# Electronic Supplementary Material (ESI) for RSC Advances
# This journal is © The Royal Society of Chemistry 2012


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#                                CCDC 
# 
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# 
#  This CIF contains data from an original supplementary publication 
#  deposited with the CCDC, and may include chemical, crystal,   
#  experimental, refinement, atomic coordinates, 
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted. 
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#  fide research purposes only. It may contain copyright material 
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data_nithi
_database_code_depnum_ccdc_archive 'CCDC 896819'
#TrackingRef 'a1znlinker.cif'


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C35 H28 N2 O6 Zn'
_chemical_formula_weight         637.96

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P21/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   13.6247(3)
_cell_length_b                   10.5447(2)
_cell_length_c                   20.8365(5)
_cell_angle_alpha                90.00
_cell_angle_beta                 96.106(2)
_cell_angle_gamma                90.00
_cell_volume                     2976.57(12)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    3851
_cell_measurement_theta_min      2.9436
_cell_measurement_theta_max      28.6697

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.18
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.424
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1320
_exptl_absorpt_coefficient_mu    0.875
_exptl_absorpt_correction_T_min  0.70300
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   psi-scan

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            12225
_diffrn_reflns_av_R_equivalents  0.0346
_diffrn_reflns_av_sigmaI/netI    0.0518
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         3.01
_diffrn_reflns_theta_max         25.50
_reflns_number_total             5535
_reflns_number_gt                4077
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0003P)^2^+2.5353P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         5535
_refine_ls_number_parameters     399
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0680
_refine_ls_R_factor_gt           0.0448
_refine_ls_wR_factor_ref         0.0874
_refine_ls_wR_factor_gt          0.0773
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_restrained_S_all      1.050
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Zn1 Zn 0.79160(3) 0.51569(3) 0.537010(17) 0.04696(12) Uani 1 1 d . . .
N1 N 0.80213(19) 0.3272(2) 0.55820(11) 0.0459(6) Uani 1 1 d . . .
O1 O 0.68923(19) 0.5670(2) 0.58896(12) 0.0718(7) Uani 1 1 d . . .
O6 O 1.0035(2) 0.7030(3) 0.74191(10) 0.0728(8) Uani 1 1 d . . .
H6 H 0.9669 0.6472 0.7259 0.109 Uiso 1 1 calc R . .
O4 O 0.90837(16) 0.6232(2) 0.55091(10) 0.0568(6) Uani 1 1 d . . .
C34 C 0.8410(3) -0.0164(4) 0.90449(16) 0.0663(11) Uani 1 1 d . . .
H34 H 0.9042 -0.0179 0.9263 0.080 Uiso 1 1 calc R . .
O5 O 0.91175(19) 0.5682(2) 0.65340(11) 0.0713(7) Uani 1 1 d . . .
C32 C 0.6604(2) -0.0149(3) 0.83973(15) 0.0533(9) Uani 1 1 d . . .
H32 H 0.5965 -0.0157 0.8189 0.064 Uiso 1 1 calc R . .
C33 C 0.6747(2) -0.0183(3) 0.90604(15) 0.0572(9) Uani 1 1 d . . .
H33 H 0.6197 -0.0216 0.9289 0.069 Uiso 1 1 calc R . .
C20 C 1.1258(3) 1.0143(3) 0.54947(17) 0.0625(10) Uani 1 1 d . . .
H20 H 1.1073 0.9964 0.5062 0.075 Uiso 1 1 calc R . .
C30 C 0.7236(3) -0.0029(3) 0.73120(14) 0.0575(9) Uani 1 1 d . . .
H30A H 0.6577 -0.0334 0.7169 0.069 Uiso 1 1 calc R . .
H30B H 0.7265 0.0855 0.7187 0.069 Uiso 1 1 calc R . .
C13 C 1.0042(2) 0.7479(3) 0.62847(14) 0.0435(8) Uani 1 1 d . . .
C21 C 1.0950(2) 0.9332(3) 0.59735(15) 0.0464(8) Uani 1 1 d . . .
C35 C 0.8318(3) -0.0138(4) 0.83800(15) 0.0688(11) Uani 1 1 d . . .
H35 H 0.8878 -0.0142 0.8161 0.083 Uiso 1 1 calc R . .
C22 C 1.0363(2) 0.8252(3) 0.58184(14) 0.0476(8) Uani 1 1 d . . .
H22 H 1.0186 0.8056 0.5386 0.057 Uiso 1 1 calc R . .
C12 C 0.9377(2) 0.6391(3) 0.61009(16) 0.0493(8) Uani 1 1 d . . .
C24 C 0.7171(2) 0.1293(3) 0.55556(15) 0.0495(8) Uani 1 1 d . . .
H24 H 0.6627 0.0820 0.5389 0.059 Uiso 1 1 calc R . .
C25 C 0.7872(2) 0.0759(3) 0.60000(13) 0.0429(7) Uani 1 1 d . . .
C23 C 0.7276(2) 0.2519(3) 0.53594(15) 0.0544(9) Uani 1 1 d . . .
H23 H 0.6798 0.2848 0.5052 0.065 Uiso 1 1 calc R . .
C26 C 0.8664(3) 0.1518(3) 0.62112(15) 0.0555(9) Uani 1 1 d . . .
H26 H 0.9171 0.1193 0.6499 0.067 Uiso 1 1 calc R . .
C9 C 0.5313(3) 0.6800(4) 0.79229(18) 0.0662(10) Uani 1 1 d . . .
H9 H 0.5809 0.6227 0.8064 0.079 Uiso 1 1 calc R . .
C11 C 0.5789(2) 0.6704(3) 0.68107(16) 0.0520(9) Uani 1 1 d . . .
H11 H 0.6284 0.6123 0.6941 0.062 Uiso 1 1 calc R . .
C5 C 0.4425(3) 0.8021(3) 0.70610(19) 0.0583(9) Uani 1 1 d . . .
C3 C 0.4934(3) 0.7994(4) 0.59863(18) 0.0633(10) Uani 1 1 d . . .
C16 C 1.1227(2) 0.9617(3) 0.66319(15) 0.0487(8) Uani 1 1 d . . .
C29 C 0.7956(3) -0.0756(3) 0.69596(15) 0.0572(9) Uani 1 1 d . . .
H29A H 0.7910 -0.1650 0.7063 0.069 Uiso 1 1 calc R . .
H29B H 0.8620 -0.0476 0.7106 0.069 Uiso 1 1 calc R . .
C10 C 0.5187(2) 0.7161(3) 0.72739(17) 0.0517(8) Uani 1 1 d . . .
C14 C 1.0339(2) 0.7769(3) 0.69435(15) 0.0501(8) Uani 1 1 d . . .
O3 O 0.4840(2) 0.8447(3) 0.53724(13) 0.0915(9) Uani 1 1 d . . .
H3 H 0.5258 0.8119 0.5171 0.137 Uiso 1 1 calc R . .
C15 C 1.0907(2) 0.8814(3) 0.71053(15) 0.0550(9) Uani 1 1 d . . .
H15 H 1.1084 0.8997 0.7539 0.066 Uiso 1 1 calc R . .
O2 O 0.6309(2) 0.7079(3) 0.51625(13) 0.0881(9) Uani 1 1 d . . .
C2 C 0.5676(2) 0.7079(3) 0.61835(16) 0.0500(8) Uani 1 1 d . . .
C17 C 1.1802(3) 1.0713(3) 0.67828(19) 0.0635(10) Uani 1 1 d . . .
H17 H 1.1986 1.0924 0.7212 0.076 Uiso 1 1 calc R . .
C27 C 0.8713(2) 0.2750(3) 0.60015(15) 0.0553(9) Uani 1 1 d . . .
H27 H 0.9252 0.3242 0.6159 0.066 Uiso 1 1 calc R . .
C31 C 0.7388(2) -0.0104(3) 0.80404(14) 0.0485(8) Uani 1 1 d . . .
C19 C 1.1821(3) 1.1182(4) 0.5658(2) 0.0753(12) Uani 1 1 d . . .
H19 H 1.2027 1.1704 0.5338 0.090 Uiso 1 1 calc R . .
C18 C 1.2090(3) 1.1461(4) 0.6306(2) 0.0729(12) Uani 1 1 d . . .
H18 H 1.2474 1.2174 0.6415 0.088 Uiso 1 1 calc R . .
C6 C 0.3808(3) 0.8469(4) 0.7524(2) 0.0744(12) Uani 1 1 d . . .
H6A H 0.3290 0.9017 0.7395 0.089 Uiso 1 1 calc R . .
C28 C 0.7771(3) -0.0588(3) 0.62271(15) 0.0576(9) Uani 1 1 d . . .
H28A H 0.8234 -0.1117 0.6025 0.069 Uiso 1 1 calc R . .
H28B H 0.7111 -0.0886 0.6083 0.069 Uiso 1 1 calc R . .
C8 C 0.4721(3) 0.7274(4) 0.8352(2) 0.0769(12) Uani 1 1 d . . .
H8 H 0.4824 0.7038 0.8784 0.092 Uiso 1 1 calc R . .
C1 C 0.6332(3) 0.6574(4) 0.57059(19) 0.0597(9) Uani 1 1 d . . .
C4 C 0.4316(3) 0.8418(4) 0.6415(2) 0.0688(11) Uani 1 1 d . . .
H4 H 0.3813 0.8981 0.6275 0.083 Uiso 1 1 calc R . .
C7 C 0.3965(3) 0.8109(4) 0.8145(2) 0.0814(13) Uani 1 1 d . . .
H7 H 0.3561 0.8423 0.8441 0.098 Uiso 1 1 calc R . .
N2 N 0.76474(19) -0.0169(2) 0.93915(11) 0.0471(6) Uani 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Zn1 0.0541(2) 0.0447(2) 0.0423(2) 0.00130(17) 0.00580(16) -0.00557(19)
N1 0.0537(17) 0.0422(15) 0.0414(15) -0.0002(12) 0.0035(12) -0.0037(14)
O1 0.0742(18) 0.0630(17) 0.0834(18) 0.0100(14) 0.0324(14) 0.0160(15)
O6 0.085(2) 0.087(2) 0.0445(14) 0.0147(14) -0.0025(12) -0.0205(16)
O4 0.0623(15) 0.0607(15) 0.0460(13) -0.0059(11) -0.0011(11) -0.0153(12)
C34 0.052(2) 0.096(3) 0.049(2) 0.006(2) -0.0019(16) -0.020(2)
O5 0.0885(19) 0.0635(17) 0.0590(15) 0.0144(13) -0.0057(13) -0.0247(15)
C32 0.048(2) 0.064(2) 0.0464(18) 0.0074(17) -0.0013(15) 0.0175(18)
C33 0.052(2) 0.067(2) 0.054(2) 0.0037(18) 0.0114(16) 0.0140(19)
C20 0.071(2) 0.059(2) 0.059(2) 0.0023(19) 0.0142(18) -0.008(2)
C30 0.065(2) 0.063(2) 0.0444(18) 0.0122(17) 0.0024(16) 0.0058(19)
C13 0.0451(19) 0.0429(19) 0.0414(17) 0.0012(14) -0.0001(14) 0.0005(15)
C21 0.0463(19) 0.0433(19) 0.0499(19) -0.0017(15) 0.0066(15) 0.0025(16)
C35 0.053(2) 0.107(3) 0.047(2) 0.008(2) 0.0097(16) -0.021(2)
C22 0.055(2) 0.049(2) 0.0385(17) -0.0060(15) 0.0031(14) 0.0001(17)
C12 0.052(2) 0.0440(19) 0.051(2) 0.0025(16) 0.0009(16) 0.0020(17)
C24 0.048(2) 0.0429(19) 0.056(2) -0.0005(16) -0.0035(15) -0.0046(16)
C25 0.056(2) 0.0402(18) 0.0326(16) -0.0026(14) 0.0062(14) 0.0023(16)
C23 0.057(2) 0.047(2) 0.056(2) 0.0069(17) -0.0066(17) -0.0026(18)
C26 0.061(2) 0.052(2) 0.050(2) 0.0025(17) -0.0121(16) 0.0038(19)
C9 0.060(2) 0.065(3) 0.074(3) 0.002(2) 0.006(2) 0.000(2)
C11 0.0415(19) 0.0421(19) 0.071(2) 0.0029(17) 0.0022(16) 0.0029(16)
C5 0.052(2) 0.043(2) 0.079(3) -0.0064(19) 0.0069(19) -0.0021(18)
C3 0.064(3) 0.057(2) 0.065(2) 0.001(2) -0.0122(19) 0.002(2)
C16 0.0432(19) 0.046(2) 0.056(2) -0.0052(17) 0.0012(15) 0.0031(16)
C29 0.076(3) 0.045(2) 0.050(2) 0.0100(16) 0.0032(17) 0.0085(19)
C10 0.046(2) 0.0411(19) 0.068(2) -0.0041(17) 0.0070(16) -0.0043(16)
C14 0.052(2) 0.057(2) 0.0408(18) 0.0045(16) 0.0005(15) 0.0006(18)
O3 0.092(2) 0.109(3) 0.0689(18) 0.0121(18) -0.0114(15) 0.0226(19)
C15 0.055(2) 0.065(2) 0.0423(19) -0.0112(17) -0.0050(16) -0.0008(19)
O2 0.114(2) 0.089(2) 0.0627(17) 0.0010(16) 0.0134(16) 0.0164(18)
C2 0.046(2) 0.0403(19) 0.063(2) -0.0071(17) 0.0001(16) -0.0014(16)
C17 0.058(2) 0.050(2) 0.080(3) -0.016(2) -0.007(2) 0.0012(19)
C27 0.058(2) 0.055(2) 0.051(2) -0.0037(17) -0.0057(17) -0.0080(18)
C31 0.059(2) 0.0423(19) 0.0436(17) 0.0083(15) 0.0007(15) 0.0003(17)
C19 0.076(3) 0.061(3) 0.091(3) 0.012(2) 0.017(2) -0.013(2)
C18 0.062(3) 0.044(2) 0.111(4) -0.004(2) -0.001(2) -0.012(2)
C6 0.064(3) 0.052(2) 0.110(4) -0.009(2) 0.022(2) 0.009(2)
C28 0.080(3) 0.045(2) 0.0471(19) -0.0005(16) 0.0051(17) 0.0029(19)
C8 0.084(3) 0.079(3) 0.070(3) -0.006(2) 0.018(2) -0.011(3)
C1 0.061(2) 0.049(2) 0.068(3) -0.003(2) 0.0025(19) -0.0109(19)
C4 0.052(2) 0.061(3) 0.091(3) -0.004(2) -0.001(2) 0.017(2)
C7 0.084(3) 0.065(3) 0.101(4) -0.012(3) 0.041(3) -0.009(3)
N2 0.0523(17) 0.0463(16) 0.0428(14) 0.0013(12) 0.0060(12) -0.0011(14)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Zn1 O1 1.932(2) . ?
Zn1 O4 1.950(2) . ?
Zn1 N2 2.033(2) 4_565 ?
Zn1 N1 2.038(3) . ?
N1 C23 1.332(4) . ?
N1 C27 1.334(4) . ?
O1 C1 1.255(4) . ?
O6 C14 1.359(4) . ?
O4 C12 1.266(3) . ?
C34 N2 1.327(4) . ?
C34 C35 1.378(4) . ?
O5 C12 1.252(4) . ?
C32 C31 1.366(4) . ?
C32 C33 1.375(4) . ?
C33 N2 1.342(4) . ?
C20 C19 1.360(5) . ?
C20 C21 1.411(4) . ?
C30 C29 1.497(4) . ?
C30 C31 1.512(4) . ?
C13 C22 1.375(4) . ?
C13 C14 1.422(4) . ?
C13 C12 1.487(4) . ?
C21 C22 1.409(4) . ?
C21 C16 1.416(4) . ?
C35 C31 1.384(4) . ?
C24 C23 1.368(4) . ?
C24 C25 1.378(4) . ?
C25 C26 1.377(4) . ?
C25 C28 1.508(4) . ?
C26 C27 1.375(4) . ?
C9 C8 1.361(5) . ?
C9 C10 1.398(5) . ?
C11 C2 1.358(4) . ?
C11 C10 1.416(4) . ?
C5 C4 1.403(5) . ?
C5 C10 1.414(4) . ?
C5 C6 1.427(5) . ?
C3 O3 1.359(4) . ?
C3 C4 1.366(5) . ?
C3 C2 1.426(4) . ?
C16 C15 1.404(4) . ?
C16 C17 1.413(4) . ?
C29 C28 1.530(4) . ?
C14 C15 1.368(4) . ?
O2 C1 1.249(4) . ?
C2 C1 1.504(5) . ?
C17 C18 1.358(5) . ?
C19 C18 1.393(5) . ?
C6 C7 1.344(5) . ?
C8 C7 1.389(5) . ?
N2 Zn1 2.033(2) 4_566 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Zn1 O4 112.36(11) . . ?
O1 Zn1 N2 119.78(11) . 4_565 ?
O4 Zn1 N2 101.67(10) . 4_565 ?
O1 Zn1 N1 100.96(11) . . ?
O4 Zn1 N1 119.81(10) . . ?
N2 Zn1 N1 102.98(10) 4_565 . ?
C23 N1 C27 116.2(3) . . ?
C23 N1 Zn1 118.2(2) . . ?
C27 N1 Zn1 125.0(2) . . ?
C1 O1 Zn1 119.6(3) . . ?
C12 O4 Zn1 112.9(2) . . ?
N2 C34 C35 123.7(3) . . ?
C31 C32 C33 120.9(3) . . ?
N2 C33 C32 122.7(3) . . ?
C19 C20 C21 120.9(3) . . ?
C29 C30 C31 116.0(3) . . ?
C22 C13 C14 118.4(3) . . ?
C22 C13 C12 120.4(3) . . ?
C14 C13 C12 121.1(3) . . ?
C22 C21 C20 122.1(3) . . ?
C22 C21 C16 118.7(3) . . ?
C20 C21 C16 119.2(3) . . ?
C34 C35 C31 119.6(3) . . ?
C13 C22 C21 122.2(3) . . ?
O5 C12 O4 122.6(3) . . ?
O5 C12 C13 119.1(3) . . ?
O4 C12 C13 118.3(3) . . ?
C23 C24 C25 120.0(3) . . ?
C26 C25 C24 116.1(3) . . ?
C26 C25 C28 122.8(3) . . ?
C24 C25 C28 121.1(3) . . ?
N1 C23 C24 124.0(3) . . ?
C27 C26 C25 120.7(3) . . ?
C8 C9 C10 121.0(4) . . ?
C2 C11 C10 122.8(3) . . ?
C4 C5 C10 119.5(3) . . ?
C4 C5 C6 122.7(4) . . ?
C10 C5 C6 117.8(4) . . ?
O3 C3 C4 119.8(3) . . ?
O3 C3 C2 120.1(4) . . ?
C4 C3 C2 120.0(3) . . ?
C15 C16 C17 122.9(3) . . ?
C15 C16 C21 118.8(3) . . ?
C17 C16 C21 118.3(3) . . ?
C30 C29 C28 112.5(3) . . ?
C9 C10 C5 119.2(3) . . ?
C9 C10 C11 123.1(3) . . ?
C5 C10 C11 117.6(3) . . ?
O6 C14 C15 119.3(3) . . ?
O6 C14 C13 120.2(3) . . ?
C15 C14 C13 120.4(3) . . ?
C14 C15 C16 121.5(3) . . ?
C11 C2 C3 118.6(3) . . ?
C11 C2 C1 121.2(3) . . ?
C3 C2 C1 120.2(3) . . ?
C18 C17 C16 120.6(3) . . ?
N1 C27 C26 122.9(3) . . ?
C32 C31 C35 116.6(3) . . ?
C32 C31 C30 121.1(3) . . ?
C35 C31 C30 122.3(3) . . ?
C20 C19 C18 119.7(4) . . ?
C17 C18 C19 121.3(4) . . ?
C7 C6 C5 120.9(4) . . ?
C25 C28 C29 114.3(3) . . ?
C9 C8 C7 120.1(4) . . ?
O2 C1 O1 123.8(4) . . ?
O2 C1 C2 119.3(3) . . ?
O1 C1 C2 116.9(3) . . ?
C3 C4 C5 121.3(3) . . ?
C6 C7 C8 121.0(4) . . ?
C34 N2 C33 116.5(3) . . ?
C34 N2 Zn1 118.6(2) . 4_566 ?
C33 N2 Zn1 124.9(2) . 4_566 ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        25.50
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         0.263
_refine_diff_density_min         -0.365
_refine_diff_density_rms         0.049