# Electronic Supplementary Material (ESI) for Dalton Transactions
# This journal is © The Royal Society of Chemistry 2013

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_global


data_louis90
#TrackingRef 'LOUIS90.CIF'


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C44 H40 B N O2 Pt'
_chemical_formula_weight         820.67

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.105(2)
_cell_length_b                   11.650(3)
_cell_length_c                   19.084(5)
_cell_angle_alpha                95.968(2)
_cell_angle_beta                 93.914(3)
_cell_angle_gamma                97.898(2)
_cell_volume                     1769.0(8)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       thin-plate
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.02
_exptl_crystal_size_mid          0.01
_exptl_crystal_size_min          0.01
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.541
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             820
_exptl_absorpt_coefficient_mu    4.005
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.9242
_exptl_absorpt_correction_T_max  0.9610
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            15883
_diffrn_reflns_av_R_equivalents  0.0715
_diffrn_reflns_av_sigmaI/netI    0.0937
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         1.78
_diffrn_reflns_theta_max         26.00
_reflns_number_total             6869
_reflns_number_gt                5511
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0776P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6869
_refine_ls_number_parameters     443
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0716
_refine_ls_R_factor_gt           0.0567
_refine_ls_wR_factor_ref         0.1451
_refine_ls_wR_factor_gt          0.1362
_refine_ls_goodness_of_fit_ref   1.020
_refine_ls_restrained_S_all      1.020
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt -0.08360(4) 0.22577(2) 0.043098(16) 0.03128(13) Uani 1 1 d . . .
B1 B 0.2315(11) 0.8108(8) 0.3514(5) 0.0329(19) Uani 1 1 d . . .
N1 N -0.1753(8) 0.0739(6) -0.0138(4) 0.0390(16) Uani 1 1 d . . .
O1 O 0.0591(6) 0.2884(4) -0.0341(3) 0.0341(12) Uani 1 1 d . . .
O2 O 0.0016(7) 0.3713(5) 0.1099(3) 0.0382(13) Uani 1 1 d . . .
C1 C -0.2199(9) 0.1544(6) 0.1150(4) 0.0264(15) Uani 1 1 d . . .
C2 C -0.2399(10) 0.2055(8) 0.1811(5) 0.042(2) Uani 1 1 d . . .
H2A H -0.1879 0.2814 0.1955 0.050 Uiso 1 1 calc R . .
C3 C -0.3373(10) 0.1457(8) 0.2277(4) 0.0395(19) Uani 1 1 d . . .
H3A H -0.3491 0.1820 0.2725 0.047 Uiso 1 1 calc R . .
C4 C -0.4160(11) 0.0323(8) 0.2069(5) 0.045(2) Uani 1 1 d . . .
H4A H -0.4808 -0.0073 0.2377 0.054 Uiso 1 1 calc R . .
C5 C -0.3975(10) -0.0218(7) 0.1397(5) 0.0386(19) Uani 1 1 d . . .
H5A H -0.4489 -0.0979 0.1256 0.046 Uiso 1 1 calc R . .
C6 C -0.3013(10) 0.0389(7) 0.0941(4) 0.0339(18) Uani 1 1 d . . .
C7 C -0.2741(9) -0.0060(7) 0.0202(5) 0.0344(18) Uani 1 1 d . . .
C8 C -0.3389(10) -0.1162(7) -0.0135(5) 0.0378(19) Uani 1 1 d . . .
H8A H -0.4057 -0.1687 0.0099 0.045 Uiso 1 1 calc R . .
C9 C -0.3027(11) -0.1467(7) -0.0822(5) 0.042(2) Uani 1 1 d . . .
H9A H -0.3438 -0.2205 -0.1053 0.051 Uiso 1 1 calc R . .
C10 C -0.2039(11) -0.0661(8) -0.1167(5) 0.043(2) Uani 1 1 d . . .
H10A H -0.1794 -0.0856 -0.1630 0.052 Uiso 1 1 calc R . .
C11 C -0.1433(10) 0.0422(7) -0.0819(4) 0.0372(18) Uani 1 1 d . . .
H11A H -0.0784 0.0956 -0.1054 0.045 Uiso 1 1 calc R . .
C12 C 0.1139(9) 0.4571(6) 0.0980(4) 0.0293(16) Uani 1 1 d . . .
C13 C 0.1950(10) 0.4660(7) 0.0358(4) 0.0326(17) Uani 1 1 d . . .
H13A H 0.2761 0.5305 0.0351 0.039 Uiso 1 1 calc R . .
C14 C 0.1641(9) 0.3849(6) -0.0265(4) 0.0283(16) Uani 1 1 d . . .
C15 C 0.2584(9) 0.4078(6) -0.0905(4) 0.0296(16) Uani 1 1 d . . .
C16 C 0.3404(10) 0.5173(7) -0.1003(4) 0.0381(19) Uani 1 1 d . . .
H16A H 0.3422 0.5803 -0.0659 0.046 Uiso 1 1 calc R . .
C17 C 0.4194(11) 0.5323(8) -0.1615(5) 0.047(2) Uani 1 1 d . . .
H17A H 0.4752 0.6055 -0.1673 0.056 Uiso 1 1 calc R . .
C18 C 0.4174(11) 0.4419(8) -0.2141(5) 0.044(2) Uani 1 1 d . . .
H18A H 0.4713 0.4536 -0.2548 0.053 Uiso 1 1 calc R . .
C19 C 0.3331(12) 0.3322(8) -0.2053(5) 0.048(2) Uani 1 1 d . . .
H19A H 0.3288 0.2700 -0.2404 0.057 Uiso 1 1 calc R . .
C20 C 0.2525(9) 0.3162(7) -0.1408(4) 0.0315(17) Uani 1 1 d . . .
H20A H 0.1970 0.2433 -0.1341 0.038 Uiso 1 1 calc R . .
C21 C 0.1501(10) 0.5507(7) 0.1601(4) 0.0343(18) Uani 1 1 d . . .
C22 C 0.2193(9) 0.6680(6) 0.1543(4) 0.0305(16) Uani 1 1 d . . .
H22A H 0.2479 0.6901 0.1108 0.037 Uiso 1 1 calc R . .
C23 C 0.2437(10) 0.7493(6) 0.2140(4) 0.0323(17) Uani 1 1 d . . .
H23A H 0.2867 0.8261 0.2092 0.039 Uiso 1 1 calc R . .
C24 C 0.2061(10) 0.7203(7) 0.2815(4) 0.0346(18) Uani 1 1 d . . .
C25 C 0.1392(11) 0.6028(7) 0.2846(4) 0.042(2) Uani 1 1 d . . .
H25A H 0.1125 0.5794 0.3281 0.050 Uiso 1 1 calc R . .
C26 C 0.1118(11) 0.5216(7) 0.2257(4) 0.042(2) Uani 1 1 d . . .
H26A H 0.0663 0.4453 0.2304 0.051 Uiso 1 1 calc R . .
C27 C 0.2224(10) 0.7567(6) 0.4239(4) 0.0344(18) Uani 1 1 d . . .
C28 C 0.3319(11) 0.6790(7) 0.4451(4) 0.0380(19) Uani 1 1 d . . .
C29 C 0.3079(12) 0.6200(8) 0.5044(5) 0.047(2) Uani 1 1 d . . .
H29A H 0.3809 0.5687 0.5162 0.057 Uiso 1 1 calc R . .
C30 C 0.1519(16) 0.5723(11) 0.6118(6) 0.079(4) Uani 1 1 d . . .
H29B H 0.0562 0.5936 0.6342 0.118 Uiso 1 1 calc R . .
H29C H 0.2496 0.5930 0.6444 0.118 Uiso 1 1 calc R . .
H29D H 0.1352 0.4897 0.5978 0.118 Uiso 1 1 calc R . .
C31 C 0.1749(13) 0.6365(8) 0.5470(5) 0.051(2) Uani 1 1 d . . .
C32 C 0.0714(13) 0.7149(8) 0.5279(5) 0.051(2) Uani 1 1 d . . .
H31A H -0.0146 0.7294 0.5559 0.062 Uiso 1 1 calc R . .
C33 C 0.0909(11) 0.7727(7) 0.4686(4) 0.043(2) Uani 1 1 d . . .
C34 C -0.0396(12) 0.8507(9) 0.4482(6) 0.060(3) Uani 1 1 d . . .
H33A H -0.1192 0.8523 0.4832 0.091 Uiso 1 1 calc R . .
H33B H -0.0962 0.8198 0.4030 0.091 Uiso 1 1 calc R . .
H33C H 0.0155 0.9284 0.4458 0.091 Uiso 1 1 calc R . .
C35 C 0.4842(12) 0.6575(8) 0.4050(5) 0.047(2) Uani 1 1 d . . .
H34A H 0.5421 0.6025 0.4272 0.070 Uiso 1 1 calc R . .
H34B H 0.5579 0.7297 0.4059 0.070 Uiso 1 1 calc R . .
H34C H 0.4482 0.6270 0.3569 0.070 Uiso 1 1 calc R . .
C36 C 0.2585(10) 0.9468(7) 0.3469(4) 0.0350(18) Uani 1 1 d . . .
C37 C 0.1375(11) 1.0027(8) 0.3122(4) 0.041(2) Uani 1 1 d . . .
C38 C 0.1604(11) 1.1251(8) 0.3144(5) 0.043(2) Uani 1 1 d . . .
H38A H 0.0771 1.1609 0.2934 0.052 Uiso 1 1 calc R . .
C39 C 0.3033(12) 1.1933(7) 0.3469(5) 0.043(2) Uani 1 1 d . . .
C40 C 0.4246(11) 1.1389(7) 0.3798(4) 0.0382(19) Uani 1 1 d . . .
H40A H 0.5215 1.1841 0.4017 0.046 Uiso 1 1 calc R . .
C41 C 0.4046(10) 1.0184(7) 0.3806(4) 0.0353(18) Uani 1 1 d . . .
C42 C -0.0269(12) 0.9361(9) 0.2767(5) 0.050(2) Uani 1 1 d . . .
H42A H -0.0913 0.9895 0.2564 0.076 Uiso 1 1 calc R . .
H42B H -0.0887 0.8982 0.3111 0.076 Uiso 1 1 calc R . .
H42C H -0.0044 0.8786 0.2402 0.076 Uiso 1 1 calc R . .
C43 C 0.5499(10) 0.9648(7) 0.4127(4) 0.0403(19) Uani 1 1 d . . .
H43A H 0.6371 1.0258 0.4329 0.060 Uiso 1 1 calc R . .
H43B H 0.5922 0.9160 0.3765 0.060 Uiso 1 1 calc R . .
H43C H 0.5115 0.9188 0.4489 0.060 Uiso 1 1 calc R . .
C44 C 0.3273(15) 1.3254(8) 0.3457(7) 0.068(3) Uani 1 1 d . . .
H44A H 0.2314 1.3471 0.3208 0.102 Uiso 1 1 calc R . .
H44B H 0.4254 1.3488 0.3222 0.102 Uiso 1 1 calc R . .
H44C H 0.3401 1.3633 0.3933 0.102 Uiso 1 1 calc R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Pt1 0.03083(18) 0.01857(17) 0.0440(2) 0.01021(12) 0.00391(12) -0.00337(12)
B1 0.029(5) 0.028(5) 0.041(5) 0.006(4) 0.006(4) -0.003(4)
N1 0.030(4) 0.035(4) 0.055(4) 0.012(3) 0.000(3) 0.010(3)
O1 0.032(3) 0.026(3) 0.043(3) 0.006(2) -0.001(2) -0.001(2)
O2 0.041(3) 0.028(3) 0.045(3) 0.007(2) 0.003(3) 0.000(3)
C1 0.019(3) 0.022(4) 0.037(4) 0.008(3) 0.000(3) -0.002(3)
C2 0.032(4) 0.034(5) 0.059(5) 0.011(4) 0.009(4) -0.004(4)
C3 0.036(5) 0.043(5) 0.038(4) 0.008(4) 0.007(3) -0.004(4)
C4 0.037(5) 0.048(5) 0.051(5) 0.024(4) 0.011(4) -0.006(4)
C5 0.036(4) 0.024(4) 0.055(5) 0.015(4) 0.001(4) -0.006(3)
C6 0.027(4) 0.026(4) 0.051(5) 0.016(4) 0.000(3) 0.004(3)
C7 0.023(4) 0.023(4) 0.058(5) 0.014(4) -0.002(3) 0.002(3)
C8 0.039(5) 0.018(4) 0.057(5) 0.013(4) 0.000(4) -0.001(3)
C9 0.039(5) 0.026(4) 0.058(5) 0.006(4) -0.005(4) -0.006(4)
C10 0.042(5) 0.035(5) 0.053(5) 0.001(4) 0.002(4) 0.009(4)
C11 0.039(5) 0.031(4) 0.043(5) 0.010(4) 0.000(4) 0.006(4)
C12 0.029(4) 0.013(3) 0.045(4) 0.012(3) -0.006(3) 0.000(3)
C13 0.029(4) 0.023(4) 0.044(4) 0.009(3) 0.000(3) -0.004(3)
C14 0.023(4) 0.017(3) 0.045(4) 0.015(3) -0.001(3) -0.001(3)
C15 0.027(4) 0.016(3) 0.045(4) 0.009(3) -0.002(3) -0.001(3)
C16 0.035(4) 0.030(4) 0.048(5) 0.007(4) 0.011(4) -0.004(4)
C17 0.049(5) 0.034(5) 0.055(5) 0.010(4) 0.014(4) -0.011(4)
C18 0.038(5) 0.042(5) 0.049(5) 0.014(4) 0.010(4) -0.011(4)
C19 0.057(6) 0.026(4) 0.056(5) -0.002(4) 0.019(4) -0.012(4)
C20 0.023(4) 0.032(4) 0.042(4) -0.001(3) 0.006(3) 0.012(3)
C21 0.032(4) 0.020(4) 0.051(5) 0.009(3) 0.004(4) 0.000(3)
C22 0.025(4) 0.025(4) 0.041(4) 0.012(3) 0.002(3) -0.003(3)
C23 0.034(4) 0.019(4) 0.044(4) 0.016(3) 0.004(3) -0.004(3)
C24 0.034(4) 0.023(4) 0.045(4) 0.008(3) 0.004(3) -0.007(3)
C25 0.053(5) 0.029(4) 0.039(4) 0.010(4) 0.008(4) -0.016(4)
C26 0.055(6) 0.021(4) 0.047(5) 0.010(4) 0.007(4) -0.014(4)
C27 0.043(5) 0.018(4) 0.037(4) 0.000(3) 0.004(3) -0.012(3)
C28 0.047(5) 0.023(4) 0.042(4) 0.006(3) 0.007(4) -0.007(4)
C29 0.057(6) 0.038(5) 0.045(5) 0.016(4) 0.002(4) -0.010(4)
C30 0.086(9) 0.075(8) 0.077(8) 0.042(7) 0.028(7) -0.016(7)
C31 0.067(6) 0.038(5) 0.046(5) 0.014(4) 0.013(5) -0.015(5)
C32 0.057(6) 0.045(6) 0.048(5) 0.003(4) 0.020(4) -0.014(5)
C33 0.051(6) 0.028(5) 0.046(5) 0.007(4) 0.009(4) -0.012(4)
C34 0.052(6) 0.061(7) 0.075(7) 0.017(6) 0.035(5) 0.008(5)
C35 0.062(6) 0.029(5) 0.052(5) 0.018(4) 0.012(4) 0.002(4)
C36 0.036(4) 0.032(4) 0.036(4) 0.013(3) 0.005(3) -0.007(4)
C37 0.041(5) 0.039(5) 0.043(5) 0.004(4) 0.010(4) 0.000(4)
C38 0.045(5) 0.035(5) 0.051(5) 0.005(4) 0.003(4) 0.014(4)
C39 0.055(6) 0.024(4) 0.051(5) 0.011(4) 0.012(4) -0.002(4)
C40 0.041(5) 0.026(4) 0.043(4) 0.003(4) 0.006(4) -0.010(4)
C41 0.041(5) 0.025(4) 0.037(4) 0.007(3) 0.004(3) -0.005(4)
C42 0.043(5) 0.049(6) 0.059(6) 0.009(5) 0.000(4) 0.004(4)
C43 0.041(5) 0.027(4) 0.050(5) 0.006(4) 0.000(4) -0.007(4)
C44 0.076(8) 0.026(5) 0.108(9) 0.024(5) 0.019(7) 0.009(5)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C1 1.996(7) . ?
Pt1 N1 1.998(7) . ?
Pt1 O2 2.021(5) . ?
Pt1 O1 2.065(5) . ?
B1 C27 1.580(12) . ?
B1 C36 1.581(12) . ?
B1 C24 1.595(12) . ?
N1 C11 1.365(11) . ?
N1 C7 1.386(11) . ?
O1 C14 1.303(9) . ?
O2 C12 1.306(9) . ?
C1 C2 1.368(11) . ?
C1 C6 1.419(10) . ?
C2 C3 1.404(12) . ?
C2 H2A 0.9300 . ?
C3 C4 1.391(12) . ?
C3 H3A 0.9300 . ?
C4 C5 1.397(12) . ?
C4 H4A 0.9300 . ?
C5 C6 1.392(11) . ?
C5 H5A 0.9300 . ?
C6 C7 1.493(12) . ?
C7 C8 1.391(11) . ?
C8 C9 1.385(12) . ?
C8 H8A 0.9300 . ?
C9 C10 1.397(13) . ?
C9 H9A 0.9300 . ?
C10 C11 1.373(12) . ?
C10 H10A 0.9300 . ?
C11 H11A 0.9300 . ?
C12 C13 1.403(11) . ?
C12 C21 1.508(11) . ?
C13 C14 1.423(11) . ?
C13 H13A 0.9300 . ?
C14 C15 1.512(11) . ?
C15 C20 1.354(11) . ?
C15 C16 1.393(11) . ?
C16 C17 1.385(12) . ?
C16 H16A 0.9300 . ?
C17 C18 1.374(12) . ?
C17 H17A 0.9300 . ?
C18 C19 1.396(12) . ?
C18 H18A 0.9300 . ?
C19 C20 1.448(11) . ?
C19 H19A 0.9300 . ?
C20 H20A 0.9300 . ?
C21 C26 1.376(12) . ?
C21 C22 1.423(10) . ?
C22 C23 1.388(11) . ?
C22 H22A 0.9300 . ?
C23 C24 1.408(11) . ?
C23 H23A 0.9300 . ?
C24 C25 1.409(10) . ?
C25 C26 1.377(11) . ?
C25 H25A 0.9300 . ?
C26 H26A 0.9300 . ?
C27 C28 1.421(12) . ?
C27 C33 1.430(11) . ?
C28 C29 1.395(12) . ?
C28 C35 1.531(12) . ?
C29 C31 1.416(13) . ?
C29 H29A 0.9300 . ?
C30 C31 1.520(13) . ?
C30 H29B 0.9600 . ?
C30 H29C 0.9600 . ?
C30 H29D 0.9600 . ?
C31 C32 1.382(14) . ?
C32 C33 1.382(12) . ?
C32 H31A 0.9300 . ?
C33 C34 1.541(12) . ?
C34 H33A 0.9600 . ?
C34 H33B 0.9600 . ?
C34 H33C 0.9600 . ?
C35 H34A 0.9600 . ?
C35 H34B 0.9600 . ?
C35 H34C 0.9600 . ?
C36 C37 1.414(12) . ?
C36 C41 1.423(11) . ?
C37 C38 1.409(12) . ?
C37 C42 1.523(12) . ?
C38 C39 1.380(12) . ?
C38 H38A 0.9300 . ?
C39 C40 1.389(12) . ?
C39 C44 1.527(12) . ?
C40 C41 1.393(11) . ?
C40 H40A 0.9300 . ?
C41 C43 1.528(11) . ?
C42 H42A 0.9600 . ?
C42 H42B 0.9600 . ?
C42 H42C 0.9600 . ?
C43 H43A 0.9600 . ?
C43 H43B 0.9600 . ?
C43 H43C 0.9600 . ?
C44 H44A 0.9600 . ?
C44 H44B 0.9600 . ?
C44 H44C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Pt1 N1 81.4(3) . . ?
C1 Pt1 O2 92.7(3) . . ?
N1 Pt1 O2 173.9(2) . . ?
C1 Pt1 O1 176.1(2) . . ?
N1 Pt1 O1 95.2(3) . . ?
O2 Pt1 O1 90.7(2) . . ?
C27 B1 C36 122.8(7) . . ?
C27 B1 C24 116.3(7) . . ?
C36 B1 C24 120.9(7) . . ?
C11 N1 C7 118.3(7) . . ?
C11 N1 Pt1 125.2(6) . . ?
C7 N1 Pt1 116.4(6) . . ?
C14 O1 Pt1 125.5(5) . . ?
C12 O2 Pt1 126.4(5) . . ?
C2 C1 C6 118.3(7) . . ?
C2 C1 Pt1 126.4(6) . . ?
C6 C1 Pt1 115.3(5) . . ?
C1 C2 C3 121.3(8) . . ?
C1 C2 H2A 119.3 . . ?
C3 C2 H2A 119.3 . . ?
C4 C3 C2 120.1(8) . . ?
C4 C3 H3A 120.0 . . ?
C2 C3 H3A 120.0 . . ?
C3 C4 C5 119.7(8) . . ?
C3 C4 H4A 120.1 . . ?
C5 C4 H4A 120.1 . . ?
C6 C5 C4 119.5(8) . . ?
C6 C5 H5A 120.3 . . ?
C4 C5 H5A 120.3 . . ?
C5 C6 C1 121.1(8) . . ?
C5 C6 C7 125.6(7) . . ?
C1 C6 C7 113.3(7) . . ?
N1 C7 C8 121.3(8) . . ?
N1 C7 C6 113.4(7) . . ?
C8 C7 C6 125.3(8) . . ?
C9 C8 C7 119.2(8) . . ?
C9 C8 H8A 120.4 . . ?
C7 C8 H8A 120.4 . . ?
C8 C9 C10 119.6(8) . . ?
C8 C9 H9A 120.2 . . ?
C10 C9 H9A 120.2 . . ?
C11 C10 C9 119.5(8) . . ?
C11 C10 H10A 120.2 . . ?
C9 C10 H10A 120.2 . . ?
N1 C11 C10 122.1(8) . . ?
N1 C11 H11A 119.0 . . ?
C10 C11 H11A 119.0 . . ?
O2 C12 C13 126.0(7) . . ?
O2 C12 C21 112.2(7) . . ?
C13 C12 C21 121.7(7) . . ?
C12 C13 C14 125.8(7) . . ?
C12 C13 H13A 117.1 . . ?
C14 C13 H13A 117.1 . . ?
O1 C14 C13 125.4(7) . . ?
O1 C14 C15 114.7(6) . . ?
C13 C14 C15 119.8(6) . . ?
C20 C15 C16 120.5(8) . . ?
C20 C15 C14 116.3(7) . . ?
C16 C15 C14 123.1(7) . . ?
C17 C16 C15 119.8(8) . . ?
C17 C16 H16A 120.1 . . ?
C15 C16 H16A 120.1 . . ?
C18 C17 C16 121.8(8) . . ?
C18 C17 H17A 119.1 . . ?
C16 C17 H17A 119.1 . . ?
C17 C18 C19 118.8(8) . . ?
C17 C18 H18A 120.6 . . ?
C19 C18 H18A 120.6 . . ?
C18 C19 C20 119.4(8) . . ?
C18 C19 H19A 120.3 . . ?
C20 C19 H19A 120.3 . . ?
C15 C20 C19 119.7(8) . . ?
C15 C20 H20A 120.2 . . ?
C19 C20 H20A 120.2 . . ?
C26 C21 C22 118.2(7) . . ?
C26 C21 C12 118.3(7) . . ?
C22 C21 C12 123.5(7) . . ?
C23 C22 C21 119.6(7) . . ?
C23 C22 H22A 120.2 . . ?
C21 C22 H22A 120.2 . . ?
C22 C23 C24 122.7(7) . . ?
C22 C23 H23A 118.7 . . ?
C24 C23 H23A 118.7 . . ?
C23 C24 C25 115.5(7) . . ?
C23 C24 B1 124.4(7) . . ?
C25 C24 B1 120.1(7) . . ?
C26 C25 C24 122.5(7) . . ?
C26 C25 H25A 118.8 . . ?
C24 C25 H25A 118.8 . . ?
C21 C26 C25 121.5(7) . . ?
C21 C26 H26A 119.3 . . ?
C25 C26 H26A 119.3 . . ?
C28 C27 C33 115.5(7) . . ?
C28 C27 B1 122.5(7) . . ?
C33 C27 B1 121.6(8) . . ?
C29 C28 C27 121.6(8) . . ?
C29 C28 C35 116.5(8) . . ?
C27 C28 C35 121.8(7) . . ?
C28 C29 C31 121.4(9) . . ?
C28 C29 H29A 119.3 . . ?
C31 C29 H29A 119.3 . . ?
C31 C30 H29B 109.5 . . ?
C31 C30 H29C 109.5 . . ?
H29B C30 H29C 109.5 . . ?
C31 C30 H29D 109.5 . . ?
H29B C30 H29D 109.5 . . ?
H29C C30 H29D 109.5 . . ?
C32 C31 C29 117.1(8) . . ?
C32 C31 C30 122.2(9) . . ?
C29 C31 C30 120.6(10) . . ?
C31 C32 C33 122.4(9) . . ?
C31 C32 H31A 118.8 . . ?
C33 C32 H31A 118.8 . . ?
C32 C33 C27 121.9(9) . . ?
C32 C33 C34 118.5(8) . . ?
C27 C33 C34 119.5(8) . . ?
C33 C34 H33A 109.5 . . ?
C33 C34 H33B 109.5 . . ?
H33A C34 H33B 109.5 . . ?
C33 C34 H33C 109.5 . . ?
H33A C34 H33C 109.5 . . ?
H33B C34 H33C 109.5 . . ?
C28 C35 H34A 109.5 . . ?
C28 C35 H34B 109.5 . . ?
H34A C35 H34B 109.5 . . ?
C28 C35 H34C 109.5 . . ?
H34A C35 H34C 109.5 . . ?
H34B C35 H34C 109.5 . . ?
C37 C36 C41 117.4(8) . . ?
C37 C36 B1 122.0(7) . . ?
C41 C36 B1 120.5(7) . . ?
C38 C37 C36 120.2(8) . . ?
C38 C37 C42 117.3(8) . . ?
C36 C37 C42 122.3(8) . . ?
C39 C38 C37 121.6(8) . . ?
C39 C38 H38A 119.2 . . ?
C37 C38 H38A 119.2 . . ?
C38 C39 C40 118.6(8) . . ?
C38 C39 C44 120.3(9) . . ?
C40 C39 C44 121.1(9) . . ?
C39 C40 C41 121.6(8) . . ?
C39 C40 H40A 119.2 . . ?
C41 C40 H40A 119.2 . . ?
C40 C41 C36 120.6(8) . . ?
C40 C41 C43 118.2(7) . . ?
C36 C41 C43 121.0(7) . . ?
C37 C42 H42A 109.5 . . ?
C37 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C37 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C41 C43 H43A 109.5 . . ?
C41 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
C41 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C39 C44 H44A 109.5 . . ?
C39 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C39 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Pt1 N1 C11 179.3(7) . . . . ?
O2 Pt1 N1 C11 -164.5(19) . . . . ?
O1 Pt1 N1 C11 -2.5(6) . . . . ?
C1 Pt1 N1 C7 -3.1(5) . . . . ?
O2 Pt1 N1 C7 13(2) . . . . ?
O1 Pt1 N1 C7 175.1(5) . . . . ?
C1 Pt1 O1 C14 -146(3) . . . . ?
N1 Pt1 O1 C14 -174.0(6) . . . . ?
O2 Pt1 O1 C14 4.1(6) . . . . ?
C1 Pt1 O2 C12 174.3(6) . . . . ?
N1 Pt1 O2 C12 158.3(19) . . . . ?
O1 Pt1 O2 C12 -3.8(6) . . . . ?
N1 Pt1 C1 C2 -177.7(7) . . . . ?
O2 Pt1 C1 C2 4.0(7) . . . . ?
O1 Pt1 C1 C2 154(3) . . . . ?
N1 Pt1 C1 C6 2.9(5) . . . . ?
O2 Pt1 C1 C6 -175.4(5) . . . . ?
O1 Pt1 C1 C6 -25(4) . . . . ?
C6 C1 C2 C3 0.4(12) . . . . ?
Pt1 C1 C2 C3 -179.0(6) . . . . ?
C1 C2 C3 C4 -0.1(13) . . . . ?
C2 C3 C4 C5 0.2(14) . . . . ?
C3 C4 C5 C6 -0.5(13) . . . . ?
C4 C5 C6 C1 0.8(12) . . . . ?
C4 C5 C6 C7 -178.1(8) . . . . ?
C2 C1 C6 C5 -0.8(11) . . . . ?
Pt1 C1 C6 C5 178.7(6) . . . . ?
C2 C1 C6 C7 178.3(7) . . . . ?
Pt1 C1 C6 C7 -2.2(8) . . . . ?
C11 N1 C7 C8 0.4(11) . . . . ?
Pt1 N1 C7 C8 -177.4(6) . . . . ?
C11 N1 C7 C6 -179.6(7) . . . . ?
Pt1 N1 C7 C6 2.7(8) . . . . ?
C5 C6 C7 N1 178.8(7) . . . . ?
C1 C6 C7 N1 -0.3(9) . . . . ?
C5 C6 C7 C8 -1.2(13) . . . . ?
C1 C6 C7 C8 179.8(7) . . . . ?
N1 C7 C8 C9 0.5(12) . . . . ?
C6 C7 C8 C9 -179.6(7) . . . . ?
C7 C8 C9 C10 -0.9(12) . . . . ?
C8 C9 C10 C11 0.4(13) . . . . ?
C7 N1 C11 C10 -0.9(12) . . . . ?
Pt1 N1 C11 C10 176.7(6) . . . . ?
C9 C10 C11 N1 0.5(13) . . . . ?
Pt1 O2 C12 C13 1.3(11) . . . . ?
Pt1 O2 C12 C21 -178.8(5) . . . . ?
O2 C12 C13 C14 2.7(12) . . . . ?
C21 C12 C13 C14 -177.2(7) . . . . ?
Pt1 O1 C14 C13 -2.1(10) . . . . ?
Pt1 O1 C14 C15 177.4(4) . . . . ?
C12 C13 C14 O1 -2.2(12) . . . . ?
C12 C13 C14 C15 178.3(7) . . . . ?
O1 C14 C15 C20 -14.4(9) . . . . ?
C13 C14 C15 C20 165.1(7) . . . . ?
O1 C14 C15 C16 162.2(7) . . . . ?
C13 C14 C15 C16 -18.3(11) . . . . ?
C20 C15 C16 C17 -1.2(12) . . . . ?
C14 C15 C16 C17 -177.8(8) . . . . ?
C15 C16 C17 C18 1.0(14) . . . . ?
C16 C17 C18 C19 0.1(15) . . . . ?
C17 C18 C19 C20 -0.9(14) . . . . ?
C16 C15 C20 C19 0.4(12) . . . . ?
C14 C15 C20 C19 177.2(7) . . . . ?
C18 C19 C20 C15 0.7(13) . . . . ?
O2 C12 C21 C26 21.3(10) . . . . ?
C13 C12 C21 C26 -158.8(8) . . . . ?
O2 C12 C21 C22 -157.6(7) . . . . ?
C13 C12 C21 C22 22.3(11) . . . . ?
C26 C21 C22 C23 -0.9(12) . . . . ?
C12 C21 C22 C23 178.0(7) . . . . ?
C21 C22 C23 C24 1.4(12) . . . . ?
C22 C23 C24 C25 -0.9(12) . . . . ?
C22 C23 C24 B1 -179.8(7) . . . . ?
C27 B1 C24 C23 -166.2(8) . . . . ?
C36 B1 C24 C23 15.7(12) . . . . ?
C27 B1 C24 C25 15.0(11) . . . . ?
C36 B1 C24 C25 -163.2(8) . . . . ?
C23 C24 C25 C26 -0.2(13) . . . . ?
B1 C24 C25 C26 178.8(8) . . . . ?
C22 C21 C26 C25 -0.1(13) . . . . ?
C12 C21 C26 C25 -179.1(8) . . . . ?
C24 C25 C26 C21 0.6(15) . . . . ?
C36 B1 C27 C28 -122.8(9) . . . . ?
C24 B1 C27 C28 59.1(10) . . . . ?
C36 B1 C27 C33 64.4(11) . . . . ?
C24 B1 C27 C33 -113.7(8) . . . . ?
C33 C27 C28 C29 2.0(11) . . . . ?
B1 C27 C28 C29 -171.2(8) . . . . ?
C33 C27 C28 C35 -176.7(7) . . . . ?
B1 C27 C28 C35 10.1(12) . . . . ?
C27 C28 C29 C31 -1.1(13) . . . . ?
C35 C28 C29 C31 177.6(8) . . . . ?
C28 C29 C31 C32 -0.9(14) . . . . ?
C28 C29 C31 C30 -179.4(9) . . . . ?
C29 C31 C32 C33 2.2(14) . . . . ?
C30 C31 C32 C33 -179.4(9) . . . . ?
C31 C32 C33 C27 -1.3(14) . . . . ?
C31 C32 C33 C34 175.0(9) . . . . ?
C28 C27 C33 C32 -0.8(12) . . . . ?
B1 C27 C33 C32 172.5(8) . . . . ?
C28 C27 C33 C34 -177.0(8) . . . . ?
B1 C27 C33 C34 -3.8(12) . . . . ?
C27 B1 C36 C37 -117.6(9) . . . . ?
C24 B1 C36 C37 60.5(11) . . . . ?
C27 B1 C36 C41 59.9(11) . . . . ?
C24 B1 C36 C41 -122.1(8) . . . . ?
C41 C36 C37 C38 -2.7(12) . . . . ?
B1 C36 C37 C38 174.8(7) . . . . ?
C41 C36 C37 C42 -177.6(8) . . . . ?
B1 C36 C37 C42 -0.1(12) . . . . ?
C36 C37 C38 C39 3.3(13) . . . . ?
C42 C37 C38 C39 178.4(8) . . . . ?
C37 C38 C39 C40 -1.8(13) . . . . ?
C37 C38 C39 C44 177.5(9) . . . . ?
C38 C39 C40 C41 -0.1(13) . . . . ?
C44 C39 C40 C41 -179.4(8) . . . . ?
C39 C40 C41 C36 0.6(13) . . . . ?
C39 C40 C41 C43 175.2(8) . . . . ?
C37 C36 C41 C40 0.9(12) . . . . ?
B1 C36 C41 C40 -176.7(7) . . . . ?
C37 C36 C41 C43 -173.6(7) . . . . ?
B1 C36 C41 C43 8.8(11) . . . . ?

_diffrn_measured_fraction_theta_max 0.989
_diffrn_reflns_theta_full        26.00
_diffrn_measured_fraction_theta_full 0.989
_refine_diff_density_max         4.326
_refine_diff_density_min         -2.590
_refine_diff_density_rms         0.207
_database_code_depnum_ccdc_archive 'CCDC 932194'
#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_global

# Attachment 'LOUIS103.CIF'


data_louis103
#TrackingRef 'LOUIS103.CIF'


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C29 H28.50 B0.50 N O Pt0.50'
_chemical_formula_weight         509.98

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   51.501(4)
_cell_length_b                   8.4801(6)
_cell_length_c                   25.3881(18)
_cell_angle_alpha                90.00
_cell_angle_beta                 118.5670(10)
_cell_angle_gamma                90.00
_cell_volume                     9738.1(12)
_cell_formula_units_Z            16
_cell_measurement_temperature    180(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_size_max          0.03
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.01
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.391
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             4144
_exptl_absorpt_coefficient_mu    2.926
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.9174
_exptl_absorpt_correction_T_max  0.9713
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      180(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            44074
_diffrn_reflns_av_R_equivalents  0.0782
_diffrn_reflns_av_sigmaI/netI    0.0649
_diffrn_reflns_limit_h_min       -63
_diffrn_reflns_limit_h_max       63
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_theta_min         1.60
_diffrn_reflns_theta_max         26.00
_reflns_number_total             9570
_reflns_number_gt                6748
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0279P)^2^+17.3000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         9570
_refine_ls_number_parameters     585
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0710
_refine_ls_R_factor_gt           0.0392
_refine_ls_wR_factor_ref         0.0847
_refine_ls_wR_factor_gt          0.0733
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_restrained_S_all      1.022
_refine_ls_shift/su_max          0.009
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.198044(4) 0.26332(2) 0.022072(9) 0.02780(7) Uani 1 1 d . . .
B1 B 0.07520(13) -0.3336(7) 0.0628(3) 0.0308(14) Uani 1 1 d . . .
O1 O 0.22968(6) 0.2152(3) 0.10914(13) 0.0224(7) Uani 1 1 d . . .
O2 O 0.16783(7) 0.1361(4) 0.03208(15) 0.0311(8) Uani 1 1 d . . .
N1 N 0.22594(9) 0.3907(4) 0.00617(18) 0.0291(10) Uani 1 1 d . . .
N2 N 0.27999(11) 0.6763(5) -0.0343(2) 0.0433(12) Uani 1 1 d . . .
C1 C 0.17135(12) 0.3145(6) -0.0624(2) 0.0331(13) Uani 1 1 d . . .
C2 C 0.14221(12) 0.2653(6) -0.0986(2) 0.0424(13) Uani 1 1 d . . .
H2A H 0.1330 0.2000 -0.0819 0.051 Uiso 1 1 calc R . .
C3 C 0.12653(13) 0.3094(7) -0.1580(3) 0.0477(16) Uani 1 1 d . . .
H3A H 0.1068 0.2730 -0.1816 0.057 Uiso 1 1 calc R . .
C4 C 0.13897(13) 0.4058(7) -0.1839(3) 0.0491(16) Uani 1 1 d . . .
H4A H 0.1278 0.4371 -0.2246 0.059 Uiso 1 1 calc R . .
C5 C 0.16763(13) 0.4557(6) -0.1500(2) 0.0421(14) Uani 1 1 d . . .
H5A H 0.1764 0.5212 -0.1675 0.051 Uiso 1 1 calc R . .
C6 C 0.18402(11) 0.4104(5) -0.0898(2) 0.0310(12) Uani 1 1 d . . .
C7 C 0.21470(11) 0.4555(5) -0.0503(2) 0.0309(12) Uani 1 1 d . . .
C8 C 0.23251(12) 0.5502(6) -0.0650(2) 0.0345(13) Uani 1 1 d . . .
H8A H 0.2246 0.5936 -0.1042 0.041 Uiso 1 1 calc R . .
C9 C 0.26232(12) 0.5824(6) -0.0221(2) 0.0346(13) Uani 1 1 d . . .
C10 C 0.27267(12) 0.5105(5) 0.0344(2) 0.0313(12) Uani 1 1 d . . .
H10A H 0.2926 0.5255 0.0645 0.038 Uiso 1 1 calc R . .
C11 C 0.25423(12) 0.4195(6) 0.0460(2) 0.0324(12) Uani 1 1 d . . .
H11A H 0.2619 0.3737 0.0847 0.039 Uiso 1 1 calc R . .
C12 C 0.31070(12) 0.7036(6) 0.0112(3) 0.0495(16) Uani 1 1 d . . .
H12A H 0.3112 0.7493 0.0471 0.074 Uiso 1 1 calc R . .
H12B H 0.3200 0.7765 -0.0047 0.074 Uiso 1 1 calc R . .
H12C H 0.3215 0.6033 0.0216 0.074 Uiso 1 1 calc R . .
C13 C 0.26954(14) 0.7552(6) -0.0917(3) 0.0511(15) Uani 1 1 d . . .
H13A H 0.2506 0.8065 -0.1028 0.077 Uiso 1 1 calc R . .
H13B H 0.2670 0.6776 -0.1225 0.077 Uiso 1 1 calc R . .
H13C H 0.2840 0.8347 -0.0886 0.077 Uiso 1 1 calc R . .
C14 C 0.17296(11) 0.0621(6) 0.0802(2) 0.0313(12) Uani 1 1 d . . .
C15 C 0.19946(11) 0.0551(6) 0.1337(2) 0.0305(12) Uani 1 1 d . . .
H15A H 0.1993 -0.0041 0.1653 0.037 Uiso 1 1 calc R . .
C16 C 0.22660(11) 0.1262(5) 0.1461(2) 0.0275(12) Uani 1 1 d . . .
C17 C 0.25376(11) 0.1003(5) 0.2053(2) 0.0290(12) Uani 1 1 d . . .
C18 C 0.28049(12) 0.1618(6) 0.2130(2) 0.0383(13) Uani 1 1 d . . .
H18A H 0.2812 0.2137 0.1806 0.046 Uiso 1 1 calc R . .
C19 C 0.30596(12) 0.1476(6) 0.2677(2) 0.0406(14) Uani 1 1 d . . .
H19A H 0.3240 0.1904 0.2725 0.049 Uiso 1 1 calc R . .
C20 C 0.30539(13) 0.0720(6) 0.3151(2) 0.0407(14) Uani 1 1 d . . .
H20A H 0.3228 0.0641 0.3528 0.049 Uiso 1 1 calc R . .
C21 C 0.27904(12) 0.0078(6) 0.3070(2) 0.0379(14) Uani 1 1 d . . .
H21A H 0.2784 -0.0470 0.3390 0.046 Uiso 1 1 calc R . .
C22 C 0.25391(12) 0.0230(6) 0.2531(2) 0.0361(13) Uani 1 1 d . . .
H22A H 0.2360 -0.0211 0.2485 0.043 Uiso 1 1 calc R . .
C23 C 0.14723(11) -0.0309(5) 0.0756(2) 0.0281(12) Uani 1 1 d . . .
C24 C 0.14328(11) -0.0573(6) 0.1256(2) 0.0350(13) Uani 1 1 d . . .
H24A H 0.1569 -0.0138 0.1633 0.042 Uiso 1 1 calc R . .
C25 C 0.11970(11) -0.1464(6) 0.1204(2) 0.0340(13) Uani 1 1 d . . .
H25A H 0.1168 -0.1581 0.1544 0.041 Uiso 1 1 calc R . .
C26 C 0.09999(10) -0.2200(5) 0.0664(2) 0.0278(11) Uani 1 1 d . . .
C27 C 0.10453(11) -0.1923(6) 0.0170(2) 0.0335(13) Uani 1 1 d . . .
H27A H 0.0917 -0.2404 -0.0203 0.040 Uiso 1 1 calc R . .
C28 C 0.12721(11) -0.0967(6) 0.0210(2) 0.0317(12) Uani 1 1 d . . .
H28A H 0.1291 -0.0760 -0.0138 0.038 Uiso 1 1 calc R . .
C29 C 0.06593(11) -0.4772(6) 0.0179(2) 0.0318(12) Uani 1 1 d . . .
C30 C 0.03615(11) -0.4983(6) -0.0268(2) 0.0341(13) Uani 1 1 d . . .
C31 C 0.02799(12) -0.6318(6) -0.0633(2) 0.0376(14) Uani 1 1 d . . .
H31A H 0.0079 -0.6438 -0.0932 0.045 Uiso 1 1 calc R . .
C32 C 0.04823(12) -0.7475(6) -0.0573(2) 0.0431(13) Uani 1 1 d . . .
C33 C 0.07752(12) -0.7254(6) -0.0142(3) 0.0415(14) Uani 1 1 d . . .
H33A H 0.0917 -0.8032 -0.0096 0.050 Uiso 1 1 calc R . .
C34 C 0.08653(12) -0.5937(6) 0.0220(2) 0.0390(14) Uani 1 1 d . . .
C35 C 0.01336(11) -0.3716(6) -0.0376(3) 0.0467(16) Uani 1 1 d . . .
H35A H -0.0065 -0.4151 -0.0618 0.070 Uiso 1 1 calc R . .
H35B H 0.0163 -0.2829 -0.0589 0.070 Uiso 1 1 calc R . .
H35C H 0.0156 -0.3351 0.0009 0.070 Uiso 1 1 calc R . .
C36 C 0.11927(12) -0.5820(7) 0.0677(3) 0.0587(19) Uani 1 1 d . . .
H36A H 0.1269 -0.6871 0.0838 0.088 Uiso 1 1 calc R . .
H36B H 0.1218 -0.5120 0.1005 0.088 Uiso 1 1 calc R . .
H36C H 0.1302 -0.5394 0.0482 0.088 Uiso 1 1 calc R . .
C37 C 0.03872(14) -0.8937(7) -0.0962(3) 0.064(2) Uani 1 1 d . . .
H37A H 0.0216 -0.8688 -0.1350 0.096 Uiso 1 1 calc R . .
H37B H 0.0334 -0.9766 -0.0763 0.096 Uiso 1 1 calc R . .
H37C H 0.0550 -0.9305 -0.1026 0.096 Uiso 1 1 calc R . .
C38 C 0.06264(11) -0.3049(6) 0.1071(2) 0.0342(13) Uani 1 1 d . . .
C39 C 0.06349(11) -0.4254(6) 0.1470(3) 0.0386(14) Uani 1 1 d . . .
C40 C 0.05546(12) -0.3938(7) 0.1912(3) 0.0446(15) Uani 1 1 d . . .
H40A H 0.0569 -0.4759 0.2179 0.054 Uiso 1 1 calc R . .
C41 C 0.04563(12) -0.2484(8) 0.1974(3) 0.0480(15) Uani 1 1 d . . .
C42 C 0.04431(12) -0.1299(7) 0.1583(3) 0.0481(16) Uani 1 1 d . . .
H42A H 0.0376 -0.0281 0.1620 0.058 Uiso 1 1 calc R . .
C43 C 0.05237(12) -0.1546(6) 0.1139(3) 0.0390(14) Uani 1 1 d . . .
C44 C 0.07299(13) -0.5925(6) 0.1427(3) 0.0531(17) Uani 1 1 d . . .
H44A H 0.0713 -0.6591 0.1726 0.080 Uiso 1 1 calc R . .
H44B H 0.0935 -0.5918 0.1505 0.080 Uiso 1 1 calc R . .
H44C H 0.0602 -0.6344 0.1025 0.080 Uiso 1 1 calc R . .
C45 C 0.03660(15) -0.2193(8) 0.2451(3) 0.074(2) Uani 1 1 d . . .
H45A H 0.0278 -0.3154 0.2512 0.110 Uiso 1 1 calc R . .
H45B H 0.0221 -0.1336 0.2323 0.110 Uiso 1 1 calc R . .
H45C H 0.0540 -0.1900 0.2827 0.110 Uiso 1 1 calc R . .
C46 C 0.04879(13) -0.0193(6) 0.0715(3) 0.0537(17) Uani 1 1 d . . .
H46A H 0.0330 0.0509 0.0682 0.080 Uiso 1 1 calc R . .
H46B H 0.0437 -0.0617 0.0319 0.080 Uiso 1 1 calc R . .
H46C H 0.0674 0.0398 0.0873 0.080 Uiso 1 1 calc R . .
C47 C 0.18781(15) 0.1991(7) 0.2668(3) 0.0479(16) Uani 1 1 d . . .
H47A H 0.2027 0.2569 0.2633 0.058 Uiso 1 1 calc R . .
C48 C 0.15922(15) 0.2515(7) 0.2391(3) 0.0531(16) Uani 1 1 d . . .
H48A H 0.1542 0.3461 0.2163 0.064 Uiso 1 1 calc R . .
C49 C 0.13792(15) 0.1673(8) 0.2444(3) 0.0624(19) Uani 1 1 d . . .
H49A H 0.1181 0.2043 0.2254 0.075 Uiso 1 1 calc R . .
C50 C 0.14497(14) 0.0295(7) 0.2771(3) 0.0537(17) Uani 1 1 d . . .
H50A H 0.1300 -0.0289 0.2801 0.064 Uiso 1 1 calc R . .
C51 C 0.17337(13) -0.0233(7) 0.3050(3) 0.0460(15) Uani 1 1 d . . .
H51A H 0.1784 -0.1177 0.3279 0.055 Uiso 1 1 calc R . .
C52 C 0.19480(14) 0.0621(7) 0.2997(3) 0.0503(16) Uani 1 1 d . . .
H52A H 0.2147 0.0257 0.3191 0.060 Uiso 1 1 calc R . .
C53 C 0.0482(3) 0.7776(11) 0.7900(5) 0.125(4) Uani 1 1 d . . .
H53A H 0.0311 0.8270 0.7594 0.150 Uiso 1 1 calc R . .
C54 C 0.0459(3) 0.6577(13) 0.8251(6) 0.121(4) Uani 1 1 d . . .
H54A H 0.0268 0.6264 0.8186 0.145 Uiso 1 1 calc R . .
C55 C 0.0702(3) 0.5851(12) 0.8684(5) 0.118(5) Uani 1 1 d . . .
H55A H 0.0685 0.5034 0.8922 0.141 Uiso 1 1 calc R . .
C56 C 0.0974(3) 0.6333(11) 0.8768(4) 0.110(4) Uani 1 1 d . . .
H56A H 0.1148 0.5830 0.9063 0.132 Uiso 1 1 calc R . .
C57 C 0.0997(3) 0.7523(11) 0.8433(5) 0.114(3) Uani 1 1 d . . .
H57A H 0.1187 0.7865 0.8505 0.136 Uiso 1 1 calc R . .
C58 C 0.0754(3) 0.8217(11) 0.8003(5) 0.125(4) Uani 1 1 d . . .
H58A H 0.0773 0.9031 0.7767 0.150 Uiso 1 1 calc R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Pt1 0.02833(11) 0.02670(11) 0.02932(11) -0.00195(10) 0.01454(8) -0.00177(10)
B1 0.020(3) 0.029(3) 0.033(4) 0.000(3) 0.004(3) -0.001(2)
O1 0.0233(18) 0.0204(16) 0.0275(18) -0.0015(14) 0.0155(15) -0.0057(13)
O2 0.028(2) 0.033(2) 0.033(2) 0.0002(16) 0.0155(18) -0.0003(16)
N1 0.033(3) 0.028(2) 0.026(2) -0.0010(18) 0.014(2) 0.0005(19)
N2 0.046(3) 0.036(3) 0.059(3) 0.006(2) 0.034(3) -0.001(2)
C1 0.034(3) 0.026(3) 0.040(3) -0.006(2) 0.019(3) 0.002(2)
C2 0.041(3) 0.043(3) 0.044(3) 0.001(3) 0.021(3) -0.003(3)
C3 0.033(3) 0.055(4) 0.040(4) 0.004(3) 0.005(3) 0.005(3)
C4 0.046(4) 0.055(4) 0.037(4) 0.011(3) 0.012(3) 0.008(3)
C5 0.048(4) 0.043(3) 0.038(4) 0.008(3) 0.023(3) 0.008(3)
C6 0.033(3) 0.026(3) 0.034(3) -0.002(2) 0.016(3) 0.003(2)
C7 0.035(3) 0.021(3) 0.038(3) 0.001(2) 0.018(3) 0.004(2)
C8 0.050(4) 0.027(3) 0.037(3) 0.004(2) 0.029(3) 0.006(3)
C9 0.047(4) 0.026(3) 0.046(4) -0.002(2) 0.034(3) 0.001(2)
C10 0.029(3) 0.026(3) 0.044(4) -0.004(2) 0.022(3) -0.002(2)
C11 0.040(3) 0.029(3) 0.031(3) -0.005(2) 0.019(3) 0.001(2)
C12 0.044(4) 0.046(4) 0.070(4) -0.005(3) 0.037(4) -0.012(3)
C13 0.072(4) 0.039(3) 0.062(4) 0.001(3) 0.048(4) -0.002(3)
C14 0.032(3) 0.027(3) 0.036(3) -0.010(2) 0.017(3) -0.001(2)
C15 0.029(3) 0.031(3) 0.033(3) 0.000(2) 0.016(3) -0.004(2)
C16 0.030(3) 0.022(3) 0.034(3) -0.008(2) 0.018(3) -0.003(2)
C17 0.029(3) 0.025(3) 0.032(3) -0.007(2) 0.014(3) -0.003(2)
C18 0.035(3) 0.047(3) 0.031(3) -0.001(3) 0.015(3) -0.005(3)
C19 0.025(3) 0.052(4) 0.040(4) -0.006(3) 0.012(3) -0.009(3)
C20 0.043(4) 0.039(3) 0.031(3) 0.003(3) 0.011(3) 0.011(3)
C21 0.038(3) 0.041(3) 0.034(3) 0.004(3) 0.016(3) 0.000(3)
C22 0.035(4) 0.040(3) 0.039(3) 0.001(3) 0.022(3) -0.006(3)
C23 0.023(3) 0.024(3) 0.038(3) -0.004(2) 0.015(3) -0.001(2)
C24 0.031(3) 0.037(3) 0.034(3) -0.006(2) 0.012(3) -0.005(2)
C25 0.030(3) 0.040(3) 0.032(3) -0.003(2) 0.015(3) -0.007(2)
C26 0.022(3) 0.027(3) 0.034(3) -0.007(2) 0.013(2) -0.002(2)
C27 0.023(3) 0.038(3) 0.035(3) -0.012(2) 0.010(3) -0.006(2)
C28 0.029(3) 0.036(3) 0.032(3) -0.005(2) 0.016(3) -0.004(2)
C29 0.028(3) 0.031(3) 0.038(3) 0.002(2) 0.017(3) -0.001(2)
C30 0.026(3) 0.038(3) 0.037(3) 0.002(2) 0.014(3) -0.005(2)
C31 0.026(3) 0.039(3) 0.040(3) -0.002(3) 0.010(3) -0.008(2)
C32 0.046(3) 0.034(3) 0.044(3) -0.003(3) 0.017(3) -0.006(3)
C33 0.041(3) 0.029(3) 0.056(4) -0.004(3) 0.024(3) 0.003(3)
C34 0.031(3) 0.041(3) 0.042(4) -0.004(3) 0.016(3) -0.003(3)
C35 0.029(3) 0.043(3) 0.049(4) -0.003(3) 0.003(3) 0.000(3)
C36 0.034(4) 0.058(4) 0.066(5) -0.011(3) 0.009(3) 0.008(3)
C37 0.069(5) 0.044(4) 0.069(5) -0.015(3) 0.024(4) -0.005(3)
C38 0.024(3) 0.039(3) 0.037(3) -0.004(2) 0.013(3) -0.011(2)
C39 0.021(3) 0.045(3) 0.042(4) 0.001(3) 0.009(3) -0.004(2)
C40 0.030(3) 0.061(4) 0.037(4) 0.010(3) 0.012(3) -0.001(3)
C41 0.029(3) 0.071(4) 0.043(3) -0.013(4) 0.016(3) -0.011(3)
C42 0.032(4) 0.053(4) 0.059(4) -0.018(3) 0.022(3) -0.011(3)
C43 0.034(3) 0.041(3) 0.047(4) -0.013(3) 0.023(3) -0.012(3)
C44 0.050(4) 0.047(4) 0.066(5) 0.022(3) 0.031(4) 0.010(3)
C45 0.070(5) 0.101(6) 0.069(5) -0.011(4) 0.048(4) -0.008(4)
C46 0.058(4) 0.035(3) 0.076(5) 0.002(3) 0.039(4) 0.003(3)
C47 0.061(4) 0.040(3) 0.042(4) -0.006(3) 0.024(4) -0.005(3)
C48 0.077(5) 0.037(3) 0.043(4) 0.004(3) 0.028(4) 0.009(4)
C49 0.052(5) 0.066(5) 0.066(5) 0.014(4) 0.026(4) 0.029(4)
C50 0.050(4) 0.054(4) 0.064(5) 0.002(3) 0.032(4) 0.002(3)
C51 0.052(4) 0.044(3) 0.038(4) 0.006(3) 0.019(3) 0.008(3)
C52 0.042(4) 0.052(4) 0.042(4) -0.001(3) 0.007(3) 0.001(3)
C53 0.140(10) 0.077(7) 0.186(12) 0.033(7) 0.100(10) 0.017(7)
C54 0.171(13) 0.088(8) 0.158(12) -0.026(7) 0.123(11) -0.028(8)
C55 0.240(17) 0.067(7) 0.090(8) -0.016(5) 0.113(11) -0.026(8)
C56 0.211(13) 0.073(7) 0.070(6) 0.012(5) 0.086(8) 0.050(7)
C57 0.152(10) 0.106(8) 0.126(9) 0.034(7) 0.102(8) 0.048(7)
C58 0.145(11) 0.095(7) 0.177(12) 0.055(8) 0.111(10) 0.024(7)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C1 1.964(5) . ?
Pt1 N1 1.987(4) . ?
Pt1 O2 2.007(3) . ?
Pt1 O1 2.065(3) . ?
B1 C38 1.562(8) . ?
B1 C26 1.566(7) . ?
B1 C29 1.577(7) . ?
O1 C16 1.273(5) . ?
O2 C14 1.284(6) . ?
N1 C11 1.340(6) . ?
N1 C7 1.378(6) . ?
N2 C9 1.353(6) . ?
N2 C13 1.453(7) . ?
N2 C12 1.464(7) . ?
C1 C2 1.397(7) . ?
C1 C6 1.415(7) . ?
C2 C3 1.380(7) . ?
C3 C4 1.382(8) . ?
C4 C5 1.372(7) . ?
C5 C6 1.402(7) . ?
C6 C7 1.460(7) . ?
C7 C8 1.398(7) . ?
C8 C9 1.421(7) . ?
C9 C10 1.407(7) . ?
C10 C11 1.361(7) . ?
C14 C15 1.392(7) . ?
C14 C23 1.497(6) . ?
C15 C16 1.412(6) . ?
C16 C17 1.500(7) . ?
C17 C22 1.377(7) . ?
C17 C18 1.395(7) . ?
C18 C19 1.386(7) . ?
C19 C20 1.377(7) . ?
C20 C21 1.383(7) . ?
C21 C22 1.367(7) . ?
C23 C28 1.389(6) . ?
C23 C24 1.396(7) . ?
C24 C25 1.382(6) . ?
C25 C26 1.402(6) . ?
C26 C27 1.403(7) . ?
C27 C28 1.385(6) . ?
C29 C34 1.417(7) . ?
C29 C30 1.418(7) . ?
C30 C31 1.394(7) . ?
C30 C35 1.516(7) . ?
C31 C32 1.386(7) . ?
C32 C33 1.389(7) . ?
C32 C37 1.514(7) . ?
C33 C34 1.379(7) . ?
C34 C36 1.526(7) . ?
C38 C43 1.422(7) . ?
C38 C39 1.425(7) . ?
C39 C40 1.394(7) . ?
C39 C44 1.520(7) . ?
C40 C41 1.371(8) . ?
C41 C42 1.393(8) . ?
C41 C45 1.509(8) . ?
C42 C43 1.389(7) . ?
C43 C46 1.523(7) . ?
C47 C48 1.367(8) . ?
C47 C52 1.375(7) . ?
C48 C49 1.368(8) . ?
C49 C50 1.378(8) . ?
C50 C51 1.360(7) . ?
C51 C52 1.379(8) . ?
C53 C58 1.346(12) . ?
C53 C54 1.396(13) . ?
C54 C55 1.358(13) . ?
C55 C56 1.374(13) . ?
C56 C57 1.360(11) . ?
C57 C58 1.342(12) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Pt1 N1 81.63(19) . . ?
C1 Pt1 O2 94.41(18) . . ?
N1 Pt1 O2 176.03(15) . . ?
C1 Pt1 O1 174.04(17) . . ?
N1 Pt1 O1 92.73(14) . . ?
O2 Pt1 O1 91.21(12) . . ?
C38 B1 C26 117.9(4) . . ?
C38 B1 C29 123.6(5) . . ?
C26 B1 C29 118.3(5) . . ?
C16 O1 Pt1 126.4(3) . . ?
C14 O2 Pt1 124.4(3) . . ?
C11 N1 C7 118.5(4) . . ?
C11 N1 Pt1 125.2(3) . . ?
C7 N1 Pt1 116.3(3) . . ?
C9 N2 C13 122.3(5) . . ?
C9 N2 C12 120.2(5) . . ?
C13 N2 C12 117.4(4) . . ?
C2 C1 C6 116.8(5) . . ?
C2 C1 Pt1 128.5(4) . . ?
C6 C1 Pt1 114.6(4) . . ?
C3 C2 C1 121.4(5) . . ?
C2 C3 C4 121.2(6) . . ?
C5 C4 C3 119.3(6) . . ?
C4 C5 C6 120.3(5) . . ?
C5 C6 C1 121.0(5) . . ?
C5 C6 C7 124.5(5) . . ?
C1 C6 C7 114.5(5) . . ?
N1 C7 C8 120.3(5) . . ?
N1 C7 C6 112.8(4) . . ?
C8 C7 C6 126.9(5) . . ?
C7 C8 C9 120.7(5) . . ?
N2 C9 C10 121.4(5) . . ?
N2 C9 C8 122.3(5) . . ?
C10 C9 C8 116.3(5) . . ?
C11 C10 C9 120.2(5) . . ?
N1 C11 C10 124.0(5) . . ?
O2 C14 C15 127.5(5) . . ?
O2 C14 C23 114.3(4) . . ?
C15 C14 C23 118.2(5) . . ?
C14 C15 C16 127.2(5) . . ?
O1 C16 C15 123.2(5) . . ?
O1 C16 C17 116.1(4) . . ?
C15 C16 C17 120.7(4) . . ?
C22 C17 C18 117.7(5) . . ?
C22 C17 C16 124.2(5) . . ?
C18 C17 C16 118.1(5) . . ?
C19 C18 C17 120.4(5) . . ?
C20 C19 C18 120.7(5) . . ?
C19 C20 C21 118.9(5) . . ?
C22 C21 C20 120.3(5) . . ?
C21 C22 C17 122.1(5) . . ?
C28 C23 C24 118.8(5) . . ?
C28 C23 C14 119.7(5) . . ?
C24 C23 C14 121.4(5) . . ?
C25 C24 C23 120.3(5) . . ?
C24 C25 C26 122.0(5) . . ?
C25 C26 C27 116.5(4) . . ?
C25 C26 B1 121.4(5) . . ?
C27 C26 B1 122.0(4) . . ?
C28 C27 C26 121.9(5) . . ?
C27 C28 C23 120.4(5) . . ?
C34 C29 C30 117.1(5) . . ?
C34 C29 B1 121.9(5) . . ?
C30 C29 B1 120.9(5) . . ?
C31 C30 C29 120.1(5) . . ?
C31 C30 C35 119.6(5) . . ?
C29 C30 C35 120.2(5) . . ?
C32 C31 C30 122.0(5) . . ?
C31 C32 C33 117.9(5) . . ?
C31 C32 C37 121.1(5) . . ?
C33 C32 C37 121.0(5) . . ?
C34 C33 C32 121.8(5) . . ?
C33 C34 C29 121.0(5) . . ?
C33 C34 C36 117.2(5) . . ?
C29 C34 C36 121.8(5) . . ?
C43 C38 C39 116.3(5) . . ?
C43 C38 B1 122.3(5) . . ?
C39 C38 B1 121.2(5) . . ?
C40 C39 C38 120.9(5) . . ?
C40 C39 C44 117.7(5) . . ?
C38 C39 C44 121.3(5) . . ?
C41 C40 C39 122.3(6) . . ?
C40 C41 C42 117.4(5) . . ?
C40 C41 C45 120.9(6) . . ?
C42 C41 C45 121.7(6) . . ?
C43 C42 C41 122.6(6) . . ?
C42 C43 C38 120.5(5) . . ?
C42 C43 C46 118.5(5) . . ?
C38 C43 C46 121.0(5) . . ?
C48 C47 C52 119.5(6) . . ?
C47 C48 C49 119.8(6) . . ?
C48 C49 C50 120.6(6) . . ?
C51 C50 C49 120.1(6) . . ?
C50 C51 C52 119.2(6) . . ?
C47 C52 C51 120.9(6) . . ?
C58 C53 C54 118.6(11) . . ?
C55 C54 C53 121.2(12) . . ?
C54 C55 C56 118.0(11) . . ?
C57 C56 C55 120.7(11) . . ?
C58 C57 C56 120.6(11) . . ?
C57 C58 C53 121.0(10) . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        26.00
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         0.751
_refine_diff_density_min         -1.451
_refine_diff_density_rms         0.111


_database_code_depnum_ccdc_archive 'CCDC 932195'