Supplementary Material (ESI) for Dalton Transactions This journal is (C) The Royal Society of Chemistry 2001 Table S2 Important bond lengths and angles in Cu(glygly)2(OH2)2.H2O. The order of entries is as for Table 3. Bonds to hydrogen are not listed. Bond Lengths (Å) CuA-O1A 1.986(2) 1.9900(4) 1.9907(3) 1.9887(4) CuB-O1B 1.973(2) 1.9772(4) 1.9781(3) 1.9772(5) CuA-O4A 1.954(2) 1.9557(5) 1.9572(4) 1.9562(5) CuB-O4B 1.963(3) 1.9655(5) 1.9668(4) 1.9662(5) CuA-O5A 2.310(2) 2.2801(5) 2.2802(4) 2.2807(5) CuB-O5B 2.370(2) 2.3394(5) 2.3406(5) 2.3406(6) CuA-N1A 1.904(2) 1.9065(5) 1.9066(4) 1.9066(5) CuB-N1B 1.901(2) 1.9007(5) 1.9014(4) 1.9010(5) CuA-N2A 2.026(2) 2.0297(5) 2.0297(4) 2.0299(5) CuB-N2B 2.006(2) 2.0114(4) 2.0116(3) 2.0122(5) O1A-C1A 1.267(3) 1.2717(7) 1.2715(6) 1.2724(7) O1B-C1B 1.271(3) 1.2745(7) 1.2739(5) 1.2744(7) O2A-C1A 1.245(3) 1.2521(6) 1.2526(5) 1.2531(6) O2B-C1B 1.251(3) 1.2560(6) 1.2564(4) 1.2561(6) O3A-C3A 1.270(3) 1.2758(7) 1.2762(6) 1.2761(7) O3B-C3B 1.264(4) 1.2672(7) 1.2674(6) 1.2669(7) N1A-C2A 1.440(3) 1.4427(7) 1.4423(5) 1.4436(6) N1B-C2B 1.448(3) 1.4445(7) 1.4439(5) 1.4447(6) N1A-C3A 1.300(3) 1.3025(7) 1.3019(5) 1.3022(7) N1B-C3B 1.301(3) 1.3097(7) 1.3101(5) 1.3102(6) N2A-C4A 1.471(4) 1.4821(8) 1.4823(6) 1.4820(7) N2B-C4B 1.472(4) 1.4793(8) 1.4791(6) 1.4797(7) C1A-C2A 1.528(4) 1.5291(7) 1.5281(6) 1.5284(7) C1B-C2B 1.520(4) 1.5254(7) 1.5247(6) 1.5266(7) C3A-C4A 1.514(4) 1.5204(7) 1.5199(6) 1.5213(6) C3B-C4B 1.519(4) 1.5218(8) 1.5214(6) 1.5224(7) Bond Angles (º) O1A-CuA-O4A 92.49(8) 92.48(2) 92.44(2) 92.43(2) O1B-CuB-O4B 91.65(9) 91.52(2) 91.52(2) 91.49(2) O1A-CuA-O5A 93.23(9) 92.81(2) 92.83(1) 92.86(2) O1B-CuB-O5B 91.78(9) 90.85(2) 90.85(2) 90.88(2) O1A-CuA-N1A 82.73(8) 82.55(2) 82.56(2) 82.57(2) O1B-CuB-N1B 83.19(8) 83.15(2) 83.12(2) 83.17(2) O1A-CuA-N2A 162.6(1) 161.70(2) 161.71(2) 161.67(2) O1B-CuB-N2B 166.9(1) 166.67(2) 166.66(2) 166.70(1) O4A-CuA-O5A 92.91(9) 93.06(2) 93.04(2) 93.05(2) O4B-CuB-O5B 84.7(1) 83.67(2) 83.68(2) 83.70(2) O4A-CuA-N1A 162.5(1) 162.37(2) 162.38(2) 162.40(2) O4B-CuB-N1B 162.8(1) 163.04(2) 163.03(2) 163.02(2) O4A-CuA-N2A 98.2(1) 98.06(2) 98.04(1) 98.10(2) O4B-CuB-N2B 101.2(1) 101.47(2) 101.49(2) 101.48(2) O5A-CuA-N1A 104.1(1) 104.03(2) 104.03(2) 104.01(2) O5B-CuB-N1B 111.8(1) 112.39(2) 112.39(2) 112.39(2) O5A-CuA-N2A 99.8(1) 101.48(2) 101.49(2) 101.48(2) O5B-CuB-N2B 92.6(1) 93.49(2) 93.45(2) 93.43(2) N1A-CuA-N2A 83.0(1) 82.91(2) 82.96(2) 82.91(2) N1B-CuB-N2B 83.6(1) 83.55(2) 83.57(2) 83.56(2) C1A-O1A-CuA 115.1(2) 115.12(4) 115.09(3) 115.15(4) C1B-O1B-CuB 114.9(2) 114.78(4) 114.75(3) 114.77(4) C2A-N1A-CuA 116.5(2) 116.73(4) 116.68(3) 116.71(4) C2B-N1B-CuB 116.0(2) 116.32(4) 116.31(3) 116.33(3) C2A-N1A-C3A 123.7(2) 123.33(5) 123.44(4) 123.33(5) C2B-N1B-C3B 124.2(2) 123.91(5) 123.99(3) 123.89(5) C3A-N1A-CuA 119.8(2) 119.94(4) 119.87(3) 119.96(4) C3B-N1B-CuB 119.6(2) 119.61(4) 119.54(2) 119.62(4) C4A-N2A-CuA 109.9(2) 110.01(3) 109.94(2) 110.01(3) C4B-N2B-CuB 109.6(2) 109.54(3) 109.52(2) 109.52(3) O1A-C1A-O2A 123.6(2) 123.82(5) 123.77(3) 123.83(5) O1B-C1B-O2B 123.0(2) 123.10(5) 123.06(5) 123.13(5) O1A-C1A-C2A 117.7(2) 117.66(4) 117.68(4) 117.67(4) O1B-C1B-C2B 118.0(2) 117.85(4) 117.88(4) 117.87(4) O2A-C1A-C2A 118.7(2) 118.51(5) 118.55(4) 118.50(4) O2B-C1B-C2B 119.0(2) 119.05(5) 119.05(4) 119.00(5) N1A-C2A-C1A 107.9(2) 107.71(5) 107.77(4) 107.69(4) N1B-C2B-C1B 107.8(2) 107.78(4) 107.81(4) 107.74(4) O3A-C3A-N1A 125.9(2) 125.98(4) 125.92(4) 125.99(4) O3B-C3B-N1B 127.2(2) 127.04(5) 126.96(3) 127.03(5) O3A-C3A-C4A 119.9(2) 119.66(5) 119.66(3) 119.66(5) O3B-C3B-C4B 119.3(2) 119.45(4) 119.48(4) 119.46(4) N1A-C3A-C4A 114.2(2) 114.35(5) 114.41(4) 114.33(5) N1B-C3B-C4B 113.6(2) 113.51(5) 113.55(4) 113.50(4) N2A-C4A-C3A 111.8(2) 111.30(4) 111.32(3) 111.28(4) N2B-C4B-C3B 112.2(2) 111.80(4) 111.82(3) 111.81(4)