Supplementary Material (ESI) for Dalton Transactions
This journal is © The Royal Society of Chemistry 2004
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#  experimental, refinement, atomic coordinates, 
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data_k0495
_database_code_depnum_ccdc_archive 'CCDC 249141'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C38 H62 B P3 Pt'
_chemical_formula_sum            'C38 H62 B P3 Pt'
_chemical_formula_weight         817.69

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P 21/n'
_symmetry_space_group_name_Hall  '-P 2yn'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   10.7765(6)
_cell_length_b                   20.0924(12)
_cell_length_c                   17.4561(12)
_cell_angle_alpha                90.00
_cell_angle_beta                 100.571(3)
_cell_angle_gamma                90.00
_cell_volume                     3715.5(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(1)
_cell_measurement_reflns_used    50607
_cell_measurement_theta_min      2.6
_cell_measurement_theta_max      25.03

_exptl_crystal_description       plate
_exptl_crystal_colour            ?
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.06
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.462
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1672
_exptl_absorpt_coefficient_mu    3.931
# Absorption correction

_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.615
_exptl_absorpt_correction_T_max  0.796
_exptl_absorpt_process_details   
;
multi-scan from symmetry-related measurements
Sortav (Blessing 1995)
;

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      150(1)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       '\f scans and \w scans with \k offsets'
_diffrn_detector_area_resol_mean 9
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_decay_%        0
_diffrn_reflns_number            18649
_diffrn_reflns_av_R_equivalents  0.0861
_diffrn_reflns_av_sigmaI/netI    0.0885
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         2.58
_diffrn_reflns_theta_max         24.99
_reflns_number_total             6408
_reflns_number_gt                4400
_reflns_threshold_expression     I>2\s(I)

_computing_data_collection       'Collect (Nonius BV, 1997-2002)'
_computing_cell_refinement       'Denzo-SMN (Otwinowski & Minor, 1997)'
_computing_data_reduction        Denzo-SMN
_computing_structure_solution    'SIR-92 (Altomare et al., 1993)'
_computing_structure_refinement  'SHELXTL V6.12(Sheldrick, 2001)'
_computing_molecular_graphics    'SHELXTL V6.12'
_computing_publication_material  'SHELXTL V6.12'


_refine_special_details          
;
Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement.  R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0456P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6408
_refine_ls_number_parameters     403
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0891
_refine_ls_R_factor_gt           0.0478
_refine_ls_wR_factor_ref         0.1154
_refine_ls_wR_factor_gt          0.0978
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_restrained_S_all      1.031
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.12265(3) 0.238723(15) 0.187919(18) 0.03746(12) Uani 1 1 d . . .
H1PT H 0.023(6) 0.219(3) 0.103(4) 0.045 Uiso 1 1 d . . .
P1 P 0.11310(19) 0.12775(10) 0.21036(12) 0.0380(5) Uani 1 1 d . . .
P2 P 0.26459(18) 0.24549(10) 0.30430(12) 0.0375(5) Uani 1 1 d . . .
P3 P 0.12333(19) 0.35158(10) 0.15675(13) 0.0411(5) Uani 1 1 d . . .
C1 C 0.1976(7) 0.1107(4) 0.3109(5) 0.0401(19) Uani 1 1 d . . .
H1A H 0.1381 0.1151 0.3476 0.048 Uiso 1 1 calc R . .
H1B H 0.2299 0.0645 0.3141 0.048 Uiso 1 1 calc R . .
C2 C 0.3094(7) 0.1599(4) 0.3348(5) 0.043(2) Uani 1 1 d . . .
H2A H 0.3812 0.1456 0.3105 0.052 Uiso 1 1 calc R . .
H2B H 0.3373 0.1586 0.3920 0.052 Uiso 1 1 calc R . .
C3 C -0.0254(7) 0.3780(4) 0.0977(5) 0.044(2) Uani 1 1 d . . .
C4 C -0.1373(8) 0.3626(4) 0.1231(5) 0.051(2) Uani 1 1 d . . .
H4A H -0.1357 0.3330 0.1657 0.061 Uiso 1 1 calc R . .
C5 C -0.2512(8) 0.3903(5) 0.0867(5) 0.058(2) Uani 1 1 d . . .
H5A H -0.3263 0.3805 0.1057 0.070 Uiso 1 1 calc R . .
C6 C -0.2564(8) 0.4312(4) 0.0239(6) 0.060(3) Uani 1 1 d . . .
H6A H -0.3342 0.4510 0.0005 0.072 Uiso 1 1 calc R . .
C7 C -0.1473(8) 0.4441(4) -0.0059(5) 0.058(2) Uani 1 1 d . . .
H7A H -0.1511 0.4704 -0.0514 0.070 Uiso 1 1 calc R . .
C8 C -0.0340(8) 0.4181(5) 0.0312(5) 0.058(2) Uani 1 1 d . . .
H8A H 0.0404 0.4277 0.0113 0.069 Uiso 1 1 calc R . .
C9 C 0.2353(7) 0.3616(4) 0.0910(5) 0.0422(19) Uani 1 1 d . . .
C10 C 0.2315(8) 0.3213(4) 0.0257(5) 0.056(2) Uani 1 1 d . . .
H10A H 0.1701 0.2870 0.0153 0.067 Uiso 1 1 calc R . .
C11 C 0.3166(9) 0.3308(5) -0.0244(5) 0.062(3) Uani 1 1 d . . .
H11A H 0.3114 0.3035 -0.0693 0.074 Uiso 1 1 calc R . .
C12 C 0.4066(8) 0.3784(5) -0.0099(5) 0.052(2) Uani 1 1 d . . .
H12A H 0.4640 0.3843 -0.0447 0.062 Uiso 1 1 calc R . .
C13 C 0.4156(7) 0.4184(4) 0.0548(5) 0.047(2) Uani 1 1 d . . .
H13A H 0.4798 0.4513 0.0652 0.057 Uiso 1 1 calc R . .
C14 C 0.3299(7) 0.4103(4) 0.1052(5) 0.045(2) Uani 1 1 d . . .
H14A H 0.3358 0.4382 0.1497 0.053 Uiso 1 1 calc R . .
C15 C -0.0469(7) 0.0931(4) 0.2073(5) 0.0386(19) Uani 1 1 d . . .
H15A H -0.0884 0.0925 0.1511 0.046 Uiso 1 1 calc R . .
C16 C -0.1278(7) 0.1384(4) 0.2488(5) 0.045(2) Uani 1 1 d . . .
H16A H -0.1294 0.1837 0.2264 0.054 Uiso 1 1 calc R . .
H16B H -0.0893 0.1414 0.3047 0.054 Uiso 1 1 calc R . .
C17 C -0.2630(8) 0.1123(4) 0.2406(6) 0.057(2) Uani 1 1 d . . .
H17A H -0.3114 0.1413 0.2703 0.069 Uiso 1 1 calc R . .
H17B H -0.3045 0.1136 0.1851 0.069 Uiso 1 1 calc R . .
C18 C -0.2645(8) 0.0414(4) 0.2707(5) 0.053(2) Uani 1 1 d . . .
H18A H -0.2304 0.0405 0.3274 0.064 Uiso 1 1 calc R . .
H18B H -0.3524 0.0247 0.2623 0.064 Uiso 1 1 calc R . .
C19 C -0.1861(8) -0.0029(4) 0.2289(5) 0.051(2) Uani 1 1 d . . .
H19A H -0.2253 -0.0051 0.1731 0.061 Uiso 1 1 calc R . .
H19B H -0.1853 -0.0485 0.2506 0.061 Uiso 1 1 calc R . .
C20 C -0.0508(7) 0.0217(4) 0.2363(5) 0.048(2) Uani 1 1 d . . .
H20A H -0.0043 -0.0076 0.2057 0.057 Uiso 1 1 calc R . .
H20B H -0.0083 0.0194 0.2916 0.057 Uiso 1 1 calc R . .
C21 C 0.1878(7) 0.0717(4) 0.1471(4) 0.0400(19) Uani 1 1 d . . .
H21A H 0.1796 0.0250 0.1655 0.048 Uiso 1 1 calc R . .
C22 C 0.3279(7) 0.0862(4) 0.1524(5) 0.048(2) Uani 1 1 d . . .
H22A H 0.3721 0.0814 0.2071 0.057 Uiso 1 1 calc R . .
H22B H 0.3392 0.1326 0.1358 0.057 Uiso 1 1 calc R . .
C23 C 0.3852(8) 0.0382(5) 0.1003(5) 0.057(2) Uani 1 1 d . . .
H23A H 0.4749 0.0501 0.1025 0.068 Uiso 1 1 calc R . .
H23B H 0.3824 -0.0075 0.1212 0.068 Uiso 1 1 calc R . .
C24 C 0.3189(8) 0.0388(5) 0.0170(5) 0.057(2) Uani 1 1 d . . .
H24A H 0.3554 0.0043 -0.0127 0.069 Uiso 1 1 calc R . .
H24B H 0.3306 0.0826 -0.0067 0.069 Uiso 1 1 calc R . .
C25 C 0.1781(8) 0.0255(5) 0.0126(5) 0.059(3) Uani 1 1 d . . .
H25A H 0.1662 -0.0203 0.0310 0.071 Uiso 1 1 calc R . .
H25B H 0.1338 0.0289 -0.0422 0.071 Uiso 1 1 calc R . .
C26 C 0.1206(8) 0.0755(4) 0.0628(5) 0.054(2) Uani 1 1 d . . .
H26A H 0.1283 0.1211 0.0427 0.065 Uiso 1 1 calc R . .
H26B H 0.0298 0.0657 0.0596 0.065 Uiso 1 1 calc R . .
C27 C 0.4142(6) 0.2867(4) 0.2984(4) 0.0337(17) Uani 1 1 d . . .
H27A H 0.3927 0.3341 0.2844 0.040 Uiso 1 1 calc R . .
C28 C 0.5114(7) 0.2887(4) 0.3733(5) 0.048(2) Uani 1 1 d . . .
H28A H 0.5359 0.2427 0.3899 0.057 Uiso 1 1 calc R . .
H28B H 0.4735 0.3098 0.4149 0.057 Uiso 1 1 calc R . .
C29 C 0.6307(8) 0.3283(4) 0.3628(5) 0.051(2) Uani 1 1 d . . .
H29A H 0.6079 0.3755 0.3518 0.061 Uiso 1 1 calc R . .
H29B H 0.6939 0.3265 0.4116 0.061 Uiso 1 1 calc R . .
C30 C 0.6877(8) 0.2999(4) 0.2962(5) 0.050(2) Uani 1 1 d . . .
H30A H 0.7198 0.2545 0.3100 0.060 Uiso 1 1 calc R . .
H30B H 0.7599 0.3279 0.2883 0.060 Uiso 1 1 calc R . .
C31 C 0.5902(7) 0.2974(4) 0.2208(5) 0.047(2) Uani 1 1 d . . .
H31A H 0.5652 0.3433 0.2039 0.056 Uiso 1 1 calc R . .
H31B H 0.6284 0.2763 0.1794 0.056 Uiso 1 1 calc R . .
C32 C 0.4731(7) 0.2582(4) 0.2313(5) 0.043(2) Uani 1 1 d . . .
H32A H 0.4964 0.2110 0.2424 0.052 Uiso 1 1 calc R . .
H32B H 0.4100 0.2597 0.1823 0.052 Uiso 1 1 calc R . .
C33 C 0.2065(7) 0.2863(4) 0.3860(4) 0.0410(19) Uani 1 1 d . . .
H33A H 0.2317 0.3341 0.3852 0.049 Uiso 1 1 calc R . .
C34 C 0.0620(7) 0.2852(4) 0.3746(5) 0.047(2) Uani 1 1 d . . .
H34A H 0.0326 0.2388 0.3778 0.056 Uiso 1 1 calc R . .
H34B H 0.0259 0.3027 0.3222 0.056 Uiso 1 1 calc R . .
C35 C 0.0160(8) 0.3277(4) 0.4370(5) 0.054(2) Uani 1 1 d . . .
H35A H 0.0387 0.3749 0.4306 0.064 Uiso 1 1 calc R . .
H35B H -0.0771 0.3247 0.4302 0.064 Uiso 1 1 calc R . .
C36 C 0.0746(8) 0.3043(5) 0.5181(5) 0.057(2) Uani 1 1 d . . .
H36A H 0.0476 0.3341 0.5571 0.069 Uiso 1 1 calc R . .
H36B H 0.0440 0.2589 0.5265 0.069 Uiso 1 1 calc R . .
C37 C 0.2173(8) 0.3038(5) 0.5299(5) 0.058(2) Uani 1 1 d . . .
H37A H 0.2526 0.2864 0.5824 0.069 Uiso 1 1 calc R . .
H37B H 0.2488 0.3497 0.5262 0.069 Uiso 1 1 calc R . .
C38 C 0.2610(8) 0.2601(4) 0.4680(5) 0.048(2) Uani 1 1 d . . .
H38A H 0.2326 0.2137 0.4732 0.058 Uiso 1 1 calc R . .
H38B H 0.3543 0.2602 0.4760 0.058 Uiso 1 1 calc R . .
B1 B 0.1517(10) 0.4222(5) 0.2341(6) 0.049(3) Uani 1 1 d . . .
H1 H 0.134(6) 0.470(4) 0.201(4) 0.04(2) Uiso 1 1 d . . .
H2 H 0.071(8) 0.416(4) 0.266(4) 0.06(2) Uiso 1 1 d . . .
H3 H 0.249(8) 0.410(4) 0.272(5) 0.06(3) Uiso 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Pt1 0.03627(17) 0.03779(19) 0.04000(19) 0.00088(15) 0.01142(13) 0.00076(14)
P1 0.0361(11) 0.0387(12) 0.0415(12) -0.0002(9) 0.0131(10) 0.0005(9)
P2 0.0331(10) 0.0441(13) 0.0370(11) -0.0002(9) 0.0105(9) 0.0018(9)
P3 0.0386(12) 0.0376(12) 0.0497(13) 0.0015(10) 0.0150(10) -0.0002(9)
C1 0.035(4) 0.037(5) 0.051(5) -0.001(4) 0.014(4) 0.003(3)
C2 0.038(5) 0.048(5) 0.046(5) -0.002(4) 0.013(4) 0.003(4)
C3 0.042(5) 0.040(5) 0.051(5) 0.001(4) 0.015(4) -0.005(4)
C4 0.052(5) 0.058(6) 0.044(5) 0.010(4) 0.012(4) 0.010(4)
C5 0.047(5) 0.067(7) 0.065(6) 0.016(5) 0.022(5) 0.015(5)
C6 0.044(5) 0.054(6) 0.081(7) 0.003(5) 0.012(5) 0.011(4)
C7 0.055(6) 0.061(6) 0.061(6) 0.010(5) 0.015(5) -0.007(5)
C8 0.040(5) 0.071(7) 0.061(6) 0.010(5) 0.008(5) 0.000(4)
C9 0.038(5) 0.044(5) 0.046(5) 0.003(4) 0.012(4) -0.003(4)
C10 0.051(6) 0.064(6) 0.057(6) -0.011(5) 0.019(5) -0.006(4)
C11 0.061(6) 0.085(7) 0.044(5) -0.009(5) 0.020(5) -0.014(5)
C12 0.037(5) 0.075(7) 0.049(5) -0.001(5) 0.021(4) -0.004(4)
C13 0.038(5) 0.042(5) 0.066(6) 0.008(4) 0.020(4) -0.003(4)
C14 0.038(5) 0.047(5) 0.048(5) 0.008(4) 0.006(4) 0.007(4)
C15 0.040(4) 0.037(5) 0.042(5) -0.003(4) 0.014(4) 0.000(3)
C16 0.051(5) 0.041(5) 0.047(5) 0.003(4) 0.022(4) 0.005(4)
C17 0.038(5) 0.054(6) 0.086(7) 0.007(5) 0.025(5) 0.004(4)
C18 0.045(5) 0.055(6) 0.064(6) -0.008(5) 0.021(5) -0.001(4)
C19 0.049(5) 0.043(5) 0.067(6) 0.002(4) 0.027(5) -0.009(4)
C20 0.051(5) 0.036(5) 0.061(6) 0.004(4) 0.020(5) 0.007(4)
C21 0.047(5) 0.035(5) 0.042(5) 0.002(4) 0.021(4) 0.004(4)
C22 0.039(5) 0.060(6) 0.047(5) -0.002(4) 0.018(4) 0.003(4)
C23 0.049(5) 0.064(6) 0.064(6) 0.002(5) 0.030(5) 0.009(4)
C24 0.058(6) 0.062(6) 0.060(6) 0.000(5) 0.030(5) 0.001(5)
C25 0.062(6) 0.072(7) 0.048(6) -0.009(5) 0.024(5) -0.014(5)
C26 0.049(5) 0.062(6) 0.057(6) -0.007(4) 0.023(5) -0.002(4)
C27 0.031(4) 0.041(4) 0.030(4) -0.003(3) 0.007(3) 0.001(3)
C28 0.038(5) 0.060(6) 0.047(5) -0.008(4) 0.014(4) -0.009(4)
C29 0.045(5) 0.059(6) 0.053(6) -0.015(4) 0.019(4) -0.009(4)
C30 0.042(5) 0.048(6) 0.064(6) -0.004(4) 0.020(5) -0.010(4)
C31 0.030(4) 0.055(6) 0.059(6) 0.002(4) 0.019(4) 0.003(4)
C32 0.037(4) 0.050(5) 0.044(5) 0.000(4) 0.013(4) 0.000(4)
C33 0.033(4) 0.045(5) 0.047(5) -0.002(4) 0.014(4) 0.001(3)
C34 0.033(4) 0.062(6) 0.046(5) -0.008(4) 0.010(4) 0.000(4)
C35 0.047(5) 0.061(6) 0.060(6) -0.001(5) 0.027(5) 0.006(4)
C36 0.056(6) 0.071(7) 0.050(6) -0.006(5) 0.022(5) 0.009(5)
C37 0.053(6) 0.076(7) 0.049(6) -0.011(5) 0.021(5) -0.006(5)
C38 0.042(5) 0.061(6) 0.043(5) -0.001(4) 0.009(4) 0.003(4)
B1 0.042(6) 0.055(7) 0.053(7) -0.004(5) 0.012(5) -0.004(5)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix.  The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry.  An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 H1PT 1.70(7) . ?
Pt1 P1 2.269(2) . ?
Pt1 P2 2.312(2) . ?
Pt1 P3 2.332(2) . ?
P1 C15 1.851(7) . ?
P1 C1 1.855(8) . ?
P1 C21 1.861(7) . ?
P2 C27 1.832(7) . ?
P2 C2 1.839(8) . ?
P2 C33 1.851(7) . ?
P3 C3 1.819(8) . ?
P3 C9 1.823(7) . ?
P3 B1 1.944(11) . ?
C1 C2 1.554(10) . ?
C3 C4 1.394(10) . ?
C3 C8 1.401(11) . ?
C4 C5 1.391(11) . ?
C5 C6 1.363(12) . ?
C6 C7 1.395(11) . ?
C7 C8 1.375(12) . ?
C9 C10 1.393(11) . ?
C9 C14 1.401(11) . ?
C10 C11 1.391(11) . ?
C11 C12 1.354(12) . ?
C12 C13 1.375(11) . ?
C13 C14 1.397(10) . ?
C15 C20 1.525(10) . ?
C15 C16 1.531(9) . ?
C16 C17 1.531(10) . ?
C17 C18 1.519(11) . ?
C18 C19 1.505(11) . ?
C19 C20 1.523(10) . ?
C21 C26 1.518(11) . ?
C21 C22 1.525(10) . ?
C22 C23 1.531(10) . ?
C23 C24 1.499(12) . ?
C24 C25 1.529(11) . ?
C25 C26 1.537(11) . ?
C27 C28 1.518(10) . ?
C27 C32 1.542(9) . ?
C28 C29 1.551(10) . ?
C29 C30 1.521(10) . ?
C30 C31 1.528(11) . ?
C31 C32 1.527(10) . ?
C33 C34 1.532(10) . ?
C33 C38 1.537(11) . ?
C34 C35 1.536(10) . ?
C35 C36 1.516(12) . ?
C36 C37 1.514(11) . ?
C37 C38 1.531(11) . ?
B1 H2 1.12(8) . ?
B1 H1 1.13(7) . ?
B1 H3 1.15(8) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
H1PT Pt1 P1 83(2) . . ?
H1PT Pt1 P2 170(2) . . ?
P1 Pt1 P2 87.12(7) . . ?
H1PT Pt1 P3 93(2) . . ?
P1 Pt1 P3 176.10(8) . . ?
P2 Pt1 P3 96.77(8) . . ?
C15 P1 C1 104.5(3) . . ?
C15 P1 C21 104.9(3) . . ?
C1 P1 C21 105.0(3) . . ?
C15 P1 Pt1 115.8(2) . . ?
C1 P1 Pt1 108.3(3) . . ?
C21 P1 Pt1 117.0(2) . . ?
C27 P2 C2 104.6(3) . . ?
C27 P2 C33 105.6(3) . . ?
C2 P2 C33 107.4(4) . . ?
C27 P2 Pt1 115.1(2) . . ?
C2 P2 Pt1 107.2(3) . . ?
C33 P2 Pt1 116.1(3) . . ?
C3 P3 C9 103.1(4) . . ?
C3 P3 B1 101.0(4) . . ?
C9 P3 B1 108.6(4) . . ?
C3 P3 Pt1 112.1(3) . . ?
C9 P3 Pt1 106.6(3) . . ?
B1 P3 Pt1 123.7(4) . . ?
C2 C1 P1 111.0(5) . . ?
C1 C2 P2 111.5(5) . . ?
C4 C3 C8 117.5(8) . . ?
C4 C3 P3 118.6(6) . . ?
C8 C3 P3 123.7(6) . . ?
C5 C4 C3 120.6(8) . . ?
C6 C5 C4 120.7(8) . . ?
C5 C6 C7 119.9(8) . . ?
C8 C7 C6 119.3(9) . . ?
C7 C8 C3 121.8(8) . . ?
C10 C9 C14 117.5(7) . . ?
C10 C9 P3 121.8(6) . . ?
C14 C9 P3 120.7(6) . . ?
C11 C10 C9 120.7(8) . . ?
C12 C11 C10 120.8(8) . . ?
C11 C12 C13 120.5(7) . . ?
C12 C13 C14 119.6(8) . . ?
C13 C14 C9 121.0(8) . . ?
C20 C15 C16 110.4(6) . . ?
C20 C15 P1 115.2(5) . . ?
C16 C15 P1 111.8(5) . . ?
C15 C16 C17 111.5(7) . . ?
C18 C17 C16 111.1(7) . . ?
C19 C18 C17 110.1(7) . . ?
C18 C19 C20 112.4(7) . . ?
C19 C20 C15 111.2(6) . . ?
C26 C21 C22 109.9(6) . . ?
C26 C21 P1 111.3(5) . . ?
C22 C21 P1 112.3(6) . . ?
C21 C22 C23 110.2(7) . . ?
C24 C23 C22 113.5(7) . . ?
C23 C24 C25 109.8(7) . . ?
C24 C25 C26 110.9(7) . . ?
C21 C26 C25 110.4(7) . . ?
C28 C27 C32 110.5(6) . . ?
C28 C27 P2 116.1(5) . . ?
C32 C27 P2 111.3(5) . . ?
C27 C28 C29 111.5(7) . . ?
C30 C29 C28 111.0(7) . . ?
C29 C30 C31 111.1(7) . . ?
C32 C31 C30 111.5(6) . . ?
C31 C32 C27 111.3(6) . . ?
C34 C33 C38 108.8(6) . . ?
C34 C33 P2 111.8(5) . . ?
C38 C33 P2 116.1(5) . . ?
C33 C34 C35 110.6(7) . . ?
C36 C35 C34 110.9(7) . . ?
C37 C36 C35 111.6(7) . . ?
C36 C37 C38 110.2(7) . . ?
C37 C38 C33 110.2(7) . . ?
H2 B1 H1 106(5) . . ?
H2 B1 H3 113(6) . . ?
H1 B1 H3 122(5) . . ?
H2 B1 P3 103(4) . . ?
H1 B1 P3 107(4) . . ?
H3 B1 P3 105(4) . . ?

_diffrn_measured_fraction_theta_max 0.981
_diffrn_reflns_theta_full        25.0
_diffrn_measured_fraction_theta_full 0.981
_refine_diff_density_max         1.609
_refine_diff_density_min         -2.218
_refine_diff_density_rms         0.142