# Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry
# This journal is © The Royal Society of Chemistry 2012


data_global
_journal_name_full               Org.Biomol.Chem.
_journal_coden_cambridge         0177
_journal_year                    ?
_journal_volume                  ?
_journal_page_first              ?
_publ_contact_author_email       skyshine@zju.edu.cn
_publ_contact_author_name        'Shugao Zhu'
loop_
_publ_author_name
'Luling Wu'
'Shugao Zhu'
'Xian Huang'

data_110414_zsg_110331b_2
_database_code_depnum_ccdc_archive 'CCDC 821990'
#TrackingRef '110414_zsg_110331b_2.cif'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C30 H24 O5'
_chemical_formula_weight         464.49

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/c'
_symmetry_space_group_name_Hall  '-P 2ybc'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   8.3183(2)
_cell_length_b                   25.3594(6)
_cell_length_c                   10.8216(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.076(2)
_cell_angle_gamma                90.00
_cell_volume                     2282.78(9)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       colorless
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.23
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.349
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             972
_exptl_absorpt_coefficient_mu    0.091
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.9713
_exptl_absorpt_correction_T_max  0.9793
_exptl_absorpt_process_details   
;
CrysAlis PRO (Oxford Diffraction, 2010)
;

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur, Atlas, Gemini ultra'
_diffrn_measurement_method       '\w scans'
_diffrn_detector_area_resol_mean 10.3592
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            21130
_diffrn_reflns_av_R_equivalents  0.0291
_diffrn_reflns_av_sigmaI/netI    0.0226
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_theta_min         2.93
_diffrn_reflns_theta_max         25.35
_reflns_number_total             4165
_reflns_number_gt                3338
_reflns_threshold_expression     >2sigma(I)

_computing_cell_refinement       'CrysAlis PRO (Oxford Diffraction, 2010)'
_computing_data_collection       'CrysAlis PRO'
_computing_data_reduction        'CrysAlis PRO'
_computing_molecular_graphics    'OLEX2 (Dolomanov et al., 2009)'
_computing_publication_material  OLEX2
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0581P)^2^+1.2058P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         4165
_refine_ls_number_parameters     319
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0555
_refine_ls_R_factor_gt           0.0407
_refine_ls_wR_factor_ref         0.1083
_refine_ls_wR_factor_gt          0.0976
_refine_ls_goodness_of_fit_ref   0.878
_refine_ls_restrained_S_all      0.878
_refine_ls_shift/su_max          0.054
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
O1 O 0.24606(16) 0.89276(5) -0.01048(12) 0.0508(4) Uani 1 1 d . . .
O2 O 0.62041(18) 0.51392(6) 0.29598(13) 0.0628(4) Uani 1 1 d . . .
O3 O 0.77932(16) 0.56451(5) 0.41028(11) 0.0497(3) Uani 1 1 d . . .
O4 O 1.04985(16) 0.50956(6) 0.27193(17) 0.0726(5) Uani 1 1 d . . .
O5 O 1.10879(14) 0.58358(5) 0.17415(12) 0.0433(3) Uani 1 1 d . . .
C1 C 0.1266(2) 0.91138(8) 0.07182(19) 0.0521(5) Uani 1 1 d . . .
H1A H 0.0784 0.9427 0.0386 0.078 Uiso 1 1 calc R . .
H1B H 0.1747 0.9193 0.1503 0.078 Uiso 1 1 calc R . .
H1C H 0.0456 0.8848 0.0823 0.078 Uiso 1 1 calc R . .
C2 C 0.3295(2) 0.84845(6) 0.02184(15) 0.0353(4) Uani 1 1 d . . .
C3 C 0.4558(2) 0.83497(7) -0.05494(17) 0.0464(5) Uani 1 1 d . . .
H3 H 0.4775 0.8553 -0.1245 0.056 Uiso 1 1 calc R . .
C4 C 0.5493(2) 0.79171(7) -0.02887(16) 0.0450(5) Uani 1 1 d . . .
H4 H 0.6339 0.7832 -0.0813 0.054 Uiso 1 1 calc R . .
C5 C 0.52060(19) 0.76054(6) 0.07368(14) 0.0307(4) Uani 1 1 d . . .
C6 C 0.3916(2) 0.77373(7) 0.14754(15) 0.0365(4) Uani 1 1 d . . .
H6 H 0.3682 0.7528 0.2158 0.044 Uiso 1 1 calc R . .
C7 C 0.2958(2) 0.81722(7) 0.12286(15) 0.0380(4) Uani 1 1 d . . .
H7 H 0.2096 0.8253 0.1740 0.046 Uiso 1 1 calc R . .
C8 C 0.7961(2) 0.81313(7) 0.24364(16) 0.0392(4) Uani 1 1 d . . .
H8 H 0.7178 0.8266 0.1910 0.047 Uiso 1 1 calc R . .
C9 C 0.8869(2) 0.84648(7) 0.31706(18) 0.0455(5) Uani 1 1 d . . .
H9 H 0.8699 0.8827 0.3128 0.055 Uiso 1 1 calc R . .
C10 C 1.0025(2) 0.82693(8) 0.39661(18) 0.0481(5) Uani 1 1 d . . .
H10 H 1.0609 0.8500 0.4462 0.058 Uiso 1 1 calc R . .
C11 C 1.0318(2) 0.77343(8) 0.40299(17) 0.0451(4) Uani 1 1 d . . .
H11 H 1.1101 0.7603 0.4561 0.054 Uiso 1 1 calc R . .
C12 C 0.9429(2) 0.73954(7) 0.32921(15) 0.0360(4) Uani 1 1 d . . .
C13 C 0.82390(19) 0.75902(6) 0.24994(14) 0.0312(4) Uani 1 1 d . . .
C14 C 0.74842(18) 0.71423(6) 0.18453(14) 0.0291(3) Uani 1 1 d . . .
C15 C 0.83039(18) 0.66722(6) 0.22371(14) 0.0307(4) Uani 1 1 d . . .
C16 C 0.9536(2) 0.68055(7) 0.32098(16) 0.0404(4) Uani 1 1 d . . .
H16A H 0.9273 0.6642 0.3994 0.049 Uiso 1 1 calc R . .
H16B H 1.0603 0.6694 0.2959 0.049 Uiso 1 1 calc R . .
C17 C 0.78900(18) 0.62010(6) 0.17197(14) 0.0289(3) Uani 1 1 d . . .
C18 C 0.67281(18) 0.62005(6) 0.07711(14) 0.0291(3) Uani 1 1 d . . .
C19 C 0.58493(18) 0.66473(6) 0.04149(14) 0.0302(3) Uani 1 1 d . . .
C20 C 0.62128(18) 0.71341(6) 0.10144(14) 0.0300(3) Uani 1 1 d . . .
C21 C 0.4716(2) 0.65689(7) -0.05445(15) 0.0376(4) Uani 1 1 d . . .
H21 H 0.4063 0.6847 -0.0797 0.045 Uiso 1 1 calc R . .
C22 C 0.4575(2) 0.60881(7) -0.11020(17) 0.0428(4) Uani 1 1 d . . .
H22 H 0.3827 0.6048 -0.1735 0.051 Uiso 1 1 calc R . .
C23 C 0.5513(2) 0.56501(7) -0.07589(16) 0.0386(4) Uani 1 1 d . . .
H23 H 0.5412 0.5330 -0.1171 0.046 Uiso 1 1 calc R . .
C24 C 0.65735(19) 0.57066(6) 0.01930(15) 0.0323(4) Uani 1 1 d . . .
C25 C 0.7799(2) 0.53403(6) 0.07524(16) 0.0362(4) Uani 1 1 d . . .
H25A H 0.8700 0.5290 0.0198 0.043 Uiso 1 1 calc R . .
H25B H 0.7324 0.5000 0.0937 0.043 Uiso 1 1 calc R . .
C26 C 0.83433(19) 0.56249(6) 0.19623(15) 0.0319(4) Uani 1 1 d . . .
C27 C 0.73207(19) 0.54305(6) 0.30495(16) 0.0350(4) Uani 1 1 d . . .
C28 C 0.6911(3) 0.54962(9) 0.52033(18) 0.0586(5) Uani 1 1 d . . .
H28A H 0.5796 0.5585 0.5100 0.088 Uiso 1 1 calc R . .
H28B H 0.7338 0.5682 0.5904 0.088 Uiso 1 1 calc R . .
H28C H 0.7014 0.5123 0.5335 0.088 Uiso 1 1 calc R . .
C29 C 1.0091(2) 0.54878(6) 0.22129(16) 0.0352(4) Uani 1 1 d . . .
C30 C 1.2781(2) 0.57225(9) 0.1892(2) 0.0522(5) Uani 1 1 d . . .
H30A H 1.3054 0.5414 0.1423 0.078 Uiso 1 1 calc R . .
H30B H 1.3010 0.5661 0.2750 0.078 Uiso 1 1 calc R . .
H30C H 1.3402 0.6017 0.1604 0.078 Uiso 1 1 calc R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
O1 0.0547(8) 0.0411(7) 0.0565(8) 0.0089(6) 0.0050(6) 0.0212(6)
O2 0.0536(9) 0.0774(10) 0.0572(9) 0.0033(7) -0.0012(7) -0.0342(8)
O3 0.0520(8) 0.0577(8) 0.0394(7) 0.0043(6) -0.0009(6) -0.0169(6)
O4 0.0383(8) 0.0610(10) 0.1184(14) 0.0460(9) -0.0072(8) 0.0073(7)
O5 0.0283(6) 0.0427(7) 0.0589(8) 0.0073(6) 0.0032(5) 0.0013(5)
C1 0.0496(12) 0.0490(12) 0.0576(12) -0.0074(9) -0.0036(9) 0.0215(9)
C2 0.0356(9) 0.0316(9) 0.0386(9) -0.0001(7) -0.0045(7) 0.0074(7)
C3 0.0528(11) 0.0443(11) 0.0420(10) 0.0158(8) 0.0119(8) 0.0132(9)
C4 0.0458(11) 0.0470(11) 0.0422(10) 0.0093(8) 0.0146(8) 0.0146(9)
C5 0.0310(8) 0.0309(8) 0.0302(8) -0.0005(7) -0.0026(6) 0.0029(7)
C6 0.0401(10) 0.0377(9) 0.0317(8) 0.0055(7) 0.0040(7) 0.0061(7)
C7 0.0355(9) 0.0418(10) 0.0369(9) -0.0018(8) 0.0059(7) 0.0083(7)
C8 0.0406(10) 0.0348(9) 0.0422(9) -0.0025(8) 0.0055(7) 0.0013(8)
C9 0.0475(11) 0.0335(9) 0.0555(11) -0.0100(8) 0.0105(9) -0.0037(8)
C10 0.0471(11) 0.0469(11) 0.0505(11) -0.0159(9) 0.0032(9) -0.0121(9)
C11 0.0413(10) 0.0490(11) 0.0449(10) -0.0063(8) -0.0055(8) -0.0062(8)
C12 0.0340(9) 0.0375(9) 0.0366(9) -0.0018(7) 0.0000(7) -0.0041(7)
C13 0.0300(8) 0.0324(9) 0.0313(8) -0.0013(7) 0.0054(6) -0.0011(7)
C14 0.0294(8) 0.0299(8) 0.0279(8) 0.0013(6) 0.0027(6) 0.0013(6)
C15 0.0279(8) 0.0321(9) 0.0319(8) 0.0025(7) -0.0014(6) -0.0003(6)
C16 0.0388(10) 0.0374(9) 0.0451(10) -0.0001(8) -0.0131(8) -0.0005(8)
C17 0.0248(8) 0.0289(8) 0.0331(8) 0.0027(7) -0.0002(6) 0.0012(6)
C18 0.0251(8) 0.0311(8) 0.0310(8) 0.0022(7) 0.0002(6) -0.0004(6)
C19 0.0269(8) 0.0328(9) 0.0310(8) 0.0026(7) 0.0001(6) 0.0013(6)
C20 0.0290(8) 0.0312(8) 0.0298(8) 0.0028(6) 0.0023(6) 0.0035(6)
C21 0.0344(9) 0.0383(9) 0.0402(9) 0.0041(8) -0.0092(7) 0.0033(7)
C22 0.0394(10) 0.0465(11) 0.0425(10) 0.0007(8) -0.0153(8) -0.0022(8)
C23 0.0400(10) 0.0351(9) 0.0407(9) -0.0047(7) -0.0071(8) -0.0031(7)
C24 0.0304(9) 0.0308(8) 0.0358(9) 0.0002(7) 0.0002(7) -0.0005(7)
C25 0.0344(9) 0.0304(9) 0.0436(9) -0.0022(7) -0.0035(7) 0.0019(7)
C26 0.0277(8) 0.0282(8) 0.0397(9) 0.0031(7) -0.0036(7) 0.0004(6)
C27 0.0287(9) 0.0323(9) 0.0441(10) 0.0064(7) -0.0073(7) -0.0003(7)
C28 0.0625(14) 0.0687(14) 0.0446(11) 0.0106(10) 0.0061(10) -0.0059(11)
C29 0.0313(9) 0.0311(9) 0.0432(9) 0.0037(7) -0.0039(7) 0.0020(7)
C30 0.0262(9) 0.0670(13) 0.0636(12) -0.0076(10) 0.0033(8) 0.0020(9)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O1 C2 1.3663(19) . ?
O1 C1 1.417(2) . ?
O2 C27 1.191(2) . ?
O3 C27 1.322(2) . ?
O3 C28 1.450(2) . ?
O4 C29 1.185(2) . ?
O5 C29 1.315(2) . ?
O5 C30 1.446(2) . ?
C1 H1A 0.9600 . ?
C1 H1B 0.9600 . ?
C1 H1C 0.9600 . ?
C2 C7 1.379(2) . ?
C2 C3 1.383(2) . ?
C3 C4 1.374(2) . ?
C3 H3 0.9300 . ?
C4 C5 1.384(2) . ?
C4 H4 0.9300 . ?
C5 C6 1.380(2) . ?
C5 C20 1.490(2) . ?
C6 C7 1.386(2) . ?
C6 H6 0.9300 . ?
C7 H7 0.9300 . ?
C8 C9 1.384(3) . ?
C8 C13 1.393(2) . ?
C8 H8 0.9300 . ?
C9 C10 1.382(3) . ?
C9 H9 0.9300 . ?
C10 C11 1.380(3) . ?
C10 H10 0.9300 . ?
C11 C12 1.386(2) . ?
C11 H11 0.9300 . ?
C12 C13 1.399(2) . ?
C12 C16 1.501(2) . ?
C13 C14 1.478(2) . ?
C14 C20 1.387(2) . ?
C14 C15 1.437(2) . ?
C15 C17 1.364(2) . ?
C15 C16 1.507(2) . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C17 C18 1.409(2) . ?
C17 C26 1.531(2) . ?
C18 C19 1.402(2) . ?
C18 C24 1.406(2) . ?
C19 C21 1.416(2) . ?
C19 C20 1.427(2) . ?
C21 C22 1.365(2) . ?
C21 H21 0.9300 . ?
C22 C23 1.407(2) . ?
C22 H22 0.9300 . ?
C23 C24 1.363(2) . ?
C23 H23 0.9300 . ?
C24 C25 1.505(2) . ?
C25 C26 1.562(2) . ?
C25 H25A 0.9700 . ?
C25 H25B 0.9700 . ?
C26 C29 1.519(2) . ?
C26 C27 1.534(2) . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C30 H30A 0.9600 . ?
C30 H30B 0.9600 . ?
C30 H30C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 O1 C1 118.04(14) . . ?
C27 O3 C28 116.78(15) . . ?
C29 O5 C30 115.95(14) . . ?
O1 C1 H1A 109.5 . . ?
O1 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
O1 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
O1 C2 C7 124.85(15) . . ?
O1 C2 C3 115.82(15) . . ?
C7 C2 C3 119.32(15) . . ?
C4 C3 C2 120.28(16) . . ?
C4 C3 H3 119.9 . . ?
C2 C3 H3 119.9 . . ?
C3 C4 C5 121.50(16) . . ?
C3 C4 H4 119.2 . . ?
C5 C4 H4 119.2 . . ?
C6 C5 C4 117.47(15) . . ?
C6 C5 C20 121.00(14) . . ?
C4 C5 C20 121.50(14) . . ?
C5 C6 C7 121.90(15) . . ?
C5 C6 H6 119.1 . . ?
C7 C6 H6 119.1 . . ?
C2 C7 C6 119.49(15) . . ?
C2 C7 H7 120.3 . . ?
C6 C7 H7 120.3 . . ?
C9 C8 C13 118.91(17) . . ?
C9 C8 H8 120.5 . . ?
C13 C8 H8 120.5 . . ?
C10 C9 C8 121.14(17) . . ?
C10 C9 H9 119.4 . . ?
C8 C9 H9 119.4 . . ?
C11 C10 C9 120.43(17) . . ?
C11 C10 H10 119.8 . . ?
C9 C10 H10 119.8 . . ?
C10 C11 C12 119.13(18) . . ?
C10 C11 H11 120.4 . . ?
C12 C11 H11 120.4 . . ?
C11 C12 C13 120.71(16) . . ?
C11 C12 C16 128.35(16) . . ?
C13 C12 C16 110.93(14) . . ?
C8 C13 C12 119.66(15) . . ?
C8 C13 C14 131.54(15) . . ?
C12 C13 C14 108.79(14) . . ?
C20 C14 C15 122.66(14) . . ?
C20 C14 C13 130.17(14) . . ?
C15 C14 C13 107.17(13) . . ?
C17 C15 C14 119.11(14) . . ?
C17 C15 C16 130.89(14) . . ?
C14 C15 C16 110.01(13) . . ?
C12 C16 C15 102.99(13) . . ?
C12 C16 H16A 111.2 . . ?
C15 C16 H16A 111.2 . . ?
C12 C16 H16B 111.2 . . ?
C15 C16 H16B 111.2 . . ?
H16A C16 H16B 109.1 . . ?
C15 C17 C18 118.19(14) . . ?
C15 C17 C26 134.72(14) . . ?
C18 C17 C26 107.01(13) . . ?
C19 C18 C24 123.38(14) . . ?
C19 C18 C17 123.81(14) . . ?
C24 C18 C17 112.78(14) . . ?
C18 C19 C21 115.77(14) . . ?
C18 C19 C20 117.65(14) . . ?
C21 C19 C20 126.55(14) . . ?
C14 C20 C19 117.94(14) . . ?
C14 C20 C5 123.12(14) . . ?
C19 C20 C5 118.93(13) . . ?
C22 C21 C19 120.41(15) . . ?
C22 C21 H21 119.8 . . ?
C19 C21 H21 119.8 . . ?
C21 C22 C23 122.75(15) . . ?
C21 C22 H22 118.6 . . ?
C23 C22 H22 118.6 . . ?
C24 C23 C22 118.34(15) . . ?
C24 C23 H23 120.8 . . ?
C22 C23 H23 120.8 . . ?
C23 C24 C18 119.26(15) . . ?
C23 C24 C25 132.55(15) . . ?
C18 C24 C25 108.02(13) . . ?
C24 C25 C26 104.33(13) . . ?
C24 C25 H25A 110.9 . . ?
C26 C25 H25A 110.9 . . ?
C24 C25 H25B 110.9 . . ?
C26 C25 H25B 110.9 . . ?
H25A C25 H25B 108.9 . . ?
C29 C26 C17 118.97(13) . . ?
C29 C26 C27 108.73(13) . . ?
C17 C26 C27 107.54(13) . . ?
C29 C26 C25 108.69(13) . . ?
C17 C26 C25 103.06(12) . . ?
C27 C26 C25 109.51(13) . . ?
O2 C27 O3 123.81(17) . . ?
O2 C27 C26 124.76(16) . . ?
O3 C27 C26 111.37(14) . . ?
O3 C28 H28A 109.5 . . ?
O3 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
O3 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
O4 C29 O5 124.24(16) . . ?
O4 C29 C26 123.22(16) . . ?
O5 C29 C26 112.42(13) . . ?
O5 C30 H30A 109.5 . . ?
O5 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
O5 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        25.35
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         0.189
_refine_diff_density_min         -0.188
_refine_diff_density_rms         0.038