Supplementary Material (ESI) for Dalton Transactions
This journal is © The Royal Society of Chemistry 2005

data_global
_journal_name_full               'Dalton Transactions'

_journal_coden_Cambridge         222

_publ_contact_author_name        'Prof Antonio Laguna'
_publ_contact_author_address     
;
Inorganic Chemistry-ICMA
University of Zaragoza-CSIC
Departamento de Quimica Inorganica-
Zaragoza
50009
SPAIN
;

_publ_contact_author_email       ALAGUNA@POSTA.UNIZAR.ES

_publ_section_title              
;
A step forward in gold-silver metallophilicity.
An AuAg4 moiety with a square pyramidal arrangement.
;
loop_
_publ_author_name
'Antonio Laguna'
'Eduardo J. Fernandez'
'de Luzuriaga,J.M.L.'
'Miguel Monge'
'Manuel Montiel'
;
M.E.Olmos
;
'Javier Perez'
'Raquel C. Puelles'
'Juan C. Saenz'

#Complex 2 in the paper:

data_RP48DICLO_in_P21/n
_database_code_depnum_ccdc_archive 'CCDC 254889'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C54 H72 Ag4 Au Cl4 F21 N2 O10'
_chemical_formula_weight         2078.38

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P21/n

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   19.2046(2)
_cell_length_b                   17.4577(2)
_cell_length_c                   24.2007(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 101.6369(6)
_cell_angle_gamma                90.00
_cell_volume                     7946.95(16)
_cell_formula_units_Z            4
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    2516
_cell_measurement_theta_min      5.10
_cell_measurement_theta_max      26.73

_exptl_crystal_description       prims
_exptl_crystal_colour            red
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.2
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.737
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             4056
_exptl_absorpt_coefficient_mu    3.038
_exptl_absorpt_correction_type   multiscan
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   Scalepack

_exptl_special_details           
;
'multi-scan from symmetry-related measurements'
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       \f-scan
_diffrn_detector_area_resol_mean 9
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            75235
_diffrn_reflns_av_R_equivalents  0.0441
_diffrn_reflns_av_sigmaI/netI    0.0359
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_theta_min         1.24
_diffrn_reflns_theta_max         27.89
_reflns_number_total             16737
_reflns_number_gt                13050
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Nonius Kappa CCD'
_computing_cell_refinement       'HKL and Scalepack (Otwinowski & Minor, 1997)'
_computing_data_reduction        
'Denzo and Scalepack (Otwinowski & Minor, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'ORTEP III for Windows'
_computing_publication_material  SHELXL-97

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0740P)^2^+36.9011P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         16737
_refine_ls_number_parameters     873
_refine_ls_number_restraints     211
_refine_ls_R_factor_all          0.0731
_refine_ls_R_factor_gt           0.0512
_refine_ls_wR_factor_ref         0.1492
_refine_ls_wR_factor_gt          0.1346
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_restrained_S_all      1.042
_refine_ls_shift/su_max          0.074
_refine_ls_shift/su_mean         0.004

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au Au 0.938813(13) 0.139425(15) 0.585198(11) 0.03862(9) Uani 1 1 d . . .
Ag1 Ag 1.04534(3) 0.23310(3) 0.66614(3) 0.04904(14) Uani 1 1 d . . .
Ag2 Ag 1.02844(3) 0.07409(3) 0.68501(2) 0.03947(13) Uani 1 1 d . . .
Ag3 Ag 0.87568(3) 0.09494(3) 0.68132(2) 0.04717(14) Uani 1 1 d . . .
Ag4 Ag 0.89674(3) 0.25420(3) 0.66125(2) 0.04135(13) Uani 1 1 d . . .
C1 C 0.8856(3) 0.2401(4) 0.5591(3) 0.0433(14) Uani 1 1 d DU . .
C2 C 0.9198(4) 0.3043(4) 0.5432(3) 0.0491(16) Uani 1 1 d DU . .
C3 C 0.8856(5) 0.3651(4) 0.5136(3) 0.0610(19) Uani 1 1 d DU . .
C4 C 0.8128(5) 0.3631(5) 0.4998(3) 0.062(2) Uani 1 1 d DU . .
C5 C 0.7742(4) 0.3005(5) 0.5114(3) 0.0537(17) Uani 1 1 d DU . .
C6 C 0.8132(4) 0.2411(4) 0.5407(3) 0.0450(15) Uani 1 1 d DU . .
F1 F 0.9917(2) 0.3069(3) 0.5566(2) 0.0678(13) Uani 1 1 d DU . .
Cl2 Cl 0.93167(19) 0.44163(17) 0.49440(14) 0.1069(11) Uani 1 1 d D . .
F3 F 0.7765(4) 0.4233(3) 0.4727(2) 0.0869(17) Uani 1 1 d DU . .
Cl4 Cl 0.68346(12) 0.29825(17) 0.49093(11) 0.0801(7) Uani 1 1 d D . .
F5 F 0.7754(2) 0.1785(3) 0.55021(19) 0.0549(10) Uani 1 1 d DU . .
C11 C 0.9847(3) 0.0319(4) 0.5882(3) 0.0419(14) Uani 1 1 d DU . .
C12 C 0.9451(4) -0.0344(4) 0.5905(2) 0.0474(16) Uani 1 1 d DU . .
C13 C 0.9648(4) -0.1072(4) 0.5783(3) 0.0565(18) Uani 1 1 d DU . .
C14 C 1.0302(4) -0.1148(5) 0.5639(3) 0.0566(18) Uani 1 1 d DU . .
C15 C 1.0728(4) -0.0519(4) 0.5590(3) 0.0493(16) Uani 1 1 d DU . .
C16 C 1.0478(4) 0.0190(4) 0.5705(3) 0.0421(14) Uani 1 1 d DU . .
F6 F 0.8807(2) -0.0275(3) 0.6059(2) 0.0615(12) Uani 1 1 d DU . .
Cl7 Cl 0.91092(18) -0.18456(15) 0.57970(15) 0.0973(9) Uani 1 1 d D . .
F8 F 1.0528(3) -0.1853(3) 0.5528(2) 0.0781(15) Uani 1 1 d DU . .
Cl9 Cl 1.15325(11) -0.06372(14) 0.53934(9) 0.0657(6) Uani 1 1 d D . .
F10 F 1.0875(2) 0.0801(2) 0.56221(17) 0.0496(10) Uani 1 1 d DU . .
O1 O 1.1555(3) 0.1947(3) 0.6571(2) 0.0513(12) Uani 1 1 d U . .
O2 O 1.1495(2) 0.0715(3) 0.6831(2) 0.0451(11) Uani 1 1 d U . .
C21 C 1.1775(3) 0.1288(4) 0.6661(3) 0.0387(14) Uani 1 1 d U . .
C22 C 1.2522(4) 0.1138(4) 0.6540(3) 0.0477(16) Uani 1 1 d U . .
F11 F 1.2993(3) 0.1098(6) 0.7008(3) 0.118(3) Uani 1 1 d U . .
F12 F 1.2747(3) 0.1671(4) 0.6248(4) 0.112(3) Uani 1 1 d U . .
F13 F 1.2579(3) 0.0490(3) 0.6288(3) 0.100(2) Uani 1 1 d U . .
O3 O 1.0173(3) -0.0089(4) 0.7531(3) 0.0723(18) Uani 1 1 d U . .
O4 O 0.9009(3) -0.0013(5) 0.7441(3) 0.087(2) Uani 1 1 d U . .
F14 F 1.0252(4) -0.1031(5) 0.8373(4) 0.134(3) Uani 1 1 d U . .
F15 F 0.9298(5) -0.0630(7) 0.8510(4) 0.178(4) Uani 1 1 d U . .
F16 F 0.9317(8) -0.1460(7) 0.7933(6) 0.210(5) Uani 1 1 d U . .
C23 C 0.9605(4) -0.0239(5) 0.7652(4) 0.058(2) Uani 1 1 d U . .
C24 C 0.9635(6) -0.0831(8) 0.8136(6) 0.095(3) Uani 1 1 d U . .
O5 O 0.7574(3) 0.1160(3) 0.6616(2) 0.0540(13) Uani 1 1 d U . .
O6 O 0.7767(3) 0.2435(3) 0.6646(2) 0.0549(13) Uani 1 1 d U . .
C25 C 0.7402(4) 0.1846(5) 0.6574(3) 0.0476(16) Uani 1 1 d U . .
C26 C 0.6583(4) 0.1986(5) 0.6391(4) 0.063(2) Uani 1 1 d U . .
F17 F 0.6296(3) 0.1541(3) 0.5967(3) 0.0822(16) Uani 1 1 d U . .
F18 F 0.6414(3) 0.2692(3) 0.6246(3) 0.0954(19) Uani 1 1 d U . .
F19 F 0.6270(3) 0.1808(5) 0.6816(3) 0.103(2) Uani 1 1 d U . .
O7 O 0.9329(3) 0.3794(3) 0.6751(3) 0.0705(18) Uani 1 1 d U . .
O8 O 1.0478(3) 0.3620(3) 0.6729(3) 0.0606(15) Uani 1 1 d U . .
C27 C 0.9945(4) 0.3997(4) 0.6744(3) 0.0509(17) Uani 1 1 d U . .
C28 C 1.0071(5) 0.4875(5) 0.6760(5) 0.069(2) Uani 1 1 d U . .
F20 F 0.9629(5) 0.5247(4) 0.6997(5) 0.161(4) Uani 1 1 d U . .
F21 F 1.0667(4) 0.5069(4) 0.7097(5) 0.158(4) Uani 1 1 d U . .
F22 F 1.0084(10) 0.5145(4) 0.6311(4) 0.236(7) Uani 1 1 d U . .
O9 O 1.0379(3) 0.1804(3) 0.7582(2) 0.0579(13) Uani 1 1 d U . .
O10 O 0.9239(3) 0.2088(4) 0.7545(2) 0.0699(17) Uani 1 1 d U . .
C29 C 0.9846(4) 0.1913(5) 0.7778(3) 0.0503(16) Uani 1 1 d U . .
C30 C 0.9951(5) 0.1811(7) 0.8422(4) 0.071(2) Uani 1 1 d U . .
F23 F 1.0482(6) 0.1474(8) 0.8663(3) 0.206(6) Uani 1 1 d U . .
F24 F 0.9427(6) 0.1524(9) 0.8572(3) 0.216(6) Uani 1 1 d U . .
F25 F 0.9946(8) 0.2445(6) 0.8661(3) 0.193(5) Uani 1 1 d U . .
N1 N 0.2322(3) 0.8993(4) 0.7993(3) 0.0472(13) Uani 1 1 d U . .
C31 C 0.1580(5) 0.8869(7) 0.7653(5) 0.087(3) Uani 1 1 d U . .
H31A H 0.1249 0.9133 0.7841 0.105 Uiso 1 1 calc R . .
H31B H 0.1550 0.9110 0.7288 0.105 Uiso 1 1 calc R . .
C32 C 0.1338(6) 0.8060(6) 0.7557(5) 0.087(3) Uani 1 1 d U . .
H32A H 0.1731 0.7764 0.7473 0.104 Uiso 1 1 calc R . .
H32B H 0.1241 0.7865 0.7910 0.104 Uiso 1 1 calc R . .
C33 C 0.0730(8) 0.7910(10) 0.7126(8) 0.146(7) Uani 1 1 d U . .
H33A H 0.0357 0.8252 0.7193 0.175 Uiso 1 1 calc R . .
H33B H 0.0850 0.8067 0.6773 0.175 Uiso 1 1 calc R . .
C34 C 0.0425(13) 0.7175(13) 0.7037(12) 0.227(13) Uani 1 1 d U . .
H34A H 0.0657 0.6893 0.6786 0.341 Uiso 1 1 calc R . .
H34B H -0.0072 0.7222 0.6875 0.341 Uiso 1 1 calc R . .
H34C H 0.0483 0.6910 0.7391 0.341 Uiso 1 1 calc R . .
C35 C 0.2444(6) 0.9877(6) 0.8024(5) 0.084(3) Uani 1 1 d U . .
H35A H 0.2949 0.9958 0.8163 0.100 Uiso 1 1 calc R . .
H35B H 0.2336 1.0067 0.7639 0.100 Uiso 1 1 calc R . .
C36 C 0.2087(8) 1.0346(6) 0.8340(5) 0.099(4) Uani 1 1 d U . .
H36A H 0.2238 1.0196 0.8731 0.119 Uiso 1 1 calc R . .
H36B H 0.1585 1.0223 0.8231 0.119 Uiso 1 1 calc R . .
C37 C 0.2148(7) 1.1175(7) 0.8318(5) 0.094(3) Uani 1 1 d U . .
H37A H 0.1879 1.1399 0.8576 0.112 Uiso 1 1 calc R . .
H37B H 0.1936 1.1347 0.7941 0.112 Uiso 1 1 calc R . .
C38 C 0.2910(10) 1.1469(9) 0.8468(5) 0.140(6) Uani 1 1 d U . .
H38A H 0.3119 1.1323 0.8847 0.210 Uiso 1 1 calc R . .
H38B H 0.2910 1.2017 0.8437 0.210 Uiso 1 1 calc R . .
H38C H 0.3181 1.1253 0.8213 0.210 Uiso 1 1 calc R . .
C39 C 0.2863(6) 0.8670(7) 0.7704(5) 0.082(3) Uani 1 1 d U . .
H39A H 0.3317 0.8888 0.7886 0.098 Uiso 1 1 calc R . .
H39B H 0.2890 0.8126 0.7787 0.098 Uiso 1 1 calc R . .
C40 C 0.2816(6) 0.8747(7) 0.7098(5) 0.083(3) Uani 1 1 d U . .
H40A H 0.2751 0.9285 0.7000 0.100 Uiso 1 1 calc R . .
H40B H 0.2394 0.8477 0.6906 0.100 Uiso 1 1 calc R . .
C41 C 0.3431(7) 0.8459(7) 0.6883(5) 0.089(3) Uani 1 1 d U . .
H41A H 0.3507 0.7924 0.6986 0.107 Uiso 1 1 calc R . .
H41B H 0.3853 0.8740 0.7061 0.107 Uiso 1 1 calc R . .
C42 C 0.3337(10) 0.8533(9) 0.6257(6) 0.131(6) Uani 1 1 d U . .
H42A H 0.2839 0.8562 0.6092 0.197 Uiso 1 1 calc R . .
H42B H 0.3541 0.8096 0.6110 0.197 Uiso 1 1 calc R . .
H42C H 0.3570 0.8990 0.6168 0.197 Uiso 1 1 calc R . .
C43 C 0.2382(7) 0.8693(7) 0.8583(4) 0.091(3) Uani 1 1 d U . .
H43A H 0.1983 0.8901 0.8724 0.110 Uiso 1 1 calc R . .
H43B H 0.2310 0.8144 0.8551 0.110 Uiso 1 1 calc R . .
C44 C 0.2995(8) 0.8814(6) 0.9008(5) 0.099(4) Uani 1 1 d U . .
H44A H 0.3038 0.9364 0.9060 0.118 Uiso 1 1 calc R . .
H44B H 0.3396 0.8655 0.8848 0.118 Uiso 1 1 calc R . .
C45 C 0.3111(12) 0.8492(8) 0.9561(6) 0.144(7) Uani 1 1 d U . .
H45A H 0.2638 0.8486 0.9646 0.173 Uiso 1 1 calc R . .
H45B H 0.3218 0.7960 0.9498 0.173 Uiso 1 1 calc R . .
C46 C 0.3502(15) 0.8638(11) 1.0028(8) 0.209(13) Uani 1 1 d U . .
H46A H 0.3887 0.8961 0.9972 0.313 Uiso 1 1 calc R . .
H46B H 0.3690 0.8170 1.0206 0.313 Uiso 1 1 calc R . .
H46C H 0.3231 0.8896 1.0264 0.313 Uiso 1 1 calc R . .
N2 N 0.6870(3) 0.8980(4) 0.6757(3) 0.0558(15) Uani 1 1 d U . .
C51 C 0.7112(5) 0.9281(5) 0.6233(4) 0.0597(19) Uani 1 1 d U . .
H51A H 0.7017 0.9826 0.6203 0.072 Uiso 1 1 calc R . .
H51B H 0.7623 0.9213 0.6287 0.072 Uiso 1 1 calc R . .
C52 C 0.6770(7) 0.8908(7) 0.5683(4) 0.090(3) Uani 1 1 d U . .
H52A H 0.6257 0.8955 0.5629 0.109 Uiso 1 1 calc R . .
H52B H 0.6887 0.8367 0.5697 0.109 Uiso 1 1 calc R . .
C53 C 0.7021(7) 0.9277(7) 0.5183(4) 0.087(3) Uani 1 1 d U . .
H53A H 0.7537 0.9277 0.5259 0.105 Uiso 1 1 calc R . .
H53B H 0.6858 0.8968 0.4849 0.105 Uiso 1 1 calc R . .
C54 C 0.6773(8) 1.0047(8) 0.5068(5) 0.107(4) Uani 1 1 d U . .
H54A H 0.6264 1.0057 0.5011 0.161 Uiso 1 1 calc R . .
H54B H 0.6919 1.0231 0.4735 0.161 Uiso 1 1 calc R . .
H54C H 0.6971 1.0369 0.5382 0.161 Uiso 1 1 calc R . .
C55 C 0.7297(4) 0.9438(5) 0.7257(3) 0.0521(16) Uani 1 1 d U . .
H55A H 0.7800 0.9365 0.7266 0.063 Uiso 1 1 calc R . .
H55B H 0.7194 0.9979 0.7192 0.063 Uiso 1 1 calc R . .
C56 C 0.7148(5) 0.9225(6) 0.7823(4) 0.066(2) Uani 1 1 d U . .
H56A H 0.6640 0.9244 0.7808 0.079 Uiso 1 1 calc R . .
H56B H 0.7308 0.8704 0.7915 0.079 Uiso 1 1 calc R . .
C57 C 0.7519(6) 0.9757(6) 0.8272(4) 0.074(2) Uani 1 1 d U . .
H57A H 0.7343 1.0271 0.8179 0.088 Uiso 1 1 calc R . .
H57B H 0.8022 0.9756 0.8264 0.088 Uiso 1 1 calc R . .
C58 C 0.7435(7) 0.9575(7) 0.8864(4) 0.091(3) Uani 1 1 d U . .
H58A H 0.6960 0.9401 0.8857 0.137 Uiso 1 1 calc R . .
H58B H 0.7526 1.0028 0.9093 0.137 Uiso 1 1 calc R . .
H58C H 0.7767 0.9182 0.9020 0.137 Uiso 1 1 calc R . .
C59 C 0.7025(5) 0.8131(5) 0.6840(4) 0.067(2) Uani 1 1 d U . .
H59A H 0.6865 0.7968 0.7176 0.081 Uiso 1 1 calc R . .
H59B H 0.6741 0.7858 0.6523 0.081 Uiso 1 1 calc R . .
C60 C 0.7793(6) 0.7884(6) 0.6894(5) 0.082(3) Uani 1 1 d U . .
H60A H 0.8068 0.8050 0.7256 0.099 Uiso 1 1 calc R . .
H60B H 0.7993 0.8121 0.6599 0.099 Uiso 1 1 calc R . .
C61 C 0.7835(7) 0.7002(7) 0.6847(6) 0.097(4) Uani 1 1 d U . .
H61A H 0.7668 0.6781 0.7165 0.117 Uiso 1 1 calc R . .
H61B H 0.7505 0.6846 0.6508 0.117 Uiso 1 1 calc R . .
C62 C 0.8519(11) 0.6669(11) 0.6832(11) 0.184(9) Uani 1 1 d U . .
H62A H 0.8529 0.6512 0.6453 0.276 Uiso 1 1 calc R . .
H62B H 0.8597 0.6231 0.7077 0.276 Uiso 1 1 calc R . .
H62C H 0.8885 0.7041 0.6955 0.276 Uiso 1 1 calc R . .
C63 C 0.6087(4) 0.9078(6) 0.6705(4) 0.067(2) Uani 1 1 d U . .
H63A H 0.5849 0.8771 0.6389 0.080 Uiso 1 1 calc R . .
H63B H 0.5959 0.8869 0.7042 0.080 Uiso 1 1 calc R . .
C64 C 0.5800(5) 0.9871(6) 0.6626(5) 0.075(3) Uani 1 1 d U . .
H64A H 0.5965 1.0114 0.6315 0.090 Uiso 1 1 calc R . .
H64B H 0.5970 1.0169 0.6964 0.090 Uiso 1 1 calc R . .
C65 C 0.4992(6) 0.9847(9) 0.6501(6) 0.104(4) Uani 1 1 d U . .
H65A H 0.4831 0.9593 0.6809 0.125 Uiso 1 1 calc R . .
H65B H 0.4826 0.9551 0.6161 0.125 Uiso 1 1 calc R . .
C66 C 0.4665(7) 1.0661(10) 0.6423(7) 0.128(5) Uani 1 1 d U . .
H66A H 0.4806 1.0946 0.6766 0.192 Uiso 1 1 calc R . .
H66B H 0.4156 1.0622 0.6331 0.192 Uiso 1 1 calc R . .
H66C H 0.4830 1.0917 0.6123 0.192 Uiso 1 1 calc R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Au 0.03939(14) 0.03607(15) 0.04118(14) -0.00077(11) 0.00996(10) -0.00078(10)
Ag1 0.0417(3) 0.0386(3) 0.0679(4) -0.0007(3) 0.0135(3) 0.0042(2)
Ag2 0.0372(3) 0.0410(3) 0.0413(3) 0.0006(2) 0.0103(2) -0.0033(2)
Ag3 0.0415(3) 0.0438(3) 0.0574(3) 0.0045(2) 0.0130(2) 0.0024(2)
Ag4 0.0401(3) 0.0402(3) 0.0449(3) -0.0037(2) 0.0113(2) -0.0008(2)
C1 0.049(3) 0.038(4) 0.043(4) 0.000(3) 0.009(3) 0.003(3)
C2 0.055(4) 0.046(4) 0.045(4) -0.002(3) 0.005(3) -0.006(3)
C3 0.082(5) 0.049(4) 0.052(4) 0.007(3) 0.011(4) -0.009(4)
C4 0.085(5) 0.049(4) 0.046(4) 0.008(3) 0.002(4) 0.012(4)
C5 0.066(4) 0.054(4) 0.037(4) -0.004(3) 0.001(3) 0.015(3)
C6 0.049(4) 0.048(4) 0.037(3) -0.008(3) 0.007(3) -0.001(3)
F1 0.056(3) 0.072(3) 0.071(3) 0.016(3) 0.003(2) -0.022(2)
Cl2 0.133(3) 0.0725(18) 0.104(2) 0.0415(16) -0.0020(18) -0.0378(17)
F3 0.120(5) 0.061(3) 0.071(3) 0.020(3) -0.002(3) 0.027(3)
Cl4 0.0586(12) 0.0993(19) 0.0758(15) -0.0014(13) -0.0023(11) 0.0206(13)
F5 0.048(2) 0.055(3) 0.061(3) -0.002(2) 0.011(2) -0.007(2)
C11 0.046(3) 0.040(4) 0.040(3) -0.001(3) 0.012(3) 0.000(3)
C12 0.048(4) 0.047(4) 0.048(4) -0.009(3) 0.013(3) -0.003(3)
C13 0.072(5) 0.044(4) 0.058(4) -0.007(4) 0.021(4) -0.010(3)
C14 0.077(5) 0.043(4) 0.051(4) -0.011(3) 0.018(4) 0.007(3)
C15 0.054(4) 0.052(4) 0.041(4) -0.008(3) 0.008(3) 0.008(3)
C16 0.044(3) 0.044(4) 0.038(3) 0.000(3) 0.008(3) 0.000(3)
F6 0.055(2) 0.053(3) 0.084(3) -0.011(2) 0.031(2) -0.015(2)
Cl7 0.127(2) 0.0475(13) 0.132(2) -0.0250(14) 0.0613(19) -0.0326(14)
F8 0.108(4) 0.048(3) 0.084(4) -0.016(3) 0.033(3) 0.011(3)
Cl9 0.0489(10) 0.0842(16) 0.0636(12) -0.0234(11) 0.0103(9) 0.0124(10)
F10 0.048(2) 0.054(2) 0.049(2) -0.0037(19) 0.0140(18) -0.0063(19)
O1 0.047(3) 0.038(3) 0.073(3) 0.002(2) 0.022(2) 0.005(2)
O2 0.036(2) 0.046(3) 0.053(3) 0.008(2) 0.008(2) -0.002(2)
C21 0.030(3) 0.041(4) 0.045(4) -0.002(3) 0.007(3) -0.001(3)
C22 0.038(3) 0.040(4) 0.068(4) -0.003(3) 0.019(3) -0.001(3)
F11 0.036(3) 0.221(8) 0.094(4) -0.014(4) 0.006(3) 0.013(4)
F12 0.091(4) 0.074(4) 0.198(7) 0.050(4) 0.097(5) 0.022(3)
F13 0.070(3) 0.065(3) 0.181(6) -0.043(4) 0.062(4) -0.004(3)
O3 0.047(3) 0.086(5) 0.086(4) 0.044(4) 0.019(3) 0.008(3)
O4 0.048(3) 0.114(6) 0.100(5) 0.064(4) 0.017(3) 0.008(3)
F14 0.089(4) 0.177(8) 0.142(6) 0.117(6) 0.040(4) 0.045(4)
F15 0.157(7) 0.265(11) 0.138(6) 0.139(6) 0.093(6) 0.107(7)
F16 0.258(12) 0.142(7) 0.206(10) 0.108(6) -0.008(8) -0.094(8)
C23 0.047(4) 0.061(5) 0.070(5) 0.026(4) 0.019(4) 0.005(4)
C24 0.062(5) 0.105(8) 0.126(9) 0.071(6) 0.039(5) 0.015(5)
O5 0.042(3) 0.048(3) 0.076(4) 0.003(3) 0.019(3) 0.000(2)
O6 0.041(3) 0.048(3) 0.078(4) -0.016(3) 0.017(2) -0.004(2)
C25 0.042(3) 0.055(4) 0.050(4) -0.007(3) 0.018(3) 0.003(3)
C26 0.040(4) 0.060(5) 0.090(6) -0.010(4) 0.013(4) 0.001(3)
F17 0.050(3) 0.085(4) 0.103(4) -0.025(3) -0.005(3) -0.001(3)
F18 0.058(3) 0.064(3) 0.154(6) -0.007(3) -0.003(3) 0.016(3)
F19 0.052(3) 0.155(6) 0.112(4) -0.005(4) 0.044(3) -0.001(4)
O7 0.054(3) 0.044(3) 0.122(5) -0.024(3) 0.036(3) -0.008(3)
O8 0.048(3) 0.036(3) 0.101(5) -0.012(3) 0.022(3) -0.002(2)
C27 0.060(4) 0.034(3) 0.060(4) -0.006(3) 0.017(4) -0.004(3)
C28 0.074(5) 0.036(4) 0.101(6) -0.004(4) 0.025(5) -0.002(4)
F20 0.144(6) 0.049(4) 0.313(12) -0.058(6) 0.099(7) -0.003(4)
F21 0.104(5) 0.061(4) 0.291(10) -0.042(6) -0.003(6) -0.029(4)
F22 0.54(2) 0.051(4) 0.128(6) 0.011(4) 0.098(8) -0.066(8)
O9 0.059(3) 0.066(4) 0.049(3) -0.006(3) 0.012(2) 0.007(3)
O10 0.059(3) 0.106(5) 0.046(3) 0.001(3) 0.012(2) 0.006(3)
C29 0.053(4) 0.051(4) 0.048(3) -0.001(3) 0.011(3) 0.004(3)
C30 0.060(5) 0.106(7) 0.047(4) -0.007(5) 0.014(4) 0.017(5)
F23 0.201(8) 0.360(15) 0.061(4) 0.064(6) 0.039(5) 0.179(10)
F24 0.166(7) 0.414(17) 0.065(4) 0.064(7) 0.020(5) -0.117(10)
F25 0.345(16) 0.158(8) 0.070(5) -0.044(5) 0.027(7) 0.041(7)
N1 0.042(3) 0.047(3) 0.051(3) 0.002(3) 0.006(2) 0.005(3)
C31 0.063(5) 0.099(7) 0.094(7) -0.019(6) 0.004(5) -0.003(5)
C32 0.074(6) 0.074(6) 0.112(8) -0.026(6) 0.017(5) -0.013(5)
C33 0.105(10) 0.122(11) 0.184(16) -0.056(12) -0.035(10) -0.018(9)
C34 0.20(2) 0.144(16) 0.29(3) -0.037(18) -0.07(2) -0.075(16)
C35 0.105(8) 0.055(5) 0.078(6) 0.006(4) -0.010(5) 0.018(4)
C36 0.139(10) 0.061(5) 0.079(7) -0.015(5) -0.018(6) 0.005(6)
C37 0.127(8) 0.075(6) 0.068(6) -0.013(5) -0.006(6) 0.045(6)
C38 0.224(15) 0.121(12) 0.067(7) -0.011(7) 0.013(9) -0.085(12)
C39 0.075(6) 0.084(7) 0.091(6) -0.026(6) 0.029(5) -0.009(5)
C40 0.083(7) 0.087(8) 0.080(6) -0.008(6) 0.018(5) 0.001(6)
C41 0.102(8) 0.095(8) 0.075(6) -0.010(6) 0.026(6) 0.019(6)
C42 0.178(16) 0.139(14) 0.081(7) 0.011(8) 0.037(9) 0.037(11)
C43 0.131(9) 0.071(7) 0.065(5) 0.007(5) 0.006(5) -0.011(6)
C44 0.149(11) 0.062(6) 0.070(5) -0.004(5) -0.014(6) 0.038(7)
C45 0.24(2) 0.091(10) 0.073(7) 0.018(7) -0.026(9) 0.007(11)
C46 0.33(3) 0.139(17) 0.109(11) 0.009(11) -0.074(15) 0.042(17)
N2 0.053(3) 0.047(3) 0.073(4) 0.010(3) 0.027(3) -0.012(3)
C51 0.061(5) 0.056(5) 0.068(4) 0.013(4) 0.027(4) -0.011(4)
C52 0.129(10) 0.077(7) 0.072(5) -0.007(5) 0.035(6) -0.033(7)
C53 0.108(8) 0.095(7) 0.064(5) -0.001(5) 0.027(6) -0.015(6)
C54 0.131(11) 0.112(9) 0.082(7) 0.023(7) 0.031(7) -0.005(8)
C55 0.048(4) 0.045(4) 0.067(4) 0.011(3) 0.020(3) -0.004(3)
C56 0.072(6) 0.061(5) 0.071(4) 0.015(4) 0.027(4) 0.001(4)
C57 0.089(7) 0.064(6) 0.075(5) 0.004(4) 0.035(5) 0.001(5)
C58 0.110(9) 0.098(9) 0.065(5) 0.011(5) 0.016(6) 0.007(7)
C59 0.079(5) 0.043(4) 0.087(6) 0.009(4) 0.036(5) -0.012(4)
C60 0.087(6) 0.064(5) 0.108(8) 0.020(6) 0.048(6) 0.008(5)
C61 0.119(9) 0.064(6) 0.116(9) 0.003(6) 0.040(8) 0.014(6)
C62 0.174(16) 0.114(13) 0.28(3) 0.041(16) 0.089(18) 0.059(12)
C63 0.049(4) 0.078(6) 0.076(6) 0.015(5) 0.018(4) -0.011(4)
C64 0.059(5) 0.087(6) 0.085(6) 0.022(5) 0.026(5) 0.002(4)
C65 0.062(5) 0.135(10) 0.118(9) 0.028(8) 0.025(6) 0.014(6)
C66 0.079(8) 0.151(12) 0.153(13) 0.033(11) 0.021(8) 0.035(8)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.

Special refinement details: the structure contains extensive regions of
badly resolved residual electron density, in which no solvent molecules
could be clearly identified. For this reason no solvetn was included in
the refinement, and the formula and related information (Mr, etc) do not
include solvent.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au C1 2.067(7) . ?
Au C11 2.068(7) . ?
Au Ag2 2.9019(6) . ?
Au Ag3 2.9364(6) . ?
Au Ag4 2.9421(6) . ?
Au Ag1 3.0134(6) . ?
Ag1 O8 2.257(5) . ?
Ag1 O1 2.272(5) . ?
Ag1 O9 2.441(6) . ?
Ag1 Ag2 2.8424(8) . ?
Ag1 Ag4 2.8563(7) . ?
Ag2 O3 2.237(6) . ?
Ag2 O2 2.335(5) . ?
Ag2 C11 2.439(6) . ?
Ag2 O9 2.546(6) . ?
Ag2 Ag3 2.9396(7) . ?
Ag3 O4 2.251(6) . ?
Ag3 O5 2.255(5) . ?
Ag3 Ag4 2.8652(8) . ?
Ag4 O7 2.297(6) . ?
Ag4 O6 2.330(5) . ?
Ag4 O10 2.349(6) . ?
Ag4 C1 2.450(6) . ?
C1 C6 1.373(9) . ?
C1 C2 1.391(9) . ?
C2 F1 1.353(8) . ?
C2 C3 1.372(10) . ?
C3 C4 1.371(11) . ?
C3 Cl2 1.718(8) . ?
C4 F3 1.355(9) . ?
C4 C5 1.380(10) . ?
C5 C6 1.386(9) . ?
C5 Cl4 1.713(8) . ?
C6 F5 1.358(8) . ?
C11 C16 1.383(8) . ?
C11 C12 1.392(9) . ?
C12 F6 1.367(8) . ?
C12 C13 1.375(10) . ?
C13 C14 1.375(10) . ?
C13 Cl7 1.706(8) . ?
C14 F8 1.349(9) . ?
C14 C15 1.389(10) . ?
C15 C16 1.376(9) . ?
C15 Cl9 1.719(7) . ?
C16 F10 1.349(8) . ?
O1 C21 1.229(8) . ?
O2 C21 1.244(8) . ?
C21 C22 1.544(9) . ?
C22 F12 1.294(9) . ?
C22 F13 1.301(9) . ?
C22 F11 1.301(10) . ?
O3 C23 1.214(9) . ?
O4 C23 1.222(10) . ?
F14 C24 1.256(12) . ?
F15 C24 1.263(14) . ?
F16 C24 1.304(17) . ?
C23 C24 1.555(12) . ?
O5 C25 1.240(9) . ?
O6 C25 1.237(9) . ?
C25 C26 1.565(10) . ?
C26 F18 1.306(11) . ?
C26 F17 1.316(10) . ?
C26 F19 1.328(11) . ?
O7 C27 1.238(9) . ?
O8 C27 1.225(9) . ?
C27 C28 1.550(11) . ?
C28 F22 1.189(13) . ?
C28 F20 1.291(12) . ?
C28 F21 1.310(12) . ?
O9 C29 1.226(9) . ?
O10 C29 1.227(9) . ?
C29 C30 1.541(11) . ?
C30 F23 1.218(11) . ?
C30 F24 1.243(12) . ?
C30 F25 1.250(13) . ?
N1 C39 1.477(11) . ?
N1 C43 1.502(12) . ?
N1 C31 1.511(11) . ?
N1 C35 1.559(12) . ?
C31 C32 1.490(16) . ?
C32 C33 1.425(16) . ?
C33 C34 1.41(2) . ?
C35 C36 1.392(16) . ?
C36 C37 1.453(15) . ?
C37 C38 1.52(2) . ?
C39 C40 1.457(15) . ?
C40 C41 1.474(15) . ?
C41 C42 1.493(16) . ?
C43 C44 1.415(16) . ?
C44 C45 1.427(17) . ?
C45 C46 1.25(2) . ?
N2 C63 1.493(10) . ?
N2 C59 1.518(11) . ?
N2 C51 1.528(9) . ?
N2 C55 1.542(11) . ?
C51 C52 1.509(14) . ?
C52 C53 1.532(14) . ?
C53 C54 1.434(17) . ?
C55 C56 1.501(11) . ?
C56 C57 1.496(14) . ?
C57 C58 1.508(13) . ?
C59 C60 1.518(13) . ?
C60 C61 1.548(15) . ?
C61 C62 1.44(2) . ?
C63 C64 1.488(14) . ?
C64 C65 1.521(14) . ?
C65 C66 1.548(19) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au C11 164.4(2) . . ?
C1 Au Ag2 139.64(18) . . ?
C11 Au Ag2 55.77(17) . . ?
C1 Au Ag3 102.08(18) . . ?
C11 Au Ag3 88.48(17) . . ?
Ag2 Au Ag3 60.459(15) . . ?
C1 Au Ag4 55.29(18) . . ?
C11 Au Ag4 139.91(17) . . ?
Ag2 Au Ag4 86.478(16) . . ?
Ag3 Au Ag4 58.341(16) . . ?
C1 Au Ag1 88.04(18) . . ?
C11 Au Ag1 103.97(18) . . ?
Ag2 Au Ag1 57.402(16) . . ?
Ag3 Au Ag1 87.893(17) . . ?
Ag4 Au Ag1 57.305(15) . . ?
O8 Ag1 O1 107.16(19) . . ?
O8 Ag1 O9 108.3(2) . . ?
O1 Ag1 O9 101.77(19) . . ?
O8 Ag1 Ag2 164.56(16) . . ?
O1 Ag1 Ag2 82.29(13) . . ?
O9 Ag1 Ag2 57.01(14) . . ?
O8 Ag1 Ag4 83.16(14) . . ?
O1 Ag1 Ag4 167.48(14) . . ?
O9 Ag1 Ag4 81.05(13) . . ?
Ag2 Ag1 Ag4 89.26(2) . . ?
O8 Ag1 Au 126.17(16) . . ?
O1 Ag1 Au 107.47(14) . . ?
O9 Ag1 Au 103.38(14) . . ?
Ag2 Ag1 Au 59.329(16) . . ?
Ag4 Ag1 Au 60.092(16) . . ?
O3 Ag2 O2 104.18(19) . . ?
O3 Ag2 C11 116.6(3) . . ?
O2 Ag2 C11 97.29(19) . . ?
O3 Ag2 O9 87.9(2) . . ?
O2 Ag2 O9 95.52(18) . . ?
C11 Ag2 O9 148.3(2) . . ?
O3 Ag2 Ag1 141.4(2) . . ?
O2 Ag2 Ag1 82.49(12) . . ?
C11 Ag2 Ag1 99.72(16) . . ?
O9 Ag2 Ag1 53.53(13) . . ?
O3 Ag2 Au 137.67(15) . . ?
O2 Ag2 Au 114.65(12) . . ?
C11 Ag2 Au 44.53(16) . . ?
O9 Ag2 Au 103.86(13) . . ?
Ag1 Ag2 Au 63.269(17) . . ?
O3 Ag2 Ag3 81.94(14) . . ?
O2 Ag2 Ag3 173.38(12) . . ?
C11 Ag2 Ag3 81.94(15) . . ?
O9 Ag2 Ag3 82.04(13) . . ?
Ag1 Ag2 Ag3 91.14(2) . . ?
Au Ag2 Ag3 60.351(16) . . ?
O4 Ag3 O5 109.6(2) . . ?
O4 Ag3 Ag4 145.1(2) . . ?
O5 Ag3 Ag4 88.64(14) . . ?
O4 Ag3 Au 131.69(18) . . ?
O5 Ag3 Au 110.40(14) . . ?
Ag4 Ag3 Au 60.929(15) . . ?
O4 Ag3 Ag2 79.04(15) . . ?
O5 Ag3 Ag2 169.46(15) . . ?
Ag4 Ag3 Ag2 87.20(2) . . ?
Au Ag3 Ag2 59.190(15) . . ?
O7 Ag4 O6 110.09(19) . . ?
O7 Ag4 O10 100.3(3) . . ?
O6 Ag4 O10 88.2(2) . . ?
O7 Ag4 C1 101.8(2) . . ?
O6 Ag4 C1 98.1(2) . . ?
O10 Ag4 C1 153.2(2) . . ?
O7 Ag4 Ag1 81.17(14) . . ?
O6 Ag4 Ag1 167.24(14) . . ?
O10 Ag4 Ag1 83.71(14) . . ?
C1 Ag4 Ag1 84.94(15) . . ?
O7 Ag4 Ag3 161.32(19) . . ?
O6 Ag4 Ag3 75.04(14) . . ?
O10 Ag4 Ag3 61.41(18) . . ?
C1 Ag4 Ag3 95.00(16) . . ?
Ag1 Ag4 Ag3 92.40(2) . . ?
O7 Ag4 Au 128.76(15) . . ?
O6 Ag4 Au 111.43(13) . . ?
O10 Ag4 Au 109.61(17) . . ?
C1 Ag4 Au 43.91(16) . . ?
Ag1 Ag4 Au 62.602(16) . . ?
Ag3 Ag4 Au 60.731(16) . . ?
C6 C1 C2 113.8(7) . . ?
C6 C1 Au 121.1(5) . . ?
C2 C1 Au 122.5(5) . . ?
C6 C1 Ag4 101.7(4) . . ?
C2 C1 Ag4 104.4(4) . . ?
Au C1 Ag4 80.8(2) . . ?
F1 C2 C3 117.2(7) . . ?
F1 C2 C1 118.4(6) . . ?
C3 C2 C1 124.4(7) . . ?
C4 C3 C2 117.7(7) . . ?
C4 C3 Cl2 120.6(6) . . ?
C2 C3 Cl2 121.7(7) . . ?
F3 C4 C3 119.8(7) . . ?
F3 C4 C5 117.9(7) . . ?
C3 C4 C5 122.2(7) . . ?
C4 C5 C6 116.0(7) . . ?
C4 C5 Cl4 121.0(6) . . ?
C6 C5 Cl4 122.9(7) . . ?
F5 C6 C1 118.4(6) . . ?
F5 C6 C5 115.9(6) . . ?
C1 C6 C5 125.7(7) . . ?
C16 C11 C12 113.4(6) . . ?
C16 C11 Au 122.1(5) . . ?
C12 C11 Au 121.6(5) . . ?
C16 C11 Ag2 101.1(4) . . ?
C12 C11 Ag2 107.3(4) . . ?
Au C11 Ag2 79.7(2) . . ?
F6 C12 C13 116.4(6) . . ?
F6 C12 C11 118.0(6) . . ?
C13 C12 C11 125.7(7) . . ?
C14 C13 C12 116.7(7) . . ?
C14 C13 Cl7 121.1(6) . . ?
C12 C13 Cl7 122.2(6) . . ?
F8 C14 C13 119.0(7) . . ?
F8 C14 C15 119.1(7) . . ?
C13 C14 C15 121.9(7) . . ?
C16 C15 C14 117.3(7) . . ?
C16 C15 Cl9 122.2(6) . . ?
C14 C15 Cl9 120.4(6) . . ?
F10 C16 C15 116.8(6) . . ?
F10 C16 C11 118.3(6) . . ?
C15 C16 C11 124.9(7) . . ?
C21 O1 Ag1 123.5(4) . . ?
C21 O2 Ag2 119.2(4) . . ?
O1 C21 O2 131.0(6) . . ?
O1 C21 C22 115.1(6) . . ?
O2 C21 C22 113.9(6) . . ?
F12 C22 F13 107.5(7) . . ?
F12 C22 F11 105.3(7) . . ?
F13 C22 F11 104.7(8) . . ?
F12 C22 C21 114.0(6) . . ?
F13 C22 C21 113.9(6) . . ?
F11 C22 C21 110.7(6) . . ?
C23 O3 Ag2 122.7(5) . . ?
C23 O4 Ag3 125.4(5) . . ?
O3 C23 O4 129.9(8) . . ?
O3 C23 C24 115.2(7) . . ?
O4 C23 C24 114.8(7) . . ?
F14 C24 F15 108.9(12) . . ?
F14 C24 F16 105.4(12) . . ?
F15 C24 F16 103.5(11) . . ?
F14 C24 C23 114.6(8) . . ?
F15 C24 C23 114.2(10) . . ?
F16 C24 C23 109.3(11) . . ?
C25 O5 Ag3 114.5(5) . . ?
C25 O6 Ag4 126.8(5) . . ?
O6 C25 O5 131.0(7) . . ?
O6 C25 C26 114.8(7) . . ?
O5 C25 C26 114.2(7) . . ?
F18 C26 F17 107.8(8) . . ?
F18 C26 F19 107.6(8) . . ?
F17 C26 F19 106.3(7) . . ?
F18 C26 C25 113.9(7) . . ?
F17 C26 C25 111.6(7) . . ?
F19 C26 C25 109.3(7) . . ?
C27 O7 Ag4 122.2(5) . . ?
C27 O8 Ag1 122.2(5) . . ?
O8 C27 O7 130.8(7) . . ?
O8 C27 C28 113.9(7) . . ?
O7 C27 C28 115.3(7) . . ?
F22 C28 F20 110.0(12) . . ?
F22 C28 F21 106.8(12) . . ?
F20 C28 F21 99.4(10) . . ?
F22 C28 C27 113.7(9) . . ?
F20 C28 C27 113.3(8) . . ?
F21 C28 C27 112.6(8) . . ?
C29 O9 Ag1 120.1(5) . . ?
C29 O9 Ag2 115.8(5) . . ?
Ag1 O9 Ag2 69.46(14) . . ?
C29 O10 Ag4 122.0(5) . . ?
O9 C29 O10 130.7(7) . . ?
O9 C29 C30 115.1(7) . . ?
O10 C29 C30 114.2(7) . . ?
F23 C30 F24 108.3(12) . . ?
F23 C30 F25 106.8(12) . . ?
F24 C30 F25 98.1(11) . . ?
F23 C30 C29 117.7(8) . . ?
F24 C30 C29 113.3(8) . . ?
F25 C30 C29 110.6(9) . . ?
C39 N1 C43 112.9(8) . . ?
C39 N1 C31 111.4(8) . . ?
C43 N1 C31 110.5(8) . . ?
C39 N1 C35 106.7(8) . . ?
C43 N1 C35 108.5(7) . . ?
C31 N1 C35 106.5(7) . . ?
C32 C31 N1 116.8(10) . . ?
C33 C32 C31 118.1(12) . . ?
C34 C33 C32 122.2(17) . . ?
C36 C35 N1 121.5(11) . . ?
C35 C36 C37 120.9(13) . . ?
C36 C37 C38 114.1(11) . . ?
C40 C39 N1 122.2(10) . . ?
C39 C40 C41 115.6(10) . . ?
C40 C41 C42 112.8(11) . . ?
C44 C43 N1 122.2(11) . . ?
C43 C44 C45 124.9(15) . . ?
C46 C45 C44 136(2) . . ?
C63 N2 C59 106.8(6) . . ?
C63 N2 C51 111.2(7) . . ?
C59 N2 C51 111.1(6) . . ?
C63 N2 C55 111.9(7) . . ?
C59 N2 C55 110.1(7) . . ?
C51 N2 C55 105.7(6) . . ?
C52 C51 N2 115.6(7) . . ?
C51 C52 C53 111.4(9) . . ?
C54 C53 C52 113.7(11) . . ?
C56 C55 N2 114.7(6) . . ?
C57 C56 C55 111.0(7) . . ?
C56 C57 C58 115.7(9) . . ?
C60 C59 N2 116.7(7) . . ?
C59 C60 C61 109.8(9) . . ?
C62 C61 C60 117.6(13) . . ?
C64 C63 N2 117.2(7) . . ?
C63 C64 C65 109.7(9) . . ?
C64 C65 C66 111.8(11) . . ?

_diffrn_measured_fraction_theta_max 0.991
_diffrn_reflns_theta_full        26.73
_diffrn_measured_fraction_theta_full 0.991
_refine_diff_density_max         3.225
_refine_diff_density_min         -0.720
_refine_diff_density_rms         0.142

#############################################################END