# Copyright The Royal Society of Chemistry, 1999 # CCDC Number: 186/1364 data_dctac _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_formula_moiety ? _chemical_formula_sum 'C14 H28 Eu N2 Na O13' _chemical_formula_weight 607.33 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Na' 'Na' 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Eu' 'Eu' -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting Monoclinic _symmetry_space_group_name_H-M 'P 21/c' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' _cell_length_a 8.612(2) _cell_length_b 9.9105(16) _cell_length_c 24.250(6) _cell_angle_alpha 90.00 _cell_angle_beta 98.38(2) _cell_angle_gamma 90.00 _cell_volume 2047.6(8) _cell_formula_units_Z 4 _cell_measurement_temperature 288 _cell_measurement_reflns_used 25 _cell_measurement_theta_min 11.39 _cell_measurement_theta_max 14.56 _exptl_crystal_description block _exptl_crystal_colour colorless _exptl_crystal_size_max 0.5 _exptl_crystal_size_mid 0.4 _exptl_crystal_size_min 0.36 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.970 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1216 _exptl_absorpt_coefficient_mu 3.156 _exptl_absorpt_correction_type none _exptl_absorpt_correction_T_min ? _exptl_absorpt_correction_T_max ? _exptl_special_details ; ? ; _diffrn_ambient_temperature 288 _diffrn_radiation_wavelength 0.71069 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'CAD4 Express (Enraf Nonius, 1992)' _diffrn_measurement_method W/2 _diffrn_detector_area_resol_mean ? _diffrn_standards_number 3 _diffrn_standards_interval_count ? _diffrn_standards_interval_time 300 _diffrn_standards_decay_% 1.9 _diffrn_reflns_number 3787 _diffrn_reflns_av_R_equivalents 0.0000 _diffrn_reflns_av_sigmaI/netI 0.0168 _diffrn_reflns_limit_h_min -10 _diffrn_reflns_limit_h_max 10 _diffrn_reflns_limit_k_min 0 _diffrn_reflns_limit_k_max 11 _diffrn_reflns_limit_l_min 0 _diffrn_reflns_limit_l_max 29 _diffrn_reflns_theta_min 2.22 _diffrn_reflns_theta_max 25.46 _reflns_number_total 3787 _reflns_number_gt 3186 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'CAD4 Express (Enraf Nonius, 1992)' _computing_cell_refinement 'CAD4 Express (Enraf Nonius, 1992)' _computing_data_reduction 'CAD4 Express (Enraf Nonius, 1992)' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Ortep-3 for Windows (Farrugia, 1997)' _computing_publication_material 'SHELXL-97 (Sheldrick, 1997)' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme 'calc w=1/[\s^2^(Fo^2^)+(0.0226P)^2^+8.0065P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 3787 _refine_ls_number_parameters 275 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0318 _refine_ls_R_factor_gt 0.0248 _refine_ls_wR_factor_ref 0.0675 _refine_ls_wR_factor_gt 0.0612 _refine_ls_goodness_of_fit_ref 1.143 _refine_ls_restrained_S_all 1.143 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Eu Eu 0.36823(2) 0.49515(2) 0.428852(8) 0.01500(7) Uani 1 d . . . Na Na 0.7241(2) 0.82070(19) 0.44639(7) 0.0282(4) Uiso 1 d . . . OW1 O 0.4046(3) 0.5900(3) 0.51825(11) 0.0208(6) Uani 1 d . . . OW2 O 0.7756(4) 1.0665(4) 0.43923(16) 0.0381(9) Uani 1 d . . . OW3 O 0.3796(5) 1.0252(4) 0.39475(16) 0.0406(9) Uani 1 d . . . OW4 O 0.2254(3) 0.9222(3) 0.45570(12) 0.0161(6) Uani 1 d . . . OW5 O 0.4980(4) 0.8556(3) 0.49624(14) 0.0304(7) Uani 1 d . . . O1 O 0.5477(4) 0.6485(3) 0.39748(14) 0.0286(7) Uani 1 d . . . O2 O 0.5592(4) 0.8325(3) 0.34603(16) 0.0384(9) Uani 1 d . . . O3 O 0.4163(4) 0.2939(3) 0.37890(13) 0.0277(7) Uani 1 d . . . O4 O 0.6188(5) 0.2321(4) 0.33731(19) 0.0580(12) Uani 1 d . . . O5 O 0.2163(3) 0.3325(3) 0.47021(13) 0.0244(7) Uani 1 d . . . O6 O 0.0920(4) 0.1379(3) 0.45098(14) 0.0291(7) Uani 1 d . . . O7 O 0.2068(3) 0.6924(3) 0.41848(14) 0.0259(7) Uani 1 d . . . O8 O -0.0240(4) 0.7793(3) 0.42768(15) 0.0351(8) Uani 1 d . . . N1 N 0.3515(4) 0.5172(3) 0.31948(14) 0.0180(7) Uani 1 d . . . N2 N 0.0820(4) 0.4567(3) 0.37688(14) 0.0176(7) Uani 1 d . . . C1 C 0.2008(5) 0.4644(4) 0.28816(17) 0.0204(9) Uani 1 d . . . H1 H 0.2075 0.3657 0.2884 0.025 Uiso 0.10 calc PR . . C2 C 0.1739(6) 0.5105(5) 0.22616(18) 0.0313(11) Uani 1 d . . . H21 H 0.1751 0.6083 0.2245 0.038 Uiso 0.10 calc PR . . H22 H 0.2584 0.4769 0.2075 0.038 Uiso 0.10 calc PR . . C3 C 0.0162(7) 0.4579(6) 0.1961(2) 0.0447(14) Uani 1 d . . . H31 H 0.0011 0.4896 0.1578 0.054 Uiso 0.10 calc PR . . H32 H 0.0181 0.3601 0.1954 0.054 Uiso 0.10 calc PR . . C4 C -0.1177(7) 0.5045(7) 0.2242(2) 0.0463(15) Uani 1 d . . . H41 H -0.2158 0.4703 0.2044 0.056 Uiso 0.10 calc PR . . H42 H -0.1224 0.6023 0.2239 0.056 Uiso 0.10 calc PR . . C5 C -0.0941(6) 0.4528(6) 0.2845(2) 0.0393(13) Uani 1 d . . . H51 H -0.0944 0.3549 0.2843 0.047 Uiso 0.10 calc PR . . H52 H -0.1807 0.4830 0.3029 0.047 Uiso 0.10 calc PR . . C6 C 0.0610(5) 0.5035(5) 0.31718(16) 0.0199(9) Uani 1 d . . . H6 H 0.0560 0.6022 0.3176 0.024 Uiso 0.10 calc PR . . C7 C 0.3825(5) 0.6614(5) 0.30876(19) 0.0247(10) Uani 1 d . . . H71 H 0.2861 0.7126 0.3077 0.030 Uiso 0.10 calc PR . . H72 H 0.4180 0.6703 0.2728 0.030 Uiso 0.10 calc PR . . C8 C 0.5066(5) 0.7187(5) 0.3539(2) 0.0271(10) Uani 1 d . . . C9 C 0.4842(5) 0.4333(5) 0.3057(2) 0.0274(10) Uani 1 d . . . H91 H 0.5793 0.4870 0.3101 0.033 Uiso 0.10 calc PR . . H92 H 0.4623 0.4047 0.2671 0.033 Uiso 0.10 calc PR . . C10 C 0.5095(6) 0.3081(5) 0.3436(2) 0.0313(11) Uani 1 d . . . C11 C 0.0430(5) 0.3133(4) 0.38326(19) 0.0237(10) Uani 1 d . . . H111 H 0.0762 0.2618 0.3530 0.028 Uiso 0.10 calc PR . . H112 H -0.0698 0.3036 0.3810 0.028 Uiso 0.10 calc PR . . C12 C 0.1236(5) 0.2564(4) 0.43953(19) 0.0234(10) Uani 1 d . . . C13 C -0.0144(5) 0.5437(5) 0.40839(19) 0.0228(9) Uani 1 d . . . H131 H -0.0234 0.5016 0.4439 0.027 Uiso 0.10 calc PR . . H132 H -0.1191 0.5521 0.3877 0.027 Uiso 0.10 calc PR . . C14 C 0.0579(5) 0.6835(4) 0.41849(19) 0.0237(9) Uani 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Eu 0.01375(11) 0.01462(11) 0.01628(11) -0.00001(9) 0.00107(7) -0.00067(9) OW1 0.0202(15) 0.0241(16) 0.0171(14) -0.0011(12) -0.0005(12) 0.0051(13) OW2 0.0286(18) 0.039(2) 0.049(2) 0.0064(18) 0.0122(16) -0.0044(16) OW3 0.051(2) 0.032(2) 0.040(2) 0.0062(16) 0.0075(17) 0.0025(17) OW4 0.0169(14) 0.0067(13) 0.0244(15) -0.0005(11) 0.0017(12) 0.0013(11) OW5 0.0288(16) 0.0261(17) 0.0366(18) 0.0011(15) 0.0059(14) 0.0053(15) O1 0.0216(16) 0.0278(18) 0.0359(18) 0.0049(15) 0.0030(14) -0.0097(14) O2 0.044(2) 0.0247(18) 0.049(2) 0.0050(16) 0.0129(18) -0.0114(16) O3 0.0338(19) 0.0193(16) 0.0323(18) -0.0006(14) 0.0127(15) 0.0040(14) O4 0.057(3) 0.049(3) 0.075(3) 0.014(2) 0.033(2) 0.030(2) O5 0.0210(16) 0.0243(16) 0.0271(16) 0.0056(13) 0.0006(13) -0.0079(13) O6 0.0283(17) 0.0182(16) 0.0415(19) 0.0074(14) 0.0077(15) -0.0016(14) O7 0.0151(15) 0.0202(16) 0.0416(19) -0.0027(14) 0.0014(13) 0.0005(12) O8 0.0308(19) 0.0258(18) 0.053(2) 0.0016(16) 0.0212(17) 0.0088(15) N1 0.0174(17) 0.0175(18) 0.0196(17) 0.0024(14) 0.0043(14) 0.0036(14) N2 0.0146(17) 0.0169(17) 0.0214(18) 0.0019(14) 0.0032(14) -0.0016(14) C1 0.023(2) 0.022(2) 0.016(2) -0.0004(17) 0.0031(17) -0.0035(17) C2 0.035(3) 0.041(3) 0.018(2) 0.000(2) 0.0019(18) -0.007(2) C3 0.057(4) 0.050(3) 0.023(3) -0.002(2) -0.007(2) -0.013(3) C4 0.038(3) 0.068(4) 0.027(3) 0.015(3) -0.013(2) -0.009(3) C5 0.026(3) 0.065(4) 0.023(2) 0.010(2) -0.009(2) -0.016(3) C6 0.0154(19) 0.027(2) 0.0171(19) 0.0044(19) 0.0006(15) -0.0038(18) C7 0.025(2) 0.020(2) 0.030(2) 0.0060(19) 0.0037(19) -0.0027(18) C8 0.020(2) 0.019(2) 0.045(3) 0.003(2) 0.013(2) -0.0018(18) C9 0.025(2) 0.025(2) 0.035(3) 0.003(2) 0.016(2) 0.006(2) C10 0.034(3) 0.027(3) 0.035(3) -0.002(2) 0.010(2) 0.007(2) C11 0.023(2) 0.018(2) 0.028(2) 0.0019(18) -0.0010(19) -0.0060(18) C12 0.018(2) 0.019(2) 0.036(3) 0.0016(19) 0.0148(19) 0.0006(18) C13 0.016(2) 0.026(2) 0.028(2) -0.0008(19) 0.0077(18) -0.0001(17) C14 0.025(2) 0.020(2) 0.027(2) 0.0044(18) 0.0049(19) 0.0024(19) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Eu OW1 2.336(3) 3_666 ? Eu OW1 2.342(3) . ? Eu O1 2.370(3) . ? Eu O5 2.387(3) . ? Eu O7 2.390(3) . ? Eu O3 2.401(3) . ? Eu N2 2.627(3) . ? Eu N1 2.644(3) . ? Eu C10 3.149(5) . ? Eu C8 3.203(5) . ? Eu C12 3.204(4) . ? Eu C14 3.240(4) . ? Na O8 2.317(4) 1_655 ? Na OW5 2.461(4) . ? Na O1 2.471(4) . ? Na OW2 2.486(4) . ? Na O5 2.521(4) 3_666 ? Na O2 2.636(4) . ? Na O6 2.779(4) 3_666 ? Na C8 2.886(5) . ? Na C12 2.983(5) 3_666 ? OW1 Eu 2.336(3) 3_666 ? O1 C8 1.271(6) . ? O2 C8 1.240(6) . ? O3 C10 1.263(6) . ? O4 C10 1.233(6) . ? O5 C12 1.260(5) . ? O5 Na 2.521(4) 3_666 ? O6 C12 1.246(5) . ? O6 Na 2.779(4) 3_666 ? O7 C14 1.286(5) . ? O8 C14 1.223(5) . ? O8 Na 2.317(4) 1_455 ? N1 C7 1.484(5) . ? N1 C9 1.490(5) . ? N1 C1 1.499(5) . ? N2 C11 1.474(5) . ? N2 C13 1.483(5) . ? N2 C6 1.506(5) . ? C1 C6 1.530(6) . ? C1 C2 1.556(6) . ? C1 H1 0.9800 . ? C2 C3 1.536(7) . ? C2 H21 0.9700 . ? C2 H22 0.9700 . ? C3 C4 1.496(9) . ? C3 H31 0.9700 . ? C3 H32 0.9700 . ? C4 C5 1.534(7) . ? C4 H41 0.9700 . ? C4 H42 0.9700 . ? C5 C6 1.535(6) . ? C5 H51 0.9700 . ? C5 H52 0.9700 . ? C6 H6 0.9800 . ? C7 C8 1.525(7) . ? C7 H71 0.9700 . ? C7 H72 0.9700 . ? C9 C10 1.541(7) . ? C9 H91 0.9700 . ? C9 H92 0.9700 . ? C11 C12 1.545(6) . ? C11 H111 0.9700 . ? C11 H112 0.9700 . ? C12 Na 2.983(5) 3_666 ? C13 C14 1.524(6) . ? C13 H131 0.9700 . ? C13 H132 0.9700 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag OW1 Eu OW1 69.41(12) 3_666 . ? OW1 Eu O1 82.81(11) 3_666 . ? OW1 Eu O1 91.97(11) . . ? OW1 Eu O5 89.54(10) 3_666 . ? OW1 Eu O5 83.66(11) . . ? O1 Eu O5 172.15(10) . . ? OW1 Eu O7 141.36(10) 3_666 . ? OW1 Eu O7 76.49(11) . . ? O1 Eu O7 80.69(11) . . ? O5 Eu O7 104.50(11) . . ? OW1 Eu O3 77.56(11) 3_666 . ? OW1 Eu O3 142.28(11) . . ? O1 Eu O3 101.67(11) . . ? O5 Eu O3 78.25(11) . . ? O7 Eu O3 140.06(11) . . ? OW1 Eu N2 149.70(11) 3_666 . ? OW1 Eu N2 119.45(11) . . ? O1 Eu N2 123.28(11) . . ? O5 Eu N2 64.55(10) . . ? O7 Eu N2 65.01(10) . . ? O3 Eu N2 81.74(11) . . ? OW1 Eu N1 119.98(10) 3_666 . ? OW1 Eu N1 151.14(11) . . ? O1 Eu N1 64.40(11) . . ? O5 Eu N1 121.61(11) . . ? O7 Eu N1 83.17(11) . . ? O3 Eu N1 63.31(11) . . ? N2 Eu N1 67.70(11) . . ? OW1 Eu C10 76.99(12) 3_666 . ? OW1 Eu C10 146.25(12) . . ? O1 Eu C10 80.48(13) . . ? O5 Eu C10 99.55(12) . . ? O7 Eu C10 133.36(12) . . ? O3 Eu C10 21.31(12) . . ? N2 Eu C10 91.43(12) . . ? N1 Eu C10 50.23(12) . . ? OW1 Eu C8 102.14(11) 3_666 . ? OW1 Eu C8 103.69(12) . . ? O1 Eu C8 20.06(11) . . ? O5 Eu C8 167.78(11) . . ? O7 Eu C8 68.49(11) . . ? O3 Eu C8 100.54(11) . . ? N2 Eu C8 103.23(12) . . ? N1 Eu C8 49.04(12) . . ? C10 Eu C8 79.86(13) . . ? OW1 Eu C12 101.35(11) 3_666 . ? OW1 Eu C12 102.85(11) . . ? O1 Eu C12 165.14(12) . . ? O5 Eu C12 19.97(11) . . ? O7 Eu C12 103.50(11) . . ? O3 Eu C12 65.85(11) . . ? N2 Eu C12 49.44(11) . . ? N1 Eu C12 101.64(11) . . ? C10 Eu C12 86.53(12) . . ? C8 Eu C12 149.34(12) . . ? OW1 Eu C14 150.05(11) 3_666 . ? OW1 Eu C14 80.67(11) . . ? O1 Eu C14 100.07(11) . . ? O5 Eu C14 85.70(11) . . ? O7 Eu C14 19.99(11) . . ? O3 Eu C14 129.83(12) . . ? N2 Eu C14 48.74(11) . . ? N1 Eu C14 87.18(11) . . ? C10 Eu C14 132.95(12) . . ? C8 Eu C14 85.90(11) . . ? C12 Eu C14 83.51(11) . . ? O8 Na OW5 162.06(15) 1_655 . ? O8 Na O1 108.17(14) 1_655 . ? OW5 Na O1 81.82(13) . . ? O8 Na OW2 88.74(13) 1_655 . ? OW5 Na OW2 93.36(13) . . ? O1 Na OW2 138.31(14) . . ? O8 Na O5 87.91(13) 1_655 3_666 ? OW5 Na O5 76.92(12) . 3_666 ? O1 Na O5 90.47(12) . 3_666 ? OW2 Na O5 128.93(14) . 3_666 ? O8 Na O2 102.77(14) 1_655 . ? OW5 Na O2 95.11(13) . . ? O1 Na O2 51.42(11) . . ? OW2 Na O2 88.26(13) . . ? O5 Na O2 141.89(13) 3_666 . ? O8 Na O6 76.92(13) 1_655 3_666 ? OW5 Na O6 85.85(12) . 3_666 ? O1 Na O6 139.67(12) . 3_666 ? OW2 Na O6 80.42(12) . 3_666 ? O5 Na O6 49.28(10) 3_666 3_666 ? O2 Na O6 168.68(12) . 3_666 ? O8 Na C8 107.83(15) 1_655 . ? OW5 Na C8 87.74(13) . . ? O1 Na C8 26.00(12) . . ? OW2 Na C8 113.01(14) . . ? O5 Na C8 116.45(13) 3_666 . ? O2 Na C8 25.44(12) . . ? O6 Na C8 165.46(13) 3_666 . ? O8 Na C12 80.71(13) 1_655 3_666 ? OW5 Na C12 81.53(12) . 3_666 ? O1 Na C12 115.14(13) . 3_666 ? OW2 Na C12 104.87(14) . 3_666 ? O5 Na C12 24.68(11) 3_666 3_666 ? O2 Na C12 166.57(13) . 3_666 ? O6 Na C12 24.64(11) 3_666 3_666 ? C8 Na C12 141.13(14) . 3_666 ? Eu OW1 Eu 110.59(12) 3_666 . ? C8 O1 Eu 120.2(3) . . ? C8 O1 Na 95.6(3) . . ? Eu O1 Na 132.29(15) . . ? C8 O2 Na 88.6(3) . . ? C10 O3 Eu 115.0(3) . . ? C12 O5 Eu 119.7(3) . . ? C12 O5 Na 98.6(3) . 3_666 ? Eu O5 Na 133.12(13) . 3_666 ? C12 O6 Na 86.9(3) . 3_666 ? C14 O7 Eu 120.6(3) . . ? C14 O8 Na 139.0(3) . 1_455 ? C7 N1 C9 109.6(3) . . ? C7 N1 C1 114.3(3) . . ? C9 N1 C1 109.1(3) . . ? C7 N1 Eu 105.7(2) . . ? C9 N1 Eu 104.3(2) . . ? C1 N1 Eu 113.3(2) . . ? C11 N2 C13 110.7(3) . . ? C11 N2 C6 113.6(3) . . ? C13 N2 C6 108.6(3) . . ? C11 N2 Eu 107.6(2) . . ? C13 N2 Eu 103.0(2) . . ? C6 N2 Eu 112.9(2) . . ? N1 C1 C6 111.1(3) . . ? N1 C1 C2 112.5(3) . . ? C6 C1 C2 110.7(4) . . ? N1 C1 H1 107.4 . . ? C6 C1 H1 107.4 . . ? C2 C1 H1 107.4 . . ? C3 C2 C1 110.9(4) . . ? C3 C2 H21 109.5 . . ? C1 C2 H21 109.5 . . ? C3 C2 H22 109.5 . . ? C1 C2 H22 109.5 . . ? H21 C2 H22 108.1 . . ? C4 C3 C2 111.4(4) . . ? C4 C3 H31 109.3 . . ? C2 C3 H31 109.3 . . ? C4 C3 H32 109.3 . . ? C2 C3 H32 109.3 . . ? H31 C3 H32 108.0 . . ? C3 C4 C5 109.1(5) . . ? C3 C4 H41 109.9 . . ? C5 C4 H41 109.9 . . ? C3 C4 H42 109.9 . . ? C5 C4 H42 109.9 . . ? H41 C4 H42 108.3 . . ? C4 C5 C6 111.5(4) . . ? C4 C5 H51 109.3 . . ? C6 C5 H51 109.3 . . ? C4 C5 H52 109.3 . . ? C6 C5 H52 109.3 . . ? H51 C5 H52 108.0 . . ? N2 C6 C1 111.8(3) . . ? N2 C6 C5 111.7(3) . . ? C1 C6 C5 111.3(4) . . ? N2 C6 H6 107.2 . . ? C1 C6 H6 107.2 . . ? C5 C6 H6 107.2 . . ? N1 C7 C8 111.0(4) . . ? N1 C7 H71 109.4 . . ? C8 C7 H71 109.4 . . ? N1 C7 H72 109.4 . . ? C8 C7 H72 109.4 . . ? H71 C7 H72 108.0 . . ? O2 C8 O1 124.3(5) . . ? O2 C8 C7 117.4(4) . . ? O1 C8 C7 118.3(4) . . ? O2 C8 Na 65.9(3) . . ? O1 C8 Na 58.4(2) . . ? C7 C8 Na 175.0(3) . . ? O2 C8 Eu 153.0(4) . . ? O1 C8 Eu 39.8(2) . . ? C7 C8 Eu 82.5(2) . . ? Na C8 Eu 93.14(14) . . ? N1 C9 C10 111.2(4) . . ? N1 C9 H91 109.4 . . ? C10 C9 H91 109.4 . . ? N1 C9 H92 109.4 . . ? C10 C9 H92 109.4 . . ? H91 C9 H92 108.0 . . ? O4 C10 O3 126.0(5) . . ? O4 C10 C9 117.5(4) . . ? O3 C10 C9 116.5(4) . . ? O4 C10 Eu 144.7(4) . . ? O3 C10 Eu 43.7(2) . . ? C9 C10 Eu 83.3(3) . . ? N2 C11 C12 111.4(3) . . ? N2 C11 H111 109.3 . . ? C12 C11 H111 109.3 . . ? N2 C11 H112 109.3 . . ? C12 C11 H112 109.3 . . ? H111 C11 H112 108.0 . . ? O6 C12 O5 125.0(4) . . ? O6 C12 C11 117.2(4) . . ? O5 C12 C11 117.9(4) . . ? O6 C12 Na 68.5(3) . 3_666 ? O5 C12 Na 56.7(2) . 3_666 ? C11 C12 Na 173.2(3) . 3_666 ? O6 C12 Eu 151.9(3) . . ? O5 C12 Eu 40.3(2) . . ? C11 C12 Eu 82.8(2) . . ? Na C12 Eu 93.36(13) 3_666 . ? N2 C13 C14 111.4(3) . . ? N2 C13 H131 109.3 . . ? C14 C13 H131 109.3 . . ? N2 C13 H132 109.3 . . ? C14 C13 H132 109.3 . . ? H131 C13 H132 108.0 . . ? O8 C14 O7 123.3(4) . . ? O8 C14 C13 120.2(4) . . ? O7 C14 C13 116.5(4) . . ? O8 C14 Eu 157.6(3) . . ? O7 C14 Eu 39.4(2) . . ? C13 C14 Eu 78.6(2) . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag OW1 Eu OW1 Eu 0.0 3_666 . . 3_666 ? O1 Eu OW1 Eu -81.56(13) . . . 3_666 ? O5 Eu OW1 Eu 91.89(13) . . . 3_666 ? O7 Eu OW1 Eu -161.50(14) . . . 3_666 ? O3 Eu OW1 Eu 30.5(2) . . . 3_666 ? N2 Eu OW1 Eu 147.89(11) . . . 3_666 ? N1 Eu OW1 Eu -115.11(19) . . . 3_666 ? C10 Eu OW1 Eu -5.8(3) . . . 3_666 ? C8 Eu OW1 Eu -98.03(14) . . . 3_666 ? C12 Eu OW1 Eu 97.46(13) . . . 3_666 ? C14 Eu OW1 Eu 178.55(14) . . . 3_666 ? OW1 Eu O1 C8 164.4(4) 3_666 . . . ? OW1 Eu O1 C8 -126.6(3) . . . . ? O5 Eu O1 C8 177.4(7) . . . . ? O7 Eu O1 C8 -50.6(3) . . . . ? O3 Eu O1 C8 88.8(3) . . . . ? N2 Eu O1 C8 1.1(4) . . . . ? N1 Eu O1 C8 36.2(3) . . . . ? C10 Eu O1 C8 86.5(3) . . . . ? C12 Eu O1 C8 57.1(6) . . . . ? C14 Eu O1 C8 -45.7(4) . . . . ? OW1 Eu O1 Na -62.65(19) 3_666 . . . ? OW1 Eu O1 Na 6.3(2) . . . . ? O5 Eu O1 Na -49.7(9) . . . . ? O7 Eu O1 Na 82.3(2) . . . . ? O3 Eu O1 Na -138.30(19) . . . . ? N2 Eu O1 Na 133.99(18) . . . . ? N1 Eu O1 Na 169.1(2) . . . . ? C10 Eu O1 Na -140.6(2) . . . . ? C8 Eu O1 Na 132.9(5) . . . . ? C12 Eu O1 Na -170.0(3) . . . . ? C14 Eu O1 Na 87.2(2) . . . . ? O8 Na O1 C8 -93.6(3) 1_655 . . . ? OW5 Na O1 C8 101.8(3) . . . . ? OW2 Na O1 C8 15.9(4) . . . . ? O5 Na O1 C8 178.5(3) 3_666 . . . ? O2 Na O1 C8 -1.5(3) . . . . ? O6 Na O1 C8 175.4(3) 3_666 . . . ? C12 Na O1 C8 178.4(3) 3_666 . . . ? O8 Na O1 Eu 125.94(19) 1_655 . . . ? OW5 Na O1 Eu -38.7(2) . . . . ? OW2 Na O1 Eu -124.6(2) . . . . ? O5 Na O1 Eu 38.0(2) 3_666 . . . ? O2 Na O1 Eu -142.0(3) . . . . ? O6 Na O1 Eu 34.9(3) 3_666 . . . ? C8 Na O1 Eu -140.5(4) . . . . ? C12 Na O1 Eu 37.9(2) 3_666 . . . ? O8 Na O2 C8 104.7(3) 1_655 . . . ? OW5 Na O2 C8 -73.7(3) . . . . ? O1 Na O2 C8 1.5(3) . . . . ? OW2 Na O2 C8 -167.0(3) . . . . ? O5 Na O2 C8 1.5(4) 3_666 . . . ? O6 Na O2 C8 -168.1(6) 3_666 . . . ? C12 Na O2 C8 1.1(7) 3_666 . . . ? OW1 Eu O3 C10 -86.1(3) 3_666 . . . ? OW1 Eu O3 C10 -115.2(3) . . . . ? O1 Eu O3 C10 -6.2(3) . . . . ? O5 Eu O3 C10 -178.2(3) . . . . ? O7 Eu O3 C10 83.2(4) . . . . ? N2 Eu O3 C10 116.2(3) . . . . ? N1 Eu O3 C10 47.1(3) . . . . ? C8 Eu O3 C10 14.2(4) . . . . ? C12 Eu O3 C10 165.3(4) . . . . ? C14 Eu O3 C10 107.7(3) . . . . ? OW1 Eu O5 C12 -126.7(3) 3_666 . . . ? OW1 Eu O5 C12 163.9(3) . . . . ? O1 Eu O5 C12 -139.6(7) . . . . ? O7 Eu O5 C12 89.7(3) . . . . ? O3 Eu O5 C12 -49.4(3) . . . . ? N2 Eu O5 C12 37.0(3) . . . . ? N1 Eu O5 C12 -1.2(4) . . . . ? C10 Eu O5 C12 -50.0(3) . . . . ? C8 Eu O5 C12 36.2(7) . . . . ? C14 Eu O5 C12 82.8(3) . . . . ? OW1 Eu O5 Na 13.7(2) 3_666 . . 3_666 ? OW1 Eu O5 Na -55.63(19) . . . 3_666 ? O1 Eu O5 Na 0.9(9) . . . 3_666 ? O7 Eu O5 Na -129.88(19) . . . 3_666 ? O3 Eu O5 Na 91.1(2) . . . 3_666 ? N2 Eu O5 Na 177.4(2) . . . 3_666 ? N1 Eu O5 Na 139.27(17) . . . 3_666 ? C10 Eu O5 Na 90.4(2) . . . 3_666 ? C8 Eu O5 Na 176.6(4) . . . 3_666 ? C12 Eu O5 Na 140.5(4) . . . 3_666 ? C14 Eu O5 Na -136.7(2) . . . 3_666 ? OW1 Eu O7 C14 -128.4(3) 3_666 . . . ? OW1 Eu O7 C14 -100.0(3) . . . . ? O1 Eu O7 C14 165.7(3) . . . . ? O5 Eu O7 C14 -20.3(3) . . . . ? O3 Eu O7 C14 68.6(4) . . . . ? N2 Eu O7 C14 32.1(3) . . . . ? N1 Eu O7 C14 100.6(3) . . . . ? C10 Eu O7 C14 98.4(4) . . . . ? C8 Eu O7 C14 149.2(4) . . . . ? C12 Eu O7 C14 0.3(3) . . . . ? OW1 Eu N1 C7 -100.5(3) 3_666 . . . ? OW1 Eu N1 C7 1.4(4) . . . . ? O1 Eu N1 C7 -36.4(2) . . . . ? O5 Eu N1 C7 149.4(2) . . . . ? O7 Eu N1 C7 46.6(2) . . . . ? O3 Eu N1 C7 -155.8(3) . . . . ? N2 Eu N1 C7 112.3(3) . . . . ? C10 Eu N1 C7 -135.6(3) . . . . ? C8 Eu N1 C7 -20.8(2) . . . . ? C12 Eu N1 C7 149.0(2) . . . . ? C14 Eu N1 C7 66.2(3) . . . . ? OW1 Eu N1 C9 15.0(3) 3_666 . . . ? OW1 Eu N1 C9 116.9(3) . . . . ? O1 Eu N1 C9 79.1(3) . . . . ? O5 Eu N1 C9 -95.1(3) . . . . ? O7 Eu N1 C9 162.1(3) . . . . ? O3 Eu N1 C9 -40.3(3) . . . . ? N2 Eu N1 C9 -132.2(3) . . . . ? C10 Eu N1 C9 -20.1(3) . . . . ? C8 Eu N1 C9 94.7(3) . . . . ? C12 Eu N1 C9 -95.5(3) . . . . ? C14 Eu N1 C9 -178.3(3) . . . . ? OW1 Eu N1 C1 133.6(2) 3_666 . . . ? OW1 Eu N1 C1 -124.6(3) . . . . ? O1 Eu N1 C1 -162.3(3) . . . . ? O5 Eu N1 C1 23.5(3) . . . . ? O7 Eu N1 C1 -79.4(3) . . . . ? O3 Eu N1 C1 78.2(3) . . . . ? N2 Eu N1 C1 -13.6(2) . . . . ? C10 Eu N1 C1 98.5(3) . . . . ? C8 Eu N1 C1 -146.8(3) . . . . ? C12 Eu N1 C1 23.0(3) . . . . ? C14 Eu N1 C1 -59.7(3) . . . . ? OW1 Eu N2 C11 -0.4(4) 3_666 . . . ? OW1 Eu N2 C11 -99.9(3) . . . . ? O1 Eu N2 C11 145.3(3) . . . . ? O5 Eu N2 C11 -34.1(3) . . . . ? O7 Eu N2 C11 -155.9(3) . . . . ? O3 Eu N2 C11 46.8(3) . . . . ? N1 Eu N2 C11 111.2(3) . . . . ? C10 Eu N2 C11 65.8(3) . . . . ? C8 Eu N2 C11 145.7(3) . . . . ? C12 Eu N2 C11 -18.4(2) . . . . ? C14 Eu N2 C11 -142.0(3) . . . . ? OW1 Eu N2 C13 116.5(3) 3_666 . . . ? OW1 Eu N2 C13 17.0(3) . . . . ? O1 Eu N2 C13 -97.7(3) . . . . ? O5 Eu N2 C13 82.8(3) . . . . ? O7 Eu N2 C13 -39.0(2) . . . . ? O3 Eu N2 C13 163.7(3) . . . . ? N1 Eu N2 C13 -131.8(3) . . . . ? C10 Eu N2 C13 -177.3(3) . . . . ? C8 Eu N2 C13 -97.4(3) . . . . ? C12 Eu N2 C13 98.5(3) . . . . ? C14 Eu N2 C13 -25.0(2) . . . . ? OW1 Eu N2 C6 -126.5(3) 3_666 . . . ? OW1 Eu N2 C6 133.9(3) . . . . ? O1 Eu N2 C6 19.2(3) . . . . ? O5 Eu N2 C6 -160.2(3) . . . . ? O7 Eu N2 C6 77.9(3) . . . . ? O3 Eu N2 C6 -79.4(3) . . . . ? N1 Eu N2 C6 -14.9(3) . . . . ? C10 Eu N2 C6 -60.3(3) . . . . ? C8 Eu N2 C6 19.6(3) . . . . ? C12 Eu N2 C6 -144.5(3) . . . . ? C14 Eu N2 C6 91.9(3) . . . . ? C7 N1 C1 C6 -80.7(4) . . . . ? C9 N1 C1 C6 156.3(3) . . . . ? Eu N1 C1 C6 40.5(4) . . . . ? C7 N1 C1 C2 44.1(5) . . . . ? C9 N1 C1 C2 -79.0(4) . . . . ? Eu N1 C1 C2 165.3(3) . . . . ? N1 C1 C2 C3 -178.3(4) . . . . ? C6 C1 C2 C3 -53.4(5) . . . . ? C1 C2 C3 C4 57.8(6) . . . . ? C2 C3 C4 C5 -59.7(6) . . . . ? C3 C4 C5 C6 58.9(7) . . . . ? C11 N2 C6 C1 -80.7(4) . . . . ? C13 N2 C6 C1 155.8(3) . . . . ? Eu N2 C6 C1 42.2(4) . . . . ? C11 N2 C6 C5 44.8(5) . . . . ? C13 N2 C6 C5 -78.7(5) . . . . ? Eu N2 C6 C5 167.7(3) . . . . ? N1 C1 C6 N2 -55.8(4) . . . . ? C2 C1 C6 N2 178.5(3) . . . . ? N1 C1 C6 C5 178.5(4) . . . . ? C2 C1 C6 C5 52.8(5) . . . . ? C4 C5 C6 N2 178.1(4) . . . . ? C4 C5 C6 C1 -56.1(6) . . . . ? C9 N1 C7 C8 -74.8(4) . . . . ? C1 N1 C7 C8 162.4(3) . . . . ? Eu N1 C7 C8 37.1(4) . . . . ? Na O2 C8 O1 -2.8(5) . . . . ? Na O2 C8 C7 175.9(4) . . . . ? Na O2 C8 Eu 41.8(7) . . . . ? Eu O1 C8 O2 150.1(4) . . . . ? Na O1 C8 O2 3.1(5) . . . . ? Eu O1 C8 C7 -28.7(5) . . . . ? Na O1 C8 C7 -175.7(4) . . . . ? Eu O1 C8 Na 147.0(3) . . . . ? Na O1 C8 Eu -147.0(3) . . . . ? N1 C7 C8 O2 170.3(4) . . . . ? N1 C7 C8 O1 -10.9(6) . . . . ? N1 C7 C8 Na -58(4) . . . . ? N1 C7 C8 Eu -28.9(3) . . . . ? O8 Na C8 O2 -82.2(3) 1_655 . . . ? OW5 Na C8 O2 106.9(3) . . . . ? O1 Na C8 O2 -177.2(5) . . . . ? OW2 Na C8 O2 14.2(3) . . . . ? O5 Na C8 O2 -178.9(3) 3_666 . . . ? O6 Na C8 O2 170.7(5) 3_666 . . . ? C12 Na C8 O2 -179.6(3) 3_666 . . . ? O8 Na C8 O1 95.0(3) 1_655 . . . ? OW5 Na C8 O1 -75.9(3) . . . . ? OW2 Na C8 O1 -168.6(3) . . . . ? O5 Na C8 O1 -1.7(3) 3_666 . . . ? O2 Na C8 O1 177.2(5) . . . . ? O6 Na C8 O1 -12.0(7) 3_666 . . . ? C12 Na C8 O1 -2.4(4) 3_666 . . . ? O8 Na C8 C7 144(4) 1_655 . . . ? OW5 Na C8 C7 -27(4) . . . . ? O1 Na C8 C7 49(4) . . . . ? OW2 Na C8 C7 -119(4) . . . . ? O5 Na C8 C7 48(4) 3_666 . . . ? O2 Na C8 C7 -133(4) . . . . ? O6 Na C8 C7 37(4) 3_666 . . . ? C12 Na C8 C7 47(4) 3_666 . . . ? O8 Na C8 Eu 115.44(13) 1_655 . . . ? OW5 Na C8 Eu -55.47(12) . . . . ? O1 Na C8 Eu 20.4(2) . . . . ? OW2 Na C8 Eu -148.16(12) . . . . ? O5 Na C8 Eu 18.71(17) 3_666 . . . ? O2 Na C8 Eu -162.3(3) . . . . ? O6 Na C8 Eu 8.4(6) 3_666 . . . ? C12 Na C8 Eu 18.0(3) 3_666 . . . ? OW1 Eu C8 O2 -81.0(8) 3_666 . . . ? OW1 Eu C8 O2 -9.6(8) . . . . ? O1 Eu C8 O2 -65.2(8) . . . . ? O5 Eu C8 O2 116.4(8) . . . . ? O7 Eu C8 O2 59.7(7) . . . . ? O3 Eu C8 O2 -160.4(7) . . . . ? N2 Eu C8 O2 115.7(8) . . . . ? N1 Eu C8 O2 159.6(8) . . . . ? C10 Eu C8 O2 -155.2(8) . . . . ? C12 Eu C8 O2 139.7(7) . . . . ? C14 Eu C8 O2 69.8(8) . . . . ? OW1 Eu C8 O1 -15.8(4) 3_666 . . . ? OW1 Eu C8 O1 55.7(3) . . . . ? O5 Eu C8 O1 -178.3(5) . . . . ? O7 Eu C8 O1 124.9(4) . . . . ? O3 Eu C8 O1 -95.2(3) . . . . ? N2 Eu C8 O1 -179.1(3) . . . . ? N1 Eu C8 O1 -135.1(4) . . . . ? C10 Eu C8 O1 -90.0(3) . . . . ? C12 Eu C8 O1 -155.0(3) . . . . ? C14 Eu C8 O1 135.0(3) . . . . ? OW1 Eu C8 C7 138.9(2) 3_666 . . . ? OW1 Eu C8 C7 -149.6(2) . . . . ? O1 Eu C8 C7 154.7(5) . . . . ? O5 Eu C8 C7 -23.6(7) . . . . ? O7 Eu C8 C7 -80.3(3) . . . . ? O3 Eu C8 C7 59.6(3) . . . . ? N2 Eu C8 C7 -24.3(3) . . . . ? N1 Eu C8 C7 19.6(2) . . . . ? C10 Eu C8 C7 64.8(3) . . . . ? C12 Eu C8 C7 -0.3(4) . . . . ? C14 Eu C8 C7 -70.2(3) . . . . ? OW1 Eu C8 Na -43.47(13) 3_666 . . . ? OW1 Eu C8 Na 28.00(14) . . . . ? O1 Eu C8 Na -27.7(3) . . . . ? O5 Eu C8 Na 154.0(5) . . . . ? O7 Eu C8 Na 97.24(14) . . . . ? O3 Eu C8 Na -122.86(13) . . . . ? N2 Eu C8 Na 153.25(12) . . . . ? N1 Eu C8 Na -162.82(19) . . . . ? C10 Eu C8 Na -117.67(15) . . . . ? C12 Eu C8 Na 177.29(16) . . . . ? C14 Eu C8 Na 107.36(13) . . . . ? C7 N1 C9 C10 148.1(4) . . . . ? C1 N1 C9 C10 -86.1(4) . . . . ? Eu N1 C9 C10 35.3(4) . . . . ? Eu O3 C10 O4 134.4(5) . . . . ? Eu O3 C10 C9 -44.8(5) . . . . ? N1 C9 C10 O4 -178.2(5) . . . . ? N1 C9 C10 O3 1.1(6) . . . . ? N1 C9 C10 Eu -28.3(3) . . . . ? OW1 Eu C10 O4 -0.7(7) 3_666 . . . ? OW1 Eu C10 O4 4.9(8) . . . . ? O1 Eu C10 O4 84.1(7) . . . . ? O5 Eu C10 O4 -87.9(7) . . . . ? O7 Eu C10 O4 151.5(6) . . . . ? O3 Eu C10 O4 -89.7(7) . . . . ? N2 Eu C10 O4 -152.4(7) . . . . ? N1 Eu C10 O4 148.6(7) . . . . ? C8 Eu C10 O4 104.4(7) . . . . ? C12 Eu C10 O4 -103.1(7) . . . . ? C14 Eu C10 O4 179.0(6) . . . . ? OW1 Eu C10 O3 89.1(3) 3_666 . . . ? OW1 Eu C10 O3 94.7(4) . . . . ? O1 Eu C10 O3 173.8(3) . . . . ? O5 Eu C10 O3 1.8(3) . . . . ? O7 Eu C10 O3 -118.8(3) . . . . ? N2 Eu C10 O3 -62.6(3) . . . . ? N1 Eu C10 O3 -121.7(4) . . . . ? C8 Eu C10 O3 -165.8(4) . . . . ? C12 Eu C10 O3 -13.4(3) . . . . ? C14 Eu C10 O3 -91.2(4) . . . . ? OW1 Eu C10 C9 -130.4(3) 3_666 . . . ? OW1 Eu C10 C9 -124.8(3) . . . . ? O1 Eu C10 C9 -45.6(3) . . . . ? O5 Eu C10 C9 142.3(3) . . . . ? O7 Eu C10 C9 21.8(3) . . . . ? O3 Eu C10 C9 140.6(5) . . . . ? N2 Eu C10 C9 77.9(3) . . . . ? N1 Eu C10 C9 18.9(2) . . . . ? C8 Eu C10 C9 -25.3(3) . . . . ? C12 Eu C10 C9 127.1(3) . . . . ? C14 Eu C10 C9 49.3(3) . . . . ? C13 N2 C11 C12 -79.5(4) . . . . ? C6 N2 C11 C12 158.0(3) . . . . ? Eu N2 C11 C12 32.3(4) . . . . ? Na O6 C12 O5 4.4(4) 3_666 . . . ? Na O6 C12 C11 -175.8(3) 3_666 . . . ? Na O6 C12 Eu 52.8(7) 3_666 . . . ? Eu O5 C12 O6 147.0(3) . . . . ? Na O5 C12 O6 -5.0(5) 3_666 . . . ? Eu O5 C12 C11 -32.8(5) . . . . ? Na O5 C12 C11 175.3(3) 3_666 . . . ? Eu O5 C12 Na 152.0(3) . . . 3_666 ? Na O5 C12 Eu -152.0(3) 3_666 . . . ? N2 C11 C12 O6 176.0(4) . . . . ? N2 C11 C12 O5 -4.2(5) . . . . ? N2 C11 C12 Na 31(3) . . . 3_666 ? N2 C11 C12 Eu -24.9(3) . . . . ? OW1 Eu C12 O6 -16.3(7) 3_666 . . . ? OW1 Eu C12 O6 -87.5(7) . . . . ? O1 Eu C12 O6 88.7(8) . . . . ? O5 Eu C12 O6 -71.1(7) . . . . ? O7 Eu C12 O6 -166.4(7) . . . . ? O3 Eu C12 O6 54.4(7) . . . . ? N2 Eu C12 O6 154.6(7) . . . . ? N1 Eu C12 O6 107.9(7) . . . . ? C10 Eu C12 O6 59.7(7) . . . . ? C8 Eu C12 O6 123.1(7) . . . . ? C14 Eu C12 O6 -166.3(7) . . . . ? OW1 Eu C12 O5 54.8(3) 3_666 . . . ? OW1 Eu C12 O5 -16.4(3) . . . . ? O1 Eu C12 O5 159.8(4) . . . . ? O7 Eu C12 O5 -95.4(3) . . . . ? O3 Eu C12 O5 125.5(3) . . . . ? N2 Eu C12 O5 -134.3(4) . . . . ? N1 Eu C12 O5 179.0(3) . . . . ? C10 Eu C12 O5 130.8(3) . . . . ? C8 Eu C12 O5 -165.8(3) . . . . ? C14 Eu C12 O5 -95.3(3) . . . . ? OW1 Eu C12 C11 -154.0(2) 3_666 . . . ? OW1 Eu C12 C11 134.8(2) . . . . ? O1 Eu C12 C11 -49.0(5) . . . . ? O5 Eu C12 C11 151.2(5) . . . . ? O7 Eu C12 C11 55.8(3) . . . . ? O3 Eu C12 C11 -83.3(2) . . . . ? N2 Eu C12 C11 16.8(2) . . . . ? N1 Eu C12 C11 -29.8(3) . . . . ? C10 Eu C12 C11 -78.0(2) . . . . ? C8 Eu C12 C11 -14.6(4) . . . . ? C14 Eu C12 C11 55.9(2) . . . . ? OW1 Eu C12 Na 31.64(13) 3_666 . . 3_666 ? OW1 Eu C12 Na -39.58(13) . . . 3_666 ? O1 Eu C12 Na 136.6(4) . . . 3_666 ? O5 Eu C12 Na -23.2(3) . . . 3_666 ? O7 Eu C12 Na -118.52(12) . . . 3_666 ? O3 Eu C12 Na 102.32(14) . . . 3_666 ? N2 Eu C12 Na -157.52(18) . . . 3_666 ? N1 Eu C12 Na 155.80(11) . . . 3_666 ? C10 Eu C12 Na 107.62(13) . . . 3_666 ? C8 Eu C12 Na 171.01(17) . . . 3_666 ? C14 Eu C12 Na -118.44(13) . . . 3_666 ? C11 N2 C13 C14 161.3(4) . . . . ? C6 N2 C13 C14 -73.4(4) . . . . ? Eu N2 C13 C14 46.6(4) . . . . ? Na O8 C14 O7 -168.0(3) 1_455 . . . ? Na O8 C14 C13 9.7(8) 1_455 . . . ? Na O8 C14 Eu -134.4(6) 1_455 . . . ? Eu O7 C14 O8 160.6(4) . . . . ? Eu O7 C14 C13 -17.2(5) . . . . ? N2 C13 C14 O8 157.3(4) . . . . ? N2 C13 C14 O7 -24.8(5) . . . . ? N2 C13 C14 Eu -35.9(3) . . . . ? OW1 Eu C14 O8 32.0(10) 3_666 . . . ? OW1 Eu C14 O8 29.2(8) . . . . ? O1 Eu C14 O8 -61.1(9) . . . . ? O5 Eu C14 O8 113.5(9) . . . . ? O7 Eu C14 O8 -46.8(8) . . . . ? O3 Eu C14 O8 -175.7(8) . . . . ? N2 Eu C14 O8 173.0(9) . . . . ? N1 Eu C14 O8 -124.5(9) . . . . ? C10 Eu C14 O8 -147.4(8) . . . . ? C8 Eu C14 O8 -75.4(9) . . . . ? C12 Eu C14 O8 133.5(9) . . . . ? OW1 Eu C14 O7 78.8(4) 3_666 . . . ? OW1 Eu C14 O7 76.0(3) . . . . ? O1 Eu C14 O7 -14.3(3) . . . . ? O5 Eu C14 O7 160.3(3) . . . . ? O3 Eu C14 O7 -128.9(3) . . . . ? N2 Eu C14 O7 -140.2(4) . . . . ? N1 Eu C14 O7 -77.7(3) . . . . ? C10 Eu C14 O7 -100.6(3) . . . . ? C8 Eu C14 O7 -28.6(3) . . . . ? C12 Eu C14 O7 -179.7(3) . . . . ? OW1 Eu C14 C13 -116.9(3) 3_666 . . . ? OW1 Eu C14 C13 -119.6(3) . . . . ? O1 Eu C14 C13 150.0(2) . . . . ? O5 Eu C14 C13 -35.3(2) . . . . ? O7 Eu C14 C13 164.3(5) . . . . ? O3 Eu C14 C13 35.5(3) . . . . ? N2 Eu C14 C13 24.2(2) . . . . ? N1 Eu C14 C13 86.7(2) . . . . ? C10 Eu C14 C13 63.7(3) . . . . ? C8 Eu C14 C13 135.8(3) . . . . ? C12 Eu C14 C13 -15.4(2) . . . . ? loop_ _geom_hbond_atom_site_label_D _geom_hbond_atom_site_label_H _geom_hbond_atom_site_label_A _geom_hbond_distance_DH _geom_hbond_distance_HA _geom_hbond_distance_DA _geom_hbond_angle_DHA _geom_hbond_site_symmetry_A O2...OW3 = 2.823(5) A O3...OW3_$1 = 2.715(5) A O4...OW2_$1 = 3.107(6) A O5...OW5_$2 = 3.099(5) A O6...OW2_$3 = 2.790(5) A O6...OW4_$1 = 2.421(4) A O6...OW3_$1 = 3.197(5) A O7...OW4 = 2.447(4) A O8...OW4 = 2.580(5) A OW1...O3_$2 = 2.967(4) A OW1...O1_$2 = 3.112(4) A OW1...OW5 = 2.826(5) A OW2...OW4_$4 = 2.552(5) A OW2...OW5_$4 = 3.110(5) A OW3...OW4 = 2.358(5) A OW3...OW5 = 3.032(5) A OW3...OW5_$4 = 2.947(5) A OW4...OW5 = 2.499(4) A _diffrn_measured_fraction_theta_max 0.938 _diffrn_reflns_theta_full 25.46 _diffrn_measured_fraction_theta_full 0.938 _refine_diff_density_max 0.649 _refine_diff_density_min -0.661 _refine_diff_density_rms 0.115