# Supplementary Material (ESI) for Dalton Transactions
# This journal is © The Royal Society of Chemistry 1999
# CCDC Number: 186/1701

data_1

_audit_creation_method            SHELXL-97
_chemical_name_systematic
;
 ?
;
_chemical_name_common             ?
_chemical_formula_moiety          ?
_chemical_formula_sum
 'C37 H51 N3 O3 P Rh'
_chemical_formula_weight          719.69

loop_
 _atom_type_symbol
 _atom_type_description
 _atom_type_scat_dispersion_real
 _atom_type_scat_dispersion_imag
 _atom_type_scat_source
 'C'  'C'   0.0033   0.0016
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H'  'H'   0.0000   0.0000
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N'  'N'   0.0061   0.0033
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O'  'O'   0.0106   0.0060
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'P'  'P'   0.1023   0.0942
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Rh'  'Rh'  -1.1178   0.9187
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting            Triclinic
_symmetry_space_group_name_H-M    P-1

loop_
 _symmetry_equiv_pos_as_xyz
 'x, y, z'
 '-x, -y, -z'

_cell_length_a                    8.9370(18)
_cell_length_b                    14.420(3)
_cell_length_c                    15.427(3)
_cell_angle_alpha                 82.42(3)
_cell_angle_beta                  88.44(3)
_cell_angle_gamma                 75.80(3)
_cell_volume                      1910.4(7)
_cell_formula_units_Z             2
_cell_measurement_temperature     293(2)
_cell_measurement_reflns_used     Fylli
_cell_measurement_theta_min       2
_cell_measurement_theta_max       30

_exptl_crystal_description        'Plate'
_exptl_crystal_colour             'Yellow'
_exptl_crystal_size_max           0.25
_exptl_crystal_size_mid           0.14
_exptl_crystal_size_min           0.04
_exptl_crystal_density_meas       ?
_exptl_crystal_density_diffrn     1.251
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000              756
_exptl_absorpt_coefficient_mu     0.525
_exptl_absorpt_correction_type    empirical
_exptl_absorpt_correction_T_min   0.473
_exptl_absorpt_correction_T_max   0.946

_exptl_special_details
;
 ?
;

_diffrn_ambient_temperature       293(2)
_diffrn_radiation_wavelength      0.71073
_diffrn_radiation_type            MoK\a
_diffrn_radiation_source          'rotating anode'
_diffrn_radiation_monochromator   graphite
_diffrn_measurement_device_type   'SMART CCD system'
_diffrn_measurement_method        'w-scan'
_diffrn_detector_area_resol_mean  512*512
_diffrn_standards_number          ?
_diffrn_standards_interval_count  ?
_diffrn_standards_interval_time   ?
_diffrn_standards_decay_%         0.00
_diffrn_reflns_number             15771
_diffrn_reflns_av_R_equivalents   0.0433
_diffrn_reflns_av_sigmaI/netI     0.1289
_diffrn_reflns_limit_h_min        -12
_diffrn_reflns_limit_h_max        13
_diffrn_reflns_limit_k_min        -11
_diffrn_reflns_limit_k_max        20
_diffrn_reflns_limit_l_min        -21
_diffrn_reflns_limit_l_max        22
_diffrn_reflns_theta_min          1.33
_diffrn_reflns_theta_max          31.66
_reflns_number_total              10954
_reflns_number_gt                 4189
_reflns_threshold_expression      >2sigma(I)

_computing_data_collection        'Siemens SMART'
_computing_cell_refinement        'Siemens SHELXTL'
_computing_data_reduction         'Siemens SAINT (Siemens, 1995)'
_computing_structure_solution     'SHELXS86 (Sheldrick, 1990)'
_computing_structure_refinement   'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'Diamond (Brandenburg, 1999)'
_computing_publication_material   'SHELXL97 (Sheldrick, 1997)'

_refine_special_details
;
 Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F^2^, conventional R-factors R are based
 on F, with F set to zero for negative F^2^. The threshold expression of
 F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F^2^ are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef  Fsqd
_refine_ls_matrix_type            full
_refine_ls_weighting_scheme
 'calc w=1/[\s^2^(Fo^2^)+(0.0616P)^2^+0.0100P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary      direct
_atom_sites_solution_secondary    difmap
_atom_sites_solution_hydrogens    geom
_refine_ls_hydrogen_treatment     mixed
_refine_ls_extinction_method      none
_refine_ls_extinction_coef        ?
_refine_ls_number_reflns          10954
_refine_ls_number_parameters      412
_refine_ls_number_restraints      1
_refine_ls_R_factor_all           0.1857
_refine_ls_R_factor_gt            0.0583
_refine_ls_wR_factor_ref          0.1713
_refine_ls_wR_factor_gt           0.1179
_refine_ls_goodness_of_fit_ref    0.924
_refine_ls_restrained_S_all       0.927
_refine_ls_shift/su_max           0.905
_refine_ls_shift/su_mean          0.058

loop_
 _atom_site_label
 _atom_site_type_symbol
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_U_iso_or_equiv
 _atom_site_adp_type
 _atom_site_occupancy
 _atom_site_calc_flag
 _atom_site_refinement_flags
 _atom_site_disorder_assembly
 _atom_site_disorder_group
Rh Rh 0.60151(4) 0.82082(3) 0.65141(3) 0.07321(18) Uani 1 d . . .
P P 0.55268(11) 0.69917(8) 0.59014(8) 0.0576(3) Uani 1 d . . .
O1 O 0.6735(3) 0.8795(2) 0.5354(2) 0.0808(10) Uani 1 d . . .
O2 O 0.6449(4) 0.9343(3) 0.7077(3) 0.1084(13) Uani 1 d . . .
O3 O 0.5106(7) 0.7359(4) 0.8223(3) 0.149(2) Uani 1 d . . .
N1 N 0.8551(5) 0.3008(3) 0.8871(3) 0.0884(12) Uani 1 d . . .
N2 N 1.1817(12) 0.0813(6) 0.9010(7) 0.193(4) Uani 1 d . . .
N3 N 0.8337(18) 0.4197(12) 1.0894(8) 0.268(6) Uani 1 d . . .
C1 C 0.5446(7) 0.7694(5) 0.7534(5) 0.105(2) Uani 1 d . . .
C2 C 0.7686(8) 0.9790(4) 0.4270(5) 0.129(2) Uani 1 d . . .
H2A H 0.8482 1.0135 0.4252 0.194 Uiso 1 calc R . .
H2B H 0.6808 1.0181 0.3939 0.194 Uiso 1 calc R . .
H2C H 0.8066 0.9201 0.4022 0.194 Uiso 1 calc R . .
C3 C 0.7226(6) 0.9567(4) 0.5189(5) 0.0921(18) Uani 1 d . . .
C4 C 0.7363(7) 1.0147(4) 0.5815(7) 0.120(3) Uani 1 d . . .
H4 H 0.7760 1.0677 0.5625 0.144 Uiso 1 calc R . .
C5 C 0.6978(8) 1.0028(5) 0.6684(7) 0.112(2) Uani 1 d . . .
C6 C 0.7176(10) 1.0763(5) 0.7272(6) 0.179(4) Uani 1 d . . .
H6A H 0.7510 1.1279 0.6928 0.268 Uiso 1 calc R . .
H6B H 0.7934 1.0455 0.7716 0.268 Uiso 1 calc R . .
H6C H 0.6209 1.1017 0.7543 0.268 Uiso 1 calc R . .
C7 C 0.6537(4) 0.6759(3) 0.4874(3) 0.0585(11) Uani 1 d . . .
C8 C 0.6268(5) 0.7485(3) 0.4157(4) 0.0725(13) Uani 1 d . . .
H8 H 0.5563 0.8069 0.4206 0.087 Uiso 1 calc R . .
C9 C 0.7039(6) 0.7344(4) 0.3375(4) 0.0856(15) Uani 1 d . . .
H9 H 0.6847 0.7833 0.2905 0.103 Uiso 1 calc R . .
C10 C 0.8073(6) 0.6497(5) 0.3291(4) 0.0876(15) Uani 1 d . . .
H10 H 0.8592 0.6407 0.2766 0.105 Uiso 1 calc R . .
C11 C 0.8351(5) 0.5774(4) 0.3982(4) 0.0830(15) Uani 1 d . . .
H11 H 0.9050 0.5192 0.3920 0.100 Uiso 1 calc R . .
C12 C 0.7596(5) 0.5900(3) 0.4778(3) 0.0669(12) Uani 1 d . . .
H12 H 0.7805 0.5407 0.5244 0.080 Uiso 1 calc R . .
C13 C 0.3508(4) 0.7130(3) 0.5599(3) 0.0561(10) Uani 1 d . . .
C14 C 0.2345(5) 0.7628(3) 0.6101(3) 0.0698(12) Uani 1 d . . .
H14 H 0.2593 0.7892 0.6581 0.084 Uiso 1 calc R . .
C15 C 0.0801(5) 0.7731(3) 0.5882(4) 0.0821(15) Uani 1 d . . .
H15 H 0.0023 0.8050 0.6226 0.098 Uiso 1 calc R . .
C16 C 0.0418(5) 0.7364(3) 0.5163(4) 0.0823(15) Uani 1 d . . .
H16 H -0.0612 0.7443 0.5015 0.099 Uiso 1 calc R . .
C17 C 0.1565(5) 0.6884(4) 0.4669(4) 0.0817(14) Uani 1 d . . .
H17 H 0.1315 0.6634 0.4182 0.098 Uiso 1 calc R . .
C18 C 0.3095(5) 0.6765(3) 0.4887(3) 0.0711(13) Uani 1 d . . .
H18 H 0.3862 0.6432 0.4544 0.085 Uiso 1 calc R . .
C19 C 0.6054(4) 0.5825(3) 0.6574(3) 0.0575(10) Uani 1 d . . .
C20 C 0.5170(5) 0.5147(3) 0.6638(3) 0.0648(11) Uani 1 d . . .
H20 H 0.4239 0.5290 0.6335 0.078 Uiso 1 calc R . .
C21 C 0.5662(6) 0.4264(3) 0.7145(3) 0.0735(13) Uani 1 d . . .
H21 H 0.5056 0.3821 0.7176 0.088 Uiso 1 calc R . .
C22 C 0.7032(6) 0.4025(3) 0.7608(3) 0.0695(12) Uani 1 d . . .
C23 C 0.7908(5) 0.4697(4) 0.7552(3) 0.0743(13) Uani 1 d . . .
H23 H 0.8838 0.4551 0.7856 0.089 Uiso 1 calc R . .
C24 C 0.7421(5) 0.5585(3) 0.7049(3) 0.0692(12) Uani 1 d . . .
H24 H 0.8022 0.6030 0.7029 0.083 Uiso 1 calc R . .
C25 C 0.7576(7) 0.3033(4) 0.8119(4) 0.0898(16) Uani 1 d . . .
H25A H 0.6681 0.2800 0.8323 0.108 Uiso 1 calc R . .
H25B H 0.8148 0.2596 0.7731 0.108 Uiso 1 calc R . .
C26 C 0.9415(7) 0.2023(4) 0.9184(4) 0.108(2) Uani 1 d . . .
H26A H 0.8771 0.1580 0.9135 0.130 Uiso 1 calc R . .
H26B H 0.9674 0.1982 0.9797 0.130 Uiso 1 calc R . .
C27 C 1.0850(9) 0.1732(5) 0.8681(5) 0.147(3) Uani 1 d . . .
H27A H 1.0577 0.1717 0.8079 0.177 Uiso 1 calc R . .
H27B H 1.1434 0.2218 0.8680 0.177 Uiso 1 calc R . .
C28 C 1.212(3) 0.0143(11) 0.8656(14) 0.44(2) Uani 1 d D . .
H28A H 1.2621 -0.0313 0.9143 0.528 Uiso 1 calc R . .
H28B H 1.2982 0.0299 0.8318 0.528 Uiso 1 calc R . .
C29 C 1.186(2) -0.0435(12) 0.8215(10) 0.322(9) Uani 1 d D . .
H29A H 1.2754 -0.0965 0.8212 0.483 Uiso 1 calc R . .
H29B H 1.1619 -0.0129 0.7627 0.483 Uiso 1 calc R . .
H29C H 1.1002 -0.0670 0.8456 0.483 Uiso 1 calc R . .
C30 C 1.2582(19) 0.0764(13) 0.9865(15) 0.309(10) Uani 1 d . . .
H30A H 1.1792 0.0894 1.0307 0.371 Uiso 1 calc R . .
H30B H 1.3200 0.0112 1.0024 0.371 Uiso 1 calc R . .
C31 C 1.349(3) 0.1380(15) 0.988(2) 0.54(3) Uani 1 d . . .
H31A H 1.2907 0.2026 0.9695 0.817 Uiso 1 calc R . .
H31B H 1.4344 0.1216 0.9488 0.817 Uiso 1 calc R . .
H31C H 1.3877 0.1338 1.0461 0.817 Uiso 1 calc R . .
C32 C 0.7703(8) 0.3489(5) 0.9572(4) 0.117(2) Uani 1 d . . .
H32A H 0.7282 0.3034 0.9963 0.141 Uiso 1 calc R . .
H32B H 0.6850 0.4007 0.9327 0.141 Uiso 1 calc R . .
C33 C 0.8815(9) 0.3914(6) 1.0097(5) 0.137(3) Uani 1 d . . .
H33A H 0.9786 0.3431 1.0185 0.165 Uiso 1 calc R . .
H33B H 0.9027 0.4466 0.9730 0.165 Uiso 1 calc R . .
C34 C 0.869(2) 0.3618(15) 1.1647(15) 0.360(14) Uani 1 d . . .
H34A H 0.7893 0.3270 1.1767 0.432 Uiso 1 calc R . .
H34B H 0.8648 0.4023 1.2107 0.432 Uiso 1 calc R . .
C35 C 1.020(2) 0.2905(13) 1.1717(7) 0.314(10) Uani 1 d . . .
H35A H 1.0050 0.2285 1.1956 0.471 Uiso 1 calc R . .
H35B H 1.0870 0.3099 1.2092 0.471 Uiso 1 calc R . .
H35C H 1.0647 0.2868 1.1146 0.471 Uiso 1 calc R . .
C36 C 0.7013(18) 0.4872(14) 1.0983(11) 0.304(11) Uani 1 d . . .
H36A H 0.6865 0.4940 1.1598 0.365 Uiso 1 calc R . .
H36B H 0.6160 0.4640 1.0793 0.365 Uiso 1 calc R . .
C37 C 0.6941(17) 0.5831(10) 1.0495(13) 0.333(12) Uani 1 d . . .
H37A H 0.6874 0.6292 1.0900 0.500 Uiso 1 calc R . .
H37B H 0.6049 0.6020 1.0121 0.500 Uiso 1 calc R . .
H37C H 0.7855 0.5808 1.0148 0.500 Uiso 1 calc R . .

loop_
 _atom_site_aniso_label
 _atom_site_aniso_U_11
 _atom_site_aniso_U_22
 _atom_site_aniso_U_33
 _atom_site_aniso_U_23
 _atom_site_aniso_U_13
 _atom_site_aniso_U_12
Rh 0.0541(2) 0.0613(2) 0.1101(4) -0.0332(2) -0.0141(2) -0.01200(17)
P 0.0389(5) 0.0543(6) 0.0834(8) -0.0197(6) -0.0060(5) -0.0121(5)
O1 0.070(2) 0.0536(18) 0.123(3) -0.0152(18) -0.0071(19) -0.0206(16)
O2 0.100(3) 0.077(2) 0.158(4) -0.051(2) -0.037(2) -0.017(2)
O3 0.185(5) 0.175(5) 0.105(4) -0.051(4) 0.018(4) -0.064(4)
N1 0.095(3) 0.083(3) 0.078(3) -0.008(2) -0.014(3) -0.005(2)
N2 0.205(8) 0.131(6) 0.189(8) -0.010(6) -0.018(6) 0.060(6)
N3 0.286(15) 0.329(16) 0.173(9) -0.092(10) 0.090(10) -0.024(12)
C1 0.100(4) 0.119(5) 0.107(5) -0.069(4) -0.008(4) -0.020(4)
C2 0.129(5) 0.077(4) 0.180(7) 0.016(4) 0.002(5) -0.038(4)
C3 0.062(3) 0.052(3) 0.155(6) -0.002(4) -0.024(3) -0.004(2)
C4 0.091(4) 0.057(3) 0.216(9) -0.028(5) -0.046(5) -0.017(3)
C5 0.091(4) 0.062(4) 0.191(7) -0.048(5) -0.056(5) -0.012(3)
C6 0.205(8) 0.087(4) 0.259(10) -0.068(5) -0.107(7) -0.028(5)
C7 0.041(2) 0.060(3) 0.082(3) -0.019(2) -0.004(2) -0.019(2)
C8 0.050(2) 0.071(3) 0.098(4) -0.012(3) -0.010(3) -0.016(2)
C9 0.068(3) 0.104(4) 0.088(4) -0.009(3) 0.003(3) -0.029(3)
C10 0.066(3) 0.115(5) 0.089(4) -0.027(4) 0.012(3) -0.029(3)
C11 0.053(3) 0.090(4) 0.109(4) -0.035(4) 0.007(3) -0.012(3)
C12 0.047(2) 0.063(3) 0.093(4) -0.020(2) 0.001(2) -0.012(2)
C13 0.039(2) 0.047(2) 0.083(3) -0.011(2) -0.002(2) -0.0109(18)
C14 0.050(2) 0.070(3) 0.089(3) -0.017(3) -0.003(2) -0.011(2)
C15 0.044(2) 0.077(3) 0.122(4) -0.020(3) 0.008(3) -0.006(2)
C16 0.042(2) 0.065(3) 0.140(5) -0.005(3) -0.014(3) -0.016(2)
C17 0.054(3) 0.086(3) 0.112(4) -0.025(3) -0.019(3) -0.020(3)
C18 0.045(2) 0.074(3) 0.100(4) -0.030(3) -0.004(2) -0.015(2)
C19 0.044(2) 0.059(2) 0.072(3) -0.017(2) -0.005(2) -0.0103(19)
C20 0.056(2) 0.064(3) 0.078(3) -0.015(2) -0.009(2) -0.020(2)
C21 0.078(3) 0.071(3) 0.082(3) -0.014(3) -0.011(3) -0.034(3)
C22 0.080(3) 0.059(3) 0.071(3) -0.016(2) -0.008(3) -0.015(2)
C23 0.054(3) 0.077(3) 0.090(4) -0.016(3) -0.020(2) -0.008(2)
C24 0.053(2) 0.064(3) 0.095(4) -0.017(3) -0.016(2) -0.018(2)
C25 0.107(4) 0.071(3) 0.092(4) -0.011(3) -0.020(3) -0.020(3)
C26 0.113(5) 0.089(4) 0.102(4) 0.014(3) -0.006(4) 0.003(4)
C27 0.127(6) 0.120(6) 0.156(7) 0.014(5) 0.011(5) 0.027(5)
C28 0.73(5) 0.152(12) 0.36(3) -0.129(14) -0.17(3) 0.107(19)
C29 0.39(2) 0.31(2) 0.312(19) -0.158(16) 0.128(17) -0.120(17)
C30 0.207(16) 0.226(19) 0.41(3) 0.008(19) -0.048(17) 0.088(13)
C31 0.41(3) 0.29(2) 0.92(6) 0.08(3) -0.41(4) -0.09(2)
C32 0.111(5) 0.133(5) 0.097(5) -0.022(4) -0.006(4) -0.004(4)
C33 0.130(6) 0.178(7) 0.107(6) -0.039(5) -0.013(5) -0.031(5)
C34 0.27(2) 0.41(3) 0.31(2) 0.10(2) 0.11(2) -0.009(19)
C35 0.33(2) 0.54(3) 0.120(8) -0.008(13) -0.056(11) -0.22(2)
C36 0.213(14) 0.39(3) 0.31(2) -0.19(2) 0.095(15) -0.006(17)
C37 0.159(11) 0.247(17) 0.60(4) -0.038(19) 0.056(16) -0.078(13)

_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
 _geom_bond_atom_site_label_1
 _geom_bond_atom_site_label_2
 _geom_bond_distance
 _geom_bond_site_symmetry_2
 _geom_bond_publ_flag
Rh C1 1.765(8) . ?
Rh O1 2.034(4) . ?
Rh O2 2.070(4) . ?
Rh P 2.2352(12) . ?
P C19 1.818(4) . ?
P C7 1.832(4) . ?
P C13 1.832(4) . ?
O1 C3 1.286(6) . ?
O2 C5 1.274(8) . ?
O3 C1 1.172(7) . ?
N1 C32 1.457(7) . ?
N1 C25 1.460(6) . ?
N1 C26 1.466(6) . ?
N2 C28 1.145(14) . ?
N2 C27 1.430(9) . ?
N2 C30 1.49(2) . ?
N3 C34 1.334(18) . ?
N3 C36 1.352(17) . ?
N3 C33 1.371(10) . ?
C2 C3 1.483(8) . ?
C3 C4 1.384(9) . ?
C4 C5 1.375(9) . ?
C5 C6 1.527(8) . ?
C7 C12 1.384(6) . ?
C7 C8 1.400(6) . ?
C8 C9 1.386(6) . ?
C9 C10 1.358(7) . ?
C10 C11 1.371(7) . ?
C11 C12 1.396(6) . ?
C13 C18 1.376(6) . ?
C13 C14 1.390(6) . ?
C14 C15 1.398(6) . ?
C15 C16 1.375(7) . ?
C16 C17 1.363(7) . ?
C17 C18 1.381(6) . ?
C19 C24 1.386(6) . ?
C19 C20 1.392(5) . ?
C20 C21 1.381(6) . ?
C21 C22 1.379(6) . ?
C22 C23 1.381(6) . ?
C22 C25 1.512(6) . ?
C23 C24 1.383(6) . ?
C26 C27 1.480(8) . ?
C28 C29 1.212(14) . ?
C30 C31 1.35(2) . ?
C32 C33 1.579(9) . ?
C34 C35 1.48(2) . ?
C36 C37 1.473(19) . ?

loop_
 _geom_angle_atom_site_label_1
 _geom_angle_atom_site_label_2
 _geom_angle_atom_site_label_3
 _geom_angle
 _geom_angle_site_symmetry_1
 _geom_angle_site_symmetry_3
 _geom_angle_publ_flag
C1 Rh O1 178.3(2) . . ?
C1 Rh O2 90.9(2) . . ?
O1 Rh O2 88.30(16) . . ?
C1 Rh P 89.17(19) . . ?
O1 Rh P 91.61(10) . . ?
O2 Rh P 179.49(10) . . ?
C19 P C7 103.14(19) . . ?
C19 P C13 104.40(18) . . ?
C7 P C13 102.38(19) . . ?
C19 P Rh 114.51(14) . . ?
C7 P Rh 115.21(13) . . ?
C13 P Rh 115.57(14) . . ?
C3 O1 Rh 128.5(4) . . ?
C5 O2 Rh 125.9(4) . . ?
C32 N1 C25 112.8(5) . . ?
C32 N1 C26 112.0(4) . . ?
C25 N1 C26 111.7(5) . . ?
C28 N2 C27 126.2(15) . . ?
C28 N2 C30 117.9(14) . . ?
C27 N2 C30 115.8(10) . . ? 
C34 N3 C36 109.9(13) . . ?
C34 N3 C33 123.0(18) . . ?
C36 N3 C33 121.7(15) . . ?
O3 C1 Rh 178.0(6) . . ?
O1 C3 C4 123.7(7) . . ?
O1 C3 C2 115.1(6) . . ?
C4 C3 C2 121.2(6) . . ?
C5 C4 C3 127.4(7) . . ?
O2 C5 C4 126.3(6) . . ?
O2 C5 C6 114.0(8) . . ?
C4 C5 C6 119.8(7) . . ?
C12 C7 C8 118.1(4) . . ?
C12 C7 P 122.7(4) . . ?
C8 C7 P 119.1(3) . . ?
C9 C8 C7 120.8(5) . . ?
C10 C9 C8 120.5(5) . . ?
C9 C10 C11 119.8(5) . . ?
C10 C11 C12 120.8(5) . . ?
C7 C12 C11 120.0(5) . . ?
C18 C13 C14 118.4(4) . . ?
C18 C13 P 122.4(3) . . ?
C14 C13 P 119.2(3) . . ?
C13 C14 C15 119.7(5) . . ?
C16 C15 C14 120.8(5) . . ?
C17 C16 C15 119.2(4) . . ?
C16 C17 C18 120.6(5) . . ?
C13 C18 C17 121.3(4) . . ?
C24 C19 C20 117.5(4) . . ?
C24 C19 P 118.7(3) . . ?
C20 C19 P 123.8(3) . . ?
C21 C20 C19 120.7(4) . . ?
C22 C21 C20 121.5(4) . . ?
C21 C22 C23 118.0(4) . . ?
C21 C22 C25 120.2(4) . . ?
C23 C22 C25 121.8(5) . . ?
C22 C23 C24 120.9(4) . . ?
C23 C24 C19 121.4(4) . . ?
N1 C25 C22 113.9(4) . . ?
N1 C26 C27 111.7(5) . . ?
N2 C27 C26 114.2(6) . . ?
N2 C28 C29 155(3) . . ?
C31 C30 N2 115(2) . . ?
N1 C32 C33 109.8(5) . . ?
N3 C33 C32 118.2(8) . . ?
N3 C34 C35 118.1(17) . . ?
N3 C36 C37 115.5(16) . . ?

_diffrn_measured_fraction_theta_max    0.851
_diffrn_reflns_theta_full              31.66
_diffrn_measured_fraction_theta_full   0.851
_refine_diff_density_max    0.441
_refine_diff_density_min   -0.503
_refine_diff_density_rms    0.091