# Supplementary Information (SI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_compound1
_database_code_depnum_ccdc_archive 'CCDC 2381276'
loop_
_audit_author_name
_audit_author_address
'shen yanglin'
;Henan University of Engineering
China
;
_audit_update_record             
;
2024-11-18 deposited with the CCDC.	2024-11-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C102 H126 Ag5.81 Cu5.20 F12 O P8 S9'
_chemical_formula_weight         3088.60

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   18.2666(13)
_cell_length_b                   21.1885(14)
_cell_length_c                   21.1999(14)
_cell_angle_alpha                60.445(2)
_cell_angle_beta                 64.889(2)
_cell_angle_gamma                86.266(2)
_cell_volume                     6353.8(8)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    9774
_cell_measurement_theta_min      2.9316
_cell_measurement_theta_max      23.5527

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.614
_exptl_crystal_F_000             3083
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.05
_exptl_absorpt_coefficient_mu    2.031
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.6661
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            86632
_diffrn_reflns_av_unetI/netI     0.0531
_diffrn_reflns_av_R_equivalents  0.0634
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         2.860
_diffrn_reflns_theta_max         23.256
_diffrn_reflns_theta_full        23.256
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             18212
_reflns_number_gt                12483
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Apex3 (Bruker, 2015)'
_computing_cell_refinement       'SAINT (Bruker, 2014)'
_computing_data_reduction        'SAINT (Bruker, 2014)'
_computing_structure_solution    'SHELXTL XT-2014/4 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0742P)²+40.1739P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         18212
_refine_ls_number_parameters     1510
_refine_ls_number_restraints     811
_refine_ls_R_factor_all          0.0935
_refine_ls_R_factor_gt           0.0543
_refine_ls_wR_factor_ref         0.1647
_refine_ls_wR_factor_gt          0.1388
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_restrained_S_all      5.874
_refine_ls_shift/su_max          0.096
_refine_ls_shift/su_mean         0.002

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.32345(5) 0.36203(4) 0.47971(4) 0.0476(2) Uani 1 1 d . . . . .
Ag2 Ag 0.1856(5) 0.2896(4) 0.4718(3) 0.0471(7) Uani 0.7581 1 d . . P A 1
Ag3 Ag 0.32379(5) 0.37318(4) 0.28328(5) 0.0511(2) Uani 1 1 d . . . . .
Ag5 Ag 0.32458(5) 0.17998(4) 0.46599(5) 0.0585(2) Uani 1 1 d . . . . .
Cu1 Cu 0.2293(2) 0.5133(2) 0.3257(2) 0.0367(6) Uani 0.836 1 d . . P A 1
Ag9 Ag 0.2188(9) 0.5162(8) 0.3125(9) 0.0367(6) Uani 0.164 1 d . . P A 2
Cu2 Cu 0.4060(8) 0.5365(6) 0.2370(8) 0.0317(12) Uani 0.7445 1 d . . P A 1
Ag12 Ag 0.3937(16) 0.5260(13) 0.2453(15) 0.0317(12) Uani 0.2555 1 d . . P A 2
Cu3 Cu 0.3968(7) 0.2378(4) 0.5949(6) 0.0297(10) Uani 0.695 1 d . . P A 1
Ag6 Ag 0.3980(11) 0.2205(6) 0.5980(10) 0.0297(10) Uani 0.305 1 d . . P A 2
Cu4 Cu 0.4473(12) 0.3233(9) 0.3585(8) 0.0384(15) Uani 0.7835 1 d . . P A 1
Ag14 Ag 0.448(3) 0.323(2) 0.349(2) 0.0384(15) Uani 0.2165 1 d . . P A 2
Cu5 Cu 0.2100(4) 0.2116(3) 0.6844(4) 0.0429(6) Uani 0.4815 1 d . . P A 1
Ag7 Ag 0.2250(2) 0.19088(16) 0.6811(2) 0.0429(6) Uani 0.5185 1 d . . P A 2
Cu8 Cu 0.2102(7) 0.1554(8) 0.3741(8) 0.0389(13) Uani 0.6624 1 d . . P A 1
Ag8 Ag 0.2283(9) 0.1517(10) 0.3646(10) 0.0389(13) Uani 0.3376 1 d . . P A 2
Cu9 Cu 0.3928(11) 0.1752(8) 0.3037(7) 0.0359(13) Uani 0.7509 1 d . . P A 1
Ag11 Ag 0.400(2) 0.1821(17) 0.2897(14) 0.0359(13) Uani 0.2491 1 d . . P A 2
S1 S 0.31893(16) 0.49074(14) 0.37939(15) 0.0476(2) Uani 1 1 d . . . . .
S2 S 0.18935(17) 0.40080(14) 0.35272(17) 0.0518(6) Uani 1 1 d . . . . .
S3 S 0.18666(16) 0.28578(16) 0.58664(17) 0.0571(7) Uani 1 1 d . . . . .
S4 S 0.18650(18) 0.17246(14) 0.47467(16) 0.0554(7) Uani 1 1 d . . . . .
S5 S 0.45902(16) 0.43326(12) 0.24717(14) 0.0442(6) Uani 1 1 d . . . . .
S6 S 0.45772(17) 0.22174(13) 0.34498(16) 0.0487(6) Uani 1 1 d . . . . .
S7 S 0.31012(16) 0.14706(13) 0.60331(15) 0.0464(6) Uani 1 1 d . . . . .
S8 S 0.31389(15) 0.26736(13) 0.26229(13) 0.0406(5) Uani 1 1 d . . . . .
S9 S 0.45536(16) 0.31874(12) 0.46130(14) 0.0436(6) Uani 1 1 d . . . . .
P2 P 0.2662(2) -0.03550(15) 1.10567(18) 0.0622(8) Uani 1 1 d D . . . .
P3 P 0.21236(15) 0.14639(15) 0.80806(15) 0.0469(6) Uani 1 1 d . . . . .
P4 P 0.39278(14) 0.21414(14) 0.71204(14) 0.0407(6) Uani 1 1 d . . . . .
P5 P 0.21908(15) 0.63225(14) 0.25832(16) 0.0432(6) Uani 1 1 d D . . . .
P6 P 0.39835(15) 0.64599(13) 0.14743(14) 0.0385(6) Uani 1 1 d . . . . .
P7 P 0.20781(16) 0.07599(15) 0.32916(16) 0.0473(6) Uani 1 1 d D . . . .
P8 P 0.39019(16) 0.07994(14) 0.28426(16) 0.0440(6) Uani 1 1 d . . . . .
F1 F 0.2100(7) -0.0708(6) 1.0889(7) 0.154(4) Uani 1 1 d D . . . .
F2 F 0.3129(6) -0.1005(4) 1.1109(6) 0.114(3) Uani 1 1 d D . . . .
F3 F 0.2099(7) -0.0843(5) 1.1987(5) 0.152(4) Uani 1 1 d D . . . .
F4 F 0.3190(7) -0.0022(5) 1.1246(6) 0.154(4) Uani 1 1 d D . . . .
F5 F 0.2141(7) 0.0274(5) 1.1009(6) 0.146(4) Uani 1 1 d . . . . .
F6 F 0.3160(6) 0.0138(4) 1.0122(4) 0.116(3) Uani 1 1 d D . . . .
O1 O 0.1776(17) 0.4035(15) 0.986(2) 0.111(7) Uani 0.3989 1 d . U P B 1
O1A O 0.112(3) 0.450(3) 1.079(3) 0.120(10) Uani 0.2095 1 d . U P C 2
C1 C 0.1685(6) 0.6642(6) 0.3289(7) 0.053(3) Uani 1 1 d . . . . .
C2 C 0.1386(9) 0.6128(8) 0.4126(8) 0.089(4) Uani 1 1 d . . . . .
H2 H 0.1451 0.5629 0.4304 0.107 Uiso 1 1 calc R U . . .
C3 C 0.1005(10) 0.6336(9) 0.4685(9) 0.109(5) Uani 1 1 d . . . . .
H3 H 0.0776 0.5982 0.5250 0.131 Uiso 1 1 calc R U . . .
C4 C 0.0958(9) 0.7048(9) 0.4423(9) 0.093(4) Uani 1 1 d . . . . .
H4 H 0.0708 0.7191 0.4816 0.111 Uiso 1 1 calc R U . . .
C5 C 0.1249(7) 0.7579(7) 0.3623(9) 0.075(4) Uani 1 1 d . . . . .
H5 H 0.1200 0.8079 0.3461 0.091 Uiso 1 1 calc R U . . .
C6 C 0.1624(7) 0.7365(6) 0.3042(8) 0.066(3) Uani 1 1 d . . . . .
H6 H 0.1834 0.7722 0.2479 0.080 Uiso 1 1 calc R U . . .
C7 C 0.1700(7) 0.6644(6) 0.1911(7) 0.059(3) Uani 1 1 d . . . . .
C8 C 0.1922(8) 0.7307(8) 0.1233(8) 0.081(4) Uani 1 1 d . . . . .
H8 H 0.2345 0.7661 0.1090 0.097 Uiso 1 1 calc R U . . .
C9 C 0.1545(10) 0.7486(10) 0.0737(10) 0.114(6) Uani 1 1 d . . . . .
H9 H 0.1719 0.7948 0.0243 0.136 Uiso 1 1 calc R U . . .
C10 C 0.0906(11) 0.6970(12) 0.0983(12) 0.115(6) Uani 1 1 d . . . . .
H10 H 0.0663 0.7073 0.0633 0.137 Uiso 1 1 calc R U . . .
C11 C 0.0603(11) 0.6302(10) 0.1728(12) 0.117(6) Uani 1 1 d . . . . .
H11 H 0.0131 0.5977 0.1911 0.140 Uiso 1 1 calc R U . . .
C12 C 0.1011(9) 0.6139(8) 0.2180(10) 0.093(4) Uani 1 1 d . . . . .
H12 H 0.0835 0.5683 0.2680 0.111 Uiso 1 1 calc R U . . .
C13 C 0.3675(5) 0.6468(5) 0.0761(5) 0.039(2) Uani 1 1 d . . . . .
C14 C 0.3779(7) 0.7106(6) 0.0043(6) 0.056(3) Uani 1 1 d . . . . .
H14 H 0.4050 0.7562 -0.0111 0.067 Uiso 1 1 calc R U . . .
C15 C 0.3491(8) 0.7075(7) -0.0441(7) 0.075(4) Uani 1 1 d . . . . .
H15 H 0.3557 0.7513 -0.0926 0.090 Uiso 1 1 calc R U . . .
C16 C 0.3110(7) 0.6424(7) -0.0238(7) 0.066(3) Uani 1 1 d . . . . .
H16 H 0.2915 0.6411 -0.0583 0.080 Uiso 1 1 calc R U . . .
C17 C 0.3007(7) 0.5796(6) 0.0454(6) 0.057(3) Uani 1 1 d . . . . .
H17 H 0.2735 0.5342 0.0601 0.068 Uiso 1 1 calc R U . . .
C18 C 0.3298(6) 0.5819(5) 0.0938(6) 0.049(2) Uani 1 1 d . . . . .
H18 H 0.3239 0.5373 0.1414 0.058 Uiso 1 1 calc R U . . .
C19 C 0.4945(6) 0.7142(5) 0.0859(6) 0.046(2) Uani 1 1 d . . . . .
C20 C 0.4970(8) 0.7888(6) 0.0577(9) 0.089(4) Uani 1 1 d . . . . .
H20 H 0.4472 0.8073 0.0701 0.106 Uiso 1 1 calc R U . . .
C21 C 0.5705(8) 0.8361(7) 0.0123(9) 0.099(5) Uani 1 1 d . . . . .
H21 H 0.5722 0.8867 -0.0036 0.118 Uiso 1 1 calc R U . . .
C22 C 0.6419(7) 0.8099(8) -0.0102(7) 0.079(4) Uani 1 1 d . . . . .
H22 H 0.6930 0.8433 -0.0450 0.095 Uiso 1 1 calc R U . . .
C23 C 0.6408(7) 0.7370(8) 0.0166(7) 0.068(3) Uani 1 1 d . . . . .
H23 H 0.6907 0.7191 0.0018 0.082 Uiso 1 1 calc R U . . .
C24 C 0.5668(6) 0.6893(6) 0.0653(6) 0.048(2) Uani 1 1 d . . . . .
H24 H 0.5658 0.6380 0.0850 0.058 Uiso 1 1 calc R U . . .
C25 C 0.4826(6) 0.0769(5) 0.2062(6) 0.048(2) Uani 1 1 d . . . . .
C26 C 0.5566(7) 0.0985(6) 0.1974(7) 0.062(3) Uani 1 1 d . . . . .
H26 H 0.5585 0.1159 0.2304 0.074 Uiso 1 1 calc R U . . .
C27 C 0.6301(8) 0.0954(7) 0.1402(8) 0.072(3) Uani 1 1 d . . . . .
H27 H 0.6811 0.1090 0.1362 0.087 Uiso 1 1 calc R U . . .
C28 C 0.6295(8) 0.0733(6) 0.0907(8) 0.074(3) Uani 1 1 d . . . . .
H28 H 0.6795 0.0716 0.0518 0.088 Uiso 1 1 calc R U . . .
C29 C 0.5541(8) 0.0529(8) 0.0976(9) 0.094(5) Uani 1 1 d . . . . .
H29 H 0.5528 0.0390 0.0618 0.112 Uiso 1 1 calc R U . . .
C30 C 0.4816(8) 0.0529(8) 0.1560(9) 0.089(4) Uani 1 1 d . . . . .
H30 H 0.4305 0.0365 0.1621 0.107 Uiso 1 1 calc R U . . .
C31 C 0.3658(7) -0.0092(5) 0.3777(6) 0.051(3) Uani 1 1 d . . . . .
C32 C 0.3237(7) -0.0134(5) 0.4509(6) 0.055(3) Uani 1 1 d . . . . .
H32 H 0.3114 0.0305 0.4517 0.066 Uiso 1 1 calc R U . . .
C33 C 0.2990(8) -0.0784(6) 0.5225(7) 0.065(3) Uani 1 1 d . . . . .
H33 H 0.2681 -0.0804 0.5727 0.079 Uiso 1 1 calc R U . . .
C34 C 0.3201(9) -0.1424(6) 0.5209(8) 0.077(4) Uani 1 1 d . . . . .
H34 H 0.3041 -0.1885 0.5702 0.092 Uiso 1 1 calc R U . . .
C35 C 0.3628(10) -0.1385(7) 0.4500(9) 0.086(4) Uani 1 1 d . . . . .
H35 H 0.3771 -0.1823 0.4497 0.104 Uiso 1 1 calc R U . . .
C36 C 0.3869(8) -0.0733(6) 0.3770(7) 0.065(3) Uani 1 1 d . . . . .
H36 H 0.4173 -0.0720 0.3271 0.078 Uiso 1 1 calc R U . . .
C37 C 0.1651(19) -0.0208(7) 0.4029(14) 0.065(3) Uani 0.495 1 d DG U P A 1
C38 C 0.1052(17) -0.0408(8) 0.4806(16) 0.079(4) Uani 0.495 1 d G U P A 1
H38 H 0.0839 -0.0039 0.4926 0.095 Uiso 0.495 1 calc R U P A 1
C39 C 0.0764(13) -0.1150(9) 0.5407(11) 0.086(5) Uani 0.495 1 d G U P A 1
H39 H 0.0355 -0.1287 0.5938 0.103 Uiso 0.495 1 calc R U P A 1
C40 C 0.1076(13) -0.1690(6) 0.5231(9) 0.080(5) Uani 0.495 1 d G U P A 1
H40 H 0.0879 -0.2197 0.5642 0.096 Uiso 0.495 1 calc R U P A 1
C41 C 0.1675(13) -0.1490(9) 0.4454(10) 0.074(5) Uani 0.495 1 d G U P A 1
H41 H 0.1888 -0.1859 0.4334 0.089 Uiso 0.495 1 calc R U P A 1
C42 C 0.1963(15) -0.0748(11) 0.3853(9) 0.068(4) Uani 0.495 1 d G U P A 1
H42 H 0.2372 -0.0611 0.3322 0.082 Uiso 0.495 1 calc R U P A 1
C43 C 0.1486(6) 0.1062(6) 0.2724(6) 0.054(3) Uani 1 1 d . . . . .
C44 C 0.1212(8) 0.1719(8) 0.2549(7) 0.078(4) Uani 1 1 d . . . . .
H44 H 0.1355 0.2013 0.2717 0.094 Uiso 1 1 calc R U . . .
C45 C 0.0754(9) 0.1962(10) 0.2152(9) 0.100(5) Uani 1 1 d . . . . .
H45 H 0.0584 0.2423 0.2035 0.120 Uiso 1 1 calc R U . . .
C46 C 0.0539(8) 0.1552(11) 0.1921(8) 0.096(5) Uani 1 1 d . . . . .
H46 H 0.0194 0.1720 0.1660 0.115 Uiso 1 1 calc R U . . .
C47 C 0.0802(8) 0.0886(9) 0.2052(7) 0.086(4) Uani 1 1 d . . . . .
H47 H 0.0661 0.0610 0.1864 0.103 Uiso 1 1 calc R U . . .
C48 C 0.1285(7) 0.0632(8) 0.2470(7) 0.072(3) Uani 1 1 d . . . . .
H48 H 0.1471 0.0177 0.2577 0.087 Uiso 1 1 calc R U . . .
C49 C 0.4865(5) 0.1974(5) 0.7245(6) 0.040(2) Uani 1 1 d . . . . .
C50 C 0.5601(6) 0.2370(5) 0.6560(7) 0.053(3) Uani 1 1 d . . . . .
H50 H 0.5609 0.2697 0.6049 0.064 Uiso 1 1 calc R U . . .
C51 C 0.6336(6) 0.2281(7) 0.6629(9) 0.075(4) Uani 1 1 d . . . . .
H51 H 0.6840 0.2574 0.6166 0.090 Uiso 1 1 calc R U . . .
C52 C 0.6344(7) 0.1785(7) 0.7347(9) 0.069(3) Uani 1 1 d . . . . .
H52 H 0.6848 0.1712 0.7381 0.083 Uiso 1 1 calc R U . . .
C53 C 0.5624(8) 0.1404(8) 0.8003(8) 0.088(4) Uani 1 1 d . . . . .
H53 H 0.5623 0.1065 0.8508 0.106 Uiso 1 1 calc R U . . .
C54 C 0.4876(7) 0.1489(8) 0.7968(7) 0.083(4) Uani 1 1 d . . . . .
H54 H 0.4375 0.1211 0.8445 0.100 Uiso 1 1 calc R U . . .
C55 C 0.3630(5) 0.2905(5) 0.7270(5) 0.041(2) Uani 1 1 d . . . . .
C56 C 0.3339(6) 0.3457(5) 0.6765(5) 0.047(2) Uani 1 1 d . . . . .
H56 H 0.3325 0.3432 0.6335 0.057 Uiso 1 1 calc R U . . .
C57 C 0.3076(7) 0.4029(6) 0.6874(6) 0.059(3) Uani 1 1 d . . . . .
H57 H 0.2880 0.4394 0.6523 0.071 Uiso 1 1 calc R U . . .
C58 C 0.3095(7) 0.4079(6) 0.7493(6) 0.057(3) Uani 1 1 d . . . . .
H58 H 0.2900 0.4469 0.7581 0.068 Uiso 1 1 calc R U . . .
C59 C 0.3401(7) 0.3554(6) 0.7979(6) 0.062(3) Uani 1 1 d . . . . .
H59 H 0.3438 0.3597 0.8390 0.074 Uiso 1 1 calc R U . . .
C60 C 0.3658(6) 0.2965(6) 0.7884(6) 0.049(2) Uani 1 1 d . . . . .
H60 H 0.3853 0.2602 0.8237 0.059 Uiso 1 1 calc R U . . .
C61 C 0.1738(6) 0.1899(5) 0.8685(6) 0.048(2) Uani 1 1 d . . . . .
C62 C 0.1427(7) 0.2528(6) 0.8391(7) 0.063(3) Uani 1 1 d . . . . .
H62 H 0.1405 0.2720 0.7890 0.076 Uiso 1 1 calc R U . . .
C63 C 0.1148(8) 0.2879(8) 0.8820(9) 0.084(4) Uani 1 1 d . . . . .
H63 H 0.0936 0.3317 0.8609 0.101 Uiso 1 1 calc R U . . .
C64 C 0.1167(8) 0.2611(9) 0.9555(9) 0.087(4) Uani 1 1 d . . . . .
H64 H 0.0965 0.2855 0.9853 0.104 Uiso 1 1 calc R U . . .
C65 C 0.1488(8) 0.1982(9) 0.9839(7) 0.085(4) Uani 1 1 d . . . . .
H65 H 0.1514 0.1790 1.0339 0.101 Uiso 1 1 calc R U . . .
C66 C 0.1774(6) 0.1628(7) 0.9408(6) 0.061(3) Uani 1 1 d . . . . .
H66 H 0.1996 0.1194 0.9610 0.074 Uiso 1 1 calc R U . . .
C67 C 0.1509(6) 0.0541(6) 0.8747(6) 0.055(3) Uani 1 1 d . . . . .
C68 C 0.0918(9) 0.0373(8) 0.8593(9) 0.098(5) Uani 1 1 d . . . . .
H68 H 0.0860 0.0727 0.8125 0.118 Uiso 1 1 calc R U . . .
C69 C 0.0404(11) -0.0305(10) 0.9111(12) 0.129(7) Uani 1 1 d . . . . .
H69 H 0.0000 -0.0417 0.8992 0.155 Uiso 1 1 calc R U . . .
C70 C 0.0469(9) -0.0806(8) 0.9777(10) 0.098(5) Uani 1 1 d . . . . .
H70 H 0.0115 -0.1273 1.0126 0.117 Uiso 1 1 calc R U . . .
C71 C 0.1015(10) -0.0659(7) 0.9956(9) 0.103(5) Uani 1 1 d . . . . .
H71 H 0.1031 -0.1013 1.0447 0.124 Uiso 1 1 calc R U . . .
C72 C 0.1574(9) 0.0008(7) 0.9439(8) 0.090(4) Uani 1 1 d . . . . .
H72 H 0.1990 0.0096 0.9557 0.108 Uiso 1 1 calc R U . . .
C73 C 0.3148(5) 0.1344(5) 0.8039(6) 0.045(2) Uani 1 1 d . . . . .
H73A H 0.3146 0.1298 0.8528 0.054 Uiso 1 1 calc R U . . .
H73B H 0.3284 0.0887 0.8033 0.054 Uiso 1 1 calc R U . . .
C74 C 0.3220(5) 0.6904(5) 0.1939(5) 0.040(2) Uani 1 1 d . . . . .
H74A H 0.3199 0.7383 0.1506 0.048 Uiso 1 1 calc R U . . .
H74B H 0.3391 0.7003 0.2272 0.048 Uiso 1 1 calc R U . . .
C75 C 0.3090(6) 0.0751(6) 0.2567(6) 0.047(2) Uani 1 1 d . . . . .
H75A H 0.3062 0.0293 0.2552 0.057 Uiso 1 1 calc R U . . .
H75B H 0.3228 0.1175 0.2016 0.057 Uiso 1 1 calc R U . . .
C76 C 0.1148(13) 0.0260(9) 0.6050(19) 0.084(3) Uani 0.5876 1 d D U P D 1
H76A H 0.0896 0.0153 0.5779 0.126 Uiso 0.5876 1 calc R U P D 1
H76B H 0.0821 -0.0050 0.6640 0.126 Uiso 0.5876 1 calc R U P D 1
H76C H 0.1708 0.0157 0.5891 0.126 Uiso 0.5876 1 calc R U P D 1
C77 C 0.1174(7) 0.1043(6) 0.5809(8) 0.084(3) Uani 1 1 d D . . . .
C78 C 0.5346(5) 0.4358(5) 0.1553(5) 0.046(2) Uani 1 1 d D . . . .
H78 H 0.5313 0.3846 0.1650 0.055 Uiso 1 1 calc R U . . .
C79 C 0.3325(7) 0.0585(6) 0.6648(8) 0.083(4) Uani 1 1 d D . . . .
C80 C 0.4239(7) 0.0632(7) 0.6353(9) 0.099(5) Uani 1 1 d D . . . .
H80A H 0.4356 0.0146 0.6665 0.148 Uiso 1 1 calc R U . . .
H80B H 0.4451 0.0990 0.6428 0.148 Uiso 1 1 calc R U . . .
H80C H 0.4507 0.0789 0.5776 0.148 Uiso 1 1 calc R U . . .
C81 C 0.2928(12) -0.0018(8) 0.6665(13) 0.147(8) Uani 1 1 d D . . . .
H81A H 0.3350 -0.0262 0.6444 0.221 Uiso 1 1 calc R U . . .
H81B H 0.2632 0.0189 0.6336 0.221 Uiso 1 1 calc R U . . .
H81C H 0.2541 -0.0378 0.7227 0.221 Uiso 1 1 calc R U . . .
C82 C 0.3401(5) 0.2908(5) 0.1585(5) 0.049(2) Uani 1 1 d D . . . .
H82 H 0.3154 0.2478 0.1621 0.058 Uiso 1 1 calc R U . . .
C83 C 0.4324(5) 0.3042(7) 0.1088(6) 0.065(3) Uani 1 1 d D . . . .
H83A H 0.4454 0.3185 0.0531 0.097 Uiso 1 1 calc R U . . .
H83B H 0.4532 0.2590 0.1332 0.097 Uiso 1 1 calc R U . . .
H83C H 0.4584 0.3439 0.1079 0.097 Uiso 1 1 calc R U . . .
C84 C 0.3030(7) 0.3564(6) 0.1200(6) 0.065(3) Uani 1 1 d D . . . .
H84A H 0.3163 0.3680 0.0650 0.098 Uiso 1 1 calc R U . . .
H84B H 0.3254 0.3991 0.1170 0.098 Uiso 1 1 calc R U . . .
H84C H 0.2431 0.3446 0.1528 0.098 Uiso 1 1 calc R U . . .
C85 C 0.5326(6) 0.1750(4) 0.3799(5) 0.052(3) Uani 1 1 d D . . . .
H85 H 0.5312 0.1852 0.4217 0.062 Uiso 1 1 calc R U . . .
C86 C 0.6169(6) 0.2071(7) 0.3087(7) 0.077(4) Uani 1 1 d D . . . .
H86A H 0.6580 0.1847 0.3270 0.116 Uiso 1 1 calc R U . . .
H86B H 0.6281 0.2606 0.2853 0.116 Uiso 1 1 calc R U . . .
H86C H 0.6195 0.1970 0.2675 0.116 Uiso 1 1 calc R U . . .
C87 C 0.5120(7) 0.0926(5) 0.4181(7) 0.067(3) Uani 1 1 d D . . . .
H87A H 0.5538 0.0692 0.4347 0.101 Uiso 1 1 calc R U . . .
H87B H 0.5108 0.0819 0.3785 0.101 Uiso 1 1 calc R U . . .
H87C H 0.4580 0.0732 0.4657 0.101 Uiso 1 1 calc R U . . .
C88 C 0.0359(12) 0.1241(12) 0.6155(16) 0.096(7) Uani 0.5876 1 d D U P D 1
H88A H 0.0442 0.1731 0.6080 0.144 Uiso 0.5876 1 calc R U P D 1
H88B H 0.0056 0.0876 0.6736 0.144 Uiso 0.5876 1 calc R U P D 1
H88C H 0.0044 0.1247 0.5876 0.144 Uiso 0.5876 1 calc R U P D 1
C89 C 0.5167(7) 0.4850(6) 0.0842(5) 0.061(3) Uani 1 1 d D . . . .
H89A H 0.5587 0.4866 0.0352 0.091 Uiso 1 1 calc R U . . .
H89B H 0.5173 0.5350 0.0754 0.091 Uiso 1 1 calc R U . . .
H89C H 0.4624 0.4654 0.0959 0.091 Uiso 1 1 calc R U . . .
C90 C 0.6190(6) 0.4609(7) 0.1401(7) 0.071(3) Uani 1 1 d D . . . .
H90A H 0.6604 0.4647 0.0896 0.106 Uiso 1 1 calc R U . . .
H90B H 0.6297 0.4250 0.1854 0.106 Uiso 1 1 calc R U . . .
H90C H 0.6216 0.5092 0.1353 0.106 Uiso 1 1 calc R U . . .
C91 C 0.5328(5) 0.3987(5) 0.4178(5) 0.039(2) Uani 1 1 d D . . . .
H91 H 0.5310 0.4400 0.3679 0.047 Uiso 1 1 calc R U . . .
C92 C 0.6175(5) 0.3782(6) 0.3935(7) 0.069(3) Uani 1 1 d D . . . .
H92A H 0.6595 0.4217 0.3659 0.104 Uiso 1 1 calc R U . . .
H92B H 0.6265 0.3601 0.3567 0.104 Uiso 1 1 calc R U . . .
H92C H 0.6212 0.3394 0.4422 0.104 Uiso 1 1 calc R U . . .
C93 C 0.5151(6) 0.4242(5) 0.4771(5) 0.049(2) Uani 1 1 d D . . . .
H93A H 0.5591 0.4647 0.4540 0.074 Uiso 1 1 calc R U . . .
H93B H 0.5123 0.3831 0.5281 0.074 Uiso 1 1 calc R U . . .
H93C H 0.4625 0.4414 0.4878 0.074 Uiso 1 1 calc R U . . .
C94 C 0.3453(5) 0.5650(5) 0.3916(5) 0.040(2) Uani 1 1 d . . . . .
H94 H 0.3197 0.6076 0.3665 0.048 Uiso 1 1 calc R U . . .
C95 C 0.4390(7) 0.5902(6) 0.3463(6) 0.059(3) Uani 1 1 d . . . . .
H95A H 0.4536 0.6280 0.3550 0.089 Uiso 1 1 calc R U . . .
H95B H 0.4579 0.6109 0.2881 0.089 Uiso 1 1 calc R U . . .
H95C H 0.4653 0.5479 0.3669 0.089 Uiso 1 1 calc R U . . .
C96 C 0.3100(6) 0.5382(6) 0.4806(6) 0.059(3) Uani 1 1 d . . . . .
H96A H 0.3266 0.5766 0.4874 0.088 Uiso 1 1 calc R U . . .
H96B H 0.3305 0.4935 0.5071 0.088 Uiso 1 1 calc R U . . .
H96C H 0.2499 0.5270 0.5053 0.088 Uiso 1 1 calc R U . . .
C97 C 0.1133(7) 0.3904(5) 0.3217(6) 0.063(3) Uani 1 1 d D . . . .
H97 H 0.0629 0.4062 0.3494 0.076 Uiso 1 1 calc R U . . .
C98 C 0.1427(8) 0.4397(7) 0.2324(6) 0.081(4) Uani 1 1 d D . . . .
H98A H 0.0997 0.4347 0.2183 0.121 Uiso 1 1 calc R U . . .
H98B H 0.1923 0.4258 0.2033 0.121 Uiso 1 1 calc R U . . .
H98C H 0.1553 0.4910 0.2171 0.121 Uiso 1 1 calc R U . . .
C99 C 0.0885(8) 0.3123(5) 0.3469(8) 0.080(4) Uani 1 1 d D . . . .
H99A H 0.0451 0.3098 0.3322 0.120 Uiso 1 1 calc R U . . .
H99B H 0.0679 0.2805 0.4058 0.120 Uiso 1 1 calc R U . . .
H99C H 0.1362 0.2956 0.3192 0.120 Uiso 1 1 calc R U . . .
C100 C 0.1118(6) 0.3331(7) 0.6321(8) 0.097(5) Uani 1 1 d D . . . .
C101 C 0.0365(7) 0.2737(7) 0.7035(7) 0.112(5) Uani 1 1 d D . . . .
H10A H -0.0047 0.2960 0.7298 0.168 Uiso 1 1 calc R U . . .
H10B H 0.0530 0.2354 0.7429 0.168 Uiso 1 1 calc R U . . .
H10C H 0.0130 0.2516 0.6835 0.168 Uiso 1 1 calc R U . . .
C102 C 0.0859(11) 0.3882(8) 0.5695(7) 0.105(7) Uani 0.8401 1 d D . P E 1
H10D H 0.0565 0.3621 0.5573 0.158 Uiso 0.8401 1 calc R U P E 1
H10E H 0.1347 0.4220 0.5198 0.158 Uiso 0.8401 1 calc R U P E 1
H10F H 0.0496 0.4164 0.5909 0.158 Uiso 0.8401 1 calc R U P E 1
C10A C 0.139(3) 0.3745(18) 0.6627(18) 0.112(5) Uani 0.1599 1 d D . P E 2
H10G H 0.1925 0.3640 0.6613 0.168 Uiso 0.1599 1 calc R U P E 2
H10H H 0.0983 0.3584 0.7186 0.168 Uiso 0.1599 1 calc R U P E 2
H10I H 0.1435 0.4276 0.6278 0.168 Uiso 0.1599 1 calc R U P E 2
Cu2A Cu 0.192(3) 0.291(2) 0.4597(18) 0.0471(7) Uani 0.2419 1 d . . P A 2
C88A C 0.0367(15) 0.1070(18) 0.579(2) 0.096(7) Uani 0.4123 1 d D U P D 2
H88D H 0.0307 0.0769 0.5578 0.144 Uiso 0.4123 1 calc R U P D 2
H88E H 0.0338 0.1581 0.5443 0.144 Uiso 0.4123 1 calc R U P D 2
H88F H -0.0077 0.0876 0.6345 0.144 Uiso 0.4123 1 calc R U P D 2
C76A C 0.1482(17) 0.0324(13) 0.592(3) 0.084(3) Uani 0.4123 1 d D U P D 2
H76D H 0.1743 0.0174 0.6284 0.126 Uiso 0.4123 1 calc R U P D 2
H76E H 0.1883 0.0399 0.5395 0.126 Uiso 0.4123 1 calc R U P D 2
H76F H 0.1017 -0.0062 0.6167 0.126 Uiso 0.4123 1 calc R U P D 2
C37A C 0.1598(18) -0.0186(8) 0.4089(13) 0.065(3) Uani 0.505 1 d DG U P A 2
C38A C 0.0931(17) -0.0240(7) 0.4767(16) 0.082(5) Uani 0.505 1 d G U P A 2
H38A H 0.0740 0.0192 0.4754 0.098 Uiso 0.505 1 calc R U P A 2
C39A C 0.0542(13) -0.0928(10) 0.5465(12) 0.090(5) Uani 0.505 1 d G U P A 2
H39A H 0.0086 -0.0965 0.5928 0.109 Uiso 0.505 1 calc R U P A 2
C40A C 0.0820(12) -0.1561(7) 0.5485(9) 0.083(5) Uani 0.505 1 d G U P A 2
H40A H 0.0554 -0.2031 0.5961 0.099 Uiso 0.505 1 calc R U P A 2
C41A C 0.1488(13) -0.1506(8) 0.4807(10) 0.073(4) Uani 0.505 1 d G U P A 2
H41A H 0.1678 -0.1938 0.4820 0.088 Uiso 0.505 1 calc R U P A 2
C42A C 0.1877(14) -0.0818(11) 0.4109(9) 0.068(4) Uani 0.505 1 d G U P A 2
H42A H 0.2333 -0.0781 0.3646 0.081 Uiso 0.505 1 calc R U P A 2
P9 P 0.1302(6) 0.5754(5) 0.6895(6) 0.111(3) Uani 0.3636 1 d G U P F 2
F12 F 0.0632(9) 0.6150(10) 0.7306(11) 0.144(6) Uani 0.3636 1 d G U P F 2
F14 F 0.1693(10) 0.6535(7) 0.6034(8) 0.116(6) Uani 0.3636 1 d G U P F 2
F15 F 0.0670(9) 0.5556(9) 0.6634(11) 0.125(6) Uani 0.3636 1 d G U P F 2
F16 F 0.1973(9) 0.5358(9) 0.6483(10) 0.115(5) Uani 0.3636 1 d G U P F 2
F17 F 0.0912(11) 0.4973(7) 0.7755(8) 0.149(7) Uani 0.3636 1 d G U P F 2
F18 F 0.1935(9) 0.5952(9) 0.7155(10) 0.127(6) Uani 0.3636 1 d G U P F 2
P1 P 0.1294(6) 0.5807(6) 0.6778(7) 0.108(3) Uani 0.3248 1 d G U P G 1
F7 F 0.0530(9) 0.5580(12) 0.7657(8) 0.134(7) Uani 0.3248 1 d G U P G 1
F8 F 0.0889(11) 0.6493(8) 0.6333(12) 0.126(6) Uani 0.3248 1 d G U P G 1
F9 F 0.0791(11) 0.5273(10) 0.6690(13) 0.123(7) Uani 0.3248 1 d G U P G 1
F10 F 0.2058(9) 0.6034(12) 0.5899(8) 0.125(6) Uani 0.3248 1 d G U P G 1
F11 F 0.1699(12) 0.5121(9) 0.7223(12) 0.143(7) Uani 0.3248 1 d G U P G 1
F13 F 0.1797(11) 0.6340(10) 0.6866(12) 0.127(6) Uani 0.3248 1 d G U P G 1
P11 P 0.1313(11) 0.6975(10) 0.7968(11) 0.122(6) Uani 0.1805 1 d G U P H 3
F19 F 0.0498(15) 0.7033(17) 0.8650(16) 0.131(10) Uani 0.1805 1 d G U P H 3
F1A F 0.1572(18) 0.7870(10) 0.7431(17) 0.097(9) Uani 0.1805 1 d G U P H 3
F1B F 0.0793(18) 0.7011(18) 0.7493(19) 0.134(12) Uani 0.1805 1 d G U P H 3
F1C F 0.2128(15) 0.6916(17) 0.7286(17) 0.133(11) Uani 0.1805 1 d G U P H 3
F1D F 0.1054(19) 0.6079(10) 0.8505(18) 0.133(10) Uani 0.1805 1 d G U P H 3
F1E F 0.1833(19) 0.6938(18) 0.8443(19) 0.145(9) Uani 0.1805 1 d G U P H 3
P10 P 0.1655(17) 0.7539(15) 0.8519(16) 0.148(8) Uani 0.1311 1 d G U P I 4
F1F F 0.163(3) 0.692(2) 0.938(2) 0.168(12) Uani 0.1311 1 d G U P I 4
F1G F 0.218(2) 0.816(2) 0.848(2) 0.077(10) Uani 0.1311 1 d G U P I 4
F1H F 0.0806(19) 0.775(3) 0.900(3) 0.147(14) Uani 0.1311 1 d G U P I 4
F1I F 0.168(3) 0.816(2) 0.765(2) 0.132(12) Uani 0.1311 1 d G U P I 4
F1J F 0.113(3) 0.692(2) 0.856(3) 0.138(9) Uani 0.1311 1 d G U P I 4
F1K F 0.250(2) 0.733(3) 0.804(3) 0.165(12) Uani 0.1311 1 d G U P I 4
O1B O 0.169(4) 0.440(4) 0.933(5) 0.112(9) Uani 0.162 1 d . U P J 3
O1C O 0.142(3) 0.417(3) 1.041(3) 0.120(8) Uani 0.2296 1 d . U P K 4


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 S9 2.463(3) . ?
Ag1 S3 2.469(3) . ?
Ag1 S1 2.523(3) . ?
Ag1 Cu4 3.050(17) . ?
Ag1 Ag2 3.138(8) . ?
Ag1 Ag14 3.19(4) . ?
Ag1 Cu2A 3.20(4) . ?
Ag2 S3 2.406(6) . ?
Ag2 S2 2.435(8) . ?
Ag2 S4 2.451(7) . ?
Ag2 Ag3 3.243(5) . ?
Ag2 Ag5 3.333(8) . ?
Ag3 S2 2.477(3) . ?
Ag3 S5 2.480(3) . ?
Ag3 S8 2.523(2) . ?
Ag3 Ag14 3.01(5) . ?
Ag3 Cu2A 3.05(3) . ?
Ag3 Ag12 3.14(2) . ?
Ag3 Cu4 3.135(19) . ?
Ag5 S6 2.454(3) . ?
Ag5 S4 2.460(3) . ?
Ag5 S7 2.530(3) . ?
Ag5 Ag14 3.02(4) . ?
Ag5 Cu4 3.027(17) . ?
Ag5 Cu9 3.176(15) . ?
Ag5 Ag11 3.37(3) . ?
Cu1 P5 2.246(5) . ?
Cu1 S2 2.251(5) . ?
Cu1 S1 2.269(3) . ?
Cu1 Cu2 2.888(14) . ?
Ag9 P5 2.140(15) . ?
Ag9 S2 2.172(16) . ?
Ag9 S1 2.639(11) . ?
Ag9 Ag12 2.86(3) . ?
Cu2 P6 2.201(14) . ?
Cu2 S5 2.281(16) . ?
Cu2 S1 2.414(14) . ?
Ag12 S5 2.22(3) . ?
Ag12 S1 2.29(3) . ?
Ag12 P6 2.33(3) . ?
Cu3 S9 2.232(10) . ?
Cu3 P4 2.246(11) . ?
Cu3 S7 2.461(9) . ?
Cu3 Cu5 3.044(14) . ?
Ag6 S7 2.239(15) . ?
Ag6 P4 2.315(16) . ?
Ag6 S9 2.363(15) . ?
Ag6 Ag7 2.816(18) . ?
Cu4 S9 2.201(14) . ?
Cu4 S6 2.292(17) . ?
Cu4 S5 2.293(16) . ?
Ag14 S6 2.18(4) . ?
Ag14 S5 2.21(4) . ?
Ag14 S9 2.40(4) . ?
Cu5 S3 2.096(7) . ?
Cu5 P3 2.303(7) . ?
Cu5 S7 2.737(5) . ?
Ag7 S7 2.268(3) . ?
Ag7 P3 2.278(4) . ?
Ag7 S3 2.361(4) . ?
Cu8 S4 2.195(15) . ?
Cu8 P7 2.317(15) . ?
Cu8 S8 2.462(14) . ?
Cu8 Cu9 2.98(2) . ?
Ag8 P7 2.19(2) . ?
Ag8 S8 2.353(18) . ?
Ag8 S4 2.384(18) . ?
Ag8 Ag11 2.80(4) . ?
Cu9 S6 2.24(2) . ?
Cu9 P8 2.258(18) . ?
Cu9 S8 2.383(18) . ?
Ag11 P8 2.25(4) . ?
Ag11 S6 2.30(4) . ?
Ag11 S8 2.34(4) . ?
S1 C94 1.838(8) . ?
S2 C97 1.834(10) . ?
S2 Cu2A 2.33(4) . ?
S3 C100 1.861(12) . ?
S3 Cu2A 2.60(3) . ?
S4 C77 1.834(12) . ?
S4 Cu2A 2.37(4) . ?
S5 C78 1.823(9) . ?
S6 C85 1.832(9) . ?
S7 C79 1.824(11) . ?
S8 C82 1.836(8) . ?
S9 C91 1.840(8) . ?
P2 F4 1.511(8) . ?
P2 F6 1.548(7) . ?
P2 F1 1.552(8) . ?
P2 F2 1.554(7) . ?
P2 F3 1.556(8) . ?
P2 F5 1.575(9) . ?
P3 C67 1.815(10) . ?
P3 C61 1.817(11) . ?
P3 C73 1.842(9) . ?
P4 C55 1.806(10) . ?
P4 C49 1.827(9) . ?
P4 C73 1.840(9) . ?
P5 C1 1.815(9) . ?
P5 C7 1.829(11) . ?
P5 C74 1.839(9) . ?
P6 C13 1.816(9) . ?
P6 C74 1.838(8) . ?
P6 C19 1.844(10) . ?
P7 C37 1.807(10) . ?
P7 C37A 1.808(10) . ?
P7 C43 1.813(10) . ?
P7 C75 1.842(9) . ?
P8 C25 1.819(10) . ?
P8 C31 1.832(10) . ?
P8 C75 1.836(9) . ?
C1 C6 1.366(14) . ?
C1 C2 1.408(16) . ?
C2 C3 1.364(17) . ?
C2 H2 0.9500 . ?
C3 C4 1.337(19) . ?
C3 H3 0.9500 . ?
C4 C5 1.363(18) . ?
C4 H4 0.9500 . ?
C5 C6 1.410(16) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C8 1.340(16) . ?
C7 C12 1.421(17) . ?
C8 C9 1.383(19) . ?
C8 H8 0.9500 . ?
C9 C10 1.38(2) . ?
C9 H9 0.9500 . ?
C10 C11 1.40(2) . ?
C10 H10 0.9500 . ?
C11 C12 1.354(19) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C18 1.379(13) . ?
C13 C14 1.393(13) . ?
C14 C15 1.364(15) . ?
C14 H14 0.9500 . ?
C15 C16 1.363(16) . ?
C15 H15 0.9500 . ?
C16 C17 1.354(15) . ?
C16 H16 0.9500 . ?
C17 C18 1.362(13) . ?
C17 H17 0.9500 . ?
C18 H18 0.9500 . ?
C19 C24 1.363(13) . ?
C19 C20 1.384(15) . ?
C20 C21 1.363(16) . ?
C20 H20 0.9500 . ?
C21 C22 1.369(18) . ?
C21 H21 0.9500 . ?
C22 C23 1.357(17) . ?
C22 H22 0.9500 . ?
C23 C24 1.371(15) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C25 C26 1.363(14) . ?
C25 C30 1.395(15) . ?
C26 C27 1.401(16) . ?
C26 H26 0.9500 . ?
C27 C28 1.348(16) . ?
C27 H27 0.9500 . ?
C28 C29 1.395(17) . ?
C28 H28 0.9500 . ?
C29 C30 1.377(17) . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?
C31 C32 1.367(14) . ?
C31 C36 1.393(13) . ?
C32 C33 1.357(14) . ?
C32 H32 0.9500 . ?
C33 C34 1.398(16) . ?
C33 H33 0.9500 . ?
C34 C35 1.328(18) . ?
C34 H34 0.9500 . ?
C35 C36 1.374(16) . ?
C35 H35 0.9500 . ?
C36 H36 0.9500 . ?
C37 C38 1.3900 . ?
C37 C42 1.3900 . ?
C38 C39 1.3900 . ?
C38 H38 0.9500 . ?
C39 C40 1.3900 . ?
C39 H39 0.9500 . ?
C40 C41 1.3900 . ?
C40 H40 0.9500 . ?
C41 C42 1.3900 . ?
C41 H41 0.9500 . ?
C42 H42 0.9500 . ?
C43 C44 1.372(16) . ?
C43 C48 1.393(15) . ?
C44 C45 1.336(17) . ?
C44 H44 0.9500 . ?
C45 C46 1.33(2) . ?
C45 H45 0.9500 . ?
C46 C47 1.39(2) . ?
C46 H46 0.9500 . ?
C47 C48 1.409(17) . ?
C47 H47 0.9500 . ?
C48 H48 0.9500 . ?
C49 C54 1.370(14) . ?
C49 C50 1.381(13) . ?
C50 C51 1.403(15) . ?
C50 H50 0.9500 . ?
C51 C52 1.364(17) . ?
C51 H51 0.9500 . ?
C52 C53 1.339(17) . ?
C52 H52 0.9500 . ?
C53 C54 1.395(16) . ?
C53 H53 0.9500 . ?
C54 H54 0.9500 . ?
C55 C60 1.391(12) . ?
C55 C56 1.400(13) . ?
C56 C57 1.364(14) . ?
C56 H56 0.9500 . ?
C57 C58 1.383(14) . ?
C57 H57 0.9500 . ?
C58 C59 1.375(15) . ?
C58 H58 0.9500 . ?
C59 C60 1.382(14) . ?
C59 H59 0.9500 . ?
C60 H60 0.9500 . ?
C61 C62 1.368(14) . ?
C61 C66 1.376(14) . ?
C62 C63 1.364(17) . ?
C62 H62 0.9500 . ?
C63 C64 1.388(18) . ?
C63 H63 0.9500 . ?
C64 C65 1.374(18) . ?
C64 H64 0.9500 . ?
C65 C66 1.377(17) . ?
C65 H65 0.9500 . ?
C66 H66 0.9500 . ?
C67 C68 1.364(16) . ?
C67 C72 1.392(16) . ?
C68 C69 1.377(19) . ?
C68 H68 0.9500 . ?
C69 C70 1.34(2) . ?
C69 H69 0.9500 . ?
C70 C71 1.308(19) . ?
C70 H70 0.9500 . ?
C71 C72 1.397(17) . ?
C71 H71 0.9500 . ?
C72 H72 0.9500 . ?
C73 H73A 0.9900 . ?
C73 H73B 0.9900 . ?
C74 H74A 0.9900 . ?
C74 H74B 0.9900 . ?
C75 H75A 0.9900 . ?
C75 H75B 0.9900 . ?
C76 C77 1.473(15) . ?
C76 H76A 0.9800 . ?
C76 H76B 0.9800 . ?
C76 H76C 0.9800 . ?
C77 C88 1.492(15) . ?
C77 C88A 1.486(18) . ?
C77 C76A 1.528(17) . ?
C78 C90 1.508(8) . ?
C78 C89 1.514(8) . ?
C78 H78 1.0000 . ?
C79 C81 1.486(9) . ?
C79 C80 1.505(9) . ?
C80 H80A 0.9800 . ?
C80 H80B 0.9800 . ?
C80 H80C 0.9800 . ?
C81 H81A 0.9800 . ?
C81 H81B 0.9800 . ?
C81 H81C 0.9800 . ?
C82 C84 1.513(8) . ?
C82 C83 1.514(8) . ?
C82 H82 1.0000 . ?
C83 H83A 0.9800 . ?
C83 H83B 0.9800 . ?
C83 H83C 0.9800 . ?
C84 H84A 0.9800 . ?
C84 H84B 0.9800 . ?
C84 H84C 0.9800 . ?
C85 C86 1.504(9) . ?
C85 C87 1.510(8) . ?
C85 H85 1.0000 . ?
C86 H86A 0.9800 . ?
C86 H86B 0.9800 . ?
C86 H86C 0.9800 . ?
C87 H87A 0.9800 . ?
C87 H87B 0.9800 . ?
C87 H87C 0.9800 . ?
C88 H88A 0.9800 . ?
C88 H88B 0.9800 . ?
C88 H88C 0.9800 . ?
C89 H89A 0.9800 . ?
C89 H89B 0.9800 . ?
C89 H89C 0.9800 . ?
C90 H90A 0.9800 . ?
C90 H90B 0.9800 . ?
C90 H90C 0.9800 . ?
C91 C93 1.510(8) . ?
C91 C92 1.518(8) . ?
C91 H91 1.0000 . ?
C92 H92A 0.9800 . ?
C92 H92B 0.9800 . ?
C92 H92C 0.9800 . ?
C93 H93A 0.9800 . ?
C93 H93B 0.9800 . ?
C93 H93C 0.9800 . ?
C94 C96 1.502(13) . ?
C94 C95 1.535(13) . ?
C94 H94 1.0000 . ?
C95 H95A 0.9800 . ?
C95 H95B 0.9800 . ?
C95 H95C 0.9800 . ?
C96 H96A 0.9800 . ?
C96 H96B 0.9800 . ?
C96 H96C 0.9800 . ?
C97 C98 1.491(9) . ?
C97 C99 1.500(9) . ?
C97 H97 1.0000 . ?
C98 H98A 0.9800 . ?
C98 H98B 0.9800 . ?
C98 H98C 0.9800 . ?
C99 H99A 0.9800 . ?
C99 H99B 0.9800 . ?
C99 H99C 0.9800 . ?
C100 C102 1.509(8) . ?
C100 C10A 1.525(8) . ?
C100 C101 1.532(8) . ?
C101 H10A 0.9800 . ?
C101 H10B 0.9800 . ?
C101 H10C 0.9800 . ?
C102 H10D 0.9800 . ?
C102 H10E 0.9800 . ?
C102 H10F 0.9800 . ?
C10A H10G 0.9800 . ?
C10A H10H 0.9800 . ?
C10A H10I 0.9800 . ?
C88A H88D 0.9800 . ?
C88A H88E 0.9800 . ?
C88A H88F 0.9800 . ?
C76A H76D 0.9800 . ?
C76A H76E 0.9800 . ?
C76A H76F 0.9800 . ?
C37A C38A 1.3900 . ?
C37A C42A 1.3900 . ?
C38A C39A 1.3900 . ?
C38A H38A 0.9500 . ?
C39A C40A 1.3900 . ?
C39A H39A 0.9500 . ?
C40A C41A 1.3900 . ?
C40A H40A 0.9500 . ?
C41A C42A 1.3900 . ?
C41A H41A 0.9500 . ?
C42A H42A 0.9500 . ?
P9 F15 1.6272 . ?
P9 F12 1.6273 . ?
P9 F17 1.6273 . ?
P9 F16 1.6273 . ?
P9 F14 1.6273 . ?
P9 F18 1.6274 . ?
P1 F13 1.6273 . ?
P1 F7 1.6273 . ?
P1 F11 1.6273 . ?
P1 F10 1.6273 . ?
P1 F8 1.6274 . ?
P1 F9 1.6274 . ?
P11 F1B 1.6272 . ?
P11 F1A 1.6272 . ?
P11 F19 1.6273 . ?
P11 F1C 1.6273 . ?
P11 F1D 1.6274 . ?
P11 F1E 1.6275 . ?
P10 F1G 1.6272 . ?
P10 F1F 1.6273 . ?
P10 F1J 1.6273 . ?
P10 F1H 1.6273 . ?
P10 F1I 1.6273 . ?
P10 F1K 1.6274 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S9 Ag1 S3 125.25(9) . . ?
S9 Ag1 S1 120.58(8) . . ?
S3 Ag1 S1 114.02(9) . . ?
S9 Ag1 Cu4 45.5(3) . . ?
S3 Ag1 Cu4 124.1(3) . . ?
S1 Ag1 Cu4 98.2(3) . . ?
S9 Ag1 Ag2 121.77(15) . . ?
S3 Ag1 Ag2 49.04(11) . . ?
S1 Ag1 Ag2 92.87(15) . . ?
Cu4 Ag1 Ag2 87.0(4) . . ?
S9 Ag1 Ag14 48.2(8) . . ?
S3 Ag1 Ag14 123.2(7) . . ?
S1 Ag1 Ag14 96.8(7) . . ?
S9 Ag1 Cu2A 119.6(7) . . ?
S3 Ag1 Cu2A 52.8(5) . . ?
S1 Ag1 Cu2A 91.7(7) . . ?
Ag14 Ag1 Cu2A 81.3(10) . . ?
S3 Ag2 S2 124.9(3) . . ?
S3 Ag2 S4 116.4(3) . . ?
S2 Ag2 S4 118.7(2) . . ?
S3 Ag2 Ag1 50.83(16) . . ?
S2 Ag2 Ag1 94.9(2) . . ?
S4 Ag2 Ag1 123.6(3) . . ?
S3 Ag2 Ag3 129.6(3) . . ?
S2 Ag2 Ag3 49.24(12) . . ?
S4 Ag2 Ag3 90.16(16) . . ?
Ag1 Ag2 Ag3 78.78(17) . . ?
S3 Ag2 Ag5 91.7(3) . . ?
S2 Ag2 Ag5 124.4(2) . . ?
S4 Ag2 Ag5 47.38(15) . . ?
Ag1 Ag2 Ag5 76.45(19) . . ?
Ag3 Ag2 Ag5 75.36(14) . . ?
S2 Ag3 S5 124.89(8) . . ?
S2 Ag3 S8 114.36(8) . . ?
S5 Ag3 S8 120.51(8) . . ?
S2 Ag3 Ag14 125.0(7) . . ?
S5 Ag3 Ag14 46.1(7) . . ?
S8 Ag3 Ag14 96.0(8) . . ?
S2 Ag3 Cu2A 48.6(8) . . ?
S5 Ag3 Cu2A 120.3(8) . . ?
S8 Ag3 Cu2A 93.9(7) . . ?
Ag14 Ag3 Cu2A 86.7(11) . . ?
S2 Ag3 Ag12 83.7(5) . . ?
S5 Ag3 Ag12 44.7(6) . . ?
S8 Ag3 Ag12 158.3(5) . . ?
Ag14 Ag3 Ag12 81.9(9) . . ?
Cu2A Ag3 Ag12 107.6(8) . . ?
S2 Ag3 Cu4 122.0(3) . . ?
S5 Ag3 Cu4 46.4(3) . . ?
S8 Ag3 Cu4 98.3(3) . . ?
S2 Ag3 Ag2 48.14(16) . . ?
S5 Ag3 Ag2 118.67(15) . . ?
S8 Ag3 Ag2 95.76(13) . . ?
Cu4 Ag3 Ag2 83.8(3) . . ?
S6 Ag5 S4 127.79(9) . . ?
S6 Ag5 S7 123.30(9) . . ?
S4 Ag5 S7 108.73(9) . . ?
S6 Ag5 Ag14 45.5(8) . . ?
S4 Ag5 Ag14 121.0(9) . . ?
S7 Ag5 Ag14 103.8(7) . . ?
S6 Ag5 Cu4 48.1(3) . . ?
S4 Ag5 Cu4 122.6(4) . . ?
S7 Ag5 Cu4 100.0(3) . . ?
S6 Ag5 Cu9 44.7(3) . . ?
S4 Ag5 Cu9 87.9(4) . . ?
S7 Ag5 Cu9 156.5(3) . . ?
Cu4 Ag5 Cu9 83.8(4) . . ?
S6 Ag5 Ag2 120.96(12) . . ?
S4 Ag5 Ag2 47.15(14) . . ?
S7 Ag5 Ag2 92.56(10) . . ?
Cu4 Ag5 Ag2 84.0(4) . . ?
Cu9 Ag5 Ag2 111.0(3) . . ?
S6 Ag5 Ag11 43.1(6) . . ?
S4 Ag5 Ag11 88.7(7) . . ?
S7 Ag5 Ag11 157.3(6) . . ?
Ag14 Ag5 Ag11 77.8(9) . . ?
P5 Cu1 S2 142.19(13) . . ?
P5 Cu1 S1 115.47(18) . . ?
S2 Cu1 S1 102.02(16) . . ?
P5 Cu1 Cu2 95.7(3) . . ?
S2 Cu1 Cu2 102.5(3) . . ?
S1 Cu1 Cu2 54.2(3) . . ?
P5 Ag9 S2 161.1(6) . . ?
P5 Ag9 S1 105.5(5) . . ?
S2 Ag9 S1 93.3(5) . . ?
P5 Ag9 Ag12 96.9(7) . . ?
S2 Ag9 Ag12 96.2(7) . . ?
S1 Ag9 Ag12 49.0(6) . . ?
P6 Cu2 S5 141.9(7) . . ?
P6 Cu2 S1 118.4(7) . . ?
S5 Cu2 S1 99.1(5) . . ?
P6 Cu2 Cu1 86.8(5) . . ?
S5 Cu2 Cu1 115.4(4) . . ?
S1 Cu2 Cu1 49.7(2) . . ?
S5 Ag12 S1 104.6(10) . . ?
S5 Ag12 P6 136.7(12) . . ?
S1 Ag12 P6 117.9(13) . . ?
S5 Ag12 Ag9 125.2(9) . . ?
S1 Ag12 Ag9 60.4(6) . . ?
P6 Ag12 Ag9 85.1(10) . . ?
S5 Ag12 Ag3 51.7(5) . . ?
S1 Ag12 Ag3 90.4(6) . . ?
P6 Ag12 Ag3 130.6(12) . . ?
Ag9 Ag12 Ag3 74.7(6) . . ?
S9 Cu3 P4 142.9(4) . . ?
S9 Cu3 S7 100.3(4) . . ?
P4 Cu3 S7 116.8(4) . . ?
S9 Cu3 Cu5 116.7(5) . . ?
P4 Cu3 Cu5 85.4(4) . . ?
S7 Cu3 Cu5 58.5(3) . . ?
S7 Ag6 P4 123.4(7) . . ?
S7 Ag6 S9 103.2(7) . . ?
P4 Ag6 S9 130.4(5) . . ?
S7 Ag6 Ag7 51.8(4) . . ?
P4 Ag6 Ag7 85.6(5) . . ?
S9 Ag6 Ag7 115.1(6) . . ?
S9 Cu4 S6 120.4(8) . . ?
S9 Cu4 S5 121.6(7) . . ?
S6 Cu4 S5 116.4(6) . . ?
S9 Cu4 Ag5 93.4(5) . . ?
S6 Cu4 Ag5 52.8(3) . . ?
S5 Cu4 Ag5 132.8(8) . . ?
S9 Cu4 Ag1 53.0(3) . . ?
S6 Cu4 Ag1 135.3(7) . . ?
S5 Cu4 Ag1 93.9(6) . . ?
Ag5 Cu4 Ag1 82.5(4) . . ?
S9 Cu4 Ag3 134.8(8) . . ?
S6 Cu4 Ag3 91.8(5) . . ?
S5 Cu4 Ag3 51.6(4) . . ?
Ag5 Cu4 Ag3 81.4(5) . . ?
Ag1 Cu4 Ag3 81.8(5) . . ?
S6 Ag14 S5 125.4(16) . . ?
S6 Ag14 S9 116.5(17) . . ?
S5 Ag14 S9 116.6(17) . . ?
S6 Ag14 Ag3 97.5(14) . . ?
S5 Ag14 Ag3 54.1(10) . . ?
S9 Ag14 Ag3 131.1(17) . . ?
S6 Ag14 Ag5 53.4(8) . . ?
S5 Ag14 Ag5 138(2) . . ?
S9 Ag14 Ag5 89.6(10) . . ?
Ag3 Ag14 Ag5 83.5(12) . . ?
S6 Ag14 Ag1 133.2(15) . . ?
S5 Ag14 Ag1 91.7(14) . . ?
S9 Ag14 Ag1 49.8(7) . . ?
Ag3 Ag14 Ag1 81.4(11) . . ?
Ag5 Ag14 Ag1 80.3(9) . . ?
S3 Cu5 P3 164.3(3) . . ?
S3 Cu5 S7 93.8(2) . . ?
P3 Cu5 S7 101.92(19) . . ?
S3 Cu5 Cu3 99.2(3) . . ?
P3 Cu5 Cu3 91.0(3) . . ?
S7 Cu5 Cu3 50.05(18) . . ?
S7 Ag7 P3 119.33(14) . . ?
S7 Ag7 S3 100.33(16) . . ?
P3 Ag7 S3 139.89(13) . . ?
S7 Ag7 Ag6 50.9(3) . . ?
P3 Ag7 Ag6 97.4(4) . . ?
S3 Ag7 Ag6 103.6(3) . . ?
S4 Cu8 P7 149.4(7) . . ?
S4 Cu8 S8 98.7(6) . . ?
P7 Cu8 S8 109.4(5) . . ?
S4 Cu8 Cu9 98.3(6) . . ?
P7 Cu8 Cu9 90.6(4) . . ?
S8 Cu8 Cu9 50.9(4) . . ?
P7 Ag8 S8 118.5(7) . . ?
P7 Ag8 S4 144.5(8) . . ?
S8 Ag8 S4 96.7(7) . . ?
P7 Ag8 Ag11 100.3(9) . . ?
S8 Ag8 Ag11 53.1(7) . . ?
S4 Ag8 Ag11 105.1(10) . . ?
S6 Cu9 P8 139.7(9) . . ?
S6 Cu9 S8 101.4(7) . . ?
P8 Cu9 S8 118.7(8) . . ?
S6 Cu9 Cu8 119.1(7) . . ?
P8 Cu9 Cu8 90.1(7) . . ?
S8 Cu9 Cu8 53.3(5) . . ?
S6 Cu9 Ag5 50.3(3) . . ?
P8 Cu9 Ag5 130.9(5) . . ?
S8 Cu9 Ag5 86.7(5) . . ?
Cu8 Cu9 Ag5 71.7(4) . . ?
P8 Ag11 S6 136.5(16) . . ?
P8 Ag11 S8 120.9(17) . . ?
S6 Ag11 S8 101.0(14) . . ?
P8 Ag11 Ag8 84.3(12) . . ?
S6 Ag11 Ag8 115.4(12) . . ?
S8 Ag11 Ag8 53.6(8) . . ?
P8 Ag11 Ag5 122.8(9) . . ?
S6 Ag11 Ag5 46.8(5) . . ?
S8 Ag11 Ag5 83.0(9) . . ?
Ag8 Ag11 Ag5 69.9(7) . . ?
C94 S1 Cu1 114.3(3) . . ?
C94 S1 Ag12 107.7(7) . . ?
C94 S1 Cu2 102.5(4) . . ?
Cu1 S1 Cu2 76.1(4) . . ?
C94 S1 Ag1 116.0(3) . . ?
Cu1 S1 Ag1 122.19(14) . . ?
Ag12 S1 Ag1 115.3(7) . . ?
Cu2 S1 Ag1 117.4(4) . . ?
C94 S1 Ag9 115.6(5) . . ?
Ag12 S1 Ag9 70.6(8) . . ?
Ag1 S1 Ag9 122.1(4) . . ?
C97 S2 Ag9 109.1(4) . . ?
C97 S2 Cu1 118.4(3) . . ?
C97 S2 Cu2A 112.9(11) . . ?
Ag9 S2 Cu2A 133.3(10) . . ?
C97 S2 Ag2 113.9(4) . . ?
Cu1 S2 Ag2 120.8(2) . . ?
C97 S2 Ag3 112.8(4) . . ?
Ag9 S2 Ag3 103.3(4) . . ?
Cu1 S2 Ag3 100.60(15) . . ?
Cu2A S2 Ag3 78.7(9) . . ?
Ag2 S2 Ag3 82.62(18) . . ?
C100 S3 Cu5 101.1(4) . . ?
C100 S3 Ag7 112.2(4) . . ?
C100 S3 Ag2 116.6(5) . . ?
Cu5 S3 Ag2 136.6(3) . . ?
C100 S3 Ag1 115.5(4) . . ?
Cu5 S3 Ag1 103.3(2) . . ?
Ag7 S3 Ag1 99.87(14) . . ?
Ag2 S3 Ag1 80.1(2) . . ?
C100 S3 Cu2A 118.4(11) . . ?
Ag7 S3 Cu2A 124.5(9) . . ?
Ag1 S3 Cu2A 78.1(9) . . ?
C77 S4 Cu8 122.5(6) . . ?
C77 S4 Cu2A 108.8(8) . . ?
C77 S4 Ag8 124.3(6) . . ?
Cu2A S4 Ag8 124.3(8) . . ?
C77 S4 Ag2 104.0(4) . . ?
Cu8 S4 Ag2 127.8(4) . . ?
C77 S4 Ag5 106.2(4) . . ?
Cu8 S4 Ag5 101.5(3) . . ?
Cu2A S4 Ag5 84.9(11) . . ?
Ag8 S4 Ag5 94.7(4) . . ?
Ag2 S4 Ag5 85.5(2) . . ?
C78 S5 Ag14 105.7(11) . . ?
C78 S5 Ag12 123.1(7) . . ?
Ag14 S5 Ag12 131.1(12) . . ?
C78 S5 Cu2 119.3(4) . . ?
C78 S5 Cu4 109.1(5) . . ?
Cu2 S5 Cu4 131.1(5) . . ?
C78 S5 Ag3 107.5(3) . . ?
Ag14 S5 Ag3 79.8(12) . . ?
Ag12 S5 Ag3 83.5(6) . . ?
Cu2 S5 Ag3 89.5(3) . . ?
Cu4 S5 Ag3 82.0(5) . . ?
C85 S6 Ag14 110.2(12) . . ?
C85 S6 Cu9 121.0(6) . . ?
C85 S6 Cu4 106.9(6) . . ?
Cu9 S6 Cu4 132.0(7) . . ?
C85 S6 Ag11 121.7(9) . . ?
Ag14 S6 Ag11 127.6(15) . . ?
C85 S6 Ag5 107.1(3) . . ?
Ag14 S6 Ag5 81.1(10) . . ?
Cu9 S6 Ag5 85.0(4) . . ?
Cu4 S6 Ag5 79.1(4) . . ?
Ag11 S6 Ag5 90.1(7) . . ?
C79 S7 Ag6 98.4(5) . . ?
C79 S7 Ag7 111.6(5) . . ?
Ag6 S7 Ag7 77.3(4) . . ?
C79 S7 Cu3 104.1(4) . . ?
C79 S7 Ag5 118.8(4) . . ?
Ag6 S7 Ag5 114.3(4) . . ?
Ag7 S7 Ag5 124.82(13) . . ?
Cu3 S7 Ag5 112.8(3) . . ?
C79 S7 Cu5 116.7(5) . . ?
Cu3 S7 Cu5 71.5(3) . . ?
Ag5 S7 Cu5 120.47(16) . . ?
C82 S8 Ag11 99.1(8) . . ?
C82 S8 Ag8 114.2(6) . . ?
Ag11 S8 Ag8 73.3(8) . . ?
C82 S8 Cu9 104.0(4) . . ?
C82 S8 Cu8 116.7(5) . . ?
Cu9 S8 Cu8 75.9(4) . . ?
C82 S8 Ag3 117.0(3) . . ?
Ag11 S8 Ag3 117.3(9) . . ?
Ag8 S8 Ag3 124.3(4) . . ?
Cu9 S8 Ag3 116.2(5) . . ?
Cu8 S8 Ag3 118.7(3) . . ?
C91 S9 Cu4 106.6(5) . . ?
C91 S9 Cu3 119.8(4) . . ?
Cu4 S9 Cu3 133.5(5) . . ?
C91 S9 Ag6 124.6(5) . . ?
C91 S9 Ag14 106.6(10) . . ?
Ag6 S9 Ag14 127.6(10) . . ?
C91 S9 Ag1 106.8(3) . . ?
Cu4 S9 Ag1 81.4(5) . . ?
Cu3 S9 Ag1 88.0(3) . . ?
Ag6 S9 Ag1 92.1(4) . . ?
Ag14 S9 Ag1 82.0(11) . . ?
F4 P2 F6 95.2(6) . . ?
F4 P2 F1 178.3(7) . . ?
F6 P2 F1 86.4(6) . . ?
F4 P2 F2 94.8(6) . . ?
F6 P2 F2 94.2(5) . . ?
F1 P2 F2 85.5(6) . . ?
F4 P2 F3 88.2(6) . . ?
F6 P2 F3 175.5(7) . . ?
F1 P2 F3 90.1(6) . . ?
F2 P2 F3 88.4(5) . . ?
F4 P2 F5 88.9(7) . . ?
F6 P2 F5 86.6(5) . . ?
F1 P2 F5 90.8(6) . . ?
F2 P2 F5 176.2(6) . . ?
F3 P2 F5 90.6(6) . . ?
C67 P3 C61 104.2(5) . . ?
C67 P3 C73 105.2(5) . . ?
C61 P3 C73 102.0(4) . . ?
C67 P3 Ag7 108.7(4) . . ?
C61 P3 Ag7 126.7(3) . . ?
C73 P3 Ag7 108.2(3) . . ?
C67 P3 Cu5 114.6(4) . . ?
C61 P3 Cu5 113.7(3) . . ?
C73 P3 Cu5 115.8(4) . . ?
C55 P4 C49 105.9(4) . . ?
C55 P4 C73 103.6(4) . . ?
C49 P4 C73 103.5(4) . . ?
C55 P4 Cu3 109.4(3) . . ?
C49 P4 Cu3 118.4(4) . . ?
C73 P4 Cu3 114.8(4) . . ?
C55 P4 Ag6 117.5(4) . . ?
C49 P4 Ag6 115.4(5) . . ?
C73 P4 Ag6 109.4(5) . . ?
C1 P5 C7 105.9(5) . . ?
C1 P5 C74 103.0(4) . . ?
C7 P5 C74 104.3(5) . . ?
C1 P5 Ag9 115.7(5) . . ?
C7 P5 Ag9 112.3(5) . . ?
C74 P5 Ag9 114.6(5) . . ?
C1 P5 Cu1 110.2(4) . . ?
C7 P5 Cu1 121.9(4) . . ?
C74 P5 Cu1 109.9(3) . . ?
C13 P6 C74 103.1(4) . . ?
C13 P6 C19 106.4(4) . . ?
C74 P6 C19 103.6(4) . . ?
C13 P6 Cu2 115.2(5) . . ?
C74 P6 Cu2 113.3(5) . . ?
C19 P6 Cu2 114.0(4) . . ?
C13 P6 Ag12 111.7(8) . . ?
C74 P6 Ag12 111.0(8) . . ?
C19 P6 Ag12 119.5(7) . . ?
C37 P7 C43 105.0(12) . . ?
C37A P7 C43 105.4(11) . . ?
C37 P7 C75 103.5(10) . . ?
C37A P7 C75 107.8(10) . . ?
C43 P7 C75 103.8(4) . . ?
C37A P7 Ag8 117.5(11) . . ?
C43 P7 Ag8 114.3(6) . . ?
C75 P7 Ag8 107.0(5) . . ?
C37 P7 Cu8 119.1(10) . . ?
C43 P7 Cu8 109.4(5) . . ?
C75 P7 Cu8 114.7(4) . . ?
C25 P8 C31 105.7(5) . . ?
C25 P8 C75 104.0(4) . . ?
C31 P8 C75 103.9(5) . . ?
C25 P8 Ag11 113.0(8) . . ?
C31 P8 Ag11 117.3(7) . . ?
C75 P8 Ag11 111.8(10) . . ?
C25 P8 Cu9 117.7(5) . . ?
C31 P8 Cu9 111.8(4) . . ?
C75 P8 Cu9 112.6(6) . . ?
C6 C1 C2 118.7(10) . . ?
C6 C1 P5 122.9(9) . . ?
C2 C1 P5 118.2(8) . . ?
C3 C2 C1 120.9(13) . . ?
C3 C2 H2 119.6 . . ?
C1 C2 H2 119.6 . . ?
C4 C3 C2 118.8(14) . . ?
C4 C3 H3 120.6 . . ?
C2 C3 H3 120.6 . . ?
C3 C4 C5 123.5(12) . . ?
C3 C4 H4 118.3 . . ?
C5 C4 H4 118.3 . . ?
C4 C5 C6 118.1(11) . . ?
C4 C5 H5 121.0 . . ?
C6 C5 H5 121.0 . . ?
C1 C6 C5 119.9(12) . . ?
C1 C6 H6 120.0 . . ?
C5 C6 H6 120.0 . . ?
C8 C7 C12 120.2(11) . . ?
C8 C7 P5 125.1(9) . . ?
C12 C7 P5 114.6(10) . . ?
C7 C8 C9 121.0(14) . . ?
C7 C8 H8 119.5 . . ?
C9 C8 H8 119.5 . . ?
C8 C9 C10 117.9(15) . . ?
C8 C9 H9 121.1 . . ?
C10 C9 H9 121.1 . . ?
C9 C10 C11 122.5(15) . . ?
C9 C10 H10 118.8 . . ?
C11 C10 H10 118.8 . . ?
C12 C11 C10 117.4(16) . . ?
C12 C11 H11 121.3 . . ?
C10 C11 H11 121.3 . . ?
C11 C12 C7 120.6(15) . . ?
C11 C12 H12 119.7 . . ?
C7 C12 H12 119.7 . . ?
C18 C13 C14 117.2(9) . . ?
C18 C13 P6 119.4(7) . . ?
C14 C13 P6 123.4(7) . . ?
C15 C14 C13 120.0(10) . . ?
C15 C14 H14 120.0 . . ?
C13 C14 H14 120.0 . . ?
C16 C15 C14 121.0(11) . . ?
C16 C15 H15 119.5 . . ?
C14 C15 H15 119.5 . . ?
C17 C16 C15 120.1(11) . . ?
C17 C16 H16 119.9 . . ?
C15 C16 H16 119.9 . . ?
C16 C17 C18 119.4(10) . . ?
C16 C17 H17 120.3 . . ?
C18 C17 H17 120.3 . . ?
C17 C18 C13 122.2(9) . . ?
C17 C18 H18 118.9 . . ?
C13 C18 H18 118.9 . . ?
C24 C19 C20 118.7(10) . . ?
C24 C19 P6 117.6(8) . . ?
C20 C19 P6 123.7(8) . . ?
C21 C20 C19 120.5(12) . . ?
C21 C20 H20 119.8 . . ?
C19 C20 H20 119.8 . . ?
C20 C21 C22 119.4(13) . . ?
C20 C21 H21 120.3 . . ?
C22 C21 H21 120.3 . . ?
C23 C22 C21 121.0(11) . . ?
C23 C22 H22 119.5 . . ?
C21 C22 H22 119.5 . . ?
C22 C23 C24 119.2(11) . . ?
C22 C23 H23 120.4 . . ?
C24 C23 H23 120.4 . . ?
C19 C24 C23 121.1(11) . . ?
C19 C24 H24 119.4 . . ?
C23 C24 H24 119.4 . . ?
C26 C25 C30 118.6(10) . . ?
C26 C25 P8 117.8(8) . . ?
C30 C25 P8 123.6(8) . . ?
C25 C26 C27 120.7(11) . . ?
C25 C26 H26 119.7 . . ?
C27 C26 H26 119.7 . . ?
C28 C27 C26 121.0(12) . . ?
C28 C27 H27 119.5 . . ?
C26 C27 H27 119.5 . . ?
C27 C28 C29 118.9(12) . . ?
C27 C28 H28 120.6 . . ?
C29 C28 H28 120.6 . . ?
C30 C29 C28 120.5(12) . . ?
C30 C29 H29 119.8 . . ?
C28 C29 H29 119.8 . . ?
C29 C30 C25 120.4(12) . . ?
C29 C30 H30 119.8 . . ?
C25 C30 H30 119.8 . . ?
C32 C31 C36 118.6(10) . . ?
C32 C31 P8 118.9(7) . . ?
C36 C31 P8 122.5(9) . . ?
C33 C32 C31 122.0(10) . . ?
C33 C32 H32 119.0 . . ?
C31 C32 H32 119.0 . . ?
C32 C33 C34 118.7(11) . . ?
C32 C33 H33 120.6 . . ?
C34 C33 H33 120.6 . . ?
C35 C34 C33 119.6(11) . . ?
C35 C34 H34 120.2 . . ?
C33 C34 H34 120.2 . . ?
C34 C35 C36 122.4(11) . . ?
C34 C35 H35 118.8 . . ?
C36 C35 H35 118.8 . . ?
C35 C36 C31 118.6(11) . . ?
C35 C36 H36 120.7 . . ?
C31 C36 H36 120.7 . . ?
C38 C37 C42 120.0 . . ?
C38 C37 P7 118.6(15) . . ?
C42 C37 P7 121.1(15) . . ?
C37 C38 C39 120.0 . . ?
C37 C38 H38 120.0 . . ?
C39 C38 H38 120.0 . . ?
C40 C39 C38 120.0 . . ?
C40 C39 H39 120.0 . . ?
C38 C39 H39 120.0 . . ?
C39 C40 C41 120.0 . . ?
C39 C40 H40 120.0 . . ?
C41 C40 H40 120.0 . . ?
C42 C41 C40 120.0 . . ?
C42 C41 H41 120.0 . . ?
C40 C41 H41 120.0 . . ?
C41 C42 C37 120.0 . . ?
C41 C42 H42 120.0 . . ?
C37 C42 H42 120.0 . . ?
C44 C43 C48 118.8(11) . . ?
C44 C43 P7 119.9(9) . . ?
C48 C43 P7 121.3(9) . . ?
C45 C44 C43 122.7(13) . . ?
C45 C44 H44 118.6 . . ?
C43 C44 H44 118.6 . . ?
C46 C45 C44 119.6(15) . . ?
C46 C45 H45 120.2 . . ?
C44 C45 H45 120.2 . . ?
C45 C46 C47 122.1(13) . . ?
C45 C46 H46 119.0 . . ?
C47 C46 H46 119.0 . . ?
C46 C47 C48 118.1(13) . . ?
C46 C47 H47 121.0 . . ?
C48 C47 H47 121.0 . . ?
C43 C48 C47 118.7(13) . . ?
C43 C48 H48 120.6 . . ?
C47 C48 H48 120.6 . . ?
C54 C49 C50 119.1(9) . . ?
C54 C49 P4 124.1(8) . . ?
C50 C49 P4 116.9(7) . . ?
C49 C50 C51 119.1(11) . . ?
C49 C50 H50 120.5 . . ?
C51 C50 H50 120.5 . . ?
C52 C51 C50 121.5(11) . . ?
C52 C51 H51 119.3 . . ?
C50 C51 H51 119.3 . . ?
C53 C52 C51 118.3(11) . . ?
C53 C52 H52 120.8 . . ?
C51 C52 H52 120.8 . . ?
C52 C53 C54 122.2(12) . . ?
C52 C53 H53 118.9 . . ?
C54 C53 H53 118.9 . . ?
C49 C54 C53 119.7(11) . . ?
C49 C54 H54 120.1 . . ?
C53 C54 H54 120.1 . . ?
C60 C55 C56 117.8(9) . . ?
C60 C55 P4 122.6(7) . . ?
C56 C55 P4 119.6(7) . . ?
C57 C56 C55 121.8(9) . . ?
C57 C56 H56 119.1 . . ?
C55 C56 H56 119.1 . . ?
C56 C57 C58 120.2(10) . . ?
C56 C57 H57 119.9 . . ?
C58 C57 H57 119.9 . . ?
C59 C58 C57 118.8(10) . . ?
C59 C58 H58 120.6 . . ?
C57 C58 H58 120.6 . . ?
C58 C59 C60 121.7(10) . . ?
C58 C59 H59 119.1 . . ?
C60 C59 H59 119.1 . . ?
C59 C60 C55 119.8(9) . . ?
C59 C60 H60 120.1 . . ?
C55 C60 H60 120.1 . . ?
C62 C61 C66 119.8(11) . . ?
C62 C61 P3 118.1(8) . . ?
C66 C61 P3 122.1(8) . . ?
C63 C62 C61 119.7(11) . . ?
C63 C62 H62 120.1 . . ?
C61 C62 H62 120.1 . . ?
C62 C63 C64 121.7(13) . . ?
C62 C63 H63 119.2 . . ?
C64 C63 H63 119.2 . . ?
C65 C64 C63 117.9(14) . . ?
C65 C64 H64 121.0 . . ?
C63 C64 H64 121.0 . . ?
C64 C65 C66 120.7(13) . . ?
C64 C65 H65 119.6 . . ?
C66 C65 H65 119.6 . . ?
C61 C66 C65 120.2(12) . . ?
C61 C66 H66 119.9 . . ?
C65 C66 H66 119.9 . . ?
C68 C67 C72 118.1(11) . . ?
C68 C67 P3 118.6(9) . . ?
C72 C67 P3 123.2(9) . . ?
C67 C68 C69 120.6(14) . . ?
C67 C68 H68 119.7 . . ?
C69 C68 H68 119.7 . . ?
C70 C69 C68 120.5(15) . . ?
C70 C69 H69 119.8 . . ?
C68 C69 H69 119.8 . . ?
C71 C70 C69 120.7(14) . . ?
C71 C70 H70 119.6 . . ?
C69 C70 H70 119.6 . . ?
C70 C71 C72 121.4(14) . . ?
C70 C71 H71 119.3 . . ?
C72 C71 H71 119.3 . . ?
C67 C72 C71 118.6(13) . . ?
C67 C72 H72 120.7 . . ?
C71 C72 H72 120.7 . . ?
P4 C73 P3 110.0(5) . . ?
P4 C73 H73A 109.7 . . ?
P3 C73 H73A 109.7 . . ?
P4 C73 H73B 109.7 . . ?
P3 C73 H73B 109.7 . . ?
H73A C73 H73B 108.2 . . ?
P6 C74 P5 111.6(4) . . ?
P6 C74 H74A 109.3 . . ?
P5 C74 H74A 109.3 . . ?
P6 C74 H74B 109.3 . . ?
P5 C74 H74B 109.3 . . ?
H74A C74 H74B 108.0 . . ?
P8 C75 P7 111.8(5) . . ?
P8 C75 H75A 109.2 . . ?
P7 C75 H75A 109.2 . . ?
P8 C75 H75B 109.2 . . ?
P7 C75 H75B 109.2 . . ?
H75A C75 H75B 107.9 . . ?
C77 C76 H76A 109.4 . . ?
C77 C76 H76B 109.5 . . ?
H76A C76 H76B 109.5 . . ?
C77 C76 H76C 109.5 . . ?
H76A C76 H76C 109.5 . . ?
H76B C76 H76C 109.5 . . ?
C88 C77 C76 114.8(13) . . ?
C88A C77 C76A 113.4(16) . . ?
C88 C77 S4 115.1(12) . . ?
C76 C77 S4 116.9(14) . . ?
C88A C77 S4 101.3(16) . . ?
C76A C77 S4 103.5(17) . . ?
C90 C78 C89 112.5(9) . . ?
C90 C78 S5 108.2(6) . . ?
C89 C78 S5 110.7(6) . . ?
C90 C78 H78 108.4 . . ?
C89 C78 H78 108.4 . . ?
S5 C78 H78 108.4 . . ?
C81 C79 C80 113.5(12) . . ?
C81 C79 S7 110.6(9) . . ?
C80 C79 S7 110.0(8) . . ?
C79 C80 H80A 109.5 . . ?
C79 C80 H80B 109.5 . . ?
H80A C80 H80B 109.5 . . ?
C79 C80 H80C 109.5 . . ?
H80A C80 H80C 109.5 . . ?
H80B C80 H80C 109.5 . . ?
C79 C81 H81A 109.5 . . ?
C79 C81 H81B 109.5 . . ?
H81A C81 H81B 109.5 . . ?
C79 C81 H81C 109.5 . . ?
H81A C81 H81C 109.5 . . ?
H81B C81 H81C 109.5 . . ?
C84 C82 C83 112.2(8) . . ?
C84 C82 S8 109.9(6) . . ?
C83 C82 S8 110.6(6) . . ?
C84 C82 H82 108.0 . . ?
C83 C82 H82 108.0 . . ?
S8 C82 H82 108.0 . . ?
C82 C83 H83A 109.5 . . ?
C82 C83 H83B 109.5 . . ?
H83A C83 H83B 109.5 . . ?
C82 C83 H83C 109.5 . . ?
H83A C83 H83C 109.5 . . ?
H83B C83 H83C 109.5 . . ?
C82 C84 H84A 109.5 . . ?
C82 C84 H84B 109.5 . . ?
H84A C84 H84B 109.5 . . ?
C82 C84 H84C 109.5 . . ?
H84A C84 H84C 109.5 . . ?
H84B C84 H84C 109.5 . . ?
C86 C85 C87 111.7(9) . . ?
C86 C85 S6 108.4(7) . . ?
C87 C85 S6 111.2(7) . . ?
C86 C85 H85 108.5 . . ?
C87 C85 H85 108.5 . . ?
S6 C85 H85 108.5 . . ?
C85 C86 H86A 109.5 . . ?
C85 C86 H86B 109.5 . . ?
H86A C86 H86B 109.5 . . ?
C85 C86 H86C 109.5 . . ?
H86A C86 H86C 109.5 . . ?
H86B C86 H86C 109.5 . . ?
C85 C87 H87A 109.5 . . ?
C85 C87 H87B 109.5 . . ?
H87A C87 H87B 109.5 . . ?
C85 C87 H87C 109.5 . . ?
H87A C87 H87C 109.5 . . ?
H87B C87 H87C 109.5 . . ?
C77 C88 H88A 109.5 . . ?
C77 C88 H88B 109.4 . . ?
H88A C88 H88B 109.5 . . ?
C77 C88 H88C 109.5 . . ?
H88A C88 H88C 109.5 . . ?
H88B C88 H88C 109.5 . . ?
C78 C89 H89A 109.5 . . ?
C78 C89 H89B 109.5 . . ?
H89A C89 H89B 109.5 . . ?
C78 C89 H89C 109.5 . . ?
H89A C89 H89C 109.5 . . ?
H89B C89 H89C 109.5 . . ?
C78 C90 H90A 109.5 . . ?
C78 C90 H90B 109.5 . . ?
H90A C90 H90B 109.5 . . ?
C78 C90 H90C 109.5 . . ?
H90A C90 H90C 109.5 . . ?
H90B C90 H90C 109.5 . . ?
C93 C91 C92 111.3(8) . . ?
C93 C91 S9 111.1(6) . . ?
C92 C91 S9 109.0(6) . . ?
C93 C91 H91 108.5 . . ?
C92 C91 H91 108.5 . . ?
S9 C91 H91 108.5 . . ?
C91 C92 H92A 109.5 . . ?
C91 C92 H92B 109.5 . . ?
H92A C92 H92B 109.5 . . ?
C91 C92 H92C 109.5 . . ?
H92A C92 H92C 109.5 . . ?
H92B C92 H92C 109.5 . . ?
C91 C93 H93A 109.5 . . ?
C91 C93 H93B 109.5 . . ?
H93A C93 H93B 109.5 . . ?
C91 C93 H93C 109.5 . . ?
H93A C93 H93C 109.5 . . ?
H93B C93 H93C 109.5 . . ?
C96 C94 C95 113.1(8) . . ?
C96 C94 S1 109.2(7) . . ?
C95 C94 S1 109.1(6) . . ?
C96 C94 H94 108.4 . . ?
C95 C94 H94 108.4 . . ?
S1 C94 H94 108.4 . . ?
C94 C95 H95A 109.5 . . ?
C94 C95 H95B 109.5 . . ?
H95A C95 H95B 109.5 . . ?
C94 C95 H95C 109.5 . . ?
H95A C95 H95C 109.5 . . ?
H95B C95 H95C 109.5 . . ?
C94 C96 H96A 109.5 . . ?
C94 C96 H96B 109.5 . . ?
H96A C96 H96B 109.5 . . ?
C94 C96 H96C 109.5 . . ?
H96A C96 H96C 109.5 . . ?
H96B C96 H96C 109.5 . . ?
C98 C97 C99 110.0(10) . . ?
C98 C97 S2 111.4(8) . . ?
C99 C97 S2 113.4(7) . . ?
C98 C97 H97 107.2 . . ?
C99 C97 H97 107.2 . . ?
S2 C97 H97 107.2 . . ?
C97 C98 H98A 109.5 . . ?
C97 C98 H98B 109.5 . . ?
H98A C98 H98B 109.5 . . ?
C97 C98 H98C 109.5 . . ?
H98A C98 H98C 109.5 . . ?
H98B C98 H98C 109.5 . . ?
C97 C99 H99A 109.5 . . ?
C97 C99 H99B 109.5 . . ?
H99A C99 H99B 109.5 . . ?
C97 C99 H99C 109.5 . . ?
H99A C99 H99C 109.5 . . ?
H99B C99 H99C 109.5 . . ?
C102 C100 C101 108.4(9) . . ?
C10A C100 C101 108.3(10) . . ?
C102 C100 S3 108.3(9) . . ?
C10A C100 S3 118(2) . . ?
C101 C100 S3 106.5(9) . . ?
C100 C101 H10A 109.5 . . ?
C100 C101 H10B 109.5 . . ?
H10A C101 H10B 109.5 . . ?
C100 C101 H10C 109.5 . . ?
H10A C101 H10C 109.5 . . ?
H10B C101 H10C 109.5 . . ?
C100 C102 H10D 109.5 . . ?
C100 C102 H10E 109.5 . . ?
H10D C102 H10E 109.5 . . ?
C100 C102 H10F 109.5 . . ?
H10D C102 H10F 109.5 . . ?
H10E C102 H10F 109.5 . . ?
C100 C10A H10G 109.5 . . ?
C100 C10A H10H 109.5 . . ?
H10G C10A H10H 109.5 . . ?
C100 C10A H10I 109.5 . . ?
H10G C10A H10I 109.5 . . ?
H10H C10A H10I 109.5 . . ?
S2 Cu2A S4 126.9(14) . . ?
S2 Cu2A S3 120.7(15) . . ?
S4 Cu2A S3 112.2(14) . . ?
S2 Cu2A Ag3 52.8(6) . . ?
S4 Cu2A Ag3 96.6(10) . . ?
S3 Cu2A Ag3 129.8(16) . . ?
S2 Cu2A Ag1 95.4(13) . . ?
S4 Cu2A Ag1 124.3(17) . . ?
S3 Cu2A Ag1 49.1(7) . . ?
Ag3 Cu2A Ag1 80.8(10) . . ?
C77 C88A H88D 109.5 . . ?
C77 C88A H88E 109.5 . . ?
H88D C88A H88E 109.5 . . ?
C77 C88A H88F 109.5 . . ?
H88D C88A H88F 109.5 . . ?
H88E C88A H88F 109.5 . . ?
C77 C76A H76D 109.4 . . ?
C77 C76A H76E 109.5 . . ?
H76D C76A H76E 109.5 . . ?
C77 C76A H76F 109.5 . . ?
H76D C76A H76F 109.5 . . ?
H76E C76A H76F 109.5 . . ?
C38A C37A C42A 120.0 . . ?
C38A C37A P7 112.7(15) . . ?
C42A C37A P7 127.0(15) . . ?
C37A C38A C39A 120.0 . . ?
C37A C38A H38A 120.0 . . ?
C39A C38A H38A 120.0 . . ?
C40A C39A C38A 120.0 . . ?
C40A C39A H39A 120.0 . . ?
C38A C39A H39A 120.0 . . ?
C39A C40A C41A 120.0 . . ?
C39A C40A H40A 120.0 . . ?
C41A C40A H40A 120.0 . . ?
C42A C41A C40A 120.0 . . ?
C42A C41A H41A 120.0 . . ?
C40A C41A H41A 120.0 . . ?
C41A C42A C37A 120.0 . . ?
C41A C42A H42A 120.0 . . ?
C37A C42A H42A 120.0 . . ?
F15 P9 F12 90.0 . . ?
F15 P9 F17 90.0 . . ?
F12 P9 F17 90.0 . . ?
F15 P9 F16 90.0 . . ?
F12 P9 F16 180.0(13) . . ?
F17 P9 F16 90.0 . . ?
F15 P9 F14 90.0 . . ?
F12 P9 F14 90.0 . . ?
F17 P9 F14 180.0 . . ?
F16 P9 F14 90.0 . . ?
F15 P9 F18 180.0(13) . . ?
F12 P9 F18 90.0 . . ?
F17 P9 F18 90.0 . . ?
F16 P9 F18 90.0 . . ?
F14 P9 F18 90.0 . . ?
F13 P1 F7 90.0 . . ?
F13 P1 F11 90.0 . . ?
F7 P1 F11 90.0 . . ?
F13 P1 F10 90.0 . . ?
F7 P1 F10 180.0(14) . . ?
F11 P1 F10 90.0 . . ?
F13 P1 F8 90.0 . . ?
F7 P1 F8 90.0 . . ?
F11 P1 F8 180.0(11) . . ?
F10 P1 F8 90.0 . . ?
F13 P1 F9 180.0 . . ?
F7 P1 F9 90.0 . . ?
F11 P1 F9 90.0 . . ?
F10 P1 F9 90.0 . . ?
F8 P1 F9 90.0 . . ?
F1B P11 F1A 90.0 . . ?
F1B P11 F19 90.0 . . ?
F1A P11 F19 90.0 . . ?
F1B P11 F1C 90.0 . . ?
F1A P11 F1C 90.0 . . ?
F19 P11 F1C 180(2) . . ?
F1B P11 F1D 90.0 . . ?
F1A P11 F1D 180(3) . . ?
F19 P11 F1D 90.0 . . ?
F1C P11 F1D 90.0 . . ?
F1B P11 F1E 180.0 . . ?
F1A P11 F1E 90.0 . . ?
F19 P11 F1E 90.0 . . ?
F1C P11 F1E 90.0 . . ?
F1D P11 F1E 90.0 . . ?
F1G P10 F1F 90.0 . . ?
F1G P10 F1J 180.0 . . ?
F1F P10 F1J 90.0 . . ?
F1G P10 F1H 90.0 . . ?
F1F P10 F1H 90.0 . . ?
F1J P10 F1H 90.0 . . ?
F1G P10 F1I 90.0 . . ?
F1F P10 F1I 180(4) . . ?
F1J P10 F1I 90.0 . . ?
F1H P10 F1I 90.0 . . ?
F1G P10 F1K 90.0 . . ?
F1F P10 F1K 90.0 . . ?
F1J P10 F1K 90.0 . . ?
F1H P10 F1K 180.0 . . ?
F1I P10 F1K 90.0 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C7 P5 C1 C6 -54.1(10) . . . . ?
C74 P5 C1 C6 55.1(10) . . . . ?
Ag9 P5 C1 C6 -179.1(9) . . . . ?
Cu1 P5 C1 C6 172.3(8) . . . . ?
C7 P5 C1 C2 129.6(10) . . . . ?
C74 P5 C1 C2 -121.1(10) . . . . ?
Ag9 P5 C1 C2 4.6(11) . . . . ?
Cu1 P5 C1 C2 -4.0(11) . . . . ?
C6 C1 C2 C3 3(2) . . . . ?
P5 C1 C2 C3 179.7(13) . . . . ?
C1 C2 C3 C4 -4(3) . . . . ?
C2 C3 C4 C5 2(3) . . . . ?
C3 C4 C5 C6 0(2) . . . . ?
C2 C1 C6 C5 -1.5(17) . . . . ?
P5 C1 C6 C5 -177.7(9) . . . . ?
C4 C5 C6 C1 0.1(18) . . . . ?
C1 P5 C7 C8 86.4(11) . . . . ?
C74 P5 C7 C8 -21.9(11) . . . . ?
Ag9 P5 C7 C8 -146.5(11) . . . . ?
Cu1 P5 C7 C8 -146.8(9) . . . . ?
C1 P5 C7 C12 -90.8(9) . . . . ?
C74 P5 C7 C12 160.9(9) . . . . ?
Ag9 P5 C7 C12 36.3(11) . . . . ?
Cu1 P5 C7 C12 36.0(10) . . . . ?
C12 C7 C8 C9 -7(2) . . . . ?
P5 C7 C8 C9 176.2(11) . . . . ?
C7 C8 C9 C10 3(2) . . . . ?
C8 C9 C10 C11 4(3) . . . . ?
C9 C10 C11 C12 -6(3) . . . . ?
C10 C11 C12 C7 2(2) . . . . ?
C8 C7 C12 C11 4(2) . . . . ?
P5 C7 C12 C11 -178.5(12) . . . . ?
C74 P6 C13 C18 -106.3(8) . . . . ?
C19 P6 C13 C18 145.1(8) . . . . ?
Cu2 P6 C13 C18 17.7(9) . . . . ?
Ag12 P6 C13 C18 13.0(11) . . . . ?
C74 P6 C13 C14 71.9(9) . . . . ?
C19 P6 C13 C14 -36.7(9) . . . . ?
Cu2 P6 C13 C14 -164.1(8) . . . . ?
Ag12 P6 C13 C14 -168.8(10) . . . . ?
C18 C13 C14 C15 1.8(15) . . . . ?
P6 C13 C14 C15 -176.4(9) . . . . ?
C13 C14 C15 C16 -0.9(18) . . . . ?
C14 C15 C16 C17 0.4(19) . . . . ?
C15 C16 C17 C18 -0.9(17) . . . . ?
C16 C17 C18 C13 1.9(16) . . . . ?
C14 C13 C18 C17 -2.4(15) . . . . ?
P6 C13 C18 C17 175.9(8) . . . . ?
C13 P6 C19 C24 -92.7(8) . . . . ?
C74 P6 C19 C24 158.9(7) . . . . ?
Cu2 P6 C19 C24 35.3(9) . . . . ?
Ag12 P6 C19 C24 34.8(12) . . . . ?
C13 P6 C19 C20 85.1(11) . . . . ?
C74 P6 C19 C20 -23.2(11) . . . . ?
Cu2 P6 C19 C20 -146.8(11) . . . . ?
Ag12 P6 C19 C20 -147.4(13) . . . . ?
C24 C19 C20 C21 -2(2) . . . . ?
P6 C19 C20 C21 -179.8(12) . . . . ?
C19 C20 C21 C22 5(2) . . . . ?
C20 C21 C22 C23 -4(2) . . . . ?
C21 C22 C23 C24 1.5(19) . . . . ?
C20 C19 C24 C23 -0.9(16) . . . . ?
P6 C19 C24 C23 177.0(8) . . . . ?
C22 C23 C24 C19 1.2(16) . . . . ?
C31 P8 C25 C26 -87.5(9) . . . . ?
C75 P8 C25 C26 163.4(8) . . . . ?
Ag11 P8 C25 C26 42.0(13) . . . . ?
Cu9 P8 C25 C26 38.1(10) . . . . ?
C31 P8 C25 C30 91.6(11) . . . . ?
C75 P8 C25 C30 -17.5(11) . . . . ?
Ag11 P8 C25 C30 -138.9(14) . . . . ?
Cu9 P8 C25 C30 -142.8(11) . . . . ?
C30 C25 C26 C27 -1.2(17) . . . . ?
P8 C25 C26 C27 178.0(8) . . . . ?
C25 C26 C27 C28 2.2(18) . . . . ?
C26 C27 C28 C29 -0.5(19) . . . . ?
C27 C28 C29 C30 -2(2) . . . . ?
C28 C29 C30 C25 3(2) . . . . ?
C26 C25 C30 C29 -2(2) . . . . ?
P8 C25 C30 C29 179.3(11) . . . . ?
C25 P8 C31 C32 152.8(8) . . . . ?
C75 P8 C31 C32 -98.0(8) . . . . ?
Ag11 P8 C31 C32 25.9(14) . . . . ?
Cu9 P8 C31 C32 23.7(11) . . . . ?
C25 P8 C31 C36 -28.6(10) . . . . ?
C75 P8 C31 C36 80.6(9) . . . . ?
Ag11 P8 C31 C36 -155.5(13) . . . . ?
Cu9 P8 C31 C36 -157.7(9) . . . . ?
C36 C31 C32 C33 -2.9(16) . . . . ?
P8 C31 C32 C33 175.8(8) . . . . ?
C31 C32 C33 C34 2.4(17) . . . . ?
C32 C33 C34 C35 -0.7(19) . . . . ?
C33 C34 C35 C36 -1(2) . . . . ?
C34 C35 C36 C31 0(2) . . . . ?
C32 C31 C36 C35 1.6(16) . . . . ?
P8 C31 C36 C35 -177.0(9) . . . . ?
C43 P7 C37 C38 -95.4(14) . . . . ?
C75 P7 C37 C38 156.1(13) . . . . ?
Cu8 P7 C37 C38 27.4(19) . . . . ?
C43 P7 C37 C42 90.4(16) . . . . ?
C75 P7 C37 C42 -18.1(18) . . . . ?
Cu8 P7 C37 C42 -146.8(13) . . . . ?
C42 C37 C38 C39 0.0 . . . . ?
P7 C37 C38 C39 -174(2) . . . . ?
C37 C38 C39 C40 0.0 . . . . ?
C38 C39 C40 C41 0.0 . . . . ?
C39 C40 C41 C42 0.0 . . . . ?
C40 C41 C42 C37 0.0 . . . . ?
C38 C37 C42 C41 0.0 . . . . ?
P7 C37 C42 C41 174(2) . . . . ?
C37 P7 C43 C44 135.8(13) . . . . ?
C37A P7 C43 C44 130.9(13) . . . . ?
C75 P7 C43 C44 -115.9(9) . . . . ?
Ag8 P7 C43 C44 0.3(11) . . . . ?
Cu8 P7 C43 C44 6.9(11) . . . . ?
C37 P7 C43 C48 -43.0(13) . . . . ?
C37A P7 C43 C48 -47.9(13) . . . . ?
C75 P7 C43 C48 65.3(9) . . . . ?
Ag8 P7 C43 C48 -178.5(8) . . . . ?
Cu8 P7 C43 C48 -171.9(8) . . . . ?
C48 C43 C44 C45 0.7(19) . . . . ?
P7 C43 C44 C45 -178.1(11) . . . . ?
C43 C44 C45 C46 1(2) . . . . ?
C44 C45 C46 C47 -3(2) . . . . ?
C45 C46 C47 C48 3(2) . . . . ?
C44 C43 C48 C47 -0.7(16) . . . . ?
P7 C43 C48 C47 178.1(8) . . . . ?
C46 C47 C48 C43 -0.8(17) . . . . ?
C55 P4 C49 C54 91.7(10) . . . . ?
C73 P4 C49 C54 -16.9(11) . . . . ?
Cu3 P4 C49 C54 -145.2(9) . . . . ?
Ag6 P4 C49 C54 -136.4(10) . . . . ?
C55 P4 C49 C50 -88.0(8) . . . . ?
C73 P4 C49 C50 163.3(7) . . . . ?
Cu3 P4 C49 C50 35.0(8) . . . . ?
Ag6 P4 C49 C50 43.8(8) . . . . ?
C54 C49 C50 C51 -2.1(15) . . . . ?
P4 C49 C50 C51 177.7(7) . . . . ?
C49 C50 C51 C52 3.6(16) . . . . ?
C50 C51 C52 C53 -3.2(18) . . . . ?
C51 C52 C53 C54 1(2) . . . . ?
C50 C49 C54 C53 0.3(18) . . . . ?
P4 C49 C54 C53 -179.5(10) . . . . ?
C52 C53 C54 C49 0(2) . . . . ?
C49 P4 C55 C60 -42.5(9) . . . . ?
C73 P4 C55 C60 66.1(8) . . . . ?
Cu3 P4 C55 C60 -171.1(8) . . . . ?
Ag6 P4 C55 C60 -173.2(8) . . . . ?
C49 P4 C55 C56 139.0(7) . . . . ?
C73 P4 C55 C56 -112.4(8) . . . . ?
Cu3 P4 C55 C56 10.4(9) . . . . ?
Ag6 P4 C55 C56 8.3(10) . . . . ?
C60 C55 C56 C57 -1.2(14) . . . . ?
P4 C55 C56 C57 177.4(8) . . . . ?
C55 C56 C57 C58 0.3(15) . . . . ?
C56 C57 C58 C59 1.6(16) . . . . ?
C57 C58 C59 C60 -2.7(17) . . . . ?
C58 C59 C60 C55 1.8(16) . . . . ?
C56 C55 C60 C59 0.2(14) . . . . ?
P4 C55 C60 C59 -178.4(8) . . . . ?
C67 P3 C61 C62 -121.3(8) . . . . ?
C73 P3 C61 C62 129.5(8) . . . . ?
Ag7 P3 C61 C62 5.7(10) . . . . ?
Cu5 P3 C61 C62 4.1(9) . . . . ?
C67 P3 C61 C66 60.7(9) . . . . ?
C73 P3 C61 C66 -48.6(9) . . . . ?
Ag7 P3 C61 C66 -172.4(7) . . . . ?
Cu5 P3 C61 C66 -173.9(7) . . . . ?
C66 C61 C62 C63 -0.5(16) . . . . ?
P3 C61 C62 C63 -178.6(9) . . . . ?
C61 C62 C63 C64 -0.4(19) . . . . ?
C62 C63 C64 C65 1(2) . . . . ?
C63 C64 C65 C66 -0.6(19) . . . . ?
C62 C61 C66 C65 0.8(16) . . . . ?
P3 C61 C66 C65 178.8(9) . . . . ?
C64 C65 C66 C61 -0.2(18) . . . . ?
C61 P3 C67 C68 106.7(11) . . . . ?
C73 P3 C67 C68 -146.4(11) . . . . ?
Ag7 P3 C67 C68 -30.7(11) . . . . ?
Cu5 P3 C67 C68 -18.2(12) . . . . ?
C61 P3 C67 C72 -69.0(11) . . . . ?
C73 P3 C67 C72 37.9(12) . . . . ?
Ag7 P3 C67 C72 153.6(10) . . . . ?
Cu5 P3 C67 C72 166.1(10) . . . . ?
C72 C67 C68 C69 0(2) . . . . ?
P3 C67 C68 C69 -176.0(14) . . . . ?
C67 C68 C69 C70 1(3) . . . . ?
C68 C69 C70 C71 1(3) . . . . ?
C69 C70 C71 C72 -3(3) . . . . ?
C68 C67 C72 C71 -2(2) . . . . ?
P3 C67 C72 C71 173.4(11) . . . . ?
C70 C71 C72 C67 4(2) . . . . ?
C55 P4 C73 P3 63.5(6) . . . . ?
C49 P4 C73 P3 173.9(5) . . . . ?
Cu3 P4 C73 P3 -55.7(6) . . . . ?
Ag6 P4 C73 P3 -62.6(7) . . . . ?
C67 P3 C73 P4 158.6(5) . . . . ?
C61 P3 C73 P4 -93.0(6) . . . . ?
Ag7 P3 C73 P4 42.5(6) . . . . ?
Cu5 P3 C73 P4 31.0(6) . . . . ?
C13 P6 C74 P5 68.5(6) . . . . ?
C19 P6 C74 P5 179.3(5) . . . . ?
Cu2 P6 C74 P5 -56.6(6) . . . . ?
Ag12 P6 C74 P5 -51.2(9) . . . . ?
C1 P5 C74 P6 155.8(5) . . . . ?
C7 P5 C74 P6 -93.8(5) . . . . ?
Ag9 P5 C74 P6 29.3(7) . . . . ?
Cu1 P5 C74 P6 38.4(5) . . . . ?
C25 P8 C75 P7 179.2(5) . . . . ?
C31 P8 C75 P7 68.7(6) . . . . ?
Ag11 P8 C75 P7 -58.6(9) . . . . ?
Cu9 P8 C75 P7 -52.3(7) . . . . ?
C37 P7 C75 P8 -91.7(12) . . . . ?
C37A P7 C75 P8 -89.7(12) . . . . ?
C43 P7 C75 P8 158.9(6) . . . . ?
Ag8 P7 C75 P8 37.6(8) . . . . ?
Cu8 P7 C75 P8 39.6(7) . . . . ?
Cu8 S4 C77 C88 -105.3(14) . . . . ?
Ag2 S4 C77 C88 49.8(15) . . . . ?
Ag5 S4 C77 C88 139.1(14) . . . . ?
Cu8 S4 C77 C76 33.9(18) . . . . ?
Ag2 S4 C77 C76 -171.0(16) . . . . ?
Ag5 S4 C77 C76 -81.7(16) . . . . ?
Cu2A S4 C77 C88A 87.6(18) . . . . ?
Ag8 S4 C77 C88A -74.7(15) . . . . ?
Ag5 S4 C77 C88A 177.7(13) . . . . ?
Cu2A S4 C77 C76A -155(2) . . . . ?
Ag8 S4 C77 C76A 43.0(18) . . . . ?
Ag5 S4 C77 C76A -64.6(17) . . . . ?
Ag14 S5 C78 C90 -87.1(14) . . . . ?
Ag12 S5 C78 C90 95.2(11) . . . . ?
Cu2 S5 C78 C90 89.3(8) . . . . ?
Cu4 S5 C78 C90 -83.7(9) . . . . ?
Ag3 S5 C78 C90 -171.1(6) . . . . ?
Ag14 S5 C78 C89 149.3(14) . . . . ?
Ag12 S5 C78 C89 -28.5(11) . . . . ?
Cu2 S5 C78 C89 -34.4(9) . . . . ?
Cu4 S5 C78 C89 152.7(8) . . . . ?
Ag3 S5 C78 C89 65.2(7) . . . . ?
Ag6 S7 C79 C81 -169.9(12) . . . . ?
Ag7 S7 C79 C81 110.5(12) . . . . ?
Cu3 S7 C79 C81 -172.6(11) . . . . ?
Ag5 S7 C79 C81 -46.1(13) . . . . ?
Cu5 S7 C79 C81 111.4(12) . . . . ?
Ag6 S7 C79 C80 -43.7(11) . . . . ?
Ag7 S7 C79 C80 -123.3(9) . . . . ?
Cu3 S7 C79 C80 -46.4(11) . . . . ?
Ag5 S7 C79 C80 80.1(10) . . . . ?
Cu5 S7 C79 C80 -122.4(9) . . . . ?
Ag11 S8 C82 C84 -169.9(11) . . . . ?
Ag8 S8 C82 C84 114.4(8) . . . . ?
Cu9 S8 C82 C84 -172.5(8) . . . . ?
Cu8 S8 C82 C84 106.5(8) . . . . ?
Ag3 S8 C82 C84 -42.8(8) . . . . ?
Ag11 S8 C82 C83 -45.4(11) . . . . ?
Ag8 S8 C82 C83 -121.1(8) . . . . ?
Cu9 S8 C82 C83 -48.0(9) . . . . ?
Cu8 S8 C82 C83 -129.0(7) . . . . ?
Ag3 S8 C82 C83 81.6(7) . . . . ?
Ag14 S6 C85 C86 -85.8(12) . . . . ?
Cu9 S6 C85 C86 93.1(8) . . . . ?
Cu4 S6 C85 C86 -88.8(8) . . . . ?
Ag11 S6 C85 C86 86.6(10) . . . . ?
Ag5 S6 C85 C86 -172.4(7) . . . . ?
Ag14 S6 C85 C87 151.1(12) . . . . ?
Cu9 S6 C85 C87 -30.0(9) . . . . ?
Cu4 S6 C85 C87 148.1(8) . . . . ?
Ag11 S6 C85 C87 -36.6(11) . . . . ?
Ag5 S6 C85 C87 64.5(8) . . . . ?
Cu4 S9 C91 C93 151.3(8) . . . . ?
Cu3 S9 C91 C93 -32.1(8) . . . . ?
Ag6 S9 C91 C93 -39.4(8) . . . . ?
Ag14 S9 C91 C93 151.9(13) . . . . ?
Ag1 S9 C91 C93 65.4(6) . . . . ?
Cu4 S9 C91 C92 -85.8(9) . . . . ?
Cu3 S9 C91 C92 90.8(7) . . . . ?
Ag6 S9 C91 C92 83.6(8) . . . . ?
Ag14 S9 C91 C92 -85.2(14) . . . . ?
Ag1 S9 C91 C92 -171.6(6) . . . . ?
Cu1 S1 C94 C96 112.0(6) . . . . ?
Ag12 S1 C94 C96 -169.5(10) . . . . ?
Cu2 S1 C94 C96 -167.8(7) . . . . ?
Ag1 S1 C94 C96 -38.6(7) . . . . ?
Ag9 S1 C94 C96 114.0(7) . . . . ?
Cu1 S1 C94 C95 -124.0(6) . . . . ?
Ag12 S1 C94 C95 -45.4(11) . . . . ?
Cu2 S1 C94 C95 -43.7(8) . . . . ?
Ag1 S1 C94 C95 85.5(7) . . . . ?
Ag9 S1 C94 C95 -121.9(7) . . . . ?
Ag9 S2 C97 C98 55.4(10) . . . . ?
Cu1 S2 C97 C98 58.3(9) . . . . ?
Cu2A S2 C97 C98 -145.7(11) . . . . ?
Ag2 S2 C97 C98 -150.7(7) . . . . ?
Ag3 S2 C97 C98 -58.8(9) . . . . ?
Ag9 S2 C97 C99 -179.9(9) . . . . ?
Cu1 S2 C97 C99 -177.0(8) . . . . ?
Cu2A S2 C97 C99 -20.9(13) . . . . ?
Ag2 S2 C97 C99 -26.0(10) . . . . ?
Ag3 S2 C97 C99 66.0(9) . . . . ?
Cu5 S3 C100 C102 -178.4(9) . . . . ?
Ag2 S3 C100 C102 -20.6(10) . . . . ?
Ag1 S3 C100 C102 71.0(9) . . . . ?
Ag7 S3 C100 C10A 62.9(11) . . . . ?
Ag1 S3 C100 C10A -50.7(11) . . . . ?
Cu2A S3 C100 C10A -140.7(15) . . . . ?
Cu5 S3 C100 C101 -62.1(9) . . . . ?
Ag7 S3 C100 C101 -59.1(9) . . . . ?
Ag2 S3 C100 C101 95.8(9) . . . . ?
Ag1 S3 C100 C101 -172.7(7) . . . . ?
Cu2A S3 C100 C101 97.4(13) . . . . ?
C43 P7 C37A C38A -84.5(13) . . . . ?
C75 P7 C37A C38A 165.2(11) . . . . ?
Ag8 P7 C37A C38A 44.2(16) . . . . ?
C43 P7 C37A C42A 102.2(17) . . . . ?
C75 P7 C37A C42A -8(2) . . . . ?
Ag8 P7 C37A C42A -129.1(16) . . . . ?
C42A C37A C38A C39A 0.0 . . . . ?
P7 C37A C38A C39A -174(2) . . . . ?
C37A C38A C39A C40A 0.0 . . . . ?
C38A C39A C40A C41A 0.0 . . . . ?
C39A C40A C41A C42A 0.0 . . . . ?
C40A C41A C42A C37A 0.0 . . . . ?
C38A C37A C42A C41A 0.0 . . . . ?
P7 C37A C42A C41A 173(2) . . . . ?

_refine_diff_density_max         2.024
_refine_diff_density_min         -0.890
_refine_diff_density_rms         0.126


# start Validation Reply Form
_vrf_THETM01_compound1           
;
PROBLEM: The value of sine(theta_max)/wavelength is less than 0.575
RESPONSE: The data were truncated by 0.9 anstrom due to the I/sigma
 drops at high angle, which leading to this alert.
;
_vrf_PLAT910_compound1           
;
PROBLEM: Missing # of FCF Reflection(s) Below Theta(Min).         32 Note  
RESPONSE:This may be due to the detector that is too close to the crystal 
miss low-angle reflections
;
# end Validation Reply Form
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_compound2
_database_code_depnum_ccdc_archive 'CCDC 2381277'
loop_
_audit_author_name
_audit_author_address
'shen yanglin'
;Henan University of Engineering
China
;
_audit_update_record             
;
2024-11-18 deposited with the CCDC.	2024-11-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C82 H186 Ag21 Cu4 F24 N4 O4 P4 S20'
_chemical_formula_weight         5032.85

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.7623(9)
_cell_length_b                   17.4036(12)
_cell_length_c                   17.9645(11)
_cell_angle_alpha                111.478(2)
_cell_angle_beta                 110.109(2)
_cell_angle_gamma                98.581(2)
_cell_volume                     3828.0(4)
_cell_formula_units_Z            1
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    8400
_cell_measurement_theta_min      2.9281
_cell_measurement_theta_max      24.4743

_exptl_crystal_description       strip
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.183
_exptl_crystal_F_000             2437
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.1
_exptl_absorpt_coefficient_mu    3.539
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.6526
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker D8 venture'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            31005
_diffrn_reflns_av_unetI/netI     0.0764
_diffrn_reflns_av_R_equivalents  0.0617
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         2.791
_diffrn_reflns_theta_max         22.722
_diffrn_reflns_theta_full        22.722
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_point_group_measured_fraction_full 0.996
_reflns_number_total             10256
_reflns_number_gt                6808
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Apex3 (Bruker, 2014)'
_computing_cell_refinement       'SAINT (Bruker, 2014)'
_computing_data_reduction        'SAINT (Bruker, 2014)'
_computing_structure_solution    'SHELXTL XT-2014/4 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0801P)²+71.0018P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         10256
_refine_ls_number_parameters     724
_refine_ls_number_restraints     59
_refine_ls_R_factor_all          0.1101
_refine_ls_R_factor_gt           0.0625
_refine_ls_wR_factor_ref         0.1809
_refine_ls_wR_factor_gt          0.1562
_refine_ls_goodness_of_fit_ref   1.011
_refine_ls_restrained_S_all      1.033
_refine_ls_shift/su_max          0.023
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.1943(11) 0.7389(10) 0.3226(10) 0.035(4) Uani 1 1 d . . . . .
C2 C 0.1920(15) 0.7327(15) 0.2366(14) 0.074(7) Uani 1 1 d . . . . .
H2A H 0.1487 0.6747 0.1888 0.111 Uiso 1 1 calc R U . . .
H2B H 0.2611 0.7425 0.2409 0.111 Uiso 1 1 calc R U . . .
H2C H 0.1646 0.7767 0.2239 0.111 Uiso 1 1 calc R U . . .
C3 C 0.2416(18) 0.8329(13) 0.3947(15) 0.090(8) Uani 1 1 d . . . . .
H3A H 0.3088 0.8574 0.3994 0.135 Uiso 1 1 calc R U . . .
H3B H 0.2487 0.8346 0.4516 0.135 Uiso 1 1 calc R U . . .
H3C H 0.1978 0.8671 0.3794 0.135 Uiso 1 1 calc R U . . .
C4 C 0.0914(13) 0.7044(14) 0.3133(15) 0.071(7) Uani 1 1 d . . . . .
H4A H 0.0500 0.7399 0.2973 0.106 Uiso 1 1 calc R U . . .
H4B H 0.0958 0.7063 0.3696 0.106 Uiso 1 1 calc R U . . .
H4C H 0.0601 0.6442 0.2667 0.106 Uiso 1 1 calc R U . . .
C5 C 0.5558(14) 0.7858(11) 0.2552(11) 0.047(4) Uani 1 1 d . . . . .
C6 C 0.5393(16) 0.8740(13) 0.2940(13) 0.067(6) Uani 1 1 d . . . . .
H6A H 0.5339 0.9003 0.2535 0.101 Uiso 1 1 calc R U . . .
H6B H 0.5969 0.9124 0.3516 0.101 Uiso 1 1 calc R U . . .
H6C H 0.4765 0.8658 0.3017 0.101 Uiso 1 1 calc R U . . .
C7 C 0.6467(16) 0.7912(14) 0.2364(14) 0.072(6) Uani 1 1 d . . . . .
H7A H 0.6523 0.7329 0.2107 0.108 Uiso 1 1 calc R U . . .
H7B H 0.7078 0.8286 0.2917 0.108 Uiso 1 1 calc R U . . .
H7C H 0.6395 0.8159 0.1943 0.108 Uiso 1 1 calc R U . . .
C8 C 0.4609(14) 0.7213(12) 0.1721(10) 0.057(5) Uani 1 1 d . . . . .
H8A H 0.4525 0.7381 0.1243 0.085 Uiso 1 1 calc R U . . .
H8B H 0.4013 0.7214 0.1847 0.085 Uiso 1 1 calc R U . . .
H8C H 0.4676 0.6629 0.1539 0.085 Uiso 1 1 calc R U . . .
C9 C 0.1757(16) 0.4338(14) 0.0114(13) 0.067(3) Uani 1 1 d . . . . .
C10 C 0.2177(16) 0.5259(13) 0.0312(13) 0.067(3) Uani 1 1 d . . . . .
H10A H 0.1907 0.5322 -0.0236 0.100 Uiso 1 1 calc R U . . .
H10B H 0.2920 0.5423 0.0555 0.100 Uiso 1 1 calc R U . . .
H10C H 0.1982 0.5637 0.0746 0.100 Uiso 1 1 calc R U . . .
C11 C 0.2027(16) 0.3698(14) -0.0544(13) 0.067(3) Uani 1 1 d . . . . .
H11A H 0.1676 0.3104 -0.0686 0.100 Uiso 1 1 calc R U . . .
H11B H 0.2763 0.3805 -0.0286 0.100 Uiso 1 1 calc R U . . .
H11C H 0.1816 0.3772 -0.1088 0.100 Uiso 1 1 calc R U . . .
C12 C 0.0604(15) 0.4117(14) -0.0196(13) 0.067(3) Uani 1 1 d . . . . .
H12A H 0.0309 0.4257 -0.0689 0.100 Uiso 1 1 calc R U . . .
H12B H 0.0461 0.4458 0.0297 0.100 Uiso 1 1 calc R U . . .
H12C H 0.0306 0.3496 -0.0392 0.100 Uiso 1 1 calc R U . . .
C13 C 0.0209(11) 0.3980(10) 0.2542(10) 0.034(4) Uani 1 1 d . . . . .
C14 C -0.0076(11) 0.4235(12) 0.1785(11) 0.046(5) Uani 1 1 d . . . . .
H14A H -0.0080 0.3780 0.1263 0.070 Uiso 1 1 calc R U . . .
H14B H 0.0422 0.4786 0.1967 0.070 Uiso 1 1 calc R U . . .
H14C H -0.0753 0.4304 0.1640 0.070 Uiso 1 1 calc R U . . .
C15 C 0.0286(13) 0.4682(11) 0.3364(11) 0.046(4) Uani 1 1 d . . . . .
H15A H 0.0798 0.5219 0.3532 0.070 Uiso 1 1 calc R U . . .
H15B H 0.0484 0.4511 0.3844 0.070 Uiso 1 1 calc R U . . .
H15C H -0.0374 0.4781 0.3257 0.070 Uiso 1 1 calc R U . . .
C16 C -0.0568(12) 0.3129(11) 0.2279(12) 0.048(5) Uani 1 1 d . . . . .
H16A H -0.1247 0.3196 0.2119 0.072 Uiso 1 1 calc R U . . .
H16B H -0.0391 0.2987 0.2780 0.072 Uiso 1 1 calc R U . . .
H16C H -0.0564 0.2660 0.1771 0.072 Uiso 1 1 calc R U . . .
C17 C 0.1114(11) 0.2884(10) 0.5274(11) 0.034(4) Uani 1 1 d . . . . .
C18 C 0.0811(14) 0.3703(12) 0.5415(14) 0.062(6) Uani 1 1 d . . . . .
H18A H 0.0649 0.3788 0.4880 0.093 Uiso 1 1 calc R U . . .
H18B H 0.1374 0.4204 0.5919 0.093 Uiso 1 1 calc R U . . .
H18C H 0.0213 0.3646 0.5538 0.093 Uiso 1 1 calc R U . . .
C19 C 0.0256(13) 0.2117(11) 0.4450(13) 0.056(5) Uani 1 1 d . . . . .
H19A H 0.0040 0.2276 0.3961 0.084 Uiso 1 1 calc R U . . .
H19B H -0.0319 0.1968 0.4580 0.084 Uiso 1 1 calc R U . . .
H19C H 0.0499 0.1614 0.4279 0.084 Uiso 1 1 calc R U . . .
C20 C 0.1361(14) 0.2738(13) 0.6081(13) 0.062(6) Uani 1 1 d . . . . .
H20A H 0.0800 0.2760 0.6254 0.093 Uiso 1 1 calc R U . . .
H20B H 0.1985 0.3192 0.6568 0.093 Uiso 1 1 calc R U . . .
H20C H 0.1459 0.2167 0.5951 0.093 Uiso 1 1 calc R U . . .
C21 C 0.4169(11) 0.0909(10) 0.3826(9) 0.035(4) Uani 1 1 d . . . . .
C22 C 0.5055(18) 0.1163(16) 0.3626(17) 0.089(8) Uani 1 1 d . . . . .
H22A H 0.5212 0.0641 0.3326 0.133 Uiso 1 1 calc R U . . .
H22B H 0.5651 0.1564 0.4182 0.133 Uiso 1 1 calc R U . . .
H22C H 0.4875 0.1449 0.3241 0.133 Uiso 1 1 calc R U . . .
C23 C 0.3294(15) 0.0200(11) 0.2990(11) 0.064(6) Uani 1 1 d . . . . .
H23A H 0.3158 0.0373 0.2511 0.096 Uiso 1 1 calc R U . . .
H23B H 0.2687 0.0107 0.3095 0.096 Uiso 1 1 calc R U . . .
H23C H 0.3469 -0.0340 0.2821 0.096 Uiso 1 1 calc R U . . .
C24 C 0.4481(14) 0.0613(10) 0.4528(10) 0.050(5) Uani 1 1 d . . . . .
H24A H 0.4759 0.0135 0.4345 0.075 Uiso 1 1 calc R U . . .
H24B H 0.3889 0.0410 0.4618 0.075 Uiso 1 1 calc R U . . .
H24C H 0.5000 0.1097 0.5084 0.075 Uiso 1 1 calc R U . . .
C25 C 0.7284(11) 0.3357(9) 0.3856(9) 0.025(3) Uani 1 1 d . . . . .
C26 C 0.8160(12) 0.4032(11) 0.3949(12) 0.045(4) Uani 1 1 d . . . . .
H26A H 0.8581 0.3738 0.3703 0.068 Uiso 1 1 calc R U . . .
H26B H 0.8576 0.4437 0.4578 0.068 Uiso 1 1 calc R U . . .
H26C H 0.7887 0.4355 0.3626 0.068 Uiso 1 1 calc R U . . .
C27 C 0.6631(13) 0.2693(11) 0.2896(10) 0.048(5) Uani 1 1 d . . . . .
H27A H 0.6389 0.2993 0.2538 0.072 Uiso 1 1 calc R U . . .
H27B H 0.6047 0.2302 0.2859 0.072 Uiso 1 1 calc R U . . .
H27C H 0.7034 0.2353 0.2673 0.072 Uiso 1 1 calc R U . . .
C28 C 0.7672(12) 0.2903(11) 0.4413(11) 0.040(4) Uani 1 1 d . . . . .
H28A H 0.7095 0.2503 0.4374 0.060 Uiso 1 1 calc R U . . .
H28B H 0.8086 0.3336 0.5032 0.060 Uiso 1 1 calc R U . . .
H28C H 0.8087 0.2575 0.4194 0.060 Uiso 1 1 calc R U . . .
C29 C 0.3049(12) 0.1707(11) 0.0946(9) 0.041(4) Uani 1 1 d . . . . .
C30 C 0.2878(14) 0.1970(12) 0.0205(10) 0.054(5) Uani 1 1 d . . . . .
H30A H 0.2952 0.1530 -0.0281 0.081 Uiso 1 1 calc R U . . .
H30B H 0.3380 0.2533 0.0430 0.081 Uiso 1 1 calc R U . . .
H30C H 0.2192 0.2016 -0.0013 0.081 Uiso 1 1 calc R U . . .
C31 C 0.4066(14) 0.1566(12) 0.1258(11) 0.064(6) Uani 1 1 d . . . . .
H31A H 0.4093 0.1093 0.0767 0.095 Uiso 1 1 calc R U . . .
H31B H 0.4162 0.1411 0.1747 0.095 Uiso 1 1 calc R U . . .
H31C H 0.4604 0.2101 0.1465 0.095 Uiso 1 1 calc R U . . .
C32 C 0.2232(16) 0.0915(12) 0.0689(12) 0.068(6) Uani 1 1 d . . . . .
H32A H 0.2196 0.0431 0.0170 0.102 Uiso 1 1 calc R U . . .
H32B H 0.1579 0.1031 0.0544 0.102 Uiso 1 1 calc R U . . .
H32C H 0.2385 0.0764 0.1183 0.102 Uiso 1 1 calc R U . . .
C33 C 0.6169(12) 0.4389(12) 0.1380(11) 0.063(5) Uani 1 1 d D . . . .
C34 C 0.541(3) 0.355(2) 0.0553(18) 0.063(5) Uani 0.50(3) 1 d D . P A 1
H34A H 0.5650 0.3416 0.0089 0.094 Uiso 0.50(3) 1 calc R U P A 1
H34B H 0.4741 0.3626 0.0334 0.094 Uiso 0.50(3) 1 calc R U P A 1
H34C H 0.5356 0.3065 0.0710 0.094 Uiso 0.50(3) 1 calc R U P A 1
C35 C 0.723(2) 0.430(3) 0.164(3) 0.063(5) Uani 0.50(3) 1 d D . P A 1
H35A H 0.7390 0.4146 0.1129 0.094 Uiso 0.50(3) 1 calc R U P A 1
H35B H 0.7264 0.3851 0.1843 0.094 Uiso 0.50(3) 1 calc R U P A 1
H35C H 0.7729 0.4860 0.2124 0.094 Uiso 0.50(3) 1 calc R U P A 1
C36 C 0.594(4) 0.507(2) 0.106(3) 0.063(5) Uani 0.50(3) 1 d D . P A 1
H36A H 0.6073 0.4953 0.0530 0.094 Uiso 0.50(3) 1 calc R U P A 1
H36B H 0.6387 0.5651 0.1526 0.094 Uiso 0.50(3) 1 calc R U P A 1
H36C H 0.5232 0.5041 0.0902 0.094 Uiso 0.50(3) 1 calc R U P A 1
C34A C 0.607(4) 0.3460(16) 0.086(2) 0.088(12) Uani 0.50(3) 1 d D . P A 2
H34D H 0.5418 0.3081 0.0728 0.132 Uiso 0.50(3) 1 calc R U P A 2
H34E H 0.6626 0.3308 0.1202 0.132 Uiso 0.50(3) 1 calc R U P A 2
H34F H 0.6104 0.3381 0.0300 0.132 Uiso 0.50(3) 1 calc R U P A 2
C35A C 0.570(3) 0.465(3) 0.069(3) 0.088(12) Uani 0.50(3) 1 d D . P A 2
H35D H 0.5777 0.4305 0.0153 0.132 Uiso 0.50(3) 1 calc R U P A 2
H35E H 0.6039 0.5269 0.0899 0.132 Uiso 0.50(3) 1 calc R U P A 2
H35F H 0.4979 0.4553 0.0543 0.132 Uiso 0.50(3) 1 calc R U P A 2
C36A C 0.7286(17) 0.480(3) 0.172(2) 0.088(12) Uani 0.50(3) 1 d D . P A 2
H36D H 0.7495 0.4542 0.1245 0.132 Uiso 0.50(3) 1 calc R U P A 2
H36E H 0.7659 0.4702 0.2224 0.132 Uiso 0.50(3) 1 calc R U P A 2
H36F H 0.7435 0.5428 0.1904 0.132 Uiso 0.50(3) 1 calc R U P A 2
C37 C -0.0366(15) 0.1731(13) -0.0244(13) 0.056(5) Uani 1 1 d . . . . .
C38 C -0.1297(15) 0.1123(16) -0.1006(13) 0.091(8) Uani 1 1 d . . . . .
H38A H -0.1865 0.1346 -0.0989 0.137 Uiso 1 1 calc R U . . .
H38B H -0.1422 0.0559 -0.0996 0.137 Uiso 1 1 calc R U . . .
H38C H -0.1233 0.1054 -0.1551 0.137 Uiso 1 1 calc R U . . .
C39 C 0.1691(14) 0.0306(13) 0.5106(11) 0.050(5) Uani 1 1 d . . . . .
C40 C 0.1189(19) -0.0397(14) 0.5272(17) 0.091(8) Uani 1 1 d . . . . .
H40A H 0.0691 -0.0881 0.4705 0.137 Uiso 1 1 calc R U . . .
H40B H 0.0845 -0.0161 0.5641 0.137 Uiso 1 1 calc R U . . .
H40C H 0.1707 -0.0607 0.5579 0.137 Uiso 1 1 calc R U . . .
C110 C 0.0236(18) 0.105(2) 0.1688(16) 0.122(6) Uani 1 1 d D . . . .
Ag1 Ag 0.57812(10) 0.60159(9) 0.28868(9) 0.0441(4) Uani 1 1 d . . . . .
Ag2 Ag 0.42725(10) 0.70997(9) 0.35494(8) 0.0450(4) Uani 1 1 d . . . . .
Ag3 Ag 0.40300(9) 0.43897(9) 0.17314(8) 0.0397(3) Uani 1 1 d . . . . .
Ag4 Ag 0.47155(10) 0.36646(9) 0.31335(8) 0.0406(5) Uani 0.966(4) 1 d . . P B 1
Ag4A Ag 0.392(3) 0.390(3) 0.300(3) 0.046(15) Uiso 0.034(4) 1 d . . P B 2
Ag5 Ag 0.5000 0.5000 0.5000 0.0452(5) Uani 1 2 d S . P B .
Ag6 Ag 0.25134(10) 0.54852(8) 0.24153(8) 0.0406(3) Uani 1 1 d . . . . .
Ag7 Ag 0.31463(10) 0.22233(8) 0.30207(8) 0.0384(3) Uani 1 1 d . . . . .
Ag8 Ag 0.18399(9) 0.32358(8) 0.37785(8) 0.0353(3) Uani 1 1 d . . . . .
Ag9 Ag 0.33692(9) 0.45612(8) 0.56651(8) 0.0371(4) Uani 0.967(2) 1 d . . P B 1
Ag9A Ag 0.369(3) 0.390(2) 0.546(2) 0.0371(4) Uani 0.033(2) 1 d . . P B 2
Ag10 Ag 0.71136(11) 0.48950(12) 0.59387(12) 0.0358(7) Uani 0.805(6) 1 d . . P B
1
A10A Ag 0.6989(5) 0.5398(6) 0.6517(6) 0.047(4) Uani 0.195(6) 1 d . . P B 2
Ag11 Ag 0.52613(19) 0.32399(13) 0.47691(14) 0.0378(9) Uani 0.605(5) 1 d . . P B
1
A11A Ag 0.4639(3) 0.32656(19) 0.5029(2) 0.0389(16) Uani 0.395(5) 1 d . . P B 2
Cu1 Cu 0.15883(14) 0.30591(13) 0.13977(12) 0.0376(5) Uani 1 1 d . . . . .
Cu2 Cu 0.28866(15) 0.18511(13) 0.50739(13) 0.0394(5) Uani 1 1 d . . . . .
F7 F 0.5433(15) 0.1492(15) -0.0515(14) 0.184(3) Uani 1 1 d D . . . .
F8 F 0.7449(16) 0.1096(15) 0.0298(14) 0.184(3) Uani 1 1 d D . . . .
F9 F 0.6355(18) 0.0754(14) -0.1049(12) 0.184(3) Uani 1 1 d D . . . .
F10 F 0.6632(18) 0.1878(14) 0.0863(12) 0.184(3) Uani 1 1 d D . . . .
F11 F 0.7061(17) 0.2091(14) -0.0206(15) 0.184(3) Uani 1 1 d D . . . .
F12 F 0.5896(17) 0.0537(14) -0.0019(14) 0.184(3) Uani 1 1 d D . . . .
O2 O 0.1136(13) 0.1296(13) 0.2499(12) 0.122(6) Uani 1 1 d D . . . .
O1 O -0.309(4) 0.028(3) 0.167(4) 0.199(16) Uiso 0.56(3) 1 d . . P C 1
O1A O -0.294(5) 0.050(4) 0.270(5) 0.199(16) Uiso 0.44(3) 1 d . . P C 2
N1 N 0.2079(11) 0.0821(11) 0.4998(10) 0.050(4) Uani 1 1 d . . . . .
N2 N 0.0370(11) 0.2205(10) 0.0386(9) 0.049(4) Uani 1 1 d . . . . .
P1 P -0.0413(4) -0.0882(3) 0.2505(3) 0.0580(14) Uani 1 1 d D . . . .
F1 F -0.099(5) -0.1830(19) 0.217(4) 0.184(3) Uani 0.242(16) 1 d D . P D 1
F2 F -0.143(3) -0.071(5) 0.224(4) 0.184(3) Uani 0.242(16) 1 d D . P D 1
F3 F 0.018(5) 0.0074(18) 0.292(4) 0.184(3) Uani 0.242(16) 1 d D . P D 1
F4 F 0.057(3) -0.109(5) 0.280(4) 0.184(3) Uani 0.242(16) 1 d D . P D 1
F5 F -0.045(5) -0.104(4) 0.160(2) 0.184(3) Uani 0.242(16) 1 d D . P D 1
F6 F -0.042(5) -0.070(4) 0.342(2) 0.184(3) Uani 0.242(16) 1 d D . P D 1
F1A F -0.066(2) -0.0073(14) 0.2947(16) 0.184(3) Uani 0.758(16) 1 d D . P D 2
F2A F 0.0692(14) -0.0295(18) 0.2896(16) 0.184(3) Uani 0.758(16) 1 d D . P D 2
F3A F -0.010(2) -0.1677(14) 0.2080(17) 0.184(3) Uani 0.758(16) 1 d D . P D 2
F4A F -0.1500(14) -0.1452(18) 0.2083(16) 0.184(3) Uani 0.758(16) 1 d D . P D 2
F5A F -0.018(2) -0.1017(18) 0.3347(13) 0.184(3) Uani 0.758(16) 1 d D . P D 2
F6A F -0.061(2) -0.0743(18) 0.1651(13) 0.184(3) Uani 0.758(16) 1 d D . P D 2
P2 P 0.6474(13) 0.1321(9) -0.0106(8) 0.200(7) Uani 1 1 d D . . . .
S1 S 0.5775(3) 0.7466(3) 0.3423(2) 0.0356(10) Uani 1 1 d . . . . .
S2 S 0.5805(3) 0.4564(3) 0.2275(3) 0.0359(10) Uani 1 1 d . . . . .
S3 S 0.2272(3) 0.4230(3) 0.1168(2) 0.0319(9) Uani 1 1 d . . . . .
S4 S 0.2739(3) 0.6770(3) 0.3642(3) 0.0379(10) Uani 1 1 d . . . . .
S5 S 0.1455(3) 0.3799(3) 0.2711(2) 0.0383(10) Uani 1 1 d . . . . .
S6 S 0.3023(3) 0.2663(3) 0.1892(2) 0.0330(9) Uani 1 1 d . . . . .
S7 S 0.6465(2) 0.3933(2) 0.4293(2) 0.0211(8) Uani 1 1 d . . . . .
S8 S 0.5398(3) 0.4664(2) 0.6145(2) 0.0266(9) Uani 1 1 d . . . . .
S9 S 0.2276(3) 0.3015(2) 0.5075(2) 0.0288(9) Uani 1 1 d . . . . .
S10 S 0.3755(4) 0.1869(3) 0.4225(3) 0.0457(12) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C4 1.47(2) . ?
C1 C2 1.50(2) . ?
C1 C3 1.53(2) . ?
C1 S4 1.861(14) . ?
C5 C7 1.49(2) . ?
C5 C6 1.53(2) . ?
C5 C8 1.52(2) . ?
C5 S1 1.875(16) . ?
C9 C10 1.49(3) . ?
C9 C11 1.51(3) . ?
C9 C12 1.53(3) . ?
C9 S3 1.873(18) . ?
C13 C15 1.49(2) . ?
C13 C16 1.53(2) . ?
C13 C14 1.53(2) . ?
C13 S5 1.854(14) . ?
C17 C20 1.49(2) . ?
C17 C19 1.53(2) . ?
C17 C18 1.52(2) . ?
C17 S9 1.867(14) . ?
C21 C24 1.49(2) . ?
C21 C23 1.51(2) . ?
C21 C22 1.52(2) . ?
C21 S10 1.846(15) . ?
C25 C28 1.51(2) . ?
C25 C27 1.52(2) . ?
C25 C26 1.53(2) . ?
C25 S7 1.877(14) . ?
C29 C32 1.49(3) . ?
C29 C31 1.50(2) . ?
C29 C30 1.52(2) . ?
C29 S6 1.910(15) . ?
C33 C35A 1.468(18) . ?
C33 C36A 1.498(18) . ?
C33 C34A 1.498(18) . ?
C33 C35 1.524(19) . ?
C33 C36 1.531(19) . ?
C33 C34 1.543(19) . ?
C33 S2 1.802(16) . ?
C37 N2 1.16(2) . ?
C37 C38 1.45(3) . ?
C39 N1 1.10(2) . ?
C39 C40 1.51(3) . ?
C110 O2 1.454(17) . ?
Ag1 S1 2.352(4) . ?
Ag1 S2 2.370(4) . ?
Ag1 Ag9A 2.74(4) 2_666 ?
Ag1 Ag3 2.9709(19) . ?
Ag1 Ag9 3.0651(17) 2_666 ?
Ag1 Ag2 3.3716(18) . ?
Ag2 S1 2.325(4) . ?
Ag2 S4 2.329(4) . ?
Ag2 A11A 2.861(3) 2_666 ?
Ag2 Ag6 2.9634(19) . ?
Ag2 Ag11 3.154(2) 2_666 ?
Ag3 S3 2.368(4) . ?
Ag3 S2 2.387(4) . ?
Ag3 Ag4A 2.76(4) . ?
Ag3 Ag4 3.1492(18) . ?
Ag4 S6 2.506(4) . ?
Ag4 S7 2.540(4) . ?
Ag4 S8 2.776(4) 2_666 ?
Ag4 Ag7 3.0446(19) . ?
Ag4 Ag5 3.1392(13) . ?
Ag4 Ag11 3.157(2) . ?
Ag4 Ag9 3.2413(18) 2_666 ?
Ag4A S6 2.13(4) . ?
Ag4A A10A 2.14(4) 2_666 ?
Ag4A S8 2.24(4) 2_666 ?
Ag4A Ag7 2.99(4) . ?
Ag4A Ag5 3.03(4) . ?
Ag5 S8 2.251(4) 2_666 ?
Ag5 S8 2.251(4) . ?
Ag5 A10A 3.006(6) 2_666 ?
Ag5 A10A 3.006(6) . ?
Ag5 A11A 3.008(3) 2_666 ?
Ag5 A11A 3.008(3) . ?
Ag5 Ag4A 3.03(4) 2_666 ?
Ag5 Ag9A 3.04(4) 2_666 ?
Ag5 Ag9A 3.04(4) . ?
Ag5 Ag11 3.039(2) 2_666 ?
Ag5 Ag11 3.039(2) . ?
Ag6 S3 2.357(4) . ?
Ag6 S4 2.373(4) . ?
Ag6 A10A 2.848(6) 2_666 ?
Ag6 Ag10 3.148(2) 2_666 ?
Ag7 S6 2.378(4) . ?
Ag7 S10 2.382(4) . ?
Ag7 A11A 3.116(3) . ?
Ag7 Ag8 3.1211(16) . ?
Ag7 Ag11 3.207(3) . ?
Ag8 S9 2.385(4) . ?
Ag8 S5 2.399(4) . ?
Ag8 Ag9A 2.96(4) . ?
Ag8 A10A 3.041(6) 2_666 ?
Ag8 Ag9 3.0600(17) . ?
Ag8 Ag10 3.159(2) 2_666 ?
Ag9 S9 2.531(4) . ?
Ag9 S7 2.565(4) 2_666 ?
Ag9 S8 2.774(4) . ?
Ag9 Ag1 3.0650(17) 2_666 ?
Ag9 Ag10 3.239(2) 2_666 ?
Ag9 Ag4 3.2413(18) 2_666 ?
Ag9A A11A 2.09(4) . ?
Ag9A S9 2.12(4) . ?
Ag9A S8 2.30(4) . ?
Ag9A Ag1 2.74(4) 2_666 ?
Ag10 S7 2.532(4) . ?
Ag10 S5 2.553(5) 2_666 ?
Ag10 S8 2.677(4) . ?
Ag10 Ag11 3.075(3) . ?
Ag10 Ag6 3.148(2) 2_666 ?
Ag10 Ag8 3.159(2) 2_666 ?
Ag10 Ag9 3.239(2) 2_666 ?
A10A Ag4A 2.14(4) 2_666 ?
A10A S5 2.141(7) 2_666 ?
A10A S8 2.235(7) . ?
A10A Ag6 2.848(6) 2_666 ?
A10A Ag8 3.041(6) 2_666 ?
Ag11 S7 2.550(4) . ?
Ag11 S10 2.609(5) . ?
Ag11 S8 2.704(4) . ?
Ag11 Ag2 3.154(2) 2_666 ?
A11A S10 2.210(5) . ?
A11A S8 2.295(5) . ?
A11A Ag2 2.861(3) 2_666 ?
Cu1 N2 1.930(15) . ?
Cu1 S6 2.311(4) . ?
Cu1 S5 2.330(4) . ?
Cu1 S3 2.374(4) . ?
Cu2 N1 1.930(16) . ?
Cu2 S10 2.310(5) . ?
Cu2 S9 2.336(4) . ?
Cu2 S1 2.426(4) 2_666 ?
F7 P2 1.584(16) . ?
F8 P2 1.552(16) . ?
F9 P2 1.547(16) . ?
F10 P2 1.563(16) . ?
F11 P2 1.586(16) . ?
F12 P2 1.586(16) . ?
P1 F5 1.532(17) . ?
P1 F3 1.514(17) . ?
P1 F1A 1.506(15) . ?
P1 F4 1.513(17) . ?
P1 F4A 1.508(15) . ?
P1 F3A 1.537(15) . ?
P1 F5A 1.546(14) . ?
P1 F2A 1.545(15) . ?
P1 F2 1.521(17) . ?
P1 F1 1.524(17) . ?
P1 F6A 1.575(14) . ?
P1 F6 1.567(17) . ?
S1 Cu2 2.426(4) 2_666 ?
S5 A10A 2.141(7) 2_666 ?
S5 Ag10 2.553(4) 2_666 ?
S7 Ag9 2.565(4) 2_666 ?
S8 Ag4A 2.24(4) 2_666 ?
S8 Ag4 2.776(4) 2_666 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C4 C1 C2 111.4(15) . . ?
C4 C1 C3 108.8(17) . . ?
C2 C1 C3 111.0(17) . . ?
C4 C1 S4 108.0(11) . . ?
C2 C1 S4 111.3(11) . . ?
C3 C1 S4 106.1(11) . . ?
C7 C5 C6 113.3(16) . . ?
C7 C5 C8 110.6(15) . . ?
C6 C5 C8 110.2(15) . . ?
C7 C5 S1 107.8(13) . . ?
C6 C5 S1 105.9(11) . . ?
C8 C5 S1 108.8(12) . . ?
C10 C9 C11 113.7(17) . . ?
C10 C9 C12 108.5(16) . . ?
C11 C9 C12 111.8(18) . . ?
C10 C9 S3 108.9(14) . . ?
C11 C9 S3 107.4(13) . . ?
C12 C9 S3 106.1(13) . . ?
C15 C13 C16 110.4(13) . . ?
C15 C13 C14 110.9(14) . . ?
C16 C13 C14 110.4(13) . . ?
C15 C13 S5 110.6(10) . . ?
C16 C13 S5 108.6(11) . . ?
C14 C13 S5 105.8(10) . . ?
C20 C17 C19 112.0(13) . . ?
C20 C17 C18 110.4(15) . . ?
C19 C17 C18 108.9(14) . . ?
C20 C17 S9 108.0(11) . . ?
C19 C17 S9 108.3(11) . . ?
C18 C17 S9 109.0(10) . . ?
C24 C21 C23 110.4(14) . . ?
C24 C21 C22 110.5(15) . . ?
C23 C21 C22 109.7(16) . . ?
C24 C21 S10 108.8(11) . . ?
C23 C21 S10 108.7(11) . . ?
C22 C21 S10 108.7(13) . . ?
C28 C25 C27 110.0(13) . . ?
C28 C25 C26 111.1(12) . . ?
C27 C25 C26 111.9(13) . . ?
C28 C25 S7 106.6(9) . . ?
C27 C25 S7 108.5(10) . . ?
C26 C25 S7 108.6(10) . . ?
C32 C29 C31 109.7(16) . . ?
C32 C29 C30 112.6(14) . . ?
C31 C29 C30 111.3(15) . . ?
C32 C29 S6 108.5(12) . . ?
C31 C29 S6 109.2(10) . . ?
C30 C29 S6 105.4(11) . . ?
C35A C33 C36A 104(2) . . ?
C35A C33 C34A 103(2) . . ?
C36A C33 C34A 99.9(19) . . ?
C35 C33 C36 119(3) . . ?
C35 C33 C34 109(2) . . ?
C36 C33 C34 101(2) . . ?
C35A C33 S2 122.1(18) . . ?
C36A C33 S2 111.8(17) . . ?
C34A C33 S2 113.7(17) . . ?
C35 C33 S2 110.5(17) . . ?
C36 C33 S2 107.9(18) . . ?
C34 C33 S2 109.5(16) . . ?
N2 C37 C38 178(2) . . ?
N1 C39 C40 178(2) . . ?
S1 Ag1 S2 176.49(14) . . ?
S1 Ag1 Ag9A 91.0(8) . 2_666 ?
S2 Ag1 Ag9A 92.2(8) . 2_666 ?
S1 Ag1 Ag3 128.85(11) . . ?
S2 Ag1 Ag3 51.60(10) . . ?
Ag9A Ag1 Ag3 102.9(8) 2_666 . ?
S1 Ag1 Ag9 114.33(10) . 2_666 ?
S2 Ag1 Ag9 68.65(10) . 2_666 ?
Ag3 Ag1 Ag9 93.26(5) . 2_666 ?
S1 Ag1 Ag2 43.56(10) . . ?
S2 Ag1 Ag2 138.66(11) . . ?
Ag9A Ag1 Ag2 79.1(8) 2_666 . ?
Ag3 Ag1 Ag2 90.74(5) . . ?
Ag9 Ag1 Ag2 102.06(5) 2_666 . ?
S1 Ag2 S4 177.37(15) . . ?
S1 Ag2 A11A 88.58(13) . 2_666 ?
S4 Ag2 A11A 93.88(14) . 2_666 ?
S1 Ag2 Ag6 128.81(11) . . ?
S4 Ag2 Ag6 51.59(11) . . ?
A11A Ag2 Ag6 100.90(8) 2_666 . ?
S1 Ag2 Ag11 109.17(11) . 2_666 ?
S4 Ag2 Ag11 73.17(11) . 2_666 ?
Ag6 Ag2 Ag11 92.30(6) . 2_666 ?
S1 Ag2 Ag1 44.18(11) . . ?
S4 Ag2 Ag1 137.54(12) . . ?
A11A Ag2 Ag1 74.43(9) 2_666 . ?
Ag6 Ag2 Ag1 89.94(5) . . ?
Ag11 Ag2 Ag1 94.10(6) 2_666 . ?
S3 Ag3 S2 178.59(14) . . ?
S3 Ag3 Ag4A 91.0(9) . . ?
S2 Ag3 Ag4A 90.4(9) . . ?
S3 Ag3 Ag1 128.51(11) . . ?
S2 Ag3 Ag1 51.09(11) . . ?
Ag4A Ag3 Ag1 99.3(8) . . ?
S3 Ag3 Ag4 112.76(10) . . ?
S2 Ag3 Ag4 68.64(10) . . ?
Ag1 Ag3 Ag4 91.71(5) . . ?
S6 Ag4 S7 151.36(13) . . ?
S6 Ag4 S8 109.46(12) . 2_666 ?
S7 Ag4 S8 97.75(11) . 2_666 ?
S6 Ag4 Ag7 49.57(10) . . ?
S7 Ag4 Ag7 110.14(9) . . ?
S8 Ag4 Ag7 116.74(9) 2_666 . ?
S6 Ag4 Ag5 123.70(10) . . ?
S7 Ag4 Ag5 70.92(8) . . ?
S8 Ag4 Ag5 44.21(7) 2_666 . ?
Ag7 Ag4 Ag5 93.42(4) . . ?
S6 Ag4 Ag3 70.48(10) . . ?
S7 Ag4 Ag3 131.06(9) . . ?
S8 Ag4 Ag3 66.86(8) 2_666 . ?
Ag7 Ag4 Ag3 118.33(5) . . ?
Ag5 Ag4 Ag3 110.99(5) . . ?
S6 Ag4 Ag11 111.74(11) . . ?
S7 Ag4 Ag11 51.81(9) . . ?
S8 Ag4 Ag11 101.93(9) 2_666 . ?
Ag7 Ag4 Ag11 62.24(5) . . ?
Ag5 Ag4 Ag11 57.72(5) . . ?
Ag3 Ag4 Ag11 168.16(7) . . ?
S6 Ag4 Ag9 156.61(10) . 2_666 ?
S7 Ag4 Ag9 50.94(8) . 2_666 ?
S8 Ag4 Ag9 54.24(8) 2_666 2_666 ?
Ag7 Ag4 Ag9 149.24(5) . 2_666 ?
Ag5 Ag4 Ag9 59.08(3) . 2_666 ?
Ag3 Ag4 Ag9 86.72(5) . 2_666 ?
Ag11 Ag4 Ag9 89.52(5) . 2_666 ?
S6 Ag4A A10A 111.9(18) . 2_666 ?
S6 Ag4A S8 162(2) . 2_666 ?
A10A Ag4A S8 61.4(11) 2_666 2_666 ?
S6 Ag4A Ag3 84.0(12) . . ?
A10A Ag4A Ag3 103.2(15) 2_666 . ?
S8 Ag4A Ag3 81.4(12) 2_666 . ?
S6 Ag4A Ag7 52.2(9) . . ?
A10A Ag4A Ag7 99.9(14) 2_666 . ?
S8 Ag4A Ag7 142.9(16) 2_666 . ?
Ag3 Ag4A Ag7 135.6(14) . . ?
S6 Ag4A Ag5 148.9(17) . . ?
A10A Ag4A Ag5 68.5(10) 2_666 . ?
S8 Ag4A Ag5 47.7(7) 2_666 . ?
Ag3 Ag4A Ag5 126.9(14) . . ?
Ag7 Ag4A Ag5 96.8(11) . . ?
S8 Ag5 S8 180.00(17) 2_666 . ?
S8 Ag5 A10A 47.72(16) 2_666 2_666 ?
S8 Ag5 A10A 132.28(16) . 2_666 ?
S8 Ag5 A10A 132.28(16) 2_666 . ?
S8 Ag5 A10A 47.72(16) . . ?
A10A Ag5 A10A 180.0(4) 2_666 . ?
S8 Ag5 A11A 49.18(11) 2_666 2_666 ?
S8 Ag5 A11A 130.82(11) . 2_666 ?
A10A Ag5 A11A 81.68(15) 2_666 2_666 ?
A10A Ag5 A11A 98.32(15) . 2_666 ?
S8 Ag5 A11A 130.82(11) 2_666 . ?
S8 Ag5 A11A 49.18(11) . . ?
A10A Ag5 A11A 98.32(15) 2_666 . ?
A10A Ag5 A11A 81.68(15) . . ?
A11A Ag5 A11A 180.0 2_666 . ?
S8 Ag5 Ag4A 47.2(8) 2_666 . ?
S8 Ag5 Ag4A 132.8(8) . . ?
A10A Ag5 Ag4A 41.5(8) 2_666 . ?
A10A Ag5 Ag4A 138.5(8) . . ?
A11A Ag5 Ag4A 96.4(7) 2_666 . ?
A11A Ag5 Ag4A 83.6(8) . . ?
S8 Ag5 Ag4A 132.8(8) 2_666 2_666 ?
S8 Ag5 Ag4A 47.2(8) . 2_666 ?
A10A Ag5 Ag4A 138.5(8) 2_666 2_666 ?
A10A Ag5 Ag4A 41.5(8) . 2_666 ?
A11A Ag5 Ag4A 83.6(8) 2_666 2_666 ?
A11A Ag5 Ag4A 96.4(7) . 2_666 ?
Ag4A Ag5 Ag4A 180.0(15) . 2_666 ?
S8 Ag5 Ag9A 48.8(7) 2_666 2_666 ?
S8 Ag5 Ag9A 131.2(7) . 2_666 ?
A10A Ag5 Ag9A 96.4(7) 2_666 2_666 ?
A10A Ag5 Ag9A 83.6(7) . 2_666 ?
A11A Ag5 Ag9A 40.4(8) 2_666 2_666 ?
A11A Ag5 Ag9A 139.6(8) . 2_666 ?
Ag4A Ag5 Ag9A 83.1(10) . 2_666 ?
Ag4A Ag5 Ag9A 96.9(10) 2_666 2_666 ?
S8 Ag5 Ag9A 131.2(7) 2_666 . ?
S8 Ag5 Ag9A 48.8(7) . . ?
A10A Ag5 Ag9A 83.6(7) 2_666 . ?
A10A Ag5 Ag9A 96.4(7) . . ?
A11A Ag5 Ag9A 139.6(8) 2_666 . ?
A11A Ag5 Ag9A 40.4(8) . . ?
Ag4A Ag5 Ag9A 96.9(10) . . ?
Ag4A Ag5 Ag9A 83.1(10) 2_666 . ?
Ag9A Ag5 Ag9A 180.0(13) 2_666 . ?
S8 Ag5 Ag11 59.26(10) 2_666 2_666 ?
S8 Ag5 Ag11 120.74(10) . 2_666 ?
S8 Ag5 Ag11 120.74(10) 2_666 . ?
S8 Ag5 Ag11 59.26(10) . . ?
Ag11 Ag5 Ag11 180.0 2_666 . ?
S3 Ag6 S4 178.21(14) . . ?
S3 Ag6 A10A 89.8(2) . 2_666 ?
S4 Ag6 A10A 92.0(2) . 2_666 ?
S3 Ag6 Ag2 129.55(11) . . ?
S4 Ag6 Ag2 50.27(11) . . ?
A10A Ag6 Ag2 98.65(16) 2_666 . ?
S3 Ag6 Ag10 110.73(11) . 2_666 ?
S4 Ag6 Ag10 71.03(10) . 2_666 ?
Ag2 Ag6 Ag10 89.71(5) . 2_666 ?
S6 Ag7 S10 163.97(16) . . ?
S6 Ag7 Ag4A 45.1(7) . . ?
S10 Ag7 Ag4A 127.0(8) . . ?
S6 Ag7 Ag4 53.34(10) . . ?
S10 Ag7 Ag4 113.37(13) . . ?
S6 Ag7 A11A 126.75(13) . . ?
S10 Ag7 A11A 44.98(13) . . ?
Ag4A Ag7 A11A 82.6(7) . . ?
S6 Ag7 Ag8 98.73(10) . . ?
S10 Ag7 Ag8 92.79(11) . . ?
Ag4A Ag7 Ag8 81.2(8) . . ?
Ag4 Ag7 Ag8 102.09(5) . . ?
A11A Ag7 Ag8 78.57(8) . . ?
S6 Ag7 Ag11 113.88(11) . . ?
S10 Ag7 Ag11 53.20(13) . . ?
Ag4 Ag7 Ag11 60.61(5) . . ?
Ag8 Ag7 Ag11 97.04(6) . . ?
S9 Ag8 S5 166.53(15) . . ?
S9 Ag8 Ag9A 45.1(7) . . ?
S5 Ag8 Ag9A 128.2(7) . . ?
S9 Ag8 A10A 128.69(18) . 2_666 ?
S5 Ag8 A10A 44.43(16) . 2_666 ?
Ag9A Ag8 A10A 84.2(7) . 2_666 ?
S9 Ag8 Ag9 53.69(10) . . ?
S5 Ag8 Ag9 115.00(12) . . ?
S9 Ag8 Ag7 96.97(10) . . ?
S5 Ag8 Ag7 92.94(10) . . ?
Ag9A Ag8 Ag7 81.9(8) . . ?
A10A Ag8 Ag7 80.0(2) 2_666 . ?
Ag9 Ag8 Ag7 103.62(5) . . ?
S9 Ag8 Ag10 116.39(11) . 2_666 ?
S5 Ag8 Ag10 52.56(11) . 2_666 ?
Ag9 Ag8 Ag10 62.75(4) . 2_666 ?
Ag7 Ag8 Ag10 99.57(5) . 2_666 ?
S9 Ag9 S7 149.15(12) . 2_666 ?
S9 Ag9 S8 110.79(12) . . ?
S7 Ag9 S8 97.19(11) 2_666 . ?
S9 Ag9 Ag8 49.39(9) . . ?
S7 Ag9 Ag8 106.47(9) 2_666 . ?
S8 Ag9 Ag8 117.30(9) . . ?
S9 Ag9 Ag1 73.08(9) . 2_666 ?
S7 Ag9 Ag1 132.39(9) 2_666 2_666 ?
S8 Ag9 Ag1 66.95(8) . 2_666 ?
Ag8 Ag9 Ag1 120.83(5) . 2_666 ?
S9 Ag9 Ag5 121.73(9) . . ?
S7 Ag9 Ag5 70.49(8) 2_666 . ?
S8 Ag9 Ag5 44.13(7) . . ?
Ag8 Ag9 Ag5 91.46(4) . . ?
Ag1 Ag9 Ag5 110.91(4) 2_666 . ?
S9 Ag9 Ag10 109.47(10) . 2_666 ?
S7 Ag9 Ag10 50.09(8) 2_666 2_666 ?
S8 Ag9 Ag10 101.45(9) . 2_666 ?
Ag8 Ag9 Ag10 60.11(4) . 2_666 ?
Ag1 Ag9 Ag10 167.83(6) 2_666 2_666 ?
Ag5 Ag9 Ag10 57.33(4) . 2_666 ?
S9 Ag9 Ag4 160.36(10) . 2_666 ?
S7 Ag9 Ag4 50.25(8) 2_666 2_666 ?
S8 Ag9 Ag4 54.29(8) . 2_666 ?
Ag8 Ag9 Ag4 145.59(5) . 2_666 ?
Ag1 Ag9 Ag4 88.28(5) 2_666 2_666 ?
Ag5 Ag9 Ag4 58.84(3) . 2_666 ?
Ag10 Ag9 Ag4 87.50(5) 2_666 2_666 ?
A11A Ag9A S9 111.8(18) . . ?
A11A Ag9A S8 62.9(10) . . ?
S9 Ag9A S8 162.9(19) . . ?
A11A Ag9A Ag1 102.8(14) . 2_666 ?
S9 Ag9A Ag1 86.6(12) . 2_666 ?
S8 Ag9A Ag1 79.3(11) . 2_666 ?
A11A Ag9A Ag8 101.5(14) . . ?
S9 Ag9A Ag8 52.9(8) . . ?
S8 Ag9A Ag8 142.4(15) . . ?
Ag1 Ag9A Ag8 138.3(14) 2_666 . ?
A11A Ag9A Ag5 69.0(10) . . ?
S9 Ag9A Ag5 148.4(16) . . ?
S8 Ag9A Ag5 47.5(7) . . ?
Ag1 Ag9A Ag5 124.7(13) 2_666 . ?
Ag8 Ag9A Ag5 95.6(10) . . ?
S7 Ag10 S5 144.37(13) . 2_666 ?
S7 Ag10 S8 101.45(12) . . ?
S5 Ag10 S8 111.35(14) 2_666 . ?
S7 Ag10 Ag5 72.34(8) . . ?
S5 Ag10 Ag5 122.44(11) 2_666 . ?
S8 Ag10 Ag5 45.56(8) . . ?
S7 Ag10 Ag11 53.04(10) . . ?
S5 Ag10 Ag11 162.10(12) 2_666 . ?
S8 Ag10 Ag11 55.56(10) . . ?
Ag5 Ag10 Ag11 59.34(5) . . ?
S7 Ag10 Ag6 133.55(11) . 2_666 ?
S5 Ag10 Ag6 72.82(10) 2_666 2_666 ?
S8 Ag10 Ag6 70.74(9) . 2_666 ?
Ag5 Ag10 Ag6 116.23(6) . 2_666 ?
Ag11 Ag10 Ag6 90.34(6) . 2_666 ?
S7 Ag10 Ag8 104.52(10) . 2_666 ?
S5 Ag10 Ag8 48.24(10) 2_666 2_666 ?
S8 Ag10 Ag8 116.96(11) . 2_666 ?
Ag5 Ag10 Ag8 91.16(5) . 2_666 ?
Ag11 Ag10 Ag8 145.86(7) . 2_666 ?
Ag6 Ag10 Ag8 120.06(6) 2_666 2_666 ?
S7 Ag10 Ag9 51.01(9) . 2_666 ?
S5 Ag10 Ag9 105.11(11) 2_666 2_666 ?
S8 Ag10 Ag9 105.37(9) . 2_666 ?
Ag5 Ag10 Ag9 59.83(3) . 2_666 ?
Ag11 Ag10 Ag9 91.03(6) . 2_666 ?
Ag6 Ag10 Ag9 174.01(8) 2_666 2_666 ?
Ag8 Ag10 Ag9 57.13(4) 2_666 2_666 ?
Ag4A A10A S5 108.2(12) 2_666 2_666 ?
Ag4A A10A S8 61.4(11) 2_666 . ?
S5 A10A S8 161.6(5) 2_666 . ?
Ag4A A10A Ag6 102.9(11) 2_666 2_666 ?
S5 A10A Ag6 85.2(2) 2_666 2_666 ?
S8 A10A Ag6 82.8(2) . 2_666 ?
Ag4A A10A Ag5 70.0(11) 2_666 . ?
S5 A10A Ag5 146.2(3) 2_666 . ?
S8 A10A Ag5 48.17(15) . . ?
Ag6 A10A Ag5 128.6(2) 2_666 . ?
Ag4A A10A Ag8 98.8(11) 2_666 2_666 ?
S5 A10A Ag8 51.66(17) 2_666 2_666 ?
S8 A10A Ag8 141.0(3) . 2_666 ?
Ag6 A10A Ag8 136.1(2) 2_666 2_666 ?
Ag5 A10A Ag8 94.63(18) . 2_666 ?
S7 Ag11 S10 143.27(15) . . ?
S7 Ag11 S8 100.22(13) . . ?
S10 Ag11 S8 114.09(15) . . ?
S7 Ag11 Ag5 72.55(9) . . ?
S10 Ag11 Ag5 123.10(13) . . ?
S8 Ag11 Ag5 45.70(8) . . ?
S7 Ag11 Ag10 52.49(9) . . ?
S10 Ag11 Ag10 163.34(13) . . ?
S8 Ag11 Ag10 54.73(9) . . ?
Ag5 Ag11 Ag10 60.15(5) . . ?
S7 Ag11 Ag2 130.31(12) . 2_666 ?
S10 Ag11 Ag2 76.34(11) . 2_666 ?
S8 Ag11 Ag2 70.11(9) . 2_666 ?
Ag5 Ag11 Ag2 115.77(8) . 2_666 ?
Ag10 Ag11 Ag2 87.62(6) . 2_666 ?
S7 Ag11 Ag4 51.52(9) . . ?
S10 Ag11 Ag4 103.76(11) . . ?
S8 Ag11 Ag4 106.54(10) . . ?
Ag5 Ag11 Ag4 60.84(4) . . ?
Ag10 Ag11 Ag4 91.94(7) . . ?
Ag2 Ag11 Ag4 176.13(10) 2_666 . ?
S7 Ag11 Ag7 105.09(10) . . ?
S10 Ag11 Ag7 46.97(10) . . ?
S8 Ag11 Ag7 119.32(12) . . ?
Ag5 Ag11 Ag7 92.19(6) . . ?
Ag10 Ag11 Ag7 147.18(8) . . ?
Ag2 Ag11 Ag7 122.42(8) 2_666 . ?
Ag4 Ag11 Ag7 57.16(5) . . ?
Ag9A A11A S10 107.0(10) . . ?
Ag9A A11A S8 63.1(10) . . ?
S10 A11A S8 163.6(3) . . ?
Ag9A A11A Ag2 103.7(10) . 2_666 ?
S10 A11A Ag2 89.10(15) . 2_666 ?
S8 A11A Ag2 81.27(13) . 2_666 ?
Ag9A A11A Ag5 70.6(10) . . ?
S10 A11A Ag5 144.09(17) . . ?
S8 A11A Ag5 47.95(11) . . ?
Ag2 A11A Ag5 126.70(11) 2_666 . ?
Ag9A A11A Ag7 98.1(10) . . ?
S10 A11A Ag7 49.63(12) . . ?
S8 A11A Ag7 141.01(15) . . ?
Ag2 A11A Ag7 137.69(11) 2_666 . ?
Ag5 A11A Ag7 94.61(9) . . ?
N2 Cu1 S6 119.8(4) . . ?
N2 Cu1 S5 117.4(4) . . ?
S6 Cu1 S5 101.97(14) . . ?
N2 Cu1 S3 113.4(4) . . ?
S6 Cu1 S3 99.97(15) . . ?
S5 Cu1 S3 101.42(16) . . ?
N1 Cu2 S10 125.6(5) . . ?
N1 Cu2 S9 121.8(5) . . ?
S10 Cu2 S9 98.75(15) . . ?
N1 Cu2 S1 103.4(5) . 2_666 ?
S10 Cu2 S1 103.46(17) . 2_666 ?
S9 Cu2 S1 99.87(15) . 2_666 ?
C39 N1 Cu2 168.2(16) . . ?
C37 N2 Cu1 175.5(15) . . ?
F5 P1 F3 92.7(19) . . ?
F5 P1 F4 93.5(19) . . ?
F3 P1 F4 89.9(19) . . ?
F1A P1 F4A 92.9(13) . . ?
F1A P1 F3A 176.8(14) . . ?
F4A P1 F3A 90.2(13) . . ?
F1A P1 F5A 88.9(12) . . ?
F4A P1 F5A 91.6(13) . . ?
F3A P1 F5A 90.7(12) . . ?
F1A P1 F2A 87.4(13) . . ?
F4A P1 F2A 177.3(13) . . ?
F3A P1 F2A 89.4(13) . . ?
F5A P1 F2A 91.1(12) . . ?
F5 P1 F2 90.0(19) . . ?
F3 P1 F2 92(2) . . ?
F4 P1 F2 176(2) . . ?
F5 P1 F1 92.9(19) . . ?
F3 P1 F1 174(2) . . ?
F4 P1 F1 89.1(19) . . ?
F2 P1 F1 88.3(19) . . ?
F1A P1 F6A 92.2(12) . . ?
F4A P1 F6A 90.2(13) . . ?
F3A P1 F6A 88.1(12) . . ?
F5A P1 F6A 177.9(14) . . ?
F2A P1 F6A 87.2(12) . . ?
F5 P1 F6 177(2) . . ?
F3 P1 F6 86.8(18) . . ?
F4 P1 F6 89.7(19) . . ?
F2 P1 F6 86.8(18) . . ?
F1 P1 F6 87.6(19) . . ?
F9 P2 F10 177.5(16) . . ?
F9 P2 F8 89.8(13) . . ?
F10 P2 F8 87.7(14) . . ?
F9 P2 F7 90.5(14) . . ?
F10 P2 F7 92.0(13) . . ?
F8 P2 F7 175.8(17) . . ?
F9 P2 F11 84.1(13) . . ?
F10 P2 F11 96.4(14) . . ?
F8 P2 F11 93.6(16) . . ?
F7 P2 F11 90.6(13) . . ?
F9 P2 F12 94.8(14) . . ?
F10 P2 F12 84.6(13) . . ?
F8 P2 F12 85.7(13) . . ?
F7 P2 F12 90.1(15) . . ?
F11 P2 F12 178.8(15) . . ?
C5 S1 Ag2 109.7(6) . . ?
C5 S1 Ag1 111.9(5) . . ?
Ag2 S1 Ag1 92.26(15) . . ?
C5 S1 Cu2 128.4(6) . 2_666 ?
Ag2 S1 Cu2 105.54(15) . 2_666 ?
Ag1 S1 Cu2 102.97(15) . 2_666 ?
C33 S2 Ag1 108.7(6) . . ?
C33 S2 Ag3 108.9(5) . . ?
Ag1 S2 Ag3 77.31(12) . . ?
C9 S3 Ag6 112.5(7) . . ?
C9 S3 Ag3 114.0(7) . . ?
Ag6 S3 Ag3 92.27(14) . . ?
C9 S3 Cu1 125.6(7) . . ?
Ag6 S3 Cu1 104.27(15) . . ?
Ag3 S3 Cu1 102.73(15) . . ?
C1 S4 Ag2 109.4(5) . . ?
C1 S4 Ag6 108.9(5) . . ?
Ag2 S4 Ag6 78.14(13) . . ?
C13 S5 A10A 135.2(6) . 2_666 ?
C13 S5 Cu1 114.0(5) . . ?
A10A S5 Cu1 96.8(3) 2_666 . ?
C13 S5 Ag8 106.8(5) . . ?
A10A S5 Ag8 83.9(2) 2_666 . ?
Cu1 S5 Ag8 118.01(19) . . ?
C13 S5 Ag10 110.4(5) . 2_666 ?
Cu1 S5 Ag10 122.98(17) . 2_666 ?
Ag8 S5 Ag10 79.19(12) . 2_666 ?
C29 S6 Ag4A 143.9(12) . . ?
C29 S6 Cu1 111.1(5) . . ?
Ag4A S6 Cu1 95.9(11) . . ?
C29 S6 Ag7 106.3(5) . . ?
Ag4A S6 Ag7 82.7(10) . . ?
Cu1 S6 Ag7 113.63(17) . . ?
C29 S6 Ag4 116.2(5) . . ?
Cu1 S6 Ag4 125.77(17) . . ?
Ag7 S6 Ag4 77.09(11) . . ?
C25 S7 Ag10 120.4(4) . . ?
C25 S7 Ag4 115.5(4) . . ?
Ag10 S7 Ag4 124.15(13) . . ?
C25 S7 Ag11 121.8(5) . . ?
Ag10 S7 Ag11 74.47(11) . . ?
Ag4 S7 Ag11 76.67(11) . . ?
C25 S7 Ag9 114.7(5) . 2_666 ?
Ag10 S7 Ag9 78.90(11) . 2_666 ?
Ag4 S7 Ag9 78.82(10) . 2_666 ?
Ag11 S7 Ag9 123.47(14) . 2_666 ?
A10A S8 Ag4A 57.2(11) . 2_666 ?
A10A S8 Ag5 84.1(2) . . ?
Ag4A S8 Ag5 85.1(10) 2_666 . ?
A10A S8 A11A 120.5(3) . . ?
Ag4A S8 A11A 168.0(10) 2_666 . ?
Ag5 S8 A11A 82.87(15) . . ?
A10A S8 Ag9A 167.3(10) . . ?
Ag4A S8 Ag9A 125.2(15) 2_666 . ?
Ag5 S8 Ag9A 83.8(9) . . ?
A11A S8 Ag9A 54.1(10) . . ?
Ag5 S8 Ag10 76.36(10) . . ?
Ag5 S8 Ag11 75.04(11) . . ?
Ag10 S8 Ag11 69.71(11) . . ?
Ag5 S8 Ag9 76.76(10) . . ?
Ag10 S8 Ag9 153.06(15) . . ?
Ag11 S8 Ag9 101.42(13) . . ?
Ag5 S8 Ag4 76.49(11) . 2_666 ?
Ag10 S8 Ag4 103.78(13) . 2_666 ?
Ag11 S8 Ag4 151.53(15) . 2_666 ?
Ag9 S8 Ag4 71.47(9) . 2_666 ?
C17 S9 Ag9A 144.4(12) . . ?
C17 S9 Cu2 109.0(5) . . ?
Ag9A S9 Cu2 95.9(11) . . ?
C17 S9 Ag8 106.7(5) . . ?
Ag9A S9 Ag8 82.0(10) . . ?
Cu2 S9 Ag8 117.88(16) . . ?
C17 S9 Ag9 116.3(5) . . ?
Cu2 S9 Ag9 125.25(16) . . ?
Ag8 S9 Ag9 76.92(11) . . ?
C21 S10 A11A 130.6(6) . . ?
C21 S10 Cu2 115.7(5) . . ?
A11A S10 Cu2 95.2(2) . . ?
C21 S10 Ag7 106.3(5) . . ?
A11A S10 Ag7 85.39(16) . . ?
Cu2 S10 Ag7 121.9(2) . . ?
C21 S10 Ag11 107.2(5) . . ?
Cu2 S10 Ag11 120.12(19) . . ?
Ag7 S10 Ag11 79.82(13) . . ?

_refine_diff_density_max         1.760
_refine_diff_density_min         -2.327
_refine_diff_density_rms         0.197


# start Validation Reply Form
_vrf_THETM01_compound2           
;
PROBLEM: The value of sine(theta_max)/wavelength is less than 0.550
RESPONSE: The data were truncated by 0.92 anstrom due to the
I/sigma drops at high angle, which leading to this alert.
;
_vrf_PLAT315_compound2           
;
PROBLEM: Singly Bonded Carbon Detected (H-atoms Missing).       C110 Check 
RESPONSE: This may be due to the poor quality of the crystal data, resulting in a
 large shift of the hydrogen atom on C110.
;
_vrf_PLAT342_compound2           
;
PROBLEM: Low Bond Precision on  C-C Bonds ...............    0.02923 Ang.  
RESPONSE: This may be due to the poor I/sigma ratio of the crystal data 
at high angles
;
_vrf_PLAT910_compound2           
;
PROBLEM: Missing # of FCF Reflection(s) Below Theta(Min).         20 Note  
RESPONSE: This may be due to the detector that is too close to the
crystal miss low-angle reflections
;
# end Validation Reply Form
