# Electronic Supplementary Material (ESI) for Dalton Transactions
# This journal is © The Royal Society of Chemistry 2013


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#                                CCDC 
# 
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# 
#  This CIF contains data from an original supplementary publication 
#  deposited with the CCDC, and may include chemical, crystal,   
#  experimental, refinement, atomic coordinates, 
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted. 
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data_1
_database_code_depnum_ccdc_archive 'CCDC 859338'
#TrackingRef '1.cif'
_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C74 H63 Dy2 N4 O13.50'
_chemical_formula_weight         1549.28
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
_cell_length_a                   12.04920(10)
_cell_length_b                   12.33190(10)
_cell_length_c                   23.7314(4)
_cell_angle_alpha                99.4190(10)
_cell_angle_beta                 95.7620(10)
_cell_angle_gamma                107.4490(10)
_cell_volume                     3276.50(7)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    9883
_cell_measurement_theta_min      2.31
_cell_measurement_theta_max      24.50
_exptl_crystal_description       Block
_exptl_crystal_colour            Colorless
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.570
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1550
_exptl_absorpt_coefficient_mu    2.332
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.7211
_exptl_absorpt_correction_T_max  0.8003
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_special_details           
;
?
;
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            46997
_diffrn_reflns_av_R_equivalents  0.0372
_diffrn_reflns_av_unetI/netI     0.0326
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_theta_min         0.88
_diffrn_reflns_theta_max         25.00
_reflns_number_total             11538
_reflns_number_gt                9688
_reflns_threshold_expression     >2sigma(I)
_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0363P)^2^+3.9765P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         11538
_refine_ls_number_parameters     734
_refine_ls_number_restraints     23
_refine_ls_R_factor_all          0.0399
_refine_ls_R_factor_gt           0.0310
_refine_ls_wR_factor_ref         0.0792
_refine_ls_wR_factor_gt          0.0749
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_restrained_S_all      1.044
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.4480(4) 0.9259(4) 0.59762(18) 0.0420(10) Uani 1 1 d . . .
C2 C 0.4207(3) 0.8824(3) 0.65167(12) 0.0541(12) Uani 1 1 d G . .
C3 C 0.5054(3) 0.9094(3) 0.70062(15) 0.0676(15) Uani 1 1 d G . .
C4 C 0.4750(5) 0.8686(4) 0.75004(13) 0.105(3) Uani 1 1 d G . .
H4 H 0.5316 0.8867 0.7828 0.126 Uiso 1 1 calc R . .
C5 C 0.3600(5) 0.8007(4) 0.75050(16) 0.124(3) Uani 1 1 d G . .
H5 H 0.3397 0.7733 0.7836 0.149 Uiso 1 1 calc R . .
C6 C 0.2753(4) 0.7736(4) 0.7016(2) 0.120(3) Uani 1 1 d G . .
H6 H 0.1984 0.7282 0.7019 0.144 Uiso 1 1 calc R . .
C7 C 0.3057(3) 0.8145(3) 0.65213(16) 0.0826(19) Uani 1 1 d G . .
H7 H 0.2491 0.7964 0.6194 0.099 Uiso 1 1 calc R . .
C8 C 0.6299(6) 0.9793(6) 0.7022(3) 0.097(2) Uani 1 1 d . . .
H8A H 0.6350 1.0583 0.7017 0.145 Uiso 1 1 calc R . .
H8B H 0.6586 0.9482 0.6690 0.145 Uiso 1 1 calc R . .
H8C H 0.6766 0.9765 0.7368 0.145 Uiso 1 1 calc R . .
C9 C 0.6712(4) 0.9142(4) 0.50587(19) 0.0408(10) Uani 1 1 d . . .
C10 C 0.7932(2) 0.9150(2) 0.52401(12) 0.0412(10) Uani 1 1 d G . .
C11 C 0.8470(3) 0.9715(3) 0.58015(12) 0.0574(12) Uani 1 1 d G . .
H11 H 0.8087 1.0113 0.6038 0.069 Uiso 1 1 calc R . .
C12 C 0.9578(3) 0.9685(3) 0.60098(13) 0.0842(19) Uani 1 1 d G . .
H12 H 0.9937 1.0063 0.6385 0.101 Uiso 1 1 calc R . .
C13 C 1.0149(2) 0.9089(3) 0.56566(19) 0.086(2) Uani 1 1 d G . .
H13 H 1.0890 0.9069 0.5796 0.103 Uiso 1 1 calc R . .
C14 C 0.9612(3) 0.8524(3) 0.50951(18) 0.0720(16) Uani 1 1 d G . .
H14 H 0.9994 0.8126 0.4859 0.086 Uiso 1 1 calc R . .
C15 C 0.8503(3) 0.8555(2) 0.48869(12) 0.0528(12) Uani 1 1 d G . .
C16 C 0.7983(5) 0.7989(4) 0.4256(2) 0.0714(16) Uani 1 1 d . . .
H16A H 0.8584 0.7819 0.4056 0.107 Uiso 1 1 calc R . .
H16B H 0.7683 0.8510 0.4076 0.107 Uiso 1 1 calc R . .
H16C H 0.7354 0.7282 0.4238 0.107 Uiso 1 1 calc R . .
C17 C 0.1761(4) 0.7374(4) 0.4010(2) 0.0490(11) Uani 1 1 d . . .
C18 C 0.0537(3) 0.6815(3) 0.36711(17) 0.0670(16) Uani 1 1 d G . .
C19 C 0.0260(4) 0.7230(4) 0.31835(18) 0.113(3) Uani 1 1 d G . .
H19 H 0.0817 0.7841 0.3082 0.136 Uiso 1 1 calc R . .
C20 C -0.0850(4) 0.6733(5) 0.28480(18) 0.150(4) Uani 1 1 d GU . .
H20 H -0.1035 0.7011 0.2522 0.180 Uiso 1 1 calc R . .
C21 C -0.1682(3) 0.5821(5) 0.3000(2) 0.151(4) Uani 1 1 d GU . .
H21 H -0.2425 0.5488 0.2776 0.181 Uiso 1 1 calc R . .
C22 C -0.1405(3) 0.5405(4) 0.3488(3) 0.134(4) Uani 1 1 d GU . .
H22 H -0.1962 0.4794 0.3589 0.161 Uiso 1 1 calc R . .
C23 C -0.0296(4) 0.5902(4) 0.3823(2) 0.096(2) Uani 1 1 d G . .
C24 C -0.0092(7) 0.5467(7) 0.4313(4) 0.116(3) Uani 1 1 d . . .
H24A H -0.0751 0.4799 0.4318 0.173 Uiso 1 1 calc R . .
H24B H 0.0007 0.6052 0.4652 0.173 Uiso 1 1 calc R . .
H24C H 0.0608 0.5249 0.4307 0.173 Uiso 1 1 calc R . .
N3 N 0.4606(2) 0.7036(2) 0.36834(10) 0.0459(9) Uani 1 1 d G . .
C25 C 0.4981(3) 0.7435(2) 0.31976(13) 0.0641(13) Uani 1 1 d G . .
H25 H 0.5017 0.8181 0.3156 0.077 Uiso 1 1 calc R . .
C26 C 0.5302(3) 0.6719(3) 0.27741(11) 0.0770(17) Uani 1 1 d G . .
H26 H 0.5552 0.6986 0.2449 0.092 Uiso 1 1 calc R . .
C27 C 0.5248(3) 0.5604(3) 0.28363(13) 0.0768(17) Uani 1 1 d G . .
H27 H 0.5462 0.5124 0.2553 0.092 Uiso 1 1 calc R . .
C28 C 0.4873(3) 0.52046(19) 0.33221(15) 0.0608(14) Uani 1 1 d GD . .
C29 C 0.4552(2) 0.5921(2) 0.37456(11) 0.0478(11) Uani 1 1 d G . .
C73 C 0.8509(8) 1.0063(8) 0.2403(5) 0.147(4) Uani 1 1 d . . .
H73A H 0.8172 1.0232 0.2052 0.177 Uiso 1 1 calc R . .
H73B H 0.8896 1.0792 0.2676 0.177 Uiso 1 1 calc R . .
C74 C 0.7536(8) 0.9283(8) 0.2662(4) 0.151(4) Uani 1 1 d . . .
H74A H 0.7126 0.8583 0.2382 0.227 Uiso 1 1 calc R . .
H74B H 0.6991 0.9684 0.2766 0.227 Uiso 1 1 calc R . .
H74C H 0.7878 0.9094 0.3000 0.227 Uiso 1 1 calc R . .
N4 N 0.3752(2) 0.62560(16) 0.46007(11) 0.0436(8) Uani 1 1 d G . .
C30 C 0.4123(2) 0.5525(2) 0.42079(11) 0.0457(10) Uani 1 1 d G . .
C31 C 0.3984(3) 0.4394(2) 0.42738(14) 0.0624(14) Uani 1 1 d GD . .
C34 C 0.3475(3) 0.39955(18) 0.47325(16) 0.0739(17) Uani 1 1 d G . .
H34 H 0.3382 0.3239 0.4777 0.089 Uiso 1 1 calc R . .
C35 C 0.3104(3) 0.4727(3) 0.51253(13) 0.0700(15) Uani 1 1 d G . .
H35 H 0.2763 0.4460 0.5432 0.084 Uiso 1 1 calc R . .
C36 C 0.3242(3) 0.5857(2) 0.50594(11) 0.0575(12) Uani 1 1 d G . .
H36 H 0.2994 0.6346 0.5322 0.069 Uiso 1 1 calc R . .
C32 C 0.4367(5) 0.3666(5) 0.3866(3) 0.086(2) Uani 1 1 d D . .
H32 H 0.4330 0.2924 0.3916 0.103 Uiso 1 1 calc R . .
C33 C 0.4796(5) 0.4065(4) 0.3392(3) 0.0812(19) Uani 1 1 d D . .
H33 H 0.5035 0.3585 0.3119 0.097 Uiso 1 1 calc R . .
C37 C 0.1682(4) 0.1769(4) 0.1779(2) 0.0497(11) Uani 1 1 d . . .
C38 C 0.1710(3) 0.2601(2) 0.23235(12) 0.0518(11) Uani 1 1 d G . .
C39 C 0.1383(3) 0.2132(2) 0.27996(15) 0.0713(15) Uani 1 1 d G . .
H39 H 0.1215 0.1340 0.2782 0.086 Uiso 1 1 calc R . .
C40 C 0.1309(4) 0.2849(4) 0.33017(12) 0.092(2) Uani 1 1 d G . .
H40 H 0.1091 0.2535 0.3620 0.110 Uiso 1 1 calc R . .
C41 C 0.1560(4) 0.4033(4) 0.33276(14) 0.091(2) Uani 1 1 d G . .
H41 H 0.1510 0.4513 0.3663 0.109 Uiso 1 1 calc R . .
C42 C 0.1886(3) 0.4502(2) 0.28515(18) 0.0828(19) Uani 1 1 d G . .
H42 H 0.2055 0.5295 0.2869 0.099 Uiso 1 1 calc R . .
C43 C 0.1961(3) 0.3786(3) 0.23494(14) 0.0616(13) Uani 1 1 d G . .
C44 C 0.2308(7) 0.4357(5) 0.1860(3) 0.099(2) Uani 1 1 d . . .
H44A H 0.2403 0.5169 0.1966 0.148 Uiso 1 1 calc R . .
H44B H 0.1706 0.4007 0.1527 0.148 Uiso 1 1 calc R . .
H44C H 0.3038 0.4264 0.1771 0.148 Uiso 1 1 calc R . .
C45 C -0.0924(4) 0.1508(4) 0.0441(2) 0.0434(10) Uani 1 1 d . . .
C46 C -0.0940(3) 0.2576(2) 0.08322(12) 0.0457(10) Uani 1 1 d G . .
C47 C -0.0824(3) 0.2601(3) 0.14233(13) 0.0638(14) Uani 1 1 d G . .
H47 H -0.0734 0.1966 0.1563 0.077 Uiso 1 1 calc R . .
C48 C -0.0843(3) 0.3576(4) 0.18055(11) 0.087(2) Uani 1 1 d G . .
H48 H -0.0765 0.3593 0.2201 0.105 Uiso 1 1 calc R . .
C49 C -0.0977(4) 0.4526(3) 0.15967(17) 0.101(2) Uani 1 1 d G . .
H49 H -0.0990 0.5179 0.1852 0.121 Uiso 1 1 calc R . .
C50 C -0.1093(4) 0.4501(2) 0.10056(19) 0.090(2) Uani 1 1 d G . .
H50 H -0.1183 0.5137 0.0866 0.108 Uiso 1 1 calc R . .
C51 C -0.1075(3) 0.3526(3) 0.06233(12) 0.0606(13) Uani 1 1 d G . .
C52 C -0.1222(7) 0.3549(5) -0.0015(3) 0.090(2) Uani 1 1 d . . .
H52A H -0.1983 0.3029 -0.0201 0.135 Uiso 1 1 calc R . .
H52B H -0.0621 0.3309 -0.0185 0.135 Uiso 1 1 calc R . .
H52C H -0.1154 0.4323 -0.0063 0.135 Uiso 1 1 calc R . .
C53 C 0.1357(4) 0.1769(4) -0.03993(19) 0.0432(10) Uani 1 1 d . . .
C54 C 0.2135(2) 0.2792(2) -0.06006(13) 0.0478(11) Uani 1 1 d G . .
C55 C 0.2196(3) 0.2671(3) -0.11884(12) 0.0615(13) Uani 1 1 d G . .
H55 H 0.1732 0.1993 -0.1444 0.074 Uiso 1 1 calc R . .
C56 C 0.2948(3) 0.3561(4) -0.13935(13) 0.0777(17) Uani 1 1 d G . .
H56 H 0.2989 0.3480 -0.1787 0.093 Uiso 1 1 calc R . .
C57 C 0.3641(3) 0.4574(3) -0.10108(19) 0.092(2) Uani 1 1 d G . .
H57 H 0.4144 0.5170 -0.1148 0.110 Uiso 1 1 calc R . .
C58 C 0.3580(3) 0.4696(2) -0.04230(18) 0.086(2) Uani 1 1 d G . .
H58 H 0.4044 0.5373 -0.0167 0.104 Uiso 1 1 calc R . .
C59 C 0.2828(3) 0.3805(3) -0.02179(12) 0.0646(14) Uani 1 1 d G . .
C60 C 0.2750(6) 0.4046(5) 0.0419(3) 0.094(2) Uani 1 1 d . . .
H60A H 0.3176 0.3640 0.0617 0.141 Uiso 1 1 calc R . .
H60B H 0.1939 0.3788 0.0470 0.141 Uiso 1 1 calc R . .
H60C H 0.3085 0.4865 0.0573 0.141 Uiso 1 1 calc R . .
N1 N 0.35756(18) 0.0726(2) 0.07485(13) 0.0490(9) Uani 1 1 d G . .
C61 C 0.4269(3) 0.1632(2) 0.05295(15) 0.0687(14) Uani 1 1 d G . .
H61 H 0.3950 0.2170 0.0408 0.082 Uiso 1 1 calc R . .
C62 C 0.5438(3) 0.1732(3) 0.04922(17) 0.089(2) Uani 1 1 d G . .
H62 H 0.5902 0.2338 0.0346 0.107 Uiso 1 1 calc R . .
C63 C 0.59142(19) 0.0928(4) 0.06741(17) 0.088(2) Uani 1 1 d G . .
H63 H 0.6697 0.0995 0.0649 0.106 Uiso 1 1 calc R . .
C64 C 0.5221(3) 0.0022(3) 0.08931(16) 0.0721(16) Uani 1 1 d GD . .
C65 C 0.4052(2) -0.0078(2) 0.09304(13) 0.0518(12) Uani 1 1 d G . .
C67 C 0.4963(6) -0.1715(7) 0.1280(4) 0.109(3) Uani 1 1 d D . .
H67 H 0.5252 -0.2291 0.1378 0.131 Uiso 1 1 calc R . .
C66 C 0.5665(6) -0.0830(7) 0.1058(3) 0.103(2) Uani 1 1 d D . .
H66 H 0.6433 -0.0798 0.1018 0.123 Uiso 1 1 calc R . .
N2 N 0.2232(2) -0.0935(2) 0.12366(12) 0.0498(9) Uani 1 1 d G . .
C68 C 0.3367(2) -0.0926(3) 0.11692(14) 0.0559(12) Uani 1 1 d G . .
C69 C 0.3802(3) -0.1749(3) 0.13603(18) 0.0806(18) Uani 1 1 d G . .
C70 C 0.3101(4) -0.2581(3) 0.1619(2) 0.108(3) Uani 1 1 d G . .
H70 H 0.3392 -0.3132 0.1747 0.130 Uiso 1 1 calc R . .
C71 C 0.1966(3) -0.2590(3) 0.16860(19) 0.102(2) Uani 1 1 d G . .
H71 H 0.1497 -0.3147 0.1859 0.123 Uiso 1 1 calc R . .
C72 C 0.1531(2) -0.1767(3) 0.14950(15) 0.0683(15) Uani 1 1 d G . .
H72 H 0.0772 -0.1773 0.1540 0.082 Uiso 1 1 calc R . .
Dy1 Dy 0.409524(16) 0.836245(14) 0.451870(8) 0.03448(6) Uani 1 1 d . . .
Dy2 Dy 0.133343(15) 0.031429(15) 0.070313(8) 0.03651(6) Uani 1 1 d . . .
O1 O 0.2547(3) 0.7801(3) 0.37243(14) 0.0582(8) Uani 1 1 d . . .
O2 O 0.2002(3) 0.7435(3) 0.45417(16) 0.0574(8) Uani 1 1 d . . .
O3 O 0.4173(3) 0.8503(2) 0.55134(12) 0.0479(7) Uani 1 1 d . . .
O4 O 0.6447(3) 1.0040(3) 0.52191(15) 0.0580(8) Uani 1 1 d . . .
O5 O 0.4945(3) 1.0330(2) 0.60154(13) 0.0485(7) Uani 1 1 d . . .
O6 O 0.5979(3) 0.8231(3) 0.47648(14) 0.0510(8) Uani 1 1 d . . .
O7 O 0.2288(3) 0.2088(3) 0.13977(15) 0.0617(9) Uani 1 1 d . . .
O8 O 0.1024(3) 0.0729(3) 0.17019(14) 0.0557(8) Uani 1 1 d . . .
O9 O -0.0170(3) 0.1047(3) 0.05836(17) 0.0645(9) Uani 1 1 d . . .
O10 O 0.1807(3) 0.1454(3) 0.00215(13) 0.0510(8) Uani 1 1 d . . .
O11 O 0.0334(2) 0.1294(2) -0.06718(13) 0.0490(7) Uani 1 1 d . . .
O12 O -0.1648(3) 0.1118(3) -0.00147(13) 0.0518(8) Uani 1 1 d . . .
O13 O 0.4814(15) 0.3355(13) 0.1716(8) 0.199(7) Uani 0.50 1 d P . .
O14 O 0.9335(6) 0.9489(5) 0.2278(3) 0.138(2) Uani 1 1 d . . .
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
C1 0.049(2) 0.036(2) 0.045(2) 0.0114(19) 0.015(2) 0.0150(19)
C2 0.084(4) 0.034(2) 0.046(3) 0.005(2) 0.024(3) 0.020(2)
C3 0.101(4) 0.049(3) 0.050(3) 0.009(2) 0.015(3) 0.021(3)
C4 0.178(8) 0.080(4) 0.049(4) 0.015(3) 0.026(4) 0.029(5)
C5 0.207(10) 0.084(5) 0.072(5) 0.021(4) 0.054(6) 0.018(6)
C6 0.154(8) 0.079(5) 0.128(7) 0.030(5) 0.093(6) 0.011(5)
C7 0.106(5) 0.057(3) 0.080(4) 0.014(3) 0.051(4) 0.007(3)
C8 0.108(5) 0.097(5) 0.077(4) 0.015(4) -0.007(4) 0.030(4)
C9 0.045(2) 0.037(2) 0.052(3) 0.0147(19) 0.018(2) 0.023(2)
C10 0.040(2) 0.029(2) 0.058(3) 0.0134(19) 0.012(2) 0.0132(17)
C11 0.060(3) 0.051(3) 0.062(3) 0.017(2) 0.008(2) 0.016(2)
C12 0.066(4) 0.082(4) 0.092(5) 0.033(4) -0.015(3) 0.007(3)
C13 0.045(3) 0.078(4) 0.144(6) 0.050(4) 0.006(4) 0.021(3)
C14 0.053(3) 0.056(3) 0.124(5) 0.031(3) 0.033(3) 0.029(3)
C15 0.048(3) 0.035(2) 0.086(4) 0.019(2) 0.027(2) 0.019(2)
C16 0.078(4) 0.053(3) 0.082(4) -0.002(3) 0.037(3) 0.020(3)
C17 0.043(2) 0.040(2) 0.062(3) 0.000(2) 0.004(2) 0.015(2)
C18 0.041(3) 0.061(3) 0.086(4) -0.025(3) 0.004(3) 0.020(2)
C19 0.080(4) 0.152(7) 0.093(5) -0.062(5) -0.045(4) 0.082(5)
C20 0.095(5) 0.209(9) 0.120(5) -0.070(6) -0.013(5) 0.077(5)
C21 0.081(5) 0.197(8) 0.134(6) -0.079(6) -0.003(5) 0.051(5)
C22 0.057(4) 0.125(6) 0.173(8) -0.083(6) 0.016(5) 0.019(4)
C23 0.070(4) 0.068(4) 0.136(7) -0.020(4) 0.032(4) 0.020(3)
C24 0.097(5) 0.092(5) 0.153(8) 0.007(5) 0.041(5) 0.028(4)
N3 0.046(2) 0.042(2) 0.047(2) 0.0000(16) 0.0052(17) 0.0155(16)
C25 0.070(3) 0.062(3) 0.061(3) 0.007(3) 0.018(3) 0.023(3)
C26 0.077(4) 0.095(5) 0.055(3) -0.002(3) 0.026(3) 0.026(3)
C27 0.067(3) 0.075(4) 0.079(4) -0.022(3) 0.012(3) 0.028(3)
C28 0.048(3) 0.053(3) 0.072(4) -0.016(3) 0.004(2) 0.020(2)
C29 0.039(2) 0.034(2) 0.061(3) -0.010(2) -0.004(2) 0.0122(18)
C73 0.109(7) 0.106(7) 0.231(12) 0.037(7) 0.041(7) 0.036(6)
C74 0.129(8) 0.135(8) 0.181(10) 0.032(7) 0.064(7) 0.016(7)
N4 0.043(2) 0.0279(17) 0.057(2) 0.0021(16) 0.0060(17) 0.0111(15)
C30 0.044(2) 0.030(2) 0.058(3) 0.001(2) 0.000(2) 0.0121(18)
C31 0.059(3) 0.031(2) 0.092(4) 0.003(2) -0.003(3) 0.017(2)
C34 0.069(3) 0.030(2) 0.116(5) 0.019(3) -0.002(3) 0.009(2)
C35 0.075(4) 0.043(3) 0.092(4) 0.029(3) 0.011(3) 0.012(3)
C36 0.061(3) 0.040(3) 0.074(3) 0.021(2) 0.014(3) 0.014(2)
C32 0.088(4) 0.038(3) 0.125(6) -0.008(3) -0.004(4) 0.032(3)
C33 0.076(4) 0.054(3) 0.107(5) -0.023(3) 0.009(4) 0.035(3)
C37 0.046(3) 0.049(3) 0.052(3) 0.006(2) 0.003(2) 0.017(2)
C38 0.045(3) 0.053(3) 0.052(3) -0.004(2) 0.000(2) 0.018(2)
C39 0.077(4) 0.075(4) 0.055(3) 0.001(3) 0.008(3) 0.021(3)
C40 0.098(5) 0.110(5) 0.058(4) -0.007(4) 0.021(3) 0.030(4)
C41 0.082(4) 0.104(5) 0.076(4) -0.026(4) 0.001(3) 0.041(4)
C42 0.068(4) 0.062(4) 0.100(5) -0.024(3) -0.011(3) 0.024(3)
C43 0.054(3) 0.051(3) 0.071(3) -0.003(3) -0.001(2) 0.017(2)
C44 0.129(6) 0.053(3) 0.109(5) 0.013(4) 0.020(5) 0.023(4)
C45 0.041(2) 0.040(2) 0.057(3) 0.013(2) 0.018(2) 0.0180(19)
C46 0.036(2) 0.052(3) 0.050(3) 0.001(2) 0.0070(19) 0.020(2)
C47 0.055(3) 0.080(4) 0.058(3) 0.006(3) 0.012(2) 0.028(3)
C48 0.071(4) 0.124(6) 0.056(3) -0.011(4) 0.012(3) 0.030(4)
C49 0.090(5) 0.094(5) 0.104(6) -0.038(4) 0.013(4) 0.040(4)
C50 0.099(5) 0.055(3) 0.116(6) -0.009(3) 0.009(4) 0.042(3)
C51 0.061(3) 0.049(3) 0.071(3) -0.001(2) 0.003(3) 0.027(2)
C52 0.127(6) 0.057(3) 0.094(5) 0.024(3) 0.006(4) 0.040(4)
C53 0.038(2) 0.043(2) 0.053(3) 0.010(2) 0.012(2) 0.0180(19)
C54 0.036(2) 0.053(3) 0.060(3) 0.022(2) 0.008(2) 0.018(2)
C55 0.057(3) 0.075(3) 0.065(3) 0.029(3) 0.019(3) 0.029(3)
C56 0.073(4) 0.102(5) 0.083(4) 0.048(4) 0.033(3) 0.042(4)
C57 0.065(4) 0.088(5) 0.132(6) 0.064(5) 0.022(4) 0.013(3)
C58 0.070(4) 0.064(4) 0.115(5) 0.044(4) -0.005(4) 0.000(3)
C59 0.058(3) 0.052(3) 0.078(4) 0.022(3) -0.002(3) 0.008(2)
C60 0.123(6) 0.060(4) 0.081(4) 0.014(3) -0.009(4) 0.010(4)
N1 0.0381(19) 0.051(2) 0.055(2) 0.0022(18) 0.0014(17) 0.0164(17)
C61 0.050(3) 0.066(3) 0.085(4) 0.015(3) 0.012(3) 0.011(3)
C62 0.046(3) 0.102(5) 0.105(5) 0.019(4) 0.016(3) 0.003(3)
C63 0.037(3) 0.125(6) 0.091(5) -0.001(4) 0.011(3) 0.020(3)
C64 0.041(3) 0.099(4) 0.074(4) 0.000(3) -0.002(3) 0.031(3)
C65 0.038(2) 0.065(3) 0.049(3) -0.004(2) -0.001(2) 0.022(2)
C67 0.089(5) 0.126(6) 0.138(7) 0.039(5) -0.004(5) 0.076(5)
C66 0.060(4) 0.141(7) 0.122(6) 0.019(5) 0.001(4) 0.064(5)
N2 0.050(2) 0.053(2) 0.050(2) 0.0124(18) 0.0027(17) 0.0228(18)
C68 0.052(3) 0.058(3) 0.058(3) 0.005(2) -0.008(2) 0.027(2)
C69 0.081(4) 0.082(4) 0.091(4) 0.023(3) -0.012(3) 0.050(4)
C70 0.102(5) 0.093(5) 0.147(7) 0.060(5) -0.016(5) 0.049(4)
C71 0.093(5) 0.099(5) 0.126(6) 0.069(5) -0.003(4) 0.029(4)
C72 0.067(3) 0.069(3) 0.073(4) 0.034(3) 0.001(3) 0.021(3)
Dy1 0.03882(11) 0.02497(10) 0.04062(12) 0.00496(8) 0.00727(8) 0.01230(8)
Dy2 0.03420(11) 0.03382(11) 0.04303(12) 0.00677(8) 0.00507(8) 0.01411(8)
O1 0.0481(18) 0.069(2) 0.0526(19) 0.0055(16) 0.0047(16) 0.0166(16)
O2 0.0470(18) 0.060(2) 0.069(2) 0.0226(17) 0.0131(16) 0.0176(16)
O3 0.0625(19) 0.0344(15) 0.0416(17) 0.0037(13) 0.0083(14) 0.0100(14)
O4 0.071(2) 0.0448(17) 0.076(2) 0.0173(16) 0.0282(18) 0.0375(16)
O5 0.0644(19) 0.0308(15) 0.0490(18) 0.0087(13) 0.0144(15) 0.0112(14)
O6 0.0404(16) 0.0445(17) 0.066(2) 0.0080(15) 0.0042(15) 0.0139(14)
O7 0.056(2) 0.0540(19) 0.062(2) -0.0032(16) 0.0177(17) 0.0044(16)
O8 0.070(2) 0.0420(18) 0.0543(19) 0.0074(15) 0.0173(16) 0.0163(16)
O9 0.054(2) 0.060(2) 0.098(3) 0.0255(19) 0.0187(18) 0.0371(17)
O10 0.0462(17) 0.0508(18) 0.0563(19) 0.0206(15) 0.0042(15) 0.0123(14)
O11 0.0410(17) 0.0444(17) 0.061(2) 0.0147(15) 0.0059(14) 0.0116(14)
O12 0.0531(18) 0.0483(18) 0.0517(19) -0.0031(15) 0.0084(15) 0.0199(15)
O13 0.204(15) 0.133(11) 0.225(17) -0.001(11) 0.036(13) 0.023(11)
O14 0.137(5) 0.117(4) 0.155(5) 0.015(4) 0.049(4) 0.033(4)
_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O5 1.254(5) . ?
C1 O3 1.261(5) . ?
C1 C2 1.499(5) . ?
C2 C3 1.3900 . ?
C2 C7 1.3900 . ?
C3 C4 1.3900 . ?
C3 C8 1.482(8) . ?
C4 C5 1.3900 . ?
C5 C6 1.3900 . ?
C6 C7 1.3900 . ?
C9 O6 1.247(5) . ?
C9 O4 1.254(5) . ?
C9 C10 1.486(5) . ?
C10 C11 1.3900 . ?
C10 C15 1.3900 . ?
C11 C12 1.3900 . ?
C12 C13 1.3900 . ?
C13 C14 1.3900 . ?
C14 C15 1.3900 . ?
C15 C16 1.527(6) . ?
C17 O2 1.250(6) . ?
C17 O1 1.258(6) . ?
C17 C18 1.506(5) . ?
C17 Dy1 2.763(4) . ?
C18 C19 1.3900 . ?
C18 C23 1.3900 . ?
C19 C20 1.3900 . ?
C20 C21 1.3900 . ?
C21 C22 1.3900 . ?
C22 C23 1.3900 . ?
C23 C24 1.387(9) . ?
N3 C25 1.3900 . ?
N3 C29 1.3900 . ?
N3 Dy1 2.6022(19) . ?
C25 C26 1.3900 . ?
C26 C27 1.3900 . ?
C27 C28 1.3900 . ?
C28 C29 1.3900 . ?
C28 C33 1.418(5) . ?
C29 C30 1.359(3) . ?
C73 O14 1.412(10) . ?
C73 C74 1.529(11) . ?
N4 C30 1.3900 . ?
N4 C36 1.3900 . ?
N4 Dy1 2.5483(18) . ?
C30 C31 1.3900 . ?
C31 C34 1.3900 . ?
C31 C32 1.418(6) . ?
C34 C35 1.3900 . ?
C35 C36 1.3900 . ?
C32 C33 1.385(7) . ?
C37 O7 1.259(5) . ?
C37 O8 1.261(5) . ?
C37 C38 1.503(5) . ?
C37 Dy2 2.784(5) . ?
C38 C39 1.3900 . ?
C38 C43 1.3900 . ?
C39 C40 1.3900 . ?
C40 C41 1.3900 . ?
C41 C42 1.3900 . ?
C42 C43 1.3900 . ?
C43 C44 1.485(7) . ?
C45 O12 1.244(5) . ?
C45 O9 1.256(5) . ?
C45 C46 1.489(5) . ?
C46 C47 1.3900 . ?
C46 C51 1.3900 . ?
C47 C48 1.3900 . ?
C48 C49 1.3900 . ?
C49 C50 1.3900 . ?
C50 C51 1.3900 . ?
C51 C52 1.513(7) . ?
C53 O11 1.251(5) . ?
C53 O10 1.259(5) . ?
C53 C54 1.509(5) . ?
C54 C55 1.3900 . ?
C54 C59 1.3900 . ?
C55 C56 1.3900 . ?
C56 C57 1.3900 . ?
C57 C58 1.3900 . ?
C58 C59 1.3900 . ?
C59 C60 1.509(7) . ?
N1 C61 1.3900 . ?
N1 C65 1.3900 . ?
N1 Dy2 2.582(2) . ?
C61 C62 1.3900 . ?
C62 C63 1.3900 . ?
C63 C64 1.3900 . ?
C64 C65 1.3900 . ?
C64 C66 1.405(6) . ?
C65 C68 1.366(4) . ?
C67 C66 1.382(7) . ?
C67 C69 1.420(7) . ?
N2 C68 1.3900 . ?
N2 C72 1.3900 . ?
N2 Dy2 2.552(2) . ?
C68 C69 1.3900 . ?
C69 C70 1.3900 . ?
C70 C71 1.3900 . ?
C71 C72 1.3900 . ?
Dy1 O4 2.270(3) 2_676 ?
Dy1 O5 2.321(3) 2_676 ?
Dy1 O3 2.329(3) . ?
Dy1 O6 2.346(3) . ?
Dy1 O1 2.368(3) . ?
Dy1 O2 2.447(3) . ?
Dy2 O9 2.267(3) . ?
Dy2 O10 2.317(3) . ?
Dy2 O11 2.346(3) 2 ?
Dy2 O12 2.348(3) 2 ?
Dy2 O7 2.399(3) . ?
Dy2 O8 2.432(3) . ?
O4 Dy1 2.270(3) 2_676 ?
O5 Dy1 2.321(3) 2_676 ?
O11 Dy2 2.346(3) 2 ?
O12 Dy2 2.348(3) 2 ?
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 C1 O3 125.6(4) . . ?
O5 C1 C2 118.3(4) . . ?
O3 C1 C2 116.0(3) . . ?
C3 C2 C7 120.0 . . ?
C3 C2 C1 122.3(3) . . ?
C7 C2 C1 117.7(3) . . ?
C4 C3 C2 120.0 . . ?
C4 C3 C8 117.7(4) . . ?
C2 C3 C8 122.3(4) . . ?
C3 C4 C5 120.0 . . ?
C6 C5 C4 120.0 . . ?
C7 C6 C5 120.0 . . ?
C6 C7 C2 120.0 . . ?
O6 C9 O4 122.2(4) . . ?
O6 C9 C10 118.8(3) . . ?
O4 C9 C10 119.0(4) . . ?
C11 C10 C15 120.0 . . ?
C11 C10 C9 117.3(3) . . ?
C15 C10 C9 122.6(3) . . ?
C12 C11 C10 120.0 . . ?
C11 C12 C13 120.0 . . ?
C14 C13 C12 120.0 . . ?
C13 C14 C15 120.0 . . ?
C14 C15 C10 120.0 . . ?
C14 C15 C16 118.1(3) . . ?
C10 C15 C16 121.8(3) . . ?
O2 C17 O1 121.0(4) . . ?
O2 C17 C18 123.5(4) . . ?
O1 C17 C18 115.5(4) . . ?
O2 C17 Dy1 62.3(2) . . ?
O1 C17 Dy1 58.7(2) . . ?
C18 C17 Dy1 173.7(3) . . ?
C19 C18 C23 120.0 . . ?
C19 C18 C17 117.5(3) . . ?
C23 C18 C17 122.5(3) . . ?
C20 C19 C18 120.0 . . ?
C19 C20 C21 120.0 . . ?
C22 C21 C20 120.0 . . ?
C21 C22 C23 120.0 . . ?
C24 C23 C22 116.9(5) . . ?
C24 C23 C18 123.1(5) . . ?
C22 C23 C18 120.0 . . ?
C25 N3 C29 120.0 . . ?
C25 N3 Dy1 121.70(14) . . ?
C29 N3 Dy1 118.22(14) . . ?
C26 C25 N3 120.0 . . ?
C25 C26 C27 120.0 . . ?
C28 C27 C26 120.0 . . ?
C27 C28 C29 120.0 . . ?
C27 C28 C33 121.1(3) . . ?
C29 C28 C33 118.9(3) . . ?
C30 C29 C28 120.8(2) . . ?
C30 C29 N3 119.1(2) . . ?
C28 C29 N3 120.0 . . ?
O14 C73 C74 109.0(8) . . ?
C30 N4 C36 120.0 . . ?
C30 N4 Dy1 120.50(13) . . ?
C36 N4 Dy1 119.42(13) . . ?
C29 C30 C31 121.5(2) . . ?
C29 C30 N4 118.4(2) . . ?
C31 C30 N4 120.0 . . ?
C30 C31 C34 120.0 . . ?
C30 C31 C32 118.8(3) . . ?
C34 C31 C32 121.2(3) . . ?
C35 C34 C31 120.0 . . ?
C36 C35 C34 120.0 . . ?
C35 C36 N4 120.0 . . ?
C33 C32 C31 119.7(5) . . ?
C32 C33 C28 120.1(5) . . ?
O7 C37 O8 119.4(4) . . ?
O7 C37 C38 121.7(4) . . ?
O8 C37 C38 118.9(4) . . ?
O7 C37 Dy2 59.3(2) . . ?
O8 C37 Dy2 60.8(2) . . ?
C38 C37 Dy2 171.1(3) . . ?
C39 C38 C43 120.0 . . ?
C39 C38 C37 117.3(3) . . ?
C43 C38 C37 122.5(3) . . ?
C40 C39 C38 120.0 . . ?
C39 C40 C41 120.0 . . ?
C42 C41 C40 120.0 . . ?
C41 C42 C43 120.0 . . ?
C42 C43 C38 120.0 . . ?
C42 C43 C44 116.5(3) . . ?
C38 C43 C44 123.5(3) . . ?
O12 C45 O9 122.9(4) . . ?
O12 C45 C46 118.9(4) . . ?
O9 C45 C46 118.3(4) . . ?
C47 C46 C51 120.0 . . ?
C47 C46 C45 117.9(3) . . ?
C51 C46 C45 122.1(3) . . ?
C48 C47 C46 120.0 . . ?
C47 C48 C49 120.0 . . ?
C50 C49 C48 120.0 . . ?
C49 C50 C51 120.0 . . ?
C50 C51 C46 120.0 . . ?
C50 C51 C52 117.3(3) . . ?
C46 C51 C52 122.6(3) . . ?
O11 C53 O10 125.8(4) . . ?
O11 C53 C54 117.3(4) . . ?
O10 C53 C54 116.9(4) . . ?
C55 C54 C59 120.0 . . ?
C55 C54 C53 117.6(3) . . ?
C59 C54 C53 122.3(3) . . ?
C54 C55 C56 120.0 . . ?
C57 C56 C55 120.0 . . ?
C56 C57 C58 120.0 . . ?
C57 C58 C59 120.0 . . ?
C58 C59 C54 120.0 . . ?
C58 C59 C60 116.4(3) . . ?
C54 C59 C60 123.4(3) . . ?
C61 N1 C65 120.0 . . ?
C61 N1 Dy2 121.80(14) . . ?
C65 N1 Dy2 117.67(14) . . ?
C62 C61 N1 120.0 . . ?
C61 C62 C63 120.0 . . ?
C64 C63 C62 120.0 . . ?
C65 C64 C63 120.0 . . ?
C65 C64 C66 118.7(4) . . ?
C63 C64 C66 121.2(4) . . ?
C68 C65 C64 121.2(2) . . ?
C68 C65 N1 118.7(2) . . ?
C64 C65 N1 120.0 . . ?
C66 C67 C69 120.2(6) . . ?
C67 C66 C64 120.2(5) . . ?
C68 N2 C72 120.0 . . ?
C68 N2 Dy2 118.47(15) . . ?
C72 N2 Dy2 120.39(15) . . ?
C65 C68 C69 121.0(2) . . ?
C65 C68 N2 118.9(2) . . ?
C69 C68 N2 120.0 . . ?
C68 C69 C70 120.0 . . ?
C68 C69 C67 118.3(4) . . ?
C70 C69 C67 121.7(4) . . ?
C71 C70 C69 120.0 . . ?
C70 C71 C72 120.0 . . ?
C71 C72 N2 120.0 . . ?
O4 Dy1 O5 75.10(11) 2_676 2_676 ?
O4 Dy1 O3 78.02(11) 2_676 . ?
O5 Dy1 O3 131.18(10) 2_676 . ?
O4 Dy1 O6 125.46(12) 2_676 . ?
O5 Dy1 O6 83.53(11) 2_676 . ?
O3 Dy1 O6 79.96(11) . . ?
O4 Dy1 O1 86.58(12) 2_676 . ?
O5 Dy1 O1 83.80(11) 2_676 . ?
O3 Dy1 O1 134.24(11) . . ?
O6 Dy1 O1 140.52(11) . . ?
O4 Dy1 O2 80.10(12) 2_676 . ?
O5 Dy1 O2 131.88(11) 2_676 . ?
O3 Dy1 O2 80.95(11) . . ?
O6 Dy1 O2 143.30(11) . . ?
O1 Dy1 O2 53.87(11) . . ?
O4 Dy1 N4 145.24(10) 2_676 . ?
O5 Dy1 N4 139.21(9) 2_676 . ?
O3 Dy1 N4 78.73(9) . . ?
O6 Dy1 N4 74.70(9) . . ?
O1 Dy1 N4 91.49(10) . . ?
O2 Dy1 N4 71.00(10) . . ?
O4 Dy1 N3 146.18(10) 2_676 . ?
O5 Dy1 N3 77.11(9) 2_676 . ?
O3 Dy1 N3 135.60(9) . . ?
O6 Dy1 N3 69.22(10) . . ?
O1 Dy1 N3 71.55(10) . . ?
O2 Dy1 N3 105.26(10) . . ?
N4 Dy1 N3 63.09(8) . . ?
O4 Dy1 C17 83.42(13) 2_676 . ?
O5 Dy1 C17 108.73(14) 2_676 . ?
O3 Dy1 C17 107.72(14) . . ?
O6 Dy1 C17 151.06(12) . . ?
O1 Dy1 C17 27.00(13) . . ?
O2 Dy1 C17 26.89(12) . . ?
N4 Dy1 C17 79.48(11) . . ?
N3 Dy1 C17 87.63(11) . . ?
O9 Dy2 O10 75.31(12) . . ?
O9 Dy2 O11 77.15(11) . 2 ?
O10 Dy2 O11 129.49(10) . 2 ?
O9 Dy2 O12 124.39(12) . 2 ?
O10 Dy2 O12 83.86(11) . 2 ?
O11 Dy2 O12 77.99(11) 2 2 ?
O9 Dy2 O7 84.82(13) . . ?
O10 Dy2 O7 84.86(11) . . ?
O11 Dy2 O7 133.39(11) 2 . ?
O12 Dy2 O7 144.26(11) 2 . ?
O9 Dy2 O8 80.22(12) . . ?
O10 Dy2 O8 133.31(11) . . ?
O11 Dy2 O8 80.98(11) 2 . ?
O12 Dy2 O8 142.04(11) 2 . ?
O7 Dy2 O8 53.54(11) . . ?
O9 Dy2 N2 146.78(11) . . ?
O10 Dy2 N2 137.88(10) . . ?
O11 Dy2 N2 78.85(9) 2 . ?
O12 Dy2 N2 71.57(10) 2 . ?
O7 Dy2 N2 95.42(11) . . ?
O8 Dy2 N2 73.59(10) . . ?
O9 Dy2 N1 145.36(11) . . ?
O10 Dy2 N1 76.49(10) . . ?
O11 Dy2 N1 137.21(9) 2 . ?
O12 Dy2 N1 71.45(10) 2 . ?
O7 Dy2 N1 72.96(10) . . ?
O8 Dy2 N1 105.64(10) . . ?
N2 Dy2 N1 63.62(9) . . ?
O9 Dy2 C37 79.26(13) . . ?
O10 Dy2 C37 108.48(13) . . ?
O11 Dy2 C37 106.84(13) 2 . ?
O12 Dy2 C37 156.03(12) 2 . ?
O7 Dy2 C37 26.82(12) . . ?
O8 Dy2 C37 26.92(12) . . ?
N2 Dy2 C37 86.14(12) . . ?
N1 Dy2 C37 91.08(11) . . ?
C17 O1 Dy1 94.3(3) . . ?
C17 O2 Dy1 90.8(3) . . ?
C1 O3 Dy1 140.1(3) . . ?
C9 O4 Dy1 177.7(3) . 2_676 ?
C1 O5 Dy1 140.3(3) . 2_676 ?
C9 O6 Dy1 114.5(3) . . ?
C37 O7 Dy2 93.9(3) . . ?
C37 O8 Dy2 92.3(3) . . ?
C45 O9 Dy2 169.7(3) . . ?
C53 O10 Dy2 142.6(3) . . ?
C53 O11 Dy2 139.9(3) . 2 ?
C45 O12 Dy2 117.2(3) . 2 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O5 C1 C2 C3 -53.6(5) . . . . ?
O3 C1 C2 C3 129.1(4) . . . . ?
O5 C1 C2 C7 125.3(4) . . . . ?
O3 C1 C2 C7 -52.0(4) . . . . ?
C7 C2 C3 C4 0.0 . . . . ?
C1 C2 C3 C4 178.8(3) . . . . ?
C7 C2 C3 C8 178.6(5) . . . . ?
C1 C2 C3 C8 -2.5(5) . . . . ?
C2 C3 C4 C5 0.0 . . . . ?
C8 C3 C4 C5 -178.7(4) . . . . ?
C3 C4 C5 C6 0.0 . . . . ?
C4 C5 C6 C7 0.0 . . . . ?
C5 C6 C7 C2 0.0 . . . . ?
C3 C2 C7 C6 0.0 . . . . ?
C1 C2 C7 C6 -178.9(3) . . . . ?
O6 C9 C10 C11 -138.5(3) . . . . ?
O4 C9 C10 C11 39.6(5) . . . . ?
O6 C9 C10 C15 37.0(5) . . . . ?
O4 C9 C10 C15 -144.9(3) . . . . ?
C15 C10 C11 C12 0.0 . . . . ?
C9 C10 C11 C12 175.6(3) . . . . ?
C10 C11 C12 C13 0.0 . . . . ?
C11 C12 C13 C14 0.0 . . . . ?
C12 C13 C14 C15 0.0 . . . . ?
C13 C14 C15 C10 0.0 . . . . ?
C13 C14 C15 C16 176.1(3) . . . . ?
C11 C10 C15 C14 0.0 . . . . ?
C9 C10 C15 C14 -175.3(3) . . . . ?
C11 C10 C15 C16 -176.0(4) . . . . ?
C9 C10 C15 C16 8.7(4) . . . . ?
O2 C17 C18 C19 151.3(4) . . . . ?
O1 C17 C18 C19 -27.7(5) . . . . ?
Dy1 C17 C18 C19 -50(3) . . . . ?
O2 C17 C18 C23 -29.9(5) . . . . ?
O1 C17 C18 C23 151.0(3) . . . . ?
Dy1 C17 C18 C23 129(3) . . . . ?
C23 C18 C19 C20 0.0 . . . . ?
C17 C18 C19 C20 178.8(3) . . . . ?
C18 C19 C20 C21 0.0 . . . . ?
C19 C20 C21 C22 0.0 . . . . ?
C20 C21 C22 C23 0.0 . . . . ?
C21 C22 C23 C24 178.2(5) . . . . ?
C21 C22 C23 C18 0.0 . . . . ?
C19 C18 C23 C24 -178.0(6) . . . . ?
C17 C18 C23 C24 3.2(6) . . . . ?
C19 C18 C23 C22 0.0 . . . . ?
C17 C18 C23 C22 -178.8(4) . . . . ?
C29 N3 C25 C26 0.0 . . . . ?
Dy1 N3 C25 C26 176.78(18) . . . . ?
N3 C25 C26 C27 0.0 . . . . ?
C25 C26 C27 C28 0.0 . . . . ?
C26 C27 C28 C29 0.0 . . . . ?
C26 C27 C28 C33 179.2(4) . . . . ?
C27 C28 C29 C30 176.4(3) . . . . ?
C33 C28 C29 C30 -2.8(4) . . . . ?
C27 C28 C29 N3 0.0 . . . . ?
C33 C28 C29 N3 -179.2(4) . . . . ?
C25 N3 C29 C30 -176.5(3) . . . . ?
Dy1 N3 C29 C30 6.6(3) . . . . ?
C25 N3 C29 C28 0.0 . . . . ?
Dy1 N3 C29 C28 -176.89(17) . . . . ?
C28 C29 C30 C31 -0.3(3) . . . . ?
N3 C29 C30 C31 176.16(17) . . . . ?
C28 C29 C30 N4 -176.33(17) . . . . ?
N3 C29 C30 N4 0.1(3) . . . . ?
C36 N4 C30 C29 176.1(3) . . . . ?
Dy1 N4 C30 C29 -7.1(3) . . . . ?
C36 N4 C30 C31 0.0 . . . . ?
Dy1 N4 C30 C31 176.77(18) . . . . ?
C29 C30 C31 C34 -176.0(3) . . . . ?
N4 C30 C31 C34 0.0 . . . . ?
C29 C30 C31 C32 3.8(4) . . . . ?
N4 C30 C31 C32 179.8(4) . . . . ?
C30 C31 C34 C35 0.0 . . . . ?
C32 C31 C34 C35 -179.8(4) . . . . ?
C31 C34 C35 C36 0.0 . . . . ?
C34 C35 C36 N4 0.0 . . . . ?
C30 N4 C36 C35 0.0 . . . . ?
Dy1 N4 C36 C35 -176.81(17) . . . . ?
C30 C31 C32 C33 -4.2(7) . . . . ?
C34 C31 C32 C33 175.6(4) . . . . ?
C31 C32 C33 C28 1.2(8) . . . . ?
C27 C28 C33 C32 -176.9(4) . . . . ?
C29 C28 C33 C32 2.3(7) . . . . ?
O7 C37 C38 C39 -157.2(4) . . . . ?
O8 C37 C38 C39 23.6(5) . . . . ?
Dy2 C37 C38 C39 109(2) . . . . ?
O7 C37 C38 C43 27.5(6) . . . . ?
O8 C37 C38 C43 -151.6(3) . . . . ?
Dy2 C37 C38 C43 -66(2) . . . . ?
C43 C38 C39 C40 0.0 . . . . ?
C37 C38 C39 C40 -175.4(3) . . . . ?
C38 C39 C40 C41 0.0 . . . . ?
C39 C40 C41 C42 0.0 . . . . ?
C40 C41 C42 C43 0.0 . . . . ?
C41 C42 C43 C38 0.0 . . . . ?
C41 C42 C43 C44 179.6(4) . . . . ?
C39 C38 C43 C42 0.0 . . . . ?
C37 C38 C43 C42 175.1(3) . . . . ?
C39 C38 C43 C44 -179.6(5) . . . . ?
C37 C38 C43 C44 -4.5(5) . . . . ?
O12 C45 C46 C47 137.0(3) . . . . ?
O9 C45 C46 C47 -43.6(5) . . . . ?
O12 C45 C46 C51 -42.5(5) . . . . ?
O9 C45 C46 C51 136.9(3) . . . . ?
C51 C46 C47 C48 0.0 . . . . ?
C45 C46 C47 C48 -179.5(3) . . . . ?
C46 C47 C48 C49 0.0 . . . . ?
C47 C48 C49 C50 0.0 . . . . ?
C48 C49 C50 C51 0.0 . . . . ?
C49 C50 C51 C46 0.0 . . . . ?
C49 C50 C51 C52 179.2(4) . . . . ?
C47 C46 C51 C50 0.0 . . . . ?
C45 C46 C51 C50 179.5(3) . . . . ?
C47 C46 C51 C52 -179.2(4) . . . . ?
C45 C46 C51 C52 0.4(5) . . . . ?
O11 C53 C54 C55 -48.5(4) . . . . ?
O10 C53 C54 C55 130.1(3) . . . . ?
O11 C53 C54 C59 135.2(3) . . . . ?
O10 C53 C54 C59 -46.2(5) . . . . ?
C59 C54 C55 C56 0.0 . . . . ?
C53 C54 C55 C56 -176.4(3) . . . . ?
C54 C55 C56 C57 0.0 . . . . ?
C55 C56 C57 C58 0.0 . . . . ?
C56 C57 C58 C59 0.0 . . . . ?
C57 C58 C59 C54 0.0 . . . . ?
C57 C58 C59 C60 -175.5(4) . . . . ?
C55 C54 C59 C58 0.0 . . . . ?
C53 C54 C59 C58 176.2(3) . . . . ?
C55 C54 C59 C60 175.2(4) . . . . ?
C53 C54 C59 C60 -8.6(5) . . . . ?
C65 N1 C61 C62 0.0 . . . . ?
Dy2 N1 C61 C62 -171.48(19) . . . . ?
N1 C61 C62 C63 0.0 . . . . ?
C61 C62 C63 C64 0.0 . . . . ?
C62 C63 C64 C65 0.0 . . . . ?
C62 C63 C64 C66 177.4(5) . . . . ?
C63 C64 C65 C68 -176.8(3) . . . . ?
C66 C64 C65 C68 5.7(5) . . . . ?
C63 C64 C65 N1 0.0 . . . . ?
C66 C64 C65 N1 -177.4(5) . . . . ?
C61 N1 C65 C68 176.9(3) . . . . ?
Dy2 N1 C65 C68 -11.3(3) . . . . ?
C61 N1 C65 C64 0.0 . . . . ?
Dy2 N1 C65 C64 171.83(19) . . . . ?
C69 C67 C66 C64 -2.0(12) . . . . ?
C65 C64 C66 C67 -3.2(9) . . . . ?
C63 C64 C66 C67 179.4(6) . . . . ?
C64 C65 C68 C69 -2.9(3) . . . . ?
N1 C65 C68 C69 -179.7(2) . . . . ?
C64 C65 C68 N2 175.1(2) . . . . ?
N1 C65 C68 N2 -1.7(4) . . . . ?
C72 N2 C68 C65 -178.0(3) . . . . ?
Dy2 N2 C68 C65 14.2(3) . . . . ?
C72 N2 C68 C69 0.0 . . . . ?
Dy2 N2 C68 C69 -167.8(2) . . . . ?
C65 C68 C69 C70 178.0(3) . . . . ?
N2 C68 C69 C70 0.0 . . . . ?
C65 C68 C69 C67 -2.4(5) . . . . ?
N2 C68 C69 C67 179.6(5) . . . . ?
C66 C67 C69 C68 4.8(10) . . . . ?
C66 C67 C69 C70 -175.6(6) . . . . ?
C68 C69 C70 C71 0.0 . . . . ?
C67 C69 C70 C71 -179.6(5) . . . . ?
C69 C70 C71 C72 0.0 . . . . ?
C70 C71 C72 N2 0.0 . . . . ?
C68 N2 C72 C71 0.0 . . . . ?
Dy2 N2 C72 C71 167.6(2) . . . . ?
C30 N4 Dy1 O4 161.7(2) . . . 2_676 ?
C36 N4 Dy1 O4 -21.5(3) . . . 2_676 ?
C30 N4 Dy1 O5 -6.6(2) . . . 2_676 ?
C36 N4 Dy1 O5 170.16(17) . . . 2_676 ?
C30 N4 Dy1 O3 -149.46(17) . . . . ?
C36 N4 Dy1 O3 27.34(16) . . . . ?
C30 N4 Dy1 O6 -66.91(16) . . . . ?
C36 N4 Dy1 O6 109.88(16) . . . . ?
C30 N4 Dy1 O1 75.59(17) . . . . ?
C36 N4 Dy1 O1 -107.61(16) . . . . ?
C30 N4 Dy1 O2 126.34(18) . . . . ?
C36 N4 Dy1 O2 -56.87(16) . . . . ?
C30 N4 Dy1 N3 7.20(15) . . . . ?
C36 N4 Dy1 N3 -176.01(17) . . . . ?
C30 N4 Dy1 C17 99.90(18) . . . . ?
C36 N4 Dy1 C17 -83.31(18) . . . . ?
C25 N3 Dy1 O4 22.3(3) . . . 2_676 ?
C29 N3 Dy1 O4 -160.83(19) . . . 2_676 ?
C25 N3 Dy1 O5 -13.01(16) . . . 2_676 ?
C29 N3 Dy1 O5 163.82(17) . . . 2_676 ?
C25 N3 Dy1 O3 -150.05(17) . . . . ?
C29 N3 Dy1 O3 26.8(2) . . . . ?
C25 N3 Dy1 O6 -100.91(17) . . . . ?
C29 N3 Dy1 O6 75.92(16) . . . . ?
C25 N3 Dy1 O1 74.67(17) . . . . ?
C29 N3 Dy1 O1 -108.50(18) . . . . ?
C25 N3 Dy1 O2 117.33(16) . . . . ?
C29 N3 Dy1 O2 -65.84(17) . . . . ?
C25 N3 Dy1 N4 176.21(17) . . . . ?
C29 N3 Dy1 N4 -6.96(14) . . . . ?
C25 N3 Dy1 C17 96.81(18) . . . . ?
C29 N3 Dy1 C17 -86.36(18) . . . . ?
O2 C17 Dy1 O4 -81.1(3) . . . 2_676 ?
O1 C17 Dy1 O4 95.4(3) . . . 2_676 ?
C18 C17 Dy1 O4 119(3) . . . 2_676 ?
O2 C17 Dy1 O5 -152.9(2) . . . 2_676 ?
O1 C17 Dy1 O5 23.6(3) . . . 2_676 ?
C18 C17 Dy1 O5 47(3) . . . 2_676 ?
O2 C17 Dy1 O3 -5.9(3) . . . . ?
O1 C17 Dy1 O3 170.5(2) . . . . ?
C18 C17 Dy1 O3 -166(3) . . . . ?
O2 C17 Dy1 O6 95.6(3) . . . . ?
O1 C17 Dy1 O6 -87.9(4) . . . . ?
C18 C17 Dy1 O6 -65(3) . . . . ?
O2 C17 Dy1 O1 -176.5(4) . . . . ?
C18 C17 Dy1 O1 23(3) . . . . ?
O1 C17 Dy1 O2 176.5(4) . . . . ?
C18 C17 Dy1 O2 -160(3) . . . . ?
O2 C17 Dy1 N4 68.5(3) . . . . ?
O1 C17 Dy1 N4 -115.0(3) . . . . ?
C18 C17 Dy1 N4 -92(3) . . . . ?
O2 C17 Dy1 N3 131.6(3) . . . . ?
O1 C17 Dy1 N3 -51.9(3) . . . . ?
C18 C17 Dy1 N3 -29(3) . . . . ?
C68 N2 Dy2 O9 -170.3(2) . . . . ?
C72 N2 Dy2 O9 21.9(3) . . . . ?
C68 N2 Dy2 O10 6.8(2) . . . . ?
C72 N2 Dy2 O10 -161.0(2) . . . . ?
C68 N2 Dy2 O11 145.27(19) . . . 2 ?
C72 N2 Dy2 O11 -22.52(19) . . . 2 ?
C68 N2 Dy2 O12 64.35(18) . . . 2 ?
C72 N2 Dy2 O12 -103.4(2) . . . 2 ?
C68 N2 Dy2 O7 -81.52(18) . . . . ?
C72 N2 Dy2 O7 110.69(19) . . . . ?
C68 N2 Dy2 O8 -130.96(19) . . . . ?
C72 N2 Dy2 O8 61.25(19) . . . . ?
C68 N2 Dy2 N1 -13.58(17) . . . . ?
C72 N2 Dy2 N1 178.6(2) . . . . ?
C68 N2 Dy2 C37 -106.71(19) . . . . ?
C72 N2 Dy2 C37 85.5(2) . . . . ?
C61 N1 Dy2 O9 -18.1(3) . . . . ?
C65 N1 Dy2 O9 170.3(2) . . . . ?
C61 N1 Dy2 O10 18.20(17) . . . . ?
C65 N1 Dy2 O10 -153.47(18) . . . . ?
C61 N1 Dy2 O11 152.90(18) . . . 2 ?
C65 N1 Dy2 O11 -18.8(2) . . . 2 ?
C61 N1 Dy2 O12 106.17(18) . . . 2 ?
C65 N1 Dy2 O12 -65.50(17) . . . 2 ?
C61 N1 Dy2 O7 -70.50(18) . . . . ?
C65 N1 Dy2 O7 117.83(19) . . . . ?
C61 N1 Dy2 O8 -113.50(17) . . . . ?
C65 N1 Dy2 O8 74.82(17) . . . . ?
C61 N1 Dy2 N2 -175.70(19) . . . . ?
C65 N1 Dy2 N2 12.62(16) . . . . ?
C61 N1 Dy2 C37 -90.55(19) . . . . ?
C65 N1 Dy2 C37 97.77(18) . . . . ?
O7 C37 Dy2 O9 -99.9(3) . . . . ?
O8 C37 Dy2 O9 89.5(3) . . . . ?
C38 C37 Dy2 O9 -1(2) . . . . ?
O7 C37 Dy2 O10 -29.5(3) . . . . ?
O8 C37 Dy2 O10 159.9(3) . . . . ?
C38 C37 Dy2 O10 69(2) . . . . ?
O7 C37 Dy2 O11 -172.8(3) . . . 2 ?
O8 C37 Dy2 O11 16.6(3) . . . 2 ?
C38 C37 Dy2 O11 -74(2) . . . 2 ?
O7 C37 Dy2 O12 88.8(4) . . . 2 ?
O8 C37 Dy2 O12 -81.8(4) . . . 2 ?
C38 C37 Dy2 O12 -172.5(19) . . . 2 ?
O8 C37 Dy2 O7 -170.6(5) . . . . ?
C38 C37 Dy2 O7 99(2) . . . . ?
O7 C37 Dy2 O8 170.6(5) . . . . ?
C38 C37 Dy2 O8 -91(2) . . . . ?
O7 C37 Dy2 N2 110.1(3) . . . . ?
O8 C37 Dy2 N2 -60.5(3) . . . . ?
C38 C37 Dy2 N2 -151(2) . . . . ?
O7 C37 Dy2 N1 46.6(3) . . . . ?
O8 C37 Dy2 N1 -124.0(3) . . . . ?
C38 C37 Dy2 N1 145(2) . . . . ?
O2 C17 O1 Dy1 3.7(5) . . . . ?
C18 C17 O1 Dy1 -177.3(3) . . . . ?
O4 Dy1 O1 C17 -82.2(3) 2_676 . . . ?
O5 Dy1 O1 C17 -157.6(3) 2_676 . . . ?
O3 Dy1 O1 C17 -12.6(3) . . . . ?
O6 Dy1 O1 C17 130.5(3) . . . . ?
O2 Dy1 O1 C17 -2.0(2) . . . . ?
N4 Dy1 O1 C17 63.0(3) . . . . ?
N3 Dy1 O1 C17 124.0(3) . . . . ?
O1 C17 O2 Dy1 -3.5(4) . . . . ?
C18 C17 O2 Dy1 177.5(4) . . . . ?
O4 Dy1 O2 C17 95.0(3) 2_676 . . . ?
O5 Dy1 O2 C17 35.5(3) 2_676 . . . ?
O3 Dy1 O2 C17 174.3(3) . . . . ?
O6 Dy1 O2 C17 -126.3(3) . . . . ?
O1 Dy1 O2 C17 2.0(2) . . . . ?
N4 Dy1 O2 C17 -104.6(3) . . . . ?
N3 Dy1 O2 C17 -50.8(3) . . . . ?
O5 C1 O3 Dy1 -2.9(8) . . . . ?
C2 C1 O3 Dy1 174.2(3) . . . . ?
O4 Dy1 O3 C1 -39.4(4) 2_676 . . . ?
O5 Dy1 O3 C1 18.3(5) 2_676 . . . ?
O6 Dy1 O3 C1 90.4(4) . . . . ?
O1 Dy1 O3 C1 -112.4(4) . . . . ?
O2 Dy1 O3 C1 -121.1(4) . . . . ?
N4 Dy1 O3 C1 166.6(5) . . . . ?
N3 Dy1 O3 C1 136.3(4) . . . . ?
C17 Dy1 O3 C1 -118.4(4) . . . . ?
O6 C9 O4 Dy1 -20(8) . . . 2_676 ?
C10 C9 O4 Dy1 162(8) . . . 2_676 ?
O3 C1 O5 Dy1 -17.0(8) . . . 2_676 ?
C2 C1 O5 Dy1 166.0(3) . . . 2_676 ?
O4 C9 O6 Dy1 1.7(5) . . . . ?
C10 C9 O6 Dy1 179.7(2) . . . . ?
O4 Dy1 O6 C9 -0.8(3) 2_676 . . . ?
O5 Dy1 O6 C9 65.7(3) 2_676 . . . ?
O3 Dy1 O6 C9 -68.2(3) . . . . ?
O1 Dy1 O6 C9 137.7(3) . . . . ?
O2 Dy1 O6 C9 -127.9(3) . . . . ?
N4 Dy1 O6 C9 -149.1(3) . . . . ?
N3 Dy1 O6 C9 144.3(3) . . . . ?
C17 Dy1 O6 C9 -176.8(3) . . . . ?
O8 C37 O7 Dy2 9.4(5) . . . . ?
C38 C37 O7 Dy2 -169.7(3) . . . . ?
O9 Dy2 O7 C37 76.4(3) . . . . ?
O10 Dy2 O7 C37 152.0(3) . . . . ?
O11 Dy2 O7 C37 9.5(3) 2 . . . ?
O12 Dy2 O7 C37 -135.9(3) 2 . . . ?
O8 Dy2 O7 C37 -5.3(3) . . . . ?
N2 Dy2 O7 C37 -70.3(3) . . . . ?
N1 Dy2 O7 C37 -130.5(3) . . . . ?
O7 C37 O8 Dy2 -9.3(4) . . . . ?
C38 C37 O8 Dy2 169.9(3) . . . . ?
O9 Dy2 O8 C37 -85.5(3) . . . . ?
O10 Dy2 O8 C37 -26.6(3) . . . . ?
O11 Dy2 O8 C37 -163.9(3) 2 . . . ?
O12 Dy2 O8 C37 139.2(3) 2 . . . ?
O7 Dy2 O8 C37 5.3(3) . . . . ?
N2 Dy2 O8 C37 115.2(3) . . . . ?
N1 Dy2 O8 C37 59.5(3) . . . . ?
O12 C45 O9 Dy2 67(2) . . . . ?
C46 C45 O9 Dy2 -112.4(18) . . . . ?
O10 Dy2 O9 C45 11.5(18) . . . . ?
O11 Dy2 O9 C45 -125.7(19) 2 . . . ?
O12 Dy2 O9 C45 -60.2(19) 2 . . . ?
O7 Dy2 O9 C45 97.6(19) . . . . ?
O8 Dy2 O9 C45 151.4(19) . . . . ?
N2 Dy2 O9 C45 -170.5(17) . . . . ?
N1 Dy2 O9 C45 48.0(19) . . . . ?
C37 Dy2 O9 C45 124.1(19) . . . . ?
O11 C53 O10 Dy2 -15.6(8) . . . . ?
C54 C53 O10 Dy2 165.9(3) . . . . ?
O9 Dy2 O10 C53 -35.6(5) . . . . ?
O11 Dy2 O10 C53 23.5(5) 2 . . . ?
O12 Dy2 O10 C53 92.4(5) 2 . . . ?
O7 Dy2 O10 C53 -121.6(5) . . . . ?
O8 Dy2 O10 C53 -96.3(5) . . . . ?
N2 Dy2 O10 C53 146.0(4) . . . . ?
N1 Dy2 O10 C53 164.8(5) . . . . ?
C37 Dy2 O10 C53 -108.7(5) . . . . ?
O10 C53 O11 Dy2 -3.6(7) . . . 2 ?
C54 C53 O11 Dy2 174.9(3) . . . 2 ?
O9 C45 O12 Dy2 -11.9(6) . . . 2 ?
C46 C45 O12 Dy2 167.4(2) . . . 2 ?
_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         0.738
_refine_diff_density_min         -0.556
_refine_diff_density_rms         0.078


data_2
_database_code_depnum_ccdc_archive 'CCDC 859339'
#TrackingRef '2.cif'
_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C72 H58 Dy2 N4 O12'
_chemical_formula_weight         1496.22
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
_cell_length_a                   13.1576(3)
_cell_length_b                   14.3885(3)
_cell_length_c                   17.4231(4)
_cell_angle_alpha                82.8720(10)
_cell_angle_beta                 83.5220(10)
_cell_angle_gamma                72.8360(10)
_cell_volume                     3117.13(12)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    9039
_cell_measurement_theta_min      2.50
_cell_measurement_theta_max      26.32
_exptl_crystal_description       Block
_exptl_crystal_colour            Colorless
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.14
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.594
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1492
_exptl_absorpt_coefficient_mu    2.447
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.6404
_exptl_absorpt_correction_T_max  0.7257
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_special_details           
;
?
;
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            42115
_diffrn_reflns_av_R_equivalents  0.0372
_diffrn_reflns_av_unetI/netI     0.0347
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         1.18
_diffrn_reflns_theta_max         25.00
_reflns_number_total             10980
_reflns_number_gt                9175
_reflns_threshold_expression     >2sigma(I)
_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0456P)^2^+7.0671P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         10980
_refine_ls_number_parameters     697
_refine_ls_number_restraints     79
_refine_ls_R_factor_all          0.0449
_refine_ls_R_factor_gt           0.0360
_refine_ls_wR_factor_ref         0.1002
_refine_ls_wR_factor_gt          0.0928
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_restrained_S_all      1.079
_refine_ls_shift/su_max          0.018
_refine_ls_shift/su_mean         0.000
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.8522(4) 0.8335(4) 0.0216(3) 0.0460(12) Uani 1 1 d . . .
C2 C 0.8049(3) 0.94178(18) 0.0073(2) 0.0465(12) Uani 1 1 d G . .
C3 C 0.8744(2) 0.9954(2) -0.0242(2) 0.0541(13) Uani 1 1 d G . .
H3 H 0.9456 0.9635 -0.0376 0.065 Uiso 1 1 calc R . .
C4 C 0.8377(3) 1.0967(2) -0.0356(3) 0.0695(17) Uani 1 1 d G . .
H4 H 0.8842 1.1326 -0.0567 0.083 Uiso 1 1 calc R . .
C5 C 0.7314(3) 1.14440(18) -0.0156(3) 0.080(2) Uani 1 1 d G . .
H5 H 0.7068 1.2122 -0.0232 0.096 Uiso 1 1 calc R . .
C6 C 0.6618(3) 1.0908(3) 0.0159(3) 0.085(2) Uani 1 1 d G . .
H6 H 0.5907 1.1227 0.0293 0.102 Uiso 1 1 calc R . .
C7 C 0.6986(3) 0.9895(3) 0.0273(3) 0.0670(17) Uani 1 1 d G . .
C8 C 0.6200(6) 0.9364(6) 0.0647(6) 0.109(3) Uani 1 1 d . . .
H8A H 0.5513 0.9826 0.0734 0.163 Uiso 1 1 calc R . .
H8B H 0.6438 0.9027 0.1134 0.163 Uiso 1 1 calc R . .
H8C H 0.6148 0.8901 0.0312 0.163 Uiso 1 1 calc R . .
C9 C 0.9545(5) 0.6042(4) -0.1284(3) 0.0572(14) Uani 1 1 d . . .
C10 C 0.9287(5) 0.6013(4) -0.2094(3) 0.095(2) Uani 1 1 d GU . .
C11 C 0.8275(5) 0.5999(4) -0.2240(3) 0.097(2) Uani 1 1 d GU . .
H11 H 0.7754 0.6001 -0.1832 0.116 Uiso 1 1 calc R . .
C12 C 0.8041(5) 0.5983(4) -0.2996(3) 0.118(2) Uani 1 1 d GU . .
H12 H 0.7363 0.5974 -0.3093 0.141 Uiso 1 1 calc R . .
C13 C 0.8819(6) 0.5981(4) -0.3606(3) 0.117(3) Uani 1 1 d GU . .
H13 H 0.8662 0.5970 -0.4111 0.140 Uiso 1 1 calc R . .
C14 C 0.9831(5) 0.5995(4) -0.3460(3) 0.115(3) Uani 1 1 d GU . .
H14 H 1.0352 0.5993 -0.3868 0.138 Uiso 1 1 calc R . .
C15 C 1.0066(4) 0.6011(4) -0.2705(4) 0.122(4) Uani 1 1 d G . .
C16 C 1.1056(7) 0.6053(6) -0.2535(5) 0.094(2) Uani 1 1 d . . .
H16A H 1.1514 0.6048 -0.3005 0.141 Uiso 1 1 calc R . .
H16B H 1.1367 0.5498 -0.2184 0.141 Uiso 1 1 calc R . .
H16C H 1.0972 0.6642 -0.2299 0.141 Uiso 1 1 calc R . .
C17 C 0.7997(4) 0.4829(4) 0.0328(3) 0.0482(12) Uani 1 1 d . . .
C18 C 0.6921(3) 0.4730(3) 0.0623(2) 0.0563(14) Uani 1 1 d G . .
C19 C 0.6885(4) 0.3833(3) 0.1007(3) 0.077(2) Uani 1 1 d G . .
H19 H 0.7506 0.3316 0.1037 0.093 Uiso 1 1 calc R . .
C20 C 0.5920(5) 0.3707(4) 0.1345(3) 0.113(3) Uani 1 1 d G . .
H20 H 0.5896 0.3106 0.1601 0.136 Uiso 1 1 calc R . .
C21 C 0.4991(4) 0.4479(6) 0.1299(3) 0.127(4) Uani 1 1 d G . .
H21 H 0.4346 0.4395 0.1525 0.153 Uiso 1 1 calc R . .
C22 C 0.5027(3) 0.5377(5) 0.0915(4) 0.120(4) Uani 1 1 d G . .
H22 H 0.4406 0.5893 0.0885 0.144 Uiso 1 1 calc R . .
C23 C 0.5992(4) 0.5502(3) 0.0577(3) 0.080(2) Uani 1 1 d G . .
C24 C 0.5923(7) 0.6495(6) 0.0113(6) 0.108(3) Uani 1 1 d . . .
H24A H 0.5209 0.6788 -0.0037 0.162 Uiso 1 1 calc R . .
H24B H 0.6411 0.6404 -0.0343 0.162 Uiso 1 1 calc R . .
H24C H 0.6104 0.6916 0.0428 0.162 Uiso 1 1 calc R . .
N2 N 0.8528(3) 0.6509(3) 0.17298(15) 0.0561(11) Uani 1 1 d G . .
C25 C 0.7448(3) 0.6567(4) 0.1817(2) 0.0750(19) Uani 1 1 d G . .
H25 H 0.7093 0.6559 0.1387 0.090 Uiso 1 1 calc R . .
C26 C 0.6899(2) 0.6640(4) 0.2547(3) 0.088(2) Uani 1 1 d G . .
H26 H 0.6177 0.6679 0.2606 0.106 Uiso 1 1 calc R . .
C27 C 0.7430(3) 0.6653(4) 0.31902(18) 0.085(2) Uani 1 1 d G . .
H27 H 0.7063 0.6701 0.3679 0.101 Uiso 1 1 calc R . .
C28 C 0.8510(3) 0.6594(3) 0.31027(16) 0.0659(16) Uani 1 1 d GD . .
C29 C 0.9059(2) 0.6522(3) 0.23725(19) 0.0540(14) Uani 1 1 d G . .
C30 C 0.9068(6) 0.6612(5) 0.3743(3) 0.0753(19) Uani 1 1 d D . .
H30 H 0.8722 0.6640 0.4239 0.090 Uiso 1 1 calc R . .
C31 C 1.0148(6) 0.6587(5) 0.3628(3) 0.082(2) Uani 1 1 d D . .
H31 H 1.0521 0.6593 0.4049 0.098 Uiso 1 1 calc R . .
N1 N 1.0603(3) 0.6493(2) 0.15063(15) 0.0512(11) Uani 1 1 d G . .
C32 C 1.0109(2) 0.6513(3) 0.22549(18) 0.0504(13) Uani 1 1 d G . .
C33 C 1.0670(3) 0.6553(3) 0.28739(14) 0.0623(16) Uani 1 1 d GD . .
C34 C 1.1726(3) 0.6572(3) 0.2744(2) 0.0737(19) Uani 1 1 d G . .
H34 H 1.2102 0.6598 0.3158 0.088 Uiso 1 1 calc R . .
C35 C 1.2220(2) 0.6552(3) 0.1996(2) 0.0770(19) Uani 1 1 d G . .
H35 H 1.2927 0.6564 0.1909 0.092 Uiso 1 1 calc R . .
C36 C 1.1659(3) 0.6512(3) 0.13765(17) 0.0646(16) Uani 1 1 d G . .
H36 H 1.1989 0.6499 0.0876 0.078 Uiso 1 1 calc R . .
C37 C 0.3746(5) 0.3361(4) 0.4431(3) 0.0507(13) Uani 1 1 d . . .
C38 C 0.3665(4) 0.4432(2) 0.4428(3) 0.0610(15) Uani 1 1 d G . .
C39 C 0.4413(4) 0.4863(3) 0.4031(3) 0.079(2) Uani 1 1 d G . .
C40 C 0.4323(5) 0.5837(4) 0.4100(3) 0.102(3) Uani 1 1 d G . .
H40 H 0.4823 0.6126 0.3834 0.122 Uiso 1 1 calc R . .
C41 C 0.3485(6) 0.6379(2) 0.4566(4) 0.119(4) Uani 1 1 d G . .
H41 H 0.3424 0.7031 0.4612 0.143 Uiso 1 1 calc R . .
C42 C 0.2737(5) 0.5948(3) 0.4963(4) 0.125(4) Uani 1 1 d G . .
H42 H 0.2176 0.6311 0.5275 0.150 Uiso 1 1 calc R . .
C43 C 0.2827(4) 0.4974(3) 0.4894(3) 0.085(2) Uani 1 1 d G . .
H43 H 0.2327 0.4686 0.5160 0.102 Uiso 1 1 calc R . .
C44 C 0.5340(9) 0.4345(7) 0.3506(6) 0.135(4) Uani 1 1 d . . .
H44A H 0.5755 0.4782 0.3303 0.203 Uiso 1 1 calc R . .
H44B H 0.5080 0.4134 0.3085 0.203 Uiso 1 1 calc R . .
H44C H 0.5779 0.3787 0.3794 0.203 Uiso 1 1 calc R . .
C45 C 0.5653(6) 0.1063(4) 0.5802(3) 0.0617(16) Uani 1 1 d . . .
C46 C 0.6220(5) 0.1084(4) 0.6472(3) 0.086(3) Uani 1 1 d G . .
C47 C 0.5705(5) 0.1146(5) 0.7214(4) 0.122(3) Uani 1 1 d GU . .
H47 H 0.4989 0.1162 0.7293 0.147 Uiso 1 1 calc R . .
C48 C 0.6259(6) 0.1185(5) 0.7837(3) 0.134(3) Uani 1 1 d GU . .
H48 H 0.5914 0.1227 0.8333 0.161 Uiso 1 1 calc R . .
C49 C 0.7328(6) 0.1162(5) 0.7719(4) 0.130(4) Uani 1 1 d GU . .
H49 H 0.7699 0.1188 0.8136 0.156 Uiso 1 1 calc R . .
C50 C 0.7844(5) 0.1099(4) 0.6977(4) 0.136(4) Uani 1 1 d GU . .
H50 H 0.8559 0.1084 0.6898 0.163 Uiso 1 1 calc R . .
C51 C 0.7289(5) 0.1060(4) 0.6354(3) 0.110(4) Uani 1 1 d GD . .
C52 C 0.7806(8) 0.1038(9) 0.5572(6) 0.148(5) Uani 1 1 d D . .
H52A H 0.7863 0.1677 0.5382 0.223 Uiso 1 1 calc R . .
H52B H 0.7390 0.0838 0.5240 0.223 Uiso 1 1 calc R . .
H52C H 0.8506 0.0582 0.5577 0.223 Uiso 1 1 calc R . .
C53 C 0.3517(4) -0.0046(4) 0.6198(3) 0.0460(12) Uani 1 1 d . . .
C54 C 0.2705(3) -0.0097(3) 0.68681(18) 0.0492(12) Uani 1 1 d G . .
C55 C 0.2244(4) 0.0760(2) 0.7222(2) 0.0687(17) Uani 1 1 d G . .
H55 H 0.2412 0.1332 0.7022 0.082 Uiso 1 1 calc R . .
C56 C 0.1532(4) 0.0763(3) 0.7876(2) 0.088(2) Uani 1 1 d G . .
H56 H 0.1223 0.1337 0.8113 0.106 Uiso 1 1 calc R . .
C57 C 0.1281(3) -0.0091(4) 0.8175(2) 0.085(2) Uani 1 1 d G . .
H57 H 0.0804 -0.0089 0.8612 0.102 Uiso 1 1 calc R . .
C58 C 0.1742(3) -0.0948(3) 0.7821(2) 0.0718(18) Uani 1 1 d G . .
H58 H 0.1574 -0.1519 0.8021 0.086 Uiso 1 1 calc R . .
C59 C 0.2454(3) -0.0951(2) 0.7167(2) 0.0544(14) Uani 1 1 d G . .
C60 C 0.2869(6) -0.1902(5) 0.6789(4) 0.0768(19) Uani 1 1 d . . .
H60A H 0.2550 -0.2379 0.7066 0.115 Uiso 1 1 calc R . .
H60B H 0.3631 -0.2137 0.6802 0.115 Uiso 1 1 calc R . .
H60C H 0.2689 -0.1792 0.6260 0.115 Uiso 1 1 calc R . .
N4 N 0.2163(2) 0.1471(3) 0.4425(2) 0.0552(11) Uani 1 1 d G . .
C61 C 0.1421(3) 0.1497(4) 0.50624(18) 0.0775(19) Uani 1 1 d G . .
H61 H 0.1612 0.1525 0.5555 0.093 Uiso 1 1 calc R . .
C62 C 0.0393(3) 0.1480(4) 0.4964(3) 0.105(3) Uani 1 1 d G . .
H62 H -0.0104 0.1498 0.5390 0.126 Uiso 1 1 calc R . .
C63 C 0.0107(2) 0.1438(4) 0.4228(3) 0.101(3) Uani 1 1 d G . .
H63 H -0.0581 0.1427 0.4162 0.121 Uiso 1 1 calc R . .
C64 C 0.0849(3) 0.1412(3) 0.3590(2) 0.077(2) Uani 1 1 d GD . .
C65 C 0.1877(3) 0.1429(3) 0.36888(18) 0.0557(14) Uani 1 1 d G . .
C66 C 0.0586(7) 0.1366(6) 0.2842(5) 0.098(3) Uani 1 1 d D . .
H66 H -0.0084 0.1319 0.2767 0.117 Uiso 1 1 calc R . .
C67 C 0.1341(6) 0.1391(5) 0.2204(5) 0.091(3) Uani 1 1 d D . .
H67 H 0.1168 0.1362 0.1706 0.109 Uiso 1 1 calc R . .
N3 N 0.3606(3) 0.1525(3) 0.32073(15) 0.0551(11) Uani 1 1 d G . .
C68 C 0.2611(3) 0.1453(3) 0.3075(2) 0.0558(14) Uani 1 1 d G . .
C69 C 0.2356(3) 0.1460(3) 0.2321(2) 0.0714(19) Uani 1 1 d GD . .
C70 C 0.3097(4) 0.1538(4) 0.16992(17) 0.093(3) Uani 1 1 d G . .
H70 H 0.2927 0.1542 0.1195 0.112 Uiso 1 1 calc R . .
C71 C 0.4092(4) 0.1610(4) 0.18317(18) 0.090(2) Uani 1 1 d G . .
H71 H 0.4588 0.1662 0.1416 0.108 Uiso 1 1 calc R . .
C72 C 0.4347(3) 0.1604(3) 0.2586(2) 0.0733(18) Uani 1 1 d G . .
H72 H 0.5012 0.1652 0.2674 0.088 Uiso 1 1 calc R . .
Dy1 Dy 0.411865(18) 0.134859(15) 0.461308(12) 0.03873(8) Uani 1 1 d . . .
Dy2 Dy 0.952362(18) 0.633684(16) 0.036671(13) 0.04165(8) Uani 1 1 d . . .
O1 O 0.9308(4) 0.6830(3) -0.0993(2) 0.0794(14) Uani 1 1 d U . .
O2 O 0.8138(3) 0.5658(3) 0.0312(2) 0.0554(9) Uani 1 1 d . . .
O3 O 0.7954(3) 0.7766(3) 0.0258(2) 0.0583(10) Uani 1 1 d . . .
O4 O 0.9509(3) 0.8002(3) 0.0280(3) 0.0599(10) Uani 1 1 d . . .
O5 O 0.9856(3) 0.5249(3) -0.0879(2) 0.0536(9) Uani 1 1 d . . .
O6 O 0.8692(3) 0.4078(3) 0.0126(2) 0.0520(9) Uani 1 1 d . . .
O7 O 0.5730(3) 0.0249(3) 0.5559(2) 0.0546(9) Uani 1 1 d . . .
O8 O 0.3420(3) 0.0769(3) 0.5807(2) 0.0551(9) Uani 1 1 d . . .
O9 O 0.4245(3) -0.0815(3) 0.6077(2) 0.0529(9) Uani 1 1 d . . .
O10 O 0.4453(3) 0.2834(3) 0.4006(2) 0.0614(10) Uani 1 1 d . . .
O11 O 0.3093(3) 0.3008(3) 0.4870(2) 0.0591(10) Uani 1 1 d . . .
O12 O 0.5044(4) 0.1839(3) 0.5532(3) 0.0763(14) Uani 1 1 d . . .
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
C1 0.055(3) 0.039(3) 0.043(3) -0.010(2) -0.001(2) -0.011(2)
C2 0.055(3) 0.039(3) 0.044(3) -0.008(2) -0.005(2) -0.010(2)
C3 0.055(3) 0.047(3) 0.057(3) -0.001(3) -0.004(3) -0.011(3)
C4 0.082(5) 0.050(4) 0.078(4) 0.009(3) -0.013(4) -0.025(3)
C5 0.090(5) 0.042(3) 0.093(5) 0.001(3) -0.005(4) 0.002(3)
C6 0.070(4) 0.051(4) 0.112(6) -0.001(4) 0.013(4) 0.005(3)
C7 0.059(4) 0.050(3) 0.079(4) 0.000(3) 0.009(3) -0.004(3)
C8 0.061(4) 0.069(5) 0.172(9) 0.011(5) 0.035(5) -0.008(4)
C9 0.071(4) 0.045(3) 0.050(3) 0.003(3) -0.015(3) -0.007(3)
C10 0.154(6) 0.043(3) 0.073(4) -0.007(3) -0.035(4) 0.005(4)
C11 0.147(5) 0.054(3) 0.089(4) -0.007(3) -0.059(4) -0.010(4)
C12 0.147(5) 0.087(4) 0.114(4) -0.008(4) -0.043(4) -0.015(4)
C13 0.152(6) 0.084(4) 0.098(5) -0.004(4) -0.012(5) -0.010(4)
C14 0.185(8) 0.072(5) 0.086(5) -0.011(4) -0.052(5) -0.014(5)
C15 0.155(10) 0.060(5) 0.146(10) 0.003(6) -0.050(8) -0.015(6)
C16 0.116(7) 0.086(6) 0.073(5) -0.004(4) 0.002(5) -0.022(5)
C17 0.047(3) 0.053(3) 0.045(3) -0.009(2) -0.005(2) -0.013(3)
C18 0.053(3) 0.072(4) 0.051(3) -0.017(3) 0.000(2) -0.026(3)
C19 0.081(5) 0.105(6) 0.062(4) -0.009(4) -0.004(3) -0.051(4)
C20 0.119(8) 0.172(10) 0.082(6) -0.009(6) 0.007(5) -0.099(8)
C21 0.078(6) 0.229(14) 0.106(7) -0.047(8) 0.027(5) -0.089(8)
C22 0.054(5) 0.176(11) 0.143(9) -0.064(8) 0.011(5) -0.040(6)
C23 0.048(4) 0.104(6) 0.092(5) -0.035(4) -0.007(3) -0.019(4)
C24 0.076(5) 0.083(6) 0.156(9) -0.021(6) -0.038(5) 0.004(4)
N2 0.057(3) 0.060(3) 0.051(3) -0.012(2) 0.000(2) -0.016(2)
C25 0.063(4) 0.095(5) 0.067(4) -0.021(4) 0.015(3) -0.025(4)
C26 0.073(5) 0.111(6) 0.079(5) -0.021(4) 0.021(4) -0.028(4)
C27 0.095(6) 0.087(5) 0.064(4) -0.015(4) 0.027(4) -0.021(4)
C28 0.085(5) 0.057(4) 0.053(3) -0.015(3) 0.007(3) -0.016(3)
C29 0.070(4) 0.043(3) 0.046(3) -0.012(2) 0.002(3) -0.011(3)
C30 0.105(6) 0.070(4) 0.048(4) -0.014(3) 0.002(4) -0.021(4)
C31 0.129(7) 0.071(4) 0.048(4) -0.017(3) -0.024(4) -0.020(4)
N1 0.063(3) 0.039(2) 0.051(3) -0.0071(19) 0.001(2) -0.014(2)
C32 0.069(4) 0.037(3) 0.044(3) -0.012(2) -0.004(3) -0.009(2)
C33 0.085(4) 0.044(3) 0.059(4) -0.009(3) -0.013(3) -0.016(3)
C34 0.084(5) 0.068(4) 0.076(5) -0.020(3) -0.025(4) -0.020(4)
C35 0.069(4) 0.079(5) 0.092(5) -0.029(4) -0.010(4) -0.026(4)
C36 0.072(4) 0.059(4) 0.068(4) -0.015(3) -0.006(3) -0.025(3)
C37 0.064(3) 0.036(3) 0.048(3) 0.001(2) -0.014(3) -0.008(3)
C38 0.084(4) 0.037(3) 0.063(4) 0.004(3) -0.023(3) -0.015(3)
C39 0.113(6) 0.055(4) 0.077(5) 0.003(3) -0.011(4) -0.039(4)
C40 0.146(8) 0.061(5) 0.109(7) 0.001(4) -0.018(6) -0.046(5)
C41 0.178(11) 0.050(5) 0.140(9) 0.003(5) -0.037(8) -0.044(6)
C42 0.165(10) 0.053(5) 0.144(9) -0.037(5) -0.002(7) -0.005(5)
C43 0.099(6) 0.044(4) 0.110(6) -0.016(4) -0.009(5) -0.013(4)
C44 0.173(10) 0.108(7) 0.142(9) -0.023(7) 0.057(8) -0.087(7)
C45 0.095(5) 0.041(3) 0.057(3) 0.002(3) -0.023(3) -0.029(3)
C46 0.138(7) 0.037(3) 0.091(5) -0.002(3) -0.066(5) -0.018(4)
C47 0.175(5) 0.108(4) 0.089(4) -0.026(4) -0.046(4) -0.028(4)
C48 0.166(4) 0.123(4) 0.112(4) -0.019(3) -0.031(3) -0.029(3)
C49 0.175(8) 0.094(6) 0.131(7) -0.010(5) -0.068(6) -0.034(6)
C50 0.166(8) 0.083(5) 0.178(8) 0.002(6) -0.081(7) -0.046(5)
C51 0.161(10) 0.049(4) 0.133(8) 0.015(5) -0.087(7) -0.033(5)
C52 0.093(7) 0.121(9) 0.238(15) -0.016(10) -0.009(9) -0.044(6)
C53 0.046(3) 0.050(3) 0.041(3) 0.000(2) 0.003(2) -0.015(2)
C54 0.051(3) 0.055(3) 0.038(3) 0.003(2) -0.001(2) -0.014(2)
C55 0.075(4) 0.068(4) 0.054(3) -0.007(3) 0.012(3) -0.012(3)
C56 0.099(6) 0.094(6) 0.061(4) -0.021(4) 0.017(4) -0.016(5)
C57 0.076(5) 0.127(7) 0.051(4) -0.007(4) 0.020(3) -0.037(5)
C58 0.065(4) 0.101(5) 0.055(4) 0.006(4) 0.004(3) -0.041(4)
C59 0.046(3) 0.065(4) 0.052(3) 0.005(3) -0.003(2) -0.021(3)
C60 0.078(5) 0.069(4) 0.088(5) -0.005(4) 0.011(4) -0.035(4)
N4 0.052(3) 0.047(3) 0.063(3) -0.004(2) -0.003(2) -0.010(2)
C61 0.055(4) 0.085(5) 0.089(5) -0.016(4) 0.007(3) -0.015(3)
C62 0.054(4) 0.132(8) 0.128(8) -0.019(6) 0.011(5) -0.029(5)
C63 0.044(4) 0.107(7) 0.150(9) -0.008(6) -0.009(5) -0.022(4)
C64 0.067(4) 0.058(4) 0.109(6) 0.003(4) -0.034(4) -0.018(3)
C65 0.053(3) 0.040(3) 0.072(4) -0.002(3) -0.016(3) -0.007(2)
C66 0.090(6) 0.075(5) 0.140(8) 0.007(5) -0.065(6) -0.028(4)
C67 0.126(7) 0.060(4) 0.097(6) 0.007(4) -0.075(5) -0.026(4)
N3 0.061(3) 0.049(3) 0.054(3) 0.000(2) -0.009(2) -0.015(2)
C68 0.070(4) 0.040(3) 0.060(3) 0.002(2) -0.026(3) -0.012(3)
C69 0.107(5) 0.046(3) 0.062(4) 0.004(3) -0.035(4) -0.016(3)
C70 0.145(8) 0.072(5) 0.061(4) 0.000(4) -0.035(5) -0.024(5)
C71 0.112(6) 0.099(6) 0.048(4) 0.010(4) -0.006(4) -0.019(5)
C72 0.090(5) 0.079(5) 0.044(3) 0.006(3) -0.002(3) -0.020(4)
Dy1 0.04517(14) 0.03247(13) 0.03688(13) -0.00134(9) -0.00017(10) -0.01047(10)
Dy2 0.04690(15) 0.03400(14) 0.04181(14) -0.00593(10) -0.00149(10) -0.00794(10)
O1 0.127(4) 0.047(2) 0.050(2) -0.0044(19) -0.015(2) 0.000(2)
O2 0.050(2) 0.045(2) 0.073(3) -0.0156(18) -0.0027(18) -0.0115(17)
O3 0.054(2) 0.040(2) 0.080(3) -0.0078(19) -0.0038(19) -0.0118(18)
O4 0.049(2) 0.038(2) 0.091(3) -0.0071(19) -0.015(2) -0.0073(17)
O5 0.060(2) 0.045(2) 0.053(2) 0.0066(17) -0.0098(18) -0.0135(17)
O6 0.053(2) 0.045(2) 0.058(2) -0.0133(17) 0.0040(17) -0.0135(17)
O7 0.071(3) 0.046(2) 0.052(2) -0.0125(17) 0.0003(18) -0.0239(18)
O8 0.063(2) 0.044(2) 0.046(2) 0.0037(17) 0.0096(17) -0.0055(17)
O9 0.052(2) 0.043(2) 0.053(2) 0.0045(16) 0.0105(17) -0.0064(17)
O10 0.081(3) 0.041(2) 0.058(2) -0.0016(18) 0.012(2) -0.018(2)
O11 0.065(2) 0.039(2) 0.067(2) -0.0054(18) 0.009(2) -0.0106(18)
O12 0.113(4) 0.039(2) 0.083(3) 0.004(2) -0.050(3) -0.021(2)
_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O3 1.251(6) . ?
C1 O4 1.257(6) . ?
C1 C2 1.498(6) . ?
C1 Dy2 2.779(5) . ?
C2 C3 1.3900 . ?
C2 C7 1.3900 . ?
C3 C4 1.3900 . ?
C3 H3 0.9300 . ?
C4 C5 1.3900 . ?
C4 H4 0.9300 . ?
C5 C6 1.3900 . ?
C5 H5 0.9300 . ?
C6 C7 1.3900 . ?
C6 H6 0.9300 . ?
C7 C8 1.506(8) . ?
C8 H8A 0.9600 . ?
C8 H8B 0.9600 . ?
C8 H8C 0.9600 . ?
C9 O1 1.241(7) . ?
C9 O5 1.247(6) . ?
C9 C10 1.497(7) . ?
C9 Dy2 2.955(6) . ?
C10 C11 1.3900 . ?
C10 C15 1.3900 . ?
C11 C12 1.3900 . ?
C11 H11 0.9300 . ?
C12 C13 1.3900 . ?
C12 H12 0.9300 . ?
C13 C14 1.3900 . ?
C13 H13 0.9300 . ?
C14 C15 1.3900 . ?
C14 H14 0.9300 . ?
C15 C16 1.388(10) . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 O6 1.253(6) . ?
C17 O2 1.256(6) . ?
C17 C18 1.491(6) . ?
C18 C19 1.3900 . ?
C18 C23 1.3900 . ?
C19 C20 1.3900 . ?
C19 H19 0.9300 . ?
C20 C21 1.3900 . ?
C20 H20 0.9300 . ?
C21 C22 1.3900 . ?
C21 H21 0.9300 . ?
C22 C23 1.3900 . ?
C22 H22 0.9300 . ?
C23 C24 1.535(10) . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
N2 C25 1.3900 . ?
N2 C29 1.3900 . ?
N2 Dy2 2.583(2) . ?
C25 C26 1.3900 . ?
C25 H25 0.9300 . ?
C26 C27 1.3900 . ?
C26 H26 0.9300 . ?
C27 C28 1.3900 . ?
C27 H27 0.9300 . ?
C28 C29 1.3900 . ?
C28 C30 1.410(6) . ?
C29 C32 1.370(4) . ?
C30 C31 1.403(7) . ?
C30 H30 0.9300 . ?
C31 C33 1.412(6) . ?
C31 H31 0.9300 . ?
N1 C32 1.3900 . ?
N1 C36 1.3900 . ?
N1 Dy2 2.635(2) . ?
C32 C33 1.3900 . ?
C33 C34 1.3900 . ?
C34 C35 1.3900 . ?
C34 H34 0.9300 . ?
C35 C36 1.3900 . ?
C35 H35 0.9300 . ?
C36 H36 0.9300 . ?
C37 O10 1.248(7) . ?
C37 O11 1.261(7) . ?
C37 C38 1.512(6) . ?
C37 Dy1 2.774(5) . ?
C38 C39 1.3900 . ?
C38 C43 1.3900 . ?
C39 C40 1.3900 . ?
C39 C44 1.504(10) . ?
C40 C41 1.3900 . ?
C40 H40 0.9300 . ?
C41 C42 1.3900 . ?
C41 H41 0.9300 . ?
C42 C43 1.3900 . ?
C42 H42 0.9300 . ?
C43 H43 0.9300 . ?
C44 H44A 0.9600 . ?
C44 H44B 0.9600 . ?
C44 H44C 0.9600 . ?
C45 O12 1.240(7) . ?
C45 O7 1.267(6) . ?
C45 C46 1.462(7) . ?
C45 Dy1 2.964(6) . ?
C46 C47 1.3900 . ?
C46 C51 1.3900 . ?
C47 C48 1.3900 . ?
C47 H47 0.9300 . ?
C48 C49 1.3900 . ?
C48 H48 0.9300 . ?
C49 C50 1.3900 . ?
C49 H49 0.9300 . ?
C50 C51 1.3900 . ?
C50 H50 0.9300 . ?
C51 C52 1.453(8) . ?
C52 H52A 0.9600 . ?
C52 H52B 0.9600 . ?
C52 H52C 0.9600 . ?
C53 O9 1.255(6) . ?
C53 O8 1.260(6) . ?
C53 C54 1.501(5) . ?
C54 C55 1.3900 . ?
C54 C59 1.3900 . ?
C55 C56 1.3900 . ?
C55 H55 0.9300 . ?
C56 C57 1.3900 . ?
C56 H56 0.9300 . ?
C57 C58 1.3900 . ?
C57 H57 0.9300 . ?
C58 C59 1.3900 . ?
C58 H58 0.9300 . ?
C59 C60 1.519(7) . ?
C60 H60A 0.9600 . ?
C60 H60B 0.9600 . ?
C60 H60C 0.9600 . ?
N4 C61 1.3900 . ?
N4 C65 1.3900 . ?
N4 Dy1 2.583(3) . ?
C61 C62 1.3900 . ?
C61 H61 0.9300 . ?
C62 C63 1.3900 . ?
C62 H62 0.9300 . ?
C63 C64 1.3900 . ?
C63 H63 0.9300 . ?
C64 C65 1.3900 . ?
C64 C66 1.399(7) . ?
C65 C68 1.362(4) . ?
C66 C67 1.409(8) . ?
C66 H66 0.9300 . ?
C67 C69 1.408(7) . ?
C67 H67 0.9300 . ?
N3 C68 1.3900 . ?
N3 C72 1.3900 . ?
N3 Dy1 2.576(2) . ?
C68 C69 1.3900 . ?
C69 C70 1.3900 . ?
C70 C71 1.3900 . ?
C70 H70 0.9300 . ?
C71 C72 1.3900 . ?
C71 H71 0.9300 . ?
C72 H72 0.9300 . ?
Dy1 O7 2.303(4) 2_656 ?
Dy1 O9 2.311(3) 2_656 ?
Dy1 O8 2.337(3) . ?
Dy1 O10 2.402(4) . ?
Dy1 O12 2.402(4) . ?
Dy1 O11 2.439(4) . ?
Dy1 O7 2.806(4) . ?
Dy2 O5 2.287(4) 2_765 ?
Dy2 O2 2.324(4) . ?
Dy2 O6 2.334(4) 2_765 ?
Dy2 O4 2.376(4) . ?
Dy2 O1 2.411(4) . ?
Dy2 O3 2.453(4) . ?
Dy2 O5 2.752(4) . ?
O5 Dy2 2.287(4) 2_765 ?
O6 Dy2 2.334(4) 2_765 ?
O7 Dy1 2.303(4) 2_656 ?
O9 Dy1 2.311(3) 2_656 ?
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 C1 O4 120.2(5) . . ?
O3 C1 C2 121.0(5) . . ?
O4 C1 C2 118.8(4) . . ?
O3 C1 Dy2 61.9(3) . . ?
O4 C1 Dy2 58.4(3) . . ?
C2 C1 Dy2 174.9(3) . . ?
C3 C2 C7 120.0 . . ?
C3 C2 C1 116.6(3) . . ?
C7 C2 C1 123.3(3) . . ?
C4 C3 C2 120.0 . . ?
C4 C3 H3 120.0 . . ?
C2 C3 H3 120.0 . . ?
C3 C4 C5 120.0 . . ?
C3 C4 H4 120.0 . . ?
C5 C4 H4 120.0 . . ?
C4 C5 C6 120.0 . . ?
C4 C5 H5 120.0 . . ?
C6 C5 H5 120.0 . . ?
C7 C6 C5 120.0 . . ?
C7 C6 H6 120.0 . . ?
C5 C6 H6 120.0 . . ?
C6 C7 C2 120.0 . . ?
C6 C7 C8 117.1(4) . . ?
C2 C7 C8 122.8(4) . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
O1 C9 O5 121.0(5) . . ?
O1 C9 C10 120.3(5) . . ?
O5 C9 C10 117.9(5) . . ?
O1 C9 Dy2 52.6(3) . . ?
O5 C9 Dy2 68.4(3) . . ?
C10 C9 Dy2 166.8(4) . . ?
C11 C10 C15 120.0 . . ?
C11 C10 C9 120.5(5) . . ?
C15 C10 C9 119.5(5) . . ?
C10 C11 C12 120.0 . . ?
C10 C11 H11 120.0 . . ?
C12 C11 H11 120.0 . . ?
C13 C12 C11 120.0 . . ?
C13 C12 H12 120.0 . . ?
C11 C12 H12 120.0 . . ?
C12 C13 C14 120.0 . . ?
C12 C13 H13 120.0 . . ?
C14 C13 H13 120.0 . . ?
C15 C14 C13 120.0 . . ?
C15 C14 H14 120.0 . . ?
C13 C14 H14 120.0 . . ?
C16 C15 C14 121.9(6) . . ?
C16 C15 C10 118.0(6) . . ?
C14 C15 C10 120.0 . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
O6 C17 O2 125.1(5) . . ?
O6 C17 C18 117.5(5) . . ?
O2 C17 C18 117.4(5) . . ?
C19 C18 C23 120.0 . . ?
C19 C18 C17 116.7(4) . . ?
C23 C18 C17 123.1(4) . . ?
C18 C19 C20 120.0 . . ?
C18 C19 H19 120.0 . . ?
C20 C19 H19 120.0 . . ?
C21 C20 C19 120.0 . . ?
C21 C20 H20 120.0 . . ?
C19 C20 H20 120.0 . . ?
C22 C21 C20 120.0 . . ?
C22 C21 H21 120.0 . . ?
C20 C21 H21 120.0 . . ?
C21 C22 C23 120.0 . . ?
C21 C22 H22 120.0 . . ?
C23 C22 H22 120.0 . . ?
C22 C23 C18 120.0 . . ?
C22 C23 C24 115.4(5) . . ?
C18 C23 C24 124.4(5) . . ?
C23 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C23 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C25 N2 C29 120.0 . . ?
C25 N2 Dy2 118.89(17) . . ?
C29 N2 Dy2 121.09(17) . . ?
N2 C25 C26 120.0 . . ?
N2 C25 H25 120.0 . . ?
C26 C25 H25 120.0 . . ?
C25 C26 C27 120.0 . . ?
C25 C26 H26 120.0 . . ?
C27 C26 H26 120.0 . . ?
C28 C27 C26 120.0 . . ?
C28 C27 H27 120.0 . . ?
C26 C27 H27 120.0 . . ?
C27 C28 C29 120.0 . . ?
C27 C28 C30 121.3(4) . . ?
C29 C28 C30 118.7(4) . . ?
C32 C29 C28 121.8(3) . . ?
C32 C29 N2 118.1(3) . . ?
C28 C29 N2 120.0 . . ?
C31 C30 C28 119.7(6) . . ?
C31 C30 H30 120.2 . . ?
C28 C30 H30 120.2 . . ?
C30 C31 C33 120.1(6) . . ?
C30 C31 H31 120.0 . . ?
C33 C31 H31 120.0 . . ?
C32 N1 C36 120.0 . . ?
C32 N1 Dy2 118.52(16) . . ?
C36 N1 Dy2 121.42(16) . . ?
C29 C32 N1 119.4(3) . . ?
C29 C32 C33 120.5(3) . . ?
N1 C32 C33 120.0 . . ?
C34 C33 C32 120.0 . . ?
C34 C33 C31 120.9(4) . . ?
C32 C33 C31 119.1(4) . . ?
C33 C34 C35 120.0 . . ?
C33 C34 H34 120.0 . . ?
C35 C34 H34 120.0 . . ?
C34 C35 C36 120.0 . . ?
C34 C35 H35 120.0 . . ?
C36 C35 H35 120.0 . . ?
C35 C36 N1 120.0 . . ?
C35 C36 H36 120.0 . . ?
N1 C36 H36 120.0 . . ?
O10 C37 O11 120.5(5) . . ?
O10 C37 C38 120.2(5) . . ?
O11 C37 C38 119.3(5) . . ?
O10 C37 Dy1 59.8(3) . . ?
O11 C37 Dy1 61.5(3) . . ?
C38 C37 Dy1 171.0(4) . . ?
C39 C38 C43 120.0 . . ?
C39 C38 C37 123.5(4) . . ?
C43 C38 C37 116.4(4) . . ?
C40 C39 C38 120.0 . . ?
C40 C39 C44 115.9(5) . . ?
C38 C39 C44 124.1(5) . . ?
C39 C40 C41 120.0 . . ?
C39 C40 H40 120.0 . . ?
C41 C40 H40 120.0 . . ?
C40 C41 C42 120.0 . . ?
C40 C41 H41 120.0 . . ?
C42 C41 H41 120.0 . . ?
C43 C42 C41 120.0 . . ?
C43 C42 H42 120.0 . . ?
C41 C42 H42 120.0 . . ?
C42 C43 C38 120.0 . . ?
C42 C43 H43 120.0 . . ?
C38 C43 H43 120.0 . . ?
C39 C44 H44A 109.5 . . ?
C39 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C39 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
O12 C45 O7 122.1(5) . . ?
O12 C45 C46 118.4(5) . . ?
O7 C45 C46 119.2(5) . . ?
O12 C45 Dy1 51.8(3) . . ?
O7 C45 Dy1 70.5(3) . . ?
C46 C45 Dy1 167.4(5) . . ?
C47 C46 C51 120.0 . . ?
C47 C46 C45 121.3(5) . . ?
C51 C46 C45 118.7(5) . . ?
C48 C47 C46 120.0 . . ?
C48 C47 H47 120.0 . . ?
C46 C47 H47 120.0 . . ?
C49 C48 C47 120.0 . . ?
C49 C48 H48 120.0 . . ?
C47 C48 H48 120.0 . . ?
C48 C49 C50 120.0 . . ?
C48 C49 H49 120.0 . . ?
C50 C49 H49 120.0 . . ?
C51 C50 C49 120.0 . . ?
C51 C50 H50 120.0 . . ?
C49 C50 H50 120.0 . . ?
C50 C51 C46 120.0 . . ?
C50 C51 C52 120.5(6) . . ?
C46 C51 C52 119.4(6) . . ?
C51 C52 H52A 109.5 . . ?
C51 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C51 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
O9 C53 O8 125.2(5) . . ?
O9 C53 C54 117.4(4) . . ?
O8 C53 C54 117.4(4) . . ?
C55 C54 C59 120.0 . . ?
C55 C54 C53 116.2(3) . . ?
C59 C54 C53 123.7(3) . . ?
C54 C55 C56 120.0 . . ?
C54 C55 H55 120.0 . . ?
C56 C55 H55 120.0 . . ?
C55 C56 C57 120.0 . . ?
C55 C56 H56 120.0 . . ?
C57 C56 H56 120.0 . . ?
C58 C57 C56 120.0 . . ?
C58 C57 H57 120.0 . . ?
C56 C57 H57 120.0 . . ?
C57 C58 C59 120.0 . . ?
C57 C58 H58 120.0 . . ?
C59 C58 H58 120.0 . . ?
C58 C59 C54 120.0 . . ?
C58 C59 C60 116.5(3) . . ?
C54 C59 C60 123.4(3) . . ?
C59 C60 H60A 109.5 . . ?
C59 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C59 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
C61 N4 C65 120.0 . . ?
C61 N4 Dy1 120.32(19) . . ?
C65 N4 Dy1 119.46(19) . . ?
C62 C61 N4 120.0 . . ?
C62 C61 H61 120.0 . . ?
N4 C61 H61 120.0 . . ?
C61 C62 C63 120.0 . . ?
C61 C62 H62 120.0 . . ?
C63 C62 H62 120.0 . . ?
C64 C63 C62 120.0 . . ?
C64 C63 H63 120.0 . . ?
C62 C63 H63 120.0 . . ?
C63 C64 C65 120.0 . . ?
C63 C64 C66 121.4(5) . . ?
C65 C64 C66 118.6(5) . . ?
C68 C65 C64 121.8(3) . . ?
C68 C65 N4 118.2(3) . . ?
C64 C65 N4 120.0 . . ?
C64 C66 C67 119.9(6) . . ?
C64 C66 H66 120.1 . . ?
C67 C66 H66 120.1 . . ?
C69 C67 C66 119.9(6) . . ?
C69 C67 H67 120.0 . . ?
C66 C67 H67 120.0 . . ?
C68 N3 C72 120.0 . . ?
C68 N3 Dy1 119.24(17) . . ?
C72 N3 Dy1 120.51(17) . . ?
C65 C68 C69 120.9(3) . . ?
C65 C68 N3 119.0(3) . . ?
C69 C68 N3 120.0 . . ?
C70 C69 C68 120.0 . . ?
C70 C69 C67 121.3(4) . . ?
C68 C69 C67 118.7(4) . . ?
C69 C70 C71 120.0 . . ?
C69 C70 H70 120.0 . . ?
C71 C70 H70 120.0 . . ?
C70 C71 C72 120.0 . . ?
C70 C71 H71 120.0 . . ?
C72 C71 H71 120.0 . . ?
C71 C72 N3 120.0 . . ?
C71 C72 H72 120.0 . . ?
N3 C72 H72 120.0 . . ?
O7 Dy1 O9 75.65(13) 2_656 2_656 ?
O7 Dy1 O8 77.11(13) 2_656 . ?
O9 Dy1 O8 131.92(12) 2_656 . ?
O7 Dy1 O10 144.43(13) 2_656 . ?
O9 Dy1 O10 76.43(13) 2_656 . ?
O8 Dy1 O10 138.46(13) . . ?
O7 Dy1 O12 124.50(13) 2_656 . ?
O9 Dy1 O12 86.99(17) 2_656 . ?
O8 Dy1 O12 76.93(16) . . ?
O10 Dy1 O12 75.19(15) . . ?
O7 Dy1 O11 152.84(14) 2_656 . ?
O9 Dy1 O11 129.15(13) 2_656 . ?
O8 Dy1 O11 89.29(13) . . ?
O10 Dy1 O11 53.49(13) . . ?
O12 Dy1 O11 73.47(15) . . ?
O7 Dy1 N3 78.86(12) 2_656 . ?
O9 Dy1 N3 77.36(12) 2_656 . ?
O8 Dy1 N3 133.91(13) . . ?
O10 Dy1 N3 73.86(13) . . ?
O12 Dy1 N3 147.79(14) . . ?
O11 Dy1 N3 94.81(13) . . ?
O7 Dy1 N4 79.30(13) 2_656 . ?
O9 Dy1 N4 136.27(13) 2_656 . ?
O8 Dy1 N4 74.30(13) . . ?
O10 Dy1 N4 107.13(13) . . ?
O12 Dy1 N4 136.61(15) . . ?
O11 Dy1 N4 74.39(13) . . ?
N3 Dy1 N4 62.92(11) . . ?
O7 Dy1 C37 164.82(14) 2_656 . ?
O9 Dy1 C37 102.23(16) 2_656 . ?
O8 Dy1 C37 113.54(15) . . ?
O10 Dy1 C37 26.67(15) . . ?
O12 Dy1 C37 69.88(14) . . ?
O11 Dy1 C37 27.04(15) . . ?
N3 Dy1 C37 85.99(14) . . ?
N4 Dy1 C37 92.90(15) . . ?
O7 Dy1 O7 75.79(13) 2_656 . ?
O9 Dy1 O7 67.29(12) 2_656 . ?
O8 Dy1 O7 68.04(12) . . ?
O10 Dy1 O7 112.57(13) . . ?
O12 Dy1 O7 49.08(12) . . ?
O11 Dy1 O7 120.95(12) . . ?
N3 Dy1 O7 140.45(11) . . ?
N4 Dy1 O7 138.41(11) . . ?
C37 Dy1 O7 117.67(13) . . ?
O7 Dy1 C45 100.71(15) 2_656 . ?
O9 Dy1 C45 76.96(17) 2_656 . ?
O8 Dy1 C45 70.16(16) . . ?
O10 Dy1 C45 94.00(15) . . ?
O12 Dy1 C45 23.91(14) . . ?
O11 Dy1 C45 96.47(15) . . ?
N3 Dy1 C45 153.55(16) . . ?
N4 Dy1 C45 143.41(16) . . ?
C37 Dy1 C45 93.33(15) . . ?
O7 Dy1 C45 25.18(13) . . ?
O5 Dy2 O2 75.01(13) 2_765 . ?
O5 Dy2 O6 77.88(13) 2_765 2_765 ?
O2 Dy2 O6 133.13(12) . 2_765 ?
O5 Dy2 O4 150.61(14) 2_765 . ?
O2 Dy2 O4 130.06(13) . . ?
O6 Dy2 O4 89.61(13) 2_765 . ?
O5 Dy2 O1 124.22(14) 2_765 . ?
O2 Dy2 O1 84.69(17) . . ?
O6 Dy2 O1 79.89(16) 2_765 . ?
O4 Dy2 O1 78.40(15) . . ?
O5 Dy2 O3 145.22(13) 2_765 . ?
O2 Dy2 O3 76.60(13) . . ?
O6 Dy2 O3 136.86(13) 2_765 . ?
O4 Dy2 O3 53.52(13) . . ?
O1 Dy2 O3 72.02(15) . . ?
O5 Dy2 N2 81.54(13) 2_765 . ?
O2 Dy2 N2 76.51(12) . . ?
O6 Dy2 N2 135.59(12) 2_765 . ?
O4 Dy2 N2 89.54(14) . . ?
O1 Dy2 N2 142.87(14) . . ?
O3 Dy2 N2 72.60(13) . . ?
O5 Dy2 N1 77.51(12) 2_765 . ?
O2 Dy2 N1 133.25(12) . . ?
O6 Dy2 N1 74.76(11) 2_765 . ?
O4 Dy2 N1 73.56(12) . . ?
O1 Dy2 N1 141.93(15) . . ?
O3 Dy2 N1 109.06(12) . . ?
N2 Dy2 N1 62.52(10) . . ?
O5 Dy2 O5 75.22(13) 2_765 . ?
O2 Dy2 O5 68.17(12) . . ?
O6 Dy2 O5 68.34(12) 2_765 . ?
O4 Dy2 O5 124.77(13) . . ?
O1 Dy2 O5 49.03(12) . . ?
O3 Dy2 O5 111.86(12) . . ?
N2 Dy2 O5 141.55(11) . . ?
N1 Dy2 O5 137.68(11) . . ?
O5 Dy2 C1 162.28(14) 2_765 . ?
O2 Dy2 C1 103.27(15) . . ?
O6 Dy2 C1 113.50(14) 2_765 . ?
O4 Dy2 C1 26.80(14) . . ?
O1 Dy2 C1 72.54(14) . . ?
O3 Dy2 C1 26.75(14) . . ?
N2 Dy2 C1 80.93(14) . . ?
N1 Dy2 C1 92.06(13) . . ?
O5 Dy2 C1 121.00(13) . . ?
O5 Dy2 C9 100.14(15) 2_765 . ?
O2 Dy2 C9 74.76(16) . . ?
O6 Dy2 C9 73.29(15) 2_765 . ?
O4 Dy2 C9 101.53(16) . . ?
O1 Dy2 C9 24.12(14) . . ?
O3 Dy2 C9 91.32(15) . . ?
N2 Dy2 C9 149.66(14) . . ?
N1 Dy2 C9 147.70(14) . . ?
O5 Dy2 C9 24.92(13) . . ?
C1 Dy2 C9 96.30(15) . . ?
C9 O1 Dy2 103.3(3) . . ?
C17 O2 Dy2 139.0(3) . . ?
C1 O3 Dy2 91.3(3) . . ?
C1 O4 Dy2 94.8(3) . . ?
C9 O5 Dy2 168.6(4) . 2_765 ?
C9 O5 Dy2 86.6(3) . . ?
Dy2 O5 Dy2 104.78(13) 2_765 . ?
C17 O6 Dy2 137.2(4) . 2_765 ?
C45 O7 Dy1 168.0(4) . 2_656 ?
C45 O7 Dy1 84.4(3) . . ?
Dy1 O7 Dy1 104.21(13) 2_656 . ?
C53 O8 Dy1 136.9(3) . . ?
C53 O9 Dy1 140.8(3) . 2_656 ?
C37 O10 Dy1 93.5(3) . . ?
C37 O11 Dy1 91.4(3) . . ?
C45 O12 Dy1 104.3(3) . . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O3 C1 C2 C3 -157.1(4) . . . . ?
O4 C1 C2 C3 21.5(6) . . . . ?
Dy2 C1 C2 C3 -34(4) . . . . ?
O3 C1 C2 C7 26.2(6) . . . . ?
O4 C1 C2 C7 -155.2(4) . . . . ?
Dy2 C1 C2 C7 150(4) . . . . ?
C7 C2 C3 C4 0.0 . . . . ?
C1 C2 C3 C4 -176.8(4) . . . . ?
C2 C3 C4 C5 0.0 . . . . ?
C3 C4 C5 C6 0.0 . . . . ?
C4 C5 C6 C7 0.0 . . . . ?
C5 C6 C7 C2 0.0 . . . . ?
C5 C6 C7 C8 177.5(6) . . . . ?
C3 C2 C7 C6 0.0 . . . . ?
C1 C2 C7 C6 176.6(4) . . . . ?
C3 C2 C7 C8 -177.3(6) . . . . ?
C1 C2 C7 C8 -0.7(7) . . . . ?
O1 C9 C10 C11 -83.0(7) . . . . ?
O5 C9 C10 C11 86.8(6) . . . . ?
Dy2 C9 C10 C11 -29.1(19) . . . . ?
O1 C9 C10 C15 96.3(6) . . . . ?
O5 C9 C10 C15 -93.9(6) . . . . ?
Dy2 C9 C10 C15 150.2(16) . . . . ?
C15 C10 C11 C12 0.0 . . . . ?
C9 C10 C11 C12 179.3(5) . . . . ?
C10 C11 C12 C13 0.0 . . . . ?
C11 C12 C13 C14 0.0 . . . . ?
C12 C13 C14 C15 0.0 . . . . ?
C13 C14 C15 C16 -178.1(6) . . . . ?
C13 C14 C15 C10 0.0 . . . . ?
C11 C10 C15 C16 178.2(6) . . . . ?
C9 C10 C15 C16 -1.1(6) . . . . ?
C11 C10 C15 C14 0.0 . . . . ?
C9 C10 C15 C14 -179.3(5) . . . . ?
O6 C17 C18 C19 30.9(6) . . . . ?
O2 C17 C18 C19 -148.2(4) . . . . ?
O6 C17 C18 C23 -153.7(4) . . . . ?
O2 C17 C18 C23 27.2(6) . . . . ?
C23 C18 C19 C20 0.0 . . . . ?
C17 C18 C19 C20 175.5(4) . . . . ?
C18 C19 C20 C21 0.0 . . . . ?
C19 C20 C21 C22 0.0 . . . . ?
C20 C21 C22 C23 0.0 . . . . ?
C21 C22 C23 C18 0.0 . . . . ?
C21 C22 C23 C24 175.2(6) . . . . ?
C19 C18 C23 C22 0.0 . . . . ?
C17 C18 C23 C22 -175.2(4) . . . . ?
C19 C18 C23 C24 -174.7(6) . . . . ?
C17 C18 C23 C24 10.0(7) . . . . ?
C29 N2 C25 C26 0.0 . . . . ?
Dy2 N2 C25 C26 178.6(2) . . . . ?
N2 C25 C26 C27 0.0 . . . . ?
C25 C26 C27 C28 0.0 . . . . ?
C26 C27 C28 C29 0.0 . . . . ?
C26 C27 C28 C30 179.6(5) . . . . ?
C27 C28 C29 C32 176.6(4) . . . . ?
C30 C28 C29 C32 -3.0(5) . . . . ?
C27 C28 C29 N2 0.0 . . . . ?
C30 C28 C29 N2 -179.6(5) . . . . ?
C25 N2 C29 C32 -176.7(4) . . . . ?
Dy2 N2 C29 C32 4.7(4) . . . . ?
C25 N2 C29 C28 0.0 . . . . ?
Dy2 N2 C29 C28 -178.6(2) . . . . ?
C27 C28 C30 C31 -177.7(5) . . . . ?
C29 C28 C30 C31 1.9(8) . . . . ?
C28 C30 C31 C33 0.5(10) . . . . ?
C28 C29 C32 N1 -176.5(2) . . . . ?
N2 C29 C32 N1 0.1(4) . . . . ?
C28 C29 C32 C33 1.6(4) . . . . ?
N2 C29 C32 C33 178.3(2) . . . . ?
C36 N1 C32 C29 178.2(4) . . . . ?
Dy2 N1 C32 C29 -4.6(3) . . . . ?
C36 N1 C32 C33 0.0 . . . . ?
Dy2 N1 C32 C33 177.2(2) . . . . ?
C29 C32 C33 C34 -178.1(4) . . . . ?
N1 C32 C33 C34 0.0 . . . . ?
C29 C32 C33 C31 0.9(5) . . . . ?
N1 C32 C33 C31 179.1(5) . . . . ?
C30 C31 C33 C34 177.1(5) . . . . ?
C30 C31 C33 C32 -2.0(8) . . . . ?
C32 C33 C34 C35 0.0 . . . . ?
C31 C33 C34 C35 -179.1(5) . . . . ?
C33 C34 C35 C36 0.0 . . . . ?
C34 C35 C36 N1 0.0 . . . . ?
C32 N1 C36 C35 0.0 . . . . ?
Dy2 N1 C36 C35 -177.1(2) . . . . ?
O10 C37 C38 C39 -7.0(7) . . . . ?
O11 C37 C38 C39 172.8(4) . . . . ?
Dy1 C37 C38 C39 80(3) . . . . ?
O10 C37 C38 C43 177.4(4) . . . . ?
O11 C37 C38 C43 -2.9(6) . . . . ?
Dy1 C37 C38 C43 -95(3) . . . . ?
C43 C38 C39 C40 0.0 . . . . ?
C37 C38 C39 C40 -175.5(5) . . . . ?
C43 C38 C39 C44 -179.3(8) . . . . ?
C37 C38 C39 C44 5.2(8) . . . . ?
C38 C39 C40 C41 0.0 . . . . ?
C44 C39 C40 C41 179.4(7) . . . . ?
C39 C40 C41 C42 0.0 . . . . ?
C40 C41 C42 C43 0.0 . . . . ?
C41 C42 C43 C38 0.0 . . . . ?
C39 C38 C43 C42 0.0 . . . . ?
C37 C38 C43 C42 175.8(4) . . . . ?
O12 C45 C46 C47 76.2(7) . . . . ?
O7 C45 C46 C47 -98.0(7) . . . . ?
Dy1 C45 C46 C47 40(2) . . . . ?
O12 C45 C46 C51 -102.5(7) . . . . ?
O7 C45 C46 C51 83.3(7) . . . . ?
Dy1 C45 C46 C51 -138.7(18) . . . . ?
C51 C46 C47 C48 0.0 . . . . ?
C45 C46 C47 C48 -178.6(5) . . . . ?
C46 C47 C48 C49 0.0 . . . . ?
C47 C48 C49 C50 0.0 . . . . ?
C48 C49 C50 C51 0.0 . . . . ?
C49 C50 C51 C46 0.0 . . . . ?
C49 C50 C51 C52 177.3(7) . . . . ?
C47 C46 C51 C50 0.0 . . . . ?
C45 C46 C51 C50 178.6(5) . . . . ?
C47 C46 C51 C52 -177.4(7) . . . . ?
C45 C46 C51 C52 1.3(8) . . . . ?
O9 C53 C54 C55 150.6(4) . . . . ?
O8 C53 C54 C55 -28.5(6) . . . . ?
O9 C53 C54 C59 -25.4(6) . . . . ?
O8 C53 C54 C59 155.4(4) . . . . ?
C59 C54 C55 C56 0.0 . . . . ?
C53 C54 C55 C56 -176.2(4) . . . . ?
C54 C55 C56 C57 0.0 . . . . ?
C55 C56 C57 C58 0.0 . . . . ?
C56 C57 C58 C59 0.0 . . . . ?
C57 C58 C59 C54 0.0 . . . . ?
C57 C58 C59 C60 -176.5(5) . . . . ?
C55 C54 C59 C58 0.0 . . . . ?
C53 C54 C59 C58 175.9(4) . . . . ?
C55 C54 C59 C60 176.2(5) . . . . ?
C53 C54 C59 C60 -7.9(6) . . . . ?
C65 N4 C61 C62 0.0 . . . . ?
Dy1 N4 C61 C62 -174.6(3) . . . . ?
N4 C61 C62 C63 0.0 . . . . ?
C61 C62 C63 C64 0.0 . . . . ?
C62 C63 C64 C65 0.0 . . . . ?
C62 C63 C64 C66 179.7(5) . . . . ?
C63 C64 C65 C68 -176.7(4) . . . . ?
C66 C64 C65 C68 3.5(5) . . . . ?
C63 C64 C65 N4 0.0 . . . . ?
C66 C64 C65 N4 -179.8(5) . . . . ?
C61 N4 C65 C68 176.8(4) . . . . ?
Dy1 N4 C65 C68 -8.5(4) . . . . ?
C61 N4 C65 C64 0.0 . . . . ?
Dy1 N4 C65 C64 174.7(3) . . . . ?
C63 C64 C66 C67 176.8(5) . . . . ?
C65 C64 C66 C67 -3.5(9) . . . . ?
C64 C66 C67 C69 0.2(11) . . . . ?
C64 C65 C68 C69 -0.2(4) . . . . ?
N4 C65 C68 C69 -177.0(2) . . . . ?
C64 C65 C68 N3 176.4(2) . . . . ?
N4 C65 C68 N3 -0.4(4) . . . . ?
C72 N3 C68 C65 -176.6(4) . . . . ?
Dy1 N3 C68 C65 9.1(4) . . . . ?
C72 N3 C68 C69 0.0 . . . . ?
Dy1 N3 C68 C69 -174.3(2) . . . . ?
C65 C68 C69 C70 176.5(4) . . . . ?
N3 C68 C69 C70 0.0 . . . . ?
C65 C68 C69 C67 -3.1(5) . . . . ?
N3 C68 C69 C67 -179.7(5) . . . . ?
C66 C67 C69 C70 -176.6(5) . . . . ?
C66 C67 C69 C68 3.1(8) . . . . ?
C68 C69 C70 C71 0.0 . . . . ?
C67 C69 C70 C71 179.7(5) . . . . ?
C69 C70 C71 C72 0.0 . . . . ?
C70 C71 C72 N3 0.0 . . . . ?
C68 N3 C72 C71 0.0 . . . . ?
Dy1 N3 C72 C71 174.2(2) . . . . ?
C68 N3 Dy1 O7 74.4(2) . . . 2_656 ?
C72 N3 Dy1 O7 -99.8(2) . . . 2_656 ?
C68 N3 Dy1 O9 152.0(2) . . . 2_656 ?
C72 N3 Dy1 O9 -22.2(2) . . . 2_656 ?
C68 N3 Dy1 O8 14.8(3) . . . . ?
C72 N3 Dy1 O8 -159.5(2) . . . . ?
C68 N3 Dy1 O10 -128.6(2) . . . . ?
C72 N3 Dy1 O10 57.1(2) . . . . ?
C68 N3 Dy1 O12 -145.2(3) . . . . ?
C72 N3 Dy1 O12 40.6(3) . . . . ?
C68 N3 Dy1 O11 -78.9(2) . . . . ?
C72 N3 Dy1 O11 106.9(2) . . . . ?
C68 N3 Dy1 N4 -9.1(2) . . . . ?
C72 N3 Dy1 N4 176.6(2) . . . . ?
C68 N3 Dy1 C37 -104.5(2) . . . . ?
C72 N3 Dy1 C37 81.3(2) . . . . ?
C68 N3 Dy1 O7 125.3(2) . . . . ?
C72 N3 Dy1 O7 -49.0(3) . . . . ?
C68 N3 Dy1 C45 166.1(3) . . . . ?
C72 N3 Dy1 C45 -8.1(4) . . . . ?
C61 N4 Dy1 O7 100.8(2) . . . 2_656 ?
C65 N4 Dy1 O7 -73.9(2) . . . 2_656 ?
C61 N4 Dy1 O9 156.6(2) . . . 2_656 ?
C65 N4 Dy1 O9 -18.1(3) . . . 2_656 ?
C61 N4 Dy1 O8 21.3(2) . . . . ?
C65 N4 Dy1 O8 -153.3(2) . . . . ?
C61 N4 Dy1 O10 -115.3(2) . . . . ?
C65 N4 Dy1 O10 70.0(2) . . . . ?
C61 N4 Dy1 O12 -29.0(3) . . . . ?
C65 N4 Dy1 O12 156.4(2) . . . . ?
C61 N4 Dy1 O11 -72.4(2) . . . . ?
C65 N4 Dy1 O11 112.9(2) . . . . ?
C61 N4 Dy1 N3 -176.3(2) . . . . ?
C65 N4 Dy1 N3 9.0(2) . . . . ?
C61 N4 Dy1 C37 -92.3(2) . . . . ?
C65 N4 Dy1 C37 93.0(2) . . . . ?
C61 N4 Dy1 O7 46.9(3) . . . . ?
C65 N4 Dy1 O7 -127.8(2) . . . . ?
C61 N4 Dy1 C45 7.2(3) . . . . ?
C65 N4 Dy1 C45 -167.5(2) . . . . ?
O10 C37 Dy1 O7 -65.4(7) . . . 2_656 ?
O11 C37 Dy1 O7 104.7(6) . . . 2_656 ?
C38 C37 Dy1 O7 -158(2) . . . 2_656 ?
O10 C37 Dy1 O9 14.9(4) . . . 2_656 ?
O11 C37 Dy1 O9 -175.1(3) . . . 2_656 ?
C38 C37 Dy1 O9 -78(3) . . . 2_656 ?
O10 C37 Dy1 O8 162.1(3) . . . . ?
O11 C37 Dy1 O8 -27.9(4) . . . . ?
C38 C37 Dy1 O8 70(3) . . . . ?
O11 C37 Dy1 O10 170.0(5) . . . . ?
C38 C37 Dy1 O10 -92(3) . . . . ?
O10 C37 Dy1 O12 97.1(4) . . . . ?
O11 C37 Dy1 O12 -92.9(3) . . . . ?
C38 C37 Dy1 O12 5(3) . . . . ?
O10 C37 Dy1 O11 -170.0(5) . . . . ?
C38 C37 Dy1 O11 98(3) . . . . ?
O10 C37 Dy1 N3 -61.2(3) . . . . ?
O11 C37 Dy1 N3 108.8(3) . . . . ?
C38 C37 Dy1 N3 -154(3) . . . . ?
O10 C37 Dy1 N4 -123.8(3) . . . . ?
O11 C37 Dy1 N4 46.2(3) . . . . ?
C38 C37 Dy1 N4 144(3) . . . . ?
O10 C37 Dy1 O7 85.5(3) . . . . ?
O11 C37 Dy1 O7 -104.5(3) . . . . ?
C38 C37 Dy1 O7 -7(3) . . . . ?
O10 C37 Dy1 C45 92.3(4) . . . . ?
O11 C37 Dy1 C45 -97.7(3) . . . . ?
C38 C37 Dy1 C45 0(3) . . . . ?
O12 C45 Dy1 O7 -174.7(4) . . . 2_656 ?
O7 C45 Dy1 O7 8.4(4) . . . 2_656 ?
C46 C45 Dy1 O7 -133.3(19) . . . 2_656 ?
O12 C45 Dy1 O9 112.9(5) . . . 2_656 ?
O7 C45 Dy1 O9 -64.0(3) . . . 2_656 ?
C46 C45 Dy1 O9 154.3(19) . . . 2_656 ?
O12 C45 Dy1 O8 -102.7(5) . . . . ?
O7 C45 Dy1 O8 80.4(3) . . . . ?
C46 C45 Dy1 O8 -61.3(19) . . . . ?
O12 C45 Dy1 O10 37.8(5) . . . . ?
O7 C45 Dy1 O10 -139.1(3) . . . . ?
C46 C45 Dy1 O10 79.3(19) . . . . ?
O7 C45 Dy1 O12 -176.9(7) . . . . ?
C46 C45 Dy1 O12 41.4(18) . . . . ?
O12 C45 Dy1 O11 -15.8(5) . . . . ?
O7 C45 Dy1 O11 167.3(3) . . . . ?
C46 C45 Dy1 O11 25.6(19) . . . . ?
O12 C45 Dy1 N3 98.8(5) . . . . ?
O7 C45 Dy1 N3 -78.1(5) . . . . ?
C46 C45 Dy1 N3 140.2(18) . . . . ?
O12 C45 Dy1 N4 -88.3(5) . . . . ?
O7 C45 Dy1 N4 94.8(4) . . . . ?
C46 C45 Dy1 N4 -47(2) . . . . ?
O12 C45 Dy1 C37 11.1(5) . . . . ?
O7 C45 Dy1 C37 -165.8(4) . . . . ?
C46 C45 Dy1 C37 52.5(19) . . . . ?
O12 C45 Dy1 O7 176.9(7) . . . . ?
C46 C45 Dy1 O7 -142(2) . . . . ?
C25 N2 Dy2 O5 -103.2(2) . . . 2_765 ?
C29 N2 Dy2 O5 75.4(2) . . . 2_765 ?
C25 N2 Dy2 O2 -26.7(2) . . . . ?
C29 N2 Dy2 O2 152.0(2) . . . . ?
C25 N2 Dy2 O6 -166.1(2) . . . 2_765 ?
C29 N2 Dy2 O6 12.5(3) . . . 2_765 ?
C25 N2 Dy2 O4 104.9(2) . . . . ?
C29 N2 Dy2 O4 -76.5(2) . . . . ?
C25 N2 Dy2 O1 35.0(3) . . . . ?
C29 N2 Dy2 O1 -146.4(3) . . . . ?
C25 N2 Dy2 O3 53.3(2) . . . . ?
C29 N2 Dy2 O3 -128.1(2) . . . . ?
C25 N2 Dy2 N1 176.6(2) . . . . ?
C29 N2 Dy2 N1 -4.8(2) . . . . ?
C25 N2 Dy2 O5 -50.2(3) . . . . ?
C29 N2 Dy2 O5 128.4(2) . . . . ?
C25 N2 Dy2 C1 79.4(2) . . . . ?
C29 N2 Dy2 C1 -102.0(2) . . . . ?
C25 N2 Dy2 C9 -7.5(4) . . . . ?
C29 N2 Dy2 C9 171.1(3) . . . . ?
C32 N1 Dy2 O5 -82.2(2) . . . 2_765 ?
C36 N1 Dy2 O5 95.0(2) . . . 2_765 ?
C32 N1 Dy2 O2 -27.0(3) . . . . ?
C36 N1 Dy2 O2 150.1(2) . . . . ?
C32 N1 Dy2 O6 -162.8(2) . . . 2_765 ?
C36 N1 Dy2 O6 14.4(2) . . . 2_765 ?
C32 N1 Dy2 O4 103.0(2) . . . . ?
C36 N1 Dy2 O4 -79.8(2) . . . . ?
C32 N1 Dy2 O1 147.2(2) . . . . ?
C36 N1 Dy2 O1 -35.6(3) . . . . ?
C32 N1 Dy2 O3 62.3(2) . . . . ?
C36 N1 Dy2 O3 -120.5(2) . . . . ?
C32 N1 Dy2 N2 4.72(18) . . . . ?
C36 N1 Dy2 N2 -178.1(2) . . . . ?
C32 N1 Dy2 O5 -133.0(2) . . . . ?
C36 N1 Dy2 O5 44.2(3) . . . . ?
C32 N1 Dy2 C1 83.4(2) . . . . ?
C36 N1 Dy2 C1 -99.4(2) . . . . ?
C32 N1 Dy2 C9 -171.4(2) . . . . ?
C36 N1 Dy2 C9 5.8(3) . . . . ?
O3 C1 Dy2 O5 -77.7(6) . . . 2_765 ?
O4 C1 Dy2 O5 98.8(6) . . . 2_765 ?
C2 C1 Dy2 O5 156(4) . . . 2_765 ?
O3 C1 Dy2 O2 4.6(3) . . . . ?
O4 C1 Dy2 O2 -178.9(3) . . . . ?
C2 C1 Dy2 O2 -121(4) . . . . ?
O3 C1 Dy2 O6 154.8(3) . . . 2_765 ?
O4 C1 Dy2 O6 -28.7(4) . . . 2_765 ?
C2 C1 Dy2 O6 29(4) . . . 2_765 ?
O3 C1 Dy2 O4 -176.5(5) . . . . ?
C2 C1 Dy2 O4 58(4) . . . . ?
O3 C1 Dy2 O1 84.6(3) . . . . ?
O4 C1 Dy2 O1 -98.9(4) . . . . ?
C2 C1 Dy2 O1 -41(4) . . . . ?
O4 C1 Dy2 O3 176.5(5) . . . . ?
C2 C1 Dy2 O3 -126(4) . . . . ?
O3 C1 Dy2 N2 -69.2(3) . . . . ?
O4 C1 Dy2 N2 107.4(3) . . . . ?
C2 C1 Dy2 N2 165(4) . . . . ?
O3 C1 Dy2 N1 -130.9(3) . . . . ?
O4 C1 Dy2 N1 45.6(3) . . . . ?
C2 C1 Dy2 N1 103(4) . . . . ?
O3 C1 Dy2 O5 76.9(3) . . . . ?
O4 C1 Dy2 O5 -106.6(3) . . . . ?
C2 C1 Dy2 O5 -49(4) . . . . ?
O3 C1 Dy2 C9 80.4(3) . . . . ?
O4 C1 Dy2 C9 -103.1(3) . . . . ?
C2 C1 Dy2 C9 -46(4) . . . . ?
O1 C9 Dy2 O5 -176.8(4) . . . 2_765 ?
O5 C9 Dy2 O5 0.5(4) . . . 2_765 ?
C10 C9 Dy2 O5 121.8(18) . . . 2_765 ?
O1 C9 Dy2 O2 111.9(5) . . . . ?
O5 C9 Dy2 O2 -70.8(3) . . . . ?
C10 C9 Dy2 O2 50.5(18) . . . . ?
O1 C9 Dy2 O6 -102.8(5) . . . 2_765 ?
O5 C9 Dy2 O6 74.4(3) . . . 2_765 ?
C10 C9 Dy2 O6 -164.2(18) . . . 2_765 ?
O1 C9 Dy2 O4 -16.8(5) . . . . ?
O5 C9 Dy2 O4 160.5(3) . . . . ?
C10 C9 Dy2 O4 -78.2(18) . . . . ?
O5 C9 Dy2 O1 177.2(7) . . . . ?
C10 C9 Dy2 O1 -61.4(17) . . . . ?
O1 C9 Dy2 O3 36.2(4) . . . . ?
O5 C9 Dy2 O3 -146.5(3) . . . . ?
C10 C9 Dy2 O3 -25.2(18) . . . . ?
O1 C9 Dy2 N2 92.7(5) . . . . ?
O5 C9 Dy2 N2 -90.1(4) . . . . ?
C10 C9 Dy2 N2 31.2(19) . . . . ?
O1 C9 Dy2 N1 -94.2(5) . . . . ?
O5 C9 Dy2 N1 83.1(4) . . . . ?
C10 C9 Dy2 N1 -155.6(16) . . . . ?
O1 C9 Dy2 O5 -177.2(7) . . . . ?
C10 C9 Dy2 O5 121.3(19) . . . . ?
O1 C9 Dy2 C1 9.9(5) . . . . ?
O5 C9 Dy2 C1 -172.9(3) . . . . ?
C10 C9 Dy2 C1 -51.6(18) . . . . ?
O5 C9 O1 Dy2 -3.0(7) . . . . ?
C10 C9 O1 Dy2 166.5(5) . . . . ?
O5 Dy2 O1 C9 3.8(5) 2_765 . . . ?
O2 Dy2 O1 C9 -64.0(4) . . . . ?
O6 Dy2 O1 C9 71.5(4) 2_765 . . . ?
O4 Dy2 O1 C9 163.2(5) . . . . ?
O3 Dy2 O1 C9 -141.6(5) . . . . ?
N2 Dy2 O1 C9 -123.3(4) . . . . ?
N1 Dy2 O1 C9 120.2(4) . . . . ?
O5 Dy2 O1 C9 1.5(4) . . . . ?
C1 Dy2 O1 C9 -169.7(5) . . . . ?
O6 C17 O2 Dy2 -25.9(9) . . . . ?
C18 C17 O2 Dy2 153.1(4) . . . . ?
O5 Dy2 O2 C17 -19.6(5) 2_765 . . . ?
O6 Dy2 O2 C17 37.1(6) 2_765 . . . ?
O4 Dy2 O2 C17 177.9(5) . . . . ?
O1 Dy2 O2 C17 107.9(6) . . . . ?
O3 Dy2 O2 C17 -179.3(6) . . . . ?
N2 Dy2 O2 C17 -104.3(6) . . . . ?
N1 Dy2 O2 C17 -75.6(6) . . . . ?
O5 Dy2 O2 C17 60.2(5) . . . . ?
C1 Dy2 O2 C17 178.6(5) . . . . ?
C9 Dy2 O2 C17 85.6(5) . . . . ?
O4 C1 O3 Dy2 -3.4(5) . . . . ?
C2 C1 O3 Dy2 175.2(4) . . . . ?
O5 Dy2 O3 C1 148.6(3) 2_765 . . . ?
O2 Dy2 O3 C1 -175.4(3) . . . . ?
O6 Dy2 O3 C1 -34.8(4) 2_765 . . . ?
O4 Dy2 O3 C1 2.0(3) . . . . ?
O1 Dy2 O3 C1 -86.7(3) . . . . ?
N2 Dy2 O3 C1 104.7(3) . . . . ?
N1 Dy2 O3 C1 53.1(3) . . . . ?
O5 Dy2 O3 C1 -115.9(3) . . . . ?
C9 Dy2 O3 C1 -101.4(3) . . . . ?
O3 C1 O4 Dy2 3.6(5) . . . . ?
C2 C1 O4 Dy2 -175.1(4) . . . . ?
O5 Dy2 O4 C1 -142.2(3) 2_765 . . . ?
O2 Dy2 O4 C1 1.4(4) . . . . ?
O6 Dy2 O4 C1 153.9(3) 2_765 . . . ?
O1 Dy2 O4 C1 74.2(3) . . . . ?
O3 Dy2 O4 C1 -2.0(3) . . . . ?
N2 Dy2 O4 C1 -70.5(3) . . . . ?
N1 Dy2 O4 C1 -131.9(3) . . . . ?
O5 Dy2 O4 C1 90.9(3) . . . . ?
C9 Dy2 O4 C1 81.1(3) . . . . ?
O1 C9 O5 Dy2 -175.2(16) . . . 2_765 ?
C10 C9 O5 Dy2 15(2) . . . 2_765 ?
Dy2 C9 O5 Dy2 -178(2) . . . 2_765 ?
O1 C9 O5 Dy2 2.6(6) . . . . ?
C10 C9 O5 Dy2 -167.2(5) . . . . ?
O5 Dy2 O5 C9 -179.5(4) 2_765 . . . ?
O2 Dy2 O5 C9 101.0(4) . . . . ?
O6 Dy2 O5 C9 -96.9(4) 2_765 . . . ?
O4 Dy2 O5 C9 -23.5(4) . . . . ?
O1 Dy2 O5 C9 -1.5(4) . . . . ?
O3 Dy2 O5 C9 36.4(4) . . . . ?
N2 Dy2 O5 C9 125.7(3) . . . . ?
N1 Dy2 O5 C9 -128.0(3) . . . . ?
C1 Dy2 O5 C9 8.2(4) . . . . ?
O5 Dy2 O5 Dy2 0.0 2_765 . . 2_765 ?
O2 Dy2 O5 Dy2 -79.49(16) . . . 2_765 ?
O6 Dy2 O5 Dy2 82.60(15) 2_765 . . 2_765 ?
O4 Dy2 O5 Dy2 156.05(13) . . . 2_765 ?
O1 Dy2 O5 Dy2 178.0(3) . . . 2_765 ?
O3 Dy2 O5 Dy2 -144.04(14) . . . 2_765 ?
N2 Dy2 O5 Dy2 -54.8(2) . . . 2_765 ?
N1 Dy2 O5 Dy2 51.5(2) . . . 2_765 ?
C1 Dy2 O5 Dy2 -172.22(15) . . . 2_765 ?
C9 Dy2 O5 Dy2 179.5(4) . . . 2_765 ?
O2 C17 O6 Dy2 -0.8(9) . . . 2_765 ?
C18 C17 O6 Dy2 -179.7(3) . . . 2_765 ?
O12 C45 O7 Dy1 -139.2(17) . . . 2_656 ?
C46 C45 O7 Dy1 35(2) . . . 2_656 ?
Dy1 C45 O7 Dy1 -136(2) . . . 2_656 ?
O12 C45 O7 Dy1 -2.9(7) . . . . ?
C46 C45 O7 Dy1 171.1(6) . . . . ?
O7 Dy1 O7 C45 -171.5(4) 2_656 . . . ?
O9 Dy1 O7 C45 108.4(4) 2_656 . . . ?
O8 Dy1 O7 C45 -89.9(4) . . . . ?
O10 Dy1 O7 C45 45.1(4) . . . . ?
O12 Dy1 O7 C45 1.7(4) . . . . ?
O11 Dy1 O7 C45 -14.8(4) . . . . ?
N3 Dy1 O7 C45 136.8(4) . . . . ?
N4 Dy1 O7 C45 -116.5(4) . . . . ?
C37 Dy1 O7 C45 16.1(4) . . . . ?
O7 Dy1 O7 Dy1 0.0 2_656 . . 2_656 ?
O9 Dy1 O7 Dy1 -80.15(15) 2_656 . . 2_656 ?
O8 Dy1 O7 Dy1 81.61(15) . . . 2_656 ?
O10 Dy1 O7 Dy1 -143.45(14) . . . 2_656 ?
O12 Dy1 O7 Dy1 173.2(3) . . . 2_656 ?
O11 Dy1 O7 Dy1 156.69(14) . . . 2_656 ?
N3 Dy1 O7 Dy1 -51.7(2) . . . 2_656 ?
N4 Dy1 O7 Dy1 55.0(2) . . . 2_656 ?
C37 Dy1 O7 Dy1 -172.44(16) . . . 2_656 ?
C45 Dy1 O7 Dy1 171.5(4) . . . 2_656 ?
O9 C53 O8 Dy1 14.8(9) . . . . ?
C54 C53 O8 Dy1 -166.1(3) . . . . ?
O7 Dy1 O8 C53 25.2(5) 2_656 . . . ?
O9 Dy1 O8 C53 -31.7(6) 2_656 . . . ?
O10 Dy1 O8 C53 -154.2(5) . . . . ?
O12 Dy1 O8 C53 -105.4(5) . . . . ?
O11 Dy1 O8 C53 -178.5(5) . . . . ?
N3 Dy1 O8 C53 85.5(5) . . . . ?
N4 Dy1 O8 C53 107.5(5) . . . . ?
C37 Dy1 O8 C53 -166.3(5) . . . . ?
O7 Dy1 O8 C53 -54.5(5) . . . . ?
C45 Dy1 O8 C53 -81.4(5) . . . . ?
O8 C53 O9 Dy1 13.1(9) . . . 2_656 ?
C54 C53 O9 Dy1 -166.0(3) . . . 2_656 ?
O11 C37 O10 Dy1 -10.2(5) . . . . ?
C38 C37 O10 Dy1 169.6(4) . . . . ?
O7 Dy1 O10 C37 155.8(3) 2_656 . . . ?
O9 Dy1 O10 C37 -165.0(4) 2_656 . . . ?
O8 Dy1 O10 C37 -25.2(4) . . . . ?
O12 Dy1 O10 C37 -74.6(3) . . . . ?
O11 Dy1 O10 C37 5.6(3) . . . . ?
N3 Dy1 O10 C37 114.5(3) . . . . ?
N4 Dy1 O10 C37 60.3(3) . . . . ?
O7 Dy1 O10 C37 -107.0(3) . . . . ?
C45 Dy1 O10 C37 -89.5(4) . . . . ?
O10 C37 O11 Dy1 10.0(5) . . . . ?
C38 C37 O11 Dy1 -169.8(4) . . . . ?
O7 Dy1 O11 C37 -146.3(3) 2_656 . . . ?
O9 Dy1 O11 C37 6.2(4) 2_656 . . . ?
O8 Dy1 O11 C37 154.6(3) . . . . ?
O10 Dy1 O11 C37 -5.6(3) . . . . ?
O12 Dy1 O11 C37 78.0(3) . . . . ?
N3 Dy1 O11 C37 -71.4(3) . . . . ?
N4 Dy1 O11 C37 -131.5(3) . . . . ?
O7 Dy1 O11 C37 90.9(3) . . . . ?
C45 Dy1 O11 C37 84.6(3) . . . . ?
O7 C45 O12 Dy1 3.5(8) . . . . ?
C46 C45 O12 Dy1 -170.5(5) . . . . ?
O7 Dy1 O12 C45 6.3(5) 2_656 . . . ?
O9 Dy1 O12 C45 -64.0(5) 2_656 . . . ?
O8 Dy1 O12 C45 70.4(5) . . . . ?
O10 Dy1 O12 C45 -140.7(5) . . . . ?
O11 Dy1 O12 C45 163.6(5) . . . . ?
N3 Dy1 O12 C45 -124.3(4) . . . . ?
N4 Dy1 O12 C45 119.8(4) . . . . ?
C37 Dy1 O12 C45 -168.2(5) . . . . ?
O7 Dy1 O12 C45 -1.8(4) . . . . ?
_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         1.393
_refine_diff_density_min         -0.868
_refine_diff_density_rms         0.101


data_2(calcination)
_database_code_depnum_ccdc_archive 'CCDC 932127'
#TrackingRef '2(calcination).cif'
_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C72 H58 Dy2 N4 O12'
_chemical_formula_weight         1496.22
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
_cell_length_a                   13.1302(6)
_cell_length_b                   14.3580(6)
_cell_length_c                   17.3903(8)
_cell_angle_alpha                82.788(2)
_cell_angle_beta                 83.566(2)
_cell_angle_gamma                72.837(2)
_cell_volume                     3098.0(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    9786
_cell_measurement_theta_min      2.37
_cell_measurement_theta_max      27.59
_exptl_crystal_description       Block
_exptl_crystal_colour            Colorless
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.604
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1492
_exptl_absorpt_coefficient_mu    2.462
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.6388
_exptl_absorpt_correction_T_max  0.6656
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_special_details           
;
?
;
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            44388
_diffrn_reflns_av_R_equivalents  0.0281
_diffrn_reflns_av_unetI/netI     0.0281
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         1.18
_diffrn_reflns_theta_max         25.00
_reflns_number_total             10914
_reflns_number_gt                9817
_reflns_threshold_expression     >2sigma(I)
_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0349P)^2^+7.9331P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         10914
_refine_ls_number_parameters     697
_refine_ls_number_restraints     44
_refine_ls_R_factor_all          0.0409
_refine_ls_R_factor_gt           0.0361
_refine_ls_wR_factor_ref         0.0922
_refine_ls_wR_factor_gt          0.0876
_refine_ls_goodness_of_fit_ref   1.078
_refine_ls_restrained_S_all      1.106
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.5454(5) 0.3953(4) 0.6279(3) 0.0518(13) Uani 1 1 d . . .
C2 C 0.5718(5) 0.3983(3) 0.7096(2) 0.085(2) Uani 1 1 d G . .
C3 C 0.6733(4) 0.3995(3) 0.7243(3) 0.087(2) Uani 1 1 d G . .
H3 H 0.7256 0.3991 0.6834 0.104 Uiso 1 1 calc R . .
C4 C 0.6966(4) 0.4013(4) 0.8000(3) 0.123(3) Uani 1 1 d GU . .
H4 H 0.7645 0.4021 0.8098 0.148 Uiso 1 1 calc R . .
C5 C 0.6185(6) 0.4018(4) 0.8610(2) 0.122(3) Uani 1 1 d GU . .
H5 H 0.6341 0.4030 0.9117 0.146 Uiso 1 1 calc R . .
C6 C 0.5170(5) 0.4006(4) 0.8463(3) 0.124(4) Uani 1 1 d G . .
H6 H 0.4647 0.4009 0.8871 0.149 Uiso 1 1 calc R . .
C7 C 0.4937(4) 0.3988(4) 0.7706(3) 0.102(3) Uani 1 1 d GD . .
C8 C 0.3891(6) 0.3948(6) 0.7531(4) 0.091(2) Uani 1 1 d D . .
H8A H 0.3432 0.3963 0.8003 0.137 Uiso 1 1 calc R . .
H8B H 0.3969 0.3354 0.7302 0.137 Uiso 1 1 calc R . .
H8C H 0.3584 0.4500 0.7174 0.137 Uiso 1 1 calc R . .
C9 C 0.6476(4) 0.1665(4) 0.4784(3) 0.0430(11) Uani 1 1 d . . .
C10 C 0.6959(3) 0.05741(17) 0.4923(2) 0.0427(11) Uani 1 1 d G . .
C11 C 0.6262(2) 0.0039(2) 0.5242(2) 0.0514(13) Uani 1 1 d G . .
H11 H 0.5550 0.0360 0.5378 0.062 Uiso 1 1 calc R . .
C12 C 0.6628(3) -0.0977(2) 0.5359(2) 0.0658(16) Uani 1 1 d G . .
H12 H 0.6162 -0.1335 0.5573 0.079 Uiso 1 1 calc R . .
C13 C 0.7692(3) -0.14568(17) 0.5156(3) 0.0729(18) Uani 1 1 d G . .
H13 H 0.7937 -0.2136 0.5234 0.088 Uiso 1 1 calc R . .
C14 C 0.8389(2) -0.0921(2) 0.4837(3) 0.078(2) Uani 1 1 d G . .
H14 H 0.9100 -0.1242 0.4701 0.094 Uiso 1 1 calc R . .
C15 C 0.8022(2) 0.0094(2) 0.4720(2) 0.0610(15) Uani 1 1 d G . .
C16 C 0.8817(5) 0.0635(5) 0.4342(6) 0.098(3) Uani 1 1 d . . .
H16A H 0.9500 0.0171 0.4238 0.147 Uiso 1 1 calc R . .
H16B H 0.8887 0.1082 0.4686 0.147 Uiso 1 1 calc R . .
H16C H 0.8565 0.0993 0.3863 0.147 Uiso 1 1 calc R . .
C17 C 0.7011(4) 0.5165(4) 0.4675(3) 0.0432(11) Uani 1 1 d . . .
C18 C 0.8093(2) 0.5261(3) 0.4380(2) 0.0518(13) Uani 1 1 d G . .
C19 C 0.8128(3) 0.6162(3) 0.3998(3) 0.0707(17) Uani 1 1 d G . .
H19 H 0.7506 0.6680 0.3970 0.085 Uiso 1 1 calc R . .
C20 C 0.9094(5) 0.6288(4) 0.3657(3) 0.103(3) Uani 1 1 d G . .
H20 H 0.9117 0.6891 0.3401 0.123 Uiso 1 1 calc R . .
C21 C 1.0024(3) 0.5514(5) 0.3698(3) 0.115(4) Uani 1 1 d G . .
H21 H 1.0670 0.5598 0.3470 0.138 Uiso 1 1 calc R . .
C22 C 0.9988(3) 0.4612(4) 0.4081(3) 0.108(3) Uani 1 1 d G . .
H22 H 1.0610 0.4094 0.4109 0.130 Uiso 1 1 calc R . .
C23 C 0.9023(3) 0.4486(3) 0.4422(3) 0.0723(18) Uani 1 1 d G . .
C24 C 0.9085(6) 0.3488(5) 0.4882(5) 0.098(3) Uani 1 1 d . . .
H24A H 0.8915 0.3068 0.4558 0.146 Uiso 1 1 calc R . .
H24B H 0.8585 0.3576 0.5332 0.146 Uiso 1 1 calc R . .
H24C H 0.9796 0.3195 0.5042 0.146 Uiso 1 1 calc R . .
N4 N 0.6471(2) 0.3491(3) 0.32695(14) 0.0513(11) Uani 1 1 d G . .
C25 C 0.7553(2) 0.3431(3) 0.31845(19) 0.0692(17) Uani 1 1 d G . .
H25 H 0.7908 0.3439 0.3616 0.083 Uiso 1 1 calc R . .
C26 C 0.8105(2) 0.3358(4) 0.2454(2) 0.079(2) Uani 1 1 d G . .
H26 H 0.8829 0.3318 0.2397 0.095 Uiso 1 1 calc R . .
C27 C 0.7575(3) 0.3346(3) 0.18085(17) 0.0749(19) Uani 1 1 d G . .
H27 H 0.7944 0.3298 0.1320 0.090 Uiso 1 1 calc R . .
C28 C 0.6493(3) 0.3407(3) 0.18936(15) 0.0596(15) Uani 1 1 d GD . .
C29 C 0.5941(2) 0.3479(3) 0.26241(18) 0.0492(12) Uani 1 1 d G . .
C30 C 0.5928(5) 0.3395(5) 0.1254(3) 0.0690(17) Uani 1 1 d D . .
H30 H 0.6273 0.3371 0.0757 0.083 Uiso 1 1 calc R . .
C31 C 0.4853(5) 0.3420(5) 0.1364(3) 0.0730(19) Uani 1 1 d D . .
H31 H 0.4483 0.3411 0.0941 0.088 Uiso 1 1 calc R . .
N3 N 0.4390(2) 0.3517(2) 0.34879(14) 0.0458(10) Uani 1 1 d G . .
C32 C 0.4887(2) 0.3496(2) 0.27388(17) 0.0463(12) Uani 1 1 d G . .
C33 C 0.4325(3) 0.3458(3) 0.21172(13) 0.0569(14) Uani 1 1 d GD . .
C34 C 0.3267(3) 0.3442(3) 0.22448(19) 0.0706(18) Uani 1 1 d G . .
H34 H 0.2891 0.3417 0.1829 0.085 Uiso 1 1 calc R . .
C35 C 0.2769(2) 0.3463(3) 0.2994(2) 0.0695(17) Uani 1 1 d G . .
H35 H 0.2061 0.3451 0.3079 0.083 Uiso 1 1 calc R . .
C36 C 0.3331(2) 0.3500(3) 0.36155(16) 0.0568(14) Uani 1 1 d G . .
H36 H 0.2998 0.3514 0.4117 0.068 Uiso 1 1 calc R . .
C37 C -0.0658(5) 0.8942(4) -0.0805(3) 0.0565(14) Uani 1 1 d . . .
C38 C -0.1222(5) 0.8914(3) -0.1474(3) 0.077(2) Uani 1 1 d G . .
C39 C -0.0706(4) 0.8848(4) -0.2217(4) 0.117(2) Uani 1 1 d GU . .
H39 H 0.0011 0.8833 -0.2297 0.141 Uiso 1 1 calc R . .
C40 C -0.1261(6) 0.8805(5) -0.2840(3) 0.122(2) Uani 1 1 d GU . .
H40 H -0.0916 0.8761 -0.3337 0.146 Uiso 1 1 calc R . .
C41 C -0.2333(6) 0.8828(4) -0.2721(3) 0.122(3) Uani 1 1 d GU . .
H41 H -0.2704 0.8798 -0.3138 0.147 Uiso 1 1 calc R . .
C42 C -0.2849(4) 0.8894(4) -0.1979(4) 0.128(3) Uani 1 1 d GU . .
H42 H -0.3566 0.8909 -0.1899 0.154 Uiso 1 1 calc R . .
C43 C -0.2293(5) 0.8937(4) -0.1355(3) 0.099(3) Uani 1 1 d GD . .
C44 C -0.2815(7) 0.8966(8) -0.0600(6) 0.136(4) Uani 1 1 d D . .
H44A H -0.3559 0.9313 -0.0629 0.204 Uiso 1 1 calc R . .
H44B H -0.2495 0.9295 -0.0290 0.204 Uiso 1 1 calc R . .
H44C H -0.2746 0.8310 -0.0367 0.204 Uiso 1 1 calc R . .
C45 C 0.1253(4) 0.6631(4) 0.0573(3) 0.0474(12) Uani 1 1 d . . .
C46 C 0.1339(3) 0.5560(2) 0.0570(2) 0.0549(14) Uani 1 1 d G . .
C47 C 0.2168(3) 0.5020(3) 0.0094(3) 0.079(2) Uani 1 1 d G . .
H47 H 0.2669 0.5310 -0.0174 0.095 Uiso 1 1 calc R . .
C48 C 0.2250(4) 0.4048(3) 0.0019(3) 0.113(3) Uani 1 1 d G . .
H48 H 0.2805 0.3687 -0.0299 0.136 Uiso 1 1 calc R . .
C49 C 0.1502(5) 0.3616(2) 0.0420(3) 0.109(3) Uani 1 1 d G . .
H49 H 0.1557 0.2965 0.0370 0.130 Uiso 1 1 calc R . .
C50 C 0.0673(4) 0.4156(3) 0.0896(3) 0.091(2) Uani 1 1 d G . .
H50 H 0.0173 0.3867 0.1164 0.110 Uiso 1 1 calc R . .
C51 C 0.0592(3) 0.5128(3) 0.0971(2) 0.0720(18) Uani 1 1 d G . .
C52 C -0.0324(9) 0.5635(7) 0.1505(6) 0.125(4) Uani 1 1 d . . .
H52A H -0.0747 0.5199 0.1697 0.187 Uiso 1 1 calc R . .
H52B H -0.0759 0.6208 0.1228 0.187 Uiso 1 1 calc R . .
H52C H -0.0054 0.5822 0.1934 0.187 Uiso 1 1 calc R . .
C53 C -0.1487(4) 0.9951(4) 0.1197(3) 0.0429(11) Uani 1 1 d . . .
C54 C -0.2293(3) 0.9903(2) 0.18729(17) 0.0449(11) Uani 1 1 d G . .
C55 C -0.2757(3) 1.0763(2) 0.2224(2) 0.0635(16) Uani 1 1 d G . .
H55 H -0.2593 1.1336 0.2020 0.076 Uiso 1 1 calc R . .
C56 C -0.3469(3) 1.0766(3) 0.2880(2) 0.083(2) Uani 1 1 d G . .
H56 H -0.3780 1.1341 0.3115 0.100 Uiso 1 1 calc R . .
C57 C -0.3715(3) 0.9909(3) 0.31841(19) 0.080(2) Uani 1 1 d G . .
H57 H -0.4191 0.9911 0.3623 0.096 Uiso 1 1 calc R . .
C58 C -0.3250(3) 0.9049(3) 0.2833(2) 0.0651(17) Uani 1 1 d G . .
H58 H -0.3415 0.8475 0.3036 0.078 Uiso 1 1 calc R . .
C59 C -0.2539(3) 0.9045(2) 0.2177(2) 0.0504(13) Uani 1 1 d G . .
C60 C -0.2129(6) 0.8094(5) 0.1800(4) 0.0734(18) Uani 1 1 d . . .
H60A H -0.2511 0.7643 0.2040 0.110 Uiso 1 1 calc R . .
H60B H -0.1381 0.7817 0.1867 0.110 Uiso 1 1 calc R . .
H60C H -0.2237 0.8220 0.1256 0.110 Uiso 1 1 calc R . .
N1 N 0.1401(3) 0.8478(3) 0.17950(14) 0.0505(11) Uani 1 1 d G . .
C61 C 0.0662(2) 0.8397(3) 0.2419(2) 0.0666(17) Uani 1 1 d G . .
H61 H -0.0005 0.8348 0.2332 0.080 Uiso 1 1 calc R . .
C62 C 0.0921(3) 0.8390(3) 0.31740(16) 0.084(2) Uani 1 1 d G . .
H62 H 0.0427 0.8336 0.3592 0.101 Uiso 1 1 calc R . .
C63 C 0.1918(4) 0.8463(3) 0.33043(15) 0.081(2) Uani 1 1 d G . .
H63 H 0.2091 0.8459 0.3809 0.098 Uiso 1 1 calc R . .
C64 C 0.2657(3) 0.8544(3) 0.2680(2) 0.0654(17) Uani 1 1 d GD . .
C65 C 0.2398(2) 0.8552(3) 0.19253(18) 0.0509(13) Uani 1 1 d G . .
C66 C 0.3681(5) 0.8620(5) 0.2795(4) 0.083(2) Uani 1 1 d D . .
H66 H 0.3857 0.8651 0.3292 0.100 Uiso 1 1 calc R . .
C67 C 0.4420(6) 0.8649(5) 0.2159(4) 0.087(2) Uani 1 1 d D . .
H67 H 0.5089 0.8706 0.2230 0.104 Uiso 1 1 calc R . .
N2 N 0.2844(2) 0.8529(3) 0.05743(19) 0.0495(10) Uani 1 1 d G . .
C68 C 0.3128(3) 0.8573(3) 0.13125(17) 0.0514(13) Uani 1 1 d G . .
C69 C 0.4158(3) 0.8591(3) 0.1413(2) 0.0714(18) Uani 1 1 d GD . .
C70 C 0.4903(2) 0.8565(4) 0.0776(3) 0.096(3) Uani 1 1 d G . .
H70 H 0.5591 0.8577 0.0844 0.116 Uiso 1 1 calc R . .
C71 C 0.4619(3) 0.8521(4) 0.0038(3) 0.097(3) Uani 1 1 d G . .
H71 H 0.5117 0.8504 -0.0388 0.116 Uiso 1 1 calc R . .
C72 C 0.3589(3) 0.8503(3) -0.00628(17) 0.0721(18) Uani 1 1 d G . .
H72 H 0.3399 0.8474 -0.0557 0.087 Uiso 1 1 calc R . .
Dy1 Dy 0.088507(17) 0.864853(15) 0.038792(12) 0.03625(7) Uani 1 1 d . . .
Dy2 Dy 0.547344(17) 0.366200(15) 0.463244(12) 0.03795(7) Uani 1 1 d . . .
O1 O 0.7055(3) 0.2231(3) 0.4743(2) 0.0535(9) Uani 1 1 d . . .
O2 O 0.5489(3) 0.1996(3) 0.4715(2) 0.0551(9) Uani 1 1 d . . .
O3 O 0.5141(3) 0.4747(2) 0.5878(2) 0.0493(8) Uani 1 1 d . . .
O4 O 0.5686(4) 0.3163(3) 0.5994(2) 0.0725(13) Uani 1 1 d . . .
O5 O 0.6316(3) 0.5925(2) 0.4878(2) 0.0485(8) Uani 1 1 d . . .
O6 O 0.6867(3) 0.4335(3) 0.4690(2) 0.0501(9) Uani 1 1 d . . .
O7 O -0.0736(3) 0.9748(2) -0.0557(2) 0.0506(9) Uani 1 1 d . . .
O8 O -0.0044(4) 0.8158(3) -0.0532(3) 0.0725(13) Uani 1 1 d . . .
O9 O -0.1586(3) 1.0767(2) 0.0808(2) 0.0512(9) Uani 1 1 d . . .
O10 O -0.0754(3) 0.9183(2) 0.1078(2) 0.0491(9) Uani 1 1 d . . .
O11 O 0.1911(3) 0.6989(3) 0.0130(2) 0.0553(9) Uani 1 1 d . . .
O12 O 0.0552(3) 0.7162(3) 0.0997(2) 0.0567(10) Uani 1 1 d . . .
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
C1 0.062(3) 0.044(3) 0.044(3) -0.001(2) -0.010(2) -0.005(3)
C2 0.142(7) 0.034(3) 0.065(4) -0.007(3) -0.024(5) 0.003(4)
C3 0.130(7) 0.049(4) 0.085(5) -0.002(3) -0.064(5) -0.014(4)
C4 0.174(9) 0.081(5) 0.105(6) -0.008(5) -0.055(5) -0.008(5)
C5 0.185(9) 0.077(5) 0.082(5) -0.002(4) -0.028(5) -0.001(6)
C6 0.245(13) 0.048(4) 0.070(5) -0.008(3) -0.065(7) -0.008(6)
C7 0.131(8) 0.054(4) 0.113(7) 0.000(4) -0.023(6) -0.015(5)
C8 0.107(6) 0.087(5) 0.078(5) -0.009(4) 0.004(4) -0.029(5)
C9 0.050(3) 0.039(3) 0.040(3) -0.010(2) 0.000(2) -0.011(2)
C10 0.048(3) 0.036(2) 0.043(3) -0.006(2) -0.006(2) -0.008(2)
C11 0.050(3) 0.044(3) 0.059(3) -0.001(2) -0.008(2) -0.010(2)
C12 0.074(4) 0.048(3) 0.076(4) 0.010(3) -0.014(3) -0.021(3)
C13 0.077(4) 0.039(3) 0.092(5) -0.003(3) -0.005(4) -0.003(3)
C14 0.067(4) 0.047(3) 0.101(5) -0.002(3) 0.009(4) 0.006(3)
C15 0.055(3) 0.046(3) 0.074(4) -0.005(3) 0.006(3) -0.005(3)
C16 0.057(4) 0.063(4) 0.155(8) 0.003(5) 0.029(5) -0.007(3)
C17 0.043(3) 0.048(3) 0.041(3) -0.007(2) -0.003(2) -0.014(2)
C18 0.047(3) 0.065(4) 0.049(3) -0.016(3) 0.000(2) -0.022(3)
C19 0.070(4) 0.091(5) 0.062(4) -0.008(3) -0.003(3) -0.041(4)
C20 0.114(7) 0.153(9) 0.074(5) -0.002(5) 0.000(5) -0.094(7)
C21 0.074(6) 0.203(12) 0.089(6) -0.040(7) 0.023(5) -0.073(7)
C22 0.045(4) 0.161(9) 0.123(7) -0.056(7) 0.008(4) -0.023(5)
C23 0.041(3) 0.092(5) 0.085(5) -0.031(4) -0.009(3) -0.011(3)
C24 0.066(5) 0.075(5) 0.144(8) -0.019(5) -0.039(5) 0.007(4)
N4 0.051(3) 0.058(3) 0.046(2) -0.011(2) 0.000(2) -0.016(2)
C25 0.059(4) 0.084(5) 0.065(4) -0.020(3) 0.011(3) -0.021(3)
C26 0.061(4) 0.105(6) 0.073(4) -0.019(4) 0.017(3) -0.029(4)
C27 0.078(5) 0.080(5) 0.059(4) -0.017(3) 0.023(3) -0.017(4)
C28 0.075(4) 0.050(3) 0.051(3) -0.011(3) 0.006(3) -0.016(3)
C29 0.057(3) 0.042(3) 0.046(3) -0.011(2) 0.002(2) -0.010(2)
C30 0.091(5) 0.066(4) 0.048(3) -0.011(3) 0.001(3) -0.018(4)
C31 0.106(6) 0.069(4) 0.047(3) -0.014(3) -0.023(3) -0.021(4)
N3 0.053(3) 0.040(2) 0.045(2) -0.0057(18) 0.0022(19) -0.0156(19)
C32 0.061(3) 0.035(3) 0.039(3) -0.009(2) -0.002(2) -0.006(2)
C33 0.073(4) 0.044(3) 0.054(3) -0.008(2) -0.015(3) -0.013(3)
C34 0.076(4) 0.066(4) 0.076(4) -0.021(3) -0.025(4) -0.017(3)
C35 0.060(4) 0.075(4) 0.083(5) -0.025(4) -0.010(3) -0.025(3)
C36 0.060(3) 0.056(3) 0.060(3) -0.013(3) -0.007(3) -0.022(3)
C37 0.081(4) 0.043(3) 0.052(3) -0.001(2) -0.019(3) -0.023(3)
C38 0.119(6) 0.039(3) 0.083(5) -0.004(3) -0.046(4) -0.024(4)
C39 0.148(4) 0.109(3) 0.097(3) -0.020(3) -0.035(3) -0.026(3)
C40 0.145(3) 0.114(3) 0.106(3) -0.017(2) -0.028(2) -0.026(3)
C41 0.171(8) 0.082(5) 0.120(6) -0.013(5) -0.063(6) -0.026(5)
C42 0.160(7) 0.075(5) 0.167(8) 0.007(5) -0.081(6) -0.043(5)
C43 0.152(9) 0.050(4) 0.106(6) 0.014(4) -0.061(6) -0.034(5)
C44 0.078(6) 0.108(8) 0.224(14) -0.008(8) -0.009(7) -0.035(6)
C45 0.059(3) 0.035(3) 0.047(3) 0.002(2) -0.012(3) -0.012(2)
C46 0.073(4) 0.038(3) 0.055(3) 0.003(2) -0.018(3) -0.017(3)
C47 0.088(5) 0.046(3) 0.101(5) -0.020(3) -0.007(4) -0.010(3)
C48 0.144(8) 0.050(4) 0.137(8) -0.033(5) -0.002(7) -0.009(5)
C49 0.155(9) 0.043(4) 0.134(8) 0.002(4) -0.035(7) -0.034(5)
C50 0.132(7) 0.053(4) 0.102(6) 0.004(4) -0.020(5) -0.046(5)
C51 0.102(5) 0.051(4) 0.070(4) 0.004(3) -0.012(4) -0.034(4)
C52 0.165(10) 0.102(7) 0.127(8) -0.018(6) 0.052(7) -0.089(7)
C53 0.040(3) 0.046(3) 0.040(3) 0.000(2) 0.000(2) -0.011(2)
C54 0.042(3) 0.052(3) 0.037(3) 0.000(2) -0.001(2) -0.011(2)
C55 0.074(4) 0.061(4) 0.048(3) -0.005(3) 0.009(3) -0.013(3)
C56 0.086(5) 0.094(5) 0.060(4) -0.024(4) 0.022(4) -0.015(4)
C57 0.075(4) 0.120(6) 0.046(3) -0.004(4) 0.016(3) -0.040(4)
C58 0.059(4) 0.093(5) 0.049(3) 0.009(3) 0.001(3) -0.039(3)
C59 0.045(3) 0.061(3) 0.045(3) 0.002(2) -0.005(2) -0.018(3)
C60 0.078(4) 0.062(4) 0.084(5) -0.002(3) 0.009(4) -0.033(3)
N1 0.057(3) 0.049(3) 0.048(2) 0.001(2) -0.009(2) -0.018(2)
C61 0.075(4) 0.075(4) 0.044(3) 0.009(3) -0.002(3) -0.020(3)
C62 0.094(5) 0.097(5) 0.047(4) 0.009(3) -0.001(3) -0.014(4)
C63 0.116(6) 0.073(4) 0.054(4) 0.001(3) -0.031(4) -0.020(4)
C64 0.095(5) 0.044(3) 0.054(3) 0.006(3) -0.028(3) -0.012(3)
C65 0.059(3) 0.036(3) 0.058(3) 0.004(2) -0.023(3) -0.012(2)
C66 0.117(6) 0.056(4) 0.086(5) 0.005(4) -0.070(5) -0.022(4)
C67 0.078(5) 0.069(4) 0.124(7) 0.006(4) -0.054(5) -0.027(4)
N2 0.043(2) 0.045(2) 0.060(3) -0.007(2) -0.003(2) -0.0106(19)
C68 0.047(3) 0.039(3) 0.067(4) 0.001(2) -0.014(3) -0.007(2)
C69 0.060(4) 0.057(4) 0.100(5) -0.002(3) -0.031(4) -0.015(3)
C70 0.043(4) 0.103(6) 0.146(8) -0.010(6) -0.010(4) -0.025(4)
C71 0.050(4) 0.123(7) 0.117(7) -0.016(5) 0.009(4) -0.027(4)
C72 0.053(4) 0.079(4) 0.079(4) -0.013(4) 0.006(3) -0.012(3)
Dy1 0.04096(13) 0.03104(12) 0.03554(12) -0.00104(9) -0.00047(9) -0.01023(9)
Dy2 0.04037(13) 0.03241(12) 0.03929(13) -0.00505(9) -0.00174(9) -0.00754(9)
O1 0.047(2) 0.0383(19) 0.074(3) -0.0073(17) -0.0010(18) -0.0104(16)
O2 0.042(2) 0.0386(19) 0.084(3) -0.0079(18) -0.0123(18) -0.0074(16)
O3 0.053(2) 0.0419(19) 0.051(2) 0.0071(16) -0.0113(16) -0.0122(16)
O4 0.118(4) 0.042(2) 0.047(2) -0.0052(17) -0.019(2) 0.000(2)
O5 0.046(2) 0.0432(19) 0.056(2) -0.0128(16) 0.0068(16) -0.0119(16)
O6 0.0435(19) 0.042(2) 0.065(2) -0.0110(17) -0.0040(17) -0.0105(16)
O7 0.066(2) 0.041(2) 0.051(2) -0.0120(16) -0.0002(17) -0.0234(17)
O8 0.109(4) 0.040(2) 0.075(3) 0.0034(19) -0.048(3) -0.021(2)
O9 0.058(2) 0.0415(19) 0.0439(19) 0.0035(15) 0.0059(16) -0.0062(17)
O10 0.047(2) 0.0414(19) 0.051(2) 0.0060(15) 0.0088(16) -0.0090(16)
O11 0.057(2) 0.0384(19) 0.066(2) -0.0053(17) 0.0068(19) -0.0111(17)
O12 0.074(3) 0.0358(19) 0.057(2) -0.0039(16) 0.0108(19) -0.0174(18)
_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O4 1.235(6) . ?
C1 O3 1.243(6) . ?
C1 C2 1.507(6) . ?
C1 Dy2 2.942(5) . ?
C2 C3 1.3900 . ?
C2 C7 1.3900 . ?
C3 C4 1.3900 . ?
C3 H3 0.9300 . ?
C4 C5 1.3900 . ?
C4 H4 0.9300 . ?
C5 C6 1.3900 . ?
C5 H5 0.9300 . ?
C6 C7 1.3900 . ?
C6 H6 0.9300 . ?
C7 C8 1.458(7) . ?
C8 H8A 0.9600 . ?
C8 H8B 0.9600 . ?
C8 H8C 0.9600 . ?
C9 O2 1.256(6) . ?
C9 O1 1.258(6) . ?
C9 C10 1.505(5) . ?
C9 Dy2 2.773(5) . ?
C10 C11 1.3900 . ?
C10 C15 1.3900 . ?
C11 C12 1.3900 . ?
C11 H11 0.9300 . ?
C12 C13 1.3900 . ?
C12 H12 0.9300 . ?
C13 C14 1.3900 . ?
C13 H13 0.9300 . ?
C14 C15 1.3900 . ?
C14 H14 0.9300 . ?
C15 C16 1.523(7) . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 O6 1.256(6) . ?
C17 O5 1.259(6) . ?
C17 C18 1.494(6) . ?
C18 C19 1.3900 . ?
C18 C23 1.3900 . ?
C19 C20 1.3900 . ?
C19 H19 0.9300 . ?
C20 C21 1.3900 . ?
C20 H20 0.9300 . ?
C21 C22 1.3900 . ?
C21 H21 0.9300 . ?
C22 C23 1.3900 . ?
C22 H22 0.9300 . ?
C23 C24 1.535(9) . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
N4 C25 1.3900 . ?
N4 C29 1.3900 . ?
N4 Dy2 2.580(2) . ?
C25 C26 1.3900 . ?
C25 H25 0.9300 . ?
C26 C27 1.3900 . ?
C26 H26 0.9300 . ?
C27 C28 1.3900 . ?
C27 H27 0.9300 . ?
C28 C29 1.3900 . ?
C28 C30 1.409(6) . ?
C29 C32 1.369(4) . ?
C30 C31 1.393(7) . ?
C30 H30 0.9300 . ?
C31 C33 1.411(6) . ?
C31 H31 0.9300 . ?
N3 C32 1.3900 . ?
N3 C36 1.3900 . ?
N3 Dy2 2.635(2) . ?
C32 C33 1.3900 . ?
C33 C34 1.3900 . ?
C34 C35 1.3900 . ?
C34 H34 0.9300 . ?
C35 C36 1.3900 . ?
C35 H35 0.9300 . ?
C36 H36 0.9300 . ?
C37 O8 1.248(7) . ?
C37 O7 1.257(6) . ?
C37 C38 1.459(7) . ?
C37 Dy1 2.967(6) . ?
C38 C39 1.3900 . ?
C38 C43 1.3900 . ?
C39 C40 1.3900 . ?
C39 H39 0.9300 . ?
C40 C41 1.3900 . ?
C40 H40 0.9300 . ?
C41 C42 1.3900 . ?
C41 H41 0.9300 . ?
C42 C43 1.3900 . ?
C42 H42 0.9300 . ?
C43 C44 1.412(8) . ?
C44 H44A 0.9600 . ?
C44 H44B 0.9600 . ?
C44 H44C 0.9600 . ?
C45 O12 1.244(6) . ?
C45 O11 1.273(6) . ?
C45 C46 1.508(6) . ?
C45 Dy1 2.776(5) . ?
C46 C47 1.3900 . ?
C46 C51 1.3900 . ?
C47 C48 1.3900 . ?
C47 H47 0.9300 . ?
C48 C49 1.3900 . ?
C48 H48 0.9300 . ?
C49 C50 1.3900 . ?
C49 H49 0.9300 . ?
C50 C51 1.3900 . ?
C50 H50 0.9300 . ?
C51 C52 1.497(10) . ?
C52 H52A 0.9600 . ?
C52 H52B 0.9600 . ?
C52 H52C 0.9600 . ?
C53 O10 1.254(6) . ?
C53 O9 1.257(6) . ?
C53 C54 1.500(5) . ?
C54 C55 1.3900 . ?
C54 C59 1.3900 . ?
C55 C56 1.3900 . ?
C55 H55 0.9300 . ?
C56 C57 1.3900 . ?
C56 H56 0.9300 . ?
C57 C58 1.3900 . ?
C57 H57 0.9300 . ?
C58 C59 1.3900 . ?
C58 H58 0.9300 . ?
C59 C60 1.515(7) . ?
C60 H60A 0.9600 . ?
C60 H60B 0.9600 . ?
C60 H60C 0.9600 . ?
N1 C61 1.3900 . ?
N1 C65 1.3900 . ?
N1 Dy1 2.575(2) . ?
C61 C62 1.3900 . ?
C61 H61 0.9300 . ?
C62 C63 1.3900 . ?
C62 H62 0.9300 . ?
C63 C64 1.3900 . ?
C63 H63 0.9300 . ?
C64 C65 1.3900 . ?
C64 C66 1.418(6) . ?
C65 C68 1.355(4) . ?
C66 C67 1.392(7) . ?
C66 H66 0.9300 . ?
C67 C69 1.396(6) . ?
C67 H67 0.9300 . ?
N2 C68 1.3900 . ?
N2 C72 1.3900 . ?
N2 Dy1 2.582(2) . ?
C68 C69 1.3900 . ?
C69 C70 1.3900 . ?
C70 C71 1.3900 . ?
C70 H70 0.9300 . ?
C71 C72 1.3900 . ?
C71 H71 0.9300 . ?
C72 H72 0.9300 . ?
Dy1 O7 2.306(3) 2_575 ?
Dy1 O10 2.311(3) . ?
Dy1 O9 2.338(3) 2_575 ?
Dy1 O12 2.397(3) . ?
Dy1 O8 2.402(4) . ?
Dy1 O11 2.435(3) . ?
Dy1 O7 2.805(4) . ?
Dy2 O3 2.285(3) 2_666 ?
Dy2 O6 2.325(4) . ?
Dy2 O5 2.335(3) 2_666 ?
Dy2 O2 2.373(4) . ?
Dy2 O4 2.409(4) . ?
Dy2 O1 2.459(3) . ?
Dy2 O3 2.746(4) . ?
O3 Dy2 2.285(3) 2_666 ?
O5 Dy2 2.335(3) 2_666 ?
O7 Dy1 2.306(3) 2_575 ?
O9 Dy1 2.338(3) 2_575 ?
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 C1 O3 121.6(5) . . ?
O4 C1 C2 120.1(4) . . ?
O3 C1 C2 117.5(5) . . ?
O4 C1 Dy2 53.0(3) . . ?
O3 C1 Dy2 68.7(3) . . ?
C2 C1 Dy2 166.7(4) . . ?
C3 C2 C7 120.0 . . ?
C3 C2 C1 120.8(4) . . ?
C7 C2 C1 119.2(4) . . ?
C2 C3 C4 120.0 . . ?
C2 C3 H3 120.0 . . ?
C4 C3 H3 120.0 . . ?
C5 C4 C3 120.0 . . ?
C5 C4 H4 120.0 . . ?
C3 C4 H4 120.0 . . ?
C4 C5 C6 120.0 . . ?
C4 C5 H5 120.0 . . ?
C6 C5 H5 120.0 . . ?
C7 C6 C5 120.0 . . ?
C7 C6 H6 120.0 . . ?
C5 C6 H6 120.0 . . ?
C6 C7 C2 120.0 . . ?
C6 C7 C8 121.6(5) . . ?
C2 C7 C8 118.4(5) . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
O2 C9 O1 120.9(5) . . ?
O2 C9 C10 118.9(4) . . ?
O1 C9 C10 120.2(4) . . ?
O2 C9 Dy2 58.5(3) . . ?
O1 C9 Dy2 62.5(3) . . ?
C10 C9 Dy2 175.4(3) . . ?
C11 C10 C15 120.0 . . ?
C11 C10 C9 116.1(3) . . ?
C15 C10 C9 123.9(3) . . ?
C10 C11 C12 120.0 . . ?
C10 C11 H11 120.0 . . ?
C12 C11 H11 120.0 . . ?
C13 C12 C11 120.0 . . ?
C13 C12 H12 120.0 . . ?
C11 C12 H12 120.0 . . ?
C14 C13 C12 120.0 . . ?
C14 C13 H13 120.0 . . ?
C12 C13 H13 120.0 . . ?
C13 C14 C15 120.0 . . ?
C13 C14 H14 120.0 . . ?
C15 C14 H14 120.0 . . ?
C14 C15 C10 120.0 . . ?
C14 C15 C16 117.4(3) . . ?
C10 C15 C16 122.6(3) . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
O6 C17 O5 125.5(5) . . ?
O6 C17 C18 117.3(4) . . ?
O5 C17 C18 117.2(4) . . ?
C19 C18 C23 120.0 . . ?
C19 C18 C17 116.5(3) . . ?
C23 C18 C17 123.3(3) . . ?
C18 C19 C20 120.0 . . ?
C18 C19 H19 120.0 . . ?
C20 C19 H19 120.0 . . ?
C21 C20 C19 120.0 . . ?
C21 C20 H20 120.0 . . ?
C19 C20 H20 120.0 . . ?
C20 C21 C22 120.0 . . ?
C20 C21 H21 120.0 . . ?
C22 C21 H21 120.0 . . ?
C21 C22 C23 120.0 . . ?
C21 C22 H22 120.0 . . ?
C23 C22 H22 120.0 . . ?
C22 C23 C18 120.0 . . ?
C22 C23 C24 115.8(4) . . ?
C18 C23 C24 124.1(4) . . ?
C23 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C23 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C25 N4 C29 120.0 . . ?
C25 N4 Dy2 118.81(16) . . ?
C29 N4 Dy2 121.18(16) . . ?
C26 C25 N4 120.0 . . ?
C26 C25 H25 120.0 . . ?
N4 C25 H25 120.0 . . ?
C27 C26 C25 120.0 . . ?
C27 C26 H26 120.0 . . ?
C25 C26 H26 120.0 . . ?
C26 C27 C28 120.0 . . ?
C26 C27 H27 120.0 . . ?
C28 C27 H27 120.0 . . ?
C29 C28 C27 120.0 . . ?
C29 C28 C30 118.3(4) . . ?
C27 C28 C30 121.7(4) . . ?
C32 C29 C28 121.9(3) . . ?
C32 C29 N4 118.1(3) . . ?
C28 C29 N4 120.0 . . ?
C31 C30 C28 120.2(5) . . ?
C31 C30 H30 119.9 . . ?
C28 C30 H30 119.9 . . ?
C30 C31 C33 120.1(5) . . ?
C30 C31 H31 119.9 . . ?
C33 C31 H31 119.9 . . ?
C32 N3 C36 120.0 . . ?
C32 N3 Dy2 118.49(15) . . ?
C36 N3 Dy2 121.47(15) . . ?
C29 C32 N3 119.4(2) . . ?
C29 C32 C33 120.5(2) . . ?
N3 C32 C33 120.0 . . ?
C34 C33 C32 120.0 . . ?
C34 C33 C31 121.0(4) . . ?
C32 C33 C31 119.0(4) . . ?
C35 C34 C33 120.0 . . ?
C35 C34 H34 120.0 . . ?
C33 C34 H34 120.0 . . ?
C34 C35 C36 120.0 . . ?
C34 C35 H35 120.0 . . ?
C36 C35 H35 120.0 . . ?
C35 C36 N3 120.0 . . ?
C35 C36 H36 120.0 . . ?
N3 C36 H36 120.0 . . ?
O8 C37 O7 121.9(5) . . ?
O8 C37 C38 117.8(5) . . ?
O7 C37 C38 120.1(5) . . ?
O8 C37 Dy1 51.7(3) . . ?
O7 C37 Dy1 70.3(3) . . ?
C38 C37 Dy1 166.9(4) . . ?
C39 C38 C43 120.0 . . ?
C39 C38 C37 121.4(5) . . ?
C43 C38 C37 118.6(5) . . ?
C38 C39 C40 120.0 . . ?
C38 C39 H39 120.0 . . ?
C40 C39 H39 120.0 . . ?
C41 C40 C39 120.0 . . ?
C41 C40 H40 120.0 . . ?
C39 C40 H40 120.0 . . ?
C40 C41 C42 120.0 . . ?
C40 C41 H41 120.0 . . ?
C42 C41 H41 120.0 . . ?
C43 C42 C41 120.0 . . ?
C43 C42 H42 120.0 . . ?
C41 C42 H42 120.0 . . ?
C42 C43 C38 120.0 . . ?
C42 C43 C44 119.4(6) . . ?
C38 C43 C44 120.5(6) . . ?
C43 C44 H44A 109.5 . . ?
C43 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C43 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
O12 C45 O11 120.0(5) . . ?
O12 C45 C46 121.2(5) . . ?
O11 C45 C46 118.8(5) . . ?
O12 C45 Dy1 59.5(3) . . ?
O11 C45 Dy1 61.3(3) . . ?
C46 C45 Dy1 170.9(3) . . ?
C47 C46 C51 120.0 . . ?
C47 C46 C45 116.9(3) . . ?
C51 C46 C45 122.9(3) . . ?
C46 C47 C48 120.0 . . ?
C46 C47 H47 120.0 . . ?
C48 C47 H47 120.0 . . ?
C49 C48 C47 120.0 . . ?
C49 C48 H48 120.0 . . ?
C47 C48 H48 120.0 . . ?
C48 C49 C50 120.0 . . ?
C48 C49 H49 120.0 . . ?
C50 C49 H49 120.0 . . ?
C49 C50 C51 120.0 . . ?
C49 C50 H50 120.0 . . ?
C51 C50 H50 120.0 . . ?
C50 C51 C46 120.0 . . ?
C50 C51 C52 115.4(4) . . ?
C46 C51 C52 124.6(4) . . ?
C51 C52 H52A 109.5 . . ?
C51 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C51 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
O10 C53 O9 125.3(4) . . ?
O10 C53 C54 117.5(4) . . ?
O9 C53 C54 117.1(4) . . ?
C55 C54 C59 120.0 . . ?
C55 C54 C53 116.5(3) . . ?
C59 C54 C53 123.4(3) . . ?
C56 C55 C54 120.0 . . ?
C56 C55 H55 120.0 . . ?
C54 C55 H55 120.0 . . ?
C57 C56 C55 120.0 . . ?
C57 C56 H56 120.0 . . ?
C55 C56 H56 120.0 . . ?
C56 C57 C58 120.0 . . ?
C56 C57 H57 120.0 . . ?
C58 C57 H57 120.0 . . ?
C59 C58 C57 120.0 . . ?
C59 C58 H58 120.0 . . ?
C57 C58 H58 120.0 . . ?
C58 C59 C54 120.0 . . ?
C58 C59 C60 116.4(3) . . ?
C54 C59 C60 123.4(3) . . ?
C59 C60 H60A 109.5 . . ?
C59 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C59 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
C61 N1 C65 120.0 . . ?
C61 N1 Dy1 120.62(16) . . ?
C65 N1 Dy1 119.16(16) . . ?
C62 C61 N1 120.0 . . ?
C62 C61 H61 120.0 . . ?
N1 C61 H61 120.0 . . ?
C61 C62 C63 120.0 . . ?
C61 C62 H62 120.0 . . ?
C63 C62 H62 120.0 . . ?
C64 C63 C62 120.0 . . ?
C64 C63 H63 120.0 . . ?
C62 C63 H63 120.0 . . ?
C63 C64 C65 120.0 . . ?
C63 C64 C66 121.3(4) . . ?
C65 C64 C66 118.7(4) . . ?
C68 C65 C64 120.9(3) . . ?
C68 C65 N1 119.0(3) . . ?
C64 C65 N1 120.0 . . ?
C67 C66 C64 119.6(6) . . ?
C67 C66 H66 120.2 . . ?
C64 C66 H66 120.2 . . ?
C66 C67 C69 120.1(6) . . ?
C66 C67 H67 119.9 . . ?
C69 C67 H67 119.9 . . ?
C68 N2 C72 120.0 . . ?
C68 N2 Dy1 119.23(18) . . ?
C72 N2 Dy1 120.56(18) . . ?
C65 C68 N2 118.5(3) . . ?
C65 C68 C69 121.5(3) . . ?
N2 C68 C69 120.0 . . ?
C68 C69 C70 120.0 . . ?
C68 C69 C67 118.9(4) . . ?
C70 C69 C67 121.0(4) . . ?
C71 C70 C69 120.0 . . ?
C71 C70 H70 120.0 . . ?
C69 C70 H70 120.0 . . ?
C70 C71 C72 120.0 . . ?
C70 C71 H71 120.0 . . ?
C72 C71 H71 120.0 . . ?
C71 C72 N2 120.0 . . ?
C71 C72 H72 120.0 . . ?
N2 C72 H72 120.0 . . ?
O7 Dy1 O10 75.75(13) 2_575 . ?
O7 Dy1 O9 76.90(12) 2_575 2_575 ?
O10 Dy1 O9 131.89(12) . 2_575 ?
O7 Dy1 O12 144.52(13) 2_575 . ?
O10 Dy1 O12 76.44(12) . . ?
O9 Dy1 O12 138.58(13) 2_575 . ?
O7 Dy1 O8 124.45(13) 2_575 . ?
O10 Dy1 O8 86.91(16) . . ?
O9 Dy1 O8 77.07(15) 2_575 . ?
O12 Dy1 O8 75.20(14) . . ?
O7 Dy1 O11 152.73(13) 2_575 . ?
O10 Dy1 O11 129.24(12) . . ?
O9 Dy1 O11 89.24(12) 2_575 . ?
O12 Dy1 O11 53.60(12) . . ?
O8 Dy1 O11 73.46(14) . . ?
O7 Dy1 N1 78.69(12) 2_575 . ?
O10 Dy1 N1 77.37(12) . . ?
O9 Dy1 N1 133.66(12) 2_575 . ?
O12 Dy1 N1 74.07(12) . . ?
O8 Dy1 N1 147.98(13) . . ?
O11 Dy1 N1 95.10(12) . . ?
O7 Dy1 N2 79.16(12) 2_575 . ?
O10 Dy1 N2 136.32(12) . . ?
O9 Dy1 N2 74.12(12) 2_575 . ?
O12 Dy1 N2 107.25(13) . . ?
O8 Dy1 N2 136.65(15) . . ?
O11 Dy1 N2 74.46(12) . . ?
N1 Dy1 N2 62.93(10) . . ?
O7 Dy1 C45 164.91(14) 2_575 . ?
O10 Dy1 C45 102.08(14) . . ?
O9 Dy1 C45 113.73(14) 2_575 . ?
O12 Dy1 C45 26.55(14) . . ?
O8 Dy1 C45 69.81(14) . . ?
O11 Dy1 C45 27.28(14) . . ?
N1 Dy1 C45 86.25(13) . . ?
N2 Dy1 C45 93.17(14) . . ?
O7 Dy1 O7 75.86(13) 2_575 . ?
O10 Dy1 O7 67.09(11) . . ?
O9 Dy1 O7 68.28(12) 2_575 . ?
O12 Dy1 O7 112.39(12) . . ?
O8 Dy1 O7 48.98(11) . . ?
O11 Dy1 O7 120.88(12) . . ?
N1 Dy1 O7 140.23(10) . . ?
N2 Dy1 O7 138.49(10) . . ?
C45 Dy1 O7 117.44(13) . . ?
O7 Dy1 C37 100.51(14) 2_575 . ?
O10 Dy1 C37 76.86(15) . . ?
O9 Dy1 C37 70.21(15) 2_575 . ?
O12 Dy1 C37 94.16(15) . . ?
O8 Dy1 C37 24.06(14) . . ?
O11 Dy1 C37 96.58(15) . . ?
N1 Dy1 C37 153.56(14) . . ?
N2 Dy1 C37 143.33(14) . . ?
C45 Dy1 C37 93.41(15) . . ?
O7 Dy1 C37 24.95(12) . . ?
O3 Dy2 O6 74.98(12) 2_666 . ?
O3 Dy2 O5 78.07(13) 2_666 2_666 ?
O6 Dy2 O5 133.45(12) . 2_666 ?
O3 Dy2 O2 150.82(13) 2_666 . ?
O6 Dy2 O2 129.78(12) . . ?
O5 Dy2 O2 89.62(12) 2_666 . ?
O3 Dy2 O4 124.11(13) 2_666 . ?
O6 Dy2 O4 84.74(15) . . ?
O5 Dy2 O4 79.89(15) 2_666 . ?
O2 Dy2 O4 78.46(14) . . ?
O3 Dy2 O1 144.82(13) 2_666 . ?
O6 Dy2 O1 76.07(12) . . ?
O5 Dy2 O1 137.06(12) 2_666 . ?
O2 Dy2 O1 53.77(12) . . ?
O4 Dy2 O1 72.04(14) . . ?
O3 Dy2 N4 81.64(12) 2_666 . ?
O6 Dy2 N4 76.48(12) . . ?
O5 Dy2 N4 135.51(11) 2_666 . ?
O2 Dy2 N4 89.32(13) . . ?
O4 Dy2 N4 142.89(13) . . ?
O1 Dy2 N4 72.50(12) . . ?
O3 Dy2 N3 77.51(11) 2_666 . ?
O6 Dy2 N3 133.17(11) . . ?
O5 Dy2 N3 74.58(11) 2_666 . ?
O2 Dy2 N3 73.71(12) . . ?
O4 Dy2 N3 141.97(14) . . ?
O1 Dy2 N3 109.46(11) . . ?
N4 Dy2 N3 62.51(9) . . ?
O3 Dy2 O3 75.04(12) 2_666 . ?
O6 Dy2 O3 68.29(12) . . ?
O5 Dy2 O3 68.47(11) 2_666 . ?
O2 Dy2 O3 124.95(12) . . ?
O4 Dy2 O3 49.10(11) . . ?
O1 Dy2 O3 111.73(11) . . ?
N4 Dy2 O3 141.58(11) . . ?
N3 Dy2 O3 137.51(10) . . ?
O3 Dy2 C9 162.37(14) 2_666 . ?
O6 Dy2 C9 102.96(14) . . ?
O5 Dy2 C9 113.48(14) 2_666 . ?
O2 Dy2 C9 26.83(13) . . ?
O4 Dy2 C9 72.46(13) . . ?
O1 Dy2 C9 26.97(13) . . ?
N4 Dy2 C9 80.87(13) . . ?
N3 Dy2 C9 92.38(12) . . ?
O3 Dy2 C9 120.97(12) . . ?
O3 Dy2 C1 99.98(14) 2_666 . ?
O6 Dy2 C1 74.73(15) . . ?
O5 Dy2 C1 73.47(14) 2_666 . ?
O2 Dy2 C1 101.69(15) . . ?
O4 Dy2 C1 24.17(13) . . ?
O1 Dy2 C1 91.20(14) . . ?
N4 Dy2 C1 149.61(14) . . ?
N3 Dy2 C1 147.75(13) . . ?
O3 Dy2 C1 24.95(12) . . ?
C9 Dy2 C1 96.23(14) . . ?
C9 O1 Dy2 90.6(3) . . ?
C9 O2 Dy2 94.6(3) . . ?
C1 O3 Dy2 168.7(4) . 2_666 ?
C1 O3 Dy2 86.4(3) . . ?
Dy2 O3 Dy2 104.96(12) 2_666 . ?
C1 O4 Dy2 102.8(3) . . ?
C17 O5 Dy2 136.6(3) . 2_666 ?
C17 O6 Dy2 138.8(3) . . ?
C37 O7 Dy1 167.4(4) . 2_575 ?
C37 O7 Dy1 84.7(3) . . ?
Dy1 O7 Dy1 104.14(13) 2_575 . ?
C37 O8 Dy1 104.2(3) . . ?
C53 O9 Dy1 136.7(3) . 2_575 ?
C53 O10 Dy1 141.1(3) . . ?
C45 O11 Dy1 91.4(3) . . ?
C45 O12 Dy1 94.0(3) . . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O4 C1 C2 C3 83.2(6) . . . . ?
O3 C1 C2 C3 -87.1(6) . . . . ?
Dy2 C1 C2 C3 27.9(18) . . . . ?
O4 C1 C2 C7 -96.2(6) . . . . ?
O3 C1 C2 C7 93.6(5) . . . . ?
Dy2 C1 C2 C7 -151.5(14) . . . . ?
C7 C2 C3 C4 0.0 . . . . ?
C1 C2 C3 C4 -179.3(4) . . . . ?
C2 C3 C4 C5 0.0 . . . . ?
C3 C4 C5 C6 0.0 . . . . ?
C4 C5 C6 C7 0.0 . . . . ?
C5 C6 C7 C2 0.0 . . . . ?
C5 C6 C7 C8 178.3(6) . . . . ?
C3 C2 C7 C6 0.0 . . . . ?
C1 C2 C7 C6 179.4(4) . . . . ?
C3 C2 C7 C8 -178.4(5) . . . . ?
C1 C2 C7 C8 1.0(6) . . . . ?
O2 C9 C10 C11 -22.8(6) . . . . ?
O1 C9 C10 C11 156.9(4) . . . . ?
Dy2 C9 C10 C11 32(4) . . . . ?
O2 C9 C10 C15 154.3(4) . . . . ?
O1 C9 C10 C15 -26.0(6) . . . . ?
Dy2 C9 C10 C15 -151(4) . . . . ?
C15 C10 C11 C12 0.0 . . . . ?
C9 C10 C11 C12 177.2(4) . . . . ?
C10 C11 C12 C13 0.0 . . . . ?
C11 C12 C13 C14 0.0 . . . . ?
C12 C13 C14 C15 0.0 . . . . ?
C13 C14 C15 C10 0.0 . . . . ?
C13 C14 C15 C16 -177.9(6) . . . . ?
C11 C10 C15 C14 0.0 . . . . ?
C9 C10 C15 C14 -177.0(4) . . . . ?
C11 C10 C15 C16 177.8(6) . . . . ?
C9 C10 C15 C16 0.8(6) . . . . ?
O6 C17 C18 C19 148.2(4) . . . . ?
O5 C17 C18 C19 -30.9(5) . . . . ?
O6 C17 C18 C23 -26.9(6) . . . . ?
O5 C17 C18 C23 154.0(4) . . . . ?
C23 C18 C19 C20 0.0 . . . . ?
C17 C18 C19 C20 -175.3(4) . . . . ?
C18 C19 C20 C21 0.0 . . . . ?
C19 C20 C21 C22 0.0 . . . . ?
C20 C21 C22 C23 0.0 . . . . ?
C21 C22 C23 C18 0.0 . . . . ?
C21 C22 C23 C24 -175.6(5) . . . . ?
C19 C18 C23 C22 0.0 . . . . ?
C17 C18 C23 C22 174.9(4) . . . . ?
C19 C18 C23 C24 175.2(6) . . . . ?
C17 C18 C23 C24 -9.8(6) . . . . ?
C29 N4 C25 C26 0.0 . . . . ?
Dy2 N4 C25 C26 -178.7(2) . . . . ?
N4 C25 C26 C27 0.0 . . . . ?
C25 C26 C27 C28 0.0 . . . . ?
C26 C27 C28 C29 0.0 . . . . ?
C26 C27 C28 C30 -179.9(5) . . . . ?
C27 C28 C29 C32 -177.1(4) . . . . ?
C30 C28 C29 C32 2.8(5) . . . . ?
C27 C28 C29 N4 0.0 . . . . ?
C30 C28 C29 N4 179.9(4) . . . . ?
C25 N4 C29 C32 177.2(4) . . . . ?
Dy2 N4 C29 C32 -4.2(3) . . . . ?
C25 N4 C29 C28 0.0 . . . . ?
Dy2 N4 C29 C28 178.6(2) . . . . ?
C29 C28 C30 C31 -2.3(8) . . . . ?
C27 C28 C30 C31 177.6(5) . . . . ?
C28 C30 C31 C33 0.1(9) . . . . ?
C28 C29 C32 N3 176.6(2) . . . . ?
N4 C29 C32 N3 -0.5(4) . . . . ?
C28 C29 C32 C33 -1.2(4) . . . . ?
N4 C29 C32 C33 -178.3(2) . . . . ?
C36 N3 C32 C29 -177.8(3) . . . . ?
Dy2 N3 C32 C29 4.7(3) . . . . ?
C36 N3 C32 C33 0.0 . . . . ?
Dy2 N3 C32 C33 -177.5(2) . . . . ?
C29 C32 C33 C34 177.8(3) . . . . ?
N3 C32 C33 C34 0.0 . . . . ?
C29 C32 C33 C31 -1.1(5) . . . . ?
N3 C32 C33 C31 -178.8(4) . . . . ?
C30 C31 C33 C34 -177.2(5) . . . . ?
C30 C31 C33 C32 1.6(8) . . . . ?
C32 C33 C34 C35 0.0 . . . . ?
C31 C33 C34 C35 178.8(4) . . . . ?
C33 C34 C35 C36 0.0 . . . . ?
C34 C35 C36 N3 0.0 . . . . ?
C32 N3 C36 C35 0.0 . . . . ?
Dy2 N3 C36 C35 177.4(2) . . . . ?
O8 C37 C38 C39 -76.3(7) . . . . ?
O7 C37 C38 C39 98.5(6) . . . . ?
Dy1 C37 C38 C39 -41.7(19) . . . . ?
O8 C37 C38 C43 102.5(6) . . . . ?
O7 C37 C38 C43 -82.7(6) . . . . ?
Dy1 C37 C38 C43 137.1(16) . . . . ?
C43 C38 C39 C40 0.0 . . . . ?
C37 C38 C39 C40 178.8(5) . . . . ?
C38 C39 C40 C41 0.0 . . . . ?
C39 C40 C41 C42 0.0 . . . . ?
C40 C41 C42 C43 0.0 . . . . ?
C41 C42 C43 C38 0.0 . . . . ?
C41 C42 C43 C44 -177.6(7) . . . . ?
C39 C38 C43 C42 0.0 . . . . ?
C37 C38 C43 C42 -178.8(4) . . . . ?
C39 C38 C43 C44 177.5(7) . . . . ?
C37 C38 C43 C44 -1.3(7) . . . . ?
O12 C45 C46 C47 -178.1(4) . . . . ?
O11 C45 C46 C47 2.1(6) . . . . ?
Dy1 C45 C46 C47 90(2) . . . . ?
O12 C45 C46 C51 6.7(7) . . . . ?
O11 C45 C46 C51 -173.1(4) . . . . ?
Dy1 C45 C46 C51 -85(2) . . . . ?
C51 C46 C47 C48 0.0 . . . . ?
C45 C46 C47 C48 -175.3(4) . . . . ?
C46 C47 C48 C49 0.0 . . . . ?
C47 C48 C49 C50 0.0 . . . . ?
C48 C49 C50 C51 0.0 . . . . ?
C49 C50 C51 C46 0.0 . . . . ?
C49 C50 C51 C52 -179.3(6) . . . . ?
C47 C46 C51 C50 0.0 . . . . ?
C45 C46 C51 C50 175.0(4) . . . . ?
C47 C46 C51 C52 179.2(7) . . . . ?
C45 C46 C51 C52 -5.8(7) . . . . ?
O10 C53 C54 C55 150.5(4) . . . . ?
O9 C53 C54 C55 -27.5(5) . . . . ?
O10 C53 C54 C59 -25.9(6) . . . . ?
O9 C53 C54 C59 156.0(4) . . . . ?
C59 C54 C55 C56 0.0 . . . . ?
C53 C54 C55 C56 -176.6(4) . . . . ?
C54 C55 C56 C57 0.0 . . . . ?
C55 C56 C57 C58 0.0 . . . . ?
C56 C57 C58 C59 0.0 . . . . ?
C57 C58 C59 C54 0.0 . . . . ?
C57 C58 C59 C60 -175.9(4) . . . . ?
C55 C54 C59 C58 0.0 . . . . ?
C53 C54 C59 C58 176.3(4) . . . . ?
C55 C54 C59 C60 175.7(5) . . . . ?
C53 C54 C59 C60 -8.0(5) . . . . ?
C65 N1 C61 C62 0.0 . . . . ?
Dy1 N1 C61 C62 -174.5(2) . . . . ?
N1 C61 C62 C63 0.0 . . . . ?
C61 C62 C63 C64 0.0 . . . . ?
C62 C63 C64 C65 0.0 . . . . ?
C62 C63 C64 C66 180.0(5) . . . . ?
C63 C64 C65 C68 -176.2(4) . . . . ?
C66 C64 C65 C68 3.8(5) . . . . ?
C63 C64 C65 N1 0.0 . . . . ?
C66 C64 C65 N1 -180.0(4) . . . . ?
C61 N1 C65 C68 176.2(4) . . . . ?
Dy1 N1 C65 C68 -9.2(3) . . . . ?
C61 N1 C65 C64 0.0 . . . . ?
Dy1 N1 C65 C64 174.6(2) . . . . ?
C63 C64 C66 C67 176.6(5) . . . . ?
C65 C64 C66 C67 -3.4(8) . . . . ?
C64 C66 C67 C69 -0.7(10) . . . . ?
C64 C65 C68 N2 176.8(2) . . . . ?
N1 C65 C68 N2 0.6(4) . . . . ?
C64 C65 C68 C69 -0.2(4) . . . . ?
N1 C65 C68 C69 -176.4(2) . . . . ?
C72 N2 C68 C65 -177.0(4) . . . . ?
Dy1 N2 C68 C65 8.3(4) . . . . ?
C72 N2 C68 C69 0.0 . . . . ?
Dy1 N2 C68 C69 -174.7(2) . . . . ?
C65 C68 C69 C70 176.9(4) . . . . ?
N2 C68 C69 C70 0.0 . . . . ?
C65 C68 C69 C67 -4.0(5) . . . . ?
N2 C68 C69 C67 179.1(5) . . . . ?
C66 C67 C69 C68 4.4(8) . . . . ?
C66 C67 C69 C70 -176.5(5) . . . . ?
C68 C69 C70 C71 0.0 . . . . ?
C67 C69 C70 C71 -179.1(5) . . . . ?
C69 C70 C71 C72 0.0 . . . . ?
C70 C71 C72 N2 0.0 . . . . ?
C68 N2 C72 C71 0.0 . . . . ?
Dy1 N2 C72 C71 174.7(2) . . . . ?
C61 N1 Dy1 O7 100.2(2) . . . 2_575 ?
C65 N1 Dy1 O7 -74.4(2) . . . 2_575 ?
C61 N1 Dy1 O10 22.4(2) . . . . ?
C65 N1 Dy1 O10 -152.1(2) . . . . ?
C61 N1 Dy1 O9 159.5(2) . . . 2_575 ?
C65 N1 Dy1 O9 -15.1(3) . . . 2_575 ?
C61 N1 Dy1 O12 -56.9(2) . . . . ?
C65 N1 Dy1 O12 128.6(2) . . . . ?
C61 N1 Dy1 O8 -40.0(3) . . . . ?
C65 N1 Dy1 O8 145.4(3) . . . . ?
C61 N1 Dy1 O11 -106.7(2) . . . . ?
C65 N1 Dy1 O11 78.8(2) . . . . ?
C61 N1 Dy1 N2 -176.4(2) . . . . ?
C65 N1 Dy1 N2 9.10(18) . . . . ?
C61 N1 Dy1 C45 -80.9(2) . . . . ?
C65 N1 Dy1 C45 104.6(2) . . . . ?
C61 N1 Dy1 O7 49.2(3) . . . . ?
C65 N1 Dy1 O7 -125.4(2) . . . . ?
C61 N1 Dy1 C37 9.3(4) . . . . ?
C65 N1 Dy1 C37 -165.3(3) . . . . ?
C68 N2 Dy1 O7 73.9(2) . . . 2_575 ?
C72 N2 Dy1 O7 -100.8(2) . . . 2_575 ?
C68 N2 Dy1 O10 18.2(3) . . . . ?
C72 N2 Dy1 O10 -156.5(2) . . . . ?
C68 N2 Dy1 O9 153.2(2) . . . 2_575 ?
C72 N2 Dy1 O9 -21.5(2) . . . 2_575 ?
C68 N2 Dy1 O12 -70.1(2) . . . . ?
C72 N2 Dy1 O12 115.2(2) . . . . ?
C68 N2 Dy1 O8 -156.6(2) . . . . ?
C72 N2 Dy1 O8 28.7(3) . . . . ?
C68 N2 Dy1 O11 -113.1(2) . . . . ?
C72 N2 Dy1 O11 72.2(2) . . . . ?
C68 N2 Dy1 N1 -8.83(19) . . . . ?
C72 N2 Dy1 N1 176.5(2) . . . . ?
C68 N2 Dy1 C45 -93.0(2) . . . . ?
C72 N2 Dy1 C45 92.3(2) . . . . ?
C68 N2 Dy1 O7 127.6(2) . . . . ?
C72 N2 Dy1 O7 -47.1(3) . . . . ?
C68 N2 Dy1 C37 167.0(2) . . . . ?
C72 N2 Dy1 C37 -7.7(3) . . . . ?
O12 C45 Dy1 O7 64.9(7) . . . 2_575 ?
O11 C45 Dy1 O7 -104.9(6) . . . 2_575 ?
C46 C45 Dy1 O7 162(2) . . . 2_575 ?
O12 C45 Dy1 O10 -15.2(3) . . . . ?
O11 C45 Dy1 O10 175.0(3) . . . . ?
C46 C45 Dy1 O10 82(2) . . . . ?
O12 C45 Dy1 O9 -162.3(3) . . . 2_575 ?
O11 C45 Dy1 O9 27.9(3) . . . 2_575 ?
C46 C45 Dy1 O9 -65(2) . . . 2_575 ?
O11 C45 Dy1 O12 -169.8(5) . . . . ?
C46 C45 Dy1 O12 97(2) . . . . ?
O12 C45 Dy1 O8 -97.3(4) . . . . ?
O11 C45 Dy1 O8 92.9(3) . . . . ?
C46 C45 Dy1 O8 0(2) . . . . ?
O12 C45 Dy1 O11 169.8(5) . . . . ?
C46 C45 Dy1 O11 -93(2) . . . . ?
O12 C45 Dy1 N1 61.0(3) . . . . ?
O11 C45 Dy1 N1 -108.7(3) . . . . ?
C46 C45 Dy1 N1 158(2) . . . . ?
O12 C45 Dy1 N2 123.6(3) . . . . ?
O11 C45 Dy1 N2 -46.2(3) . . . . ?
C46 C45 Dy1 N2 -139(2) . . . . ?
O12 C45 Dy1 O7 -85.5(3) . . . . ?
O11 C45 Dy1 O7 104.8(3) . . . . ?
C46 C45 Dy1 O7 11(2) . . . . ?
O12 C45 Dy1 C37 -92.5(3) . . . . ?
O11 C45 Dy1 C37 97.7(3) . . . . ?
C46 C45 Dy1 C37 4(2) . . . . ?
O8 C37 Dy1 O7 174.7(4) . . . 2_575 ?
O7 C37 Dy1 O7 -9.0(4) . . . 2_575 ?
C38 C37 Dy1 O7 135.0(18) . . . 2_575 ?
O8 C37 Dy1 O10 -112.8(4) . . . . ?
O7 C37 Dy1 O10 63.5(3) . . . . ?
C38 C37 Dy1 O10 -152.5(18) . . . . ?
O8 C37 Dy1 O9 102.9(4) . . . 2_575 ?
O7 C37 Dy1 O9 -80.9(3) . . . 2_575 ?
C38 C37 Dy1 O9 63.1(18) . . . 2_575 ?
O8 C37 Dy1 O12 -37.7(4) . . . . ?
O7 C37 Dy1 O12 138.5(3) . . . . ?
C38 C37 Dy1 O12 -77.5(18) . . . . ?
O7 C37 Dy1 O8 176.3(7) . . . . ?
C38 C37 Dy1 O8 -39.7(16) . . . . ?
O8 C37 Dy1 O11 16.1(4) . . . . ?
O7 C37 Dy1 O11 -167.7(3) . . . . ?
C38 C37 Dy1 O11 -23.7(18) . . . . ?
O8 C37 Dy1 N1 -99.6(5) . . . . ?
O7 C37 Dy1 N1 76.7(4) . . . . ?
C38 C37 Dy1 N1 -139.3(17) . . . . ?
O8 C37 Dy1 N2 88.8(5) . . . . ?
O7 C37 Dy1 N2 -94.9(4) . . . . ?
C38 C37 Dy1 N2 49.1(19) . . . . ?
O8 C37 Dy1 C45 -11.2(4) . . . . ?
O7 C37 Dy1 C45 165.1(3) . . . . ?
C38 C37 Dy1 C45 -50.9(18) . . . . ?
O8 C37 Dy1 O7 -176.3(7) . . . . ?
C38 C37 Dy1 O7 144(2) . . . . ?
C25 N4 Dy2 O3 103.0(2) . . . 2_666 ?
C29 N4 Dy2 O3 -75.7(2) . . . 2_666 ?
C25 N4 Dy2 O6 26.50(19) . . . . ?
C29 N4 Dy2 O6 -152.2(2) . . . . ?
C25 N4 Dy2 O5 166.4(2) . . . 2_666 ?
C29 N4 Dy2 O5 -12.3(3) . . . 2_666 ?
C25 N4 Dy2 O2 -104.9(2) . . . . ?
C29 N4 Dy2 O2 76.5(2) . . . . ?
C25 N4 Dy2 O4 -35.2(3) . . . . ?
C29 N4 Dy2 O4 146.2(2) . . . . ?
C25 N4 Dy2 O1 -52.9(2) . . . . ?
C29 N4 Dy2 O1 128.4(2) . . . . ?
C25 N4 Dy2 N3 -176.8(2) . . . . ?
C29 N4 Dy2 N3 4.53(18) . . . . ?
C25 N4 Dy2 O3 50.2(3) . . . . ?
C29 N4 Dy2 O3 -128.4(2) . . . . ?
C25 N4 Dy2 C9 -79.3(2) . . . . ?
C29 N4 Dy2 C9 102.1(2) . . . . ?
C25 N4 Dy2 C1 7.5(3) . . . . ?
C29 N4 Dy2 C1 -171.2(2) . . . . ?
C32 N3 Dy2 O3 82.35(19) . . . 2_666 ?
C36 N3 Dy2 O3 -95.1(2) . . . 2_666 ?
C32 N3 Dy2 O6 27.2(2) . . . . ?
C36 N3 Dy2 O6 -150.23(19) . . . . ?
C32 N3 Dy2 O5 163.2(2) . . . 2_666 ?
C36 N3 Dy2 O5 -14.22(18) . . . 2_666 ?
C32 N3 Dy2 O2 -102.57(19) . . . . ?
C36 N3 Dy2 O2 80.0(2) . . . . ?
C32 N3 Dy2 O4 -147.2(2) . . . . ?
C36 N3 Dy2 O4 35.4(3) . . . . ?
C32 N3 Dy2 O1 -61.71(19) . . . . ?
C36 N3 Dy2 O1 120.84(19) . . . . ?
C32 N3 Dy2 N4 -4.63(17) . . . . ?
C36 N3 Dy2 N4 177.9(2) . . . . ?
C32 N3 Dy2 O3 133.06(18) . . . . ?
C36 N3 Dy2 O3 -44.4(2) . . . . ?
C32 N3 Dy2 C9 -83.06(19) . . . . ?
C36 N3 Dy2 C9 99.5(2) . . . . ?
C32 N3 Dy2 C1 171.3(2) . . . . ?
C36 N3 Dy2 C1 -6.1(3) . . . . ?
O2 C9 Dy2 O3 -99.5(5) . . . 2_666 ?
O1 C9 Dy2 O3 76.5(6) . . . 2_666 ?
C10 C9 Dy2 O3 -156(4) . . . 2_666 ?
O2 C9 Dy2 O6 179.3(3) . . . . ?
O1 C9 Dy2 O6 -4.6(3) . . . . ?
C10 C9 Dy2 O6 122(4) . . . . ?
O2 C9 Dy2 O5 29.0(3) . . . 2_666 ?
O1 C9 Dy2 O5 -155.0(3) . . . 2_666 ?
C10 C9 Dy2 O5 -28(4) . . . 2_666 ?
O1 C9 Dy2 O2 176.1(5) . . . . ?
C10 C9 Dy2 O2 -57(4) . . . . ?
O2 C9 Dy2 O4 99.2(3) . . . . ?
O1 C9 Dy2 O4 -84.7(3) . . . . ?
C10 C9 Dy2 O4 42(4) . . . . ?
O2 C9 Dy2 O1 -176.1(5) . . . . ?
C10 C9 Dy2 O1 127(4) . . . . ?
O2 C9 Dy2 N4 -106.9(3) . . . . ?
O1 C9 Dy2 N4 69.1(3) . . . . ?
C10 C9 Dy2 N4 -164(4) . . . . ?
O2 C9 Dy2 N3 -45.2(3) . . . . ?
O1 C9 Dy2 N3 130.8(3) . . . . ?
C10 C9 Dy2 N3 -102(4) . . . . ?
O2 C9 Dy2 O3 107.1(3) . . . . ?
O1 C9 Dy2 O3 -76.9(3) . . . . ?
C10 C9 Dy2 O3 50(4) . . . . ?
O2 C9 Dy2 C1 103.6(3) . . . . ?
O1 C9 Dy2 C1 -80.3(3) . . . . ?
C10 C9 Dy2 C1 47(4) . . . . ?
O4 C1 Dy2 O3 176.6(4) . . . 2_666 ?
O3 C1 Dy2 O3 -0.1(4) . . . 2_666 ?
C2 C1 Dy2 O3 -120.4(16) . . . 2_666 ?
O4 C1 Dy2 O6 -112.1(4) . . . . ?
O3 C1 Dy2 O6 71.2(3) . . . . ?
C2 C1 Dy2 O6 -49.2(16) . . . . ?
O4 C1 Dy2 O5 102.4(4) . . . 2_666 ?
O3 C1 Dy2 O5 -74.4(3) . . . 2_666 ?
C2 C1 Dy2 O5 165.3(16) . . . 2_666 ?
O4 C1 Dy2 O2 16.3(4) . . . . ?
O3 C1 Dy2 O2 -160.4(3) . . . . ?
C2 C1 Dy2 O2 79.2(16) . . . . ?
O3 C1 Dy2 O4 -176.7(6) . . . . ?
C2 C1 Dy2 O4 62.9(15) . . . . ?
O4 C1 Dy2 O1 -36.9(4) . . . . ?
O3 C1 Dy2 O1 146.4(3) . . . . ?
C2 C1 Dy2 O1 26.0(16) . . . . ?
O4 C1 Dy2 N4 -92.9(5) . . . . ?
O3 C1 Dy2 N4 90.4(4) . . . . ?
C2 C1 Dy2 N4 -30.0(17) . . . . ?
O4 C1 Dy2 N3 94.2(4) . . . . ?
O3 C1 Dy2 N3 -82.5(4) . . . . ?
C2 C1 Dy2 N3 157.2(15) . . . . ?
O4 C1 Dy2 O3 176.7(6) . . . . ?
C2 C1 Dy2 O3 -120.4(17) . . . . ?
O4 C1 Dy2 C9 -10.3(4) . . . . ?
O3 C1 Dy2 C9 173.0(3) . . . . ?
C2 C1 Dy2 C9 52.6(16) . . . . ?
O2 C9 O1 Dy2 3.9(5) . . . . ?
C10 C9 O1 Dy2 -175.7(4) . . . . ?
O3 Dy2 O1 C9 -149.2(3) 2_666 . . . ?
O6 Dy2 O1 C9 175.4(3) . . . . ?
O5 Dy2 O1 C9 34.7(4) 2_666 . . . ?
O2 Dy2 O1 C9 -2.2(3) . . . . ?
O4 Dy2 O1 C9 86.5(3) . . . . ?
N4 Dy2 O1 C9 -104.7(3) . . . . ?
N3 Dy2 O1 C9 -53.3(3) . . . . ?
O3 Dy2 O1 C9 116.0(3) . . . . ?
C1 Dy2 O1 C9 101.4(3) . . . . ?
O1 C9 O2 Dy2 -4.1(5) . . . . ?
C10 C9 O2 Dy2 175.6(3) . . . . ?
O3 Dy2 O2 C9 142.2(3) 2_666 . . . ?
O6 Dy2 O2 C9 -0.8(4) . . . . ?
O5 Dy2 O2 C9 -153.6(3) 2_666 . . . ?
O4 Dy2 O2 C9 -73.9(3) . . . . ?
O1 Dy2 O2 C9 2.2(3) . . . . ?
N4 Dy2 O2 C9 70.9(3) . . . . ?
N3 Dy2 O2 C9 132.3(3) . . . . ?
O3 Dy2 O2 C9 -90.5(3) . . . . ?
C1 Dy2 O2 C9 -80.6(3) . . . . ?
O4 C1 O3 Dy2 176.5(15) . . . 2_666 ?
C2 C1 O3 Dy2 -13(2) . . . 2_666 ?
Dy2 C1 O3 Dy2 180(100) . . . 2_666 ?
O4 C1 O3 Dy2 -3.1(6) . . . . ?
C2 C1 O3 Dy2 167.0(5) . . . . ?
O3 Dy2 O3 C1 179.9(4) 2_666 . . . ?
O6 Dy2 O3 C1 -100.6(3) . . . . ?
O5 Dy2 O3 C1 97.1(3) 2_666 . . . ?
O2 Dy2 O3 C1 23.6(4) . . . . ?
O4 Dy2 O3 C1 1.8(3) . . . . ?
O1 Dy2 O3 C1 -36.6(3) . . . . ?
N4 Dy2 O3 C1 -125.5(3) . . . . ?
N3 Dy2 O3 C1 128.4(3) . . . . ?
C9 Dy2 O3 C1 -8.2(4) . . . . ?
O3 Dy2 O3 Dy2 0.000(1) 2_666 . . 2_666 ?
O6 Dy2 O3 Dy2 79.49(15) . . . 2_666 ?
O5 Dy2 O3 Dy2 -82.84(15) 2_666 . . 2_666 ?
O2 Dy2 O3 Dy2 -156.31(12) . . . 2_666 ?
O4 Dy2 O3 Dy2 -178.1(2) . . . 2_666 ?
O1 Dy2 O3 Dy2 143.54(13) . . . 2_666 ?
N4 Dy2 O3 Dy2 54.6(2) . . . 2_666 ?
N3 Dy2 O3 Dy2 -51.5(2) . . . 2_666 ?
C9 Dy2 O3 Dy2 171.92(14) . . . 2_666 ?
C1 Dy2 O3 Dy2 -179.9(4) . . . 2_666 ?
O3 C1 O4 Dy2 3.6(7) . . . . ?
C2 C1 O4 Dy2 -166.3(5) . . . . ?
O3 Dy2 O4 C1 -4.0(5) 2_666 . . . ?
O6 Dy2 O4 C1 63.9(4) . . . . ?
O5 Dy2 O4 C1 -72.0(4) 2_666 . . . ?
O2 Dy2 O4 C1 -163.7(4) . . . . ?
O1 Dy2 O4 C1 140.9(4) . . . . ?
N4 Dy2 O4 C1 123.1(4) . . . . ?
N3 Dy2 O4 C1 -120.2(4) . . . . ?
O3 Dy2 O4 C1 -1.8(4) . . . . ?
C9 Dy2 O4 C1 169.2(5) . . . . ?
O6 C17 O5 Dy2 0.6(8) . . . 2_666 ?
C18 C17 O5 Dy2 179.6(3) . . . 2_666 ?
O5 C17 O6 Dy2 25.9(8) . . . . ?
C18 C17 O6 Dy2 -153.2(3) . . . . ?
O3 Dy2 O6 C17 19.6(5) 2_666 . . . ?
O5 Dy2 O6 C17 -37.1(6) 2_666 . . . ?
O2 Dy2 O6 C17 -178.1(5) . . . . ?
O4 Dy2 O6 C17 -107.9(5) . . . . ?
O1 Dy2 O6 C17 179.4(5) . . . . ?
N4 Dy2 O6 C17 104.4(5) . . . . ?
N3 Dy2 O6 C17 75.6(5) . . . . ?
O3 Dy2 O6 C17 -60.0(5) . . . . ?
C9 Dy2 O6 C17 -178.5(5) . . . . ?
C1 Dy2 O6 C17 -85.5(5) . . . . ?
O8 C37 O7 Dy1 138.7(15) . . . 2_575 ?
C38 C37 O7 Dy1 -36(2) . . . 2_575 ?
Dy1 C37 O7 Dy1 135.3(18) . . . 2_575 ?
O8 C37 O7 Dy1 3.4(6) . . . . ?
C38 C37 O7 Dy1 -171.1(6) . . . . ?
O7 Dy1 O7 C37 170.9(4) 2_575 . . . ?
O10 Dy1 O7 C37 -108.9(4) . . . . ?
O9 Dy1 O7 C37 89.6(3) 2_575 . . . ?
O12 Dy1 O7 C37 -45.6(4) . . . . ?
O8 Dy1 O7 C37 -2.0(4) . . . . ?
O11 Dy1 O7 C37 14.3(4) . . . . ?
N1 Dy1 O7 C37 -137.4(3) . . . . ?
N2 Dy1 O7 C37 116.1(3) . . . . ?
C45 Dy1 O7 C37 -16.8(4) . . . . ?
O7 Dy1 O7 Dy1 0.0 2_575 . . 2_575 ?
O10 Dy1 O7 Dy1 80.27(15) . . . 2_575 ?
O9 Dy1 O7 Dy1 -81.30(15) 2_575 . . 2_575 ?
O12 Dy1 O7 Dy1 143.56(13) . . . 2_575 ?
O8 Dy1 O7 Dy1 -172.9(2) . . . 2_575 ?
O11 Dy1 O7 Dy1 -156.54(13) . . . 2_575 ?
N1 Dy1 O7 Dy1 51.8(2) . . . 2_575 ?
N2 Dy1 O7 Dy1 -54.7(2) . . . 2_575 ?
C45 Dy1 O7 Dy1 172.36(15) . . . 2_575 ?
C37 Dy1 O7 Dy1 -170.9(4) . . . 2_575 ?
O7 C37 O8 Dy1 -4.1(7) . . . . ?
C38 C37 O8 Dy1 170.6(5) . . . . ?
O7 Dy1 O8 C37 -6.3(5) 2_575 . . . ?
O10 Dy1 O8 C37 64.1(4) . . . . ?
O9 Dy1 O8 C37 -70.3(4) 2_575 . . . ?
O12 Dy1 O8 C37 140.8(4) . . . . ?
O11 Dy1 O8 C37 -163.3(4) . . . . ?
N1 Dy1 O8 C37 124.1(4) . . . . ?
N2 Dy1 O8 C37 -119.6(4) . . . . ?
C45 Dy1 O8 C37 168.1(5) . . . . ?
O7 Dy1 O8 C37 2.1(4) . . . . ?
O10 C53 O9 Dy1 15.3(9) . . . 2_575 ?
C54 C53 O9 Dy1 -166.9(3) . . . 2_575 ?
O9 C53 O10 Dy1 12.3(9) . . . . ?
C54 C53 O10 Dy1 -165.5(3) . . . . ?
O7 Dy1 O10 C53 26.0(5) 2_575 . . . ?
O9 Dy1 O10 C53 -31.1(6) 2_575 . . . ?
O12 Dy1 O10 C53 -176.2(6) . . . . ?
O8 Dy1 O10 C53 -100.7(5) . . . . ?
O11 Dy1 O10 C53 -166.4(5) . . . . ?
N1 Dy1 O10 C53 107.4(6) . . . . ?
N2 Dy1 O10 C53 82.9(6) . . . . ?
C45 Dy1 O10 C53 -169.3(5) . . . . ?
O7 Dy1 O10 C53 -54.4(5) . . . . ?
C37 Dy1 O10 C53 -78.6(5) . . . . ?
O12 C45 O11 Dy1 -10.2(5) . . . . ?
C46 C45 O11 Dy1 169.6(4) . . . . ?
O7 Dy1 O11 C45 146.7(3) 2_575 . . . ?
O10 Dy1 O11 C45 -6.3(4) . . . . ?
O9 Dy1 O11 C45 -154.6(3) 2_575 . . . ?
O12 Dy1 O11 C45 5.7(3) . . . . ?
O8 Dy1 O11 C45 -77.9(3) . . . . ?
N1 Dy1 O11 C45 71.6(3) . . . . ?
N2 Dy1 O11 C45 131.6(3) . . . . ?
O7 Dy1 O11 C45 -90.7(3) . . . . ?
C37 Dy1 O11 C45 -84.7(3) . . . . ?
O11 C45 O12 Dy1 10.4(5) . . . . ?
C46 C45 O12 Dy1 -169.5(4) . . . . ?
O7 Dy1 O12 C45 -156.0(3) 2_575 . . . ?
O10 Dy1 O12 C45 164.7(3) . . . . ?
O9 Dy1 O12 C45 24.8(4) 2_575 . . . ?
O8 Dy1 O12 C45 74.3(3) . . . . ?
O11 Dy1 O12 C45 -5.8(3) . . . . ?
N1 Dy1 O12 C45 -114.8(3) . . . . ?
N2 Dy1 O12 C45 -60.5(3) . . . . ?
O7 Dy1 O12 C45 106.9(3) . . . . ?
C37 Dy1 O12 C45 89.3(3) . . . . ?
_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         1.263
_refine_diff_density_min         -0.900
_refine_diff_density_rms         0.095


data_2_1(calcination)
_database_code_depnum_ccdc_archive 'CCDC 932128'
#TrackingRef '2_1(calcination).cif'
_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C72 H58 Dy2 N4 O12'
_chemical_formula_weight         1496.22
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
_cell_length_a                   13.1721(9)
_cell_length_b                   14.3833(10)
_cell_length_c                   17.4134(12)
_cell_angle_alpha                83.021(4)
_cell_angle_beta                 83.729(4)
_cell_angle_gamma                72.832(4)
_cell_volume                     3119.4(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    9988
_cell_measurement_theta_min      2.36
_cell_measurement_theta_max      25.58
_exptl_crystal_description       Block
_exptl_crystal_colour            Colorless
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.18
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.593
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1492
_exptl_absorpt_coefficient_mu    2.445
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.6406
_exptl_absorpt_correction_T_max  0.6673
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_special_details           
;
?
;
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            45588
_diffrn_reflns_av_R_equivalents  0.0356
_diffrn_reflns_av_unetI/netI     0.0300
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         1.49
_diffrn_reflns_theta_max         25.00
_reflns_number_total             10991
_reflns_number_gt                8930
_reflns_threshold_expression     >2sigma(I)
_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0417P)^2^+4.4846P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         10991
_refine_ls_number_parameters     697
_refine_ls_number_restraints     44
_refine_ls_R_factor_all          0.0435
_refine_ls_R_factor_gt           0.0322
_refine_ls_wR_factor_ref         0.0900
_refine_ls_wR_factor_gt          0.0831
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_restrained_S_all      1.102
_refine_ls_shift/su_max          0.018
_refine_ls_shift/su_mean         0.000
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.5658(5) 0.1055(4) 0.5806(3) 0.0586(14) Uani 1 1 d . . .
C2 C 0.6223(5) 0.1080(3) 0.6474(3) 0.087(2) Uani 1 1 d G . .
C3 C 0.5724(5) 0.1135(4) 0.7219(3) 0.125(3) Uani 1 1 d GU . .
H3 H 0.5010 0.1148 0.7305 0.149 Uiso 1 1 calc R . .
C4 C 0.6291(6) 0.1171(5) 0.7838(3) 0.161(4) Uani 1 1 d GU . .
H4 H 0.5957 0.1208 0.8337 0.193 Uiso 1 1 calc R . .
C5 C 0.7357(6) 0.1151(4) 0.7711(4) 0.136(3) Uani 1 1 d GU . .
H5 H 0.7736 0.1175 0.8124 0.163 Uiso 1 1 calc R . .
C6 C 0.7856(5) 0.1096(4) 0.6965(4) 0.137(3) Uani 1 1 d GU . .
H6 H 0.8569 0.1083 0.6880 0.164 Uiso 1 1 calc R . .
C7 C 0.7289(5) 0.1061(4) 0.6346(3) 0.115(4) Uani 1 1 d GD . .
C8 C 0.7798(8) 0.1038(8) 0.5594(6) 0.153(4) Uani 1 1 d D . .
H8A H 0.7963 0.1644 0.5440 0.229 Uiso 1 1 calc R . .
H8B H 0.7335 0.0945 0.5240 0.229 Uiso 1 1 calc R . .
H8C H 0.8444 0.0508 0.5588 0.229 Uiso 1 1 calc R . .
C9 C 0.3740(4) 0.3365(4) 0.4439(3) 0.0496(12) Uani 1 1 d . . .
C10 C 0.3658(3) 0.4435(2) 0.4439(2) 0.0611(15) Uani 1 1 d G . .
C11 C 0.2826(3) 0.4975(3) 0.4910(3) 0.086(2) Uani 1 1 d G . .
H11 H 0.2331 0.4684 0.5178 0.103 Uiso 1 1 calc R . .
C12 C 0.2734(4) 0.5949(3) 0.4981(3) 0.121(3) Uani 1 1 d G . .
H12 H 0.2178 0.6310 0.5296 0.146 Uiso 1 1 calc R . .
C13 C 0.3475(5) 0.6384(2) 0.4581(4) 0.119(3) Uani 1 1 d G . .
H13 H 0.3413 0.7035 0.4629 0.143 Uiso 1 1 calc R . .
C14 C 0.4307(4) 0.5844(3) 0.4110(3) 0.100(3) Uani 1 1 d G . .
H14 H 0.4802 0.6135 0.3843 0.120 Uiso 1 1 calc R . .
C15 C 0.4399(3) 0.4870(3) 0.4040(2) 0.0791(19) Uani 1 1 d G . .
C16 C 0.5317(8) 0.4365(7) 0.3506(6) 0.132(4) Uani 1 1 d . . .
H16A H 0.5748 0.4795 0.3329 0.199 Uiso 1 1 calc R . .
H16B H 0.5051 0.4193 0.3068 0.199 Uiso 1 1 calc R . .
H16C H 0.5741 0.3784 0.3779 0.199 Uiso 1 1 calc R . .
C17 C 0.3519(4) -0.0050(4) 0.6193(3) 0.0448(11) Uani 1 1 d . . .
C18 C 0.2711(3) -0.0102(2) 0.68646(16) 0.0475(12) Uani 1 1 d G . .
C19 C 0.2250(3) 0.0753(2) 0.7223(2) 0.0678(16) Uani 1 1 d G . .
H19 H 0.2416 0.1325 0.7027 0.081 Uiso 1 1 calc R . .
C20 C 0.1540(3) 0.0751(3) 0.7875(2) 0.087(2) Uani 1 1 d G . .
H20 H 0.1232 0.1323 0.8115 0.104 Uiso 1 1 calc R . .
C21 C 0.1291(3) -0.0104(3) 0.81689(19) 0.085(2) Uani 1 1 d G . .
H21 H 0.0816 -0.0105 0.8605 0.101 Uiso 1 1 calc R . .
C22 C 0.1752(3) -0.0959(3) 0.7810(2) 0.0710(17) Uani 1 1 d G . .
H22 H 0.1586 -0.1531 0.8007 0.085 Uiso 1 1 calc R . .
C23 C 0.2462(3) -0.0958(2) 0.7158(2) 0.0542(13) Uani 1 1 d G . .
C24 C 0.2875(5) -0.1907(5) 0.6778(4) 0.0778(18) Uani 1 1 d . . .
H24A H 0.2551 -0.2382 0.7050 0.117 Uiso 1 1 calc R . .
H24B H 0.3634 -0.2146 0.6796 0.117 Uiso 1 1 calc R . .
H24C H 0.2699 -0.1795 0.6248 0.117 Uiso 1 1 calc R . .
N4 N 0.2167(2) 0.1468(3) 0.44256(19) 0.0550(11) Uani 1 1 d G . .
C25 C 0.1430(3) 0.1485(3) 0.50632(17) 0.0769(18) Uani 1 1 d G . .
H25 H 0.1624 0.1509 0.5557 0.092 Uiso 1 1 calc R . .
C26 C 0.0404(3) 0.1467(4) 0.4963(3) 0.105(3) Uani 1 1 d G . .
H26 H -0.0089 0.1479 0.5390 0.126 Uiso 1 1 calc R . .
C27 C 0.0114(2) 0.1432(4) 0.4226(3) 0.101(3) Uani 1 1 d G . .
H27 H -0.0573 0.1420 0.4159 0.121 Uiso 1 1 calc R . .
C28 C 0.0851(3) 0.1415(3) 0.3588(2) 0.0750(18) Uani 1 1 d GD . .
C29 C 0.1877(3) 0.1433(3) 0.36880(17) 0.0559(13) Uani 1 1 d G . .
C30 C 0.0596(6) 0.1370(5) 0.2842(4) 0.098(3) Uani 1 1 d D . .
H30 H -0.0075 0.1323 0.2768 0.117 Uiso 1 1 calc R . .
C31 C 0.1331(6) 0.1394(5) 0.2203(4) 0.089(2) Uani 1 1 d D . .
H31 H 0.1152 0.1363 0.1707 0.107 Uiso 1 1 calc R . .
N3 N 0.3603(3) 0.1529(2) 0.32104(14) 0.0545(11) Uani 1 1 d G . .
C32 C 0.2610(2) 0.1457(3) 0.30742(19) 0.0549(14) Uani 1 1 d G . .
C33 C 0.2356(3) 0.1467(3) 0.2319(2) 0.0702(17) Uani 1 1 d GD . .
C34 C 0.3094(4) 0.1550(3) 0.16992(16) 0.094(2) Uani 1 1 d G . .
H34 H 0.2924 0.1558 0.1194 0.113 Uiso 1 1 calc R . .
C35 C 0.4087(4) 0.1623(4) 0.18354(16) 0.092(2) Uani 1 1 d G . .
H35 H 0.4582 0.1678 0.1421 0.110 Uiso 1 1 calc R . .
C36 C 0.4342(2) 0.1612(3) 0.2591(2) 0.0758(18) Uani 1 1 d G . .
H36 H 0.5006 0.1660 0.2682 0.091 Uiso 1 1 calc R . .
C37 C 0.1476(4) 0.1669(4) 0.9788(3) 0.0459(12) Uani 1 1 d . . .
C38 C 0.1953(3) 0.05818(17) 0.9928(2) 0.0454(11) Uani 1 1 d G . .
C39 C 0.1258(2) 0.0048(2) 1.0241(2) 0.0549(13) Uani 1 1 d G . .
H39 H 0.0548 0.0368 1.0375 0.066 Uiso 1 1 calc R . .
C40 C 0.1623(3) -0.0966(2) 1.0353(2) 0.0676(16) Uani 1 1 d G . .
H40 H 0.1157 -0.1323 1.0563 0.081 Uiso 1 1 calc R . .
C41 C 0.2683(3) -0.14452(17) 1.0153(3) 0.0794(19) Uani 1 1 d G . .
H41 H 0.2927 -0.2123 1.0228 0.095 Uiso 1 1 calc R . .
C42 C 0.3379(2) -0.0911(3) 0.9839(3) 0.086(2) Uani 1 1 d G . .
H42 H 0.4088 -0.1232 0.9705 0.103 Uiso 1 1 calc R . .
C43 C 0.3014(2) 0.0103(2) 0.9727(2) 0.0670(16) Uani 1 1 d G . .
C44 C 0.3807(5) 0.0637(5) 0.9349(6) 0.112(3) Uani 1 1 d . . .
H44A H 0.3842 0.1117 0.9675 0.167 Uiso 1 1 calc R . .
H44B H 0.3582 0.0954 0.8853 0.167 Uiso 1 1 calc R . .
H44C H 0.4499 0.0177 0.9280 0.167 Uiso 1 1 calc R . .
C45 C 0.0464(4) 0.3965(4) 1.1277(3) 0.0566(14) Uani 1 1 d . . .
C46 C 0.0715(5) 0.3993(3) 1.2094(2) 0.093(3) Uani 1 1 d G . .
C47 C 0.1725(5) 0.4005(3) 1.2245(3) 0.106(3) Uani 1 1 d G . .
H47 H 0.2247 0.4002 1.1839 0.128 Uiso 1 1 calc R . .
C48 C 0.1957(5) 0.4021(4) 1.3002(4) 0.137(3) Uani 1 1 d GU . .
H48 H 0.2633 0.4028 1.3103 0.165 Uiso 1 1 calc R . .
C49 C 0.1177(6) 0.4025(4) 1.3609(2) 0.133(3) Uani 1 1 d GU . .
H49 H 0.1332 0.4036 1.4116 0.159 Uiso 1 1 calc R . .
C50 C 0.0166(5) 0.4013(4) 1.3458(3) 0.136(4) Uani 1 1 d G . .
H50 H -0.0355 0.4016 1.3864 0.163 Uiso 1 1 calc R . .
C51 C -0.0065(4) 0.3998(4) 1.2701(3) 0.116(3) Uani 1 1 d GD . .
C52 C -0.1083(6) 0.3950(6) 1.2529(4) 0.093(2) Uani 1 1 d D . .
H52A H -0.1548 0.3989 1.2996 0.140 Uiso 1 1 calc R . .
H52B H -0.1003 0.3343 1.2319 0.140 Uiso 1 1 calc R . .
H52C H -0.1381 0.4485 1.2157 0.140 Uiso 1 1 calc R . .
C53 C 0.2003(4) 0.5171(4) 0.9670(3) 0.0484(12) Uani 1 1 d . . .
C54 C 0.3074(3) 0.5273(3) 0.9376(2) 0.0570(14) Uani 1 1 d G . .
C55 C 0.3101(3) 0.6171(3) 0.8990(3) 0.0772(19) Uani 1 1 d G . .
H55 H 0.2477 0.6684 0.8959 0.093 Uiso 1 1 calc R . .
C56 C 0.4060(5) 0.6302(4) 0.8650(3) 0.115(3) Uani 1 1 d G . .
H56 H 0.4078 0.6903 0.8392 0.138 Uiso 1 1 calc R . .
C57 C 0.4992(3) 0.5535(5) 0.8695(3) 0.128(4) Uani 1 1 d G . .
H57 H 0.5634 0.5622 0.8468 0.154 Uiso 1 1 calc R . .
C58 C 0.4966(3) 0.4637(4) 0.9081(3) 0.121(3) Uani 1 1 d G . .
H58 H 0.5589 0.4123 0.9112 0.145 Uiso 1 1 calc R . .
C59 C 0.4007(3) 0.4506(3) 0.9421(3) 0.083(2) Uani 1 1 d G . .
C60 C 0.4067(6) 0.3508(6) 0.9892(6) 0.111(3) Uani 1 1 d . . .
H60A H 0.3948 0.3068 0.9562 0.167 Uiso 1 1 calc R . .
H60B H 0.3531 0.3598 1.0319 0.167 Uiso 1 1 calc R . .
H60C H 0.4758 0.3240 1.0087 0.167 Uiso 1 1 calc R . .
N1 N 0.1469(3) 0.3490(3) 0.82684(14) 0.0582(11) Uani 1 1 d G . .
C61 C 0.2546(3) 0.3436(3) 0.81818(19) 0.0756(18) Uani 1 1 d G . .
H61 H 0.2902 0.3447 0.8612 0.091 Uiso 1 1 calc R . .
C62 C 0.3093(2) 0.3364(4) 0.7452(2) 0.091(2) Uani 1 1 d G . .
H62 H 0.3813 0.3328 0.7394 0.109 Uiso 1 1 calc R . .
C63 C 0.2562(3) 0.3347(3) 0.68087(17) 0.083(2) Uani 1 1 d G . .
H63 H 0.2928 0.3299 0.6320 0.100 Uiso 1 1 calc R . .
C64 C 0.1485(3) 0.3401(3) 0.68953(16) 0.0675(16) Uani 1 1 d GD . .
C65 C 0.0939(2) 0.3473(3) 0.76251(19) 0.0561(13) Uani 1 1 d G . .
C66 C 0.0929(6) 0.3382(5) 0.6259(3) 0.0792(19) Uani 1 1 d D . .
H66 H 0.1276 0.3348 0.5764 0.095 Uiso 1 1 calc R . .
C67 C -0.0148(6) 0.3413(5) 0.6368(3) 0.083(2) Uani 1 1 d D . .
H67 H -0.0520 0.3411 0.5944 0.099 Uiso 1 1 calc R . .
N2 N -0.0605(2) 0.3507(2) 0.84923(15) 0.0516(10) Uani 1 1 d G . .
C68 C -0.0112(2) 0.3486(3) 0.77443(18) 0.0519(13) Uani 1 1 d G . .
C69 C -0.0673(3) 0.3446(3) 0.71239(14) 0.0644(15) Uani 1 1 d GD . .
C70 C -0.1728(3) 0.3427(3) 0.7251(2) 0.0755(18) Uani 1 1 d G . .
H70 H -0.2103 0.3400 0.6836 0.091 Uiso 1 1 calc R . .
C71 C -0.2220(2) 0.3448(3) 0.7999(2) 0.0758(18) Uani 1 1 d G . .
H71 H -0.2926 0.3435 0.8085 0.091 Uiso 1 1 calc R . .
C72 C -0.1659(3) 0.3488(3) 0.86198(17) 0.0644(15) Uani 1 1 d G . .
H72 H -0.1989 0.3502 0.9120 0.077 Uiso 1 1 calc R . .
Dy1 Dy 0.411844(17) 0.134932(15) 0.461634(12) 0.03809(7) Uani 1 1 d . . .
Dy2 Dy 0.047610(18) 0.366147(15) 0.963359(12) 0.04182(8) Uani 1 1 d . . .
O1 O 0.0696(4) 0.3170(3) 1.0991(2) 0.0794(13) Uani 1 1 d . . .
O2 O 0.1306(3) 0.5925(2) 0.9872(2) 0.0525(8) Uani 1 1 d . . .
O3 O 0.0489(3) 0.1999(2) 0.9720(2) 0.0589(10) Uani 1 1 d . . .
O4 O 0.2049(3) 0.2234(2) 0.9740(2) 0.0576(9) Uani 1 1 d . . .
O5 O 0.0147(3) 0.4758(2) 1.0878(2) 0.0531(9) Uani 1 1 d . . .
O6 O 0.1863(3) 0.4341(3) 0.9686(2) 0.0554(9) Uani 1 1 d . . .
O7 O 0.3421(3) 0.0766(2) 0.58091(19) 0.0526(9) Uani 1 1 d . . .
O8 O 0.5054(4) 0.1834(3) 0.5535(2) 0.0750(12) Uani 1 1 d . . .
O9 O 0.4247(3) -0.0819(2) 0.60752(19) 0.0514(8) Uani 1 1 d . . .
O10 O 0.3094(3) 0.3004(2) 0.4877(2) 0.0580(9) Uani 1 1 d . . .
O11 O 0.4449(3) 0.2839(3) 0.4012(2) 0.0603(10) Uani 1 1 d . . .
O12 O 0.5733(3) 0.0249(2) 0.55575(19) 0.0522(8) Uani 1 1 d . . .
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
C1 0.090(4) 0.038(3) 0.052(3) 0.001(2) -0.021(3) -0.023(3)
C2 0.132(6) 0.043(3) 0.097(5) 0.000(3) -0.068(5) -0.023(4)
C3 0.230(8) 0.081(5) 0.064(4) -0.020(4) -0.068(5) -0.021(5)
C4 0.229(9) 0.131(7) 0.120(7) -0.013(6) -0.056(7) -0.031(7)
C5 0.186(6) 0.087(5) 0.150(6) -0.014(5) -0.082(6) -0.036(5)
C6 0.178(6) 0.083(4) 0.167(6) -0.002(5) -0.083(6) -0.044(4)
C7 0.186(10) 0.046(4) 0.123(7) 0.015(4) -0.091(7) -0.031(5)
C8 0.102(7) 0.129(9) 0.235(14) -0.012(9) -0.016(8) -0.046(7)
C9 0.064(3) 0.039(3) 0.045(3) -0.001(2) -0.014(3) -0.011(2)
C10 0.085(4) 0.038(3) 0.061(3) 0.001(2) -0.023(3) -0.015(3)
C11 0.104(5) 0.046(4) 0.105(5) -0.016(3) -0.010(4) -0.012(4)
C12 0.154(9) 0.054(5) 0.147(8) -0.037(5) 0.001(7) -0.008(5)
C13 0.177(10) 0.055(5) 0.134(8) 0.001(5) -0.032(7) -0.045(6)
C14 0.143(7) 0.063(5) 0.110(6) -0.001(4) -0.023(5) -0.050(5)
C15 0.118(6) 0.055(4) 0.074(4) 0.004(3) -0.013(4) -0.041(4)
C16 0.177(10) 0.107(7) 0.134(8) -0.024(6) 0.057(7) -0.092(7)
C17 0.046(3) 0.047(3) 0.039(3) -0.001(2) -0.001(2) -0.013(2)
C18 0.044(3) 0.056(3) 0.040(3) 0.000(2) -0.001(2) -0.013(2)
C19 0.076(4) 0.063(4) 0.054(3) -0.008(3) 0.016(3) -0.010(3)
C20 0.090(5) 0.101(6) 0.062(4) -0.031(4) 0.023(4) -0.017(4)
C21 0.079(4) 0.126(6) 0.051(4) -0.006(4) 0.020(3) -0.043(4)
C22 0.060(4) 0.102(5) 0.056(3) 0.007(3) -0.001(3) -0.037(4)
C23 0.051(3) 0.067(4) 0.047(3) 0.004(3) -0.005(2) -0.024(3)
C24 0.082(4) 0.067(4) 0.091(5) -0.005(3) 0.005(4) -0.037(4)
N4 0.049(2) 0.047(3) 0.066(3) -0.005(2) -0.004(2) -0.010(2)
C25 0.052(3) 0.081(5) 0.093(5) -0.014(4) 0.007(3) -0.015(3)
C26 0.054(4) 0.125(7) 0.131(7) -0.019(6) 0.015(4) -0.022(4)
C27 0.048(4) 0.102(6) 0.153(8) -0.010(5) -0.010(5) -0.022(4)
C28 0.067(4) 0.061(4) 0.102(5) 0.002(3) -0.038(4) -0.018(3)
C29 0.054(3) 0.039(3) 0.073(4) -0.001(3) -0.019(3) -0.008(2)
C30 0.090(5) 0.070(5) 0.144(8) 0.010(5) -0.069(5) -0.025(4)
C31 0.121(6) 0.061(4) 0.098(6) 0.006(4) -0.075(5) -0.025(4)
N3 0.064(3) 0.050(3) 0.049(2) 0.000(2) -0.010(2) -0.015(2)
C32 0.067(4) 0.037(3) 0.059(3) 0.006(2) -0.030(3) -0.008(2)
C33 0.107(5) 0.044(3) 0.062(4) 0.005(3) -0.036(4) -0.019(3)
C34 0.151(8) 0.072(5) 0.059(4) 0.002(3) -0.041(5) -0.023(5)
C35 0.117(6) 0.101(6) 0.047(4) 0.008(3) -0.010(4) -0.019(5)
C36 0.089(5) 0.088(5) 0.042(3) 0.009(3) -0.003(3) -0.019(4)
C37 0.053(3) 0.040(3) 0.042(3) -0.010(2) -0.003(2) -0.007(2)
C38 0.050(3) 0.038(3) 0.046(3) -0.007(2) -0.006(2) -0.007(2)
C39 0.053(3) 0.045(3) 0.062(3) 0.001(2) -0.009(3) -0.009(2)
C40 0.078(4) 0.049(3) 0.078(4) 0.011(3) -0.015(3) -0.025(3)
C41 0.088(5) 0.044(3) 0.092(5) -0.001(3) -0.009(4) 0.001(3)
C42 0.074(4) 0.049(4) 0.115(6) 0.000(4) 0.010(4) 0.003(3)
C43 0.061(4) 0.054(3) 0.077(4) -0.001(3) 0.004(3) -0.008(3)
C44 0.063(4) 0.067(5) 0.179(9) 0.009(5) 0.036(5) -0.005(3)
C45 0.065(3) 0.050(3) 0.049(3) -0.001(3) -0.012(3) -0.006(3)
C46 0.156(8) 0.041(3) 0.062(4) -0.008(3) -0.028(5) 0.009(4)
C47 0.174(9) 0.045(4) 0.102(6) -0.005(3) -0.087(6) -0.007(4)
C48 0.200(10) 0.084(5) 0.120(6) -0.010(5) -0.065(6) -0.009(6)
C49 0.210(10) 0.078(5) 0.089(6) -0.003(5) -0.037(6) -0.003(6)
C50 0.271(13) 0.054(4) 0.074(5) -0.010(4) -0.083(7) -0.007(6)
C51 0.167(10) 0.055(5) 0.120(8) 0.000(4) -0.038(7) -0.017(5)
C52 0.115(6) 0.087(5) 0.074(5) -0.003(4) -0.003(4) -0.028(5)
C53 0.053(3) 0.049(3) 0.046(3) -0.009(2) -0.005(2) -0.016(2)
C54 0.051(3) 0.074(4) 0.054(3) -0.016(3) -0.003(2) -0.025(3)
C55 0.080(4) 0.106(6) 0.064(4) -0.011(4) -0.001(3) -0.054(4)
C56 0.117(7) 0.181(10) 0.080(5) -0.011(6) 0.008(5) -0.101(7)
C57 0.087(6) 0.228(13) 0.103(7) -0.030(7) 0.019(5) -0.099(8)
C58 0.052(4) 0.185(10) 0.134(8) -0.063(7) 0.005(5) -0.031(5)
C59 0.051(4) 0.113(6) 0.092(5) -0.040(4) -0.007(3) -0.020(4)
C60 0.082(5) 0.088(6) 0.156(8) -0.027(5) -0.042(5) 0.006(4)
N1 0.062(3) 0.059(3) 0.052(3) -0.012(2) 0.001(2) -0.015(2)
C61 0.067(4) 0.093(5) 0.065(4) -0.021(3) 0.013(3) -0.022(4)
C62 0.079(5) 0.110(6) 0.081(5) -0.023(4) 0.019(4) -0.029(4)
C63 0.095(5) 0.084(5) 0.063(4) -0.015(3) 0.025(4) -0.023(4)
C64 0.091(5) 0.056(4) 0.052(3) -0.015(3) 0.006(3) -0.015(3)
C65 0.074(4) 0.047(3) 0.046(3) -0.013(2) 0.001(3) -0.014(3)
C66 0.109(6) 0.073(4) 0.050(4) -0.018(3) 0.002(4) -0.015(4)
C67 0.129(6) 0.071(4) 0.046(3) -0.016(3) -0.024(4) -0.016(4)
N2 0.065(3) 0.037(2) 0.053(3) -0.0072(19) -0.007(2) -0.012(2)
C68 0.072(4) 0.039(3) 0.041(3) -0.009(2) -0.006(2) -0.008(2)
C69 0.086(4) 0.048(3) 0.061(4) -0.014(3) -0.014(3) -0.015(3)
C70 0.087(5) 0.067(4) 0.079(4) -0.021(3) -0.028(4) -0.020(3)
C71 0.073(4) 0.076(4) 0.089(5) -0.029(4) -0.015(4) -0.026(3)
C72 0.072(4) 0.058(4) 0.070(4) -0.016(3) -0.005(3) -0.026(3)
Dy1 0.04381(13) 0.03229(12) 0.03656(12) -0.00112(9) -0.00109(9) -0.00995(9)
Dy2 0.04789(14) 0.03409(13) 0.04159(13) -0.00568(9) -0.00264(10) -0.00827(10)
O1 0.133(4) 0.043(2) 0.047(2) -0.0045(17) -0.017(2) 0.001(2)
O2 0.053(2) 0.046(2) 0.058(2) -0.0117(16) 0.0036(17) -0.0135(17)
O3 0.050(2) 0.0371(19) 0.089(3) -0.0077(18) -0.0141(19) -0.0075(16)
O4 0.052(2) 0.040(2) 0.080(3) -0.0082(18) -0.0033(18) -0.0118(17)
O5 0.058(2) 0.044(2) 0.054(2) 0.0082(16) -0.0127(17) -0.0110(16)
O6 0.049(2) 0.047(2) 0.070(2) -0.0133(17) -0.0050(17) -0.0103(16)
O7 0.061(2) 0.043(2) 0.0441(19) 0.0014(15) 0.0062(16) -0.0060(16)
O8 0.109(3) 0.039(2) 0.083(3) 0.0030(19) -0.049(3) -0.018(2)
O9 0.050(2) 0.0420(19) 0.054(2) 0.0031(15) 0.0076(16) -0.0084(16)
O10 0.063(2) 0.0391(19) 0.066(2) -0.0063(17) 0.0079(19) -0.0096(17)
O11 0.080(3) 0.041(2) 0.056(2) -0.0023(17) 0.0113(19) -0.0179(19)
O12 0.067(2) 0.044(2) 0.052(2) -0.0123(16) -0.0014(17) -0.0236(17)
_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O8 1.241(6) . ?
C1 O12 1.259(6) . ?
C1 C2 1.457(6) . ?
C1 Dy1 2.963(5) . ?
C2 C3 1.3900 . ?
C2 C7 1.3900 . ?
C3 C4 1.3900 . ?
C3 H3 0.9300 . ?
C4 C5 1.3900 . ?
C4 H4 0.9300 . ?
C5 C6 1.3900 . ?
C5 H5 0.9300 . ?
C6 C7 1.3900 . ?
C6 H6 0.9300 . ?
C7 C8 1.405(8) . ?
C8 H8A 0.9600 . ?
C8 H8B 0.9600 . ?
C8 H8C 0.9600 . ?
C9 O11 1.251(6) . ?
C9 O10 1.264(6) . ?
C9 C10 1.511(6) . ?
C9 Dy1 2.778(5) . ?
C10 C11 1.3900 . ?
C10 C15 1.3900 . ?
C11 C12 1.3900 . ?
C11 H11 0.9300 . ?
C12 C13 1.3900 . ?
C12 H12 0.9300 . ?
C13 C14 1.3900 . ?
C13 H13 0.9300 . ?
C14 C15 1.3900 . ?
C14 H14 0.9300 . ?
C15 C16 1.502(9) . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 O9 1.253(6) . ?
C17 O7 1.257(6) . ?
C17 C18 1.504(5) . ?
C18 C19 1.3900 . ?
C18 C23 1.3900 . ?
C19 C20 1.3900 . ?
C19 H19 0.9300 . ?
C20 C21 1.3900 . ?
C20 H20 0.9300 . ?
C21 C22 1.3900 . ?
C21 H21 0.9300 . ?
C22 C23 1.3900 . ?
C22 H22 0.9300 . ?
C23 C24 1.517(7) . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
N4 C25 1.3900 . ?
N4 C29 1.3900 . ?
N4 Dy1 2.581(3) . ?
C25 C26 1.3900 . ?
C25 H25 0.9300 . ?
C26 C27 1.3900 . ?
C26 H26 0.9300 . ?
C27 C28 1.3900 . ?
C27 H27 0.9300 . ?
C28 C30 1.389(7) . ?
C28 C29 1.3900 . ?
C29 C32 1.364(4) . ?
C30 C31 1.398(7) . ?
C30 H30 0.9300 . ?
C31 C33 1.421(6) . ?
C31 H31 0.9300 . ?
N3 C32 1.3900 . ?
N3 C36 1.3900 . ?
N3 Dy1 2.574(2) . ?
C32 C33 1.3900 . ?
C33 C34 1.3900 . ?
C34 C35 1.3900 . ?
C34 H34 0.9300 . ?
C35 C36 1.3900 . ?
C35 H35 0.9300 . ?
C36 H36 0.9300 . ?
C37 O4 1.252(6) . ?
C37 O3 1.259(6) . ?
C37 C38 1.503(5) . ?
C37 Dy2 2.772(5) . ?
C38 C39 1.3900 . ?
C38 C43 1.3900 . ?
C39 C40 1.3900 . ?
C39 H39 0.9300 . ?
C40 C41 1.3900 . ?
C40 H40 0.9300 . ?
C41 C42 1.3900 . ?
C41 H41 0.9300 . ?
C42 C43 1.3900 . ?
C42 H42 0.9300 . ?
C43 C44 1.523(7) . ?
C44 H44A 0.9600 . ?
C44 H44B 0.9600 . ?
C44 H44C 0.9600 . ?
C45 O1 1.244(6) . ?
C45 O5 1.244(6) . ?
C45 C46 1.503(6) . ?
C45 Dy2 2.945(5) . ?
C46 C47 1.3900 . ?
C46 C51 1.3900 . ?
C47 C48 1.3900 . ?
C47 H47 0.9300 . ?
C48 C49 1.3900 . ?
C48 H48 0.9300 . ?
C49 C50 1.3900 . ?
C49 H49 0.9300 . ?
C50 C51 1.3900 . ?
C50 H50 0.9300 . ?
C51 C52 1.428(7) . ?
C52 H52A 0.9600 . ?
C52 H52B 0.9600 . ?
C52 H52C 0.9600 . ?
C53 O2 1.256(6) . ?
C53 O6 1.256(6) . ?
C53 C54 1.491(6) . ?
C54 C55 1.3900 . ?
C54 C59 1.3900 . ?
C55 C56 1.3900 . ?
C55 H55 0.9300 . ?
C56 C57 1.3900 . ?
C56 H56 0.9300 . ?
C57 C58 1.3900 . ?
C57 H57 0.9300 . ?
C58 C59 1.3900 . ?
C58 H58 0.9300 . ?
C59 C60 1.549(9) . ?
C60 H60A 0.9600 . ?
C60 H60B 0.9600 . ?
C60 H60C 0.9600 . ?
N1 C61 1.3900 . ?
N1 C65 1.3900 . ?
N1 Dy2 2.588(2) . ?
C61 C62 1.3900 . ?
C61 H61 0.9300 . ?
C62 C63 1.3900 . ?
C62 H62 0.9300 . ?
C63 C64 1.3900 . ?
C63 H63 0.9300 . ?
C64 C65 1.3900 . ?
C64 C66 1.401(6) . ?
C65 C68 1.372(4) . ?
C66 C67 1.399(7) . ?
C66 H66 0.9300 . ?
C67 C69 1.418(6) . ?
C67 H67 0.9300 . ?
N2 C68 1.3900 . ?
N2 C72 1.3900 . ?
N2 Dy2 2.634(2) . ?
C68 C69 1.3900 . ?
C69 C70 1.3900 . ?
C70 C71 1.3900 . ?
C70 H70 0.9300 . ?
C71 C72 1.3900 . ?
C71 H71 0.9300 . ?
C72 H72 0.9300 . ?
Dy1 O12 2.303(3) 2_656 ?
Dy1 O9 2.314(3) 2_656 ?
Dy1 O7 2.340(3) . ?
Dy1 O8 2.402(4) . ?
Dy1 O11 2.407(3) . ?
Dy1 O10 2.435(3) . ?
Dy1 O12 2.803(4) . ?
Dy2 O5 2.281(3) 2_567 ?
Dy2 O6 2.327(4) . ?
Dy2 O2 2.337(3) 2_567 ?
Dy2 O3 2.372(3) . ?
Dy2 O1 2.408(4) . ?
Dy2 O4 2.454(3) . ?
Dy2 O5 2.755(4) . ?
O2 Dy2 2.337(3) 2_567 ?
O5 Dy2 2.281(3) 2_567 ?
O9 Dy1 2.314(3) 2_656 ?
O12 Dy1 2.303(3) 2_656 ?
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O8 C1 O12 122.0(5) . . ?
O8 C1 C2 117.9(5) . . ?
O12 C1 C2 119.9(5) . . ?
O8 C1 Dy1 51.8(3) . . ?
O12 C1 Dy1 70.3(3) . . ?
C2 C1 Dy1 167.0(4) . . ?
C3 C2 C7 120.0 . . ?
C3 C2 C1 122.0(5) . . ?
C7 C2 C1 118.0(5) . . ?
C4 C3 C2 120.0 . . ?
C4 C3 H3 120.0 . . ?
C2 C3 H3 120.0 . . ?
C3 C4 C5 120.0 . . ?
C3 C4 H4 120.0 . . ?
C5 C4 H4 120.0 . . ?
C4 C5 C6 120.0 . . ?
C4 C5 H5 120.0 . . ?
C6 C5 H5 120.0 . . ?
C7 C6 C5 120.0 . . ?
C7 C6 H6 120.0 . . ?
C5 C6 H6 120.0 . . ?
C6 C7 C2 120.0 . . ?
C6 C7 C8 119.1(6) . . ?
C2 C7 C8 120.9(6) . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
O11 C9 O10 120.3(5) . . ?
O11 C9 C10 120.0(5) . . ?
O10 C9 C10 119.6(4) . . ?
O11 C9 Dy1 59.9(3) . . ?
O10 C9 Dy1 61.2(3) . . ?
C10 C9 Dy1 170.9(3) . . ?
C11 C10 C15 120.0 . . ?
C11 C10 C9 116.4(3) . . ?
C15 C10 C9 123.5(3) . . ?
C12 C11 C10 120.0 . . ?
C12 C11 H11 120.0 . . ?
C10 C11 H11 120.0 . . ?
C13 C12 C11 120.0 . . ?
C13 C12 H12 120.0 . . ?
C11 C12 H12 120.0 . . ?
C12 C13 C14 120.0 . . ?
C12 C13 H13 120.0 . . ?
C14 C13 H13 120.0 . . ?
C15 C14 C13 120.0 . . ?
C15 C14 H14 120.0 . . ?
C13 C14 H14 120.0 . . ?
C14 C15 C10 120.0 . . ?
C14 C15 C16 115.3(4) . . ?
C10 C15 C16 124.7(4) . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
O9 C17 O7 125.6(4) . . ?
O9 C17 C18 117.2(4) . . ?
O7 C17 C18 117.2(4) . . ?
C19 C18 C23 120.0 . . ?
C19 C18 C17 116.5(3) . . ?
C23 C18 C17 123.4(3) . . ?
C18 C19 C20 120.0 . . ?
C18 C19 H19 120.0 . . ?
C20 C19 H19 120.0 . . ?
C21 C20 C19 120.0 . . ?
C21 C20 H20 120.0 . . ?
C19 C20 H20 120.0 . . ?
C20 C21 C22 120.0 . . ?
C20 C21 H21 120.0 . . ?
C22 C21 H21 120.0 . . ?
C23 C22 C21 120.0 . . ?
C23 C22 H22 120.0 . . ?
C21 C22 H22 120.0 . . ?
C22 C23 C18 120.0 . . ?
C22 C23 C24 116.3(3) . . ?
C18 C23 C24 123.6(3) . . ?
C23 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C23 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C25 N4 C29 120.0 . . ?
C25 N4 Dy1 120.26(18) . . ?
C29 N4 Dy1 119.52(18) . . ?
N4 C25 C26 120.0 . . ?
N4 C25 H25 120.0 . . ?
C26 C25 H25 120.0 . . ?
C25 C26 C27 120.0 . . ?
C25 C26 H26 120.0 . . ?
C27 C26 H26 120.0 . . ?
C26 C27 C28 120.0 . . ?
C26 C27 H27 120.0 . . ?
C28 C27 H27 120.0 . . ?
C30 C28 C29 118.2(5) . . ?
C30 C28 C27 121.8(5) . . ?
C29 C28 C27 120.0 . . ?
C32 C29 C28 121.8(3) . . ?
C32 C29 N4 118.2(3) . . ?
C28 C29 N4 120.0 . . ?
C28 C30 C31 121.1(6) . . ?
C28 C30 H30 119.5 . . ?
C31 C30 H30 119.5 . . ?
C30 C31 C33 119.4(6) . . ?
C30 C31 H31 120.3 . . ?
C33 C31 H31 120.3 . . ?
C32 N3 C36 120.0 . . ?
C32 N3 Dy1 119.34(17) . . ?
C36 N3 Dy1 120.42(17) . . ?
C29 C32 N3 118.9(3) . . ?
C29 C32 C33 121.0(3) . . ?
N3 C32 C33 120.0 . . ?
C32 C33 C34 120.0 . . ?
C32 C33 C31 118.3(4) . . ?
C34 C33 C31 121.7(4) . . ?
C35 C34 C33 120.0 . . ?
C35 C34 H34 120.0 . . ?
C33 C34 H34 120.0 . . ?
C34 C35 C36 120.0 . . ?
C34 C35 H35 120.0 . . ?
C36 C35 H35 120.0 . . ?
C35 C36 N3 120.0 . . ?
C35 C36 H36 120.0 . . ?
N3 C36 H36 120.0 . . ?
O4 C37 O3 120.7(5) . . ?
O4 C37 C38 120.7(4) . . ?
O3 C37 C38 118.6(4) . . ?
O4 C37 Dy2 62.3(3) . . ?
O3 C37 Dy2 58.6(2) . . ?
C38 C37 Dy2 175.2(3) . . ?
C39 C38 C43 120.0 . . ?
C39 C38 C37 116.3(3) . . ?
C43 C38 C37 123.6(3) . . ?
C38 C39 C40 120.0 . . ?
C38 C39 H39 120.0 . . ?
C40 C39 H39 120.0 . . ?
C41 C40 C39 120.0 . . ?
C41 C40 H40 120.0 . . ?
C39 C40 H40 120.0 . . ?
C42 C41 C40 120.0 . . ?
C42 C41 H41 120.0 . . ?
C40 C41 H41 120.0 . . ?
C41 C42 C43 120.0 . . ?
C41 C42 H42 120.0 . . ?
C43 C42 H42 120.0 . . ?
C42 C43 C38 120.0 . . ?
C42 C43 C44 117.1(3) . . ?
C38 C43 C44 122.8(3) . . ?
C43 C44 H44A 109.5 . . ?
C43 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C43 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
O1 C45 O5 121.8(5) . . ?
O1 C45 C46 119.9(4) . . ?
O5 C45 C46 117.7(5) . . ?
O1 C45 Dy2 52.9(3) . . ?
O5 C45 Dy2 69.0(3) . . ?
C46 C45 Dy2 167.2(4) . . ?
C47 C46 C51 120.0 . . ?
C47 C46 C45 120.2(5) . . ?
C51 C46 C45 119.8(5) . . ?
C48 C47 C46 120.0 . . ?
C48 C47 H47 120.0 . . ?
C46 C47 H47 120.0 . . ?
C47 C48 C49 120.0 . . ?
C47 C48 H48 120.0 . . ?
C49 C48 H48 120.0 . . ?
C50 C49 C48 120.0 . . ?
C50 C49 H49 120.0 . . ?
C48 C49 H49 120.0 . . ?
C49 C50 C51 120.0 . . ?
C49 C50 H50 120.0 . . ?
C51 C50 H50 120.0 . . ?
C50 C51 C46 120.0 . . ?
C50 C51 C52 121.4(5) . . ?
C46 C51 C52 118.5(5) . . ?
C51 C52 H52A 109.5 . . ?
C51 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C51 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
O2 C53 O6 125.1(5) . . ?
O2 C53 C54 117.3(4) . . ?
O6 C53 C54 117.5(4) . . ?
C55 C54 C59 120.0 . . ?
C55 C54 C53 116.6(3) . . ?
C59 C54 C53 123.3(3) . . ?
C56 C55 C54 120.0 . . ?
C56 C55 H55 120.0 . . ?
C54 C55 H55 120.0 . . ?
C57 C56 C55 120.0 . . ?
C57 C56 H56 120.0 . . ?
C55 C56 H56 120.0 . . ?
C58 C57 C56 120.0 . . ?
C58 C57 H57 120.0 . . ?
C56 C57 H57 120.0 . . ?
C57 C58 C59 120.0 . . ?
C57 C58 H58 120.0 . . ?
C59 C58 H58 120.0 . . ?
C58 C59 C54 120.0 . . ?
C58 C59 C60 116.4(4) . . ?
C54 C59 C60 123.5(4) . . ?
C59 C60 H60A 109.5 . . ?
C59 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C59 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
C61 N1 C65 120.0 . . ?
C61 N1 Dy2 118.89(17) . . ?
C65 N1 Dy2 121.10(17) . . ?
N1 C61 C62 120.0 . . ?
N1 C61 H61 120.0 . . ?
C62 C61 H61 120.0 . . ?
C63 C62 C61 120.0 . . ?
C63 C62 H62 120.0 . . ?
C61 C62 H62 120.0 . . ?
C62 C63 C64 120.0 . . ?
C62 C63 H63 120.0 . . ?
C64 C63 H63 120.0 . . ?
C65 C64 C63 120.0 . . ?
C65 C64 C66 118.7(4) . . ?
C63 C64 C66 121.3(4) . . ?
C68 C65 C64 122.1(3) . . ?
C68 C65 N1 117.9(3) . . ?
C64 C65 N1 120.0 . . ?
C67 C66 C64 120.0(5) . . ?
C67 C66 H66 120.0 . . ?
C64 C66 H66 120.0 . . ?
C66 C67 C69 120.1(5) . . ?
C66 C67 H67 120.0 . . ?
C69 C67 H67 120.0 . . ?
C68 N2 C72 120.0 . . ?
C68 N2 Dy2 118.46(16) . . ?
C72 N2 Dy2 121.49(16) . . ?
C65 C68 C69 120.2(3) . . ?
C65 C68 N2 119.7(3) . . ?
C69 C68 N2 120.0 . . ?
C68 C69 C70 120.0 . . ?
C68 C69 C67 118.9(4) . . ?
C70 C69 C67 121.1(4) . . ?
C69 C70 C71 120.0 . . ?
C69 C70 H70 120.0 . . ?
C71 C70 H70 120.0 . . ?
C72 C71 C70 120.0 . . ?
C72 C71 H71 120.0 . . ?
C70 C71 H71 120.0 . . ?
C71 C72 N2 120.0 . . ?
C71 C72 H72 120.0 . . ?
N2 C72 H72 120.0 . . ?
O12 Dy1 O9 75.84(12) 2_656 2_656 ?
O12 Dy1 O7 76.91(12) 2_656 . ?
O9 Dy1 O7 132.01(11) 2_656 . ?
O12 Dy1 O8 124.31(12) 2_656 . ?
O9 Dy1 O8 86.67(15) 2_656 . ?
O7 Dy1 O8 77.21(14) . . ?
O12 Dy1 O11 144.56(12) 2_656 . ?
O9 Dy1 O11 76.38(12) 2_656 . ?
O7 Dy1 O11 138.53(12) . . ?
O8 Dy1 O11 75.19(13) . . ?
O12 Dy1 O10 152.67(13) 2_656 . ?
O9 Dy1 O10 129.18(12) 2_656 . ?
O7 Dy1 O10 89.23(12) . . ?
O8 Dy1 O10 73.74(13) . . ?
O11 Dy1 O10 53.58(12) . . ?
O12 Dy1 N3 78.98(11) 2_656 . ?
O9 Dy1 N3 77.29(11) 2_656 . ?
O7 Dy1 N3 133.87(12) . . ?
O8 Dy1 N3 147.63(13) . . ?
O11 Dy1 N3 73.80(12) . . ?
O10 Dy1 N3 94.83(12) . . ?
O12 Dy1 N4 79.12(12) 2_656 . ?
O9 Dy1 N4 136.21(12) 2_656 . ?
O7 Dy1 N4 74.20(12) . . ?
O8 Dy1 N4 137.01(14) . . ?
O11 Dy1 N4 107.20(12) . . ?
O10 Dy1 N4 74.44(12) . . ?
N3 Dy1 N4 62.94(10) . . ?
O12 Dy1 C9 164.85(13) 2_656 . ?
O9 Dy1 C9 102.25(14) 2_656 . ?
O7 Dy1 C9 113.56(14) . . ?
O8 Dy1 C9 70.08(13) . . ?
O11 Dy1 C9 26.73(14) . . ?
O10 Dy1 C9 27.06(14) . . ?
N3 Dy1 C9 85.93(13) . . ?
N4 Dy1 C9 92.91(14) . . ?
O12 Dy1 O12 75.74(12) 2_656 . ?
O9 Dy1 O12 67.21(11) 2_656 . ?
O7 Dy1 O12 68.22(11) . . ?
O8 Dy1 O12 48.93(11) . . ?
O11 Dy1 O12 112.54(12) . . ?
O10 Dy1 O12 121.03(11) . . ?
N3 Dy1 O12 140.32(10) . . ?
N4 Dy1 O12 138.42(10) . . ?
C9 Dy1 O12 117.76(12) . . ?
O12 Dy1 C1 100.47(14) 2_656 . ?
O9 Dy1 C1 76.86(15) 2_656 . ?
O7 Dy1 C1 70.24(15) . . ?
O8 Dy1 C1 23.93(13) . . ?
O11 Dy1 C1 94.16(14) . . ?
O10 Dy1 C1 96.69(14) . . ?
N3 Dy1 C1 153.44(14) . . ?
N4 Dy1 C1 143.46(14) . . ?
C9 Dy1 C1 93.60(14) . . ?
O12 Dy1 C1 25.02(12) . . ?
O5 Dy2 O6 75.09(12) 2_567 . ?
O5 Dy2 O2 77.90(12) 2_567 2_567 ?
O6 Dy2 O2 133.28(12) . 2_567 ?
O5 Dy2 O3 150.47(13) 2_567 . ?
O6 Dy2 O3 130.08(12) . . ?
O2 Dy2 O3 89.49(12) 2_567 . ?
O5 Dy2 O1 124.33(13) 2_567 . ?
O6 Dy2 O1 84.87(15) . . ?
O2 Dy2 O1 79.83(15) 2_567 . ?
O3 Dy2 O1 78.35(14) . . ?
O5 Dy2 O4 145.09(13) 2_567 . ?
O6 Dy2 O4 76.42(12) . . ?
O2 Dy2 O4 136.97(12) 2_567 . ?
O3 Dy2 O4 53.73(12) . . ?
O1 Dy2 O4 72.10(14) . . ?
O5 Dy2 N1 81.45(12) 2_567 . ?
O6 Dy2 N1 76.24(12) . . ?
O2 Dy2 N1 135.70(11) 2_567 . ?
O3 Dy2 N1 89.69(13) . . ?
O1 Dy2 N1 142.84(14) . . ?
O4 Dy2 N1 72.49(12) . . ?
O5 Dy2 N2 77.27(11) 2_567 . ?
O6 Dy2 N2 132.98(12) . . ?
O2 Dy2 N2 74.82(11) 2_567 . ?
O3 Dy2 N2 73.67(11) . . ?
O1 Dy2 N2 142.02(14) . . ?
O4 Dy2 N2 109.15(11) . . ?
N1 Dy2 N2 62.54(10) . . ?
O5 Dy2 O5 75.13(12) 2_567 . ?
O6 Dy2 O5 68.27(11) . . ?
O2 Dy2 O5 68.34(11) 2_567 . ?
O3 Dy2 O5 124.91(12) . . ?
O1 Dy2 O5 49.23(11) . . ?
O4 Dy2 O5 112.00(11) . . ?
N1 Dy2 O5 141.31(11) . . ?
N2 Dy2 O5 137.56(10) . . ?
O5 Dy2 C37 162.38(13) 2_567 . ?
O6 Dy2 C37 103.17(14) . . ?
O2 Dy2 C37 113.42(14) 2_567 . ?
O3 Dy2 C37 26.92(13) . . ?
O1 Dy2 C37 72.34(13) . . ?
O4 Dy2 C37 26.85(13) . . ?
N1 Dy2 C37 81.13(13) . . ?
N2 Dy2 C37 92.32(12) . . ?
O5 Dy2 C37 121.00(12) . . ?
O5 Dy2 C45 100.06(14) 2_567 . ?
O6 Dy2 C45 74.75(15) . . ?
O2 Dy2 C45 73.35(14) 2_567 . ?
O3 Dy2 C45 101.70(15) . . ?
O1 Dy2 C45 24.32(13) . . ?
O4 Dy2 C45 91.43(14) . . ?
N1 Dy2 C45 149.43(14) . . ?
N2 Dy2 C45 147.87(13) . . ?
O5 Dy2 C45 24.93(12) . . ?
C37 Dy2 C45 96.27(14) . . ?
C45 O1 Dy2 102.8(3) . . ?
C53 O2 Dy2 137.2(3) . 2_567 ?
C37 O3 Dy2 94.5(3) . . ?
C37 O4 Dy2 90.9(3) . . ?
C45 O5 Dy2 169.0(4) . 2_567 ?
C45 O5 Dy2 86.1(3) . . ?
Dy2 O5 Dy2 104.87(12) 2_567 . ?
C53 O6 Dy2 138.9(3) . . ?
C17 O7 Dy1 136.7(3) . . ?
C1 O8 Dy1 104.3(3) . . ?
C17 O9 Dy1 140.7(3) . 2_656 ?
C9 O10 Dy1 91.8(3) . . ?
C9 O11 Dy1 93.4(3) . . ?
C1 O12 Dy1 167.5(3) . 2_656 ?
C1 O12 Dy1 84.6(3) . . ?
Dy1 O12 Dy1 104.26(12) 2_656 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O8 C1 C2 C3 77.3(6) . . . . ?
O12 C1 C2 C3 -97.6(6) . . . . ?
Dy1 C1 C2 C3 42.4(19) . . . . ?
O8 C1 C2 C7 -101.8(6) . . . . ?
O12 C1 C2 C7 83.2(6) . . . . ?
Dy1 C1 C2 C7 -136.8(16) . . . . ?
C7 C2 C3 C4 0.0 . . . . ?
C1 C2 C3 C4 -179.2(5) . . . . ?
C2 C3 C4 C5 0.0 . . . . ?
C3 C4 C5 C6 0.0 . . . . ?
C4 C5 C6 C7 0.0 . . . . ?
C5 C6 C7 C2 0.0 . . . . ?
C5 C6 C7 C8 177.9(7) . . . . ?
C3 C2 C7 C6 0.0 . . . . ?
C1 C2 C7 C6 179.2(4) . . . . ?
C3 C2 C7 C8 -177.9(7) . . . . ?
C1 C2 C7 C8 1.3(7) . . . . ?
O11 C9 C10 C11 177.9(4) . . . . ?
O10 C9 C10 C11 -2.8(6) . . . . ?
Dy1 C9 C10 C11 -95(2) . . . . ?
O11 C9 C10 C15 -6.3(6) . . . . ?
O10 C9 C10 C15 173.1(4) . . . . ?
Dy1 C9 C10 C15 81(2) . . . . ?
C15 C10 C11 C12 0.0 . . . . ?
C9 C10 C11 C12 176.0(4) . . . . ?
C10 C11 C12 C13 0.0 . . . . ?
C11 C12 C13 C14 0.0 . . . . ?
C12 C13 C14 C15 0.0 . . . . ?
C13 C14 C15 C10 0.0 . . . . ?
C13 C14 C15 C16 179.0(6) . . . . ?
C11 C10 C15 C14 0.0 . . . . ?
C9 C10 C15 C14 -175.7(4) . . . . ?
C11 C10 C15 C16 -178.9(7) . . . . ?
C9 C10 C15 C16 5.4(7) . . . . ?
O9 C17 C18 C19 150.2(4) . . . . ?
O7 C17 C18 C19 -28.1(5) . . . . ?
O9 C17 C18 C23 -26.0(6) . . . . ?
O7 C17 C18 C23 155.6(4) . . . . ?
C23 C18 C19 C20 0.0 . . . . ?
C17 C18 C19 C20 -176.4(4) . . . . ?
C18 C19 C20 C21 0.0 . . . . ?
C19 C20 C21 C22 0.0 . . . . ?
C20 C21 C22 C23 0.0 . . . . ?
C21 C22 C23 C18 0.0 . . . . ?
C21 C22 C23 C24 -176.5(4) . . . . ?
C19 C18 C23 C22 0.0 . . . . ?
C17 C18 C23 C22 176.1(4) . . . . ?
C19 C18 C23 C24 176.2(5) . . . . ?
C17 C18 C23 C24 -7.6(5) . . . . ?
C29 N4 C25 C26 0.0 . . . . ?
Dy1 N4 C25 C26 -174.7(2) . . . . ?
N4 C25 C26 C27 0.0 . . . . ?
C25 C26 C27 C28 0.0 . . . . ?
C26 C27 C28 C30 179.3(5) . . . . ?
C26 C27 C28 C29 0.0 . . . . ?
C30 C28 C29 C32 3.3(5) . . . . ?
C27 C28 C29 C32 -177.3(4) . . . . ?
C30 C28 C29 N4 -179.4(5) . . . . ?
C27 C28 C29 N4 0.0 . . . . ?
C25 N4 C29 C32 177.4(4) . . . . ?
Dy1 N4 C29 C32 -7.9(3) . . . . ?
C25 N4 C29 C28 0.0 . . . . ?
Dy1 N4 C29 C28 174.7(2) . . . . ?
C29 C28 C30 C31 -3.3(8) . . . . ?
C27 C28 C30 C31 177.3(5) . . . . ?
C28 C30 C31 C33 -0.1(10) . . . . ?
C28 C29 C32 N3 176.4(2) . . . . ?
N4 C29 C32 N3 -0.9(4) . . . . ?
C28 C29 C32 C33 0.2(4) . . . . ?
N4 C29 C32 C33 -177.1(2) . . . . ?
C36 N3 C32 C29 -176.2(4) . . . . ?
Dy1 N3 C32 C29 9.3(3) . . . . ?
C36 N3 C32 C33 0.0 . . . . ?
Dy1 N3 C32 C33 -174.4(2) . . . . ?
C29 C32 C33 C34 176.2(4) . . . . ?
N3 C32 C33 C34 0.0 . . . . ?
C29 C32 C33 C31 -3.7(5) . . . . ?
N3 C32 C33 C31 -179.8(4) . . . . ?
C30 C31 C33 C32 3.6(8) . . . . ?
C30 C31 C33 C34 -176.3(5) . . . . ?
C32 C33 C34 C35 0.0 . . . . ?
C31 C33 C34 C35 179.8(5) . . . . ?
C33 C34 C35 C36 0.0 . . . . ?
C34 C35 C36 N3 0.0 . . . . ?
C32 N3 C36 C35 0.0 . . . . ?
Dy1 N3 C36 C35 174.4(2) . . . . ?
O4 C37 C38 C39 157.9(4) . . . . ?
O3 C37 C38 C39 -22.0(5) . . . . ?
Dy2 C37 C38 C39 31(4) . . . . ?
O4 C37 C38 C43 -25.3(6) . . . . ?
O3 C37 C38 C43 154.7(4) . . . . ?
Dy2 C37 C38 C43 -153(4) . . . . ?
C43 C38 C39 C40 0.0 . . . . ?
C37 C38 C39 C40 176.9(4) . . . . ?
C38 C39 C40 C41 0.0 . . . . ?
C39 C40 C41 C42 0.0 . . . . ?
C40 C41 C42 C43 0.0 . . . . ?
C41 C42 C43 C38 0.0 . . . . ?
C41 C42 C43 C44 -177.4(6) . . . . ?
C39 C38 C43 C42 0.0 . . . . ?
C37 C38 C43 C42 -176.6(4) . . . . ?
C39 C38 C43 C44 177.3(6) . . . . ?
C37 C38 C43 C44 0.6(6) . . . . ?
O1 C45 C46 C47 83.7(6) . . . . ?
O5 C45 C46 C47 -87.7(6) . . . . ?
Dy2 C45 C46 C47 31.4(19) . . . . ?
O1 C45 C46 C51 -95.6(6) . . . . ?
O5 C45 C46 C51 93.0(5) . . . . ?
Dy2 C45 C46 C51 -147.9(16) . . . . ?
C51 C46 C47 C48 0.0 . . . . ?
C45 C46 C47 C48 -179.3(4) . . . . ?
C46 C47 C48 C49 0.0 . . . . ?
C47 C48 C49 C50 0.0 . . . . ?
C48 C49 C50 C51 0.0 . . . . ?
C49 C50 C51 C46 0.0 . . . . ?
C49 C50 C51 C52 177.7(6) . . . . ?
C47 C46 C51 C50 0.0 . . . . ?
C45 C46 C51 C50 179.3(4) . . . . ?
C47 C46 C51 C52 -177.8(6) . . . . ?
C45 C46 C51 C52 1.5(6) . . . . ?
O2 C53 C54 C55 -31.1(5) . . . . ?
O6 C53 C54 C55 147.8(4) . . . . ?
O2 C53 C54 C59 153.7(4) . . . . ?
O6 C53 C54 C59 -27.5(6) . . . . ?
C59 C54 C55 C56 0.0 . . . . ?
C53 C54 C55 C56 -175.4(4) . . . . ?
C54 C55 C56 C57 0.0 . . . . ?
C55 C56 C57 C58 0.0 . . . . ?
C56 C57 C58 C59 0.0 . . . . ?
C57 C58 C59 C54 0.0 . . . . ?
C57 C58 C59 C60 -175.5(5) . . . . ?
C55 C54 C59 C58 0.0 . . . . ?
C53 C54 C59 C58 175.1(4) . . . . ?
C55 C54 C59 C60 175.1(6) . . . . ?
C53 C54 C59 C60 -9.8(6) . . . . ?
C65 N1 C61 C62 0.0 . . . . ?
Dy2 N1 C61 C62 -178.7(2) . . . . ?
N1 C61 C62 C63 0.0 . . . . ?
C61 C62 C63 C64 0.0 . . . . ?
C62 C63 C64 C65 0.0 . . . . ?
C62 C63 C64 C66 -179.8(5) . . . . ?
C63 C64 C65 C68 -177.2(4) . . . . ?
C66 C64 C65 C68 2.6(5) . . . . ?
C63 C64 C65 N1 0.0 . . . . ?
C66 C64 C65 N1 179.8(5) . . . . ?
C61 N1 C65 C68 177.3(4) . . . . ?
Dy2 N1 C65 C68 -4.1(3) . . . . ?
C61 N1 C65 C64 0.0 . . . . ?
Dy2 N1 C65 C64 178.6(2) . . . . ?
C65 C64 C66 C67 -1.4(8) . . . . ?
C63 C64 C66 C67 178.4(5) . . . . ?
C64 C66 C67 C69 -1.1(10) . . . . ?
C64 C65 C68 C69 -1.2(4) . . . . ?
N1 C65 C68 C69 -178.4(2) . . . . ?
C64 C65 C68 N2 176.6(2) . . . . ?
N1 C65 C68 N2 -0.6(4) . . . . ?
C72 N2 C68 C65 -177.9(3) . . . . ?
Dy2 N2 C68 C65 4.8(3) . . . . ?
C72 N2 C68 C69 0.0 . . . . ?
Dy2 N2 C68 C69 -177.3(2) . . . . ?
C65 C68 C69 C70 177.8(4) . . . . ?
N2 C68 C69 C70 0.0 . . . . ?
C65 C68 C69 C67 -1.3(4) . . . . ?
N2 C68 C69 C67 -179.2(4) . . . . ?
C66 C67 C69 C68 2.5(8) . . . . ?
C66 C67 C69 C70 -176.7(5) . . . . ?
C68 C69 C70 C71 0.0 . . . . ?
C67 C69 C70 C71 179.2(4) . . . . ?
C69 C70 C71 C72 0.0 . . . . ?
C70 C71 C72 N2 0.0 . . . . ?
C68 N2 C72 C71 0.0 . . . . ?
Dy2 N2 C72 C71 177.3(2) . . . . ?
C32 N3 Dy1 O12 74.2(2) . . . 2_656 ?
C36 N3 Dy1 O12 -100.2(2) . . . 2_656 ?
C32 N3 Dy1 O9 152.0(2) . . . 2_656 ?
C36 N3 Dy1 O9 -22.40(19) . . . 2_656 ?
C32 N3 Dy1 O7 14.7(3) . . . . ?
C36 N3 Dy1 O7 -159.7(2) . . . . ?
C32 N3 Dy1 O8 -145.8(2) . . . . ?
C36 N3 Dy1 O8 39.8(3) . . . . ?
C32 N3 Dy1 O11 -128.7(2) . . . . ?
C36 N3 Dy1 O11 56.9(2) . . . . ?
C32 N3 Dy1 O10 -78.9(2) . . . . ?
C36 N3 Dy1 O10 106.7(2) . . . . ?
C32 N3 Dy1 N4 -9.07(18) . . . . ?
C36 N3 Dy1 N4 176.5(2) . . . . ?
C32 N3 Dy1 C9 -104.4(2) . . . . ?
C36 N3 Dy1 C9 81.1(2) . . . . ?
C32 N3 Dy1 O12 125.3(2) . . . . ?
C36 N3 Dy1 O12 -49.1(2) . . . . ?
C32 N3 Dy1 C1 165.6(3) . . . . ?
C36 N3 Dy1 C1 -8.8(4) . . . . ?
C25 N4 Dy1 O12 100.2(2) . . . 2_656 ?
C29 N4 Dy1 O12 -74.4(2) . . . 2_656 ?
C25 N4 Dy1 O9 156.2(2) . . . 2_656 ?
C29 N4 Dy1 O9 -18.5(3) . . . 2_656 ?
C25 N4 Dy1 O7 20.9(2) . . . . ?
C29 N4 Dy1 O7 -153.8(2) . . . . ?
C25 N4 Dy1 O8 -29.2(3) . . . . ?
C29 N4 Dy1 O8 156.1(2) . . . . ?
C25 N4 Dy1 O11 -115.8(2) . . . . ?
C29 N4 Dy1 O11 69.6(2) . . . . ?
C25 N4 Dy1 O10 -72.8(2) . . . . ?
C29 N4 Dy1 O10 112.6(2) . . . . ?
C25 N4 Dy1 N3 -176.7(2) . . . . ?
C29 N4 Dy1 N3 8.65(19) . . . . ?
C25 N4 Dy1 C9 -92.7(2) . . . . ?
C29 N4 Dy1 C9 92.6(2) . . . . ?
C25 N4 Dy1 O12 46.7(3) . . . . ?
C29 N4 Dy1 O12 -127.9(2) . . . . ?
C25 N4 Dy1 C1 7.3(3) . . . . ?
C29 N4 Dy1 C1 -167.4(2) . . . . ?
O11 C9 Dy1 O12 -66.2(7) . . . 2_656 ?
O10 C9 Dy1 O12 104.0(6) . . . 2_656 ?
C10 C9 Dy1 O12 -158(2) . . . 2_656 ?
O11 C9 Dy1 O9 14.8(3) . . . 2_656 ?
O10 C9 Dy1 O9 -175.0(3) . . . 2_656 ?
C10 C9 Dy1 O9 -77(2) . . . 2_656 ?
O11 C9 Dy1 O7 162.1(3) . . . . ?
O10 C9 Dy1 O7 -27.7(3) . . . . ?
C10 C9 Dy1 O7 70(2) . . . . ?
O11 C9 Dy1 O8 96.6(3) . . . . ?
O10 C9 Dy1 O8 -93.1(3) . . . . ?
C10 C9 Dy1 O8 4(2) . . . . ?
O10 C9 Dy1 O11 170.2(5) . . . . ?
C10 C9 Dy1 O11 -92(2) . . . . ?
O11 C9 Dy1 O10 -170.2(5) . . . . ?
C10 C9 Dy1 O10 98(2) . . . . ?
O11 C9 Dy1 N3 -61.3(3) . . . . ?
O10 C9 Dy1 N3 109.0(3) . . . . ?
C10 C9 Dy1 N3 -153(2) . . . . ?
O11 C9 Dy1 N4 -123.9(3) . . . . ?
O10 C9 Dy1 N4 46.4(3) . . . . ?
C10 C9 Dy1 N4 144(2) . . . . ?
O11 C9 Dy1 O12 85.3(3) . . . . ?
O10 C9 Dy1 O12 -104.5(3) . . . . ?
C10 C9 Dy1 O12 -7(2) . . . . ?
O11 C9 Dy1 C1 92.1(3) . . . . ?
O10 C9 Dy1 C1 -97.7(3) . . . . ?
C10 C9 Dy1 C1 0(2) . . . . ?
O8 C1 Dy1 O12 -175.1(4) . . . 2_656 ?
O12 C1 Dy1 O12 8.8(4) . . . 2_656 ?
C2 C1 Dy1 O12 -135.0(17) . . . 2_656 ?
O8 C1 Dy1 O9 112.2(4) . . . 2_656 ?
O12 C1 Dy1 O9 -63.9(3) . . . 2_656 ?
C2 C1 Dy1 O9 152.4(18) . . . 2_656 ?
O8 C1 Dy1 O7 -103.3(4) . . . . ?
O12 C1 Dy1 O7 80.6(3) . . . . ?
C2 C1 Dy1 O7 -63.1(17) . . . . ?
O12 C1 Dy1 O8 -176.1(6) . . . . ?
C2 C1 Dy1 O8 40.1(16) . . . . ?
O8 C1 Dy1 O11 37.3(4) . . . . ?
O12 C1 Dy1 O11 -138.8(3) . . . . ?
C2 C1 Dy1 O11 77.4(17) . . . . ?
O8 C1 Dy1 O10 -16.5(4) . . . . ?
O12 C1 Dy1 O10 167.4(3) . . . . ?
C2 C1 Dy1 O10 23.6(17) . . . . ?
O8 C1 Dy1 N3 98.6(5) . . . . ?
O12 C1 Dy1 N3 -77.5(4) . . . . ?
C2 C1 Dy1 N3 138.7(16) . . . . ?
O8 C1 Dy1 N4 -89.3(4) . . . . ?
O12 C1 Dy1 N4 94.6(4) . . . . ?
C2 C1 Dy1 N4 -49.2(18) . . . . ?
O8 C1 Dy1 C9 10.5(4) . . . . ?
O12 C1 Dy1 C9 -165.6(3) . . . . ?
C2 C1 Dy1 C9 50.6(17) . . . . ?
O8 C1 Dy1 O12 176.1(6) . . . . ?
C2 C1 Dy1 O12 -143.8(19) . . . . ?
C61 N1 Dy2 O5 103.1(2) . . . 2_567 ?
C65 N1 Dy2 O5 -75.5(2) . . . 2_567 ?
C61 N1 Dy2 O6 26.45(19) . . . . ?
C65 N1 Dy2 O6 -152.2(2) . . . . ?
C61 N1 Dy2 O2 165.9(2) . . . 2_567 ?
C65 N1 Dy2 O2 -12.8(3) . . . 2_567 ?
C61 N1 Dy2 O3 -105.2(2) . . . . ?
C65 N1 Dy2 O3 76.2(2) . . . . ?
C61 N1 Dy2 O1 -35.1(3) . . . . ?
C65 N1 Dy2 O1 146.2(2) . . . . ?
C61 N1 Dy2 O4 -53.4(2) . . . . ?
C65 N1 Dy2 O4 128.0(2) . . . . ?
C61 N1 Dy2 N2 -176.9(2) . . . . ?
C65 N1 Dy2 N2 4.49(18) . . . . ?
C61 N1 Dy2 O5 50.2(3) . . . . ?
C65 N1 Dy2 O5 -128.5(2) . . . . ?
C61 N1 Dy2 C37 -79.5(2) . . . . ?
C65 N1 Dy2 C37 101.8(2) . . . . ?
C61 N1 Dy2 C45 7.8(3) . . . . ?
C65 N1 Dy2 C45 -170.9(3) . . . . ?
C68 N2 Dy2 O5 82.25(19) . . . 2_567 ?
C72 N2 Dy2 O5 -95.0(2) . . . 2_567 ?
C68 N2 Dy2 O6 27.1(2) . . . . ?
C72 N2 Dy2 O6 -150.22(19) . . . . ?
C68 N2 Dy2 O2 163.0(2) . . . 2_567 ?
C72 N2 Dy2 O2 -14.32(19) . . . 2_567 ?
C68 N2 Dy2 O3 -103.0(2) . . . . ?
C72 N2 Dy2 O3 79.7(2) . . . . ?
C68 N2 Dy2 O1 -147.2(2) . . . . ?
C72 N2 Dy2 O1 35.5(3) . . . . ?
C68 N2 Dy2 O4 -62.0(2) . . . . ?
C72 N2 Dy2 O4 120.71(19) . . . . ?
C68 N2 Dy2 N1 -4.63(17) . . . . ?
C72 N2 Dy2 N1 178.1(2) . . . . ?
C68 N2 Dy2 O5 132.70(19) . . . . ?
C72 N2 Dy2 O5 -44.6(2) . . . . ?
C68 N2 Dy2 C37 -83.4(2) . . . . ?
C72 N2 Dy2 C37 99.3(2) . . . . ?
C68 N2 Dy2 C45 170.9(2) . . . . ?
C72 N2 Dy2 C45 -6.3(3) . . . . ?
O4 C37 Dy2 O5 77.2(6) . . . 2_567 ?
O3 C37 Dy2 O5 -98.5(5) . . . 2_567 ?
C38 C37 Dy2 O5 -153(4) . . . 2_567 ?
O4 C37 Dy2 O6 -5.0(3) . . . . ?
O3 C37 Dy2 O6 179.3(3) . . . . ?
C38 C37 Dy2 O6 124(4) . . . . ?
O4 C37 Dy2 O2 -155.3(3) . . . 2_567 ?
O3 C37 Dy2 O2 29.0(3) . . . 2_567 ?
C38 C37 Dy2 O2 -26(4) . . . 2_567 ?
O4 C37 Dy2 O3 175.7(5) . . . . ?
C38 C37 Dy2 O3 -55(4) . . . . ?
O4 C37 Dy2 O1 -85.1(3) . . . . ?
O3 C37 Dy2 O1 99.1(3) . . . . ?
C38 C37 Dy2 O1 44(4) . . . . ?
O3 C37 Dy2 O4 -175.7(5) . . . . ?
C38 C37 Dy2 O4 129(4) . . . . ?
O4 C37 Dy2 N1 68.5(3) . . . . ?
O3 C37 Dy2 N1 -107.2(3) . . . . ?
C38 C37 Dy2 N1 -162(4) . . . . ?
O4 C37 Dy2 N2 130.3(3) . . . . ?
O3 C37 Dy2 N2 -45.4(3) . . . . ?
C38 C37 Dy2 N2 -100(4) . . . . ?
O4 C37 Dy2 O5 -77.3(3) . . . . ?
O3 C37 Dy2 O5 106.9(3) . . . . ?
C38 C37 Dy2 O5 52(4) . . . . ?
O4 C37 Dy2 C45 -80.7(3) . . . . ?
O3 C37 Dy2 C45 103.5(3) . . . . ?
C38 C37 Dy2 C45 49(4) . . . . ?
O1 C45 Dy2 O5 176.4(4) . . . 2_567 ?
O5 C45 Dy2 O5 -0.3(4) . . . 2_567 ?
C46 C45 Dy2 O5 -124.3(17) . . . 2_567 ?
O1 C45 Dy2 O6 -112.2(4) . . . . ?
O5 C45 Dy2 O6 71.1(3) . . . . ?
C46 C45 Dy2 O6 -52.9(17) . . . . ?
O1 C45 Dy2 O2 102.4(4) . . . 2_567 ?
O5 C45 Dy2 O2 -74.3(3) . . . 2_567 ?
C46 C45 Dy2 O2 161.7(18) . . . 2_567 ?
O1 C45 Dy2 O3 16.5(4) . . . . ?
O5 C45 Dy2 O3 -160.2(3) . . . . ?
C46 C45 Dy2 O3 75.8(18) . . . . ?
O5 C45 Dy2 O1 -176.7(6) . . . . ?
C46 C45 Dy2 O1 59.3(17) . . . . ?
O1 C45 Dy2 O4 -36.7(4) . . . . ?
O5 C45 Dy2 O4 146.6(3) . . . . ?
C46 C45 Dy2 O4 22.6(18) . . . . ?
O1 C45 Dy2 N1 -93.4(5) . . . . ?
O5 C45 Dy2 N1 89.9(4) . . . . ?
C46 C45 Dy2 N1 -34.1(19) . . . . ?
O1 C45 Dy2 N2 94.4(4) . . . . ?
O5 C45 Dy2 N2 -82.3(4) . . . . ?
C46 C45 Dy2 N2 153.7(16) . . . . ?
O1 C45 Dy2 O5 176.7(6) . . . . ?
C46 C45 Dy2 O5 -124.0(19) . . . . ?
O1 C45 Dy2 C37 -10.2(4) . . . . ?
O5 C45 Dy2 C37 173.1(3) . . . . ?
C46 C45 Dy2 C37 49.1(18) . . . . ?
O5 C45 O1 Dy2 3.6(7) . . . . ?
C46 C45 O1 Dy2 -167.3(5) . . . . ?
O5 Dy2 O1 C45 -4.3(5) 2_567 . . . ?
O6 Dy2 O1 C45 63.7(4) . . . . ?
O2 Dy2 O1 C45 -71.9(4) 2_567 . . . ?
O3 Dy2 O1 C45 -163.5(4) . . . . ?
O4 Dy2 O1 C45 141.1(4) . . . . ?
N1 Dy2 O1 C45 122.8(4) . . . . ?
N2 Dy2 O1 C45 -120.5(4) . . . . ?
O5 Dy2 O1 C45 -1.8(3) . . . . ?
C37 Dy2 O1 C45 169.3(4) . . . . ?
O6 C53 O2 Dy2 1.1(8) . . . 2_567 ?
C54 C53 O2 Dy2 179.8(3) . . . 2_567 ?
O4 C37 O3 Dy2 -4.4(5) . . . . ?
C38 C37 O3 Dy2 175.6(3) . . . . ?
O5 Dy2 O3 C37 142.6(3) 2_567 . . . ?
O6 Dy2 O3 C37 -0.9(4) . . . . ?
O2 Dy2 O3 C37 -153.6(3) 2_567 . . . ?
O1 Dy2 O3 C37 -73.9(3) . . . . ?
O4 Dy2 O3 C37 2.4(3) . . . . ?
N1 Dy2 O3 C37 70.7(3) . . . . ?
N2 Dy2 O3 C37 132.1(3) . . . . ?
O5 Dy2 O3 C37 -90.7(3) . . . . ?
C45 Dy2 O3 C37 -80.7(3) . . . . ?
O3 C37 O4 Dy2 4.2(5) . . . . ?
C38 C37 O4 Dy2 -175.7(4) . . . . ?
O5 Dy2 O4 C37 -148.9(3) 2_567 . . . ?
O6 Dy2 O4 C37 175.0(3) . . . . ?
O2 Dy2 O4 C37 34.3(4) 2_567 . . . ?
O3 Dy2 O4 C37 -2.4(3) . . . . ?
O1 Dy2 O4 C37 86.1(3) . . . . ?
N1 Dy2 O4 C37 -105.4(3) . . . . ?
N2 Dy2 O4 C37 -53.8(3) . . . . ?
O5 Dy2 O4 C37 115.6(3) . . . . ?
C45 Dy2 O4 C37 101.1(3) . . . . ?
O1 C45 O5 Dy2 175.4(16) . . . 2_567 ?
C46 C45 O5 Dy2 -13(2) . . . 2_567 ?
Dy2 C45 O5 Dy2 179(2) . . . 2_567 ?
O1 C45 O5 Dy2 -3.1(6) . . . . ?
C46 C45 O5 Dy2 168.1(5) . . . . ?
O5 Dy2 O5 C45 179.7(4) 2_567 . . . ?
O6 Dy2 O5 C45 -100.7(3) . . . . ?
O2 Dy2 O5 C45 97.1(3) 2_567 . . . ?
O3 Dy2 O5 C45 23.9(4) . . . . ?
O1 Dy2 O5 C45 1.8(3) . . . . ?
O4 Dy2 O5 C45 -36.4(3) . . . . ?
N1 Dy2 O5 C45 -125.6(3) . . . . ?
N2 Dy2 O5 C45 128.6(3) . . . . ?
C37 Dy2 O5 C45 -8.0(4) . . . . ?
O5 Dy2 O5 Dy2 0.0 2_567 . . 2_567 ?
O6 Dy2 O5 Dy2 79.59(14) . . . 2_567 ?
O2 Dy2 O5 Dy2 -82.65(14) 2_567 . . 2_567 ?
O3 Dy2 O5 Dy2 -155.86(12) . . . 2_567 ?
O1 Dy2 O5 Dy2 -177.9(2) . . . 2_567 ?
O4 Dy2 O5 Dy2 143.89(13) . . . 2_567 ?
N1 Dy2 O5 Dy2 54.7(2) . . . 2_567 ?
N2 Dy2 O5 Dy2 -51.1(2) . . . 2_567 ?
C37 Dy2 O5 Dy2 172.26(15) . . . 2_567 ?
C45 Dy2 O5 Dy2 -179.7(4) . . . 2_567 ?
O2 C53 O6 Dy2 25.4(8) . . . . ?
C54 C53 O6 Dy2 -153.4(3) . . . . ?
O5 Dy2 O6 C53 19.9(5) 2_567 . . . ?
O2 Dy2 O6 C53 -36.8(6) 2_567 . . . ?
O3 Dy2 O6 C53 -177.8(5) . . . . ?
O1 Dy2 O6 C53 -107.7(5) . . . . ?
O4 Dy2 O6 C53 179.5(5) . . . . ?
N1 Dy2 O6 C53 104.5(5) . . . . ?
N2 Dy2 O6 C53 75.9(5) . . . . ?
O5 Dy2 O6 C53 -59.8(5) . . . . ?
C37 Dy2 O6 C53 -178.2(5) . . . . ?
C45 Dy2 O6 C53 -85.2(5) . . . . ?
O9 C17 O7 Dy1 15.6(8) . . . . ?
C18 C17 O7 Dy1 -166.3(3) . . . . ?
O12 Dy1 O7 C17 24.9(5) 2_656 . . . ?
O9 Dy1 O7 C17 -31.9(5) 2_656 . . . ?
O8 Dy1 O7 C17 -105.4(5) . . . . ?
O11 Dy1 O7 C17 -154.6(4) . . . . ?
O10 Dy1 O7 C17 -178.9(5) . . . . ?
N3 Dy1 O7 C17 85.2(5) . . . . ?
N4 Dy1 O7 C17 107.1(5) . . . . ?
C9 Dy1 O7 C17 -166.7(5) . . . . ?
O12 Dy1 O7 C17 -54.8(5) . . . . ?
C1 Dy1 O7 C17 -81.5(5) . . . . ?
O12 C1 O8 Dy1 4.3(7) . . . . ?
C2 C1 O8 Dy1 -170.6(5) . . . . ?
O12 Dy1 O8 C1 5.8(5) 2_656 . . . ?
O9 Dy1 O8 C1 -64.5(4) 2_656 . . . ?
O7 Dy1 O8 C1 69.9(4) . . . . ?
O11 Dy1 O8 C1 -141.3(4) . . . . ?
O10 Dy1 O8 C1 162.9(4) . . . . ?
N3 Dy1 O8 C1 -124.3(4) . . . . ?
N4 Dy1 O8 C1 119.2(4) . . . . ?
C9 Dy1 O8 C1 -168.8(5) . . . . ?
O12 Dy1 O8 C1 -2.2(4) . . . . ?
O7 C17 O9 Dy1 12.0(9) . . . 2_656 ?
C18 C17 O9 Dy1 -166.1(3) . . . 2_656 ?
O11 C9 O10 Dy1 9.8(5) . . . . ?
C10 C9 O10 Dy1 -169.6(4) . . . . ?
O12 Dy1 O10 C9 -146.5(3) 2_656 . . . ?
O9 Dy1 O10 C9 6.3(4) 2_656 . . . ?
O7 Dy1 O10 C9 154.8(3) . . . . ?
O8 Dy1 O10 C9 77.9(3) . . . . ?
O11 Dy1 O10 C9 -5.4(3) . . . . ?
N3 Dy1 O10 C9 -71.2(3) . . . . ?
N4 Dy1 O10 C9 -131.4(3) . . . . ?
O12 Dy1 O10 C9 91.0(3) . . . . ?
C1 Dy1 O10 C9 84.8(3) . . . . ?
O10 C9 O11 Dy1 -9.9(5) . . . . ?
C10 C9 O11 Dy1 169.5(4) . . . . ?
O12 Dy1 O11 C9 155.6(3) 2_656 . . . ?
O9 Dy1 O11 C9 -165.1(3) 2_656 . . . ?
O7 Dy1 O11 C9 -25.2(4) . . . . ?
O8 Dy1 O11 C9 -75.0(3) . . . . ?
O10 Dy1 O11 C9 5.5(3) . . . . ?
N3 Dy1 O11 C9 114.4(3) . . . . ?
N4 Dy1 O11 C9 60.2(3) . . . . ?
O12 Dy1 O11 C9 -107.3(3) . . . . ?
C1 Dy1 O11 C9 -89.7(3) . . . . ?
O8 C1 O12 Dy1 -139.7(14) . . . 2_656 ?
C2 C1 O12 Dy1 35(2) . . . 2_656 ?
Dy1 C1 O12 Dy1 -136.1(17) . . . 2_656 ?
O8 C1 O12 Dy1 -3.6(6) . . . . ?
C2 C1 O12 Dy1 171.2(6) . . . . ?
O12 Dy1 O12 C1 -171.1(4) 2_656 . . . ?
O9 Dy1 O12 C1 108.5(3) 2_656 . . . ?
O7 Dy1 O12 C1 -89.7(3) . . . . ?
O8 Dy1 O12 C1 2.1(3) . . . . ?
O11 Dy1 O12 C1 45.3(3) . . . . ?
O10 Dy1 O12 C1 -14.7(4) . . . . ?
N3 Dy1 O12 C1 136.9(3) . . . . ?
N4 Dy1 O12 C1 -116.6(3) . . . . ?
C9 Dy1 O12 C1 16.3(4) . . . . ?
O12 Dy1 O12 Dy1 0.0 2_656 . . 2_656 ?
O9 Dy1 O12 Dy1 -80.39(14) 2_656 . . 2_656 ?
O7 Dy1 O12 Dy1 81.37(14) . . . 2_656 ?
O8 Dy1 O12 Dy1 173.2(2) . . . 2_656 ?
O11 Dy1 O12 Dy1 -143.58(13) . . . 2_656 ?
O10 Dy1 O12 Dy1 156.46(12) . . . 2_656 ?
N3 Dy1 O12 Dy1 -52.0(2) . . . 2_656 ?
N4 Dy1 O12 Dy1 54.5(2) . . . 2_656 ?
C9 Dy1 O12 Dy1 -172.61(15) . . . 2_656 ?
C1 Dy1 O12 Dy1 171.1(4) . . . 2_656 ?
_diffrn_measured_fraction_theta_max 1.000
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 1.000
_refine_diff_density_max         1.281
_refine_diff_density_min         -0.720
_refine_diff_density_rms         0.085