# Copyright The Royal Society of Chemistry, 1998 # CCDC Number: 186/1166 data_1 _audit_creation_method SHELXL _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_formula_moiety ? _chemical_formula_structural ? _chemical_formula_analytical ? _chemical_formula_sum 'C43.50 H42.50 Ag Cl5.50 N O4 P2 Pt S2' _chemical_formula_weight 1267.28 _chemical_melting_point ? _chemical_compound_source ? loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'P' 'P' 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'S' 'S' 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Cl' 'Cl' 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Ag' 'Ag' -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Pt' 'Pt' -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting triclinic _symmetry_space_group_name_H-M P-1 loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 13.312(4) _cell_length_b 14.145(5) _cell_length_c 14.793(5) _cell_angle_alpha 112.19(3) _cell_angle_beta 99.97(3) _cell_angle_gamma 101.18(3) _cell_volume 2435.3(14) _cell_formula_units_Z 2 _cell_measurement_temperature 293(2) _cell_measurement_reflns_used 23 _cell_measurement_theta_min 15.9 _cell_measurement_theta_max 29.0 _exptl_crystal_description ? _exptl_crystal_colour ? _exptl_crystal_size_max 0.5 _exptl_crystal_size_mid 0.5 _exptl_crystal_size_min 0.5 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.728 _exptl_crystal_density_method ? _exptl_crystal_F_000 1246 _exptl_absorpt_coefficient_mu 3.765 _exptl_absorpt_correction_type 'Psi scans' _exptl_absorpt_correction_T_min 0.697 _exptl_absorpt_correction_T_max 0.987 _exptl_special_details ; ? ; _diffrn_ambient_temperature 293(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device 'Siemens P3m' _diffrn_measurement_method Wyckoff _diffrn_standards_number 3 _diffrn_standards_interval_count 200 _diffrn_standards_interval_time ? _diffrn_standards_decay_% 0 _diffrn_reflns_number 9042 _diffrn_reflns_av_R_equivalents 0.0220 _diffrn_reflns_av_sigmaI/netI 0.0332 _diffrn_reflns_limit_h_min 0 _diffrn_reflns_limit_h_max 15 _diffrn_reflns_limit_k_min -16 _diffrn_reflns_limit_k_max 16 _diffrn_reflns_limit_l_min -17 _diffrn_reflns_limit_l_max 17 _diffrn_reflns_theta_min 1.54 _diffrn_reflns_theta_max 25.00 _reflns_number_total 8584 _reflns_number_observed 7325 _reflns_observed_criterion >2sigma(I) _computing_data_collection ? _computing_cell_refinement ? _computing_data_reduction ? _computing_structure_solution 'SHELXS-86 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-93 (Sheldrick, 1993)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement on F^2^ for ALL reflections except for 1 with very negative F^2^ or flagged by the user for potential systematic errors. Weighted R-factors wR and all goodnesses of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The observed criterion of F^2^ > 2sigma(F^2^) is used only for calculating _R_factor_obs etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme 'calc w=1/[\s^2^(Fo^2^)+(0.0800P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment ? _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 8583 _refine_ls_number_parameters 632 _refine_ls_number_restraints 6 _refine_ls_R_factor_all 0.0568 _refine_ls_R_factor_obs 0.0451 _refine_ls_wR_factor_all 0.1340 _refine_ls_wR_factor_obs 0.1263 _refine_ls_goodness_of_fit_all 1.239 _refine_ls_goodness_of_fit_obs 1.272 _refine_ls_restrained_S_all 1.242 _refine_ls_restrained_S_obs 1.276 _refine_ls_shift/esd_max 0.000 _refine_ls_shift/esd_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_thermal_displace_type _atom_site_occupancy _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_group Pt Pt 0.31433(2) 0.11283(2) 0.08120(2) 0.03721(11) Uani 1 d . . Ag Ag 0.52715(6) 0.17118(6) 0.20656(7) 0.0776(2) Uani 1 d . . S1 S 0.3795(2) -0.00829(15) 0.1331(2) 0.0481(4) Uani 1 d . . S2 S 0.2758(2) 0.1414(2) 0.2409(2) 0.0567(5) Uani 1 d . . P1 P 0.26661(14) 0.23414(13) 0.03380(13) 0.0367(4) Uani 1 d . . P2 P 0.6819(2) 0.3100(2) 0.2405(2) 0.0530(5) Uani 1 d . . N N 0.3240(6) -0.0064(6) 0.3014(6) 0.064(2) Uani 1 d . . C1 C 0.3509(7) 0.0557(6) -0.0558(6) 0.050(2) Uani 1 d . . H1A H 0.4252(7) 0.0569(6) -0.0421(6) 0.123(8) Uiso 1 calc R . H1B H 0.3092(7) -0.0182(6) -0.0942(6) 0.123(8) Uiso 1 calc R . C2 C 0.3330(6) 0.1140(6) -0.1228(6) 0.047(2) Uani 1 d . . C3 C 0.2928(6) 0.2006(6) -0.0889(5) 0.044(2) Uani 1 d . . C4 C 0.2713(7) 0.2542(7) -0.1510(6) 0.057(2) Uani 1 d . . H4A H 0.2428(7) 0.3112(7) -0.1290(6) 0.123(8) Uiso 1 calc R . C5 C 0.2927(8) 0.2217(7) -0.2428(7) 0.068(2) Uani 1 d . . H5A H 0.2795(8) 0.2567(7) -0.2837(7) 0.123(8) Uiso 1 calc R . C6 C 0.3349(8) 0.1345(8) -0.2755(6) 0.071(3) Uani 1 d . . H6A H 0.3509(8) 0.1130(8) -0.3376(6) 0.123(8) Uiso 1 calc R . C7 C 0.3526(7) 0.0815(7) -0.2177(6) 0.061(2) Uani 1 d . . H7A H 0.3783(7) 0.0227(7) -0.2417(6) 0.123(8) Uiso 1 calc R . C8 C 0.2549(8) 0.3854(7) 0.2585(7) 0.063(2) Uani 1 d . . H8A H 0.2161(8) 0.3134(7) 0.2122(7) 0.123(8) Uiso 1 calc R . H8B H 0.2063(8) 0.4279(7) 0.2715(7) 0.123(8) Uiso 1 calc R . H8C H 0.2919(8) 0.3868(7) 0.3210(7) 0.123(8) Uiso 1 calc R . C9 C 0.3349(6) 0.4302(6) 0.2123(5) 0.047(2) Uani 1 d . . C10 C 0.3481(5) 0.3713(5) 0.1153(5) 0.0381(14) Uani 1 d . . C11 C 0.4275(6) 0.4165(6) 0.0826(6) 0.047(2) Uani 1 d . . H11A H 0.4372(6) 0.3779(6) 0.0197(6) 0.123(8) Uiso 1 calc R . C12 C 0.4939(7) 0.5204(6) 0.1439(7) 0.058(2) Uani 1 d . . H12A H 0.5483(7) 0.5497(6) 0.1221(7) 0.123(8) Uiso 1 calc R . C13 C 0.4786(8) 0.5786(7) 0.2351(7) 0.066(2) Uani 1 d . . H13A H 0.5217(8) 0.6479(7) 0.2747(7) 0.123(8) Uiso 1 calc R . C14 C 0.3987(7) 0.5344(6) 0.2690(6) 0.059(2) Uani 1 d . . H14A H 0.3878(7) 0.5752(6) 0.3306(6) 0.123(8) Uiso 1 calc R . C15 C 0.0628(7) 0.0372(7) -0.0838(9) 0.077(3) Uani 1 d . . H15A H 0.1377(7) 0.0453(7) -0.0649(9) 0.123(8) Uiso 1 calc R . H15B H 0.0361(7) 0.0027(7) -0.1564(9) 0.123(8) Uiso 1 calc R . H15C H 0.0267(7) -0.0052(7) -0.0551(9) 0.123(8) Uiso 1 calc R . C16 C 0.0437(6) 0.1446(6) -0.0449(6) 0.053(2) Uani 1 d . . C17 C 0.1273(5) 0.2381(6) 0.0084(5) 0.0410(15) Uani 1 d . . C18 C 0.1044(6) 0.3357(6) 0.0362(6) 0.052(2) Uani 1 d . . H18A H 0.1600(6) 0.3984(6) 0.0681(6) 0.123(8) Uiso 1 calc R . C19 C 0.0005(7) 0.3410(8) 0.0172(7) 0.066(2) Uani 1 d . . H19A H -0.0138(7) 0.4066(8) 0.0369(7) 0.123(8) Uiso 1 calc R . C20 C -0.0804(7) 0.2490(8) -0.0306(7) 0.068(2) Uani 1 d . . H20A H -0.1507(7) 0.2512(8) -0.0414(7) 0.123(8) Uiso 1 calc R . C21 C -0.0579(7) 0.1532(8) -0.0628(8) 0.070(3) Uani 1 d . . H21A H -0.1141(7) 0.0912(8) -0.0983(8) 0.123(8) Uiso 1 calc R . C22 C 0.3264(6) 0.0364(6) 0.2356(6) 0.048(2) Uani 1 d . . C23 C 0.3735(10) -0.0906(9) 0.2963(9) 0.089(3) Uani 1 d . . H23A H 0.3637(10) -0.1114(9) 0.3496(9) 0.123(8) Uiso 1 calc R . H23B H 0.4482(10) -0.0652(9) 0.3041(9) 0.123(8) Uiso 1 calc R . H23C H 0.3414(10) -0.1508(9) 0.2319(9) 0.123(8) Uiso 1 calc R . C24 C 0.2763(11) 0.0306(11) 0.3830(9) 0.098(4) Uani 1 d . . H24A H 0.2824(11) -0.0100(11) 0.4220(9) 0.123(8) Uiso 1 calc R . H24B H 0.2026(11) 0.0223(11) 0.3560(9) 0.123(8) Uiso 1 calc R . H24C H 0.3121(11) 0.1045(11) 0.4258(9) 0.123(8) Uiso 1 calc R . C25 C 0.6706(19) 0.4356(25) 0.3353(21) 0.054(6) Uani 0.50 d P 2 C26 C 0.7450(17) 0.5374(17) 0.3684(17) 0.076(5) Uani 0.50 d P 2 C27 C 0.7387(38) 0.6320(37) 0.4490(47) 0.128(19) Uani 0.50 d P 2 C28 C 0.6492(24) 0.6130(21) 0.4803(19) 0.073(7) Uani 0.50 d P 2 C29 C 0.5773(24) 0.5200(30) 0.4530(21) 0.107(10) Uani 0.50 d P 2 C30 C 0.5830(20) 0.4261(20) 0.3741(16) 0.071(5) Uani 0.50 d P 2 C31 C 0.8087(17) 0.3007(18) 0.2756(16) 0.044(5) Uani 0.50 d P 2 C32 C 0.8644(16) 0.3445(24) 0.3783(18) 0.094(8) Uani 0.50 d P 2 C33 C 0.9699(17) 0.3318(23) 0.4035(19) 0.095(8) Uani 0.50 d P 2 C34 C 1.0167(17) 0.2875(21) 0.3344(18) 0.081(6) Uani 0.50 d P 2 C35 C 0.9641(8) 0.2348(9) 0.2320(9) 0.081(3) Uani 1 d . . C36 C 0.8700(7) 0.2591(7) 0.2091(8) 0.064(2) Uani 1 d . . C37 C 0.6889(6) 0.3442(6) 0.1350(6) 0.052(2) Uani 1 d . . C38 C 0.7688(7) 0.4313(8) 0.1445(8) 0.073(3) Uani 1 d . . H38A H 0.8198(7) 0.4724(8) 0.2063(8) 0.123(8) Uiso 1 calc R . C39 C 0.7727(8) 0.4567(8) 0.0634(9) 0.078(3) Uani 1 d . . H39A H 0.8257(8) 0.5148(8) 0.0709(9) 0.123(8) Uiso 1 calc R . C40 C 0.6987(8) 0.3965(9) -0.0276(9) 0.076(3) Uani 1 d . . H40A H 0.7014(8) 0.4137(9) -0.0821(9) 0.123(8) Uiso 1 calc R . C41 C 0.6184(8) 0.3089(8) -0.0396(7) 0.070(2) Uani 1 d . . H41A H 0.5679(8) 0.2682(8) -0.1017(7) 0.123(8) Uiso 1 calc R . C42 C 0.6146(7) 0.2831(7) 0.0412(7) 0.063(2) Uani 1 d . . H42A H 0.5618(7) 0.2244(7) 0.0329(7) 0.123(8) Uiso 1 calc R . C25' C 0.7156(18) 0.4347(24) 0.3564(18) 0.053(6) Uani 0.50 d P 1 C26' C 0.8185(14) 0.4799(15) 0.4275(14) 0.068(5) Uani 0.50 d P 1 C27' C 0.8425(19) 0.5843(15) 0.5033(13) 0.075(6) Uani 0.50 d P 1 C28' C 0.7650(23) 0.6357(19) 0.5144(17) 0.076(6) Uani 0.50 d P 1 C29' C 0.6730(48) 0.5900(30) 0.4417(25) 0.116(21) Uani 0.50 d P 1 C30' C 0.6385(23) 0.4877(25) 0.3683(20) 0.084(7) Uani 0.50 d P 1 C31' C 0.8023(21) 0.2502(16) 0.2619(20) 0.058(7) Uani 0.50 d P 1 C32' C 0.8028(15) 0.2043(16) 0.3310(15) 0.069(5) Uani 0.50 d P 1 C33' C 0.8924(19) 0.1658(19) 0.3479(17) 0.085(6) Uani 0.50 d P 1 C34' C 0.9710(18) 0.1792(17) 0.3001(16) 0.087(7) Uani 0.50 d P 1 Cl1 Cl 0.5966(3) 0.1942(2) 0.4780(2) 0.0939(9) Uani 1 d . . O1 O 0.5600(12) 0.1473(11) 0.3781(7) 0.183(6) Uani 1 d . . O2 O 0.6675(13) 0.2945(10) 0.5100(10) 0.190(6) Uani 1 d . . O3 O 0.6655(19) 0.1381(18) 0.4949(15) 0.270(11) Uani 1 d . . O4 O 0.5249(11) 0.1911(11) 0.5368(9) 0.166(5) Uani 1 d . . C43 C -0.1030(11) 0.3354(11) -0.3242(12) 0.109(4) Uani 1 d . . Cl2 Cl -0.0054(6) 0.2788(6) -0.3043(9) 0.311(6) Uani 1 d . . Cl3 Cl -0.0529(3) 0.4558(4) -0.3281(4) 0.1411(15) Uani 1 d . . Cl4 Cl -0.1579(5) 0.3673(4) -0.2177(4) 0.154(2) Uani 1 d . . C44 C 0.9574(18) 0.0092(23) 0.4521(17) 0.240(4) Uani 0.50 d PD 2 Cl5 Cl 1.0851(11) 0.0801(14) 0.5260(10) 0.240(4) Uani 0.50 d PD 2 Cl6 Cl 0.8712(11) 0.0925(13) 0.4590(10) 0.240(4) Uani 0.50 d PD 2 Cl7 Cl 0.9659(11) -0.0255(13) 0.3265(9) 0.240(4) Uani 0.50 d PD 2 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Pt 0.0309(2) 0.0353(2) 0.0429(2) 0.01551(11) 0.00840(10) 0.00796(10) Ag 0.0457(4) 0.0756(5) 0.1010(6) 0.0517(4) -0.0069(4) -0.0104(3) S1 0.0458(10) 0.0460(10) 0.0588(11) 0.0262(9) 0.0153(9) 0.0177(8) S2 0.0687(14) 0.0602(12) 0.0540(11) 0.0281(10) 0.0257(10) 0.0300(11) P1 0.0337(9) 0.0346(8) 0.0409(9) 0.0153(7) 0.0109(7) 0.0088(7) P2 0.0347(10) 0.0544(12) 0.0574(12) 0.0185(10) 0.0078(9) 0.0012(9) N 0.065(5) 0.072(5) 0.073(5) 0.045(4) 0.024(4) 0.024(4) C1 0.054(5) 0.047(4) 0.050(4) 0.017(3) 0.018(4) 0.021(4) C2 0.039(4) 0.044(4) 0.049(4) 0.012(3) 0.013(3) 0.007(3) C3 0.043(4) 0.041(4) 0.044(4) 0.019(3) 0.010(3) 0.005(3) C4 0.061(5) 0.056(5) 0.055(5) 0.026(4) 0.009(4) 0.018(4) C5 0.084(7) 0.069(6) 0.054(5) 0.034(4) 0.017(5) 0.016(5) C6 0.079(7) 0.081(6) 0.038(4) 0.017(4) 0.012(4) 0.013(5) C7 0.066(6) 0.059(5) 0.050(5) 0.016(4) 0.020(4) 0.011(4) C8 0.076(6) 0.058(5) 0.059(5) 0.020(4) 0.034(5) 0.022(5) C9 0.046(4) 0.043(4) 0.047(4) 0.013(3) 0.008(3) 0.018(3) C10 0.034(3) 0.038(3) 0.039(3) 0.015(3) 0.006(3) 0.012(3) C11 0.035(4) 0.046(4) 0.059(4) 0.026(4) 0.009(3) 0.008(3) C12 0.046(4) 0.045(4) 0.073(6) 0.027(4) 0.001(4) 0.000(4) C13 0.071(6) 0.042(4) 0.066(6) 0.020(4) -0.001(5) 0.001(4) C14 0.065(5) 0.044(4) 0.054(5) 0.012(4) 0.004(4) 0.019(4) C15 0.041(5) 0.051(5) 0.111(8) 0.018(5) -0.002(5) 0.004(4) C16 0.036(4) 0.054(4) 0.055(4) 0.018(4) 0.005(3) 0.000(3) C17 0.037(4) 0.045(4) 0.043(4) 0.022(3) 0.007(3) 0.011(3) C18 0.041(4) 0.051(4) 0.066(5) 0.028(4) 0.013(4) 0.018(3) C19 0.049(5) 0.073(6) 0.083(6) 0.042(5) 0.010(4) 0.023(4) C20 0.042(5) 0.082(6) 0.083(6) 0.040(5) 0.006(4) 0.020(5) C21 0.038(4) 0.064(5) 0.088(6) 0.028(5) -0.007(4) 0.001(4) C22 0.042(4) 0.048(4) 0.050(4) 0.023(3) 0.009(3) 0.006(3) C23 0.110(9) 0.092(8) 0.092(8) 0.064(7) 0.026(7) 0.036(7) C24 0.118(10) 0.127(10) 0.090(8) 0.073(8) 0.057(8) 0.045(8) C25 0.034(14) 0.062(13) 0.053(14) 0.024(11) 0.000(12) -0.002(13) C26 0.066(13) 0.064(12) 0.089(14) 0.031(11) 0.010(11) 0.010(10) C27 0.124(35) 0.093(27) 0.166(46) 0.064(31) 0.023(33) 0.022(21) C28 0.098(20) 0.053(14) 0.038(13) 0.003(11) -0.011(12) 0.016(14) C29 0.103(20) 0.172(32) 0.087(17) 0.073(22) 0.042(16) 0.078(22) C30 0.085(16) 0.083(15) 0.068(12) 0.037(11) 0.037(11) 0.048(13) C31 0.036(9) 0.071(14) 0.045(10) 0.033(12) 0.022(8) 0.034(12) C32 0.056(12) 0.172(25) 0.094(15) 0.091(17) 0.026(11) 0.047(14) C33 0.058(12) 0.149(23) 0.097(16) 0.082(17) 0.010(12) 0.022(14) C34 0.063(13) 0.119(19) 0.091(15) 0.064(15) 0.030(12) 0.044(13) C35 0.052(6) 0.078(7) 0.105(8) 0.033(6) 0.025(6) 0.014(5) C36 0.056(5) 0.056(5) 0.084(6) 0.028(5) 0.027(5) 0.018(4) C37 0.041(4) 0.047(4) 0.064(5) 0.022(4) 0.011(4) 0.010(3) C38 0.050(5) 0.067(6) 0.102(7) 0.048(6) 0.004(5) 0.006(4) C39 0.064(6) 0.078(7) 0.116(9) 0.065(7) 0.024(6) 0.024(5) C40 0.078(7) 0.094(7) 0.106(8) 0.067(7) 0.053(6) 0.057(6) C41 0.073(6) 0.076(6) 0.062(5) 0.024(5) 0.026(5) 0.027(5) C42 0.062(5) 0.055(5) 0.064(5) 0.018(4) 0.019(4) 0.014(4) C25' 0.038(13) 0.073(13) 0.042(12) 0.024(10) 0.014(11) 0.002(13) C26' 0.050(10) 0.071(11) 0.061(10) 0.011(9) 0.012(8) 0.007(9) C27' 0.098(16) 0.059(11) 0.049(10) 0.005(8) 0.026(10) 0.009(11) C28' 0.103(19) 0.065(13) 0.056(13) 0.022(11) 0.020(13) 0.028(13) C29' 0.224(60) 0.075(24) 0.042(17) -0.003(16) 0.029(25) 0.090(32) C30' 0.082(19) 0.100(20) 0.068(15) 0.027(15) 0.013(12) 0.049(17) C31' 0.048(11) 0.046(12) 0.062(12) 0.014(12) -0.010(9) 0.020(11) C32' 0.055(11) 0.077(12) 0.077(12) 0.038(10) 0.007(9) 0.022(9) C33' 0.080(15) 0.095(16) 0.079(14) 0.041(12) 0.008(12) 0.028(13) C34' 0.079(14) 0.070(13) 0.074(13) -0.010(11) -0.001(11) 0.041(12) Cl1 0.130(3) 0.078(2) 0.0540(13) 0.0274(13) 0.008(2) 0.006(2) O1 0.205(13) 0.206(13) 0.068(6) 0.050(7) -0.021(7) -0.022(10) O2 0.225(16) 0.132(10) 0.134(10) -0.001(8) 0.058(10) -0.009(10) O3 0.385(29) 0.359(26) 0.257(19) 0.235(20) 0.167(20) 0.233(24) O4 0.195(13) 0.216(13) 0.141(9) 0.103(10) 0.089(9) 0.079(11) C43 0.090(9) 0.093(9) 0.135(11) 0.039(8) 0.035(8) 0.022(7) Cl2 0.206(7) 0.188(6) 0.498(15) 0.079(8) 0.062(9) 0.136(6) Cl3 0.110(3) 0.158(4) 0.178(4) 0.099(3) 0.044(3) 0.025(3) Cl4 0.192(5) 0.139(4) 0.142(4) 0.063(3) 0.070(4) 0.045(3) C44 0.186(8) 0.292(10) 0.170(6) 0.031(7) 0.031(6) 0.065(7) Cl5 0.186(8) 0.292(10) 0.170(6) 0.031(7) 0.031(6) 0.065(7) Cl6 0.186(8) 0.292(10) 0.170(6) 0.031(7) 0.031(6) 0.065(7) Cl7 0.186(8) 0.292(10) 0.170(6) 0.031(7) 0.031(6) 0.065(7) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Pt C1 2.062(7) . ? Pt P1 2.240(2) . ? Pt S1 2.369(2) . ? Pt S2 2.405(2) . ? Pt Ag 2.8746(14) . ? Ag P2 2.383(2) . ? Ag S1 2.594(2) . ? S1 C22 1.736(8) . ? S2 C22 1.728(8) . ? P1 C3 1.809(7) . ? P1 C10 1.833(7) . ? P1 C17 1.844(7) . ? P2 C31 1.72(2) . ? P2 C37 1.812(9) . ? P2 C25' 1.84(3) . ? P2 C25 1.86(3) . ? P2 C31' 1.98(2) . ? N C22 1.329(10) . ? N C24 1.431(12) . ? N C23 1.453(12) . ? C1 C2 1.527(11) . ? C2 C3 1.387(10) . ? C2 C7 1.391(11) . ? C3 C4 1.421(10) . ? C4 C5 1.360(12) . ? C5 C6 1.409(14) . ? C6 C7 1.352(13) . ? C8 C9 1.522(11) . ? C9 C14 1.390(11) . ? C9 C10 1.424(10) . ? C10 C11 1.381(10) . ? C11 C12 1.406(10) . ? C12 C13 1.364(13) . ? C13 C14 1.393(13) . ? C15 C16 1.497(12) . ? C16 C21 1.372(12) . ? C16 C17 1.394(10) . ? C17 C18 1.394(10) . ? C18 C19 1.386(11) . ? C19 C20 1.360(13) . ? C20 C21 1.367(13) . ? C25 C30 1.39(4) . ? C25 C26 1.43(3) . ? C26 C27 1.45(6) . ? C27 C28 1.37(6) . ? C28 C29 1.34(5) . ? C29 C30 1.43(4) . ? C31 C32 1.40(3) . ? C31 C36 1.42(2) . ? C32 C33 1.45(3) . ? C33 C34 1.31(3) . ? C34 C35 1.38(3) . ? C35 C36 1.382(14) . ? C35 C34' 1.50(3) . ? C36 C31' 1.31(3) . ? C37 C42 1.392(12) . ? C37 C38 1.406(12) . ? C38 C39 1.383(14) . ? C39 C40 1.362(15) . ? C40 C41 1.401(14) . ? C41 C42 1.381(13) . ? C25' C30' 1.38(4) . ? C25' C26' 1.43(3) . ? C26' C27' 1.41(3) . ? C27' C28' 1.37(3) . ? C28' C29' 1.34(6) . ? C29' C30' 1.37(4) . ? C31' C32' 1.40(3) . ? C32' C33' 1.43(3) . ? C33' C34' 1.38(3) . ? Cl1 O1 1.322(10) . ? Cl1 O3 1.37(2) . ? Cl1 O2 1.396(13) . ? Cl1 O4 1.403(12) . ? C43 Cl2 1.69(2) . ? C43 Cl3 1.730(14) . ? C43 Cl4 1.791(15) . ? C44 Cl5 1.45(4) 2_756 ? C44 Cl5 1.72(2) . ? C44 Cl7 1.76(2) . ? C44 Cl6 1.79(2) . ? C44 C44 1.79(5) 2_756 ? Cl5 C44 1.45(4) 2_756 ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C1 Pt P1 85.0(2) . . ? C1 Pt S1 93.4(2) . . ? P1 Pt S1 175.31(6) . . ? C1 Pt S2 166.9(2) . . ? P1 Pt S2 107.74(7) . . ? S1 Pt S2 74.10(7) . . ? C1 Pt Ag 96.2(2) . . ? P1 Pt Ag 117.37(5) . . ? S1 Pt Ag 58.36(6) . . ? S2 Pt Ag 80.80(7) . . ? P2 Ag S1 164.96(8) . . ? P2 Ag Pt 131.51(7) . . ? S1 Ag Pt 51.03(5) . . ? C22 S1 Pt 87.1(3) . . ? C22 S1 Ag 91.6(3) . . ? Pt S1 Ag 70.61(6) . . ? C22 S2 Pt 86.2(3) . . ? C3 P1 C10 106.6(3) . . ? C3 P1 C17 103.1(3) . . ? C10 P1 C17 106.6(3) . . ? C3 P1 Pt 103.7(2) . . ? C10 P1 Pt 114.0(2) . . ? C17 P1 Pt 121.4(2) . . ? C31 P2 C37 101.1(7) . . ? C37 P2 C25' 108.0(8) . . ? C31 P2 C25 108.6(10) . . ? C37 P2 C25 100.9(9) . . ? C37 P2 C31' 106.5(9) . . ? C25' P2 C31' 103.8(10) . . ? C31 P2 Ag 122.4(8) . . ? C37 P2 Ag 113.8(3) . . ? C25' P2 Ag 118.8(7) . . ? C25 P2 Ag 108.0(8) . . ? C31' P2 Ag 104.7(7) . . ? C22 N C24 121.9(8) . . ? C22 N C23 121.3(8) . . ? C24 N C23 116.8(8) . . ? C2 C1 Pt 117.3(5) . . ? C3 C2 C7 118.9(7) . . ? C3 C2 C1 118.5(6) . . ? C7 C2 C1 122.5(7) . . ? C2 C3 C4 120.0(7) . . ? C2 C3 P1 115.5(5) . . ? C4 C3 P1 124.4(6) . . ? C5 C4 C3 119.7(8) . . ? C4 C5 C6 119.4(8) . . ? C7 C6 C5 120.9(8) . . ? C6 C7 C2 120.9(9) . . ? C14 C9 C10 118.6(7) . . ? C14 C9 C8 117.6(7) . . ? C10 C9 C8 123.8(7) . . ? C11 C10 C9 119.5(6) . . ? C11 C10 P1 118.4(5) . . ? C9 C10 P1 122.0(5) . . ? C10 C11 C12 120.4(7) . . ? C13 C12 C11 120.2(8) . . ? C12 C13 C14 120.1(8) . . ? C9 C14 C13 121.0(8) . . ? C21 C16 C17 118.1(8) . . ? C21 C16 C15 120.1(7) . . ? C17 C16 C15 121.8(7) . . ? C18 C17 C16 118.8(7) . . ? C18 C17 P1 120.0(5) . . ? C16 C17 P1 121.0(6) . . ? C19 C18 C17 121.2(8) . . ? C20 C19 C18 119.1(9) . . ? C19 C20 C21 119.7(8) . . ? C20 C21 C16 122.9(8) . . ? N C22 S2 124.0(6) . . ? N C22 S1 123.7(6) . . ? S2 C22 S1 112.3(4) . . ? C30 C25 C26 120.4(29) . . ? C30 C25 P2 115.8(20) . . ? C26 C25 P2 123.8(21) . . ? C25 C26 C27 122.1(27) . . ? C28 C27 C26 111.9(33) . . ? C29 C28 C27 128.5(39) . . ? C28 C29 C30 119.8(27) . . ? C25 C30 C29 116.8(28) . . ? C32 C31 C36 113.4(17) . . ? C32 C31 P2 120.4(15) . . ? C36 C31 P2 126.0(15) . . ? C31 C32 C33 117.9(21) . . ? C34 C33 C32 122.6(21) . . ? C33 C34 C35 122.6(19) . . ? C36 C35 C34 112.5(12) . . ? C36 C35 C34' 116.8(12) . . ? C31' C36 C35 118.0(14) . . ? C35 C36 C31 127.8(12) . . ? C42 C37 C38 118.3(8) . . ? C42 C37 P2 120.0(6) . . ? C38 C37 P2 121.7(7) . . ? C39 C38 C37 121.0(10) . . ? C40 C39 C38 119.9(9) . . ? C39 C40 C41 120.4(9) . . ? C42 C41 C40 119.8(10) . . ? C41 C42 C37 120.6(9) . . ? C30' C25' C26' 120.7(23) . . ? C30' C25' P2 116.6(18) . . ? C26' C25' P2 122.5(19) . . ? C27' C26' C25' 118.1(21) . . ? C28' C27' C26' 120.1(21) . . ? C29' C28' C27' 117.2(22) . . ? C28' C29' C30' 126.9(34) . . ? C29' C30' C25' 115.1(31) . . ? C36 C31' C32' 129.2(20) . . ? C36 C31' P2 115.1(16) . . ? C32' C31' P2 115.7(20) . . ? C31' C32' C33' 114.5(21) . . ? C34' C33' C32' 119.5(20) . . ? C33' C34' C35 120.9(17) . . ? O1 Cl1 O3 101.8(11) . . ? O1 Cl1 O2 110.7(8) . . ? O3 Cl1 O2 100.7(13) . . ? O1 Cl1 O4 118.9(9) . . ? O3 Cl1 O4 107.9(9) . . ? O2 Cl1 O4 114.3(8) . . ? Cl2 C43 Cl3 111.4(9) . . ? Cl2 C43 Cl4 108.6(10) . . ? Cl3 C43 Cl4 105.3(8) . . ? Cl5 C44 Cl5 112.0(17) 2_756 . ? Cl5 C44 Cl7 115.1(19) 2_756 . ? Cl5 C44 Cl7 104.5(14) . . ? Cl5 C44 Cl6 112.2(18) 2_756 . ? Cl5 C44 Cl6 112.2(16) . . ? Cl7 C44 Cl6 100.2(13) . . ? Cl5 C44 C44 63.1(18) 2_756 2_756 ? Cl5 C44 C44 48.9(14) . 2_756 ? Cl7 C44 C44 125.8(20) . 2_756 ? Cl6 C44 C44 132.1(21) . 2_756 ? C44 Cl5 C44 68.0(17) 2_756 . ? _refine_diff_density_max 2.702 _refine_diff_density_min -1.972 _refine_diff_density_rms 0.149 # ==== END data_5 _audit_creation_method SHELXL _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_formula_moiety ? _chemical_formula_structural ? _chemical_formula_analytical ? _chemical_formula_sum ; 'C49.25 H55.25 Ag2 Cl3.50 N2 O8.50 P2 Pt2 S4' ; _chemical_formula_weight 1731.38 _chemical_melting_point ? _chemical_compound_source ? loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'P' 'P' 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'S' 'S' 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Cl' 'Cl' 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Ag' 'Ag' -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Pt' 'Pt' -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting triclinic _symmetry_space_group_name_H-M P-1 loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 13.174(3) _cell_length_b 14.388(3) _cell_length_c 17.637(3) _cell_angle_alpha 84.071(12) _cell_angle_beta 85.845(12) _cell_angle_gamma 83.872(12) _cell_volume 3300.0(10) _cell_formula_units_Z 2 _cell_measurement_temperature 293(2) _cell_measurement_reflns_used 202 _cell_measurement_theta_min ? _cell_measurement_theta_max ? _exptl_crystal_description ? _exptl_crystal_colour ? _exptl_crystal_size_max 0.55 _exptl_crystal_size_mid 0.45 _exptl_crystal_size_min 0.35 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.742 _exptl_crystal_density_method ? _exptl_crystal_F_000 1673 _exptl_absorpt_coefficient_mu 5.173 _exptl_absorpt_correction_type ? _exptl_absorpt_correction_T_min ? _exptl_absorpt_correction_T_max ? _exptl_special_details ; ? ; _diffrn_ambient_temperature 293(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device 'Siemens three-circle SMART' _diffrn_measurement_method ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 14032 _diffrn_reflns_av_R_equivalents 0.0291 _diffrn_reflns_av_sigmaI/netI 0.0372 _diffrn_reflns_limit_h_min -14 _diffrn_reflns_limit_h_max 10 _diffrn_reflns_limit_k_min -15 _diffrn_reflns_limit_k_max 15 _diffrn_reflns_limit_l_min -19 _diffrn_reflns_limit_l_max 19 _diffrn_reflns_theta_min 1.56 _diffrn_reflns_theta_max 23.27 _reflns_number_total 9203 _reflns_number_observed 7927 _reflns_observed_criterion >2sigma(I) _computing_data_collection 'SMART Siemens Molecular Analysis Research Tool V4.014 copyright 1989-94 SAXI' _computing_cell_refinement ? _computing_data_reduction 'SAINT (Siemens Area detector INTegration) program V4.021' _computing_structure_solution 'SHELXS-90(Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-93 (Sheldrick, 1993)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement on F^2^ for ALL reflections except for 3 with very negative F^2^ or flagged by the user for potential systematic errors. Weighted R-factors wR and all goodnesses of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The observed criterion of F^2^ > 2sigma(F^2^) is used only for calculating _R_factor_obs etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme 'calc w=1/[\s^2^(Fo^2^)+(0.0600P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment ? _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 9200 _refine_ls_number_parameters 707 _refine_ls_number_restraints 36 _refine_ls_R_factor_all 0.0625 _refine_ls_R_factor_obs 0.0511 _refine_ls_wR_factor_all 0.1634 _refine_ls_wR_factor_obs 0.1517 _refine_ls_goodness_of_fit_all 1.837 _refine_ls_goodness_of_fit_obs 1.849 _refine_ls_restrained_S_all 1.846 _refine_ls_restrained_S_obs 1.858 _refine_ls_shift/esd_max 0.001 _refine_ls_shift/esd_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_thermal_displace_type _atom_site_occupancy _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_group Pt1 Pt -0.76704(3) -0.75896(3) 0.23673(2) 0.0437(2) Uani 1 d . . Pt2 Pt -0.85367(3) -0.44880(3) 0.31610(2) 0.0499(2) Uani 1 d . . Ag1 Ag -0.72859(9) -0.51633(7) 0.18654(6) 0.0731(3) Uani 1 d . . Ag2 Ag -0.9059(2) -0.6140(2) 0.1845(2) 0.0926(9) Uani 0.50 d P 1 O9 O -0.9807(20) -0.5665(19) 0.0758(16) 0.131(9) Uani 0.50 d P 1 Ag2' Ag -0.9082(2) -0.6114(2) 0.2391(2) 0.0851(8) Uani 0.50 d P 2 P1 P -0.8935(2) -0.8351(2) 0.29688(15) 0.0436(6) Uani 1 d . . P2 P -0.7164(2) -0.4251(2) 0.3755(2) 0.0486(7) Uani 1 d . . S1 S -0.6339(2) -0.6743(2) 0.1789(2) 0.0526(7) Uani 1 d . . S2 S -0.7817(3) -0.7575(3) 0.1013(2) 0.0676(9) Uani 1 d . . S3 S -1.0038(3) -0.4712(3) 0.2569(2) 0.0827(11) Uani 1 d . . S4 S -0.8462(3) -0.3551(2) 0.1949(2) 0.0619(8) Uani 1 d . . N1 N -0.6087(7) -0.7008(7) 0.0301(5) 0.056(2) Uani 1 d . . N2 N -1.0270(10) -0.3516(8) 0.1306(6) 0.086(4) Uani 1 d . . C1 C -0.7211(9) -0.7503(9) 0.3445(6) 0.063(3) Uani 1 d . . H1A H -0.6484(9) -0.7701(9) 0.3447(6) 0.114(8) Uiso 1 calc R . H1B H -0.7306(9) -0.6848(9) 0.3547(6) 0.114(8) Uiso 1 calc R . C2 C -0.7750(9) -0.8071(8) 0.4095(6) 0.055(3) Uani 1 d . . C3 C -0.8589(8) -0.8518(7) 0.3957(6) 0.049(3) Uani 1 d . . C4 C -0.9089(10) -0.9046(8) 0.4546(6) 0.062(3) Uani 1 d . . H4A H -0.9656(10) -0.9340(8) 0.4450(6) 0.114(8) Uiso 1 calc R . C5 C -0.8748(13) -0.9131(10) 0.5265(7) 0.082(4) Uani 1 d . . H5A H -0.9089(13) -0.9472(10) 0.5663(7) 0.114(8) Uiso 1 calc R . C6 C -0.7910(12) -0.8716(10) 0.5396(7) 0.076(4) Uani 1 d . . H6A H -0.7666(12) -0.8794(10) 0.5882(7) 0.114(8) Uiso 1 calc R . C7 C -0.7425(10) -0.8194(9) 0.4838(7) 0.069(3) Uani 1 d . . H7A H -0.6860(10) -0.7907(9) 0.4948(7) 0.114(8) Uiso 1 calc R . C8 C -0.7358(11) -1.0066(9) 0.2573(9) 0.089(5) Uani 1 d . . H8A H -0.7287(11) -0.9434(9) 0.2674(9) 0.114(8) Uiso 1 calc R . H8B H -0.7050(11) -1.0174(9) 0.2076(9) 0.114(8) Uiso 1 calc R . H8C H -0.7024(11) -1.0498(9) 0.2951(9) 0.114(8) Uiso 1 calc R . C9 C -0.8434(10) -1.0207(8) 0.2602(8) 0.066(3) Uani 1 d . . C10 C -0.9218(9) -0.9516(8) 0.2758(6) 0.053(3) Uani 1 d . . C11 C -1.0231(10) -0.9703(9) 0.2792(6) 0.064(3) Uani 1 d . . H11A H -1.0742(10) -0.9232(9) 0.2907(6) 0.114(8) Uiso 1 calc R . C12 C -1.0501(12) -1.0567(9) 0.2661(7) 0.072(4) Uani 1 d . . H12A H -1.1186(12) -1.0675(9) 0.2679(7) 0.114(8) Uiso 1 calc R . C13 C -0.9753(13) -1.1264(10) 0.2504(8) 0.076(4) Uani 1 d . . H13A H -0.9915(13) -1.1856(10) 0.2418(8) 0.114(8) Uiso 1 calc R . C14 C -0.8743(13) -1.1062(9) 0.2477(8) 0.084(4) Uani 1 d . . H14A H -0.8236(13) -1.1538(9) 0.2366(8) 0.114(8) Uiso 1 calc R . C15 C -1.0400(10) -0.7826(9) 0.1540(6) 0.067(3) Uani 1 d . . H15A H -0.9792(10) -0.8252(9) 0.1600(6) 0.114(8) Uiso 1 calc R . H15B H -1.0278(10) -0.7350(9) 0.1130(6) 0.114(8) Uiso 1 calc R . H15C H -1.0949(10) -0.8165(9) 0.1425(6) 0.114(8) Uiso 1 calc R . C16 C -1.0688(9) -0.7361(8) 0.2286(6) 0.055(3) Uani 1 d . . C17 C -1.0150(8) -0.7579(7) 0.2950(6) 0.046(2) Uani 1 d . . C18 C -1.0507(9) -0.7170(8) 0.3613(6) 0.054(3) Uani 1 d . . H18A H -1.0164(9) -0.7334(8) 0.4057(6) 0.114(8) Uiso 1 calc R . C19 C -1.1353(9) -0.6530(9) 0.3620(7) 0.064(3) Uani 1 d . . H19A H -1.1572(9) -0.6254(9) 0.4066(7) 0.114(8) Uiso 1 calc R . C20 C -1.1883(10) -0.6293(10) 0.2972(9) 0.079(4) Uani 1 d . . H20A H -1.2457(10) -0.5856(10) 0.2976(9) 0.114(8) Uiso 1 calc R . C21 C -1.1558(9) -0.6708(10) 0.2322(8) 0.071(4) Uani 1 d . . H21A H -1.1926(9) -0.6553(10) 0.1888(8) 0.114(8) Uiso 1 calc R . C22 C -0.6670(9) -0.7066(8) 0.0922(6) 0.053(3) Uani 1 d . . C23 C -0.6325(12) -0.7341(11) -0.0418(7) 0.086(4) Uani 1 d . . H23A H -0.5784(12) -0.7224(11) -0.0800(7) 0.114(8) Uiso 1 calc R . H23B H -0.6956(12) -0.7014(11) -0.0584(7) 0.114(8) Uiso 1 calc R . H23C H -0.6390(12) -0.8003(11) -0.0340(7) 0.114(8) Uiso 1 calc R . C24 C -0.5167(9) -0.6578(11) 0.0254(7) 0.076(4) Uani 1 d . . H24A H -0.4845(9) -0.6603(11) -0.0250(7) 0.114(8) Uiso 1 calc R . H24B H -0.4718(9) -0.6904(11) 0.0620(7) 0.114(8) Uiso 1 calc R . H24C H -0.5314(9) -0.5935(11) 0.0361(7) 0.114(8) Uiso 1 calc R . C25 C -0.8903(9) -0.5353(10) 0.4134(7) 0.070(4) Uani 1 d . . H25A H -0.9570(9) -0.5120(10) 0.4348(7) 0.114(8) Uiso 1 calc R . H25B H -0.8957(9) -0.5977(10) 0.3989(7) 0.114(8) Uiso 1 calc R . C26 C -0.8129(9) -0.5432(8) 0.4763(7) 0.059(3) Uani 1 d . . C27 C -0.7280(9) -0.4949(8) 0.4670(6) 0.054(3) Uani 1 d . . C28 C -0.6610(10) -0.5000(9) 0.5250(7) 0.063(3) Uani 1 d . . H28A H -0.6045(10) -0.4657(9) 0.5178(7) 0.114(8) Uiso 1 calc R . C29 C -0.6760(11) -0.5530(11) 0.5909(8) 0.078(4) Uani 1 d . . H29A H -0.6300(11) -0.5565(11) 0.6290(8) 0.114(8) Uiso 1 calc R . C30 C -0.7589(14) -0.6015(11) 0.6012(8) 0.092(5) Uani 1 d . . H30A H -0.7689(14) -0.6394(11) 0.6466(8) 0.114(8) Uiso 1 calc R . C31 C -0.8292(11) -0.5965(10) 0.5464(8) 0.076(4) Uani 1 d . . H31A H -0.8873(11) -0.6283(10) 0.5559(8) 0.114(8) Uiso 1 calc R . C32 C -0.8887(11) -0.2701(11) 0.4297(9) 0.091(5) Uani 1 d . . H32A H -0.8915(11) -0.3294(11) 0.4101(9) 0.114(8) Uiso 1 calc R . H32B H -0.9302(11) -0.2223(11) 0.4007(9) 0.114(8) Uiso 1 calc R . H32C H -0.9138(11) -0.2737(11) 0.4823(9) 0.114(8) Uiso 1 calc R . C33 C -0.7850(13) -0.2472(9) 0.4239(7) 0.079(4) Uani 1 d . . C34 C -0.6965(10) -0.3086(9) 0.4006(7) 0.067(3) Uani 1 d . . C35 C -0.5978(13) -0.2834(11) 0.3988(9) 0.092(5) Uani 1 d . . H35A H -0.5429(13) -0.3242(11) 0.3823(9) 0.114(8) Uiso 1 calc R . C36 C -0.5808(18) -0.1977(14) 0.4214(13) 0.128(7) Uani 1 d . . H36A H -0.5141(18) -0.1816(14) 0.4191(13) 0.114(8) Uiso 1 calc R . C37 C -0.6575(25) -0.1362(16) 0.4469(15) 0.152(11) Uani 1 d . . H37A H -0.6447(25) -0.0790(16) 0.4625(15) 0.114(8) Uiso 1 calc R . C38 C -0.7554(23) -0.1620(11) 0.4487(9) 0.138(10) Uani 1 d . . H38A H -0.8077(23) -0.1204(11) 0.4678(9) 0.114(8) Uiso 1 calc R . C39 C -0.5987(11) -0.3278(9) 0.2216(8) 0.076(4) Uani 1 d . . H39A H -0.6542(11) -0.3017(9) 0.2536(8) 0.114(8) Uiso 1 calc R . H39B H -0.6215(11) -0.3311(9) 0.1715(8) 0.114(8) Uiso 1 calc R . H39C H -0.5435(11) -0.2888(9) 0.2180(8) 0.114(8) Uiso 1 calc R . C40 C -0.5623(9) -0.4250(9) 0.2553(7) 0.061(3) Uani 1 d . . C41 C -0.6001(8) -0.4701(8) 0.3252(6) 0.050(3) Uani 1 d . . C42 C -0.5559(8) -0.5578(8) 0.3512(7) 0.055(3) Uani 1 d . . H42A H -0.5796(8) -0.5870(8) 0.3976(7) 0.114(8) Uiso 1 calc R . C43 C -0.4741(9) -0.6041(10) 0.3073(9) 0.071(4) Uani 1 d . . H43A H -0.4451(9) -0.6634(10) 0.3250(9) 0.114(8) Uiso 1 calc R . C44 C -0.4387(11) -0.5617(12) 0.2399(8) 0.080(4) Uani 1 d . . H44A H -0.3864(11) -0.5921(12) 0.2106(8) 0.114(8) Uiso 1 calc R . C45 C -0.4822(10) -0.4705(11) 0.2144(8) 0.076(4) Uani 1 d . . H45A H -0.4560(10) -0.4405(11) 0.1691(8) 0.114(8) Uiso 1 calc R . C46 C -0.9641(10) -0.3880(8) 0.1837(7) 0.062(3) Uani 1 d . . C47 C -0.9965(16) -0.2761(12) 0.0746(9) 0.120(7) Uani 1 d . . H47A H -1.0501(16) -0.2576(12) 0.0404(9) 0.114(8) Uiso 1 calc R . H47B H -0.9352(16) -0.2977(12) 0.0461(9) 0.114(8) Uiso 1 calc R . H47C H -0.9840(16) -0.2232(12) 0.1005(9) 0.114(8) Uiso 1 calc R . C48 C -1.1285(13) -0.3872(16) 0.1264(11) 0.133(8) Uani 1 d . . H48A H -1.1633(13) -0.3527(16) 0.0847(11) 0.114(8) Uiso 1 calc R . H48B H -1.1687(13) -0.3790(16) 0.1733(11) 0.114(8) Uiso 1 calc R . H48C H -1.1188(13) -0.4526(16) 0.1185(11) 0.114(8) Uiso 1 calc R . Cl1 Cl -0.7420(3) -0.4454(3) -0.0078(2) 0.0773(9) Uani 1 d . . O1 O -0.6724(9) -0.4509(10) 0.0510(6) 0.120(4) Uani 1 d . . O2 O -0.8237(11) -0.4894(14) 0.0267(9) 0.176(8) Uani 1 d . . O3 O -0.7739(20) -0.3585(13) -0.0272(11) 0.250(12) Uani 1 d . . O4 O -0.7002(10) -0.4947(11) -0.0681(7) 0.139(5) Uani 1 d . . Cl2 Cl -0.3124(6) -0.1941(3) 0.2334(3) 0.128(2) Uani 1 d D . O5 O -0.3497(23) -0.2752(14) 0.2282(21) 0.161(11) Uani 0.54(3) d PD 1 O6 O -0.3209(28) -0.1359(16) 0.1743(11) 0.161(11) Uani 0.54(3) d PD 1 O7 O -0.3408(22) -0.1584(21) 0.2985(12) 0.161(11) Uani 0.54(3) d PD 1 O8 O -0.2072(13) -0.2183(19) 0.2404(18) 0.161(11) Uani 0.54(3) d PD 1 O5' O -0.3373(30) -0.2802(14) 0.2361(23) 0.173(12) Uani 0.46(3) d PD 2 O6' O -0.2377(21) -0.1773(27) 0.1805(16) 0.173(12) Uani 0.46(3) d PD 2 O7' O -0.3965(22) -0.1412(21) 0.2001(19) 0.173(12) Uani 0.46(3) d PD 2 O8' O -0.2990(26) -0.1603(26) 0.2954(13) 0.173(12) Uani 0.46(3) d PD 2 Cl3 Cl -0.6943(8) -0.1151(10) 0.6720(9) 0.177(6) Uani 0.50 d PD . Cl4 Cl -0.5215(11) -0.1118(12) 0.7552(10) 0.230(9) Uani 0.50 d PD . C49 C -0.5960(16) -0.0595(19) 0.6879(14) 0.103(22) Uani 0.30 d PD 1 Cl5 Cl -0.5184(13) -0.0521(13) 0.6086(10) 0.140(7) Uani 0.30 d PD 1 C49' C -0.6478(19) -0.0810(27) 0.7507(16) 0.162(50) Uiso 0.20 d PD 2 Cl5' Cl -0.6958(24) -0.1520(37) 0.8241(14) 0.235(20) Uiso 0.20 d PD 2 C50 C -0.0482(17) 0.0258(52) 0.0179(42) 0.144(31) Uiso 0.25 d PD . C51 C -0.1434(19) -0.0090(60) -0.0093(73) 0.213(53) Uiso 0.25 d PD . C52 C -0.2341(40) 0.0675(81) -0.0057(81) 0.229(58) Uiso 0.25 d PD . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Pt1 0.0430(3) 0.0451(3) 0.0435(3) -0.0054(2) -0.0011(2) -0.0059(2) Pt2 0.0452(3) 0.0556(3) 0.0499(3) -0.0083(2) -0.0073(2) -0.0028(2) Ag1 0.0829(7) 0.0637(6) 0.0719(6) -0.0196(5) 0.0128(5) -0.0025(5) Ag2 0.093(2) 0.0565(14) 0.130(2) -0.018(2) -0.042(2) 0.0139(12) O9 0.109(20) 0.131(21) 0.151(23) -0.004(18) 0.004(17) -0.014(16) Ag2' 0.0636(15) 0.0471(12) 0.140(2) -0.007(2) 0.014(2) -0.0016(10) P1 0.046(2) 0.0473(15) 0.0388(14) -0.0071(11) -0.0017(12) -0.0073(12) P2 0.046(2) 0.054(2) 0.048(2) -0.0151(13) -0.0036(13) -0.0059(13) S1 0.052(2) 0.059(2) 0.049(2) -0.0050(13) -0.0027(13) -0.0149(13) S2 0.069(2) 0.095(2) 0.045(2) -0.007(2) -0.0023(15) -0.035(2) S3 0.072(2) 0.086(2) 0.094(3) 0.008(2) -0.034(2) -0.024(2) S4 0.077(2) 0.056(2) 0.055(2) -0.0084(14) -0.008(2) -0.008(2) N1 0.045(5) 0.073(6) 0.050(6) 0.000(5) 0.004(4) -0.011(5) N2 0.104(10) 0.083(8) 0.068(7) -0.010(6) -0.029(7) 0.023(7) C1 0.058(7) 0.088(9) 0.048(7) -0.005(6) -0.010(6) -0.029(7) C2 0.058(7) 0.057(7) 0.052(7) -0.017(5) -0.004(6) 0.003(6) C3 0.051(7) 0.047(6) 0.048(6) -0.010(5) 0.000(5) -0.002(5) C4 0.074(8) 0.061(7) 0.053(7) 0.000(6) -0.009(6) -0.015(6) C5 0.119(13) 0.080(9) 0.045(7) 0.001(7) 0.005(8) -0.017(9) C6 0.101(11) 0.082(9) 0.050(8) -0.003(7) -0.017(7) -0.022(8) C7 0.066(8) 0.077(9) 0.067(8) -0.004(7) -0.024(7) -0.010(7) C8 0.086(11) 0.058(8) 0.119(13) -0.016(8) 0.001(9) 0.009(7) C9 0.069(9) 0.048(7) 0.080(9) -0.009(6) -0.004(7) 0.000(6) C10 0.069(8) 0.053(6) 0.039(6) -0.004(5) -0.012(5) -0.009(6) C11 0.079(9) 0.070(8) 0.047(7) -0.011(6) 0.004(6) -0.031(7) C12 0.092(10) 0.062(8) 0.070(8) -0.007(7) -0.004(7) -0.039(8) C13 0.099(12) 0.058(8) 0.077(9) -0.011(7) -0.008(8) -0.026(8) C14 0.107(13) 0.047(8) 0.094(11) -0.010(7) -0.004(9) 0.009(8) C15 0.072(8) 0.090(9) 0.042(6) -0.013(6) -0.010(6) -0.018(7) C16 0.047(7) 0.068(7) 0.052(7) 0.001(5) -0.006(5) -0.017(6) C17 0.042(6) 0.050(6) 0.046(6) -0.001(5) -0.005(5) -0.010(5) C18 0.055(7) 0.060(7) 0.048(6) -0.012(5) -0.003(5) 0.000(6) C19 0.049(7) 0.080(9) 0.063(8) -0.017(7) -0.003(6) 0.007(6) C20 0.050(8) 0.080(9) 0.104(11) -0.022(8) 0.001(8) 0.021(7) C21 0.040(7) 0.091(9) 0.083(9) 0.001(8) -0.019(6) -0.003(7) C22 0.051(7) 0.057(7) 0.053(7) 0.000(5) -0.008(6) -0.016(5) C23 0.104(12) 0.108(12) 0.051(8) -0.013(8) 0.004(7) -0.029(9) C24 0.042(7) 0.116(11) 0.070(8) 0.001(8) -0.005(6) -0.016(7) C25 0.046(7) 0.104(10) 0.058(7) 0.015(7) -0.003(6) -0.014(7) C26 0.054(7) 0.060(7) 0.060(7) 0.004(6) -0.005(6) 0.001(6) C27 0.048(7) 0.063(7) 0.051(7) -0.008(5) -0.003(5) 0.002(6) C28 0.058(8) 0.075(8) 0.057(7) -0.013(6) 0.000(6) -0.003(6) C29 0.055(8) 0.105(11) 0.074(10) -0.014(8) -0.006(7) 0.004(8) C30 0.112(14) 0.101(12) 0.050(8) 0.016(7) -0.013(8) 0.038(10) C31 0.072(9) 0.076(9) 0.074(9) 0.019(7) -0.008(7) -0.005(7) C32 0.080(11) 0.105(11) 0.084(10) -0.039(9) 0.007(8) 0.035(9) C33 0.113(13) 0.066(8) 0.056(8) -0.009(6) -0.005(8) 0.001(8) C34 0.072(9) 0.067(8) 0.067(8) -0.025(6) -0.007(7) -0.010(7) C35 0.093(12) 0.081(10) 0.114(12) -0.038(9) -0.025(10) -0.019(9) C36 0.136(18) 0.093(14) 0.168(20) -0.026(14) -0.014(15) -0.062(13) C37 0.215(31) 0.087(15) 0.176(23) -0.040(15) -0.029(21) -0.073(18) C38 0.278(33) 0.058(10) 0.072(11) -0.025(8) 0.018(15) 0.006(14) C39 0.071(9) 0.080(9) 0.077(9) -0.003(7) 0.001(7) -0.020(7) C40 0.040(6) 0.087(9) 0.062(7) -0.017(7) -0.003(6) -0.023(6) C41 0.040(6) 0.058(7) 0.055(7) -0.012(5) -0.010(5) -0.013(5) C42 0.046(7) 0.064(7) 0.058(7) -0.005(6) -0.006(5) -0.016(6) C43 0.046(7) 0.075(9) 0.095(11) -0.032(8) -0.013(7) 0.006(6) C44 0.061(9) 0.112(12) 0.073(9) -0.050(9) 0.002(7) -0.008(8) C45 0.051(8) 0.113(12) 0.067(8) -0.020(8) 0.001(6) -0.015(8) C46 0.068(8) 0.056(7) 0.063(7) -0.007(6) -0.020(6) 0.004(6) C47 0.170(19) 0.110(13) 0.070(10) 0.009(10) -0.047(11) 0.037(13) C48 0.079(12) 0.204(22) 0.122(15) -0.048(15) -0.057(11) 0.020(13) Cl1 0.068(2) 0.096(3) 0.069(2) -0.011(2) 0.001(2) -0.010(2) O1 0.079(8) 0.199(13) 0.085(7) -0.013(8) -0.009(6) -0.031(8) O2 0.127(12) 0.268(20) 0.164(13) -0.103(14) 0.037(10) -0.113(13) O3 0.361(31) 0.156(15) 0.187(17) 0.051(13) -0.015(18) 0.128(18) O4 0.120(10) 0.216(15) 0.086(8) -0.062(9) 0.016(7) -0.005(10) Cl2 0.221(7) 0.082(3) 0.090(3) -0.016(2) -0.053(4) -0.028(4) O5 0.192(20) 0.140(15) 0.159(18) -0.042(11) -0.045(12) -0.003(12) O6 0.192(20) 0.140(15) 0.159(18) -0.042(11) -0.045(12) -0.003(12) O7 0.192(20) 0.140(15) 0.159(18) -0.042(11) -0.045(12) -0.003(12) O8 0.192(20) 0.140(15) 0.159(18) -0.042(11) -0.045(12) -0.003(12) O5' 0.208(23) 0.186(22) 0.139(19) -0.011(15) -0.074(15) -0.037(17) O6' 0.208(23) 0.186(22) 0.139(19) -0.011(15) -0.074(15) -0.037(17) O7' 0.208(23) 0.186(22) 0.139(19) -0.011(15) -0.074(15) -0.037(17) O8' 0.208(23) 0.186(22) 0.139(19) -0.011(15) -0.074(15) -0.037(17) Cl3 0.095(8) 0.165(11) 0.271(18) -0.030(11) -0.001(10) -0.009(8) Cl4 0.145(13) 0.216(16) 0.315(23) -0.022(15) -0.061(13) 0.081(12) C49 0.079(34) 0.028(21) 0.207(68) -0.022(29) -0.074(42) 0.021(21) Cl5 0.106(13) 0.118(13) 0.203(20) -0.019(13) -0.006(13) -0.033(10) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Pt1 C1 2.056(11) . ? Pt1 P1 2.235(3) . ? Pt1 S1 2.354(3) . ? Pt1 S2 2.408(3) . ? Pt1 Ag2' 2.671(3) . ? Pt1 Ag2 2.752(3) . ? Pt2 C25 2.073(12) . ? Pt2 P2 2.228(3) . ? Pt2 S3 2.369(3) . ? Pt2 S4 2.409(3) . ? Pt2 Ag1 2.9074(11) . ? Pt2 Ag2' 2.999(3) . ? Ag1 S1 2.485(3) . ? Ag1 O1 2.564(11) . ? Ag1 S4 2.660(3) . ? Ag1 Ag2 2.856(3) . ? Ag1 Ag2' 2.905(3) . ? Ag2 O9 2.23(3) . ? Ag2 S3 2.694(5) . ? Ag2 S2 2.940(5) . ? Ag2' S3 2.299(5) . ? P1 C3 1.819(11) . ? P1 C10 1.835(11) . ? P1 C17 1.850(11) . ? P2 C41 1.806(11) . ? P2 C27 1.815(11) . ? P2 C34 1.827(12) . ? S1 C22 1.740(11) . ? S2 C22 1.738(11) . ? S3 C46 1.759(13) . ? S4 C46 1.703(13) . ? N1 C22 1.292(13) . ? N1 C24 1.411(15) . ? N1 C23 1.47(2) . ? N2 C46 1.32(2) . ? N2 C47 1.46(2) . ? N2 C48 1.49(2) . ? C1 C2 1.52(2) . ? C2 C3 1.38(2) . ? C2 C7 1.40(2) . ? C3 C4 1.39(2) . ? C4 C5 1.37(2) . ? C5 C6 1.35(2) . ? C6 C7 1.34(2) . ? C8 C9 1.45(2) . ? C9 C14 1.38(2) . ? C9 C10 1.39(2) . ? C10 C11 1.39(2) . ? C11 C12 1.38(2) . ? C12 C13 1.36(2) . ? C13 C14 1.39(2) . ? C15 C16 1.54(2) . ? C16 C21 1.40(2) . ? C16 C17 1.402(15) . ? C17 C18 1.393(14) . ? C18 C19 1.37(2) . ? C19 C20 1.38(2) . ? C20 C21 1.37(2) . ? C25 C26 1.55(2) . ? C26 C27 1.37(2) . ? C26 C31 1.40(2) . ? C27 C28 1.39(2) . ? C28 C29 1.34(2) . ? C29 C30 1.35(2) . ? C30 C31 1.38(2) . ? C32 C33 1.43(2) . ? C33 C38 1.44(2) . ? C33 C34 1.45(2) . ? C34 C35 1.38(2) . ? C35 C36 1.38(2) . ? C36 C37 1.35(3) . ? C37 C38 1.38(3) . ? C39 C40 1.50(2) . ? C40 C45 1.38(2) . ? C40 C41 1.42(2) . ? C41 C42 1.38(2) . ? C42 C43 1.43(2) . ? C43 C44 1.35(2) . ? C44 C45 1.42(2) . ? Cl1 O3 1.30(2) . ? Cl1 O2 1.378(14) . ? Cl1 O4 1.388(11) . ? Cl1 O1 1.423(11) . ? Cl2 O6 1.272(15) . ? Cl2 O8' 1.27(2) . ? Cl2 O5' 1.31(2) . ? Cl2 O7 1.319(15) . ? Cl2 O6' 1.33(2) . ? Cl2 O5 1.329(14) . ? Cl2 O7' 1.41(2) . ? Cl2 O8 1.40(2) . ? Cl3 C49 1.65(2) . ? Cl3 C49' 1.69(2) . ? Cl4 C49 1.66(2) . ? Cl4 C49' 1.68(2) . ? C49 Cl5 1.67(2) . ? C49' Cl5' 1.69(2) . ? C50 C51 1.52(2) . ? C50 C50 1.53(2) 2 ? C51 C52 1.54(2) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C1 Pt1 P1 85.1(3) . . ? C1 Pt1 S1 92.4(3) . . ? P1 Pt1 S1 177.05(9) . . ? C1 Pt1 S2 166.5(3) . . ? P1 Pt1 S2 108.08(10) . . ? S1 Pt1 S2 74.53(10) . . ? C1 Pt1 Ag2' 95.3(4) . . ? P1 Pt1 Ag2' 82.93(9) . . ? S1 Pt1 Ag2' 95.83(9) . . ? S2 Pt1 Ag2' 89.50(12) . . ? C1 Pt1 Ag2 114.9(4) . . ? P1 Pt1 Ag2 90.64(11) . . ? S1 Pt1 Ag2 89.06(11) . . ? S2 Pt1 Ag2 69.11(12) . . ? C25 Pt2 P2 85.6(4) . . ? C25 Pt2 S3 93.4(4) . . ? P2 Pt2 S3 177.69(13) . . ? C25 Pt2 S4 167.7(3) . . ? P2 Pt2 S4 106.68(11) . . ? S3 Pt2 S4 74.37(12) . . ? C25 Pt2 Ag1 122.9(4) . . ? P2 Pt2 Ag1 92.05(8) . . ? S3 Pt2 Ag1 90.25(11) . . ? S4 Pt2 Ag1 59.17(8) . . ? C25 Pt2 Ag2' 82.0(4) . . ? P2 Pt2 Ag2' 132.69(9) . . ? S3 Pt2 Ag2' 49.02(12) . . ? S4 Pt2 Ag2' 90.17(10) . . ? Ag1 Pt2 Ag2' 58.91(6) . . ? S1 Ag1 O1 95.6(3) . . ? S1 Ag1 S4 174.57(11) . . ? O1 Ag1 S4 86.4(3) . . ? S1 Ag1 Ag2 84.23(9) . . ? O1 Ag1 Ag2 110.5(3) . . ? S4 Ag1 Ag2 90.35(10) . . ? S1 Ag1 Ag2' 87.36(9) . . ? O1 Ag1 Ag2' 129.2(3) . . ? S4 Ag1 Ag2' 87.48(9) . . ? S1 Ag1 Pt2 127.24(8) . . ? O1 Ag1 Pt2 137.2(3) . . ? S4 Ag1 Pt2 51.04(7) . . ? Ag2 Ag1 Pt2 78.26(8) . . ? Ag2' Ag1 Pt2 62.12(7) . . ? O9 Ag2 S3 93.0(7) . . ? O9 Ag2 Pt1 136.9(7) . . ? S3 Ag2 Pt1 130.14(15) . . ? O9 Ag2 Ag1 108.2(7) . . ? S3 Ag2 Ag1 85.20(11) . . ? Pt1 Ag2 Ag1 79.64(8) . . ? O9 Ag2 S2 87.3(7) . . ? S3 Ag2 S2 174.1(2) . . ? Pt1 Ag2 S2 49.91(8) . . ? Ag1 Ag2 S2 89.09(12) . . ? S3 Ag2' Pt1 167.0(2) . . ? S3 Ag2' Ag1 91.69(12) . . ? Pt1 Ag2' Ag1 80.08(7) . . ? S3 Ag2' Pt2 51.05(10) . . ? Pt1 Ag2' Pt2 116.01(11) . . ? Ag1 Ag2' Pt2 58.97(6) . . ? C3 P1 C10 104.6(5) . . ? C3 P1 C17 106.6(5) . . ? C10 P1 C17 107.2(5) . . ? C3 P1 Pt1 103.4(4) . . ? C10 P1 Pt1 123.8(4) . . ? C17 P1 Pt1 109.9(3) . . ? C41 P2 C27 107.7(5) . . ? C41 P2 C34 107.1(6) . . ? C27 P2 C34 104.1(6) . . ? C41 P2 Pt2 111.1(3) . . ? C27 P2 Pt2 104.6(4) . . ? C34 P2 Pt2 121.3(4) . . ? C22 S1 Pt1 86.9(4) . . ? C22 S1 Ag1 103.3(4) . . ? Pt1 S1 Ag1 95.81(10) . . ? C22 S2 Pt1 85.3(4) . . ? C22 S2 Ag2 98.3(4) . . ? Pt1 S2 Ag2 60.97(10) . . ? C46 S3 Ag2' 107.2(4) . . ? C46 S3 Pt2 86.1(4) . . ? Ag2' S3 Pt2 79.93(15) . . ? C46 S3 Ag2 91.6(4) . . ? Pt2 S3 Ag2 91.62(14) . . ? C46 S4 Pt2 86.0(4) . . ? C46 S4 Ag1 101.7(4) . . ? Pt2 S4 Ag1 69.79(8) . . ? C22 N1 C24 121.9(10) . . ? C22 N1 C23 124.1(10) . . ? C24 N1 C23 114.0(10) . . ? C46 N2 C47 119.8(14) . . ? C46 N2 C48 121.1(14) . . ? C47 N2 C48 119.1(13) . . ? C2 C1 Pt1 116.5(8) . . ? C3 C2 C7 117.1(11) . . ? C3 C2 C1 119.8(10) . . ? C7 C2 C1 123.1(11) . . ? C2 C3 C4 120.6(10) . . ? C2 C3 P1 114.2(8) . . ? C4 C3 P1 125.2(9) . . ? C5 C4 C3 119.9(12) . . ? C6 C5 C4 119.6(13) . . ? C7 C6 C5 121.4(12) . . ? C6 C7 C2 121.5(13) . . ? C14 C9 C10 115.3(13) . . ? C14 C9 C8 120.9(12) . . ? C10 C9 C8 123.7(11) . . ? C9 C10 C11 120.8(11) . . ? C9 C10 P1 120.8(9) . . ? C11 C10 P1 118.4(9) . . ? C12 C11 C10 121.7(13) . . ? C13 C12 C11 119.3(14) . . ? C12 C13 C14 118.0(12) . . ? C9 C14 C13 124.9(13) . . ? C21 C16 C17 117.4(11) . . ? C21 C16 C15 118.9(11) . . ? C17 C16 C15 123.6(11) . . ? C18 C17 C16 119.6(10) . . ? C18 C17 P1 118.0(8) . . ? C16 C17 P1 122.3(8) . . ? C19 C18 C17 121.0(11) . . ? C18 C19 C20 120.4(11) . . ? C21 C20 C19 119.3(12) . . ? C20 C21 C16 122.3(12) . . ? N1 C22 S2 124.1(9) . . ? N1 C22 S1 123.7(9) . . ? S2 C22 S1 112.0(6) . . ? C26 C25 Pt2 114.8(8) . . ? C27 C26 C31 117.3(12) . . ? C27 C26 C25 121.3(10) . . ? C31 C26 C25 121.4(11) . . ? C26 C27 C28 120.7(11) . . ? C26 C27 P2 113.7(9) . . ? C28 C27 P2 125.6(10) . . ? C29 C28 C27 121.5(13) . . ? C28 C29 C30 118.8(14) . . ? C29 C30 C31 121.9(14) . . ? C30 C31 C26 119.8(14) . . ? C32 C33 C38 122.9(16) . . ? C32 C33 C34 125.4(13) . . ? C38 C33 C34 111.4(17) . . ? C35 C34 C33 122.5(13) . . ? C35 C34 P2 119.1(10) . . ? C33 C34 P2 118.4(10) . . ? C34 C35 C36 119.9(17) . . ? C37 C36 C35 122.6(20) . . ? C36 C37 C38 117.1(19) . . ? C37 C38 C33 126.4(21) . . ? C45 C40 C41 118.9(13) . . ? C45 C40 C39 115.2(12) . . ? C41 C40 C39 125.9(11) . . ? C42 C41 C40 119.6(11) . . ? C42 C41 P2 117.6(8) . . ? C40 C41 P2 122.2(9) . . ? C41 C42 C43 120.5(12) . . ? C44 C43 C42 120.1(13) . . ? C43 C44 C45 119.3(12) . . ? C40 C45 C44 121.6(13) . . ? N2 C46 S4 126.2(11) . . ? N2 C46 S3 120.5(11) . . ? S4 C46 S3 113.1(7) . . ? O3 Cl1 O2 108.1(14) . . ? O3 Cl1 O4 114.4(11) . . ? O2 Cl1 O4 108.7(9) . . ? O3 Cl1 O1 110.0(14) . . ? O2 Cl1 O1 103.9(9) . . ? O4 Cl1 O1 111.2(8) . . ? Cl1 O1 Ag1 119.0(6) . . ? O8' Cl2 O5' 119.2(17) . . ? O6 Cl2 O7 114.7(14) . . ? O8' Cl2 O6' 111.8(16) . . ? O5' Cl2 O6' 112.2(17) . . ? O6 Cl2 O5 114.4(15) . . ? O7 Cl2 O5 112.9(16) . . ? O8' Cl2 O7' 108.0(16) . . ? O5' Cl2 O7' 102.4(14) . . ? O6' Cl2 O7' 101.1(14) . . ? O6 Cl2 O8 106.4(15) . . ? O7 Cl2 O8 102.2(13) . . ? O5 Cl2 O8 104.5(14) . . ? Cl3 C49 Cl4 115.7(15) . . ? Cl3 C49 Cl5 109.0(14) . . ? Cl4 C49 Cl5 104.6(14) . . ? Cl4 C49' Cl3 112.4(18) . . ? Cl4 C49' Cl5' 101.4(16) . . ? Cl3 C49' Cl5' 104.5(17) . . ? C51 C50 C50 110.2(21) . 2 ? C50 C51 C52 110.2(21) . . ? _refine_diff_density_max 1.366 _refine_diff_density_min -0.910 _refine_diff_density_rms 0.168