File Name : _nj-art-12-2024-005419_ fig.s1.tif Caption : fig. s1 xrd patterns mnwo4, invo4, and a% invo4@mnwo4 composites. File Name : _nj-art-12-2024-005419_ fig.s2.tif Caption : fig. s2 xps spectra of samples: (a) survey spectra, (b) in 3d, (c) mn 2p. File Name : _nj-art-12-2024-005419_ fig.s3.tif Caption : fig. s3 xrd patterns of invo4@mnwo4 composite before and after activity cycling test File Name : _nj-art-12-2024-005419_ fig.s4.tif Caption : fig. s4 the aqe wavelength-dependence of invo4@mnwo4 for the photocatalytic co2 reduction. File Name : _nj-art-12-2024-005419_ fig.s5.tif Caption : fig. s5 (a) uv-vis drs spectra of samples, (b) tauc plots of mnwo4 and invo4. File Name : _nj-art-12-2024-005419_ fig.s6.tif Caption : fig. s6 tem images of invo4@mnwo4 photodeposited with pt (a, b) nanoparticles and pbo2(c, d)nanoparticles. File Name : _nj-art-12-2024-005419_ fig.s7.tif Caption : fig. s7 sem images of invo4@mnwo4 (a) before reaction, (b) after reaction. File Name : _nj-art-12-2024-005419_ fig.s8 .tif Caption : fig. s8 xps survey spectrum of (a) invo4@mnwo4 before and after cycling tests; the high resolution xps spectra of (b) v 2p, (c) w 4f, (d) o 1s, (e) in 3d and (f) mn 2p.