Eu1 119.91(18) . . ?
C12 N2 Eu1 121.32(18) . . ?
N1N O2N Eu1 95.75(19) . . ?
O4N N2N O6N 122.8(4) . . ?
O4N N2N O5N 117.6(3) . . ?
O6N N2N O5N 119.6(4) . . ?
O4N N2N Eu1 59.03(16) . . ?
O6N N2N Eu1 178.1(3) . . ?
O5N N2N Eu1 58.59(16) . . ?
N1 C2 C3 122.4(3) . . ?
N1 C2 C14 111.3(2) . . ?
C3 C2 C14 125.9(3) . . ?
C14 N3 C15 123.1(2) . . ?
C14 N3 C22 117.7(2) . . ?
C15 N3 C22 118.5(2) . . ?
O9N N3N O7N 121.8(3) . . ?
O9N N3N O8N 121.4(3) . . ?
O7N N3N O8N 116.7(2) . . ?
O9N N3N Eu1 179.1(2) . . ?
O7N N3N Eu1 58.42(14) . . ?
O8N N3N Eu1 58.35(14) . . ?
C4 C3 C2 118.4(3) . . ?
C4 C3 H3A 120.8 . . ?
C2 C3 H3A 120.8 . . ?
C24 N4 C25 123.6(2) . . ?
C24 N4 C32 118.7(2) . . ?
C25 N4 C32 116.8(2) . . ?
N2N O4N Eu1 96.2(2) . . ?
C3 C4 C5 121.5(3) . . ?
C3 C4 Cl1 119.2(2) . . ?
C5 C4 Cl1 119.2(2) . . ?
N2N O5N Eu1 95.8(2) . . ?
C13 C5 C4 114.9(2) . . ?
C13 C5 C6 120.0(2) . . ?
C4 C5 C6 125.0(3) . . ?
C7 C6 C5 120.7(3) . . ?
C7 C6 H6A 119.6 . . ?
C5 C6 H6A 119.6 . . ?
N3N O7N Eu1 96.08(16) . . ?
C6 C7 C8 121.1(3) . . ?
C6 C7 H7A 119.5 . . ?
C8 C7 H7A 119.5 . . ?
N3N O8N Eu1 95.92(16) . . ?
C12 C8 C9 115.6(2) . . ?
C12 C8 C7 119.4(3) . . ?
C9 C8 C7 124.9(3) . . ?
C10 C9 C8 121.5(3) . . ?
C10 C9 Cl2 118.7(2) . . ?
C8 C9 Cl2 119.8(2) . . ?
C9 C10 C11 117.6(3) . . ?
C9 C10 H10A 121.2 . . ?
C11 C10 H10A 121.2 . . ?
N2 C11 C10 122.9(3) . . ?
N2 C11 C24 110.8(2) . . ?
C10 C11 C24 126.0(3) . . ?
N2 C12 C8 123.7(3) . . ?
N2 C12 C13 116.4(2) . . ?
C8 C12 C13 119.9(2) . . ?
N1 C13 C5 123.6(2) . . ?
N1 C13 C12 117.5(2) . . ?
C5 C13 C12 118.8(2) . . ?
O1 C14 N3 121.2(3) . . ?
O1 C14 C2 116.8(2) . . ?
N3 C14 C2 122.0(3) . . ?
O1 C14 Eu1 41.57(13) . . ?
N3 C14 Eu1 145.1(2) . . ?
C2 C14 Eu1 84.27(15) . . ?
C16 C15 C20 120.8(3) . . ?
C16 C15 N3 119.7(3) . . ?
C20 C15 N3 119.5(3) . . ?
C15 C16 C17 119.0(3) . . ?
C15 C16 H15A 120.5 . . ?
C17 C16 H15A 120.5 . . ?
C16 C17 C18 121.0(3) . . ?
C16 C17 H16A 119.5 . . ?
C18 C17 H16A 119.5 . . ?
C19 C18 C17 118.5(3) . . ?
C19 C18 C21 120.5(4) . . ?
C17 C18 C21 121.0(4) . . ?
C20 C19 C18 121.5(3) . . ?
C20 C19 H18A 119.2 . . ?
C18 C19 H18A 119.2 . . ?
C19 C20 C15 119.2(3) . . ?
C19 C20 H19A 120.4 . . ?
C15 C20 H19A 120.4 . . ?
C18 C21 H20A 109.5 . . ?
C18 C21 H20B 109.5 . . ?
H20A C21 H20B 109.5 . . ?
C18 C21 H20C 109.5 . . ?
H20A C21 H20C 109.5 . . ?
H20B C21 H20C 109.5 . . ?
N3 C22 C23 112.0(3) . . ?
N3 C22 H21A 109.2 . . ?
C23 C22 H21A 109.2 . . ?
N3 C22 H21B 109.2 . . ?
C23 C22 H21B 109.2 . . ?
H21A C22 H21B 107.9 . . ?
C22 C23 H22A 109.5 . . ?
C22 C23 H22B 109.5 . . ?
H22A C23 H22B 109.5 . . ?
C22 C23 H22C 109.5 . . ?
H22A C23 H22C 109.5 . . ?
H22B C23 H22C 109.5 . . ?
O2 C24 N4 121.5(3) . . ?
O2 C24 C11 116.7(2) . . ?
N4 C24 C11 121.7(3) . . ?
C30 C25 C26 120.4(3) . . ?
C30 C25 N4 119.7(3) . . ?
C26 C25 N4 119.9(3) . . ?
C27 C26 C25 119.1(3) . . ?
C27 C26 H25A 120.4 . . ?
C25 C26 H25A 120.4 . . ?
C26 C27 C28 121.4(3) . . ?
C26 C27 H26A 119.3 . . ?
C28 C27 H26A 119.3 . . ?
C27 C28 C29 118.1(3) . . ?
C27 C28 C31 121.4(3) . . ?
C29 C28 C31 120.4(3) . . ?
C30 C29 C28 121.2(3) . . ?
C30 C29 H28A 119.4 . . ?
C28 C29 H28A 119.4 . . ?
C29 C30 C25 119.7(3) . . ?
C29 C30 H29A 120.1 . . ?
C25 C30 H29A 120.1 . . ?
C28 C31 H30A 109.5 . . ?
C28 C31 H30B 109.5 . . ?
H30A C31 H30B 109.5 . . ?
C28 C31 H30C 109.5 . . ?
H30A C31 H30C 109.5 . . ?
H30B C31 H30C 109.5 . . ?
N4 C32 C33 111.2(3) . . ?
N4 C32 H31A 109.4 . . ?
C33 C32 H31A 109.4 . . ?
N4 C32 H31B 109.4 . . ?
C33 C32 H31B 109.4 . . ?
H31A C32 H31B 108.0 . . ?
C32 C33 H32A 109.5 . . ?
C32 C33 H32B 109.5 . . ?
H32A C33 H32B 109.5 . . ?
C32 C33 H32C 109.5 . . ?
H32A C33 H32C 109.5 . . ?
H32B C33 H32C 109.5 . . ?
N3S C5S C6S 178.2(4) . . ?
C7S C8S H8SA 109.5 . . ?
C7S C8S H8SB 109.5 . . ?
H8SA C8S H8SB 109.5 . . ?
C7S C8S H8SC 109.5 . . ?
H8SA C8S H8SC 109.5 . . ?
H8SB C8S H8SC 109.5 . . ?
N4S C7S C8S 179.8(5) . . ?
C3S C4S H4SA 109.5 . . ?
C3S C4S H4SB 109.5 . . ?
H4SA C4S H4SB 109.5 . . ?
C3S C4S H4SC 109.5 . . ?
H4SA C4S H4SC 109.5 . . ?
H4SB C4S H4SC 109.5 . . ?
C5S C6S H6SA 109.5 . . ?
C5S C6S H6SB 109.5 . . ?
H6SA C6S H6SB 109.5 . . ?
C5S C6S H6SC 109.5 . . ?
H6SA C6S H6SC 109.5 . . ?
H6SB C6S H6SC 109.5 . . ?
N2S C3S C4S 178.5(5) . . ?
N1S C1S C2S 179.0(5) . . ?
C1S C2S H2SC 109.5 . . ?
C1S C2S H2SA 109.5 . . ?
H2SC C2S H2SA 109.5 . . ?
C1S C2S H2SB 109.5 . . ?
H2SC C2S H2SB 109.5 . . ?
H2SA C2S H2SB 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O1N N1N O3N 170.3(4) . . . . ?
Eu1 O1N N1N O2N -9.1(3) . . . . ?
O3N N1N O2N Eu1 -170.3(4) . . . . ?
O1N N1N O2N Eu1 9.1(3) . . . . ?
C13 N1 C2 C3 0.9(4) . . . . ?
Eu1 N1 C2 C3 174.7(2) . . . . ?
C13 N1 C2 C14 -172.2(2) . . . . ?
Eu1 N1 C2 C14 1.6(3) . . . . ?
N1 C2 C3 C4 -0.5(4) . . . . ?
C14 C2 C3 C4 171.6(3) . . . . ?
O6N N2N O4N Eu1 179.2(3) . . . . ?
O5N N2N O4N Eu1 -1.1(3) . . . . ?
C2 C3 C4 C5 -0.7(4) . . . . ?
C2 C3 C4 Cl1 -178.9(2) . . . . ?
O4N N2N O5N Eu1 1.1(3) . . . . ?
O6N N2N O5N Eu1 -179.2(3) . . . . ?
C3 C4 C5 C13 1.4(4) . . . . ?
Cl1 C4 C5 C13 179.6(2) . . . . ?
C3 C4 C5 C6 -175.6(3) . . . . ?
Cl1 C4 C5 C6 2.6(4) . . . . ?
C13 C5 C6 C7 0.5(4) . . . . ?
C4 C5 C6 C7 177.4(3) . . . . ?
O9N N3N O7N Eu1 179.0(3) . . . . ?
O8N N3N O7N Eu1 -1.8(3) . . . . ?
C5 C6 C7 C8 -0.2(4) . . . . ?
O9N N3N O8N Eu1 -179.0(3) . . . . ?
O7N N3N O8N Eu1 1.8(3) . . . . ?
C6 C7 C8 C12 0.0(4) . . . . ?
C6 C7 C8 C9 -178.5(3) . . . . ?
C12 C8 C9 C10 0.2(4) . . . . ?
C7 C8 C9 C10 178.8(3) . . . . ?
C12 C8 C9 Cl2 -178.2(2) . . . . ?
C7 C8 C9 Cl2 0.4(4) . . . . ?
C8 C9 C10 C11 -0.4(4) . . . . ?
Cl2 C9 C10 C11 178.0(2) . . . . ?
C12 N2 C11 C10 2.2(4) . . . . ?
Eu1 N2 C11 C10 -173.1(2) . . . . ?
C12 N2 C11 C24 177.0(2) . . . . ?
Eu1 N2 C11 C24 1.7(3) . . . . ?
C9 C10 C11 N2 -0.8(4) . . . . ?
C9 C10 C11 C24 -174.8(3) . . . . ?
C11 N2 C12 C8 -2.5(4) . . . . ?
Eu1 N2 C12 C8 172.7(2) . . . . ?
C11 N2 C12 C13 -179.8(2) . . . . ?
Eu1 N2 C12 C13 -4.6(3) . . . . ?
C9 C8 C12 N2 1.3(4) . . . . ?
C7 C8 C12 N2 -177.4(3) . . . . ?
C9 C8 C12 C13 178.5(2) . . . . ?
C7 C8 C12 C13 -0.1(4) . . . . ?
C2 N1 C13 C5 -0.1(4) . . . . ?
Eu1 N1 C13 C5 -173.6(2) . . . . ?
C2 N1 C13 C12 176.8(2) . . . . ?
Eu1 N1 C13 C12 3.3(3) . . . . ?
C4 C5 C13 N1 -1.0(4) . . . . ?
C6 C5 C13 N1 176.1(3) . . . . ?
C4 C5 C13 C12 -177.8(2) . . . . ?
C6 C5 C13 C12 -0.7(4) . . . . ?
N2 C12 C13 N1 0.9(4) . . . . ?
C8 C12 C13 N1 -176.5(2) . . . . ?
N2 C12 C13 C5 177.9(2) . . . . ?
C8 C12 C13 C5 0.5(4) . . . . ?
Eu1 O1 C14 N3 139.7(2) . . . . ?
Eu1 O1 C14 C2 -42.4(3) . . . . ?
C15 N3 C14 O1 -167.4(3) . . . . ?
C22 N3 C14 O1 2.9(4) . . . . ?
C15 N3 C14 C2 14.9(4) . . . . ?
C22 N3 C14 C2 -174.9(3) . . . . ?
C15 N3 C14 Eu1 -118.7(3) . . . . ?
C22 N3 C14 Eu1 51.6(5) . . . . ?
N1 C2 C14 O1 25.6(4) . . . . ?
C3 C2 C14 O1 -147.2(3) . . . . ?
N1 C2 C14 N3 -156.5(3) . . . . ?
C3 C2 C14 N3 30.7(4) . . . . ?
N1 C2 C14 Eu1 -1.1(2) . . . . ?
C3 C2 C14 Eu1 -173.9(3) . . . . ?
C14 N3 C15 C16 55.1(4) . . . . ?
C22 N3 C15 C16 -115.1(3) . . . . ?
C14 N3 C15 C20 -125.4(3) . . . . ?
C22 N3 C15 C20 64.4(4) . . . . ?
C20 C15 C16 C17 0.1(5) . . . . ?
N3 C15 C16 C17 179.6(3) . . . . ?
C15 C16 C17 C18 -1.1(5) . . . . ?
C16 C17 C18 C19 1.3(5) . . . . ?
C16 C17 C18 C21 -177.3(3) . . . . ?
C17 C18 C19 C20 -0.5(5) . . . . ?
C21 C18 C19 C20 178.1(3) . . . . ?
C18 C19 C20 C15 -0.4(5) . . . . ?
C16 C15 C20 C19 0.6(5) . . . . ?
N3 C15 C20 C19 -178.8(3) . . . . ?
C14 N3 C22 C23 -81.3(3) . . . . ?
C15 N3 C22 C23 89.5(3) . . . . ?
Eu1 O2 C24 N4 -144.3(2) . . . . ?
Eu1 O2 C24 C11 37.0(3) . . . . ?
C25 N4 C24 O2 165.5(3) . . . . ?
C32 N4 C24 O2 -2.8(4) . . . . ?
C25 N4 C24 C11 -15.8(4) . . . . ?
C32 N4 C24 C11 175.8(3) . . . . ?
N2 C11 C24 O2 -23.7(4) . . . . ?
C10 C11 C24 O2 150.8(3) . . . . ?
N2 C11 C24 N4 157.6(3) . . . . ?
C10 C11 C24 N4 -27.9(4) . . . . ?
C24 N4 C25 C30 -56.1(4) . . . . ?
C32 N4 C25 C30 112.5(3) . . . . ?
C24 N4 C25 C26 125.5(3) . . . . ?
C32 N4 C25 C26 -65.9(4) . . . . ?
C30 C25 C26 C27 1.6(4) . . . . ?
N4 C25 C26 C27 180.0(3) . . . . ?
C25 C26 C27 C28 0.2(5) . . . . ?
C26 C27 C28 C29 -0.8(5) . . . . ?
C26 C27 C28 C31 -178.8(3) . . . . ?
C27 C28 C29 C30 -0.4(5) . . . . ?
C31 C28 C29 C30 177.7(3) . . . . ?
C28 C29 C30 C25 2.1(5) . . . . ?
C26 C25 C30 C29 -2.7(4) . . . . ?
N4 C25 C30 C29 178.9(3) . . . . ?
C24 N4 C32 C33 84.8(3) . . . . ?
C25 N4 C32 C33 -84.4(3) . . . . ?

_refine_diff_density_max         1.292
_refine_diff_density_min         -0.995
_refine_diff_density_rms         0.106



