# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C # This journal is © The Royal Society of Chemistry 2013 ####################################################################### # # Cambridge Crystallographic Data Centre # CCDC # ####################################################################### # # This CIF contains data from an original supplementary publication # deposited with the CCDC, and may include chemical, crystal, # experimental, refinement, atomic coordinates, # anisotropic displacement parameters and molecular geometry data, # as required by the journal to which it was submitted. # # This CIF is provided on the understanding that it is used for bona # fide research purposes only. It may contain copyright material # of the CCDC or of third parties, and may not be copied or further # disseminated in any form, whether machine-readable or not, # except for the purpose of generating routine backup copies # on your local computer system. # # For further information on the CCDC, data deposition and # data retrieval see: # www.ccdc.cam.ac.uk # # Bona fide researchers may freely download Mercury and enCIFer # from this site to visualise CIF-encoded structures and # to carry out CIF format checking respectively. # ####################################################################### data_a _database_code_depnum_ccdc_archive 'CCDC 932964' #TrackingRef '1Eu.cif' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C148 H112 Ag2 Cl2 Eu2 F36 N6 O22 P6 Pt' _chemical_formula_weight 3981.91 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting triclinic _symmetry_space_group_name_H-M p-1 loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 15.030(4) _cell_length_b 15.677(4) _cell_length_c 19.167(4) _cell_angle_alpha 91.365(3) _cell_angle_beta 93.191(3) _cell_angle_gamma 106.915(3) _cell_volume 4310.2(17) _cell_formula_units_Z 1 _cell_measurement_temperature 293(2) _cell_measurement_reflns_used ? _cell_measurement_theta_min ? _cell_measurement_theta_max ? _exptl_crystal_description ? _exptl_crystal_colour ? _exptl_crystal_size_max 0.22 _exptl_crystal_size_mid 0.20 _exptl_crystal_size_min 0.18 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.534 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1964 _exptl_absorpt_coefficient_mu 1.935 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.6542 _exptl_absorpt_correction_T_max 1.0000 _exptl_absorpt_process_details ? _exptl_special_details ; ? ; _diffrn_ambient_temperature 293(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Bruker P4' _diffrn_measurement_method '\w scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 32935 _diffrn_reflns_av_R_equivalents 0.0431 _diffrn_reflns_av_sigmaI/netI 0.0629 _diffrn_reflns_limit_h_min -17 _diffrn_reflns_limit_h_max 17 _diffrn_reflns_limit_k_min -14 _diffrn_reflns_limit_k_max 18 _diffrn_reflns_limit_l_min -22 _diffrn_reflns_limit_l_max 22 _diffrn_reflns_theta_min 3.20 _diffrn_reflns_theta_max 25.00 _reflns_number_total 14953 _reflns_number_gt 12106 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'Bruker XSCANS' _computing_cell_refinement 'Bruker XSCANS' _computing_data_reduction 'Bruker SHELXTL' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Bruker SHELXTL' _computing_publication_material 'Bruker SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; loop_ _platon_squeeze_void_nr _platon_squeeze_void_average_x _platon_squeeze_void_average_y _platon_squeeze_void_average_z _platon_squeeze_void_volume _platon_squeeze_void_count_electrons _platon_squeeze_void_content 1 0.144 0.733 0.055 115 18 ' ' 2 0.500 0.500 0.500 549 90 ' ' 3 0.855 0.267 0.945 115 18 ' ' _platon_squeeze_details ; ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0906P)^2^+0.6268P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 14953 _refine_ls_number_parameters 1079 _refine_ls_number_restraints 418 _refine_ls_R_factor_all 0.0716 _refine_ls_R_factor_gt 0.0592 _refine_ls_wR_factor_ref 0.1701 _refine_ls_wR_factor_gt 0.1587 _refine_ls_goodness_of_fit_ref 1.064 _refine_ls_restrained_S_all 1.143 _refine_ls_shift/su_max 0.020 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Pt1 Pt 0.0000 0.5000 0.5000 0.04510(12) Uani 1 2 d S . . Ag1 Ag -0.06091(5) 0.63445(4) 0.42300(3) 0.07178(19) Uani 1 1 d . . . O1 O 0.7462(5) 0.7599(4) 0.0794(3) 0.0875(17) Uani 1 1 d . . . O2 O 0.7404(4) 0.6813(4) -0.0513(3) 0.0871(17) Uani 1 1 d . . . O3 O 0.8052(4) 0.8726(4) -0.0557(3) 0.0897(18) Uani 1 1 d . . . O4 O 0.6515(4) 0.7739(4) -0.1459(3) 0.0860(18) Uani 1 1 d . . . O6 O 0.5004(5) 0.7896(5) -0.0609(3) 0.0917(19) Uani 1 1 d . . . O5 O 0.6506(5) 0.9345(5) -0.0650(4) 0.099(2) Uani 1 1 d . . . N1 N 0.5378(5) 0.6329(5) -0.0413(3) 0.0736(18) Uani 1 1 d . . . N2 N 0.5410(4) 0.7373(4) 0.0741(3) 0.0642(16) Uani 1 1 d . . . N3 N 0.6710(5) 0.8969(5) 0.0828(4) 0.0782(19) Uani 1 1 d . . . C1 C 0.1442(5) 0.7189(4) 0.5257(4) 0.0566(16) Uani 1 1 d . . . H1A H 0.1874 0.7076 0.4934 0.068 Uiso 1 1 calc R . . H1B H 0.1796 0.7650 0.5595 0.068 Uiso 1 1 calc R . . C2 C 0.1991(5) 0.5895(5) 0.6039(4) 0.0614(18) Uani 1 1 d . . . H2A H 0.2340 0.6358 0.6378 0.074 Uiso 1 1 calc R . . H2B H 0.2379 0.5897 0.5652 0.074 Uiso 1 1 calc R . . C3 C 0.1264(6) 0.8306(5) 0.4139(4) 0.0652(18) Uani 1 1 d U . . C4 C 0.0949(8) 0.8222(7) 0.3426(5) 0.093(3) Uani 1 1 d U . . H4A H 0.0385 0.7811 0.3275 0.112 Uiso 1 1 calc R . . C5 C 0.1485(11) 0.8754(8) 0.2967(6) 0.116(4) Uani 1 1 d U . . H5A H 0.1270 0.8709 0.2499 0.140 Uiso 1 1 calc R . . C6 C 0.2295(11) 0.9327(8) 0.3156(7) 0.121(4) Uani 1 1 d U . . H6A H 0.2641 0.9674 0.2822 0.145 Uiso 1 1 calc R . . C7 C 0.2634(9) 0.9422(7) 0.3837(7) 0.117(4) Uani 1 1 d U . . H7A H 0.3207 0.9835 0.3965 0.140 Uiso 1 1 calc R . . C8 C 0.2126(7) 0.8901(6) 0.4340(5) 0.088(3) Uani 1 1 d U . . H8A H 0.2361 0.8952 0.4803 0.106 Uiso 1 1 calc R . . C9 C 0.0213(6) 0.8349(5) 0.5338(4) 0.067(2) Uani 1 1 d . . . C10 C 0.0759(8) 0.8821(7) 0.5904(6) 0.099(3) Uani 1 1 d . . . H10A H 0.1350 0.8766 0.6017 0.119 Uiso 1 1 calc R . . C11 C 0.0397(11) 0.9385(9) 0.6303(7) 0.127(5) Uani 1 1 d . . . H11A H 0.0760 0.9686 0.6692 0.152 Uiso 1 1 calc R . . C12 C -0.0394(13) 0.9517(10) 0.6174(8) 0.133(5) Uani 1 1 d . . . H12A H -0.0576 0.9941 0.6430 0.159 Uiso 1 1 calc R . . C13 C -0.0939(12) 0.9029(12) 0.5663(10) 0.157(6) Uani 1 1 d . . . H13A H -0.1549 0.9051 0.5593 0.189 Uiso 1 1 calc R . . C14 C -0.0616(9) 0.8477(9) 0.5225(7) 0.119(4) Uani 1 1 d . . . H14A H -0.0996 0.8188 0.4838 0.142 Uiso 1 1 calc R . . C15 C 0.0471(6) 0.6601(5) 0.6458(4) 0.066(2) Uani 1 1 d . . . C16 C -0.0427(7) 0.6586(6) 0.6423(5) 0.085(3) Uani 1 1 d . . . H16A H -0.0826 0.6290 0.6049 0.103 Uiso 1 1 calc R . . C17 C -0.0765(10) 0.7019(7) 0.6956(8) 0.123(5) Uani 1 1 d . . . H17A H -0.1380 0.7034 0.6923 0.148 Uiso 1 1 calc R . . C18 C -0.0202(15) 0.7405(9) 0.7502(8) 0.147(7) Uani 1 1 d . . . H18A H -0.0426 0.7696 0.7850 0.176 Uiso 1 1 calc R . . C19 C 0.0699(13) 0.7384(8) 0.7564(6) 0.124(5) Uani 1 1 d . . . H19A H 0.1067 0.7622 0.7969 0.149 Uiso 1 1 calc R . . C20 C 0.1068(8) 0.7020(6) 0.7041(5) 0.092(3) Uani 1 1 d . . . H20A H 0.1695 0.7046 0.7067 0.111 Uiso 1 1 calc R . . C21 C -0.2903(6) 0.5324(6) 0.3393(4) 0.070(2) Uani 1 1 d . . . C22 C -0.2961(8) 0.6179(7) 0.3312(6) 0.099(3) Uani 1 1 d . . . H22A H -0.2417 0.6653 0.3326 0.119 Uiso 1 1 calc R . . C23 C -0.3824(10) 0.6347(10) 0.3209(7) 0.123(4) Uani 1 1 d . . . H23A H -0.3861 0.6926 0.3165 0.147 Uiso 1 1 calc R . . C24 C -0.4632(9) 0.5614(12) 0.3174(6) 0.116(4) Uani 1 1 d . . . H24A H -0.5214 0.5700 0.3086 0.140 Uiso 1 1 calc R . . C25 C -0.4565(7) 0.4810(10) 0.3265(5) 0.107(4) Uani 1 1 d . . . H25A H -0.5114 0.4344 0.3269 0.128 Uiso 1 1 calc R . . C26 C -0.3734(7) 0.4612(7) 0.3356(5) 0.091(3) Uani 1 1 d . . . H26A H -0.3721 0.4025 0.3392 0.109 Uiso 1 1 calc R . . C27 C -0.1360(6) 0.5046(6) 0.2687(4) 0.071(2) Uani 1 1 d . . . C28 C -0.1964(7) 0.4641(7) 0.2123(5) 0.096(3) Uani 1 1 d . . . H28A H -0.2601 0.4435 0.2177 0.115 Uiso 1 1 calc R . . C29 C -0.1630(9) 0.4543(9) 0.1494(5) 0.110(4) Uani 1 1 d . . . H29A H -0.2036 0.4241 0.1124 0.132 Uiso 1 1 calc R . . C30 C -0.0679(9) 0.4894(10) 0.1397(6) 0.120(4) Uani 1 1 d . . . H30A H -0.0458 0.4855 0.0957 0.144 Uiso 1 1 calc R . . C31 C -0.0084(9) 0.5287(10) 0.1941(6) 0.121(4) Uani 1 1 d . . . H31A H 0.0552 0.5499 0.1881 0.145 Uiso 1 1 calc R . . C32 C -0.0420(7) 0.5379(8) 0.2595(5) 0.095(3) Uani 1 1 d . . . H32A H -0.0011 0.5663 0.2968 0.114 Uiso 1 1 calc R . . C33 C 0.0937(5) 0.5426(5) 0.4285(4) 0.0552(16) Uani 1 1 d . . . C34 C 0.1497(5) 0.5705(5) 0.3867(4) 0.0594(18) Uani 1 1 d . . . C35 C 0.2160(5) 0.5986(5) 0.3332(4) 0.0597(17) Uani 1 1 d . . . C36 C 0.2370(6) 0.5368(5) 0.2881(4) 0.073(2) Uani 1 1 d . . . H36A H 0.2074 0.4761 0.2913 0.088 Uiso 1 1 calc R . . C37 C 0.3012(6) 0.5653(5) 0.2393(4) 0.072(2) Uani 1 1 d . . . H37A H 0.3151 0.5229 0.2106 0.087 Uiso 1 1 calc R . . C38 C 0.3457(5) 0.6535(5) 0.2310(4) 0.0590(17) Uani 1 1 d . . . C39 C 0.3245(6) 0.7143(5) 0.2759(5) 0.080(3) Uani 1 1 d . . . H39A H 0.3533 0.7748 0.2714 0.096 Uiso 1 1 calc R . . C40 C 0.2628(6) 0.6887(6) 0.3264(4) 0.078(2) Uani 1 1 d . . . H40A H 0.2520 0.7315 0.3565 0.094 Uiso 1 1 calc R . . C41 C 0.5321(8) 0.5856(7) -0.1031(4) 0.086(3) Uani 1 1 d . . . H41A H 0.5825 0.6015 -0.1310 0.103 Uiso 1 1 calc R . . C42 C 0.4573(8) 0.5170(7) -0.1262(4) 0.087(3) Uani 1 1 d . . . H42A H 0.4567 0.4861 -0.1683 0.104 Uiso 1 1 calc R . . C43 C 0.3839(7) 0.4950(7) -0.0861(4) 0.089(3) Uani 1 1 d . . . H43A H 0.3318 0.4480 -0.1009 0.107 Uiso 1 1 calc R . . C44 C 0.3845(6) 0.5400(6) -0.0247(4) 0.079(2) Uani 1 1 d . . . H44A H 0.3329 0.5252 0.0021 0.095 Uiso 1 1 calc R . . C45 C 0.4637(6) 0.6086(6) -0.0026(4) 0.066(2) Uani 1 1 d . . . C46 C 0.4705(5) 0.6618(5) 0.0644(4) 0.0601(18) Uani 1 1 d . . . C47 C 0.4068(5) 0.6337(5) 0.1155(4) 0.0634(19) Uani 1 1 d . . . H47A H 0.3595 0.5802 0.1080 0.076 Uiso 1 1 calc R . . C48 C 0.4123(5) 0.6831(5) 0.1766(4) 0.0611(18) Uani 1 1 d . . . C49 C 0.4878(5) 0.7612(5) 0.1858(4) 0.0623(18) Uani 1 1 d . . . H49A H 0.4962 0.7955 0.2272 0.075 Uiso 1 1 calc R . . C50 C 0.5497(5) 0.7878(5) 0.1344(4) 0.0622(18) Uani 1 1 d . . . C51 C 0.6268(6) 0.8717(5) 0.1411(4) 0.069(2) Uani 1 1 d . . . C52 C 0.6532(7) 0.9205(7) 0.2036(5) 0.094(3) Uani 1 1 d . . . H52A H 0.6210 0.9019 0.2432 0.113 Uiso 1 1 calc R . . C53 C 0.7283(8) 0.9978(8) 0.2069(6) 0.104(3) Uani 1 1 d . . . H53A H 0.7466 1.0313 0.2487 0.125 Uiso 1 1 calc R . . C54 C 0.7756(8) 1.0241(8) 0.1469(7) 0.112(4) Uani 1 1 d . . . H54A H 0.8260 1.0753 0.1472 0.134 Uiso 1 1 calc R . . C55 C 0.7449(7) 0.9721(6) 0.0883(6) 0.098(3) Uani 1 1 d . . . H55A H 0.7768 0.9890 0.0483 0.117 Uiso 1 1 calc R . . C56 C 0.8634(7) 0.7564(7) 0.1613(6) 0.115(3) Uani 1 1 d DU . . C57 C 0.8171(7) 0.7362(6) 0.0894(5) 0.082(2) Uani 1 1 d . C . C58 C 0.8550(7) 0.6923(7) 0.0404(6) 0.093(3) Uani 1 1 d . . . H58A H 0.9105 0.6799 0.0525 0.112 Uiso 1 1 calc R C . C59 C 0.8133(7) 0.6671(7) -0.0246(6) 0.087(3) Uani 1 1 d . A . C60 C 0.8539(6) 0.6114(7) -0.0737(6) 0.119(3) Uani 1 1 d DU . . F4 F 0.7941(9) 0.5309(8) -0.0876(9) 0.132(4) Uani 0.50 1 d PDU A 1 F5 F 0.8735(13) 0.6488(11) -0.1323(8) 0.152(4) Uani 0.50 1 d PDU A 1 F6 F 0.9283(10) 0.5942(12) -0.0444(8) 0.140(4) Uani 0.50 1 d PDU A 1 F4' F 0.9422(8) 0.6540(11) -0.0840(8) 0.138(4) Uani 0.50 1 d PDU A 2 F5' F 0.8483(13) 0.5337(9) -0.0508(9) 0.148(4) Uani 0.50 1 d PDU A 2 F6' F 0.8148(11) 0.6026(12) -0.1390(6) 0.143(4) Uani 0.50 1 d PDU A 2 C61 C 0.9346(9) 0.9536(7) -0.1112(5) 0.126(4) Uani 1 1 d DU . . C62 C 0.8354(7) 0.8929(6) -0.1154(5) 0.083(3) Uani 1 1 d U . . C63 C 0.7943(7) 0.8652(7) -0.1805(5) 0.096(3) Uani 1 1 d . . . H63A H 0.8268 0.8877 -0.2192 0.115 Uiso 1 1 calc R . . C64 C 0.7066(8) 0.8052(7) -0.1914(5) 0.096(3) Uani 1 1 d . . . C65 C 0.6720(10) 0.7704(12) -0.2659(6) 0.125(4) Uani 1 1 d U . . C66 C 0.6257(11) 1.0550(9) -0.1261(9) 0.122(4) Uani 1 1 d U . . C67 C 0.5926(9) 0.9574(8) -0.1029(7) 0.108(3) Uani 1 1 d U . . C68 C 0.5017(10) 0.9111(9) -0.1265(8) 0.134(3) Uani 1 1 d U . . H68A H 0.4679 0.9365 -0.1574 0.161 Uiso 1 1 calc R . . C69 C 0.4635(9) 0.8281(8) -0.1035(7) 0.130(4) Uani 1 1 d DU B . C70 C 0.3634(10) 0.7795(8) -0.1281(6) 0.147(4) Uani 1 1 d DU . . F16 F 0.3513(14) 0.6954(8) -0.1433(12) 0.195(7) Uani 0.50 1 d PDU B 1 F17 F 0.3355(12) 0.8127(12) -0.1843(8) 0.163(6) Uani 0.50 1 d PDU B 1 F18 F 0.3077(11) 0.7864(16) -0.0793(10) 0.208(7) Uani 0.50 1 d PDU B 1 F16' F 0.3154(12) 0.8300(13) -0.1509(12) 0.202(7) Uani 0.50 1 d PDU B 2 F17' F 0.3180(10) 0.7332(12) -0.0772(9) 0.168(6) Uani 0.50 1 d PDU B 2 F18' F 0.3624(13) 0.7203(11) -0.1787(9) 0.185(6) Uani 0.50 1 d PDU B 2 Eu1 Eu 0.65430(3) 0.78971(3) -0.02193(2) 0.07078(16) Uani 1 1 d . . . P1 P 0.05799(14) 0.76053(12) 0.47665(10) 0.0575(4) Uani 1 1 d . . . P2 P 0.09412(12) 0.61700(12) 0.57175(9) 0.0514(4) Uani 1 1 d . . . P3 P -0.17589(14) 0.51919(13) 0.35507(10) 0.0612(5) Uani 1 1 d . . . F1 F 0.9539(10) 0.771(2) 0.1619(16) 0.175(10) Uani 0.50 1 d PDU C 1 F2 F 0.849(2) 0.8242(15) 0.1941(14) 0.180(12) Uani 0.50 1 d PDU C 1 F3 F 0.830(2) 0.6871(16) 0.1988(17) 0.193(11) Uani 0.50 1 d PDU C 1 F1' F 0.8970(19) 0.8419(9) 0.1756(17) 0.160(9) Uani 0.50 1 d PDU C 2 F2' F 0.9310(16) 0.7214(19) 0.1761(19) 0.188(11) Uani 0.50 1 d PDU C 2 F3' F 0.7999(16) 0.7253(19) 0.2061(13) 0.191(11) Uani 0.50 1 d PDU C 2 F7 F 0.9925(6) 0.9173(9) -0.0804(7) 0.234(5) Uani 1 1 d DU . . F8 F 0.9445(9) 1.0272(7) -0.0750(7) 0.252(6) Uani 1 1 d DU . . F9 F 0.9677(6) 0.9760(7) -0.1713(4) 0.222(5) Uani 1 1 d DU . . F10 F 0.5859(7) 0.7547(11) -0.2824(4) 0.237(6) Uani 1 1 d U . . F11 F 0.7199(9) 0.8115(8) -0.3140(4) 0.236(6) Uani 1 1 d U . . F12 F 0.6756(7) 0.6888(7) -0.2748(5) 0.171(3) Uani 1 1 d U . . F13 F 0.7168(8) 1.0767(7) -0.1385(7) 0.210(5) Uani 1 1 d . . . F14 F 0.5901(8) 1.0712(6) -0.1856(6) 0.210(5) Uani 1 1 d . . . F15 F 0.6165(10) 1.1105(6) -0.0813(6) 0.217(6) Uani 1 1 d . . . Cl1 Cl -0.3768(3) 1.1425(3) 0.3604(2) 0.1220(15) Uani 0.588(8) 1 d PD D 1 O7 O -0.3570(9) 1.2316(7) 0.3338(7) 0.133(5) Uani 0.588(8) 1 d PDU D 1 O8 O -0.4511(8) 1.0781(8) 0.3151(6) 0.124(5) Uani 0.588(8) 1 d PDU D 1 O9 O -0.3017(7) 1.1139(8) 0.3817(6) 0.106(4) Uani 0.588(8) 1 d PDU D 1 O10 O -0.4300(7) 1.1516(7) 0.4315(5) 0.267(4) Uani 0.588(8) 1 d PDU D 1 Cl1' Cl -0.4300(7) 1.1516(7) 0.4315(5) 0.267(4) Uani 0.412(8) 1 d PD D 2 O7' O -0.4522(17) 1.0647(12) 0.4621(10) 0.221(8) Uani 0.412(8) 1 d PDU D 2 O8' O -0.5163(10) 1.1716(16) 0.4117(10) 0.163(6) Uani 0.412(8) 1 d PDU D 2 O9' O -0.3705(13) 1.2206(14) 0.4768(8) 0.171(7) Uani 0.412(8) 1 d PDU D 2 O10' O -0.3768(3) 1.1425(3) 0.3604(2) 0.1220(15) Uani 0.412(8) 1 d PDU D 2 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Pt1 0.0455(2) 0.0446(2) 0.0494(2) 0.01108(14) 0.02084(14) 0.01597(14) Ag1 0.0780(4) 0.0526(3) 0.0832(4) 0.0102(3) -0.0058(3) 0.0181(3) O1 0.097(5) 0.103(5) 0.077(4) 0.018(3) 0.030(3) 0.047(4) O2 0.079(4) 0.105(5) 0.088(4) 0.010(3) 0.030(3) 0.039(4) O3 0.083(4) 0.103(5) 0.087(4) 0.020(3) 0.037(3) 0.028(3) O4 0.075(4) 0.111(5) 0.074(4) 0.028(3) 0.034(3) 0.023(3) O6 0.098(5) 0.104(5) 0.090(4) 0.042(4) 0.029(3) 0.049(4) O5 0.096(5) 0.102(5) 0.119(5) 0.049(4) 0.044(4) 0.048(4) N1 0.087(5) 0.078(5) 0.066(4) 0.017(3) 0.037(3) 0.033(4) N2 0.067(4) 0.069(4) 0.063(4) 0.021(3) 0.031(3) 0.022(3) N3 0.076(4) 0.066(4) 0.096(5) 0.019(4) 0.044(4) 0.018(3) C1 0.064(4) 0.045(4) 0.062(4) 0.002(3) 0.018(3) 0.014(3) C2 0.062(4) 0.056(4) 0.068(4) 0.009(3) 0.013(3) 0.018(3) C3 0.085(5) 0.054(4) 0.066(4) 0.016(3) 0.028(4) 0.030(3) C4 0.121(8) 0.086(7) 0.081(5) 0.012(5) 0.028(5) 0.038(5) C5 0.185(11) 0.106(9) 0.076(6) 0.031(6) 0.042(6) 0.062(7) C6 0.169(11) 0.086(7) 0.118(7) 0.032(7) 0.078(8) 0.038(6) C7 0.126(9) 0.079(7) 0.139(8) 0.028(6) 0.058(7) 0.009(6) C8 0.097(6) 0.071(6) 0.097(6) 0.020(5) 0.028(5) 0.021(4) C9 0.074(5) 0.060(5) 0.076(5) 0.011(4) 0.021(4) 0.029(4) C10 0.102(8) 0.082(6) 0.117(8) -0.016(6) 0.018(6) 0.034(6) C11 0.140(12) 0.107(9) 0.139(11) -0.054(8) 0.020(9) 0.045(8) C12 0.162(14) 0.116(11) 0.149(12) -0.017(9) 0.026(10) 0.085(11) C13 0.127(12) 0.163(14) 0.212(17) -0.030(13) 0.024(12) 0.091(11) C14 0.108(9) 0.134(10) 0.134(10) -0.027(8) 0.007(7) 0.068(8) C15 0.090(6) 0.052(4) 0.063(4) 0.004(3) 0.025(4) 0.027(4) C16 0.099(7) 0.069(5) 0.098(6) 0.009(5) 0.052(5) 0.031(5) C17 0.143(11) 0.078(7) 0.158(11) -0.010(7) 0.098(9) 0.034(7) C18 0.236(19) 0.093(9) 0.127(11) -0.007(8) 0.114(12) 0.055(11) C19 0.213(16) 0.099(8) 0.070(6) -0.022(5) 0.037(8) 0.057(10) C20 0.124(9) 0.078(6) 0.071(6) -0.013(5) 0.018(5) 0.025(6) C21 0.065(5) 0.080(6) 0.065(5) 0.006(4) 0.004(4) 0.024(4) C22 0.096(7) 0.084(7) 0.133(9) 0.014(6) -0.005(6) 0.052(6) C23 0.129(11) 0.131(11) 0.136(10) 0.014(8) -0.013(8) 0.085(9) C24 0.097(9) 0.179(14) 0.100(8) -0.005(9) 0.003(6) 0.085(10) C25 0.059(6) 0.171(12) 0.085(7) 0.001(7) -0.005(5) 0.028(7) C26 0.075(6) 0.102(7) 0.098(7) 0.011(5) -0.001(5) 0.032(5) C27 0.072(5) 0.085(6) 0.069(5) 0.011(4) 0.007(4) 0.041(4) C28 0.085(7) 0.104(8) 0.092(7) -0.014(6) 0.001(5) 0.022(6) C29 0.108(9) 0.166(11) 0.062(6) -0.017(6) 0.002(5) 0.053(8) C30 0.121(10) 0.199(14) 0.074(7) 0.007(7) 0.025(6) 0.095(10) C31 0.094(8) 0.188(13) 0.097(8) 0.023(8) 0.032(6) 0.061(8) C32 0.086(7) 0.136(9) 0.074(6) 0.031(6) 0.026(5) 0.044(6) C33 0.053(4) 0.054(4) 0.059(4) 0.003(3) 0.019(3) 0.014(3) C34 0.061(4) 0.065(4) 0.054(4) 0.011(3) 0.023(3) 0.017(3) C35 0.059(4) 0.069(5) 0.053(4) 0.008(3) 0.026(3) 0.019(3) C36 0.082(5) 0.064(5) 0.069(5) 0.004(4) 0.040(4) 0.008(4) C37 0.084(6) 0.065(5) 0.071(5) 0.001(4) 0.040(4) 0.022(4) C38 0.064(4) 0.060(4) 0.057(4) 0.013(3) 0.024(3) 0.020(3) C39 0.102(6) 0.051(4) 0.093(6) 0.018(4) 0.057(5) 0.022(4) C40 0.088(6) 0.067(5) 0.082(5) 0.005(4) 0.047(5) 0.020(4) C41 0.120(8) 0.094(7) 0.057(5) 0.014(5) 0.041(5) 0.046(6) C42 0.122(8) 0.093(7) 0.053(5) 0.003(4) 0.014(5) 0.043(6) C43 0.102(7) 0.105(7) 0.057(5) 0.005(5) 0.012(5) 0.022(6) C44 0.076(6) 0.093(6) 0.067(5) 0.006(4) 0.021(4) 0.020(5) C45 0.075(5) 0.079(5) 0.055(4) 0.025(4) 0.030(4) 0.033(4) C46 0.062(4) 0.074(5) 0.052(4) 0.020(3) 0.026(3) 0.028(4) C47 0.065(4) 0.068(5) 0.061(4) 0.015(4) 0.022(3) 0.020(4) C48 0.062(4) 0.070(5) 0.059(4) 0.016(3) 0.029(3) 0.026(4) C49 0.066(4) 0.062(4) 0.062(4) 0.011(3) 0.024(3) 0.019(4) C50 0.061(4) 0.069(5) 0.064(4) 0.019(4) 0.026(3) 0.026(4) C51 0.075(5) 0.066(5) 0.071(5) 0.013(4) 0.032(4) 0.020(4) C52 0.088(7) 0.093(7) 0.089(6) -0.001(5) 0.029(5) 0.004(5) C53 0.101(8) 0.106(8) 0.089(7) -0.004(6) 0.019(6) 0.003(6) C54 0.091(7) 0.097(8) 0.129(9) -0.003(7) 0.036(7) -0.006(6) C55 0.089(7) 0.069(6) 0.129(9) 0.010(6) 0.053(6) 0.004(5) C56 0.122(8) 0.123(8) 0.111(9) 0.005(6) -0.003(7) 0.056(7) C57 0.076(6) 0.080(6) 0.093(6) 0.012(5) 0.021(5) 0.026(5) C58 0.072(6) 0.104(8) 0.110(8) -0.012(6) 0.013(5) 0.035(5) C59 0.067(6) 0.086(6) 0.115(8) 0.013(6) 0.035(5) 0.025(5) C60 0.094(6) 0.131(7) 0.141(7) -0.009(6) 0.044(5) 0.044(5) F4 0.112(8) 0.130(7) 0.157(9) -0.032(6) 0.033(7) 0.038(6) F5 0.146(8) 0.169(8) 0.144(7) -0.005(6) 0.064(6) 0.042(6) F6 0.107(7) 0.151(10) 0.181(9) -0.046(7) 0.021(7) 0.068(6) F4' 0.099(6) 0.174(9) 0.141(9) -0.031(7) 0.065(6) 0.033(7) F5' 0.141(10) 0.122(7) 0.193(10) -0.019(7) 0.050(8) 0.054(7) F6' 0.128(8) 0.156(9) 0.143(7) -0.046(6) 0.034(6) 0.037(7) C61 0.124(8) 0.119(8) 0.119(9) 0.017(6) 0.061(7) 0.002(7) C62 0.080(6) 0.087(6) 0.082(6) 0.020(5) 0.037(5) 0.018(5) C63 0.088(7) 0.112(8) 0.082(6) 0.024(6) 0.043(5) 0.012(6) C64 0.104(8) 0.105(8) 0.085(7) 0.019(6) 0.022(6) 0.033(6) C65 0.124(8) 0.192(11) 0.065(6) 0.014(8) 0.031(6) 0.051(10) C66 0.125(8) 0.097(7) 0.143(9) 0.037(7) 0.001(7) 0.031(6) C67 0.109(6) 0.091(6) 0.125(7) 0.035(5) 0.003(6) 0.030(5) C68 0.125(7) 0.112(6) 0.165(8) 0.042(6) -0.004(6) 0.031(5) C69 0.115(7) 0.109(7) 0.160(8) 0.046(6) 0.009(6) 0.020(5) C70 0.117(7) 0.138(8) 0.188(10) 0.049(7) 0.000(7) 0.038(6) F16 0.179(12) 0.134(9) 0.255(17) 0.032(10) -0.027(13) 0.023(10) F17 0.143(11) 0.166(11) 0.195(11) 0.010(10) -0.027(10) 0.077(9) F18 0.132(11) 0.247(16) 0.245(13) 0.039(13) 0.038(10) 0.047(12) F16' 0.138(11) 0.217(13) 0.261(16) 0.061(11) -0.025(12) 0.074(9) F17' 0.098(9) 0.150(13) 0.259(13) 0.054(10) 0.041(9) 0.032(9) F18' 0.181(12) 0.152(12) 0.198(13) 0.024(10) -0.029(11) 0.016(10) Eu1 0.0754(3) 0.0803(3) 0.0677(3) 0.0274(2) 0.0390(2) 0.0318(2) P1 0.0648(11) 0.0461(10) 0.0654(11) 0.0075(8) 0.0142(8) 0.0200(8) P2 0.0545(10) 0.0505(10) 0.0534(9) 0.0098(7) 0.0191(7) 0.0185(8) P3 0.0644(12) 0.0580(11) 0.0643(11) 0.0081(9) 0.0062(9) 0.0220(9) F1 0.122(9) 0.26(3) 0.146(18) -0.03(2) -0.040(10) 0.076(13) F2 0.22(3) 0.218(17) 0.13(2) -0.071(17) -0.076(18) 0.144(19) F3 0.24(2) 0.215(18) 0.138(18) 0.092(16) 0.011(17) 0.088(18) F1' 0.18(2) 0.126(9) 0.162(18) -0.016(11) -0.005(16) 0.041(10) F2' 0.22(2) 0.20(2) 0.17(2) -0.012(18) -0.080(18) 0.14(2) F3' 0.211(19) 0.25(3) 0.092(11) 0.053(19) 0.024(12) 0.025(18) F7 0.079(5) 0.320(13) 0.305(13) 0.072(11) 0.029(7) 0.053(7) F8 0.223(11) 0.162(8) 0.312(13) -0.098(9) 0.080(10) -0.042(7) F9 0.155(7) 0.289(12) 0.132(6) 0.011(6) 0.062(5) -0.086(7) F10 0.158(7) 0.48(2) 0.107(6) -0.021(8) -0.021(5) 0.154(10) F11 0.286(11) 0.247(10) 0.097(5) 0.042(6) 0.031(6) -0.049(10) F12 0.187(8) 0.165(7) 0.145(7) -0.034(6) 0.002(6) 0.034(6) F13 0.173(9) 0.153(8) 0.300(14) 0.105(9) 0.047(9) 0.030(7) F14 0.242(12) 0.145(8) 0.220(11) 0.085(8) -0.016(9) 0.022(7) F15 0.354(17) 0.104(6) 0.202(10) 0.003(6) 0.086(10) 0.068(8) Cl1 0.114(3) 0.113(3) 0.115(3) -0.015(2) 0.013(2) -0.005(2) O7 0.141(9) 0.082(7) 0.138(9) 0.006(7) 0.018(8) -0.030(7) O8 0.116(8) 0.112(8) 0.111(8) -0.023(6) -0.038(6) -0.007(7) O9 0.078(7) 0.119(8) 0.117(8) -0.021(6) -0.013(6) 0.030(6) O10 0.254(8) 0.298(9) 0.214(7) -0.007(6) 0.027(6) 0.026(7) Cl1' 0.254(8) 0.298(9) 0.214(7) -0.007(6) 0.027(6) 0.026(7) O7' 0.238(14) 0.237(15) 0.142(12) 0.073(11) 0.083(11) -0.018(13) O8' 0.059(9) 0.280(14) 0.180(12) 0.034(12) 0.018(9) 0.092(10) O9' 0.166(13) 0.230(14) 0.102(10) -0.074(10) 0.027(10) 0.038(12) O10' 0.114(3) 0.113(3) 0.115(3) -0.015(2) 0.013(2) -0.005(2) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Pt1 C33 2.005(6) 2_566 ? Pt1 C33 2.005(6) . ? Pt1 P2 2.3260(19) . ? Pt1 P2 2.3260(19) 2_566 ? Pt1 Ag1 2.9291(7) 2_566 ? Pt1 Ag1 2.9291(8) . ? Ag1 P3 2.402(2) . ? Ag1 P1 2.409(2) . ? O1 C57 1.234(10) . ? O1 Eu1 2.452(6) . ? O2 C59 1.264(11) . ? O2 Eu1 2.489(6) . ? O3 C62 1.267(10) . ? O3 Eu1 2.396(6) . ? O4 C64 1.244(11) . ? O4 Eu1 2.381(6) . ? O6 C69 1.227(12) . ? O6 Eu1 2.390(7) . ? O5 C67 1.241(12) . ? O5 Eu1 2.449(6) . ? N1 C45 1.340(9) . ? N1 C41 1.368(11) . ? N1 Eu1 2.574(7) . ? N2 C46 1.340(10) . ? N2 C50 1.363(10) . ? N2 Eu1 2.564(5) . ? N3 C51 1.340(9) . ? N3 C55 1.361(11) . ? N3 Eu1 2.540(8) . ? C1 P2 1.827(7) . ? C1 P1 1.837(7) . ? C2 P2 1.831(7) . ? C2 P3 1.842(7) 2_566 ? C3 C8 1.386(13) . ? C3 C4 1.411(12) . ? C3 P1 1.804(7) . ? C4 C5 1.358(14) . ? C5 C6 1.311(17) . ? C6 C7 1.363(17) . ? C7 C8 1.391(13) . ? C9 C14 1.326(13) . ? C9 C10 1.381(13) . ? C9 P1 1.801(8) . ? C10 C11 1.398(14) . ? C11 C12 1.277(18) . ? C12 C13 1.314(19) . ? C13 C14 1.395(17) . ? C15 C16 1.341(12) . ? C15 C20 1.412(13) . ? C15 P2 1.821(8) . ? C16 C17 1.409(13) . ? C17 C18 1.32(2) . ? C18 C19 1.36(2) . ? C19 C20 1.363(14) . ? C21 C22 1.381(12) . ? C21 C26 1.409(12) . ? C21 P3 1.801(8) . ? C22 C23 1.401(14) . ? C23 C24 1.406(18) . ? C24 C25 1.308(17) . ? C25 C26 1.375(14) . ? C27 C32 1.380(12) . ? C27 C28 1.383(12) . ? C27 P3 1.824(9) . ? C28 C29 1.354(14) . ? C29 C30 1.399(16) . ? C30 C31 1.346(16) . ? C31 C32 1.397(14) . ? C33 C34 1.191(9) . ? C34 C35 1.456(9) . ? C35 C40 1.396(11) . ? C35 C36 1.399(11) . ? C36 C37 1.368(10) . ? C37 C38 1.367(10) . ? C38 C39 1.384(10) . ? C38 C48 1.475(9) . ? C39 C40 1.363(10) . ? C41 C42 1.354(14) . ? C42 C43 1.345(13) . ? C43 C44 1.357(12) . ? C44 C45 1.390(12) . ? C45 C46 1.497(11) . ? C46 C47 1.397(9) . ? C47 C48 1.374(11) . ? C48 C49 1.406(10) . ? C49 C50 1.380(9) . ? C50 C51 1.476(11) . ? C51 C52 1.380(12) . ? C52 C53 1.391(13) . ? C53 C54 1.394(14) . ? C54 C55 1.349(15) . ? C56 F2 1.301(10) . ? C56 F1' 1.304(10) . ? C56 F3 1.307(10) . ? C56 F2' 1.309(10) . ? C56 F1 1.311(10) . ? C56 F3' 1.312(10) . ? C56 C57 1.493(15) . ? C57 C58 1.392(13) . ? C58 C59 1.358(14) . ? C59 C60 1.535(14) . ? C60 F5' 1.286(9) . ? C60 F5 1.288(9) . ? C60 F6 1.324(9) . ? C60 F4' 1.329(9) . ? C60 F4 1.330(9) . ? C60 F6' 1.339(9) . ? C61 F7 1.295(9) . ? C61 F9 1.295(8) . ? C61 F8 1.299(9) . ? C61 C62 1.515(14) . ? C62 C63 1.364(14) . ? C63 C64 1.381(14) . ? C64 C65 1.525(16) . ? C65 F10 1.264(15) . ? C65 F11 1.271(14) . ? C65 F12 1.304(17) . ? C66 F15 1.249(17) . ? C66 F14 1.294(15) . ? C66 F13 1.348(16) . ? C66 C67 1.549(16) . ? C67 C68 1.391(16) . ? C68 C69 1.355(15) . ? C69 C70 1.518(18) . ? C70 F16' 1.286(9) . ? C70 F16 1.300(10) . ? C70 F17 1.308(9) . ? C70 F18 1.313(10) . ? C70 F18' 1.322(10) . ? C70 F17' 1.328(9) . ? P3 C2 1.842(7) 2_566 ? Cl1 O9 1.376(9) . ? Cl1 O7 1.452(10) . ? Cl1 O8 1.488(9) . ? Cl1 O10 1.642(9) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C33 Pt1 C33 180.000(1) 2_566 . ? C33 Pt1 P2 94.2(2) 2_566 . ? C33 Pt1 P2 85.8(2) . . ? C33 Pt1 P2 85.8(2) 2_566 2_566 ? C33 Pt1 P2 94.2(2) . 2_566 ? P2 Pt1 P2 180.000(1) . 2_566 ? C33 Pt1 Ag1 74.2(2) 2_566 2_566 ? C33 Pt1 Ag1 105.8(2) . 2_566 ? P2 Pt1 Ag1 92.90(5) . 2_566 ? P2 Pt1 Ag1 87.10(5) 2_566 2_566 ? C33 Pt1 Ag1 105.8(2) 2_566 . ? C33 Pt1 Ag1 74.2(2) . . ? P2 Pt1 Ag1 87.10(5) . . ? P2 Pt1 Ag1 92.90(5) 2_566 . ? Ag1 Pt1 Ag1 180.00(2) 2_566 . ? P3 Ag1 P1 172.26(7) . . ? P3 Ag1 Pt1 90.54(5) . . ? P1 Ag1 Pt1 95.37(5) . . ? C57 O1 Eu1 136.7(6) . . ? C59 O2 Eu1 133.1(7) . . ? C62 O3 Eu1 131.2(6) . . ? C64 O4 Eu1 135.4(7) . . ? C69 O6 Eu1 138.0(7) . . ? C67 O5 Eu1 132.4(7) . . ? C45 N1 C41 116.5(8) . . ? C45 N1 Eu1 119.7(6) . . ? C41 N1 Eu1 120.4(6) . . ? C46 N2 C50 119.4(6) . . ? C46 N2 Eu1 120.3(5) . . ? C50 N2 Eu1 120.3(5) . . ? C51 N3 C55 116.9(8) . . ? C51 N3 Eu1 121.9(5) . . ? C55 N3 Eu1 118.6(6) . . ? P2 C1 P1 114.3(4) . . ? P2 C2 P3 114.2(4) . 2_566 ? C8 C3 C4 118.8(8) . . ? C8 C3 P1 120.9(7) . . ? C4 C3 P1 120.2(7) . . ? C5 C4 C3 118.7(11) . . ? C6 C5 C4 122.6(12) . . ? C5 C6 C7 120.7(11) . . ? C6 C7 C8 120.1(12) . . ? C3 C8 C7 118.9(10) . . ? C14 C9 C10 116.1(9) . . ? C14 C9 P1 120.3(8) . . ? C10 C9 P1 123.5(7) . . ? C9 C10 C11 117.9(11) . . ? C12 C11 C10 125.0(13) . . ? C11 C12 C13 117.2(13) . . ? C12 C13 C14 120.9(14) . . ? C9 C14 C13 122.4(13) . . ? C16 C15 C20 120.1(8) . . ? C16 C15 P2 119.7(7) . . ? C20 C15 P2 120.0(7) . . ? C15 C16 C17 119.8(11) . . ? C18 C17 C16 119.7(13) . . ? C17 C18 C19 121.2(11) . . ? C18 C19 C20 120.9(13) . . ? C19 C20 C15 118.1(12) . . ? C22 C21 C26 118.6(9) . . ? C22 C21 P3 117.4(7) . . ? C26 C21 P3 124.0(7) . . ? C21 C22 C23 121.3(11) . . ? C22 C23 C24 117.9(12) . . ? C25 C24 C23 119.9(11) . . ? C24 C25 C26 124.1(12) . . ? C25 C26 C21 118.1(11) . . ? C32 C27 C28 119.4(9) . . ? C32 C27 P3 117.9(7) . . ? C28 C27 P3 122.7(7) . . ? C29 C28 C27 120.3(10) . . ? C28 C29 C30 120.3(10) . . ? C31 C30 C29 120.0(10) . . ? C30 C31 C32 120.0(11) . . ? C27 C32 C31 119.9(10) . . ? C34 C33 Pt1 178.0(7) . . ? C33 C34 C35 176.1(8) . . ? C40 C35 C36 117.6(6) . . ? C40 C35 C34 120.8(7) . . ? C36 C35 C34 121.6(7) . . ? C37 C36 C35 120.1(7) . . ? C38 C37 C36 122.8(7) . . ? C37 C38 C39 116.7(7) . . ? C37 C38 C48 122.0(7) . . ? C39 C38 C48 121.3(7) . . ? C40 C39 C38 122.5(7) . . ? C39 C40 C35 120.3(8) . . ? C42 C41 N1 124.0(9) . . ? C43 C42 C41 117.8(9) . . ? C42 C43 C44 121.3(10) . . ? C43 C44 C45 118.6(9) . . ? N1 C45 C44 121.8(8) . . ? N1 C45 C46 115.9(7) . . ? C44 C45 C46 122.3(7) . . ? N2 C46 C47 120.9(7) . . ? N2 C46 C45 117.5(6) . . ? C47 C46 C45 121.6(7) . . ? C48 C47 C46 121.6(8) . . ? C47 C48 C49 116.2(6) . . ? C47 C48 C38 121.9(7) . . ? C49 C48 C38 121.9(7) . . ? C50 C49 C48 121.2(7) . . ? N2 C50 C49 120.7(7) . . ? N2 C50 C51 116.9(6) . . ? C49 C50 C51 122.4(7) . . ? N3 C51 C52 121.9(8) . . ? N3 C51 C50 115.8(7) . . ? C52 C51 C50 122.3(7) . . ? C51 C52 C53 119.6(9) . . ? C52 C53 C54 119.1(10) . . ? C55 C54 C53 117.0(10) . . ? C54 C55 N3 125.4(9) . . ? F2 C56 F1' 35.9(17) . . ? F2 C56 F3 106.5(13) . . ? F1' C56 F3 134(3) . . ? F2 C56 F2' 126(2) . . ? F1' C56 F2' 106.6(13) . . ? F3 C56 F2' 72.5(15) . . ? F2 C56 F1 107.0(13) . . ? F1' C56 F1 75.9(16) . . ? F3 C56 F1 107.8(13) . . ? F2' C56 F1 36.4(16) . . ? F2 C56 F3' 72.1(17) . . ? F1' C56 F3' 106.6(13) . . ? F3 C56 F3' 38.5(15) . . ? F2' C56 F3' 106.5(13) . . ? F1 C56 F3' 135(2) . . ? F2 C56 C57 114.6(14) . . ? F1' C56 C57 112.3(18) . . ? F3 C56 C57 108.0(18) . . ? F2' C56 C57 116.4(18) . . ? F1 C56 C57 112.5(16) . . ? F3' C56 C57 107.8(16) . . ? O1 C57 C58 125.7(10) . . ? O1 C57 C56 115.3(9) . . ? C58 C57 C56 119.0(9) . . ? C59 C58 C57 122.1(10) . . ? O2 C59 C58 128.1(10) . . ? O2 C59 C60 112.5(10) . . ? C58 C59 C60 119.4(9) . . ? F5' C60 F5 134.7(15) . . ? F5' C60 F6 59.4(9) . . ? F5 C60 F6 109.9(10) . . ? F5' C60 F4' 109.5(10) . . ? F5 C60 F4' 61.1(9) . . ? F6 C60 F4' 53.7(8) . . ? F5' C60 F4 46.7(8) . . ? F5 C60 F4 107.9(11) . . ? F6 C60 F4 103.6(10) . . ? F4' C60 F4 138.0(13) . . ? F5' C60 F6' 109.4(11) . . ? F5 C60 F6' 43.1(8) . . ? F6 C60 F6' 134.2(13) . . ? F4' C60 F6' 101.5(10) . . ? F4 C60 F6' 67.8(9) . . ? F5' C60 C59 112.5(11) . . ? F5 C60 C59 111.9(12) . . ? F6 C60 C59 112.1(11) . . ? F4' C60 C59 110.5(10) . . ? F4 C60 C59 110.9(10) . . ? F6' C60 C59 112.8(11) . . ? F7 C61 F9 105.1(10) . . ? F7 C61 F8 104.8(11) . . ? F9 C61 F8 106.8(10) . . ? F7 C61 C62 112.3(9) . . ? F9 C61 C62 114.5(10) . . ? F8 C61 C62 112.6(10) . . ? O3 C62 C63 130.2(9) . . ? O3 C62 C61 112.8(9) . . ? C63 C62 C61 116.9(8) . . ? C62 C63 C64 122.6(8) . . ? O4 C64 C63 126.8(10) . . ? O4 C64 C65 114.8(10) . . ? C63 C64 C65 118.3(10) . . ? F10 C65 F11 110.4(13) . . ? F10 C65 F12 97.0(15) . . ? F11 C65 F12 103.4(13) . . ? F10 C65 C64 117.6(11) . . ? F11 C65 C64 115.8(13) . . ? F12 C65 C64 110.1(12) . . ? F15 C66 F14 108.1(14) . . ? F15 C66 F13 107.3(14) . . ? F14 C66 F13 101.0(14) . . ? F15 C66 C67 113.3(14) . . ? F14 C66 C67 116.4(13) . . ? F13 C66 C67 109.7(12) . . ? O5 C67 C68 130.9(11) . . ? O5 C67 C66 114.7(11) . . ? C68 C67 C66 114.4(11) . . ? C69 C68 C67 118.7(12) . . ? O6 C69 C68 126.1(13) . . ? O6 C69 C70 115.8(9) . . ? C68 C69 C70 118.0(11) . . ? F16' C70 F16 128.7(19) . . ? F16' C70 F17 35.7(13) . . ? F16 C70 F17 106.4(12) . . ? F16' C70 F18 72.9(13) . . ? F16 C70 F18 108.9(13) . . ? F17 C70 F18 106.8(12) . . ? F16' C70 F18' 107.9(13) . . ? F16 C70 F18' 35.2(12) . . ? F17 C70 F18' 75.9(12) . . ? F18 C70 F18' 135.7(18) . . ? F16' C70 F17' 107.3(12) . . ? F16 C70 F17' 72.5(12) . . ? F17 C70 F17' 132.6(18) . . ? F18 C70 F17' 39.5(11) . . ? F18' C70 F17' 105.9(12) . . ? F16' C70 C69 114.8(12) . . ? F16 C70 C69 112.3(12) . . ? F17 C70 C69 112.6(12) . . ? F18 C70 C69 109.6(12) . . ? F18' C70 C69 109.5(12) . . ? F17' C70 C69 111.0(11) . . ? O4 Eu1 O6 75.8(2) . . ? O4 Eu1 O3 73.0(2) . . ? O6 Eu1 O3 132.3(2) . . ? O4 Eu1 O5 74.7(2) . . ? O6 Eu1 O5 67.9(2) . . ? O3 Eu1 O5 69.6(2) . . ? O4 Eu1 O1 137.3(2) . . ? O6 Eu1 O1 142.6(2) . . ? O3 Eu1 O1 82.3(2) . . ? O5 Eu1 O1 128.1(3) . . ? O4 Eu1 O2 71.8(2) . . ? O6 Eu1 O2 129.2(2) . . ? O3 Eu1 O2 72.1(2) . . ? O5 Eu1 O2 134.8(2) . . ? O1 Eu1 O2 67.6(2) . . ? O4 Eu1 N3 146.0(2) . . ? O6 Eu1 N3 96.2(2) . . ? O3 Eu1 N3 90.3(2) . . ? O5 Eu1 N3 71.8(2) . . ? O1 Eu1 N3 65.5(2) . . ? O2 Eu1 N3 131.6(2) . . ? O4 Eu1 N2 137.4(2) . . ? O6 Eu1 N2 69.3(2) . . ? O3 Eu1 N2 149.6(2) . . ? O5 Eu1 N2 112.2(2) . . ? O1 Eu1 N2 73.3(2) . . ? O2 Eu1 N2 113.1(2) . . ? N3 Eu1 N2 63.5(2) . . ? O4 Eu1 N1 80.3(2) . . ? O6 Eu1 N1 65.9(2) . . ? O3 Eu1 N1 139.4(2) . . ? O5 Eu1 N1 131.4(2) . . ? O1 Eu1 N1 98.3(2) . . ? O2 Eu1 N1 70.8(2) . . ? N3 Eu1 N1 127.13(19) . . ? N2 Eu1 N1 63.7(2) . . ? C9 P1 C3 105.6(4) . . ? C9 P1 C1 108.5(4) . . ? C3 P1 C1 102.9(4) . . ? C9 P1 Ag1 117.5(3) . . ? C3 P1 Ag1 113.0(3) . . ? C1 P1 Ag1 108.3(2) . . ? C15 P2 C1 101.5(3) . . ? C15 P2 C2 107.9(4) . . ? C1 P2 C2 101.4(3) . . ? C15 P2 Pt1 120.5(3) . . ? C1 P2 Pt1 113.9(2) . . ? C2 P2 Pt1 109.8(3) . . ? C21 P3 C27 105.3(4) . . ? C21 P3 C2 103.4(4) . 2_566 ? C27 P3 C2 106.7(4) . 2_566 ? C21 P3 Ag1 118.0(3) . . ? C27 P3 Ag1 110.6(3) . . ? C2 P3 Ag1 111.9(3) 2_566 . ? O9 Cl1 O7 117.1(7) . . ? O9 Cl1 O8 115.9(7) . . ? O7 Cl1 O8 110.7(7) . . ? O9 Cl1 O10 105.8(6) . . ? O7 Cl1 O10 102.3(7) . . ? O8 Cl1 O10 102.8(6) . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag C33 Pt1 Ag1 P3 -79.3(2) 2_566 . . . ? C33 Pt1 Ag1 P3 100.7(2) . . . . ? P2 Pt1 Ag1 P3 -172.88(7) . . . . ? P2 Pt1 Ag1 P3 7.12(7) 2_566 . . . ? Ag1 Pt1 Ag1 P3 -56(100) 2_566 . . . ? C33 Pt1 Ag1 P1 105.7(2) 2_566 . . . ? C33 Pt1 Ag1 P1 -74.3(2) . . . . ? P2 Pt1 Ag1 P1 12.11(6) . . . . ? P2 Pt1 Ag1 P1 -167.89(6) 2_566 . . . ? Ag1 Pt1 Ag1 P1 129(100) 2_566 . . . ? C8 C3 C4 C5 -2.5(14) . . . . ? P1 C3 C4 C5 -179.4(8) . . . . ? C3 C4 C5 C6 1.6(19) . . . . ? C4 C5 C6 C7 -1(2) . . . . ? C5 C6 C7 C8 1(2) . . . . ? C4 C3 C8 C7 2.6(14) . . . . ? P1 C3 C8 C7 179.4(8) . . . . ? C6 C7 C8 C3 -1.6(18) . . . . ? C14 C9 C10 C11 0.0(16) . . . . ? P1 C9 C10 C11 179.3(9) . . . . ? C9 C10 C11 C12 -2(2) . . . . ? C10 C11 C12 C13 6(3) . . . . ? C11 C12 C13 C14 -8(3) . . . . ? C10 C9 C14 C13 -2.4(19) . . . . ? P1 C9 C14 C13 178.3(12) . . . . ? C12 C13 C14 C9 7(3) . . . . ? C20 C15 C16 C17 2.5(13) . . . . ? P2 C15 C16 C17 -171.9(7) . . . . ? C15 C16 C17 C18 -2.9(16) . . . . ? C16 C17 C18 C19 -1(2) . . . . ? C17 C18 C19 C20 5(2) . . . . ? C18 C19 C20 C15 -5.0(18) . . . . ? C16 C15 C20 C19 1.4(14) . . . . ? P2 C15 C20 C19 175.8(8) . . . . ? C26 C21 C22 C23 1.2(16) . . . . ? P3 C21 C22 C23 -178.0(9) . . . . ? C21 C22 C23 C24 -1.4(18) . . . . ? C22 C23 C24 C25 2.7(19) . . . . ? C23 C24 C25 C26 -4.0(19) . . . . ? C24 C25 C26 C21 3.8(17) . . . . ? C22 C21 C26 C25 -2.2(14) . . . . ? P3 C21 C26 C25 177.0(7) . . . . ? C32 C27 C28 C29 2.4(16) . . . . ? P3 C27 C28 C29 -179.5(9) . . . . ? C27 C28 C29 C30 -3.6(18) . . . . ? C28 C29 C30 C31 4(2) . . . . ? C29 C30 C31 C32 -3(2) . . . . ? C28 C27 C32 C31 -1.4(16) . . . . ? P3 C27 C32 C31 -179.6(9) . . . . ? C30 C31 C32 C27 1.5(19) . . . . ? C33 Pt1 C33 C34 -132(100) 2_566 . . . ? P2 Pt1 C33 C34 -34(20) . . . . ? P2 Pt1 C33 C34 146(20) 2_566 . . . ? Ag1 Pt1 C33 C34 -126(20) 2_566 . . . ? Ag1 Pt1 C33 C34 54(20) . . . . ? Pt1 C33 C34 C35 -166(13) . . . . ? C33 C34 C35 C40 165(12) . . . . ? C33 C34 C35 C36 -17(13) . . . . ? C40 C35 C36 C37 -0.4(13) . . . . ? C34 C35 C36 C37 -178.5(8) . . . . ? C35 C36 C37 C38 -1.4(14) . . . . ? C36 C37 C38 C39 1.3(13) . . . . ? C36 C37 C38 C48 -178.0(8) . . . . ? C37 C38 C39 C40 0.4(14) . . . . ? C48 C38 C39 C40 179.7(9) . . . . ? C38 C39 C40 C35 -2.1(16) . . . . ? C36 C35 C40 C39 2.0(14) . . . . ? C34 C35 C40 C39 -179.8(9) . . . . ? C45 N1 C41 C42 -0.4(13) . . . . ? Eu1 N1 C41 C42 -159.6(7) . . . . ? N1 C41 C42 C43 0.9(15) . . . . ? C41 C42 C43 C44 0.1(15) . . . . ? C42 C43 C44 C45 -1.5(15) . . . . ? C41 N1 C45 C44 -1.1(12) . . . . ? Eu1 N1 C45 C44 158.3(6) . . . . ? C41 N1 C45 C46 -179.2(7) . . . . ? Eu1 N1 C45 C46 -19.9(9) . . . . ? C43 C44 C45 N1 2.0(13) . . . . ? C43 C44 C45 C46 -180.0(8) . . . . ? C50 N2 C46 C47 -0.9(11) . . . . ? Eu1 N2 C46 C47 -178.3(5) . . . . ? C50 N2 C46 C45 179.9(6) . . . . ? Eu1 N2 C46 C45 2.5(9) . . . . ? N1 C45 C46 N2 11.4(10) . . . . ? C44 C45 C46 N2 -166.7(7) . . . . ? N1 C45 C46 C47 -167.8(7) . . . . ? C44 C45 C46 C47 14.1(12) . . . . ? N2 C46 C47 C48 1.8(12) . . . . ? C45 C46 C47 C48 -179.1(7) . . . . ? C46 C47 C48 C49 -2.6(11) . . . . ? C46 C47 C48 C38 -179.6(7) . . . . ? C37 C38 C48 C47 27.1(12) . . . . ? C39 C38 C48 C47 -152.1(8) . . . . ? C37 C38 C48 C49 -149.6(8) . . . . ? C39 C38 C48 C49 31.1(12) . . . . ? C47 C48 C49 C50 2.9(11) . . . . ? C38 C48 C49 C50 179.8(7) . . . . ? C46 N2 C50 C49 1.2(11) . . . . ? Eu1 N2 C50 C49 178.5(5) . . . . ? C46 N2 C50 C51 -178.0(7) . . . . ? Eu1 N2 C50 C51 -0.6(9) . . . . ? C48 C49 C50 N2 -2.2(11) . . . . ? C48 C49 C50 C51 176.9(7) . . . . ? C55 N3 C51 C52 1.4(14) . . . . ? Eu1 N3 C51 C52 163.0(7) . . . . ? C55 N3 C51 C50 -177.4(8) . . . . ? Eu1 N3 C51 C50 -15.8(10) . . . . ? N2 C50 C51 N3 10.4(11) . . . . ? C49 C50 C51 N3 -168.7(8) . . . . ? N2 C50 C51 C52 -168.3(8) . . . . ? C49 C50 C51 C52 12.6(13) . . . . ? N3 C51 C52 C53 -0.6(16) . . . . ? C50 C51 C52 C53 178.1(9) . . . . ? C51 C52 C53 C54 -0.2(18) . . . . ? C52 C53 C54 C55 0.0(19) . . . . ? C53 C54 C55 N3 0.9(19) . . . . ? C51 N3 C55 C54 -1.6(16) . . . . ? Eu1 N3 C55 C54 -163.8(10) . . . . ? Eu1 O1 C57 C58 -20.6(16) . . . . ? Eu1 O1 C57 C56 160.3(7) . . . . ? F2 C56 C57 O1 -26.4(19) . . . . ? F1' C56 C57 O1 -65.6(16) . . . . ? F3 C56 C57 O1 92.1(16) . . . . ? F2' C56 C57 O1 171.1(16) . . . . ? F1 C56 C57 O1 -149.0(15) . . . . ? F3' C56 C57 O1 51.6(17) . . . . ? F2 C56 C57 C58 154.4(17) . . . . ? F1' C56 C57 C58 115.2(16) . . . . ? F3 C56 C57 C58 -87.1(17) . . . . ? F2' C56 C57 C58 -8.1(19) . . . . ? F1 C56 C57 C58 31.8(17) . . . . ? F3' C56 C57 C58 -127.6(16) . . . . ? O1 C57 C58 C59 -3.1(17) . . . . ? C56 C57 C58 C59 176.0(10) . . . . ? Eu1 O2 C59 C58 18.9(15) . . . . ? Eu1 O2 C59 C60 -163.5(6) . . . . ? C57 C58 C59 O2 3.1(18) . . . . ? C57 C58 C59 C60 -174.3(9) . . . . ? O2 C59 C60 F5' -112.9(12) . . . . ? C58 C59 C60 F5' 64.9(14) . . . . ? O2 C59 C60 F5 58.1(13) . . . . ? C58 C59 C60 F5 -124.0(13) . . . . ? O2 C59 C60 F6 -177.8(11) . . . . ? C58 C59 C60 F6 0.1(15) . . . . ? O2 C59 C60 F4' 124.3(11) . . . . ? C58 C59 C60 F4' -57.9(14) . . . . ? O2 C59 C60 F4 -62.5(13) . . . . ? C58 C59 C60 F4 115.4(12) . . . . ? O2 C59 C60 F6' 11.4(13) . . . . ? C58 C59 C60 F6' -170.8(11) . . . . ? Eu1 O3 C62 C63 -8.6(17) . . . . ? Eu1 O3 C62 C61 175.0(6) . . . . ? F7 C61 C62 O3 60.5(13) . . . . ? F9 C61 C62 O3 -179.8(10) . . . . ? F8 C61 C62 O3 -57.4(13) . . . . ? F7 C61 C62 C63 -116.4(12) . . . . ? F9 C61 C62 C63 3.3(15) . . . . ? F8 C61 C62 C63 125.6(12) . . . . ? O3 C62 C63 C64 -1(2) . . . . ? C61 C62 C63 C64 175.6(10) . . . . ? Eu1 O4 C64 C63 -0.6(18) . . . . ? Eu1 O4 C64 C65 177.9(9) . . . . ? C62 C63 C64 O4 5.6(19) . . . . ? C62 C63 C64 C65 -172.8(12) . . . . ? O4 C64 C65 F10 36(2) . . . . ? C63 C64 C65 F10 -145.7(16) . . . . ? O4 C64 C65 F11 169.2(14) . . . . ? C63 C64 C65 F11 -12(2) . . . . ? O4 C64 C65 F12 -74.0(15) . . . . ? C63 C64 C65 F12 104.6(14) . . . . ? Eu1 O5 C67 C68 11(2) . . . . ? Eu1 O5 C67 C66 -171.2(9) . . . . ? F15 C66 C67 O5 -82.6(18) . . . . ? F14 C66 C67 O5 151.1(15) . . . . ? F13 C66 C67 O5 37.2(19) . . . . ? F15 C66 C67 C68 95.7(18) . . . . ? F14 C66 C67 C68 -31(2) . . . . ? F13 C66 C67 C68 -144.5(15) . . . . ? O5 C67 C68 C69 4(3) . . . . ? C66 C67 C68 C69 -173.9(14) . . . . ? Eu1 O6 C69 C68 -28(2) . . . . ? Eu1 O6 C69 C70 156.8(7) . . . . ? C67 C68 C69 O6 3(2) . . . . ? C67 C68 C69 C70 178.3(12) . . . . ? O6 C69 C70 F16' 155.9(15) . . . . ? C68 C69 C70 F16' -20.1(18) . . . . ? O6 C69 C70 F16 -45.0(16) . . . . ? C68 C69 C70 F16 139.0(16) . . . . ? O6 C69 C70 F17 -165.1(14) . . . . ? C68 C69 C70 F17 18.9(17) . . . . ? O6 C69 C70 F18 76.2(16) . . . . ? C68 C69 C70 F18 -99.8(17) . . . . ? O6 C69 C70 F18' -82.6(15) . . . . ? C68 C69 C70 F18' 101.3(16) . . . . ? O6 C69 C70 F17' 34.0(15) . . . . ? C68 C69 C70 F17' -142.1(15) . . . . ? C64 O4 Eu1 O6 138.7(10) . . . . ? C64 O4 Eu1 O3 -4.7(10) . . . . ? C64 O4 Eu1 O5 68.2(10) . . . . ? C64 O4 Eu1 O1 -62.1(11) . . . . ? C64 O4 Eu1 O2 -81.0(10) . . . . ? C64 O4 Eu1 N3 58.9(11) . . . . ? C64 O4 Eu1 N2 174.4(9) . . . . ? C64 O4 Eu1 N1 -153.8(10) . . . . ? C69 O6 Eu1 O4 -50.6(12) . . . . ? C69 O6 Eu1 O3 -0.2(13) . . . . ? C69 O6 Eu1 O5 28.4(12) . . . . ? C69 O6 Eu1 O1 152.8(11) . . . . ? C69 O6 Eu1 O2 -102.1(12) . . . . ? C69 O6 Eu1 N3 95.9(12) . . . . ? C69 O6 Eu1 N2 154.4(13) . . . . ? C69 O6 Eu1 N1 -136.1(13) . . . . ? C62 O3 Eu1 O4 8.8(8) . . . . ? C62 O3 Eu1 O6 -42.6(10) . . . . ? C62 O3 Eu1 O5 -70.8(9) . . . . ? C62 O3 Eu1 O1 153.6(9) . . . . ? C62 O3 Eu1 O2 84.6(9) . . . . ? C62 O3 Eu1 N3 -141.2(9) . . . . ? C62 O3 Eu1 N2 -170.1(8) . . . . ? C62 O3 Eu1 N1 59.8(10) . . . . ? C67 O5 Eu1 O4 62.1(10) . . . . ? C67 O5 Eu1 O6 -18.6(10) . . . . ? C67 O5 Eu1 O3 139.2(11) . . . . ? C67 O5 Eu1 O1 -159.1(10) . . . . ? C67 O5 Eu1 O2 105.4(10) . . . . ? C67 O5 Eu1 N3 -123.4(11) . . . . ? C67 O5 Eu1 N2 -73.4(11) . . . . ? C67 O5 Eu1 N1 0.4(11) . . . . ? C57 O1 Eu1 O4 7.1(11) . . . . ? C57 O1 Eu1 O6 152.6(8) . . . . ? C57 O1 Eu1 O3 -47.2(9) . . . . ? C57 O1 Eu1 O5 -103.6(9) . . . . ? C57 O1 Eu1 O2 26.5(9) . . . . ? C57 O1 Eu1 N3 -141.1(10) . . . . ? C57 O1 Eu1 N2 151.0(10) . . . . ? C57 O1 Eu1 N1 91.8(9) . . . . ? C59 O2 Eu1 O4 141.6(8) . . . . ? C59 O2 Eu1 O6 -165.3(7) . . . . ? C59 O2 Eu1 O3 64.2(8) . . . . ? C59 O2 Eu1 O5 97.4(8) . . . . ? C59 O2 Eu1 O1 -24.7(8) . . . . ? C59 O2 Eu1 N3 -9.6(9) . . . . ? C59 O2 Eu1 N2 -83.8(8) . . . . ? C59 O2 Eu1 N1 -132.6(8) . . . . ? C51 N3 Eu1 O4 148.1(6) . . . . ? C55 N3 Eu1 O4 -50.6(9) . . . . ? C51 N3 Eu1 O6 74.3(7) . . . . ? C55 N3 Eu1 O6 -124.4(7) . . . . ? C51 N3 Eu1 O3 -153.0(7) . . . . ? C55 N3 Eu1 O3 8.3(7) . . . . ? C51 N3 Eu1 O5 138.6(7) . . . . ? C55 N3 Eu1 O5 -60.1(7) . . . . ? C51 N3 Eu1 O1 -71.7(7) . . . . ? C55 N3 Eu1 O1 89.6(8) . . . . ? C51 N3 Eu1 O2 -87.0(7) . . . . ? C55 N3 Eu1 O2 74.2(8) . . . . ? C51 N3 Eu1 N2 11.1(6) . . . . ? C55 N3 Eu1 N2 172.4(8) . . . . ? C51 N3 Eu1 N1 10.0(8) . . . . ? C55 N3 Eu1 N1 171.3(7) . . . . ? C46 N2 Eu1 O4 26.8(7) . . . . ? C50 N2 Eu1 O4 -150.6(5) . . . . ? C46 N2 Eu1 O6 64.0(6) . . . . ? C50 N2 Eu1 O6 -113.4(6) . . . . ? C46 N2 Eu1 O3 -154.8(5) . . . . ? C50 N2 Eu1 O3 27.8(8) . . . . ? C46 N2 Eu1 O5 118.0(6) . . . . ? C50 N2 Eu1 O5 -59.4(6) . . . . ? C46 N2 Eu1 O1 -117.0(6) . . . . ? C50 N2 Eu1 O1 65.6(5) . . . . ? C46 N2 Eu1 O2 -61.1(6) . . . . ? C50 N2 Eu1 O2 121.6(5) . . . . ? C46 N2 Eu1 N3 172.5(6) . . . . ? C50 N2 Eu1 N3 -4.9(5) . . . . ? C46 N2 Eu1 N1 -8.6(5) . . . . ? C50 N2 Eu1 N1 174.1(6) . . . . ? C45 N1 Eu1 O4 -141.5(6) . . . . ? C41 N1 Eu1 O4 17.0(7) . . . . ? C45 N1 Eu1 O6 -62.8(6) . . . . ? C41 N1 Eu1 O6 95.8(7) . . . . ? C45 N1 Eu1 O3 169.5(5) . . . . ? C41 N1 Eu1 O3 -32.0(8) . . . . ? C45 N1 Eu1 O5 -82.1(6) . . . . ? C41 N1 Eu1 O5 76.4(7) . . . . ? C45 N1 Eu1 O1 81.7(6) . . . . ? C41 N1 Eu1 O1 -119.8(7) . . . . ? C45 N1 Eu1 O2 144.5(6) . . . . ? C41 N1 Eu1 O2 -57.0(7) . . . . ? C45 N1 Eu1 N3 16.3(7) . . . . ? C41 N1 Eu1 N3 174.8(6) . . . . ? C45 N1 Eu1 N2 15.1(5) . . . . ? C41 N1 Eu1 N2 173.6(7) . . . . ? C14 C9 P1 C3 95.7(9) . . . . ? C10 C9 P1 C3 -83.6(8) . . . . ? C14 C9 P1 C1 -154.5(9) . . . . ? C10 C9 P1 C1 26.2(9) . . . . ? C14 C9 P1 Ag1 -31.4(10) . . . . ? C10 C9 P1 Ag1 149.4(7) . . . . ? C8 C3 P1 C9 68.7(8) . . . . ? C4 C3 P1 C9 -114.5(7) . . . . ? C8 C3 P1 C1 -45.0(8) . . . . ? C4 C3 P1 C1 131.8(7) . . . . ? C8 C3 P1 Ag1 -161.6(6) . . . . ? C4 C3 P1 Ag1 15.2(8) . . . . ? P2 C1 P1 C9 89.2(5) . . . . ? P2 C1 P1 C3 -159.2(4) . . . . ? P2 C1 P1 Ag1 -39.3(4) . . . . ? P3 Ag1 P1 C9 108.1(6) . . . . ? Pt1 Ag1 P1 C9 -112.2(3) . . . . ? P3 Ag1 P1 C3 -15.3(7) . . . . ? Pt1 Ag1 P1 C3 124.4(3) . . . . ? P3 Ag1 P1 C1 -128.7(6) . . . . ? Pt1 Ag1 P1 C1 11.0(2) . . . . ? C16 C15 P2 C1 95.0(7) . . . . ? C20 C15 P2 C1 -79.4(7) . . . . ? C16 C15 P2 C2 -158.8(7) . . . . ? C20 C15 P2 C2 26.8(8) . . . . ? C16 C15 P2 Pt1 -31.7(8) . . . . ? C20 C15 P2 Pt1 153.8(6) . . . . ? P1 C1 P2 C15 -75.6(5) . . . . ? P1 C1 P2 C2 173.3(4) . . . . ? P1 C1 P2 Pt1 55.4(4) . . . . ? P3 C2 P2 C15 81.0(5) 2_566 . . . ? P3 C2 P2 C1 -172.8(4) 2_566 . . . ? P3 C2 P2 Pt1 -52.0(5) 2_566 . . . ? C33 Pt1 P2 C15 -20.8(4) 2_566 . . . ? C33 Pt1 P2 C15 159.2(4) . . . . ? P2 Pt1 P2 C15 -125(100) 2_566 . . . ? Ag1 Pt1 P2 C15 -95.2(3) 2_566 . . . ? Ag1 Pt1 P2 C15 84.8(3) . . . . ? C33 Pt1 P2 C1 -141.7(3) 2_566 . . . ? C33 Pt1 P2 C1 38.3(3) . . . . ? P2 Pt1 P2 C1 114(100) 2_566 . . . ? Ag1 Pt1 P2 C1 143.9(3) 2_566 . . . ? Ag1 Pt1 P2 C1 -36.1(3) . . . . ? C33 Pt1 P2 C2 105.4(3) 2_566 . . . ? C33 Pt1 P2 C2 -74.6(3) . . . . ? P2 Pt1 P2 C2 2(100) 2_566 . . . ? Ag1 Pt1 P2 C2 31.0(2) 2_566 . . . ? Ag1 Pt1 P2 C2 -149.0(2) . . . . ? C22 C21 P3 C27 -89.6(8) . . . . ? C26 C21 P3 C27 91.2(8) . . . . ? C22 C21 P3 C2 158.5(7) . . . 2_566 ? C26 C21 P3 C2 -20.7(9) . . . 2_566 ? C22 C21 P3 Ag1 34.4(8) . . . . ? C26 C21 P3 Ag1 -144.8(7) . . . . ? C32 C27 P3 C21 146.9(7) . . . . ? C28 C27 P3 C21 -31.2(9) . . . . ? C32 C27 P3 C2 -103.6(8) . . . 2_566 ? C28 C27 P3 C2 78.3(8) . . . 2_566 ? C32 C27 P3 Ag1 18.3(8) . . . . ? C28 C27 P3 Ag1 -159.8(7) . . . . ? P1 Ag1 P3 C21 -83.0(6) . . . . ? Pt1 Ag1 P3 C21 137.1(3) . . . . ? P1 Ag1 P3 C27 38.3(7) . . . . ? Pt1 Ag1 P3 C27 -101.6(3) . . . . ? P1 Ag1 P3 C2 157.1(6) . . . 2_566 ? Pt1 Ag1 P3 C2 17.2(3) . . . 2_566 ? _diffrn_measured_fraction_theta_max 0.984 _diffrn_reflns_theta_full 25.00 _diffrn_measured_fraction_theta_full 0.984 _refine_diff_density_max 1.184 _refine_diff_density_min -1.285 _refine_diff_density_rms 0.103 data_a2 _database_code_depnum_ccdc_archive 'CCDC 932965' #TrackingRef '2Eu.cif' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C156 H40 H92 Au2 Cl2 Eu2 F36 N6 O24 P6 Pt' _chemical_formula_weight 4308.34 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting triclinic _symmetry_space_group_name_H-M p-1 loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 12.36520(10) _cell_length_b 16.9603(2) _cell_length_c 26.9859(2) _cell_angle_alpha 106.747(7) _cell_angle_beta 95.282(12) _cell_angle_gamma 101.088(8) _cell_volume 5252.32(8) _cell_formula_units_Z 1 _cell_measurement_temperature 293(2) _cell_measurement_reflns_used ? _cell_measurement_theta_min ? _cell_measurement_theta_max ? _exptl_crystal_description ? _exptl_crystal_colour ? _exptl_crystal_size_max 0.25 _exptl_crystal_size_mid 0.23 _exptl_crystal_size_min 0.2 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.362 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 2112 _exptl_absorpt_coefficient_mu 2.800 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.4670 _exptl_absorpt_correction_T_max 1.0000 _exptl_absorpt_process_details ? _exptl_special_details ; ? ; _diffrn_ambient_temperature 293(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type ? _diffrn_measurement_method ? _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 39786 _diffrn_reflns_av_R_equivalents 0.0623 _diffrn_reflns_av_sigmaI/netI 0.0865 _diffrn_reflns_limit_h_min -14 _diffrn_reflns_limit_h_max 14 _diffrn_reflns_limit_k_min -20 _diffrn_reflns_limit_k_max 20 _diffrn_reflns_limit_l_min -32 _diffrn_reflns_limit_l_max 29 _diffrn_reflns_theta_min 4.32 _diffrn_reflns_theta_max 25.00 _reflns_number_total 18157 _reflns_number_gt 13937 _reflns_threshold_expression >2sigma(I) _computing_data_collection ? _computing_cell_refinement ? _computing_data_reduction ? _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; loop_ _platon_squeeze_void_nr _platon_squeeze_void_average_x _platon_squeeze_void_average_y _platon_squeeze_void_average_z _platon_squeeze_void_volume _platon_squeeze_void_count_electrons _platon_squeeze_void_content 1 -0.050 0.500 0.029 1950 178 ' ' _platon_squeeze_details ? _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details ; calc w=1/[\s^2^(Fo^2^)+(0.0622P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3 ; _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 18157 _refine_ls_number_parameters 1169 _refine_ls_number_restraints 756 _refine_ls_R_factor_all 0.0708 _refine_ls_R_factor_gt 0.0570 _refine_ls_wR_factor_ref 0.1509 _refine_ls_wR_factor_gt 0.1409 _refine_ls_goodness_of_fit_ref 1.006 _refine_ls_restrained_S_all 1.014 _refine_ls_shift/su_max 0.031 _refine_ls_shift/su_mean 0.001 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Cl1 Cl 1.1995(2) 0.65555(16) 0.41538(13) 0.1169(9) Uani 1 1 d DU . . Pt1 Pt 2.0000 1.0000 0.5000 0.04444(10) Uani 1 2 d S . . Au1 Au 1.821109(19) 0.900699(15) 0.537387(11) 0.05800(10) Uani 1 1 d . . . P1 P 1.78183(14) 1.02425(11) 0.58735(7) 0.0561(4) Uani 1 1 d . . . C1 C 1.7405(6) 0.7111(4) 0.4373(3) 0.0669(18) Uani 1 1 d . . . C2 C 1.7584(8) 0.6514(6) 0.3926(4) 0.102(3) Uani 1 1 d . . . H2A H 1.8288 0.6407 0.3892 0.122 Uiso 1 1 calc R . . C3 C 1.6697(12) 0.6095(7) 0.3546(4) 0.128(4) Uani 1 1 d . . . H3A H 1.6803 0.5699 0.3245 0.153 Uiso 1 1 calc R . . C4 C 1.5650(12) 0.6235(8) 0.3588(6) 0.132(5) Uani 1 1 d . . . H4A H 1.5059 0.5936 0.3319 0.159 Uiso 1 1 calc R . . C5 C 1.5479(9) 0.6792(9) 0.4008(6) 0.136(5) Uani 1 1 d . . . H5A H 1.4766 0.6883 0.4037 0.164 Uiso 1 1 calc R . . C6 C 1.6356(7) 0.7243(6) 0.4408(4) 0.092(3) Uani 1 1 d . . . H6A H 1.6230 0.7640 0.4702 0.111 Uiso 1 1 calc R . . C7 C 1.8690(8) 0.7052(5) 0.5307(4) 0.088(2) Uani 1 1 d U . . C8 C 1.9024(10) 0.6329(6) 0.5139(4) 0.124(3) Uani 1 1 d U . . H8A H 1.9228 0.6170 0.4808 0.149 Uiso 1 1 calc R . . C9 C 1.9071(11) 0.5792(7) 0.5465(5) 0.139(3) Uani 1 1 d U . . H9A H 1.9252 0.5274 0.5327 0.167 Uiso 1 1 calc R . . C10 C 1.8875(12) 0.5999(8) 0.5930(5) 0.151(3) Uani 1 1 d U . . H10A H 1.8848 0.5628 0.6127 0.181 Uiso 1 1 calc R . . C11 C 1.8714(13) 0.6752(9) 0.6120(5) 0.156(3) Uani 1 1 d U . . H11A H 1.8702 0.6954 0.6478 0.187 Uiso 1 1 calc R . . C12 C 1.8553(11) 0.7295(7) 0.5812(4) 0.133(3) Uani 1 1 d U . . H12A H 1.8357 0.7805 0.5960 0.160 Uiso 1 1 calc R . . C13 C 1.9803(5) 0.7838(4) 0.4639(3) 0.0519(15) Uani 1 1 d . . . H13A H 1.9772 0.7329 0.4353 0.062 Uiso 1 1 calc R . . H13B H 2.0418 0.7893 0.4907 0.062 Uiso 1 1 calc R . . C14 C 1.6353(6) 1.0226(5) 0.5817(3) 0.0684(19) Uani 1 1 d . . . C15 C 1.5601(6) 0.9450(5) 0.5688(4) 0.094(3) Uani 1 1 d . . . H15A H 1.5870 0.8962 0.5641 0.112 Uiso 1 1 calc R . . C16 C 1.4470(7) 0.9385(7) 0.5627(5) 0.132(5) Uani 1 1 d . . . H16A H 1.3974 0.8860 0.5533 0.158 Uiso 1 1 calc R . . C17 C 1.4097(7) 1.0101(8) 0.5707(5) 0.122(4) Uani 1 1 d . . . H17A H 1.3333 1.0063 0.5678 0.146 Uiso 1 1 calc R . . C18 C 1.4794(7) 1.0873(7) 0.5828(4) 0.109(3) Uani 1 1 d . . . H18A H 1.4507 1.1354 0.5883 0.131 Uiso 1 1 calc R . . C19 C 1.5919(6) 1.0944(5) 0.5869(4) 0.089(3) Uani 1 1 d . . . H19A H 1.6397 1.1469 0.5932 0.107 Uiso 1 1 calc R . . C20 C 1.8356(6) 1.0500(4) 0.6561(3) 0.0631(17) Uani 1 1 d . . . C21 C 1.9193(6) 1.0116(6) 0.6691(3) 0.080(2) Uani 1 1 d . . . H21A H 1.9434 0.9716 0.6436 0.096 Uiso 1 1 calc R . . C22 C 1.9664(8) 1.0361(8) 0.7228(4) 0.111(3) Uani 1 1 d . . . H22A H 2.0231 1.0123 0.7328 0.134 Uiso 1 1 calc R . . C23 C 1.9290(12) 1.0951(8) 0.7607(4) 0.123(4) Uani 1 1 d . . . H23A H 1.9604 1.1108 0.7958 0.148 Uiso 1 1 calc R . . C24 C 1.8452(10) 1.1299(8) 0.7457(4) 0.122(4) Uani 1 1 d . . . H24A H 1.8191 1.1690 0.7707 0.147 Uiso 1 1 calc R . . C25 C 1.8006(7) 1.1076(6) 0.6947(3) 0.088(2) Uani 1 1 d . . . H25A H 1.7440 1.1321 0.6853 0.106 Uiso 1 1 calc R . . C26 C 2.0761(5) 1.1651(4) 0.6238(3) 0.0588(16) Uani 1 1 d . . . C27 C 2.1809(6) 1.1464(4) 0.6290(3) 0.0713(19) Uani 1 1 d . . . H27A H 2.2018 1.1090 0.6009 0.086 Uiso 1 1 calc R . . C28 C 2.2529(7) 1.1831(5) 0.6752(4) 0.091(3) Uani 1 1 d . . . H28A H 2.3230 1.1712 0.6787 0.109 Uiso 1 1 calc R . . C29 C 2.2199(11) 1.2385(7) 0.7167(4) 0.115(4) Uani 1 1 d . . . H29A H 2.2674 1.2616 0.7486 0.138 Uiso 1 1 calc R . . C30 C 2.1193(10) 1.2599(6) 0.7118(4) 0.103(3) Uani 1 1 d . . . H30A H 2.1001 1.2991 0.7395 0.123 Uiso 1 1 calc R . . C31 C 2.0488(7) 1.2235(5) 0.6666(3) 0.081(2) Uani 1 1 d . . . H31A H 1.9798 1.2374 0.6634 0.097 Uiso 1 1 calc R . . C32 C 1.9212(4) 1.0436(4) 0.4474(2) 0.0493(14) Uani 1 1 d . . . C33 C 1.8798(5) 1.0733(4) 0.4183(3) 0.0591(16) Uani 1 1 d . . . C34 C 1.8299(6) 1.1075(4) 0.3811(3) 0.0624(17) Uani 1 1 d . . . C35 C 1.7909(7) 1.0560(5) 0.3296(3) 0.086(2) Uani 1 1 d . . . H35A H 1.7999 1.0008 0.3190 0.103 Uiso 1 1 calc R . . C36 C 1.7389(7) 1.0873(6) 0.2946(3) 0.092(3) Uani 1 1 d . . . H36A H 1.7129 1.0523 0.2604 0.110 Uiso 1 1 calc R . . C37 C 1.7239(6) 1.1697(5) 0.3088(3) 0.0721(19) Uani 1 1 d . . . C38 C 1.7610(7) 1.2205(5) 0.3601(3) 0.088(2) Uani 1 1 d . . . H38A H 1.7507 1.2754 0.3707 0.106 Uiso 1 1 calc R . . C39 C 1.8140(7) 1.1896(5) 0.3962(3) 0.082(2) Uani 1 1 d . . . H39A H 1.8388 1.2243 0.4306 0.098 Uiso 1 1 calc R . . C40 C 1.5940(7) 1.1925(6) 0.1831(3) 0.080(2) Uani 1 1 d . . . C41 C 1.6616(7) 1.1694(6) 0.2171(3) 0.085(2) Uani 1 1 d . . . H41A H 1.7075 1.1331 0.2044 0.102 Uiso 1 1 calc R . . C42 C 1.6608(6) 1.2008(5) 0.2709(3) 0.082(2) Uani 1 1 d . . . C43 C 1.5918(6) 1.2544(5) 0.2876(3) 0.079(2) Uani 1 1 d . . . H43A H 1.5887 1.2758 0.3231 0.095 Uiso 1 1 calc R . . C44 C 1.5269(6) 1.2769(5) 0.2515(3) 0.074(2) Uani 1 1 d . . . C45 C 1.5936(8) 1.1597(6) 0.1254(3) 0.094(3) Uani 1 1 d . B . C46 C 1.6687(11) 1.1168(10) 0.1045(4) 0.163(6) Uani 1 1 d . . . H46A H 1.7234 1.1069 0.1264 0.195 Uiso 1 1 calc R . . C47 C 1.6650(14) 1.0880(12) 0.0517(5) 0.198(8) Uani 1 1 d . . . H47A H 1.7179 1.0601 0.0371 0.237 Uiso 1 1 calc R . . C48 C 1.5794(13) 1.1015(11) 0.0201(5) 0.164(6) Uani 1 1 d . . . H48A H 1.5698 1.0785 -0.0162 0.197 Uiso 1 1 calc R . . C49 C 1.5100(10) 1.1492(8) 0.0435(4) 0.123(4) Uani 1 1 d . B . H49A H 1.4578 1.1630 0.0223 0.148 Uiso 1 1 calc R . . C50 C 1.4479(7) 1.3324(5) 0.2675(4) 0.085(2) Uani 1 1 d . C . C51 C 1.4576(8) 1.3834(6) 0.3201(4) 0.102(3) Uani 1 1 d . . . H51A H 1.5147 1.3853 0.3457 0.122 Uiso 1 1 calc R . . C52 C 1.3795(10) 1.4296(7) 0.3313(5) 0.115(3) Uani 1 1 d . . . H52A H 1.3809 1.4621 0.3657 0.139 Uiso 1 1 calc R . . C53 C 1.3000(10) 1.4289(7) 0.2935(5) 0.115(3) Uani 1 1 d . . . H53A H 1.2487 1.4625 0.3011 0.138 Uiso 1 1 calc R . . C54 C 1.2969(9) 1.3781(7) 0.2441(5) 0.115(3) Uani 1 1 d . C . H54A H 1.2407 1.3773 0.2185 0.139 Uiso 1 1 calc R . . C55 C 1.4549(16) 1.3588(10) -0.0118(11) 0.407(13) Uani 1 1 d DU . . C56 C 1.4636(18) 1.3655(10) 0.0521(5) 0.208(9) Uani 1 1 d D C . C57 C 1.5181(16) 1.4409(9) 0.0910(5) 0.196(8) Uani 1 1 d . . . H57A H 1.5478 1.4876 0.0811 0.235 Uiso 1 1 calc R D . C58 C 1.5292(13) 1.4483(9) 0.1419(6) 0.153(5) Uani 1 1 d . C . C59 C 1.5771(13) 1.5322(10) 0.1820(6) 0.188(6) Uani 1 1 d DU . . C60 C 1.2646(9) 0.9643(7) 0.1181(4) 0.134(3) Uani 1 1 d DU . . C61 C 1.2437(10) 1.0529(7) 0.1325(5) 0.125(3) Uani 1 1 d DU A . C62 C 1.1438(10) 1.0659(9) 0.1413(6) 0.154(4) Uani 1 1 d DU . . H62A H 1.0844 1.0188 0.1324 0.185 Uiso 1 1 calc R A . C63 C 1.1221(9) 1.1445(11) 0.1629(7) 0.174(4) Uani 1 1 d DU A . C66 C 1.8447(5) 1.1175(4) 0.5692(3) 0.0569(16) Uani 1 1 d . . . H66A H 1.8017 1.1159 0.5369 0.068 Uiso 1 1 calc R . . H66B H 1.8393 1.1680 0.5962 0.068 Uiso 1 1 calc R . . C76 C 1.1576(12) 1.4274(10) 0.0830(6) 0.224(5) Uani 1 1 d DU . . C77 C 1.1938(11) 1.3431(9) 0.0793(6) 0.217(4) Uani 1 1 d DU B . C78 C 1.1504(15) 1.2721(10) 0.0337(7) 0.227(5) Uani 1 1 d DU . . H78A H 1.1019 1.2779 0.0072 0.272 Uiso 1 1 calc R B . C79 C 1.1790(16) 1.1915(10) 0.0271(7) 0.214(4) Uani 1 1 d DU B . C80 C 1.1118(14) 1.1199(10) -0.0239(6) 0.237(6) Uani 1 1 d DU . . N1 N 1.5246(5) 1.2436(4) 0.1989(3) 0.0765(17) Uani 1 1 d . . . Eu1 Eu 1.36718(4) 1.25375(3) 0.13384(2) 0.10015(18) Uani 1 1 d . A . O1 O 1.5008(6) 1.3905(4) 0.1610(3) 0.119(2) Uani 1 1 d . . . F1 F 1.231(2) 0.9164(18) 0.1467(11) 0.228(12) Uani 0.50 1 d PDU A 1 F1' F 1.3435(17) 0.9615(15) 0.1524(9) 0.221(10) Uani 0.50 1 d PDU A 2 F2 F 1.3689(10) 0.9597(12) 0.1151(8) 0.146(5) Uani 0.50 1 d PDU A 1 F2' F 1.288(2) 0.9406(18) 0.0713(7) 0.229(10) Uani 0.50 1 d PDU A 2 F3 F 1.2115(15) 0.9253(15) 0.0693(6) 0.189(8) Uani 0.50 1 d PDU A 1 F3' F 1.1748(15) 0.9111(12) 0.1209(9) 0.170(8) Uani 0.50 1 d PDU A 2 F4 F 1.066(2) 1.4083(17) 0.0492(11) 0.267(13) Uani 0.50 1 d PDU B 1 F4' F 1.132(4) 1.435(2) 0.0372(9) 0.354(18) Uani 0.50 1 d PDU B 2 F5 F 1.238(2) 1.474(2) 0.0680(17) 0.329(14) Uani 0.50 1 d PDU B 1 F5' F 1.241(2) 1.4896(14) 0.1114(16) 0.319(17) Uani 0.50 1 d PDU B 2 F6 F 1.141(3) 1.466(2) 0.1302(7) 0.291(13) Uani 0.50 1 d PDU B 1 F6' F 1.072(3) 1.426(2) 0.1088(15) 0.344(16) Uani 0.50 1 d PDU B 2 F10 F 1.648(2) 1.5261(16) 0.2194(10) 0.235(12) Uani 0.50 1 d PDU C 1 F10' F 1.6845(15) 1.540(2) 0.1936(14) 0.254(12) Uani 0.50 1 d PDU C 2 F11 F 1.629(3) 1.5881(19) 0.1625(12) 0.257(14) Uani 0.50 1 d PDU C 1 F11' F 1.561(3) 1.5934(18) 0.1637(15) 0.280(14) Uani 0.50 1 d PDU C 2 F12 F 1.494(2) 1.560(2) 0.2026(14) 0.281(15) Uani 0.50 1 d PDU C 1 F12' F 1.534(3) 1.543(2) 0.2257(8) 0.248(14) Uani 0.50 1 d PDU C 2 F13 F 1.026(2) 1.2145(18) 0.2230(12) 0.333(18) Uani 0.50 1 d PDU A 1 F13' F 1.014(3) 1.158(3) 0.2309(8) 0.396(19) Uani 0.50 1 d PDU A 2 F14 F 0.958(2) 1.0793(15) 0.1897(14) 0.290(13) Uani 0.50 1 d PDU A 1 F14' F 0.9324(16) 1.0782(14) 0.1526(16) 0.321(18) Uani 0.50 1 d PDU A 2 F15 F 0.949(2) 1.161(3) 0.1400(13) 0.330(15) Uani 0.50 1 d PDU A 1 F15' F 0.978(2) 1.2140(17) 0.1689(17) 0.293(13) Uani 0.50 1 d PDU A 2 F16 F 1.097(3) 1.1513(16) -0.0624(10) 0.284(13) Uani 0.50 1 d PDU B 1 F17 F 1.010(2) 1.082(3) -0.0213(17) 0.407(19) Uani 0.50 1 d PDU B 1 F18 F 1.161(3) 1.0580(16) -0.0421(14) 0.370(19) Uani 0.50 1 d PDU B 1 F16' F 1.033(2) 1.130(2) -0.0550(14) 0.345(18) Uani 0.50 1 d PDU B 2 F17' F 1.076(3) 1.0498(18) -0.0138(15) 0.379(19) Uani 0.50 1 d PDU B 2 F18' F 1.1943(19) 1.109(2) -0.0506(11) 0.312(15) Uani 0.50 1 d PDU B 2 O2 O 1.4181(10) 1.2960(5) 0.0601(3) 0.173(4) Uani 1 1 d . . . P2 P 1.98996(13) 1.12541(10) 0.56036(6) 0.0478(4) Uani 1 1 d . . . N2 N 1.3674(6) 1.3297(5) 0.2296(3) 0.095(2) Uani 1 1 d . . . O3 O 1.2499(9) 1.3417(6) 0.1189(4) 0.192(4) Uani 1 1 d DU . . P3 P 1.85194(14) 0.77103(10) 0.49103(7) 0.0538(4) Uani 1 1 d . . . N3 N 1.5130(7) 1.1767(5) 0.0945(3) 0.102(2) Uani 1 1 d . . . O4 O 1.2409(8) 1.1731(5) 0.0574(4) 0.183(4) Uani 1 1 d DU . . O5 O 1.3315(5) 1.1097(4) 0.1359(3) 0.112(2) Uani 1 1 d DU . . O6 O 1.1857(6) 1.2093(6) 0.1605(4) 0.156(3) Uani 1 1 d . . . C64 C 1.0052(10) 1.1487(9) 0.1800(6) 0.206(5) Uani 1 1 d DU . . F7 F 1.550(2) 1.4093(17) -0.0122(10) 0.405(14) Uani 0.50 1 d PDU D 1 F8 F 1.444(3) 1.2790(13) -0.0372(11) 0.425(14) Uani 0.50 1 d PDU D 1 F9 F 1.368(2) 1.390(2) -0.0195(8) 0.409(14) Uani 0.50 1 d PDU D 1 F7' F 1.523(3) 1.3071(17) -0.0246(10) 0.414(14) Uani 0.50 1 d PDU D 2 F8' F 1.3491(18) 1.321(2) -0.0306(9) 0.412(14) Uani 0.50 1 d PDU D 2 F9' F 1.487(3) 1.4327(14) -0.0176(11) 0.413(14) Uani 0.50 1 d PDU D 2 O7 O 1.2629(15) 0.5929(10) 0.4078(8) 0.132(6) Uani 0.509(10) 1 d PDU E 1 O8 O 1.2263(16) 0.7109(11) 0.4674(4) 0.164(6) Uani 0.509(10) 1 d PDU E 1 O9 O 1.2267(17) 0.7034(9) 0.3806(6) 0.165(5) Uani 0.509(10) 1 d PDU E 1 O10 O 1.0844(8) 0.6178(10) 0.4036(8) 0.163(6) Uani 0.509(10) 1 d PDU E 1 O7' O 1.2480(17) 0.5893(10) 0.3900(8) 0.137(6) Uani 0.491(10) 1 d PDU E 2 O8' O 1.2854(13) 0.7305(8) 0.4400(8) 0.173(6) Uani 0.491(10) 1 d PDU E 2 O9' O 1.1245(15) 0.6734(11) 0.3797(5) 0.151(5) Uani 0.491(10) 1 d PDU E 2 O10' O 1.1445(15) 0.6354(11) 0.4561(6) 0.154(5) Uani 0.491(10) 1 d PDU E 2 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Cl1 0.1179(19) 0.0751(15) 0.177(3) 0.0426(16) 0.0462(19) 0.0510(14) Pt1 0.04014(18) 0.04136(18) 0.0570(2) 0.02215(14) 0.00722(14) 0.01123(13) Au1 0.05339(17) 0.04656(15) 0.0803(2) 0.02566(13) 0.02045(13) 0.01237(12) P1 0.0520(9) 0.0522(9) 0.0712(11) 0.0255(8) 0.0196(8) 0.0146(8) C1 0.064(4) 0.050(4) 0.084(5) 0.030(3) -0.001(4) -0.002(3) C2 0.104(7) 0.077(6) 0.100(7) 0.017(5) -0.014(5) -0.008(5) C3 0.142(10) 0.099(8) 0.104(8) 0.016(6) -0.032(8) -0.013(8) C4 0.118(10) 0.108(9) 0.138(11) 0.053(8) -0.048(9) -0.039(8) C5 0.078(7) 0.141(11) 0.180(13) 0.068(10) -0.025(8) -0.004(7) C6 0.070(5) 0.096(6) 0.105(7) 0.037(5) 0.004(5) 0.001(5) C7 0.127(6) 0.063(4) 0.098(5) 0.050(4) 0.038(4) 0.034(4) C8 0.188(7) 0.093(5) 0.120(6) 0.058(4) 0.031(5) 0.060(5) C9 0.223(8) 0.094(5) 0.136(6) 0.068(5) 0.036(6) 0.067(5) C10 0.245(8) 0.111(6) 0.139(6) 0.086(5) 0.056(7) 0.057(6) C11 0.253(8) 0.131(6) 0.127(6) 0.079(5) 0.059(6) 0.074(7) C12 0.211(7) 0.107(5) 0.123(6) 0.069(5) 0.059(6) 0.066(5) C13 0.045(3) 0.047(3) 0.068(4) 0.022(3) 0.010(3) 0.011(3) C14 0.057(4) 0.070(5) 0.087(5) 0.030(4) 0.025(4) 0.021(4) C15 0.066(5) 0.067(5) 0.152(8) 0.039(5) 0.029(5) 0.010(4) C16 0.056(5) 0.095(7) 0.235(14) 0.041(8) 0.042(7) 0.001(5) C17 0.051(5) 0.145(10) 0.180(11) 0.065(9) 0.027(6) 0.022(6) C18 0.072(5) 0.107(7) 0.178(10) 0.069(7) 0.038(6) 0.046(5) C19 0.056(4) 0.081(6) 0.144(8) 0.053(5) 0.020(5) 0.018(4) C20 0.062(4) 0.066(4) 0.065(4) 0.029(3) 0.018(3) 0.008(3) C21 0.075(5) 0.099(6) 0.079(5) 0.044(4) 0.016(4) 0.026(4) C22 0.091(6) 0.151(10) 0.105(8) 0.068(7) -0.007(6) 0.024(6) C23 0.167(11) 0.132(10) 0.062(6) 0.026(6) 0.017(7) 0.017(8) C24 0.119(8) 0.167(12) 0.084(7) 0.027(7) 0.019(6) 0.056(8) C25 0.092(6) 0.105(7) 0.078(6) 0.025(5) 0.022(5) 0.045(5) C26 0.058(4) 0.051(4) 0.064(4) 0.022(3) 0.003(3) 0.003(3) C27 0.073(5) 0.055(4) 0.077(5) 0.014(3) -0.004(4) 0.009(4) C28 0.087(6) 0.071(5) 0.095(6) 0.018(5) -0.029(5) 0.001(4) C29 0.143(9) 0.097(7) 0.076(6) 0.032(5) -0.041(6) -0.019(7) C30 0.117(8) 0.088(6) 0.072(6) 0.000(5) -0.004(6) -0.004(6) C31 0.085(5) 0.071(5) 0.083(5) 0.017(4) 0.015(4) 0.017(4) C32 0.038(3) 0.047(3) 0.062(4) 0.018(3) 0.010(3) 0.004(3) C33 0.054(4) 0.059(4) 0.070(4) 0.029(3) -0.001(3) 0.019(3) C34 0.062(4) 0.060(4) 0.076(5) 0.035(3) 0.006(3) 0.019(3) C35 0.102(6) 0.073(5) 0.086(6) 0.031(4) -0.009(5) 0.032(5) C36 0.105(6) 0.094(6) 0.075(5) 0.024(4) -0.017(5) 0.040(5) C37 0.068(4) 0.084(5) 0.074(5) 0.038(4) -0.002(4) 0.029(4) C38 0.111(6) 0.069(5) 0.091(6) 0.037(4) -0.011(5) 0.030(5) C39 0.104(6) 0.068(5) 0.071(5) 0.027(4) -0.023(4) 0.024(4) C40 0.082(5) 0.098(6) 0.073(5) 0.044(4) 0.009(4) 0.026(5) C41 0.086(5) 0.108(7) 0.084(6) 0.051(5) 0.005(4) 0.044(5) C42 0.075(5) 0.089(6) 0.088(6) 0.048(5) -0.011(4) 0.015(4) C43 0.077(5) 0.074(5) 0.094(6) 0.040(4) -0.010(4) 0.024(4) C44 0.076(5) 0.073(5) 0.081(5) 0.041(4) -0.004(4) 0.017(4) C45 0.110(7) 0.117(8) 0.077(6) 0.052(5) 0.021(5) 0.044(6) C46 0.170(11) 0.293(19) 0.085(7) 0.084(9) 0.039(8) 0.146(12) C47 0.224(16) 0.34(2) 0.094(9) 0.079(12) 0.051(10) 0.186(17) C48 0.194(14) 0.234(17) 0.088(8) 0.049(9) 0.026(9) 0.107(13) C49 0.142(10) 0.147(11) 0.086(7) 0.057(7) -0.002(7) 0.025(8) C50 0.090(6) 0.062(5) 0.112(7) 0.038(5) 0.004(5) 0.027(4) C51 0.114(7) 0.081(6) 0.117(8) 0.027(5) 0.005(6) 0.052(5) C52 0.136(9) 0.089(7) 0.122(8) 0.031(6) 0.015(7) 0.034(7) C53 0.121(8) 0.094(7) 0.149(10) 0.047(7) 0.016(8) 0.053(6) C54 0.106(7) 0.124(9) 0.124(9) 0.036(7) -0.008(7) 0.060(7) C55 0.78(4) 0.206(16) 0.169(9) 0.102(11) -0.153(14) -0.005(18) C56 0.39(3) 0.110(11) 0.103(9) 0.051(8) -0.028(13) 0.025(14) C57 0.32(2) 0.137(12) 0.087(8) 0.035(8) -0.002(11) -0.043(13) C58 0.202(14) 0.108(10) 0.143(12) 0.065(9) -0.016(10) -0.001(9) C59 0.274(17) 0.110(11) 0.163(12) 0.056(10) 0.010(11) -0.008(12) C60 0.139(7) 0.102(6) 0.150(7) 0.032(6) 0.025(6) 0.011(6) C61 0.109(5) 0.116(5) 0.142(6) 0.032(5) 0.007(5) 0.020(5) C62 0.101(5) 0.149(7) 0.188(8) 0.025(7) 0.016(6) 0.017(6) C63 0.095(6) 0.166(8) 0.234(9) 0.023(8) 0.032(7) 0.026(7) C66 0.057(4) 0.048(3) 0.069(4) 0.020(3) 0.013(3) 0.016(3) C76 0.249(11) 0.167(8) 0.243(10) 0.051(8) -0.087(9) 0.096(8) C77 0.237(8) 0.160(7) 0.227(8) 0.030(6) -0.097(7) 0.088(7) C78 0.248(9) 0.167(7) 0.225(8) 0.026(7) -0.111(7) 0.079(7) C79 0.240(8) 0.148(6) 0.206(8) 0.021(6) -0.115(6) 0.056(6) C80 0.253(11) 0.167(8) 0.221(11) 0.007(7) -0.123(8) 0.038(8) N1 0.082(4) 0.084(4) 0.077(4) 0.048(3) -0.003(3) 0.024(4) Eu1 0.1099(4) 0.0863(3) 0.1026(4) 0.0371(3) -0.0288(3) 0.0285(3) O1 0.159(6) 0.094(5) 0.092(4) 0.034(4) -0.030(4) 0.021(4) F1 0.28(3) 0.18(2) 0.30(2) 0.14(2) 0.14(2) 0.08(2) F1' 0.236(18) 0.155(17) 0.30(2) 0.11(2) -0.008(18) 0.091(15) F2 0.182(9) 0.112(11) 0.166(15) 0.050(12) 0.045(10) 0.070(10) F2' 0.26(3) 0.23(2) 0.235(14) 0.061(19) 0.159(16) 0.11(2) F3 0.174(15) 0.166(15) 0.178(11) -0.028(11) 0.040(9) 0.047(14) F3' 0.214(14) 0.088(10) 0.216(19) 0.046(12) 0.102(13) 0.026(10) F4 0.291(19) 0.29(3) 0.25(2) 0.101(19) -0.082(17) 0.164(19) F4' 0.44(4) 0.30(3) 0.30(2) 0.14(2) -0.14(2) 0.08(3) F5 0.35(3) 0.23(3) 0.43(4) 0.18(3) -0.06(2) 0.07(2) F5' 0.30(2) 0.191(18) 0.40(4) 0.04(3) -0.17(2) 0.097(18) F6 0.31(3) 0.25(3) 0.276(15) -0.014(18) -0.102(18) 0.18(3) F6' 0.27(2) 0.40(4) 0.33(3) 0.02(3) -0.03(2) 0.19(2) F10 0.30(2) 0.164(18) 0.168(19) 0.066(14) -0.061(18) -0.105(19) F10' 0.271(17) 0.17(2) 0.29(3) 0.093(19) -0.009(17) -0.039(17) F11 0.40(3) 0.14(2) 0.162(18) 0.058(14) -0.016(19) -0.08(2) F11' 0.49(4) 0.096(15) 0.24(3) 0.054(14) -0.01(3) 0.06(2) F12 0.42(3) 0.15(2) 0.25(3) 0.01(2) 0.10(2) 0.08(2) F12' 0.36(3) 0.17(2) 0.129(14) -0.026(12) 0.017(17) -0.02(3) F13 0.22(3) 0.28(2) 0.40(3) -0.06(2) 0.19(2) 0.01(2) F13' 0.35(4) 0.47(5) 0.325(16) 0.11(2) 0.17(2) -0.06(3) F14 0.17(2) 0.28(2) 0.36(3) 0.055(19) 0.11(2) -0.054(18) F14' 0.077(9) 0.198(15) 0.58(4) -0.03(2) 0.01(2) 0.033(12) F15 0.121(16) 0.29(3) 0.55(3) 0.11(3) -0.08(2) 0.08(3) F15' 0.14(2) 0.206(19) 0.51(4) 0.04(2) 0.05(3) 0.096(18) F16 0.25(2) 0.24(2) 0.28(2) 0.058(15) -0.21(2) 0.01(2) F17 0.30(2) 0.33(4) 0.50(4) 0.14(3) -0.16(3) -0.07(2) F18 0.41(3) 0.13(2) 0.41(4) -0.082(19) -0.25(3) 0.09(2) F16' 0.24(2) 0.28(3) 0.39(3) 0.08(2) -0.24(2) -0.06(2) F17' 0.35(4) 0.22(3) 0.44(4) 0.09(2) -0.24(3) -0.09(3) F18' 0.33(2) 0.25(3) 0.21(2) -0.10(2) -0.101(15) 0.06(2) O2 0.310(12) 0.092(5) 0.098(5) 0.025(4) -0.035(6) 0.039(7) P2 0.0474(8) 0.0413(8) 0.0580(9) 0.0190(7) 0.0097(7) 0.0123(7) N2 0.083(4) 0.105(6) 0.107(5) 0.049(4) -0.015(4) 0.037(4) O3 0.208(8) 0.151(7) 0.200(8) 0.034(6) -0.083(6) 0.086(6) P3 0.0518(9) 0.0421(8) 0.0701(11) 0.0233(7) 0.0097(8) 0.0081(7) N3 0.121(6) 0.114(6) 0.080(5) 0.054(4) -0.008(4) 0.025(5) O4 0.200(8) 0.126(6) 0.186(7) 0.028(5) -0.097(6) 0.043(5) O5 0.102(4) 0.107(5) 0.131(5) 0.050(4) -0.008(4) 0.029(4) O6 0.084(5) 0.155(8) 0.205(9) 0.015(7) 0.012(5) 0.043(5) C64 0.105(7) 0.193(9) 0.280(11) 0.016(9) 0.041(8) 0.023(7) F7 0.79(4) 0.214(16) 0.164(11) 0.114(12) -0.123(16) 0.003(19) F8 0.79(4) 0.218(16) 0.174(12) 0.064(13) -0.133(17) -0.009(18) F9 0.78(4) 0.219(17) 0.164(10) 0.120(13) -0.185(15) -0.009(19) F7' 0.78(4) 0.224(16) 0.166(12) 0.084(13) -0.135(16) -0.002(19) F8' 0.78(4) 0.222(17) 0.170(11) 0.112(13) -0.178(15) 0.001(18) F9' 0.79(4) 0.227(16) 0.163(11) 0.124(12) -0.142(16) -0.007(19) O7 0.145(9) 0.106(9) 0.171(15) 0.046(8) 0.034(11) 0.080(8) O8 0.188(14) 0.133(11) 0.165(8) 0.017(8) -0.001(9) 0.083(9) O9 0.233(14) 0.094(9) 0.186(10) 0.060(8) 0.035(11) 0.054(10) O10 0.124(7) 0.133(11) 0.215(13) 0.015(10) 0.031(9) 0.050(7) O7' 0.157(12) 0.104(8) 0.170(15) 0.036(9) 0.045(10) 0.082(8) O8' 0.203(13) 0.090(8) 0.211(14) 0.040(9) 0.008(10) 0.027(8) O9' 0.177(12) 0.122(11) 0.181(10) 0.055(8) 0.024(9) 0.087(9) O10' 0.176(12) 0.137(11) 0.183(11) 0.065(9) 0.067(9) 0.077(9) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Cl1 O10 1.408(8) . ? Cl1 O7' 1.409(8) . ? Cl1 O9' 1.410(8) . ? Cl1 O8 1.413(8) . ? Cl1 O7 1.419(8) . ? Cl1 O9 1.431(8) . ? Cl1 O10' 1.432(8) . ? Cl1 O8' 1.432(8) . ? Pt1 C32 2.035(7) 2_976 ? Pt1 C32 2.035(7) . ? Pt1 P2 2.3097(16) . ? Pt1 P2 2.3097(16) 2_976 ? Pt1 Au1 2.9504(3) 2_976 ? Pt1 Au1 2.9504(3) . ? Au1 P1 2.3084(18) . ? Au1 P3 2.3176(17) . ? P1 C14 1.799(7) . ? P1 C20 1.807(7) . ? P1 C66 1.840(6) . ? C1 C6 1.365(11) . ? C1 C2 1.401(11) . ? C1 P3 1.810(7) . ? C2 C3 1.355(13) . ? C3 C4 1.370(17) . ? C4 C5 1.314(17) . ? C5 C6 1.383(13) . ? C7 C8 1.339(12) . ? C7 C12 1.342(12) . ? C7 P3 1.782(8) . ? C8 C9 1.441(13) . ? C9 C10 1.260(14) . ? C10 C11 1.294(16) . ? C11 C12 1.435(14) . ? C13 P3 1.810(6) . ? C13 P2 1.828(6) 2_976 ? C14 C15 1.386(10) . ? C14 C19 1.400(10) . ? C15 C16 1.372(11) . ? C16 C17 1.348(14) . ? C17 C18 1.353(13) . ? C18 C19 1.364(10) . ? C20 C25 1.373(10) . ? C20 C21 1.394(10) . ? C21 C22 1.421(11) . ? C22 C23 1.391(14) . ? C23 C24 1.372(15) . ? C24 C25 1.350(12) . ? C26 C27 1.397(10) . ? C26 C31 1.403(10) . ? C26 P2 1.801(7) . ? C27 C28 1.367(10) . ? C28 C29 1.389(14) . ? C29 C30 1.366(14) . ? C30 C31 1.339(11) . ? C32 C33 1.176(8) . ? C33 C34 1.443(9) . ? C34 C39 1.392(10) . ? C34 C35 1.393(10) . ? C35 C36 1.376(10) . ? C36 C37 1.393(11) . ? C37 C38 1.383(10) . ? C37 C42 1.501(10) . ? C38 C39 1.400(10) . ? C40 N1 1.345(10) . ? C40 C41 1.373(10) . ? C40 C45 1.495(11) . ? C41 C42 1.399(11) . ? C42 C43 1.375(11) . ? C43 C44 1.386(10) . ? C44 N1 1.364(9) . ? C44 C50 1.491(11) . ? C45 C46 1.353(13) . ? C45 N3 1.364(11) . ? C46 C47 1.359(14) . ? C47 C48 1.393(16) . ? C48 C49 1.365(15) . ? C49 N3 1.316(12) . ? C50 N2 1.344(10) . ? C50 C51 1.414(12) . ? C51 C52 1.359(13) . ? C52 C53 1.346(14) . ? C53 C54 1.354(14) . ? C54 N2 1.319(11) . ? C55 F9' 1.300(10) . ? C55 F8 1.304(10) . ? C55 F9 1.316(10) . ? C55 F7 1.320(10) . ? C55 F8' 1.321(10) . ? C55 F7' 1.326(10) . ? C55 C56 1.69(3) . ? C56 O2 1.290(15) . ? C56 C57 1.399(17) . ? C57 C58 1.334(16) . ? C58 O1 1.241(13) . ? C58 C59 1.49(2) . ? C59 F11 1.306(10) . ? C59 F10' 1.309(10) . ? C59 F11' 1.311(10) . ? C59 F10 1.313(10) . ? C59 F12 1.316(10) . ? C59 F12' 1.318(10) . ? C60 F2' 1.288(9) . ? C60 F1' 1.301(9) . ? C60 F1 1.310(10) . ? C60 F3' 1.313(9) . ? C60 F2 1.316(9) . ? C60 F3 1.332(9) . ? C60 C61 1.519(9) . ? C61 O5 1.282(12) . ? C61 C62 1.326(14) . ? C62 C63 1.382(18) . ? C63 O6 1.245(16) . ? C63 C64 1.565(9) . ? C66 P2 1.818(6) . ? C76 F4' 1.296(10) . ? C76 F6 1.307(10) . ? C76 F4 1.313(9) . ? C76 F5 1.315(10) . ? C76 F6' 1.317(10) . ? C76 F5' 1.318(10) . ? C76 C77 1.557(14) . ? C77 O3 1.230(15) . ? C77 C78 1.423(18) . ? C78 C79 1.444(19) . ? C79 O4 1.214(15) . ? C79 C80 1.580(15) . ? C80 F16' 1.295(10) . ? C80 F17' 1.298(10) . ? C80 F16 1.311(10) . ? C80 F18' 1.314(10) . ? C80 F18 1.314(10) . ? C80 F17 1.322(10) . ? N1 Eu1 2.565(6) . ? Eu1 O4 2.350(8) . ? Eu1 O3 2.358(8) . ? Eu1 O2 2.398(9) . ? Eu1 O5 2.416(7) . ? Eu1 O1 2.444(7) . ? Eu1 O6 2.466(9) . ? Eu1 N2 2.533(8) . ? Eu1 N3 2.558(9) . ? F13 C64 1.322(10) . ? F13' C64 1.329(10) . ? F14 C64 1.318(9) . ? F14' C64 1.319(10) . ? F15 C64 1.318(10) . ? F15' C64 1.319(10) . ? P2 C13 1.828(6) 2_976 ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag O10 Cl1 O7' 103.2(12) . . ? O10 Cl1 O9' 56.5(8) . . ? O7' Cl1 O9' 111.6(9) . . ? O10 Cl1 O8 110.0(8) . . ? O7' Cl1 O8 129.7(13) . . ? O9' Cl1 O8 118.1(10) . . ? O10 Cl1 O7 110.6(9) . . ? O7' Cl1 O7 19.6(15) . . ? O9' Cl1 O7 131.0(12) . . ? O8 Cl1 O7 110.6(9) . . ? O10 Cl1 O9 108.8(9) . . ? O7' Cl1 O9 94.5(12) . . ? O9' Cl1 O9 52.8(8) . . ? O8 Cl1 O9 108.7(8) . . ? O7 Cl1 O9 108.0(8) . . ? O10 Cl1 O10' 61.7(8) . . ? O7' Cl1 O10' 110.3(9) . . ? O9' Cl1 O10' 110.6(8) . . ? O8 Cl1 O10' 59.2(9) . . ? O7 Cl1 O10' 97.2(11) . . ? O9 Cl1 O10' 154.7(10) . . ? O10 Cl1 O8' 147.4(10) . . ? O7' Cl1 O8' 109.3(9) . . ? O9' Cl1 O8' 108.1(8) . . ? O8 Cl1 O8' 48.0(8) . . ? O7 Cl1 O8' 100.7(13) . . ? O9 Cl1 O8' 67.7(9) . . ? O10' Cl1 O8' 106.8(8) . . ? C32 Pt1 C32 180.000(2) 2_976 . ? C32 Pt1 P2 95.48(17) 2_976 . ? C32 Pt1 P2 84.52(17) . . ? C32 Pt1 P2 84.52(17) 2_976 2_976 ? C32 Pt1 P2 95.48(17) . 2_976 ? P2 Pt1 P2 180.000(2) . 2_976 ? C32 Pt1 Au1 105.71(15) 2_976 2_976 ? C32 Pt1 Au1 74.29(15) . 2_976 ? P2 Pt1 Au1 87.61(4) . 2_976 ? P2 Pt1 Au1 92.39(4) 2_976 2_976 ? C32 Pt1 Au1 74.29(15) 2_976 . ? C32 Pt1 Au1 105.71(15) . . ? P2 Pt1 Au1 92.39(4) . . ? P2 Pt1 Au1 87.61(4) 2_976 . ? Au1 Pt1 Au1 180.000(8) 2_976 . ? P1 Au1 P3 175.40(6) . . ? P1 Au1 Pt1 90.04(4) . . ? P3 Au1 Pt1 94.43(4) . . ? C14 P1 C20 107.7(3) . . ? C14 P1 C66 104.5(3) . . ? C20 P1 C66 104.9(3) . . ? C14 P1 Au1 113.6(3) . . ? C20 P1 Au1 112.2(3) . . ? C66 P1 Au1 113.2(2) . . ? C6 C1 C2 119.0(8) . . ? C6 C1 P3 118.8(6) . . ? C2 C1 P3 122.1(6) . . ? C3 C2 C1 117.8(10) . . ? C2 C3 C4 122.3(12) . . ? C5 C4 C3 120.0(12) . . ? C4 C5 C6 120.2(13) . . ? C1 C6 C5 120.7(10) . . ? C8 C7 C12 116.0(9) . . ? C8 C7 P3 123.4(8) . . ? C12 C7 P3 120.5(7) . . ? C7 C8 C9 120.8(11) . . ? C10 C9 C8 122.6(12) . . ? C9 C10 C11 116.7(12) . . ? C10 C11 C12 124.0(13) . . ? C7 C12 C11 118.7(11) . . ? P3 C13 P2 115.0(3) . 2_976 ? C15 C14 C19 117.7(7) . . ? C15 C14 P1 118.2(6) . . ? C19 C14 P1 124.0(6) . . ? C16 C15 C14 121.6(9) . . ? C17 C16 C15 118.3(9) . . ? C16 C17 C18 122.5(8) . . ? C17 C18 C19 119.8(9) . . ? C18 C19 C14 120.0(8) . . ? C25 C20 C21 120.0(7) . . ? C25 C20 P1 122.6(6) . . ? C21 C20 P1 117.3(6) . . ? C20 C21 C22 117.1(8) . . ? C23 C22 C21 121.1(10) . . ? C24 C23 C22 119.2(10) . . ? C25 C24 C23 120.2(10) . . ? C24 C25 C20 122.4(9) . . ? C27 C26 C31 118.2(7) . . ? C27 C26 P2 118.8(5) . . ? C31 C26 P2 122.3(6) . . ? C28 C27 C26 120.1(7) . . ? C27 C28 C29 119.1(9) . . ? C30 C29 C28 121.6(8) . . ? C31 C30 C29 119.1(9) . . ? C30 C31 C26 121.8(9) . . ? C33 C32 Pt1 176.1(5) . . ? C32 C33 C34 178.0(8) . . ? C39 C34 C35 118.9(7) . . ? C39 C34 C33 121.4(7) . . ? C35 C34 C33 119.6(7) . . ? C36 C35 C34 119.8(8) . . ? C35 C36 C37 122.1(8) . . ? C38 C37 C36 118.2(7) . . ? C38 C37 C42 120.5(8) . . ? C36 C37 C42 121.1(7) . . ? C37 C38 C39 120.4(8) . . ? C34 C39 C38 120.6(7) . . ? N1 C40 C41 123.2(8) . . ? N1 C40 C45 116.5(7) . . ? C41 C40 C45 120.2(9) . . ? C40 C41 C42 119.3(8) . . ? C43 C42 C41 117.9(7) . . ? C43 C42 C37 120.9(8) . . ? C41 C42 C37 120.9(8) . . ? C42 C43 C44 120.2(8) . . ? N1 C44 C43 121.7(8) . . ? N1 C44 C50 115.9(7) . . ? C43 C44 C50 122.2(8) . . ? C46 C45 N3 121.5(9) . . ? C46 C45 C40 122.7(9) . . ? N3 C45 C40 115.8(9) . . ? C45 C46 C47 120.7(11) . . ? C46 C47 C48 117.9(13) . . ? C49 C48 C47 118.6(12) . . ? N3 C49 C48 123.3(11) . . ? N2 C50 C51 122.8(9) . . ? N2 C50 C44 116.4(8) . . ? C51 C50 C44 120.8(8) . . ? C52 C51 C50 116.6(10) . . ? C53 C52 C51 121.1(11) . . ? C52 C53 C54 118.2(11) . . ? N2 C54 C53 125.2(10) . . ? F9' C55 F8 140(4) . . ? F9' C55 F9 70.1(14) . . ? F8 C55 F9 116.1(15) . . ? F9' C55 F7 42.9(17) . . ? F8 C55 F7 115.3(16) . . ? F9 C55 F7 112.9(15) . . ? F9' C55 F8' 114.8(15) . . ? F8 C55 F8' 69.3(14) . . ? F9 C55 F8' 48.9(12) . . ? F7 C55 F8' 152(3) . . ? F9' C55 F7' 115.2(16) . . ? F8 C55 F7' 43.5(17) . . ? F9 C55 F7' 155(3) . . ? F7 C55 F7' 75.9(17) . . ? F8' C55 F7' 112.8(16) . . ? F9' C55 C56 111(2) . . ? F8 C55 C56 106(2) . . ? F9 C55 C56 102.7(18) . . ? F7 C55 C56 101.7(19) . . ? F8' C55 C56 103.1(18) . . ? F7' C55 C56 97.4(19) . . ? O2 C56 C57 125.6(11) . . ? O2 C56 C55 113.8(11) . . ? C57 C56 C55 120.6(12) . . ? C58 C57 C56 122.5(13) . . ? O1 C58 C57 126.2(14) . . ? O1 C58 C59 113.5(12) . . ? C57 C58 C59 120.3(12) . . ? F11 C59 F10' 71.8(14) . . ? F11 C59 F11' 38.9(19) . . ? F10' C59 F11' 109.1(15) . . ? F11 C59 F10 107.8(13) . . ? F10' C59 F10 41.4(13) . . ? F11' C59 F10 135(3) . . ? F11 C59 F12 108.2(15) . . ? F10' C59 F12 140(3) . . ? F11' C59 F12 73(2) . . ? F10 C59 F12 108.7(15) . . ? F11 C59 F12' 130(3) . . ? F10' C59 F12' 108.1(15) . . ? F11' C59 F12' 106.8(14) . . ? F10 C59 F12' 69.6(15) . . ? F12 C59 F12' 40.3(18) . . ? F11 C59 C58 113(2) . . ? F10' C59 C58 108(2) . . ? F11' C59 C58 111(2) . . ? F10 C59 C58 111.2(16) . . ? F12 C59 C58 108(2) . . ? F12' C59 C58 113.8(18) . . ? F2' C60 F1' 111.3(12) . . ? F2' C60 F1 127(2) . . ? F1' C60 F1 65.9(12) . . ? F2' C60 F3' 108.7(12) . . ? F1' C60 F3' 106.3(12) . . ? F1 C60 F3' 40.6(13) . . ? F2' C60 F2 64.5(11) . . ? F1' C60 F2 48.6(11) . . ? F1 C60 F2 104.5(11) . . ? F3' C60 F2 133.9(18) . . ? F2' C60 F3 41.3(10) . . ? F1' C60 F3 142.7(18) . . ? F1 C60 F3 107.7(12) . . ? F3' C60 F3 73.0(12) . . ? F2 C60 F3 104.1(10) . . ? F2' C60 C61 111.8(16) . . ? F1' C60 C61 109.4(14) . . ? F1 C60 C61 118.3(17) . . ? F3' C60 C61 109.1(14) . . ? F2 C60 C61 115.6(12) . . ? F3 C60 C61 105.6(13) . . ? O5 C61 C62 126.5(12) . . ? O5 C61 C60 112.7(10) . . ? C62 C61 C60 120.8(12) . . ? C61 C62 C63 124.4(12) . . ? O6 C63 C62 120.3(12) . . ? O6 C63 C64 120.2(13) . . ? C62 C63 C64 118.3(13) . . ? P2 C66 P1 114.5(4) . . ? F4' C76 F6 134(3) . . ? F4' C76 F4 44.0(16) . . ? F6 C76 F4 110.8(13) . . ? F4' C76 F5 65.5(16) . . ? F6 C76 F5 111.4(14) . . ? F4 C76 F5 108.9(13) . . ? F4' C76 F6' 111.8(14) . . ? F6 C76 F6' 44.5(14) . . ? F4 C76 F6' 71.8(14) . . ? F5 C76 F6' 147(3) . . ? F4' C76 F5' 111.2(13) . . ? F6 C76 F5' 64.9(15) . . ? F4 C76 F5' 144(2) . . ? F5 C76 F5' 50.3(16) . . ? F6' C76 F5' 109.0(13) . . ? F4' C76 C77 112.0(19) . . ? F6 C76 C77 112.5(16) . . ? F4 C76 C77 106.9(15) . . ? F5 C76 C77 106.0(16) . . ? F6' C76 C77 105.4(17) . . ? F5' C76 C77 107.2(15) . . ? O3 C77 C78 125.1(13) . . ? O3 C77 C76 115.7(12) . . ? C78 C77 C76 118.8(12) . . ? C77 C78 C79 122.4(13) . . ? O4 C79 C78 127.4(14) . . ? O4 C79 C80 119.1(14) . . ? C78 C79 C80 113.3(13) . . ? F16' C80 F17' 108.4(14) . . ? F16' C80 F16 38.7(16) . . ? F17' C80 F16 138(2) . . ? F16' C80 F18' 106.5(15) . . ? F17' C80 F18' 106.5(15) . . ? F16 C80 F18' 74(2) . . ? F16' C80 F18 118(3) . . ? F17' C80 F18 63(2) . . ? F16 C80 F18 105.2(14) . . ? F18' C80 F18 43.6(19) . . ? F16' C80 F17 65.1(15) . . ? F17' C80 F17 49.8(15) . . ? F16 C80 F17 103.5(14) . . ? F18' C80 F17 141(3) . . ? F18 C80 F17 104.7(15) . . ? F16' C80 C79 124(2) . . ? F17' C80 C79 111(2) . . ? F16 C80 C79 110.4(16) . . ? F18' C80 C79 99.1(16) . . ? F18 C80 C79 114.7(18) . . ? F17 C80 C79 117(2) . . ? C40 N1 C44 117.5(6) . . ? C40 N1 Eu1 121.0(5) . . ? C44 N1 Eu1 120.3(5) . . ? O4 Eu1 O3 74.1(3) . . ? O4 Eu1 O2 69.2(3) . . ? O3 Eu1 O2 72.8(4) . . ? O4 Eu1 O5 74.1(3) . . ? O3 Eu1 O5 133.2(3) . . ? O2 Eu1 O5 124.5(3) . . ? O4 Eu1 O1 134.8(3) . . ? O3 Eu1 O1 79.4(3) . . ? O2 Eu1 O1 68.2(3) . . ? O5 Eu1 O1 145.8(2) . . ? O4 Eu1 O6 72.5(4) . . ? O3 Eu1 O6 71.1(4) . . ? O2 Eu1 O6 132.8(4) . . ? O5 Eu1 O6 67.2(3) . . ? O1 Eu1 O6 131.2(3) . . ? O4 Eu1 N2 139.9(3) . . ? O3 Eu1 N2 84.0(3) . . ? O2 Eu1 N2 135.3(3) . . ? O5 Eu1 N2 99.3(2) . . ? O1 Eu1 N2 70.3(2) . . ? O6 Eu1 N2 68.7(3) . . ? O4 Eu1 N3 87.8(3) . . ? O3 Eu1 N3 142.6(3) . . ? O2 Eu1 N3 70.2(3) . . ? O5 Eu1 N3 68.2(2) . . ? O1 Eu1 N3 91.8(3) . . ? O6 Eu1 N3 134.5(3) . . ? N2 Eu1 N3 127.3(2) . . ? O4 Eu1 N1 142.1(3) . . ? O3 Eu1 N1 143.5(3) . . ? O2 Eu1 N1 117.6(3) . . ? O5 Eu1 N1 72.5(2) . . ? O1 Eu1 N1 73.8(2) . . ? O6 Eu1 N1 109.5(3) . . ? N2 Eu1 N1 64.0(2) . . ? N3 Eu1 N1 63.5(2) . . ? C58 O1 Eu1 136.5(8) . . ? C56 O2 Eu1 136.5(8) . . ? C26 P2 C66 108.8(3) . . ? C26 P2 C13 102.0(3) . 2_976 ? C66 P2 C13 102.7(3) . 2_976 ? C26 P2 Pt1 121.3(2) . . ? C66 P2 Pt1 107.3(2) . . ? C13 P2 Pt1 113.2(2) 2_976 . ? C54 N2 C50 116.1(9) . . ? C54 N2 Eu1 121.3(7) . . ? C50 N2 Eu1 122.0(6) . . ? C77 O3 Eu1 132.9(9) . . ? C7 P3 C13 104.4(4) . . ? C7 P3 C1 107.2(4) . . ? C13 P3 C1 107.5(3) . . ? C7 P3 Au1 113.2(3) . . ? C13 P3 Au1 111.3(2) . . ? C1 P3 Au1 112.7(3) . . ? C49 N3 C45 117.7(10) . . ? C49 N3 Eu1 120.7(8) . . ? C45 N3 Eu1 121.5(6) . . ? C79 O4 Eu1 133.1(10) . . ? C61 O5 Eu1 134.9(7) . . ? C63 O6 Eu1 140.3(8) . . ? F14 C64 F15 112.9(12) . . ? F14 C64 F14' 45.3(15) . . ? F15 C64 F14' 70.3(14) . . ? F14 C64 F15' 140(2) . . ? F15 C64 F15' 43.8(14) . . ? F14' C64 F15' 110.4(12) . . ? F14 C64 F13 110.5(12) . . ? F15 C64 F13 113.0(13) . . ? F14' C64 F13 145(2) . . ? F15' C64 F13 70.2(15) . . ? F14 C64 F13' 67.4(15) . . ? F15 C64 F13' 145(2) . . ? F14' C64 F13' 110.9(12) . . ? F15' C64 F13' 112.0(13) . . ? F13 C64 F13' 45.4(16) . . ? F14 C64 C63 112.0(15) . . ? F15 C64 C63 103.3(15) . . ? F14' C64 C63 108.9(14) . . ? F15' C64 C63 105.9(15) . . ? F13 C64 C63 104.6(14) . . ? F13' C64 C63 108.6(18) . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag C32 Pt1 Au1 P1 105.36(18) 2_976 . . . ? C32 Pt1 Au1 P1 -74.64(18) . . . . ? P2 Pt1 Au1 P1 10.33(6) . . . . ? P2 Pt1 Au1 P1 -169.67(6) 2_976 . . . ? Au1 Pt1 Au1 P1 -126(100) 2_976 . . . ? C32 Pt1 Au1 P3 -73.53(18) 2_976 . . . ? C32 Pt1 Au1 P3 106.47(18) . . . . ? P2 Pt1 Au1 P3 -168.55(6) . . . . ? P2 Pt1 Au1 P3 11.45(6) 2_976 . . . ? Au1 Pt1 Au1 P3 55(100) 2_976 . . . ? P3 Au1 P1 C14 -60.1(8) . . . . ? Pt1 Au1 P1 C14 134.0(3) . . . . ? P3 Au1 P1 C20 62.5(8) . . . . ? Pt1 Au1 P1 C20 -103.5(2) . . . . ? P3 Au1 P1 C66 -179(100) . . . . ? Pt1 Au1 P1 C66 15.0(2) . . . . ? C6 C1 C2 C3 0.3(13) . . . . ? P3 C1 C2 C3 179.9(8) . . . . ? C1 C2 C3 C4 -0.5(17) . . . . ? C2 C3 C4 C5 0(2) . . . . ? C3 C4 C5 C6 0(2) . . . . ? C2 C1 C6 C5 0.2(13) . . . . ? P3 C1 C6 C5 -179.3(8) . . . . ? C4 C5 C6 C1 -0.6(18) . . . . ? C12 C7 C8 C9 8.6(17) . . . . ? P3 C7 C8 C9 -175.5(9) . . . . ? C7 C8 C9 C10 -5(2) . . . . ? C8 C9 C10 C11 -5(2) . . . . ? C9 C10 C11 C12 11(3) . . . . ? C8 C7 C12 C11 -3.1(18) . . . . ? P3 C7 C12 C11 -179.1(10) . . . . ? C10 C11 C12 C7 -7(2) . . . . ? C20 P1 C14 C15 -98.3(7) . . . . ? C66 P1 C14 C15 150.5(7) . . . . ? Au1 P1 C14 C15 26.6(8) . . . . ? C20 P1 C14 C19 85.1(8) . . . . ? C66 P1 C14 C19 -26.1(8) . . . . ? Au1 P1 C14 C19 -149.9(7) . . . . ? C19 C14 C15 C16 -1.8(14) . . . . ? P1 C14 C15 C16 -178.6(9) . . . . ? C14 C15 C16 C17 -1.4(18) . . . . ? C15 C16 C17 C18 2(2) . . . . ? C16 C17 C18 C19 0.4(19) . . . . ? C17 C18 C19 C14 -3.8(16) . . . . ? C15 C14 C19 C18 4.4(14) . . . . ? P1 C14 C19 C18 -179.0(7) . . . . ? C14 P1 C20 C25 -38.0(7) . . . . ? C66 P1 C20 C25 72.9(7) . . . . ? Au1 P1 C20 C25 -163.8(6) . . . . ? C14 P1 C20 C21 144.8(6) . . . . ? C66 P1 C20 C21 -104.2(6) . . . . ? Au1 P1 C20 C21 19.0(6) . . . . ? C25 C20 C21 C22 -1.2(11) . . . . ? P1 C20 C21 C22 176.1(6) . . . . ? C20 C21 C22 C23 0.8(14) . . . . ? C21 C22 C23 C24 0.1(17) . . . . ? C22 C23 C24 C25 -0.6(19) . . . . ? C23 C24 C25 C20 0.2(18) . . . . ? C21 C20 C25 C24 0.7(14) . . . . ? P1 C20 C25 C24 -176.4(8) . . . . ? C31 C26 C27 C28 1.6(11) . . . . ? P2 C26 C27 C28 172.9(6) . . . . ? C26 C27 C28 C29 0.4(13) . . . . ? C27 C28 C29 C30 -2.8(15) . . . . ? C28 C29 C30 C31 3.1(16) . . . . ? C29 C30 C31 C26 -1.0(15) . . . . ? C27 C26 C31 C30 -1.3(12) . . . . ? P2 C26 C31 C30 -172.3(7) . . . . ? C32 Pt1 C32 C33 5(100) 2_976 . . . ? P2 Pt1 C32 C33 45(9) . . . . ? P2 Pt1 C32 C33 -135(9) 2_976 . . . ? Au1 Pt1 C32 C33 -44(9) 2_976 . . . ? Au1 Pt1 C32 C33 136(9) . . . . ? Pt1 C32 C33 C34 123(19) . . . . ? C32 C33 C34 C39 -162(21) . . . . ? C32 C33 C34 C35 22(22) . . . . ? C39 C34 C35 C36 0.8(13) . . . . ? C33 C34 C35 C36 177.2(8) . . . . ? C34 C35 C36 C37 0.2(14) . . . . ? C35 C36 C37 C38 -1.3(14) . . . . ? C35 C36 C37 C42 -176.2(8) . . . . ? C36 C37 C38 C39 1.2(13) . . . . ? C42 C37 C38 C39 176.2(8) . . . . ? C35 C34 C39 C38 -0.9(12) . . . . ? C33 C34 C39 C38 -177.2(7) . . . . ? C37 C38 C39 C34 -0.2(13) . . . . ? N1 C40 C41 C42 -1.1(13) . . . . ? C45 C40 C41 C42 180.0(8) . . . . ? C40 C41 C42 C43 -0.3(12) . . . . ? C40 C41 C42 C37 173.4(7) . . . . ? C38 C37 C42 C43 -32.6(12) . . . . ? C36 C37 C42 C43 142.2(9) . . . . ? C38 C37 C42 C41 153.9(8) . . . . ? C36 C37 C42 C41 -31.3(12) . . . . ? C41 C42 C43 C44 -0.9(12) . . . . ? C37 C42 C43 C44 -174.6(7) . . . . ? C42 C43 C44 N1 3.5(12) . . . . ? C42 C43 C44 C50 177.8(7) . . . . ? N1 C40 C45 C46 171.5(11) . . . . ? C41 C40 C45 C46 -9.5(16) . . . . ? N1 C40 C45 N3 -7.8(12) . . . . ? C41 C40 C45 N3 171.2(8) . . . . ? N3 C45 C46 C47 -1(2) . . . . ? C40 C45 C46 C47 179.9(14) . . . . ? C45 C46 C47 C48 -2(3) . . . . ? C46 C47 C48 C49 6(3) . . . . ? C47 C48 C49 N3 -6(2) . . . . ? N1 C44 C50 N2 13.6(11) . . . . ? C43 C44 C50 N2 -161.0(8) . . . . ? N1 C44 C50 C51 -167.4(8) . . . . ? C43 C44 C50 C51 18.0(12) . . . . ? N2 C50 C51 C52 1.2(14) . . . . ? C44 C50 C51 C52 -177.7(8) . . . . ? C50 C51 C52 C53 -2.7(16) . . . . ? C51 C52 C53 C54 2.8(18) . . . . ? C52 C53 C54 N2 -1.4(19) . . . . ? F9' C55 C56 O2 171(2) . . . . ? F8 C55 C56 O2 -25(2) . . . . ? F9 C55 C56 O2 97.5(19) . . . . ? F7 C55 C56 O2 -145.5(19) . . . . ? F8' C55 C56 O2 47(2) . . . . ? F7' C55 C56 O2 -68(2) . . . . ? F9' C55 C56 C57 -10(3) . . . . ? F8 C55 C56 C57 154(2) . . . . ? F9 C55 C56 C57 -84(2) . . . . ? F7 C55 C56 C57 33(2) . . . . ? F8' C55 C56 C57 -134(2) . . . . ? F7' C55 C56 C57 111(2) . . . . ? O2 C56 C57 C58 0(4) . . . . ? C55 C56 C57 C58 -178.3(16) . . . . ? C56 C57 C58 O1 5(3) . . . . ? C56 C57 C58 C59 -173.4(17) . . . . ? O1 C58 C59 F11 165.5(19) . . . . ? C57 C58 C59 F11 -16(3) . . . . ? O1 C58 C59 F10' 88(2) . . . . ? C57 C58 C59 F10' -93(2) . . . . ? O1 C58 C59 F11' -153(2) . . . . ? C57 C58 C59 F11' 26(3) . . . . ? O1 C58 C59 F10 44(2) . . . . ? C57 C58 C59 F10 -137(2) . . . . ? O1 C58 C59 F12 -75(2) . . . . ? C57 C58 C59 F12 104(2) . . . . ? O1 C58 C59 F12' -32(3) . . . . ? C57 C58 C59 F12' 146(2) . . . . ? F2' C60 C61 O5 -66.4(17) . . . . ? F1' C60 C61 O5 57.3(17) . . . . ? F1 C60 C61 O5 129.7(17) . . . . ? F3' C60 C61 O5 173.2(14) . . . . ? F2 C60 C61 O5 4.8(16) . . . . ? F3 C60 C61 O5 -109.7(13) . . . . ? F2' C60 C61 C62 114.9(18) . . . . ? F1' C60 C61 C62 -121.4(18) . . . . ? F1 C60 C61 C62 -49(2) . . . . ? F3' C60 C61 C62 -5.4(19) . . . . ? F2 C60 C61 C62 -173.9(14) . . . . ? F3 C60 C61 C62 71.6(17) . . . . ? O5 C61 C62 C63 -10(3) . . . . ? C60 C61 C62 C63 168.8(14) . . . . ? C61 C62 C63 O6 23(3) . . . . ? C61 C62 C63 C64 -169.4(14) . . . . ? C14 P1 C66 P2 -169.9(4) . . . . ? C20 P1 C66 P2 76.8(4) . . . . ? Au1 P1 C66 P2 -45.8(4) . . . . ? F4' C76 C77 O3 159(2) . . . . ? F6 C76 C77 O3 -32(2) . . . . ? F4 C76 C77 O3 -154(2) . . . . ? F5 C76 C77 O3 90(2) . . . . ? F6' C76 C77 O3 -79(2) . . . . ? F5' C76 C77 O3 37(2) . . . . ? F4' C76 C77 C78 -27(2) . . . . ? F6 C76 C77 C78 141(2) . . . . ? F4 C76 C77 C78 19(2) . . . . ? F5 C76 C77 C78 -97(2) . . . . ? F6' C76 C77 C78 94(2) . . . . ? F5' C76 C77 C78 -150(2) . . . . ? O3 C77 C78 C79 -7(3) . . . . ? C76 C77 C78 C79 -179.6(17) . . . . ? C77 C78 C79 O4 0(4) . . . . ? C77 C78 C79 C80 174.3(16) . . . . ? O4 C79 C80 F16' 171(3) . . . . ? C78 C79 C80 F16' -4(3) . . . . ? O4 C79 C80 F17' 39(3) . . . . ? C78 C79 C80 F17' -136(3) . . . . ? O4 C79 C80 F16 -148(3) . . . . ? C78 C79 C80 F16 37(3) . . . . ? O4 C79 C80 F18' -72(3) . . . . ? C78 C79 C80 F18' 113(3) . . . . ? O4 C79 C80 F18 -30(3) . . . . ? C78 C79 C80 F18 155(3) . . . . ? O4 C79 C80 F17 94(3) . . . . ? C78 C79 C80 F17 -81(3) . . . . ? C41 C40 N1 C44 3.6(12) . . . . ? C45 C40 N1 C44 -177.4(7) . . . . ? C41 C40 N1 Eu1 -164.2(6) . . . . ? C45 C40 N1 Eu1 14.8(10) . . . . ? C43 C44 N1 C40 -4.8(11) . . . . ? C50 C44 N1 C40 -179.4(7) . . . . ? C43 C44 N1 Eu1 163.1(6) . . . . ? C50 C44 N1 Eu1 -11.5(9) . . . . ? C40 N1 Eu1 O4 33.2(8) . . . . ? C44 N1 Eu1 O4 -134.3(7) . . . . ? C40 N1 Eu1 O3 -156.3(7) . . . . ? C44 N1 Eu1 O3 36.3(8) . . . . ? C40 N1 Eu1 O2 -58.0(6) . . . . ? C44 N1 Eu1 O2 134.6(5) . . . . ? C40 N1 Eu1 O5 62.4(6) . . . . ? C44 N1 Eu1 O5 -105.1(6) . . . . ? C40 N1 Eu1 O1 -111.9(6) . . . . ? C44 N1 Eu1 O1 80.6(6) . . . . ? C40 N1 Eu1 O6 119.5(6) . . . . ? C44 N1 Eu1 O6 -48.0(6) . . . . ? C40 N1 Eu1 N2 172.5(6) . . . . ? C44 N1 Eu1 N2 5.0(5) . . . . ? C40 N1 Eu1 N3 -11.4(6) . . . . ? C44 N1 Eu1 N3 -178.9(6) . . . . ? C57 C58 O1 Eu1 -24(3) . . . . ? C59 C58 O1 Eu1 154.6(9) . . . . ? O4 Eu1 O1 C58 2.9(16) . . . . ? O3 Eu1 O1 C58 -51.9(15) . . . . ? O2 Eu1 O1 C58 23.7(14) . . . . ? O5 Eu1 O1 C58 143.4(14) . . . . ? O6 Eu1 O1 C58 -104.9(15) . . . . ? N2 Eu1 O1 C58 -139.3(15) . . . . ? N3 Eu1 O1 C58 91.5(15) . . . . ? N1 Eu1 O1 C58 153.2(15) . . . . ? C57 C56 O2 Eu1 13(3) . . . . ? C55 C56 O2 Eu1 -168.5(9) . . . . ? O4 Eu1 O2 C56 146.7(18) . . . . ? O3 Eu1 O2 C56 67.6(17) . . . . ? O5 Eu1 O2 C56 -161.4(17) . . . . ? O1 Eu1 O2 C56 -17.7(17) . . . . ? O6 Eu1 O2 C56 108.9(17) . . . . ? N2 Eu1 O2 C56 5(2) . . . . ? N3 Eu1 O2 C56 -118.1(18) . . . . ? N1 Eu1 O2 C56 -74.4(18) . . . . ? C27 C26 P2 C66 155.3(5) . . . . ? C31 C26 P2 C66 -33.8(7) . . . . ? C27 C26 P2 C13 -96.7(6) . . . 2_976 ? C31 C26 P2 C13 74.2(6) . . . 2_976 ? C27 C26 P2 Pt1 30.3(6) . . . . ? C31 C26 P2 Pt1 -158.8(5) . . . . ? P1 C66 P2 C26 -78.4(4) . . . . ? P1 C66 P2 C13 174.0(3) . . . 2_976 ? P1 C66 P2 Pt1 54.5(4) . . . . ? C32 Pt1 P2 C26 17.2(3) 2_976 . . . ? C32 Pt1 P2 C26 -162.8(3) . . . . ? P2 Pt1 P2 C26 -150(100) 2_976 . . . ? Au1 Pt1 P2 C26 -88.4(3) 2_976 . . . ? Au1 Pt1 P2 C26 91.6(3) . . . . ? C32 Pt1 P2 C66 -108.5(3) 2_976 . . . ? C32 Pt1 P2 C66 71.5(3) . . . . ? P2 Pt1 P2 C66 84(100) 2_976 . . . ? Au1 Pt1 P2 C66 145.9(2) 2_976 . . . ? Au1 Pt1 P2 C66 -34.1(2) . . . . ? C32 Pt1 P2 C13 138.9(3) 2_976 . . 2_976 ? C32 Pt1 P2 C13 -41.1(3) . . . 2_976 ? P2 Pt1 P2 C13 -29(100) 2_976 . . 2_976 ? Au1 Pt1 P2 C13 33.3(2) 2_976 . . 2_976 ? Au1 Pt1 P2 C13 -146.7(2) . . . 2_976 ? C53 C54 N2 C50 -0.1(17) . . . . ? C53 C54 N2 Eu1 -171.5(9) . . . . ? C51 C50 N2 C54 0.2(14) . . . . ? C44 C50 N2 C54 179.1(8) . . . . ? C51 C50 N2 Eu1 171.5(7) . . . . ? C44 C50 N2 Eu1 -9.6(10) . . . . ? O4 Eu1 N2 C54 -44.8(10) . . . . ? O3 Eu1 N2 C54 11.8(8) . . . . ? O2 Eu1 N2 C54 69.9(9) . . . . ? O5 Eu1 N2 C54 -121.1(8) . . . . ? O1 Eu1 N2 C54 92.7(8) . . . . ? O6 Eu1 N2 C54 -60.2(8) . . . . ? N3 Eu1 N2 C54 169.3(7) . . . . ? N1 Eu1 N2 C54 173.7(9) . . . . ? O4 Eu1 N2 C50 144.4(6) . . . . ? O3 Eu1 N2 C50 -159.1(7) . . . . ? O2 Eu1 N2 C50 -101.0(8) . . . . ? O5 Eu1 N2 C50 68.0(7) . . . . ? O1 Eu1 N2 C50 -78.2(7) . . . . ? O6 Eu1 N2 C50 128.9(7) . . . . ? N3 Eu1 N2 C50 -1.5(8) . . . . ? N1 Eu1 N2 C50 2.8(6) . . . . ? C78 C77 O3 Eu1 26(2) . . . . ? C76 C77 O3 Eu1 -161.8(8) . . . . ? O4 Eu1 O3 C77 -24.5(12) . . . . ? O2 Eu1 O3 C77 48.2(13) . . . . ? O5 Eu1 O3 C77 -73.3(15) . . . . ? O1 Eu1 O3 C77 118.4(14) . . . . ? O6 Eu1 O3 C77 -101.0(13) . . . . ? N2 Eu1 O3 C77 -170.5(14) . . . . ? N3 Eu1 O3 C77 39.5(16) . . . . ? N1 Eu1 O3 C77 161.5(11) . . . . ? C8 C7 P3 C13 -49.5(10) . . . . ? C12 C7 P3 C13 126.2(9) . . . . ? C8 C7 P3 C1 64.4(10) . . . . ? C12 C7 P3 C1 -119.9(9) . . . . ? C8 C7 P3 Au1 -170.7(8) . . . . ? C12 C7 P3 Au1 5.0(10) . . . . ? P2 C13 P3 C7 -160.3(4) 2_976 . . . ? P2 C13 P3 C1 86.1(4) 2_976 . . . ? P2 C13 P3 Au1 -37.8(4) 2_976 . . . ? C6 C1 P3 C7 97.9(7) . . . . ? C2 C1 P3 C7 -81.7(8) . . . . ? C6 C1 P3 C13 -150.4(6) . . . . ? C2 C1 P3 C13 30.1(7) . . . . ? C6 C1 P3 Au1 -27.4(7) . . . . ? C2 C1 P3 Au1 153.1(6) . . . . ? P1 Au1 P3 C7 -37.9(9) . . . . ? Pt1 Au1 P3 C7 128.1(3) . . . . ? P1 Au1 P3 C13 -155.2(7) . . . . ? Pt1 Au1 P3 C13 10.8(2) . . . . ? P1 Au1 P3 C1 84.0(8) . . . . ? Pt1 Au1 P3 C1 -110.1(3) . . . . ? C48 C49 N3 C45 3.3(18) . . . . ? C48 C49 N3 Eu1 -174.2(11) . . . . ? C46 C45 N3 C49 0.5(16) . . . . ? C40 C45 N3 C49 179.8(9) . . . . ? C46 C45 N3 Eu1 178.0(10) . . . . ? C40 C45 N3 Eu1 -2.7(11) . . . . ? O4 Eu1 N3 C49 30.0(8) . . . . ? O3 Eu1 N3 C49 -29.9(10) . . . . ? O2 Eu1 N3 C49 -38.7(8) . . . . ? O5 Eu1 N3 C49 103.7(8) . . . . ? O1 Eu1 N3 C49 -104.8(8) . . . . ? O6 Eu1 N3 C49 92.5(8) . . . . ? N2 Eu1 N3 C49 -171.2(7) . . . . ? N1 Eu1 N3 C49 -175.6(8) . . . . ? O4 Eu1 N3 C45 -147.5(8) . . . . ? O3 Eu1 N3 C45 152.6(7) . . . . ? O2 Eu1 N3 C45 143.8(8) . . . . ? O5 Eu1 N3 C45 -73.8(7) . . . . ? O1 Eu1 N3 C45 77.8(7) . . . . ? O6 Eu1 N3 C45 -84.9(8) . . . . ? N2 Eu1 N3 C45 11.3(8) . . . . ? N1 Eu1 N3 C45 6.9(7) . . . . ? C78 C79 O4 Eu1 -11(4) . . . . ? C80 C79 O4 Eu1 174.8(10) . . . . ? O3 Eu1 O4 C79 16.9(19) . . . . ? O2 Eu1 O4 C79 -60.3(19) . . . . ? O5 Eu1 O4 C79 162(2) . . . . ? O1 Eu1 O4 C79 -40(2) . . . . ? O6 Eu1 O4 C79 91.6(19) . . . . ? N2 Eu1 O4 C79 77(2) . . . . ? N3 Eu1 O4 C79 -129.9(19) . . . . ? N1 Eu1 O4 C79 -168.9(17) . . . . ? C62 C61 O5 Eu1 -21(2) . . . . ? C60 C61 O5 Eu1 160.8(7) . . . . ? O4 Eu1 O5 C61 -53.8(11) . . . . ? O3 Eu1 O5 C61 -5.0(12) . . . . ? O2 Eu1 O5 C61 -103.7(11) . . . . ? O1 Eu1 O5 C61 154.2(10) . . . . ? O6 Eu1 O5 C61 23.6(10) . . . . ? N2 Eu1 O5 C61 85.6(10) . . . . ? N3 Eu1 O5 C61 -147.8(11) . . . . ? N1 Eu1 O5 C61 144.4(11) . . . . ? C62 C63 O6 Eu1 -7(3) . . . . ? C64 C63 O6 Eu1 -175.1(9) . . . . ? O4 Eu1 O6 C63 69.7(17) . . . . ? O3 Eu1 O6 C63 148.5(18) . . . . ? O2 Eu1 O6 C63 106.6(17) . . . . ? O5 Eu1 O6 C63 -9.9(16) . . . . ? O1 Eu1 O6 C63 -155.4(16) . . . . ? N2 Eu1 O6 C63 -120.6(17) . . . . ? N3 Eu1 O6 C63 1.3(19) . . . . ? N1 Eu1 O6 C63 -70.2(17) . . . . ? O6 C63 C64 F14 -168(2) . . . . ? C62 C63 C64 F14 24(3) . . . . ? O6 C63 C64 F15 70(2) . . . . ? C62 C63 C64 F15 -98(2) . . . . ? O6 C63 C64 F14' 143(2) . . . . ? C62 C63 C64 F14' -25(3) . . . . ? O6 C63 C64 F15' 25(2) . . . . ? C62 C63 C64 F15' -143(2) . . . . ? O6 C63 C64 F13 -49(3) . . . . ? C62 C63 C64 F13 144(2) . . . . ? O6 C63 C64 F13' -96(3) . . . . ? C62 C63 C64 F13' 96(3) . . . . ? _diffrn_measured_fraction_theta_max 0.981 _diffrn_reflns_theta_full 25.00 _diffrn_measured_fraction_theta_full 0.981 _refine_diff_density_max 1.829 _refine_diff_density_min -1.984 _refine_diff_density_rms 0.108