# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry 2014


data_p21c

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C18 H20 Cl N2 Rh'
_chemical_formula_weight         402.72

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           MONOCLINIC
_symmetry_space_group_name_H-M   P2(1)/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   10.5190(6)
_cell_length_b                   10.7555(6)
_cell_length_c                   14.8470(9)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.5320(10)
_cell_angle_gamma                90.00
_cell_volume                     1679.67(17)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    4074
_cell_measurement_theta_min      2.708
_cell_measurement_theta_max      23.358

_exptl_crystal_description       PRISMATIC
_exptl_crystal_colour            'PALE YELLOW'
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.593
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             816
_exptl_absorpt_coefficient_mu    1.173
_exptl_absorpt_correction_type   'EMPIRICAL SADABS'
_exptl_absorpt_correction_T_min  0.7992
_exptl_absorpt_correction_T_max  0.8917
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD AREA DETECTOR'
_diffrn_measurement_method       'OMEGA SCANS'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            15678
_diffrn_reflns_av_R_equivalents  0.0362
_diffrn_reflns_av_sigmaI/netI    0.0264
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         1.94
_diffrn_reflns_theta_max         24.99
_reflns_number_total             2959
_reflns_number_gt                2392
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0430P)²+1.2363P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    CONSTR
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         2959
_refine_ls_number_parameters     200
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0445
_refine_ls_R_factor_gt           0.0319
_refine_ls_wR_factor_ref         0.0883
_refine_ls_wR_factor_gt          0.0803
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_restrained_S_all      1.051
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.18162(3) 0.79711(3) 0.07890(2) 0.04603(13) Uani 1 1 d . . .
Cl2 Cl 0.07577(11) 0.69760(10) 0.20018(7) 0.0654(3) Uani 1 1 d . . .
C1 C 0.1958(3) 0.6333(3) 0.0133(2) 0.0400(8) Uani 1 1 d . . .
N2 N 0.2829(3) 0.5435(3) 0.03044(19) 0.0429(7) Uani 1 1 d . . .
C3 C 0.2657(4) 0.4427(4) -0.0267(3) 0.0520(10) Uani 1 1 d . . .
H3 H 0.3130 0.3697 -0.0271 0.062 Uiso 1 1 calc R . .
C4 C 0.1684(4) 0.4709(4) -0.0805(3) 0.0527(10) Uani 1 1 d . . .
H4 H 0.1352 0.4215 -0.1264 0.063 Uiso 1 1 calc R . .
N5 N 0.1258(3) 0.5868(3) -0.0558(2) 0.0454(7) Uani 1 1 d . . .
C6 C 0.0161(4) 0.6487(4) -0.0958(3) 0.0617(11) Uani 1 1 d . . .
H6A H -0.0090 0.7168 -0.0582 0.093 Uiso 1 1 calc R . .
H6B H -0.0529 0.5907 -0.1012 0.093 Uiso 1 1 calc R . .
H6C H 0.0377 0.6793 -0.1544 0.093 Uiso 1 1 calc R . .
C7 C 0.3826(4) 0.5535(4) 0.0995(3) 0.0536(10) Uani 1 1 d . . .
H7A H 0.3665 0.6263 0.1362 0.064 Uiso 1 1 calc R . .
H7B H 0.4638 0.5651 0.0703 0.064 Uiso 1 1 calc R . .
C8 C 0.3903(4) 0.4410(4) 0.1595(3) 0.0497(9) Uani 1 1 d . . .
C9 C 0.2896(4) 0.4117(5) 0.2157(3) 0.0645(12) Uani 1 1 d . . .
H9 H 0.2188 0.4635 0.2177 0.077 Uiso 1 1 calc R . .
C10 C 0.2942(5) 0.3057(5) 0.2687(3) 0.0747(14) Uani 1 1 d . . .
H10 H 0.2264 0.2859 0.3058 0.090 Uiso 1 1 calc R . .
C11 C 0.4004(5) 0.2292(5) 0.2663(3) 0.0764(15) Uani 1 1 d . . .
H11 H 0.4027 0.1570 0.3008 0.092 Uiso 1 1 calc R . .
C12 C 0.5011(5) 0.2590(5) 0.2138(3) 0.0679(12) Uani 1 1 d . . .
H12 H 0.5733 0.2091 0.2140 0.081 Uiso 1 1 calc R . .
C13 C 0.4960(4) 0.3647(4) 0.1596(3) 0.0566(10) Uani 1 1 d . . .
H13 H 0.5645 0.3841 0.1230 0.068 Uiso 1 1 calc R . .
C14 C 0.2493(4) 0.9621(4) 0.1518(3) 0.0596(11) Uani 1 1 d . . .
H14 H 0.2614 0.9646 0.2173 0.071 Uiso 1 1 calc R . .
C15 C 0.1369(4) 0.9937(4) 0.1092(3) 0.0643(12) Uani 1 1 d . . .
H15 H 0.0605 1.0203 0.1411 0.077 Uiso 1 1 calc R . .
C16 C 0.3315(4) 0.8863(4) 0.0149(3) 0.0568(11) Uani 1 1 d . . .
H16 H 0.4001 0.8413 -0.0152 0.068 Uiso 1 1 calc R . .
C17 C 0.3558(4) 0.9885(4) 0.0849(3) 0.0622(11) Uani 1 1 d . . .
H17 H 0.4423 0.9955 0.1094 0.075 Uiso 1 1 calc R . .
C18 C 0.1724(5) 1.0396(4) 0.0156(3) 0.0685(13) Uani 1 1 d . . .
H18 H 0.1085 1.0885 -0.0172 0.082 Uiso 1 1 calc R . .
C19 C 0.3013(4) 1.1032(4) 0.0354(3) 0.0721(13) Uani 1 1 d . . .
H19A H 0.3477 1.1240 -0.0187 0.086 Uiso 1 1 calc R . .
H19B H 0.2938 1.1755 0.0740 0.086 Uiso 1 1 calc R . .
C20 C 0.2170(4) 0.9184(4) -0.0286(3) 0.0588(11) Uani 1 1 d . . .
H20 H 0.1983 0.8972 -0.0915 0.071 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C1 2.019(4) . ?
Rh1 C16 2.083(4) . ?
Rh1 C20 2.098(4) . ?
Rh1 C14 2.194(4) . ?
Rh1 C15 2.213(4) . ?
Rh1 Cl2 2.3800(11) . ?
C1 N2 1.353(4) . ?
C1 N5 1.354(4) . ?
N2 C3 1.387(5) . ?
N2 C7 1.463(4) . ?
C3 C4 1.328(6) . ?
C3 H3 0.9300 . ?
C4 N5 1.375(5) . ?
C4 H4 0.9300 . ?
N5 C6 1.454(5) . ?
C6 H6A 0.9600 . ?
C6 H6B 0.9600 . ?
C6 H6C 0.9600 . ?
C7 C8 1.505(5) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C8 C13 1.381(6) . ?
C8 C9 1.391(6) . ?
C9 C10 1.386(6) . ?
C9 H9 0.9300 . ?
C10 C11 1.388(7) . ?
C10 H10 0.9300 . ?
C11 C12 1.359(7) . ?
C11 H11 0.9300 . ?
C12 C13 1.393(6) . ?
C12 H12 0.9300 . ?
C13 H13 0.9300 . ?
C14 C15 1.378(6) . ?
C14 C17 1.531(6) . ?
C14 H14 0.9800 . ?
C15 C18 1.525(7) . ?
C15 H15 0.9800 . ?
C16 C20 1.404(6) . ?
C16 C17 1.533(6) . ?
C16 H16 0.9800 . ?
C17 C19 1.543(6) . ?
C17 H17 0.9800 . ?
C18 C20 1.535(6) . ?
C18 C19 1.545(6) . ?
C18 H18 0.9800 . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C20 H20 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Rh1 C16 97.00(15) . . ?
C1 Rh1 C20 99.27(15) . . ?
C16 Rh1 C20 39.25(16) . . ?
C1 Rh1 C14 156.71(16) . . ?
C16 Rh1 C14 66.99(17) . . ?
C20 Rh1 C14 79.23(17) . . ?
C1 Rh1 C15 161.52(16) . . ?
C16 Rh1 C15 79.41(17) . . ?
C20 Rh1 C15 66.44(17) . . ?
C14 Rh1 C15 36.44(15) . . ?
C1 Rh1 Cl2 90.57(10) . . ?
C16 Rh1 Cl2 156.05(13) . . ?
C20 Rh1 Cl2 160.57(13) . . ?
C14 Rh1 Cl2 98.19(13) . . ?
C15 Rh1 Cl2 100.01(14) . . ?
N2 C1 N5 104.0(3) . . ?
N2 C1 Rh1 125.8(3) . . ?
N5 C1 Rh1 130.2(3) . . ?
C1 N2 C3 111.0(3) . . ?
C1 N2 C7 124.0(3) . . ?
C3 N2 C7 125.0(3) . . ?
C4 C3 N2 106.5(4) . . ?
C4 C3 H3 126.7 . . ?
N2 C3 H3 126.7 . . ?
C3 C4 N5 107.3(3) . . ?
C3 C4 H4 126.3 . . ?
N5 C4 H4 126.3 . . ?
C1 N5 C4 111.1(3) . . ?
C1 N5 C6 124.4(3) . . ?
C4 N5 C6 124.4(3) . . ?
N5 C6 H6A 109.5 . . ?
N5 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
N5 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
N2 C7 C8 113.0(3) . . ?
N2 C7 H7A 109.0 . . ?
C8 C7 H7A 109.0 . . ?
N2 C7 H7B 109.0 . . ?
C8 C7 H7B 109.0 . . ?
H7A C7 H7B 107.8 . . ?
C13 C8 C9 118.9(4) . . ?
C13 C8 C7 121.1(4) . . ?
C9 C8 C7 120.0(4) . . ?
C10 C9 C8 120.2(4) . . ?
C10 C9 H9 119.9 . . ?
C8 C9 H9 119.9 . . ?
C9 C10 C11 119.8(5) . . ?
C9 C10 H10 120.1 . . ?
C11 C10 H10 120.1 . . ?
C12 C11 C10 120.4(5) . . ?
C12 C11 H11 119.8 . . ?
C10 C11 H11 119.8 . . ?
C11 C12 C13 119.8(5) . . ?
C11 C12 H12 120.1 . . ?
C13 C12 H12 120.1 . . ?
C8 C13 C12 120.8(4) . . ?
C8 C13 H13 119.6 . . ?
C12 C13 H13 119.6 . . ?
C15 C14 C17 106.7(4) . . ?
C15 C14 Rh1 72.5(2) . . ?
C17 C14 Rh1 93.8(3) . . ?
C15 C14 H14 123.4 . . ?
C17 C14 H14 123.4 . . ?
Rh1 C14 H14 123.4 . . ?
C14 C15 C18 106.3(4) . . ?
C14 C15 Rh1 71.0(2) . . ?
C18 C15 Rh1 94.0(3) . . ?
C14 C15 H15 123.7 . . ?
C18 C15 H15 123.7 . . ?
Rh1 C15 H15 123.7 . . ?
C20 C16 C17 105.8(4) . . ?
C20 C16 Rh1 70.9(2) . . ?
C17 C16 Rh1 98.2(3) . . ?
C20 C16 H16 123.0 . . ?
C17 C16 H16 123.0 . . ?
Rh1 C16 H16 123.0 . . ?
C14 C17 C16 100.9(3) . . ?
C14 C17 C19 100.7(4) . . ?
C16 C17 C19 101.0(3) . . ?
C14 C17 H17 117.1 . . ?
C16 C17 H17 117.1 . . ?
C19 C17 H17 117.1 . . ?
C15 C18 C20 101.1(3) . . ?
C15 C18 C19 101.1(4) . . ?
C20 C18 C19 100.7(4) . . ?
C15 C18 H18 117.0 . . ?
C20 C18 H18 117.0 . . ?
C19 C18 H18 117.0 . . ?
C17 C19 C18 93.3(3) . . ?
C17 C19 H19A 113.0 . . ?
C18 C19 H19A 113.0 . . ?
C17 C19 H19B 113.0 . . ?
C18 C19 H19B 113.0 . . ?
H19A C19 H19B 110.4 . . ?
C16 C20 C18 106.1(4) . . ?
C16 C20 Rh1 69.8(2) . . ?
C18 C20 Rh1 98.4(3) . . ?
C16 C20 H20 123.0 . . ?
C18 C20 H20 123.0 . . ?
Rh1 C20 H20 123.0 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C16 Rh1 C1 N2 77.8(3) . . . . ?
C20 Rh1 C1 N2 117.4(3) . . . . ?
C14 Rh1 C1 N2 33.1(6) . . . . ?
C15 Rh1 C1 N2 155.3(5) . . . . ?
Cl2 Rh1 C1 N2 -79.4(3) . . . . ?
C16 Rh1 C1 N5 -101.7(3) . . . . ?
C20 Rh1 C1 N5 -62.1(3) . . . . ?
C14 Rh1 C1 N5 -146.4(4) . . . . ?
C15 Rh1 C1 N5 -24.3(7) . . . . ?
Cl2 Rh1 C1 N5 101.0(3) . . . . ?
N5 C1 N2 C3 -0.7(4) . . . . ?
Rh1 C1 N2 C3 179.7(3) . . . . ?
N5 C1 N2 C7 178.5(3) . . . . ?
Rh1 C1 N2 C7 -1.1(5) . . . . ?
C1 N2 C3 C4 0.9(4) . . . . ?
C7 N2 C3 C4 -178.3(3) . . . . ?
N2 C3 C4 N5 -0.7(4) . . . . ?
N2 C1 N5 C4 0.2(4) . . . . ?
Rh1 C1 N5 C4 179.8(3) . . . . ?
N2 C1 N5 C6 177.4(3) . . . . ?
Rh1 C1 N5 C6 -3.0(5) . . . . ?
C3 C4 N5 C1 0.3(4) . . . . ?
C3 C4 N5 C6 -176.8(4) . . . . ?
C1 N2 C7 C8 130.9(4) . . . . ?
C3 N2 C7 C8 -50.0(5) . . . . ?
N2 C7 C8 C13 114.5(4) . . . . ?
N2 C7 C8 C9 -65.0(5) . . . . ?
C13 C8 C9 C10 -1.8(6) . . . . ?
C7 C8 C9 C10 177.6(4) . . . . ?
C8 C9 C10 C11 0.6(7) . . . . ?
C9 C10 C11 C12 1.5(8) . . . . ?
C10 C11 C12 C13 -2.3(8) . . . . ?
C9 C8 C13 C12 1.0(6) . . . . ?
C7 C8 C13 C12 -178.4(4) . . . . ?
C11 C12 C13 C8 1.1(7) . . . . ?
C1 Rh1 C14 C15 153.1(4) . . . . ?
C16 Rh1 C14 C15 103.8(3) . . . . ?
C20 Rh1 C14 C15 64.7(3) . . . . ?
Cl2 Rh1 C14 C15 -95.8(3) . . . . ?
C1 Rh1 C14 C17 46.9(5) . . . . ?
C16 Rh1 C14 C17 -2.4(2) . . . . ?
C20 Rh1 C14 C17 -41.6(3) . . . . ?
C15 Rh1 C14 C17 -106.3(4) . . . . ?
Cl2 Rh1 C14 C17 157.9(2) . . . . ?
C17 C14 C15 C18 0.1(4) . . . . ?
Rh1 C14 C15 C18 -88.6(3) . . . . ?
C17 C14 C15 Rh1 88.8(3) . . . . ?
C1 Rh1 C15 C14 -145.7(4) . . . . ?
C16 Rh1 C15 C14 -65.4(3) . . . . ?
C20 Rh1 C15 C14 -104.3(3) . . . . ?
Cl2 Rh1 C15 C14 90.3(3) . . . . ?
C1 Rh1 C15 C18 -39.8(6) . . . . ?
C16 Rh1 C15 C18 40.5(3) . . . . ?
C20 Rh1 C15 C18 1.6(3) . . . . ?
C14 Rh1 C15 C18 105.9(4) . . . . ?
Cl2 Rh1 C15 C18 -163.8(2) . . . . ?
C1 Rh1 C16 C20 96.1(3) . . . . ?
C14 Rh1 C16 C20 -101.5(3) . . . . ?
C15 Rh1 C16 C20 -65.6(3) . . . . ?
Cl2 Rh1 C16 C20 -156.4(3) . . . . ?
C1 Rh1 C16 C17 -160.0(3) . . . . ?
C20 Rh1 C16 C17 103.9(4) . . . . ?
C14 Rh1 C16 C17 2.5(2) . . . . ?
C15 Rh1 C16 C17 38.4(3) . . . . ?
Cl2 Rh1 C16 C17 -52.4(4) . . . . ?
C15 C14 C17 C16 -69.8(4) . . . . ?
Rh1 C14 C17 C16 3.1(3) . . . . ?
C15 C14 C17 C19 33.8(4) . . . . ?
Rh1 C14 C17 C19 106.7(3) . . . . ?
C20 C16 C17 C14 69.1(4) . . . . ?
Rh1 C16 C17 C14 -3.3(3) . . . . ?
C20 C16 C17 C19 -34.2(4) . . . . ?
Rh1 C16 C17 C19 -106.7(3) . . . . ?
C14 C15 C18 C20 69.3(4) . . . . ?
Rh1 C15 C18 C20 -2.0(3) . . . . ?
C14 C15 C18 C19 -34.1(4) . . . . ?
Rh1 C15 C18 C19 -105.4(3) . . . . ?
C14 C17 C19 C18 -51.1(4) . . . . ?
C16 C17 C19 C18 52.4(4) . . . . ?
C15 C18 C19 C17 51.4(4) . . . . ?
C20 C18 C19 C17 -52.3(4) . . . . ?
C17 C16 C20 C18 -0.2(4) . . . . ?
Rh1 C16 C20 C18 93.2(3) . . . . ?
C17 C16 C20 Rh1 -93.4(3) . . . . ?
C15 C18 C20 C16 -69.1(4) . . . . ?
C19 C18 C20 C16 34.5(4) . . . . ?
C15 C18 C20 Rh1 2.2(3) . . . . ?
C19 C18 C20 Rh1 105.8(3) . . . . ?
C1 Rh1 C20 C16 -89.7(3) . . . . ?
C14 Rh1 C20 C16 66.7(3) . . . . ?
C15 Rh1 C20 C16 102.5(3) . . . . ?
Cl2 Rh1 C20 C16 150.7(3) . . . . ?
C1 Rh1 C20 C18 166.1(3) . . . . ?
C16 Rh1 C20 C18 -104.1(4) . . . . ?
C14 Rh1 C20 C18 -37.5(3) . . . . ?
C15 Rh1 C20 C18 -1.6(3) . . . . ?
Cl2 Rh1 C20 C18 46.6(5) . . . . ?

_diffrn_measured_fraction_theta_max 1.000
_diffrn_reflns_theta_full        24.99
_diffrn_measured_fraction_theta_full 1.000
_refine_diff_density_max         0.800
_refine_diff_density_min         -0.313
_refine_diff_density_rms         0.070
_database_code_depnum_ccdc_archive 'CCDC 957761'

data_p21n

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C24 H24 Cl N2 Rh'
_chemical_formula_weight         478.81

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           MONOCLINIC
_symmetry_space_group_name_H-M   P2(1)/n

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   11.3295(6)
_cell_length_b                   10.5864(6)
_cell_length_c                   18.0379(9)
_cell_angle_alpha                90.00
_cell_angle_beta                 106.8260(10)
_cell_angle_gamma                90.00
_cell_volume                     2070.82(19)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    9998
_cell_measurement_theta_min      2.166
_cell_measurement_theta_max      28.015

_exptl_crystal_description       PRISMATIC
_exptl_crystal_colour            'PALE YELLOW'
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.15
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.536
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             976
_exptl_absorpt_coefficient_mu    0.965
_exptl_absorpt_correction_type   'EMPIRICAL SADABS'
_exptl_absorpt_correction_T_min  0.7943
_exptl_absorpt_correction_T_max  0.8687
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD AREA DETECTOR'
_diffrn_measurement_method       'OMEGA SCANS'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            19412
_diffrn_reflns_av_R_equivalents  0.0234
_diffrn_reflns_av_sigmaI/netI    0.0165
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_theta_min         1.91
_diffrn_reflns_theta_max         25.00
_reflns_number_total             3655
_reflns_number_gt                3261
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0268P)²+1.0348P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    CONSTR
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         3655
_refine_ls_number_parameters     253
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0261
_refine_ls_R_factor_gt           0.0218
_refine_ls_wR_factor_ref         0.0561
_refine_ls_wR_factor_gt          0.0536
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_restrained_S_all      1.044
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.899291(15) 0.663596(16) 0.239065(9) 0.03571(7) Uani 1 1 d . . .
Cl2 Cl 0.78125(6) 0.55928(6) 0.30904(4) 0.05259(16) Uani 1 1 d . . .
C1 C 0.79220(18) 0.5902(2) 0.13847(12) 0.0334(4) Uani 1 1 d . . .
N2 N 0.70073(16) 0.64547(16) 0.08176(10) 0.0349(4) Uani 1 1 d . . .
C3 C 0.6496(2) 0.5605(2) 0.02308(13) 0.0431(5) Uani 1 1 d . . .
H3 H 0.5858 0.5764 -0.0217 0.052 Uiso 1 1 calc R . .
C4 C 0.7092(2) 0.4516(2) 0.04275(14) 0.0450(6) Uani 1 1 d . . .
H4 H 0.6949 0.3770 0.0143 0.054 Uiso 1 1 calc R . .
N5 N 0.79641(16) 0.47031(16) 0.11343(10) 0.0371(4) Uani 1 1 d . . .
C6 C 0.8755(2) 0.3715(2) 0.15885(14) 0.0461(6) Uani 1 1 d . . .
H6A H 0.8243 0.3102 0.1750 0.055 Uiso 1 1 calc R . .
H6B H 0.9302 0.4091 0.2052 0.055 Uiso 1 1 calc R . .
C7 C 0.9522(2) 0.3038(2) 0.11495(13) 0.0369(5) Uani 1 1 d . . .
C8 C 1.0071(2) 0.3674(2) 0.06682(16) 0.0528(6) Uani 1 1 d . . .
H8 H 0.9970 0.4544 0.0606 0.063 Uiso 1 1 calc R . .
C9 C 1.0773(3) 0.3024(3) 0.02765(16) 0.0589(7) Uani 1 1 d . . .
H9 H 1.1124 0.3457 -0.0056 0.071 Uiso 1 1 calc R . .
C10 C 1.0950(2) 0.1752(3) 0.03774(16) 0.0538(6) Uani 1 1 d . . .
H10 H 1.1429 0.1320 0.0120 0.065 Uiso 1 1 calc R . .
C11 C 1.0419(2) 0.1114(2) 0.08598(15) 0.0525(6) Uani 1 1 d . . .
H11 H 1.0539 0.0248 0.0930 0.063 Uiso 1 1 calc R . .
C12 C 0.9707(2) 0.1752(2) 0.12409(14) 0.0430(5) Uani 1 1 d . . .
H12 H 0.9346 0.1309 0.1564 0.052 Uiso 1 1 calc R . .
C13 C 0.6593(2) 0.7760(2) 0.08290(14) 0.0429(5) Uani 1 1 d . . .
H13A H 0.6674 0.8192 0.0372 0.052 Uiso 1 1 calc R . .
H13B H 0.7125 0.8183 0.1280 0.052 Uiso 1 1 calc R . .
C14 C 0.52717(19) 0.7867(2) 0.08499(13) 0.0370(5) Uani 1 1 d . . .
C15 C 0.4410(2) 0.8526(2) 0.02843(14) 0.0441(5) Uani 1 1 d . . .
H15 H 0.4630 0.8868 -0.0131 0.053 Uiso 1 1 calc R . .
C16 C 0.3219(2) 0.8681(2) 0.03298(17) 0.0558(7) Uani 1 1 d . . .
H16 H 0.2647 0.9138 -0.0050 0.067 Uiso 1 1 calc R . .
C17 C 0.2883(3) 0.8164(3) 0.0933(2) 0.0672(8) Uani 1 1 d . . .
H17 H 0.2085 0.8270 0.0966 0.081 Uiso 1 1 calc R . .
C18 C 0.3732(3) 0.7485(3) 0.14935(18) 0.0702(8) Uani 1 1 d . . .
H18 H 0.3501 0.7121 0.1900 0.084 Uiso 1 1 calc R . .
C19 C 0.4917(2) 0.7344(3) 0.14535(15) 0.0550(6) Uani 1 1 d . . .
H19 H 0.5487 0.6893 0.1837 0.066 Uiso 1 1 calc R . .
C20 C 0.9782(2) 0.8135(3) 0.19541(15) 0.0519(6) Uani 1 1 d . . .
H20 H 0.9386 0.8531 0.1452 0.062 Uiso 1 1 calc R . .
C21 C 1.0541(2) 0.7086(3) 0.20338(14) 0.0531(6) Uani 1 1 d . . .
H21 H 1.0729 0.6675 0.1594 0.064 Uiso 1 1 calc R . .
C22 C 0.9906(2) 0.8004(3) 0.32789(15) 0.0565(7) Uani 1 1 d . . .
H22 H 0.9554 0.8298 0.3685 0.068 Uiso 1 1 calc R . .
C23 C 1.0653(2) 0.6976(3) 0.33589(14) 0.0566(7) Uani 1 1 d . . .
H23 H 1.0894 0.6453 0.3827 0.068 Uiso 1 1 calc R . .
C24 C 1.0258(2) 0.8893(3) 0.27040(16) 0.0619(7) Uani 1 1 d . . .
H24 H 0.9993 0.9776 0.2695 0.074 Uiso 1 1 calc R . .
C25 C 1.1487(2) 0.7214(3) 0.28373(16) 0.0616(7) Uani 1 1 d . . .
H25 H 1.2240 0.6705 0.2936 0.074 Uiso 1 1 calc R . .
C26 C 1.1646(3) 0.8642(3) 0.29009(19) 0.0743(9) Uani 1 1 d . . .
H26A H 1.2012 0.8991 0.2522 0.089 Uiso 1 1 calc R . .
H26B H 1.2097 0.8919 0.3418 0.089 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C1 2.023(2) . ?
Rh1 C20 2.084(2) . ?
Rh1 C21 2.091(2) . ?
Rh1 C22 2.185(2) . ?
Rh1 C23 2.195(2) . ?
Rh1 Cl2 2.3618(6) . ?
C1 N5 1.353(3) . ?
C1 N2 1.360(3) . ?
N2 C3 1.382(3) . ?
N2 C13 1.462(3) . ?
C3 C4 1.331(3) . ?
C3 H3 0.9300 . ?
C4 N5 1.382(3) . ?
C4 H4 0.9300 . ?
N5 C6 1.464(3) . ?
C6 C7 1.515(3) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C12 1.380(3) . ?
C7 C8 1.381(3) . ?
C8 C9 1.390(4) . ?
C8 H8 0.9300 . ?
C9 C10 1.366(4) . ?
C9 H9 0.9300 . ?
C10 C11 1.371(4) . ?
C10 H10 0.9300 . ?
C11 C12 1.379(3) . ?
C11 H11 0.9300 . ?
C12 H12 0.9300 . ?
C13 C14 1.512(3) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 C15 1.380(3) . ?
C14 C19 1.380(3) . ?
C15 C16 1.385(3) . ?
C15 H15 0.9300 . ?
C16 C17 1.367(4) . ?
C16 H16 0.9300 . ?
C17 C18 1.378(4) . ?
C17 H17 0.9300 . ?
C18 C19 1.374(4) . ?
C18 H18 0.9300 . ?
C19 H19 0.9300 . ?
C20 C21 1.387(4) . ?
C20 C24 1.530(4) . ?
C20 H20 0.9800 . ?
C21 C25 1.539(4) . ?
C21 H21 0.9800 . ?
C22 C23 1.360(4) . ?
C22 C24 1.536(4) . ?
C22 H22 0.9800 . ?
C23 C25 1.535(4) . ?
C23 H23 0.9800 . ?
C24 C26 1.532(4) . ?
C24 H24 0.9800 . ?
C25 C26 1.523(4) . ?
C25 H25 0.9800 . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Rh1 C20 99.49(9) . . ?
C1 Rh1 C21 98.63(9) . . ?
C20 Rh1 C21 38.79(10) . . ?
C1 Rh1 C22 161.04(10) . . ?
C20 Rh1 C22 66.97(10) . . ?
C21 Rh1 C22 79.25(10) . . ?
C1 Rh1 C23 158.45(9) . . ?
C20 Rh1 C23 79.23(10) . . ?
C21 Rh1 C23 66.76(10) . . ?
C22 Rh1 C23 36.18(10) . . ?
C1 Rh1 Cl2 90.83(6) . . ?
C20 Rh1 Cl2 158.26(8) . . ?
C21 Rh1 Cl2 157.87(8) . . ?
C22 Rh1 Cl2 97.99(8) . . ?
C23 Rh1 Cl2 97.99(7) . . ?
N5 C1 N2 104.19(17) . . ?
N5 C1 Rh1 126.13(15) . . ?
N2 C1 Rh1 129.68(15) . . ?
C1 N2 C3 110.83(17) . . ?
C1 N2 C13 125.03(18) . . ?
C3 N2 C13 124.13(18) . . ?
C4 C3 N2 107.0(2) . . ?
C4 C3 H3 126.5 . . ?
N2 C3 H3 126.5 . . ?
C3 C4 N5 107.1(2) . . ?
C3 C4 H4 126.5 . . ?
N5 C4 H4 126.5 . . ?
C1 N5 C4 110.93(18) . . ?
C1 N5 C6 123.96(18) . . ?
C4 N5 C6 124.90(19) . . ?
N5 C6 C7 113.35(18) . . ?
N5 C6 H6A 108.9 . . ?
C7 C6 H6A 108.9 . . ?
N5 C6 H6B 108.9 . . ?
C7 C6 H6B 108.9 . . ?
H6A C6 H6B 107.7 . . ?
C12 C7 C8 118.4(2) . . ?
C12 C7 C6 119.6(2) . . ?
C8 C7 C6 121.9(2) . . ?
C7 C8 C9 120.4(2) . . ?
C7 C8 H8 119.8 . . ?
C9 C8 H8 119.8 . . ?
C10 C9 C8 120.3(2) . . ?
C10 C9 H9 119.9 . . ?
C8 C9 H9 119.9 . . ?
C9 C10 C11 119.7(2) . . ?
C9 C10 H10 120.1 . . ?
C11 C10 H10 120.1 . . ?
C10 C11 C12 120.2(2) . . ?
C10 C11 H11 119.9 . . ?
C12 C11 H11 119.9 . . ?
C11 C12 C7 120.9(2) . . ?
C11 C12 H12 119.5 . . ?
C7 C12 H12 119.5 . . ?
N2 C13 C14 113.31(17) . . ?
N2 C13 H13A 108.9 . . ?
C14 C13 H13A 108.9 . . ?
N2 C13 H13B 108.9 . . ?
C14 C13 H13B 108.9 . . ?
H13A C13 H13B 107.7 . . ?
C15 C14 C19 118.7(2) . . ?
C15 C14 C13 120.9(2) . . ?
C19 C14 C13 120.4(2) . . ?
C14 C15 C16 120.6(2) . . ?
C14 C15 H15 119.7 . . ?
C16 C15 H15 119.7 . . ?
C17 C16 C15 120.0(2) . . ?
C17 C16 H16 120.0 . . ?
C15 C16 H16 120.0 . . ?
C16 C17 C18 119.8(2) . . ?
C16 C17 H17 120.1 . . ?
C18 C17 H17 120.1 . . ?
C19 C18 C17 120.2(3) . . ?
C19 C18 H18 119.9 . . ?
C17 C18 H18 119.9 . . ?
C18 C19 C14 120.7(3) . . ?
C18 C19 H19 119.7 . . ?
C14 C19 H19 119.7 . . ?
C21 C20 C24 106.2(2) . . ?
C21 C20 Rh1 70.86(14) . . ?
C24 C20 Rh1 98.35(17) . . ?
C21 C20 H20 122.8 . . ?
C24 C20 H20 122.8 . . ?
Rh1 C20 H20 122.8 . . ?
C20 C21 C25 105.6(2) . . ?
C20 C21 Rh1 70.34(14) . . ?
C25 C21 Rh1 98.50(16) . . ?
C20 C21 H21 123.1 . . ?
C25 C21 H21 123.1 . . ?
Rh1 C21 H21 123.1 . . ?
C23 C22 C24 106.7(2) . . ?
C23 C22 Rh1 72.30(15) . . ?
C24 C22 Rh1 94.10(15) . . ?
C23 C22 H22 123.4 . . ?
C24 C22 H22 123.4 . . ?
Rh1 C22 H22 123.4 . . ?
C22 C23 C25 106.2(3) . . ?
C22 C23 Rh1 71.51(14) . . ?
C25 C23 Rh1 94.42(15) . . ?
C22 C23 H23 123.6 . . ?
C25 C23 H23 123.6 . . ?
Rh1 C23 H23 123.6 . . ?
C20 C24 C26 100.9(2) . . ?
C20 C24 C22 100.4(2) . . ?
C26 C24 C22 100.8(2) . . ?
C20 C24 H24 117.2 . . ?
C26 C24 H24 117.2 . . ?
C22 C24 H24 117.2 . . ?
C26 C25 C23 101.3(2) . . ?
C26 C25 C21 101.1(2) . . ?
C23 C25 C21 100.27(19) . . ?
C26 C25 H25 117.1 . . ?
C23 C25 H25 117.1 . . ?
C21 C25 H25 117.1 . . ?
C25 C26 C24 93.7(2) . . ?
C25 C26 H26A 113.0 . . ?
C24 C26 H26A 113.0 . . ?
C25 C26 H26B 113.0 . . ?
C24 C26 H26B 113.0 . . ?
H26A C26 H26B 110.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C20 Rh1 C1 N5 122.74(19) . . . . ?
C21 Rh1 C1 N5 83.44(19) . . . . ?
C22 Rh1 C1 N5 165.5(2) . . . . ?
C23 Rh1 C1 N5 38.0(4) . . . . ?
Cl2 Rh1 C1 N5 -76.48(17) . . . . ?
C20 Rh1 C1 N2 -58.2(2) . . . . ?
C21 Rh1 C1 N2 -97.5(2) . . . . ?
C22 Rh1 C1 N2 -15.5(4) . . . . ?
C23 Rh1 C1 N2 -142.9(2) . . . . ?
Cl2 Rh1 C1 N2 102.59(18) . . . . ?
N5 C1 N2 C3 0.1(2) . . . . ?
Rh1 C1 N2 C3 -179.08(15) . . . . ?
N5 C1 N2 C13 178.80(18) . . . . ?
Rh1 C1 N2 C13 -0.4(3) . . . . ?
C1 N2 C3 C4 -0.1(3) . . . . ?
C13 N2 C3 C4 -178.8(2) . . . . ?
N2 C3 C4 N5 0.1(3) . . . . ?
N2 C1 N5 C4 -0.1(2) . . . . ?
Rh1 C1 N5 C4 179.16(15) . . . . ?
N2 C1 N5 C6 -175.05(19) . . . . ?
Rh1 C1 N5 C6 4.2(3) . . . . ?
C3 C4 N5 C1 0.0(3) . . . . ?
C3 C4 N5 C6 174.9(2) . . . . ?
C1 N5 C6 C7 -128.9(2) . . . . ?
C4 N5 C6 C7 56.9(3) . . . . ?
N5 C6 C7 C12 -141.3(2) . . . . ?
N5 C6 C7 C8 40.1(3) . . . . ?
C12 C7 C8 C9 1.1(4) . . . . ?
C6 C7 C8 C9 179.7(2) . . . . ?
C7 C8 C9 C10 -1.5(4) . . . . ?
C8 C9 C10 C11 0.8(4) . . . . ?
C9 C10 C11 C12 0.1(4) . . . . ?
C10 C11 C12 C7 -0.4(4) . . . . ?
C8 C7 C12 C11 -0.2(4) . . . . ?
C6 C7 C12 C11 -178.8(2) . . . . ?
C1 N2 C13 C14 -116.1(2) . . . . ?
C3 N2 C13 C14 62.4(3) . . . . ?
N2 C13 C14 C15 -122.7(2) . . . . ?
N2 C13 C14 C19 59.7(3) . . . . ?
C19 C14 C15 C16 1.3(3) . . . . ?
C13 C14 C15 C16 -176.3(2) . . . . ?
C14 C15 C16 C17 -1.0(4) . . . . ?
C15 C16 C17 C18 -0.2(4) . . . . ?
C16 C17 C18 C19 1.1(5) . . . . ?
C17 C18 C19 C14 -0.7(5) . . . . ?
C15 C14 C19 C18 -0.5(4) . . . . ?
C13 C14 C19 C18 177.2(3) . . . . ?
C1 Rh1 C20 C21 -92.01(15) . . . . ?
C22 Rh1 C20 C21 101.85(17) . . . . ?
C23 Rh1 C20 C21 66.14(16) . . . . ?
Cl2 Rh1 C20 C21 150.69(16) . . . . ?
C1 Rh1 C20 C24 163.66(16) . . . . ?
C21 Rh1 C20 C24 -104.3(2) . . . . ?
C22 Rh1 C20 C24 -2.48(16) . . . . ?
C23 Rh1 C20 C24 -38.19(17) . . . . ?
Cl2 Rh1 C20 C24 46.4(3) . . . . ?
C24 C20 C21 C25 -0.2(3) . . . . ?
Rh1 C20 C21 C25 -93.62(17) . . . . ?
C24 C20 C21 Rh1 93.40(18) . . . . ?
C1 Rh1 C21 C20 94.43(15) . . . . ?
C22 Rh1 C21 C20 -66.46(16) . . . . ?
C23 Rh1 C21 C20 -102.11(17) . . . . ?
Cl2 Rh1 C21 C20 -151.23(17) . . . . ?
C1 Rh1 C21 C25 -161.94(18) . . . . ?
C20 Rh1 C21 C25 103.6(2) . . . . ?
C22 Rh1 C21 C25 37.18(18) . . . . ?
C23 Rh1 C21 C25 1.53(18) . . . . ?
Cl2 Rh1 C21 C25 -47.6(3) . . . . ?
C1 Rh1 C22 C23 -150.4(2) . . . . ?
C20 Rh1 C22 C23 -103.73(19) . . . . ?
C21 Rh1 C22 C23 -65.12(18) . . . . ?
Cl2 Rh1 C22 C23 92.62(16) . . . . ?
C1 Rh1 C22 C24 -44.2(4) . . . . ?
C20 Rh1 C22 C24 2.45(16) . . . . ?
C21 Rh1 C22 C24 41.07(17) . . . . ?
C23 Rh1 C22 C24 106.2(2) . . . . ?
Cl2 Rh1 C22 C24 -161.20(15) . . . . ?
C24 C22 C23 C25 0.3(3) . . . . ?
Rh1 C22 C23 C25 89.29(17) . . . . ?
C24 C22 C23 Rh1 -89.02(17) . . . . ?
C1 Rh1 C23 C22 154.1(2) . . . . ?
C20 Rh1 C23 C22 65.51(18) . . . . ?
C21 Rh1 C23 C22 104.1(2) . . . . ?
Cl2 Rh1 C23 C22 -92.63(16) . . . . ?
C1 Rh1 C23 C25 48.5(4) . . . . ?
C20 Rh1 C23 C25 -40.10(19) . . . . ?
C21 Rh1 C23 C25 -1.52(18) . . . . ?
C22 Rh1 C23 C25 -105.6(3) . . . . ?
Cl2 Rh1 C23 C25 161.76(17) . . . . ?
C21 C20 C24 C26 34.1(3) . . . . ?
Rh1 C20 C24 C26 106.5(2) . . . . ?
C21 C20 C24 C22 -69.1(2) . . . . ?
Rh1 C20 C24 C22 3.3(2) . . . . ?
C23 C22 C24 C20 69.6(2) . . . . ?
Rh1 C22 C24 C20 -3.1(2) . . . . ?
C23 C22 C24 C26 -33.7(3) . . . . ?
Rh1 C22 C24 C26 -106.48(19) . . . . ?
C22 C23 C25 C26 33.6(3) . . . . ?
Rh1 C23 C25 C26 105.60(19) . . . . ?
C22 C23 C25 C21 -70.1(3) . . . . ?
Rh1 C23 C25 C21 1.9(2) . . . . ?
C20 C21 C25 C26 -34.0(3) . . . . ?
Rh1 C21 C25 C26 -105.9(2) . . . . ?
C20 C21 C25 C23 69.8(3) . . . . ?
Rh1 C21 C25 C23 -2.0(2) . . . . ?
C23 C25 C26 C24 -51.1(2) . . . . ?
C21 C25 C26 C24 51.9(2) . . . . ?
C20 C24 C26 C25 -52.0(3) . . . . ?
C22 C24 C26 C25 51.0(2) . . . . ?

_diffrn_measured_fraction_theta_max 1.000
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 1.000
_refine_diff_density_max         0.331
_refine_diff_density_min         -0.285
_refine_diff_density_rms         0.049
_database_code_depnum_ccdc_archive 'CCDC 957762'
