# Supplementary Material (ESI) for Dalton Transactions
# This journal is © The Royal Society of Chemistry 2000
# CCDC Number: 186/1932

data_1

_audit_creation_method            SHELXL
_chemical_name_systematic
;
 ?
;
_chemical_name_common             'C25 H21 Cl N2 O P2 Pd S2'
_chemical_formula_moiety          'C25 H21 Cl N2 O P2 Pd S2'
_chemical_formula_structural      'C25 H21 Cl N2 O P2 Pd S2'
_chemical_formula_analytical      'C25 H21 Cl N2 O P2 Pd S2'
_chemical_formula_sum             'C25 H21 Cl N2 O P2 Pd S2'
_chemical_formula_weight          633.35
_chemical_melting_point           -
_chemical_compound_source         -

loop_
 _atom_type_symbol
 _atom_type_description
 _atom_type_scat_dispersion_real
 _atom_type_scat_dispersion_imag
 _atom_type_scat_source
 'C'  'C'   0.0033   0.0016
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H'  'H'   0.0000   0.0000
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N'  'N'   0.0061   0.0033
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O'  'O'   0.0106   0.0060
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'P'  'P'   0.1023   0.0942
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'S'  'S'   0.1246   0.1234
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Cl'  'Cl'   0.1484   0.1585
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Pd'  'Pd'  -0.9988   1.0072
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting            Orthorhombic
_symmetry_space_group_name_H-M    Pbca

loop_
 _symmetry_equiv_pos_as_xyz
 'x, y, z'
 '-x+1/2, -y, z+1/2'
 '-x, y+1/2, -z+1/2'
 'x+1/2, -y+1/2, -z'
 '-x, -y, -z'
 'x-1/2, y, -z-1/2'
 'x, -y-1/2, z-1/2'
 '-x-1/2, y-1/2, z'

_cell_length_a                    12.2320(2)
_cell_length_b                    18.5402(3)
_cell_length_c                    24.4688(2)
_cell_angle_alpha                 90.00
_cell_angle_beta                  90.00
_cell_angle_gamma                 90.00
_cell_volume                      5549.13(14)
_cell_formula_units_Z             8
_cell_measurement_temperature     293(2)
_cell_measurement_reflns_used      67
_cell_measurement_theta_min       12
_cell_measurement_theta_max       168

_exptl_crystal_description        plate
_exptl_crystal_colour             orange
_exptl_crystal_size_max           .02
_exptl_crystal_size_mid           .13
_exptl_crystal_size_min           .18
_exptl_crystal_density_meas       -
_exptl_crystal_density_diffrn     1.516
_exptl_crystal_density_method     -
_exptl_crystal_F_000              2544
_exptl_absorpt_coefficient_mu     1.052
_exptl_absorpt_correction_type    sadabs
_exptl_absorpt_correction_T_min   0.700714
_exptl_absorpt_correction_T_max   1.00000

_exptl_special_details
;
 1 idealised phenyl ring
;

_diffrn_ambient_temperature       293(2)
_diffrn_radiation_wavelength      0.71073
_diffrn_radiation_type            MoK\a
_diffrn_radiation_source          'fine-focus sealed tube'
_diffrn_radiation_monochromator   graphite
_diffrn_measurement_device        SMART
_diffrn_measurement_method        CCD
_diffrn_standards_number          -
_diffrn_standards_interval_count  -
_diffrn_standards_interval_time   -
_diffrn_standards_decay_%         -
_diffrn_reflns_number             25983
_diffrn_reflns_av_R_equivalents   0.0834
_diffrn_reflns_av_sigmaI/netI     0.0503
_diffrn_reflns_limit_h_min        -13
_diffrn_reflns_limit_h_max        13
_diffrn_reflns_limit_k_min        -20
_diffrn_reflns_limit_k_max        19
_diffrn_reflns_limit_l_min        -27
_diffrn_reflns_limit_l_max        27
_diffrn_reflns_theta_min          1.66
_diffrn_reflns_theta_max          23.26
_reflns_number_total              3982
_reflns_number_observed           2568
_reflns_observed_criterion        >2sigma(I)

_computing_data_collection        SMART
_computing_cell_refinement        SMART/SAINT
_computing_data_reduction         SAINT
_computing_structure_solution     'SHELXS-86 (Sheldrick, 1990)'
_computing_structure_refinement   'SHELXL-93 (Sheldrick, 1993)'
_computing_molecular_graphics     SHELXTL
_computing_publication_material   SHELXTL

_refine_special_details
;
 Refinement on F^2^ for ALL reflections except for 50 with very negative 
F^2^
 or flagged by the user for potential systematic errors.  Weighted R-
factors
 wR and all goodnesses of fit S are based on F^2^, conventional R-
factors R
 are based on F, with F set to zero for negative F^2^. The observed 
criterion
 of F^2^ > 2sigma(F^2^) is used only for calculating _R_factor_obs etc. 
and is
 not relevant to the choice of reflections for refinement.  R-factors 
based
 on F^2^ are statistically about twice as large as those based on F, and 
R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef  Fsqd
_refine_ls_matrix_type            full
_refine_ls_weighting_scheme
 'calc w=1/[\s^2^(Fo^2^)+(0.0402P)^2^+12.7192P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary      direct
_atom_sites_solution_secondary    difmap
_atom_sites_solution_hydrogens    geom
_refine_ls_hydrogen_treatment     riding
_refine_ls_extinction_method      SHELXL
_refine_ls_extinction_coef        0.00002(6)
_refine_ls_extinction_expression
 'Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^'
_refine_ls_number_reflns          3932
_refine_ls_number_parameters      300
_refine_ls_number_restraints      1
_refine_ls_R_factor_all           0.0967
_refine_ls_R_factor_obs           0.0504
_refine_ls_wR_factor_all          0.1304
_refine_ls_wR_factor_obs          0.1015
_refine_ls_goodness_of_fit_all    1.070
_refine_ls_goodness_of_fit_obs    1.131
_refine_ls_restrained_S_all       1.149
_refine_ls_restrained_S_obs       1.130
_refine_ls_shift/esd_max          0.001
_refine_ls_shift/esd_mean         0.000

loop_
 _atom_site_label
 _atom_site_type_symbol
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_U_iso_or_equiv
 _atom_site_thermal_displace_type
 _atom_site_occupancy
 _atom_site_calc_flag
 _atom_site_refinement_flags
 _atom_site_disorder_group
Pd1 Pd 0.76918(4) 0.12777(3) 0.87460(2) 0.0539(2) Uani 1 d . .
Cl1 Cl 0.9214(2) 0.18923(11) 0.84552(8) 0.0755(6) Uani 1 d . .
S1 S 0.8549(2) 0.11331(10) 0.95867(7) 0.0640(5) Uani 1 d . .
P1 P 0.77098(15) 0.02802(10) 0.98486(7) 0.0534(5) Uani 1 d . .
N1 N 0.6364(4) 0.0391(3) 0.9823(2) 0.0563(15) Uani 1 d D .
H1N H 0.5985(46) 0.0147(31) 1.0122(17) 0.076(22) Uiso 1 d D .
C25 C 0.5734(6) 0.0499(4) 0.9357(3) 0.057(2) Uani 1 d . .
O25 O 0.4761(4) 0.0323(3) 0.9357(2) 0.0670(14) Uani 1 d . .
N2 N 0.6226(4) 0.0802(3) 0.8918(2) 0.0556(15) Uani 1 d . .
P2 P 0.5534(2) 0.09689(11) 0.83530(7) 0.0579(5) Uani 1 d . .
S2 S 0.6760(2) 0.14124(12) 0.79169(7) 0.0723(6) Uani 1 d . .
C1 C 0.7953(5) 0.0135(4) 1.0558(3) 0.056(2) Uani 1 d . .
C2 C 0.8491(7) -0.0463(5) 1.0749(3) 0.087(3) Uani 1 d . .
H2A H 0.8738(7) -0.0813(5) 1.0507(3) 0.104 Uiso 1 calc R .
C3 C 0.8667(8) -0.0540(7) 1.1308(4) 0.115(4) Uani 1 d . .
H3A H 0.9019(8) -0.0949(7) 1.1441(4) 0.138 Uiso 1 calc R .
C4 C 0.8327(8) -0.0022(7) 1.1660(4) 0.098(3) Uani 1 d . .
H4A H 0.8468(8) -0.0077(7) 1.2032(4) 0.118 Uiso 1 calc R .
C5 C 0.7787(9) 0.0574(5) 1.1486(3) 0.099(3) Uani 1 d . .
H5A H 0.7549(9) 0.0922(5) 1.1732(3) 0.118 Uiso 1 calc R .
C6 C 0.7598(8) 0.0652(4) 1.0934(3) 0.085(3) Uani 1 d . .
H6A H 0.7227(8) 0.1058(4) 1.0808(3) 0.102 Uiso 1 calc R .
C7 C 0.8015(6) -0.0536(4) 0.9493(3) 0.059(2) Uani 1 d . .
C8 C 0.9018(7) -0.0642(5) 0.9244(3) 0.088(3) Uani 1 d . .
H8A H 0.9534(7) -0.0273(5) 0.9235(3) 0.106 Uiso 1 calc R .
C9 C 0.9244(9) -0.1305(6) 0.9006(4) 0.109(3) Uani 1 d . .
H9A H 0.9923(9) -0.1381(6) 0.8846(4) 0.131 Uiso 1 calc R .
C10 C 0.8487(12) -0.1852(6) 0.9003(5) 0.127(4) Uani 1 d . .
H10A H 0.8647(12) -0.2293(6) 0.8841(5) 0.152 Uiso 1 calc R .
C11 C 0.7508(10) -0.1738(6) 0.9240(5) 0.129(4) Uani 1 d . .
H11A H 0.6988(10) -0.2104(6) 0.9236(5) 0.154 Uiso 1 calc R .
C12 C 0.7260(8) -0.1093(5) 0.9486(4) 0.102(3) Uani 1 d . .
H12A H 0.6580(8) -0.1030(5) 0.9649(4) 0.122 Uiso 1 calc R .
C13 C 0.5046(6) 0.0152(4) 0.8046(3) 0.064(2) Uani 1 d . .
C14 C 0.5475(7) -0.0507(5) 0.8201(3) 0.082(2) Uani 1 d . .
H14A H 0.5981(7) -0.0533(5) 0.8484(3) 0.098 Uiso 1 calc R .
C15 C 0.5147(10) -0.1135(5) 0.7929(4) 0.105(3) Uani 1 d . .
H15A H 0.5431(10) -0.1580(5) 0.8031(4) 0.126 Uiso 1 calc R .
C16 C 0.4401(9) -0.1088(6) 0.7510(4) 0.099(3) Uani 1 d . .
H16A H 0.4183(9) -0.1506(6) 0.7330(4) 0.119 Uiso 1 calc R .
C17 C 0.3976(8) -0.0443(6) 0.7352(4) 0.099(3) Uani 1 d . .
H17A H 0.3479(8) -0.0421(6) 0.7065(4) 0.119 Uiso 1 calc R .
C18 C 0.4286(6) 0.0176(5) 0.7620(3) 0.078(2) Uani 1 d . .
H18A H 0.3986(6) 0.0617(5) 0.7516(3) 0.094 Uiso 1 calc R .
C19 C 0.4423(4) 0.1599(3) 0.8429(3) 0.066(2) Uani 1 d G .
C20 C 0.4142(7) 0.2015(4) 0.7978(2) 0.123(4) Uani 1 d G .
H20A H 0.4561(10) 0.1980(6) 0.7648(3) 0.148 Uiso 1 d G .
C21 C 0.3253(7) 0.2481(4) 0.8005(3) 0.137(4) Uani 1 d G .
H21A H 0.3059(11) 0.2768(5) 0.7694(4) 0.165 Uiso 1 d G .
C22 C 0.2646(5) 0.2531(4) 0.8484(5) 0.129(4) Uani 1 d G .
H22A H 0.2032(6) 0.2852(5) 0.8503(6) 0.155 Uiso 1 d G .
C23 C 0.2927(7) 0.2115(5) 0.8935(4) 0.232(10) Uani 1 d G .
H23A H 0.2507(10) 0.2150(7) 0.9266(5) 0.278 Uiso 1 d G .
C24 C 0.3816(7) 0.1649(4) 0.8908(3) 0.219(9) Uani 1 d G .
H24A H 0.4010(11) 0.1362(6) 0.9220(3) 0.263 Uiso 1 d G .

loop_
 _atom_site_aniso_label
 _atom_site_aniso_U_11
 _atom_site_aniso_U_22
 _atom_site_aniso_U_33
 _atom_site_aniso_U_23
 _atom_site_aniso_U_13
 _atom_site_aniso_U_12
Pd1 0.0538(4) 0.0592(4) 0.0486(3) 0.0045(3) 0.0067(3) -0.0028(3)
Cl1 0.0660(13) 0.0805(14) 0.0799(14) 0.0126(11) 0.0121(10) -0.0105(11)
S1 0.0617(12) 0.0699(13) 0.0606(11) 0.0060(9) -0.0045(9) -0.0133(10)
P1 0.0490(11) 0.0611(12) 0.0503(10) 0.0034(9) -0.0008(9) -0.0048(10)
N1 0.048(3) 0.079(4) 0.042(3) 0.015(3) 0.001(3) -0.007(3)
C25 0.049(5) 0.077(5) 0.045(4) 0.007(4) 0.000(4) -0.006(4)
O25 0.048(3) 0.101(4) 0.052(3) 0.019(3) -0.001(2) -0.014(3)
N2 0.055(4) 0.072(4) 0.040(3) 0.013(3) 0.002(3) -0.007(3)
P2 0.0563(12) 0.0729(13) 0.0445(10) 0.0082(9) -0.0004(9) -0.0052(10)
S2 0.0698(13) 0.098(2) 0.0491(11) 0.0163(10) 0.0059(9) -0.0116(12)
C1 0.051(4) 0.062(5) 0.057(4) 0.008(4) -0.005(3) -0.004(4)
C2 0.087(6) 0.104(7) 0.070(6) 0.012(5) -0.001(5) 0.032(6)
C3 0.095(7) 0.160(10) 0.090(8) 0.039(7) -0.004(6) 0.051(7)
C4 0.088(7) 0.145(10) 0.061(6) 0.020(6) -0.017(5) -0.001(7)
C5 0.151(9) 0.091(7) 0.054(5) 0.000(5) -0.017(6) -0.001(7)
C6 0.133(8) 0.068(5) 0.055(5) 0.006(4) -0.013(5) 0.013(5)
C7 0.058(5) 0.059(5) 0.059(5) 0.000(4) -0.003(4) -0.010(4)
C8 0.078(6) 0.097(7) 0.091(6) -0.025(5) 0.022(5) -0.014(5)
C9 0.105(8) 0.115(8) 0.107(7) -0.019(7) 0.050(6) 0.006(7)
C10 0.155(11) 0.082(7) 0.144(10) -0.030(7) 0.048(9) -0.007(8)
C11 0.129(10) 0.075(7) 0.182(12) -0.034(7) 0.005(9) -0.021(7)
C12 0.090(7) 0.077(7) 0.138(9) -0.010(6) 0.021(6) -0.016(6)
C13 0.066(5) 0.075(5) 0.052(5) 0.010(4) 0.000(4) -0.005(4)
C14 0.115(7) 0.078(6) 0.053(5) 0.008(5) -0.003(5) 0.014(6)
C15 0.164(10) 0.066(6) 0.084(7) -0.005(5) 0.009(7) 0.016(7)
C16 0.124(8) 0.091(8) 0.083(7) -0.023(6) 0.015(6) -0.016(7)
C17 0.109(8) 0.089(7) 0.100(8) -0.019(6) -0.030(6) -0.002(6)
C18 0.076(6) 0.078(6) 0.080(6) -0.001(5) -0.011(5) 0.004(5)
C19 0.063(5) 0.066(5) 0.070(5) -0.003(4) 0.003(4) -0.008(4)
C20 0.164(11) 0.132(9) 0.073(7) 0.011(6) -0.010(6) 0.070(8)
C21 0.170(12) 0.117(9) 0.125(10) -0.007(7) -0.027(9) 0.052(9)
C22 0.083(7) 0.096(8) 0.207(13) 0.007(9) 0.006(9) 0.001(6)
C23 0.202(15) 0.152(12) 0.342(22) 0.152(14) 0.175(15) 0.093(11)
C24 0.206(14) 0.167(12) 0.284(18) 0.146(12) 0.171(14) 0.114(11)

_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are 
taken
 into account individually in the estimation of esds in distances, 
angles
 and torsion angles; correlations between esds in cell parameters are 
only
 used when they are defined by crystal symmetry.  An approximate 
(isotropic)
 treatment of cell esds is used for estimating esds involving l.s. 
planes.
;

loop_
 _geom_bond_atom_site_label_1
 _geom_bond_atom_site_label_2
 _geom_bond_distance
 _geom_bond_site_symmetry_2
 _geom_bond_publ_flag
Pd1 N2 2.042(5) . ?
Pd1 Cl1 2.296(2) . ?
Pd1 S1 2.325(2) . ?
Pd1 S2 2.340(2) . ?
Pd1 P2 2.867(2) . ?
S1 P1 1.991(3) . ?
P1 N1 1.661(6) . ?
P1 C1 1.782(7) . ?
P1 C7 1.786(7) . ?
N1 C25 1.389(8) . ?
C25 O25 1.235(7) . ?
C25 N2 1.353(8) . ?
N2 P2 1.651(5) . ?
P2 C13 1.793(8) . ?
P2 C19 1.802(5) . ?
P2 S2 2.016(3) . ?
C1 C2 1.370(10) . ?
C1 C6 1.398(10) . ?
C2 C3 1.394(11) . ?
C3 C4 1.355(12) . ?
C4 C5 1.357(12) . ?
C5 C6 1.378(10) . ?
C7 C12 1.386(10) . ?
C7 C8 1.385(10) . ?
C8 C9 1.388(12) . ?
C9 C10 1.374(13) . ?
C10 C11 1.346(13) . ?
C11 C12 1.373(13) . ?
C13 C14 1.382(10) . ?
C13 C18 1.399(10) . ?
C14 C15 1.398(11) . ?
C15 C16 1.377(13) . ?
C16 C17 1.359(12) . ?
C17 C18 1.375(11) . ?
C19 C20 1.39 . ?
C19 C24 1.39 . ?
C20 C21 1.39 . ?
C21 C22 1.39 . ?
C22 C23 1.39 . ?
C23 C24 1.39 . ?

loop_
 _geom_angle_atom_site_label_1
 _geom_angle_atom_site_label_2
 _geom_angle_atom_site_label_3
 _geom_angle
 _geom_angle_site_symmetry_1
 _geom_angle_site_symmetry_3
 _geom_angle_publ_flag
N2 Pd1 Cl1 172.04(15) . . ?
N2 Pd1 S1 99.41(15) . . ?
Cl1 Pd1 S1 88.02(7) . . ?
N2 Pd1 S2 78.33(15) . . ?
Cl1 Pd1 S2 94.20(7) . . ?
S1 Pd1 S2 177.66(7) . . ?
N2 Pd1 P2 34.39(14) . . ?
Cl1 Pd1 P2 137.89(7) . . ?
S1 Pd1 P2 133.56(6) . . ?
S2 Pd1 P2 44.13(6) . . ?
P1 S1 Pd1 98.27(9) . . ?
N1 P1 C1 102.8(3) . . ?
N1 P1 C7 107.1(3) . . ?
C1 P1 C7 108.2(3) . . ?
N1 P1 S1 113.6(2) . . ?
C1 P1 S1 110.4(2) . . ?
C7 P1 S1 114.1(2) . . ?
C25 N1 P1 126.8(5) . . ?
O25 C25 N2 122.5(6) . . ?
O25 C25 N1 119.8(6) . . ?
N2 C25 N1 117.7(6) . . ?
C25 N2 P2 121.0(5) . . ?
C25 N2 Pd1 137.2(5) . . ?
P2 N2 Pd1 101.3(3) . . ?
N2 P2 C13 111.3(3) . . ?
N2 P2 C19 114.9(3) . . ?
C13 P2 C19 109.9(3) . . ?
N2 P2 S2 98.0(2) . . ?
C13 P2 S2 111.8(2) . . ?
C19 P2 S2 110.6(2) . . ?
N2 P2 Pd1 44.3(2) . . ?
C13 P2 Pd1 128.0(3) . . ?
C19 P2 Pd1 122.0(2) . . ?
S2 P2 Pd1 53.92(7) . . ?
P2 S2 Pd1 81.94(8) . . ?
C2 C1 C6 118.7(7) . . ?
C2 C1 P1 122.3(6) . . ?
C6 C1 P1 119.0(6) . . ?
C1 C2 C3 119.4(9) . . ?
C4 C3 C2 120.3(9) . . ?
C3 C4 C5 121.7(9) . . ?
C4 C5 C6 118.4(9) . . ?
C5 C6 C1 121.4(8) . . ?
C12 C7 C8 118.7(8) . . ?
C12 C7 P1 119.9(6) . . ?
C8 C7 P1 121.3(6) . . ?
C7 C8 C9 119.1(8) . . ?
C10 C9 C8 121.5(9) . . ?
C11 C10 C9 118.8(10) . . ?
C10 C11 C12 121.5(10) . . ?
C11 C12 C7 120.5(9) . . ?
C14 C13 C18 119.0(8) . . ?
C14 C13 P2 120.4(6) . . ?
C18 C13 P2 120.4(6) . . ?
C13 C14 C15 119.8(8) . . ?
C16 C15 C14 119.5(9) . . ?
C17 C16 C15 121.4(9) . . ?
C16 C17 C18 119.6(9) . . ?
C17 C18 C13 120.8(8) . . ?
C20 C19 C24 120.0 . . ?
C20 C19 P2 117.7(4) . . ?
C24 C19 P2 122.3(4) . . ?
C19 C20 C21 120.0 . . ?
C20 C21 C22 120.0 . . ?
C23 C22 C21 120.0 . . ?
C24 C23 C22 120.0 . . ?
C23 C24 C19 120.0 . . ?

loop_
 _geom_torsion_atom_site_label_1
 _geom_torsion_atom_site_label_2
 _geom_torsion_atom_site_label_3
 _geom_torsion_atom_site_label_4
 _geom_torsion
 _geom_torsion_site_symmetry_1
 _geom_torsion_site_symmetry_2
 _geom_torsion_site_symmetry_3
 _geom_torsion_site_symmetry_4
 _geom_torsion_publ_flag
 N2 Pd1 S1 P1 24.9(2) . . . . ?
 Cl1 Pd1 S1 P1 -157.99(10) . . . . ?
 S2 Pd1 S1 P1 40.2(19) . . . . ?
 P2 Pd1 S1 P1 29.44(14) . . . . ?
 Pd1 S1 P1 N1 -52.4(2) . . . . ?
 Pd1 S1 P1 C1 -167.2(3) . . . . ?
 Pd1 S1 P1 C7 70.7(3) . . . . ?
 C1 P1 N1 C25 -177.7(6) . . . . ?
 C7 P1 N1 C25 -63.9(7) . . . . ?
 S1 P1 N1 C25 63.1(6) . . . . ?
 P1 N1 C25 O25 154.2(6) . . . . ?
 P1 N1 C25 N2 -26.1(9) . . . . ?
 O25 C25 N2 P2 1.2(10) . . . . ?
 N1 C25 N2 P2 -178.5(5) . . . . ?
 O25 C25 N2 Pd1 171.2(5) . . . . ?
 N1 C25 N2 Pd1 -8.5(11) . . . . ?
 Cl1 Pd1 N2 C25 -156.0(9) . . . . ?
 S1 Pd1 N2 C25 2.9(7) . . . . ?
 S2 Pd1 N2 C25 -176.5(7) . . . . ?
 P2 Pd1 N2 C25 -171.3(9) . . . . ?
 Cl1 Pd1 N2 P2 15.2(14) . . . . ?
 S1 Pd1 N2 P2 174.1(2) . . . . ?
 S2 Pd1 N2 P2 -5.2(2) . . . . ?
 P2 Pd1 N2 P2 0.0 . . . . ?
 C25 N2 P2 C13 -63.8(6) . . . . ?
 Pd1 N2 P2 C13 123.2(3) . . . . ?
 C25 N2 P2 C19 62.0(6) . . . . ?
 Pd1 N2 P2 C19 -111.1(3) . . . . ?
 C25 N2 P2 S2 179.1(5) . . . . ?
 Pd1 N2 P2 S2 6.0(3) . . . . ?
 C25 N2 P2 Pd1 173.1(7) . . . . ?
 Pd1 N2 P2 Pd1 0.0 . . . . ?
 N2 Pd1 P2 N2 0.000(1) . . . . ?
 Cl1 Pd1 P2 N2 -176.9(3) . . . . ?
 S1 Pd1 P2 N2 -8.0(3) . . . . ?
 S2 Pd1 P2 N2 172.6(3) . . . . ?
 N2 Pd1 P2 C13 -81.9(4) . . . . ?
 Cl1 Pd1 P2 C13 101.2(3) . . . . ?
 S1 Pd1 P2 C13 -89.9(3) . . . . ?
 S2 Pd1 P2 C13 90.7(3) . . . . ?
 N2 Pd1 P2 C19 94.1(4) . . . . ?
 Cl1 Pd1 P2 C19 -82.8(3) . . . . ?
 S1 Pd1 P2 C19 86.1(3) . . . . ?
 S2 Pd1 P2 C19 -93.3(3) . . . . ?
 N2 Pd1 P2 S2 -172.6(3) . . . . ?
 Cl1 Pd1 P2 S2 10.49(14) . . . . ?
 S1 Pd1 P2 S2 179.37(11) . . . . ?
 S2 Pd1 P2 S2 0.0 . . . . ?
 N2 P2 S2 Pd1 -5.2(2) . . . . ?
 C13 P2 S2 Pd1 -122.0(3) . . . . ?
 C19 P2 S2 Pd1 115.3(2) . . . . ?
 Pd1 P2 S2 Pd1 0.0 . . . . ?
 N2 Pd1 S2 P2 4.2(2) . . . . ?
 Cl1 Pd1 S2 P2 -172.97(9) . . . . ?
 S1 Pd1 S2 P2 -11.1(19) . . . . ?
 P2 Pd1 S2 P2 0.0 . . . . ?
 N1 P1 C1 C2 124.9(6) . . . . ?
 C7 P1 C1 C2 11.9(7) . . . . ?
 S1 P1 C1 C2 -113.6(6) . . . . ?
 N1 P1 C1 C6 -56.1(7) . . . . ?
 C7 P1 C1 C6 -169.2(6) . . . . ?
 S1 P1 C1 C6 65.4(6) . . . . ?
 C6 C1 C2 C3 0.2(12) . . . . ?
 P1 C1 C2 C3 179.2(7) . . . . ?
 C1 C2 C3 C4 -1.3(15) . . . . ?
 C2 C3 C4 C5 1.6(17) . . . . ?
 C3 C4 C5 C6 -0.9(16) . . . . ?
 C4 C5 C6 C1 -0.2(14) . . . . ?
 C2 C1 C6 C5 0.5(13) . . . . ?
 P1 C1 C6 C5 -178.5(7) . . . . ?
 N1 P1 C7 C12 -30.3(8) . . . . ?
 C1 P1 C7 C12 79.9(7) . . . . ?
 S1 P1 C7 C12 -156.9(6) . . . . ?
 N1 P1 C7 C8 152.9(6) . . . . ?
 C1 P1 C7 C8 -97.0(7) . . . . ?
 S1 P1 C7 C8 26.3(7) . . . . ?
 C12 C7 C8 C9 -1.5(13) . . . . ?
 P1 C7 C8 C9 175.4(7) . . . . ?
 C7 C8 C9 C10 1.4(16) . . . . ?
 C8 C9 C10 C11 -0.4(19) . . . . ?
 C9 C10 C11 C12 -0.7(20) . . . . ?
 C10 C11 C12 C7 0.6(19) . . . . ?
 C8 C7 C12 C11 0.5(14) . . . . ?
 P1 C7 C12 C11 -176.4(8) . . . . ?
 N2 P2 C13 C14 -15.9(7) . . . . ?
 C19 P2 C13 C14 -144.4(6) . . . . ?
 S2 P2 C13 C14 92.5(6) . . . . ?
 Pd1 P2 C13 C14 32.0(8) . . . . ?
 N2 P2 C13 C18 168.9(6) . . . . ?
 C19 P2 C13 C18 40.4(7) . . . . ?
 S2 P2 C13 C18 -82.7(6) . . . . ?
 Pd1 P2 C13 C18 -143.2(5) . . . . ?
 C18 C13 C14 C15 0.1(12) . . . . ?
 P2 C13 C14 C15 -175.2(7) . . . . ?
 C13 C14 C15 C16 0.2(14) . . . . ?
 C14 C15 C16 C17 0.1(15) . . . . ?
 C15 C16 C17 C18 -0.7(16) . . . . ?
 C16 C17 C18 C13 1.1(14) . . . . ?
 C14 C13 C18 C17 -0.7(12) . . . . ?
 P2 C13 C18 C17 174.5(7) . . . . ?
 N2 P2 C19 C20 150.8(4) . . . . ?
 C13 P2 C19 C20 -82.8(5) . . . . ?
 S2 P2 C19 C20 41.1(5) . . . . ?
 Pd1 P2 C19 C20 100.6(4) . . . . ?
 N2 P2 C19 C24 -32.9(5) . . . . ?
 C13 P2 C19 C24 93.5(5) . . . . ?
 S2 P2 C19 C24 -142.6(4) . . . . ?
 Pd1 P2 C19 C24 -83.1(5) . . . . ?
 C24 C19 C20 C21 0.0 . . . . ?
 P2 C19 C20 C21 176.4(4) . . . . ?
 C19 C20 C21 C22 0.0 . . . . ?
 C20 C21 C22 C23 0.0 . . . . ?
 C21 C22 C23 C24 0.0 . . . . ?
 C22 C23 C24 C19 0.0 . . . . ?
 C20 C19 C24 C23 0.0 . . . . ?
 P2 C19 C24 C23 -176.3(5) . . . . ?

_refine_diff_density_max    0.668
_refine_diff_density_min   -0.414
_refine_diff_density_rms    0.079