# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
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data_euag575
_database_code_depnum_ccdc_archive 'CCDC 2329147'
loop_
_audit_author_name
_audit_author_address
'Yuliya Bryleva'
;Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences
Russia
;
_audit_update_record             
;
2024-01-29 deposited with the CCDC.	2024-03-11 downloaded from the CCDC.
;
_audit_creation_date             2023-11-30
_audit_creation_method           
;
Olex2 1.5
(compiled 2023.03.06 svn.rbb2c1857 for OlexSys, GUI svn.r6748)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '2(C15 H12 Ag0.5 Eu0.5 N5 O7 P), 3(C2 H3 N)'
_chemical_formula_sum            'C36 H33 Ag Eu N13 O14 P2'
_chemical_formula_weight         1193.52
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           20
_space_group_name_H-M_alt        'C 2 2 21'
_space_group_name_Hall           'C 2c 2'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z+1/2'
'-x, y, -z+1/2'
'x, -y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   16.0607(4)
_cell_length_b                   28.9999(9)
_cell_length_c                   38.8996(9)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     18117.8(8)
_cell_formula_units_Z            16
_cell_measurement_reflns_used    9689
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.49
_cell_measurement_theta_min      2.51
_shelx_estimated_absorpt_T_max   0.909
_shelx_estimated_absorpt_T_min   0.772
_exptl_absorpt_coefficient_mu    1.954
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6725
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0934 before and 0.0671 after correction.
The Ratio of minimum to maximum transmission is 0.9020.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.750
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       plank
_exptl_crystal_F_000             9472
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.05
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0623
_diffrn_reflns_av_unetI/netI     0.0344
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       38
_diffrn_reflns_limit_k_min       -38
_diffrn_reflns_limit_l_max       51
_diffrn_reflns_limit_l_min       -51
_diffrn_reflns_number            172059
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.891
_diffrn_reflns_theta_min         1.404
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 7.41
_diffrn_detector_type            'Bruker PHOTON III area detector'
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 Venture diffractometer'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_reflns_Friedel_coverage         0.872
_reflns_Friedel_fraction_full    1.000
_reflns_Friedel_fraction_max     1.000
_reflns_number_gt                19512
_reflns_number_total             21623
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX3'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2014/7 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         2.412
_refine_diff_density_min         -1.011
_refine_diff_density_rms         0.101
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.207(12)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1277
_refine_ls_number_reflns         21623
_refine_ls_number_restraints     73
_refine_ls_R_factor_all          0.0448
_refine_ls_R_factor_gt           0.0384
_refine_ls_restrained_S_all      1.065
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0319P)²+72.4493P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0842
_refine_ls_wR_factor_ref         0.0882
_refine_special_details          'Refined as a 2-component inversion twin.,Twin'
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.793(12)
 0.207(12)
2. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
3. Restrained distances
 N11-O13
 1.24 with sigma of 0.02
 N4S-C41S
 1.14 with sigma of 0.01
 C42S-C41S
 1.42 with sigma of 0.01
 N11-O12
 1.2459 with sigma of 0.02
 N11-O11
 1.2459 with sigma of 0.02
 O11-O12
 2.1579 with sigma of 0.02
 O13-O11 = O13-O12
 2.16 with sigma of 0.04
 C42S-N4S
 2.56 with sigma of 0.01
 Eu1-O32 \\sim Eu1-O32'
 with sigma of 0.02
 Eu1-O31 \\sim Eu1-O31'
 with sigma of 0.02
 N31-O32 \\sim N31-O32'
 with sigma of 0.02
 N31-O31 \\sim N31-O31'
 with sigma of 0.02
 Eu2-O62' \\sim Eu2-O62
 with sigma of 0.02
 Eu2-O61' \\sim Eu2-O61
 with sigma of 0.02
 N61-O62' \\sim N61-O62
 with sigma of 0.02
 N61-O61' \\sim N61-O61
 with sigma of 0.02
 Eu2-O71 \\sim Eu2-O71'
 with sigma of 0.02
 Eu2-O72 \\sim Eu2-O72'
 with sigma of 0.02
 O71-N71 \\sim O71'-N71
 with sigma of 0.02
 O72-N71 \\sim O72'-N71
 with sigma of 0.02
4. Restrained planarity
 O81, N81', O83', O82
 with sigma of 0.1
5. Uiso/Uaniso restraints and constraints
Uanis(O21) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(O13') \\sim Ueq, Uanis(O13) \\sim Ueq: with sigma of 0.002 and sigma for
terminal atoms of 0.004
Uanis(C41S) = Uanis(C42S)
Uanis(O31') = Uanis(O32')
Uanis(O83) = Uanis(O83')
Uanis(N81) = Uanis(N81')
6. Rigid body (RIGU) restrains
 O71, N71, O73, O72
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 O71', N71, O73, O72'
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
7. Others
 Sof(O32')=Sof(O31')=1-FVAR(1)
 Sof(O32)=Sof(O31)=FVAR(1)
 Sof(O61)=Sof(O62)=1-FVAR(2)
 Sof(O62')=Sof(O61')=FVAR(2)
 Sof(O72')=Sof(O71')=1-FVAR(3)
 Sof(O71)=Sof(O72)=FVAR(3)
 Sof(O83')=Sof(N81')=1-FVAR(4)
 Sof(N81)=Sof(O83)=FVAR(4)
 Sof(O13)=1-FVAR(5)
 Sof(O13')=FVAR(5)
8.a Aromatic/amide H refined with riding coordinates:
 C4C(H4C), C2I(H2I), C3F(H3F), C4F(H4F), C2C(H2C), C3I(H3I), C3C(H3C),
 C5J(H5J), C4E(H4E), C2A(H2A), C2H(H2H), C2K(H2K), C3B(H3B), C4K(H4K), C4A(H4A),
  C5I(H5I), C2D(H2D), C4G(H4G), C5K(H5K), C2F(H2F), C2O(H2O), C2E(H2E),
 C4H(H4H), C3K(H3K), C3O(H3O), C5G(H5G), C3D(H3D), C5O(H5O), C4B(H4B), C4J(H4J),
  C2B(H2B), C4I(H4I), C5D(H5D), C5F(H5F), C4D(H4D), C5C(H5C), C5E(H5E),
 C3A(H3A), C2J(H2J), C3E(H3E), C2G(H2G), C3H(H3H), C4O(H4O), C5A(H5A), C5B(H5B),
  C5H(H5H), C3G(H3G), C3J(H3J)
8.b Idealised Me refined as rotating group:
 C22S(H22A,H22B,H22C), C12S(H12A,H12B,H12C), C32S(H32A,H32B,H32C), C52S(H52A,
 H52B,H52C), C42S(H42A,H42B,H42C), C62S(H62A,H62B,H62C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu2 Eu 0.25399(2) 0.49180(2) 0.71216(2) 0.01928(8) Uani 1 1 d D . . . .
Eu1 Eu 0.49009(2) 0.74951(2) 0.53876(2) 0.01871(8) Uani 1 1 d D . . . .
Ag2 Ag 0.48141(6) 0.5000 0.5000 0.0279(2) Uani 1 2 d S T P . .
Ag3 Ag 0.25674(5) 0.74152(2) 0.75453(2) 0.03132(13) Uani 1 1 d . . . . .
Ag1 Ag 0.50382(6) 1.0000 0.5000 0.0316(2) Uani 1 2 d S T P . .
P3 P 0.25943(13) 0.62007(5) 0.73654(4) 0.0197(3) Uani 1 1 d . . . . .
P1 P 0.49893(13) 0.87847(5) 0.51553(5) 0.0204(4) Uani 1 1 d . . . . .
P4 P 0.25346(13) 0.36277(5) 0.73473(4) 0.0199(3) Uani 1 1 d . . . . .
P2 P 0.48519(13) 0.62123(5) 0.51461(4) 0.0193(3) Uani 1 1 d . . . . .
N1O N 0.1490(4) 0.3016(2) 0.76624(19) 0.0271(15) Uani 1 1 d . . . . .
O1 O 0.4965(4) 0.82812(15) 0.52301(13) 0.0273(11) Uani 1 1 d . . . . .
O3 O 0.2578(4) 0.56973(13) 0.72876(12) 0.0252(10) Uani 1 1 d . . . . .
O42 O 0.3501(4) 0.7159(2) 0.55336(19) 0.0429(17) Uani 1 1 d . . . . .
N1B N 0.3998(4) 0.9414(2) 0.48363(19) 0.0280(15) Uani 1 1 d . . . . .
O2 O 0.4847(4) 0.67180(14) 0.52144(12) 0.0244(11) Uani 1 1 d . . . . .
N1I N 0.3559(4) 0.6800(2) 0.77061(19) 0.0301(16) Uani 1 1 d . . . . .
O82 O 0.1932(3) 0.4895(2) 0.77116(14) 0.0340(12) Uani 1 1 d . . . . .
O4 O 0.2550(4) 0.41345(13) 0.72871(11) 0.0237(9) Uani 1 1 d . . . . .
O11 O 0.4071(3) 0.7526(2) 0.48597(12) 0.0336(11) Uani 1 1 d D . . . .
O53 O 0.5086(4) 0.4899(3) 0.69082(18) 0.0458(16) Uani 1 1 d . . . . .
N1D N 0.5901(4) 0.5589(2) 0.48599(19) 0.0260(14) Uani 1 1 d . . . . .
O81 O 0.3297(3) 0.4885(2) 0.76748(14) 0.0332(12) Uani 1 1 d . . . . .
N31 N 0.5014(4) 0.7492(2) 0.61431(16) 0.0314(13) Uani 1 1 d D . . . .
O33 O 0.5066(4) 0.7484(2) 0.64495(16) 0.0578(19) Uani 1 1 d . . . . .
N61 N 0.2464(4) 0.49787(17) 0.63662(16) 0.0287(13) Uani 1 1 d D . . . .
N51 N 0.4342(4) 0.4895(3) 0.69631(17) 0.0299(14) Uani 1 1 d . . . . .
C4C C 0.5470(6) 0.9615(3) 0.6117(2) 0.044(2) Uani 1 1 d . . . . .
H4C H 0.5576 0.9802 0.6312 0.053 Uiso 1 1 calc R U . . .
O23 O 0.7466(4) 0.7429(2) 0.55468(15) 0.0469(15) Uani 1 1 d . . . . .
C1I C 0.3467(4) 0.6354(3) 0.7640(2) 0.0218(15) Uani 1 1 d . . . . .
O43 O 0.2341(4) 0.7539(3) 0.5591(2) 0.066(2) Uani 1 1 d . . . . .
O52 O 0.3925(4) 0.4535(2) 0.6989(2) 0.0452(18) Uani 1 1 d . . . . .
O71 O 0.1063(9) 0.5239(8) 0.7143(11) 0.033(6) Uani 0.51(7) 1 d D U P A 1
O12 O 0.5405(3) 0.7499(2) 0.47783(13) 0.0374(12) Uani 1 1 d D . . . .
C2I C 0.3990(5) 0.6011(3) 0.7758(2) 0.0256(16) Uani 1 1 d . . . . .
H2I H 0.3897 0.5697 0.7700 0.031 Uiso 1 1 calc R U . . .
N11 N 0.4665(4) 0.7531(3) 0.46553(16) 0.0404(16) Uani 1 1 d D . . . .
O21 O 0.6325(5) 0.7820(2) 0.5505(2) 0.063(2) Uani 1 1 d . U . . .
O63 O 0.2447(5) 0.50211(18) 0.60523(16) 0.0503(17) Uani 1 1 d . . . . .
C1O C 0.1612(5) 0.3465(3) 0.7590(2) 0.0233(16) Uani 1 1 d . . . . .
C3F C 0.5513(7) 0.5855(3) 0.6108(2) 0.045(2) Uani 1 1 d . . . . .
H3F H 0.5846 0.5979 0.6287 0.053 Uiso 1 1 calc R U . . .
C4F C 0.5113(7) 0.5437(3) 0.6147(2) 0.046(2) Uani 1 1 d . . . . .
H4F H 0.5144 0.5276 0.6359 0.055 Uiso 1 1 calc R U . . .
O62' O 0.2249(16) 0.4618(5) 0.6527(4) 0.037(5) Uani 0.44(3) 1 d D . P A 2
O73 O -0.0049(4) 0.4891(3) 0.6987(2) 0.060(2) Uani 1 1 d . U . . .
N21 N 0.6727(3) 0.7452(3) 0.54913(16) 0.0299(14) Uani 1 1 d . . . . .
O72 O 0.1158(9) 0.4546(5) 0.6960(10) 0.024(4) Uani 0.51(7) 1 d D U P A 1
C1B C 0.4059(5) 0.8969(3) 0.4931(2) 0.0234(16) Uani 1 1 d . . . . .
C2C C 0.5525(5) 0.8900(3) 0.5823(2) 0.0312(17) Uani 1 1 d . . . . .
H2C H 0.5667 0.8582 0.5814 0.037 Uiso 1 1 calc R U . . .
C1D C 0.5748(5) 0.6047(3) 0.4888(2) 0.0239(16) Uani 1 1 d . . . . .
N81 N 0.2620(8) 0.4807(4) 0.7852(2) 0.033(2) Uani 0.85(2) 1 d . . P B 1
C3I C 0.4656(5) 0.6140(3) 0.7964(2) 0.034(2) Uani 1 1 d . . . . .
H3I H 0.5041 0.5917 0.8045 0.041 Uiso 1 1 calc R U . . .
N1F N 0.4572(5) 0.5483(2) 0.55689(19) 0.0410(18) Uani 1 1 d . . . . .
C3C C 0.5688(6) 0.9158(3) 0.6117(2) 0.039(2) Uani 1 1 d . . . . .
H3C H 0.5943 0.9021 0.6313 0.047 Uiso 1 1 calc R U . . .
C5J C 0.2329(8) 0.2685(3) 0.6613(2) 0.060(3) Uani 1 1 d . . . . .
H5J H 0.2153 0.2373 0.6593 0.073 Uiso 1 1 calc R U . . .
C4E C 0.2653(5) 0.5804(3) 0.4491(2) 0.0325(18) Uani 1 1 d . . . . .
H4E H 0.2205 0.5710 0.4348 0.039 Uiso 1 1 calc R U . . .
C2A C 0.6322(5) 0.8576(3) 0.4733(2) 0.0290(17) Uani 1 1 d . . . . .
H2A H 0.6177 0.8261 0.4767 0.035 Uiso 1 1 calc R U . . .
C2H C 0.1122(5) 0.6017(3) 0.7698(2) 0.0267(16) Uani 1 1 d . . . . .
H2H H 0.1216 0.5707 0.7629 0.032 Uiso 1 1 calc R U . . .
C2K C 0.3959(5) 0.3774(3) 0.7734(2) 0.0242(15) Uani 1 1 d . . . . .
H2K H 0.3864 0.4094 0.7699 0.029 Uiso 1 1 calc R U . . .
C3B C 0.2791(5) 0.8770(3) 0.4647(2) 0.0328(18) Uani 1 1 d . . . . .
H3B H 0.2373 0.8554 0.4584 0.039 Uiso 1 1 calc R U . . .
O61' O 0.2791(13) 0.5290(4) 0.6544(3) 0.033(5) Uani 0.44(3) 1 d D . P A 2
C4K C 0.4731(5) 0.3147(3) 0.7977(2) 0.0303(18) Uani 1 1 d . . . . .
H4K H 0.5177 0.3031 0.8112 0.036 Uiso 1 1 calc R U . . .
C4A C 0.7183(6) 0.9153(3) 0.4490(3) 0.042(2) Uani 1 1 d . . . . .
H4A H 0.7651 0.9246 0.4358 0.050 Uiso 1 1 calc R U . . .
C1G C 0.2718(4) 0.6534(2) 0.69761(17) 0.0244(15) Uani 1 1 d . . . . .
N71 N 0.0704(4) 0.4902(3) 0.70224(18) 0.0332(14) Uani 1 1 d D U . . .
C31S C 0.2154(9) 0.6574(4) 0.8713(4) 0.071(3) Uani 1 1 d . . . . .
N1J N 0.2259(5) 0.2896(2) 0.69173(18) 0.0430(19) Uani 1 1 d . . . . .
C1E C 0.3950(4) 0.6048(3) 0.4900(2) 0.0198(14) Uani 1 1 d . . . . .
C61S C 0.2021(6) 0.3554(4) 0.8566(3) 0.053(3) Uani 1 1 d . . . . .
O32 O 0.5156(16) 0.7141(4) 0.5962(2) 0.041(4) Uani 0.66(5) 1 d D . P C 1
C5I C 0.4197(5) 0.6919(3) 0.7918(3) 0.035(2) Uani 1 1 d . . . . .
H5I H 0.4263 0.7234 0.7979 0.042 Uiso 1 1 calc R U . . .
C2D C 0.6238(5) 0.6389(3) 0.4743(2) 0.0268(16) Uani 1 1 d . . . . .
H2D H 0.6106 0.6706 0.4773 0.032 Uiso 1 1 calc R U . . .
C1H C 0.1665(5) 0.6361(2) 0.7600(2) 0.0220(15) Uani 1 1 d . . . . .
C4G C 0.3002(6) 0.7052(3) 0.6412(2) 0.046(2) Uani 1 1 d . . . . .
H4G H 0.3082 0.7242 0.6216 0.055 Uiso 1 1 calc R U . . .
C5K C 0.4159(5) 0.2852(3) 0.7827(2) 0.0295(18) Uani 1 1 d . . . . .
H5K H 0.4233 0.2530 0.7861 0.035 Uiso 1 1 calc R U . . .
C2F C 0.5413(5) 0.6091(3) 0.5797(2) 0.0329(18) Uani 1 1 d . . . . .
H2F H 0.5666 0.6383 0.5763 0.039 Uiso 1 1 calc R U . . .
N1C N 0.4926(6) 0.9558(2) 0.55457(18) 0.0437(19) Uani 1 1 d . . . . .
N1G N 0.2494(6) 0.69808(18) 0.69837(15) 0.0383(16) Uani 1 1 d . . . . .
N6S N 0.2576(6) 0.3388(3) 0.8422(2) 0.061(2) Uani 1 1 d . . . . .
C2O C 0.1098(5) 0.3814(3) 0.7705(2) 0.0298(18) Uani 1 1 d . . . . .
H2O H 0.1212 0.4127 0.7651 0.036 Uiso 1 1 calc R U . . .
C2E C 0.3387(5) 0.6384(3) 0.4801(2) 0.0285(17) Uani 1 1 d . . . . .
H2E H 0.3446 0.6694 0.4878 0.034 Uiso 1 1 calc R U . . .
N41 N 0.3095(4) 0.7529(3) 0.55459(16) 0.0353(14) Uani 1 1 d . . . . .
O31 O 0.4769(17) 0.7847(3) 0.5974(2) 0.041(6) Uani 0.66(5) 1 d D . P C 1
N1K N 0.3520(4) 0.2988(2) 0.76410(19) 0.0278(15) Uani 1 1 d . . . . .
C4H C 0.0309(5) 0.6582(3) 0.7980(2) 0.035(2) Uani 1 1 d . . . . .
H4H H -0.0161 0.6671 0.8113 0.042 Uiso 1 1 calc R U . . .
C1K C 0.3428(4) 0.3448(2) 0.7595(2) 0.0203(15) Uani 1 1 d . . . . .
N1H N 0.1552(4) 0.6810(2) 0.7683(2) 0.0293(16) Uani 1 1 d . . . . .
C3K C 0.4636(5) 0.3619(3) 0.7925(2) 0.0292(17) Uani 1 1 d . . . . .
H3K H 0.5026 0.3831 0.8018 0.035 Uiso 1 1 calc R U . . .
C3O C 0.0410(5) 0.3696(3) 0.7902(3) 0.036(2) Uani 1 1 d . . . . .
H3O H 0.0042 0.3927 0.7985 0.043 Uiso 1 1 calc R U . . .
C5G C 0.2629(8) 0.7228(3) 0.6698(2) 0.052(3) Uani 1 1 d . . . . .
H5G H 0.2457 0.7541 0.6695 0.062 Uiso 1 1 calc R U . . .
C3D C 0.6925(5) 0.6254(3) 0.4552(2) 0.036(2) Uani 1 1 d . . . . .
H3D H 0.7278 0.6477 0.4448 0.043 Uiso 1 1 calc R U . . .
C5O C 0.0817(5) 0.2911(3) 0.7849(3) 0.036(2) Uani 1 1 d . . . . .
H5O H 0.0710 0.2596 0.7898 0.044 Uiso 1 1 calc R U . . .
C4B C 0.2732(5) 0.9224(3) 0.4549(2) 0.0348(19) Uani 1 1 d . . . . .
H4B H 0.2275 0.9325 0.4413 0.042 Uiso 1 1 calc R U . . .
C4J C 0.2650(9) 0.2904(3) 0.6326(2) 0.067(3) Uani 1 1 d . . . . .
H4J H 0.2625 0.2756 0.6109 0.081 Uiso 1 1 calc R U . . .
C1A C 0.5866(5) 0.8924(3) 0.4884(2) 0.0215(15) Uani 1 1 d . . . . .
C2B C 0.3479(5) 0.8635(3) 0.4841(2) 0.0276(17) Uani 1 1 d . . . . .
H2B H 0.3548 0.8323 0.4910 0.033 Uiso 1 1 calc R U . . .
C4I C 0.4748(5) 0.6603(3) 0.8049(2) 0.035(2) Uani 1 1 d . . . . .
H4I H 0.5187 0.6699 0.8196 0.042 Uiso 1 1 calc R U . . .
C5D C 0.6562(5) 0.5467(3) 0.4670(2) 0.0334(19) Uani 1 1 d . . . . .
H5D H 0.6678 0.5148 0.4639 0.040 Uiso 1 1 calc R U . . .
C22S C 0.4133(8) 0.2894(5) 0.8930(3) 0.077(4) Uani 1 1 d . . . . .
H22A H 0.3960 0.2813 0.9164 0.115 Uiso 1 1 calc R U . . .
H22B H 0.3682 0.3062 0.8815 0.115 Uiso 1 1 calc R U . . .
H22C H 0.4631 0.3089 0.8940 0.115 Uiso 1 1 calc R U . . .
C1F C 0.4944(5) 0.5893(2) 0.55441(17) 0.0223(14) Uani 1 1 d . . . . .
N1A N 0.6032(4) 0.9376(2) 0.48385(19) 0.0269(15) Uani 1 1 d . . . . .
C5F C 0.4662(6) 0.5253(3) 0.5872(2) 0.049(3) Uani 1 1 d . . . . .
H5F H 0.4410 0.4959 0.5897 0.058 Uiso 1 1 calc R U . . .
C12S C 0.3979(6) 0.4267(4) 0.8684(3) 0.056(3) Uani 1 1 d . . . . .
H12A H 0.3693 0.4498 0.8824 0.083 Uiso 1 1 calc R U . . .
H12B H 0.3611 0.4002 0.8648 0.083 Uiso 1 1 calc R U . . .
H12C H 0.4128 0.4402 0.8461 0.083 Uiso 1 1 calc R U . . .
N1E N 0.3884(4) 0.5598(2) 0.48035(19) 0.0239(14) Uani 1 1 d . . . . .
C4D C 0.7084(6) 0.5788(3) 0.4516(2) 0.037(2) Uani 1 1 d . . . . .
H4D H 0.7551 0.5687 0.4386 0.044 Uiso 1 1 calc R U . . .
C5C C 0.5095(8) 0.9798(3) 0.5827(2) 0.053(3) Uani 1 1 d . . . . .
H5C H 0.4950 1.0116 0.5830 0.064 Uiso 1 1 calc R U . . .
C5E C 0.3242(5) 0.5485(3) 0.4607(3) 0.0298(17) Uani 1 1 d . . . . .
H5E H 0.3178 0.5171 0.4542 0.036 Uiso 1 1 calc R U . . .
C1J C 0.2574(6) 0.3327(2) 0.69369(17) 0.0279(15) Uani 1 1 d . . . . .
C3A C 0.7004(6) 0.8696(3) 0.4530(3) 0.040(2) Uani 1 1 d . . . . .
H3A H 0.7335 0.8466 0.4422 0.048 Uiso 1 1 calc R U . . .
C2J C 0.2953(5) 0.3555(3) 0.6666(2) 0.0351(18) Uani 1 1 d . . . . .
H2J H 0.3173 0.3856 0.6696 0.042 Uiso 1 1 calc R U . . .
O22 O 0.6295(4) 0.7107(2) 0.5424(2) 0.060(2) Uani 1 1 d . . . . .
N5S N 0.2187(11) 0.4930(5) 0.8944(3) 0.135(7) Uani 1 1 d . . . . .
C1C C 0.5156(5) 0.9111(2) 0.55483(19) 0.0266(16) Uani 1 1 d . . . . .
O41 O 0.3508(4) 0.7890(2) 0.5509(2) 0.060(2) Uani 1 1 d . . . . .
N3S N 0.2712(8) 0.6441(4) 0.8571(4) 0.103(4) Uani 1 1 d . . . . .
C3E C 0.2738(5) 0.6258(3) 0.4588(2) 0.0302(16) Uani 1 1 d . . . . .
H3E H 0.2352 0.6483 0.4509 0.036 Uiso 1 1 calc R U . . .
C2G C 0.3094(5) 0.6338(3) 0.6700(2) 0.0357(18) Uani 1 1 d . . . . .
H2G H 0.3246 0.6021 0.6705 0.043 Uiso 1 1 calc R U . . .
C3H C 0.0440(5) 0.6128(3) 0.7897(2) 0.0328(18) Uani 1 1 d . . . . .
H3H H 0.0068 0.5896 0.7974 0.039 Uiso 1 1 calc R U . . .
C4O C 0.0270(6) 0.3238(3) 0.7974(3) 0.038(2) Uani 1 1 d . . . . .
H4O H -0.0196 0.3148 0.8109 0.045 Uiso 1 1 calc R U . . .
N1S N 0.5295(8) 0.4002(4) 0.8995(3) 0.092(4) Uani 1 1 d . . . . .
O51 O 0.3926(4) 0.5260(2) 0.6993(3) 0.070(3) Uani 1 1 d . . . . .
C32S C 0.1431(8) 0.6746(5) 0.8880(3) 0.084(4) Uani 1 1 d . . . . .
H32A H 0.1595 0.6916 0.9087 0.126 Uiso 1 1 calc R U . . .
H32B H 0.1069 0.6488 0.8945 0.126 Uiso 1 1 calc R U . . .
H32C H 0.1130 0.6952 0.8724 0.126 Uiso 1 1 calc R U . . .
C21S C 0.4312(9) 0.2493(7) 0.8746(3) 0.112(6) Uani 1 1 d . . . . .
C5A C 0.6681(5) 0.9477(3) 0.4643(3) 0.037(2) Uani 1 1 d . . . . .
H5A H 0.6808 0.9793 0.4606 0.045 Uiso 1 1 calc R U . . .
N4S N -0.0016(9) 0.5941(4) 0.5984(4) 0.119(5) Uani 1 1 d D . . . .
C5B C 0.3343(5) 0.9535(3) 0.4648(3) 0.0344(19) Uani 1 1 d . . . . .
H5B H 0.3291 0.9848 0.4579 0.041 Uiso 1 1 calc R U . . .
C5H C 0.0880(5) 0.6908(3) 0.7866(3) 0.0325(18) Uani 1 1 d . . . . .
H5H H 0.0782 0.7221 0.7924 0.039 Uiso 1 1 calc R U . . .
C3G C 0.3257(6) 0.6606(4) 0.6407(2) 0.045(2) Uani 1 1 d . . . . .
H3G H 0.3536 0.6481 0.6213 0.054 Uiso 1 1 calc R U . . .
C52S C 0.1513(9) 0.5422(4) 0.8480(3) 0.074(4) Uani 1 1 d . . . . .
H52A H 0.1128 0.5642 0.8587 0.112 Uiso 1 1 calc R U . . .
H52B H 0.1208 0.5226 0.8318 0.112 Uiso 1 1 calc R U . . .
H52C H 0.1949 0.5591 0.8356 0.112 Uiso 1 1 calc R U . . .
C11S C 0.4711(8) 0.4121(4) 0.8855(3) 0.060(3) Uani 1 1 d . . . . .
C51S C 0.1889(10) 0.5139(4) 0.8743(3) 0.085(5) Uani 1 1 d . . . . .
N2S N 0.4436(12) 0.2184(8) 0.8597(4) 0.208(12) Uani 1 1 d . . . . .
C3J C 0.3004(7) 0.3335(3) 0.6354(2) 0.049(3) Uani 1 1 d . . . . .
H3J H 0.3274 0.3476 0.6163 0.059 Uiso 1 1 calc R U . . .
C41S C 0.0551(8) 0.5970(7) 0.6184(5) 0.128(5) Uani 1 1 d D . . . .
C42S C 0.1255(7) 0.6137(6) 0.6343(5) 0.128(5) Uani 1 1 d D . . . .
H42A H 0.1099 0.6292 0.6557 0.192 Uiso 1 1 calc R U . . .
H42B H 0.1533 0.6358 0.6190 0.192 Uiso 1 1 calc R U . . .
H42C H 0.1634 0.5882 0.6393 0.192 Uiso 1 1 calc R U . . .
C62S C 0.1350(9) 0.3764(6) 0.8749(4) 0.118(7) Uani 1 1 d . . . . .
H62A H 0.1463 0.3750 0.8996 0.178 Uiso 1 1 calc R U . . .
H62B H 0.0832 0.3598 0.8699 0.178 Uiso 1 1 calc R U . . .
H62C H 0.1295 0.4086 0.8678 0.178 Uiso 1 1 calc R U . . .
O32' O 0.474(2) 0.7136(7) 0.5974(4) 0.029(7) Uani 0.34(5) 1 d D . P C 2
O31' O 0.527(2) 0.7819(7) 0.5965(4) 0.029(7) Uani 0.34(5) 1 d D . P C 2
O61 O 0.2194(11) 0.5305(3) 0.6569(3) 0.035(4) Uani 0.56(3) 1 d D . P A 1
O62 O 0.2700(13) 0.4622(4) 0.6513(3) 0.034(4) Uani 0.56(3) 1 d D . P A 1
O72' O 0.1092(10) 0.4559(7) 0.7095(11) 0.031(5) Uani 0.49(7) 1 d D U P A 2
O71' O 0.1159(11) 0.5286(4) 0.6974(12) 0.030(6) Uani 0.49(7) 1 d D U P A 2
O83 O 0.2658(8) 0.4676(5) 0.81503(19) 0.079(4) Uani 0.85(2) 1 d . . P B 1
O13 O 0.4456(9) 0.7466(8) 0.4342(3) 0.050(5) Uani 0.52(4) 1 d D U P D 1
O83' O 0.289(4) 0.502(3) 0.8184(12) 0.079(4) Uani 0.15(2) 1 d . . P B 2
N81' N 0.275(5) 0.4960(14) 0.7901(17) 0.033(2) Uani 0.15(2) 1 d . . P B 2
O13' O 0.4689(14) 0.7713(10) 0.4357(5) 0.073(7) Uani 0.48(4) 1 d . U P D 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu2 O3 2.351(4) . ?
Eu2 O82 2.495(5) . ?
Eu2 O4 2.361(4) . ?
Eu2 O81 2.474(5) . ?
Eu2 O52 2.539(6) . ?
Eu2 O71 2.549(11) . ?
Eu2 O62' 2.514(13) . ?
Eu2 O72 2.546(13) . ?
Eu2 O61' 2.525(12) . ?
Eu2 O51 2.488(7) . ?
Eu2 O61 2.488(10) . ?
Eu2 O62 2.533(10) . ?
Eu2 O72' 2.549(14) . ?
Eu2 O71' 2.527(12) . ?
Eu1 O1 2.363(4) . ?
Eu1 O42 2.516(6) . ?
Eu1 O2 2.354(4) . ?
Eu1 O11 2.450(5) . ?
Eu1 O12 2.504(5) . ?
Eu1 O21 2.516(7) . ?
Eu1 O32 2.492(9) . ?
Eu1 O31 2.507(9) . ?
Eu1 O22 2.510(6) . ?
Eu1 O41 2.557(7) . ?
Eu1 O32' 2.520(16) . ?
Eu1 O31' 2.505(15) . ?
Ag2 N1D 2.503(7) . ?
Ag2 N1D 2.503(7) 4_566 ?
Ag2 N1F 2.647(8) . ?
Ag2 N1F 2.647(8) 4_566 ?
Ag2 N1E 2.412(6) . ?
Ag2 N1E 2.413(6) 4_566 ?
Ag3 N1O 2.445(7) 7_556 ?
Ag3 N1I 2.473(7) . ?
Ag3 N1J 2.529(7) 7_556 ?
Ag3 N1G 2.525(6) . ?
Ag3 N1K 2.518(7) 7_556 ?
Ag3 N1H 2.455(7) . ?
Ag1 N1B 2.468(7) . ?
Ag1 N1B 2.468(7) 4_576 ?
Ag1 N1C 2.487(7) 4_576 ?
Ag1 N1C 2.487(7) . ?
Ag1 N1A 2.494(7) . ?
Ag1 N1A 2.494(7) 4_576 ?
P3 O3 1.491(4) . ?
P3 C1I 1.817(8) . ?
P3 C1G 1.808(7) . ?
P3 C1H 1.810(8) . ?
P1 O1 1.489(4) . ?
P1 C1B 1.811(8) . ?
P1 C1A 1.805(8) . ?
P1 C1C 1.818(7) . ?
P4 O4 1.488(4) . ?
P4 C1O 1.819(8) . ?
P4 C1K 1.805(8) . ?
P4 C1J 1.820(7) . ?
P2 O2 1.490(4) . ?
P2 C1D 1.818(8) . ?
P2 C1E 1.801(8) . ?
P2 C1F 1.810(7) . ?
N1O Ag3 2.445(7) 7_546 ?
N1O C1O 1.346(9) . ?
N1O C5O 1.337(11) . ?
O42 N41 1.257(10) . ?
N1B C1B 1.345(10) . ?
N1B C5B 1.329(11) . ?
N1I C1I 1.325(10) . ?
N1I C5I 1.360(11) . ?
O82 N81 1.257(12) . ?
O82 N81' 1.51(8) . ?
O11 N11 1.242(8) . ?
O53 N51 1.215(8) . ?
N1D C1D 1.354(10) . ?
N1D C5D 1.341(11) . ?
O81 N81 1.307(13) . ?
O81 N81' 1.27(8) . ?
N31 O33 1.195(9) . ?
N31 O32 1.259(10) . ?
N31 O31 1.285(12) . ?
N31 O32' 1.303(17) . ?
N31 O31' 1.244(15) . ?
N61 O63 1.227(9) . ?
N61 O62' 1.266(14) . ?
N61 O61' 1.253(13) . ?
N61 O61 1.305(11) . ?
N61 O62 1.242(11) . ?
N51 O52 1.246(10) . ?
N51 O51 1.258(10) . ?
C4C H4C 0.9500 . ?
C4C C3C 1.370(12) . ?
C4C C5C 1.386(13) . ?
O23 N21 1.209(8) . ?
C1I C2I 1.381(11) . ?
O43 N41 1.223(8) . ?
O71 N71 1.229(14) . ?
O12 N11 1.284(8) . ?
C2I H2I 0.9500 . ?
C2I C3I 1.387(11) . ?
N11 O13 1.279(13) . ?
N11 O13' 1.27(2) . ?
O21 N21 1.248(9) . ?
C1O C2O 1.383(11) . ?
C3F H3F 0.9500 . ?
C3F C4F 1.379(13) . ?
C3F C2F 1.398(11) . ?
C4F H4F 0.9500 . ?
C4F C5F 1.399(13) . ?
O73 N71 1.217(9) . ?
N21 O22 1.245(9) . ?
O72 N71 1.286(15) . ?
C1B C2B 1.389(11) . ?
C2C H2C 0.9500 . ?
C2C C3C 1.392(12) . ?
C2C C1C 1.368(10) . ?
C1D C2D 1.388(11) . ?
N81 O83 1.223(11) . ?
C3I H3I 0.9500 . ?
C3I C4I 1.390(12) . ?
N1F C1F 1.335(9) . ?
N1F C5F 1.360(10) . ?
C3C H3C 0.9500 . ?
C5J H5J 0.9500 . ?
C5J N1J 1.339(10) . ?
C5J C4J 1.382(14) . ?
C4E H4E 0.9500 . ?
C4E C5E 1.397(11) . ?
C4E C3E 1.377(11) . ?
C2A H2A 0.9500 . ?
C2A C1A 1.378(11) . ?
C2A C3A 1.396(12) . ?
C2H H2H 0.9500 . ?
C2H C1H 1.378(11) . ?
C2H C3H 1.380(11) . ?
C2K H2K 0.9500 . ?
C2K C1K 1.382(10) . ?
C2K C3K 1.393(11) . ?
C3B H3B 0.9500 . ?
C3B C4B 1.373(11) . ?
C3B C2B 1.395(11) . ?
C4K H4K 0.9500 . ?
C4K C5K 1.385(11) . ?
C4K C3K 1.391(11) . ?
C4A H4A 0.9500 . ?
C4A C3A 1.365(13) . ?
C4A C5A 1.372(13) . ?
C1G N1G 1.344(8) . ?
C1G C2G 1.358(10) . ?
N71 O72' 1.208(16) . ?
N71 O71' 1.345(18) . ?
C31S N3S 1.120(17) . ?
C31S C32S 1.422(17) . ?
N1J Ag3 2.529(7) 7_546 ?
N1J C1J 1.350(9) . ?
C1E C2E 1.383(11) . ?
C1E N1E 1.363(9) . ?
C61S N6S 1.156(13) . ?
C61S C62S 1.428(15) . ?
C5I H5I 0.9500 . ?
C5I C4I 1.372(12) . ?
C2D H2D 0.9500 . ?
C2D C3D 1.386(12) . ?
C1H N1H 1.355(9) . ?
C4G H4G 0.9500 . ?
C4G C5G 1.362(13) . ?
C4G C3G 1.357(13) . ?
C5K H5K 0.9500 . ?
C5K N1K 1.318(10) . ?
C2F H2F 0.9500 . ?
C2F C1F 1.366(11) . ?
N1C C5C 1.326(11) . ?
N1C C1C 1.346(9) . ?
N1G C5G 1.339(9) . ?
C2O H2O 0.9500 . ?
C2O C3O 1.387(11) . ?
C2E H2E 0.9500 . ?
C2E C3E 1.382(11) . ?
N41 O41 1.248(10) . ?
N1K Ag3 2.518(7) 7_546 ?
N1K C1K 1.353(9) . ?
C4H H4H 0.9500 . ?
C4H C3H 1.371(12) . ?
C4H C5H 1.389(12) . ?
N1H C5H 1.324(10) . ?
C3K H3K 0.9500 . ?
C3O H3O 0.9500 . ?
C3O C4O 1.375(12) . ?
C5G H5G 0.9500 . ?
C3D H3D 0.9500 . ?
C3D C4D 1.384(12) . ?
C5O H5O 0.9500 . ?
C5O C4O 1.382(12) . ?
C4B H4B 0.9500 . ?
C4B C5B 1.388(12) . ?
C4J H4J 0.9500 . ?
C4J C3J 1.378(14) . ?
C1A N1A 1.350(9) . ?
C2B H2B 0.9500 . ?
C4I H4I 0.9500 . ?
C5D H5D 0.9500 . ?
C5D C4D 1.389(12) . ?
C22S H22A 0.9800 . ?
C22S H22B 0.9800 . ?
C22S H22C 0.9800 . ?
C22S C21S 1.397(19) . ?
N1A C5A 1.325(11) . ?
C5F H5F 0.9500 . ?
C12S H12A 0.9800 . ?
C12S H12B 0.9800 . ?
C12S H12C 0.9800 . ?
C12S C11S 1.416(16) . ?
N1E C5E 1.325(10) . ?
C4D H4D 0.9500 . ?
C5C H5C 0.9500 . ?
C5E H5E 0.9500 . ?
C1J C2J 1.383(10) . ?
C3A H3A 0.9500 . ?
C2J H2J 0.9500 . ?
C2J C3J 1.376(11) . ?
N5S C51S 1.100(15) . ?
C3E H3E 0.9500 . ?
C2G H2G 0.9500 . ?
C2G C3G 1.405(12) . ?
C3H H3H 0.9500 . ?
C4O H4O 0.9500 . ?
N1S C11S 1.138(16) . ?
C32S H32A 0.9800 . ?
C32S H32B 0.9800 . ?
C32S H32C 0.9800 . ?
C21S N2S 1.09(2) . ?
C5A H5A 0.9500 . ?
N4S C41S 1.200(11) . ?
C5B H5B 0.9500 . ?
C5H H5H 0.9500 . ?
C3G H3G 0.9500 . ?
C52S H52A 0.9800 . ?
C52S H52B 0.9800 . ?
C52S H52C 0.9800 . ?
C52S C51S 1.443(14) . ?
C3J H3J 0.9500 . ?
C41S C42S 1.377(10) . ?
C42S H42A 0.9800 . ?
C42S H42B 0.9800 . ?
C42S H42C 0.9800 . ?
C62S H62A 0.9800 . ?
C62S H62B 0.9800 . ?
C62S H62C 0.9800 . ?
O83' N81' 1.14(8) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Eu2 O82 77.45(18) . . ?
O3 Eu2 O4 148.18(16) . . ?
O3 Eu2 O81 77.59(19) . . ?
O3 Eu2 O52 117.0(2) . . ?
O3 Eu2 O71 70.4(4) . . ?
O3 Eu2 O62' 126.1(4) . . ?
O3 Eu2 O72 119.8(3) . . ?
O3 Eu2 O61' 80.2(3) . . ?
O3 Eu2 O51 69.4(2) . . ?
O3 Eu2 O61 79.0(2) . . ?
O3 Eu2 O62 125.5(3) . . ?
O3 Eu2 O72' 115.3(7) . . ?
O3 Eu2 O71' 71.3(5) . . ?
O82 Eu2 O52 121.2(2) . . ?
O82 Eu2 O71 67.4(11) . . ?
O82 Eu2 O62' 139.8(5) . . ?
O82 Eu2 O72 82.8(9) . . ?
O82 Eu2 O61' 153.2(4) . . ?
O82 Eu2 O62 153.0(5) . . ?
O82 Eu2 O72' 70.7(10) . . ?
O82 Eu2 O71' 82.9(11) . . ?
O4 Eu2 O82 74.13(18) . . ?
O4 Eu2 O81 73.89(19) . . ?
O4 Eu2 O52 68.2(2) . . ?
O4 Eu2 O71 110.4(8) . . ?
O4 Eu2 O62' 85.4(3) . . ?
O4 Eu2 O72 70.5(5) . . ?
O4 Eu2 O61' 130.7(3) . . ?
O4 Eu2 O51 115.6(2) . . ?
O4 Eu2 O61 132.1(3) . . ?
O4 Eu2 O62 85.9(3) . . ?
O4 Eu2 O72' 67.9(3) . . ?
O4 Eu2 O71' 118.3(4) . . ?
O81 Eu2 O82 52.47(18) . . ?
O81 Eu2 O52 74.3(2) . . ?
O81 Eu2 O71 116.3(9) . . ?
O81 Eu2 O62' 151.4(5) . . ?
O81 Eu2 O72 128.8(9) . . ?
O81 Eu2 O61' 135.4(4) . . ?
O81 Eu2 O51 75.5(3) . . ?
O81 Eu2 O61 151.5(4) . . ?
O81 Eu2 O62 138.7(4) . . ?
O81 Eu2 O72' 117.9(8) . . ?
O81 Eu2 O71' 130.1(11) . . ?
O52 Eu2 O71 169.0(6) . . ?
O52 Eu2 O72 121.9(4) . . ?
O52 Eu2 O72' 127.7(7) . . ?
O62' Eu2 O52 79.9(6) . . ?
O62' Eu2 O61' 50.1(4) . . ?
O62' Eu2 O72' 69.7(12) . . ?
O62' Eu2 O71' 77.0(12) . . ?
O72 Eu2 O71 49.6(4) . . ?
O61' Eu2 O52 82.4(5) . . ?
O61' Eu2 O72' 106.5(9) . . ?
O61' Eu2 O71' 76.0(11) . . ?
O51 Eu2 O82 123.0(3) . . ?
O51 Eu2 O52 49.48(18) . . ?
O51 Eu2 O71 133.9(8) . . ?
O51 Eu2 O62' 96.9(6) . . ?
O51 Eu2 O72 154.1(9) . . ?
O51 Eu2 O61' 60.5(5) . . ?
O51 Eu2 O61 81.1(5) . . ?
O51 Eu2 O62 81.8(5) . . ?
O51 Eu2 O72' 166.1(10) . . ?
O51 Eu2 O71' 124.8(6) . . ?
O61 Eu2 O82 136.0(4) . . ?
O61 Eu2 O52 102.6(4) . . ?
O61 Eu2 O71 69.9(12) . . ?
O61 Eu2 O72 77.5(9) . . ?
O61 Eu2 O62 50.8(3) . . ?
O62 Eu2 O52 64.7(4) . . ?
O62 Eu2 O71 104.4(9) . . ?
O62 Eu2 O72 73.4(9) . . ?
O71' Eu2 O52 155.2(11) . . ?
O71' Eu2 O72' 50.4(4) . . ?
O1 Eu1 O42 118.1(2) . . ?
O1 Eu1 O11 76.7(2) . . ?
O1 Eu1 O12 74.7(2) . . ?
O1 Eu1 O21 69.3(2) . . ?
O1 Eu1 O32 128.5(3) . . ?
O1 Eu1 O31 81.2(2) . . ?
O1 Eu1 O22 114.1(2) . . ?
O1 Eu1 O41 69.8(2) . . ?
O1 Eu1 O32' 129.6(5) . . ?
O1 Eu1 O31' 82.0(4) . . ?
O42 Eu1 O41 49.46(17) . . ?
O42 Eu1 O32' 62.7(8) . . ?
O2 Eu1 O1 148.34(16) . . ?
O2 Eu1 O42 70.1(2) . . ?
O2 Eu1 O11 77.02(19) . . ?
O2 Eu1 O12 75.2(2) . . ?
O2 Eu1 O21 116.4(2) . . ?
O2 Eu1 O32 82.4(3) . . ?
O2 Eu1 O31 130.3(3) . . ?
O2 Eu1 O22 67.6(2) . . ?
O2 Eu1 O41 116.7(2) . . ?
O2 Eu1 O32' 81.9(5) . . ?
O2 Eu1 O31' 128.7(5) . . ?
O11 Eu1 O42 73.6(2) . . ?
O11 Eu1 O12 51.86(17) . . ?
O11 Eu1 O21 129.3(3) . . ?
O11 Eu1 O32 148.9(6) . . ?
O11 Eu1 O31 134.5(5) . . ?
O11 Eu1 O22 123.3(2) . . ?
O11 Eu1 O41 70.3(2) . . ?
O11 Eu1 O32' 135.8(7) . . ?
O11 Eu1 O31' 149.9(9) . . ?
O12 Eu1 O42 120.3(2) . . ?
O12 Eu1 O21 82.9(3) . . ?
O12 Eu1 O31 152.4(5) . . ?
O12 Eu1 O22 76.5(3) . . ?
O12 Eu1 O41 117.1(3) . . ?
O12 Eu1 O32' 153.1(8) . . ?
O21 Eu1 O42 156.5(3) . . ?
O21 Eu1 O41 126.5(2) . . ?
O21 Eu1 O32' 94.9(7) . . ?
O32 Eu1 O42 77.6(7) . . ?
O32 Eu1 O12 142.8(4) . . ?
O32 Eu1 O21 80.9(6) . . ?
O32 Eu1 O31 50.7(3) . . ?
O32 Eu1 O22 67.6(6) . . ?
O32 Eu1 O41 99.3(5) . . ?
O31 Eu1 O42 83.0(6) . . ?
O31 Eu1 O21 76.1(7) . . ?
O31 Eu1 O22 102.0(6) . . ?
O31 Eu1 O41 64.9(6) . . ?
O22 Eu1 O42 127.64(19) . . ?
O22 Eu1 O21 49.20(19) . . ?
O22 Eu1 O41 166.1(3) . . ?
O22 Eu1 O32' 81.8(10) . . ?
O32' Eu1 O41 85.7(9) . . ?
O31' Eu1 O42 98.8(7) . . ?
O31' Eu1 O12 140.5(6) . . ?
O31' Eu1 O21 58.9(8) . . ?
O31' Eu1 O22 84.8(10) . . ?
O31' Eu1 O41 82.6(10) . . ?
O31' Eu1 O32' 50.8(5) . . ?
N1D Ag2 N1D 91.5(3) 4_566 . ?
N1D Ag2 N1F 85.6(2) . . ?
N1D Ag2 N1F 106.3(2) 4_566 . ?
N1D Ag2 N1F 106.3(2) . 4_566 ?
N1D Ag2 N1F 85.6(2) 4_566 4_566 ?
N1F Ag2 N1F 163.1(3) 4_566 . ?
N1E Ag2 N1D 172.5(3) . 4_566 ?
N1E Ag2 N1D 172.5(3) 4_566 . ?
N1E Ag2 N1D 82.69(19) 4_566 4_566 ?
N1E Ag2 N1D 82.69(19) . . ?
N1E Ag2 N1F 78.1(2) . . ?
N1E Ag2 N1F 91.4(2) . 4_566 ?
N1E Ag2 N1F 91.4(2) 4_566 . ?
N1E Ag2 N1F 78.1(2) 4_566 4_566 ?
N1E Ag2 N1E 103.4(3) . 4_566 ?
N1O Ag3 N1I 101.5(3) 7_556 . ?
N1O Ag3 N1J 79.2(2) 7_556 7_556 ?
N1O Ag3 N1G 95.7(2) 7_556 . ?
N1O Ag3 N1K 82.18(18) 7_556 7_556 ?
N1O Ag3 N1H 173.0(3) 7_556 . ?
N1I Ag3 N1J 96.8(2) . 7_556 ?
N1I Ag3 N1G 83.6(2) . . ?
N1I Ag3 N1K 175.0(2) . 7_556 ?
N1G Ag3 N1J 174.8(3) . 7_556 ?
N1K Ag3 N1J 87.1(2) 7_556 7_556 ?
N1K Ag3 N1G 92.7(2) 7_556 . ?
N1H Ag3 N1I 81.76(19) . . ?
N1H Ag3 N1J 106.7(2) . 7_556 ?
N1H Ag3 N1G 78.5(2) . . ?
N1H Ag3 N1K 94.2(2) . 7_556 ?
N1B Ag1 N1B 94.8(3) 4_576 . ?
N1B Ag1 N1C 79.4(2) 4_576 4_576 ?
N1B Ag1 N1C 79.4(3) . . ?
N1B Ag1 N1C 94.9(2) 4_576 . ?
N1B Ag1 N1C 94.9(2) . 4_576 ?
N1B Ag1 N1A 177.0(2) 4_576 . ?
N1B Ag1 N1A 82.4(2) 4_576 4_576 ?
N1B Ag1 N1A 177.0(2) . 4_576 ?
N1B Ag1 N1A 82.4(2) . . ?
N1C Ag1 N1C 171.7(4) . 4_576 ?
N1C Ag1 N1A 83.5(2) 4_576 4_576 ?
N1C Ag1 N1A 101.9(2) 4_576 . ?
N1C Ag1 N1A 83.5(2) . . ?
N1C Ag1 N1A 101.9(3) . 4_576 ?
N1A Ag1 N1A 100.4(3) . 4_576 ?
O3 P3 C1I 111.9(3) . . ?
O3 P3 C1G 110.8(3) . . ?
O3 P3 C1H 109.8(3) . . ?
C1G P3 C1I 106.0(3) . . ?
C1G P3 C1H 112.0(3) . . ?
C1H P3 C1I 106.1(3) . . ?
O1 P1 C1B 111.2(4) . . ?
O1 P1 C1A 110.7(3) . . ?
O1 P1 C1C 110.5(3) . . ?
C1B P1 C1C 112.0(4) . . ?
C1A P1 C1B 107.2(3) . . ?
C1A P1 C1C 105.1(4) . . ?
O4 P4 C1O 110.6(3) . . ?
O4 P4 C1K 110.9(3) . . ?
O4 P4 C1J 109.5(3) . . ?
C1O P4 C1J 111.0(4) . . ?
C1K P4 C1O 107.2(3) . . ?
C1K P4 C1J 107.6(4) . . ?
O2 P2 C1D 111.2(3) . . ?
O2 P2 C1E 110.5(3) . . ?
O2 P2 C1F 110.6(3) . . ?
C1E P2 C1D 105.9(3) . . ?
C1E P2 C1F 112.7(4) . . ?
C1F P2 C1D 105.8(4) . . ?
C1O N1O Ag3 122.0(5) . 7_546 ?
C5O N1O Ag3 121.2(5) . 7_546 ?
C5O N1O C1O 116.8(7) . . ?
P1 O1 Eu1 176.1(3) . . ?
P3 O3 Eu2 175.7(3) . . ?
N41 O42 Eu1 98.1(4) . . ?
C1B N1B Ag1 122.7(5) . . ?
C5B N1B Ag1 119.6(5) . . ?
C5B N1B C1B 117.6(7) . . ?
P2 O2 Eu1 173.2(3) . . ?
C1I N1I Ag3 125.6(5) . . ?
C1I N1I C5I 116.7(7) . . ?
C5I N1I Ag3 117.1(5) . . ?
N81 O82 Eu2 93.5(5) . . ?
N81' O82 Eu2 96(3) . . ?
P4 O4 Eu2 173.1(3) . . ?
N11 O11 Eu1 96.8(4) . . ?
C1D N1D Ag2 121.6(5) . . ?
C5D N1D Ag2 119.5(5) . . ?
C5D N1D C1D 116.6(7) . . ?
N81 O81 Eu2 93.2(5) . . ?
N81' O81 Eu2 105(3) . . ?
O33 N31 Eu1 178.9(6) . . ?
O33 N31 O32 122.0(8) . . ?
O33 N31 O31 123.3(8) . . ?
O33 N31 O32' 120.8(10) . . ?
O33 N31 O31' 123.3(9) . . ?
O32 N31 Eu1 56.9(5) . . ?
O32 N31 O31 114.6(7) . . ?
O31 N31 Eu1 57.8(5) . . ?
O32' N31 Eu1 58.4(7) . . ?
O31' N31 Eu1 57.4(7) . . ?
O31' N31 O32' 115.7(11) . . ?
O63 N61 Eu2 177.4(5) . . ?
O63 N61 O62' 124.6(8) . . ?
O63 N61 O61' 119.1(8) . . ?
O63 N61 O61 121.4(7) . . ?
O63 N61 O62 123.2(7) . . ?
O62' N61 Eu2 57.9(7) . . ?
O61' N61 Eu2 58.4(6) . . ?
O61' N61 O62' 115.9(10) . . ?
O61 N61 Eu2 57.0(5) . . ?
O62 N61 Eu2 58.6(5) . . ?
O62 N61 O61 115.4(8) . . ?
O53 N51 Eu2 177.4(7) . . ?
O53 N51 O52 123.5(8) . . ?
O53 N51 O51 122.1(8) . . ?
O52 N51 Eu2 58.4(4) . . ?
O52 N51 O51 114.4(6) . . ?
O51 N51 Eu2 56.1(4) . . ?
C3C C4C H4C 120.5 . . ?
C3C C4C C5C 118.9(8) . . ?
C5C C4C H4C 120.5 . . ?
N1I C1I P3 116.1(6) . . ?
N1I C1I C2I 124.7(7) . . ?
C2I C1I P3 119.2(6) . . ?
N51 O52 Eu2 96.9(5) . . ?
N71 O71 Eu2 97.7(7) . . ?
N11 O12 Eu1 93.1(4) . . ?
C1I C2I H2I 121.1 . . ?
C1I C2I C3I 117.8(8) . . ?
C3I C2I H2I 121.1 . . ?
O11 N11 Eu1 57.8(3) . . ?
O11 N11 O12 118.1(6) . . ?
O11 N11 O13 114.0(9) . . ?
O11 N11 O13' 127.6(11) . . ?
O12 N11 Eu1 60.4(3) . . ?
O13 N11 Eu1 166.9(11) . . ?
O13 N11 O12 126.0(8) . . ?
O13' N11 Eu1 155.9(15) . . ?
O13' N11 O12 110.0(12) . . ?
N21 O21 Eu1 98.2(5) . . ?
N1O C1O P4 118.6(6) . . ?
N1O C1O C2O 123.6(7) . . ?
C2O C1O P4 117.6(6) . . ?
C4F C3F H3F 120.9 . . ?
C4F C3F C2F 118.2(9) . . ?
C2F C3F H3F 120.9 . . ?
C3F C4F H4F 120.3 . . ?
C3F C4F C5F 119.4(8) . . ?
C5F C4F H4F 120.3 . . ?
N61 O62' Eu2 96.8(8) . . ?
O23 N21 Eu1 177.4(6) . . ?
O23 N21 O21 123.2(7) . . ?
O23 N21 O22 122.7(7) . . ?
O21 N21 Eu1 57.2(4) . . ?
O22 N21 Eu1 56.9(4) . . ?
O22 N21 O21 114.1(6) . . ?
N71 O72 Eu2 96.2(7) . . ?
N1B C1B P1 118.4(6) . . ?
N1B C1B C2B 123.4(8) . . ?
C2B C1B P1 118.0(6) . . ?
C3C C2C H2C 120.6 . . ?
C1C C2C H2C 120.6 . . ?
C1C C2C C3C 118.9(7) . . ?
N1D C1D P2 116.6(6) . . ?
N1D C1D C2D 124.4(8) . . ?
C2D C1D P2 119.0(6) . . ?
O82 N81 Eu2 60.5(4) . . ?
O82 N81 O81 117.8(7) . . ?
O81 N81 Eu2 59.7(4) . . ?
O83 N81 Eu2 168.4(7) . . ?
O83 N81 O82 121.3(11) . . ?
O83 N81 O81 120.8(10) . . ?
C2I C3I H3I 120.7 . . ?
C2I C3I C4I 118.7(8) . . ?
C4I C3I H3I 120.7 . . ?
C1F N1F Ag2 110.2(5) . . ?
C1F N1F C5F 116.8(7) . . ?
C5F N1F Ag2 116.7(6) . . ?
C4C C3C C2C 118.1(8) . . ?
C4C C3C H3C 120.9 . . ?
C2C C3C H3C 120.9 . . ?
N1J C5J H5J 118.9 . . ?
N1J C5J C4J 122.3(8) . . ?
C4J C5J H5J 118.9 . . ?
C5E C4E H4E 120.8 . . ?
C3E C4E H4E 120.8 . . ?
C3E C4E C5E 118.5(7) . . ?
C1A C2A H2A 120.8 . . ?
C1A C2A C3A 118.4(8) . . ?
C3A C2A H2A 120.8 . . ?
C1H C2H H2H 120.4 . . ?
C1H C2H C3H 119.2(7) . . ?
C3H C2H H2H 120.4 . . ?
C1K C2K H2K 121.0 . . ?
C1K C2K C3K 118.1(8) . . ?
C3K C2K H2K 121.0 . . ?
C4B C3B H3B 120.8 . . ?
C4B C3B C2B 118.4(8) . . ?
C2B C3B H3B 120.8 . . ?
N61 O61' Eu2 96.6(7) . . ?
C5K C4K H4K 120.8 . . ?
C5K C4K C3K 118.4(7) . . ?
C3K C4K H4K 120.8 . . ?
C3A C4A H4A 120.2 . . ?
C3A C4A C5A 119.5(8) . . ?
C5A C4A H4A 120.2 . . ?
N1G C1G P3 117.9(5) . . ?
N1G C1G C2G 122.7(7) . . ?
C2G C1G P3 119.1(5) . . ?
O71 N71 Eu2 58.1(6) . . ?
O71 N71 O72 116.3(9) . . ?
O73 N71 Eu2 178.8(7) . . ?
O73 N71 O71 122.1(9) . . ?
O73 N71 O72 121.4(10) . . ?
O73 N71 O71' 123.1(9) . . ?
O72 N71 Eu2 58.3(6) . . ?
O72' N71 Eu2 58.0(7) . . ?
O72' N71 O73 121.2(11) . . ?
O72' N71 O71' 115.7(10) . . ?
O71' N71 Eu2 57.7(5) . . ?
N3S C31S C32S 177.9(17) . . ?
C5J N1J Ag3 118.0(6) . 7_546 ?
C5J N1J C1J 116.2(7) . . ?
C1J N1J Ag3 115.0(5) . 7_546 ?
C2E C1E P2 119.1(6) . . ?
N1E C1E P2 117.5(6) . . ?
N1E C1E C2E 123.3(7) . . ?
N6S C61S C62S 178.6(13) . . ?
N31 O32 Eu1 98.0(6) . . ?
N1I C5I H5I 118.6 . . ?
N1I C5I C4I 122.8(8) . . ?
C4I C5I H5I 118.6 . . ?
C1D C2D H2D 121.0 . . ?
C3D C2D C1D 118.0(8) . . ?
C3D C2D H2D 121.0 . . ?
C2H C1H P3 118.4(6) . . ?
N1H C1H P3 118.5(6) . . ?
N1H C1H C2H 123.0(7) . . ?
C5G C4G H4G 119.9 . . ?
C3G C4G H4G 119.9 . . ?
C3G C4G C5G 120.2(8) . . ?
C4K C5K H5K 117.9 . . ?
N1K C5K C4K 124.1(7) . . ?
N1K C5K H5K 117.9 . . ?
C3F C2F H2F 120.7 . . ?
C1F C2F C3F 118.7(8) . . ?
C1F C2F H2F 120.7 . . ?
C5C N1C Ag1 114.7(5) . . ?
C5C N1C C1C 116.3(7) . . ?
C1C N1C Ag1 118.8(5) . . ?
C1G N1G Ag3 119.2(4) . . ?
C5G N1G Ag3 116.3(5) . . ?
C5G N1G C1G 117.0(7) . . ?
C1O C2O H2O 120.9 . . ?
C1O C2O C3O 118.2(8) . . ?
C3O C2O H2O 120.9 . . ?
C1E C2E H2E 120.9 . . ?
C3E C2E C1E 118.1(7) . . ?
C3E C2E H2E 120.9 . . ?
O42 N41 Eu1 57.1(4) . . ?
O43 N41 Eu1 176.3(6) . . ?
O43 N41 O42 122.8(9) . . ?
O43 N41 O41 121.4(9) . . ?
O41 N41 Eu1 58.9(4) . . ?
O41 N41 O42 115.8(6) . . ?
N31 O31 Eu1 96.5(6) . . ?
C5K N1K Ag3 120.0(5) . 7_546 ?
C5K N1K C1K 117.1(7) . . ?
C1K N1K Ag3 122.4(5) . 7_546 ?
C3H C4H H4H 120.8 . . ?
C3H C4H C5H 118.4(8) . . ?
C5H C4H H4H 120.8 . . ?
C2K C1K P4 120.1(6) . . ?
N1K C1K P4 116.2(5) . . ?
N1K C1K C2K 123.7(7) . . ?
C1H N1H Ag3 123.1(5) . . ?
C5H N1H Ag3 120.4(5) . . ?
C5H N1H C1H 116.3(7) . . ?
C2K C3K H3K 120.7 . . ?
C4K C3K C2K 118.7(8) . . ?
C4K C3K H3K 120.7 . . ?
C2O C3O H3O 120.6 . . ?
C4O C3O C2O 118.9(8) . . ?
C4O C3O H3O 120.6 . . ?
C4G C5G H5G 118.4 . . ?
N1G C5G C4G 123.2(8) . . ?
N1G C5G H5G 118.4 . . ?
C2D C3D H3D 120.8 . . ?
C4D C3D C2D 118.5(8) . . ?
C4D C3D H3D 120.8 . . ?
N1O C5O H5O 118.3 . . ?
N1O C5O C4O 123.4(8) . . ?
C4O C5O H5O 118.3 . . ?
C3B C4B H4B 120.1 . . ?
C3B C4B C5B 119.8(8) . . ?
C5B C4B H4B 120.1 . . ?
C5J C4J H4J 119.7 . . ?
C3J C4J C5J 120.6(8) . . ?
C3J C4J H4J 119.7 . . ?
C2A C1A P1 120.0(6) . . ?
N1A C1A P1 116.6(6) . . ?
N1A C1A C2A 123.4(7) . . ?
C1B C2B C3B 118.1(7) . . ?
C1B C2B H2B 121.0 . . ?
C3B C2B H2B 121.0 . . ?
C3I C4I H4I 120.4 . . ?
C5I C4I C3I 119.2(8) . . ?
C5I C4I H4I 120.4 . . ?
N1D C5D H5D 118.7 . . ?
N1D C5D C4D 122.6(7) . . ?
C4D C5D H5D 118.7 . . ?
H22A C22S H22B 109.5 . . ?
H22A C22S H22C 109.5 . . ?
H22B C22S H22C 109.5 . . ?
C21S C22S H22A 109.5 . . ?
C21S C22S H22B 109.5 . . ?
C21S C22S H22C 109.5 . . ?
N1F C1F P2 118.7(6) . . ?
N1F C1F C2F 124.7(7) . . ?
C2F C1F P2 116.5(5) . . ?
C1A N1A Ag1 123.1(5) . . ?
C5A N1A Ag1 119.2(5) . . ?
C5A N1A C1A 116.5(7) . . ?
C4F C5F H5F 118.9 . . ?
N1F C5F C4F 122.1(8) . . ?
N1F C5F H5F 118.9 . . ?
H12A C12S H12B 109.5 . . ?
H12A C12S H12C 109.5 . . ?
H12B C12S H12C 109.5 . . ?
C11S C12S H12A 109.5 . . ?
C11S C12S H12B 109.5 . . ?
C11S C12S H12C 109.5 . . ?
C1E N1E Ag2 123.6(5) . . ?
C5E N1E Ag2 119.2(5) . . ?
C5E N1E C1E 117.1(7) . . ?
C3D C4D C5D 119.9(8) . . ?
C3D C4D H4D 120.0 . . ?
C5D C4D H4D 120.0 . . ?
C4C C5C H5C 118.0 . . ?
N1C C5C C4C 124.0(7) . . ?
N1C C5C H5C 118.0 . . ?
C4E C5E H5E 118.3 . . ?
N1E C5E C4E 123.4(7) . . ?
N1E C5E H5E 118.3 . . ?
N1J C1J P4 118.7(5) . . ?
N1J C1J C2J 124.3(7) . . ?
C2J C1J P4 117.0(5) . . ?
C2A C3A H3A 120.9 . . ?
C4A C3A C2A 118.1(8) . . ?
C4A C3A H3A 120.9 . . ?
C1J C2J H2J 120.7 . . ?
C3J C2J C1J 118.5(8) . . ?
C3J C2J H2J 120.7 . . ?
N21 O22 Eu1 98.5(4) . . ?
C2C C1C P1 119.2(6) . . ?
N1C C1C P1 117.0(6) . . ?
N1C C1C C2C 123.8(7) . . ?
N41 O41 Eu1 96.4(5) . . ?
C4E C3E C2E 119.6(7) . . ?
C4E C3E H3E 120.2 . . ?
C2E C3E H3E 120.2 . . ?
C1G C2G H2G 120.3 . . ?
C1G C2G C3G 119.5(8) . . ?
C3G C2G H2G 120.3 . . ?
C2H C3H H3H 120.6 . . ?
C4H C3H C2H 118.7(8) . . ?
C4H C3H H3H 120.6 . . ?
C3O C4O C5O 119.1(8) . . ?
C3O C4O H4O 120.5 . . ?
C5O C4O H4O 120.5 . . ?
N51 O51 Eu2 99.1(5) . . ?
C31S C32S H32A 109.5 . . ?
C31S C32S H32B 109.5 . . ?
C31S C32S H32C 109.5 . . ?
H32A C32S H32B 109.5 . . ?
H32A C32S H32C 109.5 . . ?
H32B C32S H32C 109.5 . . ?
N2S C21S C22S 178.2(16) . . ?
C4A C5A H5A 118.0 . . ?
N1A C5A C4A 124.0(8) . . ?
N1A C5A H5A 118.0 . . ?
N1B C5B C4B 122.7(7) . . ?
N1B C5B H5B 118.7 . . ?
C4B C5B H5B 118.7 . . ?
C4H C5H H5H 117.8 . . ?
N1H C5H C4H 124.4(8) . . ?
N1H C5H H5H 117.8 . . ?
C4G C3G C2G 117.3(8) . . ?
C4G C3G H3G 121.3 . . ?
C2G C3G H3G 121.3 . . ?
H52A C52S H52B 109.5 . . ?
H52A C52S H52C 109.5 . . ?
H52B C52S H52C 109.5 . . ?
C51S C52S H52A 109.5 . . ?
C51S C52S H52B 109.5 . . ?
C51S C52S H52C 109.5 . . ?
N1S C11S C12S 179.4(16) . . ?
N5S C51S C52S 179(2) . . ?
C4J C3J H3J 121.2 . . ?
C2J C3J C4J 117.6(9) . . ?
C2J C3J H3J 121.2 . . ?
N4S C41S C42S 160(2) . . ?
C41S C42S H42A 109.5 . . ?
C41S C42S H42B 109.5 . . ?
C41S C42S H42C 109.5 . . ?
H42A C42S H42B 109.5 . . ?
H42A C42S H42C 109.5 . . ?
H42B C42S H42C 109.5 . . ?
C61S C62S H62A 109.5 . . ?
C61S C62S H62B 109.5 . . ?
C61S C62S H62C 109.5 . . ?
H62A C62S H62B 109.5 . . ?
H62A C62S H62C 109.5 . . ?
H62B C62S H62C 109.5 . . ?
N31 O32' Eu1 95.4(9) . . ?
N31 O31' Eu1 97.9(8) . . ?
N61 O61 Eu2 97.0(6) . . ?
N61 O62 Eu2 96.6(6) . . ?
N71 O72' Eu2 98.3(9) . . ?
N71 O71' Eu2 95.5(7) . . ?
O82 N81' Eu2 54(2) . . ?
O81 N81' Eu2 52(2) . . ?
O81 N81' O82 104(4) . . ?
O83' N81' Eu2 172(5) . . ?
O83' N81' O82 132(7) . . ?
O83' N81' O81 124(7) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu2 O82 N81 O81 17.3(9) . . . . ?
Eu2 O82 N81 O83 -166.8(9) . . . . ?
Eu2 O82 N81' O81 -14(2) . . . . ?
Eu2 O82 N81' O83' 173(4) . . . . ?
Eu2 O81 N81 O82 -17.5(9) . . . . ?
Eu2 O81 N81 O83 166.6(8) . . . . ?
Eu2 O81 N81' O82 15(3) . . . . ?
Eu2 O81 N81' O83' -172(3) . . . . ?
Eu2 O71 N71 O73 178.6(8) . . . . ?
Eu2 O71 N71 O72 4.0(13) . . . . ?
Eu2 O72 N71 O71 -4.0(13) . . . . ?
Eu2 O72 N71 O73 -178.6(7) . . . . ?
Eu1 O42 N41 O43 175.6(7) . . . . ?
Eu1 O42 N41 O41 -4.5(7) . . . . ?
Eu1 O11 N11 O12 3.1(9) . . . . ?
Eu1 O11 N11 O13 168.4(12) . . . . ?
Eu1 O11 N11 O13' -151.2(19) . . . . ?
Eu1 O12 N11 O11 -3.0(9) . . . . ?
Eu1 O12 N11 O13 -166.3(14) . . . . ?
Eu1 O12 N11 O13' 155.6(14) . . . . ?
Eu1 O21 N21 O23 -177.0(6) . . . . ?
Eu1 O21 N21 O22 1.3(8) . . . . ?
Ag2 N1D C1D P2 17.4(8) . . . . ?
Ag2 N1D C1D C2D -164.3(6) . . . . ?
Ag2 N1D C5D C4D 164.7(7) . . . . ?
Ag2 N1F C1F P2 43.3(7) . . . . ?
Ag2 N1F C1F C2F -135.2(7) . . . . ?
Ag2 N1F C5F C4F 134.1(9) . . . . ?
Ag2 N1E C5E C4E 177.7(7) . . . . ?
Ag3 N1O C1O P4 -3.1(9) 7_546 . . . ?
Ag3 N1O C1O C2O -179.4(6) 7_546 . . . ?
Ag3 N1O C5O C4O 179.5(7) 7_546 . . . ?
Ag3 N1I C1I P3 7.3(9) . . . . ?
Ag3 N1I C1I C2I -174.0(6) . . . . ?
Ag3 N1I C5I C4I 174.5(7) . . . . ?
Ag3 N1J C1J P4 -33.9(9) 7_546 . . . ?
Ag3 N1J C1J C2J 144.0(7) 7_546 . . . ?
Ag3 N1G C5G C4G 147.2(8) . . . . ?
Ag3 N1K C1K P4 -6.9(9) 7_546 . . . ?
Ag3 N1K C1K C2K 171.2(6) 7_546 . . . ?
Ag3 N1H C5H C4H -174.5(7) . . . . ?
Ag1 N1B C1B P1 -5.4(9) . . . . ?
Ag1 N1B C1B C2B 179.9(6) . . . . ?
Ag1 N1B C5B C4B -179.6(7) . . . . ?
Ag1 N1C C5C C4C -146.5(9) . . . . ?
Ag1 N1C C1C P1 -32.7(9) . . . . ?
Ag1 N1C C1C C2C 145.4(7) . . . . ?
Ag1 N1A C5A C4A -168.3(8) . . . . ?
P3 C1I C2I C3I 179.3(6) . . . . ?
P3 C1G N1G Ag3 28.1(9) . . . . ?
P3 C1G N1G C5G 176.7(7) . . . . ?
P3 C1G C2G C3G -174.5(7) . . . . ?
P3 C1H N1H Ag3 -1.9(9) . . . . ?
P3 C1H N1H C5H -177.4(7) . . . . ?
P1 C1B C2B C3B -175.6(6) . . . . ?
P1 C1A N1A Ag1 -13.4(9) . . . . ?
P1 C1A N1A C5A 179.2(7) . . . . ?
P4 C1O C2O C3O -177.4(7) . . . . ?
P4 C1J C2J C3J 179.1(7) . . . . ?
P2 C1D C2D C3D 179.0(6) . . . . ?
P2 C1E C2E C3E 174.6(6) . . . . ?
P2 C1E N1E Ag2 7.4(8) . . . . ?
P2 C1E N1E C5E -176.5(6) . . . . ?
N1O C1O C2O C3O -1.2(14) . . . . ?
N1O C5O C4O C3O 0.9(16) . . . . ?
O1 P1 C1B N1B -178.2(6) . . . . ?
O1 P1 C1B C2B -3.2(8) . . . . ?
O1 P1 C1A C2A 10.1(8) . . . . ?
O1 P1 C1A N1A -170.5(6) . . . . ?
O1 P1 C1C C2C 23.2(8) . . . . ?
O1 P1 C1C N1C -158.7(7) . . . . ?
O3 P3 C1I N1I 176.2(6) . . . . ?
O3 P3 C1I C2I -2.5(8) . . . . ?
O3 P3 C1G N1G 160.0(6) . . . . ?
O3 P3 C1G C2G -25.5(7) . . . . ?
O3 P3 C1H C2H 5.0(8) . . . . ?
O3 P3 C1H N1H -177.5(6) . . . . ?
O42 N41 O41 Eu1 4.4(7) . . . . ?
N1B C1B C2B C3B -0.8(13) . . . . ?
O2 P2 C1D N1D 168.8(6) . . . . ?
O2 P2 C1D C2D -9.6(7) . . . . ?
O2 P2 C1E C2E 0.8(8) . . . . ?
O2 P2 C1E N1E 177.2(6) . . . . ?
O2 P2 C1F N1F 147.6(6) . . . . ?
O2 P2 C1F C2F -33.8(7) . . . . ?
N1I C1I C2I C3I 0.7(13) . . . . ?
N1I C5I C4I C3I -0.2(15) . . . . ?
O4 P4 C1O N1O 178.9(6) . . . . ?
O4 P4 C1O C2O -4.6(8) . . . . ?
O4 P4 C1K C2K 7.3(7) . . . . ?
O4 P4 C1K N1K -174.5(6) . . . . ?
O4 P4 C1J N1J -155.2(7) . . . . ?
O4 P4 C1J C2J 26.7(8) . . . . ?
O53 N51 O52 Eu2 177.8(7) . . . . ?
O53 N51 O51 Eu2 -177.7(7) . . . . ?
N1D C1D C2D C3D 0.8(13) . . . . ?
N1D C5D C4D C3D -0.8(14) . . . . ?
O33 N31 O32 Eu1 -179.8(6) . . . . ?
O33 N31 O31 Eu1 179.8(6) . . . . ?
O33 N31 O32' Eu1 -179.1(6) . . . . ?
O33 N31 O31' Eu1 179.0(6) . . . . ?
O23 N21 O22 Eu1 177.0(6) . . . . ?
C1I P3 C1G N1G -78.3(7) . . . . ?
C1I P3 C1G C2G 96.1(7) . . . . ?
C1I P3 C1H C2H -116.1(7) . . . . ?
C1I P3 C1H N1H 61.4(7) . . . . ?
C1I N1I C5I C4I 2.7(14) . . . . ?
C1I C2I C3I C4I 2.0(12) . . . . ?
O43 N41 O41 Eu1 -175.7(7) . . . . ?
O52 N51 O51 Eu2 3.3(8) . . . . ?
C2I C3I C4I C5I -2.2(14) . . . . ?
O21 N21 O22 Eu1 -1.3(8) . . . . ?
O63 N61 O62' Eu2 179.7(7) . . . . ?
O63 N61 O61' Eu2 179.9(6) . . . . ?
O63 N61 O61 Eu2 -177.7(6) . . . . ?
O63 N61 O62 Eu2 177.8(7) . . . . ?
C1O P4 C1K C2K -113.5(7) . . . . ?
C1O P4 C1K N1K 64.7(6) . . . . ?
C1O P4 C1J N1J -32.8(8) . . . . ?
C1O P4 C1J C2J 149.1(6) . . . . ?
C1O N1O C5O C4O -1.8(14) . . . . ?
C1O C2O C3O C4O 0.2(14) . . . . ?
C3F C4F C5F N1F -2.9(16) . . . . ?
C3F C2F C1F P2 -179.1(7) . . . . ?
C3F C2F C1F N1F -0.6(13) . . . . ?
C4F C3F C2F C1F -1.6(14) . . . . ?
O62' N61 O61' Eu2 -7.1(13) . . . . ?
O73 N71 O72' Eu2 -179.0(7) . . . . ?
O73 N71 O71' Eu2 179.0(7) . . . . ?
C1B P1 C1A C2A -111.3(7) . . . . ?
C1B P1 C1A N1A 68.0(7) . . . . ?
C1B P1 C1C C2C 147.7(6) . . . . ?
C1B P1 C1C N1C -34.2(8) . . . . ?
C1B N1B C5B C4B 0.2(14) . . . . ?
C1D P2 C1E C2E -119.8(7) . . . . ?
C1D P2 C1E N1E 56.6(6) . . . . ?
C1D P2 C1F N1F -91.9(7) . . . . ?
C1D P2 C1F C2F 86.7(6) . . . . ?
C1D N1D C5D C4D 1.7(13) . . . . ?
C1D C2D C3D C4D 0.2(13) . . . . ?
C3C C4C C5C N1C 0.3(17) . . . . ?
C3C C2C C1C P1 176.9(6) . . . . ?
C3C C2C C1C N1C -1.1(13) . . . . ?
C5J N1J C1J P4 -177.8(8) . . . . ?
C5J N1J C1J C2J 0.2(14) . . . . ?
C5J C4J C3J C2J -6.2(18) . . . . ?
C2A C1A N1A Ag1 166.0(6) . . . . ?
C2A C1A N1A C5A -1.4(12) . . . . ?
C2H C1H N1H Ag3 175.4(6) . . . . ?
C2H C1H N1H C5H 0.0(13) . . . . ?
C3B C4B C5B N1B 0.3(15) . . . . ?
O61' N61 O62' Eu2 7.1(13) . . . . ?
C4K C5K N1K Ag3 -171.7(6) . . . 7_546 ?
C4K C5K N1K C1K 0.3(13) . . . . ?
C1G P3 C1I N1I 55.3(7) . . . . ?
C1G P3 C1I C2I -123.5(6) . . . . ?
C1G P3 C1H C2H 128.6(6) . . . . ?
C1G P3 C1H N1H -53.9(7) . . . . ?
C1G N1G C5G C4G -2.3(16) . . . . ?
C1G C2G C3G C4G -2.0(13) . . . . ?
N1J C5J C4J C3J 8(2) . . . . ?
N1J C1J C2J C3J 1.1(14) . . . . ?
C1E P2 C1D N1D -71.1(6) . . . . ?
C1E P2 C1D C2D 110.5(7) . . . . ?
C1E P2 C1F N1F 23.3(7) . . . . ?
C1E P2 C1F C2F -158.1(6) . . . . ?
C1E C2E C3E C4E 2.2(13) . . . . ?
C1E N1E C5E C4E 1.4(13) . . . . ?
O32 N31 O31 Eu1 -3.7(9) . . . . ?
C5I N1I C1I P3 178.3(7) . . . . ?
C5I N1I C1I C2I -3.0(13) . . . . ?
C2D C3D C4D C5D -0.2(14) . . . . ?
C1H P3 C1I N1I -64.0(7) . . . . ?
C1H P3 C1I C2I 117.2(7) . . . . ?
C1H P3 C1G N1G 37.0(7) . . . . ?
C1H P3 C1G C2G -148.6(6) . . . . ?
C1H C2H C3H C4H 2.3(13) . . . . ?
C1H N1H C5H C4H 1.2(14) . . . . ?
C5K C4K C3K C2K 1.9(12) . . . . ?
C5K N1K C1K P4 -178.6(6) . . . . ?
C5K N1K C1K C2K -0.5(12) . . . . ?
C2F C3F C4F C5F 3.3(15) . . . . ?
N1G C1G C2G C3G -0.4(13) . . . . ?
C2O C3O C4O C5O 0.0(15) . . . . ?
C2E C1E N1E Ag2 -176.3(6) . . . . ?
C2E C1E N1E C5E -0.2(12) . . . . ?
O31 N31 O32 Eu1 3.7(9) . . . . ?
C1K P4 C1O N1O -60.1(7) . . . . ?
C1K P4 C1O C2O 116.4(7) . . . . ?
C1K P4 C1J N1J 84.2(8) . . . . ?
C1K P4 C1J C2J -93.9(7) . . . . ?
C1K C2K C3K C4K -2.1(12) . . . . ?
C3K C2K C1K P4 179.5(6) . . . . ?
C3K C2K C1K N1K 1.4(12) . . . . ?
C3K C4K C5K N1K -1.0(13) . . . . ?
C5G C4G C3G C2G 2.3(14) . . . . ?
C5O N1O C1O P4 178.2(7) . . . . ?
C5O N1O C1O C2O 1.9(13) . . . . ?
C4B C3B C2B C1B 1.3(12) . . . . ?
C4J C5J N1J Ag3 -147.3(10) . . . 7_546 ?
C4J C5J N1J C1J -4.6(17) . . . . ?
C1A P1 C1B N1B -57.1(7) . . . . ?
C1A P1 C1B C2B 117.9(7) . . . . ?
C1A P1 C1C C2C -96.3(7) . . . . ?
C1A P1 C1C N1C 81.8(7) . . . . ?
C1A C2A C3A C4A -0.1(14) . . . . ?
C1A N1A C5A C4A -0.4(14) . . . . ?
C2B C3B C4B C5B -1.0(13) . . . . ?
C5D N1D C1D P2 -180.0(6) . . . . ?
C5D N1D C1D C2D -1.7(12) . . . . ?
C1F P2 C1D N1D 48.7(7) . . . . ?
C1F P2 C1D C2D -129.7(6) . . . . ?
C1F P2 C1E C2E 125.1(6) . . . . ?
C1F P2 C1E N1E -58.5(7) . . . . ?
C1F N1F C5F C4F 0.6(15) . . . . ?
C5F N1F C1F P2 179.6(7) . . . . ?
C5F N1F C1F C2F 1.1(13) . . . . ?
N1E C1E C2E C3E -1.6(13) . . . . ?
C5C C4C C3C C2C 0.5(14) . . . . ?
C5C N1C C1C P1 -176.2(8) . . . . ?
C5C N1C C1C C2C 1.8(14) . . . . ?
C5E C4E C3E C2E -1.2(13) . . . . ?
C1J P4 C1O N1O 57.2(7) . . . . ?
C1J P4 C1O C2O -126.4(7) . . . . ?
C1J P4 C1K C2K 127.0(6) . . . . ?
C1J P4 C1K N1K -54.8(7) . . . . ?
C1J C2J C3J C4J 1.9(15) . . . . ?
C3A C2A C1A P1 -179.0(7) . . . . ?
C3A C2A C1A N1A 1.6(13) . . . . ?
C3A C4A C5A N1A 1.9(16) . . . . ?
C1C P1 C1B N1B 57.6(7) . . . . ?
C1C P1 C1B C2B -127.4(7) . . . . ?
C1C P1 C1A C2A 129.4(7) . . . . ?
C1C P1 C1A N1A -51.2(7) . . . . ?
C1C C2C C3C C4C -0.1(13) . . . . ?
C1C N1C C5C C4C -1.4(17) . . . . ?
C3E C4E C5E N1E -0.7(14) . . . . ?
C2G C1G N1G Ag3 -146.1(6) . . . . ?
C2G C1G N1G C5G 2.5(13) . . . . ?
C3H C2H C1H P3 175.6(7) . . . . ?
C3H C2H C1H N1H -1.7(13) . . . . ?
C3H C4H C5H N1H -0.5(15) . . . . ?
O51 N51 O52 Eu2 -3.2(8) . . . . ?
C5A C4A C3A C2A -1.6(15) . . . . ?
C5B N1B C1B P1 174.8(7) . . . . ?
C5B N1B C1B C2B 0.1(13) . . . . ?
C5H C4H C3H C2H -1.3(14) . . . . ?
C3G C4G C5G N1G -0.1(17) . . . . ?
O32' N31 O31' Eu1 3.7(14) . . . . ?
O31' N31 O32' Eu1 -3.7(14) . . . . ?
O61 N61 O62 Eu2 -5.2(11) . . . . ?
O62 N61 O61 Eu2 5.3(11) . . . . ?
O72' N71 O71' Eu2 -2.8(12) . . . . ?
O71' N71 O72' Eu2 2.8(12) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.793(12)
2 0.207(12)

_vrf_PLAT971_euag575             
;
PROBLEM: Check Calcd Resid. Dens.  0.91Ang From Eu1 3.45 eA-3
RESPONSE: This is an unidentified artefact of the structure.
;


_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent: MeCN'
_exptl_crystal_preparation       Luminescent
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_tbag573
_database_code_depnum_ccdc_archive 'CCDC 2329148'
loop_
_audit_author_name
_audit_author_address
'Yuliya Bryleva'
;Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences
Russia
;
_audit_update_record             
;
2024-01-29 deposited with the CCDC.	2024-03-11 downloaded from the CCDC.
;
_audit_creation_date             2023-11-30
_audit_creation_method           
;
Olex2 1.5
(compiled 2023.03.06 svn.rbb2c1857 for OlexSys, GUI svn.r6748)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '2(C15 H12 Ag0.5 N5 O7 P Tb0.5), 3(C2 H3 N)'
_chemical_formula_sum            'C36 H33 Ag N13 O14 P2 Tb'
_chemical_formula_weight         1200.48
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1723 4.1537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           20
_space_group_name_H-M_alt        'C 2 2 21'
_space_group_name_Hall           'C 2c 2'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z+1/2'
'-x, y, -z+1/2'
'x, -y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   16.0444(4)
_cell_length_b                   28.8706(9)
_cell_length_c                   38.8302(10)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     17986.6(9)
_cell_formula_units_Z            16
_cell_measurement_reflns_used    9095
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      30.92
_cell_measurement_theta_min      2.52
_shelx_estimated_absorpt_T_max   0.938
_shelx_estimated_absorpt_T_min   0.814
_exptl_absorpt_coefficient_mu    2.146
_exptl_absorpt_correction_T_max  0.7462
_exptl_absorpt_correction_T_min  0.6545
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0996 before and 0.0600 after correction.
The Ratio of minimum to maximum transmission is 0.8771.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.773
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             9504
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.03
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0575
_diffrn_reflns_av_unetI/netI     0.0347
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       42
_diffrn_reflns_limit_k_min       -42
_diffrn_reflns_limit_l_max       57
_diffrn_reflns_limit_l_min       -57
_diffrn_reflns_number            231949
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         31.585
_diffrn_reflns_theta_min         1.544
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 7.41
_diffrn_detector_type            'Bruker PHOTON III area detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 Venture diffractometer'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.885
_reflns_Friedel_fraction_full    1.000
_reflns_Friedel_fraction_max     0.999
_reflns_number_gt                26043
_reflns_number_total             30129
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX3'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2014/7 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.209
_refine_diff_density_min         -1.303
_refine_diff_density_rms         0.100
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.422(8)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.017
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1276
_refine_ls_number_reflns         30129
_refine_ls_number_restraints     19
_refine_ls_R_factor_all          0.0443
_refine_ls_R_factor_gt           0.0340
_refine_ls_restrained_S_all      1.019
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0254P)²+51.6233P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0719
_refine_ls_wR_factor_ref         0.0763
_refine_special_details          'Refined as a 2-component inversion twin.,Twin'
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.578(8)
 0.422(8)
2. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
3. Restrained distances
 N2S-C21S
 1.11 with sigma of 0.005
 C22S-C21S
 1.44 with sigma of 0.005
 C22S-N2S
 2.55 with sigma of 0.005
 Tb2-O61 \\sim Tb2-O61'
 with sigma of 0.02
 Tb2-O62 \\sim Tb2-O62'
 with sigma of 0.02
 N61-O61 \\sim N61-O61'
 with sigma of 0.02
 N61-O62 \\sim N61-O62'
 with sigma of 0.02
 Tb1-O32 \\sim Tb1-O32'
 with sigma of 0.02
 Tb1-O31 \\sim Tb1-O31'
 with sigma of 0.02
 N31-O32 \\sim N31-O32'
 with sigma of 0.02
 N31-O31 \\sim N31-O31'
 with sigma of 0.02
 Tb2-O51 \\sim Tb2-O51'
 with sigma of 0.02
 Tb2-O52 \\sim Tb2-O52'
 with sigma of 0.02
 O51-N51 \\sim O51'-N51
 with sigma of 0.02
 N51-O52 \\sim N51-O52'
 with sigma of 0.02
 Tb1-O42 \\sim Tb1-O42'
 with sigma of 0.02
 Tb1-O41 \\sim Tb1-O41'
 with sigma of 0.02
 N41-O42 \\sim N41-O42'
 with sigma of 0.02
 N41-O41 \\sim N41-O41'
 with sigma of 0.02
4. Others
 Sof(O61')=Sof(O62')=1-FVAR(1)
 Sof(O61)=Sof(O62)=FVAR(1)
 Sof(O31')=Sof(O32')=1-FVAR(2)
 Sof(O32)=Sof(O31)=FVAR(2)
 Sof(O52')=Sof(O51')=1-FVAR(3)
 Sof(O51)=Sof(O52)=FVAR(3)
 Sof(O41')=Sof(O42')=1-FVAR(4)
 Sof(O42)=Sof(O41)=FVAR(4)
5.a Aromatic/amide H refined with riding coordinates:
 C3H(HR), C2B(H2B), C4C(H4C), C2F(H2F), C4F(H4F), C2O(HS), C3F(H3F), C4J(HT),
 C4H(HU), C2C(H2C), C5O(HV), C3C(H3C), C4O(HW), C3O(HX), C2K(HY), C5C(H5C),
 C3E(H3E), C3A(H3A), C2I(HZ), C5H(H1), C3J(H2), C2H(H3), C3G(H4), C2E(H2E),
 C2G(H5), C2A(H2A), C4B(H4B), C4D(H4D), C5F(H5F), C4I(H6), C5G(H7), C4G(H8),
 C5B(H5B), C5I(H9), C3D(H3D), C3K(H10), C4A(H4A), C2D(H2D), C4K(H11), C2J(H12),
 C5J(H13), C3I(H14), C5A(H5A), C4E(H4E), C5E(H5E), C3B(H3B), C5D(H5D), C5K(H15)
5.b Idealised Me refined as rotating group:
 C52S(H,HA,HB), C42S(HC,HD,HE), C32S(HF,HG,HH), C12S(HI,HJ,HK), C62S(HL,HM,HN),
  C22S(HO,HP,HQ)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Tb1 Tb 0.48964(2) 0.24941(2) 0.53883(2) 0.01839(4) Uani 1 1 d D . . . .
Tb2 Tb 0.75332(2) 0.49034(2) 0.71238(2) 0.01885(5) Uani 1 1 d D . . . .
Ag1 Ag 0.48035(4) 0.0000 0.5000 0.02752(14) Uani 1 2 d S T P . .
Ag2 Ag 0.50464(4) 0.5000 0.5000 0.03134(15) Uani 1 2 d S T P . .
Ag3 Ag 0.74315(3) 0.24011(2) 0.74545(2) 0.03150(9) Uani 1 1 d . . . . .
P3 P 0.75275(9) 0.36177(3) 0.73459(3) 0.0195(2) Uani 1 1 d . . . . .
P4 P 0.75891(9) 0.61820(4) 0.73670(3) 0.0188(2) Uani 1 1 d . . . . .
P1 P 0.48412(9) 0.12152(4) 0.51489(3) 0.0187(2) Uani 1 1 d . . . . .
P2 P 0.49856(9) 0.37793(4) 0.51569(3) 0.0201(2) Uani 1 1 d . . . . .
O2 O 0.4958(3) 0.32743(11) 0.52328(10) 0.0259(8) Uani 1 1 d . . . . .
O4 O 0.7576(3) 0.56777(10) 0.72896(8) 0.0234(7) Uani 1 1 d . . . . .
O73 O 1.0068(3) 0.48877(19) 0.69070(13) 0.0431(11) Uani 1 1 d . . . . .
O3 O 0.7543(3) 0.41256(10) 0.72844(8) 0.0239(7) Uani 1 1 d . . . . .
O63 O 0.7445(3) 0.50155(14) 0.60624(12) 0.0495(12) Uani 1 1 d . . . . .
O1 O 0.4830(3) 0.17224(10) 0.52173(9) 0.0233(7) Uani 1 1 d . . . . .
O82 O 0.8298(2) 0.48734(16) 0.76679(10) 0.0315(8) Uani 1 1 d . . . . .
N61 N 0.7459(3) 0.49699(13) 0.63763(11) 0.0282(9) Uani 1 1 d D . . . .
N31 N 0.5012(3) 0.24810(17) 0.61380(11) 0.0307(9) Uani 1 1 d D . . . .
O12 O 0.4061(2) 0.25225(16) 0.48681(9) 0.0321(7) Uani 1 1 d . . . . .
C1B C 0.5742(3) 0.10507(18) 0.48911(15) 0.0215(10) Uani 1 1 d . . . . .
C1O C 0.8464(3) 0.63347(18) 0.76407(15) 0.0208(10) Uani 1 1 d . . . . .
C1D C 0.4054(3) 0.39658(19) 0.49298(15) 0.0229(11) Uani 1 1 d . . . . .
C1I C 0.6609(3) 0.34542(18) 0.75905(15) 0.0217(11) Uani 1 1 d . . . . .
N1H N 0.8519(3) 0.29750(16) 0.76377(14) 0.0267(10) Uani 1 1 d . . . . .
O51 O 0.6130(7) 0.4527(4) 0.7058(9) 0.043(4) Uani 0.61(7) 1 d D . P A 1
N71 N 0.9326(3) 0.4879(2) 0.69635(12) 0.0277(9) Uani 1 1 d . . . . .
O11 O 0.5391(2) 0.24966(18) 0.47830(9) 0.0351(8) Uani 1 1 d . . . . .
N1O N 0.8557(3) 0.67831(17) 0.77070(14) 0.0287(11) Uani 1 1 d . . . . .
O71 O 0.8914(3) 0.45213(16) 0.70008(16) 0.0447(14) Uani 1 1 d . . . . .
O81 O 0.6948(3) 0.48851(16) 0.77117(10) 0.0335(8) Uani 1 1 d . . . . .
N1A N 0.3873(3) 0.05991(15) 0.48051(13) 0.0241(9) Uani 1 1 d . . . . .
O43 O 0.7453(3) 0.24275(17) 0.55425(11) 0.0465(11) Uani 1 1 d . . . . .
N1I N 0.6485(3) 0.30045(17) 0.76601(14) 0.0266(10) Uani 1 1 d . . . . .
C3H C 0.9630(3) 0.3608(2) 0.79252(16) 0.0286(12) Uani 1 1 d . . . . .
HR H 1.0015 0.3822 0.8021 0.034 Uiso 1 1 calc R U . . .
N11 N 0.4660(3) 0.2525(2) 0.46554(12) 0.0372(11) Uani 1 1 d . . . . .
N1K N 0.6547(3) 0.67969(16) 0.76863(15) 0.0300(11) Uani 1 1 d . . . . .
N51 N 0.5710(3) 0.4886(2) 0.70283(13) 0.0338(10) Uani 1 1 d D . . . .
O61 O 0.7706(7) 0.4612(3) 0.65159(19) 0.033(2) Uani 0.618(19) 1 d D . P A 1
O72 O 0.8900(3) 0.52491(16) 0.69795(19) 0.062(2) Uani 1 1 d . . . . .
O33 O 0.5069(3) 0.24687(18) 0.64476(11) 0.0525(13) Uani 1 1 d . . . . .
C2B C 0.6218(4) 0.1393(2) 0.47416(15) 0.0260(11) Uani 1 1 d . . . . .
H2B H 0.6077 0.1710 0.4768 0.031 Uiso 1 1 calc R U . . .
O23 O 0.2354(3) 0.2541(2) 0.56051(15) 0.0635(14) Uani 1 1 d . . . . .
O21 O 0.3505(3) 0.21631(16) 0.55373(17) 0.0498(15) Uani 1 1 d . . . . .
N1D N 0.3999(3) 0.44097(17) 0.48393(14) 0.0274(10) Uani 1 1 d . . . . .
N41 N 0.6710(3) 0.24493(19) 0.54897(12) 0.0297(10) Uani 1 1 d D . . . .
O22 O 0.3517(3) 0.28951(17) 0.55160(17) 0.0527(16) Uani 1 1 d . . . . .
N1B N 0.5890(3) 0.05944(16) 0.48620(14) 0.0251(9) Uani 1 1 d . . . . .
N1E N 0.6027(3) 0.43736(16) 0.48334(15) 0.0290(11) Uani 1 1 d . . . . .
C4C C 0.5106(5) 0.0430(2) 0.61498(17) 0.0478(17) Uani 1 1 d . . . . .
H4C H 0.5141 0.0266 0.6361 0.057 Uiso 1 1 calc R U . . .
C2F C 0.5527(4) 0.3894(2) 0.58263(16) 0.0312(12) Uani 1 1 d . . . . .
H2F H 0.5668 0.3575 0.5818 0.037 Uiso 1 1 calc R U . . .
C4F C 0.5475(5) 0.4613(2) 0.61198(17) 0.0454(16) Uani 1 1 d . . . . .
H4F H 0.5574 0.4798 0.6318 0.055 Uiso 1 1 calc R U . . .
N1C N 0.4545(4) 0.04839(16) 0.55747(14) 0.0405(13) Uani 1 1 d . . . . .
C2O C 0.8990(3) 0.5993(2) 0.77580(15) 0.0256(11) Uani 1 1 d . . . . .
HS H 0.8900 0.5677 0.7700 0.031 Uiso 1 1 calc R U . . .
C3F C 0.5690(4) 0.4155(2) 0.61170(16) 0.0364(13) Uani 1 1 d . . . . .
H3F H 0.5948 0.4018 0.6312 0.044 Uiso 1 1 calc R U . . .
C4J C 0.8000(4) 0.7037(2) 0.64114(17) 0.0471(17) Uani 1 1 d . . . . .
HT H 0.8089 0.7228 0.6215 0.056 Uiso 1 1 calc R U . . .
C4H C 0.9730(4) 0.3137(2) 0.79768(17) 0.0318(13) Uani 1 1 d . . . . .
HU H 1.0178 0.3021 0.8111 0.038 Uiso 1 1 calc R U . . .
C2C C 0.5423(4) 0.10837(19) 0.57979(15) 0.0309(12) Uani 1 1 d . . . . .
H2C H 0.5691 0.1373 0.5761 0.037 Uiso 1 1 calc R U . . .
C5O C 0.9196(4) 0.6904(2) 0.79137(19) 0.0339(14) Uani 1 1 d . . . . .
HV H 0.9266 0.7222 0.7971 0.041 Uiso 1 1 calc R U . . .
C3C C 0.5523(5) 0.0846(2) 0.61066(18) 0.0419(15) Uani 1 1 d . . . . .
H3C H 0.5868 0.0967 0.6284 0.050 Uiso 1 1 calc R U . . .
C4O C 0.9752(4) 0.6587(2) 0.80458(18) 0.0349(14) Uani 1 1 d . . . . .
HW H 1.0194 0.6686 0.8191 0.042 Uiso 1 1 calc R U . . .
C1J C 0.7716(3) 0.65184(16) 0.69775(13) 0.0245(10) Uani 1 1 d . . . . .
N1G N 0.7263(4) 0.28858(17) 0.69135(14) 0.0477(16) Uani 1 1 d . . . . .
N81 N 0.7663(4) 0.4824(2) 0.78518(12) 0.0446(14) Uani 1 1 d . . . . .
C3O C 0.9658(4) 0.6126(2) 0.79642(16) 0.0311(13) Uani 1 1 d . . . . .
HX H 1.0043 0.5902 0.8047 0.037 Uiso 1 1 calc R U . . .
O53 O 0.4956(3) 0.4873(2) 0.69948(16) 0.0634(16) Uani 1 1 d . . . . .
O32 O 0.4762(9) 0.2841(2) 0.59717(17) 0.038(3) Uani 0.67(3) 1 d D . P B 1
N1J N 0.7490(4) 0.69638(13) 0.69841(11) 0.0370(11) Uani 1 1 d . . . . .
O42 O 0.6278(6) 0.2811(4) 0.5561(7) 0.027(4) Uani 0.57(6) 1 d D . P B 1
C2K C 0.6112(4) 0.6000(2) 0.77005(16) 0.0276(11) Uani 1 1 d . . . . .
HY H 0.6203 0.5687 0.7635 0.033 Uiso 1 1 calc R U . . .
O52 O 0.6137(10) 0.5264(4) 0.7026(13) 0.062(9) Uani 0.61(7) 1 d D . P A 1
C5C C 0.4640(5) 0.0258(2) 0.58798(18) 0.0477(18) Uani 1 1 d . . . . .
H5C H 0.4373 -0.0033 0.5908 0.057 Uiso 1 1 calc R U . . .
N1F N 0.4952(4) 0.45590(15) 0.55479(13) 0.0438(14) Uani 1 1 d . . . . .
C1G C 0.7578(4) 0.33149(15) 0.69362(13) 0.0287(10) Uani 1 1 d . . . . .
C3E C 0.6982(4) 0.3684(2) 0.45206(19) 0.0408(17) Uani 1 1 d . . . . .
H3E H 0.7302 0.3451 0.4409 0.049 Uiso 1 1 calc R U . . .
C3A C 0.2719(3) 0.12577(19) 0.45920(17) 0.0296(11) Uani 1 1 d . . . . .
H3A H 0.2325 0.1482 0.4518 0.036 Uiso 1 1 calc R U . . .
C61S C 0.2974(4) 0.3543(3) 0.6433(2) 0.0489(17) Uani 1 1 d . . . . .
C2I C 0.6090(3) 0.3803(2) 0.77068(17) 0.0285(12) Uani 1 1 d . . . . .
HZ H 0.6205 0.4118 0.7654 0.034 Uiso 1 1 calc R U . . .
O31 O 0.5165(10) 0.2132(3) 0.59554(19) 0.040(3) Uani 0.67(3) 1 d D . P B 1
N21 N 0.3106(3) 0.2536(2) 0.55531(12) 0.0339(10) Uani 1 1 d . . . . .
C5H C 0.9156(3) 0.2839(2) 0.78261(18) 0.0303(12) Uani 1 1 d . . . . .
H1 H 0.9228 0.2516 0.7861 0.036 Uiso 1 1 calc R U . . .
C3J C 0.8240(4) 0.6580(3) 0.64060(18) 0.0447(16) Uani 1 1 d . . . . .
H2 H 0.8503 0.6450 0.6209 0.054 Uiso 1 1 calc R U . . .
C2H C 0.8959(3) 0.3764(2) 0.77315(15) 0.0249(11) Uani 1 1 d . . . . .
H3 H 0.8872 0.4086 0.7694 0.030 Uiso 1 1 calc R U . . .
N6S N 0.2432(4) 0.33804(19) 0.65815(16) 0.0555(15) Uani 1 1 d . . . . .
C3G C 0.8007(5) 0.3323(2) 0.63520(16) 0.0506(19) Uani 1 1 d . . . . .
H4 H 0.8273 0.3467 0.6161 0.061 Uiso 1 1 calc R U . . .
C2E C 0.6316(4) 0.3566(2) 0.47297(16) 0.0293(12) Uani 1 1 d . . . . .
H2E H 0.6176 0.3250 0.4768 0.035 Uiso 1 1 calc R U . . .
C2G C 0.7963(4) 0.3541(2) 0.66664(15) 0.0347(13) Uani 1 1 d . . . . .
H5 H 0.8194 0.3841 0.6697 0.042 Uiso 1 1 calc R U . . .
C2A C 0.3377(4) 0.1386(2) 0.48042(16) 0.0273(11) Uani 1 1 d . . . . .
H2A H 0.3441 0.1698 0.4878 0.033 Uiso 1 1 calc R U . . .
C4B C 0.7068(4) 0.0789(2) 0.45142(17) 0.0348(14) Uani 1 1 d . . . . .
H4B H 0.7531 0.0685 0.4382 0.042 Uiso 1 1 calc R U . . .
C4D C 0.2724(4) 0.4227(2) 0.45500(17) 0.0342(13) Uani 1 1 d . . . . .
H4D H 0.2269 0.4329 0.4413 0.041 Uiso 1 1 calc R U . . .
C5F C 0.5112(6) 0.4801(2) 0.58319(18) 0.052(2) Uani 1 1 d . . . . .
H5F H 0.4968 0.5121 0.5836 0.063 Uiso 1 1 calc R U . . .
C4I C 0.5264(4) 0.3223(2) 0.79726(19) 0.0367(15) Uani 1 1 d . . . . .
H6 H 0.4790 0.3130 0.8102 0.044 Uiso 1 1 calc R U . . .
O83 O 0.7702(5) 0.4710(3) 0.81575(13) 0.110(3) Uani 1 1 d . . . . .
C5G C 0.7307(6) 0.2672(2) 0.66094(18) 0.063(2) Uani 1 1 d . . . . .
H7 H 0.7096 0.2366 0.6589 0.075 Uiso 1 1 calc R U . . .
C4G C 0.7653(7) 0.2887(3) 0.63209(17) 0.069(3) Uani 1 1 d . . . . .
H8 H 0.7647 0.2735 0.6104 0.082 Uiso 1 1 calc R U . . .
C5B C 0.6546(4) 0.0471(2) 0.46712(18) 0.0333(14) Uani 1 1 d . . . . .
H5B H 0.6660 0.0150 0.4642 0.040 Uiso 1 1 calc R U . . .
C5I C 0.5821(4) 0.2895(2) 0.7853(2) 0.0354(14) Uani 1 1 d . . . . .
H9 H 0.5729 0.2579 0.7910 0.043 Uiso 1 1 calc R U . . .
C52S C 0.6014(5) 0.0733(3) 0.3683(2) 0.058(2) Uani 1 1 d . . . . .
H H 0.5862 0.0643 0.3448 0.086 Uiso 1 1 calc R U . . .
HA H 0.6252 0.0465 0.3804 0.086 Uiso 1 1 calc R U . . .
HB H 0.6426 0.0983 0.3675 0.086 Uiso 1 1 calc R U . . .
C3D C 0.2779(4) 0.3768(2) 0.46486(17) 0.0335(13) Uani 1 1 d . . . . .
H3D H 0.2360 0.3552 0.4586 0.040 Uiso 1 1 calc R U . . .
C3K C 0.5433(4) 0.6120(2) 0.78983(17) 0.0317(12) Uani 1 1 d . . . . .
H10 H 0.5057 0.5888 0.7976 0.038 Uiso 1 1 calc R U . . .
C4A C 0.2644(4) 0.0805(2) 0.44903(16) 0.0314(12) Uani 1 1 d . . . . .
H4A H 0.2201 0.0711 0.4344 0.038 Uiso 1 1 calc R U . . .
C2D C 0.3467(3) 0.3632(2) 0.48431(16) 0.0287(12) Uani 1 1 d . . . . .
H2D H 0.3532 0.3319 0.4914 0.034 Uiso 1 1 calc R U . . .
C4K C 0.5301(4) 0.6575(2) 0.79827(18) 0.0347(14) Uani 1 1 d . . . . .
H11 H 0.4829 0.6665 0.8114 0.042 Uiso 1 1 calc R U . . .
C2J C 0.8087(4) 0.6316(2) 0.66977(15) 0.0357(13) Uani 1 1 d . . . . .
H12 H 0.8238 0.5998 0.6703 0.043 Uiso 1 1 calc R U . . .
C1C C 0.4928(4) 0.08907(15) 0.55461(13) 0.0233(9) Uani 1 1 d . . . . .
C5J C 0.7634(5) 0.7216(2) 0.66978(15) 0.0491(18) Uani 1 1 d . . . . .
H13 H 0.7472 0.7532 0.6696 0.059 Uiso 1 1 calc R U . . .
C42S C 0.5863(6) 0.2120(4) 0.3919(3) 0.082(3) Uani 1 1 d . . . . .
HC H 0.6203 0.1923 0.3768 0.123 Uiso 1 1 calc R U . . .
HD H 0.5336 0.1962 0.3970 0.123 Uiso 1 1 calc R U . . .
HE H 0.6165 0.2178 0.4134 0.123 Uiso 1 1 calc R U . . .
O13 O 0.4518(4) 0.2549(4) 0.43514(13) 0.117(3) Uani 1 1 d . . . . .
N5S N 0.4708(6) 0.1005(3) 0.3995(3) 0.095(3) Uani 1 1 d . . . . .
C3I C 0.5401(4) 0.3685(2) 0.79020(19) 0.0354(14) Uani 1 1 d . . . . .
H14 H 0.5032 0.3917 0.7986 0.042 Uiso 1 1 calc R U . . .
C5A C 0.3233(3) 0.04861(18) 0.46068(19) 0.0295(12) Uani 1 1 d . . . . .
H5A H 0.3171 0.0171 0.4541 0.035 Uiso 1 1 calc R U . . .
C1F C 0.5157(4) 0.41083(16) 0.55491(14) 0.0277(11) Uani 1 1 d . . . . .
C1A C 0.3933(3) 0.10481(19) 0.49043(15) 0.0216(10) Uani 1 1 d . . . . .
C1K C 0.6660(3) 0.63440(18) 0.75993(15) 0.0220(10) Uani 1 1 d . . . . .
C4E C 0.7171(4) 0.4144(2) 0.44776(19) 0.0418(17) Uani 1 1 d . . . . .
H4E H 0.7637 0.4234 0.4343 0.050 Uiso 1 1 calc R U . . .
C5E C 0.6674(4) 0.4474(2) 0.4634(2) 0.0367(14) Uani 1 1 d . . . . .
H5E H 0.6803 0.4791 0.4596 0.044 Uiso 1 1 calc R U . . .
C1H C 0.8420(3) 0.34370(18) 0.75932(15) 0.0209(10) Uani 1 1 d . . . . .
C3B C 0.6915(4) 0.1259(2) 0.45493(17) 0.0339(13) Uani 1 1 d . . . . .
H3B H 0.7271 0.1482 0.4446 0.041 Uiso 1 1 calc R U . . .
C5D C 0.3335(4) 0.45363(19) 0.46515(19) 0.0322(13) Uani 1 1 d . . . . .
H5D H 0.3282 0.4852 0.4586 0.039 Uiso 1 1 calc R U . . .
N3S N 0.2285(6) 0.3569(3) 0.3571(3) 0.102(3) Uani 1 1 d . . . . .
C51S C 0.5286(6) 0.0889(3) 0.3862(2) 0.064(2) Uani 1 1 d . . . . .
C32S C 0.3608(7) 0.3283(4) 0.3883(3) 0.098(4) Uani 1 1 d . . . . .
HF H 0.3964 0.3129 0.3712 0.147 Uiso 1 1 calc R U . . .
HG H 0.3467 0.3064 0.4066 0.147 Uiso 1 1 calc R U . . .
HH H 0.3906 0.3548 0.3981 0.147 Uiso 1 1 calc R U . . .
C5K C 0.5876(4) 0.6899(2) 0.7871(2) 0.0355(14) Uani 1 1 d . . . . .
H15 H 0.5785 0.7214 0.7930 0.043 Uiso 1 1 calc R U . . .
C31S C 0.2859(7) 0.3441(3) 0.3719(3) 0.074(3) Uani 1 1 d . . . . .
C12S C 0.3514(7) 0.4591(3) 0.3480(2) 0.076(3) Uani 1 1 d . . . . .
HI H 0.3791 0.4794 0.3313 0.113 Uiso 1 1 calc R U . . .
HJ H 0.3084 0.4408 0.3363 0.113 Uiso 1 1 calc R U . . .
HK H 0.3926 0.4382 0.3584 0.113 Uiso 1 1 calc R U . . .
C41S C 0.5701(7) 0.2536(6) 0.3755(2) 0.121(5) Uani 1 1 d . . . . .
C11S C 0.3136(8) 0.4868(3) 0.3745(2) 0.082(3) Uani 1 1 d . . . . .
O62 O 0.7170(6) 0.5294(2) 0.65772(17) 0.032(2) Uani 0.618(19) 1 d D . P A 1
C1E C 0.5859(3) 0.39176(19) 0.48813(16) 0.0236(11) Uani 1 1 d . . . . .
N2S N 0.4993(10) 0.4049(5) 0.4007(4) 0.183(7) Uiso 1 1 d D . . . .
N1S N 0.2825(9) 0.5076(4) 0.3950(2) 0.139(5) Uani 1 1 d . . . . .
N4S N 0.5624(10) 0.2876(7) 0.3627(4) 0.250(12) Uani 1 1 d . . . . .
C62S C 0.3652(6) 0.3750(4) 0.6248(3) 0.103(4) Uani 1 1 d . . . . .
HL H 0.3520 0.3755 0.6001 0.154 Uiso 1 1 calc R U . . .
HM H 0.4161 0.3569 0.6285 0.154 Uiso 1 1 calc R U . . .
HN H 0.3739 0.4067 0.6330 0.154 Uiso 1 1 calc R U . . .
C21S C 0.5522(9) 0.4059(5) 0.3805(4) 0.118(5) Uiso 1 1 d D . . . .
C22S C 0.6253(9) 0.3892(5) 0.3634(4) 0.151(6) Uiso 1 1 d D . . . .
HO H 0.6267 0.4012 0.3398 0.227 Uiso 1 1 calc R U . . .
HP H 0.6242 0.3553 0.3628 0.227 Uiso 1 1 calc R U . . .
HQ H 0.6749 0.3996 0.3759 0.227 Uiso 1 1 calc R U . . .
O61' O 0.7257(11) 0.4599(4) 0.6535(3) 0.030(3) Uani 0.382(19) 1 d D . P A 2
O62' O 0.7794(10) 0.5278(4) 0.6552(3) 0.031(4) Uani 0.382(19) 1 d D . P A 2
O31' O 0.4727(13) 0.2132(5) 0.5962(3) 0.024(4) Uani 0.33(3) 1 d D . P B 2
O32' O 0.5271(14) 0.2813(5) 0.5962(3) 0.027(5) Uani 0.33(3) 1 d D . P B 2
O52' O 0.6066(9) 0.5207(8) 0.7173(5) 0.029(4) Uani 0.39(7) 1 d D . P A 2
O51' O 0.6166(10) 0.4544(6) 0.6941(8) 0.023(4) Uani 0.39(7) 1 d D . P A 2
O41 O 0.6295(7) 0.2110(5) 0.5372(6) 0.032(3) Uani 0.57(6) 1 d D . P B 1
O41' O 0.6258(8) 0.2100(5) 0.5510(10) 0.031(5) Uani 0.43(6) 1 d D . P B 2
O42' O 0.6364(8) 0.2820(4) 0.5387(11) 0.033(6) Uani 0.43(6) 1 d D . P B 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Tb1 O2 2.334(3) . ?
Tb1 O1 2.327(3) . ?
Tb1 O12 2.425(3) . ?
Tb1 O11 2.481(4) . ?
Tb1 O21 2.496(5) . ?
Tb1 O22 2.547(5) . ?
Tb1 O32 2.486(7) . ?
Tb1 O42 2.491(8) . ?
Tb1 O31 2.476(7) . ?
Tb1 O31' 2.477(12) . ?
Tb1 O32' 2.485(11) . ?
Tb1 O41 2.504(11) . ?
Tb1 O41' 2.509(13) . ?
Tb1 O42' 2.535(11) . ?
Tb2 O4 2.327(3) . ?
Tb2 O3 2.331(3) . ?
Tb2 O82 2.445(4) . ?
Tb2 O51 2.512(11) . ?
Tb2 O71 2.521(5) . ?
Tb2 O81 2.469(4) . ?
Tb2 O61 2.521(7) . ?
Tb2 O72 2.473(5) . ?
Tb2 O52 2.499(10) . ?
Tb2 O62 2.472(7) . ?
Tb2 O61' 2.491(11) . ?
Tb2 O62' 2.504(10) . ?
Tb2 O52' 2.519(15) . ?
Tb2 O51' 2.529(15) . ?
Ag1 N1A 2.407(5) . ?
Ag1 N1A 2.407(5) 4_556 ?
Ag1 N1B 2.504(5) . ?
Ag1 N1B 2.504(5) 4_556 ?
Ag1 N1C 2.665(6) 4_556 ?
Ag1 N1C 2.665(6) . ?
Ag2 N1D 2.473(5) 4_566 ?
Ag2 N1D 2.473(5) . ?
Ag2 N1E 2.482(5) 4_566 ?
Ag2 N1E 2.483(5) . ?
Ag2 N1F 2.484(5) . ?
Ag2 N1F 2.484(5) 4_566 ?
Ag3 N1H 2.509(5) . ?
Ag3 N1O 2.469(5) 7_646 ?
Ag3 N1I 2.445(5) . ?
Ag3 N1K 2.456(5) 7_646 ?
Ag3 N1G 2.539(5) . ?
Ag3 N1J 2.522(4) 7_646 ?
P3 O3 1.486(3) . ?
P3 C1I 1.816(5) . ?
P3 C1G 1.817(5) . ?
P3 C1H 1.801(6) . ?
P4 O4 1.487(3) . ?
P4 C1O 1.815(5) . ?
P4 C1J 1.809(5) . ?
P4 C1K 1.804(5) . ?
P1 O1 1.488(3) . ?
P1 C1B 1.821(6) . ?
P1 C1C 1.810(5) . ?
P1 C1A 1.806(6) . ?
P2 O2 1.488(3) . ?
P2 C1D 1.817(6) . ?
P2 C1F 1.816(6) . ?
P2 C1E 1.808(6) . ?
O73 N71 1.210(6) . ?
O63 N61 1.226(6) . ?
O82 N81 1.252(7) . ?
N61 O61 1.233(8) . ?
N61 O62 1.302(8) . ?
N61 O61' 1.277(12) . ?
N61 O62' 1.243(11) . ?
N31 O33 1.206(6) . ?
N31 O32 1.288(9) . ?
N31 O31 1.256(8) . ?
N31 O31' 1.301(14) . ?
N31 O32' 1.249(13) . ?
O12 N11 1.267(6) . ?
C1B C2B 1.376(8) . ?
C1B N1B 1.343(7) . ?
C1O N1O 1.328(7) . ?
C1O C2O 1.376(8) . ?
C1D N1D 1.332(7) . ?
C1D C2D 1.390(8) . ?
C1I N1I 1.341(7) . ?
C1I C2I 1.383(8) . ?
N1H C5H 1.316(8) . ?
N1H C1H 1.354(7) . ?
O51 N51 1.242(13) . ?
N71 O71 1.236(7) . ?
N71 O72 1.269(7) . ?
O11 N11 1.275(6) . ?
N1O Ag3 2.469(5) 7_656 ?
N1O C5O 1.348(8) . ?
O81 N81 1.282(7) . ?
N1A C5A 1.324(7) . ?
N1A C1A 1.356(7) . ?
O43 N41 1.212(6) . ?
N1I C5I 1.341(8) . ?
C3H HR 0.9500 . ?
C3H C4H 1.384(8) . ?
C3H C2H 1.387(8) . ?
N11 O13 1.205(6) . ?
N1K Ag3 2.456(5) 7_656 ?
N1K C1K 1.363(7) . ?
N1K C5K 1.326(8) . ?
N51 O53 1.216(6) . ?
N51 O52 1.289(18) . ?
N51 O52' 1.224(17) . ?
N51 O51' 1.276(15) . ?
C2B H2B 0.9500 . ?
C2B C3B 1.400(8) . ?
O23 N21 1.224(6) . ?
O21 N21 1.253(7) . ?
N1D C5D 1.342(8) . ?
N41 O42 1.284(10) . ?
N41 O41 1.269(12) . ?
N41 O41' 1.245(14) . ?
N41 O42' 1.270(12) . ?
O22 N21 1.238(7) . ?
N1B C5B 1.336(8) . ?
N1E C5E 1.328(8) . ?
N1E C1E 1.356(7) . ?
C4C H4C 0.9500 . ?
C4C C3C 1.385(9) . ?
C4C C5C 1.380(10) . ?
C2F H2F 0.9500 . ?
C2F C3F 1.382(8) . ?
C2F C1F 1.376(8) . ?
C4F H4F 0.9500 . ?
C4F C3F 1.366(9) . ?
C4F C5F 1.373(10) . ?
N1C C5C 1.361(8) . ?
N1C C1C 1.331(7) . ?
C2O HS 0.9500 . ?
C2O C3O 1.392(8) . ?
C3F H3F 0.9500 . ?
C4J HT 0.9500 . ?
C4J C3J 1.375(10) . ?
C4J C5J 1.359(10) . ?
C4H HU 0.9500 . ?
C4H C5H 1.390(8) . ?
C2C H2C 0.9500 . ?
C2C C3C 1.390(9) . ?
C2C C1C 1.377(8) . ?
C5O HV 0.9500 . ?
C5O C4O 1.377(9) . ?
C3C H3C 0.9500 . ?
C4O HW 0.9500 . ?
C4O C3O 1.379(9) . ?
C1J N1J 1.336(6) . ?
C1J C2J 1.370(7) . ?
N1G C1G 1.341(7) . ?
N1G C5G 1.333(8) . ?
N81 O83 1.234(6) . ?
C3O HX 0.9500 . ?
N1J Ag3 2.522(4) 7_656 ?
N1J C5J 1.348(7) . ?
C2K HY 0.9500 . ?
C2K C3K 1.378(8) . ?
C2K C1K 1.383(8) . ?
C5C H5C 0.9500 . ?
N1F C5F 1.331(8) . ?
N1F C1F 1.342(6) . ?
C1G C2G 1.380(8) . ?
C3E H3E 0.9500 . ?
C3E C2E 1.384(8) . ?
C3E C4E 1.373(10) . ?
C3A H3A 0.9500 . ?
C3A C2A 1.389(8) . ?
C3A C4A 1.371(8) . ?
C61S N6S 1.142(9) . ?
C61S C62S 1.436(11) . ?
C2I HZ 0.9500 . ?
C2I C3I 1.383(8) . ?
C5H H1 0.9500 . ?
C3J H2 0.9500 . ?
C3J C2J 1.388(9) . ?
C2H H3 0.9500 . ?
C2H C1H 1.389(8) . ?
C3G H4 0.9500 . ?
C3G C2G 1.375(8) . ?
C3G C4G 1.385(10) . ?
C2E H2E 0.9500 . ?
C2E C1E 1.384(8) . ?
C2G H5 0.9500 . ?
C2A H2A 0.9500 . ?
C2A C1A 1.379(8) . ?
C4B H4B 0.9500 . ?
C4B C5B 1.384(9) . ?
C4B C3B 1.386(9) . ?
C4D H4D 0.9500 . ?
C4D C3D 1.381(8) . ?
C4D C5D 1.384(8) . ?
C5F H5F 0.9500 . ?
C4I H6 0.9500 . ?
C4I C5I 1.382(9) . ?
C4I C3I 1.381(9) . ?
C5G H7 0.9500 . ?
C5G C4G 1.396(11) . ?
C4G H8 0.9500 . ?
C5B H5B 0.9500 . ?
C5I H9 0.9500 . ?
C52S H 0.9800 . ?
C52S HA 0.9800 . ?
C52S HB 0.9800 . ?
C52S C51S 1.432(13) . ?
C3D H3D 0.9500 . ?
C3D C2D 1.393(8) . ?
C3K H10 0.9500 . ?
C3K C4K 1.370(9) . ?
C4A H4A 0.9500 . ?
C4A C5A 1.394(8) . ?
C2D H2D 0.9500 . ?
C4K H11 0.9500 . ?
C4K C5K 1.384(9) . ?
C2J H12 0.9500 . ?
C5J H13 0.9500 . ?
C42S HC 0.9800 . ?
C42S HD 0.9800 . ?
C42S HE 0.9800 . ?
C42S C41S 1.385(16) . ?
N5S C51S 1.114(12) . ?
C3I H14 0.9500 . ?
C5A H5A 0.9500 . ?
C4E H4E 0.9500 . ?
C4E C5E 1.382(9) . ?
C5E H5E 0.9500 . ?
C3B H3B 0.9500 . ?
C5D H5D 0.9500 . ?
N3S C31S 1.147(13) . ?
C32S HF 0.9800 . ?
C32S HG 0.9800 . ?
C32S HH 0.9800 . ?
C32S C31S 1.434(14) . ?
C5K H15 0.9500 . ?
C12S HI 0.9800 . ?
C12S HJ 0.9800 . ?
C12S HK 0.9800 . ?
C12S C11S 1.436(11) . ?
C41S N4S 1.106(19) . ?
C11S N1S 1.116(12) . ?
N2S C21S 1.155(6) . ?
C62S HL 0.9800 . ?
C62S HM 0.9800 . ?
C62S HN 0.9800 . ?
C21S C22S 1.431(6) . ?
C22S HO 0.9800 . ?
C22S HP 0.9800 . ?
C22S HQ 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Tb1 O12 77.02(15) . . ?
O2 Tb1 O11 74.84(15) . . ?
O2 Tb1 O21 117.86(15) . . ?
O2 Tb1 O22 69.42(15) . . ?
O2 Tb1 O32 81.42(18) . . ?
O2 Tb1 O42 71.2(4) . . ?
O2 Tb1 O31 129.1(2) . . ?
O2 Tb1 O31' 130.2(3) . . ?
O2 Tb1 O32' 82.2(3) . . ?
O2 Tb1 O41 112.5(5) . . ?
O2 Tb1 O41' 116.7(3) . . ?
O2 Tb1 O42' 66.5(3) . . ?
O1 Tb1 O2 148.43(12) . . ?
O1 Tb1 O12 76.68(14) . . ?
O1 Tb1 O11 75.34(15) . . ?
O1 Tb1 O21 70.06(16) . . ?
O1 Tb1 O22 116.83(16) . . ?
O1 Tb1 O32 129.90(18) . . ?
O1 Tb1 O42 118.0(2) . . ?
O1 Tb1 O31 81.8(2) . . ?
O1 Tb1 O31' 81.2(3) . . ?
O1 Tb1 O32' 128.5(3) . . ?
O1 Tb1 O41 67.0(3) . . ?
O1 Tb1 O41' 70.1(5) . . ?
O1 Tb1 O42' 113.4(5) . . ?
O12 Tb1 O11 52.24(13) . . ?
O12 Tb1 O21 73.26(18) . . ?
O12 Tb1 O22 70.52(18) . . ?
O12 Tb1 O32 134.2(3) . . ?
O12 Tb1 O42 134.8(6) . . ?
O12 Tb1 O31 148.4(4) . . ?
O12 Tb1 O31' 134.7(5) . . ?
O12 Tb1 O32' 150.2(5) . . ?
O12 Tb1 O41 119.3(5) . . ?
O12 Tb1 O41' 130.8(9) . . ?
O12 Tb1 O42' 119.9(9) . . ?
O11 Tb1 O21 120.45(18) . . ?
O11 Tb1 O22 117.46(18) . . ?
O11 Tb1 O32 152.9(3) . . ?
O11 Tb1 O42 88.3(6) . . ?
O11 Tb1 O32' 140.5(4) . . ?
O11 Tb1 O41 72.0(6) . . ?
O11 Tb1 O41' 84.4(9) . . ?
O11 Tb1 O42' 72.5(10) . . ?
O21 Tb1 O22 49.59(13) . . ?
O21 Tb1 O41 129.6(4) . . ?
O21 Tb1 O41' 124.1(4) . . ?
O21 Tb1 O42' 166.6(9) . . ?
O32 Tb1 O21 82.2(4) . . ?
O32 Tb1 O22 64.1(4) . . ?
O32 Tb1 O42 71.5(6) . . ?
O32 Tb1 O41 106.2(6) . . ?
O42 Tb1 O21 150.9(6) . . ?
O42 Tb1 O22 123.6(3) . . ?
O42 Tb1 O41 51.1(3) . . ?
O31 Tb1 O11 142.0(3) . . ?
O31 Tb1 O21 77.8(4) . . ?
O31 Tb1 O22 99.8(4) . . ?
O31 Tb1 O32 51.3(3) . . ?
O31 Tb1 O42 76.1(7) . . ?
O31 Tb1 O41 71.3(7) . . ?
O31' Tb1 O11 152.7(4) . . ?
O31' Tb1 O21 62.1(5) . . ?
O31' Tb1 O22 85.5(5) . . ?
O31' Tb1 O32' 51.4(4) . . ?
O31' Tb1 O41' 74.6(9) . . ?
O31' Tb1 O42' 105.1(9) . . ?
O32' Tb1 O21 98.6(5) . . ?
O32' Tb1 O22 82.4(6) . . ?
O32' Tb1 O41' 77.8(10) . . ?
O32' Tb1 O42' 68.9(11) . . ?
O41 Tb1 O22 170.1(6) . . ?
O41' Tb1 O22 157.9(9) . . ?
O41' Tb1 O42' 50.2(4) . . ?
O42' Tb1 O22 129.7(5) . . ?
O4 Tb2 O3 148.34(11) . . ?
O4 Tb2 O82 77.29(14) . . ?
O4 Tb2 O51 118.0(4) . . ?
O4 Tb2 O71 116.52(15) . . ?
O4 Tb2 O81 77.06(14) . . ?
O4 Tb2 O61 125.2(2) . . ?
O4 Tb2 O72 69.44(15) . . ?
O4 Tb2 O52 70.6(3) . . ?
O4 Tb2 O62 78.87(17) . . ?
O4 Tb2 O61' 126.8(3) . . ?
O4 Tb2 O62' 80.0(3) . . ?
O4 Tb2 O52' 70.9(4) . . ?
O4 Tb2 O51' 119.9(3) . . ?
O3 Tb2 O82 74.41(14) . . ?
O3 Tb2 O51 67.5(3) . . ?
O3 Tb2 O71 67.86(15) . . ?
O3 Tb2 O81 74.61(14) . . ?
O3 Tb2 O61 85.88(19) . . ?
O3 Tb2 O72 116.32(16) . . ?
O3 Tb2 O52 116.6(6) . . ?
O3 Tb2 O62 132.09(18) . . ?
O3 Tb2 O61' 84.6(3) . . ?
O3 Tb2 O62' 130.7(3) . . ?
O3 Tb2 O52' 108.7(6) . . ?
O3 Tb2 O51' 71.7(5) . . ?
O82 Tb2 O51 121.5(7) . . ?
O82 Tb2 O71 72.97(17) . . ?
O82 Tb2 O81 52.49(13) . . ?
O82 Tb2 O61 137.9(2) . . ?
O82 Tb2 O72 76.4(2) . . ?
O82 Tb2 O52 126.5(11) . . ?
O82 Tb2 O62 151.2(2) . . ?
O82 Tb2 O61' 150.5(4) . . ?
O82 Tb2 O62' 134.2(3) . . ?
O82 Tb2 O52' 114.6(4) . . ?
O82 Tb2 O51' 131.6(8) . . ?
O51 Tb2 O71 125.4(5) . . ?
O51 Tb2 O61 81.9(8) . . ?
O71 Tb2 O61 65.2(3) . . ?
O71 Tb2 O51' 122.0(3) . . ?
O81 Tb2 O51 75.2(8) . . ?
O81 Tb2 O71 120.00(17) . . ?
O81 Tb2 O61 154.2(3) . . ?
O81 Tb2 O72 123.7(2) . . ?
O81 Tb2 O52 78.9(12) . . ?
O81 Tb2 O62 135.6(2) . . ?
O81 Tb2 O61' 140.7(4) . . ?
O81 Tb2 O62' 153.2(3) . . ?
O81 Tb2 O52' 65.3(5) . . ?
O81 Tb2 O51' 85.5(7) . . ?
O72 Tb2 O51 161.0(8) . . ?
O72 Tb2 O71 49.79(13) . . ?
O72 Tb2 O61 79.9(3) . . ?
O72 Tb2 O52 126.3(8) . . ?
O72 Tb2 O61' 95.3(4) . . ?
O72 Tb2 O62' 58.5(4) . . ?
O72 Tb2 O52' 134.9(6) . . ?
O72 Tb2 O51' 150.6(8) . . ?
O52 Tb2 O51 50.4(4) . . ?
O52 Tb2 O71 160.3(12) . . ?
O52 Tb2 O61 95.5(11) . . ?
O62 Tb2 O51 84.2(7) . . ?
O62 Tb2 O71 104.1(2) . . ?
O62 Tb2 O61 51.3(2) . . ?
O62 Tb2 O72 80.2(3) . . ?
O62 Tb2 O52 57.9(12) . . ?
O61' Tb2 O71 80.1(4) . . ?
O61' Tb2 O62' 50.8(4) . . ?
O61' Tb2 O52' 91.5(5) . . ?
O61' Tb2 O51' 56.1(8) . . ?
O62' Tb2 O71 82.8(4) . . ?
O62' Tb2 O52' 94.2(7) . . ?
O62' Tb2 O51' 94.2(8) . . ?
O52' Tb2 O71 171.1(3) . . ?
O52' Tb2 O51' 49.7(5) . . ?
N1A Ag1 N1A 103.3(2) 4_556 . ?
N1A Ag1 N1B 82.66(14) . . ?
N1A Ag1 N1B 82.65(14) 4_556 4_556 ?
N1A Ag1 N1B 172.53(18) 4_556 . ?
N1A Ag1 N1B 172.54(18) . 4_556 ?
N1A Ag1 N1C 77.89(17) 4_556 4_556 ?
N1A Ag1 N1C 90.95(16) 4_556 . ?
N1A Ag1 N1C 77.88(16) . . ?
N1A Ag1 N1C 90.96(16) . 4_556 ?
N1B Ag1 N1B 91.8(2) 4_556 . ?
N1B Ag1 N1C 85.89(16) 4_556 4_556 ?
N1B Ag1 N1C 85.89(16) . . ?
N1B Ag1 N1C 106.77(16) . 4_556 ?
N1B Ag1 N1C 106.77(16) 4_556 . ?
N1C Ag1 N1C 162.1(3) 4_556 . ?
N1D Ag2 N1D 94.4(2) 4_566 . ?
N1D Ag2 N1E 176.51(17) 4_566 . ?
N1D Ag2 N1E 82.11(15) 4_566 4_566 ?
N1D Ag2 N1E 176.51(17) . 4_566 ?
N1D Ag2 N1E 82.10(15) . . ?
N1D Ag2 N1F 79.71(19) 4_566 4_566 ?
N1D Ag2 N1F 95.49(18) 4_566 . ?
N1D Ag2 N1F 79.71(19) . . ?
N1D Ag2 N1F 95.48(18) . 4_566 ?
N1E Ag2 N1E 101.4(2) 4_566 . ?
N1E Ag2 N1F 83.60(18) 4_566 4_566 ?
N1E Ag2 N1F 83.60(18) . . ?
N1E Ag2 N1F 100.89(19) . 4_566 ?
N1E Ag2 N1F 100.89(19) 4_566 . ?
N1F Ag2 N1F 173.0(3) 4_566 . ?
N1H Ag3 N1G 86.84(17) . . ?
N1H Ag3 N1J 92.92(17) . 7_646 ?
N1O Ag3 N1H 175.02(17) 7_646 . ?
N1O Ag3 N1G 96.87(17) 7_646 . ?
N1O Ag3 N1J 83.66(17) 7_646 7_646 ?
N1I Ag3 N1H 82.45(13) . . ?
N1I Ag3 N1O 101.47(18) . 7_646 ?
N1I Ag3 N1K 173.5(2) . 7_646 ?
N1I Ag3 N1G 79.12(18) . . ?
N1I Ag3 N1J 96.04(17) . 7_646 ?
N1K Ag3 N1H 93.90(17) 7_646 . ?
N1K Ag3 N1O 81.90(14) 7_646 7_646 ?
N1K Ag3 N1G 106.18(19) 7_646 . ?
N1K Ag3 N1J 78.68(18) 7_646 7_646 ?
N1J Ag3 N1G 175.15(19) 7_646 . ?
O3 P3 C1I 110.7(2) . . ?
O3 P3 C1G 109.5(2) . . ?
O3 P3 C1H 111.0(2) . . ?
C1I P3 C1G 111.7(3) . . ?
C1H P3 C1I 106.9(2) . . ?
C1H P3 C1G 107.0(3) . . ?
O4 P4 C1O 111.5(2) . . ?
O4 P4 C1J 111.0(2) . . ?
O4 P4 C1K 110.1(2) . . ?
C1J P4 C1O 105.8(2) . . ?
C1K P4 C1O 106.4(2) . . ?
C1K P4 C1J 111.8(2) . . ?
O1 P1 C1B 111.3(2) . . ?
O1 P1 C1C 111.0(2) . . ?
O1 P1 C1A 110.3(2) . . ?
C1C P1 C1B 105.8(3) . . ?
C1A P1 C1B 106.4(2) . . ?
C1A P1 C1C 111.9(3) . . ?
O2 P2 C1D 111.2(3) . . ?
O2 P2 C1F 110.5(2) . . ?
O2 P2 C1E 110.9(3) . . ?
C1F P2 C1D 112.1(3) . . ?
C1E P2 C1D 106.6(2) . . ?
C1E P2 C1F 105.3(3) . . ?
P2 O2 Tb1 176.4(2) . . ?
P4 O4 Tb2 175.5(2) . . ?
P3 O3 Tb2 173.6(2) . . ?
P1 O1 Tb1 172.9(2) . . ?
N81 O82 Tb2 95.1(3) . . ?
O63 N61 Tb2 177.3(4) . . ?
O63 N61 O61 122.2(5) . . ?
O63 N61 O62 120.8(5) . . ?
O63 N61 O61' 124.3(6) . . ?
O63 N61 O62' 118.5(6) . . ?
O61 N61 Tb2 59.5(4) . . ?
O61 N61 O62 116.9(6) . . ?
O62 N61 Tb2 57.6(3) . . ?
O61' N61 Tb2 58.4(5) . . ?
O62' N61 Tb2 58.8(5) . . ?
O62' N61 O61' 116.5(8) . . ?
O33 N31 Tb1 178.8(4) . . ?
O33 N31 O32 123.2(6) . . ?
O33 N31 O31 121.6(6) . . ?
O33 N31 O31' 121.8(7) . . ?
O33 N31 O32' 122.9(7) . . ?
O32 N31 Tb1 57.9(3) . . ?
O31 N31 Tb1 57.3(4) . . ?
O31 N31 O32 115.2(6) . . ?
O31' N31 Tb1 57.6(6) . . ?
O32' N31 Tb1 57.7(5) . . ?
O32' N31 O31' 115.1(8) . . ?
N11 O12 Tb1 97.1(3) . . ?
C2B C1B P1 119.0(4) . . ?
N1B C1B P1 116.3(4) . . ?
N1B C1B C2B 124.7(5) . . ?
N1O C1O P4 116.0(4) . . ?
N1O C1O C2O 124.4(5) . . ?
C2O C1O P4 119.6(4) . . ?
N1D C1D P2 117.9(4) . . ?
N1D C1D C2D 124.0(5) . . ?
C2D C1D P2 118.0(4) . . ?
N1I C1I P3 118.5(4) . . ?
N1I C1I C2I 123.4(5) . . ?
C2I C1I P3 118.0(4) . . ?
C5H N1H Ag3 120.0(4) . . ?
C5H N1H C1H 117.1(5) . . ?
C1H N1H Ag3 122.2(4) . . ?
N51 O51 Tb2 97.8(7) . . ?
O73 N71 Tb2 177.0(5) . . ?
O73 N71 O71 124.3(6) . . ?
O73 N71 O72 121.5(6) . . ?
O71 N71 Tb2 58.1(3) . . ?
O71 N71 O72 114.2(4) . . ?
O72 N71 Tb2 56.2(3) . . ?
N11 O11 Tb1 94.3(3) . . ?
C1O N1O Ag3 125.6(4) . 7_656 ?
C1O N1O C5O 117.0(5) . . ?
C5O N1O Ag3 116.9(4) . 7_656 ?
N71 O71 Tb2 97.2(3) . . ?
N81 O81 Tb2 93.1(3) . . ?
C5A N1A Ag1 119.1(4) . . ?
C5A N1A C1A 117.1(5) . . ?
C1A N1A Ag1 123.6(4) . . ?
C1I N1I Ag3 122.2(4) . . ?
C1I N1I C5I 117.3(5) . . ?
C5I N1I Ag3 120.5(4) . . ?
C4H C3H HR 120.4 . . ?
C4H C3H C2H 119.1(6) . . ?
C2H C3H HR 120.4 . . ?
O12 N11 Tb1 56.9(2) . . ?
O12 N11 O11 116.4(4) . . ?
O11 N11 Tb1 59.5(2) . . ?
O13 N11 Tb1 176.3(5) . . ?
O13 N11 O12 119.7(6) . . ?
O13 N11 O11 123.9(6) . . ?
C1K N1K Ag3 122.5(4) . 7_656 ?
C5K N1K Ag3 120.3(4) . 7_656 ?
C5K N1K C1K 117.1(5) . . ?
O51 N51 Tb2 57.6(6) . . ?
O51 N51 O52 114.7(7) . . ?
O53 N51 Tb2 178.6(6) . . ?
O53 N51 O51 121.6(8) . . ?
O53 N51 O52 123.7(7) . . ?
O53 N51 O52' 122.4(9) . . ?
O53 N51 O51' 121.2(9) . . ?
O52 N51 Tb2 57.2(5) . . ?
O52' N51 Tb2 57.8(7) . . ?
O52' N51 O51' 116.1(10) . . ?
O51' N51 Tb2 58.5(7) . . ?
N61 O61 Tb2 95.5(4) . . ?
N71 O72 Tb2 98.6(3) . . ?
C1B C2B H2B 121.0 . . ?
C1B C2B C3B 118.1(5) . . ?
C3B C2B H2B 121.0 . . ?
N21 O21 Tb1 98.0(3) . . ?
C1D N1D Ag2 123.5(4) . . ?
C1D N1D C5D 117.3(5) . . ?
C5D N1D Ag2 119.3(4) . . ?
O43 N41 Tb1 177.9(4) . . ?
O43 N41 O42 122.4(6) . . ?
O43 N41 O41 122.5(7) . . ?
O43 N41 O41' 121.3(8) . . ?
O43 N41 O42' 121.8(7) . . ?
O42 N41 Tb1 57.3(4) . . ?
O41 N41 Tb1 57.8(5) . . ?
O41 N41 O42 115.1(7) . . ?
O41' N41 Tb1 57.9(6) . . ?
O41' N41 O42' 116.7(9) . . ?
O42' N41 Tb1 59.2(5) . . ?
N21 O22 Tb1 96.0(3) . . ?
C1B N1B Ag1 122.1(4) . . ?
C5B N1B Ag1 119.0(4) . . ?
C5B N1B C1B 116.6(5) . . ?
C5E N1E Ag2 119.3(4) . . ?
C5E N1E C1E 116.5(5) . . ?
C1E N1E Ag2 123.1(4) . . ?
C3C C4C H4C 120.6 . . ?
C5C C4C H4C 120.6 . . ?
C5C C4C C3C 118.8(6) . . ?
C3F C2F H2F 120.8 . . ?
C1F C2F H2F 120.8 . . ?
C1F C2F C3F 118.4(5) . . ?
C3F C4F H4F 120.5 . . ?
C3F C4F C5F 118.9(6) . . ?
C5F C4F H4F 120.5 . . ?
C5C N1C Ag1 117.4(4) . . ?
C1C N1C Ag1 108.7(4) . . ?
C1C N1C C5C 116.3(5) . . ?
C1O C2O HS 121.1 . . ?
C1O C2O C3O 117.7(5) . . ?
C3O C2O HS 121.1 . . ?
C2F C3F H3F 120.4 . . ?
C4F C3F C2F 119.1(6) . . ?
C4F C3F H3F 120.4 . . ?
C3J C4J HT 120.1 . . ?
C5J C4J HT 120.1 . . ?
C5J C4J C3J 119.8(6) . . ?
C3H C4H HU 121.0 . . ?
C3H C4H C5H 118.1(6) . . ?
C5H C4H HU 121.0 . . ?
C3C C2C H2C 120.7 . . ?
C1C C2C H2C 120.7 . . ?
C1C C2C C3C 118.6(5) . . ?
N1O C5O HV 118.6 . . ?
N1O C5O C4O 122.8(6) . . ?
C4O C5O HV 118.6 . . ?
C4C C3C C2C 118.5(6) . . ?
C4C C3C H3C 120.8 . . ?
C2C C3C H3C 120.8 . . ?
C5O C4O HW 120.5 . . ?
C5O C4O C3O 119.1(6) . . ?
C3O C4O HW 120.5 . . ?
N1J C1J P4 118.1(4) . . ?
N1J C1J C2J 122.9(5) . . ?
C2J C1J P4 118.8(4) . . ?
C1G N1G Ag3 114.5(4) . . ?
C5G N1G Ag3 118.2(5) . . ?
C5G N1G C1G 117.7(6) . . ?
O82 N81 Tb2 58.9(3) . . ?
O82 N81 O81 118.1(4) . . ?
O81 N81 Tb2 60.1(2) . . ?
O83 N81 Tb2 169.0(6) . . ?
O83 N81 O82 122.5(6) . . ?
O83 N81 O81 119.4(6) . . ?
C2O C3O HX 120.6 . . ?
C4O C3O C2O 118.9(6) . . ?
C4O C3O HX 120.6 . . ?
N31 O32 Tb1 96.0(4) . . ?
C1J N1J Ag3 119.0(3) . 7_656 ?
C1J N1J C5J 117.2(5) . . ?
C5J N1J Ag3 115.7(4) . 7_656 ?
N41 O42 Tb1 97.0(5) . . ?
C3K C2K HY 120.6 . . ?
C3K C2K C1K 118.7(6) . . ?
C1K C2K HY 120.6 . . ?
N51 O52 Tb2 97.0(6) . . ?
C4C C5C H5C 118.3 . . ?
N1C C5C C4C 123.3(6) . . ?
N1C C5C H5C 118.3 . . ?
C5F N1F Ag2 115.4(4) . . ?
C5F N1F C1F 117.3(6) . . ?
C1F N1F Ag2 119.0(4) . . ?
N1G C1G P3 119.0(4) . . ?
N1G C1G C2G 123.7(5) . . ?
C2G C1G P3 117.2(4) . . ?
C2E C3E H3E 120.7 . . ?
C4E C3E H3E 120.7 . . ?
C4E C3E C2E 118.7(6) . . ?
C2A C3A H3A 120.2 . . ?
C4A C3A H3A 120.2 . . ?
C4A C3A C2A 119.5(5) . . ?
N6S C61S C62S 179.6(11) . . ?
C1I C2I HZ 120.6 . . ?
C1I C2I C3I 118.7(6) . . ?
C3I C2I HZ 120.6 . . ?
N31 O31 Tb1 97.4(4) . . ?
O23 N21 Tb1 176.5(5) . . ?
O23 N21 O21 121.5(6) . . ?
O23 N21 O22 122.2(6) . . ?
O21 N21 Tb1 57.0(3) . . ?
O22 N21 Tb1 59.3(3) . . ?
O22 N21 O21 116.2(4) . . ?
N1H C5H C4H 124.3(6) . . ?
N1H C5H H1 117.8 . . ?
C4H C5H H1 117.8 . . ?
C4J C3J H2 121.1 . . ?
C4J C3J C2J 117.7(6) . . ?
C2J C3J H2 121.1 . . ?
C3H C2H H3 120.9 . . ?
C3H C2H C1H 118.2(6) . . ?
C1H C2H H3 120.9 . . ?
C2G C3G H4 120.9 . . ?
C2G C3G C4G 118.2(6) . . ?
C4G C3G H4 120.9 . . ?
C3E C2E H2E 120.7 . . ?
C1E C2E C3E 118.6(6) . . ?
C1E C2E H2E 120.7 . . ?
C1G C2G H5 120.6 . . ?
C3G C2G C1G 118.7(6) . . ?
C3G C2G H5 120.6 . . ?
C3A C2A H2A 121.0 . . ?
C1A C2A C3A 118.0(5) . . ?
C1A C2A H2A 121.0 . . ?
C5B C4B H4B 120.0 . . ?
C5B C4B C3B 119.9(6) . . ?
C3B C4B H4B 120.0 . . ?
C3D C4D H4D 120.2 . . ?
C3D C4D C5D 119.6(6) . . ?
C5D C4D H4D 120.2 . . ?
C4F C5F H5F 118.4 . . ?
N1F C5F C4F 123.3(6) . . ?
N1F C5F H5F 118.4 . . ?
C5I C4I H6 120.3 . . ?
C3I C4I H6 120.3 . . ?
C3I C4I C5I 119.5(6) . . ?
N1G C5G H7 119.1 . . ?
N1G C5G C4G 121.7(6) . . ?
C4G C5G H7 119.1 . . ?
C3G C4G C5G 119.8(6) . . ?
C3G C4G H8 120.1 . . ?
C5G C4G H8 120.1 . . ?
N1B C5B C4B 123.0(5) . . ?
N1B C5B H5B 118.5 . . ?
C4B C5B H5B 118.5 . . ?
N1I C5I C4I 122.7(6) . . ?
N1I C5I H9 118.7 . . ?
C4I C5I H9 118.7 . . ?
H C52S HA 109.5 . . ?
H C52S HB 109.5 . . ?
HA C52S HB 109.5 . . ?
C51S C52S H 109.5 . . ?
C51S C52S HA 109.5 . . ?
C51S C52S HB 109.5 . . ?
C4D C3D H3D 120.9 . . ?
C4D C3D C2D 118.2(5) . . ?
C2D C3D H3D 120.9 . . ?
C2K C3K H10 120.1 . . ?
C4K C3K C2K 119.7(6) . . ?
C4K C3K H10 120.1 . . ?
C3A C4A H4A 120.8 . . ?
C3A C4A C5A 118.4(5) . . ?
C5A C4A H4A 120.8 . . ?
C1D C2D C3D 118.1(5) . . ?
C1D C2D H2D 120.9 . . ?
C3D C2D H2D 120.9 . . ?
C3K C4K H11 121.0 . . ?
C3K C4K C5K 118.1(6) . . ?
C5K C4K H11 121.0 . . ?
C1J C2J C3J 119.3(6) . . ?
C1J C2J H12 120.3 . . ?
C3J C2J H12 120.3 . . ?
N1C C1C P1 119.5(4) . . ?
N1C C1C C2C 124.4(5) . . ?
C2C C1C P1 116.1(4) . . ?
C4J C5J H13 118.5 . . ?
N1J C5J C4J 123.0(6) . . ?
N1J C5J H13 118.5 . . ?
HC C42S HD 109.5 . . ?
HC C42S HE 109.5 . . ?
HD C42S HE 109.5 . . ?
C41S C42S HC 109.5 . . ?
C41S C42S HD 109.5 . . ?
C41S C42S HE 109.5 . . ?
C2I C3I H14 120.8 . . ?
C4I C3I C2I 118.3(6) . . ?
C4I C3I H14 120.8 . . ?
N1A C5A C4A 123.5(5) . . ?
N1A C5A H5A 118.3 . . ?
C4A C5A H5A 118.3 . . ?
C2F C1F P2 119.1(4) . . ?
N1F C1F P2 117.8(4) . . ?
N1F C1F C2F 123.0(5) . . ?
N1A C1A P1 117.5(4) . . ?
N1A C1A C2A 123.5(5) . . ?
C2A C1A P1 118.8(4) . . ?
N1K C1K P4 118.9(4) . . ?
N1K C1K C2K 122.3(5) . . ?
C2K C1K P4 118.8(4) . . ?
C3E C4E H4E 120.5 . . ?
C3E C4E C5E 119.0(6) . . ?
C5E C4E H4E 120.5 . . ?
N1E C5E C4E 123.9(6) . . ?
N1E C5E H5E 118.0 . . ?
C4E C5E H5E 118.0 . . ?
N1H C1H P3 116.5(4) . . ?
N1H C1H C2H 123.2(5) . . ?
C2H C1H P3 120.3(4) . . ?
C2B C3B H3B 121.2 . . ?
C4B C3B C2B 117.7(6) . . ?
C4B C3B H3B 121.2 . . ?
N1D C5D C4D 122.8(5) . . ?
N1D C5D H5D 118.6 . . ?
C4D C5D H5D 118.6 . . ?
N5S C51S C52S 178.3(13) . . ?
HF C32S HG 109.5 . . ?
HF C32S HH 109.5 . . ?
HG C32S HH 109.5 . . ?
C31S C32S HF 109.5 . . ?
C31S C32S HG 109.5 . . ?
C31S C32S HH 109.5 . . ?
N1K C5K C4K 124.1(6) . . ?
N1K C5K H15 118.0 . . ?
C4K C5K H15 118.0 . . ?
N3S C31S C32S 176.0(12) . . ?
HI C12S HJ 109.5 . . ?
HI C12S HK 109.5 . . ?
HJ C12S HK 109.5 . . ?
C11S C12S HI 109.5 . . ?
C11S C12S HJ 109.5 . . ?
C11S C12S HK 109.5 . . ?
N4S C41S C42S 175.5(19) . . ?
N1S C11S C12S 178.4(16) . . ?
N61 O62 Tb2 95.9(4) . . ?
N1E C1E P2 116.7(4) . . ?
N1E C1E C2E 123.3(5) . . ?
C2E C1E P2 120.0(4) . . ?
C61S C62S HL 109.5 . . ?
C61S C62S HM 109.5 . . ?
C61S C62S HN 109.5 . . ?
HL C62S HM 109.5 . . ?
HL C62S HN 109.5 . . ?
HM C62S HN 109.5 . . ?
N2S C21S C22S 155.1(16) . . ?
C21S C22S HO 109.5 . . ?
C21S C22S HP 109.5 . . ?
C21S C22S HQ 109.5 . . ?
HO C22S HP 109.5 . . ?
HO C22S HQ 109.5 . . ?
HP C22S HQ 109.5 . . ?
N61 O61' Tb2 95.8(6) . . ?
N61 O62' Tb2 96.1(6) . . ?
N31 O31' Tb1 96.1(7) . . ?
N31 O32' Tb1 97.2(6) . . ?
N51 O52' Tb2 98.0(9) . . ?
N51 O51' Tb2 96.0(8) . . ?
N41 O41 Tb1 96.8(6) . . ?
N41 O41' Tb1 97.3(8) . . ?
N41 O42' Tb1 95.3(7) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Tb1 O12 N11 O11 2.4(6) . . . . ?
Tb1 O12 N11 O13 -178.3(8) . . . . ?
Tb1 O11 N11 O12 -2.3(6) . . . . ?
Tb1 O11 N11 O13 178.4(8) . . . . ?
Tb1 O21 N21 O23 176.3(5) . . . . ?
Tb1 O21 N21 O22 -4.3(6) . . . . ?
Tb1 O22 N21 O23 -176.4(5) . . . . ?
Tb1 O22 N21 O21 4.2(6) . . . . ?
Tb2 O82 N81 O81 -11.0(6) . . . . ?
Tb2 O82 N81 O83 167.2(7) . . . . ?
Tb2 O51 N51 O53 -178.8(5) . . . . ?
Tb2 O51 N51 O52 3.1(13) . . . . ?
Tb2 O81 N81 O82 10.9(6) . . . . ?
Tb2 O81 N81 O83 -167.4(6) . . . . ?
Ag1 N1A C5A C4A 177.8(5) . . . . ?
Ag1 N1A C1A P1 8.5(6) . . . . ?
Ag1 N1A C1A C2A -177.0(4) . . . . ?
Ag1 N1B C5B C4B 164.2(5) . . . . ?
Ag1 N1C C5C C4C 131.1(7) . . . . ?
Ag1 N1C C1C P1 44.5(5) . . . . ?
Ag1 N1C C1C C2C -133.2(5) . . . . ?
Ag2 N1D C5D C4D 179.7(5) . . . . ?
Ag2 N1E C5E C4E -168.3(6) . . . . ?
Ag2 N1E C1E P2 -13.0(7) . . . . ?
Ag2 N1E C1E C2E 166.6(5) . . . . ?
Ag2 N1F C5F C4F -147.8(7) . . . . ?
Ag2 N1F C1F P2 -30.3(7) . . . . ?
Ag2 N1F C1F C2F 146.2(5) . . . . ?
Ag3 N1H C5H C4H -171.4(5) . . . . ?
Ag3 N1H C1H P3 -7.7(6) . . . . ?
Ag3 N1H C1H C2H 171.4(4) . . . . ?
Ag3 N1O C5O C4O 174.5(5) 7_656 . . . ?
Ag3 N1I C5I C4I -179.4(6) . . . . ?
Ag3 N1K C1K P4 -0.8(7) 7_656 . . . ?
Ag3 N1K C1K C2K 175.3(4) 7_656 . . . ?
Ag3 N1K C5K C4K -175.2(6) 7_656 . . . ?
Ag3 N1G C1G P3 -34.5(7) . . . . ?
Ag3 N1G C1G C2G 143.8(5) . . . . ?
Ag3 N1G C5G C4G -145.5(8) . . . . ?
Ag3 N1J C5J C4J 147.8(6) 7_656 . . . ?
P3 C1I N1I Ag3 -1.8(7) . . . . ?
P3 C1I N1I C5I 177.4(5) . . . . ?
P3 C1I C2I C3I -178.1(5) . . . . ?
P3 C1G C2G C3G -179.5(5) . . . . ?
P4 C1O N1O Ag3 7.2(7) . . . 7_656 ?
P4 C1O N1O C5O 179.1(5) . . . . ?
P4 C1O C2O C3O 179.3(5) . . . . ?
P4 C1J N1J Ag3 28.8(6) . . . 7_656 ?
P4 C1J N1J C5J 176.3(5) . . . . ?
P4 C1J C2J C3J -175.5(5) . . . . ?
P1 C1B C2B C3B 178.9(5) . . . . ?
P1 C1B N1B Ag1 17.2(6) . . . . ?
P1 C1B N1B C5B 179.6(5) . . . . ?
P2 C1D N1D Ag2 -4.5(7) . . . . ?
P2 C1D N1D C5D 175.6(5) . . . . ?
P2 C1D C2D C3D -175.7(5) . . . . ?
O2 P2 C1D N1D -178.8(4) . . . . ?
O2 P2 C1D C2D -2.6(6) . . . . ?
O2 P2 C1F C2F 23.1(6) . . . . ?
O2 P2 C1F N1F -160.3(5) . . . . ?
O2 P2 C1E N1E -170.7(4) . . . . ?
O2 P2 C1E C2E 9.7(6) . . . . ?
O4 P4 C1O N1O 176.0(4) . . . . ?
O4 P4 C1O C2O -2.4(5) . . . . ?
O4 P4 C1J N1J 160.0(5) . . . . ?
O4 P4 C1J C2J -24.3(5) . . . . ?
O4 P4 C1K N1K -178.3(4) . . . . ?
O4 P4 C1K C2K 5.4(6) . . . . ?
O73 N71 O71 Tb2 177.9(5) . . . . ?
O73 N71 O72 Tb2 -177.7(5) . . . . ?
O3 P3 C1I N1I 178.1(4) . . . . ?
O3 P3 C1I C2I -4.4(6) . . . . ?
O3 P3 C1G N1G -154.7(5) . . . . ?
O3 P3 C1G C2G 26.8(6) . . . . ?
O3 P3 C1H N1H -173.8(4) . . . . ?
O3 P3 C1H C2H 7.1(5) . . . . ?
O63 N61 O61 Tb2 177.5(5) . . . . ?
O63 N61 O62 Tb2 -177.4(5) . . . . ?
O63 N61 O61' Tb2 179.4(5) . . . . ?
O63 N61 O62' Tb2 -180.0(5) . . . . ?
O1 P1 C1B C2B -10.7(5) . . . . ?
O1 P1 C1B N1B 169.3(4) . . . . ?
O1 P1 C1C N1C 145.7(5) . . . . ?
O1 P1 C1C C2C -36.3(5) . . . . ?
O1 P1 C1A N1A 176.6(4) . . . . ?
O1 P1 C1A C2A 1.9(6) . . . . ?
C1B P1 C1C N1C -93.4(5) . . . . ?
C1B P1 C1C C2C 84.6(5) . . . . ?
C1B P1 C1A N1A 55.7(5) . . . . ?
C1B P1 C1A C2A -119.0(5) . . . . ?
C1B C2B C3B C4B 1.7(9) . . . . ?
C1B N1B C5B C4B 1.3(10) . . . . ?
C1O P4 C1J N1J -78.8(5) . . . . ?
C1O P4 C1J C2J 96.8(5) . . . . ?
C1O P4 C1K N1K 60.7(5) . . . . ?
C1O P4 C1K C2K -115.6(5) . . . . ?
C1O N1O C5O C4O 1.9(10) . . . . ?
C1O C2O C3O C4O 1.2(9) . . . . ?
C1D P2 C1F C2F 147.8(5) . . . . ?
C1D P2 C1F N1F -35.5(6) . . . . ?
C1D P2 C1E N1E 68.1(5) . . . . ?
C1D P2 C1E C2E -111.5(5) . . . . ?
C1D N1D C5D C4D -0.4(10) . . . . ?
C1I P3 C1G N1G -31.7(6) . . . . ?
C1I P3 C1G C2G 149.8(5) . . . . ?
C1I P3 C1H N1H 65.3(5) . . . . ?
C1I P3 C1H C2H -113.8(5) . . . . ?
C1I N1I C5I C4I 1.4(11) . . . . ?
C1I C2I C3I C4I 0.1(10) . . . . ?
O51 N51 O52 Tb2 -3.1(13) . . . . ?
N1O C1O C2O C3O 1.0(9) . . . . ?
N1O C5O C4O C3O 0.1(11) . . . . ?
O71 N71 O72 Tb2 4.2(6) . . . . ?
O43 N41 O42 Tb1 -177.6(5) . . . . ?
O43 N41 O41 Tb1 177.5(5) . . . . ?
O43 N41 O41' Tb1 177.7(4) . . . . ?
O43 N41 O42' Tb1 -177.9(4) . . . . ?
N1I C1I C2I C3I -0.8(10) . . . . ?
C3H C4H C5H N1H -0.2(10) . . . . ?
C3H C2H C1H P3 178.9(4) . . . . ?
C3H C2H C1H N1H -0.2(9) . . . . ?
O61 N61 O62 Tb2 5.9(7) . . . . ?
O72 N71 O71 Tb2 -4.1(6) . . . . ?
O33 N31 O32 Tb1 179.6(5) . . . . ?
O33 N31 O31 Tb1 -179.5(5) . . . . ?
O33 N31 O31' Tb1 -178.8(5) . . . . ?
O33 N31 O32' Tb1 178.7(5) . . . . ?
C2B C1B N1B Ag1 -162.8(4) . . . . ?
C2B C1B N1B C5B -0.5(9) . . . . ?
N1D C1D C2D C3D 0.2(10) . . . . ?
N1B C1B C2B C3B -1.0(9) . . . . ?
C2O C1O N1O Ag3 -174.4(4) . . . 7_656 ?
C2O C1O N1O C5O -2.5(9) . . . . ?
C3F C2F C1F P2 176.9(5) . . . . ?
C3F C2F C1F N1F 0.5(9) . . . . ?
C3F C4F C5F N1F 0.4(13) . . . . ?
C4J C3J C2J C1J -0.7(10) . . . . ?
C4H C3H C2H C1H -0.8(9) . . . . ?
C5O C4O C3O C2O -1.7(10) . . . . ?
C3C C4C C5C N1C -2.3(12) . . . . ?
C3C C2C C1C P1 -179.1(5) . . . . ?
C3C C2C C1C N1C -1.2(9) . . . . ?
C1J P4 C1O N1O 55.2(5) . . . . ?
C1J P4 C1O C2O -123.2(5) . . . . ?
C1J P4 C1K N1K -54.4(5) . . . . ?
C1J P4 C1K C2K 129.3(5) . . . . ?
C1J N1J C5J C4J -0.8(11) . . . . ?
N1G C1G C2G C3G 2.1(10) . . . . ?
N1G C5G C4G C3G 3.8(16) . . . . ?
O53 N51 O52 Tb2 178.8(6) . . . . ?
O53 N51 O52' Tb2 178.4(6) . . . . ?
O53 N51 O51' Tb2 -178.5(6) . . . . ?
O32 N31 O31 Tb1 3.1(7) . . . . ?
N1J C1J C2J C3J 0.0(10) . . . . ?
O42 N41 O41 Tb1 0.2(8) . . . . ?
C2K C3K C4K C5K -1.5(11) . . . . ?
C5C C4C C3C C2C 2.9(11) . . . . ?
C5C N1C C1C P1 179.7(5) . . . . ?
C5C N1C C1C C2C 1.9(10) . . . . ?
C1G P3 C1I N1I 55.8(5) . . . . ?
C1G P3 C1I C2I -126.7(5) . . . . ?
C1G P3 C1H N1H -54.5(5) . . . . ?
C1G P3 C1H C2H 126.4(5) . . . . ?
C1G N1G C5G C4G -1.2(14) . . . . ?
C3E C2E C1E P2 -179.9(5) . . . . ?
C3E C2E C1E N1E 0.5(10) . . . . ?
C3E C4E C5E N1E 1.9(12) . . . . ?
C3A C2A C1A P1 174.7(5) . . . . ?
C3A C2A C1A N1A 0.3(9) . . . . ?
C3A C4A C5A N1A -1.5(10) . . . . ?
C2I C1I N1I Ag3 -179.2(5) . . . . ?
C2I C1I N1I C5I 0.0(9) . . . . ?
O31 N31 O32 Tb1 -3.1(7) . . . . ?
C5H N1H C1H P3 -178.1(5) . . . . ?
C5H N1H C1H C2H 0.9(9) . . . . ?
C3J C4J C5J N1J 0.1(12) . . . . ?
C2H C3H C4H C5H 1.0(9) . . . . ?
C2E C3E C4E C5E -2.4(11) . . . . ?
C2G C3G C4G C5G -3.4(14) . . . . ?
C2A C3A C4A C5A 0.5(10) . . . . ?
C4D C3D C2D C1D 0.6(9) . . . . ?
C5F C4F C3F C2F -0.8(11) . . . . ?
C5F N1F C1F P2 -177.3(6) . . . . ?
C5F N1F C1F C2F -0.8(10) . . . . ?
C5G N1G C1G P3 179.8(6) . . . . ?
C5G N1G C1G C2G -1.8(11) . . . . ?
C4G C3G C2G C1G 0.6(11) . . . . ?
C5B C4B C3B C2B -1.0(10) . . . . ?
C5I C4I C3I C2I 1.2(11) . . . . ?
C3D C4D C5D N1D 1.3(11) . . . . ?
C3K C2K C1K P4 175.6(5) . . . . ?
C3K C2K C1K N1K -0.5(9) . . . . ?
C3K C4K C5K N1K 0.1(12) . . . . ?
C4A C3A C2A C1A 0.1(10) . . . . ?
C2D C1D N1D Ag2 179.5(5) . . . . ?
C2D C1D N1D C5D -0.3(9) . . . . ?
C2J C1J N1J Ag3 -146.7(5) . . . 7_656 ?
C2J C1J N1J C5J 0.8(10) . . . . ?
C1C P1 C1B C2B -131.3(5) . . . . ?
C1C P1 C1B N1B 48.7(5) . . . . ?
C1C P1 C1A N1A -59.4(5) . . . . ?
C1C P1 C1A C2A 125.9(5) . . . . ?
C1C N1C C5C C4C -0.1(11) . . . . ?
C1C C2C C3C C4C -1.2(10) . . . . ?
C5J C4J C3J C2J 0.7(11) . . . . ?
C3I C4I C5I N1I -2.0(12) . . . . ?
C5A N1A C1A P1 -175.7(5) . . . . ?
C5A N1A C1A C2A -1.3(9) . . . . ?
C1F P2 C1D N1D 56.8(5) . . . . ?
C1F P2 C1D C2D -127.0(5) . . . . ?
C1F P2 C1E N1E -51.1(5) . . . . ?
C1F P2 C1E C2E 129.3(5) . . . . ?
C1F C2F C3F C4F 0.3(9) . . . . ?
C1F N1F C5F C4F 0.3(12) . . . . ?
C1A P1 C1B C2B 109.6(5) . . . . ?
C1A P1 C1B N1B -70.5(5) . . . . ?
C1A P1 C1C N1C 22.1(6) . . . . ?
C1A P1 C1C C2C -160.0(4) . . . . ?
C1A N1A C5A C4A 1.9(10) . . . . ?
C1K P4 C1O N1O -63.9(5) . . . . ?
C1K P4 C1O C2O 117.7(5) . . . . ?
C1K P4 C1J N1J 36.6(5) . . . . ?
C1K P4 C1J C2J -147.7(5) . . . . ?
C1K N1K C5K C4K 1.0(11) . . . . ?
C1K C2K C3K C4K 1.7(10) . . . . ?
C4E C3E C2E C1E 1.2(10) . . . . ?
C5E N1E C1E P2 179.4(5) . . . . ?
C5E N1E C1E C2E -1.0(9) . . . . ?
C1H P3 C1I N1I -60.9(5) . . . . ?
C1H P3 C1I C2I 116.6(5) . . . . ?
C1H P3 C1G N1G 84.9(6) . . . . ?
C1H P3 C1G C2G -93.5(5) . . . . ?
C1H N1H C5H C4H -0.7(10) . . . . ?
C3B C4B C5B N1B -0.6(11) . . . . ?
C5D C4D C3D C2D -1.3(10) . . . . ?
C5K N1K C1K P4 -176.9(5) . . . . ?
C5K N1K C1K C2K -0.8(9) . . . . ?
O62 N61 O61 Tb2 -5.7(7) . . . . ?
C1E P2 C1D N1D -57.9(5) . . . . ?
C1E P2 C1D C2D 118.3(5) . . . . ?
C1E P2 C1F C2F -96.7(5) . . . . ?
C1E P2 C1F N1F 79.9(6) . . . . ?
C1E N1E C5E C4E -0.2(10) . . . . ?
O61' N61 O62' Tb2 -9.5(10) . . . . ?
O62' N61 O61' Tb2 9.5(10) . . . . ?
O31' N31 O32' Tb1 3.4(10) . . . . ?
O32' N31 O31' Tb1 -3.4(10) . . . . ?
O52' N51 O51' Tb2 -4.4(12) . . . . ?
O51' N51 O52' Tb2 4.4(12) . . . . ?
O41 N41 O42 Tb1 -0.2(8) . . . . ?
O41' N41 O42' Tb1 7.1(11) . . . . ?
O42' N41 O41' Tb1 -7.2(11) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.578(8)
2 0.422(8)

_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent: MeCN'
_exptl_crystal_preparation       Luminescent
