# Electronic Supplementary Material (ESI) for Nanoscale Advances.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_221175lt_auto
_database_code_depnum_ccdc_archive 'CCDC 2300897'
loop_
_audit_author_name
_audit_author_address
'NTHU Xrayccd'
;NTHU
Taiwan
;
_audit_update_record             
;
2023-10-12 deposited with the CCDC.	2024-04-08 downloaded from the CCDC.
;
_audit_creation_date             2022-12-01
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C36 H63 Cl5 O16 Sn5'
_chemical_formula_sum            'C36 H63 Cl5 O16 Sn5'
_chemical_formula_weight         1522.56
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C H N O Sn Cl'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn 0.0259 5.4591 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           11
_space_group_name_H-M_alt        'P 1 21/m 1'
_space_group_name_Hall           '-P 2yb'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'

_cell_length_a                   11.92010(10)
_cell_length_b                   16.4662(2)
_cell_length_c                   14.64400(10)
_cell_angle_alpha                90
_cell_angle_beta                 103.9010(10)
_cell_angle_gamma                90
_cell_volume                     2790.12(5)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    17523
_cell_measurement_temperature    100.01(10)
_cell_measurement_theta_max      74.3370
_cell_measurement_theta_min      2.6700
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    20.239
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.25132
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.42.58a (Rigaku Oxford Diffraction, 2022)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.812
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             1484
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.05
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0471
_diffrn_reflns_av_unetI/netI     0.0272
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            20553
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        67.073
_diffrn_reflns_theta_max         67.073
_diffrn_reflns_theta_min         3.109
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.01(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            'HyPix-Arc 150'
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     46.00 110.00   0.40    0.33    --   70.92  15.00 150.00  160
  2  ω     84.00 109.20   0.40    0.33    --   74.26  15.00 -90.00   63
  3  ω     48.00  83.20   0.40    0.33    --   74.26  15.00 -90.00   88
  4  ω     48.00  91.20   0.40    0.33    --   74.26  15.00-150.00  108
  5  ω     76.00 116.00   0.40    0.33    --   82.74  15.00-180.00  100
  6  ω     56.00 125.20   0.40    0.33    --   82.74  15.00-120.00  173
  7  ω     64.00 106.00   0.40    0.33    --   82.74  15.00 150.00  105
  8  ω     49.00  84.20   0.40    0.33    --   82.74 -95.00-150.00   88
  9  ω     72.00 100.00   0.40    0.33    --   74.26-125.00-150.00   70
 10  ω     40.00 100.00   0.40    0.33    --   82.74-125.00-180.00  150
 11  ω     33.00  67.00   0.40    0.33    --   74.26-125.00-150.00   85
 12  ω     12.00  55.20   0.40    0.33    --   57.70-112.00  98.00  108
 13  ω     33.00  98.20   0.40    0.33    --   78.50-120.00 143.52  163
 14  ω     60.00  85.20   0.40    0.33    --   74.26-112.00  98.00   63
 15  ω     33.00  58.20   0.40    0.33    --   70.92-112.00  98.00   63
 16  ω     52.00  83.20   0.40    0.33    --   82.74-112.00  98.00   78
 17  ω     43.00  83.00   0.40    0.33    --   82.74 -95.00 -90.00  100
 18  ω     44.00  69.20   0.40    0.33    --   74.26 -95.00-180.00   63
 19  ω    -87.00 -61.00   0.40    0.33    --  -73.63 -15.00   0.00   65
 20  ω   -121.00 -89.00   0.40    0.33    --  -73.63 -15.00   0.00   80
 21  ω   -118.00 -56.00   0.40    0.33    --  -73.77 -15.00-120.00  155
 22  ω    -84.00 -59.20   0.40    0.33    --  -73.63 112.00-168.00   62
 23  ω    -72.00 -47.20   0.40    0.33    --  -73.77 112.00-168.00   62
 24  ω    -65.00 -35.00   0.40    0.33    --  -60.85 112.00-168.00   75
 25  ω    -91.00 -57.00   0.40    0.33    --  -73.77 125.00 -30.00   85
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy R, DW system, HyPix-Arc 150'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0775284000
_diffrn_orient_matrix_UB_12      -0.0753456000
_diffrn_orient_matrix_UB_13      -0.0030108000
_diffrn_orient_matrix_UB_21      -0.1079199000
_diffrn_orient_matrix_UB_22      0.0525849000
_diffrn_orient_matrix_UB_23      -0.0384164000
_diffrn_orient_matrix_UB_31      0.0089401000
_diffrn_orient_matrix_UB_32      -0.0177840000
_diffrn_orient_matrix_UB_33      -0.1012400000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'Rotating-anode X-ray tube'
_diffrn_source_type              'Rigaku (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4987
_reflns_number_total             5167
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.42.58a (Rigaku OD, 2022)'
_computing_data_collection       'CrysAlisPro 1.171.42.58a (Rigaku OD, 2022)'
_computing_data_reduction        'CrysAlisPro 1.171.42.58a (Rigaku OD, 2022)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         2.602
_refine_diff_density_min         -2.466
_refine_diff_density_rms         0.200
_refine_ls_extinction_coef       0.00016(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.090
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     406
_refine_ls_number_reflns         5167
_refine_ls_number_restraints     258
_refine_ls_R_factor_all          0.0608
_refine_ls_R_factor_gt           0.0595
_refine_ls_restrained_S_all      1.079
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0842P)²+30.3004P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1573
_refine_ls_wR_factor_ref         0.1584
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Rigid bond restraints
 C12, C13, C14, C15, C12A, C13A, C14A, C15A
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 C19, C20, C21, C22, C19A, C20A, C21A, C22A
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 C4, C4A
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
3. Uiso/Uaniso restraints and constraints
C12 \\sim C13 \\sim C14 \\sim C15 \\sim C12A \\sim C13A \\sim C14A \\sim C15A:
within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
C19 \\sim C20 \\sim C21 \\sim C22 \\sim C19A \\sim C20A \\sim C21A \\sim C22A:
within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
C4 \\sim C4A: within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02
within 2A
Uanis(C2) \\sim Ueq, Uanis(C3) \\sim Ueq, Uanis(C7) \\sim Ueq, Uanis(C16) \\sim
Ueq, Uanis(C17) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of
0.02
4. Same fragment restrains
{C12, C13, C14, C15} sigma for 1-2: 0.02, 1-3: 0.04
as in
{C12A, C13A, C14A, C15A}
{C19, C20, C21, C22} sigma for 1-2: 0.02, 1-3: 0.04
as in
{C19A, C20A, C21A, C22A}
5. Others
 Sof(C19A)=Sof(C20A)=Sof(H20D)=Sof(H20E)=Sof(H20F)=Sof(C21A)=Sof(H21D)=
 Sof(H21E)=Sof(H21F)=Sof(C22A)=Sof(H22D)=Sof(H22E)=Sof(H22F)=1-FVAR(1)
 Sof(C19)=Sof(C20)=Sof(H20A)=Sof(H20B)=Sof(H20C)=Sof(C21)=Sof(H21A)=Sof(H21B)=
 Sof(H21C)=Sof(C22)=Sof(H22A)=Sof(H22B)=Sof(H22C)=FVAR(1)
 Sof(C12A)=Sof(C13A)=Sof(H13D)=Sof(H13E)=Sof(H13F)=Sof(C14A)=Sof(H14D)=
 Sof(H14E)=Sof(H14F)=Sof(C15A)=Sof(H15D)=Sof(H15E)=Sof(H15F)=1-FVAR(2)
 Sof(C12)=Sof(C13)=Sof(H13A)=Sof(H13B)=Sof(H13C)=Sof(C14)=Sof(H14A)=Sof(H14B)=
 Sof(H14C)=Sof(C15)=Sof(H15A)=Sof(H15B)=Sof(H15C)=FVAR(2)
 Sof(C4A)=Sof(H4AA)=Sof(H4AB)=Sof(H4AC)=1-FVAR(3)
 Sof(C4)=Sof(H4A)=Sof(H4B)=Sof(H4C)=FVAR(3)
 Fixed Sof: H3A(0.5) H3B(0.5) H3C(0.5) H10A(0.5) H10B(0.5) H10C(0.5)
6.a Aromatic/amide H refined with riding coordinates:
 C5(H5), C16(H16)
6.b X=CH2 refined with riding coordinates:
 C6(H6A,H6B), C17(H17A,H17B)
6.c Idealised Me refined as rotating group:
 C3(H3A,H3B,H3C), C9(H9A,H9B,H9C), C10(H10A,H10B,H10C), C13(H13A,H13B,H13C),
 C14(H14A,H14B,H14C), C15(H15A,H15B,H15C), C20(H20A,H20B,H20C), C21(H21A,H21B,
 H21C), C22(H22A,H22B,H22C), C13A(H13D,H13E,H13F), C14A(H14D,H14E,H14F),
 C15A(H15D,H15E,H15F), C20A(H20D,H20E,H20F), C21A(H21D,H21E,H21F), C22A(H22D,
 H22E,H22F), C4A(H4AA,H4AB,H4AC), C4(H4A,H4B,H4C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.3684(11) 0.250000 0.2330(9) 0.048(4) Uani 1 2 d S T P E .
C2 C 0.2491(17) 0.250000 0.1684(14) 0.077(5) Uani 1 2 d S TU P . .
C3 C 0.1570(14) 0.250000 0.2180(13) 0.078(5) Uani 1 2 d S TU P E .
H3A H 0.153231 0.303325 0.246813 0.116 Uiso 0.5 1 calc R U P A -1
H3B H 0.172588 0.208213 0.267058 0.116 Uiso 0.5 1 calc R U P A -1
H3C H 0.083118 0.238463 0.173484 0.116 Uiso 0.5 1 calc R U P A -1
C5 C 0.7208(8) 0.4456(6) 0.5213(7) 0.047(2) Uani 1 1 d . . . . .
H5 H 0.655226 0.476604 0.526266 0.056 Uiso 1 1 calc R U . . .
C6 C 0.7754(9) 0.4674(7) 0.4581(8) 0.059(3) Uani 1 1 d . . . . .
H6A H 0.841259 0.437793 0.451245 0.071 Uiso 1 1 calc R U . . .
H6B H 0.749319 0.512940 0.418841 0.071 Uiso 1 1 calc R U . . .
C7 C 0.9607(9) 0.250000 0.5503(7) 0.027(2) Uani 1 2 d S TU P . .
C8 C 1.0773(9) 0.250000 0.5277(8) 0.036(3) Uani 1 2 d S T P . .
C9 C 1.0950(8) 0.1732(7) 0.4736(7) 0.048(2) Uani 1 1 d . . . . .
H9A H 1.088947 0.125187 0.511641 0.071 Uiso 1 1 calc R U . . .
H9B H 1.171681 0.174717 0.460238 0.071 Uiso 1 1 calc R U . . .
H9C H 1.035676 0.170691 0.414315 0.071 Uiso 1 1 calc R U . . .
C10 C 1.1663(11) 0.250000 0.6248(10) 0.064(5) Uani 1 2 d S T P . .
H10A H 1.242716 0.264688 0.616160 0.096 Uiso 0.5 1 calc R U P B -1
H10B H 1.169622 0.195756 0.652849 0.096 Uiso 0.5 1 calc R U P B -1
H10C H 1.142481 0.289556 0.666472 0.096 Uiso 0.5 1 calc R U P B -1
C11 C 0.9704(7) 0.4040(6) 0.7825(6) 0.039(2) Uani 1 1 d . . . . .
C16 C 0.9062(12) 0.250000 0.9896(9) 0.051(3) Uani 1 2 d S TU P . .
H16 H 0.987011 0.250000 1.016693 0.061 Uiso 1 2 calc R U P . .
C17 C 0.8475(12) 0.250000 1.0440(9) 0.058(4) Uani 1 2 d S TU P . .
H17A H 0.765748 0.250000 1.022228 0.070 Uiso 1 2 calc R U P . .
H17B H 0.882052 0.250000 1.109628 0.070 Uiso 1 2 calc R U P . .
C18 C 0.6524(9) 0.3745(11) 0.7783(7) 0.081(5) Uani 1 1 d . . . . .
Cl1 Cl 0.44123(17) 0.14134(15) 0.49880(14) 0.0401(5) Uani 1 1 d . . . . .
Cl2 Cl 0.8319(2) 0.250000 0.32060(19) 0.0423(7) Uani 1 2 d S T P . .
Cl3 Cl 0.6417(2) 0.13913(18) 0.14478(16) 0.0528(6) Uani 1 1 d . . . . .
O1 O 0.3776(7) 0.250000 0.3203(5) 0.037(2) Uani 1 2 d S T P . .
O2 O 0.4518(7) 0.250000 0.1914(5) 0.043(2) Uani 1 2 d S T P . .
O3 O 0.9174(4) 0.3177(4) 0.5619(4) 0.0299(12) Uani 1 1 d . . . . .
O4 O 0.8880(5) 0.4183(4) 0.7136(4) 0.0402(14) Uani 1 1 d . . . . .
O5 O 0.9825(5) 0.3403(4) 0.8320(4) 0.0396(15) Uani 1 1 d . . . . .
O6 O 0.7298(6) 0.3402(6) 0.8376(4) 0.068(3) Uani 1 1 d . . . . .
O7 O 0.6456(5) 0.3760(5) 0.6903(4) 0.0493(18) Uani 1 1 d . . . . .
O8 O 0.6772(6) 0.250000 0.5381(5) 0.0279(17) Uani 1 2 d S T P . .
O9 O 0.8168(6) 0.250000 0.7003(5) 0.0259(16) Uani 1 2 d S T P . .
O10 O 0.5918(4) 0.1728(4) 0.3478(3) 0.0307(12) Uani 1 1 d . . . . .
Sn1 Sn 0.76778(4) 0.34707(3) 0.61254(3) 0.02809(19) Uani 1 1 d . . . . .
Sn2 Sn 0.52484(6) 0.250000 0.43541(4) 0.0269(2) Uani 1 2 d S T P E .
Sn3 Sn 0.63221(6) 0.250000 0.24463(5) 0.0298(2) Uani 1 2 d S T P E .
Sn4 Sn 0.85839(6) 0.250000 0.84109(5) 0.0374(3) Uani 1 2 d S T P . .
C12 C 1.0627(17) 0.4630(15) 0.8207(14) 0.045(3) Uani 0.510(13) 1 d D U P C 1
C13 C 1.0471(19) 0.5321(14) 0.7494(15) 0.062(4) Uani 0.510(13) 1 d D U P C 1
H13A H 1.031811 0.509608 0.685654 0.093 Uiso 0.510(13) 1 calc R U P C 1
H13B H 1.117571 0.565078 0.761251 0.093 Uiso 0.510(13) 1 calc R U P C 1
H13C H 0.981805 0.566130 0.755513 0.093 Uiso 0.510(13) 1 calc R U P C 1
C14 C 1.1810(15) 0.4252(14) 0.8370(18) 0.055(4) Uani 0.510(13) 1 d D U P C 1
H14A H 1.186525 0.379627 0.880886 0.082 Uiso 0.510(13) 1 calc R U P C 1
H14B H 1.239767 0.465873 0.863582 0.082 Uiso 0.510(13) 1 calc R U P C 1
H14C H 1.193565 0.405505 0.777073 0.082 Uiso 0.510(13) 1 calc R U P C 1
C15 C 1.0471(18) 0.4942(14) 0.9148(14) 0.055(4) Uani 0.510(13) 1 d D U P C 1
H15A H 0.966590 0.510681 0.908115 0.083 Uiso 0.510(13) 1 calc R U P C 1
H15B H 1.098044 0.540879 0.934748 0.083 Uiso 0.510(13) 1 calc R U P C 1
H15C H 1.066734 0.450980 0.961976 0.083 Uiso 0.510(13) 1 calc R U P C 1
C19 C 0.5840(16) 0.4543(15) 0.8001(14) 0.060(4) Uani 0.511(14) 1 d D U P D 1
C20 C 0.635(2) 0.5368(18) 0.791(2) 0.088(7) Uani 0.511(14) 1 d D U P D 1
H20A H 0.575731 0.578578 0.789254 0.132 Uiso 0.511(14) 1 calc R U P D 1
H20B H 0.661392 0.539081 0.732595 0.132 Uiso 0.511(14) 1 calc R U P D 1
H20C H 0.700197 0.546509 0.844743 0.132 Uiso 0.511(14) 1 calc R U P D 1
C21 C 0.567(2) 0.429(2) 0.9048(15) 0.064(5) Uani 0.511(14) 1 d D U P D 1
H21A H 0.642042 0.431951 0.950777 0.096 Uiso 0.511(14) 1 calc R U P D 1
H21B H 0.537956 0.372917 0.902631 0.096 Uiso 0.511(14) 1 calc R U P D 1
H21C H 0.512376 0.465701 0.923115 0.096 Uiso 0.511(14) 1 calc R U P D 1
C22 C 0.450(2) 0.430(2) 0.743(2) 0.070(6) Uani 0.511(14) 1 d D U P D 1
H22A H 0.397408 0.439618 0.783762 0.105 Uiso 0.511(14) 1 calc R U P D 1
H22B H 0.447562 0.372443 0.725256 0.105 Uiso 0.511(14) 1 calc R U P D 1
H22C H 0.426997 0.463357 0.686187 0.105 Uiso 0.511(14) 1 calc R U P D 1
C12A C 1.0664(19) 0.4749(14) 0.8008(14) 0.045(3) Uani 0.490(13) 1 d D U P C 2
C13A C 1.1147(18) 0.4859(14) 0.7131(13) 0.049(4) Uani 0.490(13) 1 d D U P C 2
H13D H 1.190980 0.511661 0.731235 0.074 Uiso 0.490(13) 1 calc R U P C 2
H13E H 1.062239 0.520302 0.667325 0.074 Uiso 0.490(13) 1 calc R U P C 2
H13F H 1.121776 0.432737 0.684886 0.074 Uiso 0.490(13) 1 calc R U P C 2
C14A C 1.1628(17) 0.4529(15) 0.8832(14) 0.049(4) Uani 0.490(13) 1 d D U P C 2
H14D H 1.197290 0.401346 0.870703 0.073 Uiso 0.490(13) 1 calc R U P C 2
H14E H 1.132476 0.447436 0.939478 0.073 Uiso 0.490(13) 1 calc R U P C 2
H14F H 1.221745 0.495657 0.893472 0.073 Uiso 0.490(13) 1 calc R U P C 2
C15A C 1.0094(19) 0.5545(14) 0.8161(16) 0.057(4) Uani 0.490(13) 1 d D U P C 2
H15D H 1.067377 0.597902 0.827751 0.086 Uiso 0.490(13) 1 calc R U P C 2
H15E H 0.975361 0.549428 0.870465 0.086 Uiso 0.490(13) 1 calc R U P C 2
H15F H 0.948655 0.567633 0.759989 0.086 Uiso 0.490(13) 1 calc R U P C 2
C19A C 0.5415(18) 0.3922(15) 0.8175(15) 0.066(4) Uani 0.489(14) 1 d D U P D 2
C20A C 0.483(3) 0.3200(19) 0.847(3) 0.100(7) Uani 0.489(14) 1 d D U P D 2
H20D H 0.540541 0.285205 0.887885 0.150 Uiso 0.489(14) 1 calc R U P D 2
H20E H 0.443362 0.289297 0.791258 0.150 Uiso 0.489(14) 1 calc R U P D 2
H20F H 0.426322 0.338158 0.881429 0.150 Uiso 0.489(14) 1 calc R U P D 2
C21A C 0.602(3) 0.457(2) 0.9018(17) 0.068(6) Uani 0.489(14) 1 d D U P D 2
H21D H 0.543478 0.478152 0.931870 0.102 Uiso 0.489(14) 1 calc R U P D 2
H21E H 0.637428 0.501595 0.874500 0.102 Uiso 0.489(14) 1 calc R U P D 2
H21F H 0.662141 0.428548 0.948722 0.102 Uiso 0.489(14) 1 calc R U P D 2
C22A C 0.474(2) 0.4619(18) 0.741(2) 0.064(6) Uani 0.489(14) 1 d D U P D 2
H22D H 0.433803 0.435183 0.682441 0.096 Uiso 0.489(14) 1 calc R U P D 2
H22E H 0.530056 0.500759 0.728123 0.096 Uiso 0.489(14) 1 calc R U P D 2
H22F H 0.416981 0.490646 0.767903 0.096 Uiso 0.489(14) 1 calc R U P D 2
C4A C 0.2410(19) 0.219(2) 0.0743(16) 0.096(11) Uani 0.52(2) 1 d . U P E -2
H4AA H 0.317885 0.219515 0.061255 0.143 Uiso 0.52(2) 1 calc R U P E -2
H4AB H 0.188982 0.254107 0.028593 0.143 Uiso 0.52(2) 1 calc R U P E -2
H4AC H 0.210720 0.163817 0.069454 0.143 Uiso 0.52(2) 1 calc R U P E -2
C4 C 0.245(3) 0.141(3) 0.147(3) 0.110(12) Uani 0.48(2) 1 d . U P E -1
H4A H 0.178168 0.127573 0.095639 0.165 Uiso 0.48(2) 1 calc R U P E -1
H4B H 0.237351 0.112240 0.204468 0.165 Uiso 0.48(2) 1 calc R U P E -1
H4C H 0.315962 0.123594 0.130839 0.165 Uiso 0.48(2) 1 calc R U P E -1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.51(2) . ?
C1 O1 1.257(15) . ?
C1 O2 1.285(15) . ?
C2 C3 1.45(3) . ?
C2 C4A 1.45(3) . ?
C2 C4 1.82(4) . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C5 H5 0.9500 . ?
C5 C6 1.304(16) . ?
C5 Sn1 2.091(10) . ?
C6 H6A 0.9500 . ?
C6 H6B 0.9500 . ?
C7 C8 1.503(15) . ?
C7 O3 1.258(8) 4_565 ?
C7 O3 1.258(8) . ?
C8 C9 1.534(13) 4_565 ?
C8 C9 1.534(12) . ?
C8 C10 1.556(16) . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 O4 1.250(10) . ?
C11 O5 1.264(12) . ?
C11 C12 1.47(3) . ?
C11 C12A 1.61(3) . ?
C16 H16 0.9500 . ?
C16 C17 1.18(2) . ?
C16 Sn4 2.112(13) . ?
C17 H17A 0.9500 . ?
C17 H17B 0.9500 . ?
C18 O6 1.240(14) . ?
C18 O7 1.272(12) . ?
C18 C19 1.62(2) . ?
C18 C19A 1.59(2) . ?
Cl1 Sn2 2.345(2) . ?
Cl2 Sn3 2.373(3) . ?
Cl3 Sn3 2.359(3) . ?
O1 Sn2 2.121(7) . ?
O2 Sn3 2.104(8) . ?
O3 Sn1 2.145(5) . ?
O4 Sn1 2.145(6) . ?
O5 Sn4 2.124(7) . ?
O6 Sn4 2.126(8) . ?
O7 Sn1 2.108(6) . ?
O8 Sn1 2.084(4) 4_565 ?
O8 Sn1 2.084(4) . ?
O8 Sn2 2.061(7) . ?
O9 Sn1 2.047(4) 4_565 ?
O9 Sn1 2.047(4) . ?
O9 Sn4 2.001(7) . ?
O10 Sn2 2.095(6) . ?
O10 Sn3 2.116(6) . ?
Sn1 Sn1 3.1967(11) 4_565 ?
C12 C13 1.53(2) . ?
C12 C14 1.51(2) . ?
C12 C15 1.52(2) . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C19 C20 1.51(3) . ?
C19 C21 1.65(2) . ?
C19 C22 1.66(2) . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C12A C13A 1.54(2) . ?
C12A C14A 1.50(2) . ?
C12A C15A 1.52(2) . ?
C13A H13D 0.9800 . ?
C13A H13E 0.9800 . ?
C13A H13F 0.9800 . ?
C14A H14D 0.9800 . ?
C14A H14E 0.9800 . ?
C14A H14F 0.9800 . ?
C15A H15D 0.9800 . ?
C15A H15E 0.9800 . ?
C15A H15F 0.9800 . ?
C19A C20A 1.49(3) . ?
C19A C21A 1.66(2) . ?
C19A C22A 1.67(3) . ?
C20A H20D 0.9800 . ?
C20A H20E 0.9800 . ?
C20A H20F 0.9800 . ?
C21A H21D 0.9800 . ?
C21A H21E 0.9800 . ?
C21A H21F 0.9800 . ?
C22A H22D 0.9800 . ?
C22A H22E 0.9800 . ?
C22A H22F 0.9800 . ?
C4A H4AA 0.9800 . ?
C4A H4AB 0.9800 . ?
C4A H4AC 0.9800 . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 C1 C2 118.5(13) . . ?
O1 C1 O2 126.5(11) . . ?
O2 C1 C2 115.0(12) . . ?
C1 C2 C4 95.2(12) . . ?
C3 C2 C1 113.4(15) . . ?
C3 C2 C4 95.1(15) . . ?
C4A C2 C1 115.8(16) . . ?
C4A C2 C3 126.1(17) . . ?
C2 C3 H3A 109.5 . . ?
C2 C3 H3B 109.5 . . ?
C2 C3 H3C 109.5 . . ?
H3A C3 H3B 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C6 C5 H5 117.8 . . ?
C6 C5 Sn1 124.3(8) . . ?
Sn1 C5 H5 117.8 . . ?
C5 C6 H6A 120.0 . . ?
C5 C6 H6B 120.0 . . ?
H6A C6 H6B 120.0 . . ?
O3 C7 C8 117.4(5) . . ?
O3 C7 C8 117.4(5) 4_565 . ?
O3 C7 O3 125.0(10) . 4_565 ?
C7 C8 C9 111.3(6) . 4_565 ?
C7 C8 C9 111.3(6) . . ?
C7 C8 C10 105.2(9) . . ?
C9 C8 C9 111.1(10) . 4_565 ?
C9 C8 C10 108.9(7) . . ?
C9 C8 C10 108.9(7) 4_565 . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
C8 C9 H9C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C8 C10 H10A 109.5 . . ?
C8 C10 H10B 109.5 . . ?
C8 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
O4 C11 O5 125.4(9) . . ?
O4 C11 C12 123.6(12) . . ?
O4 C11 C12A 112.8(11) . . ?
O5 C11 C12 110.9(11) . . ?
O5 C11 C12A 121.8(9) . . ?
C17 C16 H16 115.1 . . ?
C17 C16 Sn4 129.7(12) . . ?
Sn4 C16 H16 115.1 . . ?
C16 C17 H17A 120.0 . . ?
C16 C17 H17B 120.0 . . ?
H17A C17 H17B 120.0 . . ?
O6 C18 O7 125.0(9) . . ?
O6 C18 C19 123.9(11) . . ?
O6 C18 C19A 112.0(12) . . ?
O7 C18 C19 105.8(13) . . ?
O7 C18 C19A 120.4(11) . . ?
C1 O1 Sn2 131.4(8) . . ?
C1 O2 Sn3 131.5(7) . . ?
C7 O3 Sn1 130.5(6) . . ?
C11 O4 Sn1 136.0(7) . . ?
C11 O5 Sn4 129.2(5) . . ?
C18 O6 Sn4 138.2(6) . . ?
C18 O7 Sn1 131.2(6) . . ?
Sn1 O8 Sn1 100.1(3) 4_565 . ?
Sn2 O8 Sn1 129.55(15) . 4_565 ?
Sn2 O8 Sn1 129.55(15) . . ?
Sn1 O9 Sn1 102.7(3) 4_565 . ?
Sn4 O9 Sn1 127.58(16) . . ?
Sn4 O9 Sn1 127.58(16) . 4_565 ?
Sn2 O10 Sn3 105.0(3) . . ?
C5 Sn1 O3 94.1(3) . . ?
C5 Sn1 O4 92.8(3) . . ?
C5 Sn1 O7 93.2(4) . . ?
C5 Sn1 Sn1 140.9(3) . 4_565 ?
O3 Sn1 Sn1 76.98(16) . 4_565 ?
O4 Sn1 O3 83.6(2) . . ?
O4 Sn1 Sn1 123.15(17) . 4_565 ?
O7 Sn1 O3 167.9(2) . . ?
O7 Sn1 O4 86.4(2) . . ?
O7 Sn1 Sn1 103.0(2) . 4_565 ?
O8 Sn1 C5 103.6(3) . . ?
O8 Sn1 O3 90.9(3) . . ?
O8 Sn1 O4 163.1(2) . . ?
O8 Sn1 O7 96.7(3) . . ?
O8 Sn1 Sn1 39.93(14) . 4_565 ?
O9 Sn1 C5 178.7(4) . . ?
O9 Sn1 O3 84.6(2) . . ?
O9 Sn1 O4 87.2(2) . . ?
O9 Sn1 O7 88.1(3) . . ?
O9 Sn1 O8 76.3(2) . . ?
O9 Sn1 Sn1 38.65(15) . 4_565 ?
Cl1 Sn2 Cl1 99.44(12) 4_565 . ?
O1 Sn2 Cl1 88.00(15) . 4_565 ?
O1 Sn2 Cl1 88.00(15) . . ?
O8 Sn2 Cl1 95.45(14) . . ?
O8 Sn2 Cl1 95.45(14) . 4_565 ?
O8 Sn2 O1 174.6(3) . . ?
O8 Sn2 O10 92.8(2) . 4_565 ?
O8 Sn2 O10 92.8(2) . . ?
O10 Sn2 Cl1 92.30(17) . . ?
O10 Sn2 Cl1 164.94(16) 4_565 . ?
O10 Sn2 Cl1 164.94(16) . 4_565 ?
O10 Sn2 Cl1 92.31(17) 4_565 4_565 ?
O10 Sn2 O1 83.0(2) 4_565 . ?
O10 Sn2 O1 83.0(2) . . ?
O10 Sn2 O10 74.7(3) 4_565 . ?
Cl3 Sn3 Cl2 95.65(8) 4_565 . ?
Cl3 Sn3 Cl2 95.65(8) . . ?
Cl3 Sn3 Cl3 101.43(14) . 4_565 ?
O2 Sn3 Cl2 174.0(2) . . ?
O2 Sn3 Cl3 88.13(15) . 4_565 ?
O2 Sn3 Cl3 88.13(15) . . ?
O2 Sn3 O10 82.9(2) . 4_565 ?
O2 Sn3 O10 82.9(2) . . ?
O10 Sn3 Cl2 92.30(15) 4_565 . ?
O10 Sn3 Cl2 92.30(15) . . ?
O10 Sn3 Cl3 163.82(17) . 4_565 ?
O10 Sn3 Cl3 91.76(17) . . ?
O10 Sn3 Cl3 91.77(17) 4_565 4_565 ?
O10 Sn3 Cl3 163.81(17) 4_565 . ?
O10 Sn3 O10 73.8(3) . 4_565 ?
C16 Sn4 O5 92.6(3) . 4_565 ?
C16 Sn4 O5 92.6(3) . . ?
C16 Sn4 O6 92.3(3) . 4_565 ?
C16 Sn4 O6 92.3(3) . . ?
O5 Sn4 O5 88.9(3) 4_565 . ?
O5 Sn4 O6 175.2(2) . 4_565 ?
O5 Sn4 O6 91.0(3) . . ?
O5 Sn4 O6 91.0(3) 4_565 4_565 ?
O5 Sn4 O6 175.2(2) 4_565 . ?
O6 Sn4 O6 88.6(5) . 4_565 ?
O9 Sn4 C16 178.7(4) . . ?
O9 Sn4 O5 86.5(2) . 4_565 ?
O9 Sn4 O5 86.5(2) . . ?
O9 Sn4 O6 88.7(2) . . ?
O9 Sn4 O6 88.7(2) . 4_565 ?
C11 C12 C13 105.9(15) . . ?
C11 C12 C14 111.9(17) . . ?
C11 C12 C15 108.9(15) . . ?
C14 C12 C13 111.9(18) . . ?
C14 C12 C15 108.0(17) . . ?
C15 C12 C13 110.2(18) . . ?
C12 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
C12 C13 H13C 109.5 . . ?
H13A C13 H13B 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C12 C14 H14A 109.5 . . ?
C12 C14 H14B 109.5 . . ?
C12 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C12 C15 H15A 109.5 . . ?
C12 C15 H15B 109.5 . . ?
C12 C15 H15C 109.5 . . ?
H15A C15 H15B 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C18 C19 C21 98.8(18) . . ?
C18 C19 C22 99.9(18) . . ?
C20 C19 C18 118.9(17) . . ?
C20 C19 C21 117(2) . . ?
C20 C19 C22 122(2) . . ?
C21 C19 C22 95.2(16) . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C19 C21 H21A 109.5 . . ?
C19 C21 H21B 109.5 . . ?
C19 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C19 C22 H22A 109.5 . . ?
C19 C22 H22B 109.5 . . ?
C19 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C13A C12A C11 109.8(15) . . ?
C14A C12A C11 109.7(16) . . ?
C14A C12A C13A 109.4(17) . . ?
C14A C12A C15A 111.9(19) . . ?
C15A C12A C11 109.0(16) . . ?
C15A C12A C13A 107.0(17) . . ?
C12A C13A H13D 109.5 . . ?
C12A C13A H13E 109.5 . . ?
C12A C13A H13F 109.5 . . ?
H13D C13A H13E 109.5 . . ?
H13D C13A H13F 109.5 . . ?
H13E C13A H13F 109.5 . . ?
C12A C14A H14D 109.5 . . ?
C12A C14A H14E 109.5 . . ?
C12A C14A H14F 109.5 . . ?
H14D C14A H14E 109.5 . . ?
H14D C14A H14F 109.5 . . ?
H14E C14A H14F 109.5 . . ?
C12A C15A H15D 109.5 . . ?
C12A C15A H15E 109.5 . . ?
C12A C15A H15F 109.5 . . ?
H15D C15A H15E 109.5 . . ?
H15D C15A H15F 109.5 . . ?
H15E C15A H15F 109.5 . . ?
C18 C19A C21A 97.7(17) . . ?
C18 C19A C22A 101.3(18) . . ?
C20A C19A C18 116(2) . . ?
C20A C19A C21A 116(2) . . ?
C20A C19A C22A 124(2) . . ?
C21A C19A C22A 96.5(17) . . ?
C19A C20A H20D 109.5 . . ?
C19A C20A H20E 109.5 . . ?
C19A C20A H20F 109.5 . . ?
H20D C20A H20E 109.5 . . ?
H20D C20A H20F 109.5 . . ?
H20E C20A H20F 109.5 . . ?
C19A C21A H21D 109.5 . . ?
C19A C21A H21E 109.5 . . ?
C19A C21A H21F 109.5 . . ?
H21D C21A H21E 109.5 . . ?
H21D C21A H21F 109.5 . . ?
H21E C21A H21F 109.5 . . ?
C19A C22A H22D 109.5 . . ?
C19A C22A H22E 109.5 . . ?
C19A C22A H22F 109.5 . . ?
H22D C22A H22E 109.5 . . ?
H22D C22A H22F 109.5 . . ?
H22E C22A H22F 109.5 . . ?
C2 C4A H4AA 109.5 . . ?
C2 C4A H4AB 109.5 . . ?
C2 C4A H4AC 109.5 . . ?
H4AA C4A H4AB 109.5 . . ?
H4AA C4A H4AC 109.5 . . ?
H4AB C4A H4AC 109.5 . . ?
C2 C4 H4A 109.5 . . ?
C2 C4 H4B 109.5 . . ?
C2 C4 H4C 109.5 . . ?
H4A C4 H4B 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2 C1 O1 Sn2 180.000(1) . . . . ?
C2 C1 O2 Sn3 180.000(1) . . . . ?
C8 C7 O3 Sn1 -170.6(6) . . . . ?
O1 C1 C2 C3 0.000(2) . . . . ?
O1 C1 C2 C4A -157.3(17) . . . . ?
O1 C1 C2 C4 -97.9(16) . . . . ?
O1 C1 O2 Sn3 0.000(2) . . . . ?
O2 C1 C2 C3 180.000(1) . . . . ?
O2 C1 C2 C4A 22.7(17) . . . . ?
O2 C1 C2 C4 82.1(16) . . . . ?
O2 C1 O1 Sn2 0.000(2) . . . . ?
O3 C7 C8 C9 30.0(12) 4_565 . . . ?
O3 C7 C8 C9 -154.4(8) . . . . ?
O3 C7 C8 C9 154.4(8) 4_565 . . 4_565 ?
O3 C7 C8 C9 -30.0(12) . . . 4_565 ?
O3 C7 C8 C10 87.8(8) . . . . ?
O3 C7 C8 C10 -87.8(8) 4_565 . . . ?
O3 C7 O3 Sn1 4.7(15) 4_565 . . . ?
O4 C11 O5 Sn4 -15.9(12) . . . . ?
O4 C11 C12 C13 -10.5(19) . . . . ?
O4 C11 C12 C14 -132.7(16) . . . . ?
O4 C11 C12 C15 108.1(16) . . . . ?
O4 C11 C12A C13A -58.9(16) . . . . ?
O4 C11 C12A C14A -179.2(14) . . . . ?
O4 C11 C12A C15A 57.9(17) . . . . ?
O5 C11 O4 Sn1 -26.2(14) . . . . ?
O5 C11 C12 C13 173.6(13) . . . . ?
O5 C11 C12 C14 51.4(18) . . . . ?
O5 C11 C12 C15 -67.8(17) . . . . ?
O5 C11 C12A C13A 118.7(14) . . . . ?
O5 C11 C12A C14A -2(2) . . . . ?
O5 C11 C12A C15A -124.4(14) . . . . ?
O6 C18 O7 Sn1 -14(3) . . . . ?
O6 C18 C19 C20 87(2) . . . . ?
O6 C18 C19 C21 -41(2) . . . . ?
O6 C18 C19 C22 -138.1(19) . . . . ?
O6 C18 C19A C20A -60(2) . . . . ?
O6 C18 C19A C21A 64(2) . . . . ?
O6 C18 C19A C22A 162.6(16) . . . . ?
O7 C18 O6 Sn4 -18(3) . . . . ?
O7 C18 C19 C20 -68(2) . . . . ?
O7 C18 C19 C21 163.8(14) . . . . ?
O7 C18 C19 C22 66.9(18) . . . . ?
O7 C18 C19A C20A 102(2) . . . . ?
O7 C18 C19A C21A -133.2(19) . . . . ?
O7 C18 C19A C22A -35(2) . . . . ?
C12 C11 O4 Sn1 158.5(10) . . . . ?
C12 C11 O5 Sn4 159.9(9) . . . . ?
C19 C18 O6 Sn4 -168.2(12) . . . . ?
C19 C18 O7 Sn1 140.3(10) . . . . ?
C12A C11 O4 Sn1 151.4(10) . . . . ?
C12A C11 O5 Sn4 166.7(10) . . . . ?
C19A C18 O6 Sn4 143.7(13) . . . . ?
C19A C18 O7 Sn1 -174.5(13) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 2.410
_oxdiff_exptl_absorpt_empirical_full_min 0.631
