# Supplementary Material (ESI) for Dalton Transactions # This journal is © The Royal Society of Chemistry 2000 # CCDC Number: 186/1969 data_fr1 _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_formula_moiety ? _chemical_formula_sum 'C36 H40 Au Mn N O12 P Ru3' _chemical_formula_weight 1264.78 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'Au' 'Au' -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Ru' 'Ru' -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Mn' 'Mn' 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'P' 'P' 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting ? _symmetry_space_group_name_H-M ? loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 9.339(3) _cell_length_b 12.966(5) _cell_length_c 17.725(5) _cell_angle_alpha 69.560(2) _cell_angle_beta 80.730(2) _cell_angle_gamma 81.070(2) _cell_volume 1973.5(11) _cell_formula_units_Z 2 _cell_measurement_temperature 293(2) _cell_measurement_reflns_used ? _cell_measurement_theta_min ? _cell_measurement_theta_max ? _exptl_crystal_description ? _exptl_crystal_colour ? _exptl_crystal_size_max ? _exptl_crystal_size_mid ? _exptl_crystal_size_min ? _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 2.128 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1220 _exptl_absorpt_coefficient_mu 5.239 _exptl_absorpt_correction_type ? _exptl_absorpt_correction_T_min ? _exptl_absorpt_correction_T_max ? _exptl_special_details ; ? ; _diffrn_ambient_temperature 293(2) _diffrn_radiation_wavelength 0.71070 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type ? _diffrn_measurement_method ? _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 4689 _diffrn_reflns_av_R_equivalents 0.0325 _diffrn_reflns_av_sigmaI/netI 0.0787 _diffrn_reflns_limit_h_min -10 _diffrn_reflns_limit_h_max 10 _diffrn_reflns_limit_k_min -13 _diffrn_reflns_limit_k_max 14 _diffrn_reflns_limit_l_min 0 _diffrn_reflns_limit_l_max 19 _diffrn_reflns_theta_min 2.64 _diffrn_reflns_theta_max 22.99 _reflns_number_total 4509 _reflns_number_gt 4478 _reflns_threshold_expression >2sigma(I) _computing_data_collection ? _computing_cell_refinement ? _computing_data_reduction ? _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme 'calc w=1/[\s^2^(Fo^2^)+(0.0081P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method SHELXL _refine_ls_extinction_coef 0.00018(6) _refine_ls_extinction_expression 'Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^' _refine_ls_number_reflns 4509 _refine_ls_number_parameters 386 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0278 _refine_ls_R_factor_gt 0.0277 _refine_ls_wR_factor_ref 0.0626 _refine_ls_wR_factor_gt 0.0625 _refine_ls_goodness_of_fit_ref 0.715 _refine_ls_restrained_S_all 0.715 _refine_ls_shift/su_max 0.171 _refine_ls_shift/su_mean 0.011 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Au1 Au 0.23757(3) 0.03433(2) 0.213109(17) 0.03819(10) Uani 1 d . . . Ru1 Ru 0.45190(6) -0.13655(4) 0.26750(4) 0.03653(15) Uani 1 d . . . Ru2 Ru 0.43582(6) -0.12859(5) 0.42565(4) 0.04093(16) Uani 1 d . . . Ru3 Ru 0.17882(5) -0.12414(4) 0.36030(3) 0.03255(15) Uani 1 d . . . Mn1 Mn 0.24673(12) -0.48307(8) 0.33391(6) 0.0403(3) Uani 1 d . . . P1 P 0.17570(19) 0.19471(14) 0.11005(11) 0.0384(4) Uani 1 d . . . O1 O 0.6421(6) 0.0507(4) 0.2148(4) 0.0716(18) Uani 1 d . . . O2 O 0.4333(7) -0.1242(6) 0.0942(4) 0.093(2) Uani 1 d . . . O3 O 0.7154(7) -0.3089(5) 0.2926(5) 0.102(3) Uani 1 d . . . O4 O 0.4033(7) 0.1241(5) 0.3498(4) 0.0709(17) Uani 1 d . . . O5 O 0.7512(6) -0.1430(6) 0.4561(4) 0.086(2) Uani 1 d . . . O6 O 0.2908(7) -0.1264(6) 0.5911(4) 0.0820(19) Uani 1 d . . . O7 O 0.4505(8) -0.3809(5) 0.4728(4) 0.089(2) Uani 1 d . . . O8 O -0.0886(6) -0.1131(6) 0.2774(4) 0.0802(19) Uani 1 d . . . O9 O 0.0603(6) 0.0790(5) 0.4054(4) 0.0736(17) Uani 1 d . . . O10 O 0.0629(7) -0.2759(5) 0.5254(4) 0.082(2) Uani 1 d . . . O12 O 0.1878(8) -0.5560(6) 0.5110(4) 0.091(2) Uani 1 d . . . O13 O 0.5554(7) -0.5683(7) 0.3427(5) 0.108(3) Uani 1 d . . . N1 N 0.2982(6) -0.2527(4) 0.3197(3) 0.0400(14) Uani 1 d . . . C1 C 0.5679(8) -0.0201(6) 0.2360(5) 0.051(2) Uani 1 d . . . C2 C 0.4351(8) -0.1287(6) 0.1593(5) 0.052(2) Uani 1 d . . . C3 C 0.6197(8) -0.2439(7) 0.2847(5) 0.059(2) Uani 1 d . . . C4 C 0.4139(8) 0.0315(7) 0.3756(5) 0.0494(19) Uani 1 d . . . C5 C 0.6366(9) -0.1371(7) 0.4429(5) 0.057(2) Uani 1 d . . . C6 C 0.3455(9) -0.1265(6) 0.5292(5) 0.052(2) Uani 1 d . . . C7 C 0.4432(9) -0.2880(7) 0.4543(5) 0.057(2) Uani 1 d . . . C8 C 0.0157(8) -0.1159(6) 0.3049(5) 0.0472(18) Uani 1 d . . . C9 C 0.1079(8) 0.0034(6) 0.3871(5) 0.0466(18) Uani 1 d . . . C10 C 0.1068(8) -0.2195(6) 0.4636(5) 0.0496(19) Uani 1 d . . . C11 C 0.2784(7) -0.3450(6) 0.3271(4) 0.0418(17) Uani 1 d . . . C12 C 0.2113(9) -0.5272(6) 0.4418(5) 0.053(2) Uani 1 d . . . C13 C 0.4327(10) -0.5349(7) 0.3398(5) 0.062(2) Uani 1 d . . . C14 C 0.3342(8) 0.2680(6) 0.0618(4) 0.0448(18) Uiso 1 d . . . C15 C 0.4355(8) 0.2692(6) 0.1102(5) 0.055(2) Uiso 1 d . . . H15 H 0.4214 0.2311 0.1676 0.078(12) Uiso 1 calc R . . C16 C 0.5584(9) 0.3257(7) 0.0759(5) 0.066(2) Uiso 1 d . . . H16 H 0.6286 0.3268 0.1096 0.078(12) Uiso 1 calc R . . C17 C 0.5782(10) 0.3786(7) -0.0046(5) 0.067(2) Uiso 1 d . . . H17 H 0.6630 0.4172 -0.0278 0.078(12) Uiso 1 calc R . . C18 C 0.4808(9) 0.3784(7) -0.0536(6) 0.065(2) Uiso 1 d . . . H18 H 0.4978 0.4156 -0.1109 0.078(12) Uiso 1 calc R . . C19 C 0.3573(8) 0.3249(6) -0.0211(5) 0.0516(19) Uiso 1 d . . . H19 H 0.2870 0.3268 -0.0557 0.078(12) Uiso 1 calc R . . C20 C 0.0435(7) 0.2947(5) 0.1420(4) 0.0390(16) Uiso 1 d . . . C21 C -0.0595(8) 0.2571(6) 0.2064(5) 0.053(2) Uiso 1 d . . . H21 H -0.0601 0.1792 0.2350 0.079(12) Uiso 1 calc R . . C22 C -0.1637(9) 0.3325(7) 0.2303(5) 0.063(2) Uiso 1 d . . . H22 H -0.2362 0.3061 0.2755 0.079(12) Uiso 1 calc R . . C23 C -0.1633(9) 0.4428(7) 0.1902(5) 0.060(2) Uiso 1 d . . . H23 H -0.2360 0.4941 0.2067 0.079(12) Uiso 1 calc R . . C24 C -0.0596(8) 0.4808(7) 0.1265(5) 0.058(2) Uiso 1 d . . . H24 H -0.0587 0.5589 0.0984 0.079(12) Uiso 1 calc R . . C25 C 0.0432(8) 0.4071(6) 0.1027(5) 0.0473(18) Uiso 1 d . . . H25 H 0.1160 0.4342 0.0579 0.079(12) Uiso 1 calc R . . C26 C 0.0966(7) 0.1748(5) 0.0303(4) 0.0406(17) Uiso 1 d . . . C27 C -0.0509(8) 0.2025(6) 0.0212(5) 0.055(2) Uiso 1 d . . . H27 H -0.1123 0.2384 0.0556 0.132(17) Uiso 1 calc R . . C28 C -0.1112(10) 0.1789(7) -0.0373(5) 0.068(2) Uiso 1 d . . . H28 H -0.2138 0.1963 -0.0421 0.132(17) Uiso 1 calc R . . C29 C -0.0227(10) 0.1307(7) -0.0875(6) 0.077(3) Uiso 1 d . . . H29 H -0.0638 0.1176 -0.1293 0.132(17) Uiso 1 calc R . . C30 C 0.1220(10) 0.1004(7) -0.0805(6) 0.073(3) Uiso 1 d . . . H30 H 0.1809 0.0648 -0.1159 0.132(17) Uiso 1 calc R . . C31 C 0.1845(9) 0.1214(7) -0.0212(5) 0.062(2) Uiso 1 d . . . H31 H 0.2864 0.0998 -0.0155 0.132(17) Uiso 1 calc R . . C32 C 0.2354(10) -0.5489(7) 0.2413(6) 0.070(2) Uiso 1 d . . . H32 H 0.3183 -0.5856 0.2177 0.105(14) Uiso 1 calc R . . C33 C 0.1410(9) -0.6002(7) 0.3078(5) 0.066(2) Uiso 1 d . . . H33 H 0.1465 -0.6777 0.3388 0.105(14) Uiso 1 calc R . . C34 C 0.0358(9) -0.5170(6) 0.3212(5) 0.057(2) Uiso 1 d . . . H34 H -0.0445 -0.5277 0.3635 0.105(14) Uiso 1 calc R . . C35 C 0.0668(9) -0.4170(7) 0.2634(5) 0.059(2) Uiso 1 d . . . H35 H 0.0116 -0.3465 0.2584 0.105(14) Uiso 1 calc R . . C36 C 0.1914(9) -0.4362(7) 0.2141(5) 0.064(2) Uiso 1 d . . . H36 H 0.2388 -0.3815 0.1692 0.105(14) Uiso 1 calc R . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Au1 0.03981(17) 0.03497(16) 0.03711(17) -0.00954(12) -0.00573(12) -0.00057(11) Ru1 0.0296(3) 0.0373(3) 0.0442(4) -0.0175(3) -0.0032(3) 0.0005(2) Ru2 0.0408(3) 0.0418(3) 0.0448(4) -0.0171(3) -0.0138(3) -0.0027(3) Ru3 0.0297(3) 0.0337(3) 0.0342(3) -0.0118(2) -0.0029(2) -0.0029(2) Mn1 0.0471(6) 0.0358(6) 0.0405(6) -0.0177(5) 0.0018(5) -0.0068(5) P1 0.0384(10) 0.0361(10) 0.0358(10) -0.0091(8) -0.0019(8) 0.0014(8) O1 0.052(3) 0.059(4) 0.097(5) -0.017(3) -0.001(3) -0.017(3) O2 0.083(5) 0.146(7) 0.068(5) -0.067(5) -0.012(4) 0.015(4) O3 0.051(4) 0.077(4) 0.162(8) -0.034(5) -0.013(4) 0.028(3) O4 0.091(5) 0.047(3) 0.080(5) -0.019(3) -0.018(4) -0.022(3) O5 0.050(4) 0.120(6) 0.098(5) -0.043(4) -0.021(4) -0.011(4) O6 0.085(5) 0.106(5) 0.065(5) -0.038(4) -0.001(4) -0.023(4) O7 0.129(6) 0.046(4) 0.094(5) -0.013(3) -0.062(5) 0.008(4) O8 0.050(4) 0.133(6) 0.069(4) -0.042(4) -0.017(3) -0.012(4) O9 0.076(4) 0.067(4) 0.083(5) -0.043(4) -0.002(3) 0.010(3) O10 0.098(5) 0.073(4) 0.056(4) -0.003(3) 0.013(4) -0.021(4) O12 0.105(5) 0.120(6) 0.042(4) -0.021(4) 0.004(4) -0.026(4) O13 0.070(5) 0.145(7) 0.105(6) -0.056(5) -0.011(4) 0.036(5) N1 0.040(3) 0.034(3) 0.050(4) -0.018(3) -0.008(3) -0.003(3) C1 0.037(4) 0.051(5) 0.062(5) -0.020(4) -0.003(4) 0.001(4) C2 0.038(4) 0.062(5) 0.058(6) -0.028(4) -0.001(4) 0.003(4) C3 0.043(5) 0.056(5) 0.076(6) -0.022(4) -0.003(4) 0.001(4) C4 0.060(5) 0.050(5) 0.049(5) -0.024(4) -0.014(4) -0.011(4) C5 0.052(5) 0.064(5) 0.059(6) -0.021(4) -0.015(4) -0.012(4) C6 0.054(5) 0.059(5) 0.049(5) -0.021(4) -0.006(4) -0.018(4) C7 0.059(5) 0.054(5) 0.061(6) -0.019(4) -0.028(4) 0.006(4) C8 0.043(4) 0.055(5) 0.050(5) -0.028(4) -0.001(4) -0.002(4) C9 0.043(4) 0.047(4) 0.052(5) -0.022(4) -0.010(4) 0.006(4) C10 0.051(5) 0.046(4) 0.051(5) -0.016(4) -0.002(4) -0.006(4) C11 0.031(4) 0.055(5) 0.041(4) -0.021(4) -0.002(3) 0.000(3) C12 0.059(5) 0.049(5) 0.053(6) -0.019(4) -0.002(4) -0.006(4) C13 0.069(6) 0.065(5) 0.057(6) -0.034(5) -0.003(5) 0.011(5) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Au1 P1 2.3041(18) . ? Au1 Ru3 2.7339(8) . ? Au1 Ru1 2.7565(9) . ? Ru1 C1 1.867(8) . ? Ru1 C3 1.915(8) . ? Ru1 C2 1.916(9) . ? Ru1 N1 2.111(6) . ? Ru1 Ru3 2.8181(10) . ? Ru1 Ru2 2.8201(12) . ? Ru2 C6 1.900(9) . ? Ru2 C5 1.929(8) . ? Ru2 C4 1.944(8) . ? Ru2 C7 1.941(9) . ? Ru2 Ru3 2.8129(11) . ? Ru3 C9 1.872(7) . ? Ru3 C10 1.900(8) . ? Ru3 C8 1.912(8) . ? Ru3 N1 2.132(5) . ? Mn1 C13 1.768(9) . ? Mn1 C12 1.784(9) . ? Mn1 C11 1.819(7) . ? Mn1 C36 2.121(9) . ? Mn1 C32 2.121(9) . ? Mn1 C33 2.144(9) . ? Mn1 C35 2.145(8) . ? Mn1 C34 2.146(8) . ? P1 C26 1.807(7) . ? P1 C14 1.813(7) . ? P1 C20 1.821(7) . ? O1 C1 1.157(9) . ? O2 C2 1.137(9) . ? O3 C3 1.119(9) . ? O4 C4 1.120(8) . ? O5 C5 1.118(9) . ? O6 C6 1.133(9) . ? O7 C7 1.127(9) . ? O8 C8 1.147(9) . ? O9 C9 1.142(8) . ? O10 C10 1.137(9) . ? O12 C12 1.144(9) . ? O13 C13 1.163(10) . ? N1 C11 1.197(8) . ? C14 C15 1.382(10) . ? C14 C19 1.391(10) . ? C15 C16 1.396(11) . ? C15 H15 0.9600 . ? C16 C17 1.346(11) . ? C16 H16 0.9600 . ? C17 C18 1.356(11) . ? C17 H17 0.9600 . ? C18 C19 1.378(10) . ? C18 H18 0.9600 . ? C19 H19 0.9600 . ? C20 C21 1.367(10) . ? C20 C25 1.378(9) . ? C21 C22 1.394(11) . ? C21 H21 0.9600 . ? C22 C23 1.357(11) . ? C22 H22 0.9600 . ? C23 C24 1.366(10) . ? C23 H23 0.9600 . ? C24 C25 1.371(10) . ? C24 H24 0.9600 . ? C25 H25 0.9600 . ? C26 C27 1.390(10) . ? C26 C31 1.417(10) . ? C27 C28 1.395(11) . ? C27 H27 0.9600 . ? C28 C29 1.363(12) . ? C28 H28 0.9600 . ? C29 C30 1.360(12) . ? C29 H29 0.9600 . ? C30 C31 1.403(12) . ? C30 H30 0.9600 . ? C31 H31 0.9600 . ? C32 C36 1.386(11) . ? C32 C33 1.382(11) . ? C32 H32 0.9600 . ? C33 C34 1.400(11) . ? C33 H33 0.9600 . ? C34 C35 1.381(10) . ? C34 H34 0.9600 . ? C35 C36 1.384(11) . ? C35 H35 0.9600 . ? C36 H36 0.9600 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag P1 Au1 Ru3 152.56(5) . . ? P1 Au1 Ru1 145.68(5) . . ? Ru3 Au1 Ru1 61.76(2) . . ? C1 Ru1 C3 91.5(3) . . ? C1 Ru1 C2 95.1(3) . . ? C3 Ru1 C2 97.3(3) . . ? C1 Ru1 N1 168.5(3) . . ? C3 Ru1 N1 95.3(3) . . ? C2 Ru1 N1 93.2(3) . . ? C1 Ru1 Au1 82.3(2) . . ? C3 Ru1 Au1 169.0(3) . . ? C2 Ru1 Au1 74.3(2) . . ? N1 Ru1 Au1 92.30(15) . . ? C1 Ru1 Ru3 120.3(2) . . ? C3 Ru1 Ru3 132.2(2) . . ? C2 Ru1 Ru3 112.7(2) . . ? N1 Ru1 Ru3 48.69(15) . . ? Au1 Ru1 Ru3 58.72(2) . . ? C1 Ru1 Ru2 86.0(3) . . ? C3 Ru1 Ru2 91.2(3) . . ? C2 Ru1 Ru2 171.4(2) . . ? N1 Ru1 Ru2 84.67(16) . . ? Au1 Ru1 Ru2 97.42(2) . . ? Ru3 Ru1 Ru2 59.85(2) . . ? C6 Ru2 C5 98.7(3) . . ? C6 Ru2 C4 94.5(3) . . ? C5 Ru2 C4 94.6(3) . . ? C6 Ru2 C7 94.4(3) . . ? C5 Ru2 C7 92.7(3) . . ? C4 Ru2 C7 167.6(3) . . ? C6 Ru2 Ru3 96.9(2) . . ? C5 Ru2 Ru3 164.3(3) . . ? C4 Ru2 Ru3 85.9(2) . . ? C7 Ru2 Ru3 84.4(2) . . ? C6 Ru2 Ru1 156.9(2) . . ? C5 Ru2 Ru1 104.3(3) . . ? C4 Ru2 Ru1 86.2(2) . . ? C7 Ru2 Ru1 82.3(2) . . ? Ru3 Ru2 Ru1 60.04(2) . . ? C9 Ru3 C10 92.7(3) . . ? C9 Ru3 C8 93.9(3) . . ? C10 Ru3 C8 97.5(3) . . ? C9 Ru3 N1 168.4(3) . . ? C10 Ru3 N1 95.6(3) . . ? C8 Ru3 N1 93.0(3) . . ? C9 Ru3 Au1 80.1(2) . . ? C10 Ru3 Au1 170.2(2) . . ? C8 Ru3 Au1 76.5(2) . . ? N1 Ru3 Au1 92.48(15) . . ? C9 Ru3 Ru2 87.8(2) . . ? C10 Ru3 Ru2 88.2(2) . . ? C8 Ru3 Ru2 174.0(2) . . ? N1 Ru3 Ru2 84.48(15) . . ? Au1 Ru3 Ru2 98.12(3) . . ? C9 Ru3 Ru1 120.4(2) . . ? C10 Ru3 Ru1 130.3(2) . . ? C8 Ru3 Ru1 114.2(2) . . ? N1 Ru3 Ru1 48.06(15) . . ? Au1 Ru3 Ru1 59.514(19) . . ? Ru2 Ru3 Ru1 60.11(3) . . ? C13 Mn1 C12 90.9(4) . . ? C13 Mn1 C11 93.3(3) . . ? C12 Mn1 C11 92.7(3) . . ? C13 Mn1 C36 111.8(4) . . ? C12 Mn1 C36 155.3(3) . . ? C11 Mn1 C36 95.5(3) . . ? C13 Mn1 C32 91.7(4) . . ? C12 Mn1 C32 136.6(3) . . ? C11 Mn1 C32 130.3(3) . . ? C36 Mn1 C32 38.1(3) . . ? C13 Mn1 C33 107.6(4) . . ? C12 Mn1 C33 100.9(3) . . ? C11 Mn1 C33 154.7(3) . . ? C36 Mn1 C33 63.9(3) . . ? C32 Mn1 C33 37.8(3) . . ? C13 Mn1 C35 149.6(4) . . ? C12 Mn1 C35 118.9(3) . . ? C11 Mn1 C35 91.3(3) . . ? C36 Mn1 C35 37.9(3) . . ? C32 Mn1 C35 63.2(3) . . ? C33 Mn1 C35 63.5(3) . . ? C13 Mn1 C34 145.4(3) . . ? C12 Mn1 C34 92.6(3) . . ? C11 Mn1 C34 120.9(3) . . ? C36 Mn1 C34 63.3(3) . . ? C32 Mn1 C34 63.0(3) . . ? C33 Mn1 C34 38.1(3) . . ? C35 Mn1 C34 37.6(3) . . ? C26 P1 C14 106.4(3) . . ? C26 P1 C20 104.1(3) . . ? C14 P1 C20 105.1(3) . . ? C26 P1 Au1 114.8(2) . . ? C14 P1 Au1 110.9(2) . . ? C20 P1 Au1 114.7(2) . . ? C11 N1 Ru1 141.8(5) . . ? C11 N1 Ru3 135.0(5) . . ? Ru1 N1 Ru3 83.2(2) . . ? O1 C1 Ru1 178.0(7) . . ? O2 C2 Ru1 176.2(7) . . ? O3 C3 Ru1 176.7(9) . . ? O4 C4 Ru2 176.9(7) . . ? O5 C5 Ru2 177.3(8) . . ? O6 C6 Ru2 179.1(7) . . ? O7 C7 Ru2 177.7(7) . . ? O8 C8 Ru3 174.7(7) . . ? O9 C9 Ru3 177.3(7) . . ? O10 C10 Ru3 179.5(7) . . ? N1 C11 Mn1 177.5(6) . . ? O12 C12 Mn1 179.4(8) . . ? O13 C13 Mn1 179.2(8) . . ? C15 C14 C19 118.5(7) . . ? C15 C14 P1 118.0(6) . . ? C19 C14 P1 123.5(6) . . ? C14 C15 C16 120.1(8) . . ? C14 C15 H15 119.9 . . ? C16 C15 H15 119.9 . . ? C17 C16 C15 119.7(9) . . ? C17 C16 H16 120.1 . . ? C15 C16 H16 120.1 . . ? C16 C17 C18 121.4(9) . . ? C16 C17 H17 119.3 . . ? C18 C17 H17 119.3 . . ? C17 C18 C19 120.1(9) . . ? C17 C18 H18 120.0 . . ? C19 C18 H18 120.0 . . ? C18 C19 C14 120.2(8) . . ? C18 C19 H19 119.9 . . ? C14 C19 H19 119.9 . . ? C21 C20 C25 119.0(7) . . ? C21 C20 P1 119.0(5) . . ? C25 C20 P1 122.0(5) . . ? C20 C21 C22 119.7(7) . . ? C20 C21 H21 120.1 . . ? C22 C21 H21 120.1 . . ? C23 C22 C21 120.4(8) . . ? C23 C22 H22 119.8 . . ? C21 C22 H22 119.8 . . ? C22 C23 C24 120.1(8) . . ? C22 C23 H23 120.0 . . ? C24 C23 H23 120.0 . . ? C25 C24 C23 119.7(8) . . ? C25 C24 H24 120.1 . . ? C23 C24 H24 120.1 . . ? C24 C25 C20 121.1(7) . . ? C24 C25 H25 119.5 . . ? C20 C25 H25 119.5 . . ? C27 C26 C31 118.3(7) . . ? C27 C26 P1 122.2(6) . . ? C31 C26 P1 119.3(6) . . ? C26 C27 C28 121.0(8) . . ? C26 C27 H27 119.5 . . ? C28 C27 H27 119.5 . . ? C29 C28 C27 119.2(9) . . ? C29 C28 H28 120.4 . . ? C27 C28 H28 120.4 . . ? C30 C29 C28 122.2(10) . . ? C30 C29 H29 118.9 . . ? C28 C29 H29 118.9 . . ? C29 C30 C31 119.6(9) . . ? C29 C30 H30 120.2 . . ? C31 C30 H30 120.2 . . ? C30 C31 C26 119.6(8) . . ? C30 C31 H31 120.2 . . ? C26 C31 H31 120.2 . . ? C36 C32 C33 109.3(8) . . ? C36 C32 Mn1 71.0(5) . . ? C33 C32 Mn1 72.0(5) . . ? C36 C32 H32 125.3 . . ? C33 C32 H32 125.4 . . ? Mn1 C32 H32 123.2 . . ? C32 C33 C34 106.6(8) . . ? C32 C33 Mn1 70.2(5) . . ? C34 C33 Mn1 71.0(5) . . ? C32 C33 H33 126.7 . . ? C34 C33 H33 126.7 . . ? Mn1 C33 H33 123.7 . . ? C35 C34 C33 108.6(8) . . ? C35 C34 Mn1 71.2(5) . . ? C33 C34 Mn1 70.9(5) . . ? C35 C34 H34 125.7 . . ? C33 C34 H34 125.7 . . ? Mn1 C34 H34 123.9 . . ? C34 C35 C36 108.1(7) . . ? C34 C35 Mn1 71.3(5) . . ? C36 C35 Mn1 70.2(5) . . ? C34 C35 H35 126.0 . . ? C36 C35 H35 125.9 . . ? Mn1 C35 H35 124.2 . . ? C32 C36 C35 107.5(8) . . ? C32 C36 Mn1 70.9(5) . . ? C35 C36 Mn1 72.0(5) . . ? C32 C36 H36 126.2 . . ? C35 C36 H36 126.2 . . ? Mn1 C36 H36 122.6 . . ? _diffrn_measured_fraction_theta_max 0.819 _diffrn_reflns_theta_full 22.99 _diffrn_measured_fraction_theta_full 0.819 _refine_diff_density_max 1.055 _refine_diff_density_min -1.491 _refine_diff_density_rms 0.098